UA79748C2 - Compositions of pesticidal concentrate as aqueous microemulsion or liquid emulsion, wherein glyphosate or salt thereof, or ester are pesticide - Google Patents

Abstract

Aqueous pesticidal concentrate emulsions or microemulsions are described which are storage stable afler exposure to temperatures ranging from 60 DEGREE C to -20 DEGREE C.

Description

where V! means linear or branched alkyl or generally --0- (Ou ; (BO) ryne o HAS about 4 to about 16 dev independently means hydrogen or linear or

IN? means hydrogen, methyl, ethyl or -СНгСнНгОЧН, has an explosive, and

BZ means hydrogen, methyl, ethyl or -CHgCsngOuH having from 1 to 3 carbon atoms, where the sum of x and y is not more than about 5; A" in each of the groups (K"O)x and groups (K ОУу means non-

B: stands for hydrogen or methyl; carefully C2-Ca alkylene, , p.

ВАЭ in each of the groups (B9O)p means independently C2-C4 And means hydrocarbylene or substituted hydrocarbylene; belene having from 2 to about 30 carbon atoms

IN? means hydrocarbylene or substituted hydrocarbene, . . belene having from 2 to about 6 carbon atoms - 1 GU in the average number from this, n has a value from 0 to about 5; and where it is related to dialkylphenols having for-

A means sludge acceptable in agriculture: "Щ anion. And in! 3. The composition according to any item 1-2, where glyphosate is mainly in the form of potassium, mono-ammonium, diammonium, sodium, monoethanolamine, n-propylamine salt , ethylamine, ethylenediamine, hexamethylenediamine or trimethylsulfonium. (51) 4. The composition according to item 3, where glyphosate is present and preferably in the form of a potassium salt. 5. The composition according to any of items 1-4, where indicated (ov2 )v3 glyphosate is in solution in the aqueous phase in amounts from approximately 310 to approximately 600 degrees B! and" independently mean hydrogen or linear mv k.e. (acid equivalent) per liter of composi- or branched alkyl group having from 1 to tion. approximately 30 carbon atoms, and at least one 6. The composition according to item 1, where the total amount of and КЕ" means an allyl group, the xeno-active substance is equal to approximately H" in each of the groups (КО)x means independently С2-Са up to approximately 300 grams per liter of the composition. alkylene, which 7. The composition according to clause 6, where the specified surface- B? means hydrogen or a linear or branched active component is in solution or an alkyl group having from 1 to about 4 atoms of stable suspension, emulsion or dispersion. carbon, and 8. The composition according to item 1, which additionally includes water is equal to the average number from 1 to approximately soluble pesticide selected from the group consisting of acifluorfen, acrolein, amitrole, asulam, be- (8) glycosides of the formula: nazoline, bentazon, bialafos, bromacil, bromoxynil, chloramben, chloroacetic acid, closn.on pyralid, 2,4-О0, 2,4-ОВ, dalapon, dicamba, dichloroprop, difenzoquat, diquat, endotal, fenac, pheno-OH xaprop, flamprop, flumiclorac, fluroglycofen, o-k (61) flupropanate, fomezafen, fosamine, glufosinate, Hn o imazamet, imazametabenz, imazamox, imazapic , ima-OH zapyr, imazaquin, imazethapir, ioxynil, MSRA, MSRV, p mecoprop, methylarsenic acid, naphthalam, ; nonanoic acid, paraquat, picloram, hinclorac, where n means the degree of polymerization or the amount of sulfamic acid, 2,3,6-TVA, TSA, triclopyr and their glycoside groups, and water-soluble salts. E means an alkyl group with a branched or straight 9. The composition according to item 1, where the active component indicated by the surface chain, which preferably has from 4 to 18, additionally contains at least one carbon atom, or a mixture of alkyl groups that is less than one nonionic surface-active substance is the average value within the specified range. Well. 10. The composition according to item 9, where the nonionic po- 11. The composition according to item 1, where the indicated cationic surface-active substance includes: the surface-active substance includes: (a) alkylated alcohols having the formula: (a) aminated Alkoxylated alcohols of the formula:

В'О- -В2ОХВУ, (49) t where В! means hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, kOo-(20).- 83 M (9)

B2 in each of the groups (B2O)x independently means C2-Ca4 5 alkylene, i

VAZ means hydrogen or a linear or branched or alkyl group having from 1 to about 4 carbon atoms, and x is an average number from 1 to about bo; (p) dialkylated alcohols having the formula:

di where B", B2 and 25 independently mean hydrogen or hydrocarbyl or substituted hydrocarbyl having from vo (820), - Vz Her where A (19) ov 30 carbon atoms, or

BZ means hydrocarbylene or substituted hydrocarvo, belene, having from 2 to about 18 carbon atoms B! means hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 VAZ and C independently means hydrocarbylene or carbon atoms; substituted hydrocarbylene having from 2 to approx.

B2 in each of the groups (220O)»x and groups (B2O)y means several 4 carbon atoms, depending on Co-Ca alkylene; VI Her 2? independently mean hydrogen or hydrocarbon

B3 and 25 are each independently hydrocarbyl or substituted hydrocarbyl having from 1 to lene or substituted hydrocarbylene having from 1 to about 30 carbon atoms, about 6 carbon atoms; t is equal to 0 or 1,

Ve means hydrogen, hydrocarbyl, or substituted hyd- p is an average number of from 0 to about rocarbyl having from 1 to about 30 atoms 40 and carbon, hydroxy substituted hydrocarbyl, (B5)n- X means -C(O)- or - 505»-, (B2O)UB7, -C(-MA MAV, -C(-0)MA'V OS- a) mono- or diammonium salts having the formula:

С(-5)МВА2ВЗ, or together with P? and the nitrogen atom to which they are attached form a cyclic or heterocyclic ring; in --7 - M -«--k--r5 d- (19 5 . . . w- . t

AND? means hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, hydroxy substituted hydrocarbyl, (P9)p-ve (VO), -C(-MA)ZMATVZ, 0 -C(-0)MA2B , C- or

С(-5)МВА2ВЗ, or together with P" and the nitrogen atom to which they are attached, form a cyclic or heterocyclic ring; 15)

B" means hydrogen or a linear or branched alkyl group having from 1 to about 4 carbon atoms; ,

B", VI? and BZ represent hydrogen, hydrocarbyl or where B, B, VU, Vo and B" independently represent hydrogen substituted hydrocarbyl, or hydrocarbyl or substituted hydrocarbyl having

B" means hydrogen, hydrocarbyl or substituted from 1! to about 30 carbon atoms, or - hydrocarbyl having from 1 to about 30 carbon atoms, | | that carbon, hydroxy substituted "hydrocarbyl, (B5)n- means hydrocarbyl or substituted hydrocarbyl, (B2OUB7, -С(-МВ!)МАТ2ВИЗ, -С(-0)МВВИЗ or - having from 1 to about 30 carbon atoms, с(-8МВгВИ, VZ means hydrocarbylene or substituted hydrocarb- p is 0 or 1, bilene having from 2 to about 30 carbon atoms and y are independently equal to an average of 1 to about 60, and ve and wo are independently hydrocarbylene or

A: means an agriculturally acceptable substituted hydrocarbylene having from 2 to approx. anion; with 4 carbon atoms, p) hydroxylated amides having the formula: B! means hydrogen or hydrocarbyl or substituted by hydrocarbyl having from 1 to about 30 atoms

Y of carbon, in -M--с-- dz t is equal to 0 or 1, (11) n is equal to the average number from 0 to approximately 40, in2 X means -С(0)- or -505-,

And C and 2 mean -C(O)-, and where P! means a hydrocarbyl or substituted hydrocarbyl A: means an agriculturally acceptable white having from about 4 to about 30 atomic anions; had carbon; (is) poly(hydroxyalkylamines) having the formula:

IN? means hydrogen or hydrocarbyl or p-substituted hydrocarbyl having from 1 to about 30 1 / carbon atoms, and and: M, (16)

BZ means hydroxyalkyl, polyhydroxyalkyl or poly(hydroxyalkyl)alkyl; y z y y M c) diamines having the formula: where ve means a hydrocarbyl or a substituted hydrocarbyl having from about 4 to about 30 carbon atoms, or -V'OVU, (13) V? means hydrogen or hydrocarbyl or C2-substituted hydrocarbyl having from 1 to about 30 atoms; carbon,

BZ means hydroxyalkyl, polyhydroxyalkyl or po- X means hydrocarbylene or substituted hydrocarly(hydroxyalkyl)alkyl, belene having from 2 to about 18 carbon atoms

IN? means hydrocarbylene or substituted hydrocarty; belene, having from 2 to about 18 carbon atoms, and is equal to 0 or 1, and this and y is equal to the average number from 0 to about

WZ means hydrogen or hydrocarbyl or substituted 30; hydrocarbyl having from 1 to about 30 triamine atoms () having the formula: carbon; Ккр () alkylated poly(hydroxyalkyl)amines having the formula: - | v5 (27) v x U

IS! (9) e E" means hydrocarbyl or substituted hydrocar- v -(083,-(83,/-M- v5 b is podrocaroyl substituted hydrocar; yl having from 1 to about 30 carbon atoms, where K' и ЕЗ independently represent hydrogen, hydrocarbyl, B2, B3, Be, and 25 independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to carbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, about 30 carbon atoms, or -(B8)5(B7O)p8e,

A" in each of the groups (H?O)x independently means C2-Ca NE means hydrogen or linear or branched alkylene; an alkyl group having from 1 to about 4 atoms

B" means hydrocarbylene or substituted hydrocar-carbon, belene having from 1 to approximately 30 carbon atoms. B" in each of the groups (BO) n means independently C2-C4 this, alkylene;

Vo means hydroxyalkyl, polyhydroxyalkyl or po- BZ means hydrocarbylene or substituted hydrocarly(hydroxyalkyl)alkyl; belene having from 1 to approximately 6 carbon atoms is equal to the average number from 0 to approximately this,

ЗО, n equals the average number from 1 to approximately y equals 0 or 1; 10, (e) dipoly(hydroxyalkyl)amine having the formula: 5 is 0 or 1, and -m--pv8--Mm--p5 x and y are independently equal to a whole number from 1 to (22) approximately 4; and in () diamines having the formula: and: , in- mm-- (ve0),-82 -M--vl3 where В! and EZ independently mean hydrogen or hydro-| | (28) carbyl or substituted hydrocarbyl having from 1 to about 22 carbon atoms, ;

B2 means hydrocarbylene or substituted hydrocarbyl, while B, BZ, B" and Y independently mean hydrogen, belene having from 2 to about 18 carbon atoms, hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or -(B2O)ХВ7,

B and 25 independently mean hydroxyalkyl, polyhyd-B means hydrocarbylene or substituted hydrocarboxyalkyl or poly(hydroxyalkyl)alkyl; bilene having from 2 to approximately 30 carbon atoms - (n) salts of quaternary poly(hydroxyalkyl)amines, which this, -b(-MAS)MATA!Z., 00 -b(-0)MALV. C- have the formula: c(-5)MA:B18-, -C(-МВ2)-, -6(5)- or -C(O)-, in B in each of the groups (290); and groups (250)y means independently C2-Ca alkylene,

B' means hydrogen or a linear or branched k- 5 XX (24) alkyl group having from 1 to about 30 carbon atoms, 2 B", B: and B!Z mean hydrogen, hydrocarbyl or

Kk , a substituted hydrocarbyl having from 1 to approximately where E! means hydrocarbyl or substituted hydrocarbyl of 30 carbon atoms, bil having from about 4 to about 30 carbon atoms, or -Xt-(B'O)UNX, and 50,

B: and EZ are independently hydrogen or hydrocarbyl equal to an average number from 0 to about bil or substituted hydrocarbyl having from 1 to bo; approximately 30 carbon atoms, (K) mono- or diquaternary ammonium salts, which

B" means hydroxyalkyl, polyhydroxyalkyl or having the formula: li(hydroxyalkyl)alkyl, x ve ve x.

X means an anion acceptable in agriculture; which

B" in each of the groups (E"O)u means independently C2-C4 B m (vo), 82 M vv (28) alkylene;

VAZ means hydrogen or a linear or branched rhoalkyl group having from 1 to about 4 atoms or carbons;

oh where is E! means hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, k- - 65 («5 o), 222 ---M----d83 (30) B2 in each of the groups (220); and groups (E2O)y means independently Co-Ca alkylene, в in ВЗ means hydrogen or linear or branched where В", 83. ВУ, В", ВВ and З independently mean vo-alkyl group having from 1 to 4 carbon atoms, day, polyhydroxyalkyl, hydrocarbyl or substituted A means hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms hydrocarbyl having from 1 to about 30 carbon atoms, or -«"B9ОХВ7, carbon, . .

B2 means hydrocarbylene or substituted hydrocarbyl and y are independently equal to the average number of belenes having from 2 to about 30 carbon atoms, 1 to about 40, and x means acceptable in agriculture

ВАЭ in each of the groups (БЕ5О)»х and groups (Е9О)y means non-anion, depending on Со-Са alkylene, (о) salts of monoalkylated quaternary

B' means hydrogen or linear or branched ammonium, the formula is shown; an alkyl group having from 1 to about 4 x-carbon atoms, x is equal to the average number from 1 to about k- their "СК Оу" (39) 30, and y is equal to the average number from about З to ЦІ about 60, and | ;

X means acceptable in agriculture where K' and EZ independently mean hydrogen or hydro-anion; carbyl or substituted hydrocarbyl having from 1 to () a secondary or tertiary amine having the formula - about 30 carbon atoms, lu: B means hydrocarbyl or substituted hydrocarbyl, 2 having from 1 to about 30 carbon atoms, in c! Shk B? in each of the groups (220O)x means independently С2-Са4

M (31) alkylene, in VZ means hydrogen or linear or branched de EC! and KE? means hydrocarbyl having from 1 to alude Group; having from 1 to about 30 carbon atoms, and : in :

VAZ means hydrogen or hydrocarbyl having an average number of from 1 to about 30 carbon atoms, X means agriculturally acceptable (t) monoalkylated amines having the formula: anion: 2 K. ' ,B OK (p ) quaternary ammonium salts having the form- in -M pu:

M (32) in re | x- where is V! and B" independently mean a hydrocarbyl or in - -M vz 35 substituted hydrocarbyl group having from 1 to (35) approximately 30 carbon atoms, or -BZ5H2,

IN? in each of the groups (E2O)x means independently C2-C4 in alkylene, 1 in 3; 4,

BZ means hydrogen or a linear or branched chain where KU, and "EC" independently means hydrogen or an alkyl group having from 1 to about 4 hydrocarbyl atoms or a substituted hydrocarbyl group having from 1 to about 30 carbon atoms,

BZ means a linear or branched alkyl group, B" means hydrocarbyl or substituted hydrocarbyl having from about 6 to about 30 carbon atoms, carbon, X means agriculturally acceptable

B means hydrocarbyl or substituted hydrocaranion; a heavy group having from 4 to about 15 atoms (a) etheramine having the formula: carbon, and p x is equal to the average number from 1 to about oOo-- in --M (36) 60; era (n) salts of dialkylated quaternary ammonium, in ; which have the formula: where E! means hydrocarbyl or substituted hydrocar- (ho) bilene having from 1 to about 30 carbon atoms, x B2 means hydrocarbylene or substituted hydrocarb- in --m-- (vg0)dz bilene having from 2 to about 30 carbon atoms - in (33) this;

BZ and 2" independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or -"VOHB,

B: in each of the groups (E2O)x means independently C2-Ca4 x is equal to the average number from 1 to approximately alkylene, 50;

AND? means hydrogen or a linear or branched () diamine having the formula: an alkyl group having from 1 to about 4 carbon atoms and -03,-(53,-M-(b60),-- B2-M- with i wherein B, B, B, and E are independently hydrogen, wherein B is hydrogen, hydrocarbyl or substituted hydrocarbyl or substituted hydrocarbyl having from hydrocarbyl having from 1 to about 30 carbon atoms and from 1 to about 30 carbon atoms, or -(B9О)ХВ7; carbon;

B: and 8 stand independently for hydrocarbylene or B? in each of the groups (BE2O)»x and groups (E2O)y means an unsubstituted hydrocarbylene having from 2 to approximately C2-Ca alkylene; of 30 carbon atoms, VAZ means hydrocarbylene or substituted hydrocar-

ВАЭ in each of the groups (БЕ5О)»x and groups (Е9О)y means non-whitene having from about 2 to about 6 depending on C2-Са alkylene, carbon atoms;

B' means hydrogen or linear or branched B and 25 means each, independently, hydrogen, a hyd-alkyl group having from 1 to about 30 ato-carbyl or a substituted hydrocarbyl having from 1 mv carbon to about 30 carbon atoms, - (B9U)n-(820)u87; x is the middle number between 1 and about A? means hydrocarbylene or substituted hydrocar-

ZO, belene having from 1 to approximately 6 carbon atoms

X means -O-, -M(B9)-, -С(0)-, -С(Ф0О-, -ОС(О)-, - this,

M(AU)C(O)-, -C(O)M(AZ)-, -5-, -50- or -505, A" means hydrogen or linear or branched and is equal to 0 or an average number from 1 to approx. - an alkyl group having from 1 to about 4 carbon atoms, n and 75 are independently 0 or 1, and n is 0 or 1, and

IN? means hydrogen or hydrocarbyl or substituted x and y are independently equal to the middle number of hydrocarbyl; 1 to about 60; (5) amine oxides having the formula: (0) dialkylated amines having the formula: o-rin -- - - M -6-от 40

IN! M-- dz (38) In M. (40) (vgo)uvZ 2 where K! means hydrogen or hydrocarbyl or substituted; p3 and sla. hydrocarbyl having from 1 to about 30 carbyl or substituted hydrocarbyl having up to 0 TOM of carbon, "AB or CH(RON, . bla 5 B? in each of the (220)x groups, (B2O)y groups and groups (220); approximately 30 carbon atoms, -(B"'С)ХА? or - сСо»-С and

В(ОВУхО В; means independently C2-Ca alkylene,

B" in each of the groups (E"O)x means independently C2-C4, НА means hydrogen or a linear or branched alkylene alkyl group having from 1 to about 22 atoms, о means hydrogen or hydrocarbyl or a substituted carbon atom, . hydrocarbyl having from 1 to about 30 atoms in means a linear or branched alkyl group, carbon, having from about 6 to about 30 atoms

AND? means hydrocarbylene or substituted hydrocar- carbon, n. belene having from 1 to about 6 carbon atoms - B? means a linear or branched alkyl group, this ' having from about 4 to about 15 atoms o. I of carbon, and it has an average number of from 1 to about Alkoxylated alcohols having (9 alkylated amino oxides having the following chemical structure: at)

Оо-- (220), --83--М--з 7 0- (39) in o where B, B", VZ and EE? each independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl, which has from 1 to approximately 30 carbon atoms, or - (8)5(ВЗ3ОХВО;

X means -0-, -OC(0)-, -C(0)0-, -M(B2)C(0)-, - B!2 means hydrogen or hydrocarbyl or substituted c(oOmM(B2)-, -5-, -5O-, -502- or -M(VU)-; BZ in each is a hydrocarbyl having from 1 to about 30 atoms of each of the groups (EZO)y and groups (EZO)y means independently of carbon;

C2-Ca alkylene; t and 5 are equal, each independently, to 0 or 1;

IN!? means hydrogen or linear or branched B means hydrocarbylene or a substituted hydrocaralkyl group having from 1 to about 30 atobilene having from 2 to about 30 carbon atoms; this, -С(-МА12)-, -(5)- or -С(0)-, n is equal to an average number from 1 to approximately 4 equal to a whole number from to 5; and because; BZ is hydrogen or hydrocarbyl or substituted m is an average number of from 1 to about hydrocarbyl having from 1 to about 30 50 atoms; carbon;

IN? Its B!" are each independently a hydrocarbi- (m) quaternary ammonium, sulfonium or lene salt or substituted hydrocarbylene having from 1 to sulfoxonium having the following chemical structure: about 6 carbon atoms;

В" means hydrocarbylene or substituted hydrocarbylene having from 2 to approximately 6 carbon atoms; it has 7 A: в- ХХ («555 («2602 - --- ((М892-І ZVUK (43)

Ge; or

A: Y Y Y A: -- Her (sh0)7ISHYVA-tr o (4) in vo or

A: "Y Her d- v'- -58 3-- (c) o) - (Me 5 M --28 (45) and or o: Y BA v- Yav85 - - (622 5 l (2530) - 8--(mle),-M-88 (46) and where B, B", VV, VU, VO Her B! stand independently and 5 are equal, each independently, to 0 or 1; hydrogen, hydrocarbyl or substituted hydrocarbyl, that B? means hydrocarbylene or substituted hydrocarbene having from 1 to about 30 carbon atoms, or - belene having from 2 to about 6 carbon atoms- (A) (AZO)MV;

X means -О-, -ОС(О)-, -Ш(АС(0)-, -С(О)М(Б1У)-, - А? means hydrocarbylene or substituted hydrocar-

C(OYU- or -5-; belene having from 2 to approximately 30 carbon atoms

ВЗ in each of the groups (ЗО) and groups (ЗО) means non- this, -С(-МВ12)-, -С(5)- or -С(0)-; depending on C2o-Ca alkylene; B!" means hydrogen or hydrocarbyl or substituted

IN! means hydrogen or a linear or branched hydrocarbyl having from 1 to about 30 atoms, an alkyl group having from 1 to about 30 carbon atoms; had carbon; 4 is equal to a whole number from 0 to 5; n equals an average number from 1 to about BZ represents hydrogen or hydrocarbyl or substituted bo; hydrocarbyl having from 1 to about 30 atoms m equal to the average number of from 1 to about carbon; and 50; each A" means acceptable in the rural economy

B2 and VZ mean, each independently, hydrocarbon anion; lene or substituted hydrocarbylene having from 1 to (x) a diamine or diammonium salt having the formula: about 6 carbon atoms;

k-- (to ZSH M-- 53 | AM- («6 2o - le do yiv or ke 7 - ok MOM kovo, OM 6 (203 (48) ko ko de E", VU, B5, Ve, B" and C independently represent either hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms,

B2 in each of the groups (B2)t and groups (220); and EZ independently k-x-' ((54) mean Co-Ca alkylene, V

BZ means hydrocarbylene or substituted hydrocarboO- (o) bilene having from about 2 to about 6 or 1 carbon atoms, or -(B2O)pAg-, and n equals, each independently, an average ee number from 0 to about 50, and 25 r is equal to the average number from 0 to approximately v-xxy (go 25552 5252 ve (55) 60; with Hei or o--(820),83 (y) compound of the formula: or kw vo do t de ve (c2) | c

В Х в'-М-кСв20), also (56) -- 2 З о (о | о--с(820),83 or vo ve В z vo vo or

KOH uh with / o- - (go) or

А- 8 ее вА- ДЯ (в«20)2 (8932 Х in (B7) and 8 О- (820), А83 or two He in 2-х (voi vo Mov (58) in vo o-( 220) with or dov" A Ge

Te k- M Yu -("520)52 3519 --- M - in (59) t w o o o- -(522O EE where B", B? and B!2 mean independently the hydrocarbyl oil phase, which contains an organic solvent , or a substituted hydrocarbyl having from 1 to about substantially immiscible with water, having soluble 30 carbon atoms, or -(B2O)p0B3; water content less than about 1095 (w/w) and

IN? in each of the groups (B2O)t, groups (20), groups (B2O)p and the surface-active component containing each group (820) means independently Co2-Ca alkylene; at least one cationic surfactant

VAZ, BB, B, VZ and B!5 independently mean a hydrogen substance, and this surface-active rheco- or hydrocarbyl or substituted hydrocarbyl having wine is present in a concentration sufficient for za- from 1 to about 30 carbon atoms; ensuring acceptable thermal stability of this

IN? means -(СНг)уУОВ"З or -«(СНгУуО(Б2О)аВЗ; VU, emulsions, so that this emulsion has a cloud point

BO and B" are independently hydrogen, a hydrocarbyl of at least about 50"C and a crystallization point, or a substituted hydrocarbyl having from 1 to about higher than about 0"C, less than 30 carbon atoms, or P-; and wherein said stabilizer contains one or several

IN? means a hydrocarbylene or substituted hydrocarbyl compound of amine or quaternary ammonium salts, bilene, having from 2 to about 30 carbon atoms, each of which contains an alkyl or aryl substituent; a snick having from about 4 to about 16

"B" means hydrogen, hydrocarbyl or substituted carbon atoms, and not more than ten ethylene hydrocarbyl having from 1 to about 30 atoms of sidic bonds in this compound, and the specified carbon, or -(CHg);: О(82О)0ВЗ; meadows are present in an amount that increases the compatibility of т, н, р, and д are independently equal to the average of the indicated surface-active component with dust from 1 to approximately 50; sticicide.

X means independently -О-, -М(Б17)-, -С(О)-, -С(0)О-, 21. The composition according to item 20, where the stabilizer is selected from -Ос(0)-, -Щ (B")С(О0)-, -С(О)М(Б5)-, -5-, -50- or - group, including salts of amines or quaternary

ZO-; ammonium having the formulas:

Y is equal to 0 or 1; UA

A means acceptable in agriculture in -M anion; and M (5) y and 7 are independently equal to a whole number from 0 to 3 approximately 30. or 12. The composition according to item 1, where this composition is stable when stored at 50"C for at least 14 days 13. The composition according to item 1, where this composition is stable when stored at 50C for at least M - 26 5 x 126z (6) and 28 days. 14. The composition according to item 1, where this composition has elm - the bone is less than approximately 1000 centipoise, with vi

OS and shear speed 45 s". 15. The composition according to item 1, where the specified surface or active component is selected in such a way that this composition does not detect the crystallization of the specified vo---(v90),-- B5 shk 7 pesticide when stored at a temperature of approximately -107C for a period of about 7 days. 16. The composition according to item 1, where the specified surface-active or I active component is selected in such a way that this composition does not show crystallization of the specified pesticide at storage at a temperature of approximately -20"C for a period of about 7 days. kOo--(0),8-m-84 A: (8) 17. The composition according to item 1, where the crystallization point is not higher than approximately - 20260. 18. The composition according to claim 1, wherein the composition is essentially homogenous when stored at 507°C for a period of one week, where B is linear or branched alkyl or aryl having from about 4 to about 16 19. The composition according to item 1, where the cloud point of the additional carbon atoms is at least approximately 607 C. B? means hydrogen, methyl, ethyl or -(СНаСНГО)ХН , 20. The emulsion composition of a liquid pesticide con- AZ means hydrogen, methyl, ethyl or -(СНСН2О)уН, concentrate, which has a continuous aqueous phase and before the sum of x and y is equal to no more than approximately 5; a jerky oil phase containing: B: means hydrogen or methyl; the pesticide component consisting of water in each of the groups (KO) n means independently C2-C4 of the soluble pesticide dissolved in the indicated vo- alkylene; bottom phase, where the pesticide is glyphosate or its VZ means hydrocarbylene or substituted by hydrocarsyl or ether, and this water-soluble belene having from 2 to about 6 carbon atoms, the pesticide is present in a concentration that is biologically relevant, n has a value from 0 to about 5, and effective when diluting the composition in the answer- A: means acceptable in agriculture bottom volume of water and applying to the leaves sensitive anion. plants;

22. The composition according to any of paragraphs 20-21, where glyphosate is mainly in the form of potassium, monoammonium, diammonium, sodium, monoethanolamine, n-propylamine, ethylamine, ethylenediamine, hexamethylenediamine or trimethylsulfonium salt. (51) 23. The composition according to item 22, where glyphosate is 4 mainly in the form of a potassium salt. and: 24. The composition according to any of paragraphs 20-23, where the specified (o82),Az glyphosate is in solution in the aqueous phase in x, in amounts from approximately 310 to approximately 600 degrees B! and B" independently represent hydrogen or linear mev c.e. (acid equivalent) per liter of compo- or branched alkyl group having from 1 to tion. about 30 carbon atoms, and at least one 25. The composition of claim 20, wherein the total amount of 3 B and 22 means an alkyl group, surfactant equals from approx. B? in each of the groups (K2O)x means independently C2-C4 from 20 to about 300 grams per liter of the composition. alkylene, 26. Composition according to claim 25, where the specified surface- VZ means hydrogen or a linear or branched active component is in solution or an alkyl group having from 1 to about 4 atoms of stable suspension, emulsion or dispersion. carbon, and 21. The composition according to claim 20 , further comprising x is an average of 1 to about a water-soluble pesticide selected from the group consisting of 60; or comprising acifluorfen, acrolein, amitrole, asulam, (4) a glycoside having the formula: benazoline, bentazon, bialaphos, bromacil, bro - moxynil, chloramben, chloroacetic acid, bug i.s. on ralide, 2,4-O0, 2,4-OB, dalapon, dicamba, dichlor-2 prop, difenzoquat, diquat, endotal, fenac, (c) fenoxaprop, flamprop, flumiclorac, fluroglion o- in (61) caffeine, flupropanate, fomezafen, fosamine, glufosinate, imazamet, imazametabenz, imazamox, H o imazapic, imazapyr, imazaquin, imazetapir, ioxynil, on p

MCRA, MCSOSRV, mecoprop, methylarsenic acid, naphthalam, nonanoic acid, paraquat, picloram, where n means the degree of polymerization or the amount of hinclorac, sulfamic acid, 2,3,6-TVA, TCA, glycosidic groups, and triclopyr and their water-soluble salts. And B means an alkyl group with a branched or straight 28. The composition according to item 20, where the active component indicated by the surface chain, which preferably has from 4 to 18, additionally contains at least one carbon atom, or a mixture of alkyl groups, which is less one nonionic surface-active substance has an average value within the specified range. | | Well. 29. The composition according to item 28, wherein the nonionic 30. The composition according to item 20, wherein the cationic surfactant includes: the surfactant includes: (a) alkylated alcohols having the formula: (a) aminated alkylated alcohol , which has the formula kOo-- (o) (49): where EK! means hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms,

B2 in each of the (22O)x groups independently means C2-C4 o-(0).-vz and (5) alkylene,

VAZ means hydrogen or a linear or branched alkyl group having from 1 to about 4 atoms or carbons, and x is an average number of from 1 to about 60; KOo-- (20). 83-- MAMA: (10) (p) dialkylated alcohols having the formula:

Kok Oo---95-- (Ou (BO) v5 where K' independently means hydrogen or linear or where B! means hydrogen or hydrocarbyl or substituted branched-branched alkyl group having from 1 to proximal hydrocarbyl having from 1 to about 30 to 4 carbon atoms, carbon atoms;

AND? in each of the groups (VO); and groups (H?O)y means non-B2 in each of the groups (B2O)x and groups (B2O)y means independently C2-Ca alkylene, depending on Co-Ca alkylene;

VZ means hydrocarbylene or substituted hydrocar- VZ and 2? means, each independently, a hydrocarbylene having from 2 to about 30 carbon atoms or a substituted hydrocarbylene having from 1 to

This, | approximately 6 carbon atoms; x and y are independently equal to the mean number of B" means hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to about 60; rocarbyl having from 1 to about 30 atoms (c) alkylated dialkylphenols having for- carbon, hydroxy substituted hydrocarbyl, (B )p- mud:

(jaO)uUV", 0 -С(-MAL)MAVIZ, 0 -0(-0)МВ2В, OS- where

С(-5)МВА2ВЗ, or together with P? and the nitrogen atom to which they are attached form a cyclic or 4-membered heterocyclic ring; к-ШНШН BV M-- M -815 A (14)

IN? means hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 atoms and in carbon, hydroxy substituted hydrocarbyl, -(B9)p- and Kk (yagO)uUV", 0 -C(-MAL)MAVIZ, 0 - 0(-0)MV2V, OS- or

C(-5)MV"gV"Z, or together with B" and the nitrogen atom to which A: 7 re are attached, form a cyclic or i heterocyclic ring; т-х m в3- А re d- 15

B' means hydrogen or linear or branched t| | (15) an alkyl group having from 1 to about 4 carbon atoms; 2 re

A", B: and BZ represent hydrogen, hydrocarbyl or where B, B2, VU, B5 and B7 independently represent hydrogen, substituted hydrocarbyl, | | Y or hydrocarbyl or substituted hydrocarbyl having

B" means hydrogen, hydrocarbyl or substituted from Her to about 30 carbon atoms, or - hydrocarbyl having from 1 to about 30 carbon atoms, hydroxy substituted hydrocarbyl, -"(H)- Be means hydrocarbyl or substituted hydrocarbyl, (ВРОув", C(-MASIMAUA, -b(-0О)MAV or - having from 1 to about 30 carbon atoms, с(-5MAA, VAZ means hydrocarbylene or substituted hydrocarb- p is equal to b or 1, | bilene having from 2 to approximately 30 carbon atoms and y are independently equal to the average number of this,

It is approximately BB and 29 mean individually hydrocarbylene or

A means acceptable in agriculture substituted hydrocarbylene having from 2 to approx. anion; what are 4 carbon atoms,

B) hydroxylated amides having the formula: B? means hydrogen or hydrocarbyl or substituted by hydrocarbyl having from 1 to about 30 atoms

of its carbon, in - -:F--5-- rz3 (9) t is equal to 0 or 1, n is equal to the average number from 0 to approximately 40,

B X means -C(0)- or -50»5-, where B! means hydrocarbyl or substituted hydrocarbo- means-F(Oi bil) having from about 4 to about 30 ato- A means acceptable in agriculture miv of carbon; anion, shi

B is hydrogen or hydrocarbyl or substituted (e) poly(hydroxyalkyl)amines having the formula: hydrocarbyl having from 1 to about 30 UA carbon atoms, and in -kmMm (16)

BZ means hydroxyalkyl, polyhydroxyalkyl or poly(hydroxyalkyl)alkyl; Kk, c) diamines having the formula: where E! means hydrocarbyl or substituted hydrocarbyl, - xx, 533 M-5---a2»B-A--p5 bil having from about 4 to about 30 carbon atoms, or -B'OVU, (19) B? means hydrogen or hydrocarbyl or substituted 2 de hydrocarbyl having from 1 to about 30 atoms where B, B: and 25 are independently hydrogen or carbon, . with, . p hydrocarbyl or substituted hydrocarbyl having from B means hydroxyalkyl, polyhydroxyalkyl or po- 1 to about 30 carbon atoms, or - ly(hydroxyalkylalkyl, and sho, veOVO B, v means hydrocarbylene or substituted hydrocarbyl

VZ means hydrocarbylene or substituted hydrocarbylene having from 2 to about 18 carbon atoms, bilene having from 2 to about 18 carbon atoms, ! y y y - this, B means hydrogen or hydrocarbyl or substituted

Ve and VZ independently mean hydrocarbylene or hydrocarbyl having from 1 to about 30 substituted hydrocarbylene having from 2 to about carbon atoms. More with, . of 4 carbon atoms, (FO apoxylated poly(hydroxyalkyl)amines, which ma-

Ve and V? independently mean hydrogen or hydrogen of the formula: c rbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, | (19) t is equal to 0 or 1, n is equal to the average number in --(Ов3,-(83,- M--Зов5 from 0 to approximately 40, and x У ;

X means -С(О)- or -50"-, where EK! and EZ independently mean hydrogen, hydrocarbyl 4) mono- or diammonium salts having the formula: white or substituted hydrocarbyl having from 1 to about 30 carbon atoms,

B2 in each of the groups (220O)x means independently C2-C4, VAZ means hydrogen or linear or branched alkylene; an alkyl group having from 1 to about 4 atoms

IN? means hydrocarbylene or substituted hydrocar- carbon, belene having from 1 to about 30 carbon atoms - B" in each of the groups (B/O)n means independently C2-Ca4 this, alkylene;

VAZ means hydroxyalkyl, polyhydroxyalkyl or po- VAZ means hydrocarbylene or substituted hydrocarly(hydroxyalkyl)alkyl; belene having from 1 to approximately 6 carbon atoms is equal to the average number from 0 to approximately this, 30, n is equal to the average number from 1 to approximately y is equal to 0 or 1; 10, (9) dipoly(hydroxyalkyl)amine having the formula: 5 is 0 or 1, and vME-M8--p--M--p5 x and y are independently an integer from 1 to about 4; (гг) () diamines having the formula: and в в - МмМ- (в80),-82 -М- dz where В! and EZ independently mean hydrogen or hydro-| | (28) carbyl or substituted hydrocarbyl having from 1 to about 22 carbon atoms, ;

B2 means hydrocarbylene or substituted hydrocarbyl, and EC", BZ, B" and KZ independently mean hydrogen, belene having from 2 to about 18 carbon atoms, hydrocarbyl or substituted hydrocarbyl having from this and 1 to about 30 carbon atoms , or -(B9О)ХВ",

