TWM612171U - Metal ion recovery device - Google Patents

Metal ion recovery device Download PDF

Info

Publication number
TWM612171U
TWM612171U TW109216914U TW109216914U TWM612171U TW M612171 U TWM612171 U TW M612171U TW 109216914 U TW109216914 U TW 109216914U TW 109216914 U TW109216914 U TW 109216914U TW M612171 U TWM612171 U TW M612171U
Authority
TW
Taiwan
Prior art keywords
assembly
base
tube
anode
cathode
Prior art date
Application number
TW109216914U
Other languages
Chinese (zh)
Inventor
張志民
吳振東
Original Assignee
鈦工房有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 鈦工房有限公司 filed Critical 鈦工房有限公司
Priority to TW109216914U priority Critical patent/TWM612171U/en
Publication of TWM612171U publication Critical patent/TWM612171U/en

Links

Images

Abstract

一種金屬離子回收裝置包括底座、框架、進、出液管、陰極管、導電套件、導流件、內、外管、導電桿件、陽極管件與擋件。框架具基壁、貫穿基壁的內環壁及圍繞基壁接於底座上的外環壁。進、出液管貫穿底座且進液管貫穿基壁。管件與桿件皆沿軸線沿伸。陰極管圍繞外環壁,導電套件圍繞陰極管固定在底座。導流件連接外環壁且由內環壁貫穿並具數進液孔,內管貫穿底座以受內環壁間隔圍繞,外管圍繞內管並接於導流件上以介於進液孔與內環壁間。導電桿件導電率高於陰極管且在內管中,陽極管件圍繞外管,擋件連接導電桿件與陽極管件端緣且遠離底座並具數的出液孔。 A metal ion recovery device includes a base, a frame, liquid inlet and outlet pipes, cathode tubes, conductive sets, guides, inner and outer pipes, conductive rods, anode pipes and stoppers. The frame has a base wall, an inner ring wall penetrating the base wall, and an outer ring wall surrounding the base wall and connected to the base. The liquid inlet and outlet pipes penetrate the base and the liquid inlet pipe penetrates the base wall. Both the pipe and the rod extend along the axis. The cathode tube surrounds the outer ring wall, and the conductive sleeve is fixed on the base around the cathode tube. The guide piece is connected to the outer ring wall and penetrated by the inner ring wall and has several liquid inlet holes. The inner tube penetrates the base to be surrounded by the inner ring wall. The outer tube surrounds the inner tube and is connected to the guide piece to intervene in the liquid inlet hole. Between the inner ring wall. The conductivity of the conductive rod is higher than that of the cathode tube and in the inner tube, the anode tube surrounds the outer tube, and the stopper connects the conductive rod and the end edge of the anode tube and is far from the base and has a number of liquid outlet holes.

Description

金屬離子回收裝置 Metal ion recovery device

本新型是有關於一種回收裝置,特別是指一種金屬離子回收裝置。 This model relates to a recovery device, especially a metal ion recovery device.

參閱圖1與圖2,一種現有的金屬離子回收裝置1,是用於連通一電解裝置的一管路(圖未示),以藉此將該電解裝置內的一剩餘電解液10傳輸到該現有的金屬離子回收裝置1內實施電解並回收該剩餘電解液10內的金屬陽離子。該現有的金屬離子回收裝置1包括一外殼11、一設置在該外殼11內的陽極管12、一設置在該外殼11內並圍繞該陽極管12的陰極管13、一配置於該外殼11之一底部並用以連通該電解裝置之管路的進液管14、一配置於該外殼11之一頂部的出液管15,及一電性連接該陽極管12之一底端與該陰極管13之一底端的電源供應器16。 1 and 2, an existing metal ion recovery device 1 is used to communicate with a pipeline (not shown) of an electrolysis device, so as to transfer a remaining electrolyte 10 in the electrolysis device to the Electrolysis is performed in the existing metal ion recovery device 1 and the metal cations in the remaining electrolyte solution 10 are recovered. The existing metal ion recovery device 1 includes a shell 11, an anode tube 12 arranged in the shell 11, a cathode tube 13 arranged in the shell 11 and surrounding the anode tube 12, and a cathode tube 13 arranged in the shell 11. A liquid inlet pipe 14 at the bottom and used to communicate with the pipeline of the electrolysis device, a liquid outlet pipe 15 arranged on a top of the casing 11, and an electrical connection between a bottom end of the anode pipe 12 and the cathode pipe 13 One of the bottom end of the power supply 16.

該現有的金屬離子回收裝置1自該電解裝置(圖未示)引入該剩餘電解液10至該外殼11內部後,該電源供應器16會供電給該陽極管12與該陰極管13,令該陽極管13釋放出電子,使該剩餘 電解液10中的陽離子(如,以含CuSO4之廢水舉例來說)在該陰極管13上獲得電子後還原成一銅鍍層100。然而,該電源供應器16是由該陽極管12與陰極管13底端朝上供電,導致該陽極管12是由其自身的底端朝上釋放出電子,以致於電鍍在該陰極管13上的該銅鍍層100存在有厚度分布不均(下厚上薄)的問題。基於前述供電方向的問題,也同樣導致該剩餘電解液存在有離子濃度分布不均的問題。因此,回收效率下降,甚至於需要循環多次回收才能夠將該剩餘電解液10中的離子降到可被業界接受的濃度。 After the existing metal ion recovery device 1 introduces the remaining electrolyte 10 from the electrolysis device (not shown) into the housing 11, the power supply 16 will supply power to the anode tube 12 and the cathode tube 13, so that the The anode tube 13 releases electrons, so that the cations in the remaining electrolyte 10 (for example, in the waste water containing CuSO 4 for example) obtain electrons on the cathode tube 13 and are reduced to a copper plating layer 100. However, the power supply 16 is powered by the bottom ends of the anode tube 12 and the cathode tube 13 facing upwards, which causes the anode tube 12 to release electrons from its own bottom ends facing upward, so that it is electroplated on the cathode tube 13 The copper plating layer 100 has the problem of uneven thickness distribution (thickness at the bottom and thin at the top). Based on the aforementioned problem of the power supply direction, the remaining electrolyte also has the problem of uneven ion concentration distribution. Therefore, the recovery efficiency is reduced, and it is even necessary to recycle multiple times to reduce the ions in the remaining electrolyte 10 to a concentration acceptable in the industry.

經上述說明可知,改良金屬離子回收裝置的結構,以使其在電流供應平均的前提下能夠維持電解液濃度的均勻,從而提升回收效率,是所屬技術領域中的相關技術人員有待解決的課題。 It can be seen from the above description that improving the structure of the metal ion recovery device so that it can maintain a uniform electrolyte concentration under the premise of an average current supply, thereby improving recovery efficiency, is a problem to be solved by those skilled in the art.

因此,本新型的目的,即在提供一種供電平均的金屬離子回收裝置。 Therefore, the purpose of the present invention is to provide a metal ion recovery device with an even power supply.

