US11753713B2 - Methods for coating a component - Google Patents
Methods for coating a component Download PDFInfo
- Publication number
- US11753713B2 US11753713B2 US17/380,444 US202117380444A US11753713B2 US 11753713 B2 US11753713 B2 US 11753713B2 US 202117380444 A US202117380444 A US 202117380444A US 11753713 B2 US11753713 B2 US 11753713B2
- Authority
- US
- United States
- Prior art keywords
- component
- slurry
- maskant
- volume
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000000034 method Methods 0.000 title claims abstract description 75
- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 239000011248 coating agent Substances 0.000 title claims abstract description 38
- 239000002002 slurry Substances 0.000 claims abstract description 48
- 239000002245 particle Substances 0.000 claims abstract description 36
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 30
- 239000010703 silicon Substances 0.000 claims abstract description 30
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 14
- 239000012530 fluid Substances 0.000 claims abstract description 14
- 230000008569 process Effects 0.000 claims abstract description 11
- 238000000151 deposition Methods 0.000 claims abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 6
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 5
- 230000000873 masking effect Effects 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 21
- 239000011230 binding agent Substances 0.000 claims description 19
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000004014 plasticizer Substances 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000011153 ceramic matrix composite Substances 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000005422 blasting Methods 0.000 claims description 6
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- 235000019439 ethyl acetate Nutrition 0.000 claims description 6
- 230000008021 deposition Effects 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 235000011054 acetic acid Nutrition 0.000 claims description 3
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 claims description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 229920001448 anionic polyelectrolyte Polymers 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 150000001768 cations Chemical class 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 125000000879 imine group Chemical group 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
- 229920000867 polyelectrolyte Polymers 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 10
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000567 combustion gas Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000011236 particulate material Substances 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- -1 Textron's SCS-6) Chemical compound 0.000 description 3
- 235000011089 carbon dioxide Nutrition 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- 229910052814 silicon oxide Inorganic materials 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- 229910052693 Europium Inorganic materials 0.000 description 2
- 229910052688 Gadolinium Inorganic materials 0.000 description 2
- 229910052689 Holmium Inorganic materials 0.000 description 2
- 229910052765 Lutetium Inorganic materials 0.000 description 2
- 229910052779 Neodymium Inorganic materials 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 229910052773 Promethium Inorganic materials 0.000 description 2
- 229910052772 Samarium Inorganic materials 0.000 description 2
- 229910052771 Terbium Inorganic materials 0.000 description 2
- 229910052775 Thulium Inorganic materials 0.000 description 2
- 229910052769 Ytterbium Inorganic materials 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004814 ceramic processing Methods 0.000 description 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 2
- 238000005328 electron beam physical vapour deposition Methods 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 2
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 2
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 2
- 229910052706 scandium Inorganic materials 0.000 description 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 2
- FRNOGLGSGLTDKL-UHFFFAOYSA-N thulium atom Chemical compound [Tm] FRNOGLGSGLTDKL-UHFFFAOYSA-N 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- 229920002799 BoPET Polymers 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010443 kyanite Substances 0.000 description 1
- 229910052850 kyanite Inorganic materials 0.000 description 1
- 238000000626 liquid-phase infiltration Methods 0.000 description 1
- 238000004518 low pressure chemical vapour deposition Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000011160 polymer matrix composite Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- FIIGRZYDBNZZFN-UHFFFAOYSA-N trioxido(trioxidosilyloxy)silane ytterbium(3+) Chemical compound [Si]([O-])([O-])([O-])O[Si]([O-])([O-])[O-].[Yb+3].[Yb+3] FIIGRZYDBNZZFN-UHFFFAOYSA-N 0.000 description 1
- AKTQKAXQEMMCIF-UHFFFAOYSA-N trioxido(trioxidosilyloxy)silane;yttrium(3+) Chemical compound [Y+3].[Y+3].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] AKTQKAXQEMMCIF-UHFFFAOYSA-N 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/288—Protective coatings for blades
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/042—Coating on selected surface areas, e.g. using masks using masks
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4529—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied from the gas phase
- C04B41/4531—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied from the gas phase by C.V.D.
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4505—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application
- C04B41/4535—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension
- C04B41/4539—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements characterised by the method of application applied as a solution, emulsion, dispersion or suspension as a emulsion, dispersion or suspension
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4572—Partial coating or impregnation of the surface of the substrate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/459—Temporary coatings or impregnations
- C04B41/4592—Temporary coatings or impregnations for masking purposes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/91—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics involving the removal of part of the materials of the treated articles, e.g. etching
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
- C23C16/24—Deposition of silicon only
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/56—After-treatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D11/00—Preventing or minimising internal leakage of working-fluid, e.g. between stages
- F01D11/08—Preventing or minimising internal leakage of working-fluid, e.g. between stages for sealing space between rotor blade tips and stator
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D25/00—Component parts, details, or accessories, not provided for in, or of interest apart from, other groups
- F01D25/007—Preventing corrosion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/005—Repairing methods or devices
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/282—Selecting composite materials, e.g. blades with reinforcing filaments
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01D—NON-POSITIVE DISPLACEMENT MACHINES OR ENGINES, e.g. STEAM TURBINES
- F01D5/00—Blades; Blade-carrying members; Heating, heat-insulating, cooling or antivibration means on the blades or the members
- F01D5/12—Blades
- F01D5/28—Selecting particular materials; Particular measures relating thereto; Measures against erosion or corrosion
- F01D5/284—Selection of ceramic materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00982—Uses not provided for elsewhere in C04B2111/00 as construction elements for space vehicles or aeroplanes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/30—Manufacture with deposition of material
- F05D2230/31—Layer deposition
- F05D2230/314—Layer deposition by chemical vapour deposition
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- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2230/00—Manufacture
- F05D2230/90—Coating; Surface treatment
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2240/00—Components
- F05D2240/10—Stators
- F05D2240/11—Shroud seal segments
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- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/10—Metals, alloys or intermetallic compounds
- F05D2300/15—Rare earth metals, i.e. Sc, Y, lanthanides
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- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/20—Oxide or non-oxide ceramics
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/20—Oxide or non-oxide ceramics
- F05D2300/21—Oxide ceramics
- F05D2300/211—Silica
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/20—Oxide or non-oxide ceramics
- F05D2300/22—Non-oxide ceramics
- F05D2300/222—Silicon
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/20—Oxide or non-oxide ceramics
- F05D2300/22—Non-oxide ceramics
- F05D2300/224—Carbon, e.g. graphite
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/40—Organic materials
- F05D2300/43—Synthetic polymers, e.g. plastics; Rubber
- F05D2300/437—Silicon polymers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05D—INDEXING SCHEME FOR ASPECTS RELATING TO NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES, GAS-TURBINES OR JET-PROPULSION PLANTS
- F05D2300/00—Materials; Properties thereof
- F05D2300/60—Properties or characteristics given to material by treatment or manufacturing
- F05D2300/603—Composites; e.g. fibre-reinforced
- F05D2300/6033—Ceramic matrix composites [CMC]
Definitions
- the present disclosure generally relates to methods for coating components, such as to a process for depositing a coating onto a selective area of a turbine component.
