TWM499253U - A heat integration apparatus - Google Patents

Abstract

HCN is typically produced by using air as the oxygen source in the Andrussow process. However, when oxygen-enriched air or pure oxygen is used, the increased water concentration in the crude hydrogen cyanide product changes the ammonia separation and recovery process. It has been found that when an oxygen-enriched air or a pure oxygen Andrussow process is used, the overhead stream from an ammonia stripper has an increased temperature that may be used to produce stream by passing the stream through a waste heat boiler. This passing of the stream through a waste heat boiler both decreases corrosion and allows for the recovered heat from the stream to be integrated with the HCN refining section of the process. A heat integration apparatus is thus provided to achieve the desired objectives.

Description

Thermal integration device Related application cross reference

The present application claims priority to U.S. Application Serial No. 61/738,830, filed on Dec.

The present invention relates to a thermal integration device for integrating heat recovered by an ammonia recovery system with an HCN refining system.

Conventionally, hydrogen cyanide ("HCN") is manufactured on an industrial scale according to the Andrussow process or the BMA process. (See, for example, Ullman's Encyclopedia of Industrial Chemistry, Vol. A8, Weinheim 1987, pp. 161-163). For example, in the Andrussow process, HCN can be produced commercially by reacting ammonia with a methane-containing gas and an oxygen-containing gas in an elevated temperature in a reactor in the presence of a suitable catalyst (U.S. Patent No. 1,934,838 and 6,596,251). Sulfur compounds and higher homologues of methane have an effect on the oxidative aminolysis parameters of methane. See, for example, Trusov, Effect of Sulfur Compounds and Higher Homologues of Methane on Hydrogen Cyanide Production by the Andrussow Method, Russian J. Applied Chemistry, 74: 10 (2001), pp. 1693-1697). Unreacted ammonia and HCN are separated by contacting the reactor effluent gas stream with an aqueous ammonium phosphate solution in an ammonia absorber. The separated ammonia is purified and concentrated for recycle for HCN conversion. HCN is typically recovered from the treated reactor effluent gas stream by absorption into water. The recovered HCN can be processed by further refining steps. Purification of HCN by biosynthesis. The Clean Development Mechanism Project Design Document Form (CDM PDD, 3rd Edition), 2006 schematically explains the Andrussow HCN manufacturing process. Purified HCN can be used for hydrocyanation, such as hydrocyanation of olefin-containing groups, or hydrocyanation of, for example, 1,3-butadiene and pentenenitrile, which can be used to make adiponitrile ("ADN"). In the BMA process, HCN is synthesized from methane and ammonia in the substantial absence of oxygen and in the presence of a platinum catalyst to produce HCN, hydrogen, nitrogen, residual ammonia, and residual methane (see, for example, Ullman's Encyclopedia of Industrial Chemistry). , Vol. A8, Weinheim 1987, pp. 161-163). Commercial operators need to conduct method safety management to dispose of the harmful properties of hydrogen cyanide. (See Maxwell et al. Assuring process safety in the transfer of hydrogen cyanide manufacturing technology, JHaz Mat 142 (2007), 677-684). In addition, HCN manufacturing process emissions from manufacturing facilities may be subject to regulations that may affect the economics of manufacturing HCN. (See Crump, Economic Impact Analysis For The Proposed Cyanide Manufacturing NESHAP, EPA, May 2000).

U.S. Patent No. 2,590,146 teaches the production of hydrogen cyanide by reacting methane, ammonia and air in the presence of a platinum-ruthenium catalyst. The hydrogen cyanide is recovered from a gas containing 23 vol.% of water vapor by contacting the gas with an aqueous solution of an acidic boric acid-polyhydroxy organic complex to dissolve and gasify hydrogen cyanide.

U.S. Patent No. 3,718,731 describes the recovery of ammonia from a gas mixture comprising hydrogen cyanide. Ammonia is recovered in the vent and two streams each having a temperature of 40 ° C to 70 ° C are returned to the absorption zone.

U.S. Patent No. 4,530,826 describes a high temperature product gas leaving the HCN reactor which has effectively utilized the heat in the waste heat boiler to a lower temperature, after which it is introduced into the ammonia absorption column. The ammonia absorption column is maintained at a relatively high temperature to prevent the hydrogen cyanide from being dissolved in the circulating sulfuric acid aqueous solution flowing downward in the column to raise the temperature of the circulating sulfuric acid aqueous solution to not less than 60 °C. Place the absorption refrigerator near the bottom of the ammonia absorption tower The position of the pores of the aqueous sulfuric acid solution is placed, and the refrigerant is produced by using an aqueous sulfuric acid solution as a driving source by using the temperature has risen.

U.S. Patent No. 7,785,399 describes a system and method for utilizing one or more waste heats of the overhead process to increase the feed temperature of the hot solvent exhaust regeneration circuit in the acid gas removal process. These methods are suitable for the selective removal of hydrogen sulfide, carbonyl sulfide (COS) and other sulfur compounds, and the removal of carbon dioxide, mercaptans, ammonia, hydrogen cyanide (HCN) and metal carbonyl compounds.

Therefore, there is a need for improved efficiency in recovering ammonia and purifying hydrogen cyanide.

In one embodiment of the present invention, there is provided a thermal integration device comprising: an ammonia absorber for contacting a crude hydrogen cyanide product comprising hydrogen cyanide, ammonia and water with an absorption solution to produce ammonia and water. An ammonia-rich stream and an absorber top stream containing hydrogen cyanide; an ammonia venting unit for separating at least a portion of the ammonia-rich stream to vaporize ammonia and water into an ammonia venturator overhead stream and a lean stream; a waste heat boiler Used to generate steam (where steam has a pressure of less than 400 kPa) by passing an ammonia vent overhead, and for partially condensing the ammonia vent overhead to a liquid stream; a scrubber For removing residual ammonia from at least a portion of the ammonia absorber overhead stream to produce an ammonia scrubber off-gas stream; an absorber for contacting a portion of the exhaust stream with dilute acidified water to produce a hydrogen cyanide absorber off-gas stream and containing cyanide a hydrogen cyanide hydrogen absorber wake; a hydrogen cyanide vent for separating at least a portion of a hydrogen cyanide absorber wake to obtain a hydrogen cyanide stream, wherein the hydrogen cyanide vent has a tube; and a tube Used to introduce steam from waste