B and 25 independently mean hydroxyalkyl, polyhyd-B means hydrocarbylene or substituted hydrocarboxyalkyl or poly(hydroxyalkyl)alkyl; bilene, having from 2 to approximately 30 carbon atoms - (p) salts of quaternary poly(hydroxyalkyl)amines, which this, -b(-MASMATV!Z., 00 -b(-0)MA'BZ., C- have formula: с(-8)МА V. -С(-МА2)-, -С(5)- or -С(О)-, in VAE in each of the groups (B9O), and groups (EO)u means no - depending on C2-Ca alkylene,

B" means hydrogen or a linear or branched в'- 585-858 xX. (24) alkyl group having from 1 to about 30 carbon atoms,

B", B", and B!Z are hydrogen, hydrocarbyl or 2-substituted hydrocarbyl having from 1 to about where B! means hydrocarbyl or substituted hydrocarbyl with 30 ulene atoms. from 1 to almost white, having from about 4 to about 30 atoms of an average number from y to priolizn and -Xt-(BA 5 and , carbon atoms, because they mean hydrogen or hydrogen, with an average number from 0 to about white or substituted hydrocarbyl having from 1 to (K) a mono- or diquaternary ammonium salt of about 30 carbon atoms, and

IN? means hydroxyalkyl, polyhydroxyalkyl or having the formula; sli vish: ate; wa li(hydroxyalkyl)alkyl, x- x-

X means an anion acceptable in agriculture; в/-М-- (re) --р2 -- м--рз3

B" in each of the groups (B"O)y means independently C2-C4 | o, and " in (29) alkylene;

VAZ means hydrogen or a linear or branched alkyl group having from 1 to about 4 atoms or carbons; entrance

X is a hydrocarbylene or a substituted hydrocarbylene having from 2 to about 18 carbon atoms; k-- 3 МХ А A -«25о5)/ в2-А- --М-- rz (30) t is equal to 0 or 1, and y is equal to the average number from 0 to about 30; in o

Ф that have the form у where В", ВЗ, ВУ, В", ВЗ and В? independently mean vo- -k ra den, polyhydroxyalkyl, hydrocarbyl or substituted

UM sk hydrocarbyl having from 1 to about 30 atoms 3 x | there are (27) carbons, or -(B5О)ХВ7, in! B2 means hydrocarbylene or substituted hydrocar- ; belene, having from 2 to about 30 carbon atoms, where E! means hydrocarbyl or substituted hydrocarbyl, white having from 1 to about 30 carbon atoms, B? in each of the groups (90); and groups (B9O)u means non-

B2, VU, B" and Ex independently mean hydrogen, hydro-dependent Co-Ca alkylene, carbyl or substituted hydrocarbyl having from 1 to B" means hydrogen or linear or branched of about 30 carbon atoms, or -(B8)5( B/O) c, an alkyl group having from 1 to about 4 carbon atoms,

x is an average number from 1 to about (0) of the mono-alkylated quaternary salt

ZO, ammonium having the formula: y is equal to the average number from about 3 to about 60, and | xx

X means an anion acceptable in agriculture; O-m- (Ou (39 (I) secondary or tertiary amine having the form: do ve / 15 vv ' ! v! - M (31) where V and are independently mean hydrogen or hydro-

M is carbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, where B! and B? means hydrocarbyl having from 1 to c means hydrocarbyl or substituted hydrocarbyl, about 30 carbon atoms, and having from 1 to about 30 carbon atoms,

BZ means hydrogen or hydrocarbyl having from 1 A" in each of the groups (K"O)x means independently C2-Ca up to about 30 carbon atoms; alkylene, shk (t) monoalkylated amines having the formula: C means hydrogen or a linear or branched (820),8z alkyl group having from 1 to about 30 carbon atoms,

EE M (32) x equals the average number from 1 to approximately 60,

B , X means acceptable in agriculture where B! and B" independently mean hydrocarbyl or anion; substituted hydrocarbyl groups having from 1 to (p) quaternary ammonium salts having the form - approximately 30 carbon atoms, or -855H8, pu:

B2 in each of the (220O)x groups independently means C2-C4 tk alkylene, | xx

ВЗ means hydrogen or a linear or branched alkyl group having from 1 to about 4 atoms Kk - m - 5 zШ from (35) carbon,

IN? means a linear or branched alkyl group having from about 6 to about 30 carbon atoms, wherein B, B, and B are independently hydrogen or

AND? means hydrocarbyl or substituted hydrocarb- hydrocarbyl or substituted hydrocarbyl having a group having from 4 to about 15 carbon atoms 1 to about 30 carbon atoms, carbon, and B2 means hydrocarbyl or substituted hydrocarbyl, x is an average number of from 1 to about having from 1 to about 30 carbon atoms, and 60; X means acceptable in agriculture (n) salts of dialkylated quaternary ammonium, anion; having the formula: (e) etheramines having the formula: (20 в3 х р оОо--в--М (36) 8-х -- (вгО0)увз (33) bod where B! means hydrocarbyl or substituted hydrocarb- ve bil having from 1 to about 30 carbon atoms, , B: means hydrocarbylene or substituted hydrocar- de RK! means hydrocarbyl or substituted hydrocarbylene having from 2 to about 30 carbon atoms, white having from 1 to approximately 30 carbon atoms, this;

A" in each of the groups (B"O)x and groups (K"O)y means non-

AZ means hydrogen or a linear or branched chain of 30 carbon atoms, or -(Б5О)хВЭ, an alkyl group having from 1 to 4 carbon atoms, А? in each of the groups (ERO)x means independently С2-Са

A" means hydrogen or hydrocarbyl or substituted alkylene, hydrocarbyl having from 1 to about 30 atoms A? means hydrogen or straight or branched carbon, | | an alkyl group having from 1 to about 4 atoms x and y are independently equal to the average number from carbon, and 1 to about 40, and x is the middle number from 1 to about

X means acceptable in agriculture 50; anion, () diamines having the formula:

k-(05,-(«8553,--M-(80),-82-M- vz ik vo where B, VZ, V? and EZ mean independently hydrogen, B and 25 mean each independently, hydrogen, hyd- hydrocarbyl or substituted hydrocarbyl having from rocarbyl or substituted hydrocarbyl having from 1 1 to about 30 carbon atoms, or -(B5O)XB7; up to about 30 carbon atoms, -(B9)p-(820)y87;

Q: and 8 stand independently for hydrocarbylene or A? means hydrocarbylene or substituted hydrocar- substituted hydrocarbylene having from 2 to about bilene having from 1 to about 6 carbon atoms 30 carbon atoms, this,

IN? in each of the groups (B9O); and groups (B90)u means non- B' means hydrogen or a linear or branched depending on C2-Ca alkylene, an alkyl group having from 1 to about 4 atoms

B' means hydrogen or linear or branched carbon, an alkyl group having from 1 to about 30 atoms, and m is 0 or 1, and mv carbon, x and y are independently equal to the average number of x is equal to the average number of 1 to about 1 to about 60; 30, (0) dialkylated amines having the formula:

X means -O-, -M(B9)-, -С(0)-, -С(Ф0О-, -ОС(О)-, - (Оу

M(АЗС(О)-, -(ОМ(ВЗ)-, -5-, -50- or -505, / y is equal to 0 or the average number from 1 to approx. (40) or 30, Kk - n and 75 are independently equal to 0 or 1, and (th)

AND? means hydrogen or hydrocarbyl or substituted B. I I hydrocarbyl; where P" is hydrogen or hydrocarbyl or substituted amine oxides having the formula: hydrocarbyl having from 1 to about 30 carbon atoms, -B'ZA? or -(820)283,

B2 in each of groups (220)x, groups (K2O)y and groups (220); means independently C2-Ca alkylene, - m - dz (38) BZ means hydrogen or a linear or branched alkyl group having from 1 to about 22 atoms? had carbon, ; B" means a linear or branched alkyl group, wherein B, B? and E3 are independently hydrogen, hydrocarbyl having from about b to about 30 carby atoms or substituted hydrocarbyl having from 1 to about 30 carbon atoms, -( В'О)ХА? or - В: means a linear or branched alkyl group,

ВО хО В"; having from about 4 to about 15 atoms

B: in each of the groups (2"O)x means independently C2-C4 carbon, and alkylene, x, y and 7 are independently equal to the average number

WZ is hydrogen or hydrocarbyl or substituted from 1 to about 40; hydrocarbyl having from 1 to about 30 atoms (m) of aminated carboxylated alcohols having carbon, the following chemical structure:

B means hydrocarbylene or substituted hydrocarbylene having from 1 to about 6 carbon atoms in this, - - x--30(523,-(830)-- -A- (Mk), (41) x equals an average number from 1 to about 50, the total number of carbon atoms in B", B? and EZ-; equals at least 8; where B", B", B? and 2? mean, each independently, () alkylated amine oxides having the form hydrogen, hydrocarbyl, or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or - where (8)5(BZ3OXHO; / X means -0-, -0ОС(0)-, - С(Ф000О-, -М(В!2)С(0)-,. - о---о(820),- 83-х --0- (39) с(ом(В., -5- , -30-, -ЗО2- or -М(ВЗ)-;

M VZ in each of the groups (EZO)n and groups (EZO)y means non-dependent C2o-Ca alkylene; ; IN!? means hydrogen or linear or branched where B! means hydrogen, hydrocarbyl, or a substituted alkyl group having from 1 to about 30 carbon atoms; hydrocarbyl having from 1 to about 30 carbon atoms; carbon; n equals the average number from 1 to approx

B2 in each of the groups (220)x means independently C2-Ca4 because; alkylene; m equals an average number from 1 to approx

VZ means hydrocarbylene or substituted hydrocarbyl 50; bilene having from about 2 to about 6 carbon atoms;

B2 and B" are, each independently, hydrocarby- A? means hydrocarbylene or substituted hydrocarlene or substituted hydrocarbylene having from 1 to belene having from 2 to about 30 carbon atoms- about 6 carbon atoms; this, -C (-МВ12)-, -С(5)- or -С(0)-,

IN? means a hydrocarbylene or a substituted hydrocar- 4 is an integer from 5 to 5; and bilene, having from 2 to about 6 carbon atoms - B? means hydrogen or hydrocarbyl or substituted thi; hydrocarbyl having from 1 to about 30 atoms

B!2 means hydrogen or hydrocarbyl or substituted carbon; a hydrocarbyl having from 1 to about 30 atoms (m) of a quaternary ammonium, sulfonium or carbon salt; sulfoxonium having the following chemical structure: t and 5 are equal, each independently, to 0 or 1;

Y 7 A vVK-x-y(023-s(830)--8-- shi - (43)

Ge or

A- to her І І A: p ny ny MI t ve ge or

А и Й Й d- в'- 5--- (c), -e kA is ( - (Mk). - m Я- г (45)

Her or her: Y V A vA-YAB8 -(625. 5 5 5 (02520)-----(1М23,-М-ят8 (46)

Her de E!, B", 88, VU. VO Her B! mean independently B!" means hydrogen or hydrocarbyl or substituted hydrogen, hydrocarbyl or substituted hydrocarbyl, which hydrocarbyl having from 1 to about 30 carbon atoms has from 1 to about 30 carbon atoms, or - carbon; (Z) (AZOV; 9 is equal to a whole number from 0 to 5;

X means -O-, -OC(O)-, -M(B)C(0)-, -"C(OM(B-, - B? means hydrogen or hydrocarbyl or substituted

C(OYU- or -5-; hydrocarbyl having from 1 to about 30 atoms

AZ in each of the (ZO) and (EZO) groups means non-carbon; and depending on C2-Ca alkylene; each A" means acceptable in the rural economy

B!2 means hydrogen or a linear or branched anion; an alkyl group having from 1 to about 30 atoms- (x) a diamine or diammonium salt having the formula: mv carbon; к--- (2-О-5-Ш M--в3--М - я ("20 t n is equal to the average number from 1 to approximately 60; ve in (47) m is equal to the average number from 1 to approximately or 50 ;

B2 and C are, each independently, hydrocarbylene or substituted hydrocarbylene having from 1 to 4 and about 6 carbon atoms; ) t and 5 are equal, each independently, to 0 or 1;

B means hydrocarbylene or substituted hydrocarbyl, belene having from 2 to about 6 carbon atoms B", VU, B5, Bе, B7 and BZ independently mean vo- cy; | | | what day or hydrocarbyl or substituted hydrocarbyl, c means hydrocarbylene or substituted hydrocar- having from 1 to about 30 carbon atoms, bilene having from 2 to about 30 carbon atoms - B2 in each of the groups (B2O) t and groups (B2O)n and this, " C(-MAU, -0(5)- or -F(0).; A? independently mean C2-Ca alkylene,

BZ means hydrocarbylene or substituted hydrocarbide B", BZ and B!2 independently mean hydrocarbyl belene having from about 2 to about 6 or substituted hydrocarbyl having from 1 to about 1 carbon atoms, or -(B2O)pAg- , there are 30 carbon atoms, or -(B2O)vB3; t and n are equal, each independently, to the average B? in each of the groups (220) t, groups (220), groups (B2O)p and a number from 0 to approximately 50 , and groups (Е20О)4 independently means Со2-Са alkylene; p is an average number from 0 to about ВЗ, ВВ, В, В!З Its вх independently means hydrogen or; or hydrocarbyl or substituted hydrocarbyl having either from 1 to approximately 30 carbon atoms; (y) a compound of the formula: В? means -"СНгУуОВ З or -"СНгУуС(Б2О)аВЗ; в" ve VU, VU Her B" mean independently hydrogen, hydrocarbyl or substituted hydrocarbyl, which has from 1 to about 30 carbon atoms, or B"; v'-h ik (52) V? means hydrocarbylene or substituted hydrocarbylene having from 2 to about 30 carbon atoms - (o) this; or B" means hydrogen, hydrocarbyl or substituted b" in hydrocarbyl having from 1 to about 30 carbon atoms, or -(CHg);O(B2O)rvZ;

A: X t, n, r and 4 are independently equal to the average number! in (53) lu from 1 to about 50;

X means independently -O-, -M(B14)-, -C(0)-, -C(O)O-, / o-- (820), E3 -os(0)-, -"(A" )С(О0)-, -С(О)М(В)-, -5-, -50- or - ве 5О»-; with Y equals 0 or 1; or in A means acceptable in agriculture

Kk in anion; and and y and 7 are independently equal to a whole number from 0 to 1 and (59) approximately 30.

Kk x (o), 7 31. The composition according to item 20, where the composition is a microemulsion. o (RO), , 32. The composition according to item 20, where the composition is optically or transparent. ve 33. The composition according to item 20, where this composition is stable when stored at 50"C for at least

M - x - - - (20),-(29);--X shchi (55) nshe 14 days.

IN! 34. The composition according to item 20, where this composition is stable--(820),E3 when stored at 50"C for at least 28 days. 35. The composition according to item 20, where this the composition has a viscosity of less than approximately 1000 centipoise, at a weight of 02С and a shear rate of 45 s. The active component is selected in such a way that this (20.83) composition does not show crystallization of the specified pesticide when stored at a temperature of approximately 0"C for a period of about 7 days. 37. The composition according to item 20, where the indicated surface- or surface-active component is selected in such a way that this

And | where the composition does not show crystallization of the specified v-A-x- - (v2o020-(B-- -Ix (57)) pesticide when stored at a temperature of approximately -107C for a period of about 7 days. and V o--(820) ,83 38. The composition according to item 20, where the surface-active component is selected in such a way that this composition does not reveal crystallization of the specified pesticide

A T ve ve when stored at a temperature of approximately -207C

NANNYA for a period of about 7 days. needle I s" (58) 39. The composition according to item 20, where the crystallization point is not higher than approximately -207C. 40. The composition according to item 20, where this composition is essentially or homogeneous during storage at 507C during the first week of the week. In 41. The composition according to item 20, where the cloud point is at least approximately 602C.

IR (59) 42. Composition of an aqueous pesticide microemulsion concentrate containing:

a pesticide component consisting of water- where B! means a linear or branched alkyl or soluble pesticide dissolved in said aryl having from about 4 to about 16 carbon atoms in an aqueous medium, where the pesticide is glyphosate, or a salt or ether thereof, wherein this hydro- B2 means hydrogen, methyl, ethyl or -СНгСНГОхН, the active pesticide is present in a concentration that is ВЗ means hydrogen, methyl, ethyl or -"СНгСснНГОуН, biologically effective when diluting the composition where the sum of x and y equals no more than about 5; in the appropriate volume of water and applied to the leaves, B" means hydrogen or methyl; P? in each of the groups of a sensitive plant; (BO) n means independently C2-Ca alkylene; an organic solvent essentially immiscible with A means hydrocarbylene or substituted with a hydrocarbon having a solubility in water of less than about - active component containing what- A means acceptable in agriculture at least one cationic surface-active anionic substance and at least one non-ionic surface- 44. The composition according to items 42 or 43, where glyphosate is a surface-active substance and a stabilizer, moreover, it is used mainly in the form of a potassium salt, a monoammonium, surface-active component is present in conium, diammonium, sodium, monoethanolamine, n- concentration, which is sufficient to ensure acceptable propylamine, ethylamine, ethylenediamine, hexamethyl- thermal stability of the composition, so that this emulsion is amine or trimethylsulfonium. has a cloud point of at least about 45. The composition according to any one of 42-44, where glyphosate is 50"С and the crystallization point is not higher than approximately sat is mainly in the form of a potassium salt.

Os, 46. The composition according to item 45, wherein said glyphosate and said stabilizer contain one or more amine or quaternary ammonium salt compounds, approximately 310 to approximately 600 grams c.e. (acids, each of which contains an alkyl or aryl equivalent of the grounding agent) per liter of the composition. snyk having from about 4 to about 16 47. The composition according to item 42, where the total number of carbon atoms and not more than ten ethylene oxide surfactants is equal to the approximate bonds in this compound, and 20 to approximately 300 grams per liter of the composition are indicated. bows are present in an amount that increases the compatibility 48. The composition according to claim 47, where the specified surface-specified surface-active component with pe- active component is in a solution or a sticide, and a stable suspension, emulsion or dispersion. where the specified stabilizer is present in an amount, add- 49. The composition according to item 42, which additionally includes a stable to increase the compatibility of the indicated behavior- a water-soluble pesticide, selected from the group that has a chemically active component with the pesticide, and includes acifluorfen, acrolein, amitrol, asulam, owl ratio of cationic surfactant benazoline, bentazon, bialaphos, bromacil, bro- active substance and stabilizer is in moxynil, chloramben, chloroacetic acid, clopi- ranges from about 1.5 : 1 to about 6:1. ralide, 2,4-O0, 2,4-OB, dalapon, dicamba, dichlor- 43. The composition according to item 42, where the stabilizer is selected from prop, difenzoquat, diquat, endothal, fenac, the group including salts of amines or quaternary fenoxaprop, flamprop, flumiclorac, fluroglyammonium, having the formulas: caffeine, flupropanate, fomezafen, fosamine, 2 glufosinate, imazameth, imazametabenz, imazamox, in! shk 5 imazapic, imazapir, imazaquin, imazetapir, ioxynil,

M (5) MSRA, MSRV, mecoprop, methylarsenic acid, 3-naphthalam, nonanoic acid, paraquat, picloram, or hinclorac, sulfamic acid, 2,3,6-TVA, TCA, b2 triclopyr and their water-soluble salts.

A- 50. The composition according to item 42, where the indicated nonionic agent includes: в - - мк --рв3 (c) (a) Xylyl xx alcohol having the formula: ! (49) and where РЕ" means hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or in B2 in each of the groups (220)x means independently C2-Ca4 p alkylene, tOo--k( c20), 5 --M (7) VAZ means hydrogen or linear or branched

Urz an alkyl group having from 1 to about 4 atoms; of carbon, and or x equals an average number from 1 to about g bo; (B) dialkylated alcohols having the formula: v'o-c(v0),-85-m-. юЮ А (8) wolf 0- (Оу (50) where В! independently means hydrogen or a linear or branched alkyl group having from 1 to approximately 4 carbon atoms,

B2 in each of the groups (BE2O)"x and groups (E2O)y means non- B2 in each of the groups (E2O)" and groups (E2O)y means independently C2-Ca alkylene, depending on C2-Ca alkylene;

BZ is hydrocarbylene or substituted hydrocarbylene, BZ and 29 are each independently hydrocarbylene having from 2 to about 30 carbon atoms or substituted hydrocarbylene having from 1 to about 6 carbon atoms; x and y are independently equal to the mean number of B" means hydrogen, hydrocarbyl or substituted hydrocarbyl from 1 to about 60; rocarbyl having from 1 to about 30 atoms (c) alkoxylated dialkylphenols having for- carbon, hydroxy substituted hydrocarbyl, (P9 )n- mud: (B2O)UV", 0 -C(-MAL)MATVTZ, 0 -C(-0)MA2B, OS-

IR C(-5)MVA"2BZ, or together with P? and the nitrogen atom to which they are attached, form a cyclic or heterocyclic ring; (B) B? means hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to approximately 30 carbon atoms, hydroxy-substituted hydrocarbyl, (P)p- (ov2)dz (B2O)UV", 0 -С(-МАЛ)МАТВТЗ, 0 -С(-0)МА2В, ОС-х, С(-5 )MV":B", or together with B" and a nitrogen atom, to which B' and B" independently mean hydrogen or linear to which they are attached, form a cyclic or branched alkyl group having from 1 to a heterocyclic ring; about 30 carbon atoms, and at least one B' is hydrogen or linear or branched from BE Her 27 is an alkyl group, an alkyl group having from 1 to about 4 atoms

B2 in each of the (220)x groups independently means C2-Ca4 carbon; alkylene, B", B: and B!Z mean hydrogen, hydrocarbyl or

BZ means hydrogen or a linear or branched substituted hydrocarbyl alkyl group having from 1 to about 4 atoms B!" means hydrogen, hydrocarbyl or substituted carbon, and hydrocarbyl having from 1 to about 30 atoms x is an average number of from 1 to approximately carbon, hydroxy-substituted hydrocarbyl, (P)n- 60; or (b2O3uB", -C(-MA)ZMAT2BZ, -C(-0)MA2B!Z or - (4) a glycoside having the formula: c(-5 )MA B, n equals 0 or 1, sn.oН x and y are independently equal to an average number from 2 1 to about 60, and (c) A means acceptable in agriculture

He is an anion in (61);

N o r) hydroxylated amides having the formula: (c) on p; k- -mM--as-- rz (17) where n means the degree of polymerization or the number of glycosidic groups, and

E means a branched or straight chain alkyl group preferably having from 4 to 18 where B" means hydrocarbyl or substituted hydrocarbyl carbon atoms, or a mixture of alkyl groups having from about 4 to about 30 is the average value within the given range of carbons; well. | | B means hydrogen or hydrocarbyl or substituted 51. The composition according to item 42, wherein the cationic hydrocarbyl having from 1 to about 30 atoms is specified, the surfactant includes : carbon, and (a) an aminated alkylated alcohol, having BZ means hydroxyalkyl, polyhydroxyalkyl or po- formula: Y li(hydroxyalkyl)alkyl; in Kk c) diamines having the formula: vo--(vg0),-vz - M (9) - x M- 8-M-otk5 x | | iz) t v2 v or , vi de B", V? and E? independently means hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or -tOo-- (20). vZ- 1 m ee A (10) (Opov, | | What

VZ means hydrocarbylene or substituted hydrocarbylene having from 2 to about 18 carbon atoms. . that this is not represented by hydrogen because it is a bond or a substitute: VAZ and Z independently mean hydrocarbylene or carbon atoms. sh r substituted hydrocarbylene having from 2 to approximately 4 carbon atoms,

In the E!? independently means hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, (19) t is 0 or 1, t - (023 (k) 5 M-re p is an average number from 0 to about where B! and EZ independently mean hydrogen, hydrocarbyl, white or substituted hydrocarbyl having from 1 to

X means -C(0)- or -5052-, approximately 30 carbon atoms, 4) mono- or diammonium salts having the formula: B2 in each of the groups (220O)x means independently C2-C4 or alkylene;

B" means hydrocarbylene or substituted hydrocar- v - -627Й- М--863-м--р5 Й belene having from 1 to about 30 carbon atoms to (and this,

IN? means hydroxyalkyl, polyhydroxyalkyl or lower (hydroxyalkyl)alkyl; or x is an average number between 0 and approx

ZO,

A: iy in y is equal to 0 or 1; (9) dipoly(hydroxyalkyl)iamine, having the formula:

What did you eat? | (22) ; in c3 where B", B2, VU, Vo and B" independently mean hydrogen; or hydrocarbyl or substituted hydrocarbyl having where K' and EZ are independently hydrogen or hydro- from 1 to about 30 carbon atoms, or - carbyl or substituted hydrocarbyl having from 1 to

WHO OB, approximately 22 carbon atoms,

Ve means hydrocarbyl or substituted hydrocarbyl, B? means hydrocarbylene or substituted hydrocarbene having from 1 to about 30 carbon atoms, belene having from 2 to about 18 carbon atoms

BZ means hydrocarbylene or substituted hydrocarbyl, and bilene having from 2 to about 30 carbon atoms; B: and 2" independently mean hydroxyalkyl, polyhydric, hydroxyalkyl or poly(hydroxyalkyl)alkyl;

BZ and 29 mean individually hydrocarbylene or (n) salts of quaternary poly(hydroxyalkyl)amines, substituted hydrocarbylene having from 2 to approximately 4 carbon atoms, their

IN! means hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 atoms in- mi - B y. of carbon, (24) t is equal to 0 or 1, n is equal to the average number from 0 to about 40, ,

X means -C(O)- or -50O"-, where B" means hydrocarbyl or substituted hydrocaryo- means-F(O)U c| bil having from about 4 to about 30 atoms-

A means an agriculturally acceptable mv of carbon, or -Xy(B'OUV, anion; B2 and EZ independently mean hydrogen or hydrocar- (e) poly(hydroxyalkyl)amines having the formula: white or substituted hydrocarbyl having from 1 to / in approximately 30 carbon atoms, in! - M (16) B? means hydroxyalkyl, polyhydroxyalkyl or

M li(hydroxyalkyl)alkyl, мя X means acceptable in agriculture where B! means hydrocarbyl or substituted hydrocaranion; bil, having from about 4 to about 30 atoms - A" in each of the groups (H"O)u means independently C2-Ca of carbon, or -B'OB5, alkylene;

B2 is hydrogen or hydrocarbyl or substituted Y3 is hydrogen or linear or branched hydrocarbyl having from 1 to about 30 atoms alkyl group having from 1 to about 4 carbon atoms, carbon;

VAZ means hydroxyalkyl, polyhydroxyalkyl or po- X means hydrocarbylene or substituted hydrocarly(hydroxyalkyl)alkyl, belene having from 2 to about 18 carbon atoms

IN? means hydrocarbylene or substituted hydrocarty; belene, having from 2 to about 18 carbon atoms, and is equal to 0 or 1, and this and y is equal to the average number from 0 to about

WZ means hydrogen or hydrocarbyl or substituted 30; hydrocarbyl having from 1 to about 30 triamine atoms (I) having the formula: carbon; () alkylated poly(hydroxyalkyl)amines having the formula:

m r re de E", VZ, VU, V", VZ and EE? independently mean vo-

M M day, polyhydroxyalkyl, hydrocarbyl or substituted as M M in (27) hydrocarbyl having from 1 to about 30 atoms x | in carbon, or -(Б2О)ХВ", their B? means hydrocarbylene or substituted hydrocarbon and B! means hydrocarbyl or substituted hydrocarbon and having from 2 to about 30 carbon atoms having from 1 to about 30 atoms of carbon, in not in and in

B2, B3, Be, and 25 independently mean hydrogen, hydro- I spoons of utvo and groups (E5O)y means non-carbyl or substituted hydrocarbyl having from 1 to B' means hydrogen or linear or branched of about 30 carbon atoms, or " (AU(A'O)H", an alkyl group having from 1 to about 4 atoms

VAZ means hydrogen or linear or branched carbon' alkyl group having from 1 to about 4 atoms x is equal to the average number of from 1 to about carbon, 30 in' in each of the groups (B'O)n means independently C2-C4 and is equal to average number from about C to alkylene; y ' y . I am about 60, and

A means hydrocarbylene or substituted hydrocarpe means an agriculturally acceptable belene having from 1 to about 6 carbon atoms: this, y - and p equals the average number from 1 to about a purine or tertiary amine having the form 10 , And ? is equal to 0 or 1, and rai x and y are independently equal to a whole number from 1 to I) M, (31) approximately 4; vz (Y) diamines having the formula: ; - -M-- (vb0),- 82 -M--yuvz3 where E! and 2 are hydrocarbyl having from 1 to about 30 carbon atoms, and (28) BZ is hydrogen or hydrocarbyl having from 1 to about 30 carbon atoms; where B", BZ, B: and 25 independently represent hydrogen, (t) monoalkylated amines having the formula: hydrocarbyl or substituted hydrocarbyl having from ;B which" 1 to about 30 carbon atoms, or -(BO)XB" , in - M (32)

B2 means hydrocarbylene or substituted hydrocarbylene M having from 2 to about 30 carbon atoms, sema MmATA i -b(-o)mAeA, and where B"! and 27 independently mean hydrocarbyl or

Siv A, F(e-MA)- (8). or -FO)., substituted hydrocarbyl groups having from 1 to

AND? in each of the groups (КО)x and groups (ЕО)y means non- approximately 30 carbon atoms, or -855H2, depending on Со-Сдалкылен, Б? in each of the groups (Б2О)х means independently С2-Са

B' means hydrogen or a linear or branched alkylene alkyl group having from 1 to about 30 atoms - BZ means hydrogen or a linear or branched chain mv alkyl group having from 1 to about 4 atoms

A", B: and BZ are hydrogen, hydrocarbyl or carbon. ru, tsu do do pr substituted hydrocarbyl having from 1 to about BZ means a linear or branched alkyl group, carbon atoms, | having from about b to about 30 atoms x equals an average number of 1 to about carbon 50, and , , B means a hydrocarbyl or substituted hydrocar- y equals an average number of 0 to about a group having from 4 to about 15 carbon atoms 60; : , I and carbon, and ( K) mono- or diquaternary ammonium salts, where x is equal to the average number from 1 to approximately having the formula: в: х- ве о х- (n) dialkylated quaternary ammonium salts having the formula: 2 З в -М- (в80) ,-82 -M-yu23 (29) (vom h- ve ro k- ih - - (Ou (33) or

And xx ve

IN! M (ve0)/-- v2 M vz (30) where v! means hydrocarbyl or substituted hydrocarbyl having from 1 to approximately 30 carbon atoms, 5 B2 in each of the groups (E2O)" and groups (E2O)u means non- and P depending on Co2-Ca alkylene,

And VAZ means hydrogen or a linear or branched alkyl group having from 1 to 4 carbon atoms,

B" means hydrogen or hydrocarbyl or substituted kg hydrocarbyl having from 1 to about 30 | xx carbon atoms, and , x and y are independently equal to the average number from Кк - 5 m 5 ж « ВЗ 1 to about 40, and

X means an anion acceptable in agriculture; z , (35) (0) salts of monoalkylated quaternary wherein B, B3 and B: independently represent hydrogen or ammonium having the formula: hydrocarbyl or substituted hydrocarbyl having from about 1 to about 30 carbon atoms, x B2 means hydrocarbyl or substituted hydrocarbyl, in -- her (Bg0),83 having from 1 to approximately 30 carbon atoms, and x X means an anion acceptable in agriculture; 4 (4) etheramines having the formula: and , (34) in where B! and 5 independently mean hydrogen or hydro? y carbyl or substituted hydrocarbyl having from 1 to y: - approximately 30 carbon atoms, to (36)

B" means hydrocarbyl or substituted hydrocarbyl, . but also having from 1 to about 30 carbon atoms And where B means hydrocarbyl or substituted hydrocarbyl 2, bil having from 1 to about 30 carbon atoms,

Not to each of the groups (A"O)x means independently Co-Ca B2 means hydrocarbylene or substituted hydrocar-

Z y y belene, having from 2 to approximately 30 carbon atoms

AZ means hydrogen or linear or branched chain; an alkyl group having from 1 to about 30 atoms and "B" independently means hydrogen, a hydrocarbyl of one carbon, or a substituted hydrocarbyl having from 1 to approximately equal to the average number of from 1 to about 30 carbon atoms, or -(B5О)ХВе, 60, ! - - .. В? in each of the groups (ЕРО)х means independently С2-Са4

X means alkylene amine acceptable in agriculture, and quaternary ammonium having the form - ВZ means hydrogen or linear or branched

B, p" is an alkyl group having from 1 to about 4 atoms

Y: carbon, and x is an average number from 1 to about 50; () diamines having the formula: n -o9.--(83,--М---(вв0))---в-М-- with (37) in vo where B, BZ, B? and BZ are independently hydrogen, o- hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or -(ВО)ХВ"7; -m-- dz

B2 and 8 are independently hydrocarbylene or (38) substituted hydrocarbylene having from 2 to approximately 30 carbon atoms, b2

ВАЭ in each of the groups (БЕ5О)»x and groups (Е9О)y means non- , depending on Co-Ca KAN )x and groups ( where y- No 3 independently means hydrogen, hydro-

B is hydrogen or linear or branched plaso substituted hydrocaroyl having an alkyl group having from 1 to about 30 carbon atoms, -(B'C)XA? or - had a carbon, 4 ШЙ 4 х is equal to the average number from 1 to approximately 4 of the groups (КО)х means independently C2-C4

Zo'; in . . -

X means -O-, -M(B2)-, -С(0)-, -С(ФО-, -ОС(О)-, - в means hydrogen or pdrokaro or substituted

М(89)С(О)-, -Ф(ОМ(В8З)-, -5-, -30- or -50", hydrocarrol having from 7 to about y atoms equal to 0 or an average number from 1 to approx. - vo ona, , , and lyzno 30, and" means hydrocarbylene or substituted hydrocarp and 2 are independently equal to 0 or 1, and belene having from 1 to approximately 6 carbon atoms

IN? means hydrogen or hydrocarbyl or substituted Ci, , hydrocarbyl; x is equal to the average number from 1 to approximately : and . 50, and 5) amine oxides having the formula: "I I I 8) pi, n formula, the total number of carbon atoms in B", B? and EZ equals at least 8;

(9 Alkoxylated amine oxides having the form- B: means a linear or branched alkyl group, lU: having from about 4 to about 15 carbon atoms, and / x, y and 7 are independently equal to the average number o--(220), - v3---0.- (39) from 1 to approximately 40;

M (m) aminated alkylated alcohols having the following chemical structure: where B! means hydrogen, hydrocarbyl, or substituted Y D hydrocarbyl having from 1 to about 30 atoms in carbon; vv

B2 in each of the (BE2O)" and (E2O)y groups means non-in, depending on Ce-Ca alkylene; | what where E!, B", VZ and EZ mean, each independently,

BZ means hydrocarbylene or substituted hydrocarbyl, hydrocarbyl or substituted hydrocarbyl, which is bilene having from about 2 to about 1 to about 30 carbon atoms, or - carbon atoms; P" and E" mean each independently (B'Z(VZOCHVO; respectively, hydrogen, hydrocarbyl or substituted hydrocarb- X means -0-, -OC(0)-, -C(FOO-, -M(B') С(О)-, - protein having from 1 to approximately 30 carbon atoms, с(оММ(Б2)-, -5-, -50-, -80»- or -М(Б3)-; -«( 85)-(А?ОуВ; VZ in each of the groups (ZO) and groups (30) means non-

AND? means hydrocarbylene or substituted hydrocarbyl, depending on Co-Ca alkylene; belene, having from 1 to about b carbon atoms, BE means hydrogen or a linear or branched chain alkyl group, having from 1 to about 30 atoms

B" means hydrogen or a linear or branched carbon chain; an alkyl group having from 1 to about 4 atoms; n is an average number of 1 to about carbons, 60; n is 0 or 1, and m is an average number of 1 to about x and y are independently equal to an average number of 50; 1 to about В and В" mean, each independently, hydrocarby- (y) dialkylated amines having the formula: lene or substituted hydrocarbylene having from 1 to (Ego) about 6 atoms carbon; ra V? means hydrocarbylene or substituted hydrocarbyl/-M (40) belene having from 2 to about 6 carbon atoms, (ho) B!2 means hydrogen or hydrocarbyl or substituted where B! means hydrogen or hydrocarbyl or a substituent having from 1 to about 30 atoms of a pdrocarol, in which V y ol olizno Zo t and 5 are each independently equal to 0 or 1; to in each branch p (B2O)x, r (i rn and groups (B2O) B means hydrocarbylene or substituted hydrocarru)" ru in tro 7 belene having from 2 to about 30 carbon atoms means independently С2-Са alkylene, this, -С(-МВ"2)-, -С(8)- or -С(0)- 3 ' Per 1 t of z z alkyl o has FROM to approximately 2U atoms. 9 is equal to the whole number from O to 5. in the group, sh to do pr VZ means hydrogen or hydrocarbyl or substituted

MW of carbon, and hydrocarbyl having from 1 to about 30 atoms

A" means a linear or branched alkyl group, carbon; having from about b to about 30 atoms (m) of a quaternary ammonium, sulfonium or carbon, sulfoxonium salt having the following chemical structure:

Y e7 A v- XX --Y 2855 (2830) 8--(3Me)Y-- Y - (43) veZ or

A- and Y Y A: v/- t (0) V-- (M rt (44) v or

A and Y Y d- vA- -- 5 - -s( 823.2 (80) -----(Mv8),-M-shaE'8 (45) and" or

Y Y VA v- 65--- pad vok (Ku T-vo (46) . where В, В", ВВ, ВУ, ВО Her В! mean independently VZ means hydrocarbylene or substituted hydrocarbyl, hydrocarbyl or substituted hydrocarbyl, that bilene having from about 2 to about 6 has from 1 to about 30 carbon atoms, or - carbon atoms, or -(82O)pAg-, (813)5(AZO)MV2; t and n are equal, each independently, on average

X means -O-, -OC(O)-, -Ш(АС(0)-, -С(О)М(В1У)-, - a number from 0 to about 50, and

C(OYU- or -5-; p is equal to the average number from 0 to approx

VZ in each of the groups (ZO) and groups (ZO) means heaven; depending on C2-Ca alkylene; or

IN! means hydrogen or a linear or branched (y) compound of the formula: an alkyl group having from 1 to about 30 carbon atoms; ko n equals the average number from 1 to approximately 60; t-x ve (52) m is equal to the average number from 1 to approximately 50; oO- - (20), Z

B2 and B3 are each independently hydrocarbylene or substituted hydrocarbylene having from 1 to about 6 carbon atoms; Since v5, t and 5 are equal, each independently, to 0 or 1; A: H

B" means hydrocarbylene or substituted hydrocarbene (53) belene having from 2 to approximately 6 carbon atoms; / o-- 2 (o,

AND? means hydrocarbylene or substituted hydrocarbylene having from 2 to about 30 carbon atoms, -C(-MA!2)-, -C(8)- or -C(0)-; or

B" means hydrogen or hydrocarbyl or hydrocarbyl substituted in b5 having from 1 to about 30 carbon atoms; | 1-X- (ra (54) 9 is equal to a whole number from 0 to 5;

BZ means hydrogen or hydrocarbyl or substituted and: 2 with hydrocarbyl having from 1 to about 30 carbon atoms; and or each A" means an agriculturally acceptable anion; B (X) is a diamine salt or diammonium having the formula: - хх « (еОоо),-(К), ех (55) к-- (8220). 5 5-5 М--в3--М-(820),.--8y В (47) o-- ("oo ,

Re Re or re or wa v! х A ve vo ky | | iya 1 i chi GU 4 - -M-- 2 in ves et (r) (48) and Y (Od (56) oO- -(520),23 ve vo to (to), where B, VU, B" , Bc, B" and 28 are independently C- or "diene or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms,

B2 in each of the groups (22O)t and groups (220) and Z independently mean C2-Ca alkylene,

dvo Y is equal to 0 or 1; then A means acceptable in agriculture k-zh (o). Jester - Their (57) anion; and

Her B y and 7 are independently equal to a whole number from 0 to o (BO) approximately 30. or 52. The composition according to item 42, where the composition is optical

AV where transparent. in 53. The composition according to item 42, where this composition is stable when stored at 50"C for at least (58) 14 days. "(02 54. The composition according to item 42, where this composition is stable or "stable" when stored at 50"C for at least 28 days.