- Ceramic matrix composites are used for certain components throughout gas turbine engines, and are increasingly used in higher temperature sections of gas turbine engines CMCs are a class of materials that consist of a reinforcing material surrounded by a ceramic matrix phase. These CMCs are lightweight compared to superalloys yet can still provide strength and durability to a component made therefrom.
- CMC and monolithic ceramic components can be coated with environmental barrier coatings (EBCs) to protect them from the harsh environment of high temperature engine sections. EBCs can provide a dense, hermetic seal against the corrosive gases in the hot combustion environment, which can rapidly oxidize silicon-containing CMCs and monolithic ceramics. Depending on the end use of the CMC component, only a portion of the component may need to be coated with an EBC. Improved coating methods for CMC components are needed to provide such a result.
- FIG. 1 is a schematic cross-sectional view of a gas turbine engine in accordance with embodiments of the present disclosure
- FIG. 2 illustrates a component having maskant and coating applied thereon in accordance with embodiments of the present disclosure
- FIG. 3 illustrates a flow-chart for a method for coating a component in accordance with example embodiments of the present disclosure.
- Approximating language may be applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about”, are not to be limited to the precise value specified. Additionally, when using an expression of “about a first value ⁇ a second value,” the about is intended to modify both values. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value.
- any numerical values recited herein include all values from the lower value to the upper value in increments of one unit provided that there is a separation of at least 2 units between any lower value and any higher value.
- the amount of a component or a value of a process variable such as, for example, temperature, pressure, time, and the like is, for example, from 1 to 90, it is intended that values such as 15 to 85, 22 to 68, 43 to 51, 30 to 32 etc. are expressly enumerated in this specification.
- compositions or components of the present disclosure can include, consist essentially of, or consist of, the components of the present disclosure as well as other materials described herein.
- “consisting essentially of” means that the composition or component may include additional materials, but only if the additional materials to not materially alter the basic and novel characteristics of the claimed methods or compositions.
- first”, “second”, and “third” may be used interchangeably to distinguish one component from another and are not intended to signify location or importance of the individual components.
- the term “powder” or the like refers to a collection of particles.
- the particles may be of any configuration, shape, or size as long as they are suitable for the flowability, dispersion and/or compaction thereof.
- average particle size or “median particle size” refers to median value of the particle size distribution, also known as d50 median.
- d100 refers to 100% of the volume percent of the particles having diameters with the stated ranges or under the stated value.
- Approximating language is applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about,” “approximately,” and “substantially,” are not to be limited to the precise value specified. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value, or the precision of the methods or machines for constructing or manufacturing the components and/or systems. For example, the approximating language may refer to being within a 10 percent margin to the stated value.
- Embodiments of the present disclosure relate to a method of processing a CMC component.
- EBCs deposited on CMC components often require deposition of a silicon bond coat.
- hard tool masks are applied to the CMC component in areas where no silicon bond coat is desired.
- the applied silicon coating can actually penetrate between the gaps of the hard tool masks and the component, thus coating undesirable areas.
- the present disclosure provides a slurry-based maskant that makes intimate contact with the CMC component, such that silicon vapors cannot penetrate around the masking and coat the component. The maskant prevents infiltration of silicon coatings deposited by CVD.
- the methods incorporating the maskant described herein are suitable for use in low pressure CVD processes and are operationally stable in environments in CVD reactors including maintaining operational stability in the temperature, vacuum, and corrosive environments present in CVD reactors. Furthermore, the maskant can be easily removed from the component without affecting the form or function of the component. Accordingly, utilization of the methods and maskants described herein allow for precise application of CVD silicon bond coats.
- the component includes a gas turbine engine component suitable for used in a gas turbine engine assembly or a gas power turbine assembly.
- FIG. 1 is a schematic cross-sectional view of a gas turbine engine herein referred to as “turbofan engine 10 ” as may incorporate various embodiments of the present disclosure.
- the turbofan engine 10 has a longitudinal or axial centerline axis 12 that extends therethrough for reference purposes.
- the turbofan engine 10 may include a turbomachine 14 disposed downstream from a fan section 16 .
- the turbomachine 14 may generally include a substantially tubular outer casing 18 that defines an annular inlet 20 .
- the outer casing 18 may be formed from multiple casings.
- the outer casing 18 encases, in serial flow relationship, a compressor section having a booster or low pressure (LP) compressor 22 , a high pressure (HP) compressor 24 , a combustion section 26 , a turbine section including a high pressure (HP) turbine 28 , a low pressure (LP) turbine 30 , and a jet exhaust nozzle section 32 .
- a high pressure (HP) shaft or spool 34 drivingly connects the HP turbine 28 to the HP compressor 24 .
- a low pressure (LP) shaft or spool 36 drivingly connects the LP turbine 30 to the LP compressor 22 .
- the (LP) spool 36 may also be connected to a fan spool 38 of the fan section 16 .
- the (LP) spool 36 may be connected directly to the fan spool 38 such as in a direct-drive configuration.
- the (LP) spool 36 may be connected to the fan spool 38 via a speed reduction device 37 such as a reduction gear gearbox in an indirect-drive or geared-drive configuration.
- speed reduction devices may be included between any suitable shafts/spools within turbofan engine 10 as desired or required.
