UA101102C2 - Process for the preparation of soluble composite fertilizer based on carbamide - Google Patents

Abstract

The invention relates to the preparation of fertilizers, and can be used in agriculture, forest management and other branches of national economy. A process for the preparation of soluble composite fertilizer based on carbamide, in which soluble organic fertilizer is additionally added to carbamide, chosen from Vermistym or Vermophosphovit, or Bioproferm, or Biotsykl, or Biokom, and sodium or potassium humate, or lignohumate; mixture of biogeneous microelements and phytohormones. The use of fertilizers increases the productivity of agricultural crops.

Description

The invention relates to the field of fertilizer production technology that can be used in rural, communal, forestry and other sectors of the national economy.

The proposed method is not described in the literature.

The main advantages of the proposed compound fertilizer, in contrast to urea, which is widely used in agriculture |1|, is that it includes, in addition to urea, humic and fulvic acids, which are found in humates and alkaline humates, plant growth regulators with phytohormonal activity, as well as valuable biogenic micro- and macroelements.

In addition, the use of these fertilizers makes it possible to increase the productivity of agricultural crops in comparison with urea by more than 10 95.

The task of this invention is to create affordable, effective and environmentally safe soluble fertilizers.

The set task is achieved due to the creation of soluble composite fertilizers based on urea, in which the following is additionally dissolved during heating: an organic fertilizer selected from: Vermistim (according to the patent OA 24334, U) or Vermophosphovit (according to the patent OA 86823, C2), or Bioproferm (according to pat. OA 22415, U), or Biocycle (according to pat. OA 43545, A), or Biocom (according to pat. OA 96338, C2), sodium humate, potassium or lignohumate, a mixture of biogenic trace elements, plant growth regulators and their various combinations in the weight ratio of reagents, mass (mass) parts (parts), and as a mixture of biogenic microelements: Be, Mn, 2p, Si, Co, Mo, B and

Mo, and Be, Mp, 2p, Si, Co, Mo are used in the form of chelating compounds, where the chelating substance is salts of ethylenediaminetetraacetic acid or its analogues, or salts of citric acid or 1-hydroxyethylidenediphosphonic acid, B in the form of boric acid, and

Mo in the form of sodium or potassium molybdate is used as plant growth regulators - Endophyt 1-1 or Endophyt I-1M, or Neophyt, or Neophyt-M, or M-oxide of 2,6-dimethylpyridine, or M-oxide of 2-methylpyridine, or M-oxide of pyridine, or Emistim-BB or Ecostim.

For a better understanding of the description of the application materials, specific examples are given.

Example 1

Composite fertilizer Me1. In a reactor with a capacity of 3 liters, 1 liter of organic fertilizer Vermystim

Zo or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, or water dissolve 1 kg of urea when heating the composite mixture to 80 "C.

The solution is filtered and used as intended.

Example 2

Composite fertilizer Me2. In a reactor with a capacity of 3 liters, 1 kg of urea and 20-150 g of lignohumate or humate of sodium, potassium are dissolved in 1 liter of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, or water when the composite mixture is heated to 60 "С The solution is filtered and used as intended.

Example C

Composite fertilizer Me3. In a reactor with a capacity of 3 l, 1 kg of urea and 20-150 g of zinc or manganese compounds, or copper, or iron, or 5- 50.0 g of cobalt, or in various combinations in the form of chelates, where the chelating substance (is ethylenediaminetetraacetic acid or citric acid or o-oxyethylidene diphosphonic acid when heated to 70 "C. The solution is filtered and used as intended.

Example 4

Composite fertilizer Me4. In a reactor with a capacity of 3 l, 1 kg of urea and 20-80 g of zinc and manganese compounds, and copper, and iron, and 5 0 g of cobalt in the form of chelates, where the chelating agent is ethylenediaminetetraacetic acid or citric or co-oxyethylidene diphosphonic acid when heated to 90 "C. The solution is filtered and used as intended.

Example 5

Composite fertilizer Me5. In a reactor with a capacity of 3 l, 1 kg of urea and 20-150.0 g of a mixture of biogenic trace elements such as REXOLIN or 50-280.0 g a mixture of biogenic microelements of the REDKOM type with intensive mixing and heating to 60 "С.

The solution is filtered and used as intended.

Example 6

Composite fertilizer Mob. In a reactor with a capacity of 3 l, 1 kg of urea and 5-25 ml of Endophyte 1-1 or Endophyte I-1M or Neophyte are dissolved in 1 liter of organic fertilizer Vermystim 60 or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, or water, or Neophyte M, or Emistymus

BB, or Ecostim, or 0.5-5.0 M-oxide of pyridine, or M-oxide of 2-methylpyridine, or M-oxide of 2,6-dimethylpyridine when heated to 50"C. The solution is filtered and used as intended.

