US106616A - Improvement in the production of colors for dyes, inks - Google Patents
Improvement in the production of colors for dyes, inks Download PDFInfo
- Publication number
- US106616A US106616A US106616DA US106616A US 106616 A US106616 A US 106616A US 106616D A US106616D A US 106616DA US 106616 A US106616 A US 106616A
- Authority
- US
- United States
- Prior art keywords
- aniline
- salt
- colors
- nickel
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003086 colorant Substances 0.000 title description 12
- 238000004519 manufacturing process Methods 0.000 title description 10
- 239000000976 ink Substances 0.000 title description 4
- 239000000975 dye Substances 0.000 title 2
- 150000003839 salts Chemical class 0.000 description 54
- 239000011780 sodium chloride Substances 0.000 description 54
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 36
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 32
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 20
- 229910052759 nickel Inorganic materials 0.000 description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 16
- 150000001875 compounds Chemical class 0.000 description 14
- 239000004744 fabric Substances 0.000 description 12
- 239000007800 oxidant agent Chemical class 0.000 description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- VKJKEPKFPUWCAS-UHFFFAOYSA-M Potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 230000001590 oxidative Effects 0.000 description 8
- 229920000767 polyaniline Polymers 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 239000010949 copper Substances 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 4
- FYGDTMLNYKFZSV-MRCIVHHJSA-N Dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 229920000591 gum Polymers 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MMCPOSDMTGQNKG-UHFFFAOYSA-N Anilinium chloride Chemical compound Cl.NC1=CC=CC=C1 MMCPOSDMTGQNKG-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 210000002268 Wool Anatomy 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000001419 dependent Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/32—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using oxidation dyes
Definitions
- this invention relates to the production of colors from aniline-such as green and purple-and more particularly of that color known as aniline-black and itconsistsin the employment for that purpose of salts of aniline in conjunction with a salt or compound of nickel as a substitute for salts or compounds of copper and of the other beforementioned metals, together with the employment of an oxidizing agent, in order that by this improved method aniline green, purple, or black may be applied, either for the purposes of dyeing, printing, writing, or marking goods or fabrics composed of either wool, silk, linen, or cotton, or mixtures of one or more of the same.
- I either employ a bath consisting of a solution of a salt of aniline, of a solution of a salt of nickel, and of a solution of an oxidizing agent--such, for example, as chlorate of potash or chlorate of soda-in which the goods or fabrics are immersed, or I employ a preliminary bath consisting either of a solution of a salt of aniline, and then immerse the goods or fabrics in a second bath containing a solution of the oxidizing agentviz.,chlorate of potash or chlorate of soda-and of the salt of nickel, or the preliminary bath may consist of an oxidizing agent with a salt of nickel, and the after bath may consist of a salt of aniline, as before described.
- the dyed goods and fabrics after being treated by either of the before-mentioned methods, are to be aged, and subsequently submitted to an acid or an alkaline bath, according to the color or shade which it is desired to produce.
- an acid batl1 such, for example, as a solution of nitric acid.
- an alkaline bath employed,thestrength of which baths will be dependent upon the color or tint it is desired to produce, as is well understood by aniline-black dyers.
- the proportions in which the several i11- gredients may be employed will vary, according to the goods or fabrics to be dyed and the desired degree of color to be produced; but I have found the following proportions to give good results, viz: about three hundred and and twenty parts, by weight, of a salt of aniline-such, for example, as the chloride of aniline, consisting of about one hundred and sixty parts, by weight, of aniline and about one hundred and sixty parts of hydrochloric acid; about twenty parts of a salt of nickelsuch, for example, as the chloride of nickeland an oxidizing agent-such, for example, as the chlorate of potash or the chlorate of soda-in the proportion of about twenty-five parts of chlorate of potash, or about sixty parts of chlorate of soda; or mixtures of the same may be employed, together with about six hundred and forty parts of Water.
