TWM499730U - Dimming device - Google Patents

Dimming device Download PDF

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Publication number
TWM499730U
TWM499730U TW103222275U TW103222275U TWM499730U TW M499730 U TWM499730 U TW M499730U TW 103222275 U TW103222275 U TW 103222275U TW 103222275 U TW103222275 U TW 103222275U TW M499730 U TWM499730 U TW M499730U
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Taiwan
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liquid crystal
refractive index
dimming device
porous film
crystal material
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TW103222275U
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Chinese (zh)
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Chun-Chieh Yi
Lung-Hai Wu
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Benq Materials Corp
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Publication of TWM499730U publication Critical patent/TWM499730U/en

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Abstract

Disclosed herein is a dimming device including a dimming element and a polarizer on a side thereof. The dimming element includes a pair of parallel electrode layers; a porous film between the pair of parallel electrode layers, wherein the porous film has a refractive index and a plurality of pores arranged in a single direction; and a birefringent liquid crystal material filled in the pores of the porous film. The direction of the absorption axis of the polarizer is parallel to or perpendicular to the arranged direction of the pores. The dimming device is in transparent state without electric field, or is in opaque state with electric field.

Description

調光裝置Dimming device

本創作是有關於一種調光裝置,特指一種具有可調整所通過之光線為透明態或不透明態之反相型高分子分散液晶調光裝置。The present invention relates to a dimming device, and particularly relates to a reverse-phase polymer dispersed liquid crystal dimming device having an adjustable light passing through a transparent or opaque state.

隨著智慧型玻璃、窗戶的發展,各種光調節裝置或光切換裝置的應用因此增加。傳統採用高分子分散液晶(PDLC)之調光裝置依其在電場作用下為透明態或不透明態,而可區分為透明態之正相型PDLC調光裝置或不透明態之反相型PDLC調光裝置。此二種型態之PDLC調光裝置的應用情況一般可取決於使用時的透明態與不透明態所佔時間比例,例如:當做為投影膜時,需長時間處於不透明態以投影成像,則可採用正相PDLC調光裝置;而當做為如窗戶、車窗或車用抬頭顯示器投影膜等應用時,主要需處於透明態,再視需要切換為不透明態,使其具有電子式窗簾功能或增加顯示對比度,則可採用反相PDLC調光裝置。然而,傳統反相PDLC調光裝置為了維持斷電時之透明態,故須使液晶分子分散於高分子基材中時,液晶分子之平均折射率與高分子之折射率一致,且須具有合適的液晶微滴大小、形狀與表面能,使液晶分子之長軸方向具有垂直於基材表面之取 向。因此,傳統反相PDLC調光裝置的製作方式較液晶微滴可隨機分散於高分子基材中的正相PDLC調光裝置複雜,且其在未施加電場下的取向程度普遍不如需施加電場的正相PDLC調光裝置,致使傳統反相PDLC調光裝置之透明態之透光效果相對於正相PDLC調光裝置亦較不清晰。With the development of smart glass and windows, the application of various light adjusting devices or light switching devices has increased. Conventionally, a polymer-dispersed liquid crystal (PDLC) dimming device is transparent or opaque under the action of an electric field, and can be distinguished as a transparent phase positive phase PDLC dimming device or an opaque reverse phase PDLC dimming device. Device. The application of the two types of PDLC dimming devices generally depends on the proportion of the time of the transparent state and the opaque state in use, for example, when used as a projection film, it is required to be in an opaque state for projection imaging for a long time. The use of normal phase PDLC dimming device; when used as a window, window or car head-up display projection film, etc., mainly need to be in a transparent state, and then switch to opaque state as needed, so that it has electronic curtain function or increase For display contrast, an inverted PDLC dimming device can be used. However, in order to maintain the transparent state during the power-off, the conventional reverse-phase PDLC dimming device must disperse the liquid crystal molecules in the polymer substrate, and the average refractive index of the liquid crystal molecules is consistent with the refractive index of the polymer, and must be suitable. Liquid crystal droplet size, shape and surface energy, so that the long axis direction of the liquid crystal molecules has a perpendicular to the surface of the substrate to. Therefore, the conventional reverse phase PDLC dimming device is more complicated than the normal phase PDLC dimming device in which the liquid crystal droplets can be randomly dispersed in the polymer substrate, and the degree of orientation under the unapplied electric field is generally not as good as the application of the electric field. The normal phase PDLC dimming device makes the transparent light transmission effect of the conventional reverse phase PDLC dimming device less clear than the normal phase PDLC dimming device.