於是,本新型之金屬離子回收裝置,適用於連通一電解裝置的排液管路,其包括一底座組件、一陰極組件、一內膽組件,及一陽極組件。 Therefore, the metal ion recovery device of the present invention is suitable for connecting a drain pipeline of an electrolysis device, and includes a base assembly, a cathode assembly, an inner container assembly, and an anode assembly.

該底座組件包括一底座、一框架、一進液管及一出液管。該框架具有一基壁、一貫穿該基壁的內環壁,及一圍繞該基壁並連接於該底座上的外環壁。該進液管貫穿該底座與該框架的基壁以與 該內環壁內的一空間隔絕,且該出液管貫穿該底座以與該內環壁內的空間連通。 The base assembly includes a base, a frame, a liquid inlet pipe and a liquid outlet pipe. The frame has a base wall, an inner ring wall penetrating the base wall, and an outer ring wall surrounding the base wall and connected to the base. The liquid inlet pipe penetrates the base and the base wall of the frame to connect with A space in the inner ring wall is isolated, and the liquid outlet pipe penetrates the base to communicate with the space in the inner ring wall.

該陰極組件包括一沿一軸線朝上沿伸以圍繞該框架之外環壁的陰極管、一圍繞且連接該陰極管以固定在該底座上的導電套件,及一連接該導電套件且反向該底座沿伸的連接件。 The cathode assembly includes a cathode tube extending upward along an axis to surround the outer ring wall of the frame, a conductive sleeve surrounding and connecting the cathode tube to be fixed on the base, and a conductive sleeve connected to the conductive sleeve and reversed The connecting piece extending along the base.

該內膽組件包括一連接於該框架之外環壁並覆蓋該框架之基壁且由該框架之內環壁所貫穿的導流件、一沿該軸線朝上延伸且貫穿該底座以受該框架之內環壁所間隔圍繞的內管,及一沿該軸線朝上延伸且圍繞該內管的外管。該導流件於鄰近該框架之外環壁處具有複數彼此間隔配置且貫穿其自身的進液孔。該外管是連接於該導流件上以介於該等進液孔與該框架之內環壁間。 The inner liner assembly includes a flow guide connected to the outer ring wall of the frame and covering the base wall of the frame and penetrated by the inner ring wall of the frame, and a guide element extending upward along the axis and passing through the base to receive the An inner tube surrounded by the inner ring wall of the frame, and an outer tube extending upward along the axis and surrounding the inner tube. The guide member has a plurality of liquid inlet holes arranged at intervals and penetrating through itself adjacent to the outer ring wall of the frame. The outer tube is connected to the guide piece so as to be interposed between the liquid inlet holes and the inner ring wall of the frame.

該陽極組件包括一沿該軸線朝上且朝下沿伸以局部位在該內膽組件之內管中的導電桿件、一沿該軸線朝上沿伸且圍繞該內膽組件之外管的陽極管件、一連接該導電桿件與該陽極管件之遠離該框架之一端緣的擋件,及一連接於位在該內膽組件之內管外之該導電桿件且反向該底座沿伸的連接件。該陽極組件之擋件具有複數彼此間隔設置且貫穿其自身的出液孔。在本新型中,該陽極組件之導電桿件具有一金屬棒及一包覆於該金屬棒上的金屬層,且該金屬棒的一第一導電率(electrical conductivity;簡稱σ1)高於該陰極管的一第二導電率(σ2)。 The anode assembly includes a conductive rod extending upward and downward along the axis to be partially located in the inner tube of the liner assembly, and a conductive rod extending upward along the axis and surrounding the outer tube of the liner assembly Anode tube, a stopper connecting the conductive rod and an end edge of the anode tube away from the frame, and a conductive rod connected to the conductive rod outside the inner tube of the liner assembly and extending in the opposite direction from the base的连接件。 The connector. The stopper of the anode assembly has a plurality of liquid outlet holes spaced apart from each other and penetrating through itself. In the present invention, the conductive rod of the anode assembly has a metal rod and a metal layer covering the metal rod, and a first conductivity (electrical conductivity; abbreviated as σ 1 ) of the metal rod is higher than the A second conductivity (σ 2 ) of the cathode tube.

本新型的功效在於:該陰極組件之陰極管是經由該連接件朝上供電,而該陽極組件之陽極管件則是經由其連接件朝上供電至其導電桿件以經由其擋件橫向供電至其該陽極管件後朝下供電,藉由前述供電方向相反的設計再配合該陽極組件之導電桿件之金屬棒與該陰極管兩者間的導電率差異以達到供電均勻的作用。 The effect of the present invention is that the cathode tube of the cathode assembly is powered upwards through the connector, and the anode tube of the anode assembly is powered upwards through the connector to its conductive rod, and power is supplied laterally through the stopper. After the anode tube is powered down, the design of the above-mentioned power supply direction is reversed and the conductivity difference between the metal rod of the conductive rod of the anode assembly and the cathode tube is matched to achieve the effect of uniform power supply.

2:底座組件 2: Base components

21:底座 21: Base

22:框架 22: Frame

221:基壁 221: basal wall

222:內環壁 222: inner ring wall

223:外環壁 223: Outer Ring Wall

23:進液管 23: Inlet pipe

24:出液管 24: Outlet pipe

3:陰極組件 3: Cathode assembly

31:陰極管 31: Cathode tube

32:導電套件 32: Conductive kit

33:連接件 33: connecting piece

4:內膽組件 4: Liner components

41:導流件 41: deflector

410:進液孔 410: Inlet hole

4101:上開口 4101: Upper opening

4102:下開口 4102: lower opening

42:內管 42: inner tube

43:外管 43: Outer tube

44:擋件 44: stop

440:出液孔 440: Liquid Outlet

5:陽極組件 5: Anode assembly

51:導電桿件 51: Conductive rod

511:金屬棒 511: Metal Rod

512:金屬層 512: Metal layer

52:陽極管件 52: Anode fittings

521:金屬管 521: metal pipe

522:貴重金屬氧化層 522: precious metal oxide layer

53:擋件 53: stop

530:出液孔 530: Liquid Outlet

54:連接件 54: Connector

6:上蓋 6: Upper cover

7:外罩組件 7: Cover assembly

71:罩體 71: Hood

72:鋼帶 72: steel belt

721:端緣 721: end edge

73:固定件 73: fixed parts

80:排液空間 80: Drainage space

801:進液區間 801: Inlet Interval

802:出液區間 802: Liquid Out Area

803:排液通道 803: Drain Channel

9:密封環 9: Sealing ring

a:軸線 a: axis

R:旋轉方向 R: Rotation direction

本新型的其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:圖1是一正視示意圖,說明一種現有的金屬離子回收裝置;圖2是一局部剖視圖,說明圖1之金屬離子回收裝置經回收金屬離子以電鍍在一陰極管上的態樣;圖3是一剖視圖,說明本新型之金屬離子回收裝置的一實施例;圖4是一正視圖,說明本新型該實施例之一外罩;圖5是一立體圖,說明本新型該實施例之一內膽組件的一導流件的複數進液孔的細部結構;及圖6是一俯視圖,說明本新型該實施例之各進液孔的一上開口與一下開口間的相對位置。 The other features and effects of the present invention will be clearly presented in the embodiments with reference to the drawings, in which: FIG. 1 is a front view schematic diagram illustrating an existing metal ion recovery device; FIG. 2 is a partial cross-sectional view illustrating FIG. 1 The metal ion recovery device recovers metal ions to be electroplated on a cathode tube; Figure 3 is a cross-sectional view illustrating an embodiment of the new metal ion recovery device; Figure 4 is a front view illustrating the present invention An outer cover of an embodiment; Figure 5 is a perspective view illustrating the detailed structure of a plurality of liquid inlet holes of a baffle component of an inner liner assembly of this embodiment of the present invention; and Figure 6 is a top view illustrating this embodiment of the present invention The relative position between the upper opening and the lower opening of each liquid inlet hole.

