UA79074C2 - Compositions and herbicidal concentrates, methods to treat plants - Google Patents

Abstract

A herbicidal composition is provided comprising an aqueous solution of N-phosphonomethylglycine, predominantly in the form of the potassium salt thereof, at a concentration of at least 300 g a.e/l of the composition; and a surfaclant component in solulion or stable suspension, emulsion, or dispersion in the water, comprising one or more surfactants in a total amount of about 20 to about 300 g/l of the composition, wherein the composition has a viscosity of less than about 250 centipoise at 0 0C or a Gardner color value less than 10.

Description

steels containing the specified surface-active 1, p represents the average value from 0 to near-substance, form transcuticular hydrophilic co 5, ВЗ, ВУ, В», Ве and В" independently represent channels through the cuticle of the specified plant. hydrogen or Si-Ca hydrocarbyl, C independently represents 11. The composition according to any of items 1-7, which is not essentially a Co2-Ca alkylene, 4 is 0 or 1, g of liquid crystals containing the specified surface numbers from 0 to 4, 5 equals 0 or 1, i equals 0 or a non-active substance, but has such a composition as 1, zid is an open or cyclic structure - when this composition is applied to a plant, it forms a ru obtained from sugars, hydroxyalkyl group, polyhydric liquid crystals containing the specified surface hydroxyalkyl or poly(hydroxyalkyl)alkyl, and a co-active substance in the aqueous layer on the surface has an average value from 1 to about 2, and is an anion of the plant. m is equal to the average value from 1 to 12. The composition according to any of items 9-11, where C and m is equal to 0 or 1 so as to preserve the neutrality of the molecule. water from the specified composition. 15. The composition according to any of paragraphs 1-13, where indicated 13. The composition according to any of items 1-12, where the indicated surfactant is selected from the group that said surface-active component preferably includes: contains one or more surface-active (a) alkylated poly(hydroxyalkylamine) compounds, each of which has a molecular structure that includes: (1) a hydrophobic group having one or more independently saturated or unsaturated, branched or unbranched, aliphatic, alicyclic, M (rd) of aromatic or aromatic C3-Siv hydrocarbyl or where B" and 23 independently represent hydrogen, hydrocarbylidene groups connected to each other from rocarbyl or substituted hydrocarbyl containing

O to about 7 bonds, independently selected from 1 to about 30 carbon atoms, 2 in each ether, thioether, sulfoxide, complex-X(B2O) group independently represents Co-Ca alkylene; of ether, thioester and amide bonds, B is a hydrocarbylene or a substituted hydrogen, and this hydrophobic group has a total of / number of rocarbylene, containing from 1 to about 30 carbon atoms, where U is from about 8 to about 20 carbon atoms, BZ is hydroxyalkyl, polyhydroxy 30; and sialalkyl or poly(hydroxyalkylalkyl; x has an average of (2) a hydrophilic group comprising: a value of 0 to about 30, y is 0 or 1; () an amino group which is cationic or which may be (B) an alkoxylated amine oxide of the formula: protonated to a cationic group and attached to an average of 0-3 oxyethylene groups or polyoxy(vo) pits of ethylene chains, where these oxyethylene groups and x and polyoxyethylene chains contain, on average, KO, (Zg) no more than E number of oxyethylene units on the mode K' represents hydrogen, hydrocarbyl or a surfactant molecule, so that hydrocarbyl containing from 1 to about 30

Eku "50. or carbon atoms; B? in each x(B2O) and y(B20) group (i) a link of an alkyl derivative sugar, such as gru- is independently a C2-Ca alkylene; c represents a glycoside, polyglycoside, or aminoglycoside, which is a hydrocarbylene or substituted hydrocarbylene, containing on average no more than about 2 containing from 2 to about 6 carbon atoms; Ki links of alkyl derivative sugar per molecule according to A: each independently represents hydrogen, a hydro-surface-active substance; rbyl or substituted hydrocarbyl, containing from 1 and the indicated hydrophobic group is attached: (a) to about 30 carbon atoms, -"(НеО)п(В'ОУН; Not directly to the amino group of the indicated hydrophilic- is a hydrocarbylene or substituted hydrocan group, (b) to the specified hydrophilic group for rbylene containing from 1 to about 6 carbon atoms by means of an ether bond that includes a ring atom, VK" represents hydrogen, a straight line or a branch of one of the specified oxyethylene groups, or a branched alkyl group containing from 1 to about 4 terminal oxyethylene units of one of the specified carbon atoms, n is 0 or 1, x and y are independent of polyoxyethylene chains, or (c) to the indicated zh have an average value from 1 to about 60; a hydrophilic group by means of an ether bond (c) alkylated diamines of the formula: with one of the specified units of an alkyl derivative of sugar. 14. The composition according to any of clauses 1-13, where the specified surface - the active component mainly in (33) includes one a because several compounds of the formula de KE! is a hydrocarbyl or substituted hyd-

GAIA(ХА tА (МАУ p (АВО)в-(АИ а (МАУ АЕ-(СНг) г)в-би! db 8 dob 30 (MAMY ONMAm, (5) rocarbyl containing from lyzKo, to lyzKo where E ! represents hydrogen or C-C3 hydrocarbyl carbon atoms; MC in each ХК) Group в о) and X independently represents an ether group independently represents C2-C4 alkylene; independently represent hydrogen, hydrocarbyl, thioester, sulfoxide, ester, or substituted hydrocarbyl, containing from 1 to thioester or amide bonds, each EE of about 30 carbon atoms, or -"ВгОУВ7; ВА яв-лвпяе соб is C2 - This is podrocarvilidene, 8 is hydrocarbylene or substituted hydrocarbylene, the total number of carbon atoms in В'(ХАg, doro bilene, containing from 2 to about b carbon atoms from about 8 to about 24, n is equal to 0 or this, " C(-MA U, (5). or (0); H" represents hydrogen, or a straight or branched alkyl group containing from 1 to about 4 carbon atoms;

A", B: and c"Z represent hydrogen, hydrocarbyl or substituted hydrocarbyl containing from 1 to "B o (vgouvz (40) about 30 carbon atoms, x has an average value from 1 to about 30 y has an average value from or 1 to about 50, provided that at least one of the 1st century

ВЗ, В and РУ is -(B2ОУВ'", at least one B? is not ethylene, ER" is not unsubstituted pro-, ve ve pylene, B! is not unsubstituted alkyl, or x dori- in -- m-- (pg20), (82-X) ranges from 2 to about 30;

V ok ok or - 2 from what v ve (now (34) | v, where V' is a hydrocarbyl or a substituted hyd- t x---(VO) v d v rocarbyl containing from about 6 to about 30 " of carbon atoms, or -B'5B?, B and B?

X(B2O) and y(22O) group independently represents Co-Ca "7, (ag) alkylene, EZ represents hydrogen, straight or branched or alkylated alkyl group containing from 1 to about 4 carbon atoms , E? represents a straight or branched alkyl group containing from about 4 and « A p to about 15 carbon atoms, x and y independently in--m-- (620), YOU have an average value of 1 to about 40; | | in (is) dialkylated alcohols of the formula: dov: te oso (43) vchovho-yaA-o-(OUV 35) where E", V? and DV!? independently represent hydrocarbyl, where K" independently represents hydrogen, straight or white or substituted hydrocarbyl containing from 1 to a branched alkyl group containing from 1 to about 30 carbon atoms, or -(B2O)pA!Z; B? in about 4 carbon atoms, K?2 in each x(B2O) and each t(B2O), p(B2O), p(B2O) and a(22o) group is independent of the y(82O) group and is C2-Ca alkylene, is a Co-Ca alkylene: BEZ.B8, B!DV!Z and

BZ is a hydrocarbylene or substituted hydro, BZ is independently hydrogen, or a hydrocarbylene containing from 2 to about 30 carbyl atoms or a substituted hydrocarbyl containing from 1 carbon, x and y independently have an average value of up to about 30 atoms carbon; B" represents - nya from 1 to about 60; and (СНгУОВ!З or -(СНгУО(Б2О)аНЗ; Б, Ве ии Б" non-

FO compounds of the formula: usually represent hydrogen, hydrocarbyl or

P is a substituted hydrocarbyl containing from 1 to about 30 carbon atoms, or B"; B'"E is a hydro-3 carbylene or a substituted hydrocarbylene containing o--(who0)8z (36) from 2 up to about 30 carbon atoms; is hydrocarbyl or substituted hydrocarbyl, either containing from 1 to about 30 carbon atoms, or

And in B! --"H2):O(82O)rAZ; t, p, r and d independently have se-

ХХ where the mean value is from 1 to about 50; Х represents the battle cell -0-, -М(В!4)-, -С(0)-, -С(000-, -ОС(0)-, - / and М(В15)С (0)-, -С(О)М(В5)-, -8-, -8О0- or -80»-; va o -(в20),83 is equal to 0 or 1; A" is a rural economy; ( 37) donatively acceptable anion; y and 7 are independently dor- or y nions of a total number from 0 to about 30. and y 16. The composition according to any of items 1-13, where the specified ve surface-active substance is selected from the group, what

In x- (BO) Yan includes: Y Y t r (a) aminated alkylated alcohol of the formula: o--(820),83 (38) ve or vosvyuutsyu

A: vv Ve vom (vo), or I

Ko (go) and A in ; (39) tOo---(220), --83 m --vm or (av) de V! is a hydrocarbyl or substituted hydrocarbyl containing at least 7 carbon atoms

this one; 2 in each x(K2O) and y(22O) group independently, ve is a Cg2-Ca alkylene; EZ and VUE are each independently a hydrocarbylene or a substituted hyd- and -m eV --mx---25. ud rocarbylene containing from 1 to about 6 carbon atoms; P" represents hydrogen, hydrocarbyl, or in (49) a substituted hydrocarbyl containing from 1 to about 10 carbon atoms, a hydroxy-substituted hydrocarbyl, ВИЗ, -С(-0)МВ'2ВЗ, -С(-5)МВ'гВЗ in HM leads or, together with RE and the nitrogen atom to which they are added, form a cyclic or heterocyclic В2 ве ring; B5 is hydrogen, hydrocarbyl or hydrogen; (50) substituted hydrocarbyl containing from 1 to about where P", A", NU, A? and K" independently represent 30 carbon atoms, hydroxy substituted hydrocarbyl, hydrogen or hydrocarbyl or substituted hydrocarbyl,

De vka AN to s fe ov - or together with a nitrogen atom, do shl pp ; ; to which they are attached, form a cyclic or refined plrecaroyl" that is connected to a heterocyclic ring; is hydrogen, | With and "this, and a branched alkyl corpse containing ChDrocaroylene, or substituted pdroarslene, Which

T to about 4 carbon atoms. KO. NN showed. B" each represents hydrocarbylene or is substituted by hydrogen, hydrocarbyl, or substituted hydrocarbyl, B: is hydrogen, hydrocarbyl, or substituted hydrocarbylene containing from 2 to about 4 substituted hydrocarbyl containing from 1 to about carbon atoms, K": represents hydrogen or hydro- 30 carbon atoms, hydroxy-substituted hydrocarbyl, carbyl or substituted hydrocarbyl, containing from 1 -(Ве)а-(В29ВВ7, -С(-МА')МВ2ВИЗ, 0 -0 (-0)МВ2ВИЗ up to about 30 carbon atoms, t equals 0 or 1, or -С(-5)МВ/2ВЗ, n equals 0 or 1, x and y nezap has an average value from 0 to about 40, X lying have an average value from 1 to about represents -С(0)- or -5О2-, 2 represents - 60, and A- represents an anion acceptable for soils- С(0)-, A represents an agricultural co-host compositions, provided that when B? is a unique anion, and BZ is isopropylene and x is equal to 1, B! (ve) poly(hydroxyalkyl) lamins of the formula: is not alkyl or РЕ" does not represent -(820)ВВ" ; in --m- A-vz (p) hydroxylated amines of the formula:

She (51) t M-- b dz de V! represents hydrocarbyl or substituted hydrocarbyl containing from about 4 to about 30 b2 carbon atoms, or -B"ОВ?5, B? represents vo-y; (46) I I 0. day or hydrocarbyl or substituted hydrocarbyl , where Kk is hydrocarbyl or substituted hyd- containing from 1 to about 30 carbon atoms, 23 rocarbyl containing from about 4 to about 30 is hydroxyalkyl, polyhydroxyalkyl. or carbon atoms, K" is hydrogen, hydrocar- poly (hydroxyalkyl)alkyl, B is hydrocarbyl or substituted hydrocarbyl containing from 1 to bilene or substituted hydrocarbylene containing from about 30 carbon atoms, K" is hydrocarbyl or substituted hydrocarbyl containing from 1 to about 18 carbon atoms, B? is sialcl, / polyhydroxyalkyl, or hydrocarbyl, hydrocarbyl or substituted hydrocarbyl, which is (hydroxyalkyl)alkyl; contains from about 1 to about 30 carbon atoms- (c) diamine of the formula: this; k-xX--yam -5 M -n5 (I) dipoly(hydroxyalkyl)amine of the formula: i vb--m 582 8-2 55

M av) where K", B? and Ah independently represent hydrogen, in z (BU hydrocarbyl or substituted hydrocarbyl containing where B! and BZ independently represent hydrogen or from 1 to about 30 carbon atoms, or - hydrocarbyl or substituted hydrocarbyl containing

ЧО ОВ", ВZ is a hydrocarbylene or from 1 to about 22 carbon atoms, В? is a co-substituted hydrocarbylene containing from 2 to about 2 hydrocarbylene or a substituted hydrocarbylene with about 18 carbon atoms, K? and A? are each so- containing from 2 to about 18 carbon atoms, and 7 hydrocarbylene or substituted hydrocarbylene, and АХ are independently hydroxyalkyl, poly- containing from 2 to about 4 carbon atoms, BU!hydroxyalkyl or poly(hydroxyalkyl)alkyl;

A" independently represent hydrogen, hydrocarbyl (94) salts of quaternary poly(hydroxyalkylamine) pho- or substituted hydrocarbyl containing from 1 to rmula: about 30 carbon atoms, t equals 0 or 1, n vz x equals the average value from 0 to about 40, X represents -С(0)- or -502-, A" represents an agriculturally acceptable anion; and, (vv) j) mono- or diammonium salts of the formula: ; c) form where B! is hydrocarbyl or substituted hydrocarbyl containing from about 4 to about 30 carbon atoms, 2 and BZ are independently carbon, P2 in each x(B2O) and y(220) group is non-hydrogen, hydrocarbyl or substituted hydrocarbyl, which is a C2-C4 alkylene, BE is a group containing from 17 to about 30 carbon atoms, B" is hydrogen, a straight or branched alkyl group, which is a hydroxyalkyl, polyhydroxyalkyl, or contains from 1 to about 4 carbon atoms, B is - poly(hydroxyalkyl)alkyl; is hydrogen, hydrocarbyl or substituted hydr- (n) triamine of the formula: rocarbyl containing from 1 to about 30 carbon atoms, x and y independently having an average value of 4 from 1 to about 40, and X is a rural

M m is a freely acceptable anion; in M two (y) salts of monoalkylated quaternary ammonium of the formula: x 1 - in ' (59) and x where E! is a hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms; P2, VU, B" and BZ independently represent in - (66) hydrogen, hydrocarbyl or substituted hydrocarbyl, where K' and E? independently represent hydrogen, hyd- contains from 1 to about 30 carbon atoms, or - rocarbyl or substituted hydrocarbyl containing (883)5(B'O) Be; B is hydrogen, straight or from 1 to about 30 carbon atoms, B" is a co-branched alkyl group containing from 1 to 6 hydrocarbyl or substituted hydrocarbyl , that about 4 carbon atoms, B" in each p(B/C) group contains from 1 to about 30 carbon atoms, P? in independently represents C2-Ca4 alkylene; BZ represents each x(К?О) group independently represents is C2-Ca is hydrocarbylene or substituted hydrocarbylene, alkylene, KZ is hydrogen, a straight or branched containing from 1 to about 6 carbon atoms, a substituted alkyl group containing from 1 to about equal to the average value from 1 to about ZO of carbon atoms, x has an average value from 1 10, 5 is equal to 0 or 1, x and y are independently equal to about 60, and X represents the total number of farmers is from 1 to about 4; sko acceptable anion; and their mixtures, where the pesticides are not bactericides, (are) quaternary ammonium salts of the formula: if the composition contains a surface-active compound of group (a) or (a). 17. The composition according to any of paragraphs 1-13, where it is indicated in! this and the surfactant is selected from the group that now: includes: (a) a secondary or tertiary amine of the formula: ve (87 v! m where B", BZ and B" independently represent hydrogen,

SHU hydrocarbyl or substituted hydrocarbyl containing 1:92; (653) y y y from 1 to about 30 carbon atoms, B? represents sodium, K" represents a hydrocarbyl containing 1 to about 30 carbon atoms, and X: hydrogen or hydrocarbyl, containing from 1 to is agriculturally acceptable about 30 carbon atoms; anion; (5) Mononuclear amines of the formula: () esters of amines of the formula: vok and i

M' o- t - -- M y , (64) as (68 where B' and B" independently represent hydrocarbyl groups б! b and : ) bil ab . -. or substituted hydrocarbyl groups containing from 1 where represents hydrocarsyl azo substituted hyd- up to about 30 carbon atoms, or -H?5B2, B? in rocarbyl, containing from 1 to about 30 atoms, each x(E2O) group independently represents C2-C4 carbon, Kk is a hydrocarbylene or substituted - alkylene, C represents hydrogen, a straight or branched hydrocarbylene containing from 2 to about 30 carbon atoms; EZ and B" independently represent a solvated alkyl group containing from 1 to about 1 4 carbon atoms, EE? is a straight or branched hydrogen, hydrocarbyl or substituted hydrocarbyl alkyl group, containing from about 6 bil, containing vd 1 to about 30 carbon atoms, up to about 30 carbon atoms, BU is either CHAROHA, A" in to each ХЧО) group independently: и и Ко : represents Co-C4 alkylene, BU represents a hydrocarbyl or substituted hydrocarbyl group, : containing from 4 to about 15 carbon atoms, x day, a straight or branched alkyl group having average value from 1 to about 60; contains from 1 to about 4 carbon atoms, x has (c) dialyoxylated quaternary ammonium salt average value FROM 1 to about 50; formulas: (9) diamines of the formula: om: x - 095.8 SHO were drinking

ШЯ -("2ou 2 " dz ; (69) and (65) where B, RU, and independently represent their own . contains from 1 to about 30 carbon atoms, or - rocarbyl, containing from 1 to a few atoms of (АО)ХВ"; B? and 28 independently represent hydro-

carbylene or substituted hydrocarbylene containing in 5 in d- from 2 to about 30 carbon atoms, 5 in each

Х(ВЗО) and у(290) group independently represents C2-C4 in -х- (85,- (830) Бе -(М8е);--М --Not alkylene, Е" represents hydrogen, straight or - a tinned alkyl group containing from 1 to about 7A carbon atoms, x has an average value from 1 (74) to about 30, X is -O-, -M(B2)-, -C(O)- , - or ts

С(ФОО-, -ОС(О)-, -Щ8УС(О)-, -Х(ОМ(ВЗ)-, -5-, -50- y | Я | that , or -505-, y is equal to 0 or with an average value of from 1 to about 30, n and 7 independently represent PC, or together with 0 or 1, ER represents hydrogen, hydrocarbyl, or substituted hydrocarbyl; (75) (n) amine oxides of the formula: or o- vya vo he A kn - i. i mm v -- 5-25 past - -2 y (76)

Not (70) or where В", В2 and ВЗ independently represent hydrogen, о- в5 вы А hydrocarbyl or substituted hydrocarbyl, -(В2О)ХВ?, or -VOVUKHOV; В? in each x(В7О) group is not 8 (3, (30 Ve (MV. M -- Ve is usually a C2-Ca alkylene, EE? is hydrogen, a straight or branched alkyl group, which in (77) contains from 1 to about carbon atoms, .. ! represents a hydrocarbylene or a substituted hydrocade VK", B", NU, A? A and VK" independently represent a sorbylene containing from 2 to about 6 carbon atoms containing up to about 30 carbon atoms, total the number of stomes of carbon B and up to about 50, or -(B13)(B30),B"2; X represents -O-, -OC(O)-, - carbon in K'", B- and B? glass- mV 14 c gives at least 8; o) a group with an independently representative structure: C2-C4 alkylene; Kk is hydrogen, a straight or branched alkyl group containing from 1 to about 3 carbon atoms, n has an average mass uva AI values from 1 to about 60; m has an average value from 1 to about 50; P2 and "Z" each independently in (72) is a hydrocarbylene or a substituted hyde, B, B, B? BZ is each independently a rocarbylene containing from 1 to about 6 hydrogen atoms, hydrocarbyl or substituted hydrocarbyl containing carbon; t and 5 are each independently 0 or 1; containing from 1 to about 30 carbon atoms, or - in is a hydrocarbylene or substituted hydr- (B'Z«(B3O)MV!O; X represents -O-, -OC(O0)-, - rocarbylene containing from 2 to about b atoms of c(F)O-, -( В12)С(0)-, -С(О)М(ВИ2)-, -8-, -80-, -3О»- carbon; ve is a hydrocarbylene or substituted- or -M(83)-; BZ in each p(b3O) group and m(b3O) group is a hydrocarbylene containing from 2 to about independently represents Co2-Ca alkylene; 5)- or -С(О).; is hydrogen, straight or branched alkyl di is hydrogen, hydrocarbyl or a substituent group containing from 1 to about 30 carbon atoms, hydrocarbyl containing in from 1 to about 30 years; n is equal to the average value from 1 to carbon atoms, d is equal to a whole number from 0 to about 60; m has an average value from 1 to approximately 5; IN? represents hydrogen, hydrocarbyl or substituent 50; B? | B" is each independently a hydrocarbyl containing from 1 to about 30 hydrocarbylene or substituted hydrocarbylene containing from 1 to about 6 carbon atoms; and each A is a hydrocarbyl containing from 1 to about 6 carbon atoms; B is an economically acceptable anion, hydrocarbylene or substituted hydrocar- (Yu diamine or diammonium salt of the formula: belene containing from 2 to about 6 carbon atoms- v3- - (2865 55035--М--83--М-- (8.0);--84 this; В" represents hydrogen, hydrocarbyl or substituted hydrocarbyl containing from 1 to about ЯЙ in (78) 30 carbon atoms; т and 5 each independently represents ?x- and is 0 or 1; РУ represents hydrocarbylene or о in substituted hydrocarbylene containing from 2 to about 30 carbon atoms, -С(-МА12)-, -С(5)- or - Б- - (5 ОО СМ зм (в0);-в

С(О0)-; 4 is equal to a whole number from 0 to 5; and 5 is hydrogen, hydrocarbyl or substituted hydrocarbyl; (79) rocarbyl containing from 1 to about 30 atoms where В, ВУ, В5, Бе, В? and VZ independently represent carbon; | that hydrogen, hydrocarbyl or substituted hydrocarbyl that () salts of quaternary ammonium, sulfonium and sul- contains from 1 to about 30 carbon atoms, P? in foxonium of the formula: each t(B2O) and n(22O) group and B? are independently C2-Ca alkylene, C is a hydrocarbon

rbylene or substituted hydrocarbylene containing an alkylamine are in a mass ratio of about 2 to about 6 carbon atoms, or - from about 5:1 to 11. (A2O)pAg-, t and n each individually have an average value item 1, where glyphosate, preferably in a value from 0 to about 50, p is equal to the average form of its potassium salt, is in a solution with a value from 0 to about 60; at a concentration that exceeds 300 g c.e. per liter (I) of alkylated alcohols of the formula: composition, the total amount of surface-active В'О-(820)ХВ3 (80) substance is from about 20 to about 300 g where В' is a hydrocarbyl or substituted hyd- per liter of the composition, and where the composition controls the growth of rocarbyl containing from 1 to about 30 Theophrastus rope atoms to a greater extent than the compo- carbon, 2 in each x(2O) group independently represents the zition of the same concentration of the potassium salt of glyphosate, which is a C2-Ca alkylene, EZ is hydrogen, directly contains a surface-active alkyl polyglycoside in mu or a branched alkyl group, containing from a combination with a surface-active alkoxyl- 1 to about 4 carbon atoms, x has an average known alkylamine with a mass ratio of alkylation from 1 to about 60; lpolyglycoside and alkylamine in the range from near- (t) alkoxylated dialkylphenols of the formula: ko 5:1 to 1:1.

B 26. The composition according to item 1, where glyphosate, preferably in the form of its potassium salt, is in the solution at a concentration exceeding 300 g c.e. per liter of the composition, the total amount of surface-active substance is from about 20 to about 300 g (Ov (81) per liter of the composition, and where the viscosity of the composition is nine B: independently represent hydrogen, the current is less than about 250 cPz at 5"C at the speed and en, pr"; displacement 45/s, and the indicated a surface-active compound or a branched alkyl group containing from nent contains one or more amine compounds or 1 to about 30 carbon atoms and at least of which alno has 2 and У group, У is a cyclic or aryl substituent, containing from each х) group independently represents С2-Са from about 4 to about 16 carbon atoms, and not bil- alkylene, E represents hydrogen, straight or the dissolution of ten ethylene oxide bonds in the compound, an alkyl group containing from 1 to about 1, the specified compounds are present in an amount of less than 4 carbon atoms, x is equal to the average value from 1 to 1,000,000,000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000, 1000 18 COMPOSITIONS according to any of clauses 1-17, where point 27. The composition according to clause 1, which additionally contains a water-soluble second herbicide selected from the group that the turbidity of the composition is at least close to includes acifluorfen, asulam, benazolin, benta- o H i- H ' ' ' zyms and the crystallization point is not higher than blizon, bialafoz, bispiribak, bromacil, bromoxynil, " i i carfentrazone, chloramben, chlorpyralid, 2.4 -0, 2,4- 19. The composition according to p. 18, where the cloud point of the compo- OV, dalapon, dicamba, dichlorprop, dichlofop, disition is at least about 60"C, and the point of fenzoquat, diquat, endothal, fenac, fenoxaprop crystallization is not higher than about -1070. ' ' ' '

Kr. Compositions according to clauses 1-19, where the composition is flamprop, fluazifop, fluoroglycofen, fluro-y. also xypyr, fomezafen, fosamine, glyphosinate, haloxion is largely homogeneous when stored at sifop, imazamet, imazametabenz, imazamox, imaza- 50"C for one week. и, 2, и pd : о, р M mod shvy zapik, imazapyr, imazaquin, imazetapyr, ioxynil, 21. The composition according to any of clauses 1-20, where the viscosity of MCRA, MCRW, mecoprop, methylarsinic acid of the composition is less than about 1000 cPs naptalum, nonanoic acid , paraquat, picloram at 5"С at a shear rate of 456. and sulfamic acid, 2,3,6-TVA, TCA and triclopyr. produces less than 250 CO at CU at 020. The composition according to po, where the second herbicide is selected from the group that includes acifluorfen, bialaphos,

UVU! and carfentrazone, chlorambenz, chlorpyralid, 2,4-0, 23. The composition according to item 1, where glyphosate is in 2,A-OB, dicamba, dichlorprop, glyphosate, MSRA solution in an amount exceeding 300 g. per liter of MSRV | mecoprop methylarsinic acid nona- composition, the total amount of surface-active new acid picloram triclopyr imazamet ima- substance is from about 20 to about 300 g memetabenz imazamox, imazapic | imazapir | ima- per liter of the composition, and where the indicated composition is not mis- zaquin and imazetapir. contains a dye or a coloring agent, and has 29. The composition according to any of clauses 27 or 28, where the color value according to Sagapeg is not more than 14. Y and b, 24 Compositions according to clause 1, where glyphosate, preferably mass ratio , based on the acid equivalent of sweat, di "per in the valence of glyphosate to the second herbicide, is in the form of its potassium salt, is in a solution from about 1:1 to about 200: at a concentration exceeding 300 g k.e. 30. The composition according to item 29, where the mass ratio of the composition, the total amount of surface-active glyphosate to the second herbicide is from about 20 to about 300 g 1:1 to about 301 per liter of the composition, and where the viscosity of the composition is less than 31 The composition according to any one of paragraphs 1-30, where the growth of a similar composition? - and rosette, protecting the growth layer of the plant, treated by applying the comparative active alkylpolyglycose id in combination with a surface-mixture that does not contain a dicarboxylic acid, but contains a chemically active alkylated alkylamine, and another that has the same composition as indicated where the surface-active alkylpolyglycoside and composition are indicated

32. The method of herbicide treatment, which includes application, which can be diluted with water to obtain a herbicide-effective amount of the composition of the aqueous herbicide mixture, ready for use according to any of paragraphs 1-31 on the leaves of the plant or spread on leaves of the plant, where the concentration is indicated. nitrate contains glirosate or a salt thereof, or its 33. A composition effective for retarding the growth of ether, with a concentration of at least about 500 g of plants, comprising an aqueous mixture containing poke. per liter, and a surface-active component, surface-active substance, glyphosate or its nature and concentration of the specified layer, or its ester and dicarbonic acid of the surface-active component in the specified concentration, and the specified surface-active substance rate is such that when applying the indicated ready-to- and the indicated dicarboxylic acid presented in ma- use of the mixture on the leaves of the plant, anisotropic aggregates are formed on the leaves in a ratio from about 5:1 to about the plant, which 501, and the nature of the indicated surface-active re - contain the specified surfactant. of iron and the specified composition is such that when applied 46. Herbicidal concentrate, stable during storage of the composition on the plant, on the leaves of the plant no, according to p. 45, which, in fact, does not include liquid crystals, anisotropic aggregates are formed containing inclusions that contain a surface-active substance, but not a surface-active substance. has such a composition that when applied to the plant 34. The composition according to p. 33, where the dicarboxylic acid of the specified concentrate or the specified mixture, ready-made selected from the group containing oxalic acid, before use, are formed in the leaves or on acid, glutaric liquid crystals containing the specified acid, maleic acid, adipic acid and surfactant in the leaves of the plant. fumaric acid, as well as their combination or mixture 47. Herbicide concentrate, stable during storage. no, according to p. 45, where the nature and concentration of the specified 35. The composition according to any of p. 33 or 34, where the surface-active component of the specified con- mixture, consisting of potassium glyphosate, ready-to-use monoammonium, on the leaves of plants, on lys- glyphosate, diammonium glyphosate, sodium glyphosate, liquid crystals are formed on the plants, which mis- monoethanolamine glyphosate, n-propylamine glyphosate indicated surface - active substance. satu, ethylamine glyphosate, ethylenediamine glyphosate- 48. Herbicide concentrate, stable at storage, hexamethylenediamine glyphosate, trimethylsun, according to any of items 45-47, where the concentrate includes glyphosate lphonium and their mixture. glyphosate salt selected from the group consisting of 36. The composition according to claim 35, wherein the composition includes potassium glyphosate, monoammonium glyphosate, diammonium potassium glyphosate. of glyphosate, sodium glyphosate, monoethanolamine 37. The composition according to any of items 33-36, where the concentration of glyphosate, n-propylamine glyphosate, ethylamine glyphosate is from about 400 to phosate, ethylenediamine glyphosate, hexamethylenedi- about 600g per .is. per liter of composition. amine glyphosate, trimethylsulfonium glyphosate and their 38. The composition according to p. 37, where the concentration of glyphosate of the mixture. is from about 500 to about bO0g k.e. on 49. Herbicidal concentrate, stable when stored - liter of the composition. no, according to any of clauses 45-48, containing the specified 39. Composition according to any of clauses 33-38, where in general, a surface-active substance with a mass ratio of the amount of surface-active substance to the acid equivalent of glyphosate gives from about 20 to about 300g per liter of compo- at least about 0.05. position 50. Herbicidal concentrate, stable during storage. 40. Composition according to any of items 33-39, where it is added, according to item 49, containing the specified surface-active and surface-active substance and the composition and substance with by mass ratio to the acidity that when the composition is applied to the plant, liquid crystals are formed in the bare equivalent of glyphosate at least from about 0.05 to about 0.33. contain the specified surfactant. 51. Herbicidal concentrate, stable during storage 41. Composition according to any of paragraphs 33-39, which, no, according to clause 45, where anisotropic aggregates are formed in essence, does not have liquid crystals containing the specified plant leaves when applied to the specified surface-active substance, but has such leaves of the specified mixture, ready to application, and the composition, which, when applying this composition on the surface, evaporates water from the applied mixture on the specified part, forms liquid crystals containing the specified part of the leaves. surface-active substance, in the water layer at 52. Herbicidal concentrate, stable when stored on the surface of plant leaves. no, according to clause 48, where the concentrate contains potassium glyphosate. 42. The composition according to any of clauses 33-41, where the phosate point. turbidity of the composition is at least equal to 53. Herbicidal concentrate, stable at 507C and the crystallization point is not higher than pancakes, according to any of items 45-52, where the concentration of glyphosate is 0". about 500 to about 600 g CU 43. The composition according to any of items 33-42, where the composition per liter of concentrate is largely homogeneous when stored at 54. Herbicidal concentrate stable when stored at 50"C within one week. no, according to any of paragraphs 45-53, where the concentrate has a point of 44. The method of herbicide treatment, which includes a cloudiness of at least about 50"C, and the point of crystallization of the herbicidally effective amount of the composition is not higher than about 07C according to any of items 33-43 on the leaves of a plant or plant 55. Storage-stable herbicidal concentrate, according to item 54, where the concentrate has a cloud point 45. Storage-stable herbicidal concentrate about 60" and the crystallization point is not higher than about -1070. positions on the plant on the leaves of the plant form- 56. Herbicidal concentrate, stable during storage, anisotropic aggregates containing the specified return, according to item 45, where the surface-active substance, which is a hnevo-active substance, is contained in the concentrate, according to in fact, the above-mentioned surfactant does not selectively affect the herbicidal activity of glyphosate. are from the group consisting of: 57. Storage-stable herbicidal concentrate (a) monoalkylated amines of the formula: no, according to any of items 45-56, where the viscosity of the concentrate is less than about 1000 cP3z at 0" sny, etc. And at a shear rate of 45/s. in (23) 58. Herbicidal concentrate, stable during storage B' is hydrogen, hydrocarbyl or a substitute, according to p. 57, where the viscosity of the concentrate is a less dense hydrocarbyl having at least 7 atoms than about 250 cPz at 0"C at the carbon shear rate; P2 in each x(B2O) and y(B2O) group is independent - 45/s. y o 0. y no represents C2-C4 alkylene; BZ is a 59. Herbicide concentrate that is stable when stored - hydrocarbylene or substituted hydrocarbylene, which can be diluted with water from the obtained - contains from 2 to about 6 carbon atoms; B and B5 of a ready-to-use aqueous herbicide mixture, each independently representing hydrogen, melting hydrocarbyl by applying it to the leaves of a plant, where the specified or substituted hydrocarbyl, containing from 1 to the concentrate contains approximately 30 surface-active carbon atoms, -( VU)(B2O)u87 or a component and potassium, monoammonium, diammonium, Be and B5, together with the nitrogen atom to which they are attached to sodium, monoethanolamine, dimethylammonium, dnani, form a cyclic or heterocyclic dimethylamine, n-propylamine, ethylamine, ring ; P is hydrocarbylene or substituted ethylenediamine, hexamethylenediamine, sulfonic hydrocarbylene, containing from 1 to about 6 xonium or trimethylsulfonium salt of glyphosate, carbon atoms, B7 is hydrogen or direct, and the concentration of k.e. of glyphosate consists of a branched or branched alkyl group, containing from 1 to 270 g per liter, and the nature of the specified behavior is approximately 4 carbon atoms, n is equal to 0 or chemically active component and compounds of the specified 1, x and y are independently equal to the average value of the concentrate is such that when applied to the plant from 1 to about 60, provided that B and VZ in the concentrate or the specified mixture, ready for freezing from Х(Б2О) groups is ethylene, then B! displacement, on the leaves of the specified plant, different from unsubstituted alkyl is formed, or when 5 anisotropic aggregates containing the specified surface is hydrogen or unsubstituted alkyl, then B. non-active substance. shi , is not hydrogen or unsubstituted alkyl, and when B? and 60. The herbicide concentrate, which is stable when stored - BZ are isopropylene and x is equal to 1, then B! no, according to item 59, where the nature and concentration of the specified is not an unsubstituted alkyl or B is not -""B2ОХУВ"; of the surface-active component of the specified con- (b) dipoly(hydroxyalkyl)amines of the formula: centrate is such that when applying the specified of the mixture, ready for use, on the leaves of the plant, liquid crystals are formed in the corners of the leaves of the plant, which contain the indicated surface-active substance. Concentrate according to any of items 59 or 60, where the concentration of glyphosate is from about 400 to " (28) about god k.e. per liter of concentrate. where in! | 3 independently represent hydrogen or 62. The concentrate according to any 3 items 59-61, where the concentrated hydrocarbyl or substituted hydrocarbyl containing nitrate has a cloud point of at least about 1 to about 22 carbon atoms, K?represents

C and the crystallization point is not higher than about the hydrocarbylene or substituted hydrocarbylene, 02. containing from 2 to about 18 carbon atoms, t and 63. The concentrate according to p. at least about 602C and the melting point about 8, provided that VK" and K? represent a stabilization no higher than about -102C. methyl, then K" is not octylene; 64. The concentrate according to any of items 59-63, where the viscosity of the (c) alkylated triamines of the formula: the density of the concentrate is less than about 1000 in: cPz at 0"C at a shear rate of 45/s. - in ry 65. The concentrate according to item 64, where the viscosity of the concentrate is less than about 250 cP3 at 0"C at a shear rate of 45/s. х ИЙ у 66. The concentrate according to item 59, where the concentrate has a density of ; (29) at least about 1.210 g/l. where V! is hydrocarbyl or substituted hyd- 67. The concentrate according to item 59, where the surface-active rockcarbyl containing from 1 to about 30 atoms of the substance contained in the concentrate is essentially not carbon; Rg, VU, V? and B? independently have a negative effect on the herbicidal activity of hydrogen glyphosate, hydrocarbyl or substituted hydrocarbyl, which satu. contains from 1 to about 30 carbon atoms, or - 68. A composition effective for retarding the growth of (88)5(87-O)pAE; Ve is a hydrogen or direct plant, containing an aqueous mixture, which includes in or a branched alkyl group containing from 1 surfactant and glyphosate or up to about 4 carbon atoms; B" in each p(V/C) is its salt or its complex ether, and the natural group independently represents C2-Ca alkylene; 8 and the indicated surface-active substance and compound is a hydrocarbylene or a substituted hydrokake of the indicated composition such that when applying com- rbilene containing from 1 to about 6 carbon atoms

fly n is equal to the average value from 1 to or about 10; 5 equals 0 or 1; x and y are independently equal to a whole number from 1 to about 4; under all conditions, when KE! is alkyl, PE? is not hydrogen, | And in all x is equal to C or 4, or P is not -(B7-O) 08; and---m--(b20),.-8-M (4) monoalkylated amines of the formula: | | ; go), VZ to vok )x dov? in (in; (above (43) and where B", VU and B? independently represent hydrocarbyl- (30) white or substituted hydrocarbyl containing from 1 to where P represents hydrocarbyl or substituted about 30 carbon atoms, or - (B2O)РВ"Z; B? in a hydrocarbyl group containing from 1 to approximately each t(B20), p(B2O), p(B2O) and a(B20) group of non-carbon atoms, B? represents is a C2-Ca alkylene, is a Co2-Ca alkylene; EZ, B8. B! D/Z i

BZ represents hydrogen, straight or branched B'x independently represents hydrogen, or a hydroalkyl group containing from 1 to about 4 atocarbyl or a substituted hydrocarbyl containing from 1 mev of carbon, B" represents a straight or branched - up to about 30 carbon atoms; B" represents - a female alkynyl, aryl or aralkyl group, which (CHgUOV"Z or -"(CHg)UuO(B2O)48Z; B, B and B" does not contain from 1 to about 30 carbon atoms, x may represent hydrogen, hydrocarbyl or an average value of from 1 to about 60; and a substituted hydrocarbyl containing from 1 to about (is) compounds of the formula: 30 carbon atoms, or P"; is a hydro-

CC de carbylene or substituted hydrocarbylene containing from 2 to about 30 carbon atoms; B" represents a hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms, or - (820), : "7 .(36) (СНг) ХВО; т, н , row and d independently have an average value from 1 to about 50; X represents -

And in o-, -M(VU-, -С(0)-, -С(Ф000-, -ОС(О)-, -М(А)С(О)-, x ВК where -С(О) M(B5)-, -8-, -ZO- or -50"-; and is equal to 0 or ex 1; A is an agriculturally acceptable anion; y and 75 are independently equal to a whole number from 0 to about 30. in o--(ho) C (37) 69. The composition according to p. 68, where the nature of the specified environmentally or environmentally active substance and the specified composition eE5 is such that when the composition is applied to the plant in the leaves of the plant, liquid crystals containing the indicated surface-active substance. t -x-- (vo), 70. The composition according to item 68, where the nature of the indicated behavior o--(820) versus the surface-active substance and the indicated composition 738) such that when the composition is applied to the plant in liquid form or in crystals containing the indicated surface-active

And IR into the substance, form transcuticular hydrophilic channels through the cuticle of the specified plant.

В' мМ (ВО) 71. The composition according to item 68, where the nature of the specified surfactant (v20), 8 of the chemically active substance and the specified composition n" is such that when the composition is applied to the plant, it becomes liquid, (39 ) crystals containing the indicated surface-active or substance are formed on the leaves of the indicated plant regardless of the presence or absence of another and 4 surface-active substance. t- XX-s 2520). (VIII in 72. The composition according to p. 71, where the nature of the specified story

The composition of the surfactant and the indicated composition is such that, when the composition is applied to the plant, liquid or crystals containing the indicated surface-active

A: ve substance, are formed in the leaves of the specified plant regardless of the presence or absence of another surfactant in --Mm- (6 2о), (8-X) o-- (vg0)uAz many layers of molecules of a surface-active substance (41) wine, where hydrophilic groups of molecules of a surface- or active substance in one layer of a multilayer

Av ve structures are oriented in the direction of hydrophilic ones

There are groups of molecules of the surface-active substance in the second part of the heavy layer of this multilayer structure, and the aqueous liquid can move inside the specified ve A'o--(hgo)vz liquid crystal in the hydrophilic region, inside "7, (аг) which the specified hydrophilic groups are located

of the first layer and the specified second layer. sat, diammonium glyphosate, sodium glyphosate, monoeta- 74. The composition according to item 73, where the cationic groups of the surface- amine glyphosate, dimethylammonium glyphosate, dimene-active molecules of the indicated first layer, tylamine glyphosate, n-propylamine glyphosate, ethylamine are in contact with a hydrophobic surface, glyphosate, ethylenediamine glyphosate, hexamethylenediene, on the specified leaves or inside the cuticle of the specified amine glyphosate, sulfoxonium glyphosate, or three-dimensional plant. tylsulfonium glyphosate and their mixture. 75. The composition according to item 73, wherein the hydrophilic 84. The composition according to item 83, wherein the composition includes in the region a channel for the penetration of glyphosate, namely potassium glyphosate. that in the cuticle of the specified plant. 85. The composition according to any of paragraphs 68-84, where item 76. The composition according to item 74, where the specified hydrophilic turbidity of the composition is at least close to 50"C and the crystallization point is not higher than 0"C. glyphosate cations within the specified plant. 86. The composition according to item 85, where the cloud point of the composition is 77. The composition according to item 71, where the indicated liquid crystals are at least about 60"C and the lyotropic crystallization point is not higher than -1076. 78. The composition according to item .68, which, in fact, does not have liquid 87. The composition according to any of items 68-86, where composite crystals containing the indicated surface-active position has a viscosity of less than 1000 cPz at 0"C at substance, but has such a composition that when applying a shear rate of 45/s. composition on the plant, forms liquid crystals that 88. The composition according to any of items 68-80, where the composition contains the specified surface-active substance in the zition is concentrated. water layer on the surface of plant leaves. 89. The composition according to item 88, where the density of the composition is at least about 1.210 g/l. are formed when water evaporates from the specified 90. The composition according to item 89, where the density of the composition is dori- the composition when applied to the specified leaves. injects at least about 1.215 g/l. 80. The composition according to any of clauses 68-71, where the mass 91. The composition according to clause 90, where the density of the composition dori- the ratio of glyphosate and the specified surface wool is at least about 1.220 g/l. of the active substance is not higher than about 92. The composition according to any of items 68-91, where 107. the surfactant contained in the composition 81. The composition according to any of items b68-80, where concen- essentially does not negatively affect the herbicidal tration of glyphosate ranges from about 400 to bly- activity of glyphosate. zko 6O0g k.e. per liter of composition. 93. The composition according to any one of clauses 68-91, which additionally contains 82. The composition according to clause 81, which contains from about 500 mg of a second herbicide. up to about bO0g per liter of acid equivalent 94. A method of herbicide treatment including non-glyphosate. application of a herbicidally effective amount of composition 83. The composition according to any of clauses 68-72, where the composition according to any of clauses 68-93 on the leaves of a plant or rosette contains a glyphosate salt selected from the group that . includes potassium glyphosate, monoammonium glypho-

This invention relates to aqueous compositions of pesticides containing a high concentration of herbicide, for example, the potassium salt of glyphosate, and surface-active substances or other adjuvants, including to compositions that form anisotropy and is practically insoluble in water (1.165 for lime aggregates (AA) or liquid crystals (LC) on the floor at 252). For this reason, henna is formed with it or inside the leaves of plants. In particular, this composition of water-soluble salt. the invention also relates to herbicidal compositions. It is possible to obtain monobasic, dibasic and containing glyphosate and one or more surface tribasic salts of glyphosate. However, in most of the active substances that form anisotropic pads, it is preferable to obtain glyphosate and apply aggregates and/or liquid crystals to facilitate its introduction on the plant in the form of a monobasic day, absorption and movement of glyphosate in the brine. Glyphosate salt, which is the most widely used. Also described are the methods for destroying or hiding, there is a mono(isopropylammonium) salt, which is used to control unwanted vegetation, in which vykoto is denoted by the abbreviation IRA. Such compositions are commercially produced. The invention is also related to the herbicides Mopzapio Sotrapu, which contain new surface-active substances and as an active ingredient IRA salt of glyphosate, including pesticide compositions containing such surface-active substances. Higa and CodeoF herbicides. All of them are water-based

Glyphosate is well known in this area as concentrates (5) compositions and, of course, an effective post-emergence foliar herbicide. Before applying to the leaves of plants, glyphosate is separated into its acidic form, water. Another commercially available glyphosate salt represented by the formula (1): is chewed in the form of ZI. compositions, contains a trimethylsulfonium salt, which is often denoted by the abbreviation TM5, which is used, for example, in the herbicide ToyspdompF 2epesa (Zupdepia).

Different salts of glyphosate, methods of obtaining a salt solution of the potassium salt of glyphosate with glyphosate hydroxide, compositions of glyphosate or its salts, potassium. methods of using glyphosate or its salts. The main advantage of IRA salt compared to other glyphosate salts for the destruction and control of the growth of weeds and darkness is the good compatibility of aqueous solutions of concentrates of other plants (described in the US patent Me4507250 from Wakei, patent U.S. Patent No. 4,481,026 to Rgizruia, this salt with a broad spectrum of surface- active ingredients.

Mo4315765 from I agde, US patent Me4140513 from substance" used here includes in

Russia, US patent Me3977860 from Egap/7, owns a wide range of adjuvants that can be

USA Meo3853530 from Rhap" and US patents are added to herbicide glyphosate compositions for

Me3799758 from Egap7|. The above-mentioned herbicide efficacy patents are incorporated herein by reference in their entirety. effectiveness of glyphosate salt in the absence of such

In the number of water-soluble salts of glyphosate, an adjuvant, to increase the stability, the ability of mosses in the literature, but which have never been used to form compositions or for other profitable foxes on an industrial scale before the date of submission of these properties of the solution, regardless of whether or not application, includes a potassium salt with the structure, the following adjuvant is preceded by the more traditional formula (2): the meaning "surfactant". и вы ША To improve the characteristics of the herbicide, gly-

Kk r. "in (2) phosate salts must usually be present according to Y along with the corresponding surface-active substance. and guilt The surface-active substance can be present in an aqueous solution with a pH similar to that in the concentrate of the composition or it can be equal to about 4, preferably in ionic form. added by the end user to the diluted com-

The potassium salt of glyphosate has a molecular weight of 207. spray position. The choice of the surface structure of the soil depends significantly on the characteristics of the "alkali metal" salts of glyphosate, which are used as herbicides. and, in particular, as one of the alkaline metals in volume 25, pages 275-287, Umugii and Vigpsiae, potassium was given, along with lithium, and a wide variety of surface sodium, cesium, and rubidium were listed. Example C describes active substances according to their by the ability to increase the biocidal efficiency of glyphosate, which uses a certain amount of glyphosate acid and is carbated in the form of an IRA salt.

Only a few herbicides were produced based on the performance of various surface-active substances at the mental level in the form of potassium salts. IReziiside does not enhance the herbicidal effectiveness of glyphosate

Mapiai, 11th edition, 1997|, how potassium salts perera- can be predicted. hidden herbicides of the auxin type 2,4-08 (2,4- Surfactants that give the most- dichlorophenoxy)(butanoic acid), dicamba (3,6- more significant increase in herbicidal efficiency- dichloro-2-methoxybenzoic acid), Dichloropropenes of glyphosate, of course, but not always, are cationic (2-(2,4-dichlorophenoxy)propanoic acid), MSRA surfactants, including (4-chloro-g-methylphenoxy)(acetic acid) and piclo- including surface-active substances that form // (4-amino-3,5,6-tripor-2-pyridinecarbonate cations in an aqueous solution or in dispersion with acid), active ingredients of herbicides determined by pH levels of about 4-5, which is characteristic of 51. products available from Oohm/Adgossivpsez under compositions of monobasic salts of glyphosate. Attached to the trade name Togdop. The methods are long-chain (usually Schi2-Siv) surface-active tertiary alkylamines and surface-active quaternary alkylammonium compounds. (ме09/444766, filed November 22, 1999), the full description of which is incorporated herein by reference. In it, with an experimental alkylamine used in water, it was found that the potassium salt of glyphosate in pure water with solutions of concentrates of compositions with IRA salt at 20"С has a solubility of about 5495 by weight, that glyphosate was very hydrophilic on the surface, it is about 44965 by weight of acid equivalents - the active substance polyoxyethylene (15) talloamine, tapes (k.e.) of glyphosate. These data are similar to the solubility, i.e. talloamine, which contains, in total, 15 mol of ethyl

IRA salt. The concentrations expressed here as a percentage of lenoxide in two polymerized ethylene oxides by weight refer to parts by weight of the salt or their chains attached to the amine group as an acid equivalent per 100 parts by weight shown in formula (3): solution. Thus, a simple aqueous concentrate of sNosnoOm potassium salt of glyphosate can be easily obtained; at a concentration of, for example, 4490 k.e. according to vac-M (3) that compared to commercially available salts of IRA glyphosate, such as in aqueous solutions (snesnuzhN concentrates available from Mopzapio Sotrapu with where M is a mixture of mainly seeds and seeds called KoipdirF O- Rak"m, Partially high con- alkyl and alkenyl chains, obtained from the centration can be obtained with little potal fats, and the sum of tep on average is superneutralization, from 5 to 1095, for example, water- about 15.

