TWM604323U - Wet separation equipment for treating metal-containing powder wastes - Google Patents

Wet separation equipment for treating metal-containing powder wastes Download PDF

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Publication number
TWM604323U
TWM604323U TW109208226U TW109208226U TWM604323U TW M604323 U TWM604323 U TW M604323U TW 109208226 U TW109208226 U TW 109208226U TW 109208226 U TW109208226 U TW 109208226U TW M604323 U TWM604323 U TW M604323U
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Taiwan
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mixing tank
metal
slurry
tank
fast
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TW109208226U
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Chinese (zh)
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張坤森
黃立綸
邱孔濱
陳雅郁
黃綺雯
曾昭恩
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國立聯合大學
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

This invention belongs to a wet separation equipment for treating metal-containing powder wastes. This wet separation equipment involving stabilization process can effectively treat metal-containing powder wastes into non-hazardous fine particles and very small amount of metal-containing sludge. Subsequently, the non-hazardous fine particles can be recycled to make products, and metal-containing sludge also can be recycled. This equipment has some advantages, e.g., time control, movability, easy cleaning, and instant monitoring. The target wastes are metal-containing powder wastes generated from high temperature processing units (such as metal-containing dust collected by dust collection equipment, and metal-containing bottom residue discharged by high temperature processing unit, etc.), and therefore subjected to wet separation and metal stabilization. The overall treatment equipment includes: (1) Vortex mixing tank: the metal-containing powder wastes and fresh water can be mixed in the mixing tank and become a slurry, which can be further conveyed by a reciprocated high-pressure pump and control valve. (2) Funnel-type mixing tank: this tank involves stirring motor, rotor, detector, dosing delivery pipe, etc. The mixed slurry can be further mixed with clean water and/or chemical solution in this mixing tank. (3) Dewater machine: after the wet treatment in funnel-type mixing tank, the slurry is delivered into dewater machine for solid/liquid separation. (4) Dosing and control equipment: including pumps for adding chemical stabilizer, pipelines and their control panels, stirring speed and time control panels, detector display panels, etc.

Description

溼式分離含重金屬粉體廢料之處理設備 Treatment equipment for wet separation of heavy metal powder waste

本創作係與含重金屬粉體廢料處理技術有關,更詳而言之是指一種可進行無害化及穩定化的一套濕式分離暨穩定化設備,且含即時監控系統,俾利於操作之準確性及方便性之溼式分離含重金屬粉體廢料之處理設備。 This creation is related to the treatment technology of heavy metal powder waste materials. More specifically, it refers to a set of wet separation and stabilization equipment that can be harmless and stabilized, and includes a real-time monitoring system to facilitate accurate operation It is a convenient and convenient wet separation processing equipment for heavy metal powder waste.

經高溫處理設備易產出含重金屬等有害粉體廢料,先前處理技術多先以「固化」進行中間處理,其後再予以「掩埋」進行最終處置。此作法易衍生固化物中有害物質溶出、造成土壤與地下水二次污染等問題,且可供固化物掩埋之掩埋場已漸不足。 High-temperature treatment equipment is easy to produce hazardous powder wastes containing heavy metals. The previous treatment technology mostly used "solidification" for intermediate treatment, and then "burying" for final disposal. This practice is prone to cause problems such as the dissolution of harmful substances in the solidified material, causing secondary pollution of soil and groundwater, and the availability of burial sites for the solidified material is gradually insufficient.

含重金屬粉體廢料因含有害重金屬,無法直接作為再利用之原料或材料,故此等含重金屬粉體廢料必須先予以處理、移除重金屬等有害物質,始得進行再利用。 Heavy metal-containing powder wastes cannot be directly used as raw materials or materials for reuse because they contain harmful heavy metals. Therefore, such heavy metal-containing powder wastes must be treated first, and heavy metals and other harmful substances must be removed before they can be reused.