А- е : : ' в5 55. The composition according to item 45, where this composition has a density of less than approximately 1000 centipoise, if not (59) 02С and a shear rate of 45 s. in vo o- (VO) 56. The composition according to item 42, where the surface

She | the active component is selected in such a way that this is where P", AR and B"? mean independently hydrocarbyl, the composition does not show crystallization of the indicated or substituted hydrocarbyl, having from 1 to approximately 30 carbon atoms, or -(А?О)рА" or -(А?О)рА" in 02C for a period of about 7 days.

AND? in each of the groups (К?О)t, groups (КО), groups (Ор 57. The composition according to item 42, where the indicated surface group (КО)4 means independently Со-Са alkylene; the active component is selected as such in such a way that this

A", AB, A", BZ and BZ independently mean hydrogen, the composition does not show crystallization of the specified or hydrocarbyl or substituted hydrocarbyl, which has a pesticide when stored at a temperature of about 1 to about 30 carbon atoms; temperature -102C for a period of about 7 days .

B: means -"(CHg)UOV Z or -""CHgUO(B2O0)483; 58. The composition according to item 42, where surface-active

Ah, No | KE" mean independently hydrogen, the hydrocarbyl component is selected so that this composable or substituted hydrocarbyl having from 1 to tion does not detect the crystallization of the indicated pesticide approximately 30 carbon atoms, or P"; when stored at a temperature of approximately -20"C

IN? means hydrocarbylene or substituted hydrocar- for a period of about 7 days. belene having from 2 to approximately 30 carbon atoms 59. The composition according to item 42, where the crystallization point is not this; higher than about -202С.

A" means hydrogen, hydrocarbyl, or substituted 60. The composition of claim 42, wherein the composition is essentially a hydrocarbyl having from 1 to about 30 atoms homogeneous when stored at 507C for one-carbon, or -(CHg);:O 61. The composition of claim 42, wherein the cloud point of the doryl is from 1 to about 50, and is at least about 602C.

X means independently -О-, -М(Б17)-, -С(О)-, -С(0)О-, -оС(0)-, -М(Б'У)С(0)-, - "С(О)М(Б5)-, -8-, -80- or - 5О"-;

This invention relates to stable pesticide emulsions and other liquid concentrates of water-soluble pesticides, such as phosphonomethylglycine (glyphosate). The herbicide compounds of this invention contain glyphosate or its and is relatively insoluble in water (1.1695 per vasyl or a complex ester such as potassium glyphosate and goyu at 25"C). For this reason, it is usually prepared - a system of surface-active substances, which includes in the form of a water-soluble salt. It contains a cationic surface-active substance. Monobasic, dibasic, and optionally nonionic surfactant and tribasic salts of glyphosate can be prepared. However, usually active substance. In this invention, the preparation of glyphosate is preferred, and optically transparent compositions of glyphosate are also used, which apply glyphosate to plants in monobasic form containing cationic and nonionic surface salts. The salt of glyphosate, which is the most widely active substance, has the cloud point which is listed is the mono(isopropylammonium) salt, often at least around 502C and the crystallization point is not abbreviated as IRA. Commercial herbicides above about -202C. Compan Monsanto products containing the IRA-salt of glyphosate

Glyphosate is well known in this area as an active ingredient, including herbicides - an effective post-emergence herbicide. In its Koipaimre, Koppapre OPga, KoppairF Oggamach acids, the tny form of glyphosate has a structure represented by KoshipashrF), Higa and Kodeof) All these herbicides are goto-formula (1): vy forms of an aqueous solution concentrate (51) and are usually diluted with water before applying it with a commercially available concentration to plant leaves by the user. Another salt of glyphosate—IRA—a salt of glyphosate, as in the aqueous solution concentrate, which was prepared in the form of 5I-compositions of the rank, available from the Monsanto Company, under the tova- for supply, includes a salt called O-Rak. Slightly higher concentrations (trimethylsulfonium), often abbreviated, can be obtained with a small amount, such as the TM5 salt, which is used, for example, by "reneutralization", for example, 5-1095, of water, in the herbicide Toispdompe bupdepia. Various salts of a solution of the potassium salt of glyphosate with potassium hydroxide. glyphosate, methods of preparation of glyphosate salts, The main advantage of IRA-salt over many ready-made forms of glyphosate or their salts and methods with other glyphosate salts was its compatibility in the ready application of glyphosate or its salts for pressure forms (compositions) of the concentrate of water drilling yans and other plants and weed control solution with a wide range of surface and other plants are described in (US patent active substances. In this context, the term "on-

Mo4507250 (Wake!), US patent Me4481026 surfactant" includes a large (Rgisruia), US patent Me4405531 (Rhap), patent range of adjuvants that can be added to

USA Me 4315765 (I agde), US patent Me 4140513 of herbicidal compositions of glyphosate for enhancement (Rhii), US patent Me 3977860 (Rhap:), patent of their herbicidal efficiency, in comparison with active

US Me3853530 (Rhap), US patent Me3799758 with glyphosate salt in the absence of such an adjuvant, (REhap2)). The above patents are incorporated herein by reference to their stability, ease of preparation, or other apparent extent. basic properties of solutions, regardless of whether

Among the water-soluble salts of glyphosate, whether or not such an adjuvant satisfies the more traditional moss in the literature, about the commercial use of the name "surfactant". which, however, it is not known where the potassium salt is, Glyphosate salts usually require the presence of the appropriate surfactant for , CA rach o c) the best herbicide form. This superficial

Kk Vi. in the active substance can be provided in a ready-made background HER | rmi concentrate or it can be added at the end o ? by the user to the diluted composition for use, preferably present in this ionic form in the spray. The choice of surface-active substance in a solution at a pH of about 4. This salt has been described as being of primary importance for herbicidal effectiveness, for example, Egap in (US patent Me44055311, cysts. For example, in the intensive research mentioned above, as one of salts of "alkali metals" in (M/eea Zsiepse, 1977, myoshte 25, glyphosate, applicable as herbicides, and Karadez 275-287, MMUup and Vygpzide | revealed a large tallow described specifically as one of such alkaline variability among surface active rheo-metals, together with lithium, sodium, cesium and rubidium, due to their ability to enhance the herbicidal effect

Example C describes the preparation of the monopotassium salt of glyphosate, which is used in the form of IRA - by the reaction of the specified amounts of the acid form of the salt. of glyphosate and potassium carbonate in the aquatic environment. carrying capacity of various surface-active substances

A very small number of herbicides are available to increase the herbicidal effectiveness of glyphosate in the form of their potassium salts. In (Reziiside) it is highly unpredictable.

Mapiai, 1117 Eaiiop, 19971, the list contains cali- Surface-active substances having ten-

Eve salts of herbicides of the auxin type 2,4-08 ((2,4- dence give the most useful enhancement of herbi- dichlorophenoxy)butyric acid), dicamba (3,6- of glyphosate effectiveness, of course, but not dichloro-2-methoxybenzoic acid ), dichloro exclusively, cationogenic surfactants of prop(2-(2,4-dichlorophenoxy)propanoic acid, substances, including surfactants

MCPA ((4-chloro-2-methylphenoxy)acetic acid) and substances that form cations in aqueous solutions of picloram (4-amino-3,5,6-trichloro-2-forms or dispersions at pH levels of about 4-5 , pyridinecarboxylic acid), an active ingredient characteristic of 5I--compositions of monobasic juices of some herbicide products sold with glyphosate. Examples are long-chain (twist-

VbVom'EIapso under the trade name Tordon. tea Si1i2-Siv surface-active substances that are

The solubility of the potassium salt of glyphosate in water with tertiary alkylamines, and surfactants (the application under consideration, with the registration substance, which is a quaternary alkylammonium. Personal number 09/444766, submitted on November 22, 1999, is an often applicable surfactant of the year |, the full description of which is included here as a link- a substance that is a tertiary alkylamine, which is As described in it, the potassium salt of glyphosate has a solubility in pure water at 207C of about 5495 for solutions of IRA-salt of glyphosate , was very hydrophilic, i.e., about 4495 acid equivalents of polyoxyethylene glyrosate surfactant by weight. -salts. Concentrations expressed in the appearance of about 15 moles of ethylene oxide in two polymedy percent by weight (wt. 9o) refer here to rised ethylene oxide chains, attached parts by weight of salt or acidic equivalent to the amine group as shown in formula (3): (ke) per 100 parts by weight of the solution. Thus, the concentrate of a simple aqueous solution of the potassium salt of glyphosate can be easily obtained in a concentration of, for example, 4490 k.e. by weight, compared

(SNeSno nn of alkylpyramine, alkylpyramonium and oxides of alkyl- and lepyramines is suitable for the preparation of com- in 8) positions of concentrates of aqueous solutions of various salts of glyphosate, and potassium salt is included in this list of salts. Here it is described that the advantage of surface- where K is a mixture of mainly C"v- and Cv-alkyl v-active substances under consideration, with alkenyl chains originating from solid application in an aqueous composition with salts of glyphosate fat, I! in general, the sum of tp is equal to the average tu consists in the fact that these surface-active substances number about 15. wines allow to increase the concentration of gly-

It was found that for some applications the phosate of this composition to very high levels. it is preferable to use slightly less hydrophilic anionic surfactants than alkylamine-containing surfactants, except for their use in combination with cationic surfactants, such as less than about 10 moles of ethylene oxide, such as described in (US patent Me5389598 and the US patent proposed in (US patent Me5668085 (Hogres et al. Me5703015|) are of course not of great interest), for example, polyoxyethylene(2)-cocoamine. This su in 3-compositions of IRA-salt of glyphosate. (The patent describes an illustrative aqueous composition that '015| describes a mixture of surface-active substances containing such a surface-active substance together with a dialkylated alkylamine and anionic salts of IRA, ammonium or potassium glyphosate. Most notably, which reduces eye irritation. This the mixture with each concentration of glyphosate in compositions of potassium surfactants is described as a suitable salt, shown in table C of the patent "085, is available for use formation of compositions of concentrates of water

Goodbye k.e. of glyphosate per liter with the weight ratio of solutions of different salts of glyphosate, and in k.e. of glyphosate to the surface-active substance, the list of mentioned salts includes the potassium salt. 21. Concentrates of patent "015 contain from approx.

The class of alkoxylated alkylamines is described in Table 5 to about 5095, preferably from about

YMMO 00/59302| for use in herbicides 3595 to approximately 4595 k.e. glyphosate and from approx. spray compositions. Various 5 to approximately 2,595 potassium glyphosate surfactants are described herein, including various EO/RO compounds. Further, (PCT publication MeuMO 00/08927 propylamine or -propyldiamine Ueyatippe "m) describes the use of certain polyaluxylated

A wide variety of surface-active phosphate esters in combination with certain quaternary ammonium type polyal-substances have been described by coxylated amidoamines in compositions that contain glyphosate as components of aqueous concentrate compositions. As one of several glypho salts, IRA-salt solutions of glyphosate. Illustrative additives marked as "applicable", the indicated salt is M-methylpolyoxyethylene(2)-lithium. cocoammonium chloride, described in (European Patent Me0274369|, M-methylpolyoxyethylene(15)- nonionic surfactants are usually reported to be less compatible with cocoaammonium chloride, described in (US patent) glyphosate, than cationic and amphoteric surfactants

Me53170031I, and various quaternary ammonium compounds, non-active substances when they are used as a unit having the formula (4): a component of surface-active substances 51I- (а'ХАХАЗ)M-СНеСНГО- (4), glyphosate compositions; the exception, apparently, is --cCHgSnH(CH3)O)aNeI- some alkylpolyglucosides, described, for example, in where P", B? and Z, each, are C-with alkyl I (Australian patent Meb27503). Others are non-ionic groups , and n is an average number from 2 to 20, descriptive surfactants that were described in (US patent No. 5,464,807) as applicable with glyphosate include

IRST publication MeuMO 97/16969| describes the composition of polyoxyethylene-(10-100)-Stiv-22 alkyl ethers, the positions of concentrates of aqueous solutions of glyphosate are described in (PCT publication MeumMo 98/17109). Other nonionic forms of IRA, methylammonium, and diammonium salts, which are mixed with surface-active substances, are usually mixed with a surfactant, which is a quaternary cationic surface-active substance, ammonium, and an acid-addition salt first, with the formation of a compatible systems of surface, secondary or tertiary alkylamine compounds. active substances for use in liquid herbicides

Other cationic surfactants, acid concentrates. However, the cationic systems that have been indicated as applicable in the compositions of horse/nonionic surface-active substances concentrates of aqueous solutions of glyphosate salts, including those that contain surface-active substances, do not provide acceptable stability when stored at low temperatures . Horses in IRST publication MeUMO 95/33379|). In |PCT concentrates containing these systems surface publication MeUMO 97/32476| it is additionally described that active substances can crystallize at highly concentrated aqueous compositions of gly- at temperatures of 0"C or lower temperatures; phosate can be prepared with some of those, limiting the use of such concentrates, the same cationogenic surface-active re- in cold conditions glyphosate concentrates containing non-ionic and which increases the stability of these compositions. alkyl ethers and cationic amine surfactants

Glyphosate salts, which are given as examples in substances, are described in (US patent Mob245713). this publication, there are IRA-salts and mono- and diammonium salts. It is claimed that this mixture of surface-active

In US patent Me5750468 it was described that substances increase the effectiveness of glyphosate and the absence of surfactants, which are salts, increases resistance to rain. The corresponding glyphosate

phosates for use in these concentrates by the Gardner meter. When the dye is added to include sodium, potassium, ammonium salts, di-concentrate of glyphosate, which has a saturation of col-methylammonium, IRA, monoethanolammonium and TM5 glir 18 according to Gardner, this concentrate remains phosate. This patent is included here in its complete dark brown in color. Concentrates with volumes as references. have a color saturation of 10 according to Gardner, weight

Apparently, a serious consideration of potassium salt glyco-coloring in a wide variety of colors, phosate as a herbicidally active ingredient gal- for example, in blue, green, red, or due to the relative complexity of the preparation- yellow color, which is often desirable to distinguish this salt in in the form of a highly concentrated product of glyphosate from other herbicide 5I products together with the predominant types of surface products. non-active substances. For example, it is widely used. above, the applicable surfactant content is somewhat incompatible in aqueous solution with the potassium or "fully loaded" surfactant salt of glyphosate. In addition, (PCT publication with an active substance. These compositions reveal

MeUMO 00/15037| notes the low compatibility of surface-reduced viscosity, so that they can be injected with standard equipment for injecting alkylamine in general with glyphosate concentrates of large volumes at 0"С at speeds of the highest strength (concentrations of ).As described in this less than 7.5 gallons per minute, usually more than 10

RStT publications to include (embed) gallons per minute and preferably more than 12.5 halo-effective surfactant levels per minute. "Agricultural use of alkylglycoside surface-applicable surface-active substance in a combination of surface-active substances" is the content of one or more surfactants of the type of alkylated alkyl-active substances of this type or of these types and in the lamina for obtaining highly concentrated such the amount that the user of this composition of high-strength compounds (concentrations) containing rust benefit in herbicidal efficiency in the potassium salt of glyphosate. nannies with a composition that is otherwise similar, but which is not

Addition of such alkylglycosides resulted in containing surfactant. The term higher viscosity compositions (compared to "fully loaded" means that the composition is compositions without alkylglycosides). This increases the sufficient concentration of the appropriate surface viscosity of these high-strength compositions of non-active substance to provide, when desired due to various reasons. In addition to the fact that their tea dilution in water and application to the leaves is more difficult to pour out of the container or wash off their herbicidal effectiveness on one or more residues from the container, adverse effects on important weed species were observed without the need for additional effects, which are manifested by the compositions of more addition of an additional amount of surfactant juice viscosity, which is more dramatic, relative to the diluted composition. requirements for delivery using pumps. "Stable during storage", in the context of com-

Volumes of liquid aqueous glyphosate products that positions of aqueous glyphosate salt concentrate, which are increasing, are purchased by users in contains additional surfactant, large refillable containers, are called lack of phase separation phenomenon at sometimes called "shuttles", which usually have effects of temperatures up to about 507"C and preferably a built-in pump or fitting for external na- no formation of glyphosate crystals or its sauce, for liquid transfer. Liquid aqueous glyphosate salts under the influence of a temperature of about 0"C during the products are also transported in a large obsya- period of time about 7 days (that is, the composition is in large cisterns (tanks), which must have a crystallization point of 0"C or more, up to 100,000 liters. This liquid is usually portable). For concentrates of aqueous solutions, the stability is in pumped tank for storage in high-temperature storage is often indicated - equipment managed by a wholesaler, retailer It has a cloud point of about 507C or a bi-trader or cooperator from which it can lower. The clouding point of the composition is usually found later in a shuttle (which is often prescribed by heating this composition until it is full) or smaller containers for distance - the solution does not become cloudy, and by providing this composition, what is the sale of the product. Since large quantities of glyphosate can be cooled, mixed, non-existent forms of glyphosate are purchased and its temperature is intermittently monitored. Tempera- are transported in early spring, the characteristics of the tour recorded when the solution becomes proso- of low-temperature injection of such ready-made rims is the value of the cloud point. Point forms are extremely important. turbidity of 50"C or more is usually considered

When adding such alkylglycosides (for example, suitable for most commercial products, Adgita! | tm APO-2067 and 2- for 5I-composition of glyphosate. Ideally, point po- ethylhexylglucoside) to the glyphosate concentrate, this turbidity should be 60"C or more, and this com- concentrate is dark brown in color. Ba- position must withstand such low tempera- so that the glyphosate concentrate is lighter ture, as about -10"C, preferably as low as in color than concentrates that contain alkylgly- about -20"С, for up to about 7 days kozid, described in (MO 00/15037I), which have a saturated- without crystal growth, even in the presence of color saturation of about 10-18, measured by the color of grass salt crystals glyphosate

The surface-active substance described in the invention can be marked as "compatible" with the glyphosate salt at the indicated composition of the liquid concentrate, applicable in the concentrations of the surface-active substance and k.e. agriculture, and the water-soluble glyphosate is a surfactant that herbicide can be prepared with a system will provide a storage-stable aqueous concentration of surfactants to withstand such rat defined immediately above, containing low temperatures as approx. -10"C, this surfactant and salt prevail in the specified but as low as approximately -20"C, during which concentrations. at least about 7 days without phase separation and

Users of liquid herbicide products without growth of crystals, even in the presence pre-measure the dose by volume, not by weight, and herbal crystals of this herbicide; provided- such products usually contain instructions for subjecting such a composition that is stable under storage to the corresponding application norms expressed at about 507"C for at least 14 in volume per unit area, for example, in liters per day, preferably at approximately 60"C or more per hectare (l/ha) or fluid ounces per acre (oz/acre). for at least 28 days; provision of such

Thus, the concentration of the herbicidal active composition, which makes possible a higher ingredient, which is important for the user, the load of herbicidal actives is indicated not in percent by weight (wt.), but in gradients and the total surface weight load per unit volume it has, for example, grams per liter of active substances; and providing such a steady- (g/L) or pounds per gallon (lb/gal). In the case of koya, when storing a composition that has a wide range of glyphosate salts, the concentration is often expressed in the spectrum of weed control, which is relatively light. per liter (g c.e./l). which is in use.

Historically, IRA-salt products of glyphosate, which are mis were most often prepared at a concentration of glyphosate, a pesticide dissolved in an aqueous medium, at approximately 360 g c.e./l. The product TM5-salt of glyphosate is essentially an organic solvent that is immiscible with

Toispdom/upo 2epesa, which contains surface water and a surface-active component. Water-reactive substances, prepared at a concentration of glycine pesticide present in a concentration that is phosate approximately 30g c.e./l. Products with a more biologically effective when diluting this com- low concentration of the acid equivalent, position in the appropriate volume of water and applied to that is more diluted, are also sold on the leaves of sensitive (to the action of the pesticide) plant. Surface markets, but bear the cost of the single-active component contains one or more glyphosate, which they contain, which primarily surface-active substances present in the con- reflect the cost of packaging, transportation centration, sufficient to ensure acceptable and storage in warehouses. heat resistance (temperature resistance) of this micro-

Additional benefits are in cost savings and in the emulsion, so that this microemulsion has a user-friendly pour point of at least about 507C and a crack point if the "fully loaded" dewatering composition is no higher than about - 107C. This concentrate, or at least the composition, the concentrate composition is optically transparent. which has an agriculturally applicable content. This invention also relates to the composition of surface-active substances, can be provided with an emulsion of a liquid herbicide concentrate, which has at least a continuous aqueous phase and an intermittent (discrete approximately 320 g c.e./l, 340 g c.e./l or significantly more) oil phase. This composition contains glyphosate less than 36b0g c.e./l, for example, at least approximately - preferably in the form of its potassium salt, monoammonium, lisno 420g c.e./l or more, or at least diammonium, sodium, monoethanolamine, n-propylamine . or trimethylsulfonium, an oil phase containing

At very high concentrations of k.e. glyphosate is an organic solvent that is essentially immiscible, such as the indicated concentrations, usually with water, and a surface-active component. place is a significant problem. This problem is a complex Glyphosate is in solution in the aqueous phase in the pouring and/or pumping of this aqueous concentration, which is biologically effective at the concentrate, which arises due to the high viscosity of the dilution of this composition in the corresponding volume of the concentrate, in particular, which is detected at low water with the formation of a reinforced mixture for the applied temperatures. Therefore, it would be very desirable to apply it to the leaves of a sensitive plant. The surface is a highly concentrated aqueous solution of potassium non-active component is in a solution of glyphosate salt, fully loaded with rural or in a stable suspension, emulsion or dispersion in the economically applicable surface-active this aqueous phase and contains one or more surfactants, and such the composition is mainly non-active substances present in a concentration less viscous than the composition of the potassium salt of glyphosate, sufficient to ensure an acceptable thermostat, containing alkylglycoside surfactants of this emulsion, so that this emulsion has exactly substances, such as those described in (PCT publication. MeUMO to a cloud point of at least about 50"C and a 00/150371. crystallization point not higher than about -1070.

As will be clear from the following description, these and Another embodiment of the present invention relates to other advantages provided by the present invention. to the composition of an aqueous pesticide microemulsion

Thus, among several features of this concentrate containing a water-soluble pesticide,

dissolved in an aqueous medium, organic when applied to the leaves of a sensitive plant. A surfactant is a solvent that is essentially immiscible with water, and the active component contains at least one surface-active component. A water-soluble cationic surfactant and that pesticide is present in a concentration that is biologically effective at least one nonionic surfactant when diluting this composition into a substance and is present in a concentration sufficient for an appropriate volume of water and application to the leaves of sensitive ensuring acceptable thermal stability of this plant. The surfactant component of the composition so that the composition has a cloud point of at least one cationic surfactant of at least approximately 50°C and a crystallisation point of no higher than approximately 0°C. surface-active substance and is present in the concen- It is known that liquid pesticide concentrates, concentration sufficient to ensure an acceptable rema, concentrates that contain potassium-glyphosate in the thermal stability of this emulsion, so that this emul- combinations with surface-active substances, sion has a cloud point at least approximately difficult to stabilize against phase separation at sub-50"C and a crystallization point no higher than approximately - higher temperatures and crystallization at low 1076. temperatures. It was found that the compatibility of cations

Another variant of this invention relates to an onogenic surfactant or an emulsion composition of a liquid herbicide concentrate, a mixture of cationic and nonionic surfactants, which has a continuous aqueous phase and intermittently active substances with a water-soluble herbicide in a frequent (discrete) oil phase. This emulsion contains a liquid herbicide concentrate can be known as a water-soluble herbicide dissolved in water. water, and return. These compounds are called here "stabilizer - chemically active component." we". Concentrates containing such surface

The water-soluble pesticide is present in a concen- active substances in combination with a radio stabilizer, which is biologically effective when dilut- also reveal optical transparency and increased no of this composition in the appropriate volume of water and nano- thermostability and provide improved concentration on the leaves of a sensitive plant . Surface control (suppression) of weeds when diluted and the active component contains at least one applied to the leaves. Compounds of salts of an amine or a cationic surface-active substance, and this of ammonium, containing a sol or an aryl surfactant component is present in the terminal substituent, which has from about 4 to a concentration sufficient to provide acceptable lyzno 22 carbon atoms, and no more than ten thermal stability of this emulsion, so that this emul- ethylene oxide bonds in this compound is effective has a cloud point of at least approximately them in increasing the compatibility of such surface active substances, even in concentrates containing at least 400 g of glyphosate per liter, and that

Another variant of the present invention refers to having a weight ratio of glyphosate:surface water to the composition of an aqueous herbicide concentrate, the active substance between approximately 1:1 and 20:11. Specifically, it contains a water-soluble herbicide dissolved in water, the compatibility increases for the surface water environment, and a surface-active component of active substances that are otherwise non-composite. A water-soluble herbicide is present in horses with a water-soluble herbicide. For example, concentration, which is biologically effective when diluting potassium glirosate concentrates containing 5% of this composition in the appropriate volume of water and 15% by weight of cationic surface-active agents, is applied to the leaves of a sensitive plant. Surfactants or mixtures of these cationic surfactants, the component contains at least one active substance and nonionic surfactant, a cationic surfactant and one active substance, are stable during storage or several compounds of amine salts or quaternary when this stabilizer is added. ammonium, each of which contains an alkyl or aryl substituent, having from approximately 4 to 16 carbon atoms and no more than ten herbicide concentrates containing cationic and ethylene oxide bonds in this compound. These co-nonionic surfactants may be present in an amount that increases the compatibility to be significantly improved by the addition of a solvent, surfactant component with the herbicide. which is essentially immiscible with water, to the concentration

A surface-active component is present in the account for the formation of an emulsion. Emulsions containing centrations sufficient to ensure an acceptable solvent, such as Agotaiys 150 or Izorag Y., time-thermostability of this composition, so that the composite shows an improvement in stability when collected has a cloud point of at least approximately 100 g under conditions of low temperature compared to 50"C and the crystallization point is not higher than approximately herbicidal compositions with a similar loading, which do not include this solvent,

Another variant of this invention relates to 10"C. These emulsions can be prepared to the composition of an aqueous herbicide concentrate, in such a way that they remain transparent, while containing a water-soluble herbicide dissolved in storage. Preferably, this concentrate is prepared in an aqueous medium, and a surface-active compound of a microemulsion that remains optically ponent. The water-soluble herbicide is present in a concentration that is biologically effective when stored for at least 7, 14 or 28 days. diluting this composition in an appropriate volume of water and It was also found that when superficial

active component of the liquid herbicide composition. This emulsion also contains a surface concentrate also includes an amine, which is mis- active component in solution or stable is alkylene oxide bonds, reducing the degree of alkox suspension, emulsion or dispersion in water. Surface strengthening improves the stability of this composition containing one or more active components when stored at low temperatures. For example, a composition of glyphosate containing al- trations sufficient to provide acceptable kyl (simple) ephyramine, which has no more than eight thermal stability of this emulsion, so that the emulsion of ethylene oxide bonds, reveals the crystal point has a cloud point of at least approximately zation not higher than -10"C, compared to a similar 50"C, preferably about 60"C, and the crystal point- loaded glyphosate composition that zation is not higher than about -10"C , preferably contains alkyl(simple) etheramine, which has ten approximately -20"C. Such stability when storing ethylene oxide bonds, which reveals a crys- point under low temperature conditions is desirable in more talization no higher than approximately 0"C. cold climatic conditions to support the

In a variant of this invention, a ready-to-pour and pump-able aqueous herbicide concentrate containing containers of a homogeneous composition is provided. is a water-soluble herbicide dissolved in water. In the preferred version, a thermostat is obtained

This water-soluble herbicide is present in a concentrated microemulsion. Microemulsion is optically stable, which is biologically effective when diluted, a transparent composition that remains stable in this composition in the appropriate volume of water and applied when stored in a specific temperature range on the leaves of a sensitive plant. This composition is a rature. Microemulsions are described (K. NoiItregd in the article, also contains a surface-active component in a solution or a stable suspension, microemulsion or (November 18, 2001) dispersion in water entitled "Uupep oiYi apa ulaheg tih apa tipadie". The surface-active component "PEr/ lumlu.gezropzeopiipe.sot/lLesp/etii. sweat" contains one or more cationic surface- The term "optically transparent" or "transparent" active substances or a mixture of one or several- is defined as the complete absence of any kind of cationic substances and one or more inhomogeneities when considered in bulk, in bottles of nonionic surfactants. microemulsion of this invention can be easily ensured by the stability of this composition, so that the composition is prepared by well-known methods and using the cloud point 50"С and the crystallization point is not higher than approximately in this area. Laboratory chemical beaker or tank is suitable for low volume

Preferably, cationic surface-active purposes, while large volumes can be processed into the substance containing the stabilizer of this invention, in standard industrial containers that move one or more amine salt compounds or are scrubbed, including reactors, tanks for - ammonium ammonium, each of which contains an alkyl solution (mixers) and tanks for mixing. or an aryl substituent having from about 4 to The mixing requirements are not critical, and the mixing- about 16 carbon atoms, and no more than de- desation should only be adequate for all ethylene oxide bonds in a given compound. These supplies are of a homogeneous finished form. The advantage is that the compounds increase the compatibility of the surface element with medium-speed mixing of the active component with the herbicide, increase the optical transparency and thermal stability of this stirrer by using stirring rods, provided with standard industrial positions and provide improved control (with propellers. Tanks- turbulators are suppression) of weed growth when diluting this is important in industrial applications as a means of composition with water and application to leaves. to reduce vortex mixing and

In another variant of the present invention, an organic solvent is added to this compression and in order to minimize the speed of propellant, which does not mix with water in order to create micro-homogeneity. Preferable are those that heat up. When the composition of the concentrate contains this sya or have a tank jacket. High solvent speed, storage stability of this compo- shift and high mixing speed are not overweighing is improved by lowering the crystallization point if excessive inclusion can occur - at least by about 10"C. Such compositions do not (capture) air in the finished form. The composition shows a crystallization point no higher than 16 prints of the composition can be added to the appropriate temperature of about -10"C, or even about -20"C, if the tank is in any order. Preferably, preferably, a surfactant is added to the tank substance from

A water or oil emulsion of a liquid herbicide - with the subsequent addition of a stabilizer, water and honey concentrate of this invention contains a pesticide. Surfactants that are not ter- aqueous phase containing water-soluble kuchimi at the treatment temperature can be non- herbicide dissolved in it. A water-soluble herbi- must be melted before preparation or the cid is present in a concentration that is biologically effective- preferably melted in the processing equipment by pective when diluting this emulsion in accordance with the addition of these components. volume of water and application to the leaves of a sensitive plant. The oil phase of this emulsion contains organo-pot contains the stabilizer of this invention, that is, a night solvent that is essentially immiscible with one or more compounds of salts of amines or quaternary

tin ammonium, each of which contains an alkyl of about 32 to about 44905 by weight compo- or aryl substituent having from about 4 to zition surface-active component in concen- about 22 carbon atoms, and not more than derations of about C to approximately 1595 by weight of seven C2-Cv-alkylene oxide bonds in this joint composition and the solvent component at this concentration. These compounds increase the surface compatibility from about 0.1 to about 595 by weight of the active component with the herbicide, increase the positions. optical transparency and thermal stability of this compound. In another variant of this invention, the composition and provide improved control (the liquid concentrate composition mainly contains sorghum) of weed growth when diluting this phosate or its salt or ether in a concentration from a microemulsion with water and applied to the leaves. about 25 to about 5090 by weight of the compo-

Preferably, the surface-active component contains one or more cationic surfactants in a concentration of from about 1 to about 3095 by weight of active substances or a mixture of one or several compositions, a stabilizer in a concentration of about cationic substances and one or more zno 0.01 to about 2595 by weight of the composition and nonionic surfactants. solvent component in a concentration of approx

Compositions of liquid concentrates of this 0.01 to about 1095 by weight of the composition. Even the invention preferably contains a water-soluble herbicide, more preferably, this composition contains glyphosate acid in a concentration of from about 10 to about - component in a concentration of from about 0.5 to surface-active component in a concentration of from about 3095 by weight of the composition and stabilizer from about 2 to about 17905 by weight of the composition- and/or component-solvent. Concentrations of stabilization, the stabilizer at a concentration of from about 0.05 tor and the solvent component are from O to to about 2095 by weight of the composition and compo- about 3095 and from O to about 1595 by weight nent solvent at a concentration of about 0, 05 compositions, respectively. to about 795 by composition weight. Most

In one embodiment of the present invention, the composition preferably contains glyphosate or a liquid concentrate preferably contains glyphosate, its salt or ether at a concentration of from about 32 or its salt or ether at a concentration of from about to about 4495 by weight of the composition, superficially 25 to about 5095 by weight of the composition, the semi-active component in a concentration from about to tion and stabilizer in a concentration of from about 0.01 about 1595 by weight of the composition and component- to about 2595 by weight of the composition. Even more solvent at a concentration of about 0.1 to more preferably this composition contains glyphosate about 595 by weight of the composition. or its salt or ether in a concentration of from approx. more than about 900 SP, at 10"C, about 2 to about 17905 by weight of the compo- more preferably not more than about 800, tion and stabilizer in a concentration of from about 0.05 700, 600, 500, 400 or z00СP, at 10C, and even up to about 20905 by composition weight. Most preferably no more than about 200 cSP, preferably this composition contains glyphosate or at 10"C, at the rate (relative deformation) of its salt or ether in a concentration of from about 32 shift 45/sec. to about 4495 by weight of the composition, surface- Term "water-soluble", which uses the active component in a concentration of about 0.1 to it in water at 207"C not less than approximately 50g/l. approximately 1595 by composition weight. Preferred water-soluble herbicides have a solution-

In another variant of this invention, the composition in deionized water at 207"C contains at least 200 g/l of the liquid concentrate of this invention. Water-dissolving glyphosate or its salt or ether are especially preferred in concentrated herbicides that have herbicidally active acids. trations from about 25 to about 50905 per vana or anionic part of the molecule and most of the composition, the surface-active component is present in the composition of the present invention at a concentration of from about 1 to about 3095 in the form of one or more water-soluble salts. of the composition and the solvent component at a concentration of from about 0.01 to about 1095 per ty, in addition to the water-soluble herbicide, other salts that the weight of the composition. Even more preferably, these contribute to the ionic strength of this aqueous phase, the composition preferably contains glyphosate or its especially preferred group of water-soluble salts or ethers in a concentration of from about 30 to herbicides are water-soluble herbicides, which are usually approximately 4,795 by weight of the composition, applied topically to the leaves of plants after germination. Although this active ingredient in a concentration of about the invention is not limited to any particular 2 to about 1795 by weight of the composition and compo- class of herbicide applied to the leaves water-solvent in a concentration of about 0.05 soluble herbicide, it was found that that he asked for about 795 by the weight of the composition. The most secure important advantages for compounds that mainly this composition contains are mainly gly-

nah Systemic movement in plants can regenerate salts, or any of their mixtures or salts, with the help of apoplastic (inanimate) level of neutralization. Especially predominant salts of the pathways, including in the vessels of the xylem and in intercalated glyphosate, include potassium salt, salt in isotonic spaces and cell walls, with the help of propylamine, ammonium salt, diammonium salt, salt of symplastic (living) pathways, including in monoethanolamine and trimethylsulfonium salt. Among the elements of the phloem and other tissues that make up the composition, potassium salt is more predominant. are from cells connected symplastically by plasmo- The relative amount of load /potassium-desms, or with the help of both apoplastic and glyphosate in a microemulsion herbicide composition- and symplastic pathways. For systemic herbicides, the properties of this invention will vary depending on what is applied to the leaves, the most important way is from many factors, including the phloem system, and the authors believe that this inven- surface-active substances that use provides the greatest advantages when water is released, and stabilizers, rheological characteristics, the active herbicide can move through the phloem. of this composition and temperature ranges at which

However, the compositions of this invention may be exposed to this composition. The loadings are also applicable when the water-soluble non-potassium phosphate herbicide in the given herbicide compositions is systemic, as, for example, in the case of paraquat. of the invention equals at least 320 g c.e./l and more

Water-soluble herbicides suitable for use in the compositions of this invention, preferably at least 330, 340, 360, 370, 380, include 390, 400, 410, 420, 430, 440, 450, 460, 470, 480, 490 acifluorfen, acrolein, amitrol, asu- 500, 510, 520, 530, 540, 550, 560, 570, 580, 590, lam, benazoline, bentazon, bialofos, bromacil, 600, 610, 620, 630, 640, 650, 660, 670, 680, 690 or bromoxynil, chloramben, chloroacetic acid, clo- 700 g c.e../l. pyralid, 2,4-О0, 2,А-ОВ, dalapon, dicamba, dichlor- Stabilizers of this invention are usually fun-prop, difenzoquat, diquat, endothal, fenac, phenocate, facilitating surface dispersion- xaprop, flamprop, flumiclorac, fluroglycofen, the active substances of the composition in water containing flupropanate, fomezafen, fosamine, glufosinate, dissolved glyphosate. These stabilizers make glyphosate, imazameth, imazametabenz, imazamox, possible addition of surface-active recho- imazapic, imazapyr, imazaquin, imazetapyr, ioxynil, wine, in the presence of salts or electrolytes, and provide

MSRA, MSRV, mecoprop, methylarsonic acid, easier dispersion in water at higher naphthalene, nonanoic acid, paraquat, piclor, concentrations or at lower viscosity, goquinclorac, sulfamic acid, 2,3,6-TVA, TCA, of a different form than those obtained in another case with triclopyr and their water-soluble salts. using only surfactant

Phloem-borne herbicides, which are also water-borne. Suitable stabilizers include preferred for use in the compositions of the primary, secondary or tertiary compounds of the invention, include, but are not limited to, Ca-Ci-alkyl- or -arylamine or their corresponding compounds, aminotriazole, azulam, bialafos , flakes of quaternary ammonium. Such stabilizers as sipiralid, dicamba, glufosinate, glyphosate, to a lesser extent increase the compatibility of certain glyimidazolinone salts, such as imazamet, imazametabenz, phosate (for example, potassium or isopropylamine salts), imazamox, imazapic, imazapyr, imazaquin, imazetapir, with surface -active substances, which otherwise phenoxy-containing herbicides, such as 2,4-0, 2,4-O8, show low or insignificant compatibility of dichlorprop, MSRA, MOSRV and mecoprop, picloram and at the same load of glyphosate. Corresponding triclopyr. A particularly preferred group of water soluble alkyl- or arylamine compounds can also be mystical compounds are salts of bialofos, glufosinate, and from 0 to about 5 C2-C4 alkylene oxide glyphosate. Another especially preferred group of groups, preferably ethylene oxide groups. The preferred water-soluble herbicides are salts of imidazolinone compounds of alkylamines, including Sv-Si2 herbicides. alkylamines having 0-2 ethylene oxide groups.