It was found that in some cases it is desirable to use Civ-2 alkyl ethers, which (described in the PCT publication, but to use a less hydrophilic surface - MeUMO 98/17109). Described (|in US patent active alkylamine which has less than about 10 Me5389598 and US patent Me57030151| anionic pomemols of ethylene oxide, for example, polyoxyethylene rhneoactive substances are usually not (2) cocamine, as presented |in US patent is of interest to 51 compositions of IRA salt glypho-mMe5668085 from Rogrez ei a!.). This patent describes, with the exception of the combination with cationic surfaces, examples of aqueous compositions containing such non-active substances. |In the patent "015)| describes a surfactant together with an IRA salt, a healthy mixture of surfactants with ammonium salts or potassium glyphosate. The highest con- dialkylamine and anionic compounds, concentration of glyphosate in potassium salt compositions, which reduces damage to the eyes It is indicated that the mixture

And (shown on table C of patent 085), the composition of surface-active substances is suitable for

ZbOg k.e. of glyphosate/l, with a weight ratio of k.e. obtaining aqueous solutions of glyphosate compound concentrates and surface-active substance 2:1. of different salts of glyphosate, among the salts was

GU UMO 00/59302| a class of alkylated potassium salts is described. (The patent "015| contains alkylamine concentrates, which can be used in amounts from about 5 to about 5095, mainly from herbicide compositions for spraying. It contains about 3595 to about 45905 keu of glyphosate, and from described solutions of potassium glyphosate , containing various about 5 to about 2595 surfactant

Ueytipe"m EO/RO of propylamines or propyldiamines, substances. In addition, (in the ROST publications of UMO are described here. mme00/08927 | the use of a certain composition is described

As components of aqueous concentrates of the composite ether of polyalkylated phosphates in the composition of the IRA salt of glyphosate, a wide variety with certain polyalkylated amidoamines was described. Ammonium was present. Illustrative examples are M- it was found that potassium salt, as one of the salts of gly-methylpolyoxyethylene (2) cocoammonium chloride, (opisphosate, is "suitable". was methylpolyoxyethylene (15) cocoammonium chloride, (the class of alkyletheramine, alkyletheramine salts is described in the US patent Me5317003, and described in patemonium and alkyletheramine oxide salts, which represent the US Mo5464807| different compounds of quaternary battle surface active substances are suitable for ammonium having the formula (4): for obtaining aqueous solutions of concentrates of com- was where B, B2, and EZ each represents a C-C alkyl indicated potassium salt. In this patent, it was described that groups and n are on average from 2 to 20. that when using the given surface

IU PCT publication MeuUMO 97/16969| described water-active substances in aqueous compositions with salts or solutions of concentrates of glyphosate compositions in glyphosate, they allow to increase the concentration of IRA salt, methylammonium and diammonium salts, the ration of glyphosate in the composition to very high levels - containing a surface-active compound of quaternaries and this is their advantage. tin ammonium and acid salt of primary, secondary It is likely that a more detailed analysis of potassium and tertiary alkylamine compound. glyphosate salt as an active herbicidal ingredient

Other cationic surface-active agents were complicated by a relatively complex combination, which, as indicated, are effective in aqueous solutions of the composition of this salt as highly concentrated solutions of concentrates of the compositions of the glyphosate ZI product together with the specified type of salts, include substances, (described in the PCT publication of a surfactant. For example, MeMuO 95/333791 publications. In addition, (in the PCT publication, a widely used

MeUMO 97/32476| it is described that highly concentrated in IRA compositions of glyphosate salts, namely aqueous compositions of glyphosate salts containing one polyoxyethylene (15) talamine, represented by the above-mentioned formula (3) from these cationic surfactants, is almost completely obtain with the additional addition of a certain incompatible with the potassium salt of glyphosate in an aqueous component, which increases the stability of the composition. solution In addition, the GROWTH of MeUUO publications

Exemplary glyphosate salts are 00/15037| it is noted that the surface-active IRA is mono- and diammonium salts and salts. Alkoxylated alkylamine has a weak compatibility

To amphoteric or zwitterionic surfaces with highly concentrated solutions of glyph-active substances, which, as was indicated, are effective. In this publication, it is described that the active components of the aqueous concentrates of glyphosate, in order to obtain an effective level of IRA surface positions, include oxides of the active substance in highly concentrated alkylamine solutions, such as polyoxyethylene (10-20) oxide containing the potassium salt of glyphosate, a surface-tal amine, described in the US patent, the active alkyl polyglycoside must necessarily be mme5118444). is in combination with surface-active

As reported, the use of nonionic po- alkylated alkylamine. surface-active substances as the only surface- The addition of such alkylpolyglycosides as a priming-active component in the 5th compositions of IRA leads to the formation of very viscous compositions (in glyphosate salt, it has a bad effect on the increase of ger- comparison with compositions without alkylpolyglycosides). of bicidal activity in comparison with the use Increasing the viscosity of highly concentrated com-cationic or amphoteric surface-active positions to such an extent is undesirable for various reasons. substances; the exceptions are certain alkylpoly- In addition to the fact that the process of pouring or washing the lucoside, which is described, (for example, in Australia) residues from the container becomes more complicated and convenient for some patent Meb27503|, and polyoxyethylene (10-100), obvious inconvenience the viscosity of the compositions lead to strict requirements regarding Under "storage stability" in the context of water-pumping equipment. Volumes of liquid aqueous pro-concentrate composition of glyphosate salt that increased ducts of glyphosate are obtained end- additionally contains surface-active the substance, which is used by the user in huge containers, refers to the lack of separation into phases during repeated use, sometimes called the effects of temperatures up to about 50"C for 14-28 days by shuttles, which usually have an internal pump, and, preferably, not the absence of crystals of glyphosate or a connector for an external pump, which, when exposed to a temperature of about 07, allows to pump out the liquid. Liquid water products prot for a period of up to 7 days (that is, glyphosate compositions are also shipped in large volumes - must have a crystallization point of 0"C or lower). of mothers in tanks with a capacity of up to about 100,000 For aqueous solutions of concentrates stability at liters. The liquid is usually pumped out by high-temperature storage is often determined in a tank for storage in a warehouse that uses a cloud point of about 507C or is sold by a wholesaler, retailer or more. The clouding point of the composition is usually determined by the cooperative community, from which it is assigned with continuous temperature registration, then it is poured into boats or small containers of natural cooling of the composition, with paneers for further distribution. Because of the large ralal mixing, after heating, the number of glyphosate compositions is purchased and the composition is made until the solution becomes cloudy. The temperature is transported in early spring, low-temperature indicator, taken at the moment when the solution becomes pro- the pumping characteristics of such compositions is clear, is the cloud point. Of course, they are extremely important for pain. six technical goals 5. compositions of glyphosate precisely

When added to the glyphosate concentrate, the cloud point of 50"C or more is estimated as alkyl polyglycosides (for example, Adgit!M APO- is acceptable. The ideal cloud point requires 2067 and 2-ethylhexylglycoside), the resulting product is considered to be 60"C or more, and the composition should has a dark brown color. UMO 00/15037| and have a color code of 14 to 18 crystals of the glyphosate salt. according to data obtained by the Sagapeg calorimeter. A surfactant called-

When the resulting glyphosate product is added here "compatible" with the glyphosate salt in the indicated dye with a color code according to the calorimeter data, the concentrations of surface-active substances and k.e.

Sagapeg is more than about 10, the concentrate acquires glyphosate, which is such a surface-active dark brown color. Concentrates with color - a substance that adds to the aqueous concentrate, which is difficult to dye blue with the code Sagapeg 10, or contains a surface-active substance and salt in the indicated green color, which is often necessary for the concentrations carried out, stability during storage, as differences between the glyphosate product and others was described immediately before. herbicide products. Consumers using liquid herbicides

It may be desirable to obtain stable products, the dose is usually measured by volume, and the storage of aqueous concentrates of the potassium composition is not by weight, and these products are usually produced from glyphosate salt or other glyphosate salts, which are used according to the instructions with the appropriate proportions. IRA of glyphosate salts containing permeation, expressed in volume per unit area, surface-active component used, i.e., liters per hectare (l/ha) or ounces per acre (used in agriculture, or "fully tion/acre). Thus, it is important for the consumer to be saturated with surface-active substances. concentration of the active herbicidal ingredient

Such compositions have a reduced viscosity and therefore mo- and not as a percentage by weight, but as a weight per unit must be pumped with conventional devices for volume, that is, grams per liter (g/L) or pounds per gallon of volumetric pumping at 0"C at a rate of (lb/gal). In the case of glyphosate salts, the concentration is at least 7.5 gallons per minute, usually more often expressed in grams of acid equivalent- gallons per minute and preferably more than that per liter (g c.u../l). 12.5 gallons per minute. Under the content of "surfactant Historically, IRA products of glyphosate salt from the active component used in the volume of surfactant, such as agriculture" have refers to the content of Coipaimrf and Coipaire pga herbicides from Mopzapio of one or more surfactants of Sotrap, most often mixed with glyphosate, of this type or types, and in such an amount that it has a concentration that is approximately equal to the benefit of the composition used , I will rate it - Goodbye k.e./l Product TM5 of glyphosate salts with the content in units of herbicidal efficiency in the pore surface-active substance from ToispaompF are combined with another similar composition, which is not mixed with glyphosate, which has a concentration of surface-active substance. Under the "complete ratio", which is equal to approximately 330 g k.e./l. "Saturated" product refers to a concentrate that has a low concentration, i.e. a more sufficient concentration of the corresponding surface-administered, can also be found on sale, active substance for obtaining, with standard - but damages that they bear per unit of glyphosate, which is diluted in water and applied to leaves, ger- include, above all, the prices for packaging, over-vebicidal effectiveness on one or more zenia and storage in a warehouse. important types of weed without the need for added In addition, benefits in reducing the cost and in the diluted composition of additional surface convenience for the consumer are possible if "fully active substance. saturated" aqueous concentrates of compositions, or, at least, a composition containing surface

the active component used in salt-active alkylpolyglycoside and alkylamine home economics, obtain with a concentration of tni with weight ratios between about 5:1 and 1:1, of glyphosate, equal to at least approximately (a) controls the growth of leaves compared to analogues 320g cfu/l, 340g cfu/l or much more Goodbye logical compositions of glyphosate potassium salt, cfu/l, for example, at least approximately 420g cfu/l (e) contains surface-active component, which is either more, or at least 440, 450, 460, 470, 480, does not include an effective amount of alkylpoly- 490, 500, 510, 520, 530, 540, 550 or 600g c.e. /l of lycoside, and selected in such a way that the composition or more. remains largely homogeneous while maintaining

Considerable difficulties usually arise when hatching at 507С for approximately 14 to 28 juicy concentrations of glyphosate k.e., indicated days, or (Its) contains a surface-active compound. The difficulties lie in the casting and/or re- nent that contains an effective amount of alkyl poly- pumping aqueous concentrates and arise due to the lycoside in combination with at least one addi- high viscosity of the concentrate, especially the resulting surfactant, which do not eat at low temperatures. Therefore, it is desirable to have an effective amount of a highly concentrated aqueous solution of alkylamine potassium salt. of glyphosate is completely saturated on the surface. In another embodiment, the present invention relates to an active component used in such a glyphosate concentrate that has a viscosity of "stickier than potassium salt compositions with a shear rate of 45/s, in which the surface-active satu containing surface-active alkylpolygly- component contains one or more amine cosides, as, for example, (described in PCT publications of compounds or salt compounds of quaternary ammonium.

MeUmMO 00/150371I. compound contains an alkyl or aryl substituent

There is also a need for surfactants having from about 4 to about 16 atoms of substances that are compatible with the pesticide composition, carbon, and no more than ten ethylene oxide such as aqueous glyphosate herbicide concen- bonds in the compound. Compounds are found in the amount, trat. Surface-active substances according to the above improve the compatibility of the surface-active finding to include along with the well-known pove- component with glyphosate salt. The invention also relates to compositions that active substances, which were not used before, form anisotropic aggregates containing suspensions in pesticide compositions. In order to obtain the aromatic active substance on the waxy cuticle of the leaf concentrates, which have improved viscosity, the stem of the plant on which the composition is applied is used. Other herability during storage and composition in comparison with the insecticidal compositions according to the present invention are formed by glyphosate concentrates were identifi- liquid crystals containing surface-active substances that are good substance on the waxy cuticle of plant leaves, on compatible with potassium or other salts of glyphosate, which is applied to the composition. Another herbicide that differs from the IRA of glyphosate salts. the composition according to the present invention forms liquid crystals

These and other advantages presented in this invention containing surfactant will become clear from the following description. waxy cuticle of leaves and inside the plant, on which

This invention relates to new surface-applied compositions. It was found that the composition of active substances for the preparation of pesticide anisotropic aggregates and liquid crystals, such as compositions, such as aqueous herbicide concentrates, epicuticular, and intracuticular, not containing glyphosate, or its salt, or its glass- depends on the presence or absence of the second day ether. It was also found that certain levels of surfactants and significantly improves hnevo-active substances, which were not used before- the properties of herbicidal compositions according to this were observed in agriculture, are strengthened by the finding. the action of agricultural herbicides, while Fig. A1 and A? a birefringent structure is shown, remaining compatible with glyphosate when triturated (A! at 100x magnification of polarized light storage. background; A2 at 200x magnification of polarized light

In the first embodiment, this invention refers to la) negative fan units, which are typical for an aqueous herbicide concentrate containing liquid crystals in the hexagonal phase. The composition - glyphosate, mainly in the form of a potassium salt, in a solution that forms these epicuticular liquid crystals, in an amount exceeding 300 grams of acid - consisted of potassium glyphosate and a mixture of the surface equivalent of the composition, and surface-active active substances . More precisely, the composition of the component in a solution or stable suspension, emulsified from glyphosate and surface-active substances or dispersions, consisting of one or two with a weight ratio of 3:11, potassium glyphosate and several surface-active substances with total mixture of surface-active substances Totap 1816 in an amount from about 20 to about 300 grams of E2ORA and Umisatipe 405. per liter of the composition. The composition or (a) has a viscosity of less than approximately 250 centipoise at 0"С from the speed (B1 at 100x magnification of the polarized light shift 45/s, Fig. VI1 and B2 shows a birefringence structure, (b) has the code color according to Sagapeg, no background; B2 at 200x magnification of polarized light - more than 14, if there is no dye or color) of a thin mosaic structure, which is typical for a substance, (c) has a lower viscosity, in compar- liquid crystals in lamellar phase. The composition, not with the viscosity of a similar composition of the potassium salt that forms these epicuticular liquid crystals, is composed of glyphosate, containing an alkyl surfactant from isopropylamine glyphosate and a polyglycoside surfactant in combination with a surfactant. More precisely , the composition of the glass - alkylated alkylamine, the indicated surface - was made of glyphosate and a surface-active substance

ny with a weight ratio of 3:1, isopropylamine gly- to the final user in the form of the main phosate and surfactant Rishigaias component, "ready to use".

AZ 8. The advantages of this invention are high

Pesticidal compositions according to the present invention of the density of concentrated aqueous solutions of potassium include aqueous herbicidal compositions of the potassium salt of glyphosate. Therefore, with a given percentage of the horse salt of glyphosate or another salt of glyphosate, which is concentrated by weight, the aqueous concentrate of the composition differs from the IRA salt of glyphosate, and strengthens the potassium salt of glyphosate, giving the user a much more herbicidal efficiency. contains many surface-active substances. Compositions for compositions than the corresponding composition of IRA salts of the present invention have stability in the presence of glyphosate. belching in a wide range of temperatures. Compos- In the first embodiment of this invention, the visions of this invention have also been shown to have improved viscosity characteristics in aqueous concentrates of compositions and much lighter presence of a surface-active component, which color compared to compositions of potassium salt used in rural economy, glyphosate containing surface-active alkyl- can be obtained unexpectedly high weight/volume con- polyglycoside in combination with surface-active centration of the potassium salt of glyphosate and a composition that alkylated alkylamine. Obtaining such is obtained, has acceptable or in some cases compositions with "improved viscosity" and "improved viscosity and color stability characteristics" is possible due to the choice of surface during storage. It was found that in order to achieve a non-active system that does not contain surfactants, the choice of an active alkyl polyglycoside is extremely important, and, in addition, such com- surfactants. positions are completely saturated and, therefore, when diluting In this embodiment, therefore, the present invention is diluted with water before applying to the leaves in order to reach the aqueous herbicidal compositions that do not reach the commercial level of effectiveness: it is necessary to add an additional surface - (1) M-phosphonomethylglycine, mainly in the active substance. It was also found that in the form of a potassium salt, in an aqueous solution, surface-active alkylpolyglycosides in combination with more than approximately 360 grams / M of surfactants, but not the surface-active phosphonomethylglycine acid equivalent of the hydroxyalkylamines, can you - per liter of the composition; and use to improve the properties of (2) a surface-active component in a solution of glyphosate potassium salt compositions, although more or a stable dispersion in water containing one of the preferred compositions according to the present invention, which are not or several surface-active substances, possess some improved characteristic in the amount effective for the needs of the countryside, we have viscosity, do not contain surface-active alcohols. Mostly, surface-active lpolyglycosides. In addition, to obtain the corresponding component is selected in such a way that the viscosity of the bottom composition can be used for this composition is no more than approximately 1000, the appropriate amount of alkylated alkylamine centipoise at 10"C, the cloud point is not lower than or other surface-active substance described approximately 50"C, and, preferably, glyphosate or its here, but under the control of the amount of alkylpolyglycoside, the salt practically does not crystallize when storing the potassium salt of glyphosate present in the composition. at a temperature of about 0"C in the period up to about 7

Of course, the ratio of alkylpolyglycoside and other days. More preferably, the viscosity of the non-bi-surfactant composition should be between less than about 500 centinoises at 45 inverse of about 1:5 and 5:11, preferably between about 1:5 and 1:11, seconds at 10°C, more preferably no more more preferably between about 1:5 and 1:12 and most preferably 250, 225, 200, 175, 150, 125 or 100 centipoise more preferably between about 1:25 and 1:1.5 Color and- However, under certain circumstances, when, for example, some concentrates are much clearer than the color of the concen- it is necessary to use a pump from low-temperature 14, preferably be permissible. The surfactant composition is less than about 13, 12, 11, 10.9, 8, 7, 6 nent, which is added to an aqueous herbicide or 5. concentrate composition, is a solution or

Herbicidal compositions according to the present invention are a stable suspension, emulsion or dispersion. may optionally contain one or more The word "predominantly" in the above context additional surfactants, one means that at least about 5095, preferably or more additional herbicides and/or other but at least about 7590, and, more preferably, adjuvants or ingredients, such as, for example, at least about 90,905, by weight of glyphosate, a type of carboxylic acid, such as oxalic acid, is present in the form of potassium or its salt , or its ester. Compositions for da-soli. The balance can be maintained by other salt-users by diluting with aqueous concem and/or gliroacetic acid, but preferably, ntrate of herbicidal compositions or by dissolving viscosity, cloud point and non-crystalline or dispersing solid particles, that the properties of the composition remained within the indicated limits containing glyphosate, immediately before application. yum on the leaves of plants or weeds for destruction As another aspect of this invention, it is given or control. Alternatively, the herbicidal compositions of a certain class of surface-active substances of the present invention can be delivered with expected high compatibility with concentrations of the potassium salt of glyphosate greater than 300 g c.e./l and up to about b00 g c.e./l. Therefore, the embodiment of this zno 2 units of alkyl derivative sugar per molecule of the invention is a surface-active substance that contains a surface-active substance. the herbicidal composition described above, where In such surfactants, the hydrophobic component, preferably, a hydrophobic group is attached to the hydrophilic group, one or more surface-active substances in one of the following ways: (a) directly to wines, each having a molecular structure that mis- amino groups, if present, (b) by means of tit: an ether bond containing an oxygen atom (1) a hydrophobic group containing at least one of the oxyethylene groups, if present, one hydrocarbyl or substituted hydrocarbyl or oxyethylene unit at the end of one of the polygroups; and oxyethylene chains, if present, or (2) a hydrophilic group containing (i) an amino group (c) by means of an ether bond of one of the pu units, an ammonium or amine oxide group containing an alkyl derivative of a sugar, if it present. hydrocarbyl or substituted hydrocarbyl substituents In a preferred embodiment, ) equals from twin; and/or (ii) a hydrocarbon group. ko 8 to about 25, and Ex) equals no more than 45,

The carbohydrate of the hydrophilic group is preferably not more than 40 and more preferably not a disaccharide, such as a monosaccharide, a disaccharide or a polysaccharide of more than 28. For example, compound 99) in Table 4 is a saccharide. A preferred sugar includes a glyco- includes a hydrophobic group containing in zides, such as alkylglycosides, alkylpolyglycosides and a total of 24 carbons and a hydrophilic group that aminoglycosides. Preferable are the surface- contains a total of 9 oxyethylene units, active substances containing on average no bit- so that EuU-33. Compound C includes 18 less than approximately two hydrocarbon groups per mole of carbon atoms (U) in its hydrophobic group and in the sphere of surfactant. a total of 7 oxyethylene units (E), yes,

In such surface-active substances, hydrogen is Eku-25. A hydrophobic group is attached to a hydrophilic group. In the first embodiment of this invention, the surface is one of the following ways. The atom at the end of the hydrophobic-active component preferably contains one group attached (a) directly to nitrogen or several surface-active substances, each amino group, ammonium or amine oxide group, which has a molecular structure containing: that it is present , or (p) directly to carbon- (1) a hydrophobic group having one or more hydrogen groups, if present. well, regardless of saturated or unsaturated, scattered

In a preferred embodiment, the hydrophobic group of the branched or unbranched, aliphatic, all-surfactant is a substituted cyclic or aromatic C3 hydrocarbyl or hydrocarbyl group containing, at least, or hydrocarbylidene groups connected between an oxyalkylene salt group in the main chain. battle from 0 to about 7 connections, regardless of

Such substituted hydrocarbyl groups include ether, thioester, sulfoxide, itself, for example, alkyloxyalkylene and alkenyloxy ester, complex thioester and amide alkylene groups containing from one to thirty bonds, this hydrophobic group has a total of oxyalkylene of KO groups, where K in each of the KO groups of carbon atoms, where / is from about 8 to bly- is independently a C2-Ca alkylene. zko 18; and

In the first embodiment of this invention, a surface- (2) hydrophilic group containing: non-active component preferably contains one () amino group, which is cationic or can be or several surface-active substances, each protonated to form a cationic group, and priene has a molecular structure containing: attached directly to 0-3 oxyethylene groups (1) a hydrophobic group having one or multiple or polyoxyethylene chains, these oxyethylene chains are independently saturated or unsaturated, dioxygen groups and polyoxyethylene chains, which contain in tinned or unbranched, aliphatic, ali- an average of no more than E number of oxyethylene cyclic or aromatic C3s of hydrocarbyl or units per molecule of surface-active reho- hydrocarbylidene groups connected to each other, so that Eu«k22; and/or from О to about 7 bonds, independently selected- (i) a unit of alkyl derivative sugar, such as ether, thioester, sulfoxide, glycoside group, polyglycoside or aminoglycoside ester, complex thioester and amide group, containing on average no more than proximate bonds, this hydrophobic group has a total / number of about 2 alkyl derivative sugar units per carbon atom, where / equals from about 8 to a molecule of surfactant. about Z0; and In such surfactants, a hydro- (2) a hydrophilic group containing: a hydrophobic group attached to the hydrophilic group (i) an amino group that is cationic or can be either: (a) directly protonated to form a cationic group , and the amino group, if it is present, (B) with the help of dnan directly to 0-3 oxyethylene groups of an ether bond containing an oxygen atom of mono- or polyoxyethylene chains, these oxyethylene groups, if it is present, groups and polyoxyethylene chains containing v or an oxyethylene unit at the end of one of the poly- an average of no more than E number of oxyethylene oxyethylene chains, if they are present, or units per molecule of surface-active substance (c) by means of an ether bond of one of units of guilt, so that Ezh)"50; and/or alkyl derivative sugar, if present. (i) a unit of an alkyl derivative of a sugar, such In the context of a surface-active component as a glycosidic, polyglycosidic or aminoglycosidic expression "predominantly includes" means that, a group containing on average no more than about at least about 5095, preferably at least , about 7595 and, more preferably, at least close to

zko 9095, according to the weight of the surface-active component EZ independently represents C2-Ca4 alkylene; t nent consists of surface-active substances with an average value from 0 to about 9, the total wine having the specified molecular features (the number of carbon atoms in B!-ХВ2)" consists of the structure. For these purposes, the weight or concen- from about 8 to about 18, n has an average value of the surface-active component, determined- from 0 to about 5, B? represents hydrogen, Si1-4, and here, compounds that are not alkyl, benzyl, anionic oxide groups or anionic surfactants, which are sometimes introduced together with the group -"СНг)иС(Ф)0, are not significantly included, where is equal to 1-3, Ве and В" a non-surface-active component, such as water, depending on which are hydrogen, C-" alkyl or C2-4 isopropanol and other solvents, or glycols (such as acyl, x and y have an average values at which ethylene glycol, propylene glycol, polyethylene glycol x-ump is equal to no more than the value of E, determined - and similar) above, A is an anion, 5 is a whole number

Without limiting the scope of this invention, in the com- from 1 to Z and it is equal to 0 or 1, so that electrical neutrality is extremely important in the support positions according to this invention. are subclasses of surfactants. It will be shown further that surfactants are defined by formulas (5) and (6) below. substances corresponding to the above-mentioned formulas (5)

One of the embodiments of this invention is a herbicide- or (6), including, but not limited to, the concentrate of the composition, as indicated above, where substances that can be described as alkylpolyglycosides, the surface-active component is preferably vulcosides, alkylaminoglycosides, polyoxyalkylenealkylates one or more chemically stable surfactants, polyoxyalkylene alkylpyramines, alkyl trine-active substances having the formula (5): methylammonium salts, alkyldimethylbenzylammonium salts

IV-(XA2) A (MAU A (VZO)p-(B)d- (MAU Ae- 5 salts, polyoxyalkylene M-methyl alkylammonium salts, -(CHg)de-(MA" zi OnNmMA (5) polyoxyalkylene M- methyl alkylpyramonium salts, where B! represents hydrogen or C-1iv hydrocar- alkyldimethylamine oxides, polyoxyalkylenealkylamibil, each X independently represents ether, oxides, polyoxyalkylene alkylpyramine oxides, altioester, sulfoxide, ester, thiosylbetaines, alkylamidopropylamines and the like. In an ester or amide bond, each 2 of one of the embodiments of this invention, the average number is independently Cg hydrocarbylidene, the number of oxyalkylene units, such as oxyalkylene units, averages from 0 to about 8, total tylene, if present , per surface molecule - the number of carbon atoms in В!-(ХВ2)t ranges from 22- active substance, zko 8 to about 24, n equals 0 or 1, p has where U is as defined above, and the average number average value from 0 to about 5, З, В", В, Бе units ch yucose, if they are present, per molecule and B' is independently hydrogen or C of the surfactant is no more than hydrocarbyl, C is independently C2-Ca alkyl than about 2. In another embodiment of this invention, len, 4 equals 0 or 1, g is from 0 to 4, 5 is the average number of oxyalkylene units, such as is equal to 0 or 1, i is equal to 0 or 1, zid represents oxyethylene units, if present, per mole (ii) of an open or cyclic structure, the product of the surface-active substance consists not of sugar, such as, for example, glucose or sugar (more than 50-), where ) is as defined above, and sucrose (referred to here as a sugar unit), an average amount of glucose units, if they contain a hydroxyalkyl, polyhydroxyalkyl or tne group, per molecule of poly(hydroxyalkyl)dalkyl surfactant, and has an average value of no more than about 42. from 1 to about 2, A is an anion , m has an average value of Illustrative examples of surface treatment types from 1 to Z im is equal to 0 or 1, so that sub-active substances, which have been found to be useful, are kept electrically neutral. Examples of the compositions according to the present invention include in the home of the preferred compound, which belongs to the type, itself: defined by formula 5, there is glucosamine, where ЕВ! (A) Surface-active substances corresponding to the hydrocarbon, т, р, 4, 5, 1 and m do- formula (5), where В' is Св-из aliphatic, compare 0, н, и and m are equal to 1, EZ is a saturated or unsaturated, straight or branched hydrogen, and 5yd is a glucose derivative with a hydrocarbyl chain, t, p, p, 5.1 and m/ the open structure is equal to 0, and m is equal to 1. This group includes several commercial surface-active

Another embodiment of the present invention is herbicides, well known in the field, or an acid concentrate of the composition, as indicated above, called here "alkyl polyglycosides" or "APs". where the surface-active component is mostly Relevant examples are sold Nepkei! under the name includes one or more superficial Adgits! m RO-2069 and Adgita! gm R-2076. active substances having the formula (6): (B) Surface-active substances corresponding to the formula (6), where B' is an aliphatic

МА is saturated or unsaturated, straight or branched Й Iдх (c) extended hydrocarbyl chain and t is 0. В

In this group, E" independently forms a hydrophobic group of the surfactant and is directly attached to a functional amino group, as, where B! represents hydrogen or a C-hydrocarbyl, for example, in alkylamines, or with the help of a probe, each X independently represents an ether bond formed by a thioether, sulfoxide, ester, thiooxygen atom of an oxyalkylene group, or an cladoether or amide bond by an oxygen atom, each B2 at the end of a polyoxyalkylene chain, as, for example, independently represents Sog-v hydrocarbylidene, kozhlad, in defined alkylpyramines.

Illustrative examples of subtypes having hyd- 4-5, it is clear that anion A can be glyphosate, rophilic groups, include: which is capable of forming dibasic salts. (1) Surfactants, where x and y are dori- (4) Surfactants, where BEZ represents 0, 25 and 29 independently represent Si-4 is an anionic oxide group and y is equal to 0. This alkyl, B " is hydrogen and y is equal to 1. This subtype includes commercial surfactants. The subtype includes (where BEZ and 29 each represent active substances known in the field or methyl) several commercial surfactants called here "alkyldimethylamine oxides" (where n, x and y of active substances known in this area are either equal to 0, and BZ and B" represent methyl), called here "alkyldimethylamines". The corresponding values are "alkyl ether dimethylamine oxides" (where p is an example of dodecyldimethylamine, which is available, has values 1-5, x and y are equal to 0, and ЕЕ and Б" represent co- for example, from AK20o under the name Agteep"mM OM120, and boj methyl) , "polyoxyalkylenalkylamine oxides" (where coco dimethylamine and thalodimethylamine are available, n is 0, x is 2 or more, E5 and B" for example, from Sess under the name Nigat"" ОМС 0О and are hydrogen), and defined "polyoxyalkyl-

Nigat OM5 0, respectively. Such surface-active lenalkylpyraminoxides" (where n equals 1-5, hnu substances are usually provided in the unprotonated equal to 2 or more, P and B" are in the form, the surface-active substance does not contain day). Suitable examples are cocodimethylanion A. However, in the composition of the potassium salt of glyphosate, glyphosate, available from AK2o under the name Agotoch "M, at a pH of about 4-5, surface-active chemical OMS, and polyoxyethylene (2) cocoamine oxide, the available wine can be protonated, and it is clear that anion from AKzo under the name Agotoch "m С/12. (5) Turn

And it can be glyphosate, which is able to form xnevo-active substances, where is EE? is an anionic dibasic salt. well, the group -СНг2С(О)О (acetate), x and y are equal to 0 and (2) Surface-active substances, where x and y are equal to 0. this subtype includes commercial compounds О, Р, Вб and В" independently represent C-surfactants known in this area- 4 alkyl and и is equal to 1. This subtype includes sti or called here "alkyl betaines" (where p doriv- (where РЕ", B and E7 each represent methyl and A represents 0, EZ represents acetate, Re and B" represent chloride ion) several commercial surfactants methyl) and defined "alkyl ether betaines" (where n of neo-active substances known in this area is equal to 1 -5, B? is acetate, P and B" are - or the "alkyltrimethylchlorides" here are methyl). A suitable example is coconium. Suitable examples are cocoalkyl chloride betaine, available, for example, from Nepkei! under Na- trimethylammonium, available, for example, from AKgo "M zvoi MeiYimiekh" mm AV-45. under the name Agdtsai "m sb. (C) Surface-active substances corresponding to (3) Surface-active substances, where henna dori- formula (6), where B! is Szvv-iz aliphatic, ny 2 or more, Re and 27 are hydrogen and saturated or unsaturated, straight or branched- is equal to 1. This subtype includes commercial extended hydrocarbon chain, t is equal to 1, X surfactants, known in this area- is an ether bond, B is propylene, or the so-called "polyoxyalkylene alkylamines" here, and n is 0. In this group, B! along with OB? (where n equals 0 and E? is hydrogen), determines the hydrophobic group of the surface-active "polyoxyalkylenalkylpyramine" (where n is a substance that is directly attached to functions 1-5 and BZ is hydrogen), " polyoxyalkylated amino group with the help of P: bond. Cilenmethylalkylammonium chloride" (where n equals 0 and surface-active substances are sub-

IN? represents methyl), and certain "chlorides" poly-type alkylpyramines, (described in the US patent xyalkylenemethylalkylpyramonium" (where n equals mMe5750468). Illustrative examples of subtypes have 1-5 and E represents methyl). Suitable examples of the various hydrophobic groups shown in formulas (B-1) are polyoxyethylene (2), cocoamine, polyoxyethylene (8-5) above. A suitable example is surface- (5) thalamine and polyoxyethylene (10) cocamine, available, active substance, corresponding, if the amino group, for example, from AkK2o under the name ESHoteep"m C/12, is protonated, formula (8):

ESHoteep'm T/15 and ESHtoteep'"mMm C/20, respectively; (snsnuHn surface-active substance corresponds, if its / amino group is not protonated, to formula (7): E-(0Stpsnag-- K (8) um (snisnuun

I -- (ОХжи-- M (7 surface-active substance, corresponding photo-

X of the formula (9): (snEsyuun (snsnuXHN where B! represents C1-15 alkyl, X represents ethyl, propyl or methyl ethyl, and hnu is equal to 5, B-- O(CHnuu- M--СНХ сг (9) as (described in the US patent Me57504681 |; and polyoxyethylene (2) M-methylcocoammonium chloride and polyoxyethylene (2) M-methylstearylammonium chloride are available, and a surfactant corresponding, for example, from AK2o called ESHpodiai "m C/12 and formulas (10):

ESHodiam"m 18/12, respectively. In the case when 5(snstochH is hydrogen, that is, in tertiary, as opposed to quaternary, surface-active compounds, in- o(stn-M- 5 (10) ammonium is usually not contained anion A. However, in the composition of the potassium salt of glyphosate at a pH of about "snstone" where in each of the formulas (8), (9) and (10), V' represents Me5750468|, the description of which is given here as h is 5, as described in full text. In another embodiment, surfactants other than alkylpyramines, (0) Surfactants corresponding to those described in US Patent Me5750468|, the description of which is formula (6), where B! is an aliphatic, is incorporated herein by reference in its entirety. saturated or unsaturated, straight or branched. , contains a total surface-active substance, each ЧР? represents the group -ОСН(СН3)СН»- and n of the formula (11): is equal to 0. to this group B! together with -ОСН(СНИЗ)СН»- В'В2М(СНг) MAV (11) groups forms a hydrophobic group of surface water, where В" and В2 independently represent Ca-ivs of an active substance that is directly attached phatic, saturated or unsaturated , direct to the functional amino group. or a branched hydrocarbyl chain, BZ and B" (snsnoun independently represent C-4 alkyl or hydrogen and g schi n greater than 2. A particularly preferred compound of this kA (OSNO description is a compound in which B'Ї B ? represent x SvNi?, n equals 3, and VZ and 27 represent vo- (snenoun day.

These surfactants are co- In another embodiment of the present invention, the fighting composition, in addition, a subtype of alkylpyramines (described in contains a surfactant in the general US patent Me5750468|. Illustrative examples of the formula (12): subtypes have different hydrophilic groups, examples В'ВЖ(СНСНо) in (12) which are presented in the formulas (B-1)-(В-5) above, where В! is an aliphatic, saturated (Е)У Surface-active substances corresponding to or unsaturated, straight or branched formula (6), where B is an aliphatic, hydrocarbyl chain, B and B are independently saturated or unsaturated, straight or branched C-1io, preferably C-4 alkyl or hydrogen, a hydrocarbyl chain, t is 1, X n is 1 or more, preferably 2 to 15. O is an amide bond, B is an n, at least one compound of this formula is not - propylene and n is equal to 0. In this group, К! hydrophobic group of the surface-active substance is a new compound. The structure of this compound is a substance that is directly attached to the functional amino group via the B2 bond. In SnuaSng Still nzuSn2gsSngoO);СНz the predominant surfactants of this This new compound, also how its use as groups x and y are equal to 0, B? is a hydrogen pesticide adjuvant, and especially with glyphosate, or Si. alkyl, E and B" are independently C- and even more preferably with the potassium salt of gly- 4 alkyl and it is equal to 1. A suitable example is phosate, which is within the scope of this invention. cocoamidopropyldimethylaminepropionate, available. In addition, hydroxy analogs of the above the compounds, for example, from Msipiuge under the name MasKailipe m demonstrate in particular good compatibility with the composition of the potassium salt of glyphosate. hydrogen, the addition contains a surface-active substance with one atom 3-8 and each XE represents a group - or several of the following formulas:

OoCH(CH3)CHg-. In this group, the polyester chain is ВгАЗМА(СНа) am you A? (13)

OoСсНн(СН3)СНо-group (polyoxypropylene Lande K! is an aliphatic, saturated) forms a surface or unsaturated, direct or branched hydrophobic group of the active substance, which directly or through the hydrocarbyl chain, 2, VU , In? and EZ independently one or more oxyethylene units are attached to C "alkyl or hydrogen, X is an anion, nana to the functional amino group. In the majority, n is equal to 2 or more; surface-active substances of this group, х and in В'Ф(СНаг)ом вв (14) are equal to 0, В?, В? and B" independently represent soda, while B" is Ca-iv aliphatic, saturated C-4 alkyl is equal to 1. These surface-active or unsaturated, straight or branched substances are a subtype of surface hydrocarbyl chain, B? and with independently active quaternary polyoxypropylenes are C-4 alkyl or hydrogen, n is equivalent to 2 ions (described in US patent Me5652197). In response or more; in one example, t is equal to 7, n is equal to 1, B», B'Yu(СНа) М В (СНg)za М вве (15)

Ve and B" each represent methyl, A represents where B" represents Ca's aliphatic, saturated chloride. saturated or unsaturated, straight or branched

In surface-active substances, in which the hydrocarbon chain, B2, BZ and 2" are independently equal to 1, A can be any anion, C3-4 alkyl or hydrogen, etc. independently used in agriculture, but preferably equivalent to 2 or more; represents chloride, bromide, iodide, sulfate, etho- A'F(CHng p mAg (CHg)za MA (16)) sulfate, phosphate, acetate, propionate, succinate, where K is an aliphatic, saturated, lactate, citrate or tartrate, or, as indicated above, pure or unsaturated, straight or branched glyphosate, a hydrocarbyl chain, P, B, and B are independently

In one of the embodiments of this invention, poly(oxyethylene) chains are composed of poly(oxyethylene) chains, which contain a surfactant of the class, the total amount is equivalent to or more than 3 moles of alkylpyramines (described in the US patent of ethylene oxide, t and p are independently equivalent to 2 or lec ; B" and EZ each independently represents more; day, hydrocarbyl or substituted hydrocarbyl, which

В'Я(СНОя M (СНО ес Но) И (СНСН о) (17) contains from 1 to approximately 30 carbon atoms, - where ВЕ! equals Са-иив aliphatic, saturated (8У(820)У8", or В: and PE", together with a nitrogen atom, to or unsaturated, straight or branched hydrogen to which they are attached, form a cyclic or carby chain, B? and BZ independently represent a heterocyclic ring; RU is a hydrocarby- is methyl or hydrogen, t and p independently equivalent or substituted hydrocarbylene containing from 1 linear or more than about 2 and equivalent to or up to about b carbon atoms, K is less than about 6, p and d independently equivalent to hydrogen or a straight or branched alkyl group, about 1-10 ; containing from 1 to approximately 4 carbon atoms, p

B!-X-(CHag)p-MAg З (18) is equal to 0 or 1, x and y are independently equal to s, and B' is an aliphatic Ca, with an average value from 1 to about 60, provided ny or unsaturated, straight or branched, however, what if P: and EZ in each of the x(B2O) groups represents a hydrocarbyl chain, B? and EZ is independently ethylene, then B! is another unsubstituted C-4 alkyl or hydrogen, X is an alkyl, or when EE? is a hydrogen or amide bond and n is equivalent to 2 or more; unsubstituted alkyl, then B" is not hydrogen unsubstituted by an alkyl, and when B: and EZ are isoprode, while B' is Ca-iv aliphatic, saturated, and x equals 1, then E! is not an unsubstituted alkyne or unsaturated, straight or branched radical or B" is not -(820),Щ8". In this context, the hydrocarbyl chain, BK? and VZ independently appear - it is preferable that EE" , VU, B and RU hydrocarbyl (they are C-alkyl; rocarbylene) groups included direct or

В!-МВА2-carbon (20) is a branched alkyl (alkylene), straight or branched, where P" is a Ca-s aliphatic, saturated alkenyl (alkenylene) group, straight or branched or unsaturated, straight or branched an alkynyl (alkynylene), aryl (arylene) or hydrocarbyl chain, 2 is a C-4 alkyl aralkyl (aralkylene). Preferably, B! is either hydrogen and "hydrocarbon" is carbon straight or branched alkyl or straight or day , for example, - a branched alkenyl group containing from bisnesnOonesnOnesn(enesn(oH)sNngon. In addition to zco 8 to about 25 carbon atoms, VE? in each of them is of special interest for glyphosate or other (B2O) groups regardless is a C2-Ca alkylene, which herbicide/pesticide compositions cause, Kk is an ethylene or 2- other derivatives, such as, for example, derivatives of the ethoxy- hydroxypropylene group, B and 2? each independent or non-ethoxylated alkyl or independently represents hydrogen, or a straight or branched amide of amino sugars (in particular, 2-aminoglucose).. Di-sugar amines are also of special interest in an alkyl group containing from 1 to approximately 6 carbon atoms, x has an average value of 1. to about 30. More preferably, B! represents a co-

B'AM-(OHg)a mA" (21) of a straight or branched alkyl group, which where EK is C4-8 aliphatic, saturated - contains from about 12 to about 22 carbon atoms or unsaturated, straight or branched carbon, B ? each of the x(B2O) groups independently has a hydrocarbyl chain, B? and BZ independently represents ethylene or propylene, Z represents Si. alkyl or hydrogen, n is equal to 2 or an ethylene or 2-hydroxypropylene group, B. and Bo are more, preferably n is equal to 2 or 3; each independently represents hydrogen, methyl or ХА2М(СНг)ТО-(СНаС ГНО)п-(СНг)р-MAV (22) tris(hydroxymethyl)methyl, x has an average value of PE", 82, BZ and 7 independently represent C from about 2 to about 30. Even more 4 alkyl, polyoxyethylene or hydrogen, t and p independently preferably, B! represents a straight or branched represent 2 or more, preferably 2 or n alkyl group , containing from about 12 to

C, n is equal to 1 or more, preferably 1. about 18 carbon atoms, B? in each of (220)

New surface-active substances have been studied, which are particularly preferred for use in pesticidal compositions, such as herbicides. hydroxypropylene group, B ii 2? each independent

It was found that surface-active substances are represented by hydrogen or methyl, x has an average value from about 4 to about 20. Most glyphosate, especially with glyphosate of potassium, ammonium and mainly, B! is a straight or branched diammonium. Cationic surface-active substances with an alkyl group containing from about 12 to about 18 carbon atoms are suitable for the preparation of pesticide compositions, B? in each of (220), which include: groups independently represents ethylene or propylene, (a) mono-alkylated amines of the formula: Gey represents an ethylene or 2-hydroxypropylene group, B and EZ represent po. (In (23) methyl, x has an average value of from about 4 to about 20. where B! is hydrogen, hydrocarbyl, or substituted hydrocarbyl having at least 7 atoms of the formula: carbon (which preferably contains from 8 to about 1 carbon atoms); B? in each x(B20) and y(B20) and 2 4 | in (24) group independently represents C2-Ca4 alkylene; BZ k- -ovu-ecu--i is hydrocarbylene or substituted hydrocarbyl, where E1 and 2Z are independently hydrogen, rbylene containing from 2 to about 6 carbon atoms, hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms , B? each has about 6 carbon atoms; B" is a straight line

X(B2O) group independently represents C2-Ca alkylene; or branched alkylene containing from 1 to

IN? is a hydrocarbylene or substituted hydrogen of about 6 carbon atoms, etc., independently of a hydrocarbylene, containing from 1 to about 30 atoms, with integers from 0 to about 7, sumatype of carbon, BZ is a hydroxyalkyl, polyhydroxy is from about From to 7, p is equal to the whole sialkyl or poly(hydroxyalkyl)alkyl; x has an average value from 1 to about 8, x has an average value from 0 to about 30, y is 0 or 1. from 0 to about 30, and y is 0 or 1. The most

In this context, RE", VZ and B" hydrocars are preferred - mainly, B! is a straight or branched (hydrocarbylene) group is an alkyl group containing from about 8 to a straight or branched alkyl group (alkylene), about 18 carbon atoms; IN? in each x(BE2O) group or a branched alkenyl (alkenylene) group, independently represents ethylene or propylene; From a straight or branched group, alkynyl (alkynylene) represents hydrogen or methyl; t and n are independently aryl (arylene) or aralkyl (aralkylene). The preferred ones are equal to whole numbers from 0 to about 7, the sum of alkylated poly(hydroxyalkylamines) has photo and n is from about 3 to 7, p is equal to an integer from 1 to about 8, x has an average value of from 0 to about 30, y is equal to 0. 27) or where B and B are independently hydrogen or hydrocarbyl or substituted hydrocarbyl containing from 1 to about 22 carbon atoms, P is hydrocarbylene or substituted hydrocarbylene containing from 2 to about 18 carbon atoms in (26) leucine, B" and E5 are independently hydroxyalkyl, polyhydroxyalkyl, or poly(hydroxyalkyl)alkyl, provided, however, that when

Well, if ВІ 23 are methyl, then P? is not an octylene. In this context, the preferred B", B? and BZ are hydrogen, while B! and BZ independently represent hydrogen, rocarbyl (hydrocarbylene) groups represent co-hydrocarbyl or substituted hydrocarbyl containing a straight or branched alkyl group (alkylene), from 1 to about 30 carbon atoms, B? in each straight or branched alkenyl group (alkenylene),

X(B2O) group independently represents C2-Ca alkylene; a straight or branched alkynyl group (alkynylene),

B" is a hydrocarbylene or substituted hydraryl (arylene) or aralkyl (aralkylene). Preferable rocarbylene containing from 1 to about 30 atoms of di-poly(hydroxyalkylamines) have the formula: carbon, t and n independently equal whole numbers lam from 0 to about 7, the sum of t and n is no more than about 7, p is equal to a whole number from 1 to no mn В сн about 8, x has an average value from 0 to close to ИЙ И, (28) ко 30, y represents 0 or 1. In this context, the preferred B, B, and 2" hydrocarbyl (hydrocarbyl and new) groups are straight or branched, where B! and EZ independently represent a hydrogen alkyl (alkylene) group, straight or branched group or hydrocarbyl or substituted hydrocarbyl that alkenyl (alkenylene), a straight or branched group containing from 1 to about 22 carbon atoms, B2 alkynyl.(alkynylene), aryl (arylene) or aralkyl is a hydrocarbylene or substituted hydroca- (aralkylene). Preferably, K' is a straight rbylene containing from 2 to about 18 carbon atoms or branches ene alkyl, or straight or branched, t and n are independently equal to the whole number of ene alkenyl group containing from about 8 to from 1 to about 8, provided, however, that when B! and VZ about 30 carbon atoms; R? in each group (PO) is methyl, then B? is not an octylene. In pi independently represents C2-C4 alkylene; EZ represents in this context, B, C are preferred: hydrocarbyl is hydrogen, straight or branched alkyl, (hydrocarbyl) groups are a straight or straight or branched alkenyl group, which is a branched alkyl (alkylene) group, straight or contains from 1 to about 30 carbon atoms; B" branched group alkenyl (alkenylene), straight or represents a straight or branched alkylene, branched group alkynyl (alkynylene), aryl Hary- containing from 1 to about 30 carbon atoms, t and lene) or aralkyl (aralkylene). In one of embodiments, n are independently equal to integers from 0 to B! and BZ independently represent hydrogen or a straight- about 7, the sum of t and n equals from about C to 7, mu or a branched alkyl group containing from p is equal to an integer from 1 to about 8, x has 1 to about 6 carbon atoms, B is an average value of v to about 30, and y is straight or branched alkylene, straight or branched

O or 1. More preferably, K' is a straight branched alkenylene, straight or branched or branched alkyl group containing from alkynylene, arylene and alkylarylene group, about 8 to about 22 carbon atoms; RK? in each containing from 9 to about 18 carbon atoms, the same (P?O) group independently represents ethylene and such as defined above. In another embodiment, V! and VZ or propylene; KZ is hydrogen, straight or independently is hydrogen or a straight or branched alkyl group containing from 1 to a branched alkyl group containing from 2 to about 22 carbon atoms, 2 is a straight alkyl, straight or branched alkenyl, straight- or a branched alkylene, straight or branched or branched alkynyl, aryl or aralgen alkenylene, straight or branched alkynyl group containing from 1 to about 30 atoms of lene, arylene and alkylarylene group, which contains carbon, or - (H8)5(А"-О)пАЭ, and groups that will leave from 2 to 7 carbon atoms, t and n are such as were, such as indicated above. Preferably, B! is defined above. Preferably, The V's are independently a straight or branched alkyl group, or represent hydrogen or a straight or branched straight or branched alkenyl group containing an alkyl group containing from 1 to about 18 from about 8 to about 30 carbon atoms, P, VU , carbon atoms, B is a straight line or a branch of A x independently represent hydrogen, a straight alkylene group or a straight or branched or branched alkyl group, or a straight or branched alkenylene group containing from 2 to about 18 alkenyl group containing from 1 to about carbon atoms, t and n independently are equal to whole 30 carbon atoms, or -(87-O)p1852, Be represents numbers from 1 to about 8. More preferably, P! and hydrogen, methyl or ethyl; B' in each n(B'C) group

BZ independently represents hydrogen or a straight line independently represents C2-Са4 alkylene, p has a silver or branched alkyl group containing from 6 regular values from 1 to about 10, x and y independently up to about 12 carbon atoms, B? represents but are equal to a whole number from 1 to about 4. a straight or branched alkylene group, which mis- More preferably, KE! is a straight or branched from 2 to about 6 carbon atoms, etc. unbranched alkyl group containing from about 8 to about 4 to about 18 carbon atoms, Kg, VU, B" and E5 is not about 8; or B1 and E3 are independently hydrogen, a straight or branched hydrogen or a straight or branched alkyl group, an alkyl group containing from 1 to about 6 containing from 1 to about 4 atoms carbon, 2 carbon atoms, or -(B"-O)08E, ВU is a straight or branched alkylene hydrogen or methyl, БЕ" in each n(B'C) group is not a group containing from 2 to about 16 carbon atoms are ethylene or propylene, n is let, t and n are independently equal to integers with an average value from 1 to about 5, x and y are independently from about 4 to about 8. Most preferably, equal to a whole number from 1 to about 4.

