US11839079B2 - Three-dimensional memory devices and methods for forming the same - Google Patents
Three-dimensional memory devices and methods for forming the same Download PDFInfo
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- US11839079B2 US11839079B2 US16/863,080 US202016863080A US11839079B2 US 11839079 B2 US11839079 B2 US 11839079B2 US 202016863080 A US202016863080 A US 202016863080A US 11839079 B2 US11839079 B2 US 11839079B2
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B43/23—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B43/27—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
- H10B41/35—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region with a cell select transistor, e.g. NAND
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
- H10B43/35—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region with cell select transistors, e.g. NAND
Definitions
- Embodiments of the present disclosure relate to contact structures having conductive portions in substrate in three-dimensional (3D) memory devices, and methods for forming the 3D memory devices.
- Planar memory cells are scaled to smaller sizes by improving process technology, circuit design, programming algorithm, and fabrication process.
- feature sizes of the memory cells approach a lower limit
- planar process and fabrication techniques become challenging and costly.
- memory density for planar memory cells approaches an upper limit.
- a 3D memory architecture can address the density limitation in planar memory cells.
- 3D memory architecture includes a memory array and peripheral devices for controlling signals to and from the memory array.
- Embodiments of 3D memory devices and methods for forming the 3D memory devices are provided.
- the memory device includes a stack structure having interleaved a plurality of conductor layers and a plurality of dielectric layers over a substrate along a vertical direction.
- the memory device also includes a channel structure extending in the stack structure along the vertical direction.
- a thickness of at least one of the plurality of dielectric layers is nominally inversely proportional to a width of the channel structure at a same depth.
- the memory device includes a stack structure having interleaved a plurality of conductor layers and a plurality of dielectric layers over a substrate along a vertical direction.
- the memory device also includes a channel structure extending in the stack structure and divided into a plurality of portions along the vertical direction. Thicknesses of dielectric layers corresponding to each of the plurality of portions are nominally inversely proportional to a width of the channel structure in the respective portion.
- the method includes the following operations.
- a dielectric stack is formed over a substrate.
- the dielectric stack includes interleaved a plurality of sacrificial layers and dielectric layers along a vertical direction.
- a thickness of at least one of the plurality of dielectric layers is different from thicknesses of other dielectric layers.
- a channel structure is formed in the dielectric stack such that a width of the channel structure is nominally inversely proportional to the at least one of the plurality of dielectric layers.
- the plurality of sacrificial layers are replaced with a plurality of conductor layers.
- FIG. 1 illustrates a cross-sectional view of an exemplary 3D memory device, in which a width of a lower portion of a channel hole is less than a width of an upper portion of the channel hole, according to embodiments of the present disclosure.
- FIGS. 2 - 4 illustrate exemplary enlarged views of region A in FIG. 1 , according to embodiments of the present disclosure.
- FIG. 5 illustrates a cross-sectional view of an exemplary 3D memory device, in which a width of a channel hole decreases as a depth of the channel hole increases, according to embodiments of the present disclosure.
- FIG. 6 illustrates an exemplary enlarged view of region A in FIG. 5 , according to embodiments of the present disclosure.
- FIG. 7 illustrates a cross-sectional view of an exemplary 3D memory device, in which a channel hole includes a narrower portion, according to embodiments of the present disclosure.
- FIG. 8 illustrates an enlarged diagram of region A in FIG. 7 , according to embodiments of the present disclosure.
- FIG. 9 illustrates a cross-sectional view of an exemplary 3D memory device, in which a channel hole includes a wider portion, according to embodiments of the present disclosure.
- FIG. 10 illustrates an enlarged view of region A in FIG. 9 , according to embodiments of the present disclosure.
- FIG. 11 illustrates a cross-sectional view of an exemplary 3D memory device, in which a width of a lower portion of a channel structure is less than a width of an upper portion of the channel structure, according to embodiments of the present disclosure.
- FIGS. 12 - 14 illustrate exemplary enlarged views of region A in FIG. 11 , according to embodiments of the present disclosure.
- FIG. 15 illustrates a cross-sectional view of an exemplary 3D memory device, in which a width of a channel structure decreases as a depth of the channel structure increases, according to embodiments of the present disclosure.
- FIG. 16 illustrates an exemplary enlarged view of region A in FIG. 15 , according to embodiments of the present disclosure.
- FIG. 17 illustrates a cross-sectional view of an exemplary 3D memory device, in which a channel structure includes a narrower portion, according to embodiments of the present disclosure.
- FIG. 18 illustrates an enlarged diagram of region A in FIG. 17 , according to embodiments of the present disclosure.
- FIG. 19 illustrates a cross-sectional view of an exemplary 3D memory device, in which a channel structure includes a wider portion, according to embodiments of the present disclosure.
- FIG. 20 illustrates an enlarged view of region A in FIG. 19 , according to embodiments of the present disclosure.
- FIG. 21 A illustrates a flowchart of an exemplary fabrication method for forming a 3D memory device, according to embodiments of the present disclosure.
- FIG. 21 B illustrates a flowchart of a detailed exemplary fabrication method for forming a 3D memory device, according to embodiments of the present disclosure.
- FIGS. 22 - 28 illustrate an exemplary fabrication method for forming a 3D memory device, according to embodiments of the present disclosure.
- references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” “some embodiments,” etc. indicate that the embodiment described may include a particular feature, structure, or characteristic, but every embodiment may not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Further, when a particular feature, structure or characteristic is described in connection with an embodiment, it would be within the knowledge of a person skilled in the pertinent art to affect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
- terminology may be understood at least in part from usage in context.
