US10697048B2 - Alloy drill and manufacturing method thereof - Google Patents
Alloy drill and manufacturing method thereof Download PDFInfo
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- US10697048B2 US10697048B2 US15/770,751 US201515770751A US10697048B2 US 10697048 B2 US10697048 B2 US 10697048B2 US 201515770751 A US201515770751 A US 201515770751A US 10697048 B2 US10697048 B2 US 10697048B2
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 93
- 239000000956 alloy Substances 0.000 title claims abstract description 93
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 36
- 229910003470 tongbaite Inorganic materials 0.000 claims abstract description 23
- 229910052802 copper Inorganic materials 0.000 claims abstract description 19
- 229910052742 iron Inorganic materials 0.000 claims abstract description 18
- 239000000843 powder Substances 0.000 claims description 72
- 229910001080 W alloy Inorganic materials 0.000 claims description 43
- 239000000463 material Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 34
- 238000005245 sintering Methods 0.000 claims description 29
- 229910000531 Co alloy Inorganic materials 0.000 claims description 28
- JPNWDVUTVSTKMV-UHFFFAOYSA-N cobalt tungsten Chemical compound [Co].[W] JPNWDVUTVSTKMV-UHFFFAOYSA-N 0.000 claims description 28
- 229910017153 MnC Inorganic materials 0.000 claims description 24
- SBYXRAKIOMOBFF-UHFFFAOYSA-N copper tungsten Chemical compound [Cu].[W] SBYXRAKIOMOBFF-UHFFFAOYSA-N 0.000 claims description 22
- JHOPGIQVBWUSNH-UHFFFAOYSA-N iron tungsten Chemical compound [Fe].[Fe].[W] JHOPGIQVBWUSNH-UHFFFAOYSA-N 0.000 claims description 21
- 238000009694 cold isostatic pressing Methods 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 13
- 238000000465 moulding Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- 238000007493 shaping process Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 239000011230 binding agent Substances 0.000 abstract description 31
- 239000000654 additive Substances 0.000 abstract description 28
- 230000000996 additive effect Effects 0.000 abstract description 27
- 238000005260 corrosion Methods 0.000 abstract description 24
- 230000002929 anti-fatigue Effects 0.000 abstract 2
- 230000007797 corrosion Effects 0.000 description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 16
- 238000000498 ball milling Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 229910039444 MoC Inorganic materials 0.000 description 8
- 229910003468 tantalcarbide Inorganic materials 0.000 description 8
- 238000005553 drilling Methods 0.000 description 7
- 238000003754 machining Methods 0.000 description 7
- 238000005452 bending Methods 0.000 description 6
- 239000000523 sample Substances 0.000 description 5
- 238000001291 vacuum drying Methods 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- 238000009413 insulation Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000462 isostatic pressing Methods 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000013001 point bending Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/04—Compacting only by applying fluid pressure, e.g. by cold isostatic pressing [CIP]
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/05—Mixtures of metal powder with non-metallic powder
- C22C1/051—Making hard metals based on borides, carbides, nitrides, oxides or silicides; Preparation of the powder mixture used as the starting material therefor
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1084—Alloys containing non-metals by mechanical alloying (blending, milling)
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/005—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides comprising a particular metallic binder
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B10/00—Drill bits
- E21B10/46—Drill bits characterised by wear resisting parts, e.g. diamond inserts
- E21B10/56—Button-type inserts
- E21B10/567—Button-type inserts with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F2003/245—Making recesses, grooves etc on the surface by removing material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F2003/247—Removing material: carving, cleaning, grinding, hobbing, honing, lapping, polishing, milling, shaving, skiving, turning the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
- B22F2998/10—Processes characterised by the sequence of their steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B2224/00—Materials of tools or workpieces composed of a compound including a metal
- B23B2224/20—Tantalum carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23B—TURNING; BORING
- B23B27/00—Tools for turning or boring machines; Tools of a similar kind in general; Accessories therefor
- B23B27/14—Cutting tools of which the bits or tips or cutting inserts are of special material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25D—PERCUSSIVE TOOLS
- B25D2222/00—Materials of the tool or the workpiece
- B25D2222/21—Metals
- B25D2222/51—Hard metals, e.g. tungsten carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25D—PERCUSSIVE TOOLS
- B25D2250/00—General details of portable percussive tools; Components used in portable percussive tools
- B25D2250/105—Exchangeable tool components
- B25D2250/111—Bits, i.e. inserts or attachments for hammer, chisel, pick
Abstract
Disclosed is an alloy drill. Components of the alloy drill are: 14-30 wt % of a binder phase being one or more of Co, Ni, Fe, and Cu; 0.32-9.7 wt % of an additive being one or more of TaC, MoC, Cr3C2, and MnC; and the remainder as a hard phase being WC. In the alloy drill, WC is used as the hard phase to improve its hardness and wear resistance, Cu, Ni, Fe, or Co as the binder phase can improve its anti-corrosion performance and anti-fatigue performance, and TaC, MoC, Cr3C2, or MnC as the additive can further improve its thermal stability and wear resistance. Thus, the alloy drill has superior wear resistance and impact toughness, and also possesses excellent anti-corrosion performance and anti-fatigue performance.