IN! and EZ independently represent hydrogen or direct Most preferably, KE! represents a straight or mu or branched alkyl group containing from a branched alkyl group containing from about 6 to about 12 carbon atoms, B? represents co 8 to about 18 carbon atoms, P, VU, B" and Bo are ethylene or propylene, etc. are independently equal to independently represent hydrogen or -(B'-O082, whole numbers from about 4 to about 8; or B and BZ is hydrogen, B' in each n(B/O) group

BZ independently represents hydrogen or straight independently represents ethylene or propylene, n or a branched alkyl group containing from 1 has an average value from 1 to about 5, x and y ne- to about 4 carbon atoms, B? is a directly equal to a whole number from 1 to the nearest or a branched alkylene group containing 4. from 2 to about 12 carbon atoms, i.e. independent (e) monoalkylated amines of the formula: but equal to whole numbers from about 4 to bli- (vgoh zko 8. (j) alkylated triamines of the formula: vi- and (30) in ДЯ "di e- M Mnve de B" is a hydrocarbyl or substituted

Кк (29) well, a hydrocarbyl group containing from 1 to close to 1 to 30 carbon atoms, B? represents Со2-Са alkylene, RBZ represents hydrogen, straight line or where K'! is a hydrocarbyl or substituted branched alkyl group containing from 1 to hydrocarbyl containing from 1 to about 30 atoms of about 4 carbon atoms, B" is a straight carbon; K-, VU, B" and EZ independently represent or branched alkynyl, aryl, or aralkyl hydrogen, hydrocarbyl, or substituted hydrocarbyl group containing from 1 to about 30 carbon atoms, or - carbon, x has an average value of from 1 to about (AU)( A"-O) n No; N is hydrogen, or straight 60. In this context, preferred B! hydrocarbyl or branched alkyl group containing from 1 or substituted hydrocarbyl groups are up to about 4 carbon atoms; K" in each n(B/O) straight or branched alkyl, straight or branched group independently represents С2о-Са alkylene; 3 tinned alkenyl, straight or branched alkyl represents a hydrocarbylene or a substituted hydrocanyl, aryl or aralkyl group. Preferably, rbylene containing from 1 to about 6 carbon atoms - B' is a straight or branched alkyl ring; n has an average value from 1 to about 10; or a straight or branched alkenyl group equal to 0 or 1; x and y are independently equal contains from 1 to about 25 atoms0 1 l of the whole number from 1 to about 4; under the condition, however, of carbon, B is a C2-Ca alkylene, and B is obvious when K! is alkyl, K2? is not hydrogen, X is hydrogen, methyl or ethyl, PE is equal to C or 4, or K" is not -("8"-O)AE. In this straight or branched alkynyl, aryl or context, preferred K", B", VU, B", BZ and 8 hydrocara-aralkyl group containing from 1 to about 25 r (hydrocarbylene) groups are carbon atoms, x has the average value is from 1 to a straight or branched alkyl group (alkylene), straight to about 40. More preferably, B' represents a mu or branched alkenyl group (alkenylene), a straight or branched alkyl group containing a straight or branched alkynyl group (alkynylene ), from 8 to about 22 carbon atoms, B? is co-aryl (arylene) or aralkyl (aralkylene). In one of the battle is ethylene or propylene, EZ is hydrogen of embodiments, 2? is straight or branched or methyl, B : is a straight or branched alkynyl, aryl, or aralkyl group, which is a cross-linked alkyl group containing 1 to about 4 or 1 to about 6 carbon atoms, x has seven carbon atoms, n is 0 or 1, x and have an independent value from 1 to about 20. In one case, they have an average value from 1 to about 60. In embodiments, the compound has the formula presented in this context, the preferred B", VU, VZ and RU hydrocata- Table 4, C. rbil (hydrocarbylene) groups include () amine oxides of the formula: a straight or branched group alkyl (alkylene),

I is a straight or branched alkenyl group (alkenyl), a straight or branched alkynyl group (alkyny-k-x5-k (31) lene), aryl (arylene), or aralkyl (aralkylene). with Mainly, EV! is straight or branched alkyl, straight or branched alkenyl where K' is a hydrocarbyl or substituted group containing from about 8 to about 25 ato- hydrocarbyl containing from about 8 to about mi carbons, B in each x(B C) group independently of carbon atoms, K" and KE" independently represent co- is a Co-Cya alkylene, R. represents a straight line -"(H"O)KHAR, H" in each (РО ) group independently or branched alkylene or alkenylene group is C2-Ca alkylene, B? is a group containing from 2 to about 6 carbon atoms, di, hydrocarbyl or substituted hydrocarbyl, which VI and 85 each independently represents hydrogen, contains from 1 to about 30 carbon atoms, x has a straight or branched alkyl group, which contains an average value of from 1 to about 50. In this from 1 to about 6 carbon atoms, and x has an average context, preferred Ki K" hydrocarbyl groups of values from 1 to about 30. More preferably, B represents a straight or branched alkyl, represents is a straight or branched alkyl group - straight or branched alkenyl, straight or branched, containing from about 12 to about 22 atoms branched apkynyl, aryl or aralkyl group - carbon, B in each x(B.СО) group independently represents Preferably, K' is a straight or branched ethylene or propylene, P is a straight alkylene or straight or branched or branched alkylene or alkenylene gralkenyl group containing from about 8 to blip containing vi d? up to about 6 carbon atoms, with 22 carbon atoms, P2 and ЕZ independently represent B5, each independently represents hydrogen, -(B'O)XAP, B" in each (in) group is methyl or tris(hydroxymethyl) methyl, and x has a series of C2-C6 alkylene, and E is from about ? to about 30. Also hydrogen or straight or branched alkyl or more preferably when B! is a straight or straight or branched alkenyl group, which cross-branched alkyl group containing from about 1 to about 30 carbon atoms and from 12 to about 18 carbon atoms, B? in each x has an average value of from 1 to about 20. More X(B O) group independently represents ethylene or preferably, K' represents a straight or branched propylene, P represents an ethylene, propylene alkyl group containing from about 8 to bly- or 2-hydroxypropylene group, B and Bo each with 22 carbon atoms , P: and BZ independently represent independently hydrogen or methyl. x is -(B'O) KHAR, A" in each x(K"-O) group, independent value from about 4 to about 20. represents ethylene or propylene; KE represents Most preferably, when V! is straight hydrogen or a straight or branched alkyl or branched alkyl group containing from or a straight or branched alkenyl group of about 12 to about 18 carbon atoms, B? in contains from about 1 to about 30 carbon atoms, each X(B O) group independently represents ethylene; and x has an average value from 1 to about 10. or propylene, BE represents ethylene, propylene

Most preferably, B! is a direct or novel or 2-hydroxypropylene group, B. and 5 is a branched alkyl group containing from approximately methyl, x has an average value from about 8 to about 18 carbon atoms, VE: and EZ are independent of 4 to about 20. each represents -(B'O)XV?, B" in each x(B2-O) (p) alkylated diamines of the formula: the group independently represents ethylene or propylene; i

VAZ is a hydrogen or alkyl group that | E contains from about 8 to about 18 carbon atoms ОВЕхн--М 4 М (33) this; x has an average value from 1 to about 5. -kch in (9) is an alkylated amine oxide of the formula: Кк и де В! is a hydrocarbyl or substituted k'o-- (gori --0 (32) hydrocarbyl containing from about 8 to about 30 carbon atoms; P? in each x(220) group and y(220) where B! represents is hydrogen, hydrocarbyl or a group independently represents C2-Ca alkylene; РК", А? substituted hydrocarbyl, containing from 1 to about and in the (B2O) group or a substituted hydrocarbyl containing from 1 to independently represents a C2-Ca4 alkylene; B represents about 30 carbon atoms, or "(H"O)UA"; H" is a hydrocarbylene or a substituted hydrocarbylene, is hydrocarbylene or substituted hydrocarbene containing from 2 to about 6 carbon atoms; B. and belene containing from 2 to about 6 carbon atoms

VAZ each independently represents hydrogen, hydrogen, "b(-MA"IMA A, "c-m" and carbyl or substituted hydrocarbyl containing from 1 c(-8)MAyaVV., -b(-MA)-, -6(5)- or -F(0)-;. B" up to about 30 carbon atoms, -(B)y-(B2O)yB7;. Be is hydrogen, or straight or branched is hydrocarbylene or substituted hydro - an alkyl group containing from 1 to about 4 atorbilene containing from 1 to about 6 carbon atoms; KE", Ni KZ represent hydrogen, leunium, B" represents hydrogen, straight or branched hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms, x has an average value of from 1 to about 30, y has an average value of Preferably, B! is straight or branched from 1 to about 50, provided, however , which, well, an alkynyl, aryl or aralkyl group, which at least one of BZ, B? and VU represents - contains from about 8 to about 30 carbon atoms - (AgOUUV", at least one B: is not ethylene, B" not this one, B? in each x(B2O) and y(B2O) group is independently unknown substituted propylene, V! is not unsubstituted is C2-C1 alkylene, BEZ is v-alkyl, or x is from 2 to about 30. In given, methyl or ethyl, x and y are independently equal to the context, preferred B, VU, VU, IN? and Бе hydro- an average value from 1 to about 20. More carbyl (hydrocarbylene) groups are mainly, В! is a straight or branched straight or branched alkyl (alkylene), or alkynyl, aryl or aralkyl group, which is a straight or branched alkenyl (alkenylene), contains from about 8 to about 25 carbon atoms - a straight or branched alkynyl (alkynylene), this , In? in each x(B2O) and y(B2O) group independently aryl (arylene) or aralkyl (aralkylene is ethylene or propylene, KE is vu) groups. Preferably, B' is straight or hydrogen or methyl, x and y independently have an average branched alkyl, straight or branched alkyl value of from 1 to about 30. More preferably, a alkyl group containing from about 8 to about IS! is a straight or branched alkyl of 22 carbon atoms, B? in each xX(B2O) group and a nyl, aryl or aralkyl group containing in the (82O) group is independently a C2-Ca alkylene, from about 8 to about 22 carbon atoms, B? in

BZ, B5 and VU independently represent hydrogen, each direct x(22O) and y(820) group independently represents a single or branched alkyl, straight or branched ethylene or propylene, EZ represents hydrogen and an alkenyl group, which contains from 1 to about or methyl, x and y independently have an average value of 22 carbon atoms, or -(820)uB8", B" is from 1 to about 5. straight or branched alkylene, straight or di- Nonionic surface - active substances for a branched alkenylene group containing from 2 to use in pesticide compositions include about 6 carbon atoms, VE! represents hydrogen, contains dialkylated alcohols of the formula: methyl or ethyl, x has an average value from 1 to В'ЯоВнг)ХО-8З-О-(82О)уВ! (35) is about 20, y has an average value from 1 to blyde EC! independently represents hydrogen, straight from 20. More preferably, B' represents a straight or branched alkyl group containing from 1 or branched alkyl or straight or branched to about 4 carbon atoms, B? in each x(22O) and xen alkenyl group, containing from about 8 to y(82O), the group independently represents Co2-Ca alkylene, about 18 carbon atoms, P? in each x(22O) group, BZ is a hydrocarbylene or substituted hydrogen, and the U(B2O) group is independently an ethylene rocarbylene containing from 2 to about 30 atoms or propylene, RU, B? and 2E independently represent carbon, x and y independently have an average value of hydrogen, a straight or branched alkyl group of from 1 to about 60. In this context, preferred containing from 1 to about b carbon atoms, or - BZ hydrocarbylene groups are straight (A2OUUV", B" represents ethylene, propylene or 2- or branched alkylene, straight or branched hydroxypropylene, E" represents hydrogen or limited alkenylene, straight or branched alkynyl, x has an average value from 1 to about 15, in lene, arylene, or aralkylene groups. Pere- has an average value from 1 to about 10. Most importantly, B! represents hydrogen, methyl, or ethyl, 2 more preferably, KE represents a direct or di- in each x (B2O) and the (82O) group independently represents a branched alkylene or straight or branched C2-Ca alkylene, B' represents a straight or alkenyl group containing from about 8 to nearly 18 branched alkylene or straight or branched alkylene carbon, K2 in each x(B2O) group and nu alke a nilene group containing from about 8 to y(820) group independently represents ethylene or about 25 carbon atoms, x and y independently have propylene; WITHOUT, IN? and E independently represent an average value from about 1 to about 20. day, methyl, or (220),87; B" represents ethylene, More preferably, B represents hydrogen or me- propylene or 2-hydroxypropylene, B represents tyl, B? in each x(B2O) and y(B2O) group is independently hydrogen, x has an average value of 1 to about represents ethylene or propylene, EZ represents 10; y has an average value from 1 to about 5. straight or branched alkylene, straight or di- and () dialkylated amines of the formula: a branched alkenylene group containing from bli- (bom from 8 to about 18 carbon atoms, x and y independently (34) have an average value from 1 to about 10.

There is buzzing I I I and Even more preferably, VE! is hydrogen, PE: where B" is a hydrocarbyl or substituted for each x(B2O) and y(B2O) group independently is a co-hydrocarbyl containing from about to about З0 ethylene or propylene, C is a straight line of atoms carbon, or "BZN", B" and K" in each ЖА'О) or a branched alkylene group containing В and У(Б2О) group independently represents a C2-Са alkyl group, sh: d len, KZ is hydrogen, straight or branched - about 8 to about 18 carbon atoms, x and y are not - and and depending on it have an average value from 1 to a close alkyl group containing from 1 to about 4 to 5 carbon atoms , P is a straight or branched Other surface-active substances for the used alkyl group containing from about 4 to becoming in pesticide compositions include about 15 carbon atoms, x and y independently have compounds of the formula: the average value from 1 up to about 40. In this context, the predominant E! hydrocarbyl groups are straight or branched alkyl, pr hole (36) or branched alkenyl, straight or branched alkynyl, aryl or aralkyl groups. (in either hydrocarbyl or substituted hydrocarbyl, which "y" in contains from 1 to about 30 carbon atoms, or - to Кк во (СНг)2О(82О)68З; t, n, r and d independently have 37 is an ordinary value from 1 to about 50; Х is equivalent to "(37)" -0-, -М(В')-, -С(0)-, -С(0)0-, -ОС (O)-,.- and i with M(8"U)C(0)-, -C(O)M(B5)-, -5-, -80- or -505-; 1 - (OK equals 0 or 1; A- is an anion accepted for agricultural compositions; y and 7vo are independently equal to a whole number from 0 to nearly 30. In this context, B", ВZ and 5- and (38 ) in the hydrocarbyl (hydrocarbylene) group are represented by their BO; they are straight or branched alkyl (alkylene-

Kk -B2O) yana vu), straight or branched alkenyl (alkenylene-new), straight or branched alkynyl (alkynyle- or new), aryl (arylene) or aralkyl v (aralkylene) groups. Mostly, V! VU and V? ne- um de ut , depending on whether they are straight or branched

M! o (39) alkyl or alkenyl groups containing from 1 to

VeMechAyuH and about 22 carbon atoms, or -(B2O)rVZ; IN? where 7 in each t(K2O), p(H?O), p(B2O) and a(BA2O) group independently represents C2-Ca alkylene; C represents either hydrogen, methyl or ethyl; B ? represents - in (СНгУОВ" or -(СНг)УОО(82О0)983; ВВ, В, ВЗ Her Vo, ; independently represent hydrogen, direct or dis-

BK-yak--in OV syh 4 branched alkyl or alkenyl group, which is mis-o prh; (40) containing from 1 to about 22 carbon atoms; B" represents -(СНгУуОВ'З or -«"СНгУО(Н?О)аНая; B, No and

Oko) in B" independently represent hydrogen, straight or branched alkyl or alkenyl groups, which either contain from 1 to about 22 carbon atoms, or B-;

KE t in V!? is a straight or branched alkyleneol | in: vu or alkenylene group containing from 2 to

Kk Z (re - about 18 carbon atoms; B" represents a straight I' (41) or a branched alkyl or alkenyl group,

I containing from 1 to about 22 carbon atoms, ovo zhdZ or -«(CHg)-O(B2O)rAZ; t, p, r and d independently have an average value from 17 to about 30; X represents either -O-, -M(B!Y-, -C(0)-, -C(FO-, -OS(O)-, -

And in M(8"U)C(0)-, -C(O)M(B5)-, -5-, -80- or -505-, is equal to 0 or 1; A- is an anion, acceptable

BOTTOM - IN HY | yes for agricultural compositions; y and 2 are independently (12) equal to a whole number from 0 to about g: 30. More preferably, В! is a straight line or a point? a branched alkyl or alkenyl group containing from about 8 to about 18 carbon atoms. this, or -(B2O)rA!Z; BZ and B" independently represent a straight or branched alkyl or phenyl group containing from 1 to about 22 atoms

КВ ХО И сы (43) carbon, or -(B2O)рА!З3; IN? in each t(v2O),

P i, p(82O), p(B2O) and a(22O) group independently represent co-

Kk Kk I fight ethylene or propylene; EZ is hydrogen ovo or methyl; B? is -(СНг2уОВ!З or - where В, ВЗ and В2 independently represent hyd- (СНг)УО(А?О)dAU; AB, ВА", VAZ independently represent rocarbyl or substituted hydrocarbyl containing hydrogen, straight or branched alkyl from 1 to about 30 carbon atoms, or -(B2O)0BU; or alkenyl groups containing from 1 to about

In each t(B2O), p(B2O), p(B2O) and a(B2O) group, there are 22 carbon atoms; B? represents -(СНгуОВв!З independently represents C2-Са alkylene; ВЗ, ВВ, В, or -"(СНг)уО(А?О)аВУ; ВУ, В? and ВЕ" independently represent-

B3 and B15 independently represent hydrogen, or are hydrogen, a straight or branched alkyl hydrocarbyl or substituted hydrocarbyl containing n or an alkenyl group containing from 1 to about 1 to about 30 carbon atoms; B" represents a cone of 22 carbon atoms, or K"; IN? represents bouj -(СН2УОВ!З or -(СНгУО(Б2О)983; В, Бе and В? straight or branched alkylene or alkenyl- independently represent hydrogen, hydrocarbyl or a new group containing from 2 to about b atoms substituted hydrocarbyl , containing from 1 to about carbon; KZ is hydrogen, a straight line of carbon atoms, or B; B" is a hydrobranched alkyl or alkenyl group, which is a miscarbylene or substituted hydrocarbylene, containing a thit from about b to about 22 carbon atoms; from 2 to about 30 carbon atoms; EC" represents co- A" represents a straight or branched alkyl or alkenyl group containing from 1 to about e 22 carbon atoms, or -"(CHg)2 :О(А?О)рАЗ; t, n, ria 4 4 of A independently have an average value from 1 to blyoon (15) of 20; X represents -О-, -МЩ(Б4)-, -С (0)-, -С(ФО)О-, - 5

ОС(0)-, -М(В)С(0)-, -С(О)М(В5)-, -5-, -50- or - where В' is hydrocarbyl or substituted

ЗО», И is equal to 0 or 1; A- is an anion, a hydrocarbyl containing at least 7 carbon atoms, suitable for agricultural compounds (predominantly contains 8 to about 30 cation atoms; both y and 75 are independently equal to the whole number of carbon); 2 in each x(B20) and y(220) group is independent

Oh to about 10. Most preferably, B! is C2-Ca4 alkylene; ВЗ and У each a straight or branched alkyl or alkene independently represents a hydrocarbylene or a substituted group containing from about 12 to about 1 hydrocarbylene containing from 1 to about 6 18 carbon atoms, or -(82О)рА3; BZ and B!2 are non-ferrous carbon atoms; P" represents hydrogen, hydrocarbyl represents a straight or branched alkyl or substituted hydrocarbyl group containing from 1 to 1 or an alkenyl group containing from 1 to about 30 carbon atoms, hydroxy-substituted with about 6 carbon atoms, or -(B2O)rBZ; B? in co-hydrocarbyl, -(82)y-(82O)UA", -C(-MA"L)MAV, - t(220), p(B2O), p(B2O ) and a(E20) to the non-ferrous group С(-ОМВгВЗ, -С(-5)МВ2В!З or together with VZ and therefore represents ethylene or propylene KZ represents the nitrogen atom to which they are attached, forming hydrogen; В? represents -(СНуОВ!З or - a cyclic or heterocyclic ring; BEZ represents co- (СнНгудФ(Б2О)483; ВВ, В, ВЗ independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl, hydrogen, straight or branched alkyl bi , containing from 1 to about 30 carbon atoms, or an alkenyl group containing from 1 to about hydroxy substituted hydrocarbyl, -(B5)y-(B2O3uB", - 6 carbon atoms; B" represents -"СН2УОВ!З or с(-МАСМА:ВЗ, -С(-0О)МАВЯ, -С(-5)МА2ВЗ or -СНгУуд(АгО) aVz; VU, B"! and B independently represent, together with B" and the nitrogen atom to which they attach hydrogen, a straight or branched alkyl group, forming a cyclic or heterocyclic ring; or an alkenyl group containing from 1 to about B" is hydrogen, straight or branched 22 carbon atoms, or B"; VE is a straight alkyl group containing 1 to about 4 atoms or a branched alkylene or alkenylene carbon group; B!, ID!2 and BZ represent hydrogen, hydrogen, containing from 2 to about 6 carbon atoms; rocarbyl or substituted hydrocarbyl, B!" represents

BZ is hydrogen, a straight or branched hydrogen, hydrocarbyl or substituted hydroalkyl or alkenyl group containing from 1 to about 30 carbon atoms to about 22 carbon atoms; В" represents this, hydroxy-substituted hydrocarbyl, -(ВУ)(82Уу87), - is a straight or branched alkyl or alkyl-c(i-МА'ЗМАгВЗ, -С(О)МВА2ВЗ or -С(-5)МВ2В/ Y, a nil group containing from 1 to about 22 atoms, n is equal to 0 or 1, x and y independently have an average carbon, or -(CHg); О(Б82О)рВЗ; т, н, р and 4 are independent of 1 to about 60, and A-represents or have an average value from 1 to about 5; X on, acceptable for agricultural compounds, is -O- or -M(B'-)-, and is equal to 0 or 1 ; zition, provided, however, that when B2 and C are

A- is an anion acceptable for agriculture - it is isopropylene and x is equal to 1, B! is not an alkyl of spodaric compositions; y and 7 are independently equal - or В" represents -(820)yВ8". In this context, there are a whole number from 1 to about 3. Predominant В", ВЗ, ВУ, В, Ве, В, В/г and ВЗ hydrocar-

The surface-active composition of this wine (hydrocarbylene) group represents a move includes any individual combination of straight or branched alkyl (alkylene), new surface-active substance, as indicated straight or branched alkenyl (alkenylene), above. The surface-active composition is especially straight or branched alkynyl (alkynylenic), preferred for use in the composition of the composition of aryl (arylene) or aralkyl (aralkylenes of glyphosate potassium, diammonium, ammonium, sodium, vu) groups. In one of the embodiments, BEZ represents monoethylamine, n-propylamine, methylamine, ethyl- direct alkylene, preferably ethylene, and B', B2, lamin, hexamethylenediamine, dimethylamine and/or VI and PE? such as defined earlier. In another embodiment, trimethylsulfonium, such as aqueous concentrates. B" represents H, alkyl, or -B2OB" and БЕ", B, Bz, B?

The surface-active composition can be introduced into and 27 such as defined earlier. In yet another embodiment, a composition containing any combination of these nos. B is a straight or branched alkyl salt of glyphosate. well, a straight or branched alkenyl group, what

It was found that various surface-active containing from about 8 to about 25 carbon atoms, which were not previously used in this , EZ is a direct or branched alkylene group containing from 1 to tively containing potassium or ammonium glyphosate. Cationic about 6 carbon atoms, B" and EZ each independent surfactants, effective in the composition but representing hydrogen, direct or branched pesticide compositions, include: an alkyl group containing from 1 to about 6 atoms- (a) aminated alkylated alcohol of carbon forms, x has an average value from about 2 moles: to about 30. More preferably, B! is a straight or branched alkyl group containing 1 2 C : : 2 v'M- (so - M (44) from about 12 to about 22 carbon atoms, K- in "to each X(B2O) group independently represents ethylene or propylene, EZ represents a straight or branched alkylene group containing from 1 to about 4 of carbon atoms, PE" and Z each independently pre-

is hydrogen, methyl or thitium from 1 to about 30 carbon atoms, n is tris(hydroxymethyl)methyl, x has an average value of about 4 to about 8; or E! and B2 independently from about 2 to about 30. Even more predominately is a straight or branched alkyl, i.e., B' is a straight or branched alkyl straight or branched alkenyl group, which is a substituent group containing from about 12 to about 4 to about 30 carbon atoms, n 18 carbon atoms, B? in each x(B2O) group is not equal to about 4 to about 8. More preferably, it is ethylene or propylene, K is but, B' is straight or branched alkyl, ethylene, P" and E? are each independently represented - well, a straight or branched alkenyl group that injects hydrogen or methyl, x has an average value of from about 8 to about 22 carbon atoms - from about 4 to about 20. Most preferably, this, B? is hydrogen, straight or branched -

IN! represents a straight or branched alkyl or alkyl, straight or branched alkenyl group containing from about 12 to about 18, a group containing from 1 to about 6 carbon atoms, carbon atoms, P? in each x(B2O) group, n is from about 4 to about 8; or R. and no represents ethylene or propylene, BZ represents B? independently represent straight or branched ethylene, B" and E? represent methyl, x has an alkyl, straight or branched alkenyl wife with an average value of from about 4 to about 20. a group containing from about 4 to about 8 atoms

Compounds of the formula (45) have predominantly carbon-containing groups, n equals from about 4 to about those indicated above, and KE" is mainly hydrogen 8. or a straight or branched alkyl or alkenyl- (c) diamine of the formula: a group, more preferably alkyl, and the most BAH M in M is preferably metal. Preferable monoalkylated amines include PES 13 or 18 Sil-15 Kk Kk esters of propylamines and PES 7, 10, 15 or 20 Svv where RK", AR and A? independently represent propylamine esters (from Totap) and RES 13 or 18 day, hydrocarbyl or substituted hydrocarbyl, which

Sial5 dimethyl ethers of propylamines and RES 10, 15 contains from 1 to about 30 carbon atoms, or 20 or 25 Stiv-in dimethyl ethers of propylamines ATO) OB, VAZ is a hydrocarbylene or (from Totap), a substituted hydrocarbylene containing from 2 to bly- (c) hydroxylated amines of the formula: with 18 carbon atoms, BEZ and BZ each represent a hydrocarbylene or substituted hydrocarbylene compound containing from 2 to about 4 carbon atoms, P" and c----- di ( 46) B!? independently represent hydrogen, hydrocarbyl

I. or substituted hydrocarbyl containing from 1 to

EC is about 30 carbon atoms, t is 0 or 1, n where B' is a hydrocarbyl or substituted with an average value from 0 to about 40, X is a hydrocarbyl containing from about 4 to about -C(0)- or - 505-, A is an anion of carbon atoms, P? is hydrogen, which is hydrogen-soluble for agricultural compositions. In the carbyl or substituted hydrocarbyl containing from 1 in this context, the predominant B", VU, B" and 25 hydroca- up to about 30 carbon atoms, C represents rbil (hydrocarbylene) groups are hydroxyalkyl, polyhydroxyalkyl, or straight or branched alkyl (alkylene), Li(hydroxyalkyl)alkyl. In this context, the preferred straight or branched alkenyl (alkenylene), KE! and B2 hydrocarbyl groups are straight or branched alkynyl (alkynylene), straight or branched alkyl, straight or branched aryl (arylene), or aralkyl (aralkylene alkenyl, straight or branched alkyl) groups. Mostly, E!, B, B? and EE" independently of a nyl, aryl or aralkyl group. Preferably, they are hydrogen, straight or branched hydroxylated amines have the formula: an alkyl or alkenyl group containing from 1 to

It has about 6 carbon atoms, EZ is a straight 1 or branched alkylene containing from 2 to

E--n n y y i, about 6 carbon atoms. More preferably, B, and (47) B2, B, and 5 independently represent hydrogen, a straight or branched alkyl group containing from n 1 to about 6 carbon atoms, C represents where B" represents hydrocarbyl or a substituted direct or branched alkylene containing from hydrocarbyl containing from about 4 to about 1 to about 6 carbon atoms. Most preferably, 30 carbon atoms, B? is hydrogen, hydrogen, VK", NU, A" and A? independently represent vo-carbyl or substituted hydrocarbyl containing from 1 day or methyl, KZ is ethylene or propy- up to about 30 carbon atoms, n equals from 1 to len. about 8. In this context, B' and Be are preferred (4) mono- or di-ammonium salts of the formula: hydrocarbyl groups are straight or branched alkyl, straight or branched al-B--di-m-n shkh ukh (49) kenyl, straight or branched alkynyl, cy and aryl or aralkyl group. Preferably, B is a straight or branched alkyl, straight or branched alkenyl group rupa, containing from AK t her about 8 to about 30 carbon atoms, B? represents is hydrogen, a straight or branched alkyl, iinns and min niv (50) a straight or branched alkenyl group, which is mis- and" and where B", B2, VU, Vo and B' independently represent co- or bi hydrogen or hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms, or -B8(OVU)nNiV'?, ВАЭ is a hydrocarbyl or substituted hydrocarbyl containing on on (53) from about 1 to about 30 carbon atoms , C is a hydrocarbylene or a substituted hydrocarbylene containing from 2 to about 18 carbon atoms, K8, BZ, and B!!! each is a hydrocarbylene, while B! is a hydrocarbyl or substituted lene or substituted hydrocarbylene containing from 2 hydrocarbyl containing from about 4 to about 4 carbon atoms, P"? represents 30 carbon atoms, or -VZOV"; B? represents di or hydrocarbyl or substituted hydrocarbyl, hydrogen or hydrocarbyl or substituted hydrocarbyl containing from 1 to about 30 carbon atoms, t containing from 1 to about 30 atoms of carbon, C is 0 or 1, n has an average value from 0 to is a hydrocarbylene or substituted hydrocar- about 40, X is -C(0)- or -505-, 2 is a carbylene containing from 2 to about 18 carbon atoms are -C(0)-, A is an anion, an acceptor, P" is hydrogen or hydrocarbyl or it is for agricultural compositions. In a da-substituted hydrocarbyl containing from about 1 to no context, the predominant K!, VAZ, VU, B? Its B contains about 30 carbon atoms, i.e., independently doriv- hydrocarbyl (hydrocarbylene) groups are represented by whole numbers from 0 to about 7, mixed with straight or branched alkyl (alkylene- equals no more than about 7, p equals the whole number), straight or branched alkenyl (alkenyl number from 1 to about 8. In this context, penu), straight or branched alkynyl (alkynylation B", B2, B3 and B" hydrocarbyl (hydrocarbylene), aryl (arylene ) or aralkyl new) groups are straight or branched (aralkylene) groups. Preferably, K", B, B", b in an alkyl (alkylene), straight or branched alkenyl group independently represent hydrogen, a straight or branched (alkenylene), straight or branched branched alkyl or alkenyl group, which is a mis-alkynyl ( alkynylene), aryl (arylene) or thit from 1 to about 6 carbon atoms, B? represents an aralkyl (aralkylene) group. Mostly, V! is a straight or branched alkyl or alkenyl is a straight or branched alkyl, nyl group containing from about 8 to about a straight or branched alkenyl group, which mis-

30 carbon atoms, t is equal to 0 or 1, and B? is from about 8 to about 30 carbon atoms, is a straight or branched alkylene, which is mis- or -VZOV"U, B? is hydrogen, straight or from 2 to about 6 carbon atoms. A more branched alkyl, straight or branched, respectively, B", Be, B", VAZ and KE" independently represent a kenyl group containing from 1 to about 30 hydrogens, a straight or branched alkyl of carbon atoms, C is a straight or branched group, containing from 1 to about 6 carbon atoms alkylene or alkenylene group that this, RK? is a straight or branched alkyl containing from 2 to about 6 carbon atoms, B an obvious group containing from about 8 to about 22 represents a straight or branched alkylene or carbon atoms, t is equal to 0 or 1, KZ represents a so-alkenyl group containing from about 8 to nearly a straight or branched alkylene containing 22 carbon atoms, t and n are independently equal - from 1 to about 6 carbon atoms. The most common are integers from 0 to about izko 7, sum ti p important, B", B, B", B? and B" independently represent from about C to 7, p is an integer number of hydrogen or methyl, KU is a straight or from about 4 to about 8; or B! and B2 independently a branched alkyl group containing from about is a straight or branched alkyl group containing 8 to about 18 carbon atoms, t is 0 a straight or branched alkenyl group containing 1, and KZ is ethylene or propylene from about 4 to about 30 carbon atoms, (e ) poly(hydroxyalkylamines of the formula: t and n are independently equal to whole numbers from 0 to в'А---я83 about 7, the sum of t and n is from about 3 to 7, and (51) p is equal to a whole number from about 4 to about where B! is hydrocarbyl or substituted 8. More preferably, B' is a straight or hydrocarbyl containing from about 4 to closely branched alkyl, straight or branched al- carbon atoms, or -BOH5, B' is a kenyl group, containing from about 8 to near hydrogen or hydrocarbyl or substituted hydrocarbyl, co 22 of carbon atoms, or -AV'ON", H" represents containing from 1 to about 30 carbon atoms, EZ hydrogen, straight or branched alkyl, straight represents hydroxyalkyl, polyhydroxyalkyl. or or a branched alkenyl group containing from poly(hydroxyalkyl)alkyl, B? is hydrocarbon 1 to about b carbon atoms, K? is a bilene or substituted hydrocarbylene containing from straight or branched alkylene or alkenyl- 2 to about 18 carbon atoms, 5 is a new group containing from 2 to about 6 hydrogen atoms, hydrocarbyl or substituted hydrocarbyl that carbon, K" is a straight or branched containing from about 1 to about 30 carbon atoms, an alkyl or alkenyl group, containing from blit. lie are equal to whole numbers from 0 to about 7, the sum of t and n is from about 3 to 7, p is equal to a whole number from about 4 to about 8; V'i -- n (52) B: independently represent a straight line or branched chain alkyl or straight or branched alkeny-

A p group containing from about 4 to about 8 carbon atoms, t and n are independently equal to a whole alkylene group, straight or branched with alkyl numbers from 0 to about 7, the sum of t and n is equal to a nyle group containing from 2 to about 18 about C to 7, p is equal to a whole number from close to carbon atoms, t and n are independently equal to integers from 4 to about 8. Even more preferably, E' is represented by numbers from 1 to about 8. More preferably, B is a straight line or a branched alkyl group that B? independently represent hydrogen, a straight or containing from about 8 to about 18 carbon atoms, a branched alkyl group containing from b to this or -VZOOV"U, B? represents hydrogen or methyl, about 12 carbon atoms, ВЕ? represents straight t and n are independently integers from 0 to or a branched alkylene group containing from about 4, BZ is a straight or branched 2 to about b carbon atoms, t and n are independently an alkylene group containing from 2 to about 6 integers from about 4 to about carbon atoms, B" is a straight or branched 8; or EV! and BZ independently represent hydrogen, an alkyl group containing from about 8 to a straight or branched alkyl group containing about 18 carbon atoms, the sum of t and n is from 1 to about 4 carbon atoms, P? represents about 4, p is equal to a whole number of about 4. a straight or branched alkylene group, which mis-

Most preferably, B' is a straight or linear group of from 2 to about 16 carbon atoms, and t |i n a branched alkyl group containing from about - independently equal whole numbers from about 4 to 8 to about 18 carbon atoms, or -VZOV ", В2 up to about 8. Most preferably, КЕ! and ВЗ is methyl, КЗ is ethylene, most preferably is hydrogen, straight or branched propylene, hydroxyethylene or 2-hydroxypropylene, EE is an alkyl group that contains from b to about represents a straight or branched alkyl of 12 carbon atoms, KE? represents an ethylene or lin group containing from about 8 to about 18 propylene, t and n are independently equal to the whole number of carbon atoms, t and n are independently are equal to integers from about 4 to about 8; B' and BZ are independently numbers from 0 to about 4, the sum of t and n is equal to represent hydrogen, straight or branched about 4, p is equal to a whole number about 4. an alkyl group containing from 1 to about 4 atoms

Such compounds are commercially available from AIIIgisp and have carbon, KE? is a straight or branched

Sapapi a female alkylene group containing from 2 to about () di-poly(hydroxyalkyl)amine of the formula: 12 carbon atoms, and t and n are independently equal to т в2 М 5 whole numbers from about 4 to about 8. т И Гд (52) (9) quaternary poly(hydroxyalkyl)amine salts: 1 Z EZ 1, v3 x de EE! and Z independently represent hydrogen 4 | 4 or hydrocarbyl or substituted hydrocarbyl, which k-ja-k (56) contains from 1 to about 22 carbon atoms, P? and" is a hydrocarbylene or substituted hydrocarbyl containing from 2 to about 18 carbon atoms, where K" is a hydrocarbyl or a substituted leucine, and P: and BZ are independently hydroxyhydrocarbyl, which contains from about 4 to about alkyl, polyhydroxyalkyl, or 30 carbon atoms, r and v independently represent poly(hydroxyalkyl)alkyl. In this context, hydrogen, hydrocarbyl, or substituted hydrocarbyl B1, B2, and B3 hydrocarbyl ( hydrocarbylene) white containing from 1 to about 30 carbon atoms, the groups are straight or branched alkyl is hydroxyalkyl, polyhydroxyalkyl or lin (alkylene), straight or branched alkeny- poly(hydroxyalkyl)alkyl. In this context, per - linear (alkenylene), straight or branched alkylated B", B2 and C hydrocarbyl groups are solyl (alkynylene), aryl (arylene) or straight or branched alkyl, straight or aralkyl (aralkylene) groups. Preferably, the di-branched alkenyl, straight or branched poly(hydroxyalkyl)amine has the formula: alkynyl, aryl or aralkyl group. Predominantly, quaternary poly(hydroxyalkyl)amine salts have the formula:

She is from n (55) c

Hm t p -i on x (57) where V! and EZ are independently hydrogen, hydrocarbyl or substituted hydrocarbyl containing P from 1 to about 22 carbon atoms, B? is a co- or hydrocarbylene or a substituted hydrocarbylene, t containing from 2 to about 18 carbon atoms, and tv ie 3 x

Its n are independently equal to integers from 1 to about 8. In this context, B", B? and

VZ hydrocarbyl (hydrocarbylene) groups are straight or branched alkyl (alkylene, vu), straight or branched alkenyl (alkenylene), straight or branched alkynyl (alkynylate), aryl (arylene) or an aralkyl (aralkylene) group. Preferably, K" and K" independently B! is hydrocarbyl or substituted but is hydrogen, a straight or branched hydrocarbyl containing from about 4 to about an alkyl group containing from 1 to about 18 30 carbon atoms, P? and VZ independently represent so- carbon atoms, P? is a straight or branched

hydrogen, hydrocarbyl or substituted hydrocarb- (88)5(А"О)п8е; VU is hydrogen, a straight or white containing from 1 to about 30 carbon atoms, a branched alkyl group containing from 1 to t and p are independently equal to integers from 0 to about 4 carbon atoms, B" in each n(B/O) group is about 7, the sum of t and n is no more than about independently represents C2-C4 alkylene; BEZ represents 7, p is an integer from 1 to about 8. In itself, hydrocarbylene or substituted hydrocarbylene, in this context, P, B2, and 23 are preferred hydrocarby- containing from 1 to about 6 carbon atoms, full groups are straight or branched has an average value from 1 to about 10, 5 doryalkyl, straight or branched alkenyl, directs 0 or 1, x and y are independently equal to the whole mu or branched alkynyl, aryl or aral - a number from 1 to about 4. in this context, hell group. Mostly, V! is a direct reactive PE", B2, BZ, VU, Vo and BZ hydrocarbyl (hydro- or branched alkyl, straight or branched carbylene) groups are a straight or de-alkenyl group containing from about 8 to a branched alkyl ( alkylene), straight or with 30 carbon atoms, P: and EZ independently represent a branched alkenyl (alkenylene), straight or hydrogen, straight or branched alkyl, branched alkynyl (alkynylene), aryl straight or branched alkenyl group, which mis- (arylene ) or an aralkyl (aralkylene) group from 1 to about 30 carbon atoms, etc., preferably, B! represents a straight or branched- depending on the integers from 0 to the nearest alkyl, straight or branched alkenyl co 7 , the sum of t and n equals from about C to 7, p groups containing from about 8 to about 30 atoms is equal to the total number from about 4 to about 8; mv carbon, K2, BZ, B?! and BZ independently represent

AB, B? and VZ independently represent a straight or hydrogen, straight or branched alkyl, branched alkyl, straight or branched alkenyl group, or miskenyl groups containing from about 4 to about 1 to about 30 atoms of carbon, or -(В!- ko 30 carbon atoms, t and n are independently equal to О) В, В? is hydrogen, methyl or ethyl; In" integers from 0 to about 7, the sum of those n doriv- in each n(B/C) group independently represents C2- is not more than about 7, p is equal to the whole number of Ca alkylene, n has an average value from 1 to about - from about 4 to about 8. More preferably, B is up to 10, x and y are independently integers, represents a straight or branched alkyl group, from 1 to about 4. More preferably, B is a straight or branched alkenyl group, which - is a straight or branched alkyl group containing from about 8 to about 22 carbon atoms, containing from about 8 to about 18 carbon atoms

IN? and VZ independently represent hydrogen, straight this, 2, VZ, B? and E? independently represent a vo- or branched alkyl, straight or branched d, straight or branched alkyl group, that alkenyl group containing from 1 to about 6 contains from 1 to about b carbon atoms, or - carbon atoms, t and n are independently equal whole (8"-O)p82U, B? represents hydrogen or methyl, E" in numbers from 0 to about 7, the sum of t and n is equal to each n(B/C) group independently represents ethylene from about C to 7, p is equal to a whole number from near- or propylene, n has an average value from 1 to 4 to about 8; B", B2 and ЕЗ independently represent about 5, x and y are independently equal to the whole number of straight or branched alkyl, straight or LU from 1 to about 4. Most preferably, B! is a branched alkenyl group containing from a straight or branched alkyl group of 4 to about 8 carbon atoms, etc., non-bonded, containing from about 8 to about 18 atoms equal to whole numbers from 0 to about 7, carbon, P2, BZ, B" and P ? independently represent the sum of t and n is equal to from about C to 7, p is equal to hydrogen, or -(B"-O)n82U, B? is hydrogen, the total number is from about 4 to about 8. Even more in each n( V/O) group independently represents ethyl, preferably, KE! represents straight or branched or propylene, n has an average value from 1 to n, an alkyl group containing from about 8 to about 5, x and y independently are equal to a total of 18 carbon atoms, P: and ЕZ are independently from 1 to about 4. Commercially available hydrogen or methyl triamines, t and n independently equals include Asgose and Sagiapi Sepatip 3119. are represented by whole numbers from 0 to about 4, sumati p Another cationic surface-active substance is about 4, p is equal to the whole number of blizzards, effective in any composition of glyphosate 4. Most preferably, B' represents a yarn is: mu or a branched alkyl group containing from () a diamine of the formula: about 8 to about 18 carbon atoms, B2 and 3 d'-kA- (Bow-- ve-m - C are methyl, t and n are independently equal to M and in (60) are integers from 0 to about 4, the sum of those n and n is about 4, and p is equal to the whole number of the pale P", AT, B" and EP independently represent zko 4. hydrogen, hydrocarbyl or substituted hydrocarbyl, which (n) triamines of the formula: contains from 1 to about 30 carbon atoms, or - in (АО)ХВ", В? is a hydrocarbylene or a bridged hydrocarbylene, containing from 2 to about 7M M -co (59) 30 carbon atoms, P: in each x(PO) and y(290) group x independently represents is Co-C4 alkylene, B/ is hydrogen, straight or branched alkyl where K'! is a hydrocarbyl or substituted group containing from 1 to about 30 carbon atoms; hydrocarbyl containing from 1 to about 30 carbon atoms, x has an average value of from 1 to about 30, carbon; M, BZ, B" and BZ independently represent y having an average value of from about C to about hydrogen, hydrocarbyl, or substituted hydrocarbyl that is 60, provided that when P? is ethylene, or contains from 1 to about 30 carbon atoms , or - y is greater than 4, РЗ3, Бе and 25 are independently

are hydrogen, straight or branched alkyl group containing from 1 to about 4 nu atoms, straight or branched alkenyl, straight or carbon, x has an average value from 1 to close branched alkynyl, aryl or aralkyl 30, y has an average value from about З to bly- a group containing from 1 to about 30 atoms narrowly 60, and Х- is an anion acceptable for lecz or -(Б9О)ХВ", В? is not ethylene, or not bi- agricultural compositions. In this case, more than one of B, VZ, B" and EE? is an alkyl group, preferably B", B2, BZ, VU, B", VU and P? hydroca- or (E5O)ХВ". In this context, the preferred B", B2, rbyl (hydrocarbylene) groups are

VZ, Ve and eE? hydrocarbyl (hydrocarbylene) groups straight or branched alkyl (alkylene), are straight or branched alkyl straight or branched alkenyl (alkenylene), (alkylene), straight or branched alkenyl straight or branched alkynyl (alkynylene), (alkenylene), straight or branched alkynyl aryl (arylene) or aralkyl (aralkylene- (alkynylene), aryl (arylene) or aralkyl) group. Preferably, B", BZ, VU, B", BZ and E are unknown (aralkylene) groups. - a branched alkyl or alkenyl group containing from a branched alkyl or alkenyl group containing from about 1 to about 22 carbon atoms or from about 1 to about 22 carbon atoms, (A2O)ХВ", B? represents a straight or branched or -(890)ХВ", B? represents a straight or branched alkylenyl or alkenylene group containing an alkylene or alkenylene group having from about 1 to about 6 carbon atoms, BU in tit from about 1 to about 6 carbon atoms, B in each x(B2O) and y(25O) group independently represents co, in each x(B9O) and y(5O) group independently represents a C2-Ca alkylene, B" represents hydrogen, straight C2-Ca alkylene, B' represents hydrogen, a straight or branched alkyl group containing from 1 mu or a branched alkyl group containing from to about 4 carbon atoms, x has an average value of 1 to about 4 carbon atoms , x has an average value from 1 to about 30, y has an average value from 1 to about 30, y has an average value from 1 to about 60. More preferably, B", VU, B", from 1 to about 60 More preferably, E", VU, B" and B", VZ and E? independently represent hydrogen,

AZ independently represents hydrogen, a straight or mu or a branched alkyl group containing from a branched alkyl group containing from about 1 to about 18 carbon atoms, or - from 1 to about 18 carbon atoms, or -(B ОВ" , (890)ХВ", В? is a straight or branched line

IN? represents a straight or branched alkylene alkylene group containing from about 1 to about a group containing from about 1 to about 6 atoms or 6 carbon atoms, RU in each x(O) and y(vO) of carbon, RU in each х(БЕ20) and у(Р:2О) group, the non-group is independently ethylene or propylene, Лежо is ethylene or propylene, B" is B' is hydrogen, straight or branched hydrogen, straight or branched alkyl an alkyl group containing from 1 to about 4 carbon atoms, a group containing from 1 to about 4 carbon atoms, x has an average value of 1 to 10, x has an average value of 1 to about 10, in 10, y has an average value from 1 to about has an average value from 1 to about 60. Most preferably, B" and ЕЗ independently represent more preferably, B' and БЕЗ independently represent straight or branched alkyl groups, a straight or branched alkyl group containing from about 8 to about 18 carbon atoms containing from about 8 to How many 18 carbon atoms, B", B", BZ and BZ independently represent this, B" and E? independently represent hydrogen, 2 hydrogen or methyl, P? is a straight or de- is a straight or branched alkylene branched alkylene group containing from about a group containing from about 1 to about 6 carbon atoms, P: in each x(P50) and miv carbon , RU in each x(VSO) and y(VZO) group is not in the (VZO) group, independently represents ethylene or lies ethylene or propylene, B" represents propylene, E" represents hydrogen, direct or separate hydrogen , a straight or branched alkyl branched alkyl group containing from 1 to about a group containing from 1 to about 4 carbon atoms 4 carbon atoms, x has an average value of this, x has an average value of 1 to about 10, in 1 to about 10, in has an average value from 10 to has an average value from 10 to about 50. about 50. () mono- or di-quaternary ammonium salts of pho- Surface-active substances effective in rmula: composition of potassium glyphosate compositions , di-ammonium, where ammonium, sodium, monoethinolamine, n-propylamine, 1 PO) x methylamine, ethylamine, hexameth ylenediamine, i.e. (61) methylamine and/or trimethylsulfonium, include

What are the non-cationic, cationic, anionic and amphoteric surface- or surface-active substances described below and their dry ingredients? t mishi

ВА (according to х (62) Cationic surfactants, effective in glyphosate compositions include: where Р, 83, ВУ, В5, ВВ И Б? independently represent co- (a) secondary or tertiary amine formulas: hydrogen, hydrocarbyl or substituted hydrocarbyl 4 "Kk (63) bel, containing from 1 to about 30 carbon atoms, and M KI

Kk or -(HPO)XA", A" is a hydrocarbylene or where B! and B? represent hydrocarbyl, substituted hydrocarbylene containing from 2 to 1 to about 30 carbon atoms, KZ represents 30 carbon atoms, K" in each Х(КРО) and у(КО"О) is hydrogen or hydrocarbyl containing from 1 to the group independently represents C2-Ca alkylene, B about 30 carbon atoms. In this context, represents hydrogen, a straight or branched alkyl

predominant B, B2 and C hydrocarbyl groups are 3595, 4095, 4595, 5095 or 5506.95 k.e., or, with a straight or branched alkyl, straight or lower, about 270g k.e. of glyphosate per liter, more branched alkenyl, straight or branched preferably at least 300, 360, 400, 420, 440460, alkynyl, aryl or aralkyl groups. Advantage - 480, 500, 520 or 540 g c.e./l. zhno, B' represents a straight or branched alkyl- (b) monoalkylated amines of the formula: l, a straight or branched alkenyl group containing from about 8 to about 30 carbon atoms (64) this, B? and VZ independently represent hydrogen, i.e. straight or branched alkyl, straight or loose B! and K" independently represent a hydrocarbylated alkenyl group containing from 1 to blebyl or substituted hydrocarbyl groups containing 6 carbon atoms. More preferably, VE! represents from 1 to about 30 carbon atoms or - straight or branched alkyl group that VAZA, В? in each x(КО"О) group independently represents containing from about 12 to about 22 carbon atoms C2-Са alkylene, C represents hydrogen, straight, B2 and ЕЗ independently represent hydrogen, methyl, or a branched alkyl group containing from tyl or ethyl. In one of the embodiments of the amine of formula 1 up to about 4 carbon atoms, KU is (СС), В! represents a straight or branched alkyl straight or branched alkyl group containing a lin group containing from about 12 to about from about 6 to about 30 carbon atoms, B 22 carbon atoms, P? and C are independently hydrocarbyl or substituted hydrocarbyl straight or branched hydroxyalkyl groups, a radical group containing from 4 to about 15 carbon atoms containing from 1 to about 6 carbon atoms. had carbon, x has an average value from 1 to close

In one of the embodiments, surface-active substance 60. In this context, the preferred K", B" and Kk wines have the formula (48), where B! is a hydro-hydrocarbyl groups are a straight or carbyl or substituted hydrocarbyl containing from branched alkyl, straight or branched al- about 8 to about 30 carbon atoms, P? represents a kenyl, straight or branched alkynyl, is a "hydroxyalkyl, polyhydroxyalkyl or aryl or aralkyl group. In one embodiment, a poly(hydroxyalkylalkyl group, BZ is B! includes from about 7 to about 30 hydrogens, hydroxyalkyl, polyhydroxyalkyl or - carbon atoms, preferably from about 8 to bly(hydroxyalkyl)alkyl. In this context, preferably 22 carbon atoms, and the remaining groups other than B! hydrocarbyl groups represent a straight line as indicated above. Preferably, K ! and K" independent or branched alkyl, straight or branched, each represents a straight or branched alkyl-alkenyl, straight or branched alkynyl, line, straight or branched alkenyl group, an aryl or aralkyl group. In one of the embodiments, it contains from 1 up to about 25 carbon atoms, K?