- the term “one or more” as used herein, depending at least in part upon context may be used to describe any feature, structure, or characteristic in a singular sense or may be used to describe combinations of features, structures or characteristics in a plural sense.
- terms, such as “a,” “an,” or “the,” again, may be understood to convey a singular usage or to convey a plural usage, depending at least in part upon context.
- the term “based on” may be understood as not necessarily intended to convey an exclusive set of factors and may, instead, allow for existence of additional factors not necessarily expressly described, again, depending at least in part on context.
- the term “nominal/nominally” refers to a desired, or target, value of a characteristic or parameter for a component or a process operation, set during the design phase of a product or a process, together with a range of values above and/or below the desired value.
- the range of values can be due to slight variations in manufacturing processes or tolerances.
- the term “about” indicates the value of a given quantity that can vary based on a particular technology node associated with the subject semiconductor device. Based on the particular technology node, the term “about” can indicate a value of a given quantity that varies within, for example, 10-30% of the value (e.g., ⁇ 10%, ⁇ 20%, or ⁇ 30% of the value).
- a staircase structure refers to a set of surfaces that include at least two horizontal surfaces (e.g., along x-y plane) and at least two (e.g., first and second) vertical surfaces (e.g., along z-axis) such that each horizontal surface is adjoined to a first vertical surface that extends upward from a first edge of the horizontal surface, and is adjoined to a second vertical surface that extends downward from a second edge of the horizontal surface.
- a “step” or “staircase” refers to a vertical shift in the height of a set of adjoined surfaces.
- the term “staircase” and the term “step” refer to one level of a staircase structure and are used interchangeably.
- a horizontal direction can refer to a direction (e.g., the x-axis or the y-axis) parallel with the top surface of the substrate (e.g., the substrate that provides the fabrication platform for the formation of structures over it), and a vertical direction can refer to a direction (e.g., the z-axis) perpendicular to the top surface of the structure.
- proportional and “nominally proportional” are interchangeable. In the present disclosure, “proportional” refers to corresponding to the size, degree, intensity, or similar, and should not be limited to a specific number or ratio. As used herein, terms “inversely proportional” and “nominally inversely proportional” are interchangeable. In the present disclosure, “inversely” refers to inversely corresponding to the size, degree, intensity, or similar, and should not be limited to a specific number or ratio.
- a channel hole formed in a stack structure of the 3D memory device becomes higher.
- the topography of the bottom portions of the channel holes is often undesirable. Defects, such as distortion or striation, often exist in the topography.
- a width of a channel hole may vary.
- the critical dimension (CD) of the lower portion can be less than the CD of the upper portion.
- the thicknesses of dielectric layers in a stack structure are the same along a vertical direction.
- the speed to program (PGM)/erase (ERS) a memory cell corresponding to a portion of a channel structure with a smaller width is often higher than the speed to program/erase a memory cell corresponding to a portion of a channel structure with a larger width.
- PGM speed to program
- ERS erase
- These memory cells corresponding to narrower channel structures are more susceptible to the disturbance caused by read operations and have undesirable erase state coupling effect.
- the properties of memory cells at different parts of the 3D memory device vary, resulting in the distribution of threshold voltage (Vt) of the memory cells to be undesirably wide, impairing the performance of the 3D memory device.
- the present disclosure provides a 3D memory device and fabrication methods for forming the 3D memory device to solve the described issues in the existing 3D memory device.
- the thicknesses of the dielectric layers which function as the gate dielectric layers of the memory cells, vary as the width of a channel structure, e.g., in contact with the dielectric layers, vary along the vertical direction.
- the variation of the thicknesses of the dielectric layers has an opposite (e.g., inverse) trend versus the variation of the width of the channel structure.
- the thicknesses of the dielectric layers decrease as the width of the channel structure increases, and the thicknesses of the dielectric layers increase as the width of the channel structure decreases.
- the thickness of a dielectric layer can be inversely proportional to or nominally inversely proportional to the width of the channel structure at the same depth.
- the variation of the thicknesses of the dielectric layers can compensate for the impact caused by the variation of the width of the channel structure and the undesirable topography.
- the erase state coupling effect of the memory cells can be improved, and the performance of the memory cells have improved uniformity and stability.
- the threshold voltages of the memory cells have improved uniformity.
- the etching process to form channel holes can be less restrictive, improving fabrication stability and process window.
- FIG. 28 illustrates a cross-sectional view of an exemplary 3D memory device 2800 , according to some embodiments.
- 3D memory device 2800 may include a substrate 13 , a stack structure 12 over substrate 13 , and a channel structure 20 extending in stack structure 12 and into substrate 13 .
- 3D memory device 2800 includes at least one source contact structure (not shown) extending in stack structure 12 and into substrate 13 .
- Substrate 13 may include any suitable semiconductor material(s).
- substrate 13 includes at least one of silicon, germanium (Ge), silicon germanium (SiGe), silicon-on-insulator (SOI), germanium-on-insulator (GOI), etc.
- substrate 13 includes a monocrystalline silicon wafer.
- substrate 13 includes an ion-doped substrate.
- substrate 13 may be a P-type doped substrate or an N-type doped substrate.
- Stack structure 12 may include interleaved a plurality of conductor layers 121 and dielectric layers 112 arranged over substrate 13 .
- Conductor layers 121 and dielectric layers 112 may be arranged alternatingly along a vertical direction (e.g., the z-axis).
- Conductor layers 121 may include any suitable conductor material such as tungsten, polysilicon, cobalt, copper, silicides, and/or aluminum.