有鑑於上述傳統技藝之問題,本創作之目的就是在提供一種具備新穎性、進步性及產業利用性等專利要件之調光裝置,以期克服現有產品之難點。In view of the above-mentioned problems of the traditional art, the purpose of the creation is to provide a dimming device with novelty, progressiveness and industrial utilization, etc., in order to overcome the difficulties of the existing products.

為達到上述目的,本創作提供一種調光裝置,其包含:調光元件,包含一對平行電極層;多孔膜位於該對平行電極層之間,多孔膜具有一折射率,且多孔膜之孔洞具有單一排列方向;以及雙折射液晶材料填充於多孔膜之孔洞中;以及偏光層設置於該調光元件之一側。偏光層之吸收軸與多孔膜之孔洞之排列方向呈平行或垂直。因調光裝置具有偏光層結構,可過濾吸收一半吸收軸方向分量之入射光,使透明態時穿過多孔膜之光線維持單一方向透射,減少吸收軸方向分量入射光於多孔膜中之折射與散射,使調光裝置具有比一般反相型PDLC調光裝置較佳之清晰度,且調整其設置角度還可於車用玻璃等應用中,以同時減少外界非金屬物之反光。此外,因多孔膜與偏光層其本身材料之色調不同,例如採用聚烯烴類之多孔膜一般為白色,偏光層一般為棕灰色,因此,調光裝置兩側之反射率隨之不同,做為窗戶等應 用時,將多孔膜側設置於入光側,更可使偏光層側具有一定防窺視效果。In order to achieve the above object, the present invention provides a dimming device comprising: a dimming element comprising a pair of parallel electrode layers; a porous film between the pair of parallel electrode layers, the porous film having a refractive index, and a hole of the porous film Having a single alignment direction; and a birefringent liquid crystal material filled in the pores of the porous film; and a polarizing layer disposed on one side of the dimming element. The absorption axis of the polarizing layer is parallel or perpendicular to the arrangement direction of the pores of the porous film. Since the dimming device has a polarizing layer structure, it can filter and absorb the incident light of the absorption axis component in half, so that the light passing through the porous film in the transparent state maintains the single direction transmission, and reduces the refraction of the incident light in the porous film in the absorption axis direction component. The scattering makes the dimming device have better definition than the general inverted PDLC dimming device, and the setting angle thereof can also be used in applications such as automotive glass to simultaneously reduce the reflection of external non-metallic objects. In addition, since the porous film and the polarizing layer have different color tones of their own materials, for example, a polyolefin-based porous film is generally white, and a polarizing layer is generally brownish-grey. Therefore, the reflectances on both sides of the dimming device are different, as Window, etc. In use, the porous film side is disposed on the light incident side, and the polarizing layer side can have a certain anti-peep effect.

在一實施例之調光裝置中,雙折射液晶材料之長軸方向具有異常光折射率(extraordinary refractive index,ne ),短軸方向具有尋常光折射率(ordinary refractive index,no );且多孔膜之折射率與雙折射液晶材料之異常光折射率或尋常光折射率之一相同。In the dimming device of an embodiment, the biaxial liquid crystal material has an extraordinary refractive index (n e ) in the long axis direction and an ordinary refractive index (n o ) in the short axis direction; The refractive index of the porous film is the same as one of the extraordinary refractive index or the ordinary refractive index of the birefringent liquid crystal material.

在又一實施例之調光裝置中,多孔膜之折射率係介於1.4至1.7。In a dimming device of still another embodiment, the refractive index of the porous film is between 1.4 and 1.7.

在另一實施例之調光裝置中,雙折射液晶材料之異常光折射率與尋常光折射率之折射率差值係介於0.2至0.25。In another embodiment of the dimming device, the difference in refractive index between the refractive index of the birefringent liquid crystal material and the refractive index of the ordinary light is between 0.2 and 0.25.

