TWM579642U - Smart seawater desalination circulation system - Google Patents

Smart seawater desalination circulation system Download PDF

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Publication number
TWM579642U
TWM579642U TW107216948U TW107216948U TWM579642U TW M579642 U TWM579642 U TW M579642U TW 107216948 U TW107216948 U TW 107216948U TW 107216948 U TW107216948 U TW 107216948U TW M579642 U TWM579642 U TW M579642U
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water
desalination
seawater
temperature
concentrated salt
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TW107216948U
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Chinese (zh)
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陳孝行
公元 阮
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國立臺北科技大學
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination

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  • Separation Using Semi-Permeable Membranes (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

本創作提供一種海水淡化循環系統,包括一海水收集單元、一熱流引導單元、一冷流引導單元以及一脫鹽處理單元,海水收集單元包含至少一脫鹽收集室;熱流引導單元用以抽取海水並進行加熱形成一濃鹽高溫水後引入脫鹽收集室中;冷流引導單元用以抽取海水做為一濃鹽低溫水並藉由熱交換產生一低溫冷卻水;脫鹽處理單元用以接收該低溫冷卻水並利用與濃鹽高溫水間之溫度梯度差生成一脫鹽蒸餾水後,以該脫鹽蒸餾水一部分做為低溫冷卻水以用於冷卻循環,以另一部分提供使用或飲用。藉此,無需外部能量消耗便能夠於船體進行海水淡化。 The present invention provides a seawater desalination circulation system comprising a seawater collection unit, a heat flow guiding unit, a cold flow guiding unit and a desalination processing unit, the seawater collecting unit comprises at least one desalination collection chamber, and the heat flow guiding unit is configured to extract seawater and perform Heating to form a concentrated salt of high temperature water and introducing into the desalination collection chamber; the cold flow guiding unit is configured to extract seawater as a concentrated salt of low temperature water and generate a low temperature cooling water by heat exchange; the desalination treatment unit is configured to receive the low temperature cooling water After a demineralized distilled water is formed by using a temperature gradient difference from the high-temperature water of the concentrated salt, a part of the desalted distilled water is used as a low-temperature cooling water for the cooling cycle, and another part is provided for use or drinking. Thereby, seawater desalination can be performed on the hull without external energy consumption.

Description

海水淡化循環系統 Seawater desalination system

本創作整體係關於一種海水淡化技術領域,尤指一種有效去除海水濁質的淡化處理分離膜及其應用該淡化分離膜之海水淡化循環系統。The present invention relates to a field of desalination technology, in particular to a desalination separation membrane for effectively removing seawater turbidity and a desalination circulation system using the desalination membrane.

淡水供應對於需要在海上長期工作的船隻(郵輪、漁船等),一直是很大的挑戰,因為從陸地盛裝淡水需要大量的空間,並且消耗大量能量來運載大型淡水箱。另一常用的選項是在漁船上安裝逆滲透機(Reverse Osmosis, RO)以淡化海水。但是RO需要高能量(10 kWh / m3)以將海水推過逆滲透膜(RO)來得到清水,且逆滲透膜容易結垢而需要經常更換。純水製備技術大致可以分為蒸發法及薄膜法2 種,蒸發法一般以加熱煮沸,將水蒸發後再凝結,以達到去除水中雜質如重金屬、農藥、離子及溶解性固體等。由於蒸發法需在沸騰下進行,能源的消耗成本甚高並需要大量熱能,因此常與火力發電廠共構,以電廠汽輪機排放的低壓蒸氣做為廉價的熱源。此外,若應用於大規模海水淡化程序,也需甚大的運作面積。Freshwater supplies have always been a challenge for vessels that need to work long-term at sea (cruises, fishing boats, etc.) because fresh water from the land requires a lot of space and consumes a lot of energy to carry large freshwater tanks. Another common option is to install reverse Osmosis (RO) on the fishing boat to desalinate seawater. However, RO requires high energy (10 kWh / m3) to push seawater through the reverse osmosis membrane (RO) to obtain clean water, and the reverse osmosis membrane is prone to scale and needs to be replaced frequently. The pure water preparation technology can be roughly divided into two methods, an evaporation method and a thin film method. The evaporation method generally uses heating to boil, and the water is evaporated and then coagulated to remove impurities such as heavy metals, pesticides, ions and dissolved solids in the water. Since the evaporation method needs to be carried out under boiling, the energy consumption cost is high and a large amount of heat energy is required, so it is often co-constructed with a thermal power plant, and the low-pressure steam discharged from the power plant steam turbine is used as an inexpensive heat source. In addition, if applied to large-scale desalination procedures, it also requires a large operating area.

薄膜法純水產製目前則以逆滲透為主,是一種利用壓力為驅動力的分離技術。以海水來說,其含鹽濃度高(濃度為3.5% 時滲透壓約為25 大氣壓),若要實行海水淡化的逆滲透運作,壓力需高於滲透壓的1 倍以上(約50~60 大氣壓),因此相當耗能。近年來,隨著薄膜製備與工程應用技術的日益發展,結合了薄膜法和蒸餾法兩者優點──薄膜蒸餾,逐漸受到重視。The membrane-pure pure aquatic system is currently based on reverse osmosis and is a separation technique that uses pressure as a driving force. In the case of seawater, the salt concentration is high (the osmotic pressure is about 25 atm when the concentration is 3.5%). If the reverse osmosis operation of seawater desalination is to be carried out, the pressure should be more than 1 time higher than the osmotic pressure (about 50 to 60 atmospheres). ), so it is quite energy intensive. In recent years, with the development of thin film preparation and engineering application technology, combining the advantages of both the thin film method and the distillation method, thin film distillation has been gradually taken seriously.

目前,海水淡化技術已經比較成熟,常用的海水淡化技術主要分為蒸發法和薄膜法,兩種方法各有優點和局限性。蒸發法是將海水加熱蒸發後得到蒸汽,然後再將蒸汽冷凝成淡水,其優點是對原海水要求低,預處理簡單,淡化水含鹽量較低,局限性是海水淡化過程發生氣液兩相變化,對熱量需求大,海水利用率低、冷卻水攜帶熱量離開等;薄膜法是利用天然或人工合成的高分子薄膜,以外加能量或化學位元差做為推動力,將海水中的鹽和水分離開得到淡水,其優點是整個過程不發生相變,一般不需要加熱,能耗低,啟動和停機較簡單,局限性是海水溫度波動影響膜通量,對預處理要求嚴格,淡化水含鹽量較高等。根據熱法和膜法兩類海水淡化技術的特點分析,可知這兩類方法具有一定的互補性,通過熱膜耦合海水淡化技術構成,能將蒸發法和薄膜法海水淡化技術方式結合起來形成薄膜蒸餾(Membrane Distillation, MD)法。然而,薄膜蒸餾(Membrane Distillation, MD)也是海水淡化的方法之一,但由於市售膜組設計複雜,且需要加熱提供熱流,導致消耗高能量(8kWh / m3)及高成本,因此實際使用並不高。At present, seawater desalination technology has been relatively mature, and the commonly used seawater desalination technology is mainly divided into evaporation method and membrane method. Both methods have their own advantages and limitations. The evaporation method is to evaporate seawater to obtain steam, and then to condense the steam into fresh water. The advantage is that the original seawater has low requirements, the pretreatment is simple, and the desalinated water has a low salt content. The limitation is that the seawater desalination process occurs. Phase change, large demand for heat, low seawater utilization rate, cooling water carrying heat away, etc.; thin film method is to use natural or synthetic polymer film, plus energy or chemical difference as a driving force, in seawater The salt and moisture leave to get fresh water. The advantage is that the whole process does not undergo phase change. Generally, no heating is required, the energy consumption is low, and the startup and shutdown are simple. The limitation is that seawater temperature fluctuation affects the membrane flux, and the pretreatment is strict and desalination. The water has a high salt content. According to the characteristics of two kinds of seawater desalination technologies, such as thermal method and membrane method, it can be seen that these two methods have certain complementarity. They are composed of hot film coupled seawater desalination technology, which can combine evaporation method and thin film desalination technology to form a film. Membrane Distillation (MD) method. However, Membrane Distillation (MD) is also one of the methods of seawater desalination, but due to the complicated design of commercially available membranes and the need to heat to provide heat flow, resulting in high energy consumption (8 kWh / m3) and high cost, not tall.