- Dielectric layers 112 may include any suitable dielectric material such as silicon oxide and/or silicon oxynitride.
- Channel structure 20 may include a semiconductor plug 15 at the bottom and in contact with substrate 13 , a functional sidewall 16 (or a functional layer 16 ) over and in contact with semiconductor plug 15 , and a channel layer 17 over functional sidewall 16 and in contact with semiconductor plug 15 .
- Semiconductor plug 15 may be a deposited and/or an epitaxially grown semiconductor layer at the bottom of channel structure 20 . In some embodiments, semiconductor plug 15 forms a channel region for the source line transistors. Semiconductor plug 15 may include a suitable semiconductor material.
- substrate 13 includes silicon and semiconductor plug 15 includes single crystalline silicon.
- functional sidewall 16 includes a blocking layer 161 , a charge trapping layer 162 over blocking layer 161 , and a tunneling layer 163 over charge trapping layer 162 .
- channel layer 17 is over charge trapping layer 162 .
- blocking layer 161 , charge trapping layer 162 , tunneling layer 163 , and channel layer 17 are arranged radially and inwardly in channel structure 20 .
- channel structure 20 includes a dielectric core that partially or fully fills up the space surrounded by channel layer 17 .
- blocking layer 161 includes, but not limited to, silicon oxide, and/or hafnium oxide.
- charge trapping layer 162 includes, but not only limited to, silicon oxide, silicon oxynitride, silicon nitride, silicon, and/or hafnium oxide.
- tunneling layer 163 includes silicon oxide, silicon oxynitride, and/or hafnium oxide.
- channel layer 17 includes polycrystalline silicon, single crystalline silicon, and/or amorphous silicon. In some embodiments, channel layer 17 further includes other semiconductor material(s).
- the dielectric core includes oxide dielectric materials, such as silicon oxide.
- the at least one source contact structure extends laterally and vertically in stack structure 12 .
- Each source contact structure may include an insulating structure and a contact in the insulating structure.
- the insulating structure may include any suitable dielectric material such as silicon oxide, and the contact may include one or more of tungsten, polysilicon, cobalt, aluminum, and copper.
- the contact may be in contact and conductively connected to substrate 13 .
- the source contact structure may include a doped region in substrate 13 at the bottom of the GLS. The contact may be conductively connected to substrate 13 through the doped region (if any).
- At least one dielectric layer 112 has a thickness that is nominally inversely proportional to a width of channel structure 20 at the same depth.
- a width of a channel structure/hole is defined as a distance between sidewalls of the channel structure/hole along a horizontal direction, e.g., the x-axis
- a depth of a channel hole/structure is defined as a distance between the top surface of stack structure 12 and any point between the top and bottom surfaces of stack structure 12 .
- a depth range is defined as a range of different depths along the vertical direction.
- the width of channel structure 20 may vary along the vertical direction. The variation may be limited to only a part of channel structure 20 or the entire channel structure 20 .
- the variation of the thickness of at least a portion of dielectric layers 112 has the inverse/opposite trend versus the variation of the width of channel structure 20 .
- the width of channel structure 20 may vary in a trend (e.g., increasing, decreasing, unchanged) in a depth range along the vertical direction, and the thicknesses of dielectric layers 112 in this depth range may vary in an opposite trend.
- the thicknesses of at least a portion of dielectric layers 112 are nominally inversely proportional to the width of channel structure 20 at respective depths.
- the thicknesses of all dielectric layers 112 are nominally inversely proportional to the width of channel structure 20 at the respective (e.g., same) depth. Details of the variation of the width of channel structure/hole and that of the thicknesses of dielectric layers are described below.
- FIGS. 1 - 10 of the present disclosure each illustrates a cross-sectional view of a 3D memory device before a gate replacement, according to some embodiments.
- FIGS. 11 - 20 of the present disclosure each illustrates a cross-sectional view of the 3D memory device after a gate replacement, according to some embodiments.
- a 3D memory device may include a stack structure 11 that has interleaved a plurality of sacrificial layers 111 and dielectric layers 112 along a vertical direction, e.g., the z-axis or also referred to as a thickness direction, over a substrate 13 .
- Stack structure 11 may be referred to as a dielectric stack.
- the 3D memory device may also include one or more channel holes 14 extending through stack structure 11 along the vertical direction.
- the width of channel hole 14 may vary along the vertical direction, e.g., at different depths. In some embodiments, the variation of thicknesses of dielectric layers 112 may have the opposite trend versus the width of the channel hole 14 along the vertical direction.
- the width of a portion (or the entirety) of channel hole 14 may decrease (or increase) along the vertical direction, and the thicknesses of a portion (or the entirety) of dielectric layers 112 at the same depths may increase (or decrease) along the vertical direction.
- a thickness of dielectric layer 112 is inversely proportional to (or nominally inversely proportional to) a width of channel hole 14 at the same depth.
- stack structure 11 can be divided into a plurality of portions. Accordingly, channel hole 14 may be divided into the plurality of portions. In some embodiments, the width of channel hole 14 in each portion may be nominally the same. In each portion, the thicknesses of dielectric layers 112 may vary in the opposite trend versus the width of channel hole 14 . In some embodiments, the variation of the thicknesses of dielectric layers 112 in each portion has the opposite trend versus the variation of the width of channel hole 14 in the same portion. In some embodiments, the thicknesses of dielectric layers 112 in each portion are nominally inversely proportional to the width of channel hole 14 in the same portion. In some embodiments, stack structure 11 is divided into an upper portion and a lower portion along the vertical direction.