The compositions of this invention may optionally contain from 0 to about 5 ethylene oxide groups. Yes

A particularly preferred water-soluble herbicide, as well as the corresponding quaternary ammonium compounds, the cide applicable in the composition of this invention, also increase the compatibility of such compositions. B is glyphosate, the acid form of which is known alternatively as M-(phosphonomethyl)glycine. For example, such surface-active substances include glyphosate salts, applicable in the compositions of the given amine or quaternary ammonium salts of the invention, described in (US patents Me3799758 and having the formula:

Mo44055311. Glyphosate salts, which can be forged? compounds according to this invention include, but are not limited to, alkali metal salts, such as sodium and potassium; ammonium salt; -e salts of C-e alkylammonium, for example, dimethylammonium and isopropylammonium; Si-- alkanolammonium salt, for example, monoethanolammonium; salts of Si-alkylsulfonium, for example, trimethylsulfonium; and their mixtures. (5)

The M-phosphonomethylglycine molecule has three acidic or acidic sites with different pKa values; respectively, one-, two- and three-axis can be used

in J about 0.7 to about 1.2, more preferably from

A from about 0.7 to about 1.15 and most preferably from about 0.7 to about 11. Non-limiting examples of preferred hydrophobic solvents include toluene, xylene, cyclohexane, dichloromethane, dichlorobenzene, perchlorethylene, liq- oil (petrol-ligrot fraction), mineral oil, (8) oil, liquid fuel, oil and kerosene. Preferred hydrophobic solvents include toluene, xylols, naphtha, and oils. Commercially available, important solvents include Agotaiys 150 still mn (from Ekhop) and Izorag I (from Ekhop). Preferred solvents include aliphatic hydrocarbons, halogenated alkyls, aryl-substituted hydrocarbons, or mixtures thereof. Examples of commercially available organic solvents include Agotaiis 150 z (7) (from Echhop) and Izorag I. (from Echhop). or The compositions of this invention may optionally contain one or more water-insoluble herbicides in a solution in a solvent or in a suspension in and in. and concentration, which is biologically effective when diluting this composition in the appropriate volume of water and applying it to the leaves of a sensitive plant. Re-

Kk is an important non-water-soluble herbicide selected from the group that includes acetochlor, aclonifen, where EK! means linear or branched alkyl alachlor, ametrine, amidosulfuron, anilophos, or aryl having from about 4 to about 16 atrazine, azafenidine, azimsulfuron, benflura- carbon atoms, K2 means hydrogen, methyl, ethyl lin, benfurezate, bensulfuronmethyl, bensulide, or -"СН.СН2гО)ХН, VZ means hydrogen, methyl, ethyl benzphendisone, benzofenap, brombutide, bromfe- or --"СН2СНгО)УН, where the sum of x and y is not equal to bilnoxim, butahpor, butafenacil, butamiphos, is greater than about 5; P" is hydrogen or methyl; raline, butroxidim, butylate, cafenestrol, carfe-

Ve in each of the n groups (290) means independently C2-C4 ntrazoneethyl, , carbetamide, xporbromuron, alkylene; IN? means a hydrocarbylene or a substituted xporidazone, xporimuronethyl, chlorotoluron, xpor-hydrocarbylene having from 2 to about 6 nitrophene, chlorpropham, chlorsulfuron, xportal carbon atoms; and A" means anion acceptable in the countryside. Dimethyl, chlorothiamide, cinidonethyl, cinmethylin, gift anion. Non-limiting examples include cinosulfuron, clethodim, clodinafoppropargyl, tea mixed with the first alkylamine (Appeep C), clomazone, clomeprop, cloransulammethyl, cyana - dimethylcocoamine (Agachai OMSOO), cocoaammoniychlosin, cycloate, cyclosulfamuron, cyclooxydime, ride (Agachai C), PEG-2-cocoaamine (Etoteep C12) and cyhalofop-butyl, daimuron, desmedifam, desme-

PEG-5-cocoamine (EFoteep C15), all of which vigothrin, dichpobenil, diclofopmethyl, diflufenican, pour AK7o Mowbray, hexylamine, dimethylhexidimefuron, dimepiperate, dimethachlor, blife: lamine, octylamine, dimethyloctylamine, dodecyltritrin, dimethenamid, dinitramine, dinoterb, difemethylamide and Salv trialkylamines. Most namid, dithiopyr, diuron, ERTS, esprocarb, etal - the predominant stabilizer is octylamine. fluralin, ethametsulfuronmethyl, etofumesate,

In compositions with a high load of glyethoxysulfuron, ethobenzanide, fenoxapropetyl, and phosate, it is preferable to add stabilizers to FPmizifopbutium. fFluazifop-P-uty fluvoa. by weight ratio of surface-active resin: " g ": stabilizer from about 1:2 to about fluchloralin, flumetsulam, flumicloracpentyl, but 100:1 and more preferably from about 1:1 to flumioxazin, flumeturon, fluorochporidone, flu- about 8:1. A particularly preferred range for poxam, flurenol, fluridone, fluroxypyr-1- is from about 1.5:1 to about 6:1. methylheptyl, flurtamone, fluthiacetmethyl,

The organic solvent of this invention, which is essentially immiscible with water for graminicides, haposulfuron, hapoxyfop, hexazi, is any soluble nonone, imazosulfuron, indanophan, isoproturon, isocom, which has a solubility in water less than approximately uron, isoxaben, isoxaflutol, isoxapyrfop, lena: 1095 (w/w) and has a specific gravity of about cyl, linuron, mefenacet, metamitron, metazachlor, 0.7 to about 1.2. These solvents promote metabenzthiazuron, methyldimron, metobenzuron, the formation of a microemulsion and the increase of dispergometobromuron, metolachlor, 5-metolachlor, metovanity of hydrophobic surface-active substances in soups, methoxuron, metribucin, . metsulfuron, or surfactants with hydrophobic molinate, monolinuron, naproanilide, napropamide, part of the molecule in the aqueous phase of the carrier. Preferred neburon, nicosulfuron, norflurazon, orbencarb, hydrophobic solvents have solubility in water oryzalin, oxadiargyl, oxadiazone, oxasulfuron, less than about 795 (wt/wt), more perevapebulate, pendimethalin, pentanochlor, pentoxazon, less than about 595 (wt/wt mass) and the most fenmedifam, piperofos, pretylahpor, primisu- preferably less than about 195 (wt/wt). These lfuron, prodiamine, profluazol, prometon, pro-solvents additionally have a specific gravity of primethrin, propachlor, propanil, propaquizafop, pro-

pazin, propham, propisochlor, propizamide, prosul- substituted hydrocarbyl having from 1 to about focarb, prosulfuron, pyrafluphenethyl, pyrazo- 30 carbon atoms, hydroxy substituted hydrocarbyl, gyl, pyrazolinate, pyrazosulfuronethyl, pyrazoxy- -(вб)-(в2О) uvB, -С(-MAT)MATVAZ, -с(-0)MAVZ phen, pyributycarb, pyridate, pyriminobacmethyl, or -С(-5)МВ":В"3, n equals 0 or 1, x and y doriv- quinoclorac, hinmerac, hizalofop, hizalofop-P, regardless of the average number from 1 to pririmsulfuron, sethoxydim, siduron, simazine, about 60, and A" means anion acceptable in rural symetryn, sulcotrione, sulfentrazone, sul-farming. In this context, the predominant fometuron, sulfosulfuron, tebutam, tebutiu- hydrocarbyl (hydrocarbylene) groups B", VU, VU, ron, tepraloxidim, terbacil, terbumeton, ter-A", Ve, B, B! ii B!Z is linear or branched butylazine, terbutrin, tenylchlor, thiazopyr, alkyl (alkylene), linear or branched thidiazimine, thifensulfuron, thiobencarb, thiocarne alkenyl (alkenylene), linear or basil, tralkoxide, trialate, triasulfuron, branched alkynyl (alkynylene), arytribenuron, triethazine, trifluralin, triflusul (arylene) or aralkyl (aralkylfuron and vernolat. new) groups. In one version, EZ means li-

Preferred cationic and nonionic surface alkylene, mainly ethylene, and P", B2, B" and 5-vo-active substances effective in preparation have the previously determined values. Otherwise, the varia- herbicidal compositions and concentrates of this vinti B? means H, alkyl or -82ОВ/ and B", B2g, BZ, B? and finding, in particular, in the preparation of compositions and con- B' have previously defined values. In another concentrates containing potassium, ammonium or diamo B! means a linear or branched alkyne salt of glyphosate, listed below, or a linear or branched alkenyl

Cationic surfactants, a group having from about 8 to about 25 effective in the formation of herbicidal compositions, carbon atoms, B: in each of the x groups (220) means include: independently C2-Ca4 alkylene, EZ means linear or (a) an aminated alkoxylated alcohol having a branched alkylene group having from 1 to the formula: approximately b carbon atoms, B and B? mean, in: each independently, hydrogen or linear or spread-

Contains an alkyl group having from 1 to approx

K 5 6 carbon atoms, and x is the average number

Kk from 1 to about 30. More preferably, B' (9) denotes a linear or branched alkyl group having from about 12 to about 22 carbon or leucine atoms, B? in each of x groups (B20О) means c! independently ethylene or propyl, EZ means a linear or branched alkylene group having from 1 to ; the neck; about 4 carbon atoms, BK" and BZ are each independently hydrogen, methyl, or tris(hydroxymethylmethyl), and x is an average number from about 2 to about 30. Even more preferably, BK" means linear or branched an alkyl group having from approximately 12 to 18 carbon atoms, the opposite of 1 : : groups means independently ethylene or propyl,

Where am I and: . means hydrogen or hydrocarbyl or by- VZ means ethylene or 2-hydroxypropylene substituted hydrocarbyl having from 1 to about 30 4:5 E carbon atoms; B? in each of the x groups (B2O) and y groups, the group and Kk mean, each independently, vo- (820) means independently C2-Ca alkylene; B3 and B5 are either methyl and x is a middle number, each independently representing a hydrocarbylene or from about 4 to about 20. The most substituted hydrocarbylene having from 1 to about groups and having. from about 1 to about 6 carbon atoms; ЕВ" means hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to 18 carbon atoms, РЕ? in each of these groups (220) means about 30 carbon atoms, hydroxy-substituted is independently ethylene or propyl, K means set; hydrocaroyl, CHAOP(AROUVY, SSMATMATA, mean methyl, and x is equal to the average number - 12913 rev. 7 points 12ri1iz ' together with Vo and the nitrogen atom to which they will attach" OS About 4 to about 20. Compounds form; no, form a cyclic or a heterocyclic ring; or (2) have the preferred groups described above, |Kk

BZ means hydrogen, hydrocarbyl or substituted hydr- means predominantly hydrogen or linyin or rosaroyl, having a mass of from 1 to about 30 atoms of ovo zyky canon Predominantly methyl. Pe. . . 2. ve. . Pevus and Fen Omans, Zvrevazhny monoapkoxylyats spitting agents

C(FOOB", -C(-5)МВ!2В!З or together with B and the atom of mpagol and zato, to which they are attached, form cyclic) etherpropylamines and PEG-7, 710, 15 or 20- Sivtv ne or heterocyclic ring; KE" means hydrogen of (simple) propylamine ether (from Totai) ! pEGZ or either a linear or branched alkyl group that -18-C1415 (simple) etherdimethylpropylamine and PEG- has from 1 to about 4 carbon atoms; В!!, В" and 10, 15 or -20 or -25-Sivl1v (pros-

BZ stands for hydrogen, hydrocarbyl, or substituted thi)etherdimethylpropylamine (from Totai). , hydrocarbyl, B" means hydrogen, hydrocarbyl or (B) hydroxylated amides having the formula:

o Kn dn sh--- 83 --- M -d

I. 1

E chestnchyaeke Dir posti, Bena IAM her ko sz)! , and where B", B2 Her 25 independently means hydrogen or hydrocarbyl or substituted hydrocarbyl having and and , sho, from 1 to about 30 carbon atoms, or - and B! means hydrocarbyl or substituted hyd- : : : rocarbyl having from about 4 to about 30 АОовОН, c. means a hydrocarbylene or note. and a substituted hydrocarbylene having from 2 to about. 2. . individually 30 carbon atoms and BZ is a hydroxylated hydrocarbylene or substituted hydrocarbylene having from 2 to about 4 carbon atoms, B and B rings, polyhydroxyalkyl or poly(hydroxyalkyl)alkyl. Y is independently hydrogen or V is hydrocarbyl or in this context, hydrocarbyl groups VK and : g : : where mean linear or branched ey substituted hydrocarbyl having from ! to approximately - is Shi ! 30 carbon atoms, t equals 0 or 1, n equals linear or branched alkenyl, linear or medium number from 0 to approximately Ж mark hydrogenated alkynyl, aryl or aralkyl -С(0)- or -50»2-. In this context, the preferred formula: ВУ, Вб Her vo mean linear or branched o alkyl (alkylene), linear or branched alkenyl (alkenylene), linear or ! || branched alkynyl (alkynylene), aryl x- -ox--5 On (arylene) or aralkyl (aralkylene) groups. ! Preferably, B", B, B" and EZ mean independently

GU On is hydrogen, a linear or branched alkyl or alkenyl group having from 1 to about 6 carbon atoms, and EZ means a linear or branched ag, alkylene, having from 2 to about 6 carbon atoms, where KE! means a hydrocarbyl or a substituted hydrocarbyl more preferably. A. Ne in o zl means rockabile having from about 4 to about 30 . according to " o and z c c zo . carbon atoms; B? means hydrogen or a hydrocarbyl cyclic group having from ! to priolizn TOMIV or a substituted hydrocarbyl having from 1 to approx. carbon atoms, and i means a linear or branched lyzno of 30 carbon atoms , and p is equal to 1 - an approximation of Nabilya di zdo approximately atom 8. In this context, the preferred hydrocarbyl compounds of the 3 groups B! and P2 mean linear or branched, independently hydrogen or methyl, and KZ means alkyl, linear or branched alkenyl, listyl or propyl, and ammonium salts having a fornium or branched alkynyl, aryl or mul: d "shЩ r aralkyl group. Mostly, V! means a linear upa: or branched alkyl or linear or branched alkenyl group having from about 8 to about 30 carbon atoms, B? means autumn BE and DREAM day, linear or branched alkyl or linear! ! or a branched alkenyl group having from 1 to c: where about 30 carbon atoms and n is from about 4 to about 8; or B! and B? mean 1 independently linear or branched alkyl or or linear or branched alkenyl group having: have from about 4 to about 30 carbon atoms in A: in A, and n is from about 4 to about ! and with | 5 and 8. More preferably P! means a linear or branched alkyl or linear or branched alkenyl group having from about 8 to about 22 carbon atoms, K2 means hydrogen, linear or branched alkyl or linear or O) branched an alkenyl group having from 1 to 1 to ri p; 7 and approximately 6 carbon atoms, and n is equal to where Kk, in ; H, Vo and V mean independently about 4 to about 8: or V and V? means day or hydrocarbyl or substituted hydrocarbyl, whether linear or branched alkyl or having from ! up to approximately 30 carbon atoms, or a linear or branched alkenyl group, which may have. podrocarsil or substitute from about 4 to about 8 carbon atoms pdrocaroyl, even d ! to pr, and n is from about 4 to about 8 carbon atoms, KU means hydrocarbylene or z- ' (c) diamines having the formula: I substituted hydrocarbylene having from 2 to about 8 carbon atoms, EZ and EZ are individual - or hydrocarbylene or substituted hydrocarbylene having from 2 to about 4 carbon atoms, B'O / ev, means independently hydrogen or hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, t is 0 or 1, n is equal to Kv hshch; average number from 0 to about 40 and X denotes and Р is -С(0)- or -502-, 7 means -С(О)- and A" means an anion acceptable in agriculture. In this context, the preferred hydrocarbyl (hydrocapt) rbylene) groups B!-B'O mean linear or di- or branched alkyl (alkylene), linear or branched alkenyl (alkenylene), linear B. 2 or branched alkynyl (alkynylene), aryl-9 a (arylene) or aralkyl (aralkylene) M group. Preferably, B", B2, VU, Vo and B" independently mean hydrogen, a linear or branched alkyl or alkenyl group having from 1 to approximately b atoms carbon, BU means a linear or branched alkyl or alkenyl group having from about 8 to about 30 carbon atoms, t is 0 or 1, and ЕZ means a linear or branched alkylene group having from 2 to about t l 22 carbon atoms. More preferably, РЕ", В2, ВУ, Во and Е7 independently mean hydrogen or a linear or branched alkyl group having there are from 1 to approximately 5 (18) carbon atoms, B? means linear or where B' means hydrocarbyl or substituted hydro- a branched alkyl group having from about 4 to about 30 8 to about 22 carbon atoms, t is 0 carbon atoms, or -AVZOV"; B? means hydrogen or 1 and BZ means linear or branched alkyl or hydrocarbyl or substituted hydrocarbyl having lene having from 2 to about 20 carbon atoms. from 1 to about 30 carbon atoms, RZ means

Most preferably, K", A", B", AB and K" mean hydrocarbylene or substituted hydrocarbylene, which is independently hydrogen or methyl, KU means linear having from 2 to about 18 carbon atoms, B or a branched alkyl group having from approx. - means hydrogen or hydrocarbyl or a substituted lyzno of 8 to about 18 carbon atoms, t is a hydrocarbyl having from 1 to about 30 atoms of 0 or 1 and Z means ethylene or propyl, carbon, eE? means --ВО)уВ7; IN? in each of the groups (e) poly(hydroxyalkyl)amines having the form - (АФО) means independently Со2-Са alkylene; In "Oznalu": contains hydrogen or linear or branched alkyl

K!-f--d3 a group having from 1 to approximately 4 carbon atoms; y is equal to the average number from 0 to approx.

And, zno 30, t and n are independently equal to whole numbers

Kk is from 0 to approximately 7, the sum of t and n is equal to no more than approximately 7, and p is equal to a whole number from 1 to approximately 8. In this context, the preferred "b (І16) : рі ; : 1 р? рі; hydrocarbyl (hydrocarbylene) groups KE", B-, BZ" and where K' means hydrocarbyl or substituted hyd- B? means linear or branched alkyl rocarbyl having from about 4 to about 30 (alkylene), linear or branched alkenyl carbon atoms, or -A'OB?, B? means hydrogen (alkenylene), linear or branched alkynyl or hydrocarbyl or substituted hydrocarbyl having (alkynylene), aryl (arylene) or aralkyl- from 1 to about 30 carbon atoms, KZ means nu ( aralkylene) group. Preferably, B! means hydroxyalkyl, polyhydroxyalkyl or linear or branched alkyl or linear or poly(hydroxyalkyl)alkyl, B means hydrocarbylene branched alkenyl group having from approximately- or substituted hydrocarbylene having from 2 to 8 to about 30 carbon atoms, or approx 18 carbon atoms, and E? means hydrogen or VZOVU, V? means hydrogen, linear or branched hydrocarbyl or substituted hydrocarbyl having from n alkyl or linear or branched alkenyl- 1 to about 30 carbon atoms. Preferably, a group having from 1 to about 30 carbon atoms, poly(hydroxyalkylamines have the formula: let, C means a linear or branched alkylene or alkenylene group having from 2 on to about 6 carbon atoms, P" means a linear or branched an alkyl or alkenyl group having from about 8 to about 22 atoms

K/---m of carbon, t and n are independently equal to integers from 0 to approximately 7, the sum of t and n is equal to

He P is approximately C to 7 and p is an integer from 7) to approximately 4 to approximately 8; or R! and 22 independently mean linear or branched alkyl or a number from 0 to about 30 and y is equal to 0 or 1. In the linear or branched alkenyl groups that have in this context, hydrocarbyl groups (hydrocarbons from about 4 to about 30 carbon atoms) are preferred rbylene) groups B", BZ and 2? mean linear or leu, t and n are independently equal to whole numbers branched alkyl (alkylene), linear or from O to approximately 7, the sum of t and n is equal to branched alkenyl (alkenylene), linear, approximately C to 7, and p is an integer from about - or branched alkynyl (alkynylene), aryl - from 4 to about 8. More preferably, B!nu (arylene) or aralkyl (aralkylene) group - means a linear or branched alkyl or Preferred carboxylated linear or branched alkenyl group having a li(hydroxyalkylamines having the formula: from about 8 to about 22 carbon atoms, with or -BZOVU, B? is hydrogen, linear or branched alkyl or linear or p branched alvya ov, (y onkenyl group having from 1 to approximately 6 carbon atoms, ВZ means linear or branched alkym) lene or alkenylene group having from 2 to P approximately b carbon atoms, B " means a linear or branched alkyl or alkenyl group, (20) having from about 8 to about 18 atoms or carbons, t and n are independently equal to integers from 0 to about 7, the sum of t and n is equal to about to 7 and p equals a whole number from m approximately 4 to approximately 8; or B! and 2? denote independently linear or branched alkyl or linear or branched alkenyl groups having from about 4 to about 8 carbon atoms, t and n are independently integers from

O to about 7, the sum of t' and n is from about (1) zno Z to 7 and p is equal to a whole number from about t n 4 to about 8. Even more preferably, B! where V! and EZ are independently hydrogen, hydro means a linear or branched alkyl group, carbyl or substituted hydrocarbyl having from 1 to having from about 8 to about 18 atoms and about 30 carbon atoms, P? in each of the x carbon groups, or -BOH", B" means hydrogen or me- (A2O) means independently C2-Ca alkylene; B" noted that t and n are independently equal to integers from hydrocarbylene or substituted hydrocarbylene, which

O to about 4, KZ means linear or branched from 1 to about 30 carbon atoms, t and p female alkylene group having from 2 to about equal independently integers from 0 to about 6 carbon atoms, P" means linear or branched approximately 7, the sum of t and n is equal to no more than an approximate alkyl group having from approximately 8 to approximately 7, p is equal to the whole number from 1 to approximately 18 carbon atoms, the sum of t and n is equal to zno 8 , x is an average number from 0 to about 4 and p is an integer of about 30 and y is 0 or 1. In this con- 4. Most preferably, K' means a linear or text, preferably hydrocarbyl (hydrocarbylene) branched alkyl group, having from approximately the group B, BZ | P: means linear or branched - 8 to about 18 carbon atoms or -BOH", B" well alkyl (alkylene), linear or branched means methyl, 3 means ethylene, propylene, hyd-alkenyl (alkenylene), linear or roxyethylene or 2-hydroxypropylene, BC " means a branched alkynyl (alkynylene), aryl linear or branched alkyl group having a va (arylene) or aralkyl (aralkylene) group. about 8 to about 18 carbon atoms, t and Preferably, B! means linear or branched n is independently equal to integers from 0 to alkyl or linear or branched alkenyl about 4, the sum of t and n equals about 4 and a p group having from about 8 to about 30 equals an integer of about 4. Such compounds are atoms carbon; P2 in each of the x groups (B2O) means commercially available from Ayagisp and SiIagiapi. independently C2-Ca alkylene; BZ means hydrogen, () alkylated poly(hydroxyalkyl)lamines, which are linear or branched alkyl or linear or have the formula: branched alkenyl group having from 1 to

VZ approximately 30 carbon atoms; РЕ" means linear and or branched alkylene having from 1 to approx.

Vo -- V contains 30 carbon atoms, t and n are independently equal to integers from 0 to approximately 7, the sum of t and " av8) n is equal to approximately 3 to 7, p is equal to an integer, where В! and ЕЗ denote independently hydrogen , a hydrocarbyl number from 1 to about 8, x is a mesocarbyl or a substituted hydrocarbyl having from 1 to a carbon number from 0 to about 30 and y is 0 about 30 carbon atoms, P? in each of the x groups or 1 More preferably, K" means linear or (BO) means independently C2-Ca alkylene; B" represents a branched alkyl group having from about 10 hydrocarbylene or substituted hydrocarbylene having 8 to about 22 carbon atoms; K" in each of x has from 10 to about 30 carbon atoms. B5 of groups (20) means independently ethylene or propyl; means hydroxyalkyl, polyhydroxyalkyl or B? means hydrogen or linear or branched poly(hydroxyalkylalkyl); x is a medium alkyl group having from 1 to about 6 carbon atoms; KB" means linear or branched, BZ means independently hydrogen or linear or alkylene having from 1 to about 6 carbon atoms - a branched alkyl group having from 6 to about has from approximately C to 7, p is an integer from 1 to 2 to approximately 6 carbon atoms, and t and n are equal to approximately 8, x is an average number from 0 to independently integers from approximately 4 to approximately 30 and y is 0 or 1. At most up to about 8; or E! and EZ are independently preferably, KE! means linear or branched hydrogen or a linear or branched alkyl group- an alkyl group having from about 8 to about 1 to about 4 atoms in carbon, there are 18 carbon atoms; RE? in each of x groups (220) B? means linear or branched alkylene means independently ethylene or propyl; BZ means a group having from 2 to about 16 hydrocarbon or methyl atoms; t and n are independently equal to this, and t and n are independently equal to integers from to integers from 0 to approximately 7, the sum of t and n to approximately 4 to approximately 8. The most predominant is from approximately З to 7, p is equal to the whole no , IS! and VZ independently mean hydrogen or a linear number from 1 to about 8, x equals a medium or branched alkyl group having from 6 to a number from 0 to about 30 and y equals 0 to about 12 carbon atoms, BC? means ethyl-(9) dipoly(hydroxyalkyl)amine having the formula: lene or propyl, and t and n are independently integers from about 4 to about 8; or

Dno B Kyiv B' and 23 independently mean hydrogen or a linear or branched alkyl group having from 1 to d! in approximately 4 carbon atoms, B? means linear

That or a branched alkylene group having from 2 to . (223 approximately 12 carbon atoms, and t and n are equal to ! independently integers from approximately 4 to about poly(hydroxyalkyl)amine, up to about 22 carbon atoms, 2 means hydro- having the formula: carbylene or substituted hydrocarbylene having from 2 to about 18 carbon atoms, and B" and B?- B means independently hydroxyalkyl, polyhydroxyalkyl or poly(hydroxyalkylalkyl. In this context, k/А-Я-«о--82 x: preferred hydrocarbyl (hydrocarbylene) groups

B, B? and EZ mean linear or branched alkyl (alkylene), linear or branched alkek? nyl (alkenylene), linear or branched alkynyl (alkynylene), aryl (arylene) or ; (24) aralkyl (aralkylene) group. Preferably, the dipoly(hydroxyalkyl)amine has the formula: where K' means hydrocarbyl or substituted hydrocarbyl having from about 4 to about 30 carbon atoms, or -Xt-(B'F)UVU, and 2 and EZ independently mean hydrogen or hydrocarbyl or substitution in vk? An isolated hydrocarbyl having from 1 to about 30 tn carbon atoms, B" means hydroxyalkyl, polyhydroxyalkyl or poly(hydroxyalkyl)alkyl, X' means an anion acceptable in agriculture; B" in without each of the y groups (BO ) means independently C2-C4 where VC! and EZ are independently hydrogen or hyalkylene; C is hydrogen or linear or dihydrocarbyl or substituted hydrocarbyl having from 1 alkyl group having from 1 to about 22 carbon atoms, K? means hydro- 4 carbon atoms; X represents hydrocarbylene or carbylene or substituted hydrocarbylene having from substituted hydrocarbylene having from 2 to about 2 to about 18 carbon atoms, and t and n up to 18 carbon atoms; t is equal to 0 or 1, and y is independently denoted by integers from 1 to approximately equal to the average number from 0 to approximately 30. In this context, hydrocarbyl groups are preferred in this context, hydrocarbyl groups are preferred, (hydrocarbylene) groups P", A? and KZ mean B2 and 23 mean linear or branched alkyl- linear or branched alkyl (alkylene), well, linear or branched alkenyl, linear linear or branched alkenyl (alkenylene- or branched alkynyl, aryl or aralkiv) , linear or branched alkynyl (alkynyl groups. new), aryl (arylene) or aralkyl (aral- Preferably, quaternary alkylene salts) groups. Preferably, K'! and KZ mean poly(hydroxyalkyl)amine having the formula: independently hydrogen or a linear or branched alkyl group having from 1 to about 18 carbon atoms, B? means a linear or branched alkylene or linear or branched alkenylene group having from 2 to about 18 carbon atoms, and t and n are independently equal to integers from 1 to approximately 8. More preferably, E! and from about 4 to about 8; or B, B: and

BZ are independently linear or branched alkyl or linear or branched alkenyl groups having from about 4 to about 8 carbon atoms, t and n are independently integers from 0 to about 7, the sum of t and n is from about Z to 7, and p equals a whole number from about 4 to about 8. Even more preferably, EW! means a linear or branched alkyl group having from about 8 to about 18 carbon atoms, B? and BZ are independently hydrogen or methyl, t and n are independently (25) integers from 0 to about 4, the sum of t and n is equal to or equal to about 4, and p is an integer d and about 4. Most preferably, B! means a linear or branched alkyl group having from about 8 to about 18 carbon atoms, PE: and

VZ stands for methyl, t and n are equal independently

Y. integers from 0 to approximately 4, the sum of t and n to-

Kk on equals approximately 4, and p is equal to a whole number

P is about 4. () triamines having the formula: ; and day or hydrocarbyl or substituted hydrocarbyl, and; y having from 1 to about 30 carbon atoms, t and n are independently equal to integers from 0 to about 7, the sum of t and n equals no more than "b (t) about 7 , p is equal to a whole number from 1 to where B! means hydrocarbyl or substituted hyd- about 8, and X' means a commercially acceptable rockcarbyl having from 1 to about 30 atoms in the economy anion. In this context, the predominant carbon, P2, VZ, VI and E? independently means the hydrocarbyl groups B", B? and BZ mean linear den, hydrocarbyl or substituted hydrocarbyl, which is either branched alkyl, linear or branched having from 1 to about 30 carbon atoms, or - alkenyl, linear or branched alkynyl, (89 )5(А"О) Ve; Ve means hydrogen or a linear or aryl or aralkyl group. Preferably, B' is a branched alkyl group having from 1 to about Ca is alkylene; C is hydr- of about 8 to about 30 carbon atoms, rocarbylene or substituted hydrocarbylene having

IN? and C are independently hydrogen or linear from 1 to about 6 carbon atoms, n is either branched alkyl or linear or branched with an average number of from 1 to about 10, 5 substituted alkenyl group having from 1 to about 0 or 1 and x and y are independently equal to a total of 30 carbon atoms, t and n are equal to a number from 1 to approximately 4. In this context, independently of the integers from 0 to approximately 7, the relevant hydrocarbyl (hydrocarbylene) groups P, the sum of t and n is equal to integers from approximately C В2, VU, VU, Vo and 28 mean linear or branched up to approximately 7 and p is equal to a whole number from applied oalkyl (alkylene), linear or approximately 4 to approximately 8; or РЕ", В2 and ЕЗ mean branched alkenyl (alkenylene), linear independently linear or branched alkyl or or branched alkynyl (alkynylene), aryl-linear or branched alkenyl groups, which are mana (arylene) or aralkyl (aralkylene) about 4 to about 30 carbon atoms. Preferably, B! means linear or leu, t and n are independently integers branched alkyl or linear or branched from 0 to about 7, the sum of t and n is equal to no bialkenyl group that have from about 8 to less than about 7, and p is a whole number of from about 30 carbon atoms, RK, VU, B" and Z are from about 4 to about 8. More preferably, B! independently hydrogen, linear or branched means linear or branched alkyl or ly- alkyl or linear or branched alkenyl niin or branched alkenyl group having a group having from 1 to about 30 carbon atoms- from about 8 to about 22 carbon atoms, this, or -(V'O)pAE, V? means hydrogen, methyl, or

IN? and C are independently hydrogen or linear ethyl; B" in each of n groups (B'C) means independently or branched alkyl or linear or branched C2-Ca4 alkylene, n is equal to the average number from 1 tinned alkenyl group having from 1 to approx. to approx. 10 and x and y are independently equal to 6 carbon atoms, t and n are independently equal to a whole number from 1 to approximately 4. For larger numbers from 0 to approximately 7, the sum of t and n is given, B! means a linear or branched alkyl equals from about C to 7, and p is a group having from about 8 to about 18 carbon atoms, P, VU, B?, and E? mean an independently branched alkylene group having from 1 to no hydrogen, linear or branched an alkyl group, approximately 6 carbon atoms, RU in each of the x groups having from 1 to approximately 6 carbon atoms, or - (BO) and in groups (PO) independently means ethylene or pА?, means hydrogen or methyl; in each propyl means hydrogen or linear or spread-

В'Oz ve, ve b vil, В" bo linear b niy of n groups (B'C) means independently ethylene or alkali alkyl group having from 1 to approximately propyl, n is equal to the average number from 1 to pri- 4 carbon atoms, x is an average number of about 5, and x and y are independently an integer from 1 to about 15, and y is an average number of from 1 to about 4. Most preferably, B! is an average number from 0 to about 60. Most preferably , means a linear or branched alkyl group, B1 and C independently mean linear or branched alkyl groups having from about 8 to about 18 atoms and having from about 8 to carbon atoms, B2, VU, B1 and E? independently mean vo- about 18 carbon atoms, and B and E? mean day or -(B'O)p8", Be means hydrogen, P" each independently hydrogen, P? means a linear or branched n group (BC) means an independently ethylene or alkylene group having from approximately 1 pil, n is equal to the average number of from 1 to approximately b carbon atoms, KU in each of x z 5 , and x and y are independently an integer number of groups (ESO) and y groups (290) are independently eth- from 1 to about 4. Triamylene or propyl are commercially available, P" is hydrogen or linear or we include Asgo5 and Ciagiapi Sepatip branched alkyl group having from 1 to approximately 4 carbon atoms, x equals the average of diamines having the formula: numbers from 1 to approximately 10, and y equals the average- (Y) diami f id 1 b 10 , и и и . и » To this number from 0 to approximately.