是以,如何改善上述的問題,申請人有鑑於習知技術中所產生之缺失,經過悉心試驗與研究,並一本鍥而不捨之精神,終構思出本創作以解決習知技藝的缺點。Therefore, how to improve the above-mentioned problems, the applicants have deliberately tried to solve the shortcomings of the conventional skills through careful experimentation and research, and a perseverance in view of the lack of the prior art.

有鑑於習知技藝之問題,本創作提供一種薄膜蒸餾海水淡化循環系統,透過為船隻提供水資源,結合簡單的設計與製造的薄膜蒸餾結構,可提供更大的薄膜面積以更有效率地生產可供飲用以及系統冷卻循環的冷卻水。此外,利用來自船隻的可用熱流(引擎冷卻水)以及冷流(冷卻循環之用)的海水淡化循環系統,而無需外部能量消耗。In view of the problems of the prior art, the present invention provides a thin film distillation seawater desalination circulation system, which can provide a larger membrane area for more efficient production by providing water resources for the vessel, combined with a simple design and manufacture of a thin film distillation structure. Cooling water for drinking and system cooling cycles. In addition, a seawater desalination cycle system using available heat flow from the vessel (engine cooling water) and cold flow (for cooling cycles) is utilized without external energy consumption.

為達到本創作之一目的,本創作提出一種海水淡化循環系統,其包括一海水收集單元、一熱流引導單元、一冷流引導單元以及一脫鹽處理單元,海水收集單元包含至少一脫鹽收集室且該脫鹽收集室具有至少一進水通道;熱流引導單元包含連接該脫鹽收集室的至少一熱流管路與配置於該熱流管路上的一加熱組件,該熱流引導單元係用以抽取海水且以該加熱組件將海水加熱升溫後形成一濃鹽高溫水,並以該熱流管路經由該進水通道將該濃鹽高溫水引入該脫鹽收集室中;冷流引導單元包含多個冷流管路與一熱交換儲槽,該冷流引導單元係用以抽取海水做為一濃鹽低溫水且以其中一該冷流管路將該濃鹽低溫水輸送至該熱交換儲槽進行熱交換,以產生一低溫冷卻水;脫鹽處理單元設於該脫鹽收集室中且包含至少一薄膜蒸餾件與至少一冷凝管路,該冷凝管路係分別連通該薄膜蒸餾件與該熱交換儲槽,該薄膜蒸餾件用以接收自其中另一該冷流管路導出的該低溫冷卻水,且其與該脫鹽收集室中的該濃鹽高溫水間之一溫度梯度差所引起蒸汽壓差而形成一脫鹽蒸餾水,該脫鹽水蒸汽滲透進入該薄膜蒸餾件的內部降溫形成一脫鹽蒸餾水,並經由該冷凝管路輸送至該熱交換儲槽以與該濃鹽低溫水進行熱交換,該脫鹽蒸餾水的一部分做為該低溫冷卻水以供該系統進行冷卻循環,而另一部分供以使用或飲用;其中該薄膜蒸餾件係由疏水性多孔薄膜製成,以脫濾該脫鹽收集室中該濃鹽高溫水的鹽分。In order to achieve the purpose of the present invention, the present invention proposes a seawater desalination circulation system comprising a seawater collection unit, a heat flow guiding unit, a cold flow guiding unit and a desalination processing unit, the seawater collecting unit comprising at least one desalination collection chamber and The demineralization collection chamber has at least one water inlet passage; the heat flow guiding unit includes at least one heat flow conduit connected to the demineralization collection chamber and a heating assembly disposed on the heat flow conduit, the heat flow guiding unit is configured to extract seawater and The heating assembly heats the seawater to form a concentrated salt high temperature water, and the concentrated salt high temperature water is introduced into the desalination collection chamber through the water inlet channel; the cold flow guiding unit comprises a plurality of cold flow lines and a heat exchange storage tank for extracting seawater as a concentrated salt of low temperature water and transporting the concentrated salt low temperature water to the heat exchange storage tank for heat exchange by one of the cold flow lines Generating a cryogenic cooling water; the desalination treatment unit is disposed in the desalination collection chamber and includes at least one thin film distillation member and at least one condensation pipeline, the condensation pipeline system Disconnecting the thin film distillation member and the heat exchange storage tank, the thin film distillation member for receiving the low temperature cooling water derived from the other of the cold flow lines, and the concentrated salt high temperature water in the desalination collection chamber a difference in temperature gradient caused by a difference in vapor pressure to form a desalted distilled water which permeates into the interior of the thin film distillation member to form a desalted distilled water, and is sent to the heat exchange storage tank via the condensation line to The concentrated salt low-temperature water is subjected to heat exchange, and a part of the desalted distilled water is used as the low-temperature cooling water for the system to perform a cooling cycle, and another part is used for use or drinking; wherein the thin film distillation piece is made of a hydrophobic porous film To degrease the salt of the concentrated salt high temperature water in the desalting collection chamber.

根據本創作一實施例,其中更包含一淡水槽,其係配設於該熱交換儲槽的下游端並用以收容來自該熱交換儲槽中之該脫鹽蒸餾水,以供使用或飲用。According to an embodiment of the present invention, there is further included a fresh water tank disposed at a downstream end of the heat exchange storage tank for receiving the demineralized distilled water from the heat exchange storage tank for use or drinking.

根據本創作一實施例,其中該薄膜蒸餾件係由鐵氟龍(PTFE)、聚乙烯醇(PVA)或聚丙烯(PP)所製成。According to an embodiment of the present invention, the film distillation member is made of Teflon (PTFE), polyvinyl alcohol (PVA) or polypropylene (PP).

根據本創作一實施例,其中該薄膜蒸餾件的孔隙之平均尺寸為在0.1μm~1μm之範圍。According to an embodiment of the present invention, the average size of the pores of the thin film distillation member is in the range of 0.1 μm to 1 μm.

根據本創作一實施例,其中該溫度梯度差為在15℃~50℃之範圍。According to an embodiment of the present invention, the temperature gradient difference is in the range of 15 ° C to 50 ° C.