- the ratio (e.g., a first ratio) of the total thickness of the upper portion of stack structure 11 to the total thickness of stack structure 11 may be any suitable fraction between 0 and 1, depending on the fabrication process and/or design.
- the ratio (e.g., a second ratio) of the total thickness of the lower portion of stack structure 11 to the total thickness of stack structure 11 may be any suitable fraction between 0 and 1, depending on the fabrication process and/or design.
- the sum of the first ratio and the second ratio is equal to 1.
- the upper portion and the lower portion of stack structure 11 may each be one half of stack structure 11 .
- the is, the lower portion of stack structure 11 may be from a bottom surface of stack structure 11 to a middle position of stack structure 11 .
- a portion above the lower portion of stack structure 11 is the upper portion of stack structure 11 . That is, the total thicknesses of the lower portion and the upper portion of stack structure 11 may each be one half of the total thickness of stack structure 11 .
- the thickness of the lower portion of stack structure 11 may be less than or equal to 1 ⁇ 3 of the total thickness of stack structure 11 .
- Sacrificial layers 111 and dielectric layers 112 may include different materials.
- dielectric layers 112 include silicon dioxide, low-k silicon dioxide, and/or silicon oxycarbide (SiCO), etc.
- sacrificial layers 111 include silicon nitride, polycrystalline silicon, carbon, and/or organics materials.
- the width of the lower portion of channel hole 14 is less than the width of the upper portion of channel hole 14 .
- the width of the lower portion of channel hole 14 is less than the width of the upper portion of channel hole 14 .
- at least one of the following scenarios can happen.
- the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 , the thickness of each of dielectric layers 112 in the lower portion is the same, and the thickness of each of dielectric layers 112 in the upper portion is the same.
- the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 , and the thicknesses of dielectric layers 112 located in the lower portion decreases, e.g., gradually from bottom to top or layer by layer, as the depth decreases.
- the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 , and sacrificial layers 111 and dielectric layers 112 located in the lower portion of are divided into a plurality of divisions 113 .
- Each division 113 may include a number of (e.g., at least one) dielectric layers 112 , and the thicknesses of dielectric layers 112 in the same division may be the same.
- the thicknesses of dielectric layers 112 in different divisions 113 may decrease, e.g., gradually from bottom to top, as the depth decreases.
- the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 , and the thicknesses of dielectric layers 112 located in the upper portion increase, e.g., gradually from top to bottom or layer by layer, as the depth increases. In some embodiments, the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 , and sacrificial layers 111 and dielectric layers 112 located in the upper portion are divided into a plurality of divisions, similar to divisions 113 .
- Each division may include a number of dielectric layers 112 , and the thicknesses of dielectric layers 112 in the same division may be the same.
- the thicknesses of dielectric layers 112 in different divisions may increase, e.g., gradually from top to bottom, as depth increases.
- the width of the upper portion of channel hole 14 is less than the width of the lower portion of channel hole 14 . In some embodiments, when the width of the upper portion of channel hole 14 is less than the width of the lower portion of channel hole 14 , at least one of the following scenarios can happen. In some embodiments, the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 , the thickness of each dielectric layer 112 in the lower portion is the same, and the thickness of each dielectric layer 112 in the upper portion is the same.
- the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 , and the thicknesses of dielectric layers 112 in the upper portion decreases, e.g., gradually from top to bottom or layer by layer, as the depth increases.
- the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11
- sacrificial layers 111 and dielectric layers 112 located in the upper portion may form a number of divisions, similar to divisions 113 . Each division may include a number of dielectric layers 112 .
- the thickness of each dielectric layer 112 in the same division is the same, and the thicknesses of dielectric layers 112 in different divisions decrease, e.g., gradually from top to bottom, as the depth increases.
- the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11 , and the thicknesses of dielectric layers 112 located in the lower portion increase, e.g., gradually from bottom to top or layer by layer, as the depth decreases.
- the thicknesses of dielectric layers 112 located in the upper portion of stack structure 11 are greater than the thicknesses of dielectric layers 112 located in the lower portion of stack structure 11
- sacrificial layers 111 and dielectric layers 112 located in the lower portion may include a number of divisions, similar to divisions 113 .
- Each division may include a number of dielectric layers 112 .
- the thickness of each dielectric layer 112 in the same division is the same, and the thicknesses of dielectric layers 112 in different divisions increase, e.g., gradually from bottom to top, as the depth decreases.
- the width of channel hole 14 decreases as the depth increases, and the thicknesses of dielectric layers 112 corresponding to the at least one portion increase as the depth increases, as shown in FIGS. 5 and 6 .
- the variation of thicknesses of dielectric layers 112 may inversely correspond to the variation of the width of channel hole 14 .
- the width of channel hole 14 corresponding to region A may gradually decrease as the depth increases, and the thicknesses of dielectric layers 112 may gradually increase as the depth increases.
- the thickness of dielectric layer 112 is nominally inversely proportional to the width of channel hole 14 of the same depth.
- channel hole 14 may be divided into a plurality of portions along the vertical direction, the thicknesses of dielectric layers 112 in at least one of the portions may vary inversely versus the trend described in region A. In some embodiments, the thicknesses of dielectric layers 112 in each portion may vary inversely versus the trend described in region A. In some embodiments, the width of the entire channel hole 14 may decrease as the depth increases, and the thicknesses of all dielectric layers 112 increase, e.g., gradually from top to bottom or layer by layer, as the depth increases in stack structure 11 .
- the width of channel hole 14 increases as the depth increases, and the thicknesses of dielectric layers 112 decreases as the depth increases.
- the variation of thicknesses of dielectric layers 112 may inversely correspond to the variation of the width of channel hole 14 .