參閱圖3、圖4與圖5,本新型金屬離子回收裝置的一實施例,適用於連通一電解裝置的排液管路(圖未示),其包括一底座組件2、一陰極組件3、一內膽組件4、一陽極組件5、一上蓋6,及一外罩組件7。 Referring to Figures 3, 4 and 5, an embodiment of the new metal ion recovery device is suitable for communicating with a drain pipe (not shown) of an electrolysis device, which includes a base assembly 2, a cathode assembly 3, An inner container assembly 4, an anode assembly 5, an upper cover 6, and an outer cover assembly 7.

該底座組件2包括一底座21、一框架22、一進液管23及一出液管24。該框架22具有一基壁221、一貫穿該基壁221的內環壁222,及一圍繞該基壁221並連接於該底座21上的外環壁223。該進液管23貫穿該底座21與該框架22的基壁221以與該內環壁222內的一空間隔絕,且該出液管24貫穿該底座21以與該內環壁222內的空間連通。本新型該實施之底座組件2是由電氣絕緣的材質所構成;具體來說,該底座組件2的細部元件是由塑料所製成,且彼此間是經由高溫熔接結合在一起。 The base assembly 2 includes a base 21, a frame 22, a liquid inlet pipe 23 and a liquid outlet pipe 24. The frame 22 has a base wall 221, an inner ring wall 222 penetrating the base wall 221, and an outer ring wall 223 surrounding the base wall 221 and connected to the base 21. The liquid inlet pipe 23 penetrates the base 21 and the base wall 221 of the frame 22 to be isolated from a space in the inner ring wall 222, and the liquid outlet pipe 24 penetrates the base 21 to be separated from the space in the inner ring wall 222 Connected. The base assembly 2 of this implementation of the present invention is made of electrically insulating materials; specifically, the detailed components of the base assembly 2 are made of plastic, and are joined to each other through high-temperature welding.

該陰極組件3包括一沿一軸線a朝上沿伸以圍繞該框架22之外環壁223的陰極管31、一圍繞且連接該陰極管31以固定在該底座21上的導電套件32,及一連接該導電套件32且反向該底座21沿伸的連接件33。具體來說,該陰極組件3之導電套件32與連接件33兩者間是透過如圖3所示的螺絲與螺帽彼此固定結合。 The cathode assembly 3 includes a cathode tube 31 extending upward along an axis a to surround the outer ring wall 223 of the frame 22, a conductive sleeve 32 surrounding and connected to the cathode tube 31 to be fixed on the base 21, and A connecting piece 33 that is connected to the conductive sleeve 32 and extends along the opposite direction of the base 21. Specifically, the conductive sleeve 32 and the connecting member 33 of the cathode assembly 3 are fixedly combined with each other through screws and nuts as shown in FIG. 3.

該內膽組件4包括一連接於該框架22之外環壁223並覆蓋該框架22之基壁221且由該框架22之內環壁221所貫穿的導流件41、一沿該軸線a朝上延伸且貫穿該底座21以受該框架22之內環壁 221所間隔圍繞的內管42,及一沿該軸線a朝上延伸且圍繞該內管42的外管43。該導流件41於鄰近該框架22之外環壁223處具有複數彼此間隔配置且貫穿其自身的進液孔410。該外管43是連接於該導流件41上以介於該等進液孔410與該框架22之內環壁221間。本新型該內膽組件4之材質雷同於前述底座組件2,同樣是由電氣絕緣的材質所構成。具體來說,該內膽組件4之導流件41、內管42與外管43等細部元件皆是由塑料所製成,且彼此間是經由高溫熔接結合在一起。 The inner bladder assembly 4 includes a flow guide 41 connected to the outer ring wall 223 of the frame 22 and covering the base wall 221 of the frame 22 and penetrated by the inner ring wall 221 of the frame 22, and a guide member 41 that faces along the axis a Extends upward and penetrates the base 21 to receive the inner ring wall of the frame 22 The inner tube 42 surrounded by the interval 221, and an outer tube 43 extending upward along the axis a and surrounding the inner tube 42. The guide member 41 has a plurality of liquid inlet holes 410 spaced apart from each other and penetrates through itself adjacent to the outer ring wall 223 of the frame 22. The outer tube 43 is connected to the flow guide 41 so as to be interposed between the liquid inlet holes 410 and the inner ring wall 221 of the frame 22. The material of the inner container assembly 4 of the present invention is the same as that of the aforementioned base assembly 2, and is also made of electrically insulating material. Specifically, the flow guide 41, the inner tube 42 and the outer tube 43 of the inner bladder assembly 4 are all made of plastic, and they are joined together by high-temperature welding.

該陽極組件5包括一沿該軸線a朝上且朝下沿伸以局部位在該內膽組件4之內管42中的導電桿件51、一沿該軸線a朝上沿伸且圍繞該內膽組件4之外管43的陽極管件52、一連接該導電桿件51與該陽極管件52之遠離該框架22之一端緣的擋件53,及一連接件54。該陽極組件5之連接件54是連接於位在該內膽組件4之內管42外的該導電桿件51且反向該底座21沿伸。該陽極組件5之擋件53具有複數彼此間隔設置且貫穿其自身的出液孔530。 The anode assembly 5 includes a conductive rod 51 extending upward and downward along the axis a to be partially located in the inner tube 42 of the inner tube assembly 4, and a conductive rod 51 extending upward along the axis a and surrounding the inner tube. The anode tube 52 of the outer tube 43 of the bladder assembly 4, a stopper 53 connecting the conductive rod 51 and an end of the anode tube 52 away from the frame 22, and a connecting member 54. The connecting member 54 of the anode assembly 5 is connected to the conductive rod 51 located outside the inner tube 42 of the inner tube assembly 4 and extends along the opposite direction of the base 21. The blocking member 53 of the anode assembly 5 has a plurality of liquid outlet holes 530 spaced apart from each other and passing through itself.

