TWM650363U - The lubricant layer contained graphene component on automobile wiper rubber strip - Google Patents
The lubricant layer contained graphene component on automobile wiper rubber strip Download PDFInfo
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- TWM650363U TWM650363U TW112206967U TW112206967U TWM650363U TW M650363 U TWM650363 U TW M650363U TW 112206967 U TW112206967 U TW 112206967U TW 112206967 U TW112206967 U TW 112206967U TW M650363 U TWM650363 U TW M650363U
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- lubricating layer
- film
- wiper strip
- water
- graphene
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 16
- 229920001971 elastomer Polymers 0.000 title description 6
- 239000000314 lubricant Substances 0.000 title 1
- 230000001050 lubricating effect Effects 0.000 claims abstract description 37
- 239000011521 glass Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 239000005871 repellent Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004636 vulcanized rubber Substances 0.000 claims description 8
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 238000011109 contamination Methods 0.000 abstract description 3
- 239000000843 powder Substances 0.000 abstract description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229920003052 natural elastomer Polymers 0.000 description 5
- 229920001194 natural rubber Polymers 0.000 description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical group C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010074 rubber mixing Methods 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- GPNLWUFFWOYKLP-UHFFFAOYSA-N s-(1,3-benzothiazol-2-yl)thiohydroxylamine Chemical compound C1=CC=C2SC(SN)=NC2=C1 GPNLWUFFWOYKLP-UHFFFAOYSA-N 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
Abstract
一種含石墨烯成分潤滑層結構的汽車雨刷條，包含有一汽車雨刷條，其設置有膠片能配合一汽車玻璃進行刮除雨水，其中有一潤滑層設置於該膠片之表面，且該潤滑層具有0.1至10%的石墨烯含量，而當該膠片運作時，能平滑且均勻地將該潤滑層配合該汽車玻璃的表面鍍膜形成一水膜層，除了具有撥水功能外，更能降低該膠片和該汽車玻璃之摩擦係數、以及避免粉末汙染之情況發生，進而保持駕駛人視野清晰之目的。 A car wiper strip with a lubricating layer structure containing graphene components, including a car wiper strip, which is provided with a film that can cooperate with a car glass to wipe off rainwater, wherein a lubricating layer is provided on the surface of the film, and the lubricating layer has 0.1 to 10% graphene content, and when the film is operated, the lubricating layer can be smoothly and evenly combined with the surface coating of the automobile glass to form a water film layer. In addition to having a water-repellent function, it can also reduce the film and The friction coefficient of the automobile glass and the avoidance of powder contamination are the purpose of maintaining a clear vision for the driver.
Description
本創作係關於一種含石墨烯成分潤滑層結構的汽車雨刷條，主要透過添加硫(或稱交聯反應)橡膠或熱可塑橡膠其中任一種來製作膠片，並在膠片上利用添加石墨烯塗料來取代石墨塗料，藉以改善摩擦係數提高潤滑，並且改善粉末汙染，以及延長雨刷的使用壽命。 This creation is about a car wiper strip with a lubricating layer structure containing graphene. The film is mainly made by adding sulfur (or cross-linking reaction) rubber or thermoplastic rubber, and adding graphene paint to the film. Replaces graphite coating to improve friction coefficient, improve lubrication, reduce powder contamination, and extend wiper service life.
一般市售汽車雨刷膠條，大部分均是以加硫橡膠為主，因彈性與壓縮變形的需求，常見的有天然膠(Natural rubber)、矽橡膠(Silicone Rubber)，但由於橡膠與擋風玻璃的磨擦係數很大，在雨刷使用過程常會出現卡、跳、噪音…等缺點。 Generally, most of the car wiper strips on the market are made of vulcanized rubber. Due to the requirements for elasticity and compression deformation, the most common ones are natural rubber and silicone rubber. However, due to rubber and windshield The friction coefficient of glass is very large, and shortcomings such as jamming, jumping, noise, etc. often occur during the use of the wiper.
所以市售雨刷在加硫成型的步驟後，會再塗佈一層潤滑層來降低摩擦係數，藉以改善前述缺點，目前解決技術都是利用石墨(graphite)塗料進行厚塗手段來達成目的，但其塗抹的量大多超過10每百(克)(橡膠)份數(Parts per hundreds of rubber(or resin)，PHR代表每百份中的等質量單位的含量)，此處，但卻很容易產生脫落，造成表面都是石墨粉末，既粘手又易汙染； 雖後續有許多廠商也針對石墨塗料進行配方改良，進一步添加石蠟、硬酯酸、二硫化鉬…等，但其成本因此會拉高許多，且製作過程也會變長；綜上所述，仍有急待需要改善的缺點。 Therefore, after the vulcanization and molding step, commercially available wipers are coated with a lubricating layer to reduce the friction coefficient to improve the aforementioned shortcomings. The current solution technology is to use thick coating of graphite paint to achieve the goal, but its The amount of application is mostly more than 10 parts per hundreds of rubber (or resin) (PHR represents the content of equal mass units per hundred parts), but it is easy to fall off. , causing the surface to be covered with graphite powder, which is sticky and easily contaminated; Although many manufacturers have subsequently improved the formula of graphite coatings and further added paraffin, stearic acid, molybdenum disulfide, etc., the cost will be much higher and the production process will be longer; in summary, it is still There are shortcomings that urgently need to be improved.