根據本創作一實施例,其中該熱交換儲槽包含一內槽體以及環設於該內槽體外的一外槽體,該內槽體連接該冷凝管路以接收該脫鹽蒸餾水,該內槽體與該外槽體彼此不連通且兩者之間形成有一容置空間以容納來自海水的該濃鹽低溫水,而相對低溫的該濃鹽低溫水與相對高溫的該脫鹽蒸餾水彼此隔著該內槽體引發熱交換作用,以使該脫鹽蒸餾水降溫形成該低溫冷卻水。According to an embodiment of the present invention, the heat exchange storage tank comprises an inner tank body and an outer tank body disposed outside the inner tank, the inner tank body is connected to the condensation pipeline to receive the desalted distilled water, the inner tank The body and the outer tank body are not in communication with each other and an accommodating space is formed therebetween to accommodate the concentrated salt low-temperature water from seawater, and the relatively low-temperature concentrated salt low-temperature water and the relatively high-temperature desalted distilled water are separated from each other. The inner tank body initiates heat exchange to cool the desalted distilled water to form the low temperature cooling water.

根據本創作一實施例,其中該薄膜蒸餾件為複數個,且各該薄膜蒸餾件的二側分別設有一連通管,其中一側的該連通管連接其中一該冷流管路以接收自該冷流引導單元的該低溫冷卻水,另外一側的該連通管連接該冷凝管路以輸送該脫鹽蒸餾水。According to an embodiment of the present invention, the plurality of thin film distillation members are plural, and each of the two sides of the thin film distillation member is respectively provided with a communication tube, wherein the communication tube on one side is connected to one of the cold flow lines to receive The low-temperature cooling water of the cold flow guiding unit is connected to the condensation line on the other side to transport the desalted distilled water.

根據本創作一實施例,其中更包含一鼓風設備,該鼓風設備連通該脫鹽收集室,用以提供該脫鹽收集室的對流氣體。According to an embodiment of the present invention, there is further included an air blowing device that communicates with the desalination collection chamber to provide convective gas of the desalination collection chamber.

根據本創作一實施例,其中該加熱組件係自太陽能板、加熱器、加熱線圈、船體之引擎裝置、及其組合中所選出之至少一種,該濃鹽高溫水的溫度至少為60℃。According to an embodiment of the present invention, the heating assembly is at least one selected from the group consisting of a solar panel, a heater, a heating coil, an engine unit of a hull, and combinations thereof, and the concentrated salt high temperature water has a temperature of at least 60 °C.

以下配合圖式及本創作之較佳實施例,進一步闡述本創做為達成欲定創作目的所採取得技術手段,有關本創作之詳細說明及技術內容,所附圖式僅提供參考與說明用,並非用來對本創作加以限制者。在本創作下述的說明中,術語“上”、“下”、“頂”、“底”“內”、“外”等指示的方位或位置關係為基於附圖所示的方位或位置關係,僅是為了便於描述本創作簡化說明,而不是指示的文中各裝置或元件必須具有特定的方位、以特定的方位構造和運作,因此不能理解為對本創作的限制。In the following, in conjunction with the drawings and the preferred embodiment of the present invention, the technical means adopted by Bentron as a purpose for achieving the desired creation are further explained, and the detailed description and technical contents of the creation are provided. The drawings are only for reference and explanation. It is not intended to limit the creation of this creation. In the following description of the present writing, the orientation or positional relationship of the terms "upper", "lower", "top", "bottom", "inside", "outside", etc. is based on the orientation or positional relationship shown in the drawings. It is to be understood that the description of the present invention is merely for the convenience of the description, and is not intended to limit the scope of the present invention.

請參閱圖1所示,其繪製本創作之海水淡化循環系統的架構圖。先行說明,本創作所述之海水淡化循環系統係主要應用於運行在還養上的各種船隻,例如:漁船、郵輪等等,但不依此為限,亦可設置在鄰近海洋的地面任意位置,以抽取海水進行脫鹽處理的系統,以供使用者可以使用或飲用來自海洋中經過脫鹽處理後的水;而圖式中各元件的配置位置或相對位置(上、下、左、右的相對位置)並非實際真實配置,僅是用以說明本創作技術之用,不依此為限制;而圖示中虛線部分表示流體的走向。在具體實施例中,本創作所述之海水淡化循環系統以設置在船體上為例進行以下說明,其包括:一海水收集單元10、一熱流引導單元20、一冷流引導單元30以及一脫鹽處理單元40。Please refer to FIG. 1 , which depicts the architecture of the seawater desalination cycle system of the present invention. Firstly, the seawater desalination cycle system described in this creation is mainly applied to various vessels that are still in operation, such as fishing boats, cruise ships, etc., but not limited thereto, and may be placed anywhere on the ground adjacent to the ocean. a system for desalination of seawater for the user to use or drink water desalinated from the ocean; and the position or relative position of each component in the drawing (upper, lower, left, and right relative positions) It is not an actual configuration, it is only used to illustrate the use of this creative technique, and is not limited by this; the dotted line in the figure indicates the direction of the fluid. In a specific embodiment, the seawater desalination cycle system described in the present invention is exemplified as being disposed on the hull, and includes: a seawater collecting unit 10, a heat flow guiding unit 20, a cold flow guiding unit 30, and a Desalination treatment unit 40.

海水收集單元10包含至少一脫鹽收集室12而脫鹽收集室12設有至少一進水通道11,在具體實施例中,該脫鹽收集室12的體積以及數量係根據船體(圖未示)的空間以及實際海水淡化處理效率作考量設計;圖示中雖顯示為2個,但不依此為限。再者,因脫鹽收集室12需要容納大量自海洋中抽取的高濃度鹽海水,在其內壁表面可進行防鏽處理。The seawater collecting unit 10 includes at least one desalination collection chamber 12 and the desalination collection chamber 12 is provided with at least one water inlet passage 11. In a specific embodiment, the volume and quantity of the desalination collection chamber 12 are based on the hull (not shown). Space and actual desalination treatment efficiency are considered. Although there are two shown in the figure, it is not limited to this. Furthermore, since the desalination collection chamber 12 needs to accommodate a large amount of high-concentration salt seawater extracted from the sea, rust-preventing treatment can be performed on the inner wall surface.

熱流引導單元20包含連接該脫鹽收集室12的至少一熱流管路21與配置於該熱流管路21上的一加熱組件22,該熱流引導單元20係用以透過一抽取裝置50抽取海洋sw中的海水,並且透過該加熱組件22將海水加熱升溫至一預設溫度後形成一濃鹽高溫水sw1,並以該熱流管路21經由該進水通道11將該濃鹽高溫水sw1引入該脫鹽收集室12中;其中抽取裝置50可以是揚程泵浦。The heat flow guiding unit 20 includes at least one heat flow line 21 connected to the desalination collection chamber 12 and a heating assembly 22 disposed on the heat flow line 21, and the heat flow guiding unit 20 is configured to extract the ocean sw through an extraction device 50. The seawater is heated by the heating unit 22 to a predetermined temperature to form a concentrated salt high temperature water sw1, and the concentrated salt high temperature water sw1 is introduced into the desalting water via the water inlet passage 11 by the heat flow line 21 In the collection chamber 12; wherein the extraction device 50 can be a lift pump.