- the fan section 16 includes a plurality of fan blades 40 that are coupled to and that extend radially outwardly from the fan spool 38 .
- An annular fan casing or nacelle 42 circumferentially surrounds the fan section 16 and/or at least a portion of the turbomachine 14 .
- the nacelle 42 may be configured to be supported relative to the turbomachine 14 by a plurality of circumferentially-spaced outlet guide vanes 44 .
- a downstream section 46 of the nacelle 42 downstream of the guide vanes 44 ) may extend over an outer portion of the turbomachine 14 so as to define a bypass airflow passage 48 therebetween.
- air 106 enters an inlet portion 108 of the turbofan engine 10 .
- a first portion of the air 106 as indicated by arrow 107 is directed into the bypass airflow passage 48 and a second portion of the air 106 as indicated by arrow 110 enters the inlet 20 of the LP compressor 22 .
- the second portion of air indicated by arrow 110 is progressively compressed as it is routed from the LP compressor 22 into the HP compressor 24 .
- the second portion of the air indicated by arrow 110 is further compressed as it is routed through the HP compressor 24 , thus providing compressed air as indicated by arrow 112 to the combustion section 26 where it is mixed with fuel and burned to provide combustion gases as indicated by arrow 114 .
- the combustion gases indicated by arrow 114 are routed through the HP turbine 28 where a portion of thermal and/or kinetic energy from the combustion gases indicated by arrow 114 is extracted via the stator vanes 54 , 64 and turbine rotor blades 58 , 68 of the first and second stages 50 , 60 respectively, thus causing the HP shaft or spool 34 to rotate, thereby supporting operation of the HP compressor 24 .
- the combustion gases indicated by arrow 114 are then routed through the LP turbine 30 where a second portion of thermal and kinetic energy is extracted from the combustion gases indicated by arrow 114 via sequential stages of LP turbine stator vanes 116 and LP turbine rotor blades 118 that are coupled to the LP shaft or spool 36 , thus causing the LP shaft or spool 36 to rotate, thereby supporting operation of the LP compressor 22 and/or rotation of the fan spool 38 .
- the combustion gases indicated by arrow 114 are then routed through the jet exhaust nozzle section 32 of the turbomachine 14 .
- CMC materials include a composite material, such as a polymer matrix composite (PMC) material or a CMC material, which has high temperature capability.
- Composite materials generally comprise a fibrous reinforcement material embedded in matrix material, e.g., a polymer or ceramic matrix material. The reinforcement material serves as a load-bearing constituent of the composite material, while the matrix of a composite material serves to bind the fibers together and act as the medium by which an externally applied stress is transmitted and distributed to the fibers.
- Exemplary CMC materials may include silicon carbide (SiC), silicon, silica, or alumina matrix materials and combinations thereof. Ceramic fibers may be embedded within the matrix, such as oxidation stable reinforcing fibers including monofilaments like sapphire and silicon carbide (e.g., Textron's SCS-6), as well as rovings and yarn including silicon carbide (e.g., Nippon Carbon's NICALON®, Ube Industries' TYRANNO®, and Dow Corning's SYLRAMIC®), alumina silicates (e.g., 3M's Nextel 440 and 480), and chopped whiskers and fibers (e.g., 3M's Nextel 440 and SAFFIL®), and optionally ceramic particles (e.g., oxides of Si, Al, Zr, Y, and combinations thereof) and inorganic fillers (e.g., pyrophyllite, wollastonite, mica, talc, kyanite, and montmor
- bundles of the fibers are formed as a reinforced tape, such as a unidirectional reinforced tape.
- a plurality of the tapes may be laid up together (e.g., as plies) to form a preform component.
- the bundles of fibers may be impregnated with a slurry composition prior to forming the preform or after formation of the preform.
- the preform may then undergo thermal processing, such as a cure or burn-out to yield a high char residue in the preform, and subsequent chemical processing, such as melt-infiltration with silicon, to arrive at a component formed of a CMC material having a desired chemical composition.
- the CMC material may be formed as, e.g., a carbon fiber cloth rather than as a tape.
- FIG. 2 illustrates an exemplary component 200 formed from a CMC material that is treated according to exemplary processes described herein, particularly with respect to the method 300 as shown by FIG. 3 .
- the component 200 includes a first portion 202 and a second portion 204 .
- a maskant 250 is applied to the first portion 202 , as will be described in more detail hereinbelow.
- the component 200 includes a first portion 202 coated with maskant 250 and a second portion 204 that is not coated with maskant 250 .
- a coating 210 is applied to the component 200 .
- the coating 210 is prevented from accessing the surface of the first portion 202 of the component 200 by the maskant 250 .
- the coating 210 can be applied directly to the surface of the second portion 204 of the component 200 .
- the coating 210 can be a silicon coating, such as a silicon bond coat used in EBC systems, that is applied via a CVD process.
- the maskant 250 and coating 210 on the first portion 202 are removed, thus providing a partially coated component 200 having only the second portion 204 coated with coating 210 .
- FIG. 3 illustrates an exemplary flowchart process of method 300 for coating certain portions of a component, such as a turbofan engine component.
- a first portion of the surface of the component is coated with a maskant leaving at least a second portion of the component uncoated by the maskant.
- the maskant can be formulated as a slurry including particulate material dispersed in a fluid carrier.
- the composition of the slurry material, including the specific particulate material utilized and additives added, is formulated such that coatings applied by CVD processes are unable to penetrate the maskant and prevent the coating from depositing on the component under the maskant.
- the slurry material can include one or more powders or particulate material in a fluid carrier.
- the particulate material can include silicon (Si), carbon (C), silicon oxide (SiO 2 ), zirconium oxide (ZrO 2 ) unstabilized or stabilized with additions of other oxides including but not limited to MgO and Y 2 O 3 , hafnium oxide (HfO 2 ) unstabilized or stabilized with additions of other oxides including but not limited to MgO and Y 2 O 3 , mullite (3Al 2 O 3 -2SiO 2 ), rare earth disilicates (Ln 2 Si 2 O 7 ), rare earth monosilicates (LnSiO 5 ), rare earth oxides (LnO x ), where Ln is Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (
- the particles have an average particle size (e.g., d50) between 0.3 ⁇ m and 3 ⁇ m. In certain embodiments, the plurality of particles have a d100 between 3 ⁇ m and 300 ⁇ m. In still other embodiments, the average particle size (e.g., d50) is 0.02 ⁇ m and the d100 is less than 1 ⁇ m.