Example 7

Composite fertilizer Me7. In a reactor with a capacity of 3 l, 1 kg of urea and 5-25 ml of Endophyte I-1 or Endo-phyte I/-1M are dissolved in 1 liter of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, or water, or Neophyte, or Neophyte M, or

Emistim BB, or Ekostim, and 0.5-5.0 M-oxide of pyridine, or M-oxide of 2-methylpyridine, or M-oxide of 2,6-dimethylpyridine when heated to 50 "C. The solution is filtered and used as intended.

Example 8

Composite fertilizer Me8. In a reactor with a capacity of 3 liters, 1 kg of urea and 5-25 ml of Endophyte /-1 or Endophyte Y-1M or Neophyte are dissolved in 1 liter of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycl, or Biocom, or water , or Neophyte M, or

Emistim BB, or Ecostim, or 0.5-5.0 M-oxide of pyridine, or M-oxide of 2-methylpyridine, or M-oxide of 2,6-dimethylpyridine and 20-150 g of a mixture of biogenic trace elements of the REXOLIN type or 50-280 .0 g of a mixture of biogenic trace elements of the REDKOM type when heated to 60 "C. The solution is filtered and used as intended.

Example 9

Composite fertilizer Me9. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of zinc or manganese compounds, or copper, or iron, 5.0 - 50.0 g of cobalt in the form of chelates, where the chelating substance is ethylenediaminetetraacetic acid or citric or c-oxyethylidenediphosphonic acid and 20-150 g of a mixture of biogenic microelements of the REKSOLIN type or 50-280.0 g of a mixture of biogenic microelements of the REDKOM type and 5-25 Jr

Endophyte I-1 or Endophyte I-1M, or Neophyte, or Neophyte M, or Emistim BB, or Ecostim, or 0.5-5.0 g of pyridine M-oxide, or 2-methylpyridine M-oxide, or M-oxide of 2,6-dimethylpyridine when heated to 60 "C. The solution is filtered and used as intended.

Example 10

Composite fertilizer Me10. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of zinc or manganese compounds, or copper, or iron, 5.0 - 50.0 g of cobalt in the form of chelates, where the chelating agent is ethylenediaminetetraacetic acid or citric or c-oxyethylidenediphosphonic acid and 20-150 g of a mixture of biogenic trace elements of the REKSOLIN type or 50-280.0 g of a mixture of biogenic trace elements of the RELKOM type and 5-25 Jr

Endophyte I-1 or Endophyte I-1M, or Neophyte, or Neophyte M, or Emistim BB, or Ecostim, and 0.5-5.0 g of M-oxide of pyridine, or M-oxide of 2-methylpyridine, with or M- of 2,6-dimethylpyridine oxide when heated to 60 "C. The solution is filtered and used as intended.

Example 11

Composite fertilizer Me11. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of zinc or manganese compounds, or copper, or iron, 5.0 -50.0 g of cobalt in the form of chelates, where the chelating agent is ethylenediaminetetraacetic acid or citric or c-oxyethylidene diphosphonic acid and 20-150 g of a mixture of biogenic microelements of the REKSOLIN type or 50-280.0 g of a mixture of biogenic microelements of the RELKOM type when heated to 65 "C. The solution is filtered and used as intended.

Example 12

Composite fertilizer Me12. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of zinc or manganese compounds, or copper, or iron, 5.0 - 50.0 g of cobalt in the form of chelates, where the chelating agent is ethylenediaminetetraacetic acid or citric acid or o-oxyethylidenediphosphonic acid and 5-25 ml of Endophyte I-1 or Endophyte I-1M, or Neophyte, or Neophyte M, or Emistim BB, or Ecostim, or 0.5-5.0 g of M-oxide of pyridine, or M-oxide of 2-methylpyridine, or M-oxide of 2,6-dimethylpyridine when heated to 60 "C. The solution is filtered and used as intended.

Example 13

Composite fertilizer Me13. In a reactor with a capacity of 3 liters, 1 kg of urea 60, 20-150 g of sodium humate, potassium or lignohumate, 20-150 g of zinc compounds are dissolved in 1 liter of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycl, or Biocom, or water or manganese,

or copper or iron, 5.0-50.0 g of cobalt or their various combinations in the form of chelates, where the chelating substance is ethylenediaminetetraacetic acid or citric acid or c-oxyethylidenediphosphonic acid at a temperature of up to 80"C. The solution is filtered (use as intended .

Example 14

Composite fertilizer Me14. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of sodium humate, potassium or lignohumate and 20-150 g of a mixture of biogenic microelements are dissolved in 1 l of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycl, or Biocom, or water type REXOLIN or 50-280.0 g of a mixture of biogenic trace elements of the REDKOM type at a temperature of up to 60 "C. The solution is filtered and used as intended.

Example 15

Composite fertilizer Me15. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of sodium humate, potassium or lignohumate and 5-25 ml of Endophyte 1- 1 or Endophyte

I-1M, or Neofit, or Neofit M, or Emistim BB, or Ecostim, and/or 0.5-5.0 g of pyridine M-oxide, or 2-methylpyridine M-oxide, or 2,6-M-oxide of dimethylpyridine at a temperature of up to 65 "C. The solution is filtered and used as intended.