根據本創作一實施例,其中該加熱組件32係為該船體之引擎裝置,而該濃鹽高溫水sw1取自該引擎運轉所需之冷卻水,抽取的海水經做為引擎運轉的冷卻水並加熱升溫到該預設溫度,而預設溫度至少為60℃或其以上。According to an embodiment of the present invention, the heating assembly 32 is an engine device of the hull, and the concentrated salt high temperature water sw1 is taken from the cooling water required for the operation of the engine, and the extracted seawater is used as the cooling water for the engine operation. And heating to the preset temperature, and the preset temperature is at least 60 ° C or above.

根據本創作一實施例,其中在海洋與抽取設備50之間之該熱流管路21上可進一步配置有過濾裝置60以過濾海水中的雜質。According to an embodiment of the present invention, a filter device 60 may be further disposed on the heat flow line 21 between the ocean and the extraction device 50 to filter impurities in the seawater.

冷流引導單元30包含冷流管路31、31’與一熱交換儲槽32,該冷流引導單元30係透過該抽取設備50抽取海洋sw中的深海水(較遠離海平面的相對低溫海水),並且透過其中一該冷流管路31將深海水之一濃鹽低溫水sw2輸送至該熱交換儲槽32進行熱交換以產生一低溫冷卻水cw,該低溫冷卻水cw用以經由抽取裝置50輸送至下述一薄膜蒸餾件41中。The cold flow guiding unit 30 includes a cold flow conduit 31, 31' and a heat exchange storage tank 32, and the cold flow guiding unit 30 extracts deep seawater in the ocean sw through the extraction device 50 (relatively low temperature seawater farther away from sea level) And through one of the cold flow lines 31, one of the deep seawater low-concentration water sw2 is sent to the heat exchange storage tank 32 for heat exchange to generate a low-temperature cooling water cw for extracting The apparatus 50 is delivered to a thin film distillation member 41 as described below.

在具體實施例中,該熱交換儲槽32包含一內槽體321以及環設於該內槽體321外的一外槽體322,該內槽體321連接該冷凝管路22以接收脫鹽蒸餾水fw2,,該內槽體321與該外槽體322彼此不連通且兩者之間形成有一容置空間320以容納該冷流引導單元30抽取自海水的該濃鹽低溫水sw2,而相對低溫的該濃鹽低溫水sw2與相對高溫的該脫鹽蒸餾水fw2彼此隔著該內槽體321進行熱交換,以使該脫鹽蒸餾水fw2降溫(或者凝結)形成該低溫冷卻水cw。In a specific embodiment, the heat exchange storage tank 32 includes an inner tank body 321 and an outer tank body 322 disposed outside the inner tank body 321 . The inner tank body 321 is connected to the condensing line 22 to receive the desalted distilled water. Fw2, the inner tank body 321 and the outer tank body 322 are not in communication with each other and an accommodating space 320 is formed therebetween to accommodate the concentrated salt low temperature water sw2 extracted from the seawater by the cold flow guiding unit 30, and relatively low temperature The concentrated salt low-temperature water sw2 and the relatively high-temperature demineralized distilled water fw2 are heat-exchanged with each other via the inner tank body 321, so that the desalted distilled water fw2 is cooled (or condensed) to form the low-temperature cooling water cw.

脫鹽處理單元40則分別設於各別的該脫鹽收集室12中,脫鹽處理單元40包含複數著薄膜蒸餾件41且n,以及至少一冷凝管路42,該冷凝管路42係分別連通該薄膜蒸餾件41與該熱交換儲槽22,該薄膜蒸餾件41用以接收自其中另一該冷流管路31’導出的該低溫冷卻水cw,且其與該脫鹽收集室12中的該濃鹽高溫水w1間之一溫度梯度差所引起蒸汽壓差而形成一脫鹽水蒸汽,該脫鹽水蒸汽滲透進入該薄膜蒸餾件的內部並且降溫形成脫鹽蒸餾水fw2,再經由該冷凝管路42輸送至該熱交換儲槽32中的內槽體321,以與容置空間320中的該濃鹽低溫水sw2進行熱交換以產生一脫鹽蒸餾水fw2,該脫鹽蒸餾水fw2一部分做為該低溫冷卻水cw以供該系統進行冷卻循環,而另一部分則可做為供以使用或飲用的清水uw;其中該薄膜蒸餾件41係由疏水性多孔薄膜製成,以脫濾該脫鹽收集室12中該濃鹽高溫水sw1的鹽分。其中供以使用或飲用的清水uw係可置放於配設於該熱交換儲槽32之下游端的淡水槽80中。The desalination treatment unit 40 is respectively disposed in each of the desalination collection chambers 12. The desalination treatment unit 40 includes a plurality of membrane distillation members 41 and n, and at least one condensation line 42 that communicates with the membranes respectively. a distillation member 41 and the heat exchange storage tank 22 for receiving the low temperature cooling water cw derived from the other of the cold flow lines 31', and which is concentrated with the demineralization collection chamber 12 The difference in temperature gradient between one of the high temperature water w1 causes a vapor pressure difference to form a desalted steam which permeates into the inside of the thin film distillation member and cools to form the desalted distilled water fw2, and then is sent to the decondensed distilled water fw2 through the condensation line 42 The inner tank body 321 in the heat exchange tank 32 exchanges heat with the concentrated salt low temperature water sw2 in the accommodating space 320 to generate a desalted distilled water fw2, and the part of the desalted distilled water fw2 is used as the low temperature cooling water cw The system is subjected to a cooling cycle, and another portion may be used as a clean water uw for use or drinking; wherein the film distillation member 41 is made of a hydrophobic porous film to degrease the concentrated salt in the desalination collection chamber 12. high temperature sw1 salt. The clear water uw for use or drinking can be placed in the fresh water tank 80 disposed at the downstream end of the heat exchange storage tank 32.

承上所述,多微孔且疏水性質的薄膜(疏水性多孔薄膜),可將兩側不同溫度的流體區隔,在薄膜兩側的溫度差會造成蒸氣壓力差,以此壓力差為驅動力,使蒸氣分子透過膜孔道擴散至冷側端,再藉由冷流體或其它冷凝裝置冷卻並加以收集。一般而言,只要將薄膜蒸餾之進流(上述濃鹽高溫水sw1)加熱至50℃以上,使之與薄膜內的低溫冷卻水cw)的兩側溫差超過20℃,就能產生足夠的蒸汽壓力差,使蒸氣透過薄膜的速率達到工程應用上的要求;根據本創作一實施例,上述預設溫度至少為40℃以上;較佳地,上述預設溫度至少為60℃以上。According to the above, the microporous and hydrophobic film (hydrophobic porous film) can separate the fluids at different temperatures on both sides, and the temperature difference between the two sides of the film causes a vapor pressure difference, which is driven by the pressure difference. The force causes the vapor molecules to diffuse through the pores of the membrane to the cold side end, which is then cooled and collected by a cold fluid or other condensing device. In general, as long as the inflow of the thin film distillation (the above-mentioned concentrated salt high-temperature water sw1) is heated to 50 ° C or more to make a temperature difference of more than 20 ° C with both sides of the low-temperature cooling water cw in the film, sufficient steam can be generated. The pressure difference causes the velocity of the vapor to pass through the film to meet the requirements of engineering applications; according to an embodiment of the present invention, the preset temperature is at least 40 ° C or higher; preferably, the preset temperature is at least 60 ° C or higher.