- the particulate material can be included in the slurry in an amount of from about 0.1% to about 64% by volume, such as from about 5% to about 50% by volume, such as from about 10% to about 40% by volume, such as from about 15% to about 35% by volume.
- the slurry can further include various slurry components, including but not limited to fluid carriers, such as organic solvents, dispersants, binders, plasticizers, and any combinations thereof.
- fluid carriers such as organic solvents, dispersants, binders, plasticizers, and any combinations thereof.
- Suitable fluid carriers can include water, alcohol, ketone, acetate, acetoacetate, xylene, toluene, benzene, ethyl benzene, alkane, nitric acid, acetic acid, esters, ethers and mixtures or combinations thereof.
- one or more dispersants can be included in the slurry.
- the dispersant can be included in an amount of from about 0.1% to about 20% of the total particle volume.
- the dispersant may comprise an anionic polyelectrolyte based on ionizable carboxylic acid (e.g., polyacrylic acid), sulfonic acid, or phosphoric acid groups, a cation polyelectrolyte based on protonizable imine groups (e.g., polyethylene imine), or non-charged polymer, such as a non-charged polymer that may adsorb to the particles, such as but not limited to fatty acids (e.g., fish oil), polyvinyl pyrrolidone, and polyethylene oxide.
- fatty acids e.g., fish oil
- polyvinyl pyrrolidone polyethylene oxide
- one or more binders can be included in the slurry.
- the slurry can include from about 5% to about 50% of binder based on the total volume of the particles present in the slurry.
- Suitable binders include, but are not limited to, polyvinyl butyral, latex binders, or any other binder that is known by one skilled in the art of ceramic processing.
- a combination of a binder and a plasticizer can be included in the slurry.
- one or more plasticizers can be added in an amount of from about 1% to about 300% of the volume of the binder in the slurry.
- Plasticizers include any low vapor pressure fluids in which the binder is soluble. Examples include di(propylene glycol) dibenzoate, dibutyl phthalate, esters, and many other fluids known by those skilled in the art of ceramic processing.
- the slurry can be formed by combining any or all of the previously described slurry components with mixing media in a container.
- the mixture can be mixed using conventional techniques known to those skilled in the art such as shaking with up to about a 1 inch (about 25.4 mm) diameter alumina or zirconia mixing media, ball milling using about a 0.25 inch to about a 1 inch (about 0.64 cm to about 2.54 cm) diameter alumina or zirconia mixing media, attritor milling using about a 1 mm to about a 5 mm diameter zirconia-based mixing media, planetary ball milling using from about a 1 mm to about a 5 mm diameter zirconia-based media, or mechanical mixing or stirring with simultaneous application of ultrasonic energy.
- the mixing media or ultrasonic energy can break apart any agglomerated ceramic particles in the slurry. Any mixing media present may then be removed by straining, for example.
- the slurry can be directly applied to the component on portions of the component where deposition of the coating is not desired.
- the slurry can be applied to the component by pouring, painting, rolling, spraying, dipping, dipping and spinning, doctor blading, or any application method known by one skilled in the art.
- the slurry can be applied at a thickness ranging from about 0.1 mils to about 100 mils, such as from about 0.5 mils to about 5 mils.
- the slurry is dried at room temperature or at a slightly elevated temperature above 30° C. to remove fluid by evaporation and to form a masked component.
- the slurry is tape cast onto a mylar film and dried. The dried slurry tape is the transferred to the component and attached by slight heat and pressure to form the masked component.
- a coating material is applied to the component.
- the coating material can be applied to, deposited or otherwise formed on surfaces of the component via any process suitable for forming layers of silicon, including vapor phase deposition techniques, pack cementation techniques, high velocity oxy-fuel (HVOF) techniques, physical vapor deposition (PVD) techniques such as electron beam physical vapor deposition (EB-PVD), ion plasma, etc., thermal spray techniques such as plasma spray (e.g., air plasma spray), etc., chemical vapor deposition (CVD) techniques, etc., or as well known to those skilled in the art.
- the silicon coating can be applied by placing the masked component in a CVD reactor and coating the component with silicon metal. Once the silicon coating is deposited, the component can be removed from the CVD reactor and further processed.
- the maskant and overlying portion of coating can be removed from the component rendering a partially coated component.
- the coated component can be exposed to a grit blast procedure for removing a portion of the maskant and overcoated silicon coating.
- the maskant and overlying coating can be removed by grit blasting where the surface of the component is subjected to the abrasive action of silicon carbide particles, steel particles, alumina particles, or other types of abrasive particles.
- the abrasive particles can be selected to have particular sizes depending on the type of coating and maskant to be removed.
- the maskant and overlying coating are removed via dry ice blasting.
- dry ice i.e., the solid form of carbon dioxide
- dry ice blasting is similar to other grit blasting procedures, except that solid carbon dioxide is used as the particulate media, which results in a less abrasive procedure.
- a method for processing a component comprising: masking a first portion of a component with a maskant, the maskant including a slurry having a plurality of particles in a fluid carrier, wherein the plurality of particles comprises at least one of silicon, carbon, one or more rare earth disilicates, monosilicates or oxides, or combinations thereof, wherein a second portion of the component is not contacted by the maskant; depositing a silicon-based coating on the component via a chemical vapor deposition process on a second portion of the component, wherein the maskant prevents deposition of the silicon-based coating on the first portion of the component; and removing the maskant and a portion of the silicon-based coating overlaying the maskant from the first portion of the component.
- the fluid carrier comprises water, alcohol, ketone, acetate, acetoacetate, xylene, toluene, benzene, ethyl benzene, alkane, nitric acid, acetic acid, esters, ethers, or a combination thereof.
- the slurry further comprises a dispersant.
- the slurry comprises from about 0.1 volume % to 20 volume % of the dispersant based on a total particle volume of the slurry.
- the dispersant comprises (i) an anionic polyelectrolyte based on ionizable carboxylic acid, sulfonic acid, or phosphoric acid groups, (ii) a cation polyelectrolyte based on protonizable imine groups, (iii) a non-charged polymer, or a combination thereof.