含重金屬粉體廢料之處理技術除上述「固化+掩埋」外,另有萃取、穩定化、燒結、玻璃化等處理技術。就其處理機制,萃取為移除,即將有害物質如重金屬等不適再利用之物質移出或去除;穩定化為將易溶出之重金屬穩定 (包含固化劑穩定、化學藥劑穩定等);燒結為利用高溫將粉體廢料部分熔融並凝結成塊;至於玻璃化則以較燒結高溫之方式,將粉體廢料全部熔融。 In addition to the above-mentioned "solidification + burying", the treatment technology of heavy metal powder waste has other treatment technologies such as extraction, stabilization, sintering, and vitrification. Regarding its processing mechanism, extraction is removal, that is, removal or removal of harmful substances such as heavy metals that are not suitable for reuse; stabilization is the stabilization of easily eluted heavy metals (Including curing agent stability, chemical agent stability, etc.); sintering is the use of high temperature to partially melt the powder waste and agglomerate into agglomerates; as for vitrification, the powder waste is completely melted by means of higher sintering temperature.

本專利兼具萃取及穩定化機制,係開發一套可處理含重金屬粉體廢料之濕式分離暨穩定化設備,俾利處理後無害之粉體可供再利用。 This patent has both extraction and stabilization mechanisms. It is to develop a set of wet separation and stabilization equipment that can treat heavy metal powder waste, so that the harmless powder after treatment can be reused.

本創作之目的即在於提供一種供溼式分離含重金屬粉體廢料之處理設備,其採垂直流離心分離,並搭配「攪拌+擾動」可降低濕式粉體總量及阻塞之損失,具較低成本、高通量、高產量及高值化之再利用生產設備。 The purpose of this creation is to provide a wet-type separation of heavy metal powder-containing waste treatment equipment, which adopts vertical flow centrifugal separation, and is combined with "stirring + disturbance" to reduce the total amount of wet powder and the loss of blockage. Low-cost, high-throughput, high-yield and high-value recycling production equipment.

緣是,為了達成前述目的,本創作係提供一種供溼式分離含重金屬粉體廢料之處理設備,包含有一漩渦式拌合槽,供將含重金屬粉體廢料與水均勻混合為漿料;一漏斗型拌合槽,包含一快混槽及一慢混槽,該快混槽與慢混槽內均具有一攪拌馬達與一轉子,該快混槽係連接漩渦式拌合槽,用以將該漩渦式拌合槽所輸送之混合漿料進行高速、快速破碎及混合,可將大顆粒含重金屬粉體破碎分解產生細粒料漿料,該慢混槽係連接快混槽,用以將該快混槽輸送之廢料液以低速混合以維持細粒料漿料的產出、進行濕式處理;一脫水機,連接該快混槽,用以將該快混槽輸送之漿料進行固/液分離,分離後之固體物置於一暫存槽,經取樣檢測符合法規標準,即可作後續再利用,而廢液可置於一廢液暫存槽;一加藥及控制設備,連接各該漩渦式拌合槽、漏斗 型拌合槽與脫水機,用以可控制各該漩渦式拌合槽、漏斗型拌合槽與脫水機之運作。 The reason is that, in order to achieve the aforementioned purpose, this creation is to provide a wet separation of heavy metal powder-containing waste processing equipment, including a vortex mixing tank for uniformly mixing heavy metal powder waste and water into a slurry; The funnel-shaped mixing tank includes a fast mixing tank and a slow mixing tank. Both the fast mixing tank and the slow mixing tank have a stirring motor and a rotor. The fast mixing tank is connected to the vortex mixing tank for mixing The mixed slurry conveyed by the vortex mixing tank is crushed and mixed at high speed and quickly, which can crush and decompose large particles of heavy metal powders to produce fine particle slurry. The slow mixing tank is connected to the fast mixing tank for mixing The waste liquid conveyed by the fast mixing tank is mixed at a low speed to maintain the output of fine-grained slurry for wet treatment; a dehydrator is connected to the fast mixing tank to solidify the slurry conveyed by the fast mixing tank /Liquid separation. The separated solids are placed in a temporary storage tank. After sampling and testing, they can be used for subsequent reuse. The waste liquid can be placed in a waste liquid temporary storage tank; one dosing and control equipment is connected The vortex mixing tank and funnel Type mixing tank and dewatering machine are used to control the operation of each of the swirl type mixing tank, funnel type mixing tank and dewatering machine.