IN! represents straight or branched alkyl, each x(7O) group independently represents C2-C4 straight or branched alkenyl, straight or disalkylene, EZ represents hydrogen, methyl or ethyl, x is a branched alkynyl, aryl or aralkyl group a value of from 1 to about 40. More pu containing from about 8 to about 30 atoms preferably, K' and B" independently represent carbon, B? represents a straight or branched straight or branched alkyl group containing a hydroxyalkyl group that contains from 1 to about 1 to about 22 carbon atoms, K? in each of 6 carbon atoms, BZ is hydrogen, straight X(B?O) group independently is ethylene or or a branched hydroxyalkyl group containing propylene, KZ is is hydrogen or methyl, x has from 1 to about 6 carbon atoms. Preferably, B! averages from 1 to about 30. Even more is straight or branched alkyl, preferably, K' is straight or branched- straight or branched alkenyl , straight or p an alkyl group containing from about 8 to a branched alkynyl, aryl or aralkyl group of 22 carbon atoms, K" is a straight or po containing from about 8 to about 22 atoms a branched alkyl group containing from 1 to carbon, B2 is a straight or branched chain of about 22 carbon atoms, K" in each x(К?О) group is a hydroxyalkyl group containing from 1 to about pi independently represents ethylene or propylene, with 4 carbon atoms, EZ is hydrogen, straight is hydrogen or methyl, x is a medium or branched hydroxyalkyl group containing from about 1 to about 10. At most from 1 to about 4 carbon atoms. More preferably, K represents a straight or branched chain, B' represents a straight or branched alkyl-alkyl group containing from about 16 to a single, straight or branched alkenyl, straight or 22 carbon atoms, B" represents methyl, 2 or branched alkynyl, aryl, or aralkyl- in each ЖР"О) group is ethylene, K is a group containing from about 8 to about 18 hydrogens, x has an average value of about carbon atoms, B2 is hydroxymethyl or 1 to about 5, or K' is a straight or dihydroxyethyl, C is hydrogen, a hydroxymegaloalkyl group containing from about 8 til or hydroxyethyl. up to about 15 carbon atoms, B" represents

In one of the embodiments, secondary and tertiary amines methyl, K? in each X(K?O) group is ethene included in glyphosate concentrates, excluded, BZ is hydrogen, x has an average knowing the IRA salt of glyphosate, such as glycation concentrates from about 5 to about 10 phosate containing potassium glyphosate, di-ammonium, In one of the embodiments, mono-alkylated amines of ammonium, sodium, monoethylamine, n-propylamine are included in glyphosate concentrates, but not in methylamine, ethylamine, hesamethylenediamine, dime- IRA salts of glyphosate, such as concentrates of glyphosate-ethylamine or trimethylsulfonium and their mixtures, which contain glyphosate of potassium, di-ammonium, ammonium, contain at least about 20o06.95 k.e. glyphosate, sodium, monoethinolamine, n-propylamine, methyl- more preferably, at least about 2595, 3095, mine, ethylamine, hexamethylenediamine, dimethyl-

mine or trimethylsulfonium and their mixtures, which include at least approximately 20-06.95 k.e. of methylated quaternary ammonium. glyphosate, itself ESHodzeitm C12 (RES 2 cocomethylammonium more preferably, at least, about 2595, 30905, chloride from AK2o Maubray!), RES 5 cocomethylammonium

ZBov, 4095, 4595, 5095 or 5506.905 k.e., or, with chloride, РЕС 5 thallomethylammonium chloride, РЕО 5 hire, about 270 g k.e. of glyphosate per liter, more dithaloammonium bromide and RES 10 dithaloammonium bromide, preferably at least 300, 360, 400, 420, 440, copper. 460, 480, 500, 520 or 540 g c.e../l. In one of the embodiments, salts of dialukoxylated (c) salts of dialkylated quaternary quaternary ammonium are part of the ammonium concentrates of the formula: glyphosate concentrates, different from IRA glyphosate, such as glyphosate concentrates containing glyphosate xx potassium, di-ammonium, ammonium, sodium, monoethanolamio (pgoune (65) n-propylamine, methylamine, ethylamine, hexamethylenediamine, dimethylamine or trimethylsulphonium and their mixture containing at least about where K' represents hydrocarbyl or substituted 20o6.965 ke glyphosate, more preferably at least hydrocarbyl containing from 1 to about 30 atoms of no, about 25965, 3095, 3595, 4095, 4595, 5095 or carbon, K? in each x(K? О) and у(КО) group are independent - 5506.95 k.e., or at least about 270 g k.e., clearly represents С2-Са alkylene, BEZ represents phosate per liter, more preferably, at least, 300, hydrogen, a straight or branched alkyl group that 360, 400, 420, 440, 460, 480, 500, 520 or 540g contains from 1 to about 4 atoms in carbon, R" yav- k.e./l is hydrogen, hydrocarbyl, or substituted hydrocarbyl (4) salts of monoalkylated quaternary rocarbyl containing from 1 to about 30 ammonium atoms of the formula: carbon, x and y independently have an average value of from 1 to about 40, and X is an anion, accepted- | used for agricultural compositions. In the present (66) context, the preferred hydrocarbyl groups B! and B" are straight or branched alkyl, straight or branched alkenyl, straight where B! and E5 independently represent hydrogen, or branched alkynyl, aryl or aralkyl hydrocarbyl or substituted hydrocarbyl containing lin groups. Preferably, K! and E" independently represent from 1 to about 30 carbon atoms, B. is a straight or branched alkyl, straight or bi hydrocarbyl or substituted hydrocarbyl containing a branched alkenyl group containing from 1 to containing from 1 to about 30 carbon atoms, P? in about 25 carbon atoms, MK" in each x(PO) and each x(22O) group independently represents C2- C4 in the (82O) group independently represents C2-Ca alkylene, alkylene, BZ represents hydrogen, straight or branched

VAZ is hydrogen, methyl, or ethyl, the sum of x and u alkyd alkyl group containing from 1 to about has an average value of about 2 to about 30. 30 carbon atoms, x has an average value of 1

More preferably, B" and K" independently represent sodium up to about 60, and X is an anion acceptable for combating a straight or branched alkyl group, which is for agricultural compositions. In this contains from 1 to about 22 carbon atoms, K- in the context, predominant B", B and 5 hydrocarbyl groups - each x(K"O) and y(B"O) group independently represents sops represent a straight or branched alkyl is ethylene or propylene, EZ is hydrogen, straight or branched alkenyl, straight or methyl, the sum of x and y has an average value of branched alkynyl, aryl or aralkyl from about 2 to about 20. Even more preferably, B! groups. Preferably, B, B" and B3 independently represent a straight or branched alkyl group, a straight or branched alkyl, straight or pU containing from about 8 to about 22 atoms, a branched alkenyl group containing from 1 to carbon, K" is a straight or branched chain of about 25 carbon atoms, P? in each x(P2O) is a gru-alkyl group containing from Y to about 22 pi independently represents a C2-Ca alkylene, KZ represents carbon atoms, B" in each Ж(КО"О) and у(БО"О) group is hydrogen, methyl or ethyl, x has an average sign- independently represents e ethylene or propylene, with a value of from 1 to about 40. More preferably, B is hydrogen or methyl, x has an average of B, and 25 independently represents a straight line or a value of from about 2 to about 20. The most branched alkyl group that contains from 1 to bly- mostly, B! is a straight line or a branch of 22 carbon atoms, B? in each x(B2O) group, there is an alkyl group containing from about 8 to about 22 carbon atoms, BZ is ethylene or propylene, EC" is a straight line or is hydrogen or methyl, x has an average branched alkyl group , containing from 1 to a value from 1 to about 30. Even more preferably, about carbon atoms, K" in each x(P/O) and no, B! represents a straight or branched alkyl- in (820) group independently represents ethylene or a group containing from about 8 to about 22 propylene, EZ represents hydrogen or methyl, x has carbon atoms, P? in each x(B2O) group, the independent mean value is from about 2 to about 15, or n represents ethylene or propylene, BZ represents

V and vk" independently represent a straight or branched hydrogen or methyl, P and VE? independently represent a branched alkyl group containing from about 8 straight or branched alkyl groups to about 22 carbon atoms, K" in each Ж(П"О) and containing from 1 to about 22 carbon atoms, x in the (82O) group is independently ethylene or has an average value from 1 to about 30. Also propylene, KZ is hydrogen or methyl, x has more preferably, P! is a straight or average value from about 5 to about 15. a branched alkyl group containing from about 8

Predominant surface-active substances are di-alcohols up to about 22 carbon atoms, B? in each x(22O)

group independently represents ethylene or propylene, well, a group containing from 1 to about 6 carbon atoms

BZ is hydrogen or methyl, P and 2? non-flyer. Most preferably, KE! represents a straight or branched alkyl or branched alkyl group containing a single group containing from 1 to about 6 atoms of about 8 to about 14 carbon atoms, P2, B3 and Vy carbon, x has an average value of about 5 to represent methyl. Preferable commercially dos- about 25. Most preferably, B! is a blunt surface-active substance of a quaternary straight or branched alkyl group containing ammonium, including Agapai "m C-50 (dodec- from about 16 to about 22 carbon atoms, P? in ltrimethylammonium chloride from AKlo Morey) and each x (P2O) group independently represents ethylene Agdchaitm T-50 (thallium trimethylammonium chloride or propylene, EZ represents hydrogen or methyl, from Ak2o More).

IN? and Ex independently represent a direct or di- In one of the embodiments, quaternary ammonium salts branched alkyl group containing from 1 to bli- are included in the composition of glyphosate concentrates, but not from 3 carbon atoms, x has an average value from the IRA of the glyphosate salt, such as glyphosate concentrates - about 5 to about 25. Preferable surfactants containing potassium glyphosate, di-ammonium, ammonium, mono-alkylated quaternary sodium, monoethanolamine, n-propylamine, methylatin ammonium active substances include РЕС 7 С18 dimine, ethylamine, hexamethylenediamine, dimethyla-methylammonium chloride and РЕС 22 С18 dimethylammonium mine or trimethylsulfonium and their mixtures, which are chloride. that is, at least about 2006.95 glyphosate k.e.,

In one of the embodiments, the mono-alkylated, more preferably, at least about 2595, 30905, quaternary ammonium salts are part of the concen- 3595, 4095, 4595, 5095 or 5506.95 k.e., or, glyphosate preparations, but not IRA of glyphosate salts, such as the smallest, about 270 g k.e. of glyphosate per liter, more than glyphosate concentrates containing glyphosate preferably, at least, 300, 360, 400, 420, 440, 460, potassium, di-ammonium, ammonium, sodium, monoethanolami- 480, 500, 520 or 540 g c.e./ l. well, n-propylamine, methylamine, ethylamine, hexame- (9 ether of amines of the formula: tylendiamine, dimethylamine or trimethylsulfo- / their mixtures, which contain at least about vie-yai - M (68) vol.95 k of glyphosate, more preferably, at least about 2595, 3095, 3595, 4095, 4595, 5095 or their 5506.905 k.e., or at least about 270 g k.e. hydrocarbyl or substituted phosate per liter, more preferably at least 300, hydrocarbyl containing from 1 to about 30 atoms of 360, 400, 420, 440, 460, 480, 500, 520 or 540g of carbon; KE? is hydrocarbylene or substituted - c.e./l. of a substituted hydrocarbylene containing from 2 to about (e) of a quaternary ammonium salt of the formula: 30 carbon atoms; EZ and B" independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl, which contains from 1 to about 30 carbon atoms, from - ВЗ (67) or -(ВО)ХАЭ, ВЗ in each x(В5-О) group independently represents Co-C4 alkylene, BU represents vo-vo den, direct or a branched alkyl group, which d e B!, BZ and B: independently represent va- contains from 1 to about 4 carbon atoms, x has den, hydrocarbyl or substituted hydrocarbyl, which averages from 1 to about 50. In this contains from i to about 30 carbon atoms , B2 contexts, the preferred P", A", VAZ and B" hydrocarbyl is a hydrocarbyl or substituted hydrocar- (hydrocarbylene) groups are straight or white, containing from 1 to about 30 carbon atoms, branched alkyl (alkylene), straight or roz- and X is an anion acceptable for village branched alkenyl (alkenylene), direct or gift compounds. In this context, branched alkynyl (alkynylene), aryl important B", B2, B3 and hydrocarbyl groups are (arylene) or aralkyl (aralkylene) groups. are straight or branched alkyl, straight or Preferably, A" is straight or branched-branched alkenyl, straight or branched alkyl, straight or branched alkenyl, alkynyl, aryl or aralkyl groups. Predominantly straight or branched alkynyl, aryl or zno, B! represents a straight or branched alkyl-aralkyl group containing from 8 to about 25 contains from about 8 to about 30 carbonized alkylene or alkenylene group containing this, and B2, B3 and B" independently represent a straight line from 2 up to about 30 carbon atoms, KZ and B" unbranched or branched alkyl, straight or branched are hydrogen, straight or branched alkenyl group containing from 1 to about 30 alkyl, straight or branched alkenyl, carbon atoms. More preferably, B' is a straight or branched alkynyl, aryl, or straight or branched alkyl, straight or branched alkyl group containing from 1 to about 30 alkylated alkenyl group containing from about 8 carbon atoms, or -""WZO )ХАЭ, ВЗ in each zho) up to about 22 carbon atoms, Р, ВЗ and В" are independent - the group independently represents C2-Са alkylene, Ko represents a straight or branched alkyl - represents hydrogen, methyl or ethyl, x has serene, a straight or branched-chain alkenyl group having a value of from 1 to about 30. More preferably, it contains from 1 to about 6 carbon atoms. Also, P! is a straight or branched-chain alkyl- more preferably, B! is a straight or different or alkenyl group containing from 8 to a branched alkyl group containing from about 8 to about 22 carbon atoms, "7 is a straight to about 16 carbon atoms, P, B3 and P" independent or branched alkylenyl or alkenylene group represent a straight or branched alkyl group, which m consists of 2 to about 6 carbon atoms

this, VZ and B? independently represent hydrogen, a straight or branched alkylene or alke - a straight or branched alkyl or alkenyl nyle group containing from about 8 to about - a group containing from 1 to about 6 carbon atoms - 25 carbon atoms, n, in and 7 are 0; or this one, or -(В82О)ХВЕ, В? in each x(E2O) group, B, 82, BZ and 27 independently represent hydrogen, z represents ethylene or propylene, 9 represents a straight or branched alkyl or alkenyl is hydrogen or methyl, x has an average value of a group containing from about 1 to about 6 ato- from 1 to about 15. Most preferably, VE! carbon atoms, 22 is a straight or branched straight or branched alkyl or female alkylene or alkenylene group, which is an alkenyl group containing from 8 to about 18 or from about 1 to about 6 carbon atoms, 5 atoms carbon, K2 represents ethylene or propyl in each y(250) group independently represents C2-Са4 lene, VZ and 2? independently represent hydrogen, alkylene, y has an average value from 1 to about methyl or -(82О)ХВЭ, ВЗ in each X(Е?О) group is not 20, n and 72 are equal to 0; or B" and C independently represent ethylene or propylene, P? represents a straight or branched alkyl group, is hydrogen, x has an average value from 1 to a straight or branched alkenyl group containing about 5. 8 to about 22 carbon atoms,

In one embodiment, the amine ether is included in B? is a straight or branched alkylene composition of glyphosate concentrates, but not an IRA salt of a gly- group containing from about 2 to about 25 atofosate, such as carbon-containing glyphosate concentrates; B" and Ex each independently represent potassium glyphosate, di-ammonium, ammonium, sodium, hydrogen, a straight or branched alkyl or monoethanolamine, n-propylamine, methylamine, an ethylalkenyl group containing from 1 to about 6 amines, hexamethylenediamine, dimethylamine or carbon atoms, or -(ВО)ХВ", В? in each x(9O) trimethylsulfonium and their mixtures, which contain, the group independently represents C2-Ca alkylene, at least, about 2006.95 k.e. of glyphosate, is more hydrogen, straight or branched, preferably at least about 2595, 30905, 35905, 40905, a group containing from 1 to about 4 atoms 45905, 5095 or 5506.90 o k.e., or , at least near carbon, x has an average value from 1 to about 270g k.e. of glyphosate per liter, more preferably, pri- ZO, n, y and 75 represent 0; or VE! is a pure, 300, 360, 400, 420, 440, 460, 480, 500, 520 straight or branched alkyl, straight or branched or 540 g c.e./l. tinned alkenyl group containing from about 1 (9) diamine of the formula: to about 22 carbon atoms, B? is a branched, linear or branched alkylene group containing (69) from about 2 to about 25 carbon atoms, where В, ВЗ, В and В5 independently represent ВЗ, В" and Е? each independently represents hydrogen, hydrogen, hydrocarbyl or substituted hydrocarbyl, which is a straight or branched alkyl group containing from 1 to about 30 carbon atoms, or - from 1 to about b carbon atoms, X is - (AYAOHV"; B? and 28 are independently hydro-С(0)- or -505-, n and y are equal to 0 and 7 is a carbylene or substituted hydrocarbylene containing 1. More preferably, K' and KE" independently represent from 2 to about 30 atoms carbon, KU in each straight or branched alkyl, straight or х(ВЗО) and у(Р5О) group independently represents a C2-C4 branched alkenyl group containing from bly- alkylene, B" represents hydrogen, straight or branched from 4 to about 18 carbon atoms, K? represents a solvated alkyl group containing from 1 to about 6 straight or branched alkyl ene group containing carbon atoms, x has an average value of 1, contains from about 2 to about 6 carbon atoms, up to about 30, X is -O-, -M(B2)-, -C(O)-, - VAZ and 5 each independently represents hydrogen, с(0О-, -ОС(О0)-, -(ВУС(О0)-, -С(О)М(Б2)-, -5-, -80- a straight or branched alkyl group , that contains ; or -502-, y is 0 or an average value of 1 to about 6 carbon atoms, n, y and 2 are from 1 to about 30, n and 7 are independently 0; or Kk", B, AZ Her K" independently represent 0 or 1, RE? is hydrogen, hydrocarbyl is hydrogen, straight or branched alkyl or substituted hydrocarbyl. In this context, a group containing from about 1 to about b ato-predominantly E!, B, VZ, VU, B5 and 2: hydrocarbyl (hydrocarbyl carbon, K7 is a straight line or dishalurocarbylene) groups are a straight line or a female alkylene group containing from about 8 to branched alkyl (alkylene), straight or di- about 25 carbon atoms, y equals 0; or K", branched alkenyl (alkenylene), straight or A", BB and Ky independently represent hydrogen, straight-branched alkynyl (alkynylene), aryl or branched alkyl group containing from (arylene) or aralkyl (aralkylene) group . about 1 to about 6 carbon atoms, K? represents

Mostly, V! and Bo independently represent a straight or branched alkylene group, a straight or branched alkyl, straight or branched containing from about 1 to about b atoms, a carbonized alkenyl group containing from about 1 let, E in each in (РО) group independently represents up to about 22 carbon atoms, B? and 28 are independently ethylene or propylene, y has an average of straight or branched alkylene values from 1 to about 10, n and 2 are equal to 0; or groups containing from about 2 to about 25 atoms - A! and Z independently represent a straight or branched carbon, BZ and B5 each independently represent a branched alkyl group containing from about 8 hydrogens, a straight or branched alkyl group to about 22 carbon atoms, K? is a po containing from 1 to about 6 carbon atoms, a straight or branched alkylene group, where p, y and 2 are equal to 0; or P, B2, B3, and B: independently of about 2 to about 6 carbon atoms, P" is hydrogen, straight or branched and E5 is each independently hydrogen, straight alkyl or alkenyl group containing from bli- or branched alkyl a group containing from 1 to about 6 carbon atoms, B? represents sodium to about 6 carbon atoms, or -(НеО)ХВ", НЕ in each ХРО) group independently represents ethylene represents a straight or branched alkyl group , or propylene, B" represents hydrogen or methyl, x containing from about 8 to about 22 carbon atoms has an average value of from 1 to about 15, n, y and 7 let; or B" and 2 independently represent - equal 0; or EE! is a straight or branched (B'O)ХВ?, BZ is a straight or branched branched alkyl group containing from about 1 alkyl group containing from about 8 to about to about 22 carbon atoms, B? represents up to 22 carbon atoms, Р" in each ХРО) group is a straight or branched alkylene group, which is ethylene or propylene, Р? is from about 2 to about 6 carbon atoms, hydrogen or methyl, x has an average value of 1

VAZ, VI and E5 each independently represents hydrogen, up to about 10. Most preferably, KE! and 2 non-

X represents -C(O)-or -505-, n and y are equal to 0 and are usually methyl, KE is a straight 7 equal to 1. Preferred diamines include mu or branched alkyl group containing from

Setipi 14-2-14, (zetipi 14-3-14, Sbetipi 10-2-10, about 8 to about 18 carbon atoms; or B! and

Setipi 10-3-10, (3etipi 10-4-10 and Setipi 16-2-16 B: independently represent -(В7О)ХВ?, ВЗ represents (С10, С14 or С16 ethylene, propylene or butylene is a straight or branched an alkyl group that

M-methyldiamine from Mopzapio), ESHToacoteepv5 "mM and contains from about 8 to about 18 carbon atoms

Ueyatip"m EOV-148. this, B" in each x(B7O) group is ethylene

In one of the embodiments, diamines are included in the composition or propylene, C is hydrogen, x has sulfur, glyphosate concentrates, but not IRA of glyphosate salts, d value from 1 to about 5. Commercially sufficient as glyphosate concentrates containing glyphosate blunt surface-active amine oxides include potassium, di-ammonium, ammonium, sodium, monoethane, amine, n-propylamine, methylamine, ethylamine, hec- In one of the embodiments, amine oxides are included in samethylenediamine, dimethylamine or of glyphosate concentrates, but not IRA of glycyrrhizinyl sulfonium salts and their mixtures containing priphosate, such as glyphosate concentrates, which are interchangeable, about 2006.95 k.e. glyphosate, more than five glyphosate of potassium, di-ammonium, ammonium, sodium, respectively, at least about 2595, 3090, 3590, 40905, monoethanolamine, n-propylamine, methylamine, ethyl 45905, 5095 or 5506.90 o k.e. , or at least about lamine, hexamethylenediamine, dimethylamine, or 270g c.e. of glyphosate per liter, more preferably, trimethylsulfonium and their mixtures, which contain at least 300, 360, 400, 420, 440, 460, 480, 500, 520, about 2006.905 k.e. of glyphosate, more or 540 g.c.e./l. preferably, at least about 25905, 30905, 3595, 4090, (n) amine oxides of the formula: 45905, 5095 or 5506.95 k.e., or at least about 270g k.e. of glyphosate per liter, preferably at least 300, 360, 400, 420, 440, 460, 480, 500, 520

DV (70) or 540g k.e./l.

Her () dialkylated amines of the formula:

On where V! В2 and З independently represent vo- - M to (7) day, hydrocarbyl or substituted hydrocarbyl, - s uk (В'ОХВ?, or -В(ОВУХОВ; В? in each x(ВО) where ЕК! is a straight line or branched alkyl group independently represents C2-Ca4 alkylene, B linear, straight or branched alkenyl, straight represents hydrogen, straight or branched alkyl or branched alkynyl, aryl or aralkyl group containing from 1 to about 30 atoms group containing from about 6 to about 30 carbons, VU is a hydrocarbylene or substituted carbon atoms, or -B"ZH, B? in each Z(K"O) and a hydrocarbylene containing from 2 to about 6 The (B82O) group independently represents C2-Ca alkylene, carbon atoms, x has an average value from 1 to B3 is hydrogen, straight or branched about 50, the total number of carbon atoms in B, an alkyl group containing from 1 to about 4 atoms

B2 and BZ is at least 8. In this context of carbon, K" is straight or branched, the predominant P", B2, BZ and Re are hydrocarbyl (a hydrogenated alkyl group containing from about b to rbylene ) groups are straight or branched - about 30 carbon atoms, x and y independently have a tinned alkyl (alkylene), straight or average value from 1 to about 40. Preferably, branched alkenyl (alkenylene), straight or A! represents a straight or branched alkyl, branched alkynyl (alkynylene), aryl straight or branched alkenyl group, which is a mis- (arylene), or aralkyl (aralkylene) group. from about 8 to about 30 carbon atoms,

Mostly, V! and 22 independently represent vo- V? in each x(B?O) and y(K2O) group independently represents a day, straight or branched alkyl, straight or C2-C4 alkylene, BZ represents hydrogen, me-branched alkenyl group containing from 1 to til or ethyl , x and y independently have an average value of about 30 carbon atoms, or -(B'O)ХВ; VZ represents a number from 1 to about 20. More preferably, B! is a straight or branched alkyl, straight or is a straight or branched alkyl group- a branched alkenyl group containing from blip containing from about 8 to about 25 carbon atoms from 8 to about 30 carbon atoms, B in each carbon, RK ? in each x(К?О) and y(22О) group, independent

X(B:O) group independently represents Co-Ca alkylene; zhno represents ethylene or propylene, KZ represents

BZ is hydrogen, methyl or ethyl, x is hydrogen or methyl, x and y independently have an average value from 1 to about 30. More pre- an average value from 1 to about 10. Even more zealously, B! and B? independently represent vo- mostly, K! represents a straight or branched, straight or branched alkyl group, that is, an alkyl group containing from about 8 to about 1 to about 6 carbon atoms, and BZ clearly has 22 carbon atoms, K2 in each GEO) and the (P?O) group independently represents ethylene or propylene,

VAZ is hydrogen or methyl, x and y are independently hydrogen, straight or branched alkyl having an average value from 1 to about 5. A subgroup containing from 1 to about 30 carbon atoms are commercially available dialkylated amines of leucine; n has an average value from 1 to about 60; include Ttuteep'"mmMm 6617 (from Sodpiv) and m has an average value from 1 to about 50; B: and

EShoteep C/12, C/15, C/20, C/25, T/12, T/15, T/20 and B" each independently represents a hydrocarbylene t/25 (from AK2o More). or a substituted hydrocarbylene containing from 1 to

Such dialkylated amines preferably contain about 6 carbon atoms; B" represents potassium hydrocarbylene or substituted hydrocarbylene, containing at least 550 grams per liter of glyphosate from 2 to about b carbon atoms; B!2 represents potassium, and , more preferably at least 560, 570 or hydrogen, hydrocarbyl or substituted hydrocarbyl 580 gram c.e. per liter of potassium glyphosate. Preferably, white containing from 1 to about 30 carbon atoms; so that such potassium glyphosate concentrates would contain t and 5 each independently represents 0 or 1; 65 from about 550 to about 600 grams c.e. per liter is hydrocarbylene or substituted potassium hydrocaglyphosate. rbylene containing from 2 to about 30 carbon atoms

Alternatively, dialkylated amines of perlecium, -С(-МА!2)-, -С(5)- or -С(0)-; 4 is equal to the total number of 0 to 5 included in the composition of glyphosate concentrates; and E? is hydrogen, potassium, containing at least 320 grams k.e. per liter hydrocarbyl or substituted hydrocarbyl containing potassium glyphosate, not containing alkylpolyglycosides of from 1 to about 30 carbon atoms. In this con- or containing alkylpolyglycosides only with light text, the preferred ones are E", B2, B", B, ВАЭ, B", BB, VU, B with a color of less than 10, preferably less than 9, 8, 7, B": hydrocarbyl ( hydrocarbylene) groups are either 5, measured with a colorimeter, are straight or branched alkyl (alkylene-

Sagapeg. In yet another embodiment, such concentrates wu), straight or branched alkenyl (alkenyl- include at least 330, 340, 350, 360, new), straight or branched alkynyl (alkynyl- 370, 380, 390, 400, 410 , 420, 430, 440, 450, 460, new), aryl (arylene) or aralkyl 470, 480, 490, 500, 510, 520, 530, 540, 550, 560, 570 (aralkylene) groups. or 580 grams k.e. per liter of potassium glyphosate. Predominantly, in one of the embodiments, the aminated alkylated potassium glyphosate concentrates contain from alcohols included in the glyphosate concentrates, about 400 to about 600 grams k.e. per liter of glyphosate, but not IRA salts of glyphosate, such as potassium phosate concentrates, more preferably from about 450 glyphosate containing potassium glyphosate, di-ammonium, to about 600, about 500 to about 600, bly-ammonium, sodium, monoethanolamine , n-propylamine, about 540 to about 600 or about 550 to blymethylamine, ethylamine, hexamethylenediamine, about 600 gram c.e. per liter of potassium glyphosate. methylamine or trimethylsulfonium and their mixtures, which

Alternatively, dialkylated amines contain at least about 2006.90 k.e. glyphosate, it is important to include in the composition of glyphosate concentrates more preferably at least about 2595, 30905, potassium containing from about 20 to about 150 3595, 4095, 4595, 5095 or 5506.95 keu, or, grams per liter of all of surface-active substances in nyam, about 270g k.e. of glyphosate per liter, more compositions, more preferably, from about 20 to preferably at least 300, 360, 400, 420, 440, about 130 grams per liter. In another embodiment, dia- 460, 480, 500, 520 or 540 g c.e./l. lkoxylated amines are included in the composition of the concen- The subclass of such cationic surfactants of potassium glyphosate, containing from about 20 to substances includes mono-alkylated about 150 grams per liter of all surface-active amines of the formula: substances of the composition and at least 320 grams of is. per liter of potassium glyphosate, more preferably, at least, o. (8202-83 -M (73) 330, 340, 350, 360, 370, 380, 390, 400, 410, 420, "where 430, 440, 450, 460, 470, 480, 490, 500, 510, 520, 530 , where B! represents hydrogen, hydrocarbyl, or 540, 550, 560, 570, or 580 gram c.e. per liter of glypho- substituted hydrocarbyl containing from 1 to about potassium phosate contained from about 400 to about independently represents C2-C4 alkylene; BZ is 600 grams per liter of potassium glyphosate, more preferably hydrocarbylene or substituted hydrocarbylene, but from about 450 to about 600, about 500 to containing from 2 to about 30 carbon atoms; B. and about 600 , about 540 to about 600 or nearly B? each independently represents hydrogen, hydro- 550 to about 600 gram c.e. per liter of glyphosate carbyl or substituted hydrocarbyl containing from 1 potassium. , , , to about 30 atoms of carbon, -(VU)p-(820)u87, or and () aminated alkylated alcohols, the following B and 5, together with the nitrogen atom to which they are attached- chemical structure: in dnan, form cyclic or heterocyclic and in k ilce; C is hydrocarbylene or substituted-1; 4 in total hydrocarbylene containing from 1 to about 30 in -K-- (in оу--Н -х de (66) carbon atoms; B" is hydrogen, a straight or branched alkyl group containing 1 to bly - where K", НУ, АВ and РЕ? each independently represents 4 carbon atoms, n is equal to 0 or 1, x and is hydrogen, hydrocarbyl or substituted hydrocarbyl - independently have an average value from 1 to blbil containing from 1 to about 30 carbon atoms, zko 60. In this context, preferred are B", VU, VU, or (-(B87)5(AZO)yB; X represents -О-, -ОС(О)-, - А and в5 hydrocarbyl (hydrocarbylene) groups яв-с(Ф)О-, -СХАС(О)-, -С(О)М(В2)-, -8-, -80-, -505- are straight or branched alkyl (al- or -M(AU)-; BZ in each p(KZO) group and ZO) group is a kylene), straight or branched alkenyl (al- is independently a C2-Ca alkylene; B!9 is a kenylene), straight or branched alkynyl

(alkynylene), aryl (arylene) or aralkyl- to Hm v'nu (aralkylene) groups. Preferably, B represents a straight or branched alkyl, straight or I and branched alkenyl group containing from about 8 to about 25 carbon atoms, P? in each 7

The X(B2O) group is independently a C2-Ca alkylene, in I it is Y

BZ is a straight or branched alkylene Kk in-vo ivvo--n-- Den ko (76) group containing from 2 to about 20 carbon atoms, B? and E5 each independently represents a vo- or day, straight or branched alkyl group containing from 1 to about 6 carbon atoms, x has k--y, v n--(AZO3a (ВК шк -еа х) (77 ) average value from 1 to about 30. More importantly, B' is a straight or branched ... alkyl group containing from about 12 to pale B", B", then those DIs independently represent 22 carbon atoms, B? in each x(B2O) group is hydrogen, hydrocarbyl or substituted hydrocarbyl, independently represents ethylene or propylene, C rbyl, containing from 1 to about 30 carbon atoms, represents a straight or branched alkylene chain, or OMA X is a -0., Y group containing from 2 to about 6 carbon atoms - В" "(В (Оу, "(ОМ )- -Ф(0)0- or -5-; this, В" and E5 each independently represents hydrogen, in each P(KTO) group! What: o) the group is independently methyl or tris(hydroxymethyl)methyl, x has sulfur - is C2-Ce apkylene; LC" is a water value from about 2 to about 30. Another day, straight or branched alkyl group, more preferably, B! is a straight line or contains from 1 to about 30 carbon atoms; n has a branched alkyl group containing from about 12 with an average value of from 1 to about 60; U has sulfur: up to about 18 carbon atoms, BV? in each x(2O) the value is from 1 to about 50; NI Her K 7 each group independently represents ethylene or propylene, independently represents hydrocarbylene or substituted

BZ is ethylene or propylene, KE" and 25 are each hydrocarbylene containing from 1 to about 6 independently representing hydrogen, methyl or carbon atoms; t and 5 are each independently tris(hydroxymethyl)methyl, x has an average value of 0 or ShO; is a hydrocarbylene or a substitution of from about 4 to about 20. The most preferred hydrocarbylene containing from 2 to about 6, B' is a straight or branched chain of alkyl carbon atoms, and is a hydrocarbylene or group containing from about 12 to about substituted hydrocarbylene containing from 2 to about 18 carbon atoms, B? in each х(Б2О) group there are approximately 30 volumes of carbon, -С(-МА 7), -6(5)- or Lezhno represents ethylene or propylene, ВЗ represents FO); A is hydrogen, hydrocarbyl or ethylene, B" and Ex are methyl, x has a substituted hydrocarbyl containing from 1 to about an average value from about 4 to about 20. Of the carbon atoms, d is an integer from 0

Preferred monoalkylated amines include up to 5; And hydrogen, hydrocarbyl or substituted pd. itself RES 13 or 18 Cis5 esters of propylamines and rocarbyl containing from 1 to about 30 atoms

RES 7, 10, 15 or 20 Siv-from esters of propylamines (from carbon; and each A-is an anion accepted

Totai) and RES 13 or 18 Cia5 dimethylpronium ethers for agricultural compositions. In yes: pilamines and RES 10, 15 or 20 or 25 Stivlv ethers / MY context, preferred B", N. A A", A B, H,, dimethylpropylamines (from Totai) and Zypopismdem- A, A "AT, AT And hydrocarbyl (hydrocarbyl-550 from Nipiztap. new) groups are straight or branched

In one of the embodiments, monoalkylated amines alkyl (alkylene), straight or branched alkyl are included in glyphosate concentrates, but not kenyl (alkenylene), straight or branched

IRA salts of glyphosate, such as glyphosate concentrates - alkynyl (alkynylene), aryl (arylene) or those containing glyphosate potassium, di-ammonium, ammonium, aralkyl (aralkylene) groups. sodium, monoethanolamine, n-propylamine, methyl. Another cationic surface-active substance of amine, ethylamine, hexamethylenediamine, dimethyl is effective in any composition of glyphosate. , at least, around 20o06b.95 k.e. of glyphosate, Vy (Vaz MA--B3--- MA (Kg ozh-- Vu (78) more preferably, at least about 2595, 3090, and I. 3595, 4095, 4595, 50950 or 5506.95 k.e., or , at least about 270 g of glyphosate per liter, more preferably at least 300, 360, 400, 420, 440, V (A MU (V 460, 480, 500, 520 or 540g c.e../l. t 'im (78)

Quaternary ammonium, sulfonium, and sulfoxonium salts are also effective cationic surfactants.

In ; rbil, containing from 1 to about 30 carbon atoms in this, B? in each t(P2O) and n(B2O) group and B? independent of zyutbov Webstuya A (74) is a C2-Ca alkylene, KZ is a hydrocarbylene or a substituted hydrocarbylene, which either contains from about 2 to about 6 carbon atoms or -(B2O)RVAZ-, and each separately has average value from 0 to about 50, p has an average value from 0 to about 60. In this context, pe-

Reversible E!, BZ, B, B», Be, B" and 28 hydrocarbyl Other nonionic surfactants for the (hydrocarbylene) group are direct or the use in such compositions of glyphosate includes branched alkyl (alkylene), straight or de- Alkoxylated dialkylphenols contain branched alkenyl (alkenylene), straight or mule: branched alkynyl (alkynylene), aryl (arylene) or aralkyl (aralkylene) groups.

In one embodiment of formula (CA), EZ is a hydrocarbylene containing from about 2 to about (81) 6 carbon atoms, and the remaining groups are as defined above.

Preferable nonionic surface-active substances for such glyphosate concentrates include in de B! and E7 are independently hydrogen, themselves are alkylated alcohols of the formula: a straight or branched alkyl group containing в'О-(Б20)ХВ3 (80) from 1 to about 30 carbon atoms and, at least, where E! is a hydrocarbyl or substituted one of K! and 7 represents an alkyl group, B2 in a hydrocarbyl containing from 1 to about 30 atoms, each x(K2O) group independently represents Co2-carbon, E2 in each x(2O) group independently represents a alkylene, B? represents hydrogen, a straight or branched C2-Са alkylene, K represents hydrogen, a straight branched alkyl group containing from 1 to nearly or a branched alkyl group containing from 1 to 4 carbon atoms, x equals the average to about 4 carbon atoms, x has an average value from 1 to about 60. Mostly, B! and teachings from 1 to about 60. In this context, pe- independently represent direct or branched revaving B! hydrocarbyl groups are alkyl groups containing from 8 to about 30 straight or branched alkyl, straight or branched carbon atoms, B? in each x(22O) group, independently alkenyl, straight or branched alkyl represents C2-Salkylene, EZ represents hydrogen, nyl, aryl or aralkyl groups. Preferably, methyl or ethyl, and x equals the average value of

IN! represents a straight or branched alkyl group, from about 5 to about 50. More preferably, a straight or branched alkenyl group, which mis- B! and B" are independently straight or branched from about 8 to about 30 carbon atoms, alkyl groups containing from about 8 to

B2 in each x(K2O) group independently represents about 22 carbon atoms, P? in each X(E2O) group

C2-Ca alkylene, Ez represents hydrogen, methyl or pi independently represents ethylene or propylene, C is ethyl, x has an average value of about 5 to represents hydrogen or methyl, x is equal to an average of about 50. More preferably, K! represents a value from about 8 to about 40. Another straight or branched alkyl group, containing more preferably, KE! and B" independently represent co- from about 8 to about 25 carbon atoms, B? are straight or branched alkyl groups, each x(P2O) group independently represents ethylene and from about 8 to about 16 carbon atoms, or propylene, B? represents hydrogen or methyl, x B2 in each x(B2O) group independently represents has an average value of from about 8 to about 40. ethylene or propylene, BZ represents hydrogen or

Even more preferably, E" is straight or methyl, x has an average value of from about 10 to a branched alkyl group containing from about 30. Preferred commercially available alkocs are 12 to about 22 carbon atoms, BK? in each sylated dialkylphenols include ethoxy (B2O) group independently represents ethylene or syllated dinonyl phenols, such as Zy!Yipopistm tm propylene, Ez represents hydrogen or methyl, x has OMR 100, Bipopistm OMR 140 and Bipopistm OMR 240 average value from about 8 to about 30. (from Nipiztap).

Preferred commercially available alkylated In one embodiment, the phenols included in the composition of the alcohols include Rgosoi"m |IA-15 (from glyphosate concentrates, but not IRA salts of glyphosate,

Rgoiateep), Vgi) "m 35, Vgi) tm 76, Vgi) "m 78, Vgi)/Mm 97 and such as glyphosate concentrates containing glypho-

Vgi)"m 98 (from Zidt Spetis! So.), Meodo! m 25-12 sat potassium, di-ammonium, ammonium, sodium, monoethano- (from Zpei), Nehoio!"m SA-10, Nehoio!"m CA-20, lamin, n-propylamine, methylamine, ethylamine, hec-

Nehoyo!tm S5-9, Nehioiim S5-15, Nehoyo! m Сб5-20, samethylenediamine, dimethylamine or

Nehoiyuo!| tm 25-25, Nehoioio! them 25-30 and Riogagtastm d38 trimethylsulfonium and their mixtures, which contain, pri- (from BA5E), 5T-8303 (from Sodpiv) and Agoz!ygi"M 66 E2O are cheap, about 2006.905 keu of glyphosate, more pe- (from MMiso/Stotriop) respectively, at least around 2595, 3090, 35905, 40905,

In one of the embodiments, 45905, 5095, or 5506.90o c.e. alcohols, or at least close to it, are part of glyphosate concentrates, but not 270g c.e. of glyphosate per liter, more preferably, at

IRA of glyphosate salts, such as glyphosate concentrates - namely, 300, 360, 400, 420, 440, 460, 480, 500, 520 tu containing glyphosate potassium, di-ammonium, ammonium, or 540 g c.e./l. sodium, monoethanolamine, n-propylamine, methylamine, ethylamine, hexamethylenediamine, dimethylane, which are effective as part of compositions of potassium glyphosate, mine or trimethylsulfonium and their mixtures, which include saturated carboxylic acids , such that, at least, about 20o06.95 k.e. of glyphosate, such as butyric, caproic, caprylic, capric, more preferably, at least about 2595, 30905, lauric, palmitic, myristic or stearic acid, or, pyric acid, and unsaturated carboxylic acids, at least, about 270 g. of glyphosate per liter, more such as palmitoleic, oleic, linoleic or preferably at least 300, 360, 400, 420, 440, 460, linolenic acid. Preferred carboxylic acids 480, 500, 520 or 540 g c.e./l. include palmitic, oleic or stearic acid. Other preferred anionic surfactants

active substances include alkyl sulph- additional additives, the addition of phata solubilizers, such as sodium lauryl sulfate and alkyl alkoc- (also commonly called a dot enhancer, silated phosphates of the formula: turbidity or stabilizer) can significantly improve p-o-(5203a to improve the properties of the compositions according to the present invention. Suitable solubilizers for the use of rat (82) together with the new compositions according to the present invention include, for example, cocoamine (Agteep de V' and VZ independently are straight C), dimethylsosoamine (Agdiai Me), cocoaammonium or branched alkyl, straight or branched chloride (Agachai b), REb 2 cocoamine (Effotep alkenyl, straight or branched alkynyl, C12), RES 5 tapoamine (Yetotep T15) and RES 5 co-aryl or aralkyl group containing from blycoamine (Epoteep C15), all are made AK2o zco 4 to about 30 carbon atoms; P? in each More! (Siotia). t(B2O) and p(22O) group independently represents C2- In addition, it was shown that that adding ba

Szalkilen; t and n independently represent from 1 to aryl or aryl amino compound, or from about 30; or accordingly! of quaternary ammonium piphosate 1 increase the compatibility of certain glyphosate salts (for example, potassium or isopropylamine) with the surface eye (83) with active substances that otherwise have low or marginal compatibility when added to glyphosate B! is a straight or branched viola. Suitable alkyl or aryl amino compounds, linear, straight or branched alkenyl, straight may also contain from 0 to about 5 EO groups. lin group containing from about 8 to about 30 Ce-C12 alkylamines containing from 0 to 2 EO groups. carbon atoms; In each t(B2O) group is independent. t equals from 1 to 12 carbons | and O to about 5 EO groups, as well as about 30. Characteristic alkylalkyloxylated phos- corresponding compounds of quaternary ammonium, also phates include olef-10 phosphate, olef-20 increases the compatibility of such compositions. In one Kk! phosphate and olef-25 phosphate. embodiments, the compounds that increase the compatibility of such an encounter include the following types: in 7 and --kK (vv) about sleep in

Сивнзу(ОснесН)о -- mA (СНаз and (СНоСНаОнобзеНзз) (84) or

Me me t A cho - 1 slsk nya V | and (87)

Sena OSNO "--(oNodv--MA-(SNasnoO estuary (85) tsi and Z or

In or in aqueous concentrated compositions, or in dry compositions according to this invention, from- to-.. usually in the region or from 1:1 to about 20:1, preferably from about 21 ve to about 10:1, more preferably from about 2:1 4; for Her" to about 8:1, even more preferably from about vo- (Kk om ge (89) 21 to about 6:1, and, most preferably, from about 371 to about 61.

The density of any composition containing alkyl or aryl containing from about 4 to about glyphosate, according to the present invention preferably up to 16 carbon atoms, B2 is hydrogen, varies from at least 1.210 grams/liter, more preferably, tyl, ethyl or -"СН2СНГО)ХН, BZ is at least about 1.215, 1.220, 1.225, 1.230, day, methyl, ethyl, or --сноИНснгоОуН, where sums and in 1.235, 1.240, 1.245, 1.250 , 1.255, 1.260, 1.265, not more than about 5; B" is hydrogen 1270, 1.275, 1.280, 1.285, 1.290, 1.295, 1.300, or methyl; BU in each n(B9O) group independently 1.305, 1.910, 1.315, 1.920, 1.325, 1.330, 1.335, is a Co-Ca alkylene; VE? is a hydro- 1.940, 1.345, 1.950, 1.955, 1.960, 1.365, 1.970, carbylene or substituted hydrocarbylene containing 1.975, 1.380, 1.985, 1.390, 1.395, 1.400, 1.405, from 2 to about 6 carbon atoms; A- is an anion acceptable in agricultural compounds or 1.450 grams/liter. zitsyah

As described here, in order to improve certain vlab- This invention also relates to the herbicidal properties of the obtained compositions in the composition of the methods, which are based on the dilution of the corresponding invention, other additives can be introduced, by the volume of water of the "herbicidally effective" volume are adjuvants or ingredients. Although the compositions of the composition described herein, with the production of the invention usually have good overall stability and viscosity without the addition of any applicable composition, and applying the composition to They may have a straight or branched lan- leaves of a plant or plants. yoke or be a cycle, and include ethenyl,

Definition of propenyl, isopropenyl, butenyl, isobutenyl, hexenyl

Under the terms "hydrocarbon" and "hydrocarbyl" and the like. used herein are understood to mean organic Unless otherwise indicated, alkynyl groups, compounds or radicals containing only sani elements herein are predominantly lower alky- carbon and hydrogen. These groups include nil groups containing from two to 18 carbon atoms in alkyl, alkenyl, alkynyl, and aryl. These groups also include the main chain and more than 30 carbon atoms. include alkyl, alkenyl, alkynyl, and aryl groups. They may have a straight or branched lan- substituted by other aliphatic or cyclic yokes or be a cycle, and include ethynyl, hydrocarbon groups such as alkaryl, al- propynyl, isopropynyl, butynyl, isobutynyl, hexynyl and kenaryl and alkynaryl. Unless otherwise specified, these are similar. groups preferably include from 1 to 30 The term "aryl" as used herein, oc- carbon atoms. remo or as part of another group means necessarily

The term "hydrocarbylene", which uses substituted homocyclic aromatic groups, is used here to understand radicals attached to their mainly monocyclic or bicyclic groups, which contain from 6 to 12 carbons in the ring at both ends to other radicals in the organic ring, such as phenyl, compounds and which consist exclusively of the elements biphenyl, naphthyl, substituted phenyl, substituted carbon and hydrogen. These groups include biphenyl or substituted naphthyl groups. Phenyl and substituted alkylene, alkenylene, alkynylene and arylene. These phenyl groups are more preferred aryls. also include alkyl, alkenyl, alkyl- The term "aralkyl" as used herein, nyl and aryl, substituted with other aliphatic or cy- means a group containing both alkyl structures and nominal hydrocarbon groups such as al- aryl , such as benzyl. caryl, alkenaryl and alkynaryl. Unless otherwise specified As used herein, alkyl, alkenyl, other, these groups preferably contain from 1 to 30 alkynyl, aryl, and aralkyl may be substituted, pri- carbon atoms. namely, by one atom other than carbon, in the "Substituted hydrocarbon" groups described here, including groups in which the carbon atom is substituted hydrocarbon groups, the yoke is replaced by a heteroatom, such as an azo atom, by at least one atom, different from carbon, tu, oxygen, silicon, phosphorus, boron, sulfur or halo, including groups in which the carbon atom of the chain. These substituents include hydroxy, ha substituted with a heteroatom such as nitrogen, nitro, amino, amido, nitro, cyano, sulfoxide, thiol, oxygen, silicon, phosphorus, boron, sulfur, or halo- thioether, thioether, ether and simple well These substituents include halogen, heter- ether, or any other substituent that can rocyclo, alkoxy, alkenoxy, alkynoxy, aryloxy, enhance the compatibility of the surface-active rheo- hydroxy, protected hydroxy, ketal, acyl, acyl- wines and /or its effectiveness in the composition of glyphosate, nitro, amino, amido, cyano, thiol, acetal, potassium sultate without adverse effect on the stability of the composition. ether, thioether, hydroxyalkyl, urea, guanidine, The term "halogen" as used herein, amidine, phosphate, amine oxide and quaternary salt alone or as part of another group refers to ammonium. chlorine, bromine, fluorine and iodine. In the superficial

"Substituted hydrocarbylene" groups, described in the active substances by the predominant substituent, are often hydrocarbylene groups substituted with fluorine. by at least one atom other than carbon. Unless otherwise specified, the term "hydroxyalkyl" includes groups in which the carbon atom of the chain includes alkyl groups substituted, at least substituted by a heteroatom, such as a nitrogen atom, not, one hydroxy group, and include oxygen, silicon, phosphorus, boron, sulfur or halogebis(hydroxyalkyl)alkyl, tris(hydroxyalkyl)alkyl./ and well. These substituents include halogen, heteropoly(hydroxyalkyl)alkyl groups. Preferable hydrocyclo, alkoxy, alkenoxy, alkynoxy, aryloxy, sialalkyl groups include hydroxymethyl (- hydroxy, protected hydroxy, ketal, acyl, acyl-CHON), hydroxyethyl (-С2НАОН), sy, nitro, amino, amido, cyano , thiol, acetal, sulbis(hydroxymethyl)methyl (-CH(CHgOH)») and phoxide, complex ether, complex thioether, simple tris(hydroxymethyl)methyl (-С(CH2gOH)»h). ether, thioether, hydroxyalkyl, urea, guanidine, The term "cyclic" as used herein, amidine, phosphate, amine oxide and quaternary salt, alone or as part of another group, means the group, ammonium. containing at least one closed ring, and

Unless otherwise indicated, the alkyl groups described herein include alicyclic, aromatic (arene) and sled herein are predominantly lower alkyl, heterocyclic groups. containing from one to 18 carbon atoms in the main chain and up to 30 carbon atoms. As used herein, alone or as a part may have a straight or branched chain of another group, means optionally substituted, semi- or be a cycle, and include methyl, ethyl, saturated or unsaturated, monocyclic or propyl, isopropyl, n -butyl, isobutyl, hexyl, 2-bicyclic, aromatic or non-aromatic groups, ethylhexyl and the like. contain at least one heteroatom in at least

Unless otherwise indicated, alkenyl groups, described in the ring, and preferably 5 or more atoms in each ring herein, are preferably lower than the alkene ring. The heterocyclic group preferably has 1 nil containing from two to 18 carbon atoms in or 2 oxygen atoms, 1 or 2 sulfur atoms and/or from 1 main chain and more than 30 carbon atoms. up to 4 nitrogen atoms in the ring, and can be attached to the rest of the molecule through carbon or heteromolecules in the resulting surfactant. Examples of heterocycles are heteroaromatic wines usually vary in the range that can groups such as furyl, thienyl, pyridyl, oxazolyl, include whole numbers greater than the maximum of pyrrolyl, indolyl, quinolinyl or isoquinolinyl and therefore or less than the minimum of the "average number". Similar, and non-aromatic heterocyclic groups, such essence in the composition of individual molecules of surface-active substances such as tetrahydrofuryl, tetrahydrothienyl, piperidinyl, which have a whole number of such pyrrolidino and the like. Examples of unit substituents outside the established range of "average" include one or more of the following numbers do not take the composition beyond the groups: hydrocarbyl, substituted hydrocarbyl, keto, of this invention, provided that the "average number" is oxy, substituted hydroxy, acyl, acyloxy, alkoc- with the established region and other requirements of zusy, alkenoxy, alkynoxy, aryloxy, halogen, amide. but, amino, nitro, cyano, thiol, thioether, As indicated above, it was found that concen- thioether, ketal, acetap, complex ether, and simple aqueous solutions of the potassium salt have exclusively ether. high specific gravity. As an example, Table 1 shows

The term "heteroaromatic" used specific gravity measured for 3095 glyphosate is used here, separately or as part of another group, ke. by weight of solutions of the potassium salt of glyphosate, in means optionally substituted aromatic groups, comparable to organic ammonium and other salts containing at least one heteroatom in, which are of interest or which represented the most, one ring, and preferably 5 or 6 atoms in interest earlier. to each ring. The heteroaromatic group is predomin- The specific masses were measured using lycine has 1 or 2 oxygen atoms, 1 or 2 sulfur atoms Mesheg OBA-300, which determines dense and/or from 1 to 4 nitrogen atoms in the ring, and can be density/specific mass. attached to the rest of the molecule through a carbon or heteroatom. Examples of heteroaromatic groups Table 1 include furyl, thienyl, pyridyl, oxazolyl, pyrrolyl, indolyl, quinolinyl or isoquinolinyl and so- Specific mass (20/15,607C) 3095 k.e. the weight of the solution is similar to it. Examples of substituents include in the glyphosate monobasic salt one or more of the following: hydrocarbyl, for: substituted hydrocarbyl, keto, hydroxy, substituted hydroxy, acyl, acyloxy, alkoxy, alkenoxy, alkynoxy, aryloxy, halogen, amido, amino, nitro, cyano, thiol, thioether, thioether, ketal, acetal, ester and simple ether.