Description
This is a US National Phase application based upon PCT Application No. PCT/CN2015/095050, filed Nov. 19, 2015, which claims the priority of Chinese Patent Application No. 201510719112.7, filed on Oct. 29, 2015, and titled with “ALLOY DRILL AND MANUFACTURING METHOD THEREOF”, and the disclosures of which are hereby incorporated by reference.
The present invention relates to the field of drill bit technology, specifically to an alloy drill bit and the manufacturing method thereof.
Drill bit is an anti-wear part of conventional equipment used in petroleum drilling, geological drilling and tunnel engineering. It usually contacts with rocks, etching solutions and other impurities directly, and achieves the aim of drilling by rubbing, impacting and scouring. Work performance of drill bit directly influences drilling quality, drilling efficiency and drilling cost.
At present, in the field of boring industry and road construction engineering, roller bit and polycrystalline diamond compact (PDC) bit are widely used, but they still have some problems that are hard to be overcome. In the art, roller bit is usually made from conventional tungsten-cobalt alloy. Although conventional tungsten-cobalt alloy has specific corrosion resistance of hard alloy, between the hardness and strength of which poses a contradiction, that is, roller bit cannot combine good wear resistance and impact toughness; therefore, in practice, mechanical properties of which cannot meet the requirements of severe working conditions, which greatly shortens the service life of the roller bit. For PDC bit in the art, cast iron or steel casting are usually chosen as the substrate material, polycrystalline diamond compact are cladded or welded to the surface of the substrate as wear resistance hardface layer. The substrate is generally obtained by casting or machining, then subjected to hardface processing by thermal spraying thereafter. The technology is often complicated and the cost is relatively high. In addition, in practice drilling operation, if there is foreign body at the bottom of the hole, broken gear or hot friction will happen to PDC bit. As the temperature rises, the carcass is burned, and even the brazing layer is melted, resulting in a missing tooth, which affects the penetration rate and accelerates the failure of the drill bit.
Therefore, a drill bit that has good wear resistance and impact toughness as well as good corrosion resistance and fatigue resistance is in urgent need in the art.
In view of above, the present disclosure aims to provide an alloy drill bit and the manufacturing method thereof, and the drill bit provided by the present disclosure has good wear resistance and impact toughness, as well as good corrosion resistance and fatigue resistance.
The present disclosure provides an alloy drill bit, consisting of:
14 to 30 wt % of a binder phase, which is one or more of Co, Ni, Fe and Cu;
0.32 to 9.7 wt % of an additive, which is one or more of TaC, MoC, Cr3C2 and MnC; and
a hard phase as balance, which is WC.
Preferably, component of the alloy drill bit is tungsten-cobalt alloy, iron-tungsten alloy or copper-tungsten alloy.
Preferably, component of the tungsten-cobalt alloy is:
9 to 14.5 wt % of Co,
5 to 8 wt % of Ni,
0.35 to 0.6 wt % of TaC,
0.3 to 0.55 wt % of MoC, and
WC as balance.
Preferably, component of the iron-tungsten alloy is:
15 to 20 wt % of Fe,
3.6 to 5.1 wt % of Co,
3.8 to 4.9 wt % of Ni,
0.32 to 0.4 wt % of Cr3C2, and
WC as balance.
Preferably, component of the copper-tungsten alloy is:
14.3 to 20.5 wt % of Cu,
6.8 to 9.7 wt % of MnC,
4.5 to 6.4 wt % of Ni, and
WC as balance.
Preferably, grain size of the tungsten-cobalt alloy, iron-tungsten alloy and copper-tungsten alloy is from 3 to 10.3 μm.
In the alloy drill bit provided by the present disclosure, WC, as the hard phase, gives the alloy drill bit relative good hardness and wear resistance; Cu, Ni, Fe or Co, as the binder phase, not only gives the alloy drill bit relative good compactness and strength, but also increases corrosion resistance and fatigue resistance of the alloy drill bit; TaC, MoC, Cr3C2 or MnC, as the additive, further increases high temperature resistance and wear resistance. Therefore, the alloy drill bit provided by the present disclosure has relatively good wear resistance and impact toughness as well as relatively good corrosion resistance and fatigue resistance.
The present disclosure provides a method for preparing the alloy drill bit above, consisting of:
mixing the hard phase, the binder phase and the additive to obtain a mixed material, wherein the hard phase is WC, the binder phase is one or more of Co, Ni, Fe and Cu, and the additive is one or more of TaC, MoC, Cr3C2 and MnC;
performing cold isostatic pressing molding on the mixed material to obtain a powder compact;
shaping the powder compact to obtain a powder compact of drill bit;
sintering the powder compact of drill bit to obtain the alloy drill bit.
