US1002118A - Process of producing multicolored effects in spun and woven goods. - Google Patents
Process of producing multicolored effects in spun and woven goods. Download PDFInfo
- Publication number
- US1002118A US1002118A US57263710A US1910572637A US1002118A US 1002118 A US1002118 A US 1002118A US 57263710 A US57263710 A US 57263710A US 1910572637 A US1910572637 A US 1910572637A US 1002118 A US1002118 A US 1002118A
- Authority
- US
- United States
- Prior art keywords
- spun
- effects
- goods
- manganese
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000000694 effects Effects 0.000 title description 14
- 238000000034 method Methods 0.000 title description 12
- 239000000835 fiber Substances 0.000 description 20
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 12
- 239000011572 manganese Substances 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 12
- 235000002908 manganese Nutrition 0.000 description 12
- 238000004043 dyeing Methods 0.000 description 11
- 229920000742 Cotton Polymers 0.000 description 8
- 235000013311 vegetables Nutrition 0.000 description 8
- 239000002253 acid Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 230000001376 precipitating effect Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 235000000177 Indigofera tinctoria Nutrition 0.000 description 1
- 241000322338 Loeseliastrum Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- RAKIIYGKODIBAO-UHFFFAOYSA-L [Mn](=O)(Cl)Cl Chemical compound [Mn](=O)(Cl)Cl RAKIIYGKODIBAO-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229940097275 indigo Drugs 0.000 description 1
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 238000009971 piece dyeing Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical class S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- 239000005418 vegetable material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0096—Multicolour dyeing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/918—Cellulose textile
Definitions
- the cotton (loose cotton, laps, yarns or twisted yarn) to be rendered capable of resisting dye is prepared with higher oxids of manganese.
- a concentrated solution of a salt of peroxid of manganese for example manganous chlorid.
- a strongly-alkaline solution for example one of caustic soda. or ammonia, whereby a manganese hydroxid is precipitated on the fiber.
- An active oxidizing agent such as a hypochlorite or chromate is usually added to this alkaline bath to efiect the formation of the insoluble higher oxids of manganese.
- the manganous' hydroxid precipitated by the alkaline solution may be transformed into the higher oxids on the fiber, by the absorption of atmospheric oxygen when drying.
- the essential feature of the process is the provision on the fiber of higher manganese oxids, whether the sesquioxid or the dioxid, which act in the final stage to liberate oxygen in the acid dye-bath and thereby destroy the grounddyestuf'f at the prepared spots.
- the cotton or other vegetable fiber must be dyed with dyestuffs which are fast to oxidizing agents (thioindigo derivatives, anthraquinone, vatdyestufi's, insoluble azo-dyestuffs or the like) before it is impregnated with the manganese salt.
- dyestuffs which are fast to oxidizing agents (thioindigo derivatives, anthraquinone, vatdyestufi's, insoluble azo-dyestuffs or the like) before it is impregnated with the manganese salt.
- the white or colored vegetable fibers thus prepared with higher oxids of manga nese are used together with undyed cotton or another vegetable fiber or an animal fiber for manufacturing spun goods and woven goods.
- spun goods and woven goods can, if required, be steeped, washed, boiled in the kier bleached or mercerized before the dyeing, without detriment to the action of the oxids of manganese. If the fabrics and spun goods thus prepared are then dyed, the dyestuffs used, so far as they are substantive cotton dyestuffs, are absorbed by the treated and untreated fibers.
- the dyed material is passed through an acid bath, and if for the second dyeing the proper dyestuffs are used, the color absorbed in the second bath is removed from those parts of the fiber which are loaded with the manganese oxids, after the passage through the acid bath it is advantageous to pass the material through a bath of oxalic acid, bisulfite or the like. In this manner a fabric of any ground-color decorated with white or colored effects is obtained.
- the dyeing in the second bath there can be used, among other dyestuffs, substantive cotton dyestuffs, azo dyestuffs capable of being diazotized, and indigo.
- the resulting spun and woven goods having multi-colored effects are characterized by the fact that their ground-color is destroyed when treated with a hypochlorite solution of 12 Twaddle, while the multicolored eflects withstand this treatment.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
IINI
rNr re.
MAX BECKE, or HooHsr-oN-THE-MAIN,
GERMANY, ASSIGNOR TO FARBWERKE VORM.
'IION 0F GERMANY.
PROCESS OF PRODUCING MULTICOLORED EFFECTS IN SPUN AND WOVEN GOODS.
No Drawing.
Specification of Letters Patent.
Patented Aug. 29, 1911.
To all whom it may concern:
Be it known that I, MAX Bnoxn, engineerchemist, a citizen of the Empire of Germany, residing at H6chst-on-the-Main, Germany, have invented certain new and useful Improvements in Processes of Producing Multicolored Effects in Spun and Woven Goods, of which the following is a specification.
