UA108670C2 - FILM OF THE SMOKING DEVICE (OPTIONS) AND THE SMOKING DEVICE (OPTIONS) - Google Patents

Abstract

Filters, smoking devices, related products and installation, and methods are disclosed. The filters include porous masses containing the active particle and the binder particle, where the active particle comprises carbon, and the porous mass has a carbon filling of at least about 6 mg / mm, and a pressure drop in the capsule of about a water column or less than mm of porous mass.

Description

The field of technology

The proposed application relates to a tobacco smoke filter for a smoking device containing an element that improves the characteristics of the smoke passing through it.

Technical level

The World Health Organization (WHO) has proposed recommendations for reducing certain components of tobacco smoke in the document MUNO Tesppis! Kerogpi Zegieh5 Mo. 951, Te zsiepiyis Vazi5 oi Torasso Rgodisi Kedshiayop, Uupo Neaipt Ogdapiganop (2008). In it, WHO recommends that certain constituents such as acetaldehyde, acrolein, benzene, benzopyrene, 1,3-butadiene and formaldehyde, among others, be reduced to levels below 12595 of the median values of the data set. Taking into account the new international recommendations related to standards for tobacco products, there is a need for new tobacco smoke filters and materials used in the manufacture of tobacco smoke filters that are able to meet the requirements of these standards.

It is known to use carbon filters of tobacco smoke to remove components of tobacco smoke. Such filters include filters with carbon on a bundle of fibers and carbon particles contained inside the filter chamber. US Patent No. 5,423,336 discloses a cigarette filter with a chamber filled with activated carbon. Published US Patent Application 2010/0147317 discloses a spiral channel cigarette filter where activated carbon is adhered to the channel walls. zZV1592952 discloses a cigarette filter where a body of continuous fibers surrounds a core of sorbent particles (eg, activated carbon) bonded together with a thermoplastic binder (eg, polyethylene and polypropylene). UMO 2008/142420 discloses a cigarette filter where an absorbent material (e.g., activated carbon) is coated with a polymeric material (e.g., polyethylene in an amount of 0.4-5 wt. MO 2009/112591 discloses a cigarette filter that produces little or no dust , with a composite material including at least one polymer (for example, polyethylene) and at least one other compound (for example, activated carbon).

The technology of carbon blocks is known, where activated carbon is formed with a binder into a monolithic porous block. In US patents MoMo 4753728, 6770736,

From 7049382, 7160453, and 7112280 carbon block technology using low-melting flowable polymeric binders is mainly used in the form of water filters.

Accordingly, there is a need for a porous mass containing active microparticles that can be used in a smoke filter, and the smoke filter has a pressure drop in the capsule, which is convenient for use by the consumer.

The essence of the invention

The application considered here relates to a filter containing a porous mass having an element that improves the characteristics of the smoke passing through it. In some embodiments of the invention, the filter is built into the smoking device.

In one embodiment, the present invention provides a filter that includes: a porous mass that includes an active particle and a binder particle, where the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least , single wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, bamboo-type carbon nanostructure, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, nanoparticles aluminum, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms, endofullerene, C4(FSbO), core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle and any combination thereof.

In one embodiment, this invention provides a smoking device that includes: a sleeve for a smoking substance; and a filter including a porous mass that includes an active particle and a particle of a binder, where the active particle includes an element selected from the group consisting of 3: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with trumpet-shaped nanoprotrusion, bamboo-type carbon nanostructure, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles , superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, 54FSbO, core-shell nanoparticles, bulbous nanoparticles,

nanoshell, bulbous nanoparticle of iron oxide, and any combination thereof.

In one embodiment, the present invention provides a smoking device filter comprising: at least two adjacent sequential sections, wherein the first section comprises a porous mass comprising an active moiety and a binder moiety, wherein the active moiety comprises an element selected from the group consisting of consists of 3: a carbon nanoparticle, a carbon nanotube with at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, nanoparticles metal, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, C4(FSbO, core nanoparticles -shell", bulbous nanoparticle, nanoshell, bulbous nanoch iron oxide and any combination thereof; and wherein the second section comprises a section comprising a member selected from the group consisting of: cavity, cellulose acetate, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, random orientation acetate, paper, corrugated paper, concentric filter , carbon on a bundle of fibers, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon, flavoring, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particles, carbon fiber, fiber, glass bead, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the present invention provides a smoking device comprising: a filter comprising a porous mass comprising an active moiety and a binder moiety, wherein the active moiety comprises an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube , having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells , bulbous nanoparticle of iron oxide and any combination thereof; and a sleeve capable of holding the smoking substance in interphase contact with the filter.

In one embodiment, the present invention provides a filter pack comprising: a pack comprising at least one filter, wherein the filter comprises a porous mass comprising an active moiety and a binder moiety, and wherein the active moiety comprises an element selected from the group , consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a trumpet-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, an iron oxide nanoparticle, a nanoparticle , metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, 54FSbO, nanoparticles of the "core" type -shell", bulbous nanoparticle, nanoshell, bulbous hall oxide nanoparticle for and any combination thereof.

In one embodiment, the present invention provides a pack of smoking devices comprising: a pack comprising at least one smoking device comprising a filter comprising a porous mass comprising an active moiety and a binder moiety wherein the active moiety comprises an , selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, a nanoparticle iron oxide, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, C4YFSbO, nanoparticles of the "core-shell" type, bulbous nanoparticles, nanoshell onka, bulbous nanoparticles of iron oxide, and any combination thereof.

In one variant of the embodiment of the invention, this invention offers a cardboard package of packs of smoking devices, which includes: a cardboard package, which includes at least one pack, a pack, which includes at least one smoking device, which includes a filter, which includes a porous mass, which includes an active moiety and a binder moiety, where the active moiety includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles , magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endoph lerene, С4ФФСбО, nanoparticles of the "core-shell" type, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment of the invention, the present invention provides a method of smoking a smoking device comprising: heating or igniting the smoking device to produce smoke, wherein the smoking device includes at least one filter section comprising a porous mass that includes an active portion and a binder portion substance, and where the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tubular nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene , low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included atoms of gadolinium, endofullerene, C4(F SbO, core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof; drawing smoke through a smoking device, where the filter section reduces the presence of at least one component of the smoke compared to a filter without a porous mass.

In one embodiment, this invention offers a method of manufacturing a porous mass, which includes: providing a mixture that includes active particles and particles of a binder; wherein the binder particles comprise a thermoplastic material and the active particles comprise an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tubular nanoprotrusion, a carbon nanostructure of the "bamboo" type , fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, nanoparticles hematite, magnetite nanoparticles, nanotubes with included atoms of gadolinium, endofullerene, С4ФФСбО, nanoparticles of the "core-shell" type, bulbous nanoparticle, nanoshell, bulbous nanoparticle of iron oxide, and any combination thereof; placing the mixture in a mold; heating the mixture in the mold to a temperature equal to or greater than the melting temperature of the binder particles, so as to form a porous mass; and removing the porous mass from the mold.

In one embodiment, the present invention provides a method of making a porous mass comprising: providing a mixture comprising active particles and binder particles, wherein the binder particles comprise a thermoplastic material and the active particles comprise an element selected from the group consisting of consists of: carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticle, nanoparticle, nanoparticle metal, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, С4ФФСбО, core-shell nanoparticles ", bulbous nanoparticle, nanoshell, bulbous nanoparticles of iron oxide and any combination thereof; heating the mixture; and extruding the mixture while it is at an elevated temperature so as to form a porous mass.

In one embodiment, the present invention provides a method of manufacturing a filter mouthpiece, 60 and the method includes: providing a first filter section; providing at least

one second filter section, wherein the second filter section includes a porous mass that includes an active particle and a binder portion, and where the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least single wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, bamboo-type carbon nanostructure, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles , magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms, endofullerene, 54FSbO, core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle and any what their combination is; and combining the first filter section and the at least one second filter section to form a filter mouthpiece.

In one embodiment, the present invention provides a method that includes: providing a container that includes at least a collection of parts of the first filter section; providing a second container that includes at least an assembly of parts of the second filter section, wherein the parts of the second filter section include a porous mass that includes an active portion and a binder portion, and where the active portion includes an element selected from the group consisting of: carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a horn-like nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, nanoparticles gold, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, 54ФСбО, core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous nanoparticles oxide iron and any combination thereof; joining part of the first filter section and part of the second filter section butt along the longitudinal axis of the part of the first filter section and part of the second filter section to form an unwrapped

From the filter mouthpiece; and wrapping a portion of the first filter section and a portion of the second filter section with paper to form a filter mouthpiece.

In one embodiment, the present invention provides a method of manufacturing a smoking device comprising: providing a filter mouthpiece comprising at least one filter section comprising a porous mass comprising an active moiety and a binder moiety, and wherein the active moiety comprises an , selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, a nanoparticle iron oxide, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, for FeSboO, nanoparticles of the "core-shell" type, bulbous nano particles, nanoshells, bulbous nanoparticles of iron oxide and any combination thereof; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two smoking device filters containing at least one filter section that includes a porous mass that includes an active portion and a binder portion; and connecting at least one of the filters of the smoking device to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, this invention offers a method of manufacturing a smoking device, including: providing a column of tobacco; attaching a filter to a column of tobacco, where the filter includes a porous mass containing an active particle and a binder particle, and where the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, 60 superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms, endofullerene, a(FeCboO), core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle and any combination thereof.

In one embodiment, the present invention provides an installation that includes: a container area that includes at least a collection of parts of the first filter section; a second container area comprising at least a collection of parts of the second filter section, wherein the parts of the second filter section include a porous mass that includes an active portion and a binder portion, and where the active portion includes an element selected from the group consisting of: carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a horn-like nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, nanoparticles gold, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, C4D(FSbO, core-shell nanoparticles , bulbous nanoparticle, nanoshell, bulbous nanoparticle of iron oxide and any combination thereof; the connection zone, where part of the first section of the filter and part of the second section of the filter are connected; the wrapping zone, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the present invention provides a smoking device filter comprising: a filter section comprising a porous mass comprising an active moiety and a binder moiety, wherein the porous mass has a porosity of from about 4095 to about 9095.

In one embodiment, the present invention provides a smoking device comprising: a sleeve for the smoking substance, and a filter comprising a porous mass comprising an active portion and a binder portion, wherein the porous mass has a porosity of from about 4095 to about 9095 .

In one embodiment, the present invention provides a smoking device filter comprising: at least two adjacent longitudinal sequential sections, wherein the first section includes a porous mass that includes an active moiety and a binder moiety, wherein the porous mass has a porosity of from about 4095 to approximately 9095; and wherein the second section comprises a section selected from the group consisting of: cavity, acetyl cellulose, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, random orientation acetate, paper, corrugated paper, concentric filter, carbon on bundles of fibers, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon, aroma, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particles, carbon fiber, fiber, glass bead, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the present invention provides a smoking device comprising: a filter that includes a porous mass that includes an active portion and a binder portion, wherein the porous mass has a porosity of from about 4095 to about 9095; and a sleeve capable of holding the smoking substance in interfacial contact with the filter.

In one embodiment, the present invention provides a filter pack comprising: a pack comprising at least one filter comprising a porous mass comprising an active moiety and a binder moiety, and wherein the porous mass has a porosity of from about 4095 to approximately 9095.

In one embodiment, the present invention provides a pack of smoking devices comprising: a pack comprising at least one smoking device comprising a filter comprising a porous mass comprising an active moiety and a binder moiety wherein the porous mass has a porosities from about 4095 to about 9095.

In one embodiment, the present invention provides a cardboard packaging of a smoking device comprising: a container comprising at least one pack comprising at least one smoking device, wherein the smoking device comprises a filter comprising a porous mass comprising an active particle and proportion of binder, and wherein the porous mass has a porosity of from about 4095 to about 9095.

In one embodiment, the present invention provides a method of smoking a smoking device, the method comprising: heating or igniting the smoking device to generate smoke, wherein the smoking device includes at least one filter section comprising a porous mass,

which includes an active fraction and a binder fraction, and wherein the porous mass has a porosity of from about 4095 to about 9095; drawing smoke through a smoking device, wherein the filter section reduces the presence of at least one component in the smoke compared to a filter without a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter, which includes: providing a mixture that includes active particles and particles of a binder; placing the mixture in a mold; heating the mixture in the mold to a temperature equal to or greater than the melting temperature of the binder particles so as to form a porous mass, wherein the porous mass has a porosity of from about 4095 to about 9095; removal of the porous mass from the mold; and forming a filter comprising a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter for a smoking device, which includes: providing a mixture that includes active particles and particles of a binder; heating the mixture; extruding the mixture while at an elevated temperature to form a porous mass, wherein the porous mass has a porosity of from about 4095 to about 9095; and forming a filter comprising a porous mass.

In one embodiment, the present invention provides a method of manufacturing a smoking device, comprising: providing a first filter section; providing at least one second filter section, wherein the second filter section includes a porous mass that includes an active portion and a binder portion, and wherein the porous mass has a porosity of from about 4095 to about 9095; connecting the first filter section and at least one second filter section to form a filter mouthpiece; and connecting at least part of the filter mouthpiece to the column of tobacco to form a smoking device.

In one embodiment, the present invention provides a method of manufacturing a filter mouthpiece, comprising: providing a container that includes at least a collection of parts of the first filter section; providing a second container including at least a plurality of parts of the second filter section, wherein the parts of the second filter section include a porous mass that includes an active portion and a binder portion, and where the porous mass has a porosity of from about 4095 to about 9095; connection of part of the first section of the filter and part of the second

From the filter section, a junction along the longitudinal axis of a part of the first filter section and a part of the second filter section to form an unwrapped filter mouthpiece; and wrapping a portion of the first filter section and a portion of the second filter section with paper to form a filter mouthpiece.

In one embodiment, the present invention provides a method of manufacturing a smoking device comprising: providing a filter mouthpiece including at least one filter section,

C5 which includes a porous mass that includes an active portion and a portion of a binder, wherein the porous mass has a porosity of from about 4095 to about 9095; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two smoking device filters comprising at least one filter section that includes a porous mass that includes an active portion and a binder portion; and connecting at least one of the filters of the smoking device to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, this invention offers a method of manufacturing a smoking device, including: providing a column of tobacco; attaching the filter to the tobacco column, wherein the filter includes a porous mass that includes an active moiety and a binder moiety, and wherein the porous mass has a porosity of from about 4095 to about 9095.

In one embodiment, the present invention provides an installation that includes: a container area that includes at least a collection of parts of the first filter section; a second container area including at least a collection of parts of the second filter section, where the parts of the second filter section include a porous mass that includes an active fraction and a binder fraction, where the porous mass has a porosity of from about 4095 to about 9095; a connection zone where part of the first filter section and part of the second filter section are combined; a wrapping zone, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the present invention provides a filter comprising: a porous mass comprising an active particle and a binder particle, wherein the porous mass has an active particle fill of at least about 1 mg/mm, and a capsule pressure drop , which is about 20 mm of water column or less per mm of porous mass, and where the active 60 fraction is not carbon.

In one embodiment, this invention provides a smoking device that includes: a smoking substance; and a filter comprising a porous mass comprising an active particle and a binder particle, wherein the porous mass has an active particle loading of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a smoking device filter comprising: at least two adjacent longitudinal sequential filter sections, wherein the first filter section includes a porous mass that includes an active particle and a binder particle, wherein the porous mass is filled with an active particle, that is at least about 1 mg/mm, and a capsule pressure drop that is about 20 mm of water column or less per mm of porous mass; and wherein the second filter section includes a section selected from the group consisting of: cavity, acetyl cellulose, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, random orientation acetate, paper, corrugated paper, concentric filter, carbon on a bundle of fibers, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon, aroma, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particle, carbon fiber , fiber, glass bead, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the present invention provides a smoking device comprising: a filter that includes a porous mass that includes an active particle and a binder particle, wherein the porous mass has an active particle content of at least about 1 mg/mm, and a capsule pressure drop of approximately 20 mm of water column or less per mm of porous mass; and a sleeve capable of holding the smoking substance in interfacial contact with the filter.

In one embodiment, the present invention provides a filter pack comprising: a pack comprising at least one filter, wherein the filter comprises a porous mass comprising an active particle and a binder particle, and wherein the porous mass is filled with an active particle that is at least about 1 mg/mm, and the pressure drop in the capsule, which is

From approximately 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a pack comprising: a container comprising at least one smoking device comprising a filter comprising a porous mass comprising an active moiety and a binder moiety, and wherein the porous mass is filled with an active fraction of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a carton package for packs of smoking devices comprising: a container comprising at least one pack comprising at least one smoking device comprising a porous mass comprising a filter comprising an active particle and a particle binder, and where the porous mass has an active particle loading of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a method of smoking a smoking device comprising: heating or igniting the smoking device to generate smoke, wherein the smoking device includes at least one filter section comprising a porous mass that includes an active moiety and a binder moiety , and wherein the porous mass has an active particle loading of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass; and drawing the smoke through the smoking device, wherein the filter section reduces the presence of at least one component in the smoke compared to a filter without a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter, which includes: providing a mixture that includes active particles and particles of a binder; placing the mixture in the mold; heating the mixture in the mold to a temperature equal to or greater than the melting temperature of the binder particles, so as to form a porous mass, where the porous mass has an active particle filling of at least about 1 mg/mm, and a pressure drop of capsules that are approximately 20 mm of water column or less per mm of porous mass; removal of the porous mass from the mold; and forming a filter comprising a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter for a smoking device, which includes: providing a mixture that includes active particles and particles of a binding agent; heating the mixture; extruding the mixture while at an elevated temperature to form a porous mass, wherein the porous mass has an active particle loading of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass; and forming a filter comprising a porous mass.