Preferably, after mixing the hard phase, the binder phase and the additive, further consisting of:
grinding, drying and granulating the mixture obtained successively to obtain the mixed material.
Preferably, pressure for the isostatic pressing is from 180 to 280 MPa.
Preferably, temperature for the sintering is from 1430 to 1470° C.
In the method for preparing alloy drill bit provided by the present disclosure, through the combination of the hard phase, the binder phase and the additive, the alloy drill bit obtained by the present disclosure has relatively high wear resistance and impact toughness as well as relatively good corrosion resistance and fatigue resistance. Alloy drill bit prepared by this method has excellent properties, which efficiently prolongs the service life of the drill bit, reducing the replacement frequency of the drill bit during operation process, reducing the cost and increasing the working efficiency.
In order to describe the technical solutions in the embodiments of the present disclosure or the art more clearly, the accompanying drawings used in description of the embodiments or the conventional art will be illustrated briefly. It is obvious that the accompanying drawings described hereinafter is merely embodiments of the present disclosure, for one of ordinary skill in the art, other accompanying drawings can also be obtained according to the accompany drawings provided without any creative efforts.
The technical solutions in the examples of the present disclosure will be described clearly and completely herein in conjunction with the examples of the present disclosure. Apparently, the described examples are only a part of the examples of the present disclosure, rather than all examples. Based on the examples in the present disclosure, all of other examples, made by one of ordinary skill in the art without any creative efforts, fall into the protection scope of the present disclosure.
The present disclosure provides an alloy drill bit, consisting of:
14 to 30 wt % of a binder phase, which is one or more of Co, Ni, Fe and Cu;
0.32 to 9.7 wt % of an additive, which is one or more of TaC, MoC, Cr3C2 and MnC; and
a hard phase as balance, which is WC.
In the examples of the present disclosure, the binder phase of the alloy drill bit can be Co and Ni; in other examples, the binder phase of the alloy drill bit can be Fe, Co and Ni; in other examples, the binder phase of the alloy drill bit can be Cu and Ni. In the examples of the present disclosure, when the binder phase of the alloy drill bit is Co and Ni, mass content of the binder phase is from 14 to 22.5 wt %, mass ratio of Co and Ni is (9 to 14.5):(5 to 8). In the examples of the present disclosure, when the binder phase of the alloy drill bit is Fe, Co and Ni, mass content of the binder phase is from 22.4 to 30 wt %, mass ratio of Fe, Co and Ni is (15 to 20):(3.6 to 5.1):(3.8 to 4.9). In the examples of the present disclosure, when the binder phase of the alloy drill bit is Cu and Ni, mass content of the binder phase is from 18.8 to 26.9 wt %, mass ratio of Cu and Ni is (14.3 to 20.5):(4.5 to 6.4).
In the examples of the present disclosure, the additive of the alloy drill bit can be TaC and MoC; in other examples of the present disclosure, the additive of the alloy drill bit can be Cr3C2 or MnC. In the examples of the present disclosure, when the additive of the alloy drill bit is TaC and MoC, mass content of the additive is from 0.65 to 1.15 wt %, mass ratio of TaC and MoC is (0.35 to 0.6):(0.3 to 0.55). In the examples of the present disclosure, when the additive of the alloy drill bit is Cr3C2, mass content of Cr3C2 is from 0.32 to 0.4 wt %. In the examples of the present disclosure, when the additive of the alloy drill bit is MnC, mass content of MnC is from 6.8 to 9.7 wt %.
In embodiments of the present disclosure, component of the alloy drill bit can be tungsten-cobalt alloy, iron-tungsten alloy or copper-tungsten alloy. In embodiments of the present disclosure, component of the tungsten-cobalt alloy is:
9 to 14.5 wt % of Co,
5 to 8 wt % of Ni,
0.35 to 0.6 wt % of TaC,
0.3 to 0.55 wt % of MoC, and
WC as balance.
In the examples of the present disclosure, Co content of the tungsten-cobalt alloy is from 10 to 14 wt %; in other examples, Co content of the tungsten-cobalt alloy is from 11 to 13 wt %; in other examples, Co content of the tungsten-cobalt alloy is from 11.5 to 12.5 wt %. In the examples of the present disclosure, Ni content of the tungsten-cobalt alloy is from 5.5 to 7.5 wt %; in other examples, Ni content of the tungsten-cobalt alloy is from 6 to 7 wt %; in other examples, Ni content of the tungsten-cobalt alloy is from 6.4 to 6.6 wt %. In the examples of the present disclosure, TaC content of the tungsten-cobalt alloy is from 0.4 to 0.55 wt %; in other examples, TaC content of the tungsten-cobalt alloy is from 0.45 to 0.5 wt %; in other examples, TaC content of the tungsten-cobalt alloy is from 0.46 to 0.48 wt %. In the examples of the present disclosure, MoC content of the tungsten-cobalt alloy is from 0.35 to 0.5 wt %; in other examples, MoC content of the tungsten-cobalt alloy is from 0.4 to 0.45 wt %; in other examples, MoC content of the tungsten-cobalt alloy is from 0.42 to 0.43 wt %.