該上蓋6是固定於該陰極管31之遠離該底座組件2的一端緣以封閉該陰極管31。該外罩組件7包括一沿該軸線a朝上延伸以套設於該陰極組件3的導電套件32外的罩體71、一圍繞該罩體71之一底部的鋼帶72,及固定於該鋼帶72之相反兩端緣721的複數固定件73。在本新型該實施例中,該陰極組件3之導電套件32及連接件 33兩者間還配置有一如圖3所示之用以避免電解液外洩的密封環9,該鋼帶72外還配置有複數用以固定該罩體71的吊環螺絲(圖4未示),且該鋼帶72是一不鏽鋼環片,而各固定件73是如圖4所示的一螺絲螺帽組。具體來說,如圖3所示之配置於該陰極組件3之導電套件32及連接件33兩者間的密封環,是透過前述固定組73(即,螺絲螺帽組)來使該鋼帶72(即,不鏽鋼環片)之彼此相向的該等端緣721間的距離縮減,以藉此束緊該鋼帶72,令該密封環9是緊密地固定於該陰極組件3之導電套件32外。 The upper cover 6 is fixed to an edge of the cathode tube 31 away from the base assembly 2 to close the cathode tube 31. The outer cover assembly 7 includes a cover 71 extending upward along the axis a to be sheathed outside the conductive sleeve 32 of the cathode assembly 3, a steel strip 72 surrounding a bottom of the cover 71, and fixed to the steel A plurality of fixing members 73 of the opposite ends 721 of the belt 72. In this embodiment of the present invention, the conductive sleeve 32 and the connecting piece of the cathode assembly 3 33 There is also a sealing ring 9 as shown in Figure 3 to prevent leakage of the electrolyte. The steel belt 72 is also provided with a plurality of ring screws for fixing the cover 71 (not shown in Figure 4). And the steel belt 72 is a stainless steel ring piece, and each fixing member 73 is a screw and nut group as shown in FIG. 4. Specifically, as shown in FIG. 3, the sealing ring disposed between the conductive sleeve 32 and the connecting piece 33 of the cathode assembly 3 is used to make the steel strip through the aforementioned fixing group 73 (ie, screw and nut group) The distance between the opposite ends 721 of 72 (ie, stainless steel ring sheet) is reduced, so as to tighten the steel strip 72 so that the sealing ring 9 is tightly fixed to the conductive sleeve 32 of the cathode assembly 3 outer.

根據上述說明並配合參閱圖3可知,本新型該陰極組件3之陰極管31、該內膽組件4之內管42、該陽極組件5之陽極管件52與其擋件53,及該上蓋6共同界定出一排液空間80;其中,該陰極管31與該陽極管件52兩者間以及該上蓋6與該陽極組件5之擋件53兩者間為該排液空間80的一進液區間801,且該內膽組件4之內管42與該陽極管件52兩者間為該排液空間80的一出液區間802;此外,該排液空間80連通該底座組件2之進液管23與該內膽組件4之導流件41的該等進液孔410。再參閱圖3,該底座組件2之框架22的內環壁222與該內膽組件4的內管42間共同界定出一排液通道803,該排液通道803連通該底座組件2的出液管24與該排液空間80的出液區間802。 According to the above description and with reference to FIG. 3, it can be seen that the cathode tube 31 of the cathode assembly 3, the inner tube 42 of the inner tube assembly 4, the anode tube 52 of the anode assembly 5 and the stopper 53, and the upper cover 6 of the present invention are jointly defined A drain space 80 is provided; wherein, between the cathode tube 31 and the anode tube 52 and between the upper cover 6 and the stopper 53 of the anode assembly 5 are an inlet space 801 of the drain space 80, And between the inner tube 42 of the inner tube assembly 4 and the anode tube 52 is an outlet space 802 of the drain space 80; in addition, the drain space 80 communicates with the inlet tube 23 of the base assembly 2 and the The liquid inlet holes 410 of the baffle 41 of the inner liner assembly 4. 3 again, the inner ring wall 222 of the frame 22 of the base assembly 2 and the inner tube 42 of the liner assembly 4 jointly define a drainage channel 803, and the drainage channel 803 communicates with the drainage of the base assembly 2. The discharge area 802 between the pipe 24 and the discharge space 80.

由上述各段對該底座組件2、該陰極組件3、該內膽組件 4與該陽極組件5等構件的詳細說明再次參閱圖3可知,就本新型該實施例與該電解裝置之排液管路及其剩餘電解液(圖未示)間的流通關係來說,其是藉由該底座組件2之進液管23來連通該電解裝置之排液管路,使該電解裝置之剩餘電解液是經由該進液管23與該內膽組件4之導流件41的進液孔410被引入該排液空間80的進液區間801內,並朝上經流經該陽極組件5之擋件53的出液孔530後進入該排液空間80的出液區間802,以朝下流進該排液通道803並進入該底座組件2的出液管24排出該實施例之金屬離子回收裝置外。 From the above sections, the base assembly 2, the cathode assembly 3, and the inner container assembly 4 and the detailed description of the anode assembly 5 and other components referring to Fig. 3 again, it can be seen that in terms of the circulation relationship between the embodiment of the present invention and the drain pipe of the electrolysis device and the remaining electrolyte (not shown), the The liquid inlet pipe 23 of the base assembly 2 is used to connect the drain pipe of the electrolytic device, so that the remaining electrolyte of the electrolytic device passes through the liquid inlet pipe 23 and the flow guide 41 of the inner container assembly 4 The liquid inlet 410 is introduced into the liquid inlet section 801 of the liquid discharge space 80, passes upward through the liquid outlet hole 530 of the stopper 53 of the anode assembly 5, and then enters the liquid outlet section 802 of the liquid discharge space 80. The liquid outlet pipe 24 flowing downward into the liquid discharge channel 803 and into the base assembly 2 is discharged out of the metal ion recovery device of this embodiment.