In Kk (Ou pet sne Manny (Yu) salts of mono- or diquaternary ammonium, which also have the formula: in KE 5 8 x: Й | x z (88) p'--- y ("P oo) --- B --Y-- 8 where B! VZ. B? and E5 are independently hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to about 30 carbon atoms, or - (АОХВ", B: means hydrocarbylene or substituted (29) hydrocarbylene having from 2 to approximately 30 carbon atoms, -С(-МАЗМА2В18-, -С(-0О)МА:В., - в? , с-m gВ-, -С( -МА12)-, -С(5)- or -С(0)-, ВЕ in each of the x groups (ВО) and in groups (920) means non-C2-Ca alkylene, B" means hydrogen or a linear - K M (Kou k-M i nu or a branched alkyl group having from 1 to about 30 carbon atoms, B!!, B? and v/z chu v means hydrogen, hydrocarbyl or substituted hydrogen - rocarbyl having from 1 to about 30 carbon atoms, x equals an average number from 1 to ; (30) about 50, and y equals an average number from 0 where B", BZ, VU, B5, B and B? mean independently to about 60. In this context, trans all hydrogen, polyhydroxyalkyl, hydrocarbyl or substituted hydrocarbyl (hydrocarbylene) groups KU, VA, and hydrocarbyl having from 1 to about 30

В" means linear or branched alkyl of carbon atoms, or -(ВО)хВ", В2 means hydrocane (alkylene), linear or branched alkenyl-rbylene or substituted hydrocarbylene having from 2 nu. (alpkenylene), linear or branched up to approximately 30 carbon atoms, and in each of x alkynyl (alkynylene), aryl (arylene) or groups (P2O) and in groups (PO) means independently C2-Ca aralkyl (aralkylene) groups. Predominantly, EK", I ih vi vi i u karakle ovu) corpses of hydrogen or linear alkylene, B" means hydrogen or linear or branched

H "or branched alkyl or dinium or diluted alkyl group having from 1 to about

U is a branched linear alkyl group of 4 carbon atoms, x equals the average number of branched alkenyl group having from d to about 1 to about 30, and y equals the average number of linear obovate aloe or 00CsLU from about 3 to about 60, THEIR name: dinium or hazhen agkenienov and it is an anion acceptable in agriculture.

In this context, the predominant hydrocarbyl (hydrocarbons with from 1 to approximately 1; carbon atoms, KE? in corbylene) groups P", B2, BZ, VU, B", Be and 9 mean - зны З х се (в о) ! Her; groups (KO) they are either linear or branched alkyl (alkylene), pen or ozga penya "means linear or branched alkenyl (alkenylene- tlo ibynzno and atoms are compared to se vu ), linear or branched alkynyl (alkynylide - up to the first carbon, x dory and new), aryl (arylene) or aralkyl (aralyne number from 1 to approximately 30, and to dorykylene) groups. Mostly, В", ВЗ, В, В5, В? and в?

More specifically, "ve" means independently hydrogen or a linear or branched alkyl or alkenyl group, which is hydrogen or a linear or branched alkyl having from 1 to about 22 carbon atoms, or a group having from up to approximately 18 carbon atoms - (VFO)XV", V? means a linear or branched allele, or -(АО)МА, A" means a linear or kylene or alkenylene group having from approx.

lyzno 1 to approximately 6 carbon atoms, is in each In one variant, a surface-active reaction of x groups (ВО) and in each of y groups (Е2О) means that the wine has the formula (31), where В! means hydrocarbyl independently of C0-C4 alkylene, B' means hydrogen or a substituted hydrocarbyl having from an approximately linear or branched alkyl group having from about 8 to about 30 carbon atoms, BV? means 1 to about 4 carbon atoms, x is se-hydroxyalkyl, polyhydroxyalkyl, or an even number from 1 to about 30, and in addition, a (hydroxyalkyl)alkyl group and C is hydrogen, is an average number from 1 to about 60. hydroxyalkyl, polyhydroxyalkyl or

More preferably, E, BZ, B", B", BZ and E? mean Li(hydroxyalkyl)alkyl. In this context, preferred independently hydrogen or linear or branched hydrocarbyl groups KE! mean a linear or dialkyl group having from approximately 1 to approximately branched alkyl, linear or branched alkene with 18 carbon atoms, or -(ВО)хВ", В? means a nil, linear or branched alkynyl, aryl-linear or branched alkylene group having a n or aralkyl group. In one variant B! from about 1 to about 6 carbon atoms, P? means linear or branched alkyl, linear in each of x groups (РО) and in groups (Е90) means unbranched or branched alkenyl, linear or branched ethylene or propyl, B" means hydrogen or a female alkynyl, aryl or aralkyl group, that a linear or branched alkyl group having from about 8 to about 30 carbon atoms, 1 to about 4 carbon atoms, x equals sele- a group having from 1 to about an average number of from 1 to about 60. At least 6 carbon atoms, and EZ means hydrogen or linear more preferably, B' and VZ means an independent or branched hydroxyalkyl group having from linear or branched alkyl groups , having 1 to about 6 carbon atoms. Preferably, B! is from about 8 to about 18 carbon atoms, and means linear or branched alkyl, linear

VU, B, BB and E? independently means hydrogen or or branched alkenyl, linear or methyl, B2 means a linear or branched alkyl- branched alkynyl, aryl or aralkyl new group having from about 1 to about a group having from about 8 to about 22 6 carbon atoms, P : in each of the x groups (BO) and in the groups of carbon atoms, B: means linear or branched- (BO) means independently ethylene or propyl, B well a hydroxyalkyl group having from 1 to approximately- means hydrogen or linear or branched alky - less than 4 carbon atoms, and EZ means hydrogen or an alkyl group having from 1 to about 4 carbon atoms, or a branched hydroxyalkyl group of carbons, x is an average number from 1 to has from 1 to about 4 carbon atoms. More than about 10, and y is equal to the average number of mostly, BC! means linear or branched up to about 50. alkyl, linear or branched alkenyl, li- (I) secondary or tertiary amine having a phonic or branched alkynyl, aryl or rmule: aralkyl group having from about 8 to pri-

He has about 18 carbon atoms, P? means hydroxymethyl or hydroxyethyl and EZ means hydrogen, hydroxymethyl or hydroxyethyl.

Kk (t) monoalkylated amines having the formula: (vya ; (31) v- v where B" and E2 mean hydrocarbyl having from 1 to about 30 carbon atoms, and RZ means vo- ; (32) day or hydrocarbyl having from 1 to about carbon atoms. In this context, preferred where B! and 2" are independently hydrocarbyl hydrocarbyl groups B", B? and EZ are linear or substituted hydrocarbyl groups having from 1 or branched alkyl, linear or branched up to about 30 carbon atoms, or -B?5BE, B? into alkenyl, linear or branched alkynyl, each of the x groups (B2O) means independently a C2-C4 aryl or aralkyl group. Preferably, PE! alkylene, BZ means hydrogen or linear or means linear or branched alkyl or ly-branched alkyl group having from 1 to about or branched alkenyl group having up to 4 carbon atoms, KE? means linear or from about 8 to about 30 carbon atoms, a branched alkyl group having from about a B? and EZ mean n independently hydrogen or linear b to about 30 carbon atoms, BU means either a branched alkyl or linear or hydrocarbyl or substituted hydrocarbyl group, a branched alkenyl group having from 1 to having from 4 to about 15 carbon atoms, and x of about 6 carbon atoms . More preferably, V! is an average number from 1 to about 60. represents a linear or branched alkyl group. In this context, preferred hydrocarbyl groups having from about 12 to about 22 B atoms, B" and 29 represent a linear or branched alkyl carbon, and K2 and E3 are independently hydrogen, linear, linear or branched alkenyl, linear methyl or ethyl. In one embodiment, an amine of the formula or a branched alkynyl, aryl, or aralkyl- (27) B' represents a linear or branched alkyl group. In one embodiment, 2! includes in itself a group having from about 12 to about 22 from about 7 to about 30 carbon atoms, carbon atoms, and B? and EZ are independently preferably from about 8 to about 22 ato- linear or branched hydroxyalkyl groups having carbon, and other groups have from 1 to about 6 carbon atoms described above. Preferably, B' and B" are independently linear or branched alkyl or linear or preferably, B! and B" represent independently a linear branched alkenyl group having from 1 to or a branched alkyl group having from 1 to about 25 carbon atoms, P: in each of the x groups of about 22 carbon atoms, P? in each of the x groups ( 820) means independently C2-Ca4 alkylene, BZ means (BO) and in groups (220) means independently ethylene or hydrogen, methyl or ethyl and x equals middle-propyl, EZ means hydrogen or methyl, and the sum of the numbers in it is from 1 to about 40. More preferably, an average number of from about 2 to about 2, BK! and B? are independently linear or about 20. Even more preferably, B! is a branched alkyl group having from 1 to about linear or branched an alkyl group having from 1 to 22 carbon atoms, B: in each of the x groups (220) from about 8 to about 22 carbon atoms, and B is independently ethylene or propyl, BZ is a linear or branched alkyl group, hydrogen or methyl, and x is an average number having from 1 to about 22 carbon atoms, B? in from 1 to approximately 30. Even more predominant in each of the x groups (BE2O) and y groups (220) means unknown, B! is linear or branched alkyl such as ethylene or propyl, C is hydrogen or a group having from about 8 to about 22 methyl, and the sum of x and y is the average number of carbon atoms, and 7 is linear or branched- from about 2 to about 20 . The most predominant alkyl group having from 1 to about 22 no, B! means linear or branched alkyl of carbon atoms, P: in each of the x groups (220) means a group having from about 8 to about 22 independently ethylene or propyl, BZ means hydrogen of carbon atoms, and P" means linear or branched or methyl and x is equal to the average number of the used alkyl group, having from 1 to approximately 6 approximately 1 to approximately 10. Most preferably, carbon atoms, P2 in each of the x groups (B2O) and in the groups

IN! means a linear or branched alkyl group, (820) means independently ethylene or propyl, BZ having from about 16 to about 22 atoms means hydrogen or methyl, and x is a middle carbon, and B? means methyl, B? in each of the x groups, the number is from about 2 to about 15, or B1 (820) is ethylene, E3 is hydrogen, and x is B? means an independently linear or branched group having an average number of from about 1 to about 5, or B! means a linear or branched zno of 22 carbon atoms, P? in each of the x groups (20) and an alkyl group having from approximately 8 to approximately groups (220) independently means ethylene or propyl, zno 15 carbon atoms, and B" means methyl, B? in BZ means hydrogen or methyl , and x equals the average of each of the x groups (220) means ethylene, BZ means in it a number from about 5 to about 15. hydrogen and x equals an average number from about Preferable surface-active substances that range from about 5 to about 10 ., dialkylated quaternary ammonium, (n) salts of dialkylated quaternary include EShodzoit7 cC12 (PEG-2-ammonium having the formula: cocomethylammonium chloride from AkKgo Mobei), (gozAZ EShodnadtm C15 (PEG-5-taloammonium chloride from AK20o x Mobei!) . , in PEG-10-dithaloammonium bromide, didodecyl-die0-10-ammonium bromide, dicoco-dieO-(15)-ammonium chloride, didodecyl-dieO-(15)-ammonium chloride, di dodecyl-

In (33) dieO-(10)-ammonium bromide, dialkyl(talo and stearyl)- y y y sho, dieO-(19,6)-ammonium bromide, polypropylene glycol-40- where K" means hydrocarbyl or substituted hyd-diethylammonium chloride ( Etsoyi CO-42 from SK UMiso), rocarbyl, which has from 1 to approximately 30 atoms of polypropylene glycol-55-diethylammonium chloride (Etsoyi! carbon, K" in each of the x groups (KO) and y groups (KO) of Co-55 from SK Umyso) and thalomethyl-EO-(8)- means independently C2-Ca alkylene, EZ means vo-ammonium chloride. day or a linear or branched alkyl group, (o) salts of monoalkylated quaternary having from 1 to 4 carbon atoms, PE" means ammonium, having the formula: day or hydrocarbyl or substituted hydrocarbyl, ! " ; having from 1 to about 30 carbon atoms, x and y in x are independently equal to an average number from 1 to about 40 and X: means anion acceptable in the rural economy. In this context, the preferred ! hydrocarbyl groups B! and EE? mean linear or " branched , linear or branched and alkenyl, linear or branched alkynyl, aryl, or aralkyl. Preferably, B and y are independently a linear or branched alkyl or linear or branched alkenyl group having from 1 to about 25 atoms carbon and independently mean hydrogen, P? in each of the x groups (BO) and in the groups (BO) is oznadrocarbyl or substituted hydrocarbyl, which independently of 1 has Co-Ca alkylene, C means hydrogen, to approximately Zo atoms p kaObi, Kk means Se methyl bo til. th sum of x y is equal to the average Mucilage ZO atom of vupetsu ev On with td number from approximately 2 to approximately 30. More (820) means independently C2-Ca alkylene, ВZ means

is hydrogen or linear or branched alkyl of 1 to about 30 carbon atoms, and X' means a group having from 1 to about 30 carbon atoms, an agriculturally acceptable anion. In this context, x equals the average number from 1 to approximately in this context, the predominant hydrocarbyl groups are B", zno 60 and X means acceptable in the rural economy. linear, linear or branched alkenyl, linear hydrocarbyl groups B", B" and 25 mean linear or branched alkynyl, aryl or aralkyl or branched alkyl, linear or branched lin groups. Preferably, BK! means linear or alkenyl, linear or branched alkynyl , a branched alkyl or linear or branched aryl or aralkyl group. Preferably, EE", B and an alkenyl group having from about 8 to about

IN? means independently linear or branched of about 30 carbon atoms, and P, B3 and B" mean alkyl or linear or branched alkenyl independently linear or branched alkyl or group having from 1 to about 25 carbon atoms linear or branched alkenyl group having this, B2 in each of the x groups (220) means independently from 1 to approximately 30 carbon atoms.

C2-Ca alkylene, C means hydrogen, methyl or ethyl and preferably, K' means linear or branched x is an average number from 1 to about 40 alkyl or linear or branched alkenyl. More preferably, B", B" and B? means a non-group having from about 8 to about 22 linear or branched alkyl groups of carbon atoms, and 2, B3 and B" means independently having from 1 to about 22 carbon atoms, P? in a linear or branched alkyl or linear or each of x groups (820) is independently an ethylene branched alkenyl group having from 1 to or propyl, BZ is hydrogen or methyl, and x is up to about 6 carbon atoms.More preferably, the average number is from 1 to about 30. Also B! means a linear or branched alkyl group, more preferably, B' means a linear or having from about 8 to about 16 atoms a branched alkyl group having from about carbons, and Rg, BZ and B" independently mean linear 8 to about 22 carbon atoms, K2 in each of x or a branched alkyl group having from 1 to groups (820) means independently ethylene or propyl, about 6 carbon atoms. Most preferably,

VAZ means hydrogen or methyl, BK" and C independently B! means a linear or branched alkyl group, means a linear or branched alkyl group having from about 8 to about 14 atoms having from 1 to about 22 carbon atoms, and x carbon, and 2, BZ and B" are methyl. Preferred is an average number from 1 to about 30. commercially available surfactants,

Even more preferably, B! means linear which contain quaternary ammonium, include or a branched alkyl group having from approx. 50 (thalotrimethylammonium from x groups (220) means independently ethylene or niyl chloride from AK70 MobeiY), propyl, KZ means hydrogen or methyl, BK? and 5 (4) (simple) etheramines having the formula: independently mean linear or branched c is an alkyl group having from 1 to about 6 carbon atoms, and x is an average number of from about 5 to about 25. Most preferably, B is a linear or branched alkyl group having from about 16 to about 22 carbon atoms, EC? in each of the x groups (220) means independent ethylene or propyl, C means hydrogen or where B! means hydrocarbyl or substituted hyd-methyl, B" and 25 independently mean linear or rocarbyl, having from 1 to about 30 atoms of a branched alkyl group having vi d 1 to near-carbon, EC? is a hydrocarbylene or a substituted lyso of C atoms, and x is an average hydrocarbylene having from 2 to about 30 atomic numbers from about 5 to about 25. Preferred are carbon atoms; BZ and B" independently mean hydrogen, surfactants that contain monoalhydrocarbyl or substituted hydrocarbyl having from coxylated quaternary ammonium, include 1 to about 30 carbon atoms, or -(BPO)ХВЕ, itself PEG-7- Siv-dimethylammonium chloride and PEG-22-B5 in each of x groups (50) means independently C2-C4

Siv-dimethylammonium chloride. alkylene, BEZ means hydrogen or linear or (p) quaternary ammonium salts having a pho- branched alkyl group having from 1 to pribrmulu: lisno 4 carbon atoms, and x is equal to the average in? and a number from 1 to about 50. In this context,

Х are the predominant hydrocarbyl (hydrocarbylene) groups в----я3 В, Бе, ес We mean linear or branched alkyl (alkylene), linear or branched

Y, alkenyl (alkenylene), linear or

Kk branched alkynyl (alkynylene), aryl (arylene) or aralkyl (aralkylene) group. , (35) Mostly, V! means linear or branched where B", B3 and B? are independently hydrogen alkyl, linear or branched alkenyl, or hydrocarbyl or substituted hydrocarbyl having linear or branched alkynyl, aryl or from 1 to about 30 carbon atoms, 2 means an aralkyl group, having from 8 to about 25 hydrocarbyl or substituted hydrocarbyl having from carbon atoms, CO means .lINIINE or a branched alkylene or alkenylene group,

having from 2 to about 30 carbon atoms, R3 and lyzno 6 carbon atoms, and n, y and 7 are 0; or

IN? mean independently hydrogen, linear or dis- В, вг2, ВЗ and 2 are independently hydrogen or branched alkyl, linear or branched alkyl, linear or branched alkyl or alkenyl kenyl, linear or branched alkynyl, a group having from about 1 to about 6 aryl or aralkyl group having from 1 to about 6 carbon atoms, B? means a linear or about 30 carbon atoms, or -(BPO)хХВ", Vo in a branched alkylene or alkenylene group, each of the x groups (BO) means independently C2-C4 having from about 8 to about 25 alkylene atoms, RU means hydrogen , methyl or ethyl, and x carbon, and n, y and 75 are equal to 0; or В!, 82, ВЗ and в is equal to an average number from 1 to about 30. independently mean hydrogen or linear or dis-

More preferably, VE! means a linear or branched alkyl or alkenyl group having an alkyl or alkenyl group having from 8 to about 1 to about 6 carbon atoms, E2 to about 22 carbon atoms, P? means linear- means a linear or branched alkylene or well or branched alkylene or alkenylene alkenylene group having from about 1 to a group having from 2 to about 6 carbon atoms- about 6 carbon atoms, P? in each of the groups this, KZ and B? independently means hydrogen, linear (BO) means independently C2-Ca4 alkylene, in a dor- or branched alkyl or alkenyl group, having an average number of from 1 to about 20, and having from 1 to about 6 carbon atoms, or - 7 equal 0; or EC! and EZ mean independently (АРО)ХАЯАУ, В? in each of the x groups (BO) means a linear or branched alkyl or linear or independently ethylene or propyl, RU means a hydrogen branched alkenyl group having from about or methyl, and x is an average number from 1 to about 8 to about 22 atoms carbon, B? means about 15. Most preferably, B' means a linear or branched alkylene group having a linear or branched alkyl or alkenyl from about 2 to about 25 carbon atoms; and a group having from 8 to approximately 18 carbon atoms, and 25 are each independently hydrogen, lithium, B? means ethylene or propyl, BZ and B" mean or branched alkyl or alkenyl are independently hydrogen, methyl or -(BPO)XV", Vo in a group having from 1 to approximately 6 carbon atoms in each of the x groups (E2O ) means independently ethylene this, or -(ВО)ХВ", В? in each of the x groups (E5O) is propyl or propyl, P? means hydrogen and x equals means independently Co-C4 alkylene, B/ means hydrogen in it numbered from 1 to about 5. or a linear or branched alkyl group that () diamines having the formula: has from 1 to about 4 carbon atoms , x gifts-

B (dv M «5 o o)y--- 82 ----sh--B3 represents an average number from 1 to approximately 30 and n, y and 7 are equal to 0; or EV! means linear or branched alkyl or linear or branched alkenyl group having from about 1 to about (37) about 22 carbon atoms, B? means linear or where B", BZ, B" Its EE? mean an independently branched alkylene group having from about 1, hydrocarbyl or substituted hydrocarbyl having from 2 to about 25 carbon atoms, РУ, В and в" have from 1 to about 30 carbon atoms, or - mean, each independently , hydrogen or linear (AO)XB; B: and 28 are independently a hydrocarby or branched alkyl group having from 1 to lene or a substituted hydrocarbylene having from 2 to about 6 carbon atoms, X is -C(0)- or approximately 30 carbon atoms, P in each of the x groups -5052-, n and y are equal to 0 and 72 is equal to 1. More pe- (BO) and y groups (PO) means independently С2-Са alkyl, respectively, БЕ! and B" means independently linear or lene, B' means hydrogen or linear or branched alkyl or linear or branched branched alkyl group having from 1 to approx. - an alkenyl group having from approximately 4 to approximately 30 carbon atoms, x equals an average of approximately 18 carbon atoms, P? means a linear or number from 1 to about 30, X means -O-, -M(B5)- a branched alkylene group having from about )-, -Щ(ВУ)С(0)-, -С(О)М(AZ)-, zno 2 to approximately 6 carbon atoms, EZ and P? ozna- -5-, -50- or -5052- , y is equal to 0 or medium, each independently, hydrogen or linear or a number from 1 to about 30, n and 7 are equal to an unbranched alkyl group having from 1 to approximately 0 or 1 and EZ means hydrogen or hydrocarbon is 6 carbon atoms, and n, y, and 7 are 0; or bil or substituted hydrocarbyl. In this context, B, B2, B3, and 2" independently mean hydrogen or preferred hydrocarbyl (hydrocarbylene) groups, a linear or branched alkyl group having from

B", B, VU, VU, B and ER independently mean linear of about 1 to about 6 carbon atoms, P? or branched alkyl (alkylene), linear or means a linear or branched alkylene group, branched alkenyl (alkenylene), linear having from about 8 to about 25 atoms or a branched alkynyl (alkynylene) aryl carbon, and y is 0; or EE", B2, BZ and B" are (arylene) or aralkyl (aralkylene) groups. are independently hydrogen or linear or branched -

Mostly, V! and B" independently means a linear or branched alkyl group having from about 1 to a branched or linear alkyl or linear or about 6 carbon atoms, B" means a linear or branched alkenyl group having from about to a branched alkylene group having from about 1 to about 22 carbon atoms, 2 and 8 from 1 to about 6 carbon atoms, P in each of means independently linear or branched alu groups (290) means independently ethylene or propyl, kylene groups having from about 2 up to and including the average number of 1 to approximately 25 carbon atoms, EZ and BEZ are each 10, and n and 2 are 0; or БЕ! and EZ are independently hydrogen or linear or independently linear or branched an alkyl group, a branched alkyl group having from 1 to about 8 to about 22 carbon atoms, 2 means a linear or branched alkyl group, BZ means a linear or branched alkyl group, a lene group having from about 2 to about - what has from about 8 to about 22 atoms but 6 carbon atoms, and B and 2? mean, each carbon; or B' and B? means independently - independently, hydrogen, linear or branched alkyl- (B'O)XE?, BZ means a linear or branched alkyl group having from 1 to about 6 atoms a ring group having from about 8 to about carbons, or -(BZO)xB7, B in each of the x groups (90) 22 carbon atoms, P" in each of the x groups (BO) independently means ethylene or propyl, B" means ethylene or propyl, EZ means hydrogen or is hydrogen or methyl, x is number-average linear or branched alkyl or linear or from 1 to about 1511, y and 7 are 0; or a branched alkenyl group having from 1 to

IN! means a linear or branched alkyl group, about 30 carbon atoms, and x is between about 1 and about 22 atoms of about 1 to about 10. The most pe- carbon, P? means a linear or branched alkyl group, respectively, B" and 22 independently mean methyl, and 23 a lene group having from about 2 to about having from about 8 to about 18 atoms independently, hydrogen, X is -C(O)- or -5052-, n and carbon; or B' and B? mean independently - y is equal to 0 and 72 is equal to 1. Preferred diamines (B'O)XE", VZ means linear or branched al- include Setipi 14-2-14, Setipi 14-3-14, a ring group having from about 8 to approx

Setipi 10-2-10, Sbetipi 10-3-10, Setipi 10-4-10 and 18 carbon atoms, P in each of the x groups (BO) denote

Setipi 16-2-16 (C0, C4 or Civ ethylene-, propyl- means ethylene or propyl, 2? means hydrogen or Al- or butylene- M-methyldiamine from Monsanto), a ring group having from about 8 to about

Eshodioteepv "m and ueyatipetm EOM-148. 18 carbon atoms, and x is equal to the average number (5) amino oxides having the formula: from 1 to about 5. Commercially available surfactants that contain amino oxides include Spetokhide 1-70. () Alkoxylated amino oxides having the formula:

Xa' (38) where B, B2 and EZ independently mean hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to 4. . c) up to approximately 30 carbon atoms, -(B'O)xB5 or - where K means hydrogen, hydrocarbyl or substitution-

В(ОВУхХОВ; ВЯ in each of the x groups (ВО) means a hydrocarbyl having from 1 to approximately 30 independently C2-Са alkylene, P5 means hydrogen or carbon atoms, P" in each of the x groups (70) In the hydrocarbyl groups or substituted hydrocarbyl having from (Y'O) means independently C2-Ca alkylene; K" means 1 to about 30 carbon atoms, Pe means a hydrocarbylene or a substituted hydrocarbylene that is rocarbylene or a substituted hydrocarbylene that has from about 2 to about 6 carbon atoms, from 1 to about 6 carbon atoms, x is equal to this, and Kk" are each independently hydrogen, having an average number of from 1 to about 50, and generally hydrocarbyl or substituted hydrocarbyl having from ! Sv3 pln 1 up to approximately 30 carbon atoms, -(82)y-(820)y87; not the number of carbon atoms in B, B? and EZ is equal to p; b Is this, CHALK(ATOUN at least 8. In this context, the predominant hyds means hydrocarbylene or substituted podcarrocarbyl (hydrocarbylene) groups B", B2, B3, B belene having from 1 to about 6 atoms carbon

Ve means a linear or branched alkyl group, AK" means hydrogen or a linear or branched (alkylene), linear or branched alkenyl or alkyl group having ge 5 and approximately 4 (alkenylene), linear or branched alkynyl carbon atoms, n is 9 or 1, and 1 x 1 doro (alkynylene), aryl (arylene) or aralkyl independently of the average number from ! to prin (aralkylene) group. Preferably, B" and B? about 60. In this context, the preferred hydrocarbyl (hydrocarbylene) groups B!, B", B? and independently contain hydrogen, linear or branched biphenyl b! and. alkyl or linear or branched alkenyl include in itself a linear or branched alkyl group having from 1 to about 30 carbon atoms (alkylene), a linear or branched alkenyl group, or -"ВО)хХВ"; c means a linear or well (alkenylene), LINEAR or a branched branched alkyl or linear or branched alkynyl (alkynylene), aryl (arylene) or alkenyl group having from about 8 to para-aralkyl (aralkylene) groups. Preferably, K' is about 30 carbon atoms, B? in each of the x groups means linear or branched alkyl or (BO) independently means C2-Ca alkylene; P? means a linear or branched alkenyl group having at least hydrogen or a linear or branched alkyl group containing about 8 to about 25 carbon atoms, or a linear or branched alkenyl group , which is in each of x groups (KO) means independently С2-Са has from 1 to about 30 carbon atoms, and x to- alkylene, PE means linear or branched and al- equals the average number from 1 to about 30. alkylene or alkenylene group having from 2 to

More preferably, B! and B2 are independently about b carbon atoms, K" and K? are hydrogen or a linear or branched alkyl group, each independently, hydrogen or a linear or branched group having from 1 to about 6 carbon atoms, and a branched alkyl group, which has 1 to approx

6 carbon atoms, and x equals the average number of x groups (20), y groups (B2O) and 7 groups (220) means from 1 to about 30. More preferably, B! means independently ethylene or propyl, BZ means hydrogen or a linear or branched alkyl group, which is either methyl, and x and y are independently equal to about 12 to about 22 carbon atoms of 1 to about 30. Even more , P: in each of x groups (B2O) means independently preferably, B' means hydrogen or linear or ethylene or propyl, C means linear or branched alkynyl, aryl or aralkyl branched alkylene or alkenylene group, which group that has from about 8 to about 22 has from 2 to about 6 carbon atoms, B" and 5 carbon atoms, EC? in each of the x groups (B2O), the u groups are each independently hydrogen, methyl or (B2O) and 2 of groups (220) independently means ethylene or tris(hydroxymethyl)methyl, and x equals middle propyl, EZ means hydrogen or methyl, and x and in an even number from about 2 to about 30. They even independently mean a number from 1 to - more preferably, B! means linear or branched 5. Preferable commercially available dialcogen alkyl group having from about 12 to silated amines include Tguteep"m 6617 about 18 carbon atoms, P2 in each of the x groups (from Sodpi5), TAM 45, 60, 80 and 105 (from Umyso) and (820) means independently ethylene or propyl, C ESHoteep'm C/12, C/15, C/20, C/25, T/12, T/12, T/20 means ethylene, propylene or -2- and T/25 (from Akgo Mobei!). hydroxypropylene group, B and EE? means each- and "m) aminated alkylated alcohols independently of hydrogen or methyl, and x equals the following chemical structure: an average number from about 4 to about , 20. Most preferably, B! means linear or ! ra is a branched alkyl group, which has from about 0. vin nn Ca nn 12 to approximately 18 carbon atoms, P: in each of the x de groups (220) independently means ethylene or propyl,

VAZ means an ethylene, propylene, or 2-hydroxypropylene group, B and E5 mean copper, B", B Ve, ОЙ B? mean, each til and x equal to an average number from about 4 independently, hydrogen, hydrocarbyl. or substituted to about 20 . and hydrocarbyl having from 1 to about 30 atoms (0) of di-carboxylated amines having the form of carbon, or -(B'Z(ВZOМВ; X means -O-, - pu: Оос(0)-, - C(FO-, -M(B!2)C(0)-, -C(OM(B12)-, -8-, - (8/2, 50-, -502- or -M(B2)- ; VZ in each of n groups (VO) and m

I in groups (30) means independently C2-C4 alkylene; VO k-- means hydrogen or linear or branched alkyl

Mo) is a molecular group having from 1 to about 30 atoms

In carbon; n is an average number from 1 to approximately 60; m equals an average number from 1 to approximately 50; P2 and B"1 are each independently "(40) hydrocarbylene or substituted hydrocarbylene, where K! means hydrogen or hydrocarbyl or having from 1 to about 6 carbon atoms; Substituted hydrocarbyl having from 1 to about 30 means hydrocarbylene or substituted hydrocarby- carbon atoms, -А"ЗНА? or -(Н?О)2НАУ, А? in each len having from 2 to about 6 carbon atoms; of x groups (K"O), U groups (PO) and 2 groups (B?O) means B!2 means hydrogen or hydrocarbyl or independently substituted C2-Ca alkylene, BZ means hydrogen or hydrocarbyl having from 1 to about 30 atoms of a linear or branched alkyl group having from carbon; t and 5 are each independently 0 1 to about 22 carbon atoms, K" means Li- or 1; Re means hydrocarbylene or a substituted ninium or branched alkyl group having from hydrocarbylene having from 2 to about 30 atoms- 6 to about 30 carbon atoms, 5 carbon atoms, -С(-МА2)-, -С(8)- or -С(0)-5 4 dori- means a linear or branched alkyl group, denotes a whole number from 0 to 5 ; and EZ is hydrogen having from about 4 to about 15 carbon atoms or hydrocarbyl or substituted hydrocarbyl having carbon, and x, y, and 2 are independently from 1 to about 30 carbon atoms. 40. In this context, the preferred hydrocarbyl (hydrocarbyl texts, preferred hydrocarbyl groups КЕ! signified) groups В, В2, ВУ, Во, Ве, В", В8, ВУ, В and в/2 are hydrogen, linear or branched alkyl, mean linear or branched alkyl (alkyl- linear or branched alkenyl, linear or lene), linear or branched alkene linear (al-branched alkynyl, aryl or aralkyl kenylene), linear or branched alkynyl groups. Mostly, K! means hydrogen, linear or (alkynylene), aryl (arylene) or aralkyl-branched alkynyl, aryl or aralkyl or (aralkylene) groups. a group having from about 1 to about 30 In one embodiment, any of the surface carbon atoms, P" in each of x groups (K"O), in groups of active substances that are amine or quaternary (NAPO) and 2 groups (K"O) means independently Ce2-Ca alkylammonium, described in sections (a)-(y) above, included, C means hydrogen, methyl or ethyl, and x and y are milked into liquid concentrates of glyphosate, other than IRA- compare independently the average number from 1 to glyphosate, such as glyphosate concentrates containing approximately 20. More preferably K' means, for example, gallium-, diammonium-, ammonium-, sodium-, monoethano- day or a linear or branched alkynyl, amine, n-propylamine, methylamine, ethylamine, hecaryl, or aralkyl group having from about 8 to about 25 carbon atoms, K" in each trimethylsulfoniiglyphosate, or their mixtures, which mis-

that stabilizer and at least approximately VAZ means ethylene or propyl, EK" and EZ mean,

Zomas.oo k.e. of glyphosate, more preferably each independently, hydrogen, methyl or less than about 3595, 4095, 4595 or more tris(hydroxymethyl)methyl, and x equals the weight average. or at least approximately Goodbye k.e. m number from about 4 to about 20. Most glyphosate per liter, more preferably at least more preferably, B! means a linear or 370, 380, 390, 400, 410, 420, 430, 440 or 450g branched alkyl group having from about c.e.u./l. 12 to about 18 carbon atoms, P: in each of x

A subclass of such cationic surface groups (220) means independently ethylene or propyl, of the active substances described above, includes BZ means ethylene, P and 25 mean methyl, and x is a monoalkylated amine having the formula: equal to an average number of from about 4 to including about 20. Preferable monoalkylated ami-! : they include PEG-13 or -18-Cia-5 (prosco--(4k0-k--5th) etherpropylamines and PEG-7-, 10-, 15- or 20-Stiv18 dv ( simple) ether propylamines (from Totype) and PEG-13- or -18-Si4-5 (simple) ether dimethylpropylamines and

PEG-10-, 15- or 20- or 25-Siviyl (simple) ether dimethylpropylamine (from Totai) and (42) Bipopistm DOM-550 from Nipiztap. where VE! means hydrogen or hydrocarbyl or quaternary ammonium, sulfonium, and sul- substituted hydrocarbyl having from 1 to about 30 phoxonium are also effective cationic carbon atoms; E2 in each of the x groups (B2O) and in the surfactant groups in the formation (820) means independently C2-Ca4 alkylene; VZ refers to potassium glyphosate concentrates and has the following hydrocarbylene or substituted hydrocarbylene chemical structure: has from 2 to approximately 30 carbon atoms; R and B in? GU means, each independently, hydrogen, hydrocarbyl or substituted hydrocarbyl having from 1 to approximately 30 carbon atoms, -(BU(82O)uB" or P" and

B", together with the nitrogen atom to which they are attached, and I form a cyclic or heterocyclic ring; 5 83) means hydrocarbylene or substituted hydrocarby- or : ; lene having from 1 to 30 carbon atoms; B" means hydrogen or a linear or branched alkyl group (Be K-H group having from 1 to approximately 4 carbon atoms, and this, n means 0 or 1, x and y are equal independently of d" in an average number of from 1 to about 60. In this context, preferred hydrocarbyl (hydrocarbylene) groups EB", BZ, B" and 5 mean linear or "88) branched alkyl (alkylene), linear or or branched alkenyl (alkenylene), linear or branched alkynyl (alkynylene), aryl (arylene) or aralkyl (aralkylene) virgin field "0 - (MVV --k group. Mostly, B! means linear or a branched alkyl or linear or branched alkenyl group having from about 8 to about 25 carbon atoms, B? in each of the x groups (20) (45) independently means C2-C alkylene, BZ3 means "a linear or branched alkylene group having or . . . 9) from 2 to about 20 carbon atoms, B? and 85 in? B are each independently hydrogen or a linear or branched alkyl group having from 1 to approximately 6 carbon atoms, and x is an average number from 1 to about 30. More preferably, B ! means a linear or branched alkyl . group having from about 12 to about 22 , (6) carbon atoms, P? in each of x groups (20) means where P" BA", BB, B, B Her B" means independently ethylene or propyl, B3 is independently a linear hydrogen, hydrocarbyl or substituted hydrocarbyl or branched alkylene group having from 2 to rocarbyl having from 1 to about 30 carbon atoms, B/ and B5 are carbon, or -(NZ)5(AZO)UA?; X means -O-, -

Each independently, hydrogen, methyl or Оос(0)-, -Ш(А")С(0)-, -С(О)М(НУ-, -С(0)О- or -5-; tris( hydroxymethyl)methyl, and x equals the average VAZ in each of n groups (PO) and m groups (KO) means a mu number from about 2 to about 30. Even independently C2-Ca alkylene; B" means hydrogen or even more preferably , B! means a linear or linear or branched alkyl group having from a branched alkyl group having from about 1 to about 30 carbon atoms; n is from 12 to about 18 carbon atoms, P in each of x is an average number from 1 to about 60; m doriv groups (820) means independently ethylene or propyl, having an average number from 1 to about 50; P? and

BZ are, each independently, hydrocarbylene amines (eg, ethoxylated quaternary or substituted hydrocarbylene having from 1 to priamines or propoxylated quaternary amines); about 6 carbon atoms; t and 5 are each alkylamine acetates, such as tallowamine acetate or independently, 0 or 1; PE" means hydrocarbylene or octylamine acetate; and amine oxides, such as ethoxy-substituted hydrocarbylene having from 2 to proximate amine oxides (eg, / M,M-bis(2- zno 6 carbon atoms; U means hydrocarbylene hydroxyethyl)ucoaminooxide ), non-ethoxylated or substituted hydrocarbylene having from 2 to pri-amino oxides (for example, cetyldimethylamino-about 30 carbon atoms, -С(-МВ2)-, -С(5)- or -oxide) and amidoaminooxides.