100:漩渦式拌合槽 100: Whirlpool mixing tank

1101:快混槽 1101: Fast Mixing Slot

1102:慢混槽 1102: slow mixing tank

110:漏斗型拌合槽 110: Funnel type mixing tank

1103:攪拌馬達 1103: Stirring motor

1104:旋轉葉片 1104: Rotating Blade

120:脫水機 120: dehydration machine

130:暫存槽 130: temporary storage slot

140:廢液暫存槽 140: Waste liquid temporary storage tank

圖1係本創作一較佳實施例之系統示意圖。 Figure 1 is a system diagram of a preferred embodiment of the author.

圖2係本創作一較佳實施例之處理流程示意圖。 Fig. 2 is a schematic diagram of the processing flow of a preferred embodiment of the present creation.

以下,茲舉本創作一較佳實施例,並配合圖式做進一步之詳細說明如後: Hereinafter, a preferred embodiment of this creation will be cited, and further detailed description will be given in conjunction with the drawings as follows:

如圖一與圖二所示,本創作一較佳實施例之溼式分離含重金屬粉體廢料之處理設備,係包含有一漩渦式混合槽100、一漏斗型拌合槽110、一脫水機120與一加藥及控制設備。 As shown in Figure 1 and Figure 2, the wet separation of heavy metal powder-containing waste processing equipment according to a preferred embodiment of the present invention includes a vortex mixing tank 100, a funnel-shaped mixing tank 110, and a dehydrator 120 With one dosing and control equipment.

該漩渦式混合槽100,係供將含重金屬粉體廢料與水均勻混合為漿料,提供氣動式隔膜污泥泵浦帶動槽內已倒入之適量水預先產生渦流,再將焚化含重金屬粉體廢料均勻撒入槽內,同時使用攪拌輔助廢料隨渦流方向以提高拌合效率,進而形成含重金屬廢料液。 The vortex mixing tank 100 is used to uniformly mix heavy metal powder waste and water into a slurry, and a pneumatic diaphragm sludge pump is provided to drive the appropriate amount of water poured into the tank to generate a vortex in advance, and then the heavy metal powder is incinerated The bulk waste is evenly sprinkled into the tank, and at the same time, the mixing auxiliary waste is used to follow the vortex direction to improve the mixing efficiency, thereby forming a heavy metal waste liquid.

該漏斗型拌合槽110:包含一快混槽1101及一慢混槽1102,該快混槽1101與慢混槽1102內均具有一攪拌馬達1103與一旋轉葉片1104,該快混槽1101係連接漩渦式拌合槽100,用以將該漩渦式拌合槽100所輸送之混合漿料進行高速、快速破碎及混合,可將大顆粒含重金屬粉體破碎分解產生細粒料漿料,該慢混槽1102係連接快混槽1101,用以將該 快混槽輸送之廢料液以低速混合以維持細粒料漿料的產出、進行濕式處理。 The funnel-shaped mixing tank 110 includes a fast mixing tank 1101 and a slow mixing tank 1102. Both the fast mixing tank 1101 and the slow mixing tank 1102 have a stirring motor 1103 and a rotating blade 1104. The fast mixing tank 1101 is Connected to the vortex mixing tank 100 for high-speed, rapid crushing and mixing of the mixed slurry conveyed by the vortex mixing tank 100, which can crush and decompose large particles of heavy metal powders to produce fine particles of slurry. The slow mixing tank 1102 is connected to the fast mixing tank 1101 for the The waste liquid conveyed by the fast mixing tank is mixed at a low speed to maintain the output of the fine-grained material slurry for wet treatment.