進一步就本新型該實施例在回收該剩餘電解液之金屬離子時的供電關係來說,其一方面是利用電氣絕緣的該底座組件2與內膽組件4來與該陰極組件3及該陽極組件5形成電性隔絕,以避免該陰極組件3之連接件33與陽極組件5之連接件54電連接至一外部電源供應器(圖未示)時形成短路。另一方面,由圖3所示可知,該陰極組件3之導電套件32是鄰近該底座組件2的底座21,且該陽極組件5之導電桿件51用來連接其連接件54的位置也鄰近該底座組件2的底座21;因此,該外部電源供應器皆是由該底座21處對該陰極組件3與該陽極組件5供電。雖然該陰極組件3與該現有的金屬離子回收裝置雷同,也是由下往上供電。然而,根據該陽極組件5之細部元件間的連接關係可知,該陽極組件5之導電桿件51及陽極管件52在遠離該框架22的端緣皆是接連其擋件53;因此,當該外部 電源供應器自底座21處供電該陽極組件5時,其電流的供電路徑便是由該導電桿件51由下往上傳遞至其擋件53以橫向傳遞至其陽極管件52並朝下傳遞電流。換句話說,本新型該實施例在回收該剩餘電解液之金屬離子時的供電關係上,該陰極組件3之陰極管31是由下而上傳遞電流,而該陽極組件5之陽極管件52則是由上而下傳遞電流;因此,本新型該實施例可藉由該陰極管31及陽極管件52兩者電流傳遞方向相反的關係,以解決該現有之電流供應不均所致的問題。 Further in terms of the power supply relationship of the embodiment of the present invention when recovering the metal ions of the remaining electrolyte, one aspect is to use the electrically insulated base assembly 2 and the inner container assembly 4 to interact with the cathode assembly 3 and the anode assembly. 5 to form an electrical isolation to avoid a short circuit when the connecting member 33 of the cathode assembly 3 and the connecting member 54 of the anode assembly 5 are electrically connected to an external power supply (not shown). On the other hand, as shown in FIG. 3, it can be seen that the conductive sleeve 32 of the cathode assembly 3 is adjacent to the base 21 of the base assembly 2, and the position where the conductive rod 51 of the anode assembly 5 is used to connect its connecting member 54 is also adjacent The base 21 of the base assembly 2; therefore, the external power supply is powered by the base 21 to the cathode assembly 3 and the anode assembly 5. Although the cathode assembly 3 is similar to the existing metal ion recovery device, it also supplies power from bottom to top. However, according to the connection relationship between the detailed elements of the anode assembly 5, the conductive rod 51 and the anode tube 52 of the anode assembly 5 are connected to the stopper 53 at the end far away from the frame 22; therefore, when the external When the power supply supplies power to the anode assembly 5 from the base 21, the current supply path is from the conductive rod 51 to its stopper 53 from bottom to top, and then to the anode tube 52 in the transverse direction and the current downward. . In other words, with regard to the power supply relationship when recovering the metal ions of the remaining electrolyte in this embodiment of the present invention, the cathode tube 31 of the cathode assembly 3 transmits current from bottom to top, while the anode tube 52 of the anode assembly 5 is The current is transferred from top to bottom; therefore, the current transfer direction of the cathode tube 31 and the anode tube 52 can be reversed in this embodiment of the present invention to solve the existing problem of uneven current supply.

基於該陽極組件5之供電路徑較該陰極組件3長,為使該陽極管件52在朝下供應電流時能與該陰極組件3之陰極管31朝上供應電流同時,並避免該導電桿件51在該實施例長時間執行離子回收程序時遭受自該剩餘電解液所形成的蒸汽而氧化以對其導電率造成不良的影響。因此,較佳地,該陽極組件5之導電桿件51具有一金屬棒511,及一包覆於該金屬棒511上並用以避免該金屬棒511遭該剩餘電解液所形成的蒸氣而氧化的金屬層512,且該金屬棒511的一第一導電率(σ1)高於該陰極管31的一第二導電率(σ2)。 Based on the fact that the power supply path of the anode assembly 5 is longer than that of the cathode assembly 3, the anode tube 52 can supply current while the cathode tube 31 of the cathode assembly 3 faces upwards when supplying current, and the conductive rod 51 is avoided. When this embodiment performs the ion recovery process for a long time, it is oxidized by the steam formed from the remaining electrolyte to adversely affect its electrical conductivity. Therefore, preferably, the conductive rod 51 of the anode assembly 5 has a metal rod 511, and a metal rod 511 coated on the metal rod 511 to prevent the metal rod 511 from being oxidized by the vapor formed by the remaining electrolyte. The metal layer 512, and a first conductivity (σ 1 ) of the metal rod 511 is higher than a second conductivity (σ 2 ) of the cathode tube 31.

較佳地,σ12

Figure 109216914-A0305-02-0012-1
6.5。更佳地,6.5
Figure 109216914-A0305-02-0012-2
σ12
Figure 109216914-A0305-02-0012-3
28.5。適用於本新型該金屬棒511之金屬材料是選自σ1為59.6×106S.m-1的銅(Cu)、σ1為63.01×106S.m-1的銀(Ag)、σ1為37.8×106S.m-1的鋁(Al)、σ1為14.43×106S.m-1的鎳(Ni),或σ1為42.56×106 S.m-1的金(Au)。該陰極組件3的陰極管31是由鈦(Ti)或不鏽鋼(stainless)所製成。在本新型該實施例中,該陽極組件5之該金屬棒511是由銅所製成,且該陰極組件3之陰極管31是由導電率為2.22×106S.m-1的鈦所製成。此外,為確保電鍍於該陰極管31之一內表面上的銅鍍層易於剝除回收;因此,更佳地,該陰極組件3之陰極管31之內表面是經拋光的表面,令該實施完金屬離子回收程序後所形成在陰極管31上的銅鍍層不易附著於其內表面,以方便該銅鍍層剝除回收。 Preferably, σ 12
Figure 109216914-A0305-02-0012-1
6.5. More preferably, 6.5
Figure 109216914-A0305-02-0012-2
σ 12
Figure 109216914-A0305-02-0012-3
28.5. The metal material suitable for the metal rod 511 of the present invention is selected from σ 1 of 59.6×10 6 S. The copper (Cu) and σ 1 of m -1 are 63.01×10 6 S. The silver (Ag) and σ 1 of m -1 are 37.8×10 6 S. The aluminum (Al) and σ 1 of m -1 are 14.43×10 6 S. m -1 nickel (Ni), or σ 1 is 42.56×10 6 S. m -1 gold (Au). The cathode tube 31 of the cathode assembly 3 is made of titanium (Ti) or stainless steel. In this embodiment of the present invention, the metal rod 511 of the anode assembly 5 is made of copper, and the cathode tube 31 of the cathode assembly 3 is made of conductivity of 2.22×10 6 S. m -1 made of titanium. In addition, in order to ensure that the copper plating layer electroplated on the inner surface of the cathode tube 31 is easily stripped and recycled; therefore, more preferably, the inner surface of the cathode tube 31 of the cathode assembly 3 is a polished surface, so that the implementation is completed The copper plating layer formed on the cathode tube 31 after the metal ion recovery process is not easy to adhere to its inner surface, so as to facilitate the stripping and recovery of the copper plating layer.

在本新型該實施例中,該陽極管件52具有一金屬管521,及一塗佈於該金屬管521上的貴重金屬氧化層522。具體來說,該金屬管521是一網狀鈦管,該貴重金屬氧化層522可以是氧化銥(IrO2)或氧化釕(RuO4)等金屬氧化物。包覆有貴重金屬氧化層的鈦,是業界常見的不溶性陽極,並非本新型之技術重點,於此不再多加贅述。 In this embodiment of the present invention, the anode tube 52 has a metal tube 521 and a precious metal oxide layer 522 coated on the metal tube 521. Specifically, the metal tube 521 is a mesh titanium tube, and the precious metal oxide layer 522 may be metal oxides such as iridium oxide (IrO 2 ) or ruthenium oxide (RuO 4 ). Titanium coated with a precious metal oxide layer is a common insoluble anode in the industry, and is not the technical focus of the present invention, so I will not repeat it here.