In one embodiment, the present invention provides a method for manufacturing a smoking device comprising: providing a first filter section; providing at least one second filter section, wherein the second filter section includes a porous mass that includes an active fraction and a binder fraction, and wherein the porous mass has an active particle loading of at least about 1 mg/mm, and a gradient pressure in the capsule, which is approximately 20 mm of water column or less per mm of porous mass; connecting the first filter section and at least one second filter section to form a filter mouthpiece; and connecting at least part of the filter mouthpiece to the column of tobacco to form a smoking device.

In one embodiment, the present invention provides a method of manufacturing a filter mouthpiece, comprising: providing a container that includes at least a collection of parts of the first filter section; providing a second container comprising at least a collection of parts of the second filter section, wherein the parts of the second filter section include a porous mass that includes an active particle and a binder particle, and wherein the porous mass has an active particle filling of at least about 1 mg/mm, and a capsule pressure drop of approximately 20 mm of water column or less per mm of porous mass; connecting part of the first section of the filter and part of the second section of the filter butt along the longitudinal axis of the part of the first section of the filter and part of the second section of the filter to form an unwrapped filter mouthpiece; wrapping part of the first filter section and part of the second filter section with paper to form the filter mouthpiece; and moving the filter nozzle to the next area for storage or use.

In one embodiment, the present invention provides a method of manufacturing a smoking device, comprising: providing a filter mouthpiece comprising at least one filter section comprising a porous mass comprising an active particle and a binder particle, wherein the porous mass is filled with an active a share that is at least approx

of 1 mg/mm, and a pressure drop in the capsule of approximately 20 mm of water column or less per mm of porous mass; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two smoking device filters containing at least one filter section that includes a porous mass that includes an active portion and a binder portion; and connecting at least one of the filters of the smoking device to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, this invention offers a method of manufacturing a smoking device, including: providing a column of tobacco; attaching the filter to a column of tobacco, wherein the filter includes an active particle and a binder particle, wherein the porous mass has an active particle loading of at least about 1 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides an installation that includes: a container area that includes at least a collection of parts of the first filter section; the zone of the second container, which includes at least a collection of parts of the second section of the filter, where the parts of the second section of the filter include a porous mass that includes an active particle and a particle of a binder, where the porous mass has a filling with an active particle that is at least about 1 mg/mm, and a capsule pressure drop of approximately 20 mm of water column or less per mm of porous mass; a connection zone where part of the first filter section and part of the second filter section are combined; the wrapping zone, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the present invention provides a filter comprising: a porous mass that includes an active moiety and a binder moiety, wherein the active moiety comprises carbon, and the porous mass has a carbon content of at least about 6 mg/mm, and a capsule pressure drop of approximately 20 mm of water column or less per mm of porous mass.

In one embodiment, this invention provides a smoking device that includes: a smoking substance; and a filter that includes a porous mass that includes an active particle and a binder particle, where the active particle includes carbon, and the porous mass has a carbon filling of at least about b mg/mm, and a pressure drop in the capsule, which is approximately 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a smoking device filter including: at least two adjacent longitudinal sequential sections, where the first section includes a porous mass that includes an active portion and a binder portion; wherein the active particle is carbon and the porous mass has a carbon loading of about 6 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass; and wherein the second section comprises a section selected from the group consisting of: cavity, acetyl cellulose, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, random orientation acetate, paper, corrugated paper, concentric filter, carbon on bundles of fibers, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon, aroma, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particles, carbon fiber, fiber, glass bead, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the present invention provides a smoking device comprising: a filter comprising a porous mass having a carbon content of at least about 6 mg/mm and a capsule pressure drop of about 20 mm water column or less than namm of porous mass; and a sleeve capable of holding the smoking substance in interfacial contact with the filter.

In one embodiment, the present invention provides a filter pack that includes: a pack that includes at least one filter that includes a porous mass having a carbon fill of at least about mg/mm and a capsule pressure drop, which is approximately 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a pack of smoking devices comprising: a pack comprising at least one smoking device comprising a filter, wherein the filter comprises a porous mass comprising an active moiety and a binder moiety, and wherein the active moiety includes carbon and the porous mass has a carbon content of at least about b mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a carton package for packs of smoking devices comprising: a container comprising at least one pack comprising at least one smoking device comprising a filter comprising a porous mass comprising an active particle and a particle binder, and where the active fraction includes carbon, and the porous mass has a carbon content of at least about 6 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides a method of smoking a smoking device comprising: heating or igniting the smoking device to produce smoke, wherein the smoking device includes a smoking substance and at least one filter section comprising a porous mass that includes an active portion and a portion of "a binder, where the active fraction includes carbon, and the porous mass has a carbon content of at least about 6 mg/mm and a pressure drop in the capsule of about 20 mm of water column or less per mm of porous mass; drawing smoke through a smoking device to create a stream of smoke; and providing the filter section with the ability to at least reduce the presence of at least one component in the smoke stream compared to a filter without a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter, which includes: supplying a mixture that includes active particles and particles of a binder; placement of the mixture in the form; heating the mixture in the mold to a temperature equal to or greater than the melting temperature of the binder particles, so as to form a porous mass, wherein the active particle includes carbon, and the porous mass has a carbon content of at least about b mg/mm , and a capsule pressure drop of approximately 20 mm of water column or less per mm of porous mass; removal of the porous mass from the mold; and forming a filter comprising a porous mass.

In one embodiment, this invention offers a method of manufacturing a filter for a smoking device, which includes: supplying a mixture that includes active particles and particles of a binder; heating the mixture; extruding the mixture while at an elevated temperature so as to form a porous mass, wherein the active particles include carbon, and the porous mass has a carbon filling of at least about 6 mg/mm and a 60 pressure drop in the capsule, which is approximately 20 mm of water column or less per mm of porous mass; forming a smoking device filter including a porous mass.

In one embodiment, the present invention provides a method of manufacturing a smoking device, including: supplying a first filter section; supplying at least one second filter section, wherein the second filter section includes a porous mass having a carbon loading of at least about b mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm porous mass; connecting the first filter section and at least one second filter section longitudinally so as to form a filter mouthpiece; and connecting at least part of the filter mouthpiece to the column of tobacco to form a smoking device.

In one embodiment, the present invention provides a method of manufacturing a filter mouthpiece, comprising: providing a container that includes at least a collection of parts of the first filter section; providing a second container comprising at least an assembly of parts of the second filter section, wherein the parts of the second filter section include a porous mass having a carbon content of at least about b mg/mm and a pressure drop across the capsule of about 20 mm of water column or less per mm of porous mass; connecting part of the first section of the filter and part of the second section of the filter butt along the longitudinal axis of the part of the first section of the filter and part of the second section of the filter to form an unwrapped filter mouthpiece; and wrapping a portion of the first filter section and a portion of the second filter section with paper to form a filter mouthpiece.

In one embodiment, the present invention provides a method of manufacturing a smoking device comprising: providing a filter mouthpiece comprising at least one filter section comprising a porous mass having a carbon content of at least about b mg/mm, and a pressure drop in the capsule of approximately 20 mm of water column or less per mm of porous mass; submission of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis to form at least two smoking device filters containing at least one filter section that includes a porous mass; and connecting at least one of the filters of the smoking device to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, this invention offers a method of manufacturing a smoking device, which includes: supplying a column of tobacco; and attaching the filter to the tobacco column, wherein the filter includes having a carbon filling of at least about 6 mg/mm and a capsule pressure drop of about 20 mm of water column or less per mm of porous mass.

In one embodiment, the present invention provides an installation that includes: a container area that includes at least a collection of parts of the first filter section; the zone of the second container, which includes at least a collection of parts of the second section of the filter, where the parts of the second section of the filter include a porous mass that includes an active part and a part of a binder, where the active part includes carbon, and the porous mass has a filling of carbon, which is , at least about b mg/mm, and a pressure drop in the capsule of about 20 mm of water column or less per mm of porous mass; a connection zone where part of the first filter section and part of the second filter section are combined along their longitudinal axes; the wrapping zone, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the present invention provides a wrap that compresses and surrounds the longitudinal axis of the porous mass filter section.

The characteristics and advantages of the proposed invention will be quite obvious to the average person skilled in the art after reading the description of the best embodiments of the invention, which are given below.

Description of drawings

In order to illustrate the invention, the drawings show the form preferred in the proposed application; however, it is to be understood that the present invention is not limited to the particular arrangements and devices shown.

Figure 1 is a cross-sectional view of an embodiment of a cigarette, including a filter section according to the present invention.

Figure 2 is a cross-sectional view of another embodiment of a cigarette, including a filter section according to the present invention.

Figure C is a cross-sectional view of another embodiment of a cigarette, including a filter section according to the present invention.

Figure 4 is a cross-sectional view of a smoking device including a filter section according to the present invention.

Figure 5 is a photomicrograph of a section of an embodiment of the porous mass of the proposed invention.

Figure 6 is a comparative document showing capsule pressure drop test results for fiber tow carbon filters having an average circumferential length of approximately 24.5 mm.

Figure 7 shows the results of a capsule pressure drop test for filters with a porous mass of the proposed invention (including polyethylene and carbon) having an average circumference of approximately 24.5 mm.

Figure 8 is a comparative document showing capsule pressure drop test results for fiber tow carbon filters having an average circumferential length of approximately 16.9 mm.

Figure 9 shows the results of a capsule pressure drop test for porous mass filters of the present invention (including polyethylene and carbon) having an average circumferential length of approximately 16.9 mm.

Detailed description of the invention

The porous mass described below can be used with a smoking device, such as a tobacco smoking device. The porous mass includes active particles and non-fibrous binder particles and may form part of the filter section of the smoking device.

The term "porous mass" as used herein refers to a mass that includes active particles and non-fibrous binder particles that form a structure bound by the binder particles and that contains void regions by which smoke can move through the porous mass and interact with active particles. In some embodiments of the invention, the structure can be formed by applying heat, so that the binder particles are softened to bond with the active particles at various points of contact. Although the proposed application refers to "tobacco", it should be understood that the porous mass described therein is also suitable for use with other substances that produce smoke when burned or heated (ie, smoking substances).

It should be noted that when "about" is discussed below with reference to a number, the term "about" modifies each number in the numerical list. It should be noted that in some numerical range lists, some of the specified lower limits may be greater than some of the specified upper limits. One of ordinary skill in the art will recognize that a selected subset will require the selection of an upper limit greater than the selected lower limit.

With reference to Figures 1-4, several embodiments of the smoking device invention are shown (which are representative, but not limiting, of the smoking devices offered below). The term "smoking device" when used in the proposed application most often refers to a cigarette, but is not limited to the aforementioned, and may be used with other smoking devices such as cigarette mouthpieces, cigars, cigar mouthpieces, smoking pipes, hookahs, hookahs, electronic smoking devices , cigarettes or self-rolling cigars, etc. Hereinafter, reference will be to cigarettes as a generic term (unless otherwise specified).

In some embodiments of the invention, the smoking device may include a sleeve capable of holding the smoking substance in interfacial contact with the filter. Suitable sleeves may include, but are not limited to, a cigarette, a cigarette mouthpiece, a cigar, a cigar mouthpiece, a smoking pipe, a hookah, a hookah, an electronic smoking device, a roll-your-own cigarette, a roll-your-own cigar, and paper.

In Figure 1, a cigarette 10 includes a column of tobacco 12 and a filter 14. The filter 14 may include at least two sections, a first section 16 and a second section 18. For example, the first section 16 may include a conventional filter material (described in more detail below) and the second section 18 includes a porous mass (described in more detail below).

As used in the proposed application, the term "tobacco stick" refers to a blend of tobacco, and optionally other ingredients and flavorings, that may be combined to make a tobacco-based smoking product, such as a cigarette or cigar. In some embodiments, the tobacco column may include ingredients selected from the group consisting of: tobacco, sugar (such as sucrose, brown sugar, invert sugar, or high fructose corn molasses), propylene glycol, glycerin, cocoa, cocoa products, locust bean gum, locust bean extracts and any combination thereof. In other embodiments of the invention, the column of tobacco may also include 60 flavors, menthol, licorice root extract, diammonium phosphate, ammonium hydroxide, and any

what combination of them. Examples of suitable types of tobacco that can be used in tobacco columns may include, but are not limited to, light leaf tobacco,

Burley, Oriental tobacco (also known as Turkish tobacco), Cavendish tile tobacco, Corojo tobacco, Criollo tobacco, Louisiana black tobacco, Shade grown tobacco, Tobacco

White Burley, and any combination thereof. Tobacco can be grown in the United States or it can be grown outside the United States.

In Figure 2, a cigarette 20 includes a column of tobacco 12 and a filter 22. The filter 22 is multi-segment with three sections. In this embodiment of the invention, typical filter materials 24 (or other alternative filter sections) may adjoin the porous mass 26 from the sides.

In Figure C, a cigarette 30 includes a column of tobacco 12 and a filter 32. The filter 32 is multi-segment with four sections. In this embodiment of the invention, the end section 34 is a conventional material, but the sections 36, 37, and 38 can be any combination of other filter materials and porous mass (provided that at least one of these sections is porous mass of the proposed invention).

The above-mentioned embodiments of the invention are typical and not limiting. The claimed filters may have any number of sections, for example 2, 3, 4, 5, 6, or more sections, and the sections may be arranged in any acceptable configuration. It is desirable that at least one of the sections of the filter includes the porous mass of the proposed invention. In addition, the sections can be the same or different from each other.

Examples of sections that can be included with the porous masses of the proposed invention to form filters may include, but are not limited to, sections that include at least one element selected from the following: acetyl cellulose, polypropylene, polyethylene, polyolefin fiber tow, polypropylene fiber tow , polyethylene terephthalate, random orientation acetate, varieties of paper, varieties of corrugated paper, concentric filters (for example, a peripheral filter of a fiber tow and a core of tape material), carbon on a fiber tow (sometimes called a "Dalmatian filter"), silica, magnesium silicate, zeolites, molecular sieves, metallocenes, salts, catalysts, sodium chloride, nylon, flavorings, tobacco, capsules,

From cellulose, cellulose derivatives, catalytic converters, iodic anhydride, coarse powders, carbon particles, carbon fibers, fibers, glass beads, nanoparticles, hollow chambers (for example, formed by solid elements such as paper or plastic), hollow chambers with partitions, and any combination thereof. If a zeolite is used, examples of suitable zeolites include, but are not limited to, VETA, 5BA-15, MOM-41,

MOM-48, modified with 3-aminopropylsilyl groups, and any combination thereof. In some embodiments, the filter may be such that it degrades significantly over time (eg, over a period of about 2 to about 5 years), naturally, or in the presence of a catalyst, which, in some embodiments, may be present in the filter itself. filter sections. Also included are fiber tows and types of paper with active materials (glued to it or impregnated into it or incorporated into it in some other form). Such active materials include activated carbon (or charcoal), ion exchange resins, zeolites, siccators, catalysts, or other materials adapted for exposure to tobacco smoke. Hollow chambers, if used, may be filled (or partially filled) with active ingredients or materials including active ingredients. Such active ingredients include activated carbon (or charcoal), ion-exchange resins, desiccants, or other materials adapted for exposure to tobacco smoke. Additionally, the section may be a porous mass of binder particles (ie, only binder particles without any active particles). For example, such a porous mass without active particles can be made with thermoplastic particles (such as polyolefin powders, including the binder particles described below), which are connected or pressed together into a porous cylindrical shape.

In another embodiment of the invention, the section may include a space that defines a cavity between two sections of the filter (one section including the porous mass of the proposed invention). The cavity can be, for example, filled with granular coal, or, as another example, flavoring. The cavity may contain a capsule, for example, a polymer capsule, which itself contains an aroma or catalyst. The cavity, in some embodiments of the invention, may also contain a molecular sieve that reacts with selected smoke constituents to remove or reduce the concentration of the constituents without adversely affecting the desired smoke constituents. In an embodiment of the invention, the cavity may include tobacco as an additional flavoring agent. It should be noted that if the cavity is not sufficiently filled with the selected substance, then in some embodiments of the invention, this may cause a lack of interaction between the components of the main stream of smoke and the substance in the cavity and in the other section(s) of the filter.