In the examples of the present disclosure, component of the iron-tungsten alloy is:
15 to 20 wt % of Fe,
3.6 to 5.1 wt % of Co,
3.8 to 4.9 wt % of Ni,
0.32 to 0.4 wt % of Cr3C2, and
WC as balance.
In the examples of the present disclosure, Co content of the iron-tungsten alloy is from 4 to 5 wt %; in other examples, Co content of the iron-tungsten alloy is from 4.2 to 4.8 wt %; in other examples, Co content of the iron-tungsten alloy is from 4.4 to 4.6 wt %. In the examples of the present disclosure, Ni content of the iron-tungsten alloy is from 4 to 4.5 wt %; in other examples, Ni content of the iron-tungsten alloy is from 4.2 to 4.3 wt %. In the examples of the present disclosure, Cr3C2 content of the iron-tungsten alloy is from 0.34 to 0.38 wt %; in other examples, Cr3C2 content of the iron-tungsten alloy is from 0.35 to 0.36 wt %.
In the examples of the present disclosure, component of the copper-tungsten alloy is:
14.3 to 20.5 wt % of Cu,
6.8 to 9.7 wt % of MnC,
4.5 to 6.4 wt % of Ni, and
WC as balance.
In the examples of the present disclosure, Cu content of the copper-tungsten alloy is from 15 to 18 wt %; in other examples, Cu content of the copper-tungsten alloy is from 16 to 17 wt %. In the examples of the present disclosure, MnC content of the copper-tungsten alloy is from 7 to 9 wt %; in other examples, MnC content of the copper-tungsten alloy is from 7.5 to 8.5 wt %, in other examples, MnC content of the copper-tungsten alloy is from 7.8 to 8.2 wt %. In the examples of the present disclosure, Ni content of the copper-tungsten alloy is from 5 to 6 wt %; in other examples, Ni content of the copper-tungsten alloy is from 5.2 to 5.8 wt %, in other examples, Ni content of the copper-tungsten alloy is from 5.4 to 5.6 wt %.
In the examples of the present disclosure, grain size of the tungsten-cobalt alloy, iron-tungsten alloy and copper-tungsten alloy is from 3 to 10.3 μm; in other examples, grain size of the tungsten-cobalt alloy, iron-tungsten alloy and copper-tungsten alloy is from 5 to 8 μm; in other examples, grain size of the tungsten-cobalt alloy, iron-tungsten alloy and copper-tungsten alloy is from 6 to 7 μm.
In the examples of the present disclosure, diameter of the alloy drill bit is from 140 to 200 nm; in other examples, diameter of the alloy drill bit is from 150 to 180 nm; in other examples, diameter of the alloy drill bit is from 160 to 170 nm. In the examples of the present disclosure, height of the alloy drill bit is from 80 to 90 mm; in other examples, height of the alloy drill bit is from 82 to 88 mm; in other examples, height of the alloy drill bit is from 84 to 86 mm. The alloy drill bit provided by the present disclosure has a relatively large size.
The present disclosure provides a method for preparing the alloy drill bit according the technical solutions above, consisting of:
mixing the hard phase, the binder phase and the additive to obtain a mixed material, wherein the hard phase is WC, the binder phase is one or more of Co, Ni, Fe and Cu, and the additive is one or more of TaC, MoC, Cr3C2 and MnC;
performing cold isostatic pressing molding on the mixed material to obtain a powder compact;
shaping the powder compact to obtain a powder compact of drill bit; and
sintering the powder compact of drill bit to obtain the alloy drill bit.
In the present disclosure, the hard phase, the binder phase and the additive are mixed to obtain a mixed material, wherein the hard phase is WC, the binder phase is one or more of Co, Ni, Fe, and Cu, and the additive is one or more of TaC, MoC, Cr3C2 and MnC. In the present disclosure, the hard phase, the binder phase and the additive are in accordance with the hard phase, the binder phase and the additive in the technical solutions above, so that they are not repeated herein. In the present disclosure, the hard phase, the binder phase and the additives are used in an amount such that the mass contents of the hard phase, the binder phase and the additive in the mixed material are in accordance with the mass contents of the hard phase, the binder phase and the additive in the alloy for drill bit described in the technical solutions above. This content will not be repeated here.
In the example of the present disclosure, when component of the alloy drill bit is tungsten-cobalt alloy, the method for preparing the alloy drill bit consists of:
mixing WC, Co, Ni, TaC and MoC to obtain a mixed material;
performing cold isostatic pressing molding on the mixed material to obtain a powder compact;
shaping the powder compact to obtain a powder compact of drill bit; and
sintering the powder compact of drill bit to obtain an alloy drill bit.