- the non-charged polymer comprises fatty acids, polyvinyl pyrrolidone, polyethylene oxide, or a combination thereof.
- the slurry further comprises one or more binders.
- the slurry includes from about 5 volume % to about 50 volume % of binder based on a total volume of the plurality of particles.
- the one or more binders comprise polyvinyl butyral, latex binders, or combinations thereof.
- the slurry further comprises one or more plasticizers.
- the slurry includes from about 1% to about 300% of the one or more plasticizers based on a volume of a binder.
- the one or more plasticizers comprise di(propylene glycol) dibenzoate, dibutyl phthalate, esters, or a combination thereof.
- removing the maskant and the portion of the silicon-based coating overlaying the first portion of the component utilizes a grit blasting treatment.
- the component comprises a ceramic matrix composite material.
- the component comprises a gas turbine engine component.
- gas turbine engine component comprises nozzles, blades, turbine center frames, stators, or combinations thereof.
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Abstract
A method for processing a component is provided and includes masking a first portion of the component with a maskant. The maskant includes a slurry having a plurality of particles in a fluid carrier. The plurality of particles comprises at least one of silicon, carbon, one or more rare earth disilicates, monosilicates or oxides, and combinations thereof. The method includes depositing a silicon-based coating on a second portion of the component via a chemical vapor deposition process and removing the maskant and any overlying silicon-based coating from the first portion of the component.
Description
The present disclosure generally relates to methods for coating components, such as to a process for depositing a coating onto a selective area of a turbine component.
Ceramic matrix composites (CMCs) are used for certain components throughout gas turbine engines, and are increasingly used in higher temperature sections of gas turbine engines CMCs are a class of materials that consist of a reinforcing material surrounded by a ceramic matrix phase. These CMCs are lightweight compared to superalloys yet can still provide strength and durability to a component made therefrom. CMC and monolithic ceramic components can be coated with environmental barrier coatings (EBCs) to protect them from the harsh environment of high temperature engine sections. EBCs can provide a dense, hermetic seal against the corrosive gases in the hot combustion environment, which can rapidly oxidize silicon-containing CMCs and monolithic ceramics. Depending on the end use of the CMC component, only a portion of the component may need to be coated with an EBC. Improved coating methods for CMC components are needed to provide such a result.
The above and other aspects, features, and advantages of the present disclosure will become more apparent in light of the subsequent detailed description when taken in conjunction with the accompanying drawings in which:
One or more embodiments of the present disclosure will be described below. Unless defined otherwise, technical, and scientific terms used herein have the same meaning as is commonly understood by one of ordinary skill in the art to which this disclosure belongs.
Approximating language, as used herein throughout the specification and claims, may be applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about”, are not to be limited to the precise value specified. Additionally, when using an expression of “about a first value−a second value,” the about is intended to modify both values. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value.
Here, and throughout the specification and claims, range limitations may be combined and/or interchanged, such ranges are identified and include all the sub-ranges contained therein unless context or language indicates otherwise. Any numerical values recited herein include all values from the lower value to the upper value in increments of one unit provided that there is a separation of at least 2 units between any lower value and any higher value. As an example, if it is stated that the amount of a component or a value of a process variable such as, for example, temperature, pressure, time, and the like is, for example, from 1 to 90, it is intended that values such as 15 to 85, 22 to 68, 43 to 51, 30 to 32 etc. are expressly enumerated in this specification. For values which are less than one, one unit is considered to be 0.0001, 0.001, 0.01 or 0.1 as appropriate. These are only examples of what is specifically intended and all possible combinations of numerical values between the lowest value and the highest value enumerated are to be considered to be expressly stated in this application in a similar manner.
The methods and materials described in the present disclosure can include, consist essentially of, or consist of, the components of the present disclosure as well as other materials described herein. As used herein, “consisting essentially of” means that the composition or component may include additional materials, but only if the additional materials to not materially alter the basic and novel characteristics of the claimed methods or compositions.
The singular forms “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise.
As used herein, the terms “first”, “second”, and “third” may be used interchangeably to distinguish one component from another and are not intended to signify location or importance of the individual components.
As used herein the term “powder” or the like refers to a collection of particles. The particles may be of any configuration, shape, or size as long as they are suitable for the flowability, dispersion and/or compaction thereof.
As used herein the term “average particle size” or “median particle size” refers to median value of the particle size distribution, also known as d50 median. Also, as used herein, d100 refers to 100% of the volume percent of the particles having diameters with the stated ranges or under the stated value.
Approximating language, as used herein throughout the specification and claims, is applied to modify any quantitative representation that could permissibly vary without resulting in a change in the basic function to which it is related. Accordingly, a value modified by a term or terms, such as “about,” “approximately,” and “substantially,” are not to be limited to the precise value specified. In at least some instances, the approximating language may correspond to the precision of an instrument for measuring the value, or the precision of the methods or machines for constructing or manufacturing the components and/or systems. For example, the approximating language may refer to being within a 10 percent margin to the stated value.
Embodiments of the present disclosure relate to a method of processing a CMC component. For instance, EBCs deposited on CMC components often require deposition of a silicon bond coat. In order to selectively coat the surfaces of CMC components, hard tool masks are applied to the CMC component in areas where no silicon bond coat is desired. However, during CVD coating processes, the applied silicon coating can actually penetrate between the gaps of the hard tool masks and the component, thus coating undesirable areas. Unlike hard tool masks, the present disclosure provides a slurry-based maskant that makes intimate contact with the CMC component, such that silicon vapors cannot penetrate around the masking and coat the component. The maskant prevents infiltration of silicon coatings deposited by CVD. Advantageously, the methods incorporating the maskant described herein are suitable for use in low pressure CVD processes and are operationally stable in environments in CVD reactors including maintaining operational stability in the temperature, vacuum, and corrosive environments present in CVD reactors. Furthermore, the maskant can be easily removed from the component without affecting the form or function of the component. Accordingly, utilization of the methods and maskants described herein allow for precise application of CVD silicon bond coats.