Flavorings that may be suitable for use in the present invention include any flavoring that is suitable for use in smoking devices, including flavorings to add flavor and/or aroma to the smoke stream. Flavoring agents may include, but are not limited to, organic material (or natural flavoring particles), natural flavoring carriers, artificial flavoring carriers, and any combination thereof. Organic materials (or naturally flavored particles) include, but are not limited to, tobacco, cloves (eg, ground cloves and clove buds), cocoa, and the like. Natural and artificial flavors may include, but are not limited to, menthol, clove, cherry, chocolate, orange, mint, mango, vanilla, cinnamon, tobacco, etc. Such flavors can be provided by menthol, anethole (licorice), limonene (citrus), eugenol (clove), and the like. In some embodiments, more than one flavoring may be used, including any combination of flavorings provided in the proposed application. Such flavors can be placed in the tobacco column or in the filter section. In addition, in some embodiments of the invention, the porous masses of the proposed invention may include a flavoring agent.

The amount to include will depend on the required level of flavoring in the smoke, taking into account all filter sections, the length of the smoking device, the type of smoking device, the diameter of the smoking device, and other factors known to those skilled in the art.

The sections that include the filter can be wrapped in paper to form filter mouthpieces. The term "paper" as used in the proposed application refers generally to any type of wrapping paper used in the manufacture of smoking devices, including rim paper, cork wrapping paper, rim backing paper, and the like. Suitable papers for use in connection with the present invention include wood-based papers, flax-containing papers, linen-based papers, functionalized papers (eg, those that are functionalized to reduce resin content and/or or carbon monoxide), special types of marking

From paper, types of painted paper, and any combination thereof. In some embodiments, the paper types may have high porosity, be corrugated, and/or have high surface strength. In some embodiments of the invention, the types of paper may include additives, adhesives, and/or include substances that provide printing properties.

In some embodiments of the invention, the filter mouthpieces that include the porous mass of the proposed invention can have lengths ranging from about 80 mm to about 150 mm. In processing, the filter mouthpieces can then be divided into about 4 or about 6 separate segments of about 5 to about 35 mm in length during the operation of joining the rim of the smoking device. For double or triple filters, the filters may first be cut into segments and combined with paper and/or charcoal segments before the rim is attached. The filter mouthpieces may be attached to the column of tobacco by means of a paper or other smoking device in order to produce a finished smoking device. For example, in the traditional production of cigarettes, at least three types of paper are used: wrapping paper imitating the texture of a cork, cigarette paper and rim paper. Cork Wrapping Paper refers to the paper used to wrap the filter section of a cigarette during the manufacture of the filter and before it is attached to the column of tobacco. Cigarette paper refers to the paper used to wrap a section of tobacco column during the manufacture of such column of tobacco and before it is attached to the filter section. Finally, rim paper refers to the paper used to wrap the filter section and portion of the tobacco column when the two sections are combined to form a cigarette. The joints of the different types of paper used to form the cigarette are combined using at least one adhesive, and more than one type of adhesive may be used in the formation of the cigarette. For example, when forming a typical cellulose acetyl filter section, a polyvinyl alcohol adhesive may be used to attach the filter to the paper, and a hot melt adhesive may be used on the edge of the paper to hold the filter wrapped. Also, cigarette paper can use starch paste to join the ends of the paper. Finally, the rim paper can be applied more completely, that is, applied over a large part of the surface, and not only in the area of contact with the hot-melt adhesive, to ensure that the proper connection of the filter section and the tobacco section is maintained. In some cigarette products, 60 ventilation holes are made through the rim paper or through both the rim paper and the wrapper paper,

that imitates the texture of a cork to ensure air flow in the smoke stream.

In some embodiments of the invention, the filters can have a diameter in the range of about 5 mm to about 10 mm and a length of about 5 mm to about 35 m. In some embodiments of the invention, for example, for ultra-fine or super-fine cigarettes, the filters can have a diameter in the range of less, than 5 mm, for example, 3 mm or less, including, but not limited to, a lower diameter limit of 0.5 mm. In embodiments of the invention, the cigar filters may have a diameter greater than 20 mm, such as approximately 30 mm, if desired. By analogy, the filter size for other smoking devices may vary based on intended use and consumer demand (eg, in a smoking pipe).

In Figure 4, a smoking pipe 40 includes a bowl with a tobacco chamber 42, a mouthpiece with a mouthpiece 44, and a channel 46 connecting the bowl with a tobacco chamber 42 and a mouthpiece with a mouthpiece 44. The channel 46 includes a cavity 47. The cavity 47 is adapted to accommodate a filter 48 .

The filter 48 may be the multi-segment filter discussed above or may consist solely of a porous mass. The size of the filter may vary depending on the dimensions of the cavity 47. In some embodiments, the filter 48 may be removable, replaceable, disposable, reusable, and/or degradable.

In the aforementioned embodiments of the invention, the typical materials and the porous mass are "connected". The term "connected" as used in the proposed application means that the porous mass is linearly (or sequentially) adjacent to the tobacco column or other filter section, such that when the cigarette is smoked, the smoke from the tobacco column must pass through (eg, in series ) porous mass to reach its intended recipient (e.g., a smoker). As mentioned above, the porous mass can be connected to the column of tobacco using technical means for paper packaging, for example, using paper and/or an adhesive. Additionally, in some embodiments of the invention, the porous mass can be connected to the column of tobacco using an adhesive, which is preferably free of components that, when burned, could create obstacles for the purposes of the invention.

As shown in Figures 1-3, in some embodiments of the invention, the filter section including the porous mass and at least one other filter section may be coaxial,

Z placed next to each other, butt-joined, and having equivalent cross-sectional areas (or practically equivalent cross-sectional areas). However, it is clear that it is not necessary to connect the porous mass and typical materials in this way, and that other possible configurations may exist. Further, although it is contemplated that the porous mass will most often be used in combination or multi-segment cigarette filter configurations as shown in Figures 1-3, the invention is not limited to this circumstance, and the smoking device may include only the porous mass of the present invention as indicated above in relation to Figure 4.

Also, although in some embodiments of the invention the porous mass will be contained adjacent to the column of tobacco, as shown in Figure 1, this disclosure is not so limited. For example, the porous mass of the present invention may be separated from the tobacco by a hollow cavity (e.g., a tube or channel, such as in a smoking pipe or hookah, or as a mouthpiece for a cigarette or cigar) e.g., see Figure 4. In other variants of the embodiment of the invention, the porous mass of the proposed invention can be separated from the column of tobacco with the help of an element that bends and allows the consumer to shape the smoking device.

In some embodiments of the invention, the porous masses of the proposed invention include active particles that are at least partially connected to the particles of the binder.

For example, see in Figure 5, a photomicrograph of an embodiment of the invention of a porous mass, where active particles (for example, particles of activated carbon) 50 and particles of a binder 52.

Item 54 shows an example of a touch point. Note: in this variant of the embodiment of the invention (Figure 5), the particles of the binder and the active particles are connected at the points of contact, and the points of contact are randomly distributed throughout the porous mass, and the particles of the binder retain their original physical form (or practically retain their original physical form, i.e. no more than 1095 changes (eg shrinkage) in shape relative to original). (Active particles and binder particles are discussed in more detail below.) Although without any theoretical limitations, it is assumed that the contact points are formed when the binder particles are heated to their softening temperature, which, however, is insufficient to achieve actual melting. In some embodiments of the invention, it is assumed that the porous masses of the proposed invention are created in such a way that they demonstrate a minimum pressure drop in the capsule (defined below) with a maximum increase in the surface area of the active particles. 60 Any mass ratio of active particles to binder particles is possible in the porous mass. In some embodiments of the invention, this ratio can be from about 1 to about 99% by weight of active particles and from about 99 to about 1% by weight of binder particles. In some embodiments of the invention, this ratio can give from about 25 to about 99 mab.9o of active particles and from about 1 to about 75 mab.9Uo of binder particles. In some embodiments of the invention, this ratio can give from about 40 to about 99 mab.90 of active particles and from about 1 to about 60 mab.90 of binder particles. In one embodiment of the invention of the porous mass, the active particles are from about 50 to about 99 wt.95 by weight, while the binder particles are from about 1 to about 50 wt.95 by weight. In another embodiment of the invention, the active particles comprise from about 60 to about 95 wt.9Uo by weight, while the binder particles comprise from about 5 to about 40 wt.95 by weight. In addition, in yet another embodiment of the invention, the active particles include from about 75 to about 90 wt.90 by weight, while the binder particles are from about 10 to about 25 wt.95 by weight.

In one embodiment of the porous mass, the porous mass has a porosity in the range of about 4095 to about 9095. In another embodiment, it has a porosity in the range of about 6095 to about 9095. In yet another embodiment, it has a porosity in the range of about 6095 to about 8595. Porosity is the free space left after taking into account the space occupied by active particles.

For the determination of the porosity coefficient, without regard to limitations due to any particular theory, it is assumed that the tests indicate that the final density of the mixture is almost entirely determined by the active fraction; therefore, the space occupied by the binder particles was not taken into account in these calculations. Thus, the porosity factor in this context is calculated based on the space remaining after calculations for active particles. To determine the porosity coefficient, the upper and lower diameters were first averaged based on the size according to the sieve number for the active particles, and then the volume was calculated (with the assumption of spherical shape, based on this averaged

From the diameter) using the density of the active material. The percentage porosity is then calculated as follows:

Coefficient of stiffness) -1-- volume of porous mass cm - (weight of active particles g)/ density of active particles g/cm! ||Their 100 cm volume of porous mass?

In one embodiment of the invention, the porous mass has a pressure drop in the capsule (PTK) in the range of about 0.10 to about 25 millimeters of water column or less per mm of the length of the porous mass. As used in the proposed application, the term "capsule pressure drop" refers to the static pressure difference between the two ends of the sample as it is traversed by the air stream under conditions established when the volumetric flow rate is 17.5 mL/sec at the outlet end, when the sample is completely sealed in the measuring device, so that air cannot penetrate through the package. PTK was measured in accordance with the method Mo41 recommended by SOMKEZTA (the Center for Scientific Research Cooperation in the field of tobacco) in June 2007. In another embodiment of the invention, the porous mass of the proposed invention can have a PTC in the range of about 0.10 to about 10 millimeters of water column or less per mm of the length of the porous mass. In other embodiments of the invention, the porous mass of the proposed invention can have a PTC of about 2 to about 7 millimeters of water column or less per mm of the length of the porous mass (or no more than 7 millimeters of water column or less per mm of the length of the porous mass). To achieve the required PTC, the active particles must have a larger particle size than the binder particles. In one embodiment of the invention, the ratio of the particle size of the binder to the size of the active particle is in the range of about 1:1.5 to about 1:4.

In some embodiments of the invention, the porous mass of the proposed invention can be filled with an active particle that is at least approximately 1 mg/mm, 2 mg/mm,

With mg/mm, 4 mg/mm, 5 mg/mm, 6 mg/mm, 7 mg/mm, 8 mg/mm, 9 mg/mm, 10 mg/mm, 11 mg/mm, 12 mg/mm, 13 mg/mm, 14 mg/mm, 15 mg/mm, 16 mg/mm, 17 mg/mm, 18 mg/mm, 19 mg/mm, 20 mg/mm, 21 mg/mm, 22 mg/mm, 23 mg/mm, 24 mg/mm, or 25 mg/mm in combination with a PTC that is less than approximately 20 millimeters of water column or less per millimeter of porous mass, 19 millimeters of water column or less per millimeter of porous mass, 18 millimeters of water column or less per millimeter of porous mass, 17 millimeters of water column or less per millimeter of porous mass, 16 millimeters of water column or less per millimeter of porous mass, 15 millimeters of water column or less per millimeter of porous mass, 14 millimeters of water column or less per millimeter of porous mass, 13 millimeters of water column or less per millimeter of porous mass, 12 millimeters of water column or less per millimeter of porous mass, 11 millimeters of water column or less per millimeter of porous mass, 10 millimeters of water column or less per millimeter of pores standing mass, 9 millimeters of water column or less per millimeter of porous mass, 8 millimeters of water column or less per millimeter of porous mass, 7 millimeters of water column or less per millimeter of porous mass, 6 millimeters of water column or less per millimeter of porous mass, 5 millimeters of water column column or less per millimeter of porous mass, 4 millimeters of water column or less per millimeter of porous mass, From millimeter of water column or less per millimeter of porous mass, 2 millimeters of water column or less per millimeter of porous mass, or 1 millimeter of water column or less per millimeter porous mass. For example, in some embodiments of the invention, the porous mass may have an active particle loading of at least about 1 mg/mm and a PTC of approximately 20 millimeters of water column or less per millimeter of porous mass. In other embodiments of the invention, the porous mass may have an active particle filling of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass, where the active particle is not carbon. In other embodiments of the invention, the porous mass may contain an active fraction, including carbon, with a filling amounting to at least b mg/mm in combination with PTK, which is 10 millimeters of water column or less per millimeter of porous mass.

Depending on how the porous mass is made, the porous mass can be of any desired length. In a portion forming process, for example, the length will probably correspond to the size of the mold(s) being used. Additionally, in a continuous production process, the porous mass can be one long continuous cylinder of any required length. In any case, the porous mass can be further cut into the necessary smaller segments or sections. The required length may depend on the specific application for which the porous mass may be used. In one embodiment of the invention, the porous mass

Zo can be from about 1 mm to about 35 mm in length. In another embodiment of the invention, the porous mass can have a length of about 2 mm to about 30 mm. In yet another embodiment of the invention, the porous mass may have a length of about 7 mm to about 20 mm.

The porous mass can have any physical form. The porous mass may have a spiral shape, a triangular shape, a disc shape, or a square shape in some embodiments of the invention. In one embodiment of the invention, it has the shape of a cylinder. A hybrid form may also be acceptable. In some embodiments of the invention, the porous mass can be processed to have a lighter weight, if necessary, for example, by drilling a portion of the porous mass. In one embodiment of the invention, the porous mass may have a specific shape for the cigarette mouthpiece or smoking pipe, which is adapted to be placed inside the cigarette mouthpiece or smoking pipe to allow the smoke to pass through the filter to the consumer. When considering in the proposed application the shape of the porous mass in relation to the filter of a typical smoking device, the shape can be represented in terms of the diameter or the length of the circle (where the length of the circle is the perimeter of the circle) of the cross-section of the cylinder. However, in embodiments where the porous mass of the present invention is in a shape other than a regular cylinder, it should be understood that the term "perimeter" is used to refer to the perimeter of a cross-section of any shape, including a circular cross-section.

The active particles may be any material adapted to improve the smoke passing therethrough. "Adapted to improve the smoke passing therethrough" refers to any material that can remove, reduce, or add constituents to the smoke stream. Removal or reduction (or addition) can be selective. For example, in a stream of cigarette smoke, components such as those shown below in the following list may be selectively removed or reduced. This table is available from the US Food and Drug Administration as a proposed draft master list of harmful/potentially harmful constituents in tobacco products, including tobacco smoke; and any abbreviations in the following list are chemical compounds well known in the art. In some embodiments of the invention, the active particle can reduce or remove at least one component selected from the list of 60 components in smoke below, including any combination thereof.

y y y M-Nitrosodiethanolamine a. and lo. M-Nitrosodimethylamine and Polonium-210 (Radioactive pa 4-(methylnitrosamino)-1-(Z-pyridyl)- Uranium-235 (Radioactive 1-butanol (MMA) isotope) tires

One example of an active material is activated carbon (or activated charcoal or activated charcoal). Activated carbon can be of low activity (adsorption of SSiX is from about 50 95 to about 75 95) or with high activity (adsorption of SSi. is from about 75 95 to about 95 95) or with a combination thereof. In some embodiments of the invention, activated carbon can be a nanosized carbon particle, such as carbon nanotubes with any number of walls, tubular carbon nanoprotrusions, carbon nanostructures of the "bamboo" type, fullerenes and fullerene aggregates, and graphene, including low-layer graphene and oxidized graphene . Other examples of such materials include ion exchange resins, siccators, silicates, molecular sieves, metallocenes, silicic acid gels, metallocene, activated aluminum, zeolites, perlite, sepiolite, roller earth, magnesium silicate, metal oxides (eg, iron oxide and iron oxide nanoparticles , such as ResOx with a size of about 12 nm), nanoparticles (e.g. metal nanoparticles such as gold and silver; metal oxide nanoparticles such as aluminum; magnetic, paramagnetic and superparamagnetic nanoparticles such as gadolinium oxide, various crystal structures of iron oxide,

such as hematite and magnetite, nanotubes with incorporated gadolinium atoms, and endofullerenes such as safFsSovo; and core-shell nanoparticles and bulbous nanoparticles, such as gold and silver nanoshells, iron oxide bulbous nanoparticles, and other nanoparticles or microparticles with an outer shell of any of the aforementioned materials), and any combination of the foregoing (including activated carbon ). It should be noted that nanoparticles include nanorods, nanospheres, varieties of nanorice) nanowire, nanostars (such as nanotripods and nanotetrapods), hollow nanostructures, hybrid nanostructures that are two or more nanoparticles connected as one, and non-nanoparticles with a nanocoating or walls having a thickness in the nanometer range. It should also be noted that nanoparticles include functionalized nanoparticle derivatives, including, but not limited to, nanoparticles that have been covalently or noncovalently functionalized, for example, by pi-packing, physical adsorption, ionic association, van der Waals bonding, and the like. Suitable functional groups may include, but are not limited to, substances including amines (17, 2", or 3"), amides, carboxylic acids, aldehydes, ketones, ethers, esters, peroxides, silyls, organosilanes, hydrocarbons, aromatic hydrocarbons , and any combination thereof; polymers; chelating agents such as ethylenediaminetetraacetate, diethylenetriaminepentaacetic acid, triglycolamino acid, and a structure including a pyrrole ring; and any combination thereof. Functional groups can improve the removal of smoke components and/or improve the introduction of nanoparticles into the porous mass. Ion exchange resins include, for example, a polymer with a main chain, such as a copolymer of styrene divinylbenzene (SDB), acrylates, methacrylates, phenolformaldehyde condensates, and epichlorohydrin-amine condensates; and a set of electrically charged functional groups attached to the main chain of the polymer. In some embodiments of the invention, the active particles are a combination of different active particles. In some embodiments of the invention, the porous mass may include several active particles. In some embodiments of the invention, the active part may include at least one element selected from the group of active parts disclosed in the proposed application. It should be noted that "item" is used as a general term to describe items in a list. In some embodiments of the invention, the active particles are combined with at least one flavoring agent.