The term "acyl", used here, alone or as part of another group, means a group obtained by removing the hydroxyl group from the -COOH group of an organic carboxylic acid, i.e., ВС(0)-, where В is equal to ВЕ" , В'О-, В'В2М- or Thus, 1 liter 3095 keu by weight of the solution

B!8-, B' is a hydrocarbyl, the heterosubstituent of the potassium salt of glyphosate at 207С contains an approximate hydrocarbyl or heterocyclo, and B? represents no more than 376 g of glyphosate c.e./l, while 1 liter is 30,905 c.e. hydrogen, hydrocarbyl or substituted hydrocarbyl. by weight of the IRA solution of glyphosate salts at 207C

The term "acyloxy" as used here means approximately 347g glyphosate cfu/l. By others, separately or as part of another group, means acyl- words, with an equivalent k.e. by weight, the concentrated group, as indicated above, attached with the help of a potassium salt solution carries about 895 more oxygen bonds (--0--), i.e., KS(FO)O-, where K is glyphosate k.e. per liter as defined in the description of the term "acyl". High specific mass of potassium salt solutions

The term "pesticide" includes chemical and is especially significant in solutions of surface-killing agents used as active active substances, where the maximum value ingredients of products for controlling pests of bread- glyphosate concentration cannot be reached them cereals and lawns, and diseases, ectoparasites not only due to the limited solubility of potassium salt of animals and other pests. in water, but also due to the limited compatibility of

The term also includes regulators of rheologically active substances. In such solutions, plant overgrowth, pesticides, potassium salt synergists can be that (a) yeasts, herbicides (which achieve a higher maximum value reduce the phototoxicity of herbicides for grain glyphosate k.e. . weight/volume concentrations than cereals), and preservatives whose contact with the skin of IRA salts in the presence of the same compatible surface- or especially in the eyes may expose them to danger with the active substance at the same percentage effect of pesticides. An increase in the danger of such an effect of the concentration of the surface-active substance, (B) in pesticides occurs when the given weight/volume concentrations of glyphosate come from the source to the subject that applies the pesticide. and surface-active substance known or located in the vicinity of the application. see stability during storage, in comparison with

When indicated here, the maximum or minimum stability of the corresponding composition obtained from the "average number" relative to the structural features - IRA with salt and/or (c) at given weight/volume con- such as oxyethylene units or glucocentrations of glyphosate k .is. and surface-active wall units, a specialist in this area will be able to achieve improved fluidity and it has been shown that the whole number of such units in separate measurements compared to the corresponding composition, i.e. the composition with water, forms liquid crystals that the salt obtained from IRA . contain a surface-active substance as on a leaf

The advantages of the compositions according to this invention in plants (epicuticular wax) and inside the plant decrease as the concentration decreases (intracuticular liquid crystals). The ration of glyphosate and become minimal at concentrations of other compositions according to this invention, herbicidal glyphosate below approximately 3600 g c.e./l, i.e., a composition containing an aqueous mixture of glyphosate is lower than the concentrations found in commercial or its salt, or its ester, and surface-active products of IRA salts of glyphosate, such as substances containing liquid crystals from surface

Coipaimrfb herbicides. In the preferred compositions according to the active substance. according to this invention, the concentration of glyphosate is Corresponding salts of glyphosate, which can be used at least 400 g c.e.u./l or approximately 420 g c.e.u./l, are produced in accordance with these compositions according to the data, in particular, the preferred compositions are not lower than approx. according to the invention, include, for example, but 440, 460 or 480 g k.e./l, for example, from about a salt of alkali metals, for example sodium salt and ca- 480 to about 540 g k.e./pro. It is likely that the upper lithium, ammonium salts, di-ammonium salts, such as di-limit of the concentration of glyphosate in the composition according to this tylamonium, alkylamine salts, for example, dimethyla- invention containing surface-active rechomin, and isopropylamine salts, salts alkanolamine, a wine that improves storage stability, for example, ethanolamine salt, alkylsulfonium salt, is more than about 650 g c.e.u./l, this limit is derived from the solubility limit of potassium salt of glyphosate in xonium , their mixture or their combination. Different commercial waters in combination with an additional restriction due to the compositions of glyphosate sold today have the presence of a surface-active substance. Mopsapio Sotrapu, include ammonium

It is expected that the limit of this higher value of salt, sodium salt and isopropylamine salt. The composition of glyphosate concentration can be provided with glyphosate, which is sold today 7epesa, with a minimum amount of surface-active recho- include trimethylsulfonium salts. Individuals. In some cases, this small amount of the preferred salt of glyphosate is effective in the new surfactant may be inadequate to reliably increase the herbicidal efficacy of glyphosate to an acceptable salt. -ammonium, sodium salt, monoethanolamine measure. However, in certain specialized applications- salt and trimethylsulfonium salt. Potassium salt, when the composition must be diluted, salt, ammonium salt and di-ammonium salts are preferred because of a small volume of water for processing the composition of these glyphosate salts, the largest volume, for example, from about 10 to about probably form liquid crystals. 5 ol/ha, a very low concen- In addition to glyphosate, or its salt, or its ester, tion of the surfactant in the concentrate, the herbicidal compositions of the present invention can also be useful, such as, for example, containing at least one surfactant -active re- about 20g/l. These are the specialized applications of cast iron. In one of the embodiments according to this invention, they include gore-misk, sopigo! Agoryei nature of surface-active substance and herbicide - arriisayop and yiga-Yum-moishte aegia! 5 rgauipd. For a composition such that when using a composition of general application, usually with the help of tion on plants or when using a mixture, spraying the following dilution from rye by diluting the composition with water, by about 50 to about 1000 l/ha, usually from a waxy cuticle (epicuticularly) plants form about 100 to about 40Ol/ha, in water, anisotropic aggregates are concentrated, containing the surface of the surface-active substance in the concentrate of the active substance. These anisotropic aggregates of the composition according to the present invention are predominant on plants regardless of the presence in the water from about 60 to about Зб0Ог/l, and more re-composition of the second surface-active substance. important from about 60 to 200 g/l. Anisotropic aggregates can form immediately

The herbicidal compositions of the present invention after application to the leaves of plants or may include at least one active substance formed on the surface after evaporation from the composition, which in combination with glyphosate, water present on the leaves after application. In addition to either its salt or its ether, and when used, anisotropic aggregates can be formed in cheap compositions on plants or the use of concentrates of herbicidal compositions. of the mixture obtained by diluting the composition with water. To determine whether herbicides form anisotropic aggregates containing positions containing glyphosate, or its salt, or a surface-active substance on the leaf (epicutic - its ester, and a surface-active substance , anisotolar wax) of plants. In some compositions for free aggregates with a surface-active substance, the invention, a surface-active substance contained on the leaves of plants can be combined with glyphosate, or its salt, or its following methods with the study of double- ether, when using the composition on plants of low radiation refraction. or application of the mixture obtained by dilution First, the glass slide is covered with wax. compositions with water, forms liquid crystals that mis- The preferred wax for applying a surface-active substance on the leaves of plants glass is a mixture of carnuba wax and beeswax (epicuticular wax). In other compositions per daka in a weight ratio of approximately 10:1, according to the invention, a surface-active substance, incl. A mixture of transparent wax is obtained, which is mixed with glyphosate or its salt, or it is filled with about 595 carnuba wax and about 0.590 ether, when applying the composition on beeswax plants in isopropanol, and maintain it or when using the mixture obtained diluted at a temperature about 82" C. The end of the glass

A 2.4 cm x 7.2 cm microscope slide was immersed for 1 minute, 10 minutes, 2 hours and more than 24 hours in the wax mixture up to 3 hours after applying a drop to the surface of the wax. bins about one-third the length of the object- Observations can also be made in a foot of glass. After about 10-15 seconds, intermediate segments of time, in order to fix the slide very slowly and with a constant speed - significant movements are possible during this time. the bone is removed from the wax mixture and left to cool. The temperature of the wax layer increases with ti. On both sides of the glass slide, leave it for prolonged exposure to the light of the microscope. There is a layer of wax. in many cases it has been determined that it is not

The visual evaluation of the specimen glass can significantly affect the results, which can inform about the thickness and inhomogeneity of the chews. However, in some cases, the temperature of the wax coating. If there are clearly visible irregularities on the glass, the glass is thrown away. If on the glass it would be preferable to illuminate the sample visible inhomogeneity, the wax coating carefully only for a short period of time, which is necessary to observe on one side of the glass slide aceto- precautions, so that the temperature of the wax layer remains. Further evaluation of the suitability of coated wax close to the ambient temperature of the glass for the test is carried out by studying the glass environment. under the microscope. Glass is selected for use. In the dark field (polarized light) layer in this experiment, if double refraction was observed under microwax, with a scope with a 4.9x lens, the wax layer is uniform, and in the light field, features of a dense surface and wax particles all over the glass have henna drops in each time interval. They were of uniform density. Preference is given to making the necessary records below: coatings in which several visible birefringence (u/p) is observed; wax particles and very dark areas are visible when the Time of appearance of the initial double beam- using polarized light. lenience;

The next stage of this process is the nature of birefringence; the day of the experiment. For this purpose, samples of glypho- The appearance of the surface of the drop as a "dry" composition; solid herbicidal composition containing one or a droplet; several dissolved surface-active substances - Effect of temperature (heating of glass), if any; wine, if necessary, from 1595 to 2095 by weight Other notable changes. glyphosate acid equivalent. Indicated To document the observed changes, the sample obtained with a content of 41956 by weight of IRA is optional, the image was recorded from the use- salt of glyphosate in an aqueous solution. the melting of the ZSSO MTI camera and Itade-Rgo program

For the experiment, you need or use Rin5. Experiments, if desired, can be performed by the devices listed below, or recorded by him on video, especially during the first 15 equivalent: minutes. In addition to images obtained using

Mikop ZM2-10A stereoscopic microscope with a 4.9x lens, to obtain a complete comparison, it is equipped for observation in polarized light of different samples examined on the same glass, it can be light, for photomicrography and for video, the recorded background can be recorded using 0.75 vol. recording and recording. you're in. A particularly effective parameter for

ZSSO MTI camera. observation of anisotropic aggregates is observed

Diagnostic tools Oiadniviis Ipsigitepiv nya double refraction (u/p) through 5-20 150 11 -P5 power supply. minutes after the deposition of the drop under investigation,

Color video monitor by Zopu Tgypygop, on a wax-coated glass slide. del RMM-1353MO. Herbicidal compositions according to the present invention, which

This trafer video recorder Mii5irivpi, forming epicuticular anisotropic aggregates, model H5Z-55600. significantly improved the characteristics available on

Computer Nem/ey Raskaga Ramiyop 7270, from the moment of herbicide compositions. Not based

MMipdom5 95 and the established Itade-Rgo program based on some certain theory, it is likely that

Riiz version 2.0 for electronic image processing - epicuticular anisotropic aggregates can be formed. dig or enlarge hydrophilic channels through

Printer Nemley Raskaga Oezkiei 870S5e. the epicuticular waxy surface of the cuticle grew

To carry out the experiment, subject matter. These formed or enlarged transcuticular glass, coated with wax, obtained and selected as described above, the channels through the waxy surface can be facilitated above, were installed on the microscope table, you transfer glyphosate through the epicuticular with a system installed for the passage of the world-wax of the cuticle of the plant and inside the plant more la both direct and polarized. For analysis 1, it is faster than in the system without anisotropic aggregates. microliter drop of the sample, the drop was applied to the wax- In addition, it is likely that most of the anisotropic wax layer, using carefully cleaned 1- aggregates located on the epicuticular po- microliter syringe Natiop. This and subsequent observations, which are in a form different from a simple walkie-talkie, were carried out under a microscope with a 4.9x objective. Duplicate structures were performed for each composition, as they tend to form co- or triplicate analyses. Multiple analyzes can plex structures, such as cylindrical, disc-shaped, be conducted simultaneously on one glass. Post- or ribbon-like structures. "Majority" means the duration of changes occurring under the microscope in the sample, which is more than 5095 by weight of surface-active re- observed through the microscope and recorded through the chutney present in the form of complex aggregates, certain time intervals. Effective intervals of states different from simple micelles. Preferably, more than 7595 by weight of the surface-active substance Neihoim 05-25 (RE 25 Siv-Siv alcohol from is present in the form of complex aggregates, different from Neihegepe) and ESHtoteep'm T/20, Neiho!"m 05-25 and from simple micelles. The diameter of the anisotropic aggregates ESHoteep'm T/25, Vgi|"m 78 (REO 20 Siv alcohol from according to the present invention is usually at least zZidt Spetis! Sotrapu) and Epoteep m T/20, Vgi) tm about 20 nanometers, preferably, at least 78 and Epoteep'm T/25, Vgi)m 78 and Eptodcyaidm/ T/20 about 30 nanometers. (RES 10 thallomethyl ammonium chloride from AkKgo More),

With regard to the formation of anisotropic aggregates - Vgi)"m 78 and Etodiad'"mMm T/25 (RES 15 thalomethyl tives containing a surfactant, in ammonium chloride from AK20 Mowbray), Riogatas"m AZ 8 in the presence of glyphosate, a critical parameter ukla- (RE 27 Siv-Siv alcohol from Vavzi) and Epoteep "m T/20, data (P), which was determined as: RiIogatastm AZ8 and Etoteep "m T/25, Ritsgatas"m dz8 and

REMLA ESHtodchaai m T/20, Riogatastm AZ8 and Eptodiaid m T/25, where M is the volume of the hydrophobic tail of ZT 8303 (REYA 14 Siv alcohol from Sodpiv) and Epodiaa tm molecule, | represents the effective length of the hyd- T/25, Agozygi"m 66 E10 (RES 10 with Stiv alcohol from the hydrophobic tail, A represents the region, zainya- Miyso/Sgotriop) and EShodtsai'tm T/25, Agozygi"m 66 tu hydrophilic heads, may have an important E20 (RES 20 with Siv alcohol from UmMiso/Stotriop) and aspect. It is likely that the amphiphilic substances that ESHodzeitm T/25, Agozygi"M 66 E20 and EEPtoteep'm are used in the formation of anisotropic agents T/25, Neyoho!im C5-20 and ESHtoteep"m T/5 (5 , have a critical stacking parameter of loamine from AK20 Mowbray), NeiohoY" cS5-20 and more than about 1/3.

In the preferred embodiment, in which anisotropic Neiyuho! m 05-20 and E(oteep'm T/35 (25 EO taloa- aggregates are formed on the epicuticular wax min from AKgo Mobei), Neiohoi them Сб5-20 and E(poteep "m of the surface of the cuticle of the plant, surface-active T/40 (30 EO taloamine from Aklo Mobei), Neioho! m substance, which includes anisotropic aggregates, 05-20 and Ttuteep'"mMm 6617 (RES 50 stearylamine from is an amphiphilic substance containing a compound from Sodpiv), Neioho! tm 25 -15 (RES 15 Siv-Siv alcohol from cationic head and hydrophobic tail. Without Neyegepe) and ESHtoteep'm T/25, Neho!"m 05-20 and binding to a certain theory, it is likely that cationic RE 22 dimethyl quaternary ammonium chloride, a group of carriers first adheres to the surface of Neioho! m 05-20 and lecithin, Neioho! M C5-25 and lecithin, until a large part of the surface is tin, Neiohoi"m 05-20 and Agdtsai"m 0 -50 (dodecyl carries a negative charge. It is more likely that trimethyl ammonium chloride from AkKgo Mobe!i), Neyoho! tm cationic group contributes to the formation of hydrophilic C5-20 and lauryl chloride, Neyoho!"M C5-15 and transcuticular channels in the epicuticle p- laurylcholine chloride, Rgoso!mM | A 15 (RES 15 C12 in the wax layer, which are formed or sbil- alcohol from Rgoiateep) and ESHPodtsiaid"m T25, Neyoho! gm are sewn in quantity due to surface-active C5-20 and RES 7 dimethyl quaternary ammonium chloride substances of this invention. ryd, Neiohoi m 05-20 and betipitm 10-2-10 (Sto eti-

Cationic groups attract water molecules, which len M-methyl diamine from Mopzapiso), Neioho! m C5-20 additionally increase the hydrophilic channels and, thus, betitipitm 10-3-10 (C1o propylene M-methyl diamine from the way, provide an improved way for the entrance of Mopzapio), Neyoho! "M С5-20 and betypithm 104-10 (Composition of glyphosate, which is polar. butylene M-methyl diamine from Mopsapio), Neyoho! "m

Surface-active substances that effectively С5-20 and betypi 14-2-14 (Си4 ethylene M-methyl diamine form anisotropic aggregates in the presence of gli- from Mopzapio), Neyoho! m 05-20 and betypitim 14-3-14 of phosate, include nonionic, cationic, anionic (Si" propylene M-methyl diamine from Mopsapio), pal- and amphoteric surface-active substances and their sumitic acid and EShotep' "mMm T/25, lecithin and mishi. ESHToteep "m T/25, lecithin and E(podtsai "m T/25, leci-

Mixtures of surface-active substances, such as ukatin and Epoteep m T/20, lecithin and ESHpodtsai "m T/20 and above, are also effective in the formation of anisotrope-lecithin and Ripogai m mes 754 (fluorinated alkyl of even aggregates. Preferred mixtures include ammonium chloride from ZM). according to individual testing, does not form ammonium, quaternary ammonium, dialkylated anisotropic aggregates, amine, diamine, or cationic surfactant Herbicidal compositions according to the present invention, which alkylcholine halide (for example, laurylcholine chloro- include glyphosate and a surfactant). Other preferred mixtures contain: phospholipid nu, which forms anisotropic aggregates on a waxy amphoteric surfactant, dialcok- plant surface , can be obtained as aqueous silated oamine or cationic surface-concentrated compositions containing, at least, active dialuoxylated quaternary ammonium, about 50 g c.e. of glyphosate/l, more preferably, surface-active fluorinated quaternary at least, about 250 g c.e. of glyphosate/l, even more ammonium, such as RiIsogai "m 754, or a non-ionic pove- preferably, at least about 300, 360, 380, 400, rhneo-active alkylated alcohol; or ani- 440, 480, 500, 540 or 600g of glyphosate/l. One of the examples of a preferred aqueous concentrate of a glyonic surface-active phosate composition contains isopropylamine or kaamine. Examples of such preferred mixtures include the glyphosate salt at approx. Bye bye, glyphosate contains NeiohoY"m C5-20 (RE 20 Siv-Siv tu/l, or approximately the same level as before, in alcohol from Neyegepe) and EShotep'"m T/20 (10 EO and currently Mopzapio loamin from Aklo More!) NeiohoY"m cS5-20 and Sogrogayyop are used in their commercial herbicide composition

ESHoteep'm T/25 (15 EO taloamine from AK7o More), KoipatsyrfF. Another predominant water concen-

glyphosate composition contains isopropylamine on plant leaves, can be obtained from glyphosate or potassium salt of glyphosate from about 300 to a bright concentrate from about 1 to about 40 zko 600, preferably from about 400 to about grams of acid equivalent per liter, preferably , 600, from about 440 to about 600, from about 2 to about 18 grams of acid equiv- 440 to about 480, from about 480 to about valence per liter, more preferably, from about 4,600 or from about 480 to about 540g k.e. see - up to about 11 grams of acid equivalent per liter. phosphate/l Any specialist in this area will understand

Regarding the weight of the main component, it was noted that any factors affect the level of a single aqueous concentrate of the composition for the given glyphosate used, which is necessary for the invention containing the surface-active substance of the desired result. wine, which forms anisotropic aggregates on the cuticle surface In the glyphosate composition of the present invention, can be formed with glyphosate at any convenient amounts of concentration can be used, at least about 35, 40, 41, 42, 43, and amounts that enhance the herbicidal effect efficiency, 44, 45, 46, 47, 48, 49 or 5095 k.e. The concentration of surfactants, which include ani- about 35 to about 5095 k.e., from about 40 to zotropic aggregates on the waxy surface of the plant. about 50905 k.e., from about 45 to about 5095 Mostly, the surfactant is present- k.e. or more is preferable, especially for potash in a concentrated glyphosate composition over daglyphosate. by the invention in a concentration of about 25 to

In yet another embodiment, concentrated composi- about 250g/l, more preferably, from about 50 tions that form anisotropic aggregates on the wax to about 200g/l. Although the glyphosate composition of the plant surface may be a dry composition, according to the present invention there may be more, which can be obtained in the form of powder, granules, or granules. These dry compositions are usually dispersed or dissolved in water before use, in order to save money. use the concentration levels indicated above. Ger-

Based on the condition that the compositions are water-dispersing compositions according to the present invention, which are ready-to-use, preferably, in such compositions significantly before direct application to the leaves, the presence of almost completely soluble in water can be obtained with a concentration of surface components, provided that compositions were water-active substances from about 0.1 g/l to about soluble. Dry water-soluble or water-dispersible - 10g/l, preferably from about 1g/l to about 5g/l. In some herbicidal compositions according to the present invention, from about 2095 to about 8095 (by weight) of the invention, the nature of the surface-active substance, e.g. glyphosate, preferably from about 5095 to about 500 g and a mixture of herbicidal composition is such that at about 8095 (by weight) k.e. of glyphosate, and, the most effective composition or mixture on the plant, obtained from about 6095 to about 7595 (after diluting the composition with water, on the leaves of goya) k.e. glyphosate plants are formed liquid crystals containing

In the dry composition according to the present invention, glypho-surfactant (epicuticular liquid sat can serve as the basis for other component crystals). In other words, additional inert ingredients can be added to the liquid crystals that the compositions or to provide such a basis contain a surface-active substance. to create or increase the number of hydrophilic

One of the examples of an inert base that can be formed through channels through the epicuticular wax of the cuticle in accordance with this invention are plants. Ammonium sulfate is an important limit of the herbicide composition. Any person skilled in the art in this invention will understand that the term "dry" that the substance is capable of forming crystals in the pres- used herein does not mean that dry composts of glyphosate on wax, porous substances, such as zits according to this invention, are deprived of the leaf cuticle by 10095, with the formation of transcuticular di. Of course, the dry compositions according to the present invention of the hydrophilic channels epicuticularly through the wax include from about 0.595 to about 595 (per cuticle. A distinctive characteristic by surface weight) of water. It is preferable that the dry compositions for active substances, which contain liquid crystals in the present invention, contain less than about 1905 glyphosate entities, the orientation of water molecules is (by weight). rheologically active substance is arranged in an orderly

Dry, water-soluble, or water-dispersible powders along the line. Of course, the liquid crystals of the position according to this invention can have a high degree of order, in comparison with iso- obtained by any method, by boiling solutions, and more fluid in comparison with mine in this area, including drying of the crucible - solid crystals. Fluidity of liquid crystals by len, agglomeration in a liquid layer (iPsia-bey can be an important factor for improving addiotegaiiyop), granulation in cups or ex- transfer of glyphosate through the plant. blowing In the dry formulation, glyphosate can be Many of the surfactants described here present as a salt or as an acid. Compositions that substances that form liquid crystals on the surface contain glyphosate acid, may optionally cuticles in the presence of glyphosate to facilitate containing an acid acceptor, such as ammonium, carbo- transfer of glyphosate through the internal structures of nat or alkali metal bicarbonate, ammonium dihyd- plants , do not form liquid crystals in concentrated phosphate or the like, so that the used glyphosate solutions at a concentration of vaches when dissolved or dispersed in water could normally, which is commercially acceptable. Of course, get a water-soluble salt of glyphosate. these surfactants form a liquid

Of course, herbicidal compositions according to this are crystals in the sediment deposited by drying the glyphosate, which are ready for direct application.

is obtained from drops or when spraying diluted through the plant. Of course, these types of worm-like compositions on the surface of the cuticle of the plant. Zvymycel will form surface-active substances, without correlation with a certain theory, ureas, which are quite "flexible". it is true that the formation of liquid crystals in concentrated glyphosate solution is not so necessary to determine the initial concentration of phosate and surface-active substances in sediment-related (although in some circumstances it can be them during drying sediments, which by their nature is convenient) with the formation of liquid crystals on the surface by liquid crystals, can be applied to and in the plant itself. Of course, it is more important that the methods of research. Conductive liquid crystals, including surface-active dily at 50905 relative humidity and 247"C. A separate substance, formed as a dry residue on cuticles were obtained according to the sheet described here. However, in some compositions, liquid crystals. Liquid crystals The crystals that form glyphosate can be formed in concentrated calculated composition containing the specified glyphosate/surfactant and on the bone of the glyphosate salt (for example, potassium), liquid leaves and in the leaf, but not in diluted mixture, steel formed by surface-active

As previously indicated, the formation of liquid crystals (for example, Siv-Siv ether EO 15 dimestals epicuticularly can occur as a result of propylamine), placed on the pre-separation by drying drops containing glyphosate or cuticles of leaves in the form of drops with 1 and a surface-active substance applied to a microliter of water and observed with the help of polarizolin. Several factors of the surrounding environment of the microscope for determining the double-beam height, including air temperature, humidity and refraction. In a separate experiment, those drops that showed biradial formation of crystals inside or on the plant were considered and wind speed can affect the speed. In refraction, and it was confirmed the formation of charac- in some situations, liquid crystals can actually kternal structures of liquid crystals. be formed by phase separation After the birefringence was drops on the sheet. Although surfactants were determined, the drops were removed from the cuticle so quickly, we, listed here, form liquid crystals in as soon as possible, diluted in 1 ml of 99.995 (nomi- the presence of glyphosate, probably so that the molecules nal) 020 and transferred to 5 mm test tubes for the surface-active substance, they mostly had NMR. The spectrum can be obtained by using a molecular weight of less than about 2500. With a 400 MHz spectrometer, whether the molecular weight of a surfactant equipped with a 5 mm Maiogas pulse probe exceeds 2500, liquid crystals can still be adjusted. For example, a 30-degree pulse to form, but they are not efficient enough to can be used to obtain scan- transfer of glyphosate compared to low mo- with the appropriate cycle time. Determination by molecular surfactants. can be carried out with the help of doublet integration

Liquid crystals containing surface-active signal glyphosate and signal water. substance in the presence of glyphosate, epicuticularly According to this method, the concentration is usually lyotropic liquid crystals; of glyphosate in these drops was determined as 37905 (/-69/5). However, it was noted that the evaporation of water with the presence of a solvent, in this case - drying drops, is relatively fast (in waves. Liquid crystal mesophases do not depend on bodies). Thus, the results may vary depending on the presence of the solvent, but also depending on the temperature from 3795 to 5095o0b/wt. depending on the technique of the tour. Lyotropic liquid crystals containing a surface- performing by a specialist the transfer of a drop from the cuticle- an active substance in the presence of glyphosate, which are placed in a test tube for conducting NMR. form transcuticular hydrophilic channels, as To determine whether the herbicidal compo- forms observations, the zation containing glyphosate, or its salt, or its in the hexagonal structure, reversed hexago-ether, and the surface-active substance liquid crystalline structure may be present , lamellar and multi-lamellar whether containing a surfactant on a structure having at least about 20 to a plant leaf, about 30 or more separate, distinct layers can be used described. then the method using a two-beam micro-

The cubic form of lyotropic liquid crystalloscopy in polarized light with high resolution is possible. Both smekrichna and yum were also registered. This method with high resolution radiation nematic forms of liquid crystals containing refraction is able to distinguish the structure of liquid surfactant in the presence of glyphosate crystals and their characteristic microscopic structure. In the herbicidal compositions according to this invention, from other types of anisotropic aggregates or solids, liquid crystals were formed independently of the crystals deposited in the solution during evaporation in the absence or presence of the second surface water. Next, the procedure of the experiment is described. active substance. Before carrying out the experiment on double

In addition, some surface-active substances in the refraction of the cuticle of the rope plant in the presence of glyphosate can form a worm-Theophrast (Abshiyop (peorpgazbr), which grows in these-like micelles, another class of structural organizations of the plate. To isolate the cuticle can be vyko- in liquid form , which can contribute to the translocation of ristani other plants that contain prickly pear, glyphosate through the waxy cuticle and in the plant. Giant ragweed and birch. To isolate angular micelles, usually less organized into spheres, basic solutions of glacial acetic acid were prepared compared to liquid crystals, but enough stru- acid and sodium acetate.The concentration of the basic ctured to form hydrophilic channels on and glacial acetic acid solution is in the plant to facilitate the translocation of glyphosate range from about 1 to about 595 (wt./wt.) and the concentration of the basic solution of sodium acetate satu to the surface-active substance is located in the area from approx ko 1 and about 595 moose in the region from about 1:11 to about 101 (weight/weight). To obtain a buffer solution with a pH (wt./wt.), preferably about 3:1 (wt./wt.). At from about 4.2 to about 4.6, both cuticles were mixed with a drop of water sample, which was pre-flowing solutions. chewed, and observed in polarized light

After obtaining the buffer solution, obtain (7.5x magnification) sent through the cuticle. pour the enzyme solution. Of course, for maxi- Images of the sample drops were obtained on the cutaneous efficiency of the enzyme solution, spheres are prepared and stored in a computer with a video monitor, immediately before or shortly before the selection using the computer program Riazp Roipi cuticles. The enzyme solution was obtained by adding 128 at this point in time. The images were then scaled from about 1 to about 595 (w/w) and digitized using Itade Rgo, Meaiah about 0.1 to about 0.595 (w/w) cellulose in Subegpeijsv. water Of course, the activity of pectinase is In each experiment, drops of the sample nano- 3600 units/gram and the activity of cellulose from close to two times for two almost identical pieces of 10600 units/gram. The enzyme solution was stirred. If it was sterile filtered under a polarized microscope and it was ready for 7.5x magnification, double-beam use or storage was observed. refraction, the sample was immediately transferred under polari-

A healthy leaf was plucked from the plant, and its folded microscope with the ability from 100x to 400x was abraded the mouth side with a small sea mite of multiple magnification. com. The leaf was then thoroughly washed with buffered Under this microscope, at 200x magnification, the solution obtained above, and a characteristic pattern of liquid crystals was observed in the healthy part, the leaf was cut to isolate the cuticle. The part of the leaf separated from solid crystals and other substances was infiltrated with fresh enzyme birefringence. If the liquid crystals in a solution and stored at a temperature of about 30"С to about 35"С for about 1 hour, the sample com- 30"С to about 35"С formed epicuticular liquid crystals on us or until the leaves of the plant separate from the leaf tissue. cuticle. After separation, the cuticle carefully Herbicidal compositions according to the present invention, which were removed from the buffer solution and thoroughly washed with glyphosate, or its salt, or its complex was washed with deionized water and stored in buffer ether, form epicuticular liquid crystals with a solution with a pH of about 4 to 6 and with humidity significantly improved properties compared to air from about 3095 to about 7595 and herbicide compositions available at this temperature from about 20 to about 30"C before use, and can be superior in quality to herbicide tanya . Of course, the cuticle was kept under the control of compositions that simply form anisotropic aggregates for at least about 24 hours epicuticularly. Not relying on a certain theodyne to achieve a state of equilibrium from the medium, probably the composition of liquid crystals on the epic - the ticular part of the plant forms or increases

After separating the cuticle, it was used to measure the number of hydrophilic channels through the waxy layer in an experiment to determine whether the cuticle forms. These formations or an increase in the amount of hydrogenated herbicide composition of glyphosate and surfactant channels can significantly increase the active substance liquid crystals containing the transfer of glyphosate substance through the waxy surfactant on the waxy surface of the cuticle and inside the plant. cuticles The cuticle was transferred to a slide using surface-active substances, which were effectively examined under a microscope (they form epicuticular liquid crystals without polarization in the presence of light) to identify cracks and other damages. properties of glyphosate, include nonionic, cationic

If cracks or amphoteric surfactants and other damages were detected on the surface of the cuticle, it was excluded. If you found a mouse. the corresponding cuticle, it was then examined under a microscope (at 7.5x magnification) with a polarized zano above, also effectively form an epicuticle- light to obtain a dark field for post-stellar liquid crystals. Preferred mixtures include cuttings. If the surface of the cuticle was marked with an alkylated alcohol of a non-ionic surface, small areas covered with crystals of this region-active substance and dialkylated quarters were carefully avoided during the experiment. tin ammonium, monoalkylated quaternary-

After examining the cuticle for the presence of ammonium, or dialkylated amine cationic defects, the glass slide was placed in the area of the surface-active substance. Others are preferred by heating/cooling, in which it was possible- mixtures containing a phospholipid amphoteric surface to adjust the temperature of the glass under the non-active substance and alkylated alcohol during the experiment. The slide was heated and nonionic surface-active substance. Examples of the cuticle were left to reach a state of equilibrium - such preferred mixtures include those with a temperature of the glass from 1570 to Neiohoim 05-20 (REb 20 Stiv-Siv alcohol from about 35 "C. After reaching equilibrium, prepare Neyegepe) and Yeshoteep' "m T/20 (10 EO taloamine from the sample of the solution under investigation. The sample can be AKkgo Morbrei), Neyoho! "m 25-20 and ESHtoteep m T/25 (15 be either diluted or concentrated, but EO taloamine from Aklo Mowbray), NeiohoY m C5-25 preferably, so that the sample is diluted in such a way- (PE 25 Siv-Siv isopoi from Neyegepe) and EIpoteep m nom, so that the concentration of glyphosate (in the sample that T/20, Neiyuhoim Sb5-25 and ESHToteep'm T/25, VgiY 78 is being investigated, was in the region of about (RES 20C, alcohol from Zidt Spetis! Sotrap ) and 1 95 to about 1095 (wt./wt.) and the ratio of glypho- ESHToteep m T/20, Vgi) 78 and EPoteep m T/25, Vgi) 78 and

EyuShodisid'm T/20 (RES 10 thalomethyl chloride to an amino-concentrated solution of glyphosate is not so important from AkK2o Mobei!), Vg)"m 78 and Etodtsiai'"m tT/25 ve or related (although in some cases can (RES 15 thallomethyl ammonium chloride from AKgo More), be useful) with the formation of liquid crystals on

Riiogaiastm AZV (RES 27 6-C, alcohol from Vabi) and the surface or inside the leaves. Of course, more

It is important that liquid crystals containing surface-

T/25, Ryogatastm AZV and ESHodiai m T/20, Riigatasm non-active substance, were formed in the sediment that

AZ8B and EISHoditsaa m T/25, 5T 8303 (RES 14 3, 6 alcohol fell out when applied to the surface of the sheet. However, in from Sodpiz) and ESHTtodchaidtm T/25, AgozygEM 66 E10 in some compositions liquid crystals can form (RES 10 isoC, 8 alcohol from UMiso/Sgotriop) and used as in concentrated solutions of glyphosate

EyushShodoai m T/25, Agozypi"m 66 E20 (RES 20 isos, 8 tu/surfactant, and on the surface alcohol from Umiso/Sgotriop) and E(Shodtsiaim T/25, and inside the sheet, but not in a diluted mixture for

Agozygi"M 66 E20 and ESHpoteep m T/25, Nekhioho! M C5- spraying. and ESHpoteep'"m T/15 (5 EO taloamine from AK2o As was indicated above, the formation of liquid crystals

Mobeyi), Neyohoi m С5-20 and ESHoteep'm T/30 (20 EO of tals epicuticularly and intracuticularly can be thalamine from AKgo Mobrei), Neiohoi" (5-20 and the result of precipitation of glyphosate and surface

ESHoteep'm T/35 (25 EO taloamine from AK7o More), a non-active substance contained in drops,

Neyokhoi m 05-20 and ESHoteep'm T/40 (30 EO taloa- applied to the plant. Some environmental factors from Ak»o Mobrei), Nefokhoiim Sb5-20 and Tguteep'm his environment, including the temperature of the air- 6617 ( RES 50 stearylamine from Sodpiv), Neyoho! temperature, humidity and wind speed can affect

C5-15 (PE 15 Steve-Siv alcohol from Negegepe) and how quickly liquid crystals form on the surface

ESHoteep'm T/25, Neiohoi!"M C5-20 and REO 22 dimeric or inside the plant. In some cases, til quaternary ammonium chloride, Neioho! M 5-20 and liquid crystals can actually form lecithin, and Neioho! "m 05-25 and lecithin. Some of them are caused by the separation of the droplet phase. Although the surfactants of the above-mentioned mixtures are synergistic, in which the active substances listed here form liquid crystals in the presence of glyphosate, it is possible that, in an individual study, the surfactant molecules do not form anisotropic aggregates and/or epicuticular liquid usually had a molecular weight less than about crystals. 2500. When the molecular weight of the surfactant

In some herbicidal compositions according to this substance exceeds about 2500, liquid crystals of the invention, the nature of the surface-active substance can still be formed inside and on the mixture of the herbicidal composition such that on the surface of the plant, but may not be as effectively applied composition or mixture , ready for nano- affect the transfer of glyphosate, as low mos- obtained by diluting the composition in water, molecular surface-active substances. on the plant, both on the plant leaf (epicuticularly), Liquid crystals containing a surface-active substance and inside the plant leaves (intracuticularly) in the presence of glyphosate epicuticularly and liquid crystals containing surface-intracuticularly are formed, usually are lyotropic liquid vo-active substance In other words, liquid crystals are crystals; i.e., the formation of liquid crystals of zvital, containing a surface-active substance, is induced in the presence of a solvent, which is formed to create or increase the amount of water. Mesophases of liquid crystals depend not only on the solvent, but also on the temperature. The waxy layer of the cuticle of the plant and also the formation of sterigal lyotropic liquid crystals containing a surface-active substance in the presence of glyphosate inside the plant (intracuticularly) for the formation of pathways inside the plant that can significantly increase epicuticularly and intracuticularly, with cubic transfer of glyphosate by structure, hexagonal structure, negative - plant. These transcuticular paths can be a hexagonal structure and with a laminar one and are responsible for increasing the effectiveness of such a multilaminar structure that has, at least, the presented composition. An important characteristic of about 20 to about 30 or more separate properties of herbicidal compositions according to the given layers. Also, it was observed that both symmetric and the finding that form both epicuticular and asymmetric forms of liquid crystals containing intracuticular liquid crystals is that a surface-surface-active substance in the presence of a glyph-active substance is able to form liquid crystals - satu, both epicuticularly and intracuticularly. In steel both on and in the plant. herbicidal compositions according to the present invention, as

A large number of surface-active substances, both epicuticularly and intracuticularly, liquid crystals described here, which in the presence of glyphosate formed liquid crystals containing surfactant in the surface of the cuticle and inside the presence of glyphosate, are formed independently of the plant, to improve the transfer of glyphosate in the presence or absence of the second surface infrastructure of the plant, may not form the active substance. crystals in glyphosate concentrates at a concentration usually acceptable for commercial purposes. contain glyphosate and surfactant,

Of course, these surfactants form epicuticularly and intracuticularly bury liquid crystals in the deposited glyphosate sediment, liquid crystals, liquid crystals contain many layers of this/surfactant, which forms surfactant molecules, so that from drops or by spraying a diluted hydrophilic group of molecules of a surface-active composition on the surface of the plant cuticle. Super-substances in one layer of the multi-layered structure are likely, and not based on a certain theory, to be oriented in the direction of hydrophilic groups, that the formation of liquid crystals of glyphosate in the molecules of the surface-active substance of the second layer of this multi-layered structure. Liquid crystals In this embodiment, it is preferable that the weight of the present invention, both epicuticularly and innoculation k.e. of glyphosate and the second anionic herbicide- cuticularly, can form this type of bagicide was at least about 1:1, for example, from the tolayer structure and can have a large number from about 1:1 to about 200:1, preferably from 1:1 to layers , as described above. about 30:1. The second anionic herbicide is preferred

In some compositions according to the present invention, which is selected from the group containing adzifluorfen, bio- containing glyphosate and a surfactant, laphoz, carfentrazone, clopiralid, 2,4-0, 2,4-O8, which form epicuticularly and intracuticularly dalapon , dichlorprop, glufosinate, MSPA, MSRV, liquid crystals, liquid crystals can have orien- mecoprop, methylarsinic acid, non-anionic cation in their multi-layered structure, so that lic acid, picloram, triclopyr and herbicides are imidazol-ophilic groups of surfactant molecules - of a new class, including imazamet, imazametha- irons of one layer of the multilayer structure benz, imazamox, imazapic, imazapyr, imazaquin, ima- interact with the hydrophobic surface of the rosetapyr sheet. the line on which the composition is applied. Also, the present invention covers liquid concen-

In addition, the molecules of the surface-active composition, which has an aqueous phase, where iron glyphosate of one layer of the multilayer structure can be present in the form of its potassium salt, and the non-aqueous phase interact with the hydrophobic surface, the locus that necessarily contains a second herbicide lysed inside the cuticle of the leaf, on which active ingredient, which is a practically water-dispersible composition. valid Examples of such compositions include

In addition, some surfactants themselves emulsions (including macro- and microemulsions, the presence of glyphosate can form a worm- "water in oil", "oil in water" and "water in oil in similar micelles, another class of organized structures water"), suspensions and suspoemulsions. The non-aqueous phase in liquid forms, which can improve transfer- may not necessarily contain microencapsulated glyphosate through the wax layer of the cuticle and a component, for example, microencapsulated ger- inside and throughout the plant, both epicuticularly and bicide. In the composition of this invention, which has neo- intracuticularly. Worm-shaped micelles are usually in the bottom phase, the total concentration of k.e. of glyphosate into less organized than liquid crystals, but the composition, despite this, is in a state of being sufficiently organized for the formation of fins indicated for aqueous concentrates of composi- hydrophilic channels on the surface and inside the plants. lines to improve penetration and transfer Examples of water-insoluble herbicides that glyphosate throughout the plant. Of course, these types of worms can be used in such a composition, such micelles will form on the surface - they include acetochlor, aclonifen, alachlor, active substances that are quite "elastic". ametryn, amidosulfuron, anilophos, atrazine, aza-

Although the present invention is directed directly to the aqueous concentrate of the composition of potassium salt sat, bensulfuronmethyl, benzulide, benzofenap, glyphosate, such an aqueous concentrate of the composition of bifenox, bromobutide, bromophenoxime, butachlor may optionally additionally contain one or butamiphos, butralin, butroxydim, butylate, cafe- several additional pesticides such as naprinstrol, carbetamide, carfentrazonetil, chlormeclad, water-soluble herbicidal active ingredients, toxifene, chlorbromuron, chloridazone, chlorimu- including but not limited to , water-soluble ron-ethyl, chlornitrophen, chlorotoluron, forms of acifluorfen, asulam, benazolin, ben-chlorpropham, chlorsulfuron, chlorthal-dimethyl, tazon, bialaphos, bispiribac, bromacil, bro-chlorothiamide, cinmethylin, cinosulfuron, clethodim, moxynil, carfentrazone, chloramben , clopyrali - clodinafop-propargyl, clomazone, clomeprop, clod, 2,A-0, 2,4A4-O8, dalapone, dicamba, ransulam-methyl, cyanazine, cyclo at, cislo-dichloroprop, dichlofon, difenzoquat, diquat, sulfamuron, cycloxide, cigalofop-butyl, endotal, fenac, fenoxaprop, flamprop, daimuron, desmedifam, desmethrin, dichlobenil, fluazifop, fluoroglycofen, fluroxypyr, diclofop-methyl, diflufenican, dimefuron, difomezafen, fosamine, glyphosinate, heloxifomepiperate, dimethachlor, dimethamethrin, dimethane, imazamet, imazamethabenz, imazamox, imazamid, dinitramine, dinoterb, difenamide, dithiopyr, picu, imazapyr, imazaquin, imazethapyr, ioxynil, diuron, ERTS, esprocarb, etalfluralin, eta-

MSRA, MOSRV, mecoprop, methylarsinic acid-metsulfuron-methyl, etofumesate, ethoxysuth, napthalam, non-anionic acid, paraquat, lfuron, ethobenzanid, fenoxaprop-ethyl, fenuron, picloram, sulfamic acid, 2,3,6-TVA, TSA flamprop-methyl, fluzasulfuron, fluazifopbu- and triclopyr. til, fluchloralin, flumetsulam, flumiclorac-

The embodiment of this invention, thus, represents pentyl, flumioxazin, fluometuron, fluorochlorine herbicide aqueous concentrate composition, rhydon, fluoroglycophen-ethyl, flupoxam, flurenol containing glyphosate, preferably in the form of potassium fluridone, fluroxypyr-1-methylheptyl, flurta- glyphosate salts, and the second anionic herbicide, peremon, fluthiacet-methyl, fomesafen, halosulfuron, important in the form of a potassium salt or another salt, accepted - haloxyfopmethyl, hexazinone, imazosulfuron, noi for agricultural composition, or its indanophan, isoproturon, isouron, isoxaben, isoacids, the total concentration of glyphosate and the second xaflutol, isoxapyrifop, lactofen, lenacil, an anionic herbicide is from about 360 to linuron, mefenacet, metamitron, metazachlor, me- about 570 g c.e./l, the composition additionally contains tabenzthiazuron, methyldimron, metobenzuron, meto-surfactant component, selected odpotobromuron, metolachlor, metosulam, metoxuron, according to this invention, with a concentration of met ribuzin, mesylfuron, molinate, monolinuron, about 20 to about ZO00g/l. naproanilid, napropamide, naptalam, neburon, nico-

sulfuron, norflurazon, orbencarb, oryzalin, but use the following method with a high-resolution oxadiargyl, oxadiazon, oxasulfuron, oxyflu- divided polarizing microscope. orfen, pebulate, pendimethalin, pentanochlor, pen- When determining whether liquid cristoxazone, phenmedipham, piperophos, pretilachlor, tali are formed intracuticularly, primisulfuron, prodiamine, prometon, promethrin, cuticle of fruits or vegetables such as pear or propachlor are usually used. propanil, propaquizafop, propazine, tomato, because they are harder. Extraction of propham, propisochlor, propizamide, prosulfocarb, cuticles in this case is carried out in the same way as prosulfuron, pyraflufen-ethyl, pyrazolinate, pyra- extraction of the cuticle of Theophrastus, but with zosulfuron-ethyl, pyrazoxifene, pyributycarb, with some changes. Of course, pectinase (10,000 units of activity per duron, simazine, symmetrin, sulsotrione, sulfentra - 100 ml). The concentration of the enzyme solution of vyzon, sulfometuron, sulfosulfuron, tebutam, tea is from about 10956 to about 3090 tebutiuron, terbacil, terbumeton, terbuthylazine, weight/weight. and the final enzyme solution contains terbutrin, tenylchlor, thiazopyr, thifensulfuron, from about 50 to about 200 units/ml. Cuticles - thiobencarb, thiocarbazyl, tralkoxide, trialate, lu are incubated with the enzyme at room temperature - triasulfuron, tribenuron, triethazine, trifluratura for about 1 hour or more until hatching, triflusulfuron and vernolate. It is preferable to divide the cuticle. After the separation of the cuticle, its weight ratio k.e. glyphosate to such water- wash thoroughly before use. of soluble herbicides was at least 1:1, for example. To determine whether liquid crystals are formed, from about 1:1 to about 200:1, whether compositions containing surface-active re- from 1:11 to about 301 ervine/glyphosate, intracuticular, cuticle,

Excipients other than the above-mentioned suspension above, used as a separate side of the rhneo-active component, may optionally be present in the composition for this non-porous material such as parafilm. Cuticle by stroke, provided that the cloud point (4 is placed on a supporting agar gel, which non-crystalline properties of the composition, such as in- is on the supporting grid, which is usually zani in this invention. Such additional excipients consist of carbon fibers. The composition includes in usual composite additives, cuticles/agar/mesh are placed on the glass slide, such as dyes, concentrators, crystal inhibitors, antifreezes, including glycols, defoamers, parafilm, anti-slip agents, are placed on the glass slide in this experiment , which improve the compatibility and similar interesting herbicidal compositions containing surface-

The type of excipient that is often used is the active substance and glyphosate. When polarized in the glyphosate composition, there is an inorganic salt, which is observed in the light with a 100-fold increase, such as ammonium sulfate, which is introduced into the composition, the presence of liquid crystals of the composition, as to increase the herbicidal activity or, as indicated above, as a cuticle , and parafilm as the basis of the herbicidal activity of glyphosate. Since the troll is washed either manually or mechanically, the content of inorganic salt in the composition is necessary with a lazy brush at room temperature. for such an improvement, usually relatively large- Of course, the liquid crystals formed on the parafilm are often more than the amount of glyphosate that can be easily washed away. As a parafilm, as a control, and tytes, the addition of such a salt to the composition for da- cuticle, after washing, is left for the achieved invention can rarely be useful. The amount of equilibrium state within about 24 to ammonium sulfate, for example, which can be added in about 48 hours in an environment that controls the aqueous composition, stable during storage, which is mis- (temperature from 20 to about 25"C, humidity from potassium glyphosate salt with a concentration of approximately 5095 to 7595). at least ZbOg c.e./l, is so small that it does not give any significant effect. reach equilibrium, the application area com- inject a small amount of synergistic compound, the positions are thoroughly washed again by hand or such as an anthraquinone compound or phenyl- mechanically soaped brush. - tent publications of MeUMO 98/33384 and UMO rised light with 100 x magnification for detection of liquid crystals 98/333851|, respectively. If after carrying out

In order to determine whether the herbicide compo- second washing forms a microstructure containing glyphosate or its salt or were those containing surfactant on removed after two washing cycles. In addition, the following methods can be applied to the leaves of the plant and inside the leaves of the plant, another washing cycle can be carried out. First, the composition that the cuticles, which is obvious evidence of the presence contains surfactant/glyphosate liquid crystals and that the liquid crystals do not wash off- is examined, as indicated above, to determine sia, because they are intracuticular. After the second formation of liquid crystals epicuticularly on the washing sheet, they examined, did not see any plants. If epi- formation of liquid crystals on any paraphy- liquid crystals are formed on the leaves of the plant, to determine whether lm used as a control. intracuticular liquid crystals are also formed. Of course, in order to improve the characteristics of the composition, a small amount of

solubilizer bone. Of course, the ratio of only the active substance and carboxylic acid/carboxyl salt is about 50:1 (by weight), more preferably about bonic acid can be from about 1:1 to about 251, even more preferably, about 10:1, and most - zco 50:1, more preferably from 5:1 to 401 and most preferably, about 8:1 surface - more preferably from about 5:1 to about 20:1. of active ethoxylated etheramine to the required amount of surface solubilizer. active substance and carboxylic acid/carbon salt

A specialist in this field will understand that bonic acid significantly improves herbicidal properties - various factors can affect the amount of required herbicidal composition obtained. of the solubilizer to achieve the desired Di-carboxylic acid or its salt, which can be characteristics. The solubilizer can also be added to the herbicide composition according to this invention in the composition with a low ratio, in order to improve the efficiency, suitable for which it does not act as a solubilizer, but improves the efficiency for use with glyphosate or its salts, such a ratio of surface or its esters. Suitable salts of the glyphosate active substance and the solubilizer equal to blephosate include salts listed above 5:1, about 4:1, about 3:11, about 2:1 or more, especially isopropylamine salt, potassium salt and about 11. trimethylammonium salt.

In addition, the addition of a solubilizer improves the present invention also includes a method of characterizing the viscosity of concentrated composi- for killing or controlling weeds or this according to the present invention. It is preferable that the amount of unwanted vegetation, which includes the stages of the solubilizer added to the composition, the dilution of the liquid concentrate in the appropriate ring is sufficient to obtain the viscosity of the composition less than that of water with the formation of a mixture that is stored 1000 c.p. at 07С and with a deviation coefficient of 45/s, in the tank, and the application of herbicide effective even more preferably less than about 500s.p. with the amount of mixture stored in the tank, on

OS ii with a deviation coefficient of 45/s and the most leaves of weeds or unwanted vegetation. Also, mostly less than about 300 s.p. at 0"C and with co- the invention includes a method of destruction or control by the deviation coefficient of 45/s. In the preferred embodiment of weeds or unwanted vegetation, which is included in the herbicidal compositions according to the present invention, they have stages of dilution of a solid free-flowing concen- viscosity from about 100 s.p. at 0"С and from the coefficient in the appropriate amount of water to obtain a deviation volume of 45/s to about 500 s.p. at OS and from the mixture, for storage in the tank, and application with a deviation coefficient of 45/s. In order to obtain these herbicidally effective amounts of the mixture, which preserves the viscosity characteristics of the new composition in the tank, to pour the weeds or weeds according to the present invention, a small amount of vegetation is required. hundred solubilizer. In the herbicidal method using com-

Another ingredient, which may be optional, the position of this invention, the composition is diluted by adding to the herbicidal composition of glyphosate according to the appropriate volume of water to obtain a solution of this invention for additional improvement for application, which is then applied to the leaves of herbicidal efficiency and herbicidal properties plant or plants in an amount sufficient for those, there is di-carboxylic acid or salt of di- obtaining the desired herbicidal effect. This is carboxylic acid. The corresponding di-carbonic acidity, which is applied, is usually expressed in lots that can be added to herbicide composi- the amount of glyphosate per unit area that is treated, containing glyphosate or its salt, or it is poured, that is, grams of acid equivalent per ether, and surface-active substance as described hectare (g c.e./ha), which constitutes "the desired herbicide- here above, includes, for example, oxalic effect", of course and as an example, at least 8595 acid, malonic acid, succinic acid, gluta- control of plant species, as measured by succinic acid, maleic acid, adipic acid growth or mortality over time, in lot and fumaric acid, and their combinations or mixtures that act oxalic acid is the predominant herbicidal or phototoxic agent. Also, as side effects of glyphosate in treated plants. In addition to or instead of dicarboxylic acid, depending on the type of plant and growing conditions, the herbicidal compositions according to the present invention for the period of time necessary for the maximum effect of improving the herbicidal properties can be in glyphosate, it can be short, for example, the salts of the above-mentioned dicarbonic oxides, but usually this period is approx. Suitable salts include, for example, one, two weeks. alkali metal salts such as potassium salts, alkano- Selection of the amount to be applied that is herbicide- amine salts and salts of lower alkylamines. Preferable but effective salts for the composition according to this invention include potassium oxalate, disodium oxalate, agricultural potassium, sodium oxalate, disodium oxalate, farm oxalate. This specialist will also determine, diammonium, diethanolamine oxalate, dimethyl oxalate, what individual conditions for the plant, weather umolamine, oalkanolamine salts of oxalic acid and you and growth conditions, as well as specific active salts of lower alkylamines of oxalic acid. ingredients and their weight ratio in the composition,

Compositions containing di-carboxylic acid will affect the degree of achievement of herbicidal such as oxalic acid or dicarboxylic salt efficiency in the practical implementation of this acid, such as potassium oxalate, usually contain the invention. There is enough information about the level of use and a significant amount of dicarboxylic acid/salt of the composition of glyphosate. More than two dozen carboxylic acid to achieve the effectiveness of years of glyphosate application and unubiquitinated dosli- herbicide composition obtained. The rules relative to this use gave a weighted ratio of the total amount of surface weed information from which a weed control specialist can choose the amount of glyphosate used, which is herbicidally active. a substance and/or an inorganic salt effective for individual species at each stage, such as ammonium sulfate, for the purpose of additional increase under certain environmental conditions of the effectiveness of the herbicide. However, in the majority of cases. six conditions herbicidal methods of use for

Herbicidal compositions of glyphosate salts according to the present invention provide acceptable effectiveness in the control of a wide variety of the absence of such adjuvants. plants that are found everywhere, and probably, in the method of using the composition, that the potassium salt does not differ in this respect, the composition according to the present invention is considered from other glyphosate salts. house, composition, after starting in water, after

Examples of extremely important annual seedlings are applied to the leaves of plants, genetically dicotyledonous plants, for the control of which can be deformed or tolerant to glyphosate, and the composition according to the present invention can be used, at the same time to the leaves of weeds or unwanted dew, but not limited by them, the cable car Theophrastus lyn, in the immediate vicinity of such stairs. (Archiope (peorngawii), amaranth (Atagapiyiv spp.), The result of this method of use is cont- sycamore tree (Voitepya spp.), oil role over weeds or unwanted plants, field canusta, canola, Indian mustard and so leaving practically undamaged seedling further (Vgazvisa 5yr.), comelina (Sotteyipa 5yr.), plants. Seedlings of genetically transformed or cranberry (Egodiyt srr.), sunflower (Neyyapinp5 glyphosate tolerant plants are included in 5yr), birch (Irotova 5yr.), kohia ( Cospia zsoragia), the same family sold by Mopzapio Sotrapu or mallow (Maima 5yr.), wild buckwheat, bitter gourd and so on under the license of Mopsapio Sotrapu with the trade name dibne (Roiuudopyt v5yr.), purslane (Rogitasa srr.), Koshypair KeaduF. They include, but not solyanka (Zaivoia srr.), Syda (Gr. bida), wild mountain- are limited, various cotton family, soybean, canola, sorghum (Zipari5 aguepviv) and netreba (Hapipisht of blood beet, wheat and corn.