在另一實施例之調光裝置中,雙折射液晶材料係選自由層列型液晶、膽固醇液晶、棒狀液晶、碟型液晶、柱型液晶、高分子液晶、扭轉向列型液晶、超扭轉向列型液晶及其組合所組成之群組。In another embodiment of the dimming device, the birefringent liquid crystal material is selected from the group consisting of smectic liquid crystal, cholesteric liquid crystal, rod liquid crystal, dish liquid crystal, column liquid crystal, polymer liquid crystal, twisted nematic liquid crystal, super twist A group consisting of nematic liquid crystals and combinations thereof.

在另一實施例之調光裝置中,多孔膜之基材係選自由聚烯烴類高分子、聚酯類高分子、聚醯胺類高分子、聚偏氟乙烯及其組合所組成之群組。In another embodiment, the substrate of the porous film is selected from the group consisting of a polyolefin polymer, a polyester polymer, a polyamine polymer, a polyvinylidene fluoride, and a combination thereof. .

在另一實施例之調光裝置中,多孔膜之孔洞之平均孔徑係介於0.01μm至0.2μm,孔隙率係介於30%至90%。In another embodiment of the dimming device, the pores of the porous membrane have an average pore diameter of from 0.01 μm to 0.2 μm and a porosity of from 30% to 90%.

在另一實施例之調光裝置中,偏光層係為吸收型偏光板、反射型偏光板、染色型偏光板、塗佈型偏光板、光柵型偏光板或其組合。In the dimming device of another embodiment, the polarizing layer is an absorption type polarizing plate, a reflective polarizing plate, a dyeing type polarizing plate, a coating type polarizing plate, a grating type polarizing plate, or a combination thereof.

1‧‧‧調光裝置1‧‧‧ dimming device

2‧‧‧調光元件2‧‧‧ dimming components

21‧‧‧平行電極層21‧‧‧ parallel electrode layer

22‧‧‧多孔膜22‧‧‧Porous membrane

23‧‧‧孔洞23‧‧‧ holes

24‧‧‧雙折射液晶材料24‧‧‧Birefringent liquid crystal material

3‧‧‧偏光層3‧‧‧ polarizing layer

31‧‧‧吸收軸31‧‧‧Absorption axis

L‧‧‧入射光L‧‧‧ incident light

Ly‧‧‧光線Ly‧‧‧Light

第1圖係為本創作之係為本創作一實施例之調光裝置示意圖;第2A圖、第2B圖係為本創作一實施例之調光裝置產生透明態與不透明態原理之示意圖。FIG. 1 is a schematic diagram of a dimming device according to an embodiment of the present invention; FIG. 2A and FIG. 2B are schematic diagrams showing the principle of generating a transparent state and an opaque state by a dimming device according to an embodiment of the present invention.

為使本創作之創作特徵、內容與優點及其所能達成之功效更易瞭解,茲將本創作配合附圖,並以實施例之表達形式詳細說明如下,而其中所使用之圖式,其主旨僅為示意及輔助說明書之用,未必為本創作實施後之真實比例與精準配置,故不應就所附之圖式的比例與配置關係解讀、侷限本創作於實際實施上的權利範圍,合先敘明。In order to make the creative features, content and advantages of the creation and the functions that can be achieved are more easily understood, the present invention is combined with the drawings and the following is a detailed description of the embodiments, and the schematic of the drawings used therein is For the purpose of illustration and supplementary manual, it is not necessarily the true proportion and precise configuration after the implementation of the original creation. Therefore, the scope and configuration relationship of the attached drawings should not be interpreted or limited. Explain first.

以下將參照相關圖式,說明依本創作調光裝置之實施例,為使便於理解,下述實施例中之相同元件係以相同之符號標示來說明。The embodiments of the dimming device according to the present invention will be described below with reference to the related drawings. For the sake of understanding, the same components in the following embodiments are denoted by the same reference numerals.

請配合參看第1圖所示,本創作提供一種調光裝置1,其包含:調光元件2,包含一對平行電極層21;多孔膜22位於該對平行電極層21之間,多孔膜22具有一折射率,且多孔膜22之孔洞23具有單一排列方向;以及雙 折射液晶材料24填充於多孔膜22之孔洞23中;以及偏光層3設置於調光元件2之一側;其中偏光層3之吸收軸31與該多孔膜22之孔洞23之排列方向呈平行或垂直。Referring to FIG. 1 , the present invention provides a dimming device 1 comprising: a dimming element 2 comprising a pair of parallel electrode layers 21; a porous film 22 between the pair of parallel electrode layers 21, the porous film 22 Has a refractive index, and the pores 23 of the porous membrane 22 have a single alignment direction; The refractive liquid crystal material 24 is filled in the hole 23 of the porous film 22; and the polarizing layer 3 is disposed on one side of the dimming element 2; wherein the absorption axis 31 of the polarizing layer 3 and the hole 23 of the porous film 22 are arranged in parallel or vertical.