此處值得一提的是,本新型該實施例之陰極管31是由鈦薄片經捲繞而成,其在捲繞過程中預留有約10mm的重疊處以構成管狀的態樣。具體來說,該陰極管31是圍繞該底座組件2之框架22外環壁223,該陰極管31的底端是由圍繞於其外的該導電套件32固定在該底座21上,且該陰極管31之遠離該底座件2的端緣(即,頂端)是由該上蓋6所填塞以封閉該陰極管31。因此,當該實施例執行 完離子回收程序欲自該陰極管31回收銅鍍層時,只要拆除該上蓋6與該導電套件32,該陰極管31便會依其自身的彈性自動地彈開攤平成薄片狀,並在攤平成薄片狀的同時令其內表面所電鍍沉積的銅鍍層瞬間地局部剝離,而該陰極管31在攤平成薄片狀後,銅鍍層已局部地剝離其內表面;因此,如此狀態下未剝離的銅鍍層便易於剝除回收。 It is worth mentioning here that the cathode tube 31 of this embodiment of the present invention is wound from a titanium sheet, and an overlap of about 10 mm is reserved during the winding process to form a tubular shape. Specifically, the cathode tube 31 surrounds the outer ring wall 223 of the frame 22 of the base assembly 2, and the bottom end of the cathode tube 31 is fixed on the base 21 by the conductive sleeve 32 surrounding it, and the cathode The end (ie, the top end) of the tube 31 away from the base member 2 is filled by the upper cover 6 to close the cathode tube 31. Therefore, when this example is executed When the ion recovery procedure is to recover the copper coating from the cathode tube 31, only the upper cover 6 and the conductive sleeve 32 are removed, and the cathode tube 31 will automatically spring and flatten into a thin sheet according to its own elasticity, and then flatten into At the same time, the copper plating layer on the inner surface of the cathode tube 31 is partially peeled off at the same time. After the cathode tube 31 is flattened into a sheet shape, the copper plating layer has partially peeled off its inner surface; therefore, the copper that is not peeled off in this state The coating can be easily stripped and recycled.

較佳地,參閱圖5與圖6,該內膽組件4之導流件41是一板狀體,該內膽組件4之該等進液孔410是呈環形排列且彼此間的距離相等,且該導流件41的各進液孔410是呈斜向貫穿該板狀體。具體來說,沿該軸線a的一旋轉方向R,該導流件41之該等進液孔410的一上開口4101皆是位在各自所對應之一下開口4102的前方。配合參閱圖3,本新型該實施例之導流件41上的進液孔410斜向貫穿該板狀體的用意在於,使該剩餘電解液經一幫浦(圖未示)自該等進液孔410引入至該排液空間80後,能呈現出如圖3所示的渦流,以令在該排液空間80內進行金屬離子回收程序過程中的該剩餘電解液能持續維持均勻的濃度。 Preferably, referring to FIGS. 5 and 6, the air guide 41 of the liner assembly 4 is a plate-shaped body, and the liquid inlet holes 410 of the liner assembly 4 are arranged in a ring shape and have the same distance from each other. In addition, the liquid inlet holes 410 of the guide member 41 penetrate the plate-shaped body in an oblique direction. Specifically, along a rotation direction R of the axis a, the upper openings 4101 of the liquid inlet holes 410 of the guide member 41 are all located in front of the respective corresponding lower openings 4102. With reference to Fig. 3, the liquid inlet hole 410 on the deflector 41 of this embodiment of the present invention obliquely penetrates the plate-shaped body to allow the remaining electrolyte to flow from the same through a pump (not shown) After the liquid hole 410 is introduced into the drain space 80, it can present a vortex as shown in FIG. 3, so that the remaining electrolyte during the metal ion recovery process in the drain space 80 can continue to maintain a uniform concentration .

更佳地,該內膽組件4之導流件41之進液孔410的數量是大於該陽極組件5之擋件53之出液孔530的數量,該陽極組件5之該等出液孔530是呈環形排列且彼此間的距離相等;如圖3所示,該內膽組件4還包括一呈板狀的擋件44,該內膽組件4之擋件44連接 該內管42與外管43之同一端緣並由該陽極組件5之擋件53所覆蓋,且該內膽組件4之擋件44具有複數貫穿其自身的出液孔440,該內膽組件4之擋件44之出液孔440的數量是相同於該陽極組件5之擋件53之出液孔530的數量,且該內膽組件4之擋件44之該等出液孔440是呈環形排列且彼此間的距離相等,並分別與該陽極組件5之各自所對應之出液孔530位置重疊。在本新型該實施例中,下方導流件41之進液孔410的數量與上方陽極組件5之擋件53出液孔530的數量分別是八個與六個。藉此,在該排液空間80內的剩餘電解液能以較慢的流速自該進液區間801流進該出液區間802,以令在剩餘電解液能在該進液區間801停留較久的時間以充分地執行金屬離子回收程序,並達到有效回收金屬離子的功效。 More preferably, the number of the liquid inlet holes 410 of the baffle 41 of the inner container assembly 4 is greater than the number of the liquid outlet holes 530 of the stopper 53 of the anode assembly 5, and the number of the liquid outlet holes 530 of the anode assembly 5 Are arranged in a ring and the distances between each other are equal; as shown in FIG. 3, the liner assembly 4 further includes a plate-shaped stopper 44, and the stopper 44 of the liner assembly 4 is connected The inner tube 42 and the outer tube 43 have the same end edge and are covered by the stopper 53 of the anode assembly 5, and the stopper 44 of the inner tube assembly 4 has a plurality of liquid outlet holes 440 passing through it. The number of the outlet holes 440 of the stopper 44 of 4 is the same as the number of the outlet holes 530 of the stopper 53 of the anode assembly 5, and the number of the outlet holes 440 of the stopper 44 of the inner container assembly 4 is They are arranged in a ring shape and have the same distance from each other, and respectively overlap with the positions of the corresponding outlet holes 530 of the anode assembly 5. In this embodiment of the present invention, the number of the liquid inlet holes 410 of the lower flow guide 41 and the number of the liquid outlet holes 530 of the stopper 53 of the upper anode assembly 5 are eight and six, respectively. Thereby, the remaining electrolyte in the drain space 80 can flow from the inlet section 801 into the outlet section 802 at a slower flow rate, so that the remaining electrolyte can stay in the inlet section 801 for a longer time. Time to fully implement the metal ion recovery program and achieve the effect of effectively recovering metal ions.

根據本新型上述各段的詳細說明,就本新型該實施例之供電路徑來說,該陰極管31與該陽極管件52上所形成的電流傳遞方向彼此相反,能解決先前技術所述之電流供應不均的問題。 According to the detailed description of the above paragraphs of the present invention, as far as the power supply path of this embodiment of the present invention is concerned, the current transmission directions formed on the cathode tube 31 and the anode tube 52 are opposite to each other, which can solve the current supply described in the prior art. The problem of unevenness.