- a salt of aniline- such, for example, as the chloride of aniline, consisting of about one hundred and sixty parts, by weight, of aniline and about one
- the operation of dyeing may be performed at the ordinary temperature; but an increased temperaturemay sometimes be advantageously adopted.
- the constituents of the bath may be subdivided, the one bath consisting of the salts of aniline, and the second of the salt or compound of nickel and the oxidizing agents, as before described.
- the soluble salts of nickelthe chloride of nickel for example-or I employ an insoluble salt of nickel-such, for example, as the sulphide of nickel-or mixtures of the soluble and insoluble salts, and also employ, in addition thereto or in conjunction therewith, an oxidizing agentsuch, for example, as chloride of potash or chloride of soda-together with a thickening material such as gum, starch, or dextrine.
- a salt of anilinechloride of anilinetor example consisting of about one hundred and sixty parts, by Weight, of aniline, and one hundred and sixty parts, by weight, of hydrochloric acid, and about twenty parts, by weight, of a salt of nickel-the chloride, for example-about twenty-five parts of chloratb of potash or sixty of chlorate of soda and about six hundred and forty parts, by weight, of water and about two hundred parts of gum, starch, deXt-rine, or other thickening material will give good results.
- the printed, written, or marked goods or fabrics are to be submitted to an aging or oxidizin g process, according to the color required, and subsequently to the action of an alkaline bath when it is desired to produce a black or purple color, and to an acid bath when itis desired to produce a green color, as is well understood by aniline-black printers.
- the salt of aniline which I prefer employing for the before mentioned purposes is the chloride, but other salts may be substituted; and the salts or compounds of nickel which 1 prefer to employ are the chloride and the sulphide, but other salts or compounds of nickel may be substituted.
Description
' UNITED STATES PATENT Grates,
ROBERT PINKNEY, OF LONDON, ENGLAND.
IMPROVEMENT IN THE PRODUCTION OF COLORS FOR DYES, INKS, &c., FROM ANlLINE.
Specification forming part of Letters Patent No. 106,6!6, dated August 23, 18 70.
To all whom it may concern:
Be ,it known that I, ROBERT PINKNEY, of Bread-Street Hill, in the city of London, England, ink-manufacturer, have invented Improvements in the Production of Colors from Aniline, of which the following is a specification.
Hitherto in order to produce the colors known as anilineblacks,it has been proposed to employ, in conjunction with salts of aniline and an oxidizing agent, certain metallic saltssuch, for example, as copper, antimony, and iron-and, more particularly, salts of copper.
Now, this invention relates to the production of colors from aniline-such as green and purple-and more particularly of that color known as aniline-black and itconsistsin the employment for that purpose of salts of aniline in conjunction with a salt or compound of nickel as a substitute for salts or compounds of copper and of the other beforementioned metals, together with the employment of an oxidizing agent, in order that by this improved method aniline green, purple, or black may be applied, either for the purposes of dyeing, printing, writing, or marking goods or fabrics composed of either wool, silk, linen, or cotton, or mixtures of one or more of the same.
When applying my invention for the purposes of dyeing I either employ a bath consisting of a solution of a salt of aniline, of a solution of a salt of nickel, and of a solution of an oxidizing agent--such, for example, as chlorate of potash or chlorate of soda-in which the goods or fabrics are immersed, or I employ a preliminary bath consisting either of a solution of a salt of aniline, and then immerse the goods or fabrics in a second bath containing a solution of the oxidizing agentviz.,chlorate of potash or chlorate of soda-and of the salt of nickel, or the preliminary bath may consist of an oxidizing agent with a salt of nickel, and the after bath may consist of a salt of aniline, as before described. The dyed goods and fabrics, after being treated by either of the before-mentioned methods, are to be aged, and subsequently submitted to an acid or an alkaline bath, according to the color or shade which it is desired to produce. Thus, for instance, if it be desired to produce a green color or shade, I employ an acid batl1such, for example, as a solution of nitric acid. If it be desired to produce a black or purple color, then an alkaline bathisemployed,thestrength of which baths will be dependent upon the color or tint it is desired to produce, as is well understood by aniline-black dyers.