在一實施例之調光裝置中,雙折射液晶材料之長軸方向具有異常光折射率,短軸方向具有尋常光折射率;且該多孔膜之折射率與雙折射液晶材料之異常光折射率或尋常光折射率之一相同。In the dimming device of an embodiment, the birefringent liquid crystal material has an extraordinary refractive index in the long axis direction and an ordinary refractive index in the short axis direction; and the refractive index of the porous film and the extraordinary refractive index of the birefringent liquid crystal material Or one of the ordinary refractive indices is the same.

請一併參看第2A圖與第2B圖,其為本創作一實施例之調光裝置產生透明態與不透明態原理之示意圖,如第2A圖所示,雙折射液晶材料24填入多孔膜22之孔洞23後,因孔洞23具有單一排列方向(x軸方向),故雙折射液晶材料24填入孔洞23後,雙折射液晶材料24之長軸亦具有與排列方向相同之配向。在所選擇之該多孔膜22的折射率與該雙折射液晶材料24之尋常光折射率相同的情況下,當平行電極層(未示於圖上)未對多孔膜22施加電場時,雙折射液晶材料24並不轉動而維持原方向,入射光L經過偏光層3後,x軸方向的光被吸收軸31吸收而無法通過,僅剩下y軸方向分量之光線Ly穿透。因光線Ly之震動方向與雙折射液晶材料24之短軸方向(y軸方向)一致,故可感受到雙折射液晶材料24的尋常光折射率,且因多孔膜22的折射率與該雙折射液晶材料24之尋常光折射率相同,光線Ly並不會在多孔膜22與雙折射液晶材料24之界面發生折射,而可直接穿透形成透明態。如第2B圖所示,當平行電極層(未示於圖上)對多孔膜22施加電場時,雙折 射液晶材料24會扭轉一角度而使長軸向y軸方向偏轉,穿透偏光層3之光線Ly此時可同時感受到雙折射液晶材料24在y軸分量的異常光折射率和x軸分量的尋常光折射率,且因多孔膜22的折射率與雙折射液晶材料24之異常光折射率不同,光線Ly會在多孔膜22與雙折射液晶材料24之界面發生折射,而無法直接穿透形成不透明態。Please refer to FIG. 2A and FIG. 2B together, which is a schematic diagram of the principle of producing a transparent state and an opaque state of the dimming device according to an embodiment of the present invention. As shown in FIG. 2A, the birefringent liquid crystal material 24 is filled into the porous film 22 . After the holes 23, since the holes 23 have a single arrangement direction (x-axis direction), the birefringent liquid crystal material 24 is filled in the holes 23, and the major axis of the birefringent liquid crystal material 24 also has the same alignment direction. In the case where the refractive index of the porous film 22 selected is the same as the ordinary refractive index of the birefringent liquid crystal material 24, when an electric field is not applied to the porous film 22 in the parallel electrode layer (not shown), the birefringence The liquid crystal material 24 does not rotate and maintains the original direction. After the incident light L passes through the polarizing layer 3, the light in the x-axis direction is absorbed by the absorption axis 31 and cannot pass, and only the light ray Ly remaining in the y-axis direction component is penetrated. Since the direction of vibration of the light ray coincides with the short-axis direction (y-axis direction) of the birefringent liquid crystal material 24, the ordinary refractive index of the birefringent liquid crystal material 24 can be felt, and the refractive index of the porous film 22 and the birefringence The ordinary light refractive index of the liquid crystal material 24 is the same, and the light Ly does not refract at the interface between the porous film 22 and the birefringent liquid crystal material 24, but can directly penetrate to form a transparent state. As shown in FIG. 2B, when an electric field is applied to the porous film 22 in a parallel electrode layer (not shown), the double fold The liquid crystal material 24 is deflected by an angle to deflect the long axial y-axis direction, and the light ray that penetrates the polarizing layer 3 can simultaneously sense the extraordinary refractive index and x-axis component of the birefringent liquid crystal material 24 in the y-axis component. The ordinary refractive index is different, and since the refractive index of the porous film 22 is different from the extraordinary refractive index of the birefringent liquid crystal material 24, the light Ly is refracted at the interface between the porous film 22 and the birefringent liquid crystal material 24, and cannot be directly penetrated. Form an opaque state.