In some embodiments of the invention, a mixture of active particles can be used to remove many harmful substances from the smoke stream. For example, although activated charcoal has proven to be successful in removing substances such as formaldehyde and acetone from cigarette smoke, it is not effective in removing carbon monoxide. However, carbon monoxide can be removed from the gas stream by exposure to iodic anhydride, a molecular sieve (such as metallocene), a molecular oxide, a metal catalyst (such as palladium), and the like.

In one embodiment of the invention, the active particles have particle sizes ranging from particles having at least one size equal to approximately less than one nanometer, such as graphene, to such larger particles as a particle having a diameter equal to approximately 5000 microns. The active particles can have a size in the range of a lower size limit that in at least one dimension is about: 0.1 nanometer, 0.5 nanometer, 1 nanometer, 10 nanometers, 100 nanometers, 500 nanometers, 1 micron, 5 micron, 10 micron , 50 microns, 100 microns, 150 microns, 200 microns, and 250 microns. The active particles can have a size ranging from an upper size limit that in at least one dimension is about: 5000 microns, 2000 microns, 1000 microns, 900 microns, 700 microns, 500 microns, 400 microns, 300 microns, 250 microns, 200 microns, 150 microns, 100 microns, 50 microns, 10 microns and 500 nanometers. Any combination of the above lower limits and upper limits may be applicable for use in the present invention where the selected maximum size is greater than the selected minimum size. In some embodiments of the invention, the active particles may be a mixture of particles with sizes between the above lower and upper limits...

The binder particles can be any suitable thermoplastic binder particles. In one variant of the embodiment of the invention, the particles of the binder exhibit a practically non-flowing state at their melting point. This means a material that, when heated to its melting point, exhibits little or no polymer flow. Materials satisfying this criterion include, but are not limited to, ultrahigh molecular weight polyethylene, very high molecular weight polyethylene, high molecular weight polyethylene, and combinations thereof. In one variant of the embodiment of the invention, the particles of the binder have an index of melt flowability (MEI, AZTM 01238), which is less than or equal to approximately 3.5 g/10 min at a temperature of 190 "С and an effort equal to 15 kg (or approximately 0-3.5 g/10 min at a temperature of 190 "with an effort equal to 15 kg). In another variant of the embodiment of the invention, particles of the binder have a melt flow index (MFT) that is less than or equal to approximately 2.0 g/10 min at a temperature of 19070 th force equal to 15 kg (or approximately 0-2.0 g /10 min at a temperature of 19070 and an effort equal to 15 kg). One example of such a material is ultrahigh molecular weight polyethylene, PEUVMV(ONMMURE) (which has no polymer flow, an ITR of approximately 0 at a temperature of 190 "C and a force equal to 15 kg, or

an ITR of about 0-1.0 at a temperature of 190 "C and a force equal to 15 kg); another such material may be very high molecular weight polyethylene, PEDVMV (MNMUURE) (which may have an ITR in the range of, for example, about 1 ,0-2.0 g/10 min at a temperature of 190 7C and a force equal to 15 kg); or high molecular weight polyethylene, PEVMV (NMUMRE) (which can have an ITR in the range, for example, about 2.0-3 .5 g/1Hv at a temperature of 1907 and a force equal to 15 kg.) In some embodiments of the invention, it may be more appropriate to use a mixture of binder particles having different molecular weights and/or different melt flow indices.

In molecular weight terms, "ultra high molecular weight polyethylene" as used in the proposed application refers to polyethylene compositions with a weight average molecular weight of at least about 3 x 105 g/mol.

In some embodiments, the molecular weight of the ultrahigh molecular weight polyethylene composition is between about 3 x 105 g/mol and about 30 x 105 g/mol, or between about 3 x 105 g/mol and about 20 x 105 g/mol, or between about 3 x 105 g/mol and about 10 x 105 g/mol, or between about 3 x 106 g/mol and about 6 x 106 g/mol. "Very high molecular weight polyethylene" as used in the proposed application refers to polyethylene compositions having a weight average molecular weight of at least about 3 x 1059 g/mol and greater than about 1 x 106 g/mol. In some embodiments of the invention, the molecular weight of the very high molecular weight polyethylene composition is between about 2 x 105 g/mol and less than about 3 x 106 g/mol. "High molecular weight polyethylene" as used in the proposed application refers to compositions of polyethylene with a weight average molecular weight of

At least, approximately from 3 x 105 g/mol to 1 x 105 g/mol. For purposes of the present description of the invention, the molecular weight referred to in this application is defined according to Eq

Margolis ("Molecular weight according to Margolis").

Suitable polyethylene materials are commercially available from several suppliers, including SOKF UONMUURE from Tisop Roiutegzv II C, a branch of SeIapeze Sogrogayop oi VOaiav, TU, and

OM (Holland), VgazKet (Brazil), Weijpud Rasiogu Mo. 2 (UAE), Zpapopai SpPetisai, i. si (People's Republic of China), Miihichi and Azai (Japan). Specifically, SOKF polymers can include: the SCRF 2000 series (2105, 2122, 2122-5, 2126), the SOKFO 4000 series (4120, 4130, 4150, 4170, 4012, 4122-5, 4022-6, 4050-3/4150-3 ), the SOKF 8000 series (8110, 8020), the SKO X series (X143,

X184, X168, X172, X192).

One example of a suitable polyethylene material is one having an intrinsic viscosity in the range of about 5 deciliters/g to about 30 deciliters/g and a degree of crystallinity of about 80 95 or greater, as described in published US patent application Mo. 2008/0090081. Another example of a suitable polyethylene material is a material having a molecular weight in the range of about 300,000 g/mol to about 2,000,000 g/mol as defined by the AZTM-O 4020 standard, an average particle size, O5o, of about 300 μm to about 1500 μm, and a bulk density of about 0.25 g/ml to about 0.5 g/ml as described in published US patent application Mob1/330,535 filed May 2010.

Particles of the binder can have any shape. Such shapes include spherical, hyperionic, asteroid, crondular, or interplanetary dust-like, granular, potato-shaped, complex, or a combination thereof. In the best embodiments of the invention, the binder particles suitable for use in this invention are non-fibrous. In some embodiments of the invention, particles of the binder are in the form of powder, granules, or dust. In some embodiments of the invention, the particles of the binder are a combination of different particles of binders.

In some embodiments of the invention, the particles of the binder can have a size in the range from the lower limit of the size, which in at least one dimension is equal to approximately: 0.1 nanometer, 0.5 nanometer, 1 nanometer, 10 nanometers, 100 nanometers, 500 nanometers, 1 micron, 5 micron, 10 micron, 50 micron, 100 micron, 150 micron, 200 micron and 250 micron. The binder particles can have a size ranging from an upper size limit that in at least one dimension is approximately: 5000 microns, 2000 microns, 1000 microns, 900 microns, 700 microns, 500 microns, 400 microns, 300 microns, 250 microns , 200 microns, 150 microns, 100 microns, 50 microns, 10 microns, and 500 nanometers. Any combination of the above lower limits and upper limits may be applicable for use in the present invention where the selected maximum size is greater than the selected minimum size. In some embodiments of the invention, the particles of the binder may be a mixture of particles having sizes in the range of the above lower and upper limits.

Additionally, the binder particles may have a bulk density in the range of about 0.10 g/cm 3 to about 0.55 g/cm. In another embodiment of the invention, the bulk density can be in the range of about 0.17 g/cm3 to about 0.50 g/cm3. In yet another embodiment of the invention, the bulk density may be in the range of about 0.20 g/cm3 to about 0.47 g/cm3.

In addition to the above-mentioned binder particles, other typical thermoplastics can be used as binder particles. Such thermoplastics include, but are not limited to, polyolefins, polyesters, polyamides (or nylons), polyacrylics, polystyrenes, polyvinyls, polytetrafluoroethylene (PTFE)RTEE), polyether ether ketone (PEEK), any copolymer thereof, any derivative thereof, and any combination of them.

Non-fibrous plasticized cellulose derivatives may also be used as binder particles in the present invention. Examples of applicable polyolefins include, but are not limited to, polyethylene, polypropylene, polybutylene, polymethylpentene, any copolymer thereof, any derivative thereof, any combination thereof, and the like. Examples of applicable polyethylenes also include low density polyethylene, linear low density polyethylene, high density polyethylene, any copolymer thereof, any derivative thereof, any combination thereof, and the like. Examples of applicable polyesters include polyethylene terephthalate, polybutylene terephthalate, polycyclohexyldimethylterephthalate, polytrimethylene terephthalate, any copolymer thereof, any derivative thereof, any combination thereof, and the like. Examples of applicable polyacrylates include, but are not limited to, polymethyl methacrylate, any copolymer thereof, any derivative thereof, any combination thereof, and the like. Examples of applicable polystyrenes

These include, but are not limited to, polystyrene, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, butadiene-styrene, styrene-maleic anhydride, any copolymer thereof, any derivative thereof, any combination thereof, etc. Examples of applicable polyvinyls include, but are not limited to, ethylene vinyl acetate, ethylene vinyl alcohol, polyvinyl chloride, any copolymer thereof, any derivative thereof, any combination thereof, and the like.

Examples of applicable cellulose polymers include, but are not limited to, acetyl cellulose, cellulose acetobutyrate, plasticized cellulose polymers, cellulose propionate, ethyl cellulose, any copolymer thereof, any derivative thereof, any combination thereof, and the like. In some embodiments of the invention, the portion of the binder may be any copolymer, any derivative, and any combination of the above binders.

The porous mass is effective in removing components from the smoke, for example, those listed above. Porous mass can be used to reduce the delivery of certain components of tobacco smoke noted by the WHO. For example, a porous mass, where activated carbon is used as active particles, can be used to reduce the delivery of certain components of tobacco smoke to levels that are lower than those recommended by WHO. (See Table 13 below.) In one embodiment of the invention, the porous mass using activated carbon has a length in the range of about 4 mm to about 11 mm. Constituents include: acetaldehyde, acrolein, benzene, benzo(|a|pyrene, 1, 3- butadiene, and formaldehyde. A porous mass with activated carbon can reduce acetaldehydes in the smoke stream from about 3.0 956 to about 6.5 90/mm pore mass length; acrolein in the smoke stream from about 7.595 to about 12 9U0/mm pore mass length; benzene in the smoke stream from about 5.5 95 to about 8.0 95/mm pore mass length; benzo(a|pyrene in the smoke stream from about 9.095 to about 21.0 96/mm of porous mass length; 1,3-butadiene in the smoke stream from about 1.5 95 to about 3.5 90/mm of porous mass length; and formaldehyde in the stream of smoke - from about 9.0 95 to about 11.0 95/mm length of the porous mass In another example, the porous mass where an ion exchange resin is used as the active particles can be used to reduce the delivery of certain constituents of tobacco smoke to levels that are lower from WHO recommended See below Table 14. In one embodiment of the invention pores The mass where the ion exchange resins are used has a length in the range of about 7 mm to about 1 mm. Ingredients include: acetaldehyde, acrolein and formaldehyde. In some embodiments of the invention, the porous mass of the proposed invention, containing an ion-exchange resin, can reduce: acetaldehyde in the smoke stream - from approximately 5.0 96 to approximately 7.0 9Ub/mm length of the porous mass; acrolein in the smoke stream - from about 4.095 to about 6.5 960/mm length of porous mass; and formaldehyde in the smoke stream - from about 9.0 95 to about 11.0 95 /mm length of porous mass.

The porous mass may be produced in any suitable manner. In some embodiments of the invention, it can be a periodic technological process. In others, it can be a continuous process.

In one variant of the embodiment of the invention of the applicable method, the active particles and particles of the binder are mixed with each other, and the mixture is placed in a mold. The mold is heated to a temperature that is equal to or exceeds the melting temperature of the binder particles, for example, in one embodiment of the invention - from approximately 150 C to 300 "C, and is held at this temperature for a period of time sufficient to heat the mold and its contents to the required temperature. The mass is then removed from the mold and cooled to room temperature. Such methods can be used in small batches or in larger batches that may be suitable for industrial production.

In some embodiments of the invention, the applicable process may be a free sintering method, since the binder particles do not flow (or have very low flow) at the sintering temperature and in the absence of pressure on the mixed materials in the mold. In this version of the embodiment of the invention, point bonds are formed between the active particles and particles of the binding substance. It is believed that this ensures the formation of predominant bonds and maximizes the voids between the particles while minimizing the clogging of the surface of the active particles due to the molten binder, which flows freely.

Also see US Patents 6,770,736, 7,049,382 and 7,160,453 are incorporated herein by reference.

Alternatively, the porous mass of the proposed invention can be produced using a technological process that includes sintering under pressure. When heating a mixture of active particles and particles of a binder (or at a temperature that can be lower, equal or higher than the melting point of the particles of the binder), pressure is applied to the mixture to promote the coalescence of the porous mass.

Also, in some variants of the embodiment of the invention, the porous mass can be produced using the technological process of extrusion and sintering, where the mixture is heated in the extruder cylinder and pushed into the porous mass.

Any suitable method for forming the filter of the smoking device, which includes the porous mass of the proposed invention, can be used in combination with the porous masses. For example, in one variant of the embodiment of the invention, a device can be used for manufacturing a filter of a smoking device, which contains at least a set of zones, including: a container zone, which includes at least a set of parts of the first section of the filter; the zone of the second container, which includes at least a collection of parts of the second filter section, and the parts of the second filter section include a porous mass containing an active particle and a portion of a binder, and the porous mass has: a filling with an active particle, which is at least approximately 1 mg/mm, PTK, which is approximately 20 millimeters of water column or less per millimeter of porous mass; a connection zone where part of the first filter section and part of the second filter section are connected; the packaging area, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use. In some embodiments of the invention, this process can form a filter mouthpiece that includes a collection of filters that, when cut, can be used to form multiple smoking devices (for example, 4 cigarettes per 1 filter mouthpiece).

In some embodiments of the invention, the filters of the smoking device can be directly moved to the production line, by means of which they can be connected to the columns of tobacco to form smoking devices. An example of such a method includes a method for manufacturing a smoking device comprising: providing a filter mouthpiece including at least one filter section including a porous mass including an active portion and a binder portion; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two filters comprising at least one filter section, each filter section comprising a porous mass comprising an active portion and a binder portion; and connecting at least one of the filters to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In typical cigarette manufacturing, the machines that attach the filter section to the column of tobacco, as well as the machines that join the multi-component filter section, tend to compress the cigarette sections as they progress through the joining process. In some embodiments of the invention, the porous mass of the proposed invention may be incompressible or less compressible than a typical acetyl cellulose filter section, which may lead to complications in some manufacturing processes. In embodiments of the invention where ultrahigh molecular weight polymers, such as ultrahigh molecular weight polyethylene, are used, the porous mass of the present invention exhibits a tendency toward incompressibility. In such cases, it may be desirable to wrap or pack the porous mass of the section in a material that is compressible. The wrapping or packing material is placed along the longitudinal axis of the porous mass filter section, such that the wrapping or packing material is between the porous mass and the wrapping paper, simulating the cork texture. The wrapping or packing material should be chosen to provide the required compressibility while exhibiting a relatively high pressure drop, so that the smoke drawn through the section will preferentially pass through the porous mass rather than through the wrapping or packing material, or the packing material is more pressure drop in the packed porous mass. In some embodiments of the invention, the wrapping material may have a pressure drop in the capsule that is 1 95 higher than the pressure drop in the capsule of the porous mass, and in other embodiments of the invention, the difference may be: 5 95 higher, 10 95 higher, 25 95 above 50 95 above 75 95 above 100 95 above 125 95 above 150 95 above 175 95 above 200 95 above 225 95 above 250 95 above 275 95 higher, or 300 96 higher. One skilled in the art will agree that the difference in capsule pressure between the wrapping or packing material and the porous mass may be even greater as long as this does not adversely affect the user and as long as the wrapping or packing material continues to provide the required compressibility. In some embodiments of the invention, the wrapping or packaging material may include acetyl cellulose, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, acetate with arbitrary orientation, paper, corrugated paper, carbon on

From fiber bundles, silica, magnesium silicate, nylon, cellulose and any combination thereof. In other embodiments of the invention, the wrapping or packaging material is placed along the longitudinal axis of the filter section with a porous mass, so that the wrapping or packaging material is located outside of the wrapping paper, imitating the cork texture. One skilled in the art will agree that the diameter of the porous mass should be selected

C5 in such a way as to compensate for the increase in diameter when adding a layer of paper or wrapping or packaging materials. The final diameter of the filter must match the diameter of the tobacco column for the filter/tobacco column connection step. In other embodiments of the invention, the wrapping or packing material is located along the longitudinal axis of the filter section with the porous mass in such a way that the wrapping or packing material is in direct contact with the porous mass. This configuration can eliminate the use of paper in the sintering process. In other embodiments of the invention, the filters of the smoking device can be placed in a suitable container for storage until the next use. Suitable storage containers include those commonly used in smoking filter technology, including, but not limited to, nest boxes, cylindrical boxes, bags, cartons, and the like.