Examples of particularly important contemporaneous plants can be monocots, which can be controlled by diluting the concentrate of the composition according to the present invention, but not the present invention in water. Application of the composition is limited to them, ovsyug (Amepa iaisha), axono- for processing the plant on the leaves mainly provonus compressed (AhoNiriz5 5yr.), stokolos fluffy woodpecker by spraying, using any zvi- (Vgotiz Tesiogit), blood dew ( Oidiagia 5rr.), tea methods of spraying the liquid, such as spray nozzles (Espinispioa sgazdaPo), plantain for spraying, sprinklers or the like. (Eiivipe ipais), annual fenugreek (ie. Compositions according to this invention can be used Shogit), rice (Ogula zayima), ottochloa (It was used in agricultural technology, where apa-

Niaosa), buckwheat (Razraiisht Niasht), canarrats for different amounts of pesticides, canary grass (RPaiagi5 yr.), foxtail are sown in different parts of the field, depending on (Zeiagia 5yr.), wheat (Tgyisit aeviimit ) and corn - differences, such as the growth of certain species of the genus (7ea tauz). saliva, soil composition and the like. In one of

Dicotyledonous plants can be used as examples of particularly important multi-year implementations of such technologies, which can be controlled by the general positioning system, which exploits the composition according to this invention, but is not limited to a sprayer for applying the desired color. ,) of the composition on different parts of the field. cottonwood (Azsieriaz 5yr.), field thistle (Sigviit Composition for the treatment of plants mainly agmepze), slanka birch (SopmoYimshts5 agmepviv) and sufficiently diluted for immediate spraying, hairy vypuearia (Riegagia 5yr.). using a standard device for developing

Examples of particularly important perennial pollination used in rural economy are monocotyledonous plants that can be controlled by planting. Effective spray volumes for the composition of the present invention are, but are not limited to, spray-applied, chewed, brachiaria (Vgaspiagia spp.), bermuda grass (SuNidop dasiuiop) can vary from about 10 to about 1000 ), ground almond liters per hectare (l/ha) or higher. (Suregi5 ezsshepii5), net round (S.goishpaiv5), pi- Examples swarm (EI(utiz herep5), lalang (Itregaia suiipagisa), The following examples are given only for perennial fenugreek (Hoiisht regeppe), millet illustrations and are not intended to limit the framework chicken (Rapisht tahitit), paspalum expanded this invention. Examples will allow to better grow- (Razraisht diiagashit), reed (Rypgadtytsev5 5yr.), to understand this invention and evaluate its advantages and pev- johnson's grass (Zogdpyt Paierepze) and rye no changes in performance (Tura srp.) Example A. Production of potassium salt of glyphosate

Examples of other particularly important boga- In a glass vessel with a capacity of approximately 4 littoric plants, which can be controlled by com- were added 1264.1 grams of glyphosate acid with a position according to this invention, are, but not limited to, a frequency of 95.7956. The vessel was placed in a bath with them, horsetail (Ediyizeht 5 years), ice/water for cooling. A mechanical stirrer with a screw blade (Kibyz 5yr.) and an ordinary tussock (Shieh epgoraeiv) were placed in a vessel with an eagle's fern (Riegidisht adiyypit), blackberries. approximately half the diameter of the vessel. Add-

If desired, when preparing the composition, a commercial 4595 solution of sodium hydroxide was prepared before use, the user can mix (MUK Zsiepijs Rgodisi5). The speed was added under one or more adjuvants with the composition according to the control to avoid strong bubbling of the dispensed invention and dilute with water. Such adjuvant that was formed. The height of the stirrer is set

was mixed in such a way that a small amount of phosphoric acid was added to the volume of the mobile liquid to ensure good mixing. In total, to bring the pH to a value between 4.9 and 5.1. 966.2 grams of potassium hydroxide solution were obtained. The concentrated mixture was stirred with the help of magnetic centration, and the concentration was adjusted by adding 195.3 grams of a deionizer (CoIe-Ragteg, Spisado, I) to homogenized water. They continued to stir. In the case when the substances were viscous and, therefore, for another hour. The final output was 2418.4 grams, which showed a weight loss of 7.2 shekels, the substances were rolled on a rolling gram. The calculated data were 50.095 glyphosate (05 Biopemzhage, Mapzhap, MU) before dissolving acid or 6195 potassium glyphosate and calculated surfactant. The substance remaining after neutralization was 10895. The pH of 1095 was diluted overnight and evaluated to ensure that the day in deionized water was 4.76. it is one phase and without bubbles.

The density of the resulting solution at 20"7С was The density was then determined using approximately 1.4661 grams/milliliter and a volume of 1000 grams Mesheg RA-300 densitometer, and calculated the con- at 20"С was as a result approximately 682ml. concentrations in grams per liter.

This corresponded to a concentration (weight/volume) of approximately 7 ZbOgrams/liter. a large amount of substance in an analytical test tube

Example B. Preparation of comparative composites until the solution became cloudy or non-prositizing and the compositions according to the present invention rime, then the analytical tube was stopped heating

Compositions from 2-01 to 2-13 containing surfaces and noted the temperature at which the solution became non-active substances were obtained as described transparent upon cooling. The temperature is lower. Each composition contained a potassium salt of glycol, which made the solution clear, was recorded as the phosate point, and was obtained using 5095 de-turbidity. rank k.e. of sodium glyphosate from example A above. Pore- Viscosity was measured using the device and compositions containing potassium salt Naake Modei MT500 (Naake, Ips., KagpzpNe glyphosate, surface-active alkyl polyglycoside and Segtapu) with the appropriate MM series of glasses and cis- alkylated alkylamine (compositions 2.01- 2.05) by the theme of sensor nodes with a shift speed of 45 sec. was obtained in such a way as to repeat the composition of the water bath. samples, for

Publications of MEUMO 00/15037|, respectively. of which unusable samples were obtained, viscosity

Sample Preparation: A 4-ounce mug was measured with a Vgookyeii Mode! About 80 grams of OM-z (117ml) solution was added with an adapter for small samples (5tai! Zatrie liyu glyphosate of example A. Adarieg) (Vgookpeii Iarogaiyughiev, Ips., 5iotsdpop, appropriate proportion of adjuvant and water was added to it. In some samples Mavzv5.).

Table 2

Compositions of example B (from 2.01 to 2.05) p ee en ee och ee

Fo tive- Fo tive- Fo active-| o tive- Fo active-

NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI NOSTI

Adity RSH2O67 | 715601|10.92) 12.85 | 5.00 | 17.73 (12.41) 12.15 8.50 | 13.50 | 5.45

EFoteepS/15 /-/-:/ 77777711 17365| 2 Yushshshsh | 3451 sh | 386 | |772| |z8 (Propylene glycol.//gg/// 1 000| 2 sh (10001 | 0001 |000| |196

Water 1209 2 sh |97l2 | sh |893| |06 11111111 forehead 17 forehead00 | 10000 | forehead | lo0b00 /Density (/сM) 20277771 rziya3i 03509 | 13408) |13288, | 3824 g/lke of glyphosate 77777777 171111 |542/lI// 5b4g/l| d4bbg/l| (4B/l | | 54Zg/li of active substances (point of consumption/777712590 1590C1 117111111111111111 fl2gov lo | 226 | lo /457| 10 | 209 lo |501 11111115 714831 5 | z382| 5 11630) 5 |226| 5 | 5801 11111110 018771 0 |z335| 0 1668 0 |271| o1 1623 -111513 -11151. 5B /|485| 5 |880| -5 | 398 | -5 | t266

Table C

Compositions of example B (from 2.06 to 2.13) do do do do do do do be active-i Zo |active| Active 965 active Active 95 active 95 active 96 active active active active active active active active active active active active active active active 74581 //74.00137.0095

Never; ipolslemei | | | | 1111 HER 1 1 111

Ebfotech/// | | /H 7 h h h h h h 1 1 h 1 1 1 1 17

Ephodna pi p PNYA PNYA NYA CAPTURE CAPTURE HORSE HE LOVE LOVE HORSE KN HORSE HORSE NANNYA

Totayi.///-/ HER 1 YY 1 y y yy 1 1 1 1 1 1 1 7 (Phosphorus../Г/ | | Г Her y y yy yy 1 y 1 1 1 1 17

Water HER GG 71177171 11717171 1717 17 1 0000010 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00

A and E (g/lk.e. glyphosate 1494| 1/449| |487| |449| /|529| |4/6| |493| | a4954

Total circle. quality of solid surface 12.46 Mb5g/li 16.1 I209g/li 13.7 M82g/li 16.2 |209g/li 14.6 | 196 | 9.10 | 119 112.50) 165 |12.51| There are 167 active cases; rue, rue, es, rue ryu

Viscosity at Temp. Tempo. Tempo. Tempo. Tempo. Tempo. Tempo. Tempo. 777777 7 | 25143|25|73| 25 | 70 | 25 | 3 | 25| |25| /|251|32/|25 7777 7 17151551 151102) 15 | 82 | 15 | 15 | 15 |5y| 15 | 33 | 15 | 61 | 15 | 115 7777177, tl0 191170 |122)| 710 131 10 in) 29 | lo | 531 then in z6 | then | 109 10 | 123 77777717 15 |125| 5 17144) 5 |177| 5 | with 3 | 5 |61z3| 5 | 46 | 5 | 113) 5 | 160

Table 4. Surface-active substances used in example C

Superficially | | and active Chemical structure Trade name! the supplier of the substance is and , and and

And | 104-75-65

ADM and SATaNeV)

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Saint M (Servant rial abacsegsot) s | and is not commercially available

Sina and (strain according to the example of O described above) and commercially not available san m-n (EOM and Z

And (reduced by ethoxylation of k-methyloctadecylamine)

It is not commercially available

Sivniai M (BO6aH (obtained by the ethoxylation of M. methyloctadecylamin)

E: Iv 0830

Sho VN ie av a (ASF) 0 pi SU

San y t Y -- century

R M is not commercially available

NN. t SA BIK

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MK, is it homercially available ah and t STVA svo. with nave and (Totshav) (Se Mne

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Ho ny ko OO TOALOIM (Totav) (Sebor va a av an

R that shi TO TVALONV S Ttotan) svi you fa a not

B o. and hearts | RASIV (Totav) n SPOGLOALYATTOtTan) 4 t GOA-17 SGotai) and В-1910-5 SMnso) is m and M Z ver kozh vom n GT in В-1910-6 SM ИKO

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Food with SA 85632-63-9 vk "t um Teyatiye EOK-14B

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The following compounds are not compatible with 3195 k.e. potassium glyphosate and 1095 surfactant, but may be compatible with 3195 k.e. diammonium glyphosate and 1095 surfactants.

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State University of Education

Example C. Obtaining typical samples of the composition of the blisters, 0.200 g of surface-active zinc according to this invention of the substance was added. Then enough was added to the contents

To obtain 3195 by mass k.e. potassium gly- amount of deionized water, bringing the total phosate/1095 by mass of surface-active com- weight to 2,000m. The mixture was stirred for 2 positions in the bubble, weighed 1.550g 4095 hours by weight at room temperature and checked for k.e. aqueous solution of the sodium salt of glyphosate. In that solution formation. If the solution was formed,

the bubble being analyzed was left overnight at To obtain 3795 by mass k.e. room temperature. If the contents of the bubble again MNa"glyphosate/1295 by mass of surfactants remained in the form of a solution, the analytical fluff-compositions in the bubble were weighed 1.7bg 41.995 per mouth and stored at 50"C for 1 week. If by mass ke. of aqueous diammonium salt glyphosate, no phase separation was observed within one (1.7 equiv.). In the same vessel, 0.2 g of surfactant, a surface-active substance, and an analytically active substance were added. Other actions according to the protocol were considered as "acceptable". All surface-active substances are the same as described for obtaining the sample from 31905, presented in Table 4, by weight. Surface-active substances described in the novel at 31905 k.e. potassium/1095 k.e. by mass according to Table 4, which were compared at 3795 k.e. potassium/12905 of the surfactant being evaluated. ke. by mass of surface-active substance, which

To obtain 3795 by mass k.e. potassium gly- is evaluated, shown in Table 5 below. phosate/1295 by mass of surface-active com- Table 5 lists this compatibility and vy- positions in the vessel weighed 41.1 g 4595 by mass viscosity for selected compositions of example S. Zroke. aqueous solution of the sodium salt of glyphosate. It turned out that not all the results of the comparative tests are presented here. Some surfactants and 2.9 g of deionized water to the total keel-active substances (but not specified here) that have a density of 50.0 m. Other protocol steps were the same, but not compared even at 3195 wt as described for the 3195 wt sample. k.e.

Surface-active substances described in Table 4, Example 0: Preparation of a-methyl-s-O0ch- which were compared at 3795 k.e. potassium/129o k.e. by methyloctadecylaminopoly(oxy-1,2-ethanediyl) by weight of the surfactant, which is estimated. The preparation of intermediate compound C from Table 4 is shown in Table 5 below.

To obtain 4095 by mass k.e. potassium glyphosate/1095 by mass of surface-active com- -0--(COMPRESSED,; positions in the bubble weighed 1.79g of 4595 by mass (90) ke. aqueous solution of the sodium salt of glyphosate. 0.2g was added to this vessel surfactant Other actions according to the protocol were the same as hep methyl ether tosylate 1 g) described to obtain a sample with 31 wt. and (oxyethylene) glycol (1):

Surfactants, described in Table 4, hepta(oxyethylene) glycol methyl ether (350 which were compared at 4075 ke. potassium/lO75 ke. for average MM, 47g, Tecv., Algisp) and triethylamine stsYa. (17.59g, 1.Eq.) was dissolved in anhydrous methylene chloride, toluenesulfonyl chloride (28.16g, 1.1Eq.), phosate/1555 by mass of surface-active com- dissolved in anhydrous methylene chloride (20 ml), placed in a blister! weighed T1OSH two o 300 lin were added, maintaining the temperature below ove U evo ak u echo ud schi e bh a 1070. After stirring for 4 hours at surface-active substance. in a bubbler at room temperature, the reaction mixture was filtered with a sufficient amount of deionized water, enough and the solvent was removed from the filtrate while reducing the total weight to 2,000 m. Other actions under protoconometric pressure with the production of b4g orally were the same as described for the production of gum butter, 9595 yield. "H NMR a 7.8 (d, 2H), 7.5 samples with 3195 by mass. Surface-active substances (d, 28), 41 (t, 2H), 3.6-3.4 (m, 26H), 3.2 (c, ZN), 2.4 wines described in Table 4, which were compared at 45905 (c, ZN). by mass of surface-active ! Preparation of compound C from Table 4, the substance to be evaluated, shown in Table 5, M-methyloctadecylamine (283 av. MW, 18.49 g, obtained 3195 by mass ke. Mny" glypho 2.2 equiv.) was dissolved in 200 ml of toluene and then add a holding of 9 M c.e. glyphosate potassium carbonate (4.1 g, Tekv.). Tosylate (1) satu/1090 by mass of surface-active composi- (15 eq., eq.) was slowly added to the mixture and then ho . oh . 1.48 g of AT was weighed in the bubble, by mass k.e. the reaction mixture was placed in an atmosphere of nitrogen and aqueous diammonium salt glyphosate (1.7 equiv). The same was heated overnight at 802. After the vessel was closed, 0.2 g of surface-active reaction solution was added, the solid was removed by tin and 0.32 g of deionized water. Other actions during proto-filtration through celite. toluene was removed from the filter sample by the same procedure as described above under reduced pressure. Crude product chroma-razk 5 M o. Surfactants were rotographed using the methylene chlorides described in Table 4, which were compared at 31 aryl/methanol/ammonium hydroxide in the ratio k.e. potassium/1095 ke. by mass of surfactant 80:51. 16bg of a yellow semi-solid was obtained, which is estimated to be shown in Table 5, substance (II), yield 8595. H NMR, 3.6-3, Ap(m, 26H) below. 3.Zp(s, ЗН), 2.6p(t, 2Н), 2.2p(s, ЗН), 1.4p(m, 2Н), 1.2p(s, ZON), 0.8p(t , ZN).

Table 5

This compatibility and viscosity are given for the selected 3795 by mass c.e., 4095 by mass c.e. and 4595 by mass c.e. compositions of example C

Comparison of the given viscosity The cloud point | Comparison | Comparison Comparison Comparison

Turn- - | Ninnia 3795 k.e. | weight/4095 k.e. | weight/4595 k.e. | weight/3196 k.e. weight/37905 k.e. weight/3795 k.e. Ky") 37965 k.e. Ki gli- - - : - - - - hnevo- - Ki glyphosate | What is glyphosate | What is glyphosate | glyphosate dia- | glyphosate dia- glyphosate at | phosate at 1290 o, o, o, - o, - o, active ou | at 1255 for at 1095 for | at 1595 for |monium at 1095 | monium at 1295 substance 1275 by mass | by mass zavan mass zavan- mass zavan-| by mass zavan-|by mass zava-| by weight, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading, loading

E Tak NaaKemiv. 2907 Yes Yes 257C; 57.29s605 1520; 110.89s65 1020; 142.38vsB5 570; 17357ор5 0"С; 273.01сР5 -57С; 400.48сБ5 7711771 taco/ pbolepaitos | pa 77777777! С1111111111111

Yes Naake Miv. 2907 2570; 101.82сР5 1520; 118.51s6r5 1020; 198.34sBr5 570; 221.90sR5

OS; M67.bOsR5

So NaaKemiv. 2907 2570; 1077оР5 1570; 1420srR5 1020; 1963сР5 5"С; 2269сР5

OS; 2517оР5 -576С (оо ShPisk

M Tak NaaKemiv. 2907 Yes No (Sei) 257C; 31.49s605 15270; 64.1 5or5 102; 7boB5 5"S; 96.58s65

OS; 146.77СР5 -57С; 164.23sB5

AA Yes p'sokneya 2907 Yes Yes Yes Yes

Izso5zPU 1026.

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OS; 384.53СР5 -57С; 646.90sB5

So NaaKemiv. 2907 257; 49.37sr5 15270; 82.5 Isr5 1020; 138.80sB5 570; 150.26сР5

OS; 231.17сР5 -57С; 397.16sB5

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Yes (small nya: ZNYI ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХ ХХХ

MM YY yes | Nistel)

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It should be noted that the compositions according to the invention, containing the potassium salt of glyphosate without K t alkyl polyglycoside as a component of the system of surface- (36) non-active substances, usually have a significantly low viscosity in comparison with similarly composed compositions of the potassium salt of glyphosate, which mostly contain APO. The value of this advantage of viscosity in (37) depends on some selected values and concentration and surface-active substance(s), where B! and BZ independently represent the hydrocarbyl that is used. For example, the white or substituted hydrocarbyl indicated above, containing from 1 to the description of certain embodiments according to the present invention does not contain approximately 30 carbon atoms , or -(B2O)5B/2; In it, a list of possible applications of the given t(B2O), p(BgO), p(BgO) and a(B2O) group is not found. It is clear that Lezhno is a C2-Ca alkylene; C, BB, BZ and B0 of the described paths are adapted to certain embodiments, independently they represent day, hydrocarbyl and

Example E. Preparation of surface-active Pizno ZO. pdrocaroyl, ranging from 1 to pris" of substances EEV-ШШШ of carbon; is

The obtained compounds of formulas (36) or (37) (CHg2UOV"Z or -"CHgudF(B2O)aVU; B», B and B" independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl containing from 1 to approximately 30 carbon atoms, or B"; B!" is a hydrocarbyl or substituted hydrocarbyl containing from 1 to approximately 30 carbon atoms or - Table 7 (CHg);O(A2O)pAU; t p, p and 4 have an independent average value from 1 to approximately 50; X represents co- С(0)0-, -ОС(0)-,.-

M(B'5)C(O)-, "C(OMSH(VZU, -8-, -80-, or -8O"-; 1 equals 0 or 1; A- is an anion acceptable for agricultural of compositions, U17 26 | SenU | SN | SNU 15156. are independently equal to the whole number from 0 to approx- (270 | Sina; | SNU | SN | 251 approximately 30

The compound was obtained by adding compound B!-

XN into epoxide with a molar ratio of 1:1 in the presence of a base such as isobutyl aluminum hydride o2i 0 | SivNU; | SNU |isopropyl| 5 |000000СсСсС (OIVAG), Mann or Lewis acid such as | 2K HER SivNUu | SNU and isopropyl 10 Y.00000011сСсС

БезЗЕСО, with the formation of the intermediate compound (91), as (2100 CoNoz | CHz | isopropyl| 510000 is represented in the reaction scheme shown below: | 2t | CoNa | CHz | isopropyl| 10 | Compounds (38) and (39) were obtained k-KHN - shu (91) where and in t copper (38)

Compound (91) was then alkylated using conventional methods to obtain the compound of formula (36). When in the above-mentioned reaction scheme Х Хx represents -М'В8ВО-, then the compound /Уе в' is formed (37). (39)

Alkyl aminopropanediol compounds were obtained (volume 7 of the formula (36), where X represents -M(B'), BZ, B5, Be -(bome and B" represent hydrogen, 22O represents ethide, where B! and B ? independently represent hydrocarlene and E" represents -CHgO(B2O)4B8Z. Ethylene oxide was used for alkoxybil or substituted hydrocarbyl containing from 1 to 30 carbon atoms, or -(B2O)p6B"Z; B? in each t(22O), p(82O), p(B?O) and a(B2O) group is independently a C2-Ca alkylene; C, BB, BZ and Bo

Table 6 independently represents hydrogen, hydrocarbyl, and substituted hydrocarbyl containing from 1 to about 30 carbon atoms; BC? is - (CHgUOV!Z or -(CHg)UO(B2O)4A3, B5, Be and B" independently represent hydrogen, hydrocarbyl or substituted hydrocarbyl containing from 1 to approx.; 4. riy v ab mine hydrocarbyl or substituted hydrocarbyl CONTAINING from 1 to about 30 carbon atoms or - (CHg):O(A2O)0AZ; t, n, r and d independently have an average value of from 1 to about 50; X is -О-, -М(В")-, -С(0)-, -С(О)0-в. -ОС(О)-, - лк | коко | НН | 23 | ш 425 | M (А"5)С(0)-, -С(О)М(А)-, -5-, -50-, or -50"-; 1,770 kokb | НН | 30 | 427 | is equal to 0 or 1 ; A- is an anion acceptable for agricultural compositions; y and 7

Alkylaminopropanol compounds 2a-c, represented independently equal to the whole number from 0 to attached by the formula (36), where X represents -M(B17)-, VU, about 30.

В», ВАЕ and В" represent hydrogen, Б2О is a compound obtained by adding the compound ВБ'- to ethylene, and 2" is -"СНгОСНеСенНв5, ode- ЧН to an epoxide with a molar ratio of 1:1 in the reaction amine from a benzylglycid base, such as diisobutyl aluminum hydride, was then alkylated and removed (OIVAG), Mann or Lewis acid, with the formation of protection from the benzyl group by the usual cap intermediate compound (92), as represented in the catalytic hydrogenation scheme , so that KB" then showed the reaction shown below: -СНоОВЗ. For alkylation, ethylene oxide was used in

Alkylaminopropanol compounds 2а-), represented by -яХН also: as в--х- (and (92) are given by formula (36), where X is -М(Б17)-, ВУ, т он

VU, Vb, and B" represent hydrogen, B2O represents ethylene, and P" represents -CHgOVZ, was obtained by reacting an amine with the corresponding glycidyl. . by conventional methods to obtain the compound

Ethylene oxide was used for alkylation. formula (38). When in the above-mentioned reaction scheme X represents -М'В8ЗВЗ-, the compound is formed

The number of formed alkylene oxide groups in honey! Willow. the length of the main chain of the compound (92) depends on the molar ratio of the B'-HN compound and the epoxide present in the reaction. If the molar ratio in? of the B!-HN compound and epoxide is 1:3, for example, (93) 2 is -СНеСНе- and t is 2 in the formula г and (92). The compound can then be alkylated as в'-хА-ох indicated above. T

Compounds (40), (A1), (42) and (43) were obtained: Compound (93) was then alkylated by conventional methods to form a compound of the formula (voA Ux B (40) or (40). the product includes

In one quaternary ammonium salt (that is, one X point is -M"B8B8Z-), the compound has the formula (41) or (42). When the starting product contains two salts of chet-

Kk - 8 5 of spin ammonium (that is, one X is - 4th ( 4 , М"АЗВе-, and the other is -МУВ!!В12-), forming (Ве т (41)) a compound of the formula (43). 9 I-Y Example E: Preparation of gemini (setipi) glucose units 27, AAA, BBB, SSS of formulas (28) - n

And in dya t (94) poktayutt (42) r. ; or Compound 77: give? 1,12-methylaminoglucite dodecane: K-methyl, 'k in p-12: 1-deoxy-1-(methylamino)-O-glucite (195 MW,

Fe e 8 15g, 2eq.), 1,12-dibromododecane (328 MW, 12.6Hg, (VO VO 1eq.), sodium bicarbonate (7.1g, 2.2eq.) and 120ml

To a mixture (43) of anhydrous dimethylformamide, hydrogen was introduced into the atmosphere and heated for 17 hours at

With a temperature of 70"C. After completion of the reaction, all bicarbode B/, BZ, and B!2 independently represent unreacted sodium hydnate, filtered carbonyl or substituted hydrocarbonyl was removed, which by mixing and then at under reduced pressure from the reaction mixture from 1 to about 30 carbon atoms, or - the mixture was removed by DMF. To the precipitate of the crude product (B2O)BW!Z; B2 in each t(B2O), p(B2O), p(BgO) and added 400 ml ethyl acetate and a mixture of stirring

I(B2O) group independently represents Co-Ca alkylene; within a few hours to remove DMF,

VAZ, ВВ, В", ВИЗ | В! independently represent what remained of the precipitated product. Crude lead, hydrocarbonyl, or substituted hydrocarboduct was recrystallized twice from a methanol solution containing from 1 to about 30 carbon atoms; lpu/water with a ratio of 11 and received 6.68 g

Ve is -(CH2UOV!Z or -(CHg)uO(B2O0)83. white solid product or 1595 yield. H NMR

B5, Ve and B7 independently represent hydrogen, hydrogen, Z0OMNa, MeOOa: 1.25-1.4 (width, 16H), 1.5 p rocarbonyl or substituted hydrocarbonyl, which mis- (quant., 4H), 2.45 p (sept., 4H), 2.55 p (d, 4H), 3.6- tit from 1 to about 30 carbon atoms, or B; 3, vr (plural, 12H). Analysis for SavNevMgOn: theo-

Vo is a hydrocarbonyl group or is retically substituted: C 54.3, M 10.1, M 4.8; was found: C hydrocarbonylene containing from 2 to about 30 54.2, M 9.9, M 4.5. carbon atoms; P is a hydrocarbonyl or Compound AAA substituted hydrocarbonyl containing from 1 to 1,6-texylaminoglucytpropane: K- hexyl, p-Z: zko 30 carbon atoms, or -(CHg)2O(B2O)pBZ; t, 1-deoxy-1-(hexylamino)-Y-glucite (265 MW, p, r and d independently have an average value of 1 15.76g, 2eq.), 1,3-dibromopropane (202 MW, 6.0g , to about 50; X represents -O-, -M(B12-, -С(О)-, 2 equiv.), sodium bicarbonate (5.49G, 2.2 equiv.) and 180 ml of -С(Ф)0. -, -оС(О», -МСХВА'US(О)-, -СКОЖМ(В'З-, -5-, - anhydrous dimethylformamide was placed in atmo- 50- or -5052-; And is equal to 0 or 1; A - is an offer of nitrogen and was heated for 17 hours at an anion acceptable for agricultural com- 70"С. After the completion of the reaction, all bicarbose positions; y and 27 are independently equal to the total number of sodium nates that did not react, the filter was removed from O to about 30. by walkie-talkie and then under reduced pressure from the reaction

Compounds of formula (40), (41), (42) or (43) were removed from the mixture by DMF. The precipitate of the raw product was oxidized by adding the compound B!-X-(B2O)y-KHN. 100 ml of ethyl acetate and a 1:1 molar ratio of stirrer-epoxide was added to the mixture for several hours to remove DMF, a base such as diisobutylaluminum hydride remaining from the precipitated product. (OIVAG) as presented below: The solvent was decanted and the product was subjected to additional drying under vacuum overnight at 80"C. 12g of yellow semi-solid product, which was 9095 pure. All attempts at recrystallization or chromatography for additional purification failed. Output, 7195. H-NMR

BOOMNI, MeOYU". ), 2.55-y/y 2.75p (plural, 12H), 3.6-3.8p (plural, 12H). S- vyu-ya yuh-3--ii (23)

NMR 50 MN, MeOO»: 13.8r, 22.8r, 25.8r, 26.5r, kha 26.2r, Zg, Or, 53.0r, 54.5r, 56.8r, 63.8r, 70, Or, Commercially available selected ethoxylate 71.2p, 72.0p, 72.5p. 20-NMR experiments gave an alcohol (such as Vgii"m 58) was converted into the final structure conformation. one tosylate by treatment with tosyl chloride in the presence of

Sos Compound; ov. St. properties of potassium hydroxide. The resulting tosylate was then 1,8-hexylaminoglucytoctane:ke hexyl, n-8:1- reacted with the appropriate alkylamine (such as deoxy-1-(hexylamino)-O-glucite (265 MW, 15.0g, methylamine, benzylamine, dimethylamine and similar to that - 2 eq.), 1,8-dibromooctane (262 MV, 7.68 g, Tec.), carne) in anhydrous tetrahydrofuran (THF) at 802C, potassium bonate (8.56, 2.2 eq.) and 180 ml of anhydrous overnight to obtain the desired product. of dimethylformamide was placed in an atmosphere of nitrogen Example H: Preparation of the compound of formula (25) and heated for 20 hours at 70. After the completion of the reaction, all the sodium bicarbonate of the mud indicated below was obtained as follows: no reacted, was removed by filtration and then removed from the reaction mixture under reduced pressure

DMF. To the precipitate of the crude product was added 10 ml of ethyl acetate and the mixture was stirred for several hours to remove the remaining DMF from the precipitated product. ?

The solvent was decanted, and the product was subjected to additional drying under vacuum overnight. The alcohol (such as Vgyl "m 58) was converted into the reaction at 80"C. Additional purification was achieved by treating the soluble tosylate with tosyl chloride in addition of the crude product in a minimal amount of potassium hydroxide. To obtain the desired methanol and removing any solid product, the resulting tosylate was then reacted with the precipitated product. Obtained 13.6 bg of yellow semi- corresponding amine derivative (such as n-alkyl glu- solid product with 9095 frequency. Yield 38905. H- amines and the like) in the presence of anhydrous

NMR 300 MN, MeООО»: 0.9p (t, EM), 1.2-1 4p (ext., sodium bicarbonate in the form of powders at boiling - 18H), 1.4-1 br (ext., 8H ), 2.4-2.6p (plural, 12Н), shadowed with a reflux refrigerator with anhydrous 3.55-3.8 (plural, 12Н). ethanol for one or two days before receiving

The combination of BBB of the desired product. 1,8-octylaminoglucitepropane: K:- octyl, n-:Z3: 1- Example I: Preparation of the compound of formula (74) deoxy-1-(octylamino)-O-glucite (293 MW, 6.45g, Alkoxylated quaternary ammonium salt 2 eq.), 1,3-dibromopropane (202 MV, 2.2 g, Leq.), of the formula presented below, was also obtained sodium bicarbonate (2.0 g, 2.2 eq.) and bOml of anhydrous as follows: dimethylformamide was placed in the nitrogen atmosphere was heated for 17 hours at 70°C. After the completion of the reaction, all unreacted sodium bicarbonate was removed by filtration and then treated with reduced pressure was removed from the reaction mixture with methyl chloride in anhydrous THF at 502C

DMF. 200ml was added to the precipitate of the crude product overnight to obtain the desired product. of ethyl acetate and the mixture was stirred for several hours to remove the remaining DMF. The amine oxide was obtained as follows: the precipitated product. The solvent was decanted and the dried product was subjected to additional drying under vacuum. with overnight at 80"C. 8.88 g of white sidngiossna al sppeiosneni pico were obtained. recrystallization or chromatography for Alkyl alkoxy dimethylamine was oxidized with hydrogen peroxide in methanol at room temperature, additional purification did not give results. Output during the night with obtaining the desired product. 6495. H-'NMR 600МН2, Me»: 0.87p (t, 6H), 1.2- , and 1.35p (ext., 2OH), 1.5p (quint., 4H) . the compound of formula (72) is obtained- 12H). C-NMR 600 MN;, MeOOa: 14.6br, 23.7r, I n 24.55r, 27.4r, 28.6br, 30.4r, 30.8r, Z3 , Or, 54, Or, and scha von kn 55.8r, 58.2r, 64.8r, 71.7r, 72.5r, 73.0r, 73.8r. 2B- sf OSNSNI) ag MN; I senegiosnsni oh

NMR experiments gave the final structure of the conformation. Alkyl alkoxy amine was converted into the desired

Example C: Preparation of the compound of formula (23) by treatment with formamidesulfonate

Alkoxylated amine was obtained, in which the acid in methanol at room temperature had the formula: during the night.

Another compound of formula (72) was obtained in this way. 1) o-0-k-ovenoi o Ne sense A x sons (osnsnu i s- nsnyme,

The product was synthesized by acylation of the corresponding amine with chloroethyl isocyanate, then the chloride was replaced by dimethylamine.

Example I: Preparation of compounds of formula (78) and (79)

Compound (79) was obtained by alkylation with tetramethylpropylenediamine with an excess of hexadecylpoly(ethylene oxide)tosylate under reflux in ethanol for two days and purified by ion-exchange chromatography OOMUEX 50UUH2-400, eluting with 5095 concentrated NCI in ethanol.

Soso-Ni tho-SNISNOsN) SN Ota test SosonneIsSnoo sleep). SN, MN. Soso

Compound (78) was obtained by alkylation, then by reducing the obtained lithium aluminocamine diamide with poly(ethylene oxide) ditosylate in the presence of hydride (AN). Alternatively, this compound can be prepared by refluxing diamine with two equivalents of long-chain alkyl bromide. ethanol for two days. Gemin (setip) diamines were ethoxylated at standard

Example M: Obtaining a compound of the formula conditions.

The compound was obtained by the interaction of the corresponding diamines with two equivalents of acid chloride,

YOU are a tool TNE snysny VUD (snosn, p sy YOU JH Chenden, 5, svv KAK chen a isnu (spon

Example M: Preparation of the compound of formula (26): I

Commercially available ethoxylate alcohol was converted to the corresponding tosylate by treatment with tosyl chloride in the presence of potassium hydroxide. O-glucosamine hydrochloride was then reduced in the presence of sodium borohydride and water to obtain ring-opened glucosamine salt I. In the presence of UN Kk. - alkylation of potassium carbonate, glucosamine interacted with Alkoxylated compounds of formulas (33), (35), (64) alkyl ethoxytosylate to obtain the desired and (71) was obtained by selecting a commercially available product, as shown below: a blunt starting product, such as a tertiary snIsnyurA amine, and by alkylation of the starting product using methods known in this area with the formation

Mn.

Example R. Experiment on the formation of anisotropic aggregates and/or liquid crystals

By applying the various methods described here, to determine whether the K - alkyl forms a surfactant

Example 0 And the substance in the presence of glyphosate anisotropic aggregates

O-glucosamine hydrochloride was then reduced to gats, epicuticular liquid crystals and/or intracuticular liquid crystals obtained in the presence of sodium borohydride and water, the applicants were glucosamine salt with an open ring. Glu- investigated a large number of surface-active cosamine salts were neutralized with sodium hydroxide substances to form anisotropic aggregates and/or and it interacted with alkylaldehyde corresponding liquid crystals. A large number of sections of the chain were investigated under reducing conditions, i.e., in surfactants in the presence of glyphosate in the presence of ethanol, 495 Pa/С and hydrogen in the form of sat, using isopropylamine glyphosate gas with boron and 40 s 3 to obtain the desired composition, and were OTHER surfactants were investigated, as shown below: active substances in potassium glyphosate compositions.

The table below shows the results of the number of tests.

Nonionic surface-active substances of the formula: 0000 SVO in IRA compositions of glyphosate: "Mkhi Gorgov's name Sivba Yeri AKA

Ii ze | SD S Ni (NN SANY cm so ss: SYA YANA S 11-15 7 Ptereyoi 15-5-9 No 11-15 15 | Gegatsoi 15-5-15 iVONA pi nn i i xx ur p WHAT Yes o

GI I NEehSA her ti: nena ryu zknatnnknnnknkn

No 7 YAKE No No No to her Y pa I No No Yes pe 5 INeashog sv S Yak lev 55 Peyuhoi 28-50 NO zho pelu Tr Neva eva 0000000 ak YAKU write she shh write B t soeeeeea yivk ak pu ti te i yivk stok pk

Peoiy SO Agov BOB N, nni "ni sho

TE tozlevti pi uh nn ssh Jak as inny evvne surface-active substances oviSishee ESeri (AH ! composition of IRA glyphosate: s

Auto ROOvO alkyh polyglycozyh os SU Z

Biopopis OMRYAO(REO I'm dinonifenaya! 00000 o o SO SN Vk

Cationic surfactants of the formula: р P form ext

You! (voun in IRA glyphosate compositions: hu Trading nazna ISiyna ShSeri AH - popy POD KAKN MKK koko (8-16) Z Tiyoteso SILO IB her No

Coco 5 TEfotesn S/15 No No No

KOKO Y0 Bfotesp S/20 No KU

Coco 15 |Efotesp.S/25 no No No talo (16-18) 0 Bvote y? 00 NO NI talo Efoshesp 115 S no Ni tlo te TO INI No NO talo popivsp I INI i i talo 15 |Bifotesp T/25 INi B

And stevrinl(18) 50 Ttushesp 6617 no Lako So in the composition of potassium glyphosate: | And : - pnya three koko (8-16) 2 Rfotesp SL iNP y So p-- Ov Myh KN tenet koko vi ESHoteep S/15 No no IN talo (16-18) Attesy TI? her I: So talo 5 Efotesip TL 5 and NP U Yes!

Katidnin surface-active compounds and n ormules! 4 form. Cy-M and in compositions of TRA of glyphosate; Y talo (16-18) Atgshchesp Tini viv

Cationic surface-active compositions. formulas: and SYA, sya, in compositions of IRA glyphosate: Sho ikh Trade name: Yipta P.Seri LA id | NV no NO No koko(8-16) 0 Apteev OMS SHHI no UN

Italo (16-19) Agplpesp TMOYU | no ralo 0000000 neo OMVO A (no I ini shk zh Porgov name: shi ee tva S eri AA talo (16-18) Apyreev OMTO No Yes Yes

Eaponn surface actin Evenings form t sy s n koko (8516) |Aitpeep 20 VoodninI talo (16-15) Atsheep ZT non Yes

Cionic surfactants of the formula: | t sy- h dream

SN

(in IRA glyphosate compositions: in 0,000,000 li ss CH CHO SSZ

Cationic surfactants Formulas: according to ! Se t h Trading knowledge Posivy S eri. coco (8516) 5 NV NO No NO ti talo 20 NV NO Yes Yes

Cationic surface-active substances of the formula: snovok exists in the compositions of IRA glyphosate 0000000 ж0007LЖ 0 TTorgovanazvai 00 Sishe Ser AKA S ia 66 ia PI VO 0000 nni NE sonya lin sn S with vhomnpositions of potassium glyphosate: 14-15 more IV NO Tako Yes 16-18 io on NP Yes Yes 16-18th NE of NP Tyakivko

Cationic surfactants of the formula: PI ! write (water

On

In IRA compositions of glyphosate: ,

OK reno rev trewerk in compositions of potassium glyphosate: m Сх Trade name 0000000 PSima Ser АХ ши НИ Tako yes ii ІВ NVO 00 NO Tako Yes

Cationic surface-active substances van 000000 formulas: Y xx

Ffu---"vOoZh and

In compositions of IRA glyphosate: 7 ru Poroshtshi 3333 ovo rea kATYA hoko(8-16) 2 Efodnachs2 TEY EE coco I НВ вг- 1st coco 5 Vehodivi YEREM No No NO ss NNYA ss SANY SZANIA SVNYA talo 10 "BShodnai 11/20 in potassium glyphosate applications: m tu forgovanatva 00 DS ipia y. Seri AH

Cationic surface-active substances of the formula: Her"

Xh

Sy--(voun s, y compositions of IRA glyphosate: now nn nu Torikh Torgovanezva 00 name Spa | ipzha Ser | eri MA zvlo(16-1)005000ОНВ | NI act talo 30 НВ No no

Cationic dessert NI formulas: i

G h

Sen -- (OUN si in compositions of SHA glyphosate:

Cationic surface-active substances of the formula: article x

He is SV!

St in IRA compositions of glyphosate: sobesu (12) 0 Atooai 050 t vn no

Atdiai T-50 | No, no, M in compositions of potassium tliphosate: no, no, no

Trade name Y S ivita

SCHI talo (16-18) Atatsai 1:50 am Yes Yes

Capone surface-actin substances 00 What are the formulas: сн, СНИ se M снд су in IRA compositions. of glyphosate: shi z SO Torgovanayavya 0000000 ShSivshe Per AKA S. and I ben bo NI ak her 3. |betivi 16-3-10 No o (Pk Z

M 2 Set M NO WE (yes -

In ben MHC NI lac tt Pi oon no z oche Romeo honey vn iAnionic surfactants in IRA compositions of glyphosate: others: still Seri AKA 7 vkftbuffers Dyak olef-th phosphate No No Yes wounds M NO No No its palmitic acid No INo Yes oleic acid 00000000 | yes steranic acid 00000000 nov as caprylic acid Х НИ Ин These sodium alkylbenzene Fulphonate 0000000 No No НИ sodium lauryl sulfate | NO No Yes Phosphated aryl ethoxylate 00000000 --My No Phosphate ether, free acid Phosphated nonylphenyl ethoxylate, free acid other No

Amphoteric surfactants in. compositions of IRA glyphosate

Hespty IN Yes Yes

Meimeehtm VS soso bedve 00000000 ViOONEO SINO

Fluorinated surfactants in the composition of IRA glyphosate: t "Trade name 1 evna AA

Binogadim 135 quaternary ammonium iodide n

ESHogay"M 754 quaternary ammonium chlorides NO NO NO

Battle with BS15 with fluorinated and 88 alkyl carboxylate and

Rimgovatm ESI21 ammonium perfluoroaluct sulfonase Yes No INi

Eochuei RI. 80 perfluorinated phosphinic/phosphonic acid

Surface-active mixtures of RA SIvna SHSeri KA compositions

Netyuhoi SAZ/LvVOoteev G/25

ZT 8302/Btodnai 1725 no No

ZT ZOZ Frodnai 1725 Ii

Akovigii 66 E2O/LEVOotevp T/25 Yes

Neiyukhoi SVZOLEVOotest 1/20 Yes Yes

Neiohoi School/EVOtevn T/25 Takh

Neyuhoi SVO0/Vogtest T/30 Yes

Neyohoi SOZ0LESHOotesya T/40 0

Neyuhoi SYAZO- Agatsai S-30 | WE

Neyuho!yi E525 EN Otesy 125 Yes Yes Yes

Neukhoi SBIZ EfShoshesy 12500000 Yes

Neokhoi C520 i Efoshtesp 120 Yes "Yes Yes

NeyuhoiC525 Biotest 20 0000000 Taco Yes

Neyuhoi SVI5 Clauryl choline chloride

You 78-- Efothesp 120 Yes Yes Yes

BA Vfodiai 56 Ta kola

You 78-- Bipodvad 125 Yes Yes Yes

Meodoi 1-9.irotest T/25 NO

IArgittsi RO 2069/1 vote T/25 No

Regvyoi 15-85 9 Voshevy 13500000 in "Tegeoyi 15-5-12/Byotevv T/25 "Rgosoi TA 10 Kvodnai 125 V S "Rgoso! BA 12 1 EShodtsad 125 NI NO. No

Neyuhoi C520 I RES 7? dimethyl ammonium chloride Yes

Neyuho! С820- РЕС 22 dimethyl ammonium chloride

Riigagas AZV i Biyodoaya 125 Yes (Riagayas AZV I TIVoyuesp 120 Yes

Rishgataye AZ8 and Bibodnad 120

Neyuhoi C520-2 betivi 10-2-10 "Neyuhoi C520 i Ostipi 10-3-10 NI Tako

Neyuhoi C5 20 kOetipi 10-4-10 "Neiohoi C8 20 "Oetipi 14-2-14 vi odnin mon Ou

Ineyuho! C5 20 "Set! 14-3-14 IN us Yes

Caprylic acid t Bioshesp 125. No

Capric acid and EpPoteep 725 But NP No: !

Lauric acids Biotesp 125 t 7 she 06020626 6 6 2 14110 | shi

"Myristic acid is Gotest T25 NO NO No

Palmitic acids Biotesya 125 Yes (Oleic acid Bioteep 125 No

Lecithin I Efoteep 125 N No ITak

Lecithin I Binodnai 125. Nv ac

Lecithin and Btposnai t20

Eichozhes RE KO i- Efotesep 125 No no V I

Bitotaya Sto Tetu VV

Eshodnai T12 I Tegoyoi 15-8-7 No no |V

Bfodnai SI in Tegvnoi 15-5-9 | No No GI

BshShodiai TI2 kTegvnoi 15-89 00

Bfodiai CI2 in Tagaytay! 15-8-12 00000000 IN IT

Bshodnad IZ Sk Tegvnoi 13541300 No OO

Eibodshki SI 2 Tegryoi 115-85-15 What not

ESHPodnad SI2 in Atoplig 06 ETO NI No No

Surface-active mixtures and compositions of Steve's potassium (ShSeri IA tliphosate: ШЙ

Efodiaa C12 in Tegetsoi 15-5-7 Yes

Epodtspai TI2 in Tegvia 15-8-7 NI Yes

Efosdpai 12 5 TetvyoYi 15-59 NP Tako So

Biodnach 15 i Te 135 BUT as tank Z

Bfodchai SI? KTegeyoi15-8-420000000, BUT SHSZ Yes

Bod pai 112 Tetroi I NEO0 Tak Tako

Efodnai C12 E Tegrnoi 15-85-15 NI Yes

Pyodednya T12 i Testovy 5-8-15 NP Yes Yes

Byodvai SIYA KAgovyibo VIJ NI sis

Efodnai TZ Senya OO TE

Su is an alkyl group containing m carbon atoms

X stands for the porous anion

EO stands for ethylene oxide

AA is an anisotropic aggregate

And C ipiga means intracuticular liquid crystal

I C eri means epicuticular liquid crystal

NA means that the study was not conducted

NB means that it does not correspond (ie, it does not have a trade name)

A particularly preferred herbicide is herbicides, in order to determine the effective proportion of mMephosphonomethylglycine (glyphosate), its salt, adduct, the amount applied is often used, or an ester, or a compound that converts per unit area, obtaining 8595 control into glyphosate in plant tissue or by some other plant species, which is measured by the reduced form of glyphosate ion. Glyphosate salts, which inhibit growth or kill. can be used in accordance with this invention. The effectiveness of the herbicide is one of the biological findings given in US patent No. 4,405,531|, which effects that can be improved thanks to the given here as a reference. Glyphosate salts of the above invention. The term "herbicide efficacy" includes alkali metals, halogens, as used herein, any degree of organic amines or ammonium, and includes, but not the observed control, growth ros- limited, the following salts: salts of mono -, di- and tri-lin, which may include one or more alkali metals: potassium, lithium and sodium; alkaline salts (1) destroy, (2) inhibit the growth of ground metals: calcium, barium and magnesium; salt bearing or proliferation, and (3) absence, liqui- of other metals, including copper, manganese, nickel dation or other reduction of plant growth and their active- and zinc; salts of mono-, di- and tri-halogens: fluorine, sodium. chlorine, bromine and iodine; salts of monoammonium, alkyl and phe- The given effectiveness of the herbicide, formulated nilamonium, including mono-, di- and tri-forms, here, represents "inhibition" as a percentage of od- containing ammonium, methylammonium, ethylammonium, burned at carrying out standard methods in dipylammonium, butylammonium and aniline. Alkylamine salts, in that region, which reflect a visual assessment of let- including mono-, di- and tri-forms containing plant metallicity and reduced growth in tylamine, ethylamine, propylamine, butylamine, methyl- compared with untreated plants, which about - butylamine, stearylamine and talloamine; alkenyl salts - administered by specialists specially trained for mines, based on ethylene, propylene or butylene; conducting such observations and recording them. In all cyclic organic amine salts, including pyridine, cases, one expert conducts all evaluations of piperidine, morpholone, pyrrolidone, and picolene; salts of percent inhibition within any experi- alkylsulfonium: methylsulfonium, ethylsulfonium, ment or test. Such measurements are dospropylsulfonium and butylsulfonium; other salts, in commercial and regularly reported Mopzapio, including sulfoxonium, methoxymethylamine and Sotrap in the course of evaluation of herbicides. phenoxyethylamine. Preferred salts of glyphosate include the selection of applicable proportions that are biologically potassium salts (multi-, di-, and tri-forms), effective for certain exogenous chemicals, sodium (mono-, di-, and tri-forms), ammonium salts, which are carried out within the framework of normal research on methylammonium, isopropylammonium, and monoethanolamine and are conducted in the field of agriculture. Any trimethylsulfonium. which specialist in this area will find it easy to recognize

Since commercially knowledgeable herbicides such conditions for certain plants, weather conditions and derivatives of M-phosphonomethylglycine are its growth conditions, as well as specific exogenous defined salts, glyphosate compositions, effective in given chemicals and their selected compositions, which will be able to epheme invention, will be described in more detail, which can be achieved during the practical use of these salts. These salts are well known and are included in the present invention. The effective proportion of ammonium salts, IRA, alkali metal salts (such as those used for exogenous chemicals, monopotassium, dipotassium, and tripotassium salts) and trimethylsulphate salts can be obtained from all the above-mentioned conditions. As for the phonium. Salts of M-phosphonomethylglycine are the commercial use of the method according to the present invention for significant in part because of their solubility in water. glyphosate herbicide, enough information is known

The salts listed above are well soluble in the appropriate ratios used, thus achieving a high concentration. Glyphosate is used for more than two decades of solutions that can be diluted before seven years, and published studies regarding its use. According to the method according to the given wine-use, sufficient information has been provided, with which course, with regard to the glyphosate herbicide, the aquatic person engaged in the destruction of weeds can solutions containing a herbicide-effective amount- choose the proportion of glyphosate to be used, the amount of glyphosate and other components, according to which would be herbicidally effective for a particular given invention are applied to the leaves of plants. For example, at certain stages of growth, under certain conditions, an aqueous solution can be obtained under different conditions. by applying a concentrated solution of glyphosate salt Herbicidal compositions of glyphosate or its derivatives, dissolving or dispersing in water are effective for controlling a large amount of dry (i.e., granulated, in the form of powder, widespread plants. Such compositions mo- tablets or briquettes) compositions of glyphosate. should be applied to the plant in a herbicide

External chemicals can be applied in an effective amount, and they can effectively control the plant in a proportion sufficient to produce one or more plant species from one harvested biological effect. These proportions, which use one or more of the following genera without exception: are listed, are usually expressed as the amount of AryiShop, Atagapipyv, ApPetivia, Ausieriaz, Amepa, external chemicals per unit of area that is processed. for example, gram per hectare (g/ha). "Desired effect" may vary depending on the chemical, development, standards and practical use of the research market and use of certain class of exogenous chemicals - Irotoea, Kospia, I oisht, Mama, Ogula, OiKospis. For example, in the case of Rapisit, Ravgraisht, Rpayagiv, RPgadtiyev,

Roiudopyt, Rogpshasa, Riegdisht, Riegapya, Nybriv, to be used for any of the above-mentioned zaivoia, Zeiapya, bida, bipari5, Zogopyt, Tiysit, species.