- the width of channel hole 14 may gradually increase as the depth increases, and the thicknesses of dielectric layers 112 may gradually decrease as the depth increases.
- the thickness of dielectric layer 112 is nominally inversely proportional to the width of channel hole 14 of the same depth.
- channel hole 14 may be divided into a plurality of portions along the vertical direction, the thicknesses of dielectric layers 112 in at least one of the portions may vary in accordance with the trend described above. In some embodiments, the thicknesses of dielectric layers 112 in each portion may vary in accordance with the trend described above. In some embodiments, the width of the entire channel hole 14 may increase as the depth increases, and the thicknesses of all dielectric layers 112 decrease, e.g., gradually from top to bottom or layer by layer, as the depth increases in stack structure 11 .
- channel hole 14 includes one or more narrower portions 141 .
- narrower portion 141 may be formed by protruding portions on the sidewalls of channel hole 14 .
- the lateral distance between the sidewalls of narrower portion 141 may be less than the lateral distance between the sidewalls of channel hole 14 without the protruding portions, as shown in FIGS. 7 and 8 .
- Narrower portion 141 may be at any suitable location between the top and bottom surfaces of channel hole 14 (or top and bottom surfaces of stack structure 11 ).
- the width of narrower portion 141 is less than the width at any other location in channel hole 14 .
- the number of the narrower portions 141 in channel hole 14 may be depending on the design and/or fabrication and should not be limited by the embodiments of the present disclosure.
- the thicknesses of dielectric layers 112 corresponding to narrower portion 141 are greater than the thicknesses of other dielectric layers 112 located in stack structure 11 . That is, the thicknesses of dielectric layers 112 at the same depth(s) of narrower portion 141 may be greater than the thicknesses of other dielectric layers 112 located in stack structure 11 .
- channel hole 14 includes one or more wider portions 142 .
- wider portion 142 may be formed by recessed portions on the sidewalls of channel hole 14 .
- the lateral distance between the sidewalls of wider portion 142 may be greater than the lateral distance between the sidewalls of channel hole 14 without the recessed portions, as shown in FIGS. 9 and 10 .
- Wider portion 142 may be at any suitable location between the top and bottom surfaces of channel hole 14 (or top and bottom surfaces of stack structure 11 ).
- the width of wider portion 142 is greater than the width at any other location in channel hole 14 .
- the number of the wider portions 142 in channel hole 14 may be depending on the design and/or fabrication and should not be limited by the embodiments of the present disclosure.
- the thicknesses of dielectric layers 112 corresponding to wider portion 142 are less than the thicknesses of other dielectric layers 112 located in stack structure 11 . That is, the thicknesses of dielectric layers 112 at the same depth(s) of wider portion 142 may be less than the thicknesses of other dielectric layers 112 located in stack structure 11 .
- the thicknesses of dielectric layers 112 may determine the thicknesses of the gate dielectric layers each between a pair of conductor layers (e.g., gate electrodes).
- the thicknesses of the dielectric layers may have an impact on the speed to program/erase memory cells and other parameters such as coupling effects.
- the thicknesses of dielectric layers 112 may be nominally inversely proportional to the width of channel holes 14 .
- a greater width of channel hole 14 may correspond to smaller thicknesses of dielectric layers 112 at the same depth(s), and a smaller width of channel hole 14 may correspond to greater thicknesses of dielectric layers 112 at the same depth(s).
- FIGS. 11 - 20 illustrate stack structure 12 of the 3D memory device after the gate replacement process, according to some embodiments.
- Stack structure 12 illustrated in FIGS. 11 - 20 may respectively be formed from stack structures 11 illustrated in FIGS. 1 - 10 , by the gate replacement process.
- sacrificial layers 111 may be replaced by conductor layers 121 , which may include a suitable conductive material such as metal (e.g., tungsten, cobalt, etc.) and/or silicon.
- conductor layers 121 include doped polycrystalline silicon. For example, in FIG.
- conductor layers 121 and dielectric layers 112 in the lower portion of stack structure 12 may include a plurality of divisions 122 , similar to divisions 113 .
- a detailed description of the structures of channel hole 14 and thicknesses of dielectric layers 112 in stack structures 12 may be referred to the description of stack structure 11 in FIGS. 1 - 10 and are not repeated herein.
- FIG. 21 A illustrates a flowchart of an exemplary fabrication method 2101 for forming a stack structure 12 , according to some embodiments.
- FIG. 21 B illustrates a flowchart of a detailed fabrication method of method 2100 , according to some embodiments. It is understood that the operations shown in methods 2100 and 2101 are not exhaustive and that other operations can be performed as well before, after, or between any of the illustrated operations. Further, some of the operations may be performed simultaneously, or in a different order than shown in FIGS. 21 A and 21 B .
- a dielectric stack is formed over a substrate (Operation 2103 ).
- the dielectric layer includes interleaved a plurality of sacrificial layers and dielectric layers along the vertical direction, and a thickness of at least one dielectric layer is different from the thicknesses of other dielectric layers.
- FIG. 22 illustrates a corresponding structure.
- a substrate 13 can first be provided (Operation 2102 ).
- a substrate 13 may include any suitable material such as a semiconductor material, e.g., silicon, germanium (Ge), silicon germanium (SiGe), silicon-on-insulator (SOI), and/or germanium-on-insulator (GOI).
- substrate 13 includes a monocrystalline silicon wafer.
- substrate 13 is an ion-doped substrate.
- substrate 13 may be a P-type doped substrate or an N-type doped substrate.