Storage and transfer containers used with the porous mass filter sections of the present invention may require modification to accommodate the presence of the porous mass. For example, cylindrical or other shaped mouthpieces or cigarettes that include filter sections with a porous mass of the proposed invention may weigh more or be more fragile than a filter section made of acetyl cellulose. Additionally, due to the active nature of the porous mass, it may be desirable to transport the porous mass sections or cigarettes comprising the porous mass sections in such a way that the porous mass does not undergo environmental contamination.

In some embodiments of the invention, the method of manufacturing a filter may include: providing a mixture including active particles and particles of a binder; placing the mixture in a mold; heating the mixture in the form to a temperature that is equal to or exceeds the melting temperature of the particles of the binder, in such a way as to form a porous mass selected from at least one porous mass of the proposed invention; removal of the porous mass from the mold; and forming a filter comprising a porous mass. because In some embodiments of the invention, the method of manufacturing a smoking device filter may include: providing a mixture that includes an active portion and a portion of a binder; heating the mixture; extrusion of the mixture at an elevated temperature in such a way as to form a porous mass selected from at least one porous mass of the proposed invention; and forming a filter comprising a porous mass.

In some embodiments of the invention, the method for manufacturing a smoking device may include: providing a first filter section; providing at least one second filter section, where the second filter section includes a porous mass selected from at least one porous mass of the proposed invention; connecting the first filter section and at least one second filter section to form a filter mouthpiece; and connecting at least part of the filter mouthpiece to the column of tobacco to form a smoking device.

In some embodiments of the invention, the method of manufacturing a filter mouthpiece may include: providing a container that includes, at least, a set of parts of the first section of the filter; providing a second container, including at least a set of parts of the second section of the filter, where parts of the second section of the filter include a porous mass selected from at least one porous mass of the proposed invention; connecting a portion of the first filter section and a portion of the second filter section butt along the longitudinal axis of the portion of the first filter section and portion of the second filter section to form an unpackaged filter mouthpiece; packing part of the first filter section and part of the second filter section with paper to form the filter mouthpiece; and moving the filter mouthpiece to the next area for storage or use.

In some embodiments of the invention, the method of manufacturing a smoking device may include: providing a filter mouthpiece that includes at least one filter section that includes a porous mass selected from at least one porous mass of the proposed invention; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two smoking device filters containing at least one filter section that includes a porous mass that includes an active portion and a binder portion; and connecting at least one of the filters of the smoking device to the column of tobacco along the longitudinal axis of the filter and

From the longitudinal axis of the column of tobacco to form at least one smoking device.

In some variants of the embodiment of the invention, the method of manufacturing a smoking device may include: providing a column of tobacco; connecting the filter to the column of tobacco, where the filter includes a porous mass selected from at least one porous mass of the proposed invention. The device includes: a container zone, which includes at least a set of parts of the first section of the filter; the zone of the second container, which includes at least a set of parts of the second section of the filter, where the parts of the second section of the filter include a porous mass selected from at least one porous mass of the proposed invention; a connection zone where part of the first filter section and part of the second filter section are connected; a packing zone, where part of the first filter section and part of the second filter section are packed with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In some embodiments, the invention provides a pack of filters that include the porous mass of the proposed invention. The package may be a flip-top package, a pencil case package, a hard-top package, a soft-top package, or any other applicable packaging container. In one embodiment, the invention offers a pack including a pack and at least one filter, which includes at least one filter section containing a porous mass that includes an active particle and a portion of a binder, and the porous mass is filled with an active particle , which is at least about 1 mg/mm, PTC which is about 20 millimeters of water column or less per millimeter of porous mass. In one embodiment, the invention offers a pack including a pack and at least one filter, which includes at least one filter section containing a porous mass, which includes an active part and a part of a binder, and the porous mass has: filling with an active a fraction of at least about 1 mg/mm, PTC that is about 20 millimeters of water column or less per millimeter of porous mass. In some embodiments of the invention, the packs may have an outer wrapper, such as a polypropylene wrapper, and, optionally, a tear-off tab. In some embodiments of the invention, the filters can be sealed inside the pack in the form of a bag. A package can contain multiple filters, for example 20 or more. However, the package may also include a single filter in some embodiments of the invention, such as embodiments of the invention of an exclusive bo filter, such as variants for individual sale or a filter that includes special spices,

such as vanilla, clove or cinnamon.

In some embodiments, the invention offers a pack of smoking devices that includes at least one smoking device containing a filter that includes the porous mass of the proposed invention. The package may be a flip-top package, a pencil case package, a hard-top package, a soft-top package, or any other applicable packaging container. In one embodiment, the invention provides a pack of cigarettes, including a pack and at least one cigarette, including a filter, which includes at least one filter section, which contains a porous mass, which includes an active portion and a portion of a binder, and the porous the mass has: an active particle loading of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass. In one embodiment, the invention provides a pack of cigars comprising a pack and at least one cigar comprising a filter comprising at least one filter section containing a porous mass comprising an active portion and a binder portion, wherein the porous the mass has: an active particle loading of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass. In some embodiments of the invention, the packs may have an outer wrapper, such as a polypropylene wrapper and, optionally, a tear-off tab. In some embodiments of the invention, smoking devices can be sealed inside a pack in the form of a bag. A package may contain several smoking devices, for example 20 or more. However, the package may also include a single smoking device in some embodiments, such as exclusive smoking embodiments such as a cigar or a smoking device that includes special spices such as vanilla, cloves, or cinnamon.

In some embodiments, the invention offers a cardboard package of packs of smoking devices, which includes at least one pack of smoking devices, which includes at least one smoking device containing the porous mass of the proposed invention. For example, in one embodiment, the invention provides a carton of cigarettes, and the carton of cigarettes includes at least one pack of cigarettes, and the pack of cigarettes includes a pack and at least one cigarette that includes a filter that includes at least one section

From a filter containing a porous mass that includes an active fraction and a binder fraction, the porous mass having: an active particle loading of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass. In some embodiments of the invention, the cardboard packaging (for example, the container) has physical integrity that allows it to withstand the weight of the cigarette packs. It may be

C5 is achieved due to the use of thicker cardboard for the formation of cardboard packaging or the use of adhesives that provide greater strength to connect elements of cardboard packaging.

Since a consumer is expected to smoke a smoking device that includes a porous mass as described in the proposed application, the invention also provides methods for smoking such a smoking device. For example, in one embodiment, the invention provides a method of smoking a smoking device, which includes: heating or igniting the smoking device to form smoke, and the smoking device includes at least one filter section containing a porous mass that includes an active portion and a binder portion substances, and the porous mass has: filling with an active particle that is at least about 1 mg/mm, PTK that is about 20 millimeters of water column or less per millimeter of porous mass; and drawing the smoke through the smoking device, wherein the filter section reduces the presence of at least one component in the smoke compared to a filter without a porous mass. In some embodiments of the invention, the smoking device is a cigarette. In other embodiments of the invention, the smoking device is a cigar, a cigar mouthpiece, a smoking pipe, a hookah, a hookah, an electronic smoking device, a smokeless smoking device, a self-rolling cigarette, a self-rolling cigar, or another smoking device.

In one variant of the embodiment of the invention, a smoking device is proposed, which includes a porous mass of active particles adapted to improve tobacco smoke passing through said active particles and particles of a binder. The active particles are from about 195 to about 99 95 by weight of the porous mass, and the particles of the binder are from about 1 95 to about 99 95 by weight of said porous mass. The active particles and said binder particles are connected together at points randomly distributed in the porous mass. The active particles have a larger particle size than the binder particles.

In another embodiment, the invention offers a filter that includes a porous mass that includes an active portion and a portion of a binder, and the active portion includes an element

selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tubular nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, an oxide nanoparticle iron, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, C4(FSbO , core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof...

In one embodiment, the invention provides a filter that includes a porous mass that includes an active portion and a binder portion, and the porous mass has a carbon filling of at least about 6 mg/mm and a pressure drop in the capsule ("PTK "), which is approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a filter that includes a porous mass that includes an active fraction and a binder fraction, and the porous mass has: an active fraction fill of at least about 1 mg/mm, and a PTC of about 20 millimeters of water column or less per millimeter of porous mass, and where the active particle is not carbon.

In one embodiment, the invention offers a method of manufacturing a tobacco smoke filter for a smoking device, which includes: mixing particles of a binder and active particles in such a way as to obtain a porous mass having an active particle content of at least approximately 1 mg/ mm, and PTC that is approximately 20 millimeters of water column or less per millimeter of porous mass, and where the active particle is not carbon.

In one embodiment, the invention offers a method of manufacturing a tobacco smoke filter for a smoking device, which includes the steps of mixing binder particles and active particles, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube, has at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, oxide nanoparticles

From iron, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, etc. FeSboO, core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment, the invention provides a method of manufacturing a tobacco smoke filter for a smoking device, comprising mixing binder particles and active particles in such a way as to produce a porous mass having a carbon content of at least about 6 mg/mm, PTK, which is approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a smoking device filter including at least one filter section containing a porous mass that includes an active fraction and a binder fraction, and the porous mass has: a filling with an active fraction that is at least approximately 1 mg/mm, and a PTC of approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a smoking device filter that includes at least one filter section containing a porous mass that includes an active portion and a binder portion, and the active portion includes an element selected from the group consisting of: carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a horn-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles , silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, 54ФСбО, core-shell nanoparticles, bulbous nanoparticles , nanoshell, bulbous nanoparticle of iron oxide and bu any combination of them.

In one embodiment, the invention provides a smoking device filter that includes at least one filter section that contains a porous mass that includes carbon and a fraction of 60 binder, and the porous mass has a carbon filling that is,

at least about 6 mg/mm, and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a smoking device that includes a filter that includes at least one section of the filter containing a porous mass, and the porous mass contains an active particle and a portion of a binder, and the porous mass has: filling with an active particle that is at least about 1 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a smoking device that includes a filter that includes at least one section of the filter that contains a porous mass, and the porous mass contains an active portion and a binder portion, and the active portion includes an element selected from the group, consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, an iron oxide nanoparticle, a nanoparticle, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, 54(ФСб0, nanoparticles of the type " core-shell", bulbous nanoparticle, nanoshell, bulbous of iron oxide nanoparticles and any combination thereof.

In one embodiment, the invention provides a smoking device that includes a filter that includes at least one filter section containing a porous mass, wherein the porous mass has a carbon content of at least about 6 mg/mm and a PTC of approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a method of manufacturing a cigarette, which includes: providing a column of tobacco; attaching the filter to the column of tobacco, wherein the filter includes a section that includes a porous mass containing an active moiety and a binder moiety, wherein the porous mass has: an active moiety fill of at least about 1 mg/mm, a PTC that is about 20 millimeters of water column or less per millimeter of porous mass, and where the active particle is not carbon; and formation

From a cigarette.

In one embodiment, the invention provides a smoking device that includes a filter that includes an active particle, and the active particle includes an element selected from the group consisting of 3: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tubular nanoprotrusion, bamboo-type carbon nanostructure, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms, endofullerene, 54FSbO, core-shell nanoparticle, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof.

In one embodiment, the invention provides a smoking device that includes a column of tobacco that includes tobacco and, optionally, an element selected from the group consisting of 3: sugar, sucrose, brown sugar, invert sugar, high fructose corn molasses, propylene glycol, glycerin, cocoa, cocoa products, locust bean gum, locust bean extracts, and any combination thereof, and a filter that includes an active moiety, wherein the active moiety includes an element selected from the group consisting of: a carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a horn-like nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, nanoparticles silver, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnet ny nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, С4(ФСбО), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment, the invention provides a smoking device that includes a column of tobacco that includes tobacco and, optionally, an element selected from the group consisting of 3: sugar, sucrose, brown sugar, invert sugar, high fructose corn molasses , propylene glycol, glycerin, cocoa, cocoa products, locust bean gum,

carob bean extracts and any combinations thereof, flavor, menthol, licorice root extract, diammonium phosphate, ammonium hydroxide, and any combinations thereof, and a filter comprising an active moiety, wherein the active moiety comprises an element selected from the group consisting of consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, an iron oxide nanoparticle, a nanoparticle, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, 54FSbO, nanoparticles of the "core- shell", bulbous nanoparticle, nanoshell, bulbous nanoparticle approx sid of iron and any combination thereof.

In one embodiment, the invention provides a smoking device that includes a column of tobacco that includes a source of tobacco selected from the group consisting of: light leaf tobacco, Burley tobacco, oriental tobacco, Cavendish tobacco, "Corojo" tobacco, " criollo", Louisiana black tobacco, shade grown tobacco, White Burley tobacco, and any combination thereof, and optionally an element selected from the group consisting of: sugar, sucrose, brown sugar, invert sugar , high-fructose corn molasses, propylene glycol, glycerin, cocoa, cocoa products, locust bean gum, locust bean extracts and any combinations thereof, flavoring, menthol, licorice root extract, diammonium phosphate, ammonium hydroxide, and any combinations thereof, and a filter that includes an active particle, and the active particle includes an element selected from the group consisting of 3: a carbon nanoparticle, a carbon nanotube having at least one wall carbon nanoparticle with a trumpet-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms,

From endofullerene, 54FSbO, core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment, the invention offers a method of manufacturing a cigarette, which includes: providing a column of tobacco; attaching the filter to the column of tobacco, wherein the filter includes a section that includes a porous mass, wherein the porous mass contains an active portion and a binder portion, and the active portion includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube that has at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, bamboo-type carbon nanostructure, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, oxide nanoparticles metal, aluminum nanoparticle, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with included gadolinium atoms, endofullerene, 54FSbO, core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous oxide nanoparticle iron and any combination thereof.

In one embodiment, the invention offers a method of manufacturing a cigarette, which includes: providing a column of tobacco; attaching the filter to the tobacco column, wherein the filter includes a section that includes a porous mass, wherein the porous mass has a carbon content of at least about 6 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass .

In one embodiment, the invention offers a method of making a cigar, which includes: providing a column of tobacco, attaching a filter to the column of tobacco, and the filter includes a section that includes a porous mass containing an active portion and a portion of a binder, and the porous mass has: a filling an active fraction of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a method of making a cigar, which includes: providing a column of tobacco; attaching the filter to the tobacco column, wherein the filter includes a section that includes a porous mass containing an active particle and a binder portion, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having , at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles , aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous nanoparticles iron oxide and any combination thereof, and forming cigars

In one embodiment, the invention offers a method of making a cigar, which includes: providing a column of tobacco; attaching the filter to the tobacco column, wherein the filter includes a section that includes a porous mass that includes activated carbon and a portion of a binder, wherein the porous mass has a carbon content of at least about 6 mg/mm, and a PTC of approximately 20 millimeters of water column or less per millimeter of porous mass; and cigar shaping.

In one embodiment, the invention provides a pack of cigarettes, including a pack and at least one cigarette, including a filter, which includes at least one filter section, which contains a porous mass, which includes an active portion and a portion of a binder, and the porous the mass has: an active particle loading of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass, and wherein the active particle is not carbon.

In one embodiment, the invention provides a pack of cigarettes including a pack and at least one cigarette including a filter, which includes at least one filter section containing a porous mass, which includes an active portion and a portion of a binder, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles,

Z superparamagnetic nanoparticle, gadolinium oxide nanoparticle, hematite nanoparticle, magnetite nanoparticle, nanotube with incorporated gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof.

In one embodiment, the invention provides a pack of cigarettes, including a pack and at least one cigarette, including a filter, which includes at least one filter section, which contains a porous mass, which includes an active portion and a portion of a binder, and the porous the mass has a carbon content of at least about b mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a pack of cigars comprising a pack and at least one cigar comprising a filter comprising at least one filter section containing a porous mass comprising an active portion and a binder portion, wherein the porous mass has: an active particle fill of at least about 1 mg/mm, and

PTK, which is approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a cigar that includes a filter that includes at least one section of the filter that contains a porous mass that includes an active particle and a portion of a binder, and the porous mass has: filling with an active particle that is at least , about 1 mg/mm, and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a pack of cigars, including a pack and at least one cigar, including a filter, which includes at least one filter section, containing a porous mass, which includes an active portion and a portion of a binder, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, 60 superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles and, nanoshell, bulbous nanoparticle of iron oxide and any combination thereof.