根據本創作一實施例,其中該溫度梯度差為在15℃~50℃之範圍。According to an embodiment of the present invention, the temperature gradient difference is in the range of 15 ° C to 50 ° C.

根據本創作一實施例,其中該薄膜蒸餾件41的該件體結構二側分別設有一連通管(圖未示),其中一側的該連通管連接其中一該冷流管路31’以接收自該冷流引導單元30的該低溫冷卻水cw,另外一側的該連通管連接該冷凝管路42以輸送該脫鹽蒸餾水fw2。According to an embodiment of the present invention, a connecting tube (not shown) is respectively disposed on two sides of the body of the thin film distillation member 41, wherein the connecting tube on one side is connected to one of the cold flow lines 31'. The low-temperature cooling water cw received from the cold flow guiding unit 30 is connected to the condensing line 42 to transport the desalted distilled water fw2.

根據本創作一實施例,其中更包含一鼓風設備70,該鼓風設備連通該脫鹽收集室12,用以提供該脫鹽收集室12的對流氣體,以使熱流混合完全並通過薄膜蒸餾件41,增強水蒸氣並減少薄膜污染。According to an embodiment of the present invention, there is further included an air blowing device 70 that communicates with the desalination collection chamber 12 for providing a convective gas of the desalination collection chamber 12 such that the heat flow is completely mixed and passes through the thin film distillation member 41. Enhance water vapor and reduce film contamination.

補充說明,其高疏水性質的膜材,液體不會穿透而僅氣體分子會通過此膜材孔道,膜材本身只是提供液體與膜材之間達成液汽平衡的支撐物。目前有很多運動衣物具防水透氣之機能性,其材質內即有一層疏水多孔膜,如商業應用的GORE-TEX 薄膜,雨水不能滲透ORE-TEX 物料,但身體排出的汗氣卻易透過小孔,孔隙度可達90%,而孔徑比水蒸氣分子大700 倍。該物料不易讓水穿透。膜材的親/疏水性一般以接觸角大小進行定量的判定,以液滴測量法從水滴與薄膜表面的接觸角(contact angle)影像進行觀察,當接觸角度愈大表示薄膜疏水性愈高;反之,若接觸角度愈小則薄膜親水性愈高。一般以接觸角大於90°為疏水性表面,反之為親水性表面,而沒有改質的鐵氟龍膜面接觸角常超過120°,因此具備高疏水性。It is added that the membrane with high hydrophobicity, the liquid will not penetrate and only gas molecules will pass through the pores of the membrane, and the membrane itself is only a support for achieving liquid-vapor equilibrium between the liquid and the membrane. At present, there are many sports clothes with waterproof and breathable function. There is a layer of hydrophobic porous film inside the material. For example, GORE-TEX film for commercial applications, rainwater can not penetrate ORE-TEX materials, but the sweat discharged from the body is easy to pass through the small holes. The porosity is up to 90%, and the pore size is 700 times larger than the water vapor molecule. This material is not easy to penetrate water. The affinity/hydrophobicity of the membrane material is generally determined by the contact angle size, and the droplet measurement method is used to observe the contact angle image of the water droplet from the surface of the film. The greater the contact angle, the higher the hydrophobicity of the film; Conversely, if the contact angle is smaller, the hydrophilicity of the film is higher. Generally, the contact angle is greater than 90° for the hydrophobic surface, and conversely for the hydrophilic surface, and the Teflon film contact angle without modification is often more than 120°, so it has high hydrophobicity.

薄膜蒸餾之孔徑通常是0.1~0.6微米,孔徑太大則液體易滲入貫穿,而孔徑太小則提高了蒸氣分子於膜內之傳送阻力。因蒸氣通量與膜孔隙度成正比,高孔隙度(40~85%)是應用於此運作之薄膜的重要物性;因需分隔高低溫,膜材需具備低熱傳導性(減少防止薄膜兩側間的熱損),也需考慮熱穩定性與化學穩定性,以因應高溫與廢水污染問題。The pore size of the thin film distillation is usually 0.1 to 0.6 μm. When the pore diameter is too large, the liquid easily penetrates into the pores, and the pore size is too small to increase the transport resistance of the vapor molecules in the membrane. Since the vapor flux is proportional to the membrane porosity, high porosity (40~85%) is an important physical property of the film used for this operation; due to the need to separate high and low temperatures, the film needs to have low thermal conductivity (reducing the prevention of both sides of the film) Heat loss and chemical stability are also considered in order to cope with high temperature and wastewater pollution problems.

根據本創作一實施例,其中該薄膜蒸餾件41係選用由鐵氟龍(PTFE)、聚乙烯醇(PVA)、二氟乙烯(PVDF)或聚丙烯(PP)所製成的高疏水性多孔薄膜件體;較低地,該薄膜蒸餾件41係由鐵氟龍(PTFE)所製成,其具有極佳的疏水性質且具有較高的化學穩定性。According to an embodiment of the present invention, the thin film distillation member 41 is made of high hydrophobic porous material made of Teflon (PTFE), polyvinyl alcohol (PVA), difluoroethylene (PVDF) or polypropylene (PP). The film member body; lowerly, the film distillation member 41 is made of Teflon (PTFE), which has excellent hydrophobic properties and high chemical stability.

根據該薄膜蒸餾件41在低溫產水側的凝結方式的不同,薄膜蒸餾常大致區分為四種運作方式:直接接觸式(Direct Contact Membrane Distillation, DCMD)、空氣間隙式(Air Gap Membrane Distillation, AGMD)、氣體掃掠式(Sweep Gas Membrane Distillation, SGMD )及真空式(Vacuum Membrane Distillation, VMD)。According to the condensation mode of the thin film distillation member 41 on the low temperature water producing side, the thin film distillation is generally roughly divided into four operation modes: Direct Contact Membrane Distillation (DCMD), Air Gap Membrane Distillation (AGMD). ), Sweep Gas Membrane Distillation (SGMD) and Vacuum Membrane Distillation (VMD).

直接接觸式(DCMD)是以溫度較高的進水與透過液端的冷卻循環水,分別於薄膜兩側與薄膜直接接觸,作同向或反向流動,蒸氣分子透過膜孔道擴散至低溫滲透端,並直接將其冷凝收集。現今薄膜蒸餾之研究,約有80% 屬於此運作模組,優點在於模組件結構簡單,又因兩股液體皆與薄膜直接接觸,模組流道中熱傳以及質傳的阻力較小,所以蒸氣透過速率大,但是伴隨著膜熱傳導損耗也相對較高,導致熱效率較低。The direct contact type (DCMD) is a cooling water with a relatively high temperature inlet and a permeate end, which are in direct contact with the film on both sides of the film, and flow in the same direction or in the opposite direction, and the vapor molecules diffuse through the membrane channel to the low temperature permeate end. And collect it directly by condensation. At present, about 80% of the research on thin film distillation belongs to this operation module. The advantage is that the mold assembly has a simple structure, and since both liquids are in direct contact with the film, the heat transfer in the module flow channel and the resistance of the mass transfer are small, so The vapor transmission rate is large, but the membrane heat conduction loss is also relatively high, resulting in lower thermal efficiency.