- a dielectric stack can be formed on the substrate (Operation 2104 ). As shown in FIG. 22 , a stack structure 11 can be formed over substrate 13 . As previously described, stack structure 11 may be a dielectric stack and include a plurality of sacrificial layers 111 and dielectric layers 112 arranged alternatingly along the vertical direction on substrate 13 . Stack structure 11 may be formed by depositing sacrificial layers 111 and dielectric layers 112 repeatedly and alternatingly along the vertical direction using a suitable deposition method such as physical vapor deposition (PVD), chemical vapor deposition (CVD), and/or atomic layer deposition (ALD). In some embodiments, sacrificial layers 111 include silicon nitride and dielectric layers 112 include silicon oxide.
- PVD physical vapor deposition
- CVD chemical vapor deposition
- ALD atomic layer deposition
- the thickness of at least one dielectric layer 112 is different from the thicknesses of other dielectric layers 112 .
- the thicknesses of the at least one dielectric layer 112 may vary along the vertical direction in an inverse trend versus any trend(s) described in FIGS. 1 - 20 .
- the thickness of dielectric layers 112 may gradually increase as the depth increases (e.g., from the top to the bottom of stack structure 11 ).
- method 2101 proceeds to Operation 2105 , in which a channel structure is formed in the dielectric stack such that a width of the channel structure is nominally inversely proportional to the at least one dielectric layer.
- FIGS. 23 - 26 illustrate the corresponding structures.
- a channel hole can be formed in the stack structure (Operation 2106 ).
- a channel hole 14 may be formed by any suitable patterning process.
- a bottom of channel hole 14 may expose substrate 13 .
- a patterned mask layer (not shown) is formed on a top surface of stack structure 11 .
- the patterned mask layer may include one or more openings that define the shape and position of channel holes 14 .
- the patterned mask layer may include a patterned photoresist layer and/or any hard etching mask(s).
- a suitable etching process may be performed to remove portions of stack structure 11 based on the patterned mask layer, forming channel holes 14 .
- the etching process may include dry etch and/or wet etch.
- stack structure 11 is etched using dry etch.
- the width of channel hole 14 decreases, e.g., gradually from top to bottom along the direction, as the depth increases.
- more than one patterned mask layers are used to form channel hole 14 with a lower portion and an upper portion (e.g., channel hole 14 shown in FIGS. 1 and 11 ).
- a first patterned mask layer with a smaller opening may first be used to define the lateral dimensions of the lower portion
- a second patterned mask layer with a larger opening may be used to define the lateral dimensions of the upper portion.
- a suitable etching process may be performed after the formation of each patterned mask to form the lower and upper portions of channel hole 14 .
- the etching time of each etching is controlled such that the lower and upper portions of channel hole 14 may have desired lengths along the vertical direction.
- any patterned mask layers may be removed after channel hole 14 is formed.
- the formation of the dielectric stack includes more than one deposition operations separated by one or more patterning/etching.
- the dielectric stack can be deposited incrementally, e.g., portion by portion. Each portion can be etched separately to form a respective portion of channel hole 14 before a subsequent portion of the dielectric stack is deposited.
- More than one patterned mask layers can be used in the formation of channel hole 14 .
- the patterned mask layers may have various dimensions to form channel hole 14 of desired width along the vertical direction.
- the etching time of each etching is controlled such that each portion of channel hole 14 may have desired lengths along the vertical direction.
- the narrower portion, the wider portion, and the portions above and below the narrower/wider portion can be deposited separately.
- Each portion can be etched using a patterned mask layer of a desired dimension before the deposition of the portion above it.
- any patterned mask layers are removed before the deposition of the dielectric stack and after the formation of the dielectric stack.
- a channel structure can be formed in the channel hole (Operation 2108 ).
- a semiconductor plug 15 may be formed at the bottom of channel hole 14 .
- Semiconductor plug 15 may be in contact with substrate 13 .
- semiconductor plug 15 is formed by epitaxial growth and is referred to as an epitaxial layer.
- semiconductor plug 15 is grown in situ at the bottom of channel hole 14 using selective epitaxial growth from substrate 13 .
- semiconductor plug 15 has the same lattice and material as substrate 13 .
- substrate 13 includes silicon
- semiconductor plug 15 includes epitaxial silicon.
- Semiconductor plug 15 may be used to form channel regions for the source line transistors.
- a functional sidewall 16 may be formed over the sidewall surface of channel hole 14 , and a channel layer 17 may be formed on functional sidewalls 16 over, e.g., the top surface of, semiconductor plug 15 .
- FIG. 25 illustrates a cross-sectional view of functional sidewall 16 over the channel hole.
- functional sidewall 16 is also referred to as a functional layer, and includes a blocking layer 161 , a charge trapping layer 162 , and a tunneling layer 163 .
- blocking layer 161 may be formed on the sidewall surface of channel hole 14
- charge trapping layer 162 may be formed over blocking layer 161
- tunneling layer 163 may be formed over charge trapping layer 162 .
- blocking layer 161 includes, but not limited to, silicon oxide, hafnium oxide, etc.
- charge trapping layer 162 includes, but not limited to, silicon oxide, hafnium oxide, etc.
- tunneling layer 163 includes, but not limited to, silicon oxide, hafnium oxide, etc.
- blocking layer 161 , charge trapping layer 162 , and tunneling layer 163 can each be formed using PVD, CVD, and/or ALD.
- blocking layer 161 includes silicon oxide
- charge trapping layer 162 includes silicon nitride
- tunneling layer 163 includes silicon oxynitride and/or silicon oxide.