C(O)-; B" means hydrogen or hydrocarbyl or substituted hydrocarbyl cationic surfactants having from 1 to about 30 substances include amines and quaternary carbon atoms; 4 is equal to a whole number from 0 to amines substituted by alkoxy groups containing approx. 5; B? means hydrogen or hydrocarbyl or substituted 2-15 ethoxy- and/or propoxy units, and C12-18 hydrocarbyl having from 1 to about 30 alkyl groups. More preferred are C2-18 carbon atoms; and each A" means acceptable in dialkylated amines and quaternary amines. Another anion to agriculture. In this context, more preferred are diethoxylated thalamines, preferably hydrocarbyl (hydrocarbylene) groups containing from about 4 to about 15 units

V, r, VU, V, Ve, V, Ve. VU, VO. B, BZ Its B1a sign- ethoxylation, and PEG-(2-20)-thaloammonium chlorides, including linear or branched alkyl (alkylene- which do not necessarily contain a methyl group. Naive), linear or branched alkenyl (alkenyl- more preferred Commercially available dialkoxy-new), linear or branched alkynyl fused amines include Tuuteep"mM 6617 (alkynylene), aryl (arylene) or aralkyl (from Sodpis), TAM 45, 60, 80 and 105 (from M/iso) and well (aralkylene) groups.

Another cationic surfactant and T/25 (from Ak2o Mowbray). The most preferred surfactants effective in the compositions of this extract-active substances that contain a di- carboxyl addition are a diamine or diammonium salt having quaternary ammonium, include sludge: EShodadtm C12, C15, T25 (from AK»o Morea) and Etsoi

В-ВО MI (НВ, Сб-42 | 00-55 (from SK UMyso). Other suitable cationogenic surfactants can be determined by specialists with qualifications in this field by routine experimentation. (47) The compositions of this of the invention are stable at or under loads, i.e. glyphosate: a cationic surface-active substance, calculated by mass, from about 12 to about 2001. High hopes (Woody (WTO B, loading Glyphosate: a cationic surface-active substance is usually limited by considerations - where in; (8) We are herbicidal efficiency, not the stability of the composition, because for adequate activation, see P", A", AB, Av, A" and EZ mean independently of phosate must be present sufficient hydrogen or hydrocarbyl or substituted hydrocarbyl, the quality of the surfactant. A high nava- having from 1 to about 30 carbon atoms, K? in the concentration of the surfactant usually each of the t groups (KO) and n groups (KO) and KU mean that the stabilizer is required to be turned on independently preferred C2-Са alkylene, EZ means hydrocarbylene ratio cationogenic surface-active or substituted hydrocarbylene, having from approx. ?O)pAv-, t and n are equal, each independently, Nonionic surface-active substances for the average number from 0 to approximately 50 and p dorov- use in the preparation of herbicide compounds the average number from 0 to approximately 60. In this and concentrates of this invention include, in this context, hydrocarbyl (hydrocarbylene) themselves: groups P", AU, A", AB, AE, BA" and 8 mean linear (a) alkylated alcohols having the form or branched alkyl (alkylene), linear or lu: branched alkenyl (alkenylene), linear ! 2 with or a branched alkynyl (alkynylene), aryl-co-- z - -t-ohk nu (arylene) or aralkyl (aralkylene) group. In one variant of formula (44), EZ means ; hydrocarbylene having from about 2 to about (49) 6 carbon atoms, and the other groups are the same as described in B! means hydrocarbyl or substituted worthy above. , , , rocarbyl having from 1 to about 30 atoms

Some preferred cationic surface carbon, BC? in each of the x groups (B?O) means the active substances include ethoxylates independently of C2-Ca alkylene, RZ means hydrogen or alkylamines (including etheramines and diamines), such a linear or branched alkyl group, which has as an ethoxylate of tallowamine , ethoxylate of cocoamine, 1 to about 4 carbon atoms, and x equals se- ethoxylate of etheramine, ethoxylate of thalloethylenediamide- an average number from 1 to about 60. In this, well, And! ethoxylates of amidoamines; quaternary ammonium contexts, predominant hydrocarbyl groups B! alkylamine derivatives, such as alkylated quaternary linear or branched alkyl, linear or branched alkenyl, linear or branched or linear or branched alkenylene group, alkynyl, aryl or aralkyl groups. Predominantly having from about 8 to about 18 atoms, B! represents a linear or branched alkyl carbon, and x and y are independently an average or linear or branched alkenyl group having from 1 to about 10. Even more having from about 8 to about 30 carbon atoms, B! means hydrogen, P? in each of x groups of leucine, B: in each of x groups (220) means independent (820) and in groups (220) means independently ethylene or but C2-Ca alkylene, BZ means hydrogen, methyl or propyl, BZ means linear or branched alkyl-ethyl, and x is an average number of from about kylene group having from about 8 to about 50. More preferably, E' means up to 18 carbon atoms, and x and y are linear or branched alkyl groups, having from independently an average number of from 1 to about 8 to about 25 carbon atoms, P? in 5. each of the x groups (820) independently means ethylene (c) alkoxylated dialkylphenols having either propyl, KE means hydrogen or methyl, and x gives the formula: gives an average number from about 8 to about 40. Even more preferably, E!' means a linear or branched alkyl group having from about 12 to about 22 carbon atoms, 2 in each of the x groups (220) independently means ethylene or propyl, BZ means hydrogen or methyl, and x equals the average number from about 8 to about 30. Preferred commercially available alkylated alcohols include: Ethylenediamine, 4

Rgoso! them | A-15 (from Rgoiateep); Vgi) "m 35, Vgi) m 56, V

Vgi) "m 76, Vgi)"m 78, Vgi) m 97, Vgi) m 98 and Tegoyo! tm HO (from bidta SPetisai5 So.) Meodoitm 25-12 and (3,8

Meodoitm 45-13 (from ZPPeia); Ppeiho!"M CA-10, peioho! im SA-20, peioho! im C5-9, peioho! M C5-15, peiohoi im 25-20, peioho! M C5-25, peioho! im C5-30,

Risgaiastm AZ8 and Risgagastm I E700 (from VABE); 51- and (1) 8303 (from Sodpiv); Agoz!ygi"m 66 E10 and Agozyg"m 66 where V! and B" independently stand for hydrogen or

E20 (from Umiso/Stotriop); ethoxylated (9,4 linear or branched alkyl group having from

EO)-talo, propoxylated (4,4 EO)-talo and 1 to about 30 carbon atoms, and at least alkoxylated (5-16 BO and 2-5 PO)-talo (from one of P! and P: means an alkyl group , P2 in each of

Myso/Stotrup). x groups (BO) means independently Co-Ca alkylene, BZ (B) dialkylated alcohols having the for- means hydrogen or a linear or branched alkyl group: a group having from 1 to approximately 4 atoms of uchov, o 8-0 -- (OB of carbon, and x is an average number from 1 to about 60. Preferably, B" and B" are independently linear or branched alkyl groups having from 8 to about 30 carbon atoms, P? in each of x of groups (220) is independently C2-C4 (50) alkylene, EZ is hydrogen, methyl or ethyl, and x where B' is independently hydrogen or linear is equal to the mean number from about C to or a branched alkyl group having from 1 to about 50. More preferably, Kkk and . mean approximately 4 carbon atoms, B in each of the x groups independently linear or branched alkyl groups, (B2O) and in groups (220) means independently Co-Ca alkyl having from approximately 8 to approximately 22 lene atoms, BZ means hydrocarbylene or substituted hydrogen carbon, K" in each of the x groups (KO) means non-zorocarbylene, which has is from 2 to about 30 atoms of either ethylene or propyl, KZ is hydrogen or carbon, and x and y are independently the average methyl and x is the average number from about 1 to about 60. In this context, but 8 to about 40 . Even more preferably, preferred hydrocarbylene groups ВЗ mean Вб A mean independently linear or branched- linear or branched alkylene, linear or branched alkyl groups having ВД about 8 to branched alkenylene, linear or branched- about 16 carbon atoms, K" in each of x groups, alkynylene, arylene or aralkylene (Y'O) means independently ethylene or propyl, K group. Mostly, V! means hydrogen, methyl or means hydrogen or methyl and x is middle ethyl, P2 in each of the x groups (220) and in the groups (20) is a number from about 10 to about 30. C2-Ca alkylene independently , BZ means a linear important commercially available alkoxylated dialkyl or branched alkylene or linear or branched phenols include ttoxylated tinned alkenylene group having from about dinonylphenols such as Zipopis CMP 100.8 to about 25 carbon atoms, and x and y equal to - Zyipopist OMR 140 and Z,ypopis?" OMR 240 (from independently the average number from about 1 Nipietate, , to about 20. More preferably, B! means Other suitable nonionic surface-active hydrogen or methyl, BK? in each of x groups (BO) and y substances include alkylpolyglucosides; group (220) means independently ethylene or propyl, glycerol esters, such as glycine monolaurate

BZ means linear or branched alkylene ryne, and ethoxylated glyceryl monococoate; etok-

fortified castor oil; ethoxylated complex vB' are esters of reduced sugars, such as monolaurate poly-A v? in oxyethylene sorbitol; complex esters of other polyatomic |! and many alcohols, such as sorbitan monolaurate and sucrose mono-d/-A-5 Kc stearate; ethoxylated amides such as /polyoxyethylenecocoamide; ethoxylated complex de d---(vgouv! ethers, such as polyethylene glycol monolaurate 1000 sh and polyethylene glycol dilaurate 6000; ethoxylated alkyl- or arylphenols, such as noni- - (53) phenol ethoxylate, octylphenol ethoxylates, or dodecylphenol ethoxylates, dinonylphenol ethoxylates ( and ethoxylates of tristyrylphenol; ethoxylates of alcohols, such as ethoxylates of fatty alcohols (for example, ethoxylate of oleyl alcohol), ethoxylates of tridecyl alcohol, and ethoxylates of other alcohols, such as

Meodoi, and ethoxylates of oxoalcohols (ketoalcohols); and 0-8 2х8 copolymers of ethylene oxide and propylene oxide, such as Riogopis-type, Teigopis-type, or (54) Tegoyo-type copolymers! Khn. or

Additional nonionic surface-active substances for inclusion in the composition of surface-active substances, which can be (WTO (VY uh Y; used in this invention), are polyoxyethylene- and 'in (5-30)-Cv-alkyl esters and polyoxyethylene-(5-30)-Sv-1-alkylphenyl ethers, where "(5-30)" means that the average number of ethylene oxide units in the polyoxyethylene or lene chains of these surface-active in general, the value is from about 5 to about 30. And with |:

Examples of such nonionic surface-active BA substances include polyoxyethylene-| and nonylphenols, -octanols, -decanols and - Day nn (VIH and trimethylnonanols. Specific nonionic surfactants that have been shown to be useful include MEOBOY 91-6 from ZPPEI (polyoxyethylene-(6)-Si-1 linear primary alcohol), MEOBO/ tm 1-7 from ZPEI! (polyoxyethylene-(7)-Si linear primary alcohol), TEVSITOY "m 15-" B8) 5-9 from Opiop Sagride (polyoxyethylene-(9)-C12-15 or secondary alcohol) and ZIOCHROMISTM MPO5 from cats in

Nipiztap (polyoxyethylene-(9,5)-nonylphenol). | let

Preferable nonionic surfactants include alkylated alcohols, and containing from about 5 to about 25 ethoxy- and propoxy groups and Sti2 alkyl groups More preferred are from about 10 to about 20 C 7) alkylated alcohols. Non-limiting examples include the commercially available products Etpidip-I, Agozygi 66, and Rishgaias P700. Other suitable nonionic surfactants - Visn (In VC. we can be determined by specialists with qualifications in this area by routine experimentation. ov

Other surface-active substances for use in herbicide compositions and concentrates of this invention include compounds of the formula "058" Я. ARO)RA!Z; BZ and B"" mean independently linear v. dune All | v or branched alkyl or alkenyl groups, ; Shen having from 1 to about 22 carbon atoms, Vyov-- and V--chvou or -(B2O)RVZ, B2 in each of t groups (20), n groups

Y (820), p groups (820) and 4 groups (820) means independently ethylene or propyl; EZ stands for hydrogen

And or methyl; BK" means -(СНег)УуОВ!З or - - (8558) (СНуд(В?О)48З; ВВ, В", В!" mean independently where В", В? and В! mean independently hydrocarbon hydrogen, linear or branched alkyl or albyl or substituted hydrocarbyl having from 1 to kenyl groups having from 1 to about 22 about 30 carbon atoms, or -(B2O)РВ"Z; B? in carbon atoms; K A its Kk means independently each of t groups (B2O), n groups (BO), p groups (BO) and d hydrogen or linear or branched alkyl or groups (220) means independently C2-Ca4 alkylene; RU, alkenyl group having 1 to about 22

ВВ, В, ВЗ Its vh means independently hydrogen or carbon atoms, or kA means linear or hydrocarbyl or substituted hydrocarbyl having from a branched alkylene or alkenylene group, 1 to about 30 carbon atoms; B? means - having from 2 to about 6 carbon atoms; Kk (CHgUOV!Z or -(CHgUO(H2O)482; B5, Be and B7 denote hydrogen or linear or branched alkyl independently hydrogen, hydrocarbyl or substituted or alkenyl groups having from about 6th hydrocarbyl, which has from 1 to about 30 to about 22 carbon atoms, and means li- carbon atoms, or B"; B" means hydrocarbylene or branched alkyl or alkylene or substituted hydrocarbylene having from 2 to 1 to about 22 carbon atoms: about 30 carbon atoms; B/? is hydrogen, this, or "(CHg)2O(AMO) PAX; t, n, p, and a are non-hydrocarbyl or substituted hydrocarbyl having from X оon the middle pole I to about I 1 to about 30 carbon atoms, or - means independently М И (0), КО), (СНг)2О(А2О)РАЗ; t, n, r and d are independently equal to -ob(оу, KA (0), "(om )" B", -30- or Y of an average number from 1 to approximately 50; X means - ZO2-, and is equal to 0 or 1; A / means acceptable in tea regardless of -O-, - М(В'З-, -С(0)-, -С(Ф)О-, - to the agriculturist your anion; and her 7 mean

ОС(О)-, М(В'5)С(0)-, -С(ОМ(В'5)-, -8-, -80- or - independently an integer from О to approximately 10. The most 50 "-; And is 0 or 1; A means acceptable in more preferably, Kk means a linear or agriculture anion; and y and 72 mean a branched alkyl or alkenyl group that is independently an integer from 0 to about 30. Y have from about 12 up to about 18 atoms in this context, the preferred hydrocarbyl (hydrocarbon, or "ON OrA7; A and k means rbylene) groups P", BZ and B5-VI5 mean linear independently linear or branched alkyl or or branched alkyl (alkylene), linear or alkenyl groups having from ! to approximately 6 branched alkenyl (alkenylene), linear ruthenium atoms, or , p groups (K o) h groups (GO) nu (arylene) or aralkyl (aralkylene) independently means ethylene or propyl; E means groups. Mostly, B", BZ and B? mean independent hydrogen; D And with Means and ЕNeon or - a linear or branched alkyl or alkenyl- (cngud(HO) and "vv" mean independent groups having from 1 to about 22 hydrogen atoms, a linear or branched alkyl or alkenyl- carbon, or -(B2O )РВ!2; B? in each of the t groups a kenyl group having from 1 to approximately 6 (B2O), n groups (220), p groups (B2O) and a groups (20) of carbon atoms; ER, A Her KE means independently means independently C2-Ca4 alkylene; BZ means hydrogen or linear or branched alkyl or day, methyl or ethyl; B" means -"CH2UOB" or - alkenyl group having from 1 to about 22 (CHgUO(B2O ) "BZ; B, Bé | B are independently carbon atoms, or kavi means a linear or hydrogen, linear or branched alkyl or al-branched alkylene or alkenylene GROUP, kenyl group having from 1 to about 22 having from 2 to about 6 carbon atoms; K carbon atoms, or B; B8, B!!, BZ and B'x5 mean means hydrogen or linear or branched independently hydrogen or linear or di a branched alkyl or alkenyl group having from about or an alkenyl group having from 1 to about 6 to about 22 carbon atoms, Kk means about 22 carbon atoms; WO means a linear or linear or branched alkyl or alkenyl branched alkylene or alkenylene group, a group having from 1 to about 22 carbon atoms: having from 2 to about 18 carbon atoms; B'- this, or -(СНг)гО(АО) А; t, p, r i a are equal means a linear or branched alkyl or al- regardless of the average number of from 1 to about kenyl group, having from 1 to about 22 atoms- ХХ means regardless of -0- or ШЧА )- І carbon atoms , or -(CHg)2O(В?О)РВЗ; t, Пп, р and д gives 0 or 1; A means anion acceptable in rural areas regardless of the average number from 71 to the economy, and in !i 2 means independently approximately 30; X means independently -O-, -M(B4)-, - an integer from 1 to approximately 3.

С(О-, -с(Ф)0-, -ОС(О)-, -Щ(А)С(0)-, -ФЩКОМ(В)-, Fluorine wetting agents (surface- -5-, -90 - or -505-, i is equal to 0 or 1; A" means active) agents applicable in this anion acceptable in agriculture; and in and 7 findings, there are organic molecules represented by the form- mean independently an integer from 0 to approx. 30. More preferably, B' means a linear or heavy, and - (60) a branched alkyl or alkenyl group, where Px means a fluoroaliphatic radical, and b means a group that contains at least one hydrophilic group, such as a cationic and nonionic !І groups. Ri means a fluorinated, monovalent (| snuy aliphatic organic radical containing at least four carbon atoms each. Preferably, it | ! is a saturated perfluoroaliphatic ! /-o monovalent organic radical. However, as per - HAP substituents of the chain of the molecular skeleton can be hydrogen and chlorine atoms present in it U 0--K. Although radicals containing a large number of carbon atoms, can act adequately, compounds containing no more than 1 carbon atoms are preferable, since large | E radicals usually represent a less effective and efficient utilization of fluorine than, perhaps, radicals with Ash shen p and shorter chains of the molecular skeleton. I would

Predominantly, Re contains approximately 5-14 carbon atoms, or a few elements. Cationogenic groups that are applicable in the fluorophores in this invention may include a branched or straight chain that is preferably cationic an amine or quaternary amino group having from 4 to 18 carbon atoms, or an alkylnium mixture. Such cationic hydrophilic amine groups or their groups, having an average value within the limits of quaternary ammonium can have the following formulas, the specified range. The number of glucose groups per alk such as МН», МНА?, -М(Б2)», (МН, -(МНоВХ, - ring group) can vary, and possible derivatives (МН(Б2)2Х) or -(М(Б2) cX, where X represents an anionogen- alkylmono- or di- or polyglucose or saccharides. ny counterion, such as a halide, hydroxide, sul- Commercial alkylpolyglycosides usually contain phate, bisulfate, acetate or carboxylate, and each a mixture of derivatives, where n is expressed as

B2 independently means a C-1 alkyl group. Per- average value. Preferably, n is from 1, X is a halide, hydroxide, or bisulphate to about 5, and more preferably from 1 to a phate. Predominantly, cationic organofluorine lyzno 3. A characteristic alkylglycoside is a product, the wetting agents used in the given 2042 p a ste ne aetee ris name of the invention contain hydrophilic groups that are catio- 042 (Itregia etisa | p pope ), where p nogenic groups of quaternary ammonium. Non-ionic - equal to the average value of 1.7 1 M is a mixture of gene groups that are applicable in organofluorine octyl (4575) and decyl (5576), the product, commercially wetting agents used in this invention, available under the trade name ASKIMOY-RZ2069, include in self-groups, which are (Nepkei Sogr), where n is equal to the average value, hydrophilic, but under the conditions of the pH of ordinary sulfonyl (2076), decyl (4095) and economic applications, they do not ionize. undecyl (40965), and the product is commercially available

Nonionic groups can have such formulas as - under the trade name VEKOG. AOb202 (AKgo More),

О(СНеСН»)ХН, where x is greater than zero, preferably 1-30, - which is 2-ethyl-1-hexylglycoside. 5bMng, 502МНСНеСНеОН, 502М (СНеСНоН)", - In one variant of this invention, herbicides

СОМН", -СОМНОНеСН»ОН or -ОМ (СНеСНоОН)». compositions include at least one

Several organofluorine wetting agents, neonogenic surfactant! that are suitable for use in this invention, there is at least one cationic surfactant available from ZM under the trade name Riyogai. substance, for example, such as described here. Such com-

They include nonionic agents Richogai bination of surface-active substances are described in

ES-170C, Eishogai ES-171 and Gishogai ES-430 (I(US patents with numbers 6245713 and 59983321, which

Additional cationic surfactants are incorporated herein by reference in their entirety. active substances suitable for use Preferably, the weight ratio of cationization in the herbicidal compositions of this invention, gen:neonogenic surfactant are surfactants described in (patent) is from about 20:1 to about 171, and tach US Nos. 5703015, 5750468, 5389598, more preferably from about 10:1 to about 5563111, 5622911, 5849663, 5863909, 5985794, 0Ш0Ш/171. In high glyphosate loading forms, 6030923 and 6093679 stable microemulsions are incorporated herein by reference. can be obtained at

Cationogenic organofluorine surface-active loads k.e. Glyphosate: Total surfactants applicable here include active substance, by weight, approx.

Eimogai ES-750 and other surfactants - from 1:3 to approximately 100:1. As in the variants that we, such as, for example, described in (US patents containing only cationic surfactant numbers 2764602, 2764603, 3147064 and 4069158). substances, high ratios of glypho-

Apkylpolyglycosides are also suitable for sat: the surfactant is usually limited to the use in compositions and concentrates of this chewed rather by considerations of the herbicidal efficacy of the invention and is described, for example, in (U.S. patent on tivity than the stability of the composition, because for the number 6117820). In this context, the term "al- ensuring the possibility of an adequate herbicidal kylglycoside" includes mono- and polyalkylglyco- action of glyphosate surface-active substance povin-zide. Glycosides are represented by the formula: to be present in sufficient quantity. A high load of surface-active substance

Tea requires the inclusion of a stabilizer in the majority of microemulsions of this invention can be added to the weight ratio of the total surface other components, such as solvents and organic non-active substance: stabilizer from approximately acid. These admixtures usually work by increasing the 1:50 to about 50:1. solubility or dispersibility of surface

The surface-active component of this wine - active substances in the phase of the aqueous carrier, for sure contains any combination of surfactants, allowing the preparation of strong microemulsion-active substances and stabilizers, such as emulsions, which show increased heat resistance and a higher pH. This composition of surface-active stability, reduced viscosity and high load is particularly preferable for the application of glyphosate. in the preparation of compositions and concentrates that can be added to these compositions containing potassium, diammonium, ammonium, sodium, monoenes to increase solubility or dispersed ethanolamine, n-propylamine, methylamine, ethylamine -, the presence of surface-active substances in the aqueous phase of hexamethylenediamine-, dimethylamine- and/or trimethine, etc. obtaining the appropriate stability of myclsulfonyglyphosate. In a composition or concentrated emulsion. Water-soluble solvents can be ration containing any combination of these salts added to increase the solubility of surfactant glyphosate, a composition of surfactants with a hydrophilic part of milk-active substances can be included. spheres in the aqueous phase. Non-limiting examples

The density of any glyphosate-containing form of the water-soluble solvents included in the present invention is preferably, namely, acetates, C-e alkanols, C-e diols, C-e alkyls and more preferably at least 1.3 g/l, more preferably at least alkylene glycol ethers and polyalkylene glycols and their ZNO 1.305, 1.310, 1.315, 1.320, 1.325, 1.330, 1.335, mixtures. The alkanol can be selected from methanol, 1.340, 1.345, 1.350, 1.355, 1.360, 1.365, 1.370, ethanol, n-propanol, isopropanol, various isomers- 1.375, 1.380, 1.385, 1.390, 1.395, 1.400, 1.405, butanol, pentanol and hexanol and their 1.410, 1.415, 1.420, 1.425, 1.430, 1.435, 1.440, 1.445 mixtures. You can also use, along with vka- or 1.450g/l. with or instead of alkanols, diols such as

The surface-active component of the methylene-, ethylene-, propylene-, or butylene glycol compositions of this invention may optionally contain glycol mixtures, including polyalkylene glycols. Kol or glycol ether of the formula: can also be used mixtures of hydrophobic and hyd-

НО-(ВО)хХ-ВУ, (62) rophilic solvents. where B" in each of the x groups (BO) means an independent It is preferable to limit the total number of linear or branched Cg-is alkylene group, x factor in the number of no more than about 2595, and is equal to from 1 to about 4 and EE? means hydrogen is more preferably not more than about 1595 from or a C1-Ca hydrocarbyl group. Glycols and glycol ethers of the entire composition. Particularly preferred ranges of glycols under consideration include, but the nom is about 0-1595. If any of of these or not limited to them, monoethylene glycol, dietetic solvents have a solubility less than lenglycol, propylene glycol or their methyl, 25905, in water (at room temperature, 2170), then ethyl, n-propyl, n-butyl or tert- quantity of such solvents with limited solubility - butyl ethers, dipropylene glycol or its place in water should not exceed approximately tyl, ethyl, n-propyl, n-butyl or 596, and the amount of water-soluble solvents tert-butyl ethers, tripropyl nglycol or (such as ethanol) is increased in this case to its methyl, ethyl, n-propyl, n- amount sufficient to maintain microemul- butyl or tert-butyl ethers, 1,3- sion. These amounts of solvents are usually called butanediol, 1,4-butanediol, 2-methyl-1,3-propanediol, effective for dispersing or solubilizing 2,2-dimethyl-1,3-propanediol, 2-methyl-1,3- amounts. pentanediol and 2-methyl-2,4-pentanediol. To increase the stability of the microemulsion, organic acids can be added to glycols having 4 or more carbon atoms. Among them, 2-methyl-1,3-lots are more preferred. The authors of the invention believe that without binding propanediol and 1,4-butanediol. himself with any specific theory that organizes

In the present invention, the microemulsion is defined as acids or their corresponding salts are stabilized as a liquid system in which the surface-active microemulsion with a high loading of two components is dispersed in continuous water by various mechanisms. First, hydrophilic and hydro- liquid phase containing dissolved glyphosate salt. hydrophobic parts of these acids act as binding agents

For the formation and maintenance of a microemulsion, an organic solvent is used between the phase of the aqueous carrier and the nonionic ones, which in fact are not the walls of surface-active substances. Secondly, mixed with water, the acids of this invention act as buffers, thus stabilizing the appropriate stability of this microemulsion. according to the pH of the composition. Corresponding organic acids

Microemulsions of this invention are physically stable - include, among others, acetic, dichloroacetic liquid systems, which are also stable tova, lemon, malic, oxalic, salicylic and during storage. They are optically transparent in the presence of citric acid. Effective organic concentrations at room temperature and are isotropic. They form acids between approximately 0.95% by weight and with careful mixing of the ingredients and not 5% by weight. require shear deformation or other addition of energy to increase microemulsion stability. The order of addition of ingredients that are not compositions of this invention may be added is a crucial aspect of this invention. other impurities, including inorganic acids and

To increase the stability of microemulsions to oxidizing agents. Non-limiting examples include boric acid, perchloric acid worldwide. Similarly, the lot, phosphoric acid, sulfuric acid compositions of the present invention, containing glyphosate salt, hydrogen moside, lithium perchlorate, sodium phosphate, should be applied to any and all types of sodium rat and sodium iodide . plants on which glyphosate is biologically effective.

This invention also includes a method. Thus, for example, the compositions of this invention for the destruction or suppression of weeds or weeds, containing glyphosate as a herbicidally active plant, which involves the stage of dilution of the ingredient, can be applied to plants in liquid concentrate in an appropriate amount of a herbicidally effective amount and can be effectively watered to obtain a tank mixture that suppresses one or more types of plants used to apply the mixture, and on one or more of the following genera without mixing a herbicidally effective amount of this mixture : Arshiyop, Atagapipy5, Apetivzia, Azsieriav, reservoir for weed leaves or unwanted growth Amepa, Akhoporiv, Voitepa, Vgasniapa, Vgavzvisa, linnosti. The present invention also relates to sp-Vgotiv, SPeporodiit, Sigviit, Sottveip, sob destruction or suppression of weeds or non-Sopmoimishv5, Supodop, Suregiv, Pidnan, desired vegetation, which involves "stages of Espipospis, Eivizipe, Eg/utiv, Edyizesht, Egodiit, diluting the concentrate of solid particles in Neiiapiyiv, Itregaga, Irotoea, Kosnia, ot, the appropriate amount of water to obtain a mixture for Mayim, Ogul, Onospios, Rapisit, Razraisht, reservoir and applying the herbicidally effective RPaiagiv, Raigadtiiev, Roiudopyt, Ropshias, quantity tank mixture for weed leaves or Riegidipt, Riegapa, Nyriv, Zaivoia, Zeiapa, 5ida, unwanted vegetation. zipari5, Zogapyt, Tgyistst, Turpa, eh, HapipicCht and

In the herbicidal method of applying compo- 7ea. sions of this invention, this composition is diluted Particularly important examples of contemporaneous in the appropriate volume of water to ensure broad-leaved species for which a layer is used for application, which is then applied to the leaves of the glyphosate composition, are, without limitation, the following: plants or plants at the rate application, sufficient for the desired herbicidal effect. This norm is white (Atagapipyv5 5yr.), biopugey (Voitegia 5yr.), the application is usually expressed in the form of several canola (rapeseed), canola (rutabaga), Indian mustard and hundred glyphosate per unit of cultivated area, etc. (Vgazvzisa 5yr.), comelina (Sotteiypa 5yr.), for example, in grams k.e. per hectare, (g c.e./ha). Zvygrabelki (Egodisht 5yr.), sunflower (NeiYiapitiv5 tea and as an illustration, "desirable herbicidal action" 5yr.), morning glory (Irotoea 5yr.), kohia (Kospia is at least 85905 protection of plant species that vimi- zsoraghia), madva (Mother, 5 years old), birch buckwheat, ruts due to reduced growth or mortality - pepper fungus, etc. (Roiudopyt 5yr.), purslane after a period of time during which glyphosate was (Rogpsiasa 5yr.), Russian kurai (potash cou- shows its full herbicidal or phytotoxic effects in paradise) (Zaizoia 5yr.), brisket (5ida 5yr. .), mustard in processed plants. Depending on the type of rospolov (5bipariz5 aguepzi5) and netreba (Hapipiyt flax and growing conditions, this period of time can vary. be as short as a week, but usually Particularly important examples of the same-years require a period of at least two weeks for narrow-leaved species for which glyphosate is used to show its full effect. positions of glyphosate, are, without limitation, the following: viv-

The choice of application norms, which are herbicide efexyug (Amepa Taisha), axononus (Achoporyv5 yr.), appropriate for the composition of this invention, roof colossus (Vgotiv5 yesiogit), eleusin is within the competence of a specialist in rural (Oidyaga 5 yr. .), cock's millet (Espipospioa sgy5- of agriculture. For specialists with qualifications in this field), Indian eleusine (Eili5ipe ipais), ryegrass of the region it will also be clear that the states of individual pasture (GG oiisht tiyShogit), rice (Ogula 5aiima), plants, weather conditions and cultivation conditions - otochloa (Oyospioa podosa), paspalum (RazraYit nya, as well as specific active ingredients and their vago-poiasht), Canary grass Canary (RPaiagi5v ratios will affect the rate of vrr.), mousey (Zeiagia b5rr .), wheat (Tyysit of herbicidal efficiency obtained from aesiimite) and corn (7ea taub5). application of this invention in practice. Especially important examples are the use of glyphosate compositions, there are broad-leaved species for which a large amount of information is used regarding the corresponding glyphosate compositions, there are, without limitation, the following: application rates. For more than two decades, the use of wormwood (Apetivzia 5 yr.), cottonwood (Ausieria 5 yr.), glyphosate treatment and published studies that thistle (Sigisht aguepbe), field birch belong to this application, gave rich information from which a specialist in weed control (Riegapia spp.) can choose application rates. - compositions of glyphosate, are, without limitation, the following: specific environmental conditions. brachiaria (Vgaspiagia 5rr.), pig's-fingered

The method of this invention, in which the water-soluble (Supodop aasiuyup), chufa (Suregi5 ezsshepiiv), the herbicide is glyphosate, more specifically, osmikavets (S. goishpdy5), wheatgrass (EIutiv5 herepv), pre-soluble salt of glyphosate, applicable to any imperata (Itregaia suiipagisa), perennial ryegrass and all types of plants, in relation to which glyphoni (Hoiisht regeppe), large millet (Rapisit sat is biologically effective as a herbicide. It includes tachytite), paspalum expanded (Razrait tea in itself a very large variety of species of ros-ayasgasht), reed (Ripgadtyevz 5yr.), johnson grass (Zogdpyt paierepze) and rush (Turpa 5yr.). are given exclusively from the elements carbon and hydrogen. These

Other particularly important examples of basic molecules include alkylene, alkylene species, for which componylene, alkynylene, and arylene are used. These parts of the glyphosate molecules are, without limitation, the following: horsetail also includes groups of alkyl, alkenyl, alkyl- (Ediyezest 5yr.), common eagle (Riegiaint nil and aryl, replaced by other aliphatic or cyadiypyt), blackberry ( Kyry5 5yr.) and Ulex (Utesnyk) by callous hydrocarbon groups, such as alka- (Shekh eigorayev). ryl, alkenaryl and alkynaryl. If there are no others

So, for example, the composition of glyphosate of these instructions, these parts of the molecules preferably contain 1- the invention and the method of processing plants with such compounds- 30 carbon atoms. these can be used on any of these "Substituted hydrocarbyl" parts of molecules, species. In the specific method under discussion, described here, are hydrocarbyl parts of the plant treatment composition, which are substituted by at least one atom, by infusing the composition of the present invention in the corresponding than carbon, including parts of the molecules, volume of water for use in the field. In those in which the carbon chain atom is replaced by hete, the composition for plant treatment, which contains glirosate by a rhoatom, such as a nitrogen, oxygen, or silicon atom, is obtained by diluting phosphorus, boron, sulfur, or halogen. These substitutes of the position of this invention in water and this composition for include halogen, heterocyclo, alkoxy, treatment is applied to weeds or unwanted grow- alkenoxy, alkynoxy, aryloxy, hydroxy, protected. hydroxy, ketal, acyl, acyloxy, nitro, amino,

Applying compositions for plant treatment to amido, cyano, thiol, acetal, sulfoxide, complex leaves of plants is mainly carried out by spraying - ether, complex thioether, simple ether, simple yum, using any generally accepted - thioether, hydroxyalkyl, urea, guanidine, amidine , that method for spraying liquids such as phosphate, amine oxide and quaternary ammonium salt. spray tip or atomizer (dis- “Substituted hydrocarbylene” parts of the molecules, atomizer) with a rotating disc (from the dendrite described here, are hydrocarbylene parts mo- atomizer). The compositions of this invention can molecules that are replaced by at least one atom, be used in high-precision methods of processing other than carbon, including parts of the millet of agricultural crops, in which a device for variation is used, in which the atom of the carbon chain is replaced number of exo-heteroatoms, such as nitrogen, oxygen, silicic chemical applied to various nium, phosphorus, boron, sulfur, or halogen. These substitu- parts of the field, depending on variables such as nicks include halogen, heterocyclo, al- specific plant species present, growth stage coke, alkenoxy, alkynoxy, aryloxy, hydroxy, plants, soil moisture status, etc. In one vari- protected hydroxy, ketal, acyl, acyloxy, nitro, anti such methods system of global (generally- amino, amido, cyano, thiol, acetal, sulfoxide, nogo) regulation, which is used spray- ether, complex thioether, simple ether, salivary device, a simple thioether, hydroxyalkyl, urea, guanidine, can be used to apply the desired amount of the composition that amidine, phosphate, amine oxide and quaternary salt is considered, to different parts of the field. ammonium

The plant treatment composition is mainly Unless otherwise indicated, the alkyl groups, diluted enough to be easily spray- described here, are mainly lower alkyl, which can be placed using a standard agricultural- has from one to 18 carbon atoms in the main spraying equipment. From the chain and up to 30 carbon atoms. They can be a straight or branched chain or vary depending on such factors as the type of excipients and include methyl, ethyl, propyl, and the concentration of the active ingredient and subject to isopropyl, n-butyl, isobutyl, hexyl, 2-ethylhexyl and processing species. Applicable norms for applying, etc. of water composition per leaf surface area can be, unless otherwise specified, alkenyl groups are in the range of about 25 to described here is preferably a lower alkenyl that about 1,000 liters per hectare (l/ha), preferably contains from two to 18 of carbon atoms in the main from about 50 to about ZbOl/ha, with a nano-chain and up to 30 carbon atoms. They can hay by spraying. be a straight or branched chain or cy-

The terms "hydrocarbon" and "hydrocarbyl", which are exclamatory and include ethenyl, propenyl, are used herein to describe organic compounds propenyl, butenyl, isobutenyl, hexenyl, etc. or radicals consisting exclusively of eleme- Unless otherwise indicated, alkynyl groups, nts of carbon and hydrogen. These parts of the molecules, including those described here, are mostly lower alkynyl containing alkyl, alkenyl, alkynyl, and aryl groups. These contain from two to 18 carbon atoms in the main part of the molecules, including chain groups and up to 30 carbon atoms. They can be alkyl, alkenyl, alkynyl, and aryl substituted by other ali- be straight or branched chain or cyphatic or cyclic hydrocarbon groups and include ethynyl, propynyl, bu- groups such as alkaryl, alkenaryl, and alkynaryl. tinyl, isobutynyl, hexynyl, etc.