空氣間隙式(AGMD)與直接接觸式(DCMD)的差異在於滲透端液體並非與薄膜直接接觸,而是在其中設置了冷凝熱交換面,蒸氣分子穿過薄膜後,仍要通過一段空氣間隙再擴散至冷凝板上以凝結成液滴。由於薄膜不與冷卻液體直接接觸,可降低薄膜傳導之熱損失,且凝結的液體可以直接收集利用,不會與冷卻流體混合,故適用範圍較為廣泛,並已成功用於純水生產和濃縮各種非揮發性溶。然而,其缺點是多了此空氣間隙,將增加了蒸氣分子整體擴散之質傳阻力,造成通量常明顯低於直接接觸式。The difference between air gap type (AGMD) and direct contact type (DCMD) is that the liquid at the osmotic end is not in direct contact with the film, but a condensing heat exchange surface is disposed therein. After the vapor molecules pass through the film, they still pass through an air gap. Diffused to the condensing plate to condense into droplets. Since the film is not in direct contact with the cooling liquid, the heat loss of the film conduction can be reduced, and the condensed liquid can be directly collected and utilized without mixing with the cooling fluid, so the application range is wide, and it has been successfully used for pure water production and concentration. Non-volatile solution. However, the disadvantage is that this air gap is increased, which will increase the mass transfer resistance of the vapor molecules as a whole, and the flux is often significantly lower than the direct contact type.

氣體掃流式(SGMD)係將滲透端的液體改為流動的氣體,當蒸氣分子擴散穿透膜孔道後,隨即被掃流的惰性氣體帶走並透過外部裝置冷凝收集,此方式適用於去除稀薄溶液中的揮發性物質。雖然此運作之滲透通量大且膜材之傳導熱損失小於前述兩種運作模組,但此程序需設計有外部冷凝器,設備成本會較高。The gas sweep type (SGMD) changes the liquid at the permeate end to a flowing gas. When the vapor molecules diffuse through the pores of the membrane, they are then taken away by the inert gas that is swept away and collected by condensation through an external device. This method is suitable for removing thin particles. Volatile substances in the solution. Although the permeation flux of this operation is large and the conduction heat loss of the membrane is smaller than the above two operation modules, the procedure needs to be designed with an external condenser, and the equipment cost is high.

真空式(VMD)與氣體掃掠式相似,但在薄膜另一側並非低溫流體,而是以抽真空的方式將蒸氣抽走,並在組件外實現水蒸氣的冷凝,此運作可維持較高之蒸氣壓差,且消除了膜孔內的不凝氣(空氣)降低蒸氣於薄膜孔道中的質傳阻力,這皆有助於提升滲透通量,而缺點則是為維持穩定真空需設置真空泵以負壓抽取,所需耗能可能較高,且因此運作可提供之蒸氣壓力差較大,膜孔被進料液體貫穿潤濕的風險也較高。此程序除可應用於水處理外,亦可用於提取出可溶性氣體或移除稀薄溶液中的揮發性物質。The vacuum type (VMD) is similar to the gas sweep type, but it is not a cryogenic fluid on the other side of the membrane, but evacuates the vapor by vacuuming and condenses the water vapor outside the module. This operation can be maintained high. The difference in vapor pressure and the elimination of non-condensable gas (air) in the pores of the membrane reduces the mass transfer resistance of the vapor in the pores of the membrane, which contributes to the improvement of the permeate flux, and the disadvantage is that a vacuum pump is required to maintain a stable vacuum. With negative pressure extraction, the required energy consumption may be higher, and therefore the vapor pressure difference that the operation can provide is large, and the risk of the membrane pores being wetted by the feed liquid is also high. This procedure can be used to extract soluble gases or to remove volatiles from thin solutions, in addition to water treatment.

據此,本創作再提出一種基於海水淡化循環系統的薄膜蒸餾件的一實施例,如圖2所示。在本實施例中,該薄膜蒸餾件P1為由疏水性多孔薄膜製成,其材質為選自鐵氟龍(PTFE)、聚乙烯醇(PVA)或聚丙烯(PP)之其中一者,其表面分布有多個膜孔P10。該薄膜蒸餾件P1係以直接接觸式(DCMD)運作方式做為件體結構設計。其中該薄膜蒸餾件P1的孔隙之平均尺寸為在0.1μm~1μm之範圍;較佳地,孔隙之平均尺寸為在0.4μm~1μm之範圍。該薄膜蒸餾件P1的該件體結構二側表面分別設有一連通口P11,且於上下兩端係分別設有封口P12以密封該件體。請參閱圖4所示,其顯示本創作圖2的薄膜蒸餾件P1的在應用上的一實施態樣。Accordingly, the present invention proposes an embodiment of a thin film distillation member based on a seawater desalination cycle system, as shown in FIG. In the present embodiment, the thin film distillation member P1 is made of a hydrophobic porous film and is made of one selected from the group consisting of Teflon (PTFE), polyvinyl alcohol (PVA), and polypropylene (PP). A plurality of film holes P10 are distributed on the surface. The thin film distillation member P1 is designed as a body structure in a direct contact type (DCMD) operation mode. The average size of the pores of the thin film distillation member P1 is in the range of 0.1 μm to 1 μm; preferably, the average size of the pores is in the range of 0.4 μm to 1 μm. The two sides of the film structure of the film distillation member P1 are respectively provided with a communication port P11, and a sealing mouth P12 is respectively provided at the upper and lower ends to seal the body. Referring to FIG. 4, an embodiment of the application of the thin film distillation member P1 of FIG. 2 is shown.

本創作再提出一種基於海水淡化循環系統的薄膜蒸餾件的另一實施態樣,如圖3a~3b所示。在本實施例中,該薄膜蒸餾件P2製成包含有一膜片P21以及一蛇狀流道基座P22,該膜片P21為疏水性多孔薄膜製成,其材質為選自鐵氟龍(PTFE)、聚乙烯醇(PVA)或聚丙烯(PP)之其中一者,該膜片P21表面分布有多個膜孔P210且包覆該蛇狀流道基座P22。 其中該薄膜蒸餾件P2係以直接接觸式(DCMD)運作方式作設計。其中該海水淡化膜片P21的孔隙之平均尺寸為在0.1μm~1μm之範圍;較佳地,孔隙之平均尺寸為在0.4μm~1μm之範圍。蛇狀流道基座P22的兩側端分別開設有一連通口P220,而蛇狀流道基座P22中的流道幾何結構集其尺寸係根據實際應用做變化,在此不限定。The present invention further proposes another embodiment of a thin film distillation member based on a seawater desalination cycle system, as shown in Figures 3a to 3b. In the present embodiment, the film distillation member P2 is formed to include a diaphragm P21 and a serpentine flow path base P22. The diaphragm P21 is made of a hydrophobic porous film and is made of a material selected from the group consisting of Teflon (PTFE). Or one of polyvinyl alcohol (PVA) or polypropylene (PP), a plurality of film pores P210 are distributed on the surface of the membrane P21 and the serpentine flow path base P22 is coated. The film distillation member P2 is designed in a direct contact (DCMD) operation mode. The average size of the pores of the seawater desalination membrane P21 is in the range of 0.1 μm to 1 μm; preferably, the average pore size is in the range of 0.4 μm to 1 μm. The two sides of the serpentine flow path base P22 respectively have a communication port P220, and the size of the flow channel geometry in the serpentine flow path base P22 varies according to the actual application, and is not limited herein.