In the present disclosure, when WC, Co, Ni, TaC and MoC are mixed, WC, Co, Ni, TaC and MoC are used in an amount so that the component of the mixed material obtained is in accordance with the component of the tungsten-cobalt alloy in the technical solution above. This content will not be repeated here.
In the example of the present disclosure, when component of the alloy drill bit is iron-tungsten alloy, the method for preparing the alloy drill bit consists of:
mixing WC, Co, Ni, Fe and Cr3C2 to obtain a mixed material;
performing cold isostatic pressing molding on the mixed material to obtain a powder compact;
shaping the powder compact to obtain a powder compact of drill bit; and
sintering the powder compact of drill bit to obtain the alloy drill bit.
In the present disclosure, when WC, Co, Ni, Fe and Cr3C2 are mixed, WC, Co, Ni, Fe and Cr3C2 are used in an amount so that the component of the mixed material obtained is in accordance with the component of the iron-tungsten alloy in the technical solution above. This content will not be repeated here.
In the example of the present disclosure, when component of the alloy drill bit is copper-tungsten alloy, the method for preparing the alloy drill bit consists of:
mixing WC, Ni, Cu and MnC to obtain a mixed material;
performing cold isostatic pressing molding on the mixed material to obtain a powder compact;
shaping the powder compact to obtain a powder compact of drill bit; and
sintering the powder compact of drill bit to obtain the alloy drill bit.
In the present disclosure, when WC, Ni, Cu and MnC are mixed, WC, Ni, Cu and MnC are used in an amount so that the component of the mixed material obtained is in accordance with the component of the copper-tungsten alloy in the technical solution above. This content will not be repeated here.
In the examples of the present disclosure, the hard phase is in a state of powder. In the examples of the present disclosure, fisher particle size of the hard phase is from 7 μm to 25 μm; in other examples, fisher particle size of the hard phase is from 7 μm to 12 μm; in other examples, fisher particle size of the hard phase is from 20 μm to 25 μm. In the examples of the present disclosure, mass ratio of the hard phase with a particle size of 7 μm to 12 μm and the hard phase with a particle size of 20 μm to 25 μm is (25 to 40):(60 to 75); in other examples, mass ratio of the hard phase with a particle size of 7 μm to 12 μm and the hard phase with a particle size of 20 μm to 25 μm is (30 to 35):(65 to 70).
In the present disclosure, after obtaining the mixed material, the mixed material is subjected to cold isostatic pressing molding to give a powder compact. In the present disclosure, powder compact with high density and high strength can be obtained by employing isostatic pressing molding. In the examples of the present disclosure, pressure for the cold isostatic pressing is from 180 to 280 MPa; in other examples, pressure for the cold isostatic pressing is from 200 to 250 MPa; in other examples, pressure for the cold isostatic pressing is from 220 to 230 MPa. In the examples of the present disclosure, time of the cold isostatic pressing is from 14 to 20 min; in other examples, time of the cold isostatic pressing is from 16 to 18 min. There is no special restriction on operation method of the cold isostatic pressing in the present disclosure, and it can be any of the cold isostatic pressing operation method well-known to one of ordinary skill in the art.
In the present disclosure, after mixing the hard phase, the binder phase and the additive, consisting of:
sequentially grinding, drying and granulating the mixture obtained to obtain the mixed material.
In the examples of the present disclosure, the mixed material gives the alloy drill bit prepared by the method provided by the present disclosure relatively high wear resistance and impact toughness as well as relatively good corrosion resistance and fatigue resistance. In examples of the present disclosure, method for grinding can be wet ball milling. In examples of the present disclosure, ball-to-powder mass ratio in the wet ball milling process can be (3 to 5):1; in other examples, ball-to-powder mass ratio in the wet ball milling process can be (3.5 to 4.5):1; in other examples, ball-to-powder mass ratio in the wet ball milling process can be (3.8 to 4.2):1. In the examples of the present disclosure, grinding ball in the wet ball milling process can be hard alloy. In the examples of the present disclosure, diameter of the grinding ball in the wet ball milling process can be from 5 to 10 mm; in other examples of the present disclosure, diameter of the grinding ball in the wet ball milling process can be 5 mm, 6 mm, 8.5 mm, 9.5 mm or 10 mm. In the examples of the present disclosure, solvent in the wet ball milling process is alcohol. In the examples of the present disclosure, time of the wet ball milling is from 30 to 40 h; in other examples, time of the wet ball milling is from 34 to 36 h.
In the examples of the present disclosure, the drying method is vacuum drying. In the examples of the present disclosure, vacuum degree of the vacuum drying is from 0.06 to 0.1 MPa; in other examples, vacuum degree of the vacuum drying is from 0.07 to 0.08 MPa. In the examples of the present disclosure, temperature for the drying is from 90 to 100° C.; in other examples, temperature for the drying is from 92 to 98° C.; in other examples, temperature for the drying is from 94 to 96° C. In the examples of the present disclosure, time of the drying is from 5 to 8 h; in other examples, time of the drying is from 6 to 7 h. In the examples of the present disclosure, the granulating method is roller granulation.
