US1021882A - Explosive. - Google Patents

Explosive. Download PDF

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Publication number
US1021882A
US1021882A US64747311A US1911647473A US1021882A US 1021882 A US1021882 A US 1021882A US 64747311 A US64747311 A US 64747311A US 1911647473 A US1911647473 A US 1911647473A US 1021882 A US1021882 A US 1021882A
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United States
Prior art keywords
explosive
carbo
hydrate
chlorate
per cent
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Expired - Lifetime
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US64747311A
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James F O'brien
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Individual
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Classifications

    • CCHEMISTRY; METALLURGY
    • C06EXPLOSIVES; MATCHES
    • C06BEXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B29/00Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
    • C06B29/02Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
    • C06B29/04Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with an inorganic non-explosive or an inorganic non-thermic component

Definitions

  • This invention relates to an explosive in powder form; and the prime object thereof is the; production of a relatively simple substance which will give thedeslred reaction and which is comparativel inexpensive to manufacture; and particu arly, to provide means for regulating the speed of combustion in a simple and efiicient manner.
  • my explosive is based on a combin'a tion of a chlorate of an alkali metal with a carbo-hydrate or with a number of carbo-hydrates; and in further comgen compound .is normal i kept comparatively small, approximatey two percent.
  • This explosive-the form giving the most powerful results- is comprised of potassium. chlorate seventy-five per cent. and of sugar twentyfive per cent. with the desired amount of Prussian blue.
  • the explosive as above described has many distinct advantages. It is extremely simple in its composition and manufacture and can be made Very inexpensively. In practice, I add sufiicient water to the sugar or other carbo-hydrate to form a solution and then apply heat to melt or dissolve the carbo-hydrate.
  • the chlorate is powdered and is then mixed with the carbo-hydrate.
  • the cyanogen compound may either be placed directly in the carbo-hydrate before mixing or it may be placed in the mixture of the chlorate andthe calico-hydrate.
  • the resultant mass is pasty anti is granulated'and dried for Appelrcial use ⁇ Vith a minimum amount of the cyanogen compound, or with none atall, the powder is comparatively slow in combustion and is suitable for such work. as blasting in soft coaland the like where it is not desiredto break the blast up into fine particles.
  • the maximum amount of cyanogen compound the explosive is rendered sufficiently quick in combustion to have an action somewhat resembling dynamite and ni-tro-glycerin. The explosive is thus-suited for universal use. It has been in explosive action than eighty per cent. dynamite. Lastly, the explosive leaves no'residuewhatever after combustion, it is entirely smokeless, and it creates no poisonous gases by its combustion.
  • lpAn explosive consisting of potassium chlorate and sugar in proportions approxi-' mately three to one and containing a relatively small amount of Prussian blue.
  • An explosive consisting of "KClO seventy five parts, C H O twenty five parts, and a relatively small amount of Fe (Fe(CN) ,3.
  • An explosive consisting of KCIO seventy five parts, C H O, twenty five parts, and a maximum of approximately two percent. of the total of the said ingredients of Fe (Fe(CN),),.