In U. S. Patent No. 815,671 is described a process for modifying the atfinity of wool fiber for dyestuffs in such a manner that multi-colored effects of any kind can be obtained in dyeing fabrics composed entirely or partly of wool. Hitherto no analogous process for producing such effects on vegetable fiber has been known. Now I have found that similar white or colored effects can be produced in dyeing cotton and other vegetable material by applying, on the one hand, the oxidizing action of the higher oxids of manganese upon certain dyestuffs, and on the other hand, the stability of certain cotton dyestuffs to this oxidizing action.
According to the new method the procedure is as follows: The cotton (loose cotton, laps, yarns or twisted yarn) to be rendered capable of resisting dye is prepared with higher oxids of manganese. For this purpose it is impregnated with a concentrated solution of a salt of peroxid of manganese, for example manganous chlorid. It is then treated with a strongly-alkaline solution, for example one of caustic soda. or ammonia, whereby a manganese hydroxid is precipitated on the fiber. An active oxidizing agent such as a hypochlorite or chromate is usually added to this alkaline bath to efiect the formation of the insoluble higher oxids of manganese.
Or in lieu of such addition, the manganous' hydroxid precipitated by the alkaline solution may be transformed into the higher oxids on the fiber, by the absorption of atmospheric oxygen when drying. The essential feature of the process is the provision on the fiber of higher manganese oxids, whether the sesquioxid or the dioxid, which act in the final stage to liberate oxygen in the acid dye-bath and thereby destroy the grounddyestuf'f at the prepared spots. For the production of color effects contrasting with those of the subsequent dyeing, the cotton or other vegetable fiber must be dyed with dyestuffs which are fast to oxidizing agents (thioindigo derivatives, anthraquinone, vatdyestufi's, insoluble azo-dyestuffs or the like) before it is impregnated with the manganese salt. The white or colored vegetable fibers thus prepared with higher oxids of manga nese are used together with undyed cotton or another vegetable fiber or an animal fiber for manufacturing spun goods and woven goods. These spun goods and woven goods can, if required, be steeped, washed, boiled in the kier bleached or mercerized before the dyeing, without detriment to the action of the oxids of manganese. If the fabrics and spun goods thus prepared are then dyed, the dyestuffs used, so far as they are substantive cotton dyestuffs, are absorbed by the treated and untreated fibers. However, if the dyed material is passed through an acid bath, and if for the second dyeing the proper dyestuffs are used, the color absorbed in the second bath is removed from those parts of the fiber which are loaded with the manganese oxids, after the passage through the acid bath it is advantageous to pass the material through a bath of oxalic acid, bisulfite or the like. In this manner a fabric of any ground-color decorated with white or colored effects is obtained. For the dyeing in the second bath there can be used, among other dyestuffs, substantive cotton dyestuffs, azo dyestuffs capable of being diazotized, and indigo.
The resulting spun and woven goods having multi-colored effects are characterized by the fact that their ground-color is destroyed when treated with a hypochlorite solution of 12 Twaddle, while the multicolored eflects withstand this treatment.
The great technical advantage of the present process consists in the possibility of keeping the current patterns in stock and dyeing them any ground color, as and when required.
In calico printing the production of resist and discharge effects on indigo-dyed goods by means of the higher oxids of manganese and acids is known; however, a great number of the usual resist, discharge and printing processes cannot be applied in multi-colored dyeing. Moreover the piece dyeing of fabrics consists of vegetable fiber with colored effects, has not yet been carried out in practice, whereas this problem has already been solved as regards wool fiber in an excellent manner, according to U. S. Patent No. 815,671. The possibility of industrially producing contrast-effects of any tint in dyeing vegetable fibers in the piece was not, therefore, to be foreseen.
Having now described my invention, what I claim is:
1. The herein described process of producing multicolored effects in spun and woven goods, by precipitating on vegetable fibers manganese oxids, then Working the fibers thus treated together with untreated fibers, dyeing the goods thus manufactured, and subsequently treating the goods with agents capable of developing the oxidizing action of the manganese oxids.
2. The herein-described process of producing multi-colored effects in spun and woven goods, by precipitating on the ,,vegetable fibers dyed with dyestuffs resisting OX- 1dizing agents, manganese oxids,,then workin the fibers thus treated together with unb treated fibers, dyeing the goods thusmanufactured, and subsequently treating the goods with agents capable of developing the oxidizing action of the manganese oxids.
In testimony whereof, I affix my signature JEAN GRUN CARL GRUND.
Copies of this patent may be obtained for five cents each, by addressing the Commissioner of Patents,
Washington, D. 0.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US57263710A US1002118A (en) | 1910-07-18 | 1910-07-18 | Process of producing multicolored effects in spun and woven goods. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US57263710A US1002118A (en) | 1910-07-18 | 1910-07-18 | Process of producing multicolored effects in spun and woven goods. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1002118A true US1002118A (en) | 1911-08-29 |
Family
ID=3070439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US57263710A Expired - Lifetime US1002118A (en) | 1910-07-18 | 1910-07-18 | Process of producing multicolored effects in spun and woven goods. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1002118A (en) |
-
1910
- 1910-07-18 US US57263710A patent/US1002118A/en not_active Expired - Lifetime
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