Unless otherwise indicated, these parts of the molecules The term "aryl" as used herein specifically contain 1-30 carbon atoms. mo or as part of another group, means non-

The term "hydrocarbylene", used necessarily substituted homocyclic aromatic here, describes radicals attached at their two ends of groups, preferably monocyclic or bicyclic to other radicals in an organic compound that make up groups containing from 6 to 12 carbon atoms in what-

The term "heteroaromatic" used is substituted phenyl, substituted biphenyl, or is substituted here alone or as part of another naphthyl. A more preferred aryl is phenyl and the group means optionally substituted aromatic substituted phenyl. groups having at least one heteroatom

The term "aralkyl" in this context means at least one ring and preferably 5 or 6 groups containing both alkyl and aryl atoms in each ring. A heteroaromatic group such as benzyl. preferably has 1 or 2 oxygen atoms, 1 or 2 atoms

As used herein, alkyl, alkenyl, alky-sulfur and/or 1-4 nitrogen atoms in the ring and may be ponyl, aryl, and aralkyl may be substituted with less than one carbon atom attached to the rest of the molecule. which differs from a carbon or heteroatom. Examples of heteroaromatic groups, including may be groups in which the groups include furyl, thienyl, pyridyl, octa- carbon chain atom substituted heteroatosazolyl, pyrrolyl, indolyl, quinolinyl or isoquinolinyl and mom, such as nitrogen atom, oxygen, silicon, phospho- etc. Examples of substituents include one ru, boron, sulfur, or halogen. These substituents include one or more of the following groups: hydrocarbyl, substituted hydroxy, nitro, amino, amido, cyano, substituted hydrocarbyl, keto, hydroxy, protected hydrosulfoxide, thiol, complex thioether, simple thioeroxy, acyl . , surface-active substance and/or increase its acetal, complex ether and simple ether. efficiency in potassium glyphosate composition without skin- The term "acyl" used here has an adverse effect on the stability during storage of this com- remo or as part of another group, means positions. part of the molecule formed by removing the hydroxy

The terms "halogen" or "halo", which is a group from the -COOH organic carboxylic acid group, is used here separately or in the form of a part of another acid, for example, BC(O)-, where B means B!, B'Y- group, refer to chlorine, bromine, fluorine and iodine. ; В'В2М- or В!5-, В! means hydrocarbyl, hetero-

Fluorine substituents are often preferred in surface-substituted hydrocarbyl or heterocyclo, and B? cognitively active compounds. is hydrogen, hydrocarbyl or substituted hydrocarbyl.

Unless otherwise indicated, the term "hydroxy- The term "acyloxy" as used herein includes alkyl groups substituted either singly or as part of another group, means at least one hydroxy group, and includes an acyl group as defined above , connected through the oxygen group of bis(hydroxyalkyl)alkyl, tris(hydrogen bond (-0--), for example, KS(O)O-, where K is xyalkylalkyl and poly(hydroxyalkylalkyl). Predominant values are defined in connection with the term hydroxyalkyl groups include hydroxy-"acyl". ) and the "average number" leg with reference to the tris(hydroxymethyl)methyl (-C(CHgOH)z) structure, a characteristic feature such as oxyethylene units or

The term "cyclic" as used herein glucosidic units, a person skilled in the art alone or as part of another group, means in this field should understand that the whole number of a group having at least one closed ring, such units in separate molecules in the drug and includes in itself alicyclic, aromatic (arene) and surfactant usually varies - heterocyclic groups. in a range that may include whole or

The terms “heterocyclo” or “heterocyclic” in sla, greater than the maximum, or less than used herein alone or as part of the minimum “average number”. The presence of a compound group means optionally substituted, complete versions of individual surface-active molecules, which are saturated or unsaturated, monocyclic or bicyclic, having a whole number of such units beyond the indicated cyclic, aromatic or non-aromatic group, of any range in the "average number", does not lead to having at least one heteroatom in each composition within the framework of this invention, as long as it is in one ring and preferably 5 or 6 atoms in the "average number" is within the limits specified for each ring. A heterocyclo group (heterocyclic range, and all other requirements are satisfied. group) preferably has 1 or 2 oxygen atoms, 1 or The term "pesticide" includes chemicals and 2 sulfur atoms and/or 1-4 nitrogen atoms in the ring and may microbial agents, that are used as active be linked to another part of the molecule through insect control product ingredients- carbon or heteroatom. Examples of heterocyclic pests and diseases of crops and lawns, ectoparous groups include heteroaromatic animal pathogens and other pests in public health, such as furyl, thienyl, pyridyl, oxazolyl, pyro- health care. This term also includes lyl, indolyl, quinolinyl or isoquinolinyl, etc., and plant growth regulators, insect repellants, non-aromatic heterocyclic groups such as tetrahy- pests, synergists, herbicide-making agents, tetrafuryl, tetrahydrothienyl, piperidinyl, pyrrolides are safe (which reduce phytotoxicity, etc. Examples of substitutes include herbicides for cultivated plants), and preventive age- one or more of the following groups: hydrocarbyl, nts, when delivered to the target, the actions of the substituted hydrocarbyl, keto, hydroxy, protected by the pesticide to undergo skin and especially hydroxy, acyl, acyloxy, alkoxy, alkenoxy, al- eye tissues. quinoxy, aryloxy, halogen, amido, amino, nitro, The following examples are for illustrative cyano, thiol, thioether, thioether, curative purposes only and are not intended to limit tal, acetal, ester, and ether. scope of this invention. Examples will provide a better understanding of this invention and an understanding of its gala constant under all different norms of exogenous advantages and certain variations of implementation. chemical

The sprayable compositions of these examples The concentrate compositions were tested by placing, in addition to the listed ingredients, dissolving or dispersing in water for fillers, an exogenous chemical such as potassium formation of the sprayable compositions. These salts of glyphosate. The amount of exogenous chemical in sprayable compositions obtained from Birala to ensure the desired rate in grams of concentrates, the concentration of ingredients per hectare (g/ha) when applied in a volume that varied with the concentration of the fillers, 9UZl/ Ha. Several standards of exogenous chemical - exogenous chemical. that was applied for each composition. So, with the exception of - In the following examples that illustrate this set of cases, which are determined especially by the invention, greenhouse and field tests of sprayable compositions were conducted to assess the relative herbicidal effect - the concentration of the exogenous chemical was varied in the composition of glyphosate. Compositions included in direct proportion to the rate of the exogenous chemical, for comparative purposes, can be identi- but the concentration of filler ingredients is collected as follows: wines

Composition 411 41965 by weight of the IRA salt of glyphosate in an aqueous solution, together with surface-active

B substances containing talamine with phosphate ester. This song is for sale

By the Monsanto company under the trade name Koshpdyr Oigat 9,769 ethoxylated thalamines and dipropylene glycol as an active ingredient. This composition is sold by the Monsanto Company under the trade name KoppdirF Oigamah

Various fillers were used in the compositions of these examples. They can be identified as follows: сС1 000 |2-ethylhexylammonio//// ІІ ba 0000 |b-methyllutamate///////І111111111111111111111111 di-C12-di-EO-10-ammonium chloride wine Siv-185 RO ( 3,1) EO (10,4

St. 000 fActovakislotad///::/ |; SSS

Experimental nonionic Siv-iz EO (9,4) PO (2,2) noic acid

Sea5 0 | Bisbsethyleoxylam)y//:/:/OO|І SSS bab 00 | Boranakislota.d//://///І.1777777111111111111111111111

232 |Citric acid.d//-/://./ЇЇ717111111111111111111111 с34 00 |Dituerytriol////Ї71111111111111111111 с36 |Dodecyltrimethylammonium bromide

C37 |Dodecyltrimethylammonium chloride | -':/ОССССССССССС11111111111111с1 с38 |Dodecyltrimethylamd./:///| 77777771. Я17SSSSSSSS11111111111111111 ammonium with IV SG! su Yinyu: SSS

C74 00 |Hexylamn/o/// HER

C75,000 | Hexanol////1Ї7111111111111

Sub 0 | NTMAVS S/G!

C78,000 (Isoproplamno HER 71111111

С80 00 |Perchloratliyu.d////1Ї11111111111111111111 с82 0 |Mabluchnakislota.d////|Ї ССС

C85 | Molroplamno//// ІІ с87 ІМабов///7/7////СЄ1О s88 0 | MuiModimethylhexilamn.o///І 77777711 s89 0 | MuiMdimethylosilamn.o//// ІІ se 000 | Octadedmylamno/// sei 000 fOctilamn/////Ї11111111111111 s93 |Oxalic acid./-:/ ЇІ 77777711 094 |Perchloric acid.d/-:/ | (77777711 p95 | Bromidphenyltlymethylammonium.

Seb 0 | Phosphoric acid. food//:/ ОЙ.

C97 | Polyethylene glycol 400 units -:/ | (77777711 se8 |PropyleneglycolbiPHARE)ІГ/-:: | (Cs p99 | Propylene Lycol 2000th -:/ ІІ 77777111

C103 | By salicylate.d//-/-:// | 4:71 p104 фЙодиднаттиюд//-/:///Ї7777777111111111111111111111111

C105 | Sulfuric acid.d//:/// HER. talamine-8-EO (TAM 80)

C111 00 | Tartaric acid.d////77777/ HER

С113 0 | Tregoctylamine.

С117 |Triethylhexylammonium!Ви.дГ ОИ 77777771

C118 0 | Trivtyloctylamn.io//-/:/// ІІ 77777771 s119 00 | Triphenylamno///// ІІ s120 | Trinatritcitrat.//-/://..ССССС/І|І7771111

ShRU MY PI SET OO p128 |vdecilamn.////////СЙ1111 p129,. | ..77777777 ://-С:/ st46 | 77777771 | Tetrabutylammonium hydroxide, id//:.:7/:, 8/И4С:С:/х/Н)С:(/(«08))/С: SD p155 | Oxalate ammonium /-:///// HER 11777111

Example 1 1026.

We evaluated the stability of 477 g of k.e./l solution of ca- Example 2 lithium glirosate 36.595 k.e. potassium glyphosate, 1295 We evaluated the stability of 523 g c.e./l solution of potassium

Mu/ysatepe TAM 80 (C109), 595 octylamine (C91) and lyo-glyrosate 39.395 k.e. potassium glyphosate, 1295 water up to 10095 were combined at room temperature - Muysatipé TAM 80 (C109), 695 octylamine (C91) and thuri (KT) with further mixing with a magnetic water up to 10095 were combined at room temperature - with a mixing rod at approximately 507C, until a homogenous sample was obtained with subsequent mixing with a magnetic one. At 50"C and with a mixing rod at approximately 507C, while at room temperature a single-phase, homogeneous sample was obtained. At 50"C and at a clear solution. The stability was maintained at room temperature, a single-phase,

From the days of the cycle during the 12-hour period between -10 and a clear solution. Stability was maintained during

From the days of the cycle during a 12-hour period between -10

Example With a mixing rod at about 507C while

We evaluated the stability of 477 g c.e./l of the solution and obtained a homogeneous sample. If there is no inlay glirosate 36,590 k.e. potassium glyphosate, 1295 instructions, these compositions were evaluated at 50"C and

Mu/ysatipe TAM 80 (CI0O9), 595 octylamine (C91) and at room temperature. The "transparent" result of mixing water up to 10095 at room temperature indicates the formation of a transparent single-phase solution with subsequent mixing with a magnetic mixture. A "turbid" result indicates that a single-phase solution, which is not yet cloudy, was obtained by the shaft rod at approximately 50°C. A "failed" result means that a homogeneous sample was obtained. At 50"7С and at kimcha" indicates that there was little room for separation at room temperature, a single-phase, prophase was obtained. clear solution. Example 4

Examples 4-6 Evaluation of the compatibility of the test stabilizer

In examples 4-6, the stability of the com- 526 composition containing 37.49o k.e. was evaluated. (approximately the positions of potassium glirosate with a high load of 490g c.e./l) potassium glyphosate, 6,095 EMSO! CO-40 for compositions with varying concentrations (surfactant), 0-6.095 octylamine (Stab.) and water up to 100905 surfactant and octylamine. Com-

Massive | 77772077 830 | Central Committee | 50 2 Sh | 60 2 25 women

Example 5 490 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 527 composition containing 37.49o k.e. (approximately octylamine stabilizer (Stab.)

Masoe | 60 | 60 | 60 | 60 | 60 | 60 | 60 | 60

Masoe | 50 | 50 | 50 | 50 | 50 | 50 | 60 | 60

Example 6 490 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 528 composition containing 37.49o k.e. (approximately octylamine stabilizer (Stab.)

Masoe | 50 | 50 | 50 | 70 | 70 | 60 | 60 Tue |Curky |Curky |Transparent Transparent |Transparent | - | -

Examples 7-14 of the sample. Unless otherwise noted, these compositions

In examples 7-14, the stability of the com- was evaluated at high temperature (about 507C), positions of potassium glirosate with a high load at room temperature, at 10"C, 0C and at - for compositions with compatibility and concentrations that 107C. In addition, the sample -10"C was evaluated through varying, short-chain alkylamines for one week. A "transparent" result indicates alkyl groups. Combine the components of the composition to obtain a transparent single-phase solution. The "turbid at room temperature and then mixed" result indicates the obtaining of a cloudy solution with a magnetic mixing rod in a non-phase solution. The result "failure" indicates that approximately 50"C, until a homogeneous phase separation occurred.

Example 7 7.3895 Ethydip-Y, 0-3.095 stabilizer Izorag GI. 480 g.e./l potassium glirosate, 4.9295 TAM 80, (Stab.), 0-6.095 hexylamine (Amine) and water up to 10095 yazo8me5 | 1,795 | 2,796|Transparent |Muddy |Muddy |Failure |Failure |Failure

Example 8 7.3895 Ethydip-Y, 0-3.095 stabilizer Izorag GI. 480 g.e./l of potassium glirosate, 4.9295 TAM 80, (Stab.), 0-6.095 octylamine (Amine) and water up to 10095 909ЕЗС | 095 | 4095 | Transparent | Transparent | Transparent | Transparent | Opaque | Opaque z09v | 22595 | 4,595 |Transparent |Transparent |Transparent |Transparent |Cloudy |Failure

Example 9 7.3895 Ethydip-Y, 0-3.095 stabilizer Izorag /. 480 g.e./l of potassium glirosate, 4.9295 TAM 80, (Stab.), 0-6.095 decylamine (Amine) and water up to 100905 91091Uu | 3,095 | 6095 |Transparent )|Transparent |Transparent |Transparent |Opaque |Opaque

Example 10 (Stab.), 0-6.095 dodecylamine (Amine) and water up to 480 g.e.u./l of potassium glirosate, 4.9295 TAM 80, 10096 7.3895 Ethydip-Y, 0-3.095 stabilizer Izorag I. ( 1 week)

Example 11 150 (Stab.), 0-6.095 octylamine (Amine) and water up to 480 g.e.u./l of potassium glirosate, 4.9295 TAM 80, 10096 7.3895 Ethydip-Y, 0-3.090 stabilizer Agotayis

Example 12 7.3895 Ethydip-Y, 0-3.095 stabilizer Izorag GI. 480 g.e./l of potassium glirosate, 4.9295 TAM 45, (Stab.), 0-6.095 octylamine (Amine) and water up to 10095

Z13I5BM | 22595 | 4,595 |Transparent )|Transparent |Transparent Transparent |Opaque |Opaque 913E2I | 3,095 | 6,095 |Transparent |Transparent |Transparent Transparent |Opaque |Opaque

Example 13 150 (Stab.), 0-6.095 octylamine (Amine) and water up to 480 g.e.u./l of potassium glirosate, 4.9295 TAM 45, 10096 7.3895 Ethydip-Y, 0-3.090 stabilizer Agotaiis 91407M | 096 | 6б.О095|Transparent |Transparent |Transparent |Transparent |Opaque |Opaque With ЕТ4Е4Н | 096 | 4096 |Transparent |Transparent |Transparent |Transparent |Cloudy |Failure. From 914127 | 1,596 | b.096 | Transparent | Transparent | Transparent | Transparent | Opaque | Opaque (With

Example 14 (PAR 2-experiment 915AZUM), octylamine (Stab. 1), 3795 (about 480 g c.e./l) of potassium glyphosate, Agotais 150 (Stab. 2) and water up to 10095

Etiidep-I. (PAR 1), TAM 60 (PAR 2) or TAM 80 915062 | - | 4biya | drink | - |Transparent | Transparent./-/- from 15 years. | - | 5 | 09996 | - |Transparent |Transparent./-/-:ЗГ"( 915Е5Т | - | vis | Wow | - |Transparent | Transparent./-/--- я15Р9К | - | 4bb | 296 | -- |Transparent |Transparent,. 7/-/-(Z яи5о6М | - | Bebo | 26 | - |Transparent |Transparent./-/-(З зИ5НЗО | 7 - | 73596 | иб2о6 | - |Transparent | Failure./-- z15IVO | - | 9 | and | - |Transparent |Failure./7/-- 156 | 7-1 | paras 7777-7711 - 0 |Transparent// |Failure.// ei5kov. | - | ve | 1956 | - |Transparent |Transparent. 7//--(Z

Examples 15-151 tallow, were not tested additionally at lower

In examples 15-151, stability at certain temperatures was evaluated. A "transparent" result indicates that glyphosate compositions with a high load have produced a transparent single-phase solution. (by concept) for compositions with compatibility and con- "Curdy" result indicates the obtaining of cloudy with varying concentrations of alkylamines with short single-phase solutions. The result is "failure" evidenced by chains of alkyl groups. If there is no other evidence that there was a separation of phases or clumps, the potassium salt of glyphosate was evaluated. Hardening component. those compositions were combined at room tempera- Example 15 ture with subsequent mixing with a magnetic Mixing rod compatibility assessment of the stabilizer test at approximately 60"C until 101 compositions containing 36.9905 k.e. (approximately) did not obtain a homogeneous sample. If there are no other glyphosate potassium 480g/l) and listed below instructions, these compositions were evaluated at a high component of surface-active substances (surfactants) and temperature (about 60"C) and during the night with stabilizers (Stab.) at the specified temperatures. An attempt that was unsuccessful

Mass | 6 | 6 | 6 | 5 | 5 | with | 5 | 7

Example 16 370 g of CU/L) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 104 composition containing 31905 k.e. (approximately octylamine stabilizer (Stab.)

Masos | 6 | 6 | 6 | 6 | 6 | 6 | 6 | 6

Mass | 6 | 6 | 6 | 6 | 6 | 6 | 6 | 6

Example 17 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer is below the component of surface-active substances 106 of the composition containing 31905 k.e. (approx.) and stabilizers (Stab.) mass | 777783 | 55 | 21 | 106 | 68 25 KkZf

Example 18 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 108 compositions containing 36,990 k.e. (approximately the octylamine stabilizer (Stab.) Experiment

Masoe | 36 | 48 | 6 | 72 | 84 | 12 | 12 | 48 pAR2 | hundred | spo | hundred | spo | hundred | - | - | -

Mass | 84 | 72 | 6 | 48 | 36 | - | - | - 7 (F 1 week

Example 19 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 110 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Mass | 77777761 11117144 15

Example 20 480 g c.e./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 112 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Masoe | 36 | 48 | 6 | 72 | 84 | 12 | 12 pPAR2 | si2i | sli! | si! | si! | seven | /- | -

Masoe | 84 | 72 | 6 | 48 | 36 | - | -

Example 21 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 114 compositions containing 36.9905 k.e. (approximately stabilizers (Stab.) mass | 36 | 48 | 6 | 72 | 84 | 12 | 2 pАР2 | spo | spo | spo | spo | spo | - | -

Masoe | 8A | 72 | 6 | 48 | 36 | - | -

Example 22 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 116 compositions containing 36,990 k.e. (approximately stabilizers (Stab.) mass | 36 | 48 | 6 | 72 | 84 | 712 | 2 pАР2 | со | с40 | сао | со | со | - | - mass | 84 | 72 | 6 | 48 | 36 | - |-

Example 23 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 117 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Experiment. | AbV | VK | 7 s5T | 777 year entry

Mmasoye | 7776 | 76 | 6 | 6 | 6 os 0 |Muddy/// |Not available / |N/A/ |N/A // |Muddy//

Mmasoye | 7776 | 76 | 6 | 6 | 6

Example 24 480 g.e./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 118 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Masoe | 77777776 777776 | 77776 | 46 | 5 Yu same "6

Masye /////// Ї777777717117611177717171717161Ї1117171711716 11111116

Example 25 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 119 of the composition containing 31905 c.e. (approximately (surfactants) and stabilizers (Stab.)

axis 77

Example 26 (about 370 g c.e.u./l) of isopropylamine-glyphosate (all

Evaluation of the compatibility of the stabilizer test other experiments) and the components listed below 120 compositions containing 36,990 k.e. (approximately surface-active substances (surfactants) and stabilizers - 480 g.e./l) of potassium glyphosate (experience of ABA), 3190 k.e. moat (Stab.) mass | 755 | 55 | 6 | 6 | 5

Stab2 | 7 p25 | .c25 | 625 | - | -

Masov | 77703 2 | 03 2 2 shЩ| 05 2 |! - | -

Example 27 480 g.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 122 compositions containing 36,990 c.e. (approximately stabilizers (Stab.) mass | 36 | 48 | 6 | 72 | 84 | 12 | 12

PPAR2 | so | s4o0 | sao | s4o0 | p40 | - | -

Masoe | 84 | 72 | 6 | 48 | 36 | - | -

Example 28 124 composition containing 36.9905 k.e. (about

Evaluation of the compatibility of the test stabilizer 480 g c.e./l) of potassium glyphosate and the components of surface-active substances (surfactants) and stabilizers (Stab.) listed below by mass | 36 | 48 | 6 | 72 | 84 | 712 | 2

PPAR2 | hundred | spo | we | spo | spo | - | -

Masoe | 84 | 72 | 6 | 48 | 36 | - | -

Example 29 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer is below the component of surface-active substances 125 of the composition containing 31905 k.e. (approx.) and stabilizers (Stab.) 0 Research | AB | Vb | СО | 777 02 | EA mass | 77/55 2 Sh | 6 | 5 | 7 | 6 nshidomshkii | 6032 | 7777-7771 17111171 mass | 777705. | ..YuuYUYY-7111717- 17 171111717-111171111103

Example 30 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below 102 components of surface-active substances - 126 compositions containing 31905 k.e. (approximately wines (surfactants) and stabilizers (Stab.)

Mmasoye |! 77723 | 77677776 76 | 6 nshidomshki || /c15 | 6032 | --p32 | -:((- | sh c32 ( mass of HER 77733 | sh(OZ | 03 2 | sh - | 03 25 о 77777770 |Ned./// |Ned./ |Ned./ |Ned./ |Ned./

Example 31 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 127 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Macie | (6 | B "6 | 6 | 6 | 6 | 6

Mass | 3 | shshshsh 4 | 2 SH 5B | 6 | 5 | 5

Example 32 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer is below the component of surface-active substances 128 of the composition containing 31905 k.e. (approximately (surfactants) and stabilizers (Stab.)

Masoe | 6 | 6 | 72 | 74 | 74 | 74 | 74

Masoe | 6 | 6 | 6 | with | 4 | with | 6 os 0000 |Muddy |Not available |Non-ext. |Non-ext. |Failure |Muddy |Muddy

Example 33 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 129 of the composition containing 31905 c.e. (approximately (surfactants) and stabilizers (Stab.)

Stab./////// | with | 7777 s 77771 sya1 7111 cm 1111-11

Mas |! 77777273 140 15 | -

Example 34 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 130 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Masoe | 6 | 6 | 72 | 72 | 72 | 72 | 72 | 72

Mas" | 6 | 6 | 6 | 6 | 5 | 44 | 6 | 6

Example 35 480g c.e./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 131 compositions containing 36,990 c.e. (approximately stabilizers (Stab.)

Mas" | 6 | 6 | 6 | 6 | 6 | 6

Example 36 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the component of surface-active substances 133 of the composition containing 31905 k.e. (approximately (surfactants) and stabilizers (Stab.)

Masoe | 7 | 55 | 6 | 6 | 1 | 6 | 6 | 6

Example 37 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 134 compositions containing 36.9905 k.e. (approximately stabilizers (Stab.)

Example 38 480 g.e.u./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 135 compositions containing 36,990 k.e. (approximately stabilizers (Stab.) others | 7- Y - y - | - | sa | spa | spa | spa maso | /- | - І! - | - І! 1! І 1! 1 1 1

Example 39 480 g c.e./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 136 compositions containing 36.9905 k.e. (approximately stabilizers (Stab.) others | - | - | sma | spa | spa | spi | - | -

Mass | - | - She is from | 25 | 15 | with | - | -

Masoe | 6 | 6 | 5 | 5 | 5 | 5 | 0 | 12

Example 40 480g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 137 compositions containing 36.9905 k.e. (approximately stabilizers (Stab.) other 7

Example 41 c.e./l) of potassium glyphosate and the compounds listed below

Evaluation of the compatibility of the stabilizer test component of surfactants (surfactants) and 138 composition containing 36.5905 k.e. (approximately stabilizers (Stab.) 480g c.e./l) (test NOM (F 3895 - about 513g

Experiment | - BIR | 648 | 7 NOM | 7 8R./

Masov 7 Y777777117176511777111185 | 1.11119 22.2.

Example 42 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 139 of the composition containing 31905 c.e. (approximately (surfactants) and stabilizers (Stab.)

Example 43 370 g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 140 of the composition containing 3195 k.e. (approximately (surfactants) and stabilizers (Stab.)

Stab2 | 7777-7717 17717171717-111177111cm 11 cm

Vehicle registration number 77777111

Stab2 | 7777771717-71717171717171777171717111с3о | 7777630 | 77777771 maso Y77777717171717-1111171Г1111110651 11111111

Example 44 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the component of surface-active substances 141 of the composition containing 3195 k.e. (approximate) weight of (PAR) and stabilizers (Stab.) | 77/75 | 6 | 7 | 8 | 5 sh shK;8

Example 45 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 143 compositions containing 36,790o k.e. (approximately stabilizers (Stab.)

Mas HER 77777727 11111114 01111116 | Yuyuki 8 | 2 Yuyuzh hshchlo os 00 |Failure/////////// |Incomplete |Non-ext. // |Muddy/// |Muddy//

Example 46 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 144 compositions containing 36,790 k.e. (approximately stabilizers (Stab.)

Mass | 2 BZHyuzh"YUR/ 4 HER 6 |! 8 | 0

Example 47 145 composition containing 36,790o k.e. (about

Evaluation of the compatibility of the test stabilizer 480 g c.e./l) of potassium glyphosate and the components of surface-active substances (surfactants) and stabilizers (Stab.) listed below

Mas |! 77772777 4 11716 | 8 | 2 and 0

Example 48 480 g.e.u./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 146 compositions containing 36,790o k.e. (approximately stabilizers (Stab.) mass | 77772... |

Example 49 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 147 compositions containing 36,790o k.e. (approximately stabilizers (Stab.)

Experiment. | AB | In | Sat 25 | obb | 7-8

Mass | 77772 2 | шХХС(4 | 6 ! 8 | yuyu tu |Cloudy// |Failure | Transparent | Transparent // |Transparent./-

Example 50 480g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 148 compositions containing 36.1905 k.e. (approximately stabilizers (Stab.)

Experiment | - AbH/ | 7 th SU | ro | in ZO mass | 777772 | ..YurYuyuD4 4 4 ЮЩщ| 6 | 8 | what

Example 51 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 149 compositions containing 36,790o k.e. (approximately stabilizers (Stab.) mass | 777772. | ..ЮрЮюД4а4 4 4 | ю6 | шв8 | 0

Example 52 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 150 compositions containing 36.790o k.e. (approximately stabilizers (Stab.)

Example 53 C70Og c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the component of surface-active substances 151 of the composition containing 3195 k.e. (approximately (surfactants) and stabilizers (Stab.)

Mass | (1 |! 2 | from | 44 | 5 | 6

Stab2 | - HER 777-171 -111111- 11-11 -

Mass | 7-11

Mas G77771177117 17111187 11111111

Stab2 | 77777 77777777 -111717117117111s30 | 7777 szo | 7 szo

Mass | 77777711 11117111 2 13

Example 54 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 152 of the composition containing 31905 k.e. (approximately (surfactants) and stabilizers (Stab.)

Macie | 6 | 6 | 6 | 6 | 6 | 6 mass | 1 HER 2 | with | 4 | 5 | 6

Example 55 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 153 of the composition containing 31905 c.e. (approximately (surfactants) and stabilizers (Stab.)

Mass | 1 | 2 | with | 4 | 5 | 6

Example 56 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 154 of the composition containing 31905 k.e. (approximately (surfactants) and stabilizers (Stab.)

To you 1 | 2 |! with | 4 | 5 | 6

Example 57 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 155 compositions containing 36,790o k.e. (approximately stabilizers (Stab.)

Masov 77777777 Y7771717171717171717168177717171711711771717171717111682 7 |7771717171711716811

Example 58 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surfactants (surfactants) and 156 compositions containing 36,790o k.e. (approximately stabilizers (Stab.)

Mass | 77767777 17111787 1179 | ЮюЮДщфщ0

Example 59 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 157 compositions containing 36.1905 k.e. (approximately stabilizers (Stab.)

Mass | 777772 | 14 | 6 B | 8 | 0"

Example 60 480g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 158 compositions containing 36.1905 k.e. (approximately stabilizers (Stab.)

Mass | 77772 | .ЮЙ4 5 | 6 | 8 | i am

Example 61 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 159 compositions containing 36,790 k.e. (approximately stabilizers (Stab.)

Mass | 777772 | ..77p74 | ЮюЮЙщб' | 8 | 6

Example 62 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 160 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Stab. | p85 | p85 | sv5 | se5 | p85 | p85 | sv5 | - and

Masoe | 025 | 05 | 1 | 2 | with | 4 | 5 | -

Example 63 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 161 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Example 64 480 g c.e./l) of potassium glyphosate and components of the stabilizer

Evaluation of the compatibility of the tori test stabilizer (Stab.), without added surface-active 163 composition containing 36.790o k.e. (approximately substances.

Example 65 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 164 composition containing 36.79o k.e. (approximately stabilizers (Stab.)

Example 66 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the component of surface-active substances 165 of the composition containing 31905 k.e. (approximately (surfactants) and stabilizers (Stab.)

Example 67 k.e./l) of potassium glyphosate and stabilizer components

Evaluation of the compatibility of the test stabilizer (Stab.), without added surface-active substance - 167 compositions containing 590 k.e. (approximately 480 g

Example 68 480 g c.e./l) of potassium glyphosate and components of the stabilizer

Evaluation of the compatibility of the tori test stabilizer (Stab.), without added surface-active 175 composition containing 595 118k.e. (approximately substances.

Example 69 (approximately 480 g c.e./l) of potassium glyphosate and calculated

Evaluation of the compatibility of the stabilizer tests below components of surface-active substances 176 (AZO) and 178 composition containing 36,990 k.e. wines (PAR) and stabilizers (Stab.)

Masoe | 49 | with | 4 | 5 | 6 | 7 | 0 | tt pAR2 | hundred | hundred | hundred | spo | spo | hundred | - | -

Mass | 74 | 7 | 6 | 5 | 4 | with | - | -

Example 70 480 g c.e./l) of potassium glyphosate and are listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 180 compositions containing 36,990 k.e. (approximately stabilizers (Stab.)

Mass | 6 | 5 | 6 | 5 | 6 | 6

Example 71 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 182 composition, which contains 36,990 k.e. (approximately stabilizers (Stab.)

Example 72 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 184 composition containing 36.9905 k.e. (approximately stabilizers (Stab.)

Experiment | ASI | VM | s5K | OR | in ZY | vm | sya ur pAR2 | c3 | sz | sz | sz | sz | sz | -

Masoe | 74 | 74 | 74 | 74 | 74 | 74 | -

Example 73 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 185 composition containing 36,790o k.e. (approximately stabilizers (Stab.)