綜上所述,本創作所述之海稅淡化循環系統,利用來自船隻本身的熱流和冷流來降低能量消耗,允許廢水或海水可滲透通過該系統,在而根據船體空間大小可設置有多個獨立運行的脫鹽收集室以更有效率地連續產生脫鹽後的清水。薄膜蒸餾件的形態並未特別限定,可以是袋式、片狀、圓筒狀、中空捲筒式或其他的特殊設計,只要可以為船隻產生大量的淡水皆可。此外,熱流來自於引擎的冷卻水,用於冷卻引擎的海水,從引擎加熱後溫度高達60℃以上進入脫鹽收集室,並透過薄膜蒸餾件體的水蒸氣滲透出脫鹽蒸餾水,而冷流由深海水抽取並被與泵入熱交換系統進行熱交換,以產生做為系統冷卻循環的低溫冷卻水以及可用於飲用的清水。再者,鼓風裝置更設計用於完全混合熱流並通過薄膜蒸餾件體,增強水蒸氣並減少薄膜污染。In summary, the sea tax desalination cycle system described in the present invention utilizes heat flow and cold flow from the vessel itself to reduce energy consumption, allowing wastewater or seawater to permeate through the system, and may be provided according to the size of the hull space. A plurality of independently operated desalination collection chambers continuously produce desalinated fresh water more efficiently. The form of the film distillation member is not particularly limited, and may be a bag type, a sheet shape, a cylindrical shape, a hollow drum type or the like, as long as it can generate a large amount of fresh water for the vessel. In addition, the heat flow comes from the cooling water of the engine, which is used to cool the seawater of the engine. After the engine is heated, the temperature reaches up to 60 °C and enters the desalination collection chamber, and the water vapor permeates through the thin film distillation body to permeate the demineralized distilled water, while the cold current flows from the deep sea. The water is pumped and exchanged with the pumped heat exchange system to produce cryogenic cooling water as a system cooling cycle and fresh water for drinking. Furthermore, the blasting device is more designed to completely mix the heat flow and through the thin film distillation body to enhance water vapor and reduce film contamination.

惟以上所記載之具體實施例,僅係用於例釋本創作之特點及功效,而非用於限定本創作之可實施範疇,於未脫離本創作上揭之精神與技術範疇下,任何運用本創作所揭示內容而完成之等效改變及修飾,均仍應為下記載之申請專利範圍所涵蓋。However, the specific embodiments described above are only used to illustrate the features and functions of the present invention, and are not intended to limit the scope of implementation of the present invention, without departing from the spirit and technical scope of the creation. The equivalent changes and modifications made by the present disclosure are still covered by the scope of the patent application described below.

10‧‧‧海水收集單元10‧‧‧Seawater collection unit

11‧‧‧進水通道 11‧‧‧Water inlet channel

12‧‧‧脫鹽收集室 12‧‧‧Desalting collection room

20‧‧‧熱流引導單元 20‧‧‧Heat flow guide unit

21‧‧‧熱流管路 21‧‧‧Hot flow line

22‧‧‧加熱組件 22‧‧‧heating components

30‧‧‧冷流引導單元 30‧‧‧Cold flow guiding unit

31 、31’‧‧‧冷流管路 31, 31’‧‧‧ cold flow piping

32‧‧‧熱交換儲槽 32‧‧‧Heat exchange tank

320‧‧‧容置空間 320‧‧‧ accommodating space

321‧‧‧內槽體 321‧‧‧ inner tank

322‧‧‧外槽體 322‧‧‧ outer trough body

40‧‧‧脫鹽處理單元 40‧‧‧Desalting unit

41‧‧‧薄膜蒸餾件 41‧‧‧film distillation parts

42‧‧‧冷凝管路 42‧‧‧Condensation line

50‧‧‧抽水裝置 50‧‧‧ pumping device

60‧‧‧過濾裝置 60‧‧‧Filter device

70‧‧‧鼓風裝置 70‧‧‧Blowing device

80‧‧‧淡水槽 80‧‧‧light sink

sw1‧‧‧濃鹽高溫水 Sw1‧‧‧Concentrated salt high temperature water

sw2‧‧‧濃鹽低溫水 Sw2‧‧‧Concentrated salt low temperature water

fw2‧‧‧脫鹽蒸餾水 Fw2‧‧‧desalted distilled water

cw‧‧‧低溫冷卻水 Cw‧‧‧Cryogenic cooling water

P1‧‧‧薄膜蒸餾件 P1‧‧‧film distillation parts

P10‧‧‧膜孔 P10‧‧‧ film hole

P11‧‧‧連通口 P11‧‧‧Connected

P12‧‧‧封口 P12‧‧‧ Seal

P2‧‧‧薄膜蒸餾件 P2‧‧‧film distillation parts

P21‧‧‧膜片 P21‧‧‧ diaphragm

P210‧‧‧膜孔 P210‧‧‧ film hole

P22‧‧‧蛇狀流道基座 P22‧‧‧Snake channel base

P220‧‧‧連通口 P220‧‧‧Connecting port

圖1係顯示本創作之海水淡化系統的系統架構圖。 圖2係顯示本創作之薄膜蒸餾件一實施例的外觀示意圖。 圖3a~3b係顯示本創作之薄膜蒸餾件另一實施例的外觀示意圖。 圖4係顯示本創作之圖2的薄膜蒸餾件於應用實施態樣。Figure 1 is a system architecture diagram showing the seawater desalination system of the present invention. Fig. 2 is a schematic view showing the appearance of an embodiment of the film distillation member of the present invention. 3a-3b are schematic views showing the appearance of another embodiment of the film distillation member of the present invention. Fig. 4 is a view showing the application of the film distillation member of Fig. 2 of the present invention.