In some embodiments of the present disclosure, the component includes a gas turbine engine component suitable for used in a gas turbine engine assembly or a gas power turbine assembly. Referring now to the drawings, FIG. 1 is a schematic cross-sectional view of a gas turbine engine herein referred to as “turbofan engine 10” as may incorporate various embodiments of the present disclosure. As shown in FIG. 1 , the turbofan engine 10 has a longitudinal or axial centerline axis 12 that extends therethrough for reference purposes. In general, the turbofan engine 10 may include a turbomachine 14 disposed downstream from a fan section 16.
The turbomachine 14 may generally include a substantially tubular outer casing 18 that defines an annular inlet 20. The outer casing 18 may be formed from multiple casings. The outer casing 18 encases, in serial flow relationship, a compressor section having a booster or low pressure (LP) compressor 22, a high pressure (HP) compressor 24, a combustion section 26, a turbine section including a high pressure (HP) turbine 28, a low pressure (LP) turbine 30, and a jet exhaust nozzle section 32. A high pressure (HP) shaft or spool 34 drivingly connects the HP turbine 28 to the HP compressor 24. A low pressure (LP) shaft or spool 36 drivingly connects the LP turbine 30 to the LP compressor 22. The (LP) spool 36 may also be connected to a fan spool 38 of the fan section 16. In particular embodiments, the (LP) spool 36 may be connected directly to the fan spool 38 such as in a direct-drive configuration. In alternative configurations, the (LP) spool 36 may be connected to the fan spool 38 via a speed reduction device 37 such as a reduction gear gearbox in an indirect-drive or geared-drive configuration. Such speed reduction devices may be included between any suitable shafts/spools within turbofan engine 10 as desired or required.
As shown in FIG. 1 , the fan section 16 includes a plurality of fan blades 40 that are coupled to and that extend radially outwardly from the fan spool 38. An annular fan casing or nacelle 42 circumferentially surrounds the fan section 16 and/or at least a portion of the turbomachine 14. It should be appreciated by those of ordinary skill in the art that the nacelle 42 may be configured to be supported relative to the turbomachine 14 by a plurality of circumferentially-spaced outlet guide vanes 44. Moreover, a downstream section 46 of the nacelle 42 (downstream of the guide vanes 44) may extend over an outer portion of the turbomachine 14 so as to define a bypass airflow passage 48 therebetween.
During operation of the turbofan engine 10, as illustrated in FIG. 1 , air 106 enters an inlet portion 108 of the turbofan engine 10. A first portion of the air 106 as indicated by arrow 107 is directed into the bypass airflow passage 48 and a second portion of the air 106 as indicated by arrow 110 enters the inlet 20 of the LP compressor 22. The second portion of air indicated by arrow 110 is progressively compressed as it is routed from the LP compressor 22 into the HP compressor 24. The second portion of the air indicated by arrow 110 is further compressed as it is routed through the HP compressor 24, thus providing compressed air as indicated by arrow 112 to the combustion section 26 where it is mixed with fuel and burned to provide combustion gases as indicated by arrow 114.
The combustion gases indicated by arrow 114 are routed through the HP turbine 28 where a portion of thermal and/or kinetic energy from the combustion gases indicated by arrow 114 is extracted via the stator vanes 54, 64 and turbine rotor blades 58, 68 of the first and second stages 50, 60 respectively, thus causing the HP shaft or spool 34 to rotate, thereby supporting operation of the HP compressor 24. The combustion gases indicated by arrow 114 are then routed through the LP turbine 30 where a second portion of thermal and kinetic energy is extracted from the combustion gases indicated by arrow 114 via sequential stages of LP turbine stator vanes 116 and LP turbine rotor blades 118 that are coupled to the LP shaft or spool 36, thus causing the LP shaft or spool 36 to rotate, thereby supporting operation of the LP compressor 22 and/or rotation of the fan spool 38. The combustion gases indicated by arrow 114 are then routed through the jet exhaust nozzle section 32 of the turbomachine 14.
As described certain components of the turbofan engine 10 can be fabricated from CMC materials. CMC materials include a composite material, such as a polymer matrix composite (PMC) material or a CMC material, which has high temperature capability. Composite materials generally comprise a fibrous reinforcement material embedded in matrix material, e.g., a polymer or ceramic matrix material. The reinforcement material serves as a load-bearing constituent of the composite material, while the matrix of a composite material serves to bind the fibers together and act as the medium by which an externally applied stress is transmitted and distributed to the fibers.
Exemplary CMC materials may include silicon carbide (SiC), silicon, silica, or alumina matrix materials and combinations thereof. Ceramic fibers may be embedded within the matrix, such as oxidation stable reinforcing fibers including monofilaments like sapphire and silicon carbide (e.g., Textron's SCS-6), as well as rovings and yarn including silicon carbide (e.g., Nippon Carbon's NICALON®, Ube Industries' TYRANNO®, and Dow Corning's SYLRAMIC®), alumina silicates (e.g., 3M's Nextel 440 and 480), and chopped whiskers and fibers (e.g., 3M's Nextel 440 and SAFFIL®), and optionally ceramic particles (e.g., oxides of Si, Al, Zr, Y, and combinations thereof) and inorganic fillers (e.g., pyrophyllite, wollastonite, mica, talc, kyanite, and montmorillonite). For example, in certain embodiments, bundles of the fibers, which may include a ceramic refractory material coating, are formed as a reinforced tape, such as a unidirectional reinforced tape. A plurality of the tapes may be laid up together (e.g., as plies) to form a preform component. The bundles of fibers may be impregnated with a slurry composition prior to forming the preform or after formation of the preform. The preform may then undergo thermal processing, such as a cure or burn-out to yield a high char residue in the preform, and subsequent chemical processing, such as melt-infiltration with silicon, to arrive at a component formed of a CMC material having a desired chemical composition. In other embodiments, the CMC material may be formed as, e.g., a carbon fiber cloth rather than as a tape.
Similar to FIG. 2 , FIG. 3 illustrates an exemplary flowchart process of method 300 for coating certain portions of a component, such as a turbofan engine component. At 302, a first portion of the surface of the component is coated with a maskant leaving at least a second portion of the component uncoated by the maskant. According to embodiments, the maskant can be formulated as a slurry including particulate material dispersed in a fluid carrier. The composition of the slurry material, including the specific particulate material utilized and additives added, is formulated such that coatings applied by CVD processes are unable to penetrate the maskant and prevent the coating from depositing on the component under the maskant.