詳言之,提供氣動式隔膜污泥泵浦及控制閥將該漩渦式拌合槽100內含重金屬廢料液輸送至快混槽1101內,待廢料液達定量時,預先啟動控制系統使攪拌馬達1103帶動旋轉葉片1104,此時需先快速轉動旋轉葉片1104,使粉體廢料液不易因團聚現象而產生沉澱,並於短時間(10分鐘)提高「攪拌+擾動」之控制參數,待既定時間完成槽內粉體之重金屬相轉移後,隨即降低「攪拌+擾動」之控制參數,其後在較低「攪拌+擾動」參數進行脫水機溼式分離,將粉體與含重金屬廢水分別收集。該慢混槽1102內細粒料液達定量時,預先啟動控制系統使攪拌馬達1103帶動旋轉葉片1104,此時需先快速轉動旋轉葉片1104,使細粒料液能懸浮於適量水中,再調回低「攪拌+擾動」之控制參數,並於長時間(30分鐘)過程中,添加強酸穩定劑進行穩定化處理,待符合系統設定之參數,繼以後續該脫水機120溼式分離將細粒料與含重金屬廢水分別收集。 In detail, a pneumatic diaphragm sludge pump and a control valve are provided to transport the heavy metal waste liquid in the vortex mixing tank 100 to the fast mixing tank 1101. When the waste liquid reaches a certain amount, the control system is activated in advance to make the mixing motor 1103 drives the rotating blade 1104. At this time, the rotating blade 1104 needs to be quickly rotated to prevent the powder waste liquid from being precipitated due to the agglomeration phenomenon. In a short time (10 minutes), the control parameter of "stirring + disturbance" is increased. After the heavy metal phase transfer of the powder in the tank is completed, the control parameter of "stirring + disturbance" is then reduced, and then the dehydrator wet separation is performed at the lower "stirring + disturbance" parameter, and the powder and heavy metal wastewater are collected separately. When the fine granular liquid in the slow mixing tank 1102 reaches a certain amount, the control system is activated in advance to make the stirring motor 1103 drive the rotating blade 1104. At this time, the rotating blade 1104 needs to be quickly rotated to make the fine granular liquid suspend in an appropriate amount of water, and then adjust Reduce the control parameters of "Stirring + Disturbance", and add a strong acid stabilizer for stabilization during a long period of time (30 minutes). Once the parameters set by the system are met, the dehydrator 120 wet separation will be fine. The pellets and heavy metal wastewater are collected separately.

該脫水機120,係離心脫水機,連接該快混槽1101,用以將該快混槽1102輸送之漿料進行固/液分離,分離後之固體物置於一暫存槽130,經取樣檢測符合法規標準,即可作後續再利用,而廢液可置於一廢液暫存槽140。 The dehydrator 120 is a centrifugal dehydrator and is connected to the fast mixing tank 1101 for solid/liquid separation of the slurry conveyed by the fast mixing tank 1102. The separated solids are placed in a temporary storage tank 130 and tested by sampling It can be reused later if it meets the legal standards, and the waste liquid can be placed in a waste liquid temporary storage tank 140.

該加藥及控制設備,係連接各該漩渦式拌合槽110、漏斗型拌合槽110與脫水機120,含加入穩定化學藥劑之泵浦、管線及其控制盤、攪拌轉速與時間控制盤、偵測器 顯示盤等元件,用以可控制各該漩渦式拌合槽110、漏斗型拌合槽110與脫水機120之運作。 The dosing and control equipment is connected to each of the vortex mixing tank 110, funnel-shaped mixing tank 110 and dehydrator 120, including pumps, pipelines and control panels, mixing speed and time control panels for adding stable chemicals , Detector The display panel and other elements are used to control the operation of each of the vortex mixing tank 110, the funnel-shaped mixing tank 110 and the dehydrator 120.

根據上述整套發明適合推廣國內外相關焚化處理廠產出不同之粉體廢料之後端再利用及去化設備,並可依廠內土地大小設置之中/大型實廠。濕式分離含重金屬粉體廢料之穩定化處理設備整套總成屬一般中大型固定反應槽。 According to the above-mentioned whole set of inventions, it is suitable to promote the recycling and decontamination equipment of different powder wastes produced by relevant incineration plants at home and abroad, and medium/large real plants can be installed according to the size of the land in the plant. The complete set of stabilization equipment for wet separation of heavy metal powder waste materials is a general medium and large fixed reaction tank.