In the present disclosure, after obtaining the powder compact, the powder compact is subjected to shaping to give a powder compact of the drill bit. In the examples of the present disclosure, shaping method is 5-axis CNC machining. In the examples of the present disclosure, the 5-axis CNC machining is based on Cimatron E 5-axis automatic programming and IMSpost post-processing, also Cimatron and VERICUT software for simulation. First, product graphic is analyzed and programming coordinates are established and adjusted; and then cutting tools and multi-axis blanks required for programming are established. Based on the characteristics of the powder compacts and products, the CNC machining is designed by first machining the bottom of the product and grooving and then the top and middle of the product.
In the present disclosure, after obtaining the powder compact of drill bit, the powder compact of drill bit is subjected to sintering to give an alloy drill bit. In the examples of the present disclosure, equipment for sintering can be pressure sintering furnace. In the examples of the present disclosure, temperature of the sintering is from 1430 to 1470° C.; in other examples, temperature of the sintering is from 1440 to 1460° C. In the examples of the present disclosure, time of the sintering is from 6 to 12 h; in other examples, time of the sintering is from 8 to 10 h. In the examples of the present disclosure, thermal insulation time after the sintering is from 30 to 50 min; in other examples, thermal insulation time after the sintering is from 35 to 45 min.
The density of the alloy drill bit provided by the present disclosure is measured by draining method, and the result shows that the density of the alloy drill bit provided by the present disclosure is from 14 to 15 g/cm3.
The hardness of the alloy drill bit provided by the present disclosure is measured by a Rockwell hardness tester, and the result shows that the hardness of the alloy drill bit provided by the present disclosure is from 85 to 95 HRA.
The bending strength of the alloy drill bit provided by the present disclosure is measured by an universal strength tester using three point bending test, and the result shows that the bending strength of the alloy drill provided by the present disclosure is from 3100 to 3200 MPa.
Normal temperature dry sliding wear testing is carried out on an MM2000 Sliding Wear Testing Machine. Size of sample is 10 mm×10 mm×10 mm; material of grinding ring is 42CrMo (hardness of HRC53) that has subjected to quenching and low temperature tempering; normal loading is 20 Kgf; rotational speed of the grinding ring is 400 r/min; wearing time is 60 min; and total sliding distance is about 3800 m; relative wear resistance (=wear weight loss of the standard sample/wear weight loss of the test sample) is taken as index of wear resistance of material. The relative wear resistance of the alloy drill bit provided by the present disclosure is tested and the result shows that the relative wear resistance of the alloy drill bit provided by the present disclosure is from 78 to 80 (that of 42CrMo steel that has subjected to quenching and low temperature tempering is set as 1).
Corrosion test is carried out in a constant-temperature bath at 20° C. with 0.5 mol/L of hydrochloric acid to test the corrosion resistance of material. 316L stainless steel serves as the control sample, and the corrosion weight loss is measured after 168 h of soaking. Relative corrosion resistance (=corrosion weight loss of the standard sample/corrosion weight loss of the test sample) is taken as index of corrosion resistance of material. The relative corrosion resistance of the alloy drill bit provided by the present disclosure is tested and the result shows that the relative corrosion resistance of the alloy drill bit provided by the present disclosure is from 32 to 35 (that of 316 L stainless steel is set as 1).
All raw materials used in the examples of the present disclosure hereinafter are commercially available.
Co, Ni, TaC, MoC and WC were mixed to give a mixture. The mixture contained 12 wt % of Co, 6 wt % of Ni, 0.5 wt % of TaC, 0.5 wt % of MoC, and the balance was WC. In the WC, the mass ratio of the powder with a fisher particle size of 11 μm and the powder with a fisher particle size of 23 μm was 25:75.
The mixture was subjected to wet ball milling for 36 h. In the milling process, ball-to-powder mass ratio was 4:1. The grinded product was subjected to vacuum drying under 0.08 MPa at 95° C. The dried product was subjected to roller granulation to give a mixed material.
The mixed material was subjected to cold isostatic pressing molding at 225 MPa for 16 min to give a powder compact.
The powder compact was subjected to 5-axis CNC machining to give a powder compact of the drill bit. First, 3 oblique holes were drilled at the bottom of the powder compact (section with screw threads), and then the bottom was grooved. The powder compact was rolled over to process the top of the powder compact, and then the middle of the powder compact was processed. Finally, 3 big holes and undercut as well as 30 holes were processed. The shape of the powder compact of the drill bit was shown in FIG. 1 and FIG. 2 . FIG. 1 was the structural representation of the powder compact of the drill bit prepared in Example 1 of the present disclosure, and FIG. 2 was the front view of the powder compact of drill bit prepared in Example 1 of the present disclosure.
The powder compact of drill bit was put in a pressure sintering furnace and subjected to high temperature sintering to give the alloy drill bit. The time of sintering was 12 h, the temperature of sintering was 1470° C., and the thermal insulation time after sintering was 30 min.