The slurry material can include one or more powders or particulate material in a fluid carrier. The particulate material can include silicon (Si), carbon (C), silicon oxide (SiO2), zirconium oxide (ZrO2) unstabilized or stabilized with additions of other oxides including but not limited to MgO and Y2O3, hafnium oxide (HfO2) unstabilized or stabilized with additions of other oxides including but not limited to MgO and Y2O3, mullite (3Al2O3-2SiO2), rare earth disilicates (Ln2Si2O7), rare earth monosilicates (LnSiO5), rare earth oxides (LnOx), where Ln is Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), or combinations thereof, rare earth monosilicates (Ln2SiO5) where Ln is Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), or combinations thereof. In certain embodiments, the particulate material comprises silicon (Si), carbon (C), yttrium disilicate (Y2Si2O7), ytterbium disilicate (Yb2Si2O7), and combinations thereof.
In some embodiments, the particles have an average particle size (e.g., d50) between 0.3 μm and 3 μm. In certain embodiments, the plurality of particles have a d100 between 3 μm and 300 μm. In still other embodiments, the average particle size (e.g., d50) is 0.02 μm and the d100 is less than 1 μm.
The particulate material can be included in the slurry in an amount of from about 0.1% to about 64% by volume, such as from about 5% to about 50% by volume, such as from about 10% to about 40% by volume, such as from about 15% to about 35% by volume.
The slurry can further include various slurry components, including but not limited to fluid carriers, such as organic solvents, dispersants, binders, plasticizers, and any combinations thereof. Suitable fluid carriers can include water, alcohol, ketone, acetate, acetoacetate, xylene, toluene, benzene, ethyl benzene, alkane, nitric acid, acetic acid, esters, ethers and mixtures or combinations thereof.
In certain embodiments, one or more dispersants can be included in the slurry. For instance, the dispersant can be included in an amount of from about 0.1% to about 20% of the total particle volume. The dispersant may comprise an anionic polyelectrolyte based on ionizable carboxylic acid (e.g., polyacrylic acid), sulfonic acid, or phosphoric acid groups, a cation polyelectrolyte based on protonizable imine groups (e.g., polyethylene imine), or non-charged polymer, such as a non-charged polymer that may adsorb to the particles, such as but not limited to fatty acids (e.g., fish oil), polyvinyl pyrrolidone, and polyethylene oxide.
In other embodiments, one or more binders can be included in the slurry. For instance, the slurry can include from about 5% to about 50% of binder based on the total volume of the particles present in the slurry. Suitable binders include, but are not limited to, polyvinyl butyral, latex binders, or any other binder that is known by one skilled in the art of ceramic processing. In certain embodiments, a combination of a binder and a plasticizer can be included in the slurry. In such embodiments, one or more plasticizers can be added in an amount of from about 1% to about 300% of the volume of the binder in the slurry. Plasticizers include any low vapor pressure fluids in which the binder is soluble. Examples include di(propylene glycol) dibenzoate, dibutyl phthalate, esters, and many other fluids known by those skilled in the art of ceramic processing.
The slurry can be formed by combining any or all of the previously described slurry components with mixing media in a container. The mixture can be mixed using conventional techniques known to those skilled in the art such as shaking with up to about a 1 inch (about 25.4 mm) diameter alumina or zirconia mixing media, ball milling using about a 0.25 inch to about a 1 inch (about 0.64 cm to about 2.54 cm) diameter alumina or zirconia mixing media, attritor milling using about a 1 mm to about a 5 mm diameter zirconia-based mixing media, planetary ball milling using from about a 1 mm to about a 5 mm diameter zirconia-based media, or mechanical mixing or stirring with simultaneous application of ultrasonic energy. The mixing media or ultrasonic energy can break apart any agglomerated ceramic particles in the slurry. Any mixing media present may then be removed by straining, for example.
Once prepared, the slurry can be directly applied to the component on portions of the component where deposition of the coating is not desired. For example, the slurry can be applied to the component by pouring, painting, rolling, spraying, dipping, dipping and spinning, doctor blading, or any application method known by one skilled in the art. The slurry can be applied at a thickness ranging from about 0.1 mils to about 100 mils, such as from about 0.5 mils to about 5 mils. In embodiments, the slurry is dried at room temperature or at a slightly elevated temperature above 30° C. to remove fluid by evaporation and to form a masked component. In another embodiment, the slurry is tape cast onto a mylar film and dried. The dried slurry tape is the transferred to the component and attached by slight heat and pressure to form the masked component.
At (304), a coating material is applied to the component. The coating material can be applied to, deposited or otherwise formed on surfaces of the component via any process suitable for forming layers of silicon, including vapor phase deposition techniques, pack cementation techniques, high velocity oxy-fuel (HVOF) techniques, physical vapor deposition (PVD) techniques such as electron beam physical vapor deposition (EB-PVD), ion plasma, etc., thermal spray techniques such as plasma spray (e.g., air plasma spray), etc., chemical vapor deposition (CVD) techniques, etc., or as well known to those skilled in the art. The silicon coating can be applied by placing the masked component in a CVD reactor and coating the component with silicon metal. Once the silicon coating is deposited, the component can be removed from the CVD reactor and further processed.
At (306), the maskant and overlying portion of coating can be removed from the component rendering a partially coated component. For example, in certain embodiments the coated component can be exposed to a grit blast procedure for removing a portion of the maskant and overcoated silicon coating. For example, the maskant and overlying coating can be removed by grit blasting where the surface of the component is subjected to the abrasive action of silicon carbide particles, steel particles, alumina particles, or other types of abrasive particles. The abrasive particles can be selected to have particular sizes depending on the type of coating and maskant to be removed. In certain embodiments, the maskant and overlying coating are removed via dry ice blasting. In such procedures, dry ice (i.e., the solid form of carbon dioxide) is pressurized in an air stream and accelerated at a surface of the component. Dry ice blasting is similar to other grit blasting procedures, except that solid carbon dioxide is used as the particulate media, which results in a less abrasive procedure.