- blocking layer 161 , charge trapping layer 162 , and tunneling layer 163 are each formed by ALD.
- method 2100 also includes a recess etching process that removes a portion of functional sidewall 16 to expose semiconductor plug 15 , as shown in FIG. 25 .
- FIG. 26 illustrates a cross-sectional view of channel layer 17 over the surfaces of functional sidewall 16 and semiconductor plug 15 .
- channel layer 17 can be formed by PVD, CVD, and/or ALD.
- channel layer 17 includes polycrystalline silicon and is formed by ALD.
- channel layer 17 includes other semiconductor materials.
- method 2100 further includes filling channel hole 14 with a suitable dielectric material (not shown), e.g., a dielectric core.
- a suitable dielectric material e.g., a dielectric core.
- the dielectric core is formed over channel layer 17 , e.g., after channel layer 17 is formed.
- the dielectric core may be formed by PVD, CVD, and/or ALD.
- the dielectric core includes silicon oxide and is formed ALD.
- a channel structure 20 having a semiconductor plug 15 , a functional sidewall 16 , a channel layer 17 , and a dielectric core may be formed.
- method 2101 proceeds to Operation 2107 , in which the plurality of sacrificial layers may be replaced with a plurality of conductor layers.
- FIGS. 27 and 28 illustrate the corresponding structures.
- a gate line slit (GLS, not shown) can be formed in the stack structure (Operation 2110 ).
- the gate line slit may extend vertically and laterally in stack structure 11 , exposing (e.g., extending into) substrate 13 .
- the location of the gate line slit may be determined based on the design and/or fabrication, and is not limited herein.
- the gate line slit may also expose interleaved sacrificial layers 111 and dielectric layers 112 on the sidewalls.
- a patterned mask layer (not shown) may be formed over stack structure 11 .
- the patterned mask layer may include an opening that defines the shape and position of the gate line slit.
- a suitable etching process e.g., dry etching and/or wet etching, can be performed to remove the portion on stack structure 11 exposed by the patterned mask layer, forming the gate line slit.
- stack structure 11 is etched by a dry etching process to form the gate line slit.
- the patterned mask layer may then be removed.
- a plurality of lateral recesses may be formed through the gate line slit (Operation 2112 ).
- sacrificial layers 111 may be removed to form a plurality of lateral recesses 18 .
- sacrificial layers 111 are removed using a wet etching process.
- sacrificial layers 111 may be removed by a wet etching solution that selectively etches sacrificial layers 111 over dielectric layers 112 . That is, the etching rate of sacrificial layers 111 may be higher than the etching rate of dielectric layers 112 , such that the etching of dielectric layers 112 can be negligible.
- Lateral recesses 18 interleaved with dielectric layers 112 , may then be formed.
- a plurality of conductor layers may be formed in the lateral recesses (Operation 2114 ). As shown in FIG. 28 , a plurality of conductor layers 121 may be formed in lateral recesses 18 . Conductor layers 121 may be formed by any suitable methods such as PVD, CVD, and/or ALD. In some embodiments, conductor layers 121 include tungsten and/or polysilicon, and are deposited using ALD. A stack structure 12 may be formed. In some embodiments, conductor layers 121 and channel structures 20 may form a plurality of memory cells, and stack structure 12 is also referred to as a memory stack.
- methods 2101 and 2100 further include filling the GLS with an insulating structure and a contact in the insulating structure.
- the insulating structure may include any suitable dielectric material such as silicon oxide, and the contact may include one or more of tungsten, polysilicon, cobalt, aluminum, and copper.
- the contact may be in contact and conductively connected to substrate 13 .
- a doping process may be performed to form a doped region in substrate 13 at the bottom of the GLS.
- the insulating structure may provide insulation between the contact and surrounding conductor layers 121 .
- the insulating structure, the contact, and the doped region (if any), may function as a source contact structure of the 3D memory device.
- the insulating structure and the contact may each be formed by a suitable deposition method such as CVD, PVD, and/or ALD.
- the doping process may include ion implantation.
- Embodiments of the present disclosure provide a memory device.
- the memory device includes a stack structure having interleaved a plurality of conductor layers and a plurality of dielectric layers over a substrate along a vertical direction.
- the memory device also includes a channel structure extending in the stack structure along the vertical direction.
- a thickness of at least one of the plurality of dielectric layers is nominally inversely proportional to a width of the channel structure at the same depth.
- the channel structure is divided into a lower portion and an upper portion along the vertical direction, a width of the channel structure in the lower portion being less than a width of the channel structure in the upper portion.
- the thicknesses of the dielectric layers in the lower portion are greater than the thicknesses of the dielectric layers in the upper portion.
- the thickness of each of the dielectric layers in the lower portion is the same. In some embodiments, the thickness of each of the dielectric layers in the upper portion is the same.
- the thicknesses of the dielectric layers in the lower portion decrease as the depth decreases.
- the conductor layers and the dielectric layers include at least one first division along the vertical direction, each first division having at least one dielectric layer. In some embodiments, in each of the at least one first division, the thickness of each dielectric layer is the same. In some embodiments, the thicknesses of the dielectric layers in the at least one first division decrease as the depth decreases.
- the thicknesses of the dielectric layers in the upper portion increase as the depth increases.
- the conductor layers and the dielectric layers include at least one second division along the vertical direction, each second division having at least one dielectric layer.
- the thickness of each dielectric layer is the same. In some embodiments, the thicknesses of the dielectric layers in the at least one second division increase as the depth increases.
- the channel structure is divided into a lower portion and an upper portion along the vertical direction, a width of the channel structure in the upper portion being less than a width of the channel structure in the lower portion.