有鑑於雨刷在車輛上的高頻繁使用率，所以為了能夠改善前述習用之缺點，本新型之主要目的，在於提供一種含石墨烯成分潤滑層結構的汽車雨刷條，透過以硫化橡膠、或是熱可塑橡膠配合主基材料透過射出加工來提高產能效率外，另以添加石墨烯塗料來取代石墨塗料，其主要特徵在於：一潤滑層主要設置於一膠片表面，該潤滑層具有0.1至10%的石墨烯含量，而當該膠片運作時，能平滑且均勻地將該潤滑層配合該汽車玻璃的表面鍍膜形成一水膜層，除了具有潑水功能外，更能降低該膠片和該汽車玻璃之摩擦係數，進而保持駕駛人視野清晰之目的，藉此得以降低摩擦係數提高潤滑效果、改善粉末汙染、以及延長雨刷使用壽命。 In view of the high frequency of use of wipers on vehicles, in order to improve the shortcomings of the aforementioned conventional methods, the main purpose of the present invention is to provide a car wiper strip with a lubricating layer structure containing graphene components, through vulcanized rubber or thermoplastic In addition to improving production efficiency through injection processing of the rubber-coated main base material, graphene coating is added to replace the graphite coating. Its main features are: a lubricating layer is mainly provided on the surface of a film, and the lubricating layer contains 0.1 to 10% graphite. When the film is operated, it can smoothly and evenly combine the lubricating layer with the surface coating of the automobile glass to form a water film layer. In addition to having a water-repellent function, it can also reduce the friction coefficient between the film and the automobile glass. , in order to maintain a clear field of vision for the driver, thereby reducing the friction coefficient, improving lubrication effect, improving powder contamination, and extending the service life of the wiper.
該膠片係為硫化橡膠(Vulcanized Rubber)、或熱可塑橡膠(Thermoplastic elastomer，TPE)其中任一種。 The film is either vulcanized rubber (Vulcanized Rubber) or thermoplastic elastomer (TPE).
該潤滑層主要係由噴塗所形成，該潤滑層主要的厚度為0.1至100微米(Micrometer，u)。 The lubricating layer is mainly formed by spraying, and the main thickness of the lubricating layer is 0.1 to 100 micrometers (Micrometer, u).
該潤滑層(30)成分具有矽油0.01至2每百克份數(PHR)，能強化鍍膜撥水的功能。 The lubricating layer (30) has a silicone oil content of 0.01 to 2 parts per hundred grams (PHR), which can enhance the water-repellent function of the coating.
(10):汽車雨刷條 (10):Car wiper strip
(11):膠片 (11):Film
(20):汽車玻璃 (20):auto glass
(30):潤滑層 (30): Lubricating layer
(40):水膜層 (40): Water film layer
[第1圖]係為本新型的示意圖。 [Picture 1] is a schematic diagram of the new type.
[第2圖]係為本新型基於汽車玻璃未有水膜層的放大示意圖。 [Picture 2] is an enlarged schematic diagram of this new type of automobile glass without a water film layer.
[第3圖]係為本新型基於汽車玻璃有水膜層的放大示意圖。 [Picture 3] is an enlarged schematic diagram of the water film layer on automobile glass based on this new type.
[第4圖]係為本新型基於膠片之潤滑層的放大示意圖。 [Figure 4] is an enlarged schematic diagram of the new film-based lubricating layer.
通常根據本新型最佳之可行之實施例，並配合圖式第1~4圖詳細說明後，俾增加對本新型之瞭解，本新型係一種含石墨烯成分潤滑層結構的汽車雨刷條，其具有一汽車雨刷條(10)，該汽車雨刷條(10)設置有一膠片(11)，前述設置方式採扣接或嵌接…等此領域常見手段，並不加以贅述，該膠片(11)能配合一汽車玻璃(20)運作，該膠片(11)主要係為硫化橡膠(Vulcanized Rubber)、或熱可塑橡膠(Thermoplastic elastomer，TPE)其中任一種。 Generally, according to the best feasible embodiment of the present invention and the detailed description in Figures 1 to 4 of the drawings, in order to increase the understanding of the present invention, the present invention is a car wiper strip with a lubricating layer structure containing graphene components, which has A car wiper strip (10). The car wiper strip (10) is provided with a film (11). The aforementioned installation method adopts common methods in this field such as buckling or embedding, which will not be described in detail. The film (11) can be matched with An automobile glass (20) operates, and the film (11) is mainly made of either vulcanized rubber (Vulcanized Rubber) or thermoplastic elastomer (TPE).