In one embodiment, the invention provides a carton of cigarettes, wherein the carton of cigarettes includes at least one pack of cigarettes, and the pack of cigarettes includes a pack and at least one cigarette that includes a filter that includes at least one filter section that includes a porous a mass that includes an active fraction and a binder fraction, wherein the porous mass has: an active particle loading of at least about 1 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass, and where the active moiety is not carbon.

In one embodiment, the invention provides a cigarette carton package, and the cigarette carton package includes at least one pack of cigarettes including a pack and at least one cigarette including a filter that includes at least one filter section containing a porous mass, which includes an active portion and a portion of a binder, and the active portion includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type ", fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated atoms gadolinium, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment, the invention provides a cigarette carton package, and the cigarette carton package includes at least one pack of cigarettes including a pack and at least one cigarette including a filter that includes at least one filter section containing a porous mass, which includes an active fraction and a binder fraction, and the porous mass has: carbon filling, which is at least approx.

Zo b mg/mm, and PTK, which is approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a carton of cigars, wherein the carton of cigars includes at least one pack of cigars including a pack and at least one cigar including a filter that includes at least one filter section containing a porous mass, which includes an active fraction and a binder fraction, and the porous mass has: an active fraction filling of at least about 1 mg/mm, and

PTK, which is approximately 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a carton of cigars, wherein the carton of cigars includes at least one pack of cigars including a pack and at least one cigar including a filter that includes at least one filter section containing a porous mass, which includes an active portion and a portion of a binder, and the active portion includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type ", fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms yu, endofullerene, za(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof.

In one embodiment, the invention provides a carton of cigars, wherein the carton of cigars includes at least one pack of cigars including a pack and at least one cigar including a filter that includes at least one filter section containing a porous mass, which includes an active portion and a binder portion, wherein the porous mass has: a carbon loading of at least about 6 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a method of manufacturing a filter for a smoking device, which includes embedding a filter in the filter of a smoking device, which includes,

at least one filter section containing a porous mass containing an active particle and a binder particle, the porous mass having: an active particle fill of at least about 1 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass, and where the active fraction is not carbon.

In one embodiment, the invention offers a method of manufacturing a filter of a smoking device, which includes embedding a filter in the filter of a smoking device, which includes at least one filter section containing a porous mass that contains an active part and a part of a binder, and the active part includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tubular nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, 54ФСбО , nanoparticles of the "core-obo" type lonka", bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle and any combination thereof.

In one embodiment, the invention offers a method of manufacturing a filter of a smoking device, which includes embedding a filter in the filter of a smoking device, which includes at least one section of the filter containing a porous mass that contains an active part and a part of a binder, and the porous mass has a carbon content of at least about 6 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention offers a method for manufacturing a filter of a smoking device, which includes: providing a first filter section, providing at least a second filter section, and the second filter section contains a porous mass containing an active part and a part of a binder, and the porous the mass has: an active particle fill of at least about 1 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass; connection of the first section of the filter and,

From at least one second filter in such a way as to form a smoking device filter.

In one embodiment, the invention offers a method for manufacturing a filter of a smoking device, which includes: providing a first filter section, providing at least a second filter section, and the second filter section contains a porous mass containing an active part and a part of a binder, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene , 54FSbO, nanochaz core-shell, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof; connecting the first filter section and at least one second filter so as to form a smoking device filter.

In one embodiment, the invention offers a method for manufacturing a filter of a smoking device, which includes: providing a first filter section, providing at least a second filter section, and the second filter section contains a porous mass containing an active part and a part of a binder, and the porous the mass has: a carbon content of at least about 6 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass; connecting the first filter section and at least one second filter so as to form a smoking device filter.

In one embodiment, the invention provides a method of smoking a smoking device, which includes: heating or igniting the smoking device to form smoke, and the smoking device includes at least one filter section containing a porous mass that contains an active part and a part of a binder, and the porous mass has: filling with an active particle that is at least about 1 mg/mm, PTC that is about 20 millimeters of water column or less per millimeter of porous mass; and drawing the smoke through the smoking device, wherein the filter section reduces the presence of at least one

From the smoke component compared to a filter without a porous mass.

In one embodiment, the invention provides a method of smoking a smoking device, which includes: heating or igniting the smoking device to produce smoke, and the smoking device includes at least one filter section containing a porous mass that contains an active portion and a portion of a binder, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tube-like nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene , oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms , endofullerene, 54(FSb0, core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof; and drawing the smoke through the smoking device, wherein the filter section reduces the presence of at least one component of the smoke compared to a filter without a porous mass.

In one embodiment, the invention provides a method of smoking a smoking device, which includes: heating or igniting the smoking device to produce smoke, and the smoking device includes at least one filter section containing a porous mass that contains an active portion and a binder portion, and the porous mass has: a carbon content of at least about 6 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass; and drawing the smoke through the smoking device, wherein the filter section reduces the presence of at least one component of the smoke compared to a filter without a porous mass.

In one embodiment, the invention offers a device for manufacturing a filter of a smoking device, containing at least a set of sections, including: a container, including at least a set of parts of the first section of the filter; the second container, including at least a set of parts of the second filter section, and the parts of the second filter section include a porous mass containing an active part and a part of a binder, and

The porous mass has: an active fraction filling of at least about 1 mg/mm, a PTC of about 20 or less millimeters of water column or less per millimeter of porous mass; the connection zone, where part of the first section of the filter and part of the second section of the filter are connected; the packaging area, where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the invention offers a device for manufacturing a filter of a smoking device, containing at least a set of sections, including: a container, including at least a set of parts of the first section of the filter; the second container, including at least a collection of parts of the second filter section, and the parts of the second filter section include a porous mass containing an active particle and a part of a binder, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle , a carbon nanotube having at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, a fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous nanoparticles of iron oxide and any combination thereof; a connection zone where part of the first filter section and part of the second filter section are connected; a packaging area where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the invention offers a device for manufacturing a filter of a smoking device, containing at least a set of sections, including: a container, including at least a set of parts of the first section of the filter; a second container including at least a collection of parts of the second filter section, and the parts of the second filter section include a porous mass containing an active portion and a portion of a binder, and because the porous mass has a carbon filling of at least about 6 mg /mm, PTK,

which is approximately 20 millimeters of water column or less per millimeter of porous mass; a connection zone where part of the first filter section and part of the second filter section are connected; a packaging area where part of the first filter section and part of the second filter section are wrapped with paper to form the filter of the smoking device; and a conveyor for moving the smoking device filter to the next area for storage or use.

In one embodiment, the invention offers a method for manufacturing a smoking device filter, which includes: a container that includes at least a set of parts of the first section of the filter; the second container, including at least a set of parts of the second filter section, and the parts of the second filter section include a porous mass containing an active part and a part of a binder; connecting a portion of the first filter section and a portion of the second filter section butt along the longitudinal axis of the portion of the first filter section and portion of the second filter section to form an unpackaged filter mouthpiece; wrapping part of the first filter section and part of the second filter section in paper to form the filter mouthpiece; and moving the filter nozzle to the next area for storage or use.

In one embodiment, the invention provides a method for manufacturing a smoking device, including: providing a filter mouthpiece, including at least one filter section, including a porous mass, which includes an active portion and a binder portion, and the porous mass has: filling an active fraction of at least about 1 mg/mm, a PTC of about 20 millimeters of water column or less per millimeter of porous mass; provision of a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two filters comprising at least one filter section, each filter section comprising a porous mass comprising an active portion and a binder portion; and connecting at least one of the filters to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, the invention provides a method for manufacturing a smoking device comprising: providing a filter mouthpiece comprising at least one filter section comprising a porous mass comprising an active moiety and a binder moiety, wherein the active moiety comprises an element, selected from the group consisting of: a carbon nanoparticle,

From a carbon nanotube with at least one wall, a carbon nanoparticle with a funnel-shaped nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous iron oxide nanoparticles, and any combination thereof; providing a column of tobacco; cutting the filter mouthpiece across its longitudinal axis through the center of the mouthpiece to form at least two filters comprising at least one filter section, each filter section includes a porous mass that includes active part and part of the binder; and connecting at least one of the filters to the column of tobacco along the longitudinal axis of the filter and the longitudinal axis of the column of tobacco to form at least one smoking device.

In one embodiment, the invention provides a smoking device holder that includes a filter that includes at least one filter section having an active particle fill of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a holder for a smoking device that includes a filter that includes at least one filter section containing an active particle, and the active particle includes an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having , at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles , aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, z(FeSboO), core-shell nanoparticles, bulbous nanoparticles, nanoshells, bulbous nanoparticles iron oxide 60 and any combination thereof.

In one embodiment, the invention provides a smoking device holder that includes a filter that includes at least one filter section having a carbon content of at least about b mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a smoking pipe that includes a filter that includes at least one filter section containing a porous mass, the porous mass having an active particle fill of at least about 1 mg/mm, and a PTC that is 20 millimeters of water column or less per millimeter of porous mass.

In one embodiment, the invention provides a tube that includes a filter that includes at least one section of the filter that contains a porous mass that includes an active portion and a portion of a binder, and the active portion includes an element selected from the group consisting of 3 : carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, 54FSbO, core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous nanoparticle of iron oxide, etc any combination thereof.

In one embodiment, the invention provides a smoking device filter that includes at least three adjacent sequential sections, where the first section has an active particle fill of at least about 1 mg/mm and a PTC of about 20 millimeters of water column or less than a millimeter of porous mass, and a second section and a third section, each of which includes a section selected from the group consisting of: cavity, cellulose acetate, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, acetate with arbitrary orientation, paper, corrugated paper, concentric filter, carbon on fiber bundle, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon,

From flavoring, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particle, carbon fiber, fiber, glass ball, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the invention provides a smoking device filter comprising at least three adjacent sequential sections, wherein the first section comprises a porous mass comprising an active moiety and a binder moiety, wherein the active moiety comprises an element selected from the group consisting of with: carbon nanoparticle, carbon nanotube having at least one wall, carbon nanoparticle with a funnel-shaped nanoprotrusion, carbon nanostructure of the "bamboo" type, fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles , gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, endofullerene, C4(FSbO), nanoparticles of the "core- shell", bulbous nanoparticle, nanoshell, bulbous nanoch iron oxide and any combination thereof; and each of the second and third sections includes a section selected from the group consisting of: cavity, cellulose acetate, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate, random orientation acetate, paper, corrugated paper, concentric filter , carbon on a bundle of fibers, silica, magnesium silicate, zeolite, molecular sieve, metallocene, salt, catalyst, sodium chloride, nylon, flavoring, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, coarse powder, carbon particles, carbon fiber, fiber, glass bead, nanoparticle, hollow chamber, hollow chamber with partitions, and any combination thereof.

In one embodiment, the invention provides a smoking device containing a filter that includes a porous mass that includes an active portion and a binder portion, and the active portion is able to remove or reduce at least one component from the smoke stream, and the smoke component is selected from group consisting of: acetaldehyde, acetamide, acetone, acrolein, acrylamide, acrylonitrile, aflatoxin B-1, 4-aminobiphenyl, 1-60 aminonaphthalene, 2-aminonaphthalene, ammonia, ammonium salt, anabasine, anatabine, O-anisidine,

arsenic, A-a-C, benzIa|anthracene, benzIb|Ifluoranthene, benzIaceanthrylene, benzIk|Ifluoranthene, benzene, benzo(b)furan, benzo(a|pyrene, benzo|siphenanthrene, beryllium, 1,

Z-butadiene, butyraldehyde, cadmium, caffeic acid, carbon monoxide, catechin, chlordioxin/furan, chromium, chrysene, cobalt, coumarin, cresol, crotonaldehyde, cyclopenta|c, a|pyrene, dibenz(a, p)acridine, dibenz (a, |)acridine, dibenz(a, niathracene, dibenzo(c, d)carbazole, dibenzo(a, e|pyrene, dibenzo(a, pypyrene, dibenzoga, Cpyrene, dibenzoia,

Cpyrene, 2, b-dimethylaniline, ethylcarbamate (urethane), ethylbenzene, ethylene oxide, eugenol, formaldehyde, furan, diy-p-1, diy-p-2, hydrazine, hydrogen cyanide, hydroquinone, indeno|1,2,3- pyrene, I, isoprene, lead, MedA-a-C, mercury, methyl ethyl ketone, 5-methylchrysene, 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (MMK), 4-(methylnitrosamino) -1- (Z-pyridyl)-1- butanol (MMA), naphthalene, nickel, nicotine, nitrate, nitrogen oxide, nitrite, nitrobenzene, nitromethane, 2-nitropropane, M-Nitrosoanabase (MAV), M-Nitrosodiethanolamine (MOEGA) , M-

Nitrosodiethylamine, M-Nitrosodimethylamine (MOMA), M-Nitrosoethylmethylamine, M-

Nitrosomorpholine (MMOK), M-Nitronornicotine (MMM), M-Nitrosopiperidine (MPIR), M-nitrosopyrrolidine (MRUK), M-nitrososarcosine (MZAK), phenol, RpPIr, polonium-210 (radioactive isotope), propionaldehyde, propylene oxide, pyridine, quinoline, resorcinol, selenium, styrene, resin, 2-toluidine, toluene, Tgr-P-1, Ter-P-2, uranium-235 (radioactive isotope), uranium-238 (radioactive isotope), vinyl acetate, vinyl chloride, and any combinations thereof.

In one embodiment, the invention offers a method of manufacturing a smoking device filter, which includes: providing a first filter section, providing at least a second filter section, and the second filter section contains a porous mass containing an active part and a part of a binder, and the active part capable of removing or reducing at least one smoke component from the smoke stream, and the smoke component is selected from the group consisting of: acetaldehyde, acetamide, acetone, acrolein, acrylamide, acrylonitrile, aflatoxin B-1, 4-aminobiphenyl, 1-aminonaphthalene, 2-aminonaphthalene, ammonia, ammonium salt, anabazin, anatabine, O-anisidine, arsenic, A-a-C, benz(Ia|anthracene, benzIr|fluoranthene, benzI/)aceanthrylene, benzI|rluoranthene, benzene, benzo( p)furan, benzo(a|pyrene, benzo|c|Iphenanthrene, beryllium, 1,3-butadiene, butyraldehyde, cadmium, caffeic acid, carbon monoxide, catechin, chlordioxin/furan, chromium, chrysene, cobalt, coumarin, cresol,

From croton aldehyde, cyclopenta|c, «|pyrene, dibenz(a, p)acridine, dibenz(a, |)acridine, dibenzia, P|athracene, dibenzo(c, d)carbazole, dibenzo(a, e|pyrene, dibenzo(a, PA|pyrene, dibenzo(a, Cpyrene, dibenzo(a, Cpyrene, 2, b-dimethylaniline, ethylcarbamate (urethane), ethylbenzene, ethylene oxide, eugenol, formaldehyde, furan, diy-r-1, ayy-r -2, hydrazine, hydrogen cyanide, hydroquinone, indeno/1,2,3-sa|pyrene, I, isoprene, lead, MedA-a-C, mercury, methyl ethyl ketone, 5-methylchrysene, 4-(methylnitrosamino)-1- (Z-pyridyl)-i-butanone (MMK), 4-(methylnitrosamino)-1-(Z-pyridyl)-1-butanol (MMA), naphthalene, nickel, nicotine, nitrate, nitrogen oxide, nitrite, nitrobenzene, nitromethane , 2-nitropropane, M-Nitrosoanabase (MAV), M-

Nitrosodiethanolamine (MOEGA), M-Nitrosodiethylamine, M-Nitrosodimethylamine (MOMA), M-

Nitrosoethylmethylamine, M(MMOK), M-nitronornicotine (MMM), M-nitrosopiperidine (MPIR), M-nitrosopyrrolidine (MRUK), M-Nitrososarcosine (M5BAK), phenol, RpIr, polonium-210 (radioactive isotope), propionaldehyde, oxide propylene, pyridine, quinoline, resorcinol, selenium, styrene, resin, 2-toluidine, toluene, Tgr-P-1, Ter-P-2, uranium-235 (radioactive isotope), uranium-238 (radioactive isotope), vinyl acetate, vinyl chloride, and any combinations thereof; and connecting the first filter section and at least one second filter so as to form a smoking device filter.

In one embodiment, the invention provides a porous mass having a porosity in the range of about 40 95 to about 90 95.

In one embodiment, the invention provides a filter that includes a porous mass having a porosity in the range of about 40 95 to about 90 95.

In one embodiment, the invention provides a smoking device that includes a filter that includes a porous mass having a porosity in the range of about 40 95 to about 90 95.