Turpa, Shekh, Hapipisht and 7ea. Efficiency in greenhouse tests,

Especially important species for which can be usually at low proportions of exogenous chem- applicable compositions of glyphosate, given below than those used in the field, is a proof example, but not limited to them: a given indicator of the stability of the action of work in the field

Annual broad-leaved trees: in the usual proportions used. Theophrastus rope plant (Arysop of Ipeorpgavia) However, even the most promising composition of amaranth (Atagapipi5 5yr.) sometimes fails to show an increase in action in separate sycamore tree (Vogtegia 5yr.) experiments in the greenhouse. As shown in the examples of gare, sania, Indian mustard, and so on in the manner given here, the nature of the increase (Vgazvisa s.r.) occurs during a series of experiments conducted sotteiipa (Sotteinpa 5yr.) in the greenhouse; when this character is determined, then

Nagee (Egodiyut spp.) this is unconditional proof of biological improvement of sunflower (Neyiapipyv 5 spp.), which will be useful in this area. birch (Irotoea 5yr.) Compositions according to this invention can be sown on plants by spraying, using mallow (Mayima 5yr.) any usual methods for spraying liquid, buckwheat, mustard and the like (Roiudopyt 5yr.) ) such as spray nozzles, sprinklers or purslane (Rogishasa 5yr.) and the like. Compositions according to this invention cornflower (Zaizoyia 5yr.) can be used in technologies that are used (5ida 5yr.) in agriculture, in which mustard mustard (Zipari5 agmepviv) is used to apply various netreb (Khapipicht 5yr. .) quantities of exogenous chemicals for different areas

Annual narrow-leaved plants: fields, depending on conditions, such as a certain type of oleander (Amepa Taisha) growing plant, soil and the like. Axonoggus compressed (AchoNiriz 5yr.), one of the embodiments of such technologies, can use a general positioning system, that a blood glove (Oidkagia 5yr.) is used with a sprayer, for applying flat (Espinispioa sgiz- daii) of the desired amount of composition to different parts of the field. plantain (Eiisipe ipais) The composition when applied to plants, one-year-old fenugreek (I oishisht tiykTogyt) is usually sufficiently diluted for light naneris (Ogula zayima) haying, using standard village spoo- tokhloya (Onospioa nidosa) dar devices for spraying. Preferred buckwheat (Razraisht Nigasht) proportions for application according to this invention canary grass canary grass (RPaiagi5 5yr.) vary depending on a number of factors, in foxtail (Zeiagia 5yr.), including mud and the concentration of the active component (Tgyisut aeviimit) and the type of plant being processed. Effective corn (7ea tauz) quantities for applying the water composition spray- perennial broadleaf: ling on a growing field can range from common wormwood (Agpetivia 5yr.) from about 25 to about 1,000 liters per hectare (l/ha). cottonwood (Azsieriaz spp.) Predominant quantities for the use of water comb- field cottonwood (Sigvisht agmepze) positions are in the area from about 50 to slanka birch (Sopmo|mshi5 agmepviv) about ZbOl/ha. Hairy Nuearia (Riegagia 5yr.) To obtain the desired biological (i.e.,

Perennial narrow-leaved: the herbicidal) effect of the living tissues of the brachiaria plant (Vgaspiagia spp.) should be absorbed and distributed throughout the plant Bermuda grass (SuNidop dasiuop) a large number of exogenous chemicals (including ground almond (Suregy5 ezsshepyv) herbicides with glyphosate). Thus, it is important to use herbicide compositions so that they do not excessively damage certain tissues of the plant and lalang (Itregaia suiipagisa) and thus do not reduce the distribution of the herbicide on the perennial fenugreek ) plant. However, some limited extent of local chicken millet (Rapisit tahitit) damage in its effect may be insignificant, paspalum expanded (RazraYisht ayagayusht) or even beneficial, for the biological effectiveness of reeds (Rpgadtiyev 5yr.) of some exogenous chemicals. johnson's grass (Zogdpyt PpaIerepze) A large amount of the composition of this invention of ryegrass (Turpa 5yr.) is given as an example in the following further examples.

Other perennials: A large number of concentrates of glyphosate compositions - horsetail (Edpizhest 5yr.) have sufficient herbicidal efficiency, poka- fern-eagle (Riegidicht adiyipit) in experiments conducted in orange-blackberry (Kibiv 5yr.) fields, and confirmed in experiments in the field, a wide variety of weed species at different

Thus, the method according to the present invention, which conditions of application. belongs to the glyphosate herbicide, it can be exogenous chemical, such as potassium Mopzapio Sotrapu with the trade name glyphosate salt, as additional excipients to the listed ingredients. The amount of exogenous chemical was VOSHMOIR OGSTKAMAKHF. selected in such a way as to obtain the desired number of Composition 360: which contains 4195 by weight of IRA in grams per hectare (g/ha), when applying glyphosate salt in an aqueous solution together with dusting, a volume of 93 l/ Ha. Each composition is enriched with a neo-active substance. This composition was sold with several ratios of exogenous Mopzapio Sotrapa with the trade name of chemicals. Thus, unless otherwise stated, the OSTKAF CHAMBER when the spray compositions were studied, Composition 280: which contains 480g c.e./l of IRA salt, the concentration of the exogenous chemical differed from glyphosate in an aqueous solution together with 120g/l etok- in direct proportion to the ratio of exogenous silified etheramine surface-active chemical, but the concentration of excipients support (M121). was constant at different ratios of exo- Composition 560: which contains 540 g.e.u./l of potassium gene chemicals. glyphosate salts in a solution together with 135 g/l ethoxyl

The concentrate of the composition was studied by diluting etheramine of the surface-active substance by pouring, dissolving or dispersing it in water with (M121). formation of a composition for spraying. In these Composition 553: which contains ZboOg c.e.u./l IRA salt compositions for spraying, obtained from concentrated glyphosate in solution together with 111 g/l ethoxylated nitrates, the concentration of excipients varied in the quaternary surfactant, depending on the change exogenous chemical. based on thalamine with 25EO, 74g/l polyoxyet-

In the following examples, presented for 10EO of cetyl ether and 12 g/l of myristyl dime- illustration of this invention, tests in orantylamine oxide. zeres and in the field were carried out in order to evaluate the Composition 318: which contains 487g c.e./l of potassium relative herbicidal efficiency of compositions of glysol glirosate in aqueous solution together with b5g/l of phosate. Compositions for comparative purposes include (2PO) (9EO) alkylated alcohol, 97g/l, contain the following: ethoxylated (10EO) thalamine and 85g/l n-

Composition 139: which contains 570 g/l IRA salt with octylamine. of glyphosate in an aqueous solution without adding pove- Composition 765: which contains 472g k.e./l of potassium rhnevo-active substance. of glyphosate salts in an aqueous solution together with 117g/l

Composition 554: which contains 725 g/l potassium cocamine 5EO, 52g/l isosteaaryl 10EO and 13g/l glirosate salt in an aqueous solution without the addition of cocoamine. surfactant. In the compositions of these examples, use

Composition 754: which contains 4195 by weight of IRA were private excipients. they can be identified as glyphosate salts in an aqueous solution together with a non-active substance. This composition sold

Link | Gorgova Manufacturer Chemical description name 18162 1816B15ВА 10000000 КС16-1 ДО(СНОСНООИ (СН2ИЗМНО

ABE10 Agtozshibb |Myso Ethoxylated branched alkyl

E-10 10BO

AOMei OE 68(89)

АРОб7 АРО 2067 Alkyl polyglycoside C8-10 alkyl group 1 1,7-glucose groups

АРобО АРО 2069 Alkyl polyglycoside C8-10 alkyl group and 1,6-glucose g

AKA1 Agro NE- | Miso C4EOZ phosphoric acid 6bvA1

AKMS Agteep S Mixture of C8-16 (coco)alkyl primary amine

AKObb Agozshii6bb | Miso REO-20 isostearyl ether

E10

AKO27 Agdchai T-2795 solution of thalotrimethylammonium 27 chloride

AKOZ37 Atachay Coco trimethylammonium chloride (370 in 1237 water)

AKO5O Agdpay S-50

VIA 8-2050-01A Ethoxylated C16-18 linear alcohol 9.4 g viv 8-2050-018 Alkyloxylated C1b-18 linear -. alcohol 9.4 BO -2.2 RO vis B-2050-01С Alkyloxylated C16-18 linear alcohol 9.4 BO 4-42 RO

OM own alcohol 9.6 EO 4-44 RO

INVYZ5 Visa | Btoxylated (23BO) lauryl ether

VKIZHE (Vpihb6 | 0 | Polyoxyethylene(1OBO) cetyl ether

VK158 | Vpiy58 | 0 | Polyoxyethylene(2OBO) cetyl ether

MON SL WE eFFir

SETAS 77777771, 711111 ICethyltrimethylammonium chloride.b7/--Z,

BA175 | //// Totavo BOyefiramn./://С:/ИН9

ERI75 | 000.

T/25 ammonium chloride m a coco 15 BO benzyl quaternary

And the age of 00 Renault

In t u 00 n ation (about quaternary bo a J ionni 5850-8688 '

SEM2 Sepatype SIagiapi Monoethoxylated alkylamine

BY Sn ss 01/37-2

SEM5 Sepatype SIagiapi Monoethoxylated alkylamine

AI dreams dreams 01/37-3 '

T200MEAD IN SIVMMeVO)ZN 01/37-4 I bai LISH x

C8520

RE 8000 (SIZO(ССНСН»)РО(ОН» eFIUD

ЦЕ700 Ришпгаиас VABE Alkoxylated C16-C18 alkyl,

PASS by

MI17 MO Mm59117 | |Btoxylated ephyramines/ /-/-://

MI21 MOM 58121

ACM550

МИ128 МОМ78128 Composition with 480 g c.e./l monoethanolamine glyphosate 1 120 g/М121

Mb MOM tek Composinia 3357 g cap IRA glyphosate with і і і ші shk IBTPLEMOT. Я5 giletoyyvylovnya 10111111 100BO) thaloaminі57t/lnoctylamine.

Мо619 МОМО68619 Composition with 360 g c.e./l IRA glyphosate with 70 g/l ETH2»5, 46 g/l VKI56 and 23 g/l

SETAS

Мо20 МОМ68620 Composition with 360 g c.e./l IRA of glyphosate from ЕЕНЕЕсНТя tek

SETAS

MREOI | MREAB | 0 BOsefiramn.//:///СССС:/ poiniDSHYNY --- aisvNNY suspenoid and 9 EO

OA | 11111110 dBimka, 0 |Octylamine//:/ ////::6СССС:(Lo/C((C dimethyl amine

БЙ ННЯ ННЯ зий propyl-1-amine и 1 poshko na(ethylene oxide)-dimethylamine

M nan di(propylene oxide) nona(ethylene oxide) dib tylamine

MD nn di(propylene oxide)nona(ethylene oxide)-3'- aminopropylamine 71117717 bbonyyuyuenie di(propylene oxide)nona(ethylene oxide)-M- methylglucamine

ND nn penta(propylene oxide)eicose(ethyleneoxy d)-dimethylamine

NI I I I texa(styrene oxide)tri(propylene oxide)dimethylamine 509 1777777111101711111101011 (M-omethyloctadecylaminoglycitol/7//-

Y nn eicose (ethylene oxide) dimethylamine 851 77777771 | Hexadecyl-eicose (styrene oxide) tris:/

LIN NYNNSHY-y eicose (ethylene oxide) methylamine and Hexadecyl-deca (ethylene oxide)-M-methyl- glucamine 814 ІІ 77777717 PPodeoxy-I-(octadecylamino)-O-glycitol

SALIVA NN POLON ss NI nona(ethylene oxide)-M-methyl-glucamine schiv Ie 001 IMedodetsiyaglyukamiyi I

I 0111 Mmepeonzhtapecilamintlyucitoh at 518 | M, Medichetiloctadetsny shecytoya nn sn-Koramino ethno skin

519 77171711 Btoxylated cetyl alcohol//-/-- 52077770 Momethyldodecylaminoglucitol/7/-/-/- and pen chloramino Thursday. m a 10 EO isotridecyl phosphate ether (6095 monoester) 8523. | 777777771017111117111110 dnshexyllucamine7/:/// 54777311 |ndodecyllucamine

LI PI NN iii chloride)

LI PNYA PNYA 5 ai chloride)

ONLY iy chloride) 542 | 77771711 Mu Moctylglucitolide-propane.7/- 543. 77777777 17171711 Mu MododecylglucitolideZ-propane.//- 544 77777771 |M.Mohexylglucitolide-propane.//- 545 | M, M'-dioctyl-1,3-diaminopropane

GO shine 11 veins eicose(ethylene oxide) 1 deca(styrene oxide) 110000 syu octadeca(ethylene oxide) 5-31 nn deca(ethylene oxide) 51221 donya eicose(styrene oxide) 551... ..ЮЮЙБНЩЮЮЮЮ Г7171И1ИЕ0 |Dodecyltetra(styrene oxide)dtris./:- OO

LY PN THEY sx: CH dodecylaminomethane 511 shen dimethylamine 17771770 nen deca(ethylene oxide)dimethylamine

BY PONY IN Ammonium chloride

BANNI NYNNA NNYA Khaniv ammonium chloride

MAMI PI POLON B Y rimethyl ammonium chloride 55877771 |Monostoxylated alkylamine./- 10111117 sivmMmesdvotno/:///|НС яр тн

C18MMe(VOLIN 86071771, |Momethyldodecylaminogluditol/7/-/- 86177177 |Btoxylated cetyl alcohol (10BO)) 56277701 hexadecyl-decaethylene oxide)-tris:/- 56577777 77717171 |Octylaminogluditol/7/:/:/ 2 methylamine ports

568 Hexadecyl-eicose(ethylene oxide) methylamine fr rn deca(ethylene oxide)propylenediammonium chloride sr nnnnia eicose(ethylene oxide)propylenediammonium chloride -i-- nene propanediol-penta(ethylene oxide)

I propanediol-deca(ethylene oxide) 511 nn propanediol-penta(ethylene oxide) i 177177 sho ropandiol-deca(ethylene oxide) di(propylene oxide)nona(ethylene oxide)-dimethylamine 578 I-hydroxy-3-(M-methyl-ene penta(ethylene oxide)

VYMY NO PI a octadecylamino)propan-2-ol- nonone (ethylene oxide) 11 dodecylamino)propan-2-ol-penta (styrene oxide)

BOSH PI SHY they are deca(ethylene oxide) hydroxyethyleneamine

MI I Hexadecyl-deca(ethylene oxide)-2-methylamineethylene-M-methylamine mice: AI dimethylaminoethylene-M-methylamine

Pl PINNY TIRES neck 2-hydroxypropylamine 585 | .Ю.ЮюЮЙЭ 1 (Ethoxylated methylstearylamine 7//- shcha Y Y S Tetokenlyated methyltearylamine 7 1000 Ethoxylated methylteyrylamine PO,

KV. 7 tsnsyuyu write 5EO Y | a MO ICHES BMe» What What 0 etM sleep Me!) |) and E dimethylamine what you o Gazheicosaethyleneoxylidimethylamine 5OZ Talonin nka tent WHO B(eTy leno KoVdnymethylamine that | Thialo-eikosdietivenokovno vno 10000000 Thalo-pentacosoatelyenokop iris; chav Shch 00000 Idecaystylenoxyiaiexidetsnia -m, M

And dimethylamine

00011 dimethylamine 11 rshshennnk methyldodecylamine su i PO Bis-(cocaamino)-eicose (ethylene oxide)

KT pon propanediolpentadeca (ethylene oxide) 11 Enn propanedioltrieicose (ethylene oxide) bo NNYA PNYA nn propanediolheptaeicose (ethylene oxide) day propanedioltrieicose ethylene oxide) 10000 Breeds of propanediol triaconta (ethylene oxide) 1112-10 5IZHI? 5SHTOPIS Nipiztai Sio-» alcohol ethoxylate 12 EO noise (My be dOMm-50 112-6

TrA-9

Т003А В-1910-03А| aloamni YUBO -:/ SY

Т003В В-1910-038 00 TaloaminkI15BOdГ/Г/(/ оо3с |В-1910-032| (Talodamn20BOd -/-::/ too3o |В-1910-033| fHaloamino5VOd /-/:/ 19 toozE |В-1910- 036| | Haloamine 30BO -/-::/ ( 12352 T23E1RAV2 (Totai Efiramine with Si". with linear alcohol suspenoid with 1 EO and 2 EO on amine Si". khnuta

T23E5 T23E1RAV»5 | Totar Efiramine with C.12". 1 with linear alcohol suspenoid with 1 EO and 5 EO on amine Si".

ШИ песнистоснисниеожко х-у-5 chlorine 12 хунку че лЕ0рнеоейнеянн 155-9 alcohol

ТРАОЕ ОРА-40О0Е | Totai Polyethylene glycol 400 transformed into a break in the morning

Ministry of Emergency Situations O(SSNNO SN») МН»)

TRAEB MORA-14-|Totai Hexamethylenediol was converted into

Eb symmetrical diephyramine and bEO) 7014 O014-M3 Totav Trimethylisodecyloxypropylamine

SHY 111 chloride (quaternary etheramine)

Totan Trimethylisotridecyloxypropylamine chloride (quaternary)

MAKO2 Ouagopis K- Miso Ethoxylated Cocoamine 2EO 202

MAKOB Magopis K- | Miso Ethoxylated cocosmin ZEO 205

Miiso M-dedecyoxypropyl-1,3-diaminopropane

VI1910-5 3.4 g

MEHb Ehregitepa| | with M-dedecyoxypropyl-1,3-diaminopropane

In 1910-6 6.1 g

МЖЭХ7 Ehregity | ZhMyso M-dedecyoxypropyl-1,3-diaminopropane

VI910-7 9.5 EO

M1T05 Myisatipe | Myiso Ethoxylated thalamine 10 BO

THERE 105 J

У1Т305 Mysatipe GMyso Cocoamine 5 EO

THERE 305 .

MITvo Miisatipe Ethoxylated talamine 6 BO

THERE 60

MIT80 UMisatipe GMiiso Ethoxylated talamine 8 BO

THERE 80

Unless otherwise specified, the aqueous compositions for the application of the glyphosate composition were prepared by mixing the surface by spraying with a suitable sprayer with an active agent with the appropriate amount of 9501 E, calibrated to spray the volume of potassium glyphosate, which was added as 47.5905 (vol./06.) 93 liters per hectare (l/ha) at a pressure of 165 kilopascals. solution The composition was placed in water (aPa). After treatment, the pots were returned to the baking bath at 557°C to 60°C for approximately 30 hours before being evaluated. minutes to obtain a transparent homogeneous solution. The processing was carried out using a dilution. In some compositions, a surface-active and aqueous composition. It can be prepared by heating the substance before mixing. as a composition for spraying directly from

Unless otherwise specified, the following procedure of ingredients, or dilution with water was previously used to determine the herbicidal composition of the resulting concentrate. efficiency of the compositions of the examples that are being studied. To assess the herbicidal efficiency, all grow. lines in the experiment were evaluated using

A family of plants of the selected species was planted in 8 mm by a single specialist who recorded the percentage of counter-flowering peas in the mixed soil, which was prepared, visual measurements of the efficiency of each of the sites were sterilized and fertilized with 14-14-14 MRK, treated plants compared to untreated ones slowly releasing fertilizer in the amount of 3.bkg/m3. plants Control 095 showed no

The pot was installed in a greenhouse with an irrigation effect, and control 10095 showed that all plants are on top. About a week after the appearance, we were completely destroyed. The reported values of seedling seedlings were thinned if necessary, in the control represent the average value for including removed all unhealthy or abnormal- all repetitions of each treated sample. plants to create the same series of test plants. Aqueous concentrates of compositions containing salt

Plants were grown to a certain tested do- glyphosate and excipients, received as shown in blackberries in a greenhouse, where they received light as tables and. minimum 14 hours a day. If natural light was not sufficient to meet the daily requirement, artificial light with an intensity of about 475 micro-Einsteins was produced and used to make up the difference. Exposure temperature was not controlled

ZO within days Approximately 1 against points, and

Plants were irrigated from above during the experiment in order to ensure an adequate level of soil moisture. ЩШ1. 1

The pots were processed in different ways in a completely out- |73z4s9m| Kk |30| 521 |100Ї (МЖДФБ | same random experimental model with b repetitions. A group of pots was left without the specified treatment. mag. istepiae ESNSE) were grown and processed according to the standard methods described above.

The compositions of Table 1a and comparative compositions 139, 553 and 360 were used. The results, averaged for all repetitions of each processed sample, are shown in Table 16 and Table 1c. AVITN 5 control

They tabulate GOvy | 0 1 83 | 47 | 558

AVITN 96 control 736010 1 583 | 87 | 867 tZVAYU | 0 | 25 | 525 | 617 39 | 0 1 625 | 758 | v8ov | | 76875 0 | 45 | 658 | 42 vBa | 642 | 850 | 858 | 900 | | 73605M| 0 | 58 | 508 | 642 tzadyaM 0 | 608 | 775 | 842 | MB 0 | 325 | 667 | 758

Stzavzak | 0 1 833 | 808 | 833 | | YARA | 0 | cha | 683 | 7/75 zok | 0 | 425 | 70 1 783

Table 2p

ESNOE 96 control

Gov's table 0 1 83 | 183 | 392

ESNOE 95 control 139 10 | 408 | 458 | 625 | 0736875 0 | 583 | 675 ДЮжЧКкМ о т3бсовв | 0 | 53 | 667 | 758 7z36o5M | 0 | 267 | 5353 | 675

TZARUA | 833 | 483 | 558 | 70

GZK | 0 1 283 | 625 | 683

Results for AVITN and ESNSRE: all compositions showed lower herbicidal efficiency relative to comparative compositions 360 and 553 on AVOTN and ESNSRE.

Results for AVIOTN and ESNSRE: compositions Example C 734P2H and 734069UU showed the same herbicidal Aqueous concentrates of compositions containing salt efficiency relative to the comparative composition of 360 glyphosate and excipients, obtained as shown in Theophrastus rope (AVIOTN). tables For.

Example 2

Aqueous concentrates of compositions containing salt Table For glyphosate and excipients, obtained as shown in the table | B64ABA | KO|BAO| Mi21 Sh13502| B |.

IA; Component Component by | kzoi 00101011. 1 822 forehead 1 SG zvo | kaz, 86 11410000 1000 1 SGS 7zaveA | K 1301 509 1100, 55 Sh1 1

And 734aZ3K | Kk |30| 518 |100 HER | Plants of Theophrastus rope plant (Abishop

Ieorpgavia, AVIOTN) and flatfish (Espinispioa sgyv5-

Plants of Theophrastus rope plant (Archyop daiii, mag. yishtepiae ESNSRE) were grown and processed

Ipeorpgavia, AVOTN) and flat-leaved (Espinispioa) were grown by the standard methods described above. daii, mag. tatepiae ESNSE) were grown and processed. The compositions of Table 1 were used and compared by the standard methods described above. compositions 139, 554, 754 and 360. Results,

The compositions of Table 2a were used and the averages for all repetitions of each treated flax composition 554, 553, and 360 were compared. The results, sample averages, are shown in Tables Zb and Zs. for all replicates of each processed sample, shown in Table 25 and 2c.

Table ZB

AVOTN 5 control | 92 | 300 | 475 | 600

Table 4p

ESNSE 95 control /b88O3E | 26.7 | 367 | 600 | 683 554 | 0 | 0 | 192 | 283

Table Zs

ESNOE 95 control 7860 | 792 1 900 | 992 1 992 | Example 5

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in the table below. about b88E2M | 600 | 808 | 962 | 933 | Table by city: onto onto

Comtoye salt) pl | Comte | dl |KOMto position nent 1 ent2

Example 4 with ! !

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in (734039 | К | 30 | 100! | /

Table 4a and 7z4azn| Kk | from | led |t100

Plants of Theophrastus rope plant (AVIOTN) and ploskuhu (ESNSE) were grown and processed according to the standard compositions of table 5a and comparative compositions p7aBrivkh, Kk ia31031170177 819114 139, 360 and 553. The results, average for all replicates

G7zavlon| Кк 143 816 1141 юю Ю Щ ШЧD M 1 1 riv of each processed sample, shown in table 737С1ЗА| Kk |43| 817 |14|! |! | zo and 5o. 737068 | K | 30 | 588

Table 55

Plants of Theophrastus rope plant (AVITN) and ploskuha (ESNSE) were grown and processed by the standard AVyTN with control methods described above. The compositions of Table 4 and comparative compositions 139 were used 0 1 62501 758 | 808 554, 553 and 360. The results averaged for all repetitions of each processed sample are shown in the table (553 | 642 | 85.0 | 858 | 900 4р and 4. 734А9О | 0 | 608 | 775 | 842 73487у | 0 | 633 | 808 | 833

Table 45

AVOTN 5 control 554 | 0 | 713.3 | 308 | 583

Table 5p

Table 65

ESNSE 95 control

AVIiITN 95 control 139, | 0 | 408 | 458 | 625 (554 | 0 | 125 | 267 | 600 754 | 0 | 767 | 858 | 908 (627092 | 0 | 217 | 525 | 817

Results for AVITN and ESNSE: compositions 7АЗЕ8О and 743053Н showed similar herbicidal efficiency for AVITN relative to the comparative composition 360. Table bs

Example 6

Aqueous concentrates of compositions containing ESNeE salt with glyphosate control and excipients were obtained as shown in table va. 54 | 0 | 0 | 33 | 42 754 | 0 | 667 | 708 | 775

Table ba - - all 117731 8001 65717427 627/3K | to | z0 | 547 | 100 -BLYAVM ko 1230 100ВА8 01000

And batNnaH | to | 30 | 549 | 10.0

HovalzE | to | from | in | 100 | Results for AVOTN and ESNSRE: compositions and 62704UM and 627I3E showed similar herbicidal activity

Plants of Theofrastus rope plant (AVOTN) Its surface efficiency relative to the comparative composition of the kuchu (ESNSE) were grown and processed by standard 75A methods described above. Applying - Example 7 the entire confusion of the table ba | comparative compositions Aqueous concentrates of compositions containing salt. of glyphosate and excipients, obtained as shown in the table of each processed sample, shown in table 7a 6p and bs. AND

Table 7a 360 | IRA | 360 | (::YKYSSS HER 7777/7ї1777717777777111171111111171Г1111111111111g1 754 | IRA | 445 | tAmMlO5 | 509 | иimto | 224 554 | KO 725 | ГГ

Theophrastus rope plants (AVITN) and plos- 554, 754 and 360. The results, the average for all povtokuhu (ESNSE) were grown and processed standards of each processed sample, are shown in the table by the methods described above. The compositions of table 7a and comparative compositions were applied

Table 75 and 72g1AZK | Kk |301 | | vnoto | 10.0 (72givz3m| Kk |30| | | imtoo | t00

AVITN 95 control

Plants of Theophrastus rope plant (AVITN) and ploskukha (ESNSE) were grown and processed according to standard 7754 | 830 | were the compositions of the plates and the comparative compositions 553, 139 and 360. The results, average for all repetitions of each processed sample, are shown in Table 8p and all.

Table 85

AVOTN ze control for 101 3081 Ya va

Table To

ESNSE 95 control 7360 | 850 | 970 | 996 | 998 | / 721E2M | l25 | 567 | 80 | 883 uva | 830 | 950 | 998 | 990 leva 906 | 974 | 980 1 996 | 172183 0 | 283 | 583 | 80 (450070 | 830 | 912 | 966 | 984- (450042 | 850 | 940 | 990 | 992 | Table vs 451EbN | 89.0 | 890 | 958 | 99.6

Composition) 75 g of patches in /ha (2oB; k.e./ha | 300Og k.e./ha

Composition 75g c.e./ha 150g c.e./ha|225g c.e./ha| ZOOg k. e./ha -539 1 0 | 58 vav | 675

Results for AVITN and ESNSRE: all compositions of this example had lower efficiency than standards 754 and 360.

Example 8 and ! ! | 721E2M | 66.7 | 80 | 923 | 998

Aqueous concentrates of COMPOSITIONS CONTAINING GLYPHOSATE SALT and excipients were obtained as shown in Table va. | 72giv3mM | 0 | 608 | 75.8 | 733

Table Ba Results for AVITN and ESNSE:

Results for AVITN and ESNSRE: all compositions of this example were not as effective as the obo standard. An example from the city

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table a.

And 721E2M| K |z30| 551 |100Yi 72g1R5s| Kk |z30| 552 | 100Y

Table 9a 62260 | CC | 480 | could! | 1600 | /! HER Her 5603 | KO 1 540 | mi2i | 1350 | Y....K,.:G/ HER S / E!77777771771717171Г2 23984. | CC | 480 | could! | 1200 | /! Her her 76798 | CC | 510 | i816E | 50 | AUCOS | 15 7678M | CC | 510 | 1816E | 50 | AVKOZ7 | 15,360 | IRA | from 60 | / HER 9 1 HER 754 | IRA | 45 | / / g GG her (554 | KK HER 75 | GO THO1TE

Theophrastus rope plants (AVITN) and plot compositions 554, 553 and 360. The results, average for the kitchen (ESNSE) were grown and processed standard- of all repetitions of each processed sample, shown by the methods described above. Applied in table 105 and Jus. the compositions of Table 39a and the comparative compositions 554, 139 and 360. The results, averaged for all 100 replicates of each processed sample, are shown in the table

Or and 9s. AVIiITN 95 control

Table | in | 00 1 117 | baB | 692.

AVITN 95 control ovidya5 | aa | 733 | 833 800 le 10 | 175 | I will fight 683 and | 01 08 | 375 1 550 73601 233 | 650 | 800 16 900 76140 | 775 | 892 | 922 | 948 (uvib85 | la | 867 | 915 | 960 vBtb1A | 125 | 600 | 77 | 767 | Table 10s

ESNOE 96 control and | 00 | 00 | Because | 333 (

Table Zo o

BONSK In control of tweedyav | 7001 5751 6831 725 ugobo | 642 | 792 | 80016 928 | (7v1s85 | 60o | 750 | 825 | 850

Example 11

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 114.

Table 1a

Results for AVITN and ESNSRE: all compositions of this example were not as effective as standards 360 and 754. However, compositions 622 and 676 were 1 2 close to standards 360 and 754.

Example 10

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 10a.

Tablydyatoa GO 7v7 |kI|BoH 1 1 7360 |1РАИЗ3560й 00110156 1 1

Studiev | ko143 85 1001 86 1121 (MN KIS

Plants Theofrast’s rope plant (AVIOTN) and ploskuhu (ESNSE) were grown and processed standard

And 761E9M | Kk | 301 5610 160 561 |40| by the methods described above. Applied- (761240 | Кк | 30| 510 |80| 9561 |2.0| were compositions of table Pa and comparative 7610851 КК | 30 | 610 |т100| 561 |00| compositions 554, 139, 754 and 360. Results, average for all replicates of each processed sample,

Plants Theophrastus rope plant (AVOTN) and plantain shown in Tables 116 and 116. kukha (ESNSE) were grown and processed by the standard methods described above. Compositions of tables 10a and comparative were used

Table 116 Table 11p

AVITN 95 control ESNSE 95 control 360 | 700 | 825 | 892 | 900 o lo5AZ5 | 600 | 825 | 897 | 970" lobEZN | 71.7 | 825 | 892 | 900 787 | 750 | 825 | 850 | 900

Results for AVIiITN and ESNSRE: all compositions of this example were as effective as standards 754 and 360.

Example 12

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 12a.

Table 12a 4TvANO | Co. 1480 | VTNI2 | 400 | eETnya55 | 600 | 50Ve | 600

Obviously! Co. 15 | vTNi2 | 6075 | UT | | Her 360 | IRA | 360 | g (Her Her Her 1 754 | RA | 445 | tTAM'O5 | 59 | imtoo | 224 554 | 7KO1 HER 7725 | ГГ

Plants of Theofrast's rope plant (AVITN) and flat plant (ESNSE) were grown and processed according to the standard methods described above. The compositions of table 4a and comparative compositions 554, 139, 754 and 360 were used. The results, average for all repetitions of each processed sample, are shown in 1 С/8ЕТН ОЙ 617 | 783 | 900 | 9850 tables 125 and 126. and so on

Results for AVITN and ESNSRE: all composites

Table 125 tions of this example were similar to each other in their effectiveness. None of the compositions was

AVITN 95 control is as effective as standards 360 and 754 for

AVITN. Compositions 476E1H and 476B6M were similar to standards 360 and 754 for ESNSE. 139 | 00 | 77 | 650 | 817 | Example 13

Aqueous concentrates of compositions containing salt -54 71 50 1 17 771 7 8337779007 ee honors were obtained as shown in 47686M | 600 | 650 | 750 | 867

Table tZa about 47702M | 56.7 | 600 | 850 | 850

Table 120

ESNoK ze control: --8v0----aya- Plants of Theophrastus rope plant (AVIOTN) and plantain (754 | 633 | 650 | 850 | 900 | kuhu (ESNSE) were grown and processed standard-

by the methods described above. Using repetitions of each processed sample, the composition of table 13a and comparative compositions of table 146 and 14c are shown. tions 554, 553, and 754. The results averaged over all replicates of each sample processed are shown in Table 14, Table 1365, and Table 13c.

AVIiITN 95 control

Table 136

Composition of akerhNe in 75g, 100g, 150g

AVITN 95 control of glyphosate pu e 95) k.e./ha | ke./ha | ke/ha and 7139, | sh.-.HGRSHKR 0 | 710.8 | 125 | 575

Composition 75 g c.e./ha |150 g c.e./ha|225 g c.e./ha| ZOOg k.e./ha vm | 00 | because 1 82 | ov3 10 | 541 0-00 277 754 17001 00 1 800 | 808 | about avre 549A7) | 35.81 5751 80816 900 1 649848 649S9X 64902 649ETA 0.05ze 649E8S vA9s6M bongM | 71.7 1 8081 9001857 | 554 | 05" | 45.88 | 73.3 | 775 table 13p

ESNSE 95 control Table 14p

Composition 75g c.e./ha (150g c.e./ha | 225g c.e./ha | З00g c.e./ha ESNOE 75 control 554 | 00 | 00 | 167 | 67 tva 11770071 425 1 800 | 87 1 | composition | Surface- | 75; | 100k | 41507 glyphosate of my k.e./ha | ke/ha | cell/a 649А7 g 7 - и- 549848 | 7139. | 0 ByuBm.M1|50 1 75 | 317 х 554 | 0 | 00 | 58 | 133 649С9Х -3з5.17700555й-31 6001 89218507 вivoa b49ETA | 001 167 | 6251 758 | ze : : : 649Е8С 1 g 7 7 z

Because b49N2M

Results for AVITN and ESNSE: the most ac- 55 0 O5l 33.3 55.0 65.8 ! the active composition for AVOTY was BT98SV, and the most active composition for ESNSE was 553.

Example 14

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in Results for AVITN and ESNSE: comparison of table 14a. M121 as a surfactant for each

IRA and K of glyphosate salts showed that this surface

Table 14a vo-active system is the most effective for strengthening IA. All highly effective compositions of each surface-active real test were noted in IRA versions of K salts.

M121 wine (surfactant!. 100 Surface-active system M121 apparently reaches its maximum efficiency at a level of 139 |IRAI 77777777 1570 about 0.195 to 0.595 spray volume for 00554 1Kkg 1725 | of each glyphosate salt, after which the effectiveness did not change or decreased, if the levels of

Theophrastus rope plant (AVITN) and surfactant plants grew up to 195 or Kuhu (ESNSE) were grown and treated standard- 595 for both salts. by the methods described above. In Example 15, the compositions of Table 14a and comparative aqueous concentrates of compositions containing salt compositions 139 and 554 were used. The results averaged for all glyphosate and excipients were obtained as shown in Table 15a.

Table 15a

And with 87756 | KO | 410 | MAO | 1322 | ///::To HER. Y.777777717 1147777 1 and z8724M | CC | 476 | UANo5 | 662 | 7 | 662 387-302 | CC | 488 | MAVO5 | 667 | AROEY | 667 of 87986 | Kk | (| MAO | 408 | 117 | 816 | AROEI | 13.6

Plants of Theophrastus rope plant (AVITN) and ploskukha (ESNSE) were grown and processed using the standard methods described above (Table 15). The compositions of table 15a and comparative ESNSR 96 control compositions 554, 360, 139 and 754 were used. The average results are shown in table 156 and 156.

Table 155 754 | 710 | 740 | 918 | 906" (387-155 | 680 | 780 | 936 | 960

AVOTN In control 7-54 71778071 8071 880 1790077 387-982 | 66.0 | 72.0 | gout | by day

Example 16 p. , I

Aqueous concentrates of compositions containing salt 387-59A | 66.0 | 800 | 850 | 870 | glyphosate and excipients, obtained as shown in

Szv7vkh | 690 | 740 | 830 | 860 | table 16a.

Table 16ba and Z8713M | KO 410 | MAO | 1322 | .//::K((M/Y Г717777777777171711711

And Z387257 | KO | 476 | MAVO5 | 662 | 117 | 662 387-386 | Kk | 488 | MANO5 | 667 | AROBU | 667 387-890 | UK | 483 | is TNI2 | 660 | 7 | 66

Z8/LIvU | KO 543 | еТНИ2 | 543 | her7y | 814 7960 | IRA | with | b HER HER (GG Her 1 1754 | RA | 445 | UMTo5 | 59 | eat | 224 | ..: 554 117 KOO HER 75 | 11111111

Plants of Theofrastus rope plant (AVITN) and flat-leaved plant (ESNSE) were grown and processed by the standard methods described above. The compositions of table 16ba and comparative compositions 554, 139, 360 and 754 were used. The results, averaged for all repetitions of each processed sample, are shown in table 1660 and 16c.

Table 166 (387-386 | 220 | 690 | 800 | 830

AVOTN 5 control vm o| 80 1 650 | 770 | 800 from 87-1zm| 600 | 830 | 840 | 88.0

Table 16c Table 175

ESNSE 95 control AVIiITN 95 control 7139 | 00 | 142 | 500 | 858 360 | 00 | 550 | 908 | 995 754 | 620 | 6950 | 820 | 930 387-13М!| 660 | 81.6 | 890 | 878 | awwwww!| 00 | 633 | 700 | 930 (387-25E | 66.0 | 720 | 838 | 858 387-8901 610 | 660 | 760 | 822

The results for AVIOTN and ESNSRE: compositions 387-13M were similar in effectiveness to state- | 488IZA | 00 | 308 | 750 | 913 darts 360 and 754 for ESNSE. The composition 387-25E was even more effective. None of the compositions in this experiment were as effective as standards 360 and 754 for AVOSTN.

Example 17

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in Table 17c of Table 17a.

ESNSE 95 control

Table 17a 7339 1.00 | 67 | 517 | 77 7553 | 608 | 733 | 800 | 967 av8s7O 1 00 | 300 | 650 | 750 savvrbN at 00 | 317 | 633 | 758 a88E2U | 192 | 600 | 700 | 808

Plants of Theofrast's rope plant (AVITN) and flat plant (ESNSE) were grown and processed according to the standard methods described above. Applied- Results for AVITN and ESNSE: the best com- of the composition of table 17a and the comparative position among all was the 553 standard, because the compositions 139, 553 and 360. The results, average for it was the most effective, in comparison with the com- of all repetitions of each processed of the sample, shown by the positions being tested. Compositions containing no in table 1865 and 18s. potassium salt are more active than the corresponding IRA salts.

Example 18

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 18a.

Table 18A 86 Front -ine MO 2.0096 PNNSh 863B8M M510 1.0095 Net2O2O 1.0095 863C40 RSS50 1.0095 PNNSh 863065 Robbo 0.5095 Net2O2O, IRA | 6 | / | NET2O 2.0096

Plants of Theofrastus rope plant (AVITN) and flat-leaved plant (ESNSE) were grown and processed by the standard methods described above. The compositions of table 15a and comparative compositions 360 and 139 were used. The results, average for all repetitions of each processed sample, are shown in table 186 and 18c.

Table 1865

AVIyITN 95 control 10 Ok.e.g/ha | 20 Ok.e.g/tha | З0Ok.e.g/ha | 40 Ok.e.g/ha | 10 Ok.e.g/ha | 200 k.e.g/ha | З0Ok.e.g/ha | 400 k.e.g/ha 7139 | 0 | 33 | 60 | 75 | 0 | 5 | 517 | 767 vbzAYAMU | 33 | 60 | 817 | 877 | 77 | 60 | 837 | 877 863v8M vvzsia | 33 | 5 | 733 | 827 | 0 | 233 | 7/7 | 827 863065 | 1.7 | 583 | 883 | 943 | 0 | 617 | 923 | 983 863Е2М 863Р7Х | 0 | 617 | 867 | 973 | 1.7 | 667 | 873 | 983 vb3a3B | 17 | 67 | 85 | 90 | 5 | 633 | 753 | 95

Results for AVIOTN and ESNSRE: composition Example 19 863E2M showed better efficiency and was more Aqueous concentrates of compositions containing salt effective than standards 360 at the amount of glyphosate and excipients, obtained as shown in 100 ae g/ha. At 200 ae g/ha 863V8M and 8630538 were table 19a. more effective than the 360 standard for AVOTN.

Table 19a

ЗАвА2 M NET2O go 71111 za8vbmM | IRA | 62 | (Б ИИ (| 589.2Ю5Б| 2.0096 за8соХ НЕТ2О 1.7596 0.2595 86306М | IRA /|7/62 | 7777777717171717171717171171ЙЙ71117171171111111111111158187017191111581701716111

Z48Eg2M NET2O 1.7096 0.309e za8ghz | IRA | 62 | (F | 77777707 77717550... Yu. | 2 that z48054K NET2O 1.4096 0.60

Theophrastus rope plants (AVITN) and plot compositions 360 and 139. The results, the average for all taste buds (ESNSE) were grown and processed standard replicates of each processed sample, shown in the methods described above. Apply - tables 196 and 19p. the compositions of table 19a and comparative were included

Table 195

AVIyITN 95 control 10 Ok.e.g/ha | 20 Ok.e.g/tha | З0Ok.e.g/ha | 40 Ok.e.g/ha | 10 Ok.e.g/ha | 200 k.e.g/ha | З0Ok.e.g/ha | 400 k.e.g/ha 7139 | 5 | 28.3 | 567 | 60 | 50 | 45 | 65 | 667 and z60 | 60 | 81 | 877 | 95 | 567 | 833 | 937 | 943

ЗАВАгМ за8авб6мМ | 0 2 | 45 | 6853 | 65 | 5 | 385.3 | 6853 | 667 z4a8seh | 683 | 90 | 933 | 943 | 7 | 84 | 92 | 943 86306U

And Z48g25 | 5 | 417 | 65 | 633 | 467 | 617 | 7853 | 80 (

Table 19 p

ESNSE 95 control /OzaBA2MU | 36.7 | 40 | 75 | 80 | 467 | 483 | 633 | 817 zavs4k | 38.3 | 433 | 7853 | 867 | from | 50 | 60 | 867

Results for AVITN and ESNSE: compositions 348А2МУ, 348С9Х, 348Е2М and 34804К and standard 360 І 471в9х | 600 | 700 | 800 | 950 had high levels of control for AVITN at all test rates and for ESNSE at test rates of 300 and 400 ae g/ha.

Example 20 |471P4A | 675 | 733 | 800 | 990

Aqueous concentrates of compositions containing salt and glyphosate and excipients were obtained as shown in Results for AVOTN Her ESNSH: the best compositions of table 202. among all were 471075 and 471E4A.

Both compositions 471075 and 471E4A showed bi-

Table 20a had greater potency on AVOTN than standard 360 and showed similar activity on ESNSE to standard 360. Composition 471E8C also had greater 1 2 potency on AVIOTN than standard 360 showed.

Example 21

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 21a. table 2ta

Plants Theophrastus rope plant (AVITN) and Kompokh flat plant (ESNSR) were grown and processed according to the standard methods described above. The compositions of Table 20a and comparative compositions 360 and 139 were used. The results, average for all repetitions of each processed sample, are shown in Tables 206 and 20. table (С Я8вОАЖ | РА | 30Й 1 I VNIZB 101 48083М | ИРА 730) | VAV | 10.0

AVITN 95 control (avoseM (RA |301 1 | vABV 1 10.01

Plants of Theofrast's rope plant (AVITN) and ploskuha (ESNSRE) were grown and processed according to the standard methods described above. Table 2t1a and comparative compositions were used

And 47189Хх | 200 | 408 | 858 | 98.7 | compositions 360 and 139. Results, average for all lard | 11.7 | 725 | 908 | 9950 | replicates of each processed sample are shown in Table 215 and 21. table 21

Table 20s AVITN 95 control

ESNOR 5 control

Composition) 50 g c.e./ha and 100 g c.e./ha (200 g c.e./ha | 400 g c.e./ha

Composition 50g CU/ha |100g CU/ha|20Og CU/ha| 400 g c.e./ha

AGAVS | 625 | 833 | 900 | 985

Table 22 p

ESNSE 95 control 554 | 00 | 00 | 475 | 483

Table 21 p

ESNSE 95 control

And 457s2M | 68.3 | 785.3 | 808 | 99.0

Results for AVITN and ESNSE: the most active composition tested for AVITN was 62370. Several compounds showed comparable activity for ESNSE.

Example 23

Aqueous concentrates of compositions containing salt

Example 22 sh , , glyphosate and excipients, obtained as shown in

Aqueous concentrates of the composition containing the SALT of table 23a, glyphosate and excipients were obtained as shown in table 22a. Table 23a

Table 22a Kny rya Components Components CT aa v 14-13 757AZ3A | K |43| 597 14!

St5BEb5 | K 43 8597 109| 519 051

And bezla | Kk | z0 | 593 | 100 | G75BO8E | Kk 14310101 819 | 141 shk " what

Theophrastus rope plant (AVIOTN) and plantain plants

And kukha (ESNSE) was grown and processed standard-

Theophrastus rope plant (AVOTN) and the flat methods described above. The applied plant (ESNSR) was grown and processed according to the standard compositions of table 21a and their comparative methods, described above. Applied - compositions 554, 360 and 553. Average results for each composition in table 22a and comparative of all repetitions of each processed sample, shown - compositions 554, 754 and 553. Average results for no in table 235 and 23c. of all repetitions of each processed sample are shown in Tables 225 and 226. Table 235

Table 225 AVITN 95 control

AVITN 5 control t i GB KB LA TTBOG KB LArOBG LA ZObgSV7 Tue Thu Wed We st MET 554 | 00 | 42 | 225 | 558 | 553 | 725 | 8751 9001 920 1 754 | 00 | 567 | 752 | 858

And 62383M | 31.7 | 733 | 900 | 908 (6239) | 65.0 | 875 | 917 | 950

Summary | 7251 9001 9331 968 I I 8 1 13

Table 23c of the studied compositions were more effective than standard 139 for AVITN. Standard 360 was the most

ESNOR 96 control with a more active composition for both AVOTN and

Alya "OExample 25 554 | 00 | 67 | 375 | 433 | Water is not! !

SOME COMPOSITION CONCENTRATES CONTAINING GLYPHOSATE SALT AND EXCIPIENTS WERE RECEIVED AS SHOWN IN 755AVMU | 00 | 583 | 692 | 725 | table 25a.

Table 252 755092 | 00 | 625 | 717 | 742 tBBOVE vBovev | Kk |javoob| mREFT 200, 1 i i t VZN tlo VI Z KE No NN NIE tive | effective compositions studied for AVITN and for ESNSE were standards Бб2С18 1 КО480.00Й EAT75 190.01 ЕОЧ75 130.0 360 and 553. 66205 | Kk 8000, EAT75 60.01 EO175- |6О.0

Example 24 zvo | Kk ivooo| vd | | KK

Aqueous concentrates of compositions containing salt (754 | K 480.00 EA1T75 | (| Shshch(BFI glyphosate) and excipients were obtained as shown in | 560 | K 480.00 EAT75 |121| 135 table 24a.

Theophrastus rope plant (AVIOTN) and plantain plants

Table 24a kuhu (ESNSE) was grown and processed according to the standard methods described above. The compositions of table 25a and comparative compositions 154, 560 and 360 were used. The results averaged for all repetitions of each processed sample are shown in table 256 1 256.

Plants of Theophrastus rope plant (AVITN) and plos-Table 255 Kuhu (ESNSE) were grown and processed by the standard-AVITN 95 control methods described above. The compositions of table 24a and comparative compositions 139 and 360 were used. The results, average for all repetitions of each processed sample, are shown in I 360 | 485.3 | 800 1 883 | 900 tables 246 and 24b.

Table 245

AVITN 95 control 139 | 00 | 500 | 717 | 908

And from 60 | 33.3 | 7.0 | 880 | 99.0

Table 25 p

ESNSE 95 control

Table 24 p

ESNSE 95 control 65965 | 15.0 | 51.7 | 600 | 642 659048 | 275 | 600 | 592 | 66.7 o bb4AZa | 342 | 525 | 600 | 675

Results for AVITN and ESNSRE: composition

Results for AVITN and ESNSRE: all studies - 662095 was close in its effectiveness to the genie composition and were more effective than standard 360 in all performance options. dart 139 standard ESNSR. Also three out of four

Example 26

Aqueous concentrates of compositions containing salt I 2о6о85| 60 685.0 | 820 | 840 glyphosate and excipients, obtained as shown in I 2hobrzmM | 80 | 600 | 820 | 840 of table 26a. tolicava 206120 | 26.0 | 660 | 830 | 860

Table 26 p

ESNeE with control - 7773601 RA 1 36013330 | 2obAgMU | 26.0 | 630 | 710 | 800 beans 1 290 6001 -730----850--

Theophrastus rope plant (AVITN) and plantain plants

K (ESNSRE) grew and processed standard - svovovzA | 570 | 660 750 Х КВУ |/ уху рошу р дар by the methods described above. The compositions of Table 26va and comparative compositions 754, 128, and 280 were used. The results, average for | 280 | 600 | 850 | 978 | 976 of all repetitions of each processed sample, are shown in Tables 266 and 26c. Results for AVYOTN and ESNSE : none of the studied compositions was as effective as

Table 260 standards 754, 128 and 280 in each investigated plant.

AVITN 95 control Example 27

Aqueous concentrates of compositions containing salt (754 | 300 | 800 | 860 | 960 | glyphosate) and excipients were obtained as shown in gobA2gMU | 00 | 670 | 80 | 840 | table 27a.

Table 27a about bIbAE | KO | 50 | MORA | 1350 | | HER 9 / bbAbNO | KO 1 540 | Mmi21 | 1350 | HER Her 9 Her

And 6bibazz | CC 1,550 | is TNT2 | 675 | UT | 675 960 | Kk | from 60 | is Ta | ОЙ 77777777 14777 Her (754 | Kk | 445 | in Na | Her:

Plants of Theofrast's rope plant (AVOTN) and flat plant (ESNSE) were grown and processed according to the standard methods described above. The compositions of Table 27a and comparative compositions 360, 754, 139 and 554 were used. The results, averaged for all repetitions of each processed sample, are shown in Tables 27b and 27c. Table 27 p

Table 270 ESNSE 95 control

Network 439 1 58 1 308 | 6001 749 vd | 73771192 4677177850077

6151 | 750 | 912 | 932 | 990 | AVITN 615S3M and 61502M had better efficiency.

