US1181409A - Process for stabilizing alkaline hydrogen-peroxid solutions. - Google Patents
Process for stabilizing alkaline hydrogen-peroxid solutions. Download PDFInfo
- Publication number
- US1181409A US1181409A US76473813A US1913764738A US1181409A US 1181409 A US1181409 A US 1181409A US 76473813 A US76473813 A US 76473813A US 1913764738 A US1913764738 A US 1913764738A US 1181409 A US1181409 A US 1181409A
- Authority
- US
- United States
- Prior art keywords
- peroxid
- solutions
- bath
- bleaching
- alkaline hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 13
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title description 11
- 230000000087 stabilizing effect Effects 0.000 title description 6
- 238000004061 bleaching Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 159000000003 magnesium salts Chemical class 0.000 description 8
- 239000003513 alkali Substances 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000002244 precipitate Substances 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229940053326 magnesium salt Drugs 0.000 description 4
- 150000003377 silicon compounds Chemical class 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000003518 caustics Substances 0.000 description 3
- 150000002681 magnesium compounds Chemical class 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 235000001055 magnesium Nutrition 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229940091250 magnesium supplement Drugs 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- MKPXGEVFQSIKGE-UHFFFAOYSA-N [Mg].[Si] Chemical compound [Mg].[Si] MKPXGEVFQSIKGE-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- -1 silica compound Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
Description
STATES PATENT onnicn.
i ALOIS SCHAIDHAUF, OF FRANKFORT-ON-THE-MAIN, GERMANY, ASSIGNOR TO ROESSLER & HASSLACHER CHEMICAL COMPANY, OF NEW YORK, N. Y., A
CORPORATION OF GERMANY.
PROCESS FOR STABILIZING ALKALINE HYDROGEN-PEROXID SOLUTIONS.
No Drawing.
by first nearly or entirely neutralizing the alkali by a strong acid or by some suitable salt of neutral reaction, as for instance magnesium chlorid or calcium chlorid.
Such processes have even been applied in those cases in which fibers offering great resistance to alkali have been subjected to bleaching.
It has been considered a settled fact tlat ecompose most quickly at the usual temperature and especially at the high temperatures applied in bleaching processes. The same conditions prevail when an aqueous solution of pure hydrogen-peroxid is diluted to the proper concentration necessary for bleaching processes and for these purposes is furthermore rendered alkaline. Undoubtedly free caustic alkali exerts a strongly decomposing action on the hydrogenperoxid, necessitating, in the case of using sodium-peroxid, the neutralization of the alkali by nearly or absolutely equivalent quantities of strong acid or suitable salts respectively. Such treatment causes the formation of an objectionable mud or sediment in the bath.
I have discovered that the decomposing action of the caustic alkali instead of forming mud or sediment in the bath during the process because of the addition of the considerable quantities of acid or compound respectively, may conveniently be counteracted by slight additions of a soluble mag nesium salt, said compound being insufiicient in quantity to cause the formation of any mud or sediment which in some way or other might play the part of a disturbing elementthe results obtained by the use of soluble magnesium salts are even surpassed by magnesla or magnesium salts in combi- Specification of Letters Patent.
Application filed ma 1, 1918. Serial No. 764,738.
Patented May 2, 1916.
nation with a suitable silica compound or silicates. I
The following experiments illustrate the elficiency of my new process: I
1. 0.2 g. Na O dissolved in 100 cc. of pure water heated for 1 hour at 85 C. had lost all oxygen.
2. 0.2 g. Na Q in 10000. of water plus 0.015 g. crystallized waterglass had lost all oxygen after one hour.
3. 0.2 g. Na Q in 100 cc. of water plus 0.012 g. crystallized MgCl showed, after being at 85 C. for 1 hour, still 40%, for
2 hours, still 10.7%, for 3 hours, still 3.8%, of the original amount of 0 gen.