Claims (10)

一種海水淡化循環系統,其包括:一海水收集單元,包含至少一脫鹽收集室且該脫鹽收集室具有至少一進水通道;一熱流引導單元,包含連接該脫鹽收集室的至少一熱流管路與配置於該熱流管路上的一加熱組件,該熱流引導單元係用以抽取海水且以該加熱組件將海水加熱升溫後形成一濃鹽高溫水,並以該熱流管路經由該進水通道將該濃鹽高溫水引入該脫鹽收集室中;一冷流引導單元,包含多個冷流管路與一熱交換儲槽,該冷流引導單元係用以抽取海水做為一濃鹽低溫水且以一該冷流管路將該濃鹽低溫水輸送至該熱交換儲槽進行熱交換,以產生一低溫冷卻水;以及一脫鹽處理單元,設於該脫鹽收集室中且包含至少一個薄膜蒸餾件與至少一冷凝管路,該冷凝管路係分別連通該薄膜蒸餾件與該熱交換儲槽,該薄膜蒸餾件用以接收自另一該冷流管路導出的該低溫冷卻水,且其與該脫鹽收集室中的該濃鹽高溫水間之一溫度梯度差所引起蒸汽壓差而生成一脫鹽水蒸汽,該脫鹽水蒸汽滲透進入該薄膜蒸餾件的內部降溫形成一脫鹽蒸餾水,並經由該冷凝管路輸送至該熱交換儲槽以與該濃鹽低溫水進行熱交換脫鹽蒸餾水,該脫鹽蒸餾水的一部分做為該低溫冷卻水以供該系統進行冷卻循環,而另一部分供以使用或飲用;其中該薄膜蒸餾件係袋式、片狀、圓筒狀、中空捲筒式或其他形態的構造體。 A seawater desalination cycle system comprising: a seawater collection unit comprising at least one desalination collection chamber and the desalination collection chamber having at least one inlet passage; a heat flow guiding unit comprising at least one heat flow conduit connecting the desalination collection chamber a heating assembly disposed on the heat flow conduit, the heat flow guiding unit is configured to extract seawater, and the heating assembly heats the seawater to form a concentrated salt high temperature water, and the hot water pipeline passes the water inlet passage through the water inlet passage The concentrated salt high temperature water is introduced into the desalination collection chamber; a cold flow guiding unit comprises a plurality of cold flow conduits and a heat exchange storage tank, wherein the cold flow guiding unit is configured to extract seawater as a concentrated salt of low temperature water and a cold flow line conveying the concentrated salt low temperature water to the heat exchange storage tank for heat exchange to generate a low temperature cooling water; and a desalination treatment unit disposed in the desalination collection chamber and including at least one thin film distillation piece And the at least one condensation line, the condensation line is respectively connected to the thin film distillation piece and the heat exchange storage tank, and the thin film distillation piece is received from another cold flow line The low temperature cooling water, and a difference in temperature gradient between the temperature gradient of the concentrated salt and the high temperature water in the demineralization collection chamber generates a demineralized water vapor, and the demineralized water vapor permeates into the inner portion of the thin film distillation member to form a temperature. Distilling distilled water and transporting it to the heat exchange storage tank via the condensation line to exchange heat with the concentrated salt low temperature water for demineralized distilled water, and a part of the desalted distilled water is used as the low temperature cooling water for the system to perform a cooling cycle, and Another portion is provided for use or for drinking; wherein the thin film distillation member is in the form of a bag, a sheet, a cylinder, a hollow drum or other form. 如請求項1所記載之海水淡化循環系統,其中該溫度梯度差為在15℃~50℃之範圍。 The seawater desalination cycle system of claim 1, wherein the temperature gradient difference is in the range of 15 ° C to 50 ° C. 如請求項1所記載之海水淡化循環系統,其係更包含一淡水槽,其係配設於該熱交換儲槽的下游端並用以收容來自該熱交換儲槽中之該脫鹽蒸餾水,以供使用或飲用。 The seawater desalination cycle system of claim 1, further comprising a fresh water tank disposed at a downstream end of the heat exchange storage tank for receiving the demineralized distilled water from the heat exchange storage tank for Use or drink. 如請求項1所記載之海水淡化循環系統,其中該熱交換儲槽包含一內槽體以及環設於該內槽體外的一外槽體,該內槽體連接該冷凝管路以接收該脫鹽蒸餾水,該內槽體與該外槽體彼此不連通且兩者之間形成有一容置空間以容納來自海水的該濃鹽低溫水,而相對低溫的該濃鹽低溫水與相對高溫的該脫鹽蒸餾水彼此隔著該內槽體引發熱交換作用,以使該脫鹽蒸餾水降溫形成該低溫冷卻水脫鹽蒸餾水。 The seawater desalination cycle system of claim 1, wherein the heat exchange storage tank comprises an inner tank body and an outer tank body disposed outside the inner tank, the inner tank body connecting the condensation pipeline to receive the desalination Distilled water, the inner tank body and the outer tank body are not in communication with each other and an accommodating space is formed therebetween to accommodate the concentrated salt low-temperature water from seawater, and the concentrated salt low-temperature water and the relatively high temperature of the low-temperature water are relatively low temperature The distilled water initiates heat exchange interaction with each other through the inner tank body to cool the desalted distilled water to form the low-temperature cooling water desalted distilled water. 如請求項1所記載之海水淡化循環系統,其中該薄膜蒸餾件為複數個,且各該薄膜蒸餾件的二側分別設有一連通管,其中一側的該連通管連接其中一該冷流管路以接收自該冷流引導單元的該低溫冷卻水,另外一側的該連通管連接該冷凝管路以輸送該脫鹽蒸餾水。 The seawater desalination cycle system of claim 1, wherein the film distillation member is plural, and each of the two sides of the film distillation member is respectively provided with a communication tube, wherein the communication tube on one side is connected to one of the cold currents. The pipeline receives the cryogenic cooling water from the cold flow guiding unit, and the communication pipe on the other side is connected to the condensation pipeline to deliver the desalted distilled water. 如請求項1所記載之海水淡化循環系統,其中更包含一鼓風設備,該鼓風設備連通該脫鹽收集室,用以提供該脫鹽收集室的對流氣體。 The seawater desalination cycle system of claim 1, further comprising an air blowing device connected to the desalination collection chamber for providing a convection gas of the desalination collection chamber. 如請求項1所記載之海水淡化循環系統,其中該加熱組件係自太陽能板、加熱器、加熱線圈、船體之引擎裝置、及其組合中所選出之至少一種,該濃鹽高溫水的溫度至少為60℃。 The seawater desalination cycle system according to claim 1, wherein the heating component is at least one selected from the group consisting of a solar panel, a heater, a heating coil, an engine device of a hull, and a combination thereof, and a temperature of the concentrated salt high temperature water. At least 60 ° C. 如請求項1所記載之海水淡化循環系統,其中該薄膜蒸餾件係由鐵氟龍(PTFE)、聚乙烯醇(PVA)或聚丙烯(PP)所製成。 The seawater desalination cycle system of claim 1, wherein the film distillation member is made of Teflon (PTFE), polyvinyl alcohol (PVA) or polypropylene (PP). 如請求項1所記載之海水淡化循環系統,其中該薄膜蒸餾件的孔隙之平均尺寸為在0.1μm~1μm之範圍。 The seawater desalination cycle system according to claim 1, wherein the average pore size of the thin film distillation member is in the range of 0.1 μm to 1 μm. 如請求項1所記載之海水淡化循環系統,其中該薄膜蒸餾件為一直接接觸式(Direct Contact Membrane Distillation,DCMD)的疏水性多孔薄膜。 The seawater desalination cycle system of claim 1, wherein the film distillation member is a direct contact Membrane Distillation (DCMD) hydrophobic porous film.
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TWI809591B (en) * 2021-12-08 2023-07-21 四季洋圃生物機電股份有限公司 Sea and fresh water separation device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI809591B (en) * 2021-12-08 2023-07-21 四季洋圃生物機電股份有限公司 Sea and fresh water separation device

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