Further aspects of the disclosure are provided by the subject matter of the following clauses:
A method for processing a component, comprising: masking a first portion of a component with a maskant, the maskant including a slurry having a plurality of particles in a fluid carrier, wherein the plurality of particles comprises at least one of silicon, carbon, one or more rare earth disilicates, monosilicates or oxides, or combinations thereof, wherein a second portion of the component is not contacted by the maskant; depositing a silicon-based coating on the component via a chemical vapor deposition process on a second portion of the component, wherein the maskant prevents deposition of the silicon-based coating on the first portion of the component; and removing the maskant and a portion of the silicon-based coating overlaying the maskant from the first portion of the component.
The method of any preceding clause, wherein the plurality of particles have an average particle size between 0.3 μm and 3 μm.
The method of any preceding clause, wherein the plurality of particles are present in the slurry in an amount of from about 0.1 volume % to about 64 volume %.
The method of any preceding clause, wherein the fluid carrier comprises water, alcohol, ketone, acetate, acetoacetate, xylene, toluene, benzene, ethyl benzene, alkane, nitric acid, acetic acid, esters, ethers, or a combination thereof.
The method of any preceding clause, wherein the slurry further comprises a dispersant.
The method of any preceding clause, wherein the slurry comprises from about 0.1 volume % to 20 volume % of the dispersant based on a total particle volume of the slurry.
The method of any preceding clause, wherein the dispersant comprises (i) an anionic polyelectrolyte based on ionizable carboxylic acid, sulfonic acid, or phosphoric acid groups, (ii) a cation polyelectrolyte based on protonizable imine groups, (iii) a non-charged polymer, or a combination thereof.
The method of any preceding clause, wherein (iii) the non-charged polymer comprises fatty acids, polyvinyl pyrrolidone, polyethylene oxide, or a combination thereof.
The method of any preceding clause, wherein the slurry further comprises one or more binders.
The method of any preceding clause, wherein the slurry includes from about 5 volume % to about 50 volume % of binder based on a total volume of the plurality of particles.
The method of any preceding clause, wherein the one or more binders comprise polyvinyl butyral, latex binders, or combinations thereof.
The method of any preceding clause, wherein the slurry further comprises one or more plasticizers.
The method of any preceding clause, wherein the slurry includes from about 1% to about 300% of the one or more plasticizers based on a volume of a binder.
The method of any preceding clause, wherein the one or more plasticizers comprise di(propylene glycol) dibenzoate, dibutyl phthalate, esters, or a combination thereof.
The method of any preceding clause, wherein the slurry is applied at a thickness of from about 0.1 mils to about 100 mils.
The method of any preceding clause, comprising drying the slurry at an elevated temperature to remove at least a portion of the fluid carrier from the slurry.
The method of any preceding clause, wherein removing the maskant and the portion of the silicon-based coating overlaying the first portion of the component utilizes a grit blasting treatment.
The method of any preceding clause, wherein the component comprises a ceramic matrix composite material.
The method of any preceding clause, wherein the component comprises a gas turbine engine component.
The method of any preceding clause, wherein the gas turbine engine component comprises nozzles, blades, turbine center frames, stators, or combinations thereof.
This written description uses examples to describe the disclosure, including the best mode, and also to enable any person skilled in the art to practice the disclosure, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the disclosure is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they have structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
Claims (19)
1. A method for processing a component, comprising:
masking a first portion of a component with a maskant, wherein the component comprises a ceramic matrix composite material, the maskant including a slurry having a plurality of particles in a fluid carrier, wherein the plurality of particles comprises at least one of silicon, carbon, one or more rare earth disilicates, monosilicates or oxides, or combinations thereof, wherein a second portion of the component is not contacted by the maskant;
depositing a silicon-based coating via a chemical vapor deposition process on the second portion of the component, wherein the maskant prevents deposition of the silicon-based coating on the first portion of the component; and
removing the maskant and a portion of the silicon-based coating overlaying the maskant from the first portion of the component.
2. The method of claim 1 , wherein the plurality of particles has an average particle size between 0.3 μm and 3 μm.
3. The method of claim 1 , wherein the plurality of particles is present in the slurry in an amount of from about 0.1 volume % to about 64 volume %.
4. The method of claim 1 , wherein the fluid carrier comprises water, alcohol, ketone, acetate, acetoacetate, xylene, toluene, benzene, ethyl benzene, alkane, nitric acid, acetic acid, esters, ethers, or a combination thereof.
5. The method of claim 1 , wherein the slurry further comprises a dispersant.
6. The method of claim 5 , wherein the slurry comprises from about 0.1 volume % to 20 volume % of the dispersant based on a total particle volume of the slurry.
7. The method of claim 5 , wherein the dispersant comprises (i) an anionic polyelectrolyte based on ionizable carboxylic acid, sulfonic acid, or phosphoric acid groups, (ii) a cation polyelectrolyte based on protonizable imine groups, (iii) a non-charged polymer, or a combination thereof.
8. The method of claim 7 , wherein (iii) the non-charged polymer comprises fatty acids, polyvinyl pyrrolidone, polyethylene oxide, or a combination thereof.
9. The method of claim 1 , wherein the slurry further comprises one or more binders.
10. The method of claim 9 , wherein the slurry includes from about 5 volume % to about 50 volume % of binder based on a total volume of the plurality of particles.
11. The method of claim 9 , wherein the one or more binders comprise polyvinyl butyral, latex binders, or combinations thereof.
12. The method of claim 1 , wherein the slurry further comprises one or more plasticizers.
13. The method of claim 12 , wherein the slurry includes from about 1% to about 300% of the one or more plasticizers based on a volume of a binder.
14. The method of claim 12 , wherein the one or more plasticizers comprise di(propylene glycol) dibenzoate, dibutyl phthalate, esters, or a combination thereof.
15. The method of claim 1 , wherein the slurry is applied at a thickness of from about 0.1 mils to about 100 mils.
16. The method of claim 1 , comprising drying the slurry at an elevated temperature to remove at least a portion of the fluid carrier from the slurry.
17. The method of claim 1 , wherein removing the maskant and the portion of the silicon-based coating overlaying the first portion of the component utilizes a grit blasting treatment.
18. The method of claim 1 , wherein the component comprises a gas turbine engine component.
19. The method of claim 18 , wherein the gas turbine engine component comprises a nozzle, a blade, a turbine center frame, a stator, or a combination thereof.
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