此外,就該剩餘電解液在本新型該實施例之排液空間80內的流動方式與停留在該進液區間801的時間來細說,本新型該實施例透過該導流件41呈斜向貫穿其板狀體的進液孔410,能令該剩餘電解液進入到該該進液區間801呈現渦流態,以使實施金屬離子回收程序過程中的剩餘電解液濃度均勻分布,更利用導流件41之進液孔410的數量大於該陽極組件5之擋件53之出液孔530的數量之 設計,令在該剩餘電解液能在該進液區間801停留較久的時間以充分地執行金屬離子回收程序,並達到有效回收金屬離子的功效。 In addition, regarding the flow mode of the remaining electrolyte in the discharge space 80 of the embodiment of the present invention and the time to stay in the liquid inlet section 801, the embodiment of the present invention is oblique through the deflector 41. The liquid inlet hole 410 penetrating the plate-shaped body can make the remaining electrolyte enter the liquid inlet area 801 and present a vortex state, so that the concentration of the remaining electrolyte during the metal ion recovery process is evenly distributed, and the diversion is even more utilized. The number of the liquid inlet holes 410 of the member 41 is greater than the number of the liquid outlet holes 530 of the stopper 53 of the anode assembly 5 It is designed to allow the remaining electrolyte to stay in the inlet section 801 for a long time to fully perform the metal ion recovery procedure and achieve the effect of effectively recovering metal ions.

綜上所述,本新型金屬離子回收裝置利用該陰極管31與陽極組件5的設計能均勻地供電,且利用該導流件41之進液孔410之斜向貫穿其板狀體與下方進液孔410數量大於上方出液孔440、530數量的設計,能使其在實施金屬離子回收程序時的剩餘電解液濃度均勻分布且停留充分時間以達有效的回收效果,故確實能達成本新型的目的。 In summary, the new metal ion recovery device utilizes the design of the cathode tube 31 and the anode assembly 5 to evenly supply power, and utilizes the liquid inlet 410 of the guide member 41 to penetrate the plate-shaped body and the downward direction. The number of liquid holes 410 is larger than the number of outlet holes 440 and 530 above, which can make the remaining electrolyte concentration evenly distributed during the metal ion recovery process and stay for a sufficient time to achieve an effective recovery effect, so it can indeed achieve a new cost the goal of.

惟以上所述者,僅為本新型的實施例而已,當不能以此限定本新型實施的範圍,凡是依本新型申請專利範圍及專利說明書內容所作的簡單的等效變化與修飾,皆仍屬本新型專利涵蓋的範圍內。 However, the above are only examples of the present model. When the scope of implementation of the present model cannot be limited by this, all simple equivalent changes and modifications made in accordance with the patent scope of the present model application and the contents of the patent specification still belong to This new patent covers the scope.

2:底座組件 2: Base components

21:底座 21: Base

22:框架 22: Frame

221:基壁 221: basal wall

222:內環壁 222: inner ring wall

223:外環壁 223: Outer Ring Wall

23:進液管 23: Inlet pipe

24:出液管 24: Outlet pipe

3:陰極組件 3: Cathode assembly

31:陰極管 31: Cathode tube

32:導電套件 32: Conductive kit

33:連接件 33: connecting piece

4:內膽組件 4: Liner components

41:導流件 41: deflector

410:進液孔 410: Inlet hole

42:內管 42: inner tube

43:外管 43: Outer tube

44:擋件 44: stop

440:出液孔 440: Liquid Outlet

5:陽極組件 5: Anode assembly

51:導電桿件 51: Conductive rod

511:金屬棒 511: Metal Rod

512:金屬層 512: Metal layer

52:陽極管件 52: Anode fittings

521:金屬管 521: metal pipe

522:貴重金屬氧化層 522: precious metal oxide layer

53:擋件 53: stop

530:出液孔 530: Liquid Outlet

54:連接件 54: Connector

6:上蓋 6: Upper cover

80:排液空間 80: Drainage space

801:進液區間 801: Inlet Interval

802:出液區間 802: Liquid Out Area

803:排液通道 803: Drain Channel

9:密封環 9: Sealing ring

a:軸線 a: axis

Claims (10)