The alloy drill bit prepared in Example 1 of the present disclosure was shown in FIG. 3 . FIG. 3 was a photo of the alloy drill bit provided by Example 1 of the present disclosure. The diameter of the alloy drill bit prepared in Example 1 of the present disclosure was 175 mm, and the height was 87 mm.
According to the methods described in the technical solutions above, density, hardness, bending strength, relative wear resistance and relative corrosion resistance of the alloy drill bit prepared in Example 1 of the present disclosure were tested. The test results showed that the alloy drill bit provided by Example 1 of the present disclosure has a density of 14.30 g/cm3, hardness of 90.5HRA, bending strength of 3100 MPa, relative wear resistance of 79.7 and relative corrosion resistance of 32.8.
Cu, Ni, MnC and WC were mixed to give a mixture. The mixture contained 20.5 wt % of Cu, 6.4 wt % of Ni, 9.7 wt % of MnC, and the balance was WC. In the WC, the mass ratio of the powder with a fisher particle size of 12 μm and the powder with a fisher particle size of 25 μm was 40:60.
The mixture was subjected to wet ball milling for 36 h. In the milling process, ball-to-powder mass ratio was 3.5:1. The grinded product was subjected to vacuum drying under 0.08 MPa at 95° C. The dried product was subjected to roller granulation to give a mixed material.
The mixed material was subjected to cold isostatic pressing molding at 250 MPa for 18 min to give a powder compact.
The powder compact was subjected to 5-axis CNC machining to give a powder compact of the drill bit. First, 3 oblique holes were drilled at the bottom of the powder compact (section with screw threads), and then the bottom was grooved. The powder compact was rolled over to process the top of the powder compact, and then the middle of the powder compact was processed. Finally, 3 big holes and undercut as well as 30 holes were processed.
The powder compact of drill bit was put in a pressure sintering furnace and subjected to high temperature sintering to give the alloy drill bit. The time of sintering was 12 h, the temperature of sintering was 1460° C., and the thermal insulation time after sintering was 50 min.
According to the methods described in the technical solutions above, density, hardness, bending strength, relative wear resistance and relative corrosion resistance of the alloy drill bit prepared in Example 2 of the present disclosure were tested. The test results showed that the alloy drill bit provided by Example 2 of the present disclosure has a density of 14.45 g/cm3, hardness of 89.4HRA, bending strength of 3200 MPa, relative wear resistance of 78.5 and relative corrosion resistance of 35.2.
In view of the examples above, the present disclosure provides an alloy drill which consists of: 14 to 30 wt % of a binder phase, wherein the binder phase is one of Co, Ni, Fe and Cu, or a mixture thereof; 0.32 to 9.7 wt % of an additive, wherein the additive is one of TaC, MoC, Cr3C2 and MnC, or a mixture thereof; the balance is a hard phase, wherein the hard phase is WC. In the alloy drill bit provided by the present disclosure, WC, as the hard phase, gives the alloy drill bit good hardness and wear resistance; Cu, Ni, Fe, or Co, as the binder phase, gives the alloy drill bit good powder compactness and strength, and increases corrosion resistance and fatigue resistance of the alloy drill bit. TaC, MoC, Cr3C2 or MnC, as the additive, further increases high temperature resistance and wear resistance. Therefore, the alloy drill bit provided by the present disclosure has good wear resistance and impact toughness as well as good corrosion resistance and fatigue resistance.
Claims (6)
1. An alloy drill bit, consisting of:
tungsten-cobalt alloy, iron-tungsten alloy or copper-tungsten alloy;
wherein the tungsten-cobalt alloy consists of:
9 to 14.5 wt % of Co,
5 to 8 wt % of Ni,
0.35 to 0.6 wt % of TaC,
0.3 to 0.55 wt % of MoC, and
WC as balance;
wherein the iron-tungsten alloy consists of:
15 to 20 wt % of Fe,
3.6 to 5.1 wt % of Co,
3.8 to 4.9 wt % of Ni,
0.32 to 0.4 wt % of Cr3C2, and
WC as balance;
wherein the copper-tungsten alloy consists of:
14.3 to 20.5 wt % of Cu,
6.8 to 9.7 wt % of MnC,
4.5 to 6.4 wt % of Ni, and
WC as balance.
2. The drill bit according to claim 1 , wherein grain size of the tungsten-cobalt alloy, iron-tungsten alloy and copper-tungsten alloy is from 3 to 10.3 μm.