In some embodiments, the invention provides a filter that can be used in a smoking device, and the filter includes a porous mass that includes an active portion and a binder portion, and the filter contains at least one or any of the following items a combination of: (a) an active particle comprising an element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a tube-like nanoprotrusion, a bamboo-type carbon nanostructure, a fullerene, an aggregate because of fullerene, graphene, low-layer graphene, oxidized graphene, nanoparticles of iron oxide,

nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with included gadolinium atoms, endofullerene, C4D(FSbO, nanoparticles core-shell, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof; (b) a porous mass having a porosity in the range of about 40 95 to about 90 bo; (c) an active fraction, comprising carbon, and a porous mass having a carbon content of at least about b mg/mm and a PTC of about 20 millimeters of water column or less per millimeter of porous mass; and (d) a porous mass having an active particle fill of at least about 1 mg/mm and a PTC of 20 millimeters of water column or less per millimeter of porous mass.

In order to facilitate a better understanding of the proposed invention, below are given and described examples of typical variants of its implementation. The following examples should in no way be construed as limiting or defining the scope of the invention.

Examples

The following example illustrates the effectiveness of the porous mass in extracting some components of cigarette smoke. The porous mass was made from 25 wt. 95 ZYM 2105 from the company

Tisopa, "E Vaiav, TX and 75 wt. 95 RISA VS 259 (95 95 active carbon) from the company RISA OZA,

Ips. oi Soimtryv5, ON. The porous mass has a percentage porosity of 72,905 and a capsule pressure drop (PDC) of 2.2 millimeters of water column/mm of porous mass length. The porous mass has a circumference equal to approximately 24.5 mm. RISA KS 259 carbon had an average particle size of 569 microns (μm). The porous mass was made by mixing resin (ZK 2105) and carbon (RISA KS 259), and filling the mold with the mixture without applying pressure to the heated mixture (free sintering). The mold was then heated to 200 "C for 40 minutes. After that, the porous mass was removed from the mold and allowed to cool. A section of the porous mass of a certain length was used in combination with

With sufficient adacetyl cellulose tow to produce a filter with a total capsule pressure drop of 70 millimeters of water column. All smoke analyzes were performed in accordance with tobacco industry standards. All cigarettes were smoked using Sapadiap ipiephe rgoioso! (i.e., T-115, "Oegegtipayop oi "Tag, "Misoiipe apa

Saptop Mopohide ip Maipziigeat Tobrasso ZtokKe, " Neaip Sapada, 1999) and Segsheap 450 cigarette smoking machines.

Table 1 5 mm. . 15 mm. porous 10 mm porous.

Porous carbonyls

Control masses, Cho masses, 15 mm Cho Cho mcg/per cigarette masses, 13 mm harness

Formaldehyde, | 104 | 51 /|-51/| 00 /-00| 00 | -100

Crotonaldehyde | 101.7 | 2944 |-71| 00 /-00| 00 | -100

Butyraldehyde, | 114.8 | 433 |-2| 00 /|-00| 00 | -100

Table 2 mm 10 mm 15 mm porous porous porous

Other connections Mass control, Zo mass, Zo mass, Zo 20 mm 15 mm 13 mm harness harness harness

MKkg/sig pshie 1» |» | the same) that is| star (ng/sig)

Table C

Resin, Nicotine 5mm Porous 10mm Porous 15mm Porous etc Mass Control, 20mm | Mass control, 15 mm Control | masses, 13 mm harness harness harness

The following example illustrates the effectiveness of the porous mass in removing some of the 5 components of cigarette smoke. The porous mass was made from 30 wt. 95 ZIOK X192 from the company Tisopa, "E Vbayyakh, TX ii 70 wt. 95 RISA 30 x 70 (60 95 active carbon) from the company

RISA ZA, Ips. oi Soishtry5, ON. The porous mass has a percentage of porosity equal to 75 95 and a pressure drop in the capsule (PTK) equal to 3.3 millimeters of water column/mm length of the porous mass. The porous mass has a circumference equal to approximately 24.5 mm. RISA 30 x 70 carbon had an average particle size of 405 microns (µm).

The porous mass was made by mixing resin (ZY X192) and carbon (RISA 30 x 70) and filling the mold with the mixture without applying pressure to the heated mixture (free sintering). The mold was then heated to 220°C for 60 minutes. The porous mass was then removed from the mold and allowed to cool. A section of the porous mass of a certain length was used in combination with a sufficient amount of acetyl cellulose tow to produce a filter with a total pressure drop of capsule, which was 70 millimeters of water column. All smoke analyzes were performed in accordance with tobacco industry standards. All cigarettes were smoked using Sapadiap ipepzer rgoiosoi (i.e., T-115, Oeieptipatiop oi "Tag,"

Misoiipe apa Sagrop Mopohide ip Maipzigeat Torasso ZtokKe, "Neany Sapada, 1999) and Segsheap 450 cigarette smoking machines.

Table 4 5 mm 10 mm 15 mm

Carbonyls porous o porous o porous o µg/per cigarette Mass control, 20 mm iv mass, 15 mm iv mass, 13 mm iv harness harness harness

Formaldehyde. | 7.9 2 / 53 | 32 | 00 | oh | 00 | about

Acetaldehyde 477.7. | 4780 | 0 | 413.5 | 3 | 337.8 | -29 aldehyde (Methylethyl ether, | 195.7 / 100.8 | 49 | 371 | -81 | 192 | -90

Table 5 mm 10 mm 15 mm porous porous porous

Other connections Mass control, Zo mass, Zo mass, Zo 20 mm 15 mm 13 mm harness harness harness

Benzene (mcg/sy) | 118.7 | 827 | -30 | 401 | -66 | 23.5 | -80

MKkg/sig pe Ge ||| Theo Ilyu| able (ng/sig)

Table 6. 15 mm. . 10 mm porous. ground control, 15 mm etc. 20 mm ground harness, 13 mm harness harness

Resin (mg/sy) | 415 | 45 | | 42 | | from 84

Nicotine (mg/sy) | 28 2 | 28 2 sh | | 29 | | 28

Water (mg/sy) | 16.97 | (170 | | 177 | | 7126 (CO(mg/sy) | 308 | (9332 2 shЩ | | 355 | | 316 /

The following example illustrates the effectiveness of the porous mass of ion exchange resin 5 in removing some components of cigarette smoke. The porous mass was made from 20 wt. 95

SYK 2105 from the company Tisopa, "E Oaiyav, TX and 80 wt. 95 of amine-based resin (AMVEXITE

IKA9BKE from the company Copt 4. Naag5h oi Riade!rnia, RA). A 10 mm long section of porous mass was used in combination with sufficient acetyl cellulose tow (12 mm) to produce a filter with a total capsule pressure drop of 70 millimeters of water column. All smoke analyzes were performed in accordance with tobacco industry standards. All cigarettes were smoked using Sapadiap ipiepze rgoiosoi (i.e.,

T-115, "ROeseptipayop oi "Tag, " Misoiipe apa Sagbop Mopohide ip Maipzigeat Tobrasso Ztoke, "

Neaky Sapada, 1999) and Segiieap 450 cigarette smoking machines.

Table 7

Formaldehyde. | 8077777 IMO | 77777 lo

The following example illustrates the effectiveness of a porous mass of sicatative in extracting water from cigarette smoke. The porous mass was made from 20 wt. 956 ZY 2105 from the Tisopa company, "E VOaiah, TX and 80 wt. 95 sicativ (calcium sulfate, OKIEKITE from the MU company.

A. Nattopa OKIEKITE So. CPU Oi Hepia, ON). A 10 mm long section of porous mass was used in combination with sufficient acetyl cellulose tow (15 mm) to produce a filter with a total capsule pressure drop of 70 millimeters of water column. All smoke analyzes were performed in accordance with tobacco industry standards. All cigarettes were smoked using Sapadiap ipiepze rgoiosoi (i.e.,

T-115, "Oeiiieptipayop oi "Tag, " Misoiipe apa Sagrop Mopohide ip Maipzigeat Tobasso Ztoke, "

Neaky Sapada, 1999) and Segiyep 450 cigarette smoking machines.

Table 8 siccatives siccatives

Cambridge waters pen! with | in" | from nicotine resin

Relation

In the following example, a filter element with carbon on the harness is compared with a porous mass having features of the invention. This comparison compares levels of total carbon saturation. In other words, the amount of carbon in each element is the same; and it is allowed to change the length of the element in such a way that equal amounts of carbon are obtained. The described change in the composition of the smoke is made in relation to a typical acetyl cellulose filter (95 change in relation to a typical acetyl cellulose filter). All filter mouthpieces consisted of a carbon element and a bundle of acetyl cellulose. All filter mouthpieces contained a cellulose acetyl cord of sufficient length to produce a specified pressure drop equal to 70 millimeters of water column. The total length of the filter was 20 mm (carbon element and wire element). The carbon was 60 95 RISA activated carbon with a particle size of 30 x 70. All cigarettes were smoked using Sapadiap ipiephe rgoiosoiY (i.e., T-115, "Regeptipayop oi" Tag, " Misoiipe apa Sagrop Mopohide ip Maipzigeat Torasso ZtokKe, " Neay

Sapada, 1999).

Table 9

PI Po iy Pon iy 39 mg 56 mg 10 mm) 9o change 2 mm), o change (10 mm) 95 9o change| (With mm), 9o shift

In the following example, a porous mass made with highly active carbon (95 95 by absorption of SCIx) is compared with a porous mass made with less active carbon (60 95 by absorption of SCIl). Combination filters were made using a 10 mm long porous mass section plus acetyl cellulose of sufficient length to achieve a specified combined capsule pressure drop of 69-70 millimeters of water column. These filters were attached to a commercially available tobacco column and smoked on a Segieap ZM 450 cigarette smoking machine using Sapadiap ipiepze rgoiosoi (i.e., T-115, "Regeptipayop oi "Tag, " Misoiipe apa Sagrop Mopohide ip Maipzigeat Torasso ZtokKe, " Nay

Sapada, 1999). The highly active carbon was RISA KS 259, with a particle size of 20 x 50, with an activity of 95 95 (according to the absorption of SSIs). Carbon with low activity was RISA ROSA, with a particle size of 30 x 70, with an activity of 60 95 (according to the absorption of SSIs). The carbon content of each element of the porous mass was 18.2 mg/mm for the low activity carbon and 16.7 mg/mm for the high activity carbon. The data are shown in comparison with a typical filter with

From acetyl cellulose.

Table 10

Table 11

The following example illustrates the effect of particle size on capsule pressure drop (CPD).

Porous masses with carbon having different particle sizes were formed into filters (with a length of -39 mm and a circumference of 24.5 mm) by adding a mixture of carbon and resin (ZK 2105) to the mold and heating (free sintering) the mixture at temperature of 2007 for 40 minutes. The porous mass was then removed from the mold and allowed to cool to room temperature. PTCs were determined for 10 porous masses and averaged.

Table 12

PI Bod Bash tea VNS SVNVOYU ratio of the part ve! 3150 NN of the length of the porous mass

In the following example, the porous masses described in Tables 1-3 are used to demonstrate that filters made with 3 such porous masses can be used to produce cigarettes that meet World Health Organization (WHO) standards for cigarettes WHO standards can be found in M/UNO TesNpisa! Rerop 5egivs Mo. 951, Te Zsiepiyis Vavi5 oi Torasso Rgodisi Nedsiaiop, Mopa Neay

Ogodapigayop (2008), Tabrieye 3,10, rade 112. The results below demonstrate that porous mass can be used to reduce the listed constituents from tobacco smoke to levels below WHO recommended levels.

Table 13

Brand

Top Tobacco with Pho Pho Delivered Delivered (mcg) Avg. limit (125 95 by the greatest decrease" decrease" quantity at quantity at value | medium | by delivery (And at length | at length : length of value) | harmful 5 MM 10 mm length 5 mm 10 mm substances!

Continuation of table 13

Brand from Verkhnia about tobacco from Fo and Fo | Delivered Delivered (μg) average limit (125 95 greatest decrease" |decrease" pekness at amount at value | average | by delivery (And at length | at length . length value) | harmful 5 MM 10 mm length 5 mm 10 mm substances!

Benzogd|ipyrene | 91 | 11.4 | 13.8 | 100 | 100 | 00 | 00 (Formaldehyde | 3777. | 471. 1 905 1 51 | 100 | 244 | 00 I 1 The information is based on the data presented in the work of Sopiv, ME, eyi a!., (2004) Maipsigeat ztoke

Iohisapi uieiaz i rgedisiipd heiayop5Pirz vid a mogijide tagkeyi zatrye oi sidagene rgapavz:I5O ztokipd sopaiio55, Kedshiayogu TohisoIodu i Rpagtasiodu, 39:111-134ta in the work of Sotspiv ME, ei a!., (2005) Ztoke sotrozyop i Pigiparzgipedisii sottegosia! sidagene5 5tokea m/yp ipgee taspipeztokKipd sopaiiop5, Kedshiagu Tohisoiodu and Rpappasoiodu, 41:185-227. 2 96 reduction obtained in Tables 1-3 above.

In the following example, a porous mass using ion exchange resins as active particles, as shown in Table 4, is used to demonstrate that filters made with such a porous mass can be used to produce cigarettes that meet the standards of the World Health Organization (EXCITED) for cigarettes. WHO standards can be found in M/NO Tesppis! Kerogi Zeghie5 Mo. 951, Te

Zsiepiyis Vaziz oi Torasso Rgodisi Vediyayop, UUopa Neatsyy Ogodapigayop (2008), Tabie 3,10, rade 112. The results below demonstrate that porous mass can be used to reduce the listed constituents from tobacco smoke to levels below WHO recommended levels.

Table 14

The upper limit of the tobacco brand with 0 beredne | bi; | the largest M oilkiy | phishtny values! average | delivery of harmful 10 mm length 10 mm value) substances! (Formaldehyde. | 377 | 471 | 905 2 | 00 | 00 / 1 The information is based on the data presented in the work of Sotspiv, ME, ei a!., (2004) Maipsigeat ztoke

Iokhisapi uyeid5 and rgedisiipu heiayopzePirz vid a uhogidulide tagkei zatrye oi sidagene rgapav:IZO 5tokipa sopaiiopv5, Nedshiagu Tohisoiodu i Rpagtasiodu, 39:111-134, and in the work of Sotspiv ME, ei ai., (2005) Ztoke sotrozyop i Togkopaipoparsi! sottegosia! sidagene5 5tokea m/yp ipgee taspipez- ztokipd sopaiiop5, Kkedshiagu Tohisoiodu and Rpagtasoiodu, 41:185-227. 2 96 reduction obtained in Table 4 above.

In the following example, the pressure drop across the filter capsule was measured. Porous masses were formed by mixing particles of the binder (ultra high molecular weight polyethylene) and active particles (carbon) at the required mass ratio in a rotating vessel until good mixing was achieved. The mold is made of a stainless steel tube having a length of 120 mm, an inner diameter of 7.747 mm and a circumferential length of 24.34 mm. Each mold was circumferentially lined with standard non-porous filter wrapping paper to mimic the texture of a cork. With a fitting on the bottom to seal the bottom of the mold, the mixture was then placed into the paper lined molds so as to reach the top of the mold. The form is rammed (hit) against the rubber stopper ten times, then trimmed to reach the top of the paper inside the form again, and tapped three more times. The top of the mold is then sealed and placed in an oven and heated to a temperature of 220°C for a period of 25 to 45 minutes, depending on the design of the mold, the molecular weight of the binder particle, and the heat transfer. The pressure drop across the capsule was measured in millimeters of water column. The relevant mixture components and test results are shown below in Tables 15 to 20. The polyethylene binder particles used were obtained from the company Tisopa Roiutegt» GI S, a branch of Seiapese Sogrogayop oi VaiIav,

TH under the trade marks listed below, and the molecular weight is indicated in parentheses: ZYKF 2126 (approximately 4 x 105 g/mol), SShKF 4050-3 (approximately 8-9 x 106 g/mol),

Suka 2105 (approx. 0.47 x 106 g/mol), OSHKF X192 (approx. 0.60 x 105 g/mol), SZKF 4012 (approx. 1.5 x 105 g/mol), and ZR F 4022-6 (approx. 4 x 105 g/mol).