Description

UNITED S TES ATENT OFFICE.
JAMES F. OIBRIEN, OF CHICAGO, ILLINOIS.
:exrnosrvn- 1,021,882, Specification of Letters Fatent. Patented Apr. 2 1912.
No Drawing." A Application filed September'E, 1911. Serial No. 647,473.
4' To ellwhom it may concern:
Be it known that I, JAMES F; OBRIEN, a citizen of the United States, residing at Chicago, in the county of Cook, State of Illinois, have invented new and useful .Im-
. provements i-n Explosives, of which the folof the explosive. The pro ort-ion of 'cyano lowing is a specification. V
This invention relates to an explosive in powder form; and the prime object thereof is the; production of a relatively simple substance which will give thedeslred reaction and which is comparativel inexpensive to manufacture; and particu arly, to provide means for regulating the speed of combustion in a simple and efiicient manner.
, Broadly considered, my explosive is based on a combin'a tion of a chlorate of an alkali metal with a carbo-hydrate or with a number of carbo-hydrates; and in further comgen compound .is normal i kept comparatively small, approximatey two percent. t
or less. With a maximum of two per cent. of this cyanogen compound the explosive is a as quick as is desired for all ordinary work;
while, with a minimumamount of the cyanogen compound, the explosive is sufliciently slow for such work as blasting in soft coal.-
" In practice, I use a mixture of potassium chlorate, about seventy-five per cent, and sugar or sugar and starchabout twenty five per cent. To these I add the desired amount of cyanogen com .ound in the form of ferric ferro-cyanid, or russian blue.-
The most preferred form of this explosive-the form giving the most powerful results-is comprised of potassium. chlorate seventy-five per cent. and of sugar twentyfive per cent. with the desired amount of Prussian blue. This is the specific form which I wish to cover in the following claims, although I also wish to-cover the general combination of a chlorate of an alali metal, a carbo-hydrate or carbo-hydrates, and the Prussian blue or a cyanogen comp'mmd'a The explosive as above described has many distinct advantages. It is extremely simple in its composition and manufacture and can be made Very inexpensively. In practice, I add sufiicient water to the sugar or other carbo-hydrate to form a solution and then apply heat to melt or dissolve the carbo-hydrate. The chlorate is powdered and is then mixed with the carbo-hydrate. The cyanogen compound may either be placed directly in the carbo-hydrate before mixing or it may be placed in the mixture of the chlorate andthe calico-hydrate. The resultant mass is pasty anti is granulated'and dried for hommercial use \Vith a minimum amount of the cyanogen compound, or with none atall, the powder is comparatively slow in combustion and is suitable for such work. as blasting in soft coaland the like where it is not desiredto break the blast up into fine particles. With the maximum amount of cyanogen compound the explosive is rendered sufficiently quick in combustion to have an action somewhat resembling dynamite and ni-tro-glycerin. The explosive is thus-suited for universal use. It has been in explosive action than eighty per cent. dynamite. Lastly, the explosive leaves no'residuewhatever after combustion, it is entirely smokeless, and it creates no poisonous gases by its combustion.
Having described my invention, I claim:
lpAn explosive, consisting of potassium chlorate and sugar in proportions approxi-' mately three to one and containing a relatively small amount of Prussian blue.
2. An explosive, consisting of "KClO seventy five parts, C H O twenty five parts, and a relatively small amount of Fe (Fe(CN) ,3. An explosive, consisting of KCIO seventy five parts, C H O, twenty five parts, and a maximum of approximately two percent. of the total of the said ingredients of Fe (Fe(CN),),.
In witness that I claim the foregoing I have hereunto subscribed my name this 30th day of August 1911.
, JAMES F. OBRIEN.
Witnesses:
JAS. H. BALLAGH, James T. BARKELEW.'
. v fer five cents each, by addressing the commissioner of I'atents,
80 determined by repeated tests to be stronger Y
US64747311A 1911-09-05 1911-09-05 Explosive. Expired - Lifetime US1021882A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2955033A (en) * 1952-05-15 1960-10-04 Standard Oil Co Combustion catalyst
US2973255A (en) * 1961-02-28 Preparation of acetonylacetone di-
US2984556A (en) * 1954-03-19 1961-05-16 Shell Oil Co Fuel composition and process for its manufacture
US2987389A (en) * 1952-02-26 1961-06-06 Standard Oil Co Ammonium nitrate explosive
US3028273A (en) * 1952-05-17 1962-04-03 Standard Oil Co Catalyst for nh4no3 combustion
US3028810A (en) * 1952-05-17 1962-04-10 Standard Oil Co Propellent grain
US3044912A (en) * 1952-05-13 1962-07-17 Standard Oil Co Ammonium nitrate-cyanide explosive
US3087843A (en) * 1953-08-10 1963-04-30 Phillips Petroleum Co Solid propellant compositions

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2973255A (en) * 1961-02-28 Preparation of acetonylacetone di-
US2987389A (en) * 1952-02-26 1961-06-06 Standard Oil Co Ammonium nitrate explosive
US3044912A (en) * 1952-05-13 1962-07-17 Standard Oil Co Ammonium nitrate-cyanide explosive
US2955033A (en) * 1952-05-15 1960-10-04 Standard Oil Co Combustion catalyst
US3028273A (en) * 1952-05-17 1962-04-03 Standard Oil Co Catalyst for nh4no3 combustion
US3028810A (en) * 1952-05-17 1962-04-10 Standard Oil Co Propellent grain
US3087843A (en) * 1953-08-10 1963-04-30 Phillips Petroleum Co Solid propellant compositions
US2984556A (en) * 1954-03-19 1961-05-16 Shell Oil Co Fuel composition and process for its manufacture

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