3. A method for preparing the alloy drill bit according to claim 1 ,
wherein the alloy drill bit consists of tungsten-cobalt alloy, the method for preparing the alloy drill bit comprises:
mixing WC, Co, Ni, TaC and MoC to obtain a mixed material,
performing cold isostatic pressing molding on the mixed material to obtain a powder compact,
shaping the powder compact to obtain a powder compact of drill bit, and
sintering the powder compact of drill bit to obtain an alloy drill bit; or
wherein the alloy drill bit consists of iron-tungsten alloy, the method for preparing the alloy drill bit comprises:
mixing WC, Co, Ni, Fe and Cr3C2 to obtain a mixed material,
performing cold isostatic pressing molding on the mixed material to obtain a powder compact,
shaping the powder compact to obtain a powder compact of drill bit, and
sintering the powder compact of drill bit to obtain the alloy drill bit; or
wherein the alloy drill bit consists of copper-tungsten alloy, the method for preparing the alloy drill bit comprises:
mixing WC, Ni, Cu and MnC to obtain a mixed material,
performing cold isostatic pressing molding on the mixed material to obtain a powder compact,
shaping the powder compact to obtain a powder compact of drill bit, and
sintering the powder compact of drill bit to obtain the alloy drill bit.
4. The method according to claim 3 , wherein after mixing WC, Co, Ni, TaC and MoC, after mixing WC, Co, Ni, Fe and Cr3C2, or after mixing WC, Ni, Cu and MnC, the method further comprises:
sequentially grinding, drying and granulating the mixture obtained to obtain the mixed material.
5. The method according to claim 3 , wherein pressure for the cold isostatic pressing molding is from 180 to 280 MPa.
6. The method according to claim 3 , wherein temperature for the sintering is from 1430 to 1470° C.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510719112.7A CN105349867B (en) | 2015-10-29 | 2015-10-29 | Alloy bit and preparing method thereof |
| CN201510719112 | 2015-10-29 | ||
| CN201510719112.7 | 2015-10-29 | ||
| PCT/CN2015/095050 WO2017070993A1 (en) | 2015-10-29 | 2015-11-19 | Alloy drill and manufacturing method thereof |
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| US20180305790A1 US20180305790A1 (en) | 2018-10-25 |
| US10697048B2 true US10697048B2 (en) | 2020-06-30 |
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| CN106191606A (en) * | 2016-07-15 | 2016-12-07 | 无锡森锐硬质合金制品有限公司 | A kind of high temperature cemented carbide |
| CN108798530A (en) | 2017-05-03 | 2018-11-13 | 史密斯国际有限公司 | Drill main body constructs |
| EP3631140A4 (en) | 2017-05-31 | 2021-01-20 | Smith International, Inc. | Cutting tool with pre-formed hardfacing segments |
| CN107245628B (en) * | 2017-06-27 | 2019-02-01 | 株洲硬质合金集团有限公司 | Make the cemented carbide material and preparation method thereof of Binder Phase using Ni-Cu continuous solid solution |
| CN107676034A (en) * | 2017-09-19 | 2018-02-09 | 西迪技术股份有限公司 | A kind of high-abrasive material and torsion impact device |
| CN108277414A (en) * | 2018-02-25 | 2018-07-13 | 株洲市超宇实业有限责任公司 | A kind of production method for 3D glass heat bender hard alloy soaking plates |
| USD875147S1 (en) * | 2018-05-10 | 2020-02-11 | Seed Technologies Corp., Ltd. | Drill bit |
| US11180989B2 (en) * | 2018-07-03 | 2021-11-23 | Baker Hughes Holdings Llc | Apparatuses and methods for forming an instrumented cutting for an earth-boring drilling tool |
| CN109439993A (en) * | 2018-10-23 | 2019-03-08 | 株洲市超宇实业有限责任公司 | A kind of polyethylene, polypropylene pelletizing template cemented carbide material and application |
| CN109576598A (en) * | 2018-11-27 | 2019-04-05 | 汪杨志 | Drill bit alloy with Thermal conductivity |
| DE102019110950A1 (en) * | 2019-04-29 | 2020-10-29 | Kennametal Inc. | Hard metal compositions and their applications |
| CN110195742B (en) * | 2019-05-28 | 2023-12-05 | 成都高新区正通特种材料厂 | Bearing made of high wear-resistant alloy material |
| CN111455250A (en) * | 2020-04-26 | 2020-07-28 | 株洲精特硬质合金有限公司 | Hard alloy material for crushing iron ore and preparation method thereof |
| CN111826569A (en) * | 2020-07-21 | 2020-10-27 | 广东正信硬质材料技术研发有限公司 | Wear-resistant high-hardness hard alloy drilling tool and preparation method thereof |
| CN112359258B (en) * | 2020-10-22 | 2022-04-08 | 长沙黑金刚实业有限公司 | Mining hard alloy formula, mining hard alloy and preparation method thereof |
| CN113234981A (en) * | 2021-05-20 | 2021-08-10 | 九江金鹭硬质合金有限公司 | High-temperature-resistant high-thermal-expansion-coefficient hard alloy |
| CN113846257B (en) * | 2021-09-29 | 2022-11-15 | 郑州大学 | Medium-entropy alloy binder hard alloy and preparation method thereof |
| GB202204522D0 (en) * | 2022-03-30 | 2022-05-11 | Element Six Gmbh | Cemented carbide material |
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| CN105349867A (en) | 2016-02-24 |
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