. 4. 0.2 g. Na O in 100 cc. of water plus 0.015 g. ofcryfiallized waterglass plus 0.012 g. crystalhzed MgCl showed after 1 hour 18% 2 hours 20%, 3 hours 10.3%, of the original amount of oxygen.
In many countries there may be water which occasionally carries the amount of soluble magnesium salt or the silicon-magnesium compound necessary to stabilize the solutions of sodium-peroxid or to respectively counteract the decomposing influence of the caustic alkali on the hydrogen-peroxid solutions. In such cases one need only dissolve the necessary quantity of sodium-peroxid and immediately obtains a stable alkaline bleaching bath. If the water one has at disposal does not containat all the co nst1tuents coming here into question, or if it does not carry the same in proper proportion, or if there is only one of the constituents present, one may quickly ascertam by a simple experiment, which chemicals and what quantities of the same must be added to surely obtain the desired eflect and where in the claims I refer to water naturally containing in solution magnesia or magnesium salts or a suitable magnesium and silicon compound, I mean to includeappended claims debath a soluble magnesium compound in a quantity insuflicient to create a precipitate of mud in said bleaching bath.
2. The process of stabilizing bleaching baths containing hydrogen peroxid in an alkaline solution, consisting in adding to the bath a quantity of a soluble magnesium compound and proportionately of a soluble silicon compound, said quantity being insufficient to create a precipitate of mud in the bleaching bath.
3. The process of stabilizing bleaching baths containing hydrogen peroxid in an alkaline solution, consisting in adding to the bath a quantity of a soluble magnesium compound and proportionately of a soluble silicate, said quantity being insuilicient to 1c)reate a precipitate of mud in the bleaching ath.
4. The process of stabilizing bleaching baths containing hydrogen Peroxid in an alkaline solution, consisting in adding to the bath a quantity of a soluble magnesium salt, and proportionately of a soluble silicate, said quantity being insufficient to create a precipitate of mud in the bleaching bath.
5. The process of stabilizing bleaching baths containing hydrogen peroxid'in an alkaline solution, consisting in adding to the bath a quantity of a soluble magnesium salt and proportionately of a soluble silicon compound, said quantity being insufiicient to create a precipitate of mud in the bleaching bath.
6. The process for making a stable bath containing hydrogen peroxid in an alkaline solution, consisting in dissolving sodium peroxid in water containing in solution magnesia, or magnesium salts.
7. The process for making a stable bath containing hydrogen peroxid in an alkaline solution, consisting 1n dissolving sodium peroxid in water naturally containing in solution a suitable magnesium and silicon compound.
In testimony whereof I have signed my name to this specification in the presence of two subscribing witnesses.
ALOIS SCHAIDHAUF. Witnesses:
JEAN GRUND, CARL GRUND.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76473813A US1181409A (en) | 1913-05-01 | 1913-05-01 | Process for stabilizing alkaline hydrogen-peroxid solutions. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76473813A US1181409A (en) | 1913-05-01 | 1913-05-01 | Process for stabilizing alkaline hydrogen-peroxid solutions. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1181409A true US1181409A (en) | 1916-05-02 |
Family
ID=3249384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US76473813A Expired - Lifetime US1181409A (en) | 1913-05-01 | 1913-05-01 | Process for stabilizing alkaline hydrogen-peroxid solutions. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1181409A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2838459A (en) * | 1955-02-01 | 1958-06-10 | Pennsalt Chemicals Corp | Stabilization of solutions containing peroxygen compounds |
| US3437599A (en) * | 1966-10-28 | 1969-04-08 | Ppg Industries Inc | Hydrogen peroxide decomposition control with alkaline earth metal carbonates |
-
1913
- 1913-05-01 US US76473813A patent/US1181409A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2838459A (en) * | 1955-02-01 | 1958-06-10 | Pennsalt Chemicals Corp | Stabilization of solutions containing peroxygen compounds |
| US3437599A (en) * | 1966-10-28 | 1969-04-08 | Ppg Industries Inc | Hydrogen peroxide decomposition control with alkaline earth metal carbonates |
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