US114956A - Caleb mabshall - Google Patents

Caleb mabshall Download PDF

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Publication number
US114956A
US114956A US114956DA US114956A US 114956 A US114956 A US 114956A US 114956D A US114956D A US 114956DA US 114956 A US114956 A US 114956A
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Prior art keywords
iron
furnace
scale
caleb
sheet
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/68Temporary coatings or embedding materials applied before or during heat treatment
    • C21D1/70Temporary coatings or embedding materials applied before or during heat treatment while heating or quenching
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/06Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12993Surface feature [e.g., rough, mirror]

Definitions

  • the first part of my invention consists of an improved method of removing the scale from iron by means of a saline bath and subsequent heating of the iron in a suitable furnace.
  • This method is applicable both to sheet-iron, so as to prepare it for being polished and burnished, and also for the purpose of removing the scale from all kinds of iron and iron articles which are to be coated with tin, zinc, lead, copper, and other metals and alloys.
  • the second part of my invention consists in finishing sheet-iron, after the scale has been removed by a saline bath, by heating it in a furnace of suitable construction and rolling, at the temperature and in the manner hereinafter more fully set forth.
  • the third part ofmy invention is a new article of polished sheet-iron free from acids in every part.
  • I first break down and roll iron in the ordinary way.
  • the iron thus prepared is covered with a scale, which must be removed previous to making it into polished sheet-iron or before coating it with another metal.
  • I prepare a saturated solution of common salt (chloride of sodium) in water. In this solution I immerse the sheets or pieces of iron from four to five minutes.
  • the iron after being removed from the saline bath and drained, is placed in a furnace having a strong heat free from smoke, flame, and sulphur.
  • the temperature in the furnace should be about the same as ordinarily used in removing scale.
  • the furnace should be so constructed as to carry any smoke and flame over the iron and along the roof of the furnace.
  • furnace for my purpose:
  • the fire-grate is placed at the back of the furnace.
  • a bridge ten to twelve inches high is placed between the fire and the bottom of the furnace, in order to carry the smoke and flame over the iron, along the roof, to the stack, which is at the front end of the furnace.
  • the iron is permitted to remain in the furnace till the operator or workman discovers the scale to be rising from the surface of the iron, when it is removed and dipped into a bath of lime-water or other alkaline solution.
  • the heating in the furnace detaches the scale, and the immersion in lime-water or alkaline solution is for the purpose of preventing any rusting till the subsequent operations are finished.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Description

UNITED STATES PATENT-OFFICE.
CALEB MARS HALL, OF PHILADELPHIA, PENNSYLVANIA, ASSIGNOR TO MARSHALL, PHILIPS & 00., OF SAME PLACE.
COATING WITH OTHER METALS.
IMPROVEMENT IN THE MANUFACTURE OF SHEET-IRON AND REMOVING SCALE FROM IRON FOR To all whom it may concern:
Be it known that I, CALEB MAnsHALL, of the city and county of Philadelphia, and State of Pennsylvania, have made a new and useful Improvement in the Manufacture of American Polished Sheet-Iron, and in the preparation of iron to be coated with other metals by the process of galvanizing, tinning, and coating with other metals or alloys of metals.
The first part of my invention consists of an improved method of removing the scale from iron by means of a saline bath and subsequent heating of the iron in a suitable furnace. This method is applicable both to sheet-iron, so as to prepare it for being polished and burnished, and also for the purpose of removing the scale from all kinds of iron and iron articles which are to be coated with tin, zinc, lead, copper, and other metals and alloys.
The second part of my invention consists in finishing sheet-iron, after the scale has been removed by a saline bath, by heating it in a furnace of suitable construction and rolling, at the temperature and in the manner hereinafter more fully set forth.
The third part ofmy invention is a new article of polished sheet-iron free from acids in every part.
The following description will enable any one skilled in the art to make and use my invention.
I first break down and roll iron in the ordinary way. The iron thus prepared is covered with a scale, which must be removed previous to making it into polished sheet-iron or before coating it with another metal. To remove the scale, I prepare a saturated solution of common salt (chloride of sodium) in water. In this solution I immerse the sheets or pieces of iron from four to five minutes.
Heretofore it has been usual to immerse the sheets in an acid solution. This I find will not make a good article, since, even after neutralizing the acid with the bases used for that purpose, some acid still adheres, and causes the rusting of the iron after it is finished; but by using a solution of common salt or other equivalent saline solution instead of acid the preparation of the iron, by removing the scale, is obtained without the after effects of acids.
Specification forming part of Letters Patent No. 114,956, dated May 16, 1871.
The iron, after being removed from the saline bath and drained, is placed in a furnace having a strong heat free from smoke, flame, and sulphur. The temperature in the furnace should be about the same as ordinarily used in removing scale. The furnace should be so constructed as to carry any smoke and flame over the iron and along the roof of the furnace.
The following is a suitable construction of furnace for my purpose: The fire-grate is placed at the back of the furnace. A bridge ten to twelve inches high is placed between the fire and the bottom of the furnace, in order to carry the smoke and flame over the iron, along the roof, to the stack, which is at the front end of the furnace. At the sameend, under the stack, is a door through which to put in and take out the iron.
The iron is permitted to remain in the furnace till the operator or workman discovers the scale to be rising from the surface of the iron, when it is removed and dipped into a bath of lime-water or other alkaline solution. The heating in the furnace detaches the scale, and the immersion in lime-water or alkaline solution is for the purpose of preventing any rusting till the subsequent operations are finished.
If the iron is to be galvanized, tinned, or coated, these processes are performed in the ordin ary manner after the scalin g process above described has been completed.
The following additional treatment is required to manufacture polished sheet iron: For this purpose the sheets are again placed in the furnace and brought to a dark cherryred heat, which is rather lower than the heat commonly used. The sheets are then rolled with ordinary chilled rolls polished for that purpose. In this operation the sheets are rolled three or four in a pack, in the common way, and two or three heats will complete ,the process. To finish the sheet-iron, it is then taken and annealed, in packs or in a box, in the manner commonly practiced in most rollingmills in making common sheet-iron, care being taken not to have the heat so high as to raise the scale. By this treatment a good article of American polished sheet-iron is produced.
If any peculiar stamp or finish on the surface is required, it may be given by proper rolls for the purpose.
There are no germs of decay or rust in the body of the iron, as is the case when acids are used. This gives my invention great value over others now used in which acids are employed.
Having thus described my invention, what I claim, and desire to secure by Letters Patent of the United States, is
1. The improved process herein described for removing scale from the surface of sheet and other iron, the same consisting in treating CALEB MARSHALL.
Witnesses:
' ALFRED MARSHALL, A. H. SHOEMAKER.
US114956D Caleb mabshall Expired - Lifetime US114956A (en)

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