在又一實施例之調光裝置中,多孔膜之折射率係介於1.4至1.7。In a dimming device of still another embodiment, the refractive index of the porous film is between 1.4 and 1.7.

在另一實施例之調光裝置中,雙折射液晶材料之異常光折射率與尋常光折射率之折射率差值係介於0.2至0.25,以獲得較佳之透明態與不透明態差異。In another embodiment of the dimming device, the refractive index difference between the extraordinary refractive index of the birefringent liquid crystal material and the ordinary refractive index is between 0.2 and 0.25 to obtain a better difference between the transparent state and the opaque state.

在另一實施例之調光裝置中,雙折射液晶材料係選自由層列型液晶、膽固醇液晶、棒狀液晶、碟型液晶、柱型液晶、高分子液晶、扭轉向列型液晶、超扭轉向列型液晶及其組合所組成之群組。In another embodiment of the dimming device, the birefringent liquid crystal material is selected from the group consisting of smectic liquid crystal, cholesteric liquid crystal, rod liquid crystal, dish liquid crystal, column liquid crystal, polymer liquid crystal, twisted nematic liquid crystal, super twist A group consisting of nematic liquid crystals and combinations thereof.

在另一實施例之調光裝置中,多孔膜之基材係選自由聚烯烴類高分子、聚酯類高分子、聚醯胺類高分子、聚偏氟乙烯及其組合所組成之群組。In another embodiment, the substrate of the porous film is selected from the group consisting of a polyolefin polymer, a polyester polymer, a polyamine polymer, a polyvinylidene fluoride, and a combination thereof. .

在另一實施例之調光裝置中,視所需要透光程度,可調整選用不同平均孔徑及孔隙率之多孔膜,多孔膜之孔洞之平均孔徑係介於0.01μm至0.2μm,孔隙率係介於30%至90%。In the dimming device of another embodiment, the porous film having different average pore diameters and porosity may be adjusted depending on the degree of light transmission required, and the average pore diameter of the pores of the porous film is between 0.01 μm and 0.2 μm, and the porosity is Between 30% and 90%.

在另一實施例之調光裝置中,偏光層係為吸收型偏光板、反射型偏光板、染色型偏光板、塗佈型偏光板、 光柵型偏光板或其組合。In another embodiment, the polarizing layer is an absorption type polarizing plate, a reflective polarizing plate, a dyeing type polarizing plate, a coating type polarizing plate, A grating type polarizing plate or a combination thereof.

以上所述之實施例僅係為說明本創作之技術思想及特點,其目的在使熟習此項技藝之人士能夠瞭解本創作之內容並據以實施,當不能以之限定本創作之專利範圍,即大凡依本創作所揭示之精神所作之均等變化或修飾,仍應涵蓋在本創作之專利範圍內。The embodiments described above are only for explaining the technical idea and characteristics of the present invention, and the purpose thereof is to enable those skilled in the art to understand the contents of the present invention and implement them according to the scope of the patent. That is, the equivalent changes or modifications made by the people in accordance with the spirit revealed by this creation should still be covered by the scope of the patent of this creation.

1‧‧‧調光裝置1‧‧‧ dimming device

2‧‧‧調光元件2‧‧‧ dimming components

21‧‧‧平行電極層21‧‧‧ parallel electrode layer

22‧‧‧多孔膜22‧‧‧Porous membrane

23‧‧‧孔洞23‧‧‧ holes

24‧‧‧雙折射液晶材料24‧‧‧Birefringent liquid crystal material

3‧‧‧偏光層3‧‧‧ polarizing layer

31‧‧‧吸收軸31‧‧‧Absorption axis

Claims (10)