- the thicknesses of the dielectric layers in the upper portion are greater than the thicknesses of the dielectric layers in the lower portion.
- the thickness of each of the dielectric layers in the lower portion is the same. In some embodiment, the thickness of each of the dielectric layers in the upper portion is the same.
- the thicknesses of the dielectric layers in the upper portion decrease as the depth increases.
- the conductor layers and the dielectric layers include at least one first division along the vertical direction, each first division comprising at least one dielectric layer.
- the thickness of each dielectric layer is the same. In some embodiments, the thicknesses of the dielectric layers in the at least one first division decrease as the depth increases.
- the thicknesses of the dielectric layers in the lower portion increase as the depth decreases.
- the conductor layers and the dielectric layers include at least one second division along the vertical direction, each second division comprising at least one dielectric layer.
- the thickness of each dielectric layer is the same. In some embodiments, the thicknesses of the dielectric layers in the at least one second division increase as the depth decreases.
- the width of the channel structure decreases as the depth increases.
- the thicknesses of the dielectric layers increase as the depth increases.
- the width of the channel structure increases as the depth increases.
- the thicknesses of the dielectric layers decrease as the depth increases.
- the channel structure includes a narrower portion between a top surface and a bottom surface of the stack structure, a width of the narrower portion being less than a width of the rest of the channel structure.
- thicknesses of the dielectric layers corresponding to the narrower portion are greater than thicknesses of dielectric layers corresponding to the rest of the channel structure.
- the channel structure includes a wider portion between a top surface and a bottom surface of the stack structure, a width of the wider portion being greater than a width of the rest of the channel structure
- thicknesses of the dielectric layers corresponding to the wider portion are less than thicknesses of dielectric layers corresponding to the rest of the channel structure.
- the channel structure includes a semiconductor plug at a bottom of the channel structure, a blocking layer over a sidewall of the channel structure, a charge trapping layers over the blocking layer, a tunneling layer over the charge trapping layer, a semiconductor layer over the tunneling layer, and a dielectric core over the semiconductor layer.
- Embodiments of the present disclosure provide a memory device.
- the memory device includes a stack structure having interleaved a plurality of conductor layers and a plurality of dielectric layers over a substrate along a vertical direction.
- the memory device also includes a channel structure extending in the stack structure and divided into a plurality of portions along the vertical direction. Thicknesses of dielectric layers corresponding to each of the plurality of portions are nominally inversely proportional to a width of the channel structure in the respective portion.
- the channel structure is divided into a lower portion and an upper portion along the vertical direction, a width of the channel structure in the lower portion being less than a width of the channel structure in the upper portion.
- the thicknesses of the dielectric layers in the lower portion are greater than the thicknesses of the dielectric layers in the upper portion.
- the thickness of each of the dielectric layers in the lower portion is the same. In some embodiments, the thickness of each of the dielectric layers in the upper portion is the same.
- the channel structure is divided into a lower portion and an upper portion along the vertical direction, a width of the channel structure in the upper portion being less than a width of the channel structure in the lower portion.
- the thicknesses of the dielectric layers in the upper portion are greater than the thicknesses of the dielectric layers in the lower portion.
- the thickness of each of the dielectric layers in the lower portion is the same. In some embodiments, the thickness of each of the dielectric layers in the upper portion is the same.
- the channel structure includes a narrower portion between a top surface and a bottom surface of the stack structure, a width of the narrower portion being less than a width of the rest of the channel structure.
- thicknesses of the dielectric layers corresponding to the narrower portion are greater than thicknesses of conductor layers corresponding to the rest of the channel structure.
- the channel structure includes a wider portion between a top surface and a bottom surface of the stack structure, a width of the wider portion being greater than a width of the rest of the channel structure
- thicknesses of the dielectric layers corresponding to the wider portion are less than thicknesses of dielectric layers corresponding to the rest of the channel structure.
- the channel structure includes a semiconductor plug at a bottom of the channel structure, a blocking layer over a sidewall of the channel structure, a charge trapping layers over the blocking layer, a tunneling layer over the charge trapping layer, a semiconductor layer over the tunneling layer, and a dielectric core over the semiconductor layer.
- Embodiments of the present disclosure also provide a method for forming a 3D memory device.
- the method includes the following operations.
- a dielectric stack is formed over a substrate.
- the dielectric stack includes interleaved a plurality of sacrificial layers and dielectric layers along a vertical direction.
- a thickness of at least one of the plurality of dielectric layers is different from thicknesses of other dielectric layers.
- a channel structure is formed in the dielectric stack such that a width of the channel structure is nominally inversely proportional to the at least one of the plurality of dielectric layers.
- the plurality of sacrificial layers are replaced with a plurality of conductor layers.
- the method further includes forming a gate line slit in the dielectric stack.
- Replacing the plurality of sacrificial layers with the plurality of conductor layers includes removing the plurality of sacrificial layers to form a plurality of lateral recesses and depositing a conductor material to fill the plurality of lateral recesses.
- forming the channel structure include forming a channel hole in the dielectric stack, forming a semiconductor plug at a bottom of the channel hole, and forming a functional sidewall over and in contact with the semiconductor plug.
- forming the functional sidewall includes forming a blocking layer over a sidewall of the channel hole, forming a charge trapping layer over the blocking layer, and forming a tunneling layer over the charge trapping layer.
- the method further includes forming a semiconductor layer over the tunneling layer and forming a dielectric core to fill the channel hole.
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CN110379817B (en) | 2020-05-19 |
US20200411544A1 (en) | 2020-12-31 |
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