本發明主要將廢料浸水拌合及離心脫水,其後粉體再浸水拌合並添加穩定劑(>95%強酸),使粉體趨於穩定化再離心脫水,其後脫水後之含重金屬廢液收集槽採用中和沉澱法,並以脫水機分別分離收集所產生沉澱污泥及廢水,若符合再利用去化標準,則提供去化業使用,若無則持續改善精進。 The invention mainly immersed the waste in water, mixed and centrifuged for dehydration, then the powder was soaked in water and mixed and added with a stabilizer (>95% strong acid) to stabilize the powder and then centrifuged for dehydration, and then the heavy metal-containing waste liquid after dehydration The collection tank adopts the neutralization sedimentation method, and separates and collects the precipitated sludge and waste water produced by the dehydrator. If it meets the reuse and dechemical standard, it will be provided for use in the dechemical industry. If not, continue to improve and refine.

100:漩渦式拌合槽 100: Whirlpool mixing tank

1101:快混槽 1101: Fast Mixing Slot

1102:慢混槽 1102: slow mixing tank

110:漏斗型拌合槽 110: Funnel-shaped mixing tank

1103:攪拌馬達 1103: Stirring motor

1104:旋轉葉片 1104: Rotating Blade

120:脫水機 120: dehydration machine

130:暫存槽 130: temporary storage slot

140:廢液暫存槽 140: Waste liquid temporary storage tank

Claims (1)

一種溼式分離含重金屬粉體廢料之處理設備,包含有:一漩渦式拌合槽,供將含重金屬粉體廢料與水均勻混合為漿料(slurry);一漏斗型拌合槽,包含一快混槽及一慢混槽,該快混槽與慢混槽內均具有一攪拌馬達與一轉子,該快混槽係連接漩渦式拌合槽,用以將該漩渦式拌合槽所輸送之混合漿料進行高速、快速破碎及混合,可將大顆粒含重金屬粉體破碎分解產生細粒料漿料,該慢混槽係連接快混槽,用以將該快混槽輸送之廢料液以低速混合以維持細粒料漿料的產出、進行濕式處理;一脫水機,連接該快混槽,用以將該快混槽輸送之漿料進行固/液分離,分離後之固體物置於一暫存槽,經取樣檢測符合法規標準,即可作後續再利用,而廢液可置於一廢液暫存槽;及一加藥及控制設備,連接各該漩渦式拌合槽、漏斗型拌合槽與脫水機,用以可控制各該漩渦式拌合槽、漏斗型拌合槽與脫水機之運作。 A processing equipment for wet separation of heavy metal powder waste materials, comprising: a whirlpool mixing tank for uniformly mixing heavy metal powder waste materials and water into a slurry; a funnel-shaped mixing tank, including one A fast mixing tank and a slow mixing tank. Both the fast mixing tank and the slow mixing tank have a stirring motor and a rotor. The fast mixing tank is connected to the vortex mixing tank for conveying the vortex mixing tank The mixed slurry is crushed and mixed at high speed and quickly, which can crush and decompose large particles containing heavy metal powders to produce fine-grained slurry. The slow mixing tank is connected to the fast mixing tank for conveying waste liquid from the fast mixing tank. Mixing at a low speed to maintain the output of fine-grained material slurry for wet treatment; a dehydrator connected to the fast mixing tank for solid/liquid separation of the slurry conveyed by the fast mixing tank, and the separated solid The material is placed in a temporary storage tank, after sampling and testing to meet the regulatory standards, it can be reused later, and the waste liquid can be placed in a waste liquid temporary storage tank; and a dosing and control device, connected to each of the vortex mixing tanks , Funnel-type mixing tank and dewatering machine, to control the operation of the vortex-type mixing tank, funnel-type mixing tank and dewatering machine.
TW109208226U 2020-06-29 2020-06-29 Wet separation equipment for treating metal-containing powder wastes TWM604323U (en)

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