Experiment. | AN | and STA | 7 09R. | in

Stab!//////// | 77777c91 7777 sei 17711 cm 11 cm 111-111

Mas 77777411 Y777111731 11111281 11111311

Stab2 | 7777777 1111171 177111с47 | 77771 rays | sia | sia

Mas ЯИ 7777-1711 28 111111 a

Mas Y777777117311 11111141 11111161 11111116

Stab2 | 777777 sia | 777 s |771111 st | 7777-77

Mas 7 Y77777111731171 11111121 11111111

Example 74 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 186 composition containing 36.9905 k.e. (approximately stabilizers (Stab.)

Mass | 0 | 2 | 4 | 6 | 8 | 5

Example 75 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 187 compositions containing 36.9905 k.e. (approximately stabilizers (Stab.)

Mass | 6 | 1 | 2 | with | 44 | 5

Stab2 | --/- | 6045 | p45 | sya5 | sa5 | p45

Mass | (| 51 | 4 | of | 2 | 1!

Example 76 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 188 composition containing 36,990 k.e. (approximate stabilizers (Stab.) mass | 6 | 2 | 4 | 6 | 2 | 44

Stab2 | /- | .p98 | St | - | se | everything

Mass | - | 4 | 2 | - | 44 | 2

Example 77 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 189 compositions containing 36,790o k.e. (approximately stabilizers (Stab.) 0 Experiment

Stab2 | 77777 - 777717 77777c89 | se | 7777 - 77777777 words

Mass HER 777777 11717111 401 1111211 - 144

Mass |! 77777141 | 77771716 11111112 1174

Stab2 | 777 siu | 77777777 -177771717171171777717171711slo1 | hundred

Mas Y 77777772 71771717 -111111171С1111111114а41111112

Example 78 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 190 compositions containing 36.79 k.e. (approximately stabilizers (Stab.)

Mass | 76 | 2 | 4 | 6 | 2

Stab2 | 7777-7777 77777c83 | 7777 sv3 | 77777 - 71777711 cm

Mass ОЙ 11711114 28 111-144 mass | 77771407 Y77717171717161 11111121 4

Stab2 | 77777624 | 77777 -7777717777171711 s 17771171 s

Mass | 77777721 4y4 11111112

Example 79 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 191 compositions containing 36,790o k.e. (approximately stabilizers (Stab.)

Mass | 77677772 | 2 ЩЩЩфх4 | 6 | 2

Stab2 | 7/7 - 77 |77717с727 | Article 2 /- 7/7 777717177log

Mass | 7/7 -17 71117141 2 | - | 44

Mass 7 | 7777/7401 Y111717171716 11111214

Stab2 | 777 s2 | 77777777 77717117 7777111св4 |17777717171711с841 mass | 77777772 11111171 11111141

Example 80 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 721 composition containing 36.99o k.e. (approximately stabilizers (Stab.) mass | 25 | 37 | 62 | 74 | 86 | 98

Masoe | 98 | 86 | 62 | 498 | 37 | 25 Tue |Clear |Clear |Failure |Failure |Failure |Cloudy/-

Example 81 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 722 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mass | 4 HER 4 | 4 | 6 | 6 | 6 (Ff 4 weeks

Example 82 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 723 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mamasu | 4 | 4 | 4 | 6 | 6 | 6

(fi weeks

Example 83 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 724 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mamasu | 4 | 4 | 4 | 6 | 6 | 6

Example 84 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 725 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

To you 4 | 4 | 4 | 6 | 6 | 6 "4 weeks

Example 85 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 726 composition containing 36.99o k.e. (approximately stabilizers (Stab.) 0 Research | AVM | vs | Sp | 000 | in ba |sh

Stab.///////// | 77291 | s 7777 s 17111 cm 1111-11

Mass | 77771401 17111732 1111-11

Example 86 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 727 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Stab,i/////// | 77777177cm1711711cm 77717171cm 71111711 bulk Ї7777711131Ї11112а1 11111111 (Ff 4 weeks

Example 87 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 728 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masoe | n | 9898 | 86 | 74 | pi | 98 | 86 | 74

Example 88 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 729 composition containing 36.99o k.e. (approximately stabilizers (Stab.) mass | them | 98 | 86 | 74 | Chi | 98 | 86 | 74

Masoe | 5 | 5 | 5 | 5 | 6 | 6 | 6 | 6

Example 89 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 730 composition containing 36.99o k.e. (approximate stabilizers (Stab.) mass 111 | 98 | 86 | 74 | We | 98 | 86 | 74 (ax | N/A | N/A )| N/A )| N/A )|Transparent |Curky |Curky |Curky

Example 90 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 731 composition containing 36,990 c.e. (approximately stabilizers (Stab.)

Masoe | 111 | 98 | 86 | 74 | Article | 98 | 86 | 74 boss |Transparent |Muddy |Muddy |Muddy |Transparent |Failure |Failure |Failure

Example 91 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 732 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masoe | and | 98 | 86 | 74 | pi | 98 | 86 | 74

Example 92 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 733 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mass | 111 | 98 | 86 | 74 | Is | 98 | 86 | 74

Example 93 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 734 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mass | 1 | 98 | 86 | 74 | ml | 98 | 86 | 74

Example 94 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 735 composition containing 36.99o k.e. (approximately stabilizers (Stab.) mass | 6 | 6 | 6 | 44 | 44 | cha

(Ff 4 weeks

Example 95 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 736 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masos | 111 | 98 | 86 | 74 | pl! | 98 | 86 | 74

Example 96 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 737 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masos | 1 | 98 | 86 | 74 | pl | 98 | 86 | 74

Example 97 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 738 composition containing 36.99o k.e. (approximately stabilizers (Stab.) t (Ff 4 weeks

Example 98 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 739 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masoyes | her | 98 | 86 | 74 | Article | 98 | 86 | 74

Example 99 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 740 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masos | ate | 98 | 86 | 74 | pl | 98 | 86 | 74 t (Ff 4 weeks

Example 100 480g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 741 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Example 101 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 742 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mass | 111 | 98 | 86 | 74 | Is | 98 | 86 | 74

Example 102 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 743 composition containing 36.99o c.e. (approximately stabilizers (Stab.)

Mass. | 1 | 98 | 86 | 74 | pl | 98 | 86 | 74

Example 103 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 744 composition containing 36,995 c.e. (approximately stabilizers (Stab.)

Mass | 1 | 98 | 86 | 74 | Article | 98 | 86 | 74

Example 104 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 745 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masoe | 1 | 98 | 86 | 74 | Article | 98 | 86 | 74

Example 105 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 747 composition containing 36.99o k.e. (approximately stabilizers (Stab.) pAR2 | sb3 | sv2g | svo | -- | - | - mass | 74 | 7 | 74 | - | - |! -

Example 106 c.e.u./l) of potassium glirosate and the compounds listed below

Evaluation of the compatibility of the stabilizer test component of surfactants (surfactants) and 749 composition containing 595 c.e. (approximately 480g of stabilizers (Stab.)

Example 107 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 751 composition containing 36.995 c.e. (approximately stabilizers (Stab.) about Dosld | A/V | В2М | Сг | роя | ЕР | ЗМ | СОМ

Stab. | p30 | p30 | szo | spo | szo | - | - mass | 74 | 74 | 74 | 74 | 74 | - | -

Example 108 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 753 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Example 109 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 755 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

PPAR2 | /- | standing | spo | standing | - | hundred | hundred

Masoe | - | 74 | 74 | 74 | - | 74 | 74

Stab.i//// | p30 | - | - | - | szo | - | - mass | 74 | - | - | - | 74 | - | -

Example 110 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 757 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

PAR2 | word | word | word | 777 с1т0ю | 7777-71 mass | 774 | 774 | 74 | 74 | -

Stables/////// | 7777-1171 -1111711111171-11117117szo maso HER 777777 -11 17111711 -11171174

Example 111 C70g c.e./l) of the specified glyphosate salt and listed

Evaluation of the compatibility of the test stabilizer below the surfactant component 759 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Mass | 6 | 6 | 6 | 6 | 6 | 6 | 6

Example 112 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 761 composition containing 36.99o c.e. (approximately stabilizers (Stab.)

Example 113 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 762 composition containing 36.99o k.e. (approximately stabilizers (Stab.) 0 Dosldo | -- AZA | VL | SYA | 7,090 | in C

PPAR2 | word | 777 from | 777777 -717 11111171

Masoe |! 77/74 | 77177400 1117-1111 -111111-

Example 114 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 763 composition containing 36,995 k.e. (approximately stabilizers (Stab.)

Macie | 6 | 6 | 6 | 6 | 6 | 6

Example 115 480 g c.e./l) of potassium glyphosate and listed below

The compatibility score is 36.99o k.e. (approximately stable - components of surface-active substances (surfactants) and test lysator 764 compositions containing stabilizers (Stab.) o Dosld | А | В | СУМ | ро | вм | в

Mmasoye | 74 | 74 | 74 | 6 | 6 | 6

Macie | 6 | 6 | 6 | 6 | 6 | 6

Example 116 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 765 composition containing 36.99o k.e. (approximately stabilizers (Stab.): maso | 77777727 7717171712 | 2 | yuyu | 6 t (Ff 4 weeks

Example 117 480 g.e.u./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 767 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Masov | 777727 77711716 111727 |11111716 1711112 mass | 74 | 86 2 | 74 | 86 | 74 2 KKk«f

Mass | 7776 777727. | 2 щЩщЦбБ | 27 | 6 2 yu«ShZ

Example 118 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 768 composition containing 36.99o c.e. (approx. weight of stabilizers (Stab.) | 7777771727 71111176 11111216 11

Example 119 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 771 compositions containing 36,990 c.e. (approximately stabilizers (Stab.) t (Ff 4 weeks

Example 120 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants), 773 composition containing 36.99o c.e. (approximately Adaiime (impurities) (Dom.) and stabilizers (Stab.)

House | 630 | 630 | p30 | 7 c3o | 7 p.m

Example 121 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 775 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

PPAR2 | 7 - | .- | standing | hundred | layer | standing | hundred

Mass | - Y - | 74 | 74 | 74 | 74 | 74

Example 122 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 776 composition containing 36,995 c.e. (approximately stabilizers (Stab.)

Example 123 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 777 composition containing 36.99o k.e. (approximately stabilizers (Stab.) pАР2 0 |смо 7 f|смо 1-11 mass 178 77777184 777777 1-11 pАР2 1-11 mass 1-11

Mass //////|6 7777/1677 16777777 1677/5777

Example 124 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 7178 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Example 125 480 g c.e./l) potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 779 compositions containing 36,990 c.e. (approximately stabilizers (Stab.)

Masov | 777777717567 77777716 |1771717171171641 11111152

Mas 7 HER 77777784 777771717179 11177771 9617|777171171781

Example 126 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 780 of the composition containing 3195 k.e. (approximately (surfactants) and stabilizers (Stab.)

Fri: Wed: PO with: MON POLO with: MON NO UNO OO

Mass. 7 Y77777111111171H1111g1g

Example 127 C70g c.e./l) of isopropylamine-glyphosate and listed

Evaluation of the compatibility of the test stabilizer below the surface-active substance component 781 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Stab.//// | -- | c3z8 | sz8 | sz38 | si5 | si5 | Saturday mass | - | 1 | with | 5 | 1! | with | 5 (Ff 4 weeks

(Ff 4 weeks

Example 128 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 782 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Stables//////// | 7 p77 | Article | sl | /-/ | sl

Mass | 77777118 Y1111715 1117-1111 t (Ff 4 weeks t (Ff 4 weeks

Example 129 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 783 composition containing 36.99o c.e. (approximately stabilizers (Stab.)

Mass | (0 47777777 77717176 17771716 111116

Example 130 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 784 composition containing 36.99o k.e. (approximate stabilizers (Stab.) mass! 111 | 99 | 87 | 74 | ply | 99 | 87 | 74 10s | Transparent | Cloudy | Cloudy | Cloudy | Not lit. | Not lit. | Not lit. | Not lit. t (Ff 4 weeks

Example 131 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 785 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

Mass | 6 | 6 | 74 | 74 | 74 | 74

Mass | 2 2 | 1 | 6 | 6 | 6 | 6 oStab2 | p9 | p9 | - | Article | Article | Art

Mass | 4 | 4 | - |! 1 | with | 5

Experiment. | 077 | but | 8M | 2 9 mm | Fr

Mas |! 77/76 76 | 6 | 6 | 6

Mas HER 776 7771767 | 7776 | 76 12 2 oStab2 | 7/7 - 77777 77777st | Article | Article | Mr

Mas Y 7777-17 G171111111171111115317 111115 1711 t (Ff 4 weeks

Example 132 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the component of surface-active substances 786 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Mass | 84 | 84 | 65 | 84 | 6 | 65 | 73

Stab.i | su | /- | Article | Article | Article | Article | -

Masoe | 07 6 юЮЩщ | - | 14 | 2 | 08 | 04 | - t(Ff 4 weeks

Mass | 7 | 6 | in | 68 | 72 | 77 | 77

Stab.i | with | su | - | su | Article | Article | Art

Mass | 08 | 2 | - | 2 | 2 | 04 | 14

Mass G1111111109117 111 axis 77777777

Example 133 370 g of CU/L) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 787 composition containing 3195 c.e. (approximately stabilizers (Stab.)

Masos | 52 | 56 | 6 | 64 | 68 | 72 | 76

Masos | 78 | 84 | 9 | 96 | 102 | 108 | CPU4

Stabi//// | - HER - 1 - 1 - | - | - 1 -

Mass | 7-1 7-11 1-1 - 1-1

Masos | 8 6 yush | 84 | 88 | 92 | 96 | 49

Stables////// | 777-171 -17111117-1111117-1 17-71 sp

Masov/////Y 7777-1717 -17111117-171111117-111- 11 t (Ff 4 weeks

Example 134 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer below the surfactant component 788 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Massos | 52 | 56 | 6 | 64 | 68 | 72 | 76

Masos | 78 | 84 | 9 | 96 | 102 | 7108 | і4 i-o"s" |Failure )|Muddy |Failure |Incomplete |Non-ext. |Non-ext. |Not ext. t (Ff 4 weeks

Mass | 7/8 2 YU | 6 YUB 84 | 2 sh 88 | 92 | 96

Example 135 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 789 composition containing 36.99o k.e. (approximately stabilizers (Stab.)

PPAR2 | hundred | standing | siz3 | standing | - | - | sp

Mass | 74 | 74 | 74 | 74 | - | - | 74

Mass | 6 | 5 | 6 | 5 | 1 | 1! | "4 (F 4 weeks

Mass HER 77777140 11171640 | 44 | 5

Example 136

Evaluation of the compatibility of the stabilizer test 790 composition containing 36.99 k.e. (approx. 480 g c.e./l) of potassium glyphosate and the components of surface-active substances (surfactants) and stabilizers (Stab.) listed below

Stab her Y 777777 - 17717117 Y717171717се97|77771с91 177177 с со

Mas Y 77777111 11111413 | 6

Stab2 | 7/7 77171777 -111117111111c9

Mas Y 77777117 1111171-1117111111-111171111111ai4 1

Its mass is 77771717 Ha 11113116 | 1

Stab2 | (khs95 2 2 (| 2 shfshgs5 | - / - | se

Mas Y777175 17 17111711171 11117111 -111711

Example 137 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactants) and 791 composition containing 36.99o c.e. (approximately stabilizers (Stab.)

Masos | 74 | 98 | 6 | 8 | 6 | in

Stab. 2 | Article | Article | with | Mr | - | -

Mass | 1771771 11 1-11 -

It has | -.YD988 6 6Yushch | 74 | 98 | 6 | 8

Stab2 | 7777-7777 7771115 77711151 77717115 | with

Mas OII 7777-1111 g

Example 138 C70g c.e./l) of isopropylamine-glyphosate and listed

The evaluation of the compatibility of the test stabilizer is below the component of surface-active substances 792 of the composition containing 3195 c.e. (approximately (surfactants) and stabilizers (Stab.)

Mass | 6 | 7 | 71 | 83 | 74 | 74 | 6 | 6

Stab. | Article | Article | p77 | Article | - | Article | - | Mr

Masov | 14 | 17 | 15 | 18 | - | 1! | - | t t (Ff 4 weeks

Example 139,793 composition containing 36.99o c.e. (about

Evaluation of the compatibility of the test stabilizer 480t c.e./l) of potassium glyphosate and the components of surface-active substances (surfactants) and stabilizers (Stab.) listed below

PARI | 7777-7117 -1111171111 смо | word | sp

Mass HER 77777771 -11117|111240 2400 | 24

Stabi | 77-77 .p38 | with | with | with

Mass | 7777-7774 | 6 | 74 | 6

Stab2 | - | - HER - HER - | Mr

Mas Y 777-111 (F 4 weeks

Mass 7 | 7777/7747 | 77777167 17717117740 | 6

Stab2 | 11111111

Mass

Example 140 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 795 composition containing 36,995 k.e. (approximately stabilizers (Stab.)

South Africa? | hundred | spo | hundred | hundred | spo | spo | hundred | -

Maso | 74 | 6 | 6 | 6 | 74 | 74 | 74 | -

Stabi | - | - | sei | se | sei | su | se | with

Mass | - | - | 6 | 6 | 6 | 1! | 4 | 1

Stab2 | - | - | - |! - | sl | - | sp" | -

Mass | - | - Y - | - І 1 | - | 1 | -

Example 141 480 g c.e./l) of potassium glyphosate and listed below

Evaluation of the compatibility of the test stabilizer component of surface-active substances (surfactant) and 798 composition containing 36,995 k.e. (approximate stabilizers (Stab.) weight | 7763 2 | 74 | 98 2 Sh | 937 | 37

Masov | 77/63 2 shЩ| 49 | 25 | 86 | 86

Stab2 | 7-2 | - 1 - 1 - | t mass Y 77777111 -111й1

Example 142

Evaluation of the compatibility of the active substance test stabilizer (surfactant) and stabilizers (Stab.). 097 compositions containing 3895 k.e. IRA-glyphosate "Stable" result is defined as one and the components of the surface phase listed below.

Mas Y!7777711176111117Й111111171771171г111112а11 12 pPARZ | 77777717 11111117 1717171717171717-11111117117111111с43 | with

KLEN UNO OO NNYA KON: MON KO ON

Example 143 of glyphosate and the components listed below

Evaluation of the compatibility of the surfactant test stabilizer (surfactant) and stabilizers of the 099 composition containing 36,595 k.e. potassium- (Stab.). "Stable" is defined as one phase.

Mamasu | 7 | 9 | 7 | 9 | 7 | 9 | 7 | 9 th

Example 144

Evaluation of the compatibility of the active substance test stabilizer (surfactant) and stabilizers (Stab.). 100 compositions containing 38905 k.e. IRA-glyphosate "Stable" is defined as one phase. and the surface components listed below

Mmasoye | 6 |! 6 | 7 | 6 | 6 | 7

Stab.i | p125 | - | himself | hundred | -- | p125

To you 717 G 7-11 11 1-1 1 7 (F 1 week

Example 145 of glyphosate and the components listed below

Evaluation of the compatibility of the surfactant test stabilizer (surfactant) and stabilizers of the 706 composition containing 36,595 k.e. potassium- (Stab.). "Stable" is defined as one phase.

mass | 77 HER 7 | 9 | 7 | 7 | 9

Stab.i | c1i25 | - | si | c1i25 | - | p125

Mass | 1 | - 1 1 her - 11 1 7 (F 1 week

Example 146 compositions were approximately 448g c.e./liter. All com-

The effectiveness of the effect of stabilizers on the ponents was evaluated and then shaken until the

IRA-salts of glyphosate with cationic and non-ionogenic, homogenous finished form. Each is prepared with surfactants. The aqueous form was stable, transparent, dark yellow. order 146. Concentrations of glyphosate for each

Table a of example 146 tovAZM | seeds | 4 | p43 | 7 | si25 | 1 | - | - 7о6вVO | Article | 4 | himself | 7 | si | 1 | - | - tovsUK | seeds | 4 | hundred 7 | si | 1 | - | -

Compositions of table a of example 146 and compare - AVITN). The results in the form of the average for the concentration of IRA-glyphosate applied to the plants of all repetitions of each treatment are shown in Theophrastus’s rope plant (Abshiop of Ipeorpgazvia, shown below in table b of example 146.

Table B of example 146 95 suppression AVITN 7067 | 77777607 777771 7va | 777937 | 777965 2 years KME 7 t7o6bEYAM | 77776077 77777822 | 942 | Yuk

Effectiveness of compositions 706015, 706E8. and days the composition was prepared as indicated in the table and 706P9M was similar to the efficiency of the standards of example 147. Glyphosate concentrations for each glyphosate. the compositions are given in g.e.u./liter. All components

Example 147 was added and then shaken to obtain a

The effectiveness of stabilizers on the native finished form was evaluated. Each ready-made form of glyphosate potassium salt with cationic and nonionic surfactants is stable, transparent, dark yellow. It's nom.

Table a of example 147 111 t50AZS | 475 | SM | 4 | with | 9 | cm | t UBoVvM/ | 475 | sl | 5 | seeds | 9 | cm | t

And 7Bos3r | 465 | Mr | 6 | sia | 1 | shines | 25

Compositions of table a of example 147 and compare - AVITN). The results in the form of the average for the concentration of IRA-glyphosate applied to the plants of all repetitions of each treatment are shown in Theophrastus rope plant (Abshiop Ipeorpgazvii, shown below in Table B of example 147.

Table B of example 147 95 suppression of AVITN e/ha

The effectiveness of the composition 750СО0УМ was similar to that of the composition prepared as indicated in table a to eliminate the effectiveness of glyphosate standards. of example 148. Concentrations of glyphosate for each

Example 148 compositions are given in g c.e./liter. All components

The effectiveness of the stabilizers was evaluated by adding and then shaking to obtain potassium salts of glyphosate with cationic and non-ionic ready forms. Each finished form with genetic surface-active substances. It was a stable, transparent, yellow solution.

Table a of example 148

TAZ | 478 | cm | 4 | from 9 | c4 | t 77487 | 478 | cm | 4 | sa | 9 | cm | iz o ttasoR | 475 | SM | 4 | p47 | 9 | cm | 15 774030 | 478 | town | 4 | p47 | 9 | Stusizv | 7 (7taEOK | 481 | st | 4 | cm | 9 | hundred | 25 o774R7M | two | st | 4 | st | 9 | cm | 25

The compositions of table a of example 148 and a comparison of all repetitions of each treatment are shown in the total concentration of IRA-glyphosate applied on the diluted table B of example 148 below. .

AVITN). Results as an average for

Table B of example 148 95 suppression of AVITN 1 ttasoR | 555 | 657 | 80 2 | 902 | 952 of the CPC

Effectiveness of compositions 774SOR, 774030 and their surface-active substances. Salt 774E9K was similar to the efficiency of the glyphosate standard and the concentration in g cfu/l for each

AVoipatsr Shikga. compositions and other components are as indicated-

Example 149 is not in the table of example 149a.

The effectiveness of the stabilizers was evaluated

IRA-salts of glyphosate with cationic and non-ionic

Table a of example 149 oZZA7X | IRA | 360 | p27 | 64 | p43 | 96 | syu | 1)

OZZEBS hundred

RESPONSE p109 03357 7 03 ZATU additionally contains 1,595 TNE-OH (СИ 14) and 195 Izorag I (С77)

The compositions of table a of example 149 and the comparative for all repetitions of each treatment, the full concentrations of IRA-glyphosate were applied to the morning glory (IROBZ5) described in table p of example 149. The results in the form of average

Table 5 of example 149 95 suppression of IROB55 14 days after treatment 200g c.e./ha 400g c.e./ha god c.e./ha 800g c.e./ha

OZZATU

033835 7935 | ..ЮюЮЙв65 2 шЩ | 7 2 Sh | 802 257-"« o33s9R 03305

OZZEBO 592 | ..yuYuYUYD80..Yu.Yu..YuyuY8you you

OZZEVI- 25 7777 o 7257777 | ..7717178v0771 o33s7M

Voshpatsr Shvamakhi | (47 | 708272YUY | 767 2Yu- | v

Effectiveness of compositions OZ3ZA7U, OZZSOR, IRA-salts of glyphosate with cationic and non-ionogenic О33О5М and О33Е5С, containing amine stabilizers and surface-active substances. Salt with a short chain was similar in effectiveness to glyphosate and the concentration in g c.e.u./l for each tyu of the Kospadyr Oigamakh standard or exceeding the composition and other components are as indicated by her. not in the table but in example 150.

Example 150

The effectiveness of the stabilizers was evaluated

Table a of example 150 o43zAZS | IRA | 360 | cS27 | 64 | si3 | 96 | Stu | 1 04389М со 043030 с109 043011. С107 043ЕБС sto8 043ЕВК с109 с109 с43019 слох 043АЗС contains additionally 1.595 ТНЕ-ОН (С114) "х 043011, 043Е50, 04З3Е8К and 043010, each, contain additionally 1,5(С91) octylamine

Compositions of table a of example 150 and comparative (ESNSRE). The results in the form of the average flax concentration of IRA-glyphosate were applied to the ros- for all repetitions of each treatment are shown in the flax of Theophrastus (AVITN) and millet semi-tables B and c of example 150.

Table B of the example of 150 units of AVITN suppression 17 days after treatment 100g c. e./ha 200g c. e. 817 |777171790111111958 043030 043011. 1275 | Du 7b7 | .-.yuYu 80.77 17883 043Е5О 04ЗЕ8К

Table from example 150 of suppression of ESNSE 17 days after processing 7771 04ZAZS | 77777 65 | 7777оив3 1 |777171711780111171111185 2 ЮШШЩ 04363077 | 7777/7575 | 725 | -:| 80 ю8852Ж !«Ф 7 o43ЕЯК | 77533 | 708.4. | .ЮюЮЬРещАдюггб | .YUYuzhvo0 shi (Comp. 725K. 77777777 Я717171717333 7771711 483 | 7567 |. 6024

Effectiveness of compositions 043Е5С, 04ЗЕ8К and IRA salts of glyphosate with cationic and nonionic 043010 containing amine stabilizers with short surfactants. Salt by chain, was similar to the effectiveness of Staglyphosate and the concentration in g c.e.u./l for each ndart Koppdir Oigamah on the Theofras ropeway - compositions and other components are as specified or exceeded It. not in the table but in example 151.

Example 151

The effectiveness of the stabilizers was evaluated

Table a of example 151 044AZH | IRA | from 60 | p27 | 64 | p43 | 96 | hundred | 1 K( x 043АХ contains additionally 1.595 TNE-OH (С114) x 04307у, 043Е2К, 04317 and 04300Р, each, additionally contains 1.595 octylamine (С91)

Compositions of table a of example 151 and comparative (ESNSRE). The results in the form of the average flax concentration of IRA-glyphosate were applied to the ros- for all repetitions of each treatment are shown in the flax of Theophrastus (AVITN) and millet semi-tables B and c of example 151.

Table B of example 151 about suppression of AVIyTN 17 days after processing 7 04407u | 7.35 ..Uts | Bk at 742 | 867 24Ю« | sh 9 2 yuzhKks 7 o44BZHK | 467 | 783 2 shshshch | 8672 4Ю | BzhkK 90 2 245-e 0441 | 77776077 77771758 |7771777875 17717111 9011 7 o4deoR | 4587 | 7 775 | 858 2 shsh | 2 rooms 9 56 rooms x 4 rooms

VoypatsrShamakhi | 7777733 | 7777/7992 |. 883 2 2YUDsch | sh 90 6yuzyah

Comp. 725K.// | 77771707 Y7717171717171401|777171117775 | 792 (

Table from example 151 of suppression of ESNSE after 17 days of treatment with TK z i o o PO: Х Я PO: POL 04405677 | 77/54 77777773 |777717117711 11111861 044 | 44 | 777765 2 | 77768 2 2 Yushchf| shf84 2 25B k 0441 | 77748 | 77766777 | 77777v6877|1711711174

The effectiveness of all compositions was equal to the evaluation of the compatibility of the stabilizer mixed active- effectiveness of standards in experiments with a rope rope composition containing about 35.7 wt.9o

Theophrastus or exceeded their effectiveness. potassium salt of glyphosate and about 3.1 wt. by a.i. 2,4-

The efficiency of 044АЖХ, 044050 and 04300ОР that mis- O (experiment 018АЗО contained about 41.9 wt. - the surface-active components hidden below exceeded the efficiency of the Koppdir standard

Shkgamakh on the rooster's millet. substances (surfactants) and stabilizers (Stab.)

Example 152

О015ЕЗС | standing | 92 | cm | 28 | 6 g of KZhZbb/ o og4NZE | Sig4 | 92 2 | sSbi25 | 40 | (698 gyu ZhShDshch,1/

And o18AZO | with you! | 98 | - | - | 83 g

In suppression of morning glory (IROG A) 5 days after treatment with compositions of potassium salt of glyphosate 2,4-0 and standard composition 3041 11 o1ЯАХТ | 777 617777 Y777717171711707771117|771717171717887717 1119011 0148 | 64 | 77777775 | 7777783... |рюЙ18в11 1 о04с5М 77777637 71171711 811117111111861 7 04ооК | 77776077 777171717178477777|7771717171717871117|Fr1118611 771 015ЕЗС | 68 | 77777711 |77171717171718211 111184 of God 77771761 771717171717757 | 77777782. 77777862 77 o24НЗЕ | 64 | 777768 27 | 77177771 | oregl7lv 77

Uvi | 61 2 2 | ..Юююююйл 2 shushch | 86 4 yuYuyush | 88 25 kz in

All the tested compositions gave results that were statistically the same in terms of the positions of the potassium salt of glyphosate y2,4-O and stan. 906 suppression by dart composition 3041 netreby (KHAM5T) 7 days after processing the com- 014889 | 777207... | ..YuyuYuYuYuyuzhyaaz 2 4yuyu|ryIvv ii os 77777211 11111117 11116011 1111181

And oya4rok | 77720 ||. |v nyn khz i y Po o PO Z U i PO s PO nn hi ie si ah I PO: TYA POT po shi Sat Sat I Fri: po PO po PON

The effectiveness varied depending on the compatibility assessment of the stabilizer of the mixed ac- rate of application. At 100g/ha, 015EZS and 024ANZE of the composition containing a sample amount were more effective; at 200 g/ha, the composition of the potassium salt of glyphosate (given in wt. /ha composition 02412X gave the highest content of surface-active substances (surfactants) and efficiency. stabilizers (Stab.)

Example 153 so di SCHO; about oz4V5E | 349 | 29 | Article 29 92 | si28 | 27 | 60 yuKzhKshch/6 uo suppression of ХАМ5Т after treatment with compositions of the potassium salt of glyphosate «2,4-О0 and standard composition 3041

All compositions gave statistically the same glyphosate and the components listed below. Constant efficiency at all rates of application. soreness was assessed after 3 days at 50"C and at

Example 154 at room temperature. Table 154a represents

Stabilizer Compatibility Evaluation Tests give composition data, and Table 15406 presents 762 and 542 compositions containing 30.595 c.e. IRA - results of stability.

Table 154a

Table 15465

This invention is not limited to the above, and this invention can be applied in its numerous variants above and can be modified in various ways, the most convenient for specific requirements. The above description of preferred applications. options is intended only for familiarization Example 155 of other specialists with qualifications in this field with the Evaluation of the compatibility of the stabilizer mixed with the present invention, its principles and its practical composition containing potassium (K) or IRA tical application, so that other specialists with ( I) the salt of glyphosate (given in mass.bo c.e.) and 2,4-0 qualification in this area could be adapted (given in mass.9o c.e.) or in the form of acid (A),

or in the form of IRA-salt (I), and the listed components of surface-active substances (surfactants) and stabilizers (Stab.).

Table 155a 5594M | 28703) | 16) | si2ha | 92 | - | - 559-888 | 287(yuYu | 130) | sow | 92 | - | - 559-335 | 287(Y | 16 | si29 | 92 | - | - 55975 | 28703 | 30) | p129 | 92 | - | -

Compositions of table a of example 155 and compare (ХАМ5Т). The results in the form of an average for the flax composition of KoshpdyrzhO Oigatakh and ET Mavie of all repetitions of each treatment are shown in tab.

Table B of example 155 of IROGA suppression thirteen days after treatment: НН и У и о з п По: ТЯ ПО: У 55935 2ЮЩ | 46 9 | 7 2 shshsh | 82 5 shSh | 80 5 жщзруб'( 15597 | ...юЮюЮюЮюжьйва7 | 77777772 |7777171717178177117 11111861 7 89УАЗО 77777787 77777784 |77777171778611111 11111821 569-224. | .Ю.Юь/У ;Н 66777807 |77717171717182117 11111188 ее

Table from example 155

Uo suppression of KHAM5T thirteen days after processing 1 5BIZEN | -

Efficacy of 2,4-O in the acid form and in the form had little effect on efficacy. salt is the same. Dipropylene glycol did not affect Example 156 efficacy. Oxalic acid and octylamine Evaluation of the compatibility of the stabilizer of mixed ac-

tive composition containing potassium salt glypho- (Stab.). Regarding the composition of the compositions, see satu, 2,4-O and the listed surface components - table 156a. active substances (surfactants) and stabilizers

Table a of example 156

BovAZM | 405 2 Shshch | -( 072 | p129 | 725 | - | - 5о6ВбО | 406 2 sh- | -:(X 0071 | p129 | 725 | - | - o BoА5T | 416 | -/: 0607777 | p124 | 760 | - | - o 5B 'оВ3О | 405 2 щЩщ | -( 060 | с1и24 | 760 | - | - о BOVAT. | 405 2 щЩщ | -( 072 | с129 | 760 | - | - 5о8ВЙ | 405 2 ЮщЩщЦЦ| -( 072 | с129 | 760 | - | - o 5o3VN | 404 | yuyu 066 7 | s124 | lo | /- | - o BODABU | 404 | -.KIy 0.65... | s124 | 910 | 7 - | - o 504vYAK | 405 2 шЩщ | -(Х 0074 | с1и29 | 910 | - | - о 505а2С | 405 7 | 7 0072 | с129, | 910 | - | - lova | - 324 | -..р/ю/ 760 | с124 | 920 | - | - OBBAZE | 319 | 160 | s1i24 | 9lo | 7-7 | - about BOLA2MU | 324 | -/| 66 | s1i29 | 920 | - | - about Bovbn | 324 | -.-./u/i82 | s129 | 910 | 7 - | -

The compositions of table A of example 156 and compared were applied to morning glory plants (IROH A) and non-demanding compositions of Koipadire Opgatakh and/or standard (KHAM5T). The results in the form of an average for (51054M) containing 260 g.e.u./l IRA-glyphosate, of all repetitions of each treatment are shown in tab. 2.6g.e.u./l IRA 2.4-O and 9.8wt 9o ethoxylated faces p, c and a of example 156. (6 EF) talloamine as a surface-active substance

Table 5 of example 156 before the suppression of IROGA 11 BOvAZM | 7777777 30777777 Y77711111116811111111 11111151 1 506 VBO 77777733 11111148 |77777111111801171 11 BOVAT | 77777773 11118011 111 50 MABU | 777777777732 |in 1111 БО5БА2С|Й7777777771128771 11111116 11111181

Each composition had a higher efficiency than the standard OKhattah. The IRA standard provided the highest efficiency.

Table with example 156 catch | 7777/6077 77777171717771117 11171189 // o8BAZE | 7 60777777 77777778 17717171 79111 11111832 7 50vbnN | 7777 63 7777783 77171780171111911 7 o47VY | 77777787... | ..ЮюЮюЮюыв86 7 |77р7рЙ719017 111934 p ET p i PO: To PO 7: ZON ON: TO

Compositions 047811. and О59А0И gave a higher overall suppression of IROGA than standard 51054U.

Table a of example 156 suppression of KHAMZT 10ov8a 771739. | ..YuriurD695 41177173 |...

O8BASE

BOTA2MU

BOTvbN 047811.

OBODOY niny shi shin shi tyny write pi 51054

Compositions 047811, 059A0I, 501A2MU/ and 5О1В6Н application. gave a higher overall suppression on The authors note that when used

KHAMZ5T than standard 51054UM. the word(s) “contain” or “contains” or “what

This invention is not limited to the "contains" in the entire description (including the above variants and may be in different ways below the claims), if there are no other codified. The above description of the preferred verbs, these words are used on the basis and with variants is intended only to introduce a clear understanding that they should be interpreted as "including" and not as given the invention, its principles and its prac- "those that exclude", and what the authors have on the tical application, so that other experts mean that each of these words should be interpret- qualification in this area could adapt in this way when considering everything is given and apply this invention in its numerous descriptions. forms that are most convenient for specific requirements

Computer layout L. Lytvynenko Signed Circulation 26 approx.

Ministry of Education and Science of Ukraine

State Department of Intellectual Property, str. Urytskogo, 45, Kyiv, MSP, 03680, Ukraine

SE "Ukrainian Institute of Industrial Property", str. Glazunova, 1, Kyiv - 42, 01601