一種金屬離子回收裝置,其包含: 一底座組件,包括一底座、一框架、一進液管及一出液管,該框架具有一基壁、一貫穿該基壁的內環壁,及一圍繞該基壁並連接於該底座上的外環壁,該進液管貫穿該底座與該框架的基壁以與該內環壁內的一空間隔絕,且該出液管貫穿該底座以與該內環壁內的空間連通; 一陰極組件,包括一沿一軸線朝上沿伸以圍繞該框架之外環壁的陰極管、一圍繞且連接該陰極管以固定在該底座上的導電套件,及一連接該導電套件且反向該底座沿伸的連接件; 一內膽組件,包括一連接於該框架之外環壁並覆蓋該框架之基壁且由該框架之內環壁所貫穿的導流件、一沿該軸線朝上延伸且貫穿該底座以受該框架之內環壁所間隔圍繞的內管,及一沿該軸線朝上延伸且圍繞該內管的外管,該導流件具有複數彼此間隔配置且貫穿其自身的進液孔,該外管是連接於該導流件上以介於該等進液孔與該框架之內環壁間;及 一陽極組件,包括一沿該軸線朝上且朝下沿伸以局部位在該內膽組件之內管中的導電桿件、一沿該軸線朝上沿伸且圍繞該內膽組件之外管的陽極管件、一連接該導電桿件與該陽極管件之遠離該框架之一端緣的擋件,及一連接於位在該內膽組件之內管外之該導電桿件且反向該底座沿伸的連接件,該陽極組件之擋件具有複數彼此間隔設置且貫穿其自身的出液孔; 其中,該陽極組件之導電桿件具有一金屬棒及一包覆於該金屬棒上的金屬層,且該金屬棒的一第一導電率(σ 1)高於該陰極管的一第二導電率(σ 2)。 A metal ion recovery device, comprising: a base assembly, including a base, a frame, a liquid inlet pipe and a liquid outlet pipe, the frame has a base wall, an inner ring wall penetrating the base wall, and a surrounding The base wall is connected to the outer ring wall on the base, the liquid inlet pipe penetrates the base and the base wall of the frame to be isolated from a space in the inner ring wall, and the liquid outlet pipe penetrates the base to communicate with the The space in the inner ring wall is connected; a cathode assembly including a cathode tube extending upward along an axis to surround the outer ring wall of the frame, and a conductive sleeve surrounding and connecting the cathode tube to be fixed on the base, And a connecting piece connected to the conductive sleeve and opposite to the extension of the base; an inner liner assembly including a connecting piece connected to the outer ring wall of the frame and covering the base wall of the frame and penetrated by the inner ring wall of the frame A deflector, an inner pipe extending upward along the axis and passing through the base to be surrounded by the inner ring wall of the frame, and an outer pipe extending upward along the axis and surrounding the inner pipe, the diversion The member has a plurality of liquid inlet holes arranged spaced apart from each other and penetrates through itself, the outer tube is connected to the guide member so as to be interposed between the liquid inlet holes and the inner ring wall of the frame; and an anode assembly including an A conductive rod extending upward and downward along the axis to be partially located in the inner tube of the inner tube assembly, an anode tube extending upward along the axis and surrounding the outer tube of the inner tube assembly, and a connection The conductive rod and the stopper of the end of the anode tube away from the frame, and a connecting member connected to the conductive rod located outside the inner tube of the liner assembly and extending opposite to the base, the The stopper of the anode assembly has a plurality of liquid outlet holes spaced apart from each other and penetrates through itself; wherein, the conductive rod of the anode assembly has a metal rod and a metal layer covering the metal rod, and the metal rod A first conductivity (σ 1 ) is higher than a second conductivity (σ 2 ) of the cathode tube. 如請求項1所述的金屬離子回收裝置,其中,σ 12≥6.5。 The metal ion recovery device according to claim 1, wherein σ 12 ≥ 6.5. 如請求項1所述的金屬離子回收裝置,其中,該內膽組件之導流件是一板狀體,該內膽組件之該等進液孔是呈環形排列且彼此間的距離相等,且該導流件的各進液孔是呈斜向貫穿該板狀體。The metal ion recovery device according to claim 1, wherein the guide member of the inner container assembly is a plate-shaped body, the liquid inlet holes of the inner container assembly are arranged in a ring shape and the distances between each other are equal, and The liquid inlet holes of the guide piece penetrate the plate-shaped body obliquely. 如請求項3所述的金屬離子回收裝置,其中,沿該軸線的一旋轉方向,該導流件之該等進液孔的一上開口皆是位在各自所對應之一下開口的前方。The metal ion recovery device according to claim 3, wherein, along a rotation direction of the axis, one of the upper openings of the liquid inlet holes of the guide member is located in front of the corresponding one of the lower openings. 如請求項3所述的金屬離子回收裝置,其中,該內膽組件之導流件之進液孔的數量是大於該陽極組件之擋件之出液孔的數量。The metal ion recovery device according to claim 3, wherein the number of liquid inlet holes of the flow guide of the inner container assembly is greater than the number of liquid outlet holes of the stopper of the anode assembly. 如請求項5所述的金屬離子回收裝置,其中,該陽極組件之該等出液孔是呈環形排列且彼此間的距離相等。The metal ion recovery device according to claim 5, wherein the liquid outlet holes of the anode assembly are arranged in a ring shape and have the same distance from each other. 如請求項6所述的金屬離子回收裝置,其中,該內膽組件還包括一擋件,該內膽組件之擋件連接該內管與外管之同一端緣並由該陽極組件之擋件所覆蓋,該內膽組件之擋件具有複數貫穿其自身的出液孔,該內膽組件之擋件之出液孔的數量是相同於該陽極組件之擋件之出液孔的數量,且該內膽組件之擋件之該等出液孔是呈環形排列且彼此間的距離相等,並分別與該陽極組件之各自所對應之出液孔位置重疊。The metal ion recovery device according to claim 6, wherein the inner container assembly further includes a stopper, and the stopper of the inner container assembly connects the same end edge of the inner tube and the outer tube and is formed by the stopper of the anode assembly Covered, the stopper of the liner assembly has a plurality of liquid outlet holes penetrating through itself, and the number of liquid outlet holes of the stopper of the inner liner assembly is the same as the number of liquid outlet holes of the stopper of the anode assembly, and The liquid outlet holes of the stopper of the inner bladder assembly are arranged in a ring shape with equal distances from each other, and overlap with the positions of the respective outlet holes of the anode assembly. 如請求項1所述的金屬離子回收裝置,其中,該陰極組件之陰極管之一內表面是經拋光的表面。The metal ion recovery device according to claim 1, wherein one of the inner surfaces of the cathode tubes of the cathode assembly is a polished surface. 如請求項1所述的金屬離子回收裝置,還包含一上蓋,該上蓋是固定於該陰極管之遠離該底座組件的一端緣以封閉該陰極管。The metal ion recovery device according to claim 1, further comprising an upper cover fixed to an edge of the cathode tube away from the base assembly to close the cathode tube. 如請求項9所述的金屬離子回收裝置,其中,還包含一外罩組件,該外罩組件包括一沿該軸線朝上延伸以套設於該陰極組件的導電套件外的罩體、一圍繞該罩體之一底部的鋼帶,及固定於該鋼帶之相反兩端緣的複數固定件。The metal ion recovery device according to claim 9, further comprising an outer cover assembly, the outer cover assembly includes a cover extending upward along the axis to be sheathed outside the conductive sleeve of the cathode assembly, and a cover surrounding the cover A steel belt at the bottom of one of the bodies, and a plurality of fixing pieces fixed on the opposite ends of the steel belt.
TW109216914U 2020-12-22 2020-12-22 Metal ion recovery device TWM612171U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW109216914U TWM612171U (en) 2020-12-22 2020-12-22 Metal ion recovery device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW109216914U TWM612171U (en) 2020-12-22 2020-12-22 Metal ion recovery device

Publications (1)

Publication Number Publication Date
TWM612171U true TWM612171U (en) 2021-05-21

Family

ID=77037247

Family Applications (1)

Application Number Title Priority Date Filing Date
TW109216914U TWM612171U (en) 2020-12-22 2020-12-22 Metal ion recovery device

Country Status (1)

Country Link
TW (1) TWM612171U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI737554B (en) * 2020-12-22 2021-08-21 鈦工房有限公司 Metal ion recovery device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI737554B (en) * 2020-12-22 2021-08-21 鈦工房有限公司 Metal ion recovery device

Similar Documents

Publication Publication Date Title
CN206204466U (en) Electroplating processes device
TWM612171U (en) Metal ion recovery device
JP2006144125A (en) Electroplating method on interior of component, apparatus for electroplating the same and stator bar clip
TWI737554B (en) Metal ion recovery device
JP2007284736A (en) Membrane-fitted hollow electrode for electrodeposition coating
JPH07145496A (en) Method and apparatus for recovering metal from metal salt solution
CN104726901A (en) Diaphragm swirl-flow electrolyzer
CN202519357U (en) Cathode conductive structure for barrel plating
CN205635825U (en) Aluminum alloy welded joint's micro -arc oxidation corrosion resistant protector
TWI707990B (en) Method and equipment for horizontal and double-sided simultaneous electroplating of solar cells
CN211227384U (en) Silver plating equipment of lead frame
EP0133363A1 (en) Immersion type electrode structure
US3994786A (en) Electroplating device and method
CN112391668A (en) Electroplating device for hollow parts
CN208361959U (en) A kind of electrode group for electrochemical treatments pharmaceutical wastewater
CN204779852U (en) Electrolysis system and anode assembly thereof
CN220468218U (en) Solar cell electroplating device
CN211645411U (en) Electrolytic tank for silver electrolysis
CN218539874U (en) Novel titanium blue and coating film device
CN213701027U (en) Terminal cleaning line
CN215175984U (en) Corrosion-resistant water heater
CN218175188U (en) Recycling device for heating steam condensate water
CN111485276B (en) Electroplating equipment
CN214218895U (en) Intraductal electrolysis brush head device
CN210367974U (en) Wire electroplating conductive access device