而該汽車雨刷條(10)係利用一般橡膠混煉工藝的過程中，在雨刷條成型後加工，添加不同份量的石墨烯所組構成；首先以天然橡膠(Natural Rubber，NR)為例，其中該天然橡膠(NR)、碳黑(carbon black)、硫磺(sulfur)、鋅氧粉(Zinc oxide)、硬脂酸(Stearic acid)等成分先置入捏合機混煉分散10分鐘，之後再將混煉膠置入雙滾輪密煉，此時再分別加入促進劑A、促進劑B、促進劑C直至混煉完成後，再將上述混煉後的半成品置入雨刷模具中，經熱壓硫化成型，而熱壓硫化成型條件為攝氏溫度170℃、時間3分鐘。 The automobile wiper strip (10) is composed of adding different amounts of graphene after the wiper strip is formed using a general rubber mixing process. First, natural rubber (NR) is taken as an example. The natural rubber (NR), carbon black, sulfur, zinc oxide, stearic acid and other ingredients are first put into the kneader and kneaded and dispersed for 10 minutes, and then The mixed rubber is placed in a double roller for internal mixing. At this time, accelerator A, accelerator B, and accelerator C are added respectively until the mixing is completed. The above-mentioned mixed semi-finished product is then placed in the wiper mold and vulcanized by hot pressing. Molding, and hot press vulcanization molding conditions are 170°C and 3 minutes.
上述促進劑A係巰基苯並噻唑(accelerator M，MBT)，促進劑B係二硫化二苯並噻唑(Accelerator DM，MBTS)，而促進劑C則係為苯並噻唑次磺醯胺 (N-cyclohexylbenzothiazole-2-sulphenamide，CBS)，此類促進劑能依橡膠混煉之過程加以增減或替換，並非完全不可更動的進行使用；該潤滑層(30)主要係由噴塗所形成，該潤滑層(30)主要的厚度為0.1至100微米(Micrometer，u)，且該潤滑層(30)含有石墨烯成分0.1%至10%。 The above-mentioned accelerator A is mercaptobenzothiazole (accelerator M, MBT), accelerator B is dibenzothiazole disulfide (Accelerator DM, MBTS), and accelerator C is benzothiazole sulfenamide (N-cyclohexylbenzothiazole-2-sulphenamide, CBS), this type of accelerator can be added, deleted or replaced according to the rubber mixing process, and is not completely unchangeable; the lubricating layer (30) is mainly formed by spraying. The main thickness of the lubricating layer (30) is 0.1 to 100 micrometer (Micrometer, u), and the lubricating layer (30) contains 0.1% to 10% graphene component.
一潤滑層(30)，其主要設置於該膠片(11)表面，該潤滑層(30)具有0.1至10%的石墨烯含量，請參閱如第3圖所示，當該膠片(11)運作時，能平滑且均勻地將該潤滑層(30)配合該汽車玻璃(20)的表面鍍膜形成一水膜層(40)；再請參閱如第4圖所示，若經長時間使用耗損下，該潤滑層(30)鍍膜有耗損下，該膠片(11)運作時，也可進行填補修復讓該潤滑層(30)鍍膜的效果恢復如初；若該潤滑層(30)中的成分再添加矽油0.01至2每百克份數(PHR)的話，則能夠強化鍍膜撥水的功能。 A lubricating layer (30), which is mainly provided on the surface of the film (11). The lubricating layer (30) has a graphene content of 0.1 to 10%. Please refer to Figure 3. When the film (11) operates When, the lubricating layer (30) can be smoothly and evenly combined with the surface coating of the automobile glass (20) to form a water film layer (40); please refer to Figure 4 again, if the wear and tear after long-term use , when the coating of the lubricating layer (30) is worn out, when the film (11) is in operation, it can also be filled and repaired to restore the coating effect of the lubricating layer (30) to the original; if the ingredients in the lubricating layer (30) are added again If the silicone oil is 0.01 to 2 parts per hundred grams (PHR), it can enhance the water-repellent function of the coating.
該潤滑層(30)除了具有潑水功能外，更能降低該膠片(11)和該汽車玻璃(20)之摩擦係數，其測試於塗抹前後可以讓摩擦係數由2.9降低至0.2，使得撥水鍍膜的效用更為明顯，更可進一步保持駕駛人視野清晰之目的。 In addition to having a water-repellent function, the lubricating layer (30) can also reduce the friction coefficient between the film (11) and the automobile glass (20). When tested before and after application, the friction coefficient can be reduced from 2.9 to 0.2, making the water-repellent coating The effect is more obvious and can further maintain the driver's clear vision.
(11):膠片 (11):Film
(20):汽車玻璃 (20):auto glass
(30):潤滑層 (30): Lubricating layer
(40):水膜層 (40): Water film layer
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW112206967U TWM650363U (en) | 2023-07-05 | 2023-07-05 | The lubricant layer contained graphene component on automobile wiper rubber strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW112206967U TWM650363U (en) | 2023-07-05 | 2023-07-05 | The lubricant layer contained graphene component on automobile wiper rubber strip |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWM650363U true TWM650363U (en) | 2024-01-11 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW112206967U TWM650363U (en) | 2023-07-05 | 2023-07-05 | The lubricant layer contained graphene component on automobile wiper rubber strip |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TWM650363U (en) |
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2023
- 2023-07-05 TW TW112206967U patent/TWM650363U/en unknown
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