Table 15

Comparative examples

Carbon filling, Pobi -

And comparative for comparatives: . . . of examples (Risa coal Comparative example 1 | Comparative example 2 example C 30 x 70) (vyko 2126) (Kf 4050-3) (17 Mixture: SOKF

M o. Average amount Average amount 2126: СОМКФ 4050-3) ace ratio of carbon in mg/mm of carbon in mg/mm Average amount of carbon and particles. carbon in mg/mm of binder 50/50 11.10 20.65 12.66 60/40 13.90 20.40 15.41 70/30 17.15 19.89 18.30 80/20 20, 52 16.61 20.66 90/10 21.01 13.99 21.11

Table 16

Comparative examples

Comparative

Pressure drop in the capsule. - Example C for comparative Comparative Example 1 vve 2 (17 Mixture of OKO examples (SK 2126). 2126: OKO 4050-3). p (Rice carbon 30 x 70) and (Rice carbon 30 x 70) Average amount of C s, (Rice carbon 30 x ch shch: average amount

Mass ratio | millimeters of water nay: 70) millimeters of water s. of carbon and particles of the column/mm Average amount of column/mm: binding substance millimeters of water column/mm 50/50 60/40 70/30 80/20 90/10

Table 17

Porous masses of the proposed invention

Carbon filling (carbon Part Part Part Part Part

Risa 30 x 70) binding binding binding binding

Mass of substances 1 (ZOKF | substances 2 (ZSHKF | substances Z (ZK substances 4 (ZOKO ratio 2105) x192) 4012) 4022-6) of carbon and particles | The average number of | The average number of | The average number of | The average amount of binding carbon in mg / mm | of carbon in mg/mm | of carbon in mg/mm | carbon in mg/mm of substance 50/50 11.66 10.51 60/40 10.61 11.16 13.35 12.66 65/35 11.70 12.23 70/30 12.70 13.22 15, 01 14.55 75/25 13.81 14.30 in/20 14.75 15.34 16.20 16.57

Where MA is indicated, mouthpieces for the corresponding elements were not manufactured.

Table 18

Porous masses of the proposed invention

Em drop V Part Part Part Part Part (carbon rice 30 x binding binding binding binding

Y - substances 1 (Z0KF substances 2 substances C (ZOKFO) substances 4 (ZKF

M 2105) (KOH 192) 4012) 4022-6) ace , , , , a. Average: Average: Average: Average: ratio y y y : y y y millimeters millimeters millimeters millimeters millimeters of carbon and particles y . of water water water water binding pillar/mm pillar/mm pillar/mm pillar/mm substance 50/50 18.48 60/40 15.71 65/35 70/30 11.43 75/25 80/20

Where MA is indicated, mouthpieces for the corresponding elements were not manufactured.

Table 19

The porous mass of the proposed invention is also a mixture of particles Medium PTK, millimeters

Cell size Carbon, binding |Average saturation and water column/mm of carbon Rice mass. What substances, ! carbon, mg/mm. about porous mass mass Uo 80 x 325 80x325 | 60 | 40 | 12.24 80x325 14.05 80x325 | 80 | 20 | 17.02 1. The mixture of binder particles was a mixture of ZOMKF 2105 and OKO X192 in a ratio of 171 by weight.

Table 20

Additional comparative examples

Available for sale Average PTK for 20th generation of filters, PTK/mm length cigarette filters Length (mm) :. and millimeters of water porous mass (from adcetyl cellulose) column/mm

The data shown in Figures b to 9 was generated from an additional test of PTK porous masses of the proposed invention, based on carbon saturation and comparative examples. Porous masses were formed by mixing particles of a binder, namely, ultrahigh molecular weight polyethylene selected from ZOEF 2105, SOMF X192,

SOKF 4012 and SOKF 8020) and active particles (carbon) at the required mass ratio in a rotating vessel until good mixing is achieved. The mold, made of stainless steel tubing, has a length of 120 mm, an inner diameter of 7.747 mm, and a circumference of 24.5 mm (theoretical) or about 17.4 (theoretical). Each of the molds was lined circumferentially with standard non-porous wrapping paper that imitates the texture of a cork.

With a fitting on the bottom to seal the bottom of the mold, the mixture was then placed into the paper lined molds so as to reach the top of the mold. The form is rammed (struck) ten times against the rubber stopper, then trimmed to meet the top of the paper inside the form again, and struck three more times. The top of the mold is then sealed and placed in an oven, and heated to a temperature of 220 "C for a period of 25 to 45 minutes, depending on the design of the mold, the molecular weight of the binder particle, and the heat transfer. The filter is then cut to lengths of up to 100 mm.

The circumference length of the tested filters is given. They had an almost round shape.

The capsule pressure drop was measured in millimeters of water column according to the procedure

ASSOCIATION

Figure 6 is a comparative document showing the results of capsule pressure drop tests for carbon filters on a harness having an average circumferential length of approximately 24.5 mm.

Figure 7 shows the results of capsule pressure drop tests for porous mass filters of the present invention (including polyethylene and carbon) having an average circumference of approximately 24.5 mm.

Figure 8 is a comparative document showing the results of capsule pressure drop tests for carbon filters on a harness having an average circumferential length of approximately 16.9 mm.

Figure 9 shows the results of capsule pressure drop tests for porous mass filters of the present invention (including polyethylene and carbon) having an average circumference of approximately 16.9 mm.

Therefore, the proposed invention is well adapted to achieve the stated goals and advantages, as well as those that are intrinsic to it. The specific embodiments of the invention disclosed above are given by way of example only, as the proposed invention may be modified and applied in different but equivalent ways that will be apparent to those skilled in the art who take advantage of the ideas of the proposed application. In addition, no limitations are intended regarding the details of the design or development presented in the proposed application other than those described below in the claims. Therefore, it is obvious that

The specific illustrative embodiments of the invention disclosed above may be changed, combined or modified, and all such changes are considered within the scope and spirit of the proposed invention. While the compounds and methods are described in terms of "comprising," "comprising," or "comprising" various components or steps, the compounds and methods may also "consist primarily of" or "consist of" various components and steps. All numbers and ranges disclosed above are subject to change by a certain amount. Whenever a range of numeric values with a lower bound and an upper bound is revealed, any number and any included range that falls within the range is revealed specifically. In particular, each range of values (as "from about a to about p" or, equivalently, "from about a to B", or, equivalently, "from about a to B") disclosed herein is to be understood as which sets each number and the range it covers within a wider range of values. Also, the terms in the claims have their direct ordinary meaning, unless otherwise clearly and clearly indicated by the patent owner. In addition, the indefinite articles "a" or "ap" used in the formula are defined in the proposed application as meaning one or more than one element that the article represents. In the event of any conflict in the use of a word or term in this description of the invention and in one or more patents or other documents that may be incorporated by reference in the proposed application, those definitions consistent with this description of the invention shall apply.

Claims (30)

FORMULA OF THE INVENTION 1. A smoking device filter that contains: a porous mass that includes a collection of active particles and a collection of particles of a non-fibrous binder, where the active particles and particles of a non-fibrous binder are connected together in a collection of contact points obtained by sintering, and where the active particles contain at least one element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a horn-like nanoprotrusion, a carbon nanostructure of the "bamboo" type, fullerene, a fullerene aggregate, graphene, low-layer graphene , oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, 60 silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticle, paramagnetic nanoparticle, superparamagnetic nanoparticle, gadolinium oxide nanoparticles, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated atoms gadolinium, endofullerene, SYA4(FSbO, n core-shell nanoparticle, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof; and where the non-fibrous binder particles have a melt flow index of less than or equal to about 3.5 g/10 min at a temperature of 190 "C and a force of 15 kg. 2. The filter of the smoking device according to claim 1, which is characterized in that the particles of the non-fibrous binder contain a thermoplastic material. C. A smoking device filter according to claim 1, characterized in that the non-fibrous binder particles contain at least one element selected from the group consisting of: ultra high molecular weight polyethylene, very high molecular weight polyethylene, high molecular weight polyethylene by weight, polyolefin, polyester, polyamide, nylon, polyacrylic, polystyrene, polyvinyl, polytetrafluoroethylene, polyetheretherketone, non-fibrous plasticized cellulose, polyethylene, polypropylene, polybutylene, polymethylpentene, low density polyethylene, linear low density polyethylene, high density polyethylene, polyethylene terephthalate, polybutylene terephthalate, polycyclohexyldimethyl terephthalate, polytrimethylene terephthalate, polyacrylate, polymethyl methacrylate, polystyrene, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, butadiene-styrene, styrene-maleic anhydride, ethylene vinyl acetate, ethylene vinyl alcohol, polyvinyl chloride, acetyl cellulose, acetob cellulose waste, plasticized cellulose polymers, cellulose propionate, ethyl cellulose, any derivative thereof, any copolymer thereof, and any combination thereof. 4. The smoking device filter of claim 1, wherein at least some of the non-fibrous binder particles have a particle size in at least one dimension ranging from about 0.1 nanometers to about 5000 microns. 5. The smoking device filter of claim 1, wherein the porous mass has a porosity of from about 40 95 to about 90 95. 6. The filter of the smoking device according to claim 1, which is characterized by the fact that the porous mass includes the ratio of active particles to particles of the binder, which is in the range of ZO from about 1 wt. 95 active particles and approximately 99 wt. 95 parts of the binder to about 99 wt. 95 active particles and approximately 1 wt. 95 particles of binder. 7. The filter of the smoking device according to claim 1, characterized in that the porous mass has a pressure drop across the shell of from about 0.1 to about 20 mm of water column per millimeter of length of the porous mass. 8. A smoking device that contains a smoking substance in interfluidic communication with the filter of the smoking device according to claim 1. 9. A smoking device filter that contains: a porous mass that includes active particles and particles of a non-fibrous binder, where the active particles and particles of a non-fibrous binder are connected together in a set of contact points obtained by sintering, where the active particle includes carbon, and wherein the porous mass has a carbon content of at least about 6 mg/mm and a pressure drop across the shell of about 20 mm of water column or less per millimeter of porous mass; where the particles of the non-fibrous binder have a melt flow index that is less than or equal to approximately 3.5 g/10 min at a temperature of 190 "C and a force equal to 15 kg. 10. The filter of the smoking device according to claim 9, characterized in that at least some of the non-fibrous binder particles include at least one element selected from the group consisting of: ultra-high molecular weight polyethylene, very high molecular weight polyethylene, polyethylene high molecular weight, polyolefin, polyester, polyamide, nylon, polyacrylic, polystyrene, polyvinyl, polytetrafluoroethylene, polyetheretherketone, non-fibrous plasticized cellulose, polyethylene, polypropylene, polybutylene, polymethylpentene, low density polyethylene, linear low density polyethylene, high density polyethylene, polyethylene terephthalate , polybutylene terephthalate, polycyclohexyldimethylterephthalate, polytrimethylene terephthalate, polyacrylate, polymethyl methacrylate, polystyrene, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, butadiene-styrene, styrene-maleic anhydride, ethylene vinyl acetate, ethylene-vinyl alcohol, polyvinyl chloride , acetyl cellulose, cellulose acetobutyrate, plasticized cellulose polymers, cellulose propionate, ethyl cellulose, any derivative thereof, any copolymer thereof, and any combination thereof. 11. The filter of the smoking device according to claim 9, characterized in that the porous mass has a porosity coefficient of from about 40 95 to about 90 95. 12. A smoking device that contains a smoking substance in interfluidic communication with a smoking device filter according to claim 9. 13. A smoking device filter comprising: a porous mass that includes a collection of active particles and a collection of particles of a non-fibrous binder, wherein the porous mass has a porosity of from about 4095 to about 90 95, and where the active particles and particles of non-fibrous of the binder are connected together in a set of contact points obtained due to sintering; particles of the non-fibrous binder have a melt flow index that is less than or equal to approximately 3.5 g/10 min at a temperature of 190 "C and a force equal to 15 kg. 14. The filter of the smoking device according to claim 13, which is characterized in that the particles of the non-fibrous binder contain a thermoplastic material. 15. The filter of the smoking device according to claim 13, characterized in that at least some particles of the non-fibrous binder include at least one element selected from the group consisting of: polyethylene with ultra-high molecular weight, polyethylene with very high molecular weight, polyethylene with high molecular weight, polyolefin, complex polyester, polyamide, nylon, polyacrylic, polystyrene, polyvinyl, polytetrafluoroethylene, polyetheretherketone, non-fibrous plasticized cellulose, polyethylene, polypropylene, polybutylene, polymethyllentene, low density polyethylene, linear low density polyethylene, high density polyethylene, polyethylene terephthalate, polybutylene terephthalate, polycyclohexyldimethylterephthalate, polytrimethylene terephthalate, polyacrylate, polymethyl methacrylate, polystyrene, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, butadiene-styrene, styrene-maleic anhydride, ethylene vinyl acetate, ethylene-vinyl alcohol, polyvinyl chloride, acetyl cellulose, cellulose acetobutyrate, plasticized cellulose polymers, cellulose propionate, ethyl cellulose, any derivative thereof, any copolymer thereof, and any combination thereof. 16. The smoking device filter of claim 13, wherein at least some of the non-fibrous binder particles have a particle size in at least one dimension ranging from about 0.1 nanometers to about 5000 microns. 17. The filter of the smoking device according to claim 13, characterized in that the active particles include at least one element selected from the group consisting of: ion-exchange resin, desiccant, silicate, molecular sieve, silicic acid gel, activated aluminum, zeolite, perlite, sepiolite, fuller's earth, magnesium silicate, metal oxide, iron oxide, activated carbon and any combinations thereof. 18. The smoking device filter according to claim 13, characterized in that the active particles include at least one element selected from the group consisting of: a carbon nanoparticle, a carbon nanotube having at least one wall, a carbon nanoparticle with a horn-like nanoprotrusion, a carbon nanostructure of the type "bamboo", fullerene, fullerene aggregate, graphene, low-layer graphene, oxidized graphene, iron oxide nanoparticles, nanoparticles, metal nanoparticles, gold nanoparticles, silver nanoparticles, metal oxide nanoparticles, aluminum nanoparticles, magnetic nanoparticles, paramagnetic nanoparticles, superparamagnetic nanoparticles, oxide nanoparticles gadolinium, hematite nanoparticles, magnetite nanoparticles, nanotubes with incorporated gadolinium atoms, indofullerene, SDFSbO, core-shell nanoparticles, bulbous nanoparticle, nanoshell, bulbous iron oxide nanoparticle, and any combination thereof. 19. The smoking device filter of claim 13, wherein at least some of the active particles have a particle size in at least one dimension ranging from about 0.1 nanometers to about 5000 microns. 20. The filter of the smoking device according to claim 13, which is characterized in that the porous mass includes the ratio of active particles to particles of the binder, which is in the range of about 1 wt. 95 active particles and approximately 99 wt. 95 parts of the binder to about 99 wt. 95 active particles and approximately 1 wt. 95 particles of binder. 21. The smoking device filter of claim 13, wherein the porous mass has a carbon content of at least about b mg/mm and a pressure drop across the shell of about 20 mm of water column or less per millimeter length of the porous mass. 22. The smoking device filter of claim 13, wherein the porous mass has a pressure drop across the shell of from about 0.1 to about 7 mm of water column per millimeter of length of the porous mass. 23. The smoking device filter of claim 13, wherein the porous mass has an active particle loading of at least about 1 mg/mm and a pressure drop across the shell of less than about 20 mm of water column per millimeter of porous length mass, and where the active part is not carbon. 24. A smoking device that contains: a smoking substance, and a filter in interfluidic communication with the smoking substance, and the filter contains a porous mass that includes a collection of active particles and a collection of particles of a non-fibrous binder, where the porous mass has a porosity coefficient that is from about 40 95 to about 90 95, and where the active particles and particles of the non-fibrous binder are connected together in a set of contact points obtained by sintering; where the particles of the non-fibrous binder have a melt flow index that is less than or equal to approximately 3.5 G/10 min at a temperature of 190 "C and a force equal to 15 kg. 25. The smoking device according to claim 24, which is characterized by the fact that the filter consists mainly of a porous mass. 26. The smoking device according to claim 24, characterized in that the filter includes a set of sections, where at least one section includes a porous mass. 27. The smoking device according to claim 26, characterized in that the filter includes at least one section that includes at least one element selected from the group consisting of: acetyl cellulose, polypropylene, polyethylene, polyolefin tow, polypropylene tow, polyethylene terephthalate, polybutylene terephthalate , acetate with random orientation, paper, corrugated paper, concentric filter, fiber bundle peripheral filter and tape material core, carbon on fiber bundle, Dalmatian filter, silica, magnesium silicate, zeolite, molecular sieve, salt, catalyst, sodium chloride, nylon, flavoring, tobacco, capsule, cellulose, cellulose derivative, catalytic converter, iodic anhydride, fine powder, carbon particle, carbon fiber, fiber, glass ball, hollow chamber, hollow chamber with partitions and any combination thereof. 28. The smoking device according to claim 24, characterized in that the filter includes a cavity. 29. The smoking device of claim 24, wherein the porous mass has an active particle loading of at least about 1 mg/mm and a jacket pressure drop of less than about 20 mm of water column per millimeter length of the porous mass, and where the active moiety is not carbon. 30. The smoking device of claim 24, wherein the porous mass has a carbon content of at least about b mg/mm and a pressure drop across the shell of about 20 mm of water column or less per mm of porous mass. a oz va pn , eh y i I Channnkonchkuzhkynnn 5 I ! 44 k. iv. Fig. 1 She m Shan kt chin Y In one nuretnnnnnnnia and in that Fig. 2 MO zu -iv Fig. FROM THE BOOKS OF M AK M KIH ACTS i m z h. "M more Fig. 4 o s KAK u KK oo KK ВХ: From what p. sho VV sho OKO x: Sto Vo o B V sho s o Ko OO KK SO . In Kv 00 There is her 0 them J There is KV Z KK OKU ZOM PIY KK ЭХ SK шш ши p. o Ka PK OK Eh Ki oh KU O UK. 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