The proportions in which the several i11- gredients may be employed will vary, according to the goods or fabrics to be dyed and the desired degree of color to be produced; but I have found the following proportions to give good results, viz: about three hundred and and twenty parts, by weight, of a salt of aniline-such, for example, as the chloride of aniline, consisting of about one hundred and sixty parts, by weight, of aniline and about one hundred and sixty parts of hydrochloric acid; about twenty parts of a salt of nickelsuch, for example, as the chloride of nickeland an oxidizing agent-such, for example, as the chlorate of potash or the chlorate of soda-in the proportion of about twenty-five parts of chlorate of potash, or about sixty parts of chlorate of soda; or mixtures of the same may be employed, together with about six hundred and forty parts of Water.
The operation of dyeing may be performed at the ordinary temperature; but an increased temperaturemay sometimes be advantageously adopted.
Instead of employing a bath containing the whole of the ingredients, as before mentioned, the constituents of the bath may be subdivided, the one bath consisting of the salts of aniline, and the second of the salt or compound of nickel and the oxidizing agents, as before described.
When applying my invention for the purpose of printing or marking I employ; in conjunction with the salt of aniline, by preference, the chloride of aniline, either the soluble salts of nickelthe chloride of nickel, for example-or I employ an insoluble salt of nickel-such, for example, as the sulphide of nickel-or mixtures of the soluble and insoluble salts, and also employ, in addition thereto or in conjunction therewith, an oxidizing agentsuch, for example, as chloride of potash or chloride of soda-together with a thickening material such as gum, starch, or dextrine.
For the purpose of printing I employ the materials in about the following proportions. These proportions will vary according to the nature of the goods to be printed and the in tensity of the color it is desired to produce; but I have found that about three hundred and twenty parts, by weight, of a salt of anilinechloride of anilinetor example, consisting of about one hundred and sixty parts, by Weight, of aniline, and one hundred and sixty parts, by weight, of hydrochloric acid, and about twenty parts, by weight, of a salt of nickel-the chloride, for example-about twenty-five parts of chloratb of potash or sixty of chlorate of soda and about six hundred and forty parts, by weight, of water and about two hundred parts of gum, starch, deXt-rine, or other thickening material will give good results.
When applying my invention for the purpose of writing or marking I employ the before-mentioned materials in about the same proportions as I- employ for the purposes of printing.
The printed, written, or marked goods or fabrics are to be submitted to an aging or oxidizin g process, according to the color required, and subsequently to the action of an alkaline bath when it is desired to produce a black or purple color, and to an acid bath when itis desired to produce a green color, as is well understood by aniline-black printers.
The salt of aniline which I prefer employing for the before mentioned purposes is the chloride, but other salts may be substituted; and the salts or compounds of nickel which 1 prefer to employ are the chloride and the sulphide, but other salts or compounds of nickel may be substituted.
Having now described and particularly ascertained the nature of the said invention and the manner in which the same is or may be used or carried into effectl would bs e, in conclusion, that what I consider novel, and therefore claim as my invention, is-
Ihe production of colors from aniline by the employment of a salt or compound of nickel in conjunction with a salt or compound of aniline and an oxidizing agent, in the manner as hcreinbefore described.
In testimony whereof I have signed my name to this specification in the presence of two sub- 47 Lincolns Inn Fields, Middlesew.-
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US106616A true US106616A (en) | 1870-08-23 |
Family
ID=2176092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US106616D Expired - Lifetime US106616A (en) | Improvement in the production of colors for dyes, inks |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US106616A (en) |
-
0
- US US106616D patent/US106616A/en not_active Expired - Lifetime
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