一種調光裝置,包含:一調光元件,包含一對平行電極層;一多孔膜位於該對平行電極層之間,該多孔膜具有一折射率,且該多孔膜之孔洞具有單一排列方向;以及一雙折射液晶材料填充於該多孔膜之孔洞中;以及一偏光層設置於該調光元件之一側,其中該偏光層之吸收軸與該多孔膜之孔洞之排列方向呈平行或垂直。A dimming device comprising: a dimming element comprising a pair of parallel electrode layers; a porous film between the pair of parallel electrode layers, the porous film having a refractive index, and the holes of the porous film having a single alignment direction And a birefringent liquid crystal material is filled in the hole of the porous film; and a polarizing layer is disposed on one side of the dimming element, wherein an absorption axis of the polarizing layer is parallel or perpendicular to a direction in which the hole of the porous film is arranged . 如申請專利範圍第1項所述之調光裝置,其中該多孔膜之該折射率係介於1.4至1.7。The dimming device of claim 1, wherein the refractive index of the porous film is between 1.4 and 1.7. 如申請專利範圍第1項所述之調光裝置,其中該雙折射液晶材料之長軸方向具有一異常光折射率,短軸方向具有一尋常光折射率。The dimming device of claim 1, wherein the birefringent liquid crystal material has an extraordinary refractive index in a long axis direction and an ordinary refractive index in a short axis direction. 如申請專利範圍第3項所述之調光裝置,其中該多孔膜之該折射率與該雙折射液晶材料之異常光折射率或尋常光折射率之一相同。The dimming device of claim 3, wherein the refractive index of the porous film is the same as one of an extraordinary refractive index or an ordinary refractive index of the birefringent liquid crystal material. 如申請專利範圍第3項所述之調光裝置,其中該雙折射液晶材料之異常光折射率與尋常光折射率之折射率差值係介於0.2至0.25。The dimming device of claim 3, wherein the refractive index difference between the extraordinary refractive index of the birefringent liquid crystal material and the ordinary refractive index is between 0.2 and 0.25. 如申請專利範圍第1項所述之調光裝置,其中該雙折射液晶材料係選自由層列型液晶、膽固醇液晶、棒狀液晶、碟型液晶、柱型液晶、高分子液晶、扭轉向列型液晶、超扭轉向列型液晶及其組合所組成之群組。The dimming device of claim 1, wherein the birefringent liquid crystal material is selected from the group consisting of smectic liquid crystal, cholesteric liquid crystal, rod liquid crystal, dish liquid crystal, column liquid crystal, polymer liquid crystal, and twisted nematic A group of liquid crystals, super twisted nematic liquid crystals, and combinations thereof. 如申請專利範圍第1項所述之調光裝置,其中該多孔膜之基材係選自由聚烯烴類高分子、聚酯類高分子、聚醯胺類高分子、聚偏氟乙烯及其組合所組成之群組。The dimming device according to claim 1, wherein the substrate of the porous film is selected from the group consisting of a polyolefin polymer, a polyester polymer, a polyamine polymer, a polyvinylidene fluoride, and a combination thereof. The group formed. 如申請專利範圍第1項所述之調光裝置,其中該多孔膜之孔洞之平均孔徑係介於0.01μm至0.2μm。The dimming device of claim 1, wherein the pores of the porous membrane have an average pore diameter of from 0.01 μm to 0.2 μm. 如申請專利範圍第1項所述之調光裝置,其中該多孔膜之孔洞之孔隙率係介於30%至90%。The dimming device of claim 1, wherein the porous film has a porosity of between 30% and 90%. 如申請專利範圍第1項所述之調光裝置,其中該偏光層係為吸收型偏光板、反射型偏光板、染色型偏光板、塗佈型偏光板、光柵型偏光板或其組合。The dimming device according to claim 1, wherein the polarizing layer is an absorbing polarizing plate, a reflective polarizing plate, a dyeing polarizing plate, a coating polarizing plate, a grating polarizing plate, or a combination thereof.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI737512B (en) * 2019-10-10 2021-08-21 南韓商Lg化學股份有限公司 Light modulation device and vehicle comprising the same
TWI780830B (en) * 2020-07-24 2022-10-11 南韓商Lg化學股份有限公司 Light modulating device and window and sunroof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI737512B (en) * 2019-10-10 2021-08-21 南韓商Lg化學股份有限公司 Light modulation device and vehicle comprising the same
TWI780830B (en) * 2020-07-24 2022-10-11 南韓商Lg化學股份有限公司 Light modulating device and window and sunroof

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