Example 16

Composite fertilizer Me16. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of sodium humate, potassium or lignohumate and 20-150 g of zinc compounds are dissolved in 1 l of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycl, or Biocom, or water manganese, or copper, or iron and 5.0-50.0 g of cobalt or their various combinations in the form of chelates, where the chelating substance is ethylenediaminetetraacetic acid or citric acid, or c-oxyethylidenediphosphonic acid 120-150 g of a mixture of biogenic trace elements of the REXOLIN type or 50 -280.0 g of a mixture of biogenic trace elements of the REDKOM type at a temperature of up to 55 "C. The solution is filtered and used as intended.

Example 17

Composite fertilizer Me17. In a reactor with a capacity of 3 l, 1 kg of Vermystim or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, or water is dissolved in 1 liter of organic fertilizer

From urea, 20-150 g of sodium humate, potassium or lignohumate and 20-150 g of zinc or manganese compounds, or copper, or iron and 5.0-50.0 g of cobalt or their various combinations in the form of chelates, where the chelating substance is ethylenediaminetetraacetic acid and 5-25 ml of Endophyte 1-1 or

Endophyte I-1M, or Neophyte, or Neophyte M, or EEmystim BB, or Ecostim, and/or 0.5-5.0 g of pyridine M-oxide, or 2-methylpyridine M-oxide, or 2,6 M-oxide -dimethylpyridine at a temperature of up to 60 "C. The solution is filtered and used as intended.

Example 18

Composite fertilizer Me18. In a reactor with a capacity of 3 l, 1 kg of urea, 20-150 g of sodium humate, potassium or lignohumate and 20-150 g of zinc compounds are dissolved in 1 l of organic fertilizer Vermystim or Vermophosphovit, or Bioproferm, or Biocycl, or Biocom, or water manganese, or copper, or iron and 5.0-50.0 g of cobalt or their various combinations in the form of chelates, where the chelating substance is ethylenediaminetetraacetic acid or citric acid, or c-oxyethylidenediphosphonic acid 120-150 g of a mixture of biogenic trace elements of the REXOLIN type or 50 - 280.0 g of a mixture of biogenic trace elements of the REDKOM type and 5-25 ml of Endophyte 1-1 or

Endophyte I-1M, or Neophyte, or Neophyte M, or EEmystim BB, or Ecostim, or 0.5-5.0 g of pyridine M-oxide, or 2-methylpyridine M-oxide, or 2,6-dimethylpyridine M-oxide at a temperature of up to 60 "C. The solution is filtered and used as intended.

Example 19

Composite fertilizer Me19. In the reactor, with a capacity of 3 l, in 0.5 l of water or Vermistym, or

0.45 kg of urea, 165.0 g of REACOMU-C, 40.0 g of lignohumate and 75.0 ml of Ecostim, or Neophyte, or Endophyte 1-1 are dissolved in Vermophosphovit, or Bioproferm, or Biocycle, or Biocom at a temperature of up to 65 " C. The solution is filtered and used as intended.

Sources of information: 1. Vlasyuk P.A. Biological elements in the vital activity of plants. - Ed. "Scientific opinion" - K. 1969. - P. 39-64.

Claims (2)

FORMULA OF THE INVENTION 1. The method of obtaining a soluble composite fertilizer based on urea, which is characterized by the fact that a soluble organic fertilizer selected from 60 of: Vermistim or Vermophosphovit, or Bioproferm, or Biocycle, or Biocom, and sodium or potassium humate, or lignohumate is additionally added to urea; a mixture of biogenic trace elements and plant growth regulators in various combinations of fertilizer components, with the following ratio of components, wt. time.: 1:1:0.02-0.015):(0.005-0.28):0.0005-0.025). 2. The method according to claim 1, which differs in that as a mixture of biogenic microelements: Ee, Mp, 2p, Sy, Co, Ma, B, Mo are used, and Ee, Mp, 2p, Sy, Co, Md are used in the form of chelates compounds, where the chelating substance is salts of ethylenediaminetetraacetic acid or its analogues, or salts of citric acid, or 1-hydroxyethylidenediphosphonic acid, B in the form of boric acid, and Mo in the form of sodium or potassium molybdate, in the amount relative to urea, by weight. time: 1:(0.005-0.28). Q. The method according to claim 1 or claim 2, which differs in that as plant growth regulators are used - Endophyt 1-1 or Endophyt I-1M, or Neophyt, or Neophyt-M, and/or Emistim-BB, or Ecostim, or M-oxide of 2-methylpyridine, or M-oxide of 2,6-dimethylpyridine, or M-oxide of pyridine in the amount relative to urea, wt. time: 1:(0.005-0.025):(0.0005-0.005).