Example 28 754 | 725 | 875 | 980 | 990 | Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in

Results for AVOTN and ESNSRE: none of the results of table 28a. of frozen compositions of AVIOTN was not as effective as standards 360 and 754. The studied compositions

Table 28a

And oZbobN | Kk | 5401 could! | 135Y: HER HER (GG 17

And ol2vem | IEA | 480 | could | 12017777 1171 С111111111111711111111111111711 2687) | Kk | 540 | etNI2 | 54 | UMtTo5 | 811 scrap |027 26936 | CC | 540 | gTNI2 | 81 | UMTo5 | 54 | scrap |027 27246 | Kk | 550 | including 2 | 61 | Umto5 | 74 | scrap |027| Sh

I 4598H 1 KO | 480 | could! | 1211 77777777 17711171 siIMs | 51 17 sieve1O | 935 46030 | Kk | 5 | could! | 135 HER HER shshsh | | spo | « 56335 | K | 540 | gtnI2 | 608 | UMTo5 |743| АНОбЕ | | sus |t102 bo | KO | 472 | AVMS | | uUltzoo | | / / 360 177717

And 754 | | 445 | Uulto5 | 59 | them too |224| .....-:(KN | Her her

Theophrastus rope plant (AVOTN) and plantain plants I 56335 | 25.0 | 600 | 650 | 700 kuhu (ESNSE) were grown and processed by the standard methods described above. The compositions of Table 28a were used and comparative results for AVOTN and ESNSR: In this composition, the 360 and 754 compositions were used. The results, averaged for all trials, there was no composition so many repetitions of each processed sample, are shown in the effective as standards 360 and 754 AVOTN. However, tables 28b and 28c. most compositions were similar to the 754 standard

Example 29

Table 285 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in

AVITN 95 control table 29a. table ha 553 |IRAITZ601 VNIBE 16.41 ETNO5 19.81 2687) | 00 | 767 | 817 | 833 26932 | 00 | 733 | 817 | 817 2t04x | 00 | 750 | 7ub7 | 800 27168 | 00 | 600 | 767 | 817 27242 | 33 | 600 | 783 | 817

Theophrastus rope plant (AVIOTN) and the 28s Kuhu plant (ESNSE) were grown and processed according to the standard methods described above. Apply-

The composition of table 29a and comparative compositions 553, 554, and 754 were controlled by ESNSE 95. The results, averaged for all repetitions of each processed sample, are shown in table 29r.

Table 295

AVITN 95 control 754 | 0 | b | 57 | 80 54 | 0 | 0 | 0 | 17

And m368 | 0 | 142 | 65 | 775 968095 | 40 | 56 | 55 | 68 968E6M | 20 | 47 | 58 | 66 32rta | 0 | 383 | 6952 | 792

Results for AVITN and ESNSE: a better experience

Results for AVITN: in terms of its effective composition during this test, standard 553 was the best composition in the experiment; 96884B was the best composition among all the experiments. rymenti M318 was less effective than standard Example 31 553, and more effective than M368 and 754. M368 and Aqueous concentrates of compositions containing salt 754 were identical in performance. glyphosate and excipients, obtained as shown in

Example 30 of table C1a.

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in Table 31a of the Table of Contents.

Table Zba T7ZOAOA | КИз01 52 (ОЙ FI

B SHEP шЕ х ш я 553 |IRA/360| INVIBE |64| ETHNO | 96 a8lLeMu | Ka, 51 09| vnib 5 mbt9 IRA )/360| VNIBE | 4 | ETHNO" | 6 | 4871991 | Kk 4.3.1 1816E )/0.8| in the sky 0.6) 73OEV) | K 1301 ESH25 |10Y

And o7zmAyaT | K|43| | | outside

Plants of Theophrastus rope plant (AVOTN) and flat-leaved plant (ESNSE) were grown and processed in standard and evvs5) | Kk ovo! | 72| eMmsa2 | 6 | By the methods described above. Apply-

And there were compositions of tables for and comparative

Plants of the Theophrastus rope plant (AVOTN) and plot compositions 139, 553 and 360. The results, average for the kitchen (ESNSE) were grown and processed standard- of all repetitions of each processed sample, shown by the methods described above. Used in table 316 and 31p. were the compositions of table Zba and comparative compositions 553, 554 and 360. The results, average for Table 316 of all repetitions of each processed sample, are shown in table 306 and 30s. AVITN 75 control

Table 306 139 | 0 1 60 | 738 | 80

AVITN 95 control I z60 | 40 | 80 | 92 | 913 553. | 50 | 825 | 933 | 90 554 | 0 | 16 | 63 | 70 | 730070 | 788 | 90 | 978 | 96

And from 60 | 70 | 75 | 85 | 90 | 73007C | 725 | 875 | 978 | 96 553 | 78 | 83 | 90 | 94 | about avunzK | 525 | 775 | 90 | 925

And mb2go | 73 | 82 | 88 1 90 | 48 laMu | 60 | 80 | 958 | 958

And mb19 | 73 | 80 | 89 | 94 | 489 | 688 | 80 | 925 | 888 Z68 BUT | 69 | 7 | 78 | 84 eb8VaA | 69 | 78 | 82 | 93 | 7308 | 538 | 80 | 913 | 913

And 7mAYAT | 5 | 738 | 863 | 90 ( 968E6M | 60 | 69 | 80 | 81 | Table Z1s

ESNSE 95 control

Table Z0s

ESNSE 95 control 7Z0AOA | 65 | 813 | 80 | 935 554 | 0 | 6 | 15 | 24 | 730070 | 688 | 80 | go38 | 925 o avTnZK | 625 | 775 | 80 | 873

7ZOEV.) Example 33 731AZT Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in

Results for AVIOTN and ESNSRE: composition of table ZZa. 7307 was the most effective composition in this experiment and showed improved herbicidal efficiency in comparison with the composition of Zal, similar herbicidal efficiency compared to 1 composition 360 for grass (ESNSRE), but showed a greater herbicidal efficiency compared to 487070 compositions for broadleaf plants (AVOTN) 48709 at high n levels. 487EVU 487HOR

Aqueous concentrates of compositions containing salt 48764 1816 glerosate and excipients were obtained as shown in 496А5Т ETНО5 table 32a.

Theophrastus rope plant (AVIOTN) and plantain plants

Table З2а куху (ESNSE) was grown and processed according to the standard methods described above. Apply-

Compo- - o Compo-| Compo-| 5 ny y y y y zition Salt o nent 1 o nent ? The remaining compositions of Table ZZa are comparative

ВАИБ6 ЕФо5 1 9.61 compositions 139, 553 and 360. Results, average for 9bbATA| Kk 139 (| 12 | Mt801 6 of all repetitions of each processed sample, show- 966v2UM| Kk 36.9! | 12 | Ultvo no in table 3365 and 33s. 966s5t| КК /369| | 12 | UMtvO zvbr8y| Kk |369| | 12 UltvO Table 336

Plants of Theophrastus rope plant (AVITN) and plan- AVOTN t control, they are about sleds outside the composition of table З2а and comparative properties | at 1 542 | in | vaBk compositions 360, 553, 554, 560, 754 and 765. Results, average for all repetitions of each processed 48720 | 0 | 392 | 683 | 733 samples shown in table 326 and 32p. 487848 4872070 | 25.8 | 708 | 792 | 80

Table 325 48709 | 0 | 54542 | 775 | 808 487E8U

AVITN 96 control 1878 | 01 77 | 808 | 858 48754E | 15.8 | 633 | 80 | 825

Composition oogk eta two keta og kva Zoo kela 1496А5Т 1001 325: 1 733 | 7657 ee Table ZZs

ESNSE 95 control

Composition 5Og k.e./ha |10Og k.e./grove God k.e./ha| 200 g.e./ha ovbATA | 3.3 | 508 | 767 | 80 | 139 | 0 | 442 | 65 | 642 (662 | 47.5 | 73.3 | A I 360 | 48.3 | 683 | 725 | 775 ( 9665 53 | 642 | 683 | 783 | 80 ( 96608. 487A20 487848

Table 32c 48707y 487091

ESNSE 95 control of AVTEVU 487РОР

Composition 1 boh c.e./ha|150g c.e./ha|200g c.e./ha| ЗО0Ог к.е./ha 487С4Е 196А5Т 487В4Е showed herbicidal efficiency similar to - : efficiency of comparative composition 553; as com- 765 | 367 | 542 | 60 | 667 | i 487VAV por ia 553 bbATA position SVTVYAK, so | comparative composition 96682 were the most effective compositions in the experiment with AVOTN.

Example 34 7т3ов5х

Aqueous concentrates of compositions containing 730C1P glyphosate salt and excipients were obtained as shown in Table 487E2I of Zda. 487275

Table C4a Table 34c

ESNOR 95 control of tzagaZa K Zo Zb I K iya| 75 /ha | 150/ha225/ha| 300 / 732838 732С97 73ОАБА | from 60 | 508 | 808 | 825 | 892 73Ов5Х | 553 | 60 | 758 | 808 | 883 730SIR 732AZO 487ERI 732в3А 48775 732097 7ZOABA

Plants Theophrastus rope plant (AVITN) and plos- t3ов5Х | 583 | 75 | 80 | 892

ESNSRE) were grown and processed the standard t30c1R kitchen (b Z 487E2I | 575 | 80 | 80 | 867) by the methods described above. The compositions of table 34a and comparative compositions 139, 553 and two average results for AVITN and ESNSRE: the composition of your bly for the rest of the sample, showed that 730С1Р was the most effective composition in the experiment with a broad-leaved plant (AVITN);

Table 345 composition t30c9T showed a very strong herbicidal efficiency in comparison with composition 360 and

AVITN 95 control by comparative composition 553 at the two lowest levels. Composition 730С9Т was the most

Composition 75g c.e./ha 1 50g c.e./ha|225g c.e./ha| 30Og k.e./ha active composition on the flat (ESNSRE); the composition 732C9T showed a very strong herbicidal activity in comparison with the comparative composition 360. 732АЗО Example 35 732гв3А Aqueous concentrates of compositions containing 732097 salt of glyphosate and excipients were obtained as shown in 7ЗОАБА table 354.

Table Z5a 554. | IRA | 0 | VN5b ETN25 96 | sh 5S85 368 | IRA | 0 | EMO. UMITO5 | 6 | OA | 65 38 | TO HER 0 | EMIY- UMITO5 905А32 иЕ700 УМИТО5 90586 СРО УМИТО5 905058 иЕ700 ЭХРВ2 6 | OA | 65 905030 I E700 EHRV2 905EOI. ЕХРВ2 УМИТО5 | 6 | OA | 65 9О5Е8М ЭХРВ2 ЭХРВ2 | 6 | OA | 65

Plants of Theophrastus rope plant (AVOTN) and flat-leaved plant (ESNSE) were grown and processed by standard | 368 | 15 | 45 | 675 | 60 by the methods described above. The compositions of table 35a and comparative esnYa compositions 368, 318, 553, 754, 554 and 765 were used. The result - | 9056M | 15.8 | 25.8 | 55 | 642 you, average for all repetitions of each processed 505095 sample, are shown in table 350. ooBEOS 14171 483.1 601 583 table Z5B ZoBEVM

AVITN 95 control Example 36

Aqueous concentrates of compositions containing salt

Composition 75g CU/ha 125g CU/ha 75g CU/ha| 250 g of CU/ha of glyphosate and excipients were obtained as shown in Table Zba. 754 | 117 | 60 | 683 | 675

Table Zba

Table 37a

Composition Salt g/l Component g/l

Theophrastus rope plant (AVIOTN) and plantain plants

Plants of Theofrast's rope plant (AVITN) and ploskuha (ESNSE) were grown and processed standard-kuha (ESNSRE) were grown and processed according to the standard methods described above. Applied by the methods described above. The compositions of table Z37a were used and the compositions of table Zba and comparative compositions 553, 554, and 360 were compared. The average results for compositions 553, 554, and 754. The average results for all repetitions of each processed sample were shown for all repetitions of each processed sample. shown in table 376 and 37p. not in table 3665 and 36p.

Table 375

Table 3605

AVITN 95 control

AVITN 95 control 554 | 0 | 142 | 542 | 658 554 | 0 | 67 | 608 | 617 | from | 33 | 783 | 875 | 90 tvovl o; 23.3 | 60 | 742 | 792 boss | 61.7 | 742 | 883 | 90 | Table 37 p

ESNSE 95 control

Table Zbs

ESNSE 95 control 5 | 0 | 33 | 7183 | 458 554 | 0 1 67 | 28.33 | 467

Composition 553 was the most effective ego | 533 | 717 | 751. BYUBKk 80 | composition on a plane (ESNSRE) at high levels.

Example 38, Aqueous concentrates of compositions containing salt

Results for AVOTN and ESNOR: In this glyphosate and excipients, obtained as shown in the experiment, composition 767Н2К and composition 553 of table 382. were the most effective compositions on the Theofrast rope (AVITN). Composition 553 was Table Zva the most active on the plane si (ESNSRE). Composition 610E87 and composition 61054E showed very high efficiency in comparison with composition 754 both on the Theophrastus ropeway (AVITN) and on the flat surface (ESNSE) at low levels.

Example 37

Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in Table 378.

Plants of Theophrastus rope plant (AVITN) and plots of all replicates of each processed sample, show-cooker (ESNSE) were grown and processed standard in table 3965 and 39c. by the methods described above. Table 396 was applied to the compositions of table Zva and comparative compositions 553, 554 and 360. The results, average for AVITN 5 control half of table ZV ZVs, processed sample, showed- IComposition | 75g c.e./ha 1 50g c.e./ha|225g c.e./ha| З00g к.е./ha y

Z60 | 292 | 70 | 85 | 90

Table Zv about T2LNOA

AVOTN I control 721170 | 325 | 733 | 801 858 (Composition | 75 g c.e./ha/1 50 g c.e./ha | 225 g c.e./ha | 300 gc.e./ha t2147s | 225 | 683 | 80 1 85 va | 0 | 27 | 433 | v83 | Ta1KZK 52 170 87 | 858 | 800 Te

Ltd

I g bozvaM : : : 603S5t 60308.) Table 39s 6OZEVI 6OZEbU ESNOR Z control bozszo IComposition| 75g CU/ha | 150g CU/ha (225g CU/ha| ЗО0g CU/ha table 38

Volitsia is about | 553 | 6952 | 75 | 80 | 842

EONSK with control tmnoA | 533 | 7081 7751 80

Composition 75 g.e./ha | 50 g CU/ha | 225 g CU/ha | Z00g k.e./ha t217u va | about | about | 33 | 192 | lyuk is eh Ne ni ni tin s sn

TE1ORA boZATA lovi 6o3s5t : : voZO in 6OZEV Results for AVIOTN and ESNSRE: composition bOSEbU 553 was the most effective composition both on the 603090 ropeway of Theophrastus (AVITN) and on the flat (ESNSR). Compositions 721С2М/ and 721091 were shown

Results for AVIOTN and ESNSE: The composition of comparable herbicidal efficacy compared to 553 was the most effective composition both on composition 360. Theophrastus rope plant (AVITN) and on flat Example 40 (ESNSRE). Aqueous concentrates of compositions containing salt

Example 39 of glyphosate and excipients, obtained as shown in

Aqueous concentrates of compositions containing table 4ba salt. glyphosate and excipients, obtained as shown in table 39a. Table 4ba

Table by Compo- | salt g/l | Compose| ud |Compos| unit 1 unit 2 compo compo i ompo- 72tН vnoto tt to 721NOA NOT t211Р vno 721170 IM'TOO T21К5Х IMTOO 72147с NOT t21с5н| K | 30,554 | 10! 721KZK IchmTOO t21r971| Kk | from | 556 | 10,721 sq.m Kk | 301 554 | 11

Tt21ATu | Kk 130 2 shTs! (| вВноо 7т21ву | Кк | 30| ЮщЮщЮЯ| | mtoo Theophrastus rope plant (AVOTN) and ploskukha (ESNSE) plants were grown and processed standard

Theophrastus rope plant (AVOTN) and the flat methods described above. The applied plant (ESNSE) was grown and processed according to the standard compositions of table 4b0a and their comparative methods, described above. Applied - compositions 139, 360 and 553. Results, average for each composition in table 39a and comparative of all repetitions of each processed sample, shown - compositions 139, 360 and 553. Results, average for no in table 4bb and 40c.

Table 406 about Theophrastus rope plant (AVIOTN) and plant

AVITN 75 control strain (ESNSE) was grown and processed standard-

Composition | 75 g.e./ha | 5Og k.e./ha|225g k.e./haIZO0Og k.e. /Ha! Tables were compared with comparative compositions 751, 360, 554 1 159. The results, averaged for the repetitions of each treated sample, 721875 are shown in Tables 416 and 416. 721021 | 42 | 658 | 80 | 825

T21NIR Table /1b t2115X 721058 | 46.7 | 692 | 833 | 90 | AVOTN Z control 721697 - 721AZV 150 gk.e./ha|200g k.e./ha|ZOOg k.e./ha| 400 g CU/ha 72483010 831 44215827 | Her 0 | 142 | 608 | 683

Taslytsyaoo And tvRoy

ESNSE 95 control tone | 42 | 658531 801 825 721H7u

E 721191

Composition | 75g CU/ha | 1 50g CU/ha | 225g CU/ha | for (levs | 457 | 692 | 833 | 80 pisoR I 633 | 857 80188

T21AYAE 721P78 721851 | 0 | 83 | 442 | 5952 721021

T21NIR Table 41s t2l15X o 721058 ESNOR 6 control 721697 : 721AZV | 001 47 1 592 1 6899 150g c.e./ha|225g c.e./ha|ZOOg c.e./ha 721830. 1701 108130 13751 | 39 | 0 | 37 | 87 | 858 results for AVSHTN 1 ESNOR: In exper. and 721С9Т and composition 553 were the most effective compositions on the ropeway 791Н7О

Theophrastus (AVOTN) and on the plane (ESNSRE). 721191

Example 4! 7o1oVu

Aqueous concentrates of compositions containing salt 721СОР glyphosate and excipients were obtained as shown in 721АДЕ | 01 417 1 592 | 692. table 41a. 721851 | 0 1 108 | z0 | from 75 |)

Table 4a Results for AVITN and ESNSE: In the experiment, composition 721 SOR and composition 553 were the most effective compositions on the Theophrastus ropeway (AVITN). Composition 553 was the most 791148 the most effective composition of flat 727 notes (BONSYU. ad 42 721KoI imtoo rad o 71с8y 1 koi 301 85471707 Aqueous concentrates of compositions containing salt 7210ОР |. Kk | 301 856 1101 Ж (| ЖжжBBж| glyphosate and excipients, received as shown in

T2LADE | Kk 130 Yuk | | enter table 42a. 72g1v5t | Kk 30, Central Bank | | imtoo

Table 42a 64305 M121 114 | BA | 236! 652А9К ETNI2 UMITbO imToo 652885 ETNI2 UMITbO imToo 65120 ETNI2 UMITvO imO 650С75 ETNI2 UMIT6O AVT 651Не ЕТНИ2 UMITvO Аня 649025 ETNI2 UMITvO ANA 860 | 1360 17777711111111111171С111171Г11111111Гг1111г 75 | | 45 | 7771

Theophrastus rope plant (AVITN) plants and the flat methods described above. The applied plant (ESNSE) was grown and processed with the standard compositions of table 43Za and comparative compositions by the methods described above. Applications 560, 754 and 350. The results averaged for all compositions of Table 42a and comparative replicates of each processed sample are shown in compositions 139, 553, 360 and 754. Results averaged Tables 435 and 43bs. for all replicates of each processed sample, shown in Table 425 and 42c. Table 43

Table 425 AVIyITN 95 control

AVITN 95 control (127845 | 15 | 683 | 742 | 80 l2e3rgr | 08 | «33 | 783 | 867 560 | 333 | 7 | 80 | 858 and z60 | 35 | 792 | 82 | 90

Table 4Zs

ESNSE 95 control

Table 42 p

ESNSE 95 control l129AVO | 175 | 517 | 508 | 60 (64305 | 96.0 | 99.7 | 998 | 998 650s75 | 840 | 9965 | 960 | 100.0 | 560 | 525 | 60 | 617 | 692

And 754 | 60 | 625 | 6952 | 858 and z60 | 575 | 683 | 80 | 947

And 7139 | 21.7 | 475 | 600 | 855

Results for AVIOTN and ESNSE: Composition 140051 showed similar herbicidal efficiency than the comparative composition 560 on Theophrastus rope (AVITN) and showed higher efficiency

Results for AVOTN and ESNSRE: Composition than the comparative composition 560 on the plane 652A9K, 652885 and 651220 were slightly better than (ESNSRB). Composition 129020 was one of the most compositions 650275, 651H9E and 6490525 on AVIyTN. weaker ones on Theophrastus' ropeway, but

The effect of the compositions was slightly worse than the effect of the canceling composition with the 560 composition on the flat. An increase of 360. the amount of surface-active substance from 9.995

Example 43 (composition of 127AZK and 127845) to 13.295 (composition of

Aqueous concentrates of compositions containing salts 129A80 and 12987) had no significant effect. glyphosate and excipients, obtained as shown in Example 44 of table 43a. Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in

Table 4 According to table 44a. so | to | Because, tTRAEE 19877 Table Ma 56017111 5 77171711 11111110 | own | to | 49 | MEHB in 909 035 1 |55 HER ovo Go 1 69611121 212213 11771010101175701 1 of 60 | | zv0| /

Plants of Theophrastus rope plant (AVITN) and ploskuha (ESNSE) were grown and processed standard

Plants of Theophrastus rope plant (AVITN) and plots of all replicates of each processed sample, show-cooker (ESNSE) were grown and processed according to the standards in table 45b and 45c. by the methods described above. Compositions of table 44a and comparative Table 450 of compositions 139 and 360 were used. The results, average for all o repetitions of each processed sample, are shown in AVITN 95 control of tables 446 and 446. |Composition| 75g k.e./ha Y 5Og k.e./ha|225g k.e./ha|ZO0g k.e./ha 554 | 00 | 00 | 100 | from 08

Your table 00 | 675 | 8501 892 553 | 25.8 | 850 | 900 | 925

AVITN 95 ni bi2di5 | 742 | 88.3 | 900 1 908

Composition! god k.e./ha!1 5Og k.e./ha|2O0g k.e./ha| ЗО0Ог k.e./ha 612 | 00 | 267 | 817 | 842 572 ATV b12s7u | 8.3 | 767 | 867 | 900 5723 16131511 79 1 b12rar 572s2o ex b12РОР 574А3В | 33 | ride | 40 | 60 vtavvs | 701 12 | 381 62 1 612055 5lasto | 781 38 | 51 1 73 | bin tovo ov sov tva zboAr | 85 | 88 | 90 | 93

And 7139 | 0 | 9 | 1 | 39 | Table 456 of 60 | 1 360 | 68 | 79 | 86 | ESNSE 95 control

Table 44c 150 g c.e./ha|225 g c.e./pa| З00g к.е./ha 554 | 00 | 1.7 | 7133 | 242

ESNSE 95

Composition! god k.e./ha!1 5Og k.e./ha|2O0g k.e./ha| ЗО0Ог k.e./ha

BT2АТВ b12АТВ 572831. 6512В8И 5Б72с2ю 17743331 78071776 6127

BTaAZV | 22145 | 53 1 68 SDR 5Taves BIV 5TASTO BIZOYE

ЗБ0АЮ | 77631821 801 8551 612050 bignvg | oo 1 88 1 50 I 850

Results for AVITN and ESNSE: the most

Results for AVOTN and ESNSE: In the experiment, the most effective composition on the Theofrast cableway was composition 721С9Т and composition 553. 612А15 was the composition. The most effective composition was 553. Example 46 Water concentration (ESNSE). Example 45 Aqueous concentrates of components were obtained as shown in table 46a. compositions containing glyphosate salt and excipients were obtained as shown in table 45a. Table of food

Table 45a 607 AZ C opening

Б12А15 607С4 5128 607048 612С7У 607Е5Н б12р4Р бО7Е6Р 61?ЕЖХ 607570 б12ПОР . 612455 Theophrastus rope plant (AVITN) and 6b12H5t kuhu plant (ESNSE) were grown and processed according to the standard methods described above. Apply-

Plants of Theophrastus rope plant (AVITN) and flat compositions of table 4ba and comparative kuhu (ESNSE) were grown and processed with standard compositions 554, 754 and 553. The results are average for them by the methods described above. Applying all repetitions of each processed sample, the compositions of table 45a and comparative ones in table 466 and 46c appeared. compositions 554, 754 and 553. Results, average for

Table 466 Plants Theophrastus rope plant (AVIOTN) and Plos- o kuchu (ESNSE) were grown and processed standard

AVITN 75 control by the methods described above. Applied- ongeonia ve Ketle rZhogteLerovet lovlya Saliva Tu orenAlen 754-001 35 vo5 in all repetitions of each processed sample, show- 553. | 00 | 742 | 892 | 933 | no table 1476. 6b07Aza | 00 | 00 | 308 | 642 bvo7vl | 642 | 81.7 | 892 | 900 | Table 475 6бО7EB5Н 6О7ЕвР AVOTN Ze control bo7a7o | Composition | 50g k.e./ha M bOg k.e./hai2OOg k.e./hai4O0g k.e./ha 139, | 00 | 225 | 808 | 917

Table 1 of

IT IS IN THE CONTROL OF 187ATV

Composition) 75g CU/ha 1 50g CU/ha | 225g CU/ha | ZO0g k.e./ha vsR ov | 001 001 15001 275 | | 487S1R | 875 | 925 | 978 | 987 7754 | 00 1 283 | 7001 725 | 487OBH zVleBA | 88 | 800 1 975 883 b07Aza 1 001 1081 5501675 487g9t | 850 | 90.0 1 96.7 | 99.7 50787 487038 507EBN 496AZO 6076. | 00 | 00 | 292 | 542 607270 | 00 | 650 | 725 | 733 | Table 47c and ESNSE 95

Results for AVOTN and ESNSRE: Composition » control 6078 71 was the most effective on the ropeway IComposition| 5Og k.e./ha POOg k.e./ha|2O0Og k.e./ha| 400 g c.e./ha

Theophrastus and composition 607AZ C was the most | 39 | 00 | 557 | 683 | 883 more effective than 607Eb6R, both on the Teofras-100.0 cableway and on the flat (ESNSRE). Example 47 Aqueous concentrates of compositions containing glyphosate salt and 487A75 100.0 100.0 excipients were obtained as shown in table 487821 100.0 47a. 487С1Р 100.0 100.0 48705Х 100.0

Table 47а 487Е5В 100.0 48797 100.0 487838 100.0 487А75 496 АЗ О 100.0 487821

А487С1Р Results for AVOTN and ESNSRE: All 48705X compositions, with the exception of 487А75, were the most effective

А87Е5Н by them in comparison with compositions 360, 553 and 139 on 487Е9Т ropeway of Theophrastus (AVyTN). Example 48 Water

ToEAZE Ethno concentrates of compositions containing glyphosate salt 48a.

Table 48a

O31E32 | K | 485 | Sepg./ | 90 | Here you are sleeping 60 | Sepi | 30 oz1M5V Eto | 60 | Sep3 | 30 оз1М3О Ето спыш ши 031501. EFft2 | 60 | Sepi/ | 20,265 | K | 391 | 558 2 | 100 | / /

EFft2 65 | / / 0754 | IRA | 445 | .ЙЙ//СС/Й SGS

The plants of the Theophrastus rope plant (AVITN) and plot compositions 139, 554 and 754. The results, the average for the kitchen (ESNSE) were grown and processed by the standard of all repetitions of each processed sample, shown by the methods described above. Used in table 485 and 48p. there were 234 compositions of table 48a and comparative ones

Table 486 Table 48p

AVITN 95 control ESNSE 95 control 554 | 00 | 00 | 167 | 700 | 554 | 00 | 33 | 117 | 467 139, | 00 | 150 | 300 | 775 | 139 | 08 | 192 | 150 | 358

Results for AVITN and ESNSRE: Compositions 265 and 769 had the same herbicidal efficiency in comparison with 754 on Theophrastus rope plant (AVITN) and on flats (ESNSRE). Example 49 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 49a.

Table 49a at 015А6О 171 KO | 391 | 8585. | 131 | / ! HER

And bg4OR | K | 485 | 586 2 | 131 | yen | 65

And b24Va | KO | 485 | 2 sh 587 | 91 | in 2 | 9 | 4

Theophrastus rope plant (AVITN) and plantain plants 754 | 458 | 808 | 875 | 90 kuhu (ESNSE) were grown and processed by the standard methods described above. The compositions of table 49a and comparative Results for AVOTN and ESNSRE were used: Composition of compositions 139, 554, 754 and 360. Results, average 024EOR had a high herbicidal efficiency for all repetitions of each processed sample, red of all comparative compositions on AVOTN. Com- shown in table 496 and 49p. position 02401X had a high herbicidal efficiency in comparison with comparative compositions

Table 496 139 and 554. Compositions 015А6О, 024А5О and 024821. showed increased herbicidal efficiency in

AVITN 75 control compared with comparative compositions 139 and this, containing glyphosate salt and excipients, oder" 015А6О | 55 | 80 | 867 | 892 | ; chewed as shown in table 50a. omosm! 01 01 17 1 17 Table 50a about greyhound | 292 | 808 | 825 | 90 7139, | 0 | 715 | 733 | 758 | O15VgA TT CAT 58511261 554 | 08 | 20 | 717 | 808 754 | 4588 | 808 | 875 | 90

Table 49o 7139 | 1570 |!

ESNOE 95 control of 170175, 252111 360 | |366th TV Hor

Plants Theofrast’s rope plant (AVIOTN) and ploskuhu (ESNSE) were grown and processed standard

Gog4sz3mMI 001 0 117 117. | by the methods described above. The compositions of table 50a and comparative compositions 139, 554, 754 and 360 were used. Results, average 13910115 1 733 | 758 for all replicates of each processed sample, 554 | 08 | tho | 717 | 808 | shown in table 506 and 50c.

Table 506

Table 50 p

AVITN 95 control

ESNSE 95 control 139 | 0 | 75 | 617 | 758 554 | 0 | 183 | 742 | 792 | 7139 | 08 | 67 | 35 | 525 | 08 | 28.3 | 483 | 558

And from 60 | 60 | 825 | 875 | 942

And call | lo8 | 558 | 767 | 80 K

Results for AVITN and ESNSRE: All compositions showed great herbicidal efficiency in comparison with compositions 139 and 554. Example 51 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 51a.

Table 51a 2651 | K | z91 17777885... | 1056 | 7 Y1777777S/y1711111111111111111Y1 76985 | Kk | 490 1 2 7596 | 0 ETHNIS -/| b | 71171 o 767a2 | K | 510 | l816E | 5005 | AVOZY | 55

BOM | CC | 5 1 mi: | 995 | Her her g HER 563R5 | K | 540 | ееТНИ2 | bbvl | ..G/S/SIYMLMKS//СЇ111717 11111111

Compositions 67719 and 563P5 additionally contained Table 510 102 g/l ethylene glycol. Compositions of table 51a and - comparative composition 754 were sprayed in

Egedeigiskerigd, Texas on 2-3 inch tall Nettle Stem Wrapping Nettle (-AMAM), a common winter annual that is usually treated with KOSHSHMOSHR OSTKAF in the pre-sowing period. The results averaged over all replicates of each 7756006 621 7231 7381 82 treatment are shown in Table 516,

Example 52 238 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 52a.

Table 52a 560 | K | 540 | mi |135Y Shshch | Her Her Her 95902 | K | 480 | is TNI2 | 48 | UMT8O | 48 | imtoo | 24 95904E | K | 480 | ETHNIC? | 48 | UMTO5 | 48 | imtoo | 24 | glickl | Z3 47820 | K | 480 | ETHNIC? | 48 | UMTO5 | 48 | imtoo | 24 | glickl | 120 9605927 | K | 540 | are there shadows | 61 | UT | 74! !/!/ / her

And evonZzS | KO | 540 | ETHNIC? | 61 | UMTO5 | 74 | (Р | | sglikl | 34 478Е6К | Кк | 540 | etni? | 61 | UMto5 | 74 | -( | | sglikl | 102

And 9b0Mx | K | 540 | Eetni? | 68 | UMTO5 | 68| !/ !/!/ / 96008) | K | 540 | ETHNIC? | 68 | UMTO5 | 68 | | | glickl | 34 v93M | Kk | 540 | etni2 | 68 | Umto5 | 68 | - | | glickl | 102

Lemon acid is a good thing. | 0001111 ek |rfyarovnyu i te, 00110111 and Z60 IRA z360 HER 777 HER Г111111111111Г11111111Г111г11 (754 | RA | 445 | UyTO5 | 59 | im | 2 | HER Her yG

Plants of Theophrastus rope plant (AVITN) and plantain Theophrastus plant plant (AVIOTN) and plantain plant (ESNSE) were grown and processed in standard - plant species (ESNSE) were grown and processed according to the standard methods described above. Applied by the methods described above. The compositions of table 5ba were used and the compositions 240 of table 53a and the comparative compositions 554, 754 and 360 were compared. The average results for compositions 139, 554, 754 and 360. The average results of all repetitions of each processed sample are shown for all repetitions of each processed sample, not in table 5265 and 526. shown in table 5365 and 53c.

Table 5265 Table 535

AVITN 95 control AVIyITN 95 pain control | 33.3 | 7Ub/ | 867 | 90 95902) | 55 | 81.7 | 883 | 90 | | 354В5У | 08 | 38.3 | 583 | 767 95904E | 61.7 | 80 | 8853 | 90 | And z5asaMM | 25 | 45 | 6952 | 80 47820 | 433 | 80 | 90 | 90 | | 35404E | 08 | 50 | 60 | 75 9600927 | 36.7 | 83.3 | 8853 | 90 ebonZsS | 46.7 | 80 | 90 | 933 4786 | 36.7 | 80 | 90 | 95 9b014x | 65 | 80 | 90 | 8917 9608 | 28.3 | 833 | 85 | 90,693 MO | 5 | 767 | 85 | 90 187A7M | 16.7 | 75 | 90 | 93 | Four out of six compositions were similar in effectiveness to standards 754 and 360. Two tests 754 | 75 | 883 | 97 | 96 | the remaining ones were slightly less effective on the Theophrastus ropeway than the standards.

Example 54 Aqueous concentrates of compositions that

Table 52c contains glyphosate salt and excipients obtained

ESNSE 96 control as shown in table 54a.

Table zma - - evoov 1 500031 66713801 91

St87Aya 1 4331 6671 78331907

Theophrastus rope plant (AVIOTN) and plantain plants

In this test, standards 360 and 754 beech (ESNSR) were grown and treated standards with the best compositions. Adding them in the ways described above. The application of glycols and citric acid had a slight effect on the compositions of table 54a and comparative efficiency. Example 53 Aqueous concentrates of compositions 139 and 554. Results averaged for all items containing glyphosate salt and excipients. replicates of each treated sample shown in were obtained as shown in Table 53a. tables 546 and 54.

Table 53a Table 545

Compo- Compo- Compo- AVITN 95 control - Salt |g k.e./l g/l g/l this |ilrekely| demtt |U merto | "7. zB4dYAE | KOI 46071 mti3 1081 eTNI5 1057

ZBaVBM 1 berths 460.1 Mti3 1091 ETNI? 104 35490 1 KO 480.1 Mti3 1081 ETNI? 104

Table 55 p

ESNOR 95 control and | 70101 27

Table 54 p

ESNSE 95 control 754 | 73.3 | 817 | 90 | 972

And LmMA | 60 | 6952 | 65

The K salt composition was not performed better than composition 360 or composition 754 for the control of Theophrastus ropewalker. 243 Example 56 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 5va.

Body 5va t Component 3 Component i C 7 9 1 5ia 1 3773

Example 55 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 55a. 73406 | Kk 30| sh | | ReReovo | 10.0)

TOPIC | K | 43 | 516 |14

Table 55a 737090 | Kk |43| 520 |14 and 737о6н | Kk | 30 | 521 |100Y

PES for C data omposition)| Salt |g k.e./l g/l g/l y 1 2 Plants Theophrastus rope plant (AVITN) and plantain azagat | K | 480 | Mi21 |90 / AVO27 | 930 | Kukha (ESNSE) was grown and processed according to the standard itself 190 VO 60 by the methods described above. The compositions of table 5ba and comparative azdgo | were used Ko avo | could | 90) ARObo | 307 Mlo higher, compogids ee, vve gg sezulgyati, average for all repetitions of each processed sample, tva PRA! 445 (M | 1 | | are shown in table 560 and 56p. 360 IRA! zbo | Ulto5 |59|1 shЩ 554 |K|725| 2 sh | | imtoo | 2.2 Table 565 o,

Plants of Theophrastus rope plant (AVITN) and plantain AVOTN Z control kitchen (ESNSYU) were grown and processed standard" by the methods described above. Applied - | 734А2О |. 010 | 35: | 575 | 70. 1 compositions of table 55a and comparative compositions 139 . 792 737090 | 0 | 467 | 708 | 775

Table 555 737о6н | 0 | 46.7 | 758 | 775 554 | 0 | 0 | 408 | 583

AVITN 95 control and z60 | 0 | 75.8 | 825 | 883

Table 56 p

ESNSE 95 control at 4z49u7u | 56.7 | 667 | 81.7 | (90

And from 60 | 725 | 80 | 85 | 942 tZaELA | 175 | 60 | 675 | 70 (737090, 0 | z5 | 525 | 77

737Оо6Нн Table 575 554 | 0 | 17 | 92 | 242"

AVOTN control

Composition 75g c.e./ha 1 5Og c.e./ha|225g c.e./ha| З00g c.e./ha

All compositions containing glucamine, one or 6b63VVK 0 | 0 1 0 1 0 under these 6б3сз3мМ| 0 | 0 | 0 HER 0 in combination with РОО69, were less active than com- ! : : z54AdOV| 0 | 0 | 0 | 0 position 360 on the Theophrastus ropeway and the plane. 5687 1 08177010

Example 57 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained by vvsgM | 0110 | 9 | 9' 558A HER 0101010 as shown in table 57a. 754 | 25 | 80 | 867 | 898 75 | 0 | 708 | 808 | 85

Table 57a and C8 375 | 80 | 90 | 892

Toispaomi and (MAM) 1 2 663v8K РОобО ETНИ2 Table 57с 663сЗМ РООбО ЕТНИ2 564АОВ РООбО ЕТНИ2 ESNSE 95 control 56887 РОа0б9 ETNI2! 10.8 568С2U raovz ETNI5 Composition 75g c.e./ha P 50g c.e./ha|225g c.e./ha|ZO0g c.e./ha

Z68 Achi. Rob |96| ETNI5 b63zVaK | 42 | 08 | 0 | 25 v63szmM| 0 | 08 1 0 1 5 1. Also contains 336 Ego 564008 56887/U | 0 1 0 | 75 | 08 ! 55802 | 0 | 0 11 0 1 0

Theophrastus rope plant (AVITN) and plantain plants 568 | 00 | Щ06ХХ.16Х..006.0ХХ.16Х..0.1 kuhu (ESNSE) was grown and processed by the standard methods described above. Applicable - 765 | 133 | 55 | 60 | 65 / were the compositions of table 57a and comparative compositions 318, 765, 754. The results, average for Toispaoma and 10 52.5 55.8 of all repetitions of each processed sample, are shown in tables 5765 and 576.

Compositions 754, 765 and 318 showed better control on both the Theophrastus ropeway (AVIOTN) and flat sea (ESNSRE) than Toispaoulp IO. Example 58 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 58a and table 586.

Table 5va 67632 ETNI2 UMIT8O IimToo 677ROK ETNI?2 Ut8o imTOO 678430 ETNI2 UMIT8O | 66 | 5 sh imtoo 562А1В ETNI? 2 TUESDAY 5 90 1 HER. 56319 ETNI2 UMITO5 74 | Sh( G 5646. ETNI2 68 | UMITO5 68 76725 | Kk | mo /Y/ (0/7 1816E ANVOZ7 767860. | K | 50 /! Shsh( her | 1816E ANOZ7

Z60 | IRA | from 600 | HER І17777777777711711711111171с111111111111g 754 | RA | 445 | Her Her r Her 117

Theophrastus rope plant (AVITN) and 5BZIZM Kuhu plant (ESNSE) were grown and treated with standard 5bAMbI. by the methods described above. Applies- 76725 | 49 | 83 | 86 | 89 compositions of table 58a and comparative 767860 | 70 | 75 | 83 | 89 compositions 139, 765, 754. Average results for I 360 | 73 | 86 | 90 | 95 of all replicates of each processed sample are shown in Table 580 1 580.

Tab 58r0 aolitsia Table 58c o,

AVITN 95 control ESNSE 96 control

Composition 1 god k.e./ha| 1 50g c.e./ha |(200g c.e./ha| |200 g.e.u./ha| З00Og.e.e./ha 67TROK BLBEZA 66 1,896 FOR 1,558,677 YEAR 678/3С | 32 | 73 | 80 | 87 | import 562А1В : :

562A1B | 66 | 92 1 946 | 994 | All compositions of potassium salt were minimally effective on the Theophrastus ropeway, compared to com- 564Mb | 62 | 90 | 968 | 98.6 | position 360 and composition 754. The effectiveness of the amine and phosphate ether compositions on ESNCE were almost completely equivalent to compositions 360 and 754. Example 59 Aqueous concentrates of composition 8-2 containing glyphosate salt and excipients were obtained as shown in table 59a.

Table 59a entry | Kk; 30 | sh(Mk | | utvo | 6 9v9AgO | Ko 130 17777177 17111111 Umtvo 17 6 | im | 15 98339 | Kk | 30 | in TNI? | z | uUtvoO | z 989870 | Kk | 30 | is TNF | 6 | (17777717 fo имтоо | 15 в9с3А | Кк | 30 | в еТНИ? | | uUmtvo | 6 | иимтоо | 15 7360 | RA | 360 | / ІІ / ІІ ІІ 754 | РА | 445 | Uyto5 | 59 | mo | 2

Plants of Theophrastus rope plant (AVITN) and ploskukha (ESNSE) were grown and processed standard- I z60 | 57 | 83 | 895 | 91 in the ways described above. Apply- | 754 | 54 | 83 | 88 | 90 compositions of Table 59a and comparative compositions 360 and 754. The results averaged for all Table 59c replicates of each processed sample are shown in Tables 596 and 59c. ESNSE 595 control table 596

AVOTN with" control over | 11 | 54 1 59 | 66 1

Sevzih3 48 10801085 1080 989870) 2 | 4 | 53 | 60

Sevedao | 64 1 82 1 87 1 89 1

Sevevlyui 01 88 | 811 83

Seveszia | 74.1 8 | 8719801 vm 7511 89182185 I 754 | 0 | 55 | 59 | 76 /

Example 60 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in the table below.

Table bba

And bi3a1A 1 KO | 550 | mi | ol | t2zE2 | 24 | | g shU!U6

Theophrastus rope plants (AVITN) and plot- compositions 139, 360, 554 and 754. Results, medium kuhu (ESNSE) were grown and processed standard- for all repetitions of each processed sample, by the methods described above. Applicable - shown in table 605 and boss. there were compositions of tables bbOa and comparative

Table 600 Table boss

AVITN 795 control ESNSE 95 control (Composition 1 00g k.e./ha 5Og k.e./haI(2OOg k.e./ha | З00g k.e./ha бАЗО1А | 96 | 997 9958 | 998 652AVI bBeVYAN b5TETN

BBOsBU 549s6M 1 5581 5331 8018977 I 6zinZH| 93 | 98.3 | 975 | 998 blzobm | 928 | 952 | 98 | 100 / 139 1217 | yal5 | 60 | 855

Example 61 249 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained as shown in table 61a.

Table 6b1a 48404) | CC | 369 | EM | 6 | Tue5 | 6 484R6R | CC | 369 | AEU | 12 / Her 484670 | Kk | with 36959 | Shshch HER 1 Tue5 | 12

Theophrastus rope plant (AVITN) and 484871 kuchu plants (ESNSE) were grown and processed by the standard (А84С4) methods described above. 484048 compositions of table b'a and comparative 484E5H compositions 553 and 554 were used. Results, average for all tvaBO repetitions of Y R BBabova; 00101 13331 25. 1 b5a (445/l) 3.3 | 78.33 | 85 | 875 tabulates rBZobopl| 6331 842 1 817-195

AVITN 95 control Example 62 Aqueous concentrates of compositions containing glyphosate salt and excipients were obtained

Composition 1 0Og c.e./ha/150g c.e./ha|20Og c.e./ha| 300 g c.e./ha as shown in table 62a. 4843

Table 6b2a

VAIB56 ETN25 | 96 CC with 97 OAZM EHROA jur 970870 EHROV lo 11 9700s00 EHROS og 970025 EHROA EMO. | 6 970E5B ECHROV EMO. | 6 97040 EHROS EMO. | 6

Theophrastus rope plants (AVITN) and plot- compositions 139, 360, 554 and 754. Results, medium kuhu (ESNSE) were grown and processed standard- for all repetitions of each processed sample, by the methods described above. The compositions shown in Tables 625 and 626 and Table 62a and comparative compositions are applied

Table 625 478840 ЕХРВб УМИТО5 478080 ЭХР8Е | 6 | ULTO5 | 6

AVITN 95 control 478068 EHRV6 UMTO5 478E27 EHRV6 UMTO5

Composition 1 boh c.e./ha|150g c.e./ha|200g c.e./ha| ЗО0Ог к.е./ha 4785. EHRVYE | 12101 97OAZMI 47tvsam| Kk |zva| 1 | Uytob 97087

OO Roslyny ropeway of Theofrast (AVIOTN) and flat-

ZTOEBA is applied in the ways listed above. 97040 by the methods described above. The compositions of table bZa and comparative compositions 139, 360, 554 and 754 were used. The results, averaged for all repetitions of each treated sample, are shown in table 636.

Table b2s Table 635

ESNSE 95 control AVITN 75 control

Composition 1Og k.e./ha M5Og k.e./ha|gOog k.e./ha| 300g k.e./ha (Composition 1 0Ogk. e./ha|1 5Og k.e./ha|200g k.e./ha| 30Og k.e./ha 970AZUU | 15.71 375 | 42561 80. 970870 478А25 970000 478840 970025 478280 970Е5В 478068 97040 | 08 1 375 | 442 1 492 478Е27

And 554 | 0 | 17 | 33 | 193 | 478 EBU | 0 | 258 | 567 | 767 z78s4M zvasavt; 0 | shzh0 | that | 25,754 | 1588 | 467 | 475 | 60 | t5a(a5ot)| 0 | 192 | 65 | 80 /

Example 63 Aqueous concentrates of compositions that EHRZ6 and UMITO5 were all identical in execution, containing glyphosate salt and excipients, were obtained for the control of Theophrastus ropeworm. 754 was as shown in table 63a. less effective than only UMITO5, but more effective than only 868. All Z were less effective

Table bZa ktive than any mixture. Example 64 Aqueous concentrates of compositions containing glyphosate salt and other excipients Component 95 Component 95 were obtained as shown in the table

Composition Salt (MLM) 4 (mMy/LlM) 2 (MILA) owner.

VAB6 ETN25 | 9.6 478А25 ЭХРВ6 УТО5

Table b4a 622Н7 M121 lo GG 56OR2 M121 135. HER 23918 M121 NE POLYN PON PO NO 676U5 ETHNI?2 Ut8o IMTOO 6772 ETHNI2 UMITVO imo 767K9 1816E AVOZ7 151 ShchshiII

Plants of Theophrastus rope plant (AVITN) and plantain 6765 | 1251 60 1777 1 767. kukha (ESNSE) were grown and processed by the standard 6772 methods described above. Apply- tbtke | 18.3 | 658 | 80 | 833 compositions of table b4a and comparative | 139 | 0 | 175 | 50 | 683 compositions 139, 360, 554 and 754. Results, average 754 | 30 | 683 | 80 | 908 are shown in table 646 and 64p. :

Table 646 Table 64p

AVITN 95 control ESNOR 75 control

Composition 1 boh c.e./ha|150g c.e./ha|200g c.e./ha| ЗО0Ог к.е./ha Composition 100 гк.е./ha 50 г.е./ha|200 g.е./ha| 300 hq.e./ha b22n bog | be 1 le 18010958 5BORonya 23918 hav | in 1 va5 | in | you

And 765 | 433 | 558 | 60 | 733

The cloud point was determined for certain liquid compositions of examples 66-69, as indicated below. An example of the composition in a test tube was heated in a water bath until it became cloudy. test tube,

The composition of the potassium salt of glyphosate was not investigated, then removed from the water bath, effective as compositions 754 and 360. The two compositions of the sample were mixed, determining the temperature under the potassium salt, both with a surface-active rheometer, until it became transparent wine with a ratio of 3:1, were close to The temperature at which the sample became transparent, the efficiency of both standards. Example 65 Water was recorded as the cloud point of the composition. Pro-concentrates of compositions containing glyphosate salt cents, marked as "9o" in the following examples, and excipients, received as shown in the table are wt./wt., unless otherwise indicated. bza Example 66 The surfactants used in example 68 are UMisatipe

Table b5a TAM-60, ethoxylate of talloamine with 6 moles of ethylene oxide. Component of the component of oxide, M/ysatype TAM-80, ethoxylate of talloamine with 8 moles of ethylene oxide and Misotype TAM-105, ethoxylate

Gb56A2O | KO 14801 MANVOB | 60 | ULT8O 1 60 talamine silate with 10 moles of ethylene oxide. Aqueous (65688 | K | 480| MAVO5 | 54 | UMT8O | 66 | concentrates of the compositions of example 66 were obtained by mixing the following components: (1) an aqueous concentrated solution of glyphosate in the form of a potassium salt; (2) a surface-active substance such as 23984 | K |480| mii7 |t120| | | indicated above; and (3) water. The composition may be

And 46007 | Kk 480| mi21 |135| (| | calculated for the content of 360 grams/liter of glyphosate (29.095 CU) of glyphosate and 90 grams/liter (7.2595) of surface

Plants of Theophrastus rope plant (AVITN) and plos- active substances. The specific mass of the composition when cooked (ESNSE) was grown and processed by the standard 20/15.6"С and was determined as 1.25. The cloud point was determined by the methods described above. The applied composition of each surface-active composition was determined, and the compositions of table B5Ba and comparative ones were determined as shown below in the table.compositions 360 and 754. The results averaged over all replicates of each treated sample are shown in table 655 and 65c wine

Table 655

AVITN 95 control

Example 67 Surface-active substances of example 67 were studied with the maximum addition of potassium glyphosate. Water concentrate compo- o v5bvvI | 408 | 80 | 875 | 97 | zition, containing 450 grams/liter c.e. (346905 keu) of potassium salt of glyphosate and 6.9295 of surface-active substance was obtained using a method similar to example 66. Specific mass of com- 46007. 1 4751 80 | 8831 91.71 positions at 255 2015.670 was determined as 1 30.

The cloud point of each surfactant composition was determined as shown in the table below. fault

Table b5c

ESNSE 95 control

Example 68 The surfactant used in Example 68 was EtToteep

C/15 (ethoxylated cocamine (15EO)). Water 656VVI | 30 | 51.7 | 625 | 633 | concentrate composition containing 606 grams/liter of 656С6U | 392 | 567 | 60 | 70 | k.e. (29096 keu) of glyphosate potassium salt and 5.0595 surface-active substances were obtained by a method similar to example 66. Specific mass

COMPOSITION at 20/15, was determined as 1.399.

The cloud point of the composition was determined as 7276. Example 69 The surfactant used in example 69 was

Nipivtap bipopis DSM-550 (M121). Water con- Table 706 concentrate composition containing 486 grams/liter c.e. (36,695 k.e.) of potassium salt of glyphosate, 22 grams/liter AVITN 95 control of higher and higher acne substances: o 6b75Ag2I | 00 | 650 | 800 | 850 by a method similar to example 68. The specific gravity (6759 | 00 1 6892 | 850 | 850 of the composition at 20/15.67"С was determined as 1.329.

The cloud point of the composition was determined to be 675045 | 392 | 825 | 900 | 908 70"C. Example 70 Aqueous concentrates of compositions containing glyphosate salt and excipients are obtained (67525 | 45.0 | 792 | 892 | 900) as shown in table 70a.

Table 7ba 554 | 00 | 00 | 7133 | 533 (553 | 800 | vv 1 917 | 942

Table 70 p

ESNSOE 95 control 754 | |75| HER 754 | (545 9

And 553. GO | |z0Yi

Plants of Theofrast's rope plant (AVITN) and flat plant (ESNSE) were grown and processed according to the standard methods described above. Apply- | 0203554 | 00 | 17 | 50 | 300 were the compositions of Table 7bOa and the comparative compositions 553 and 554. The results, averaged for all repetitions of each treated sample, are shown in Tables 705 and 70c. "Sh them." . i VK Kaya u a sv U V o KK A i i VENY m .

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Ministry of Education and Science of Ukraine

State Department of Intellectual Property, str. Urytskogo, 45, Kyiv, MSP, 03680, Ukraine

SE "Ukrainian Institute of Industrial Property", str. Glazunova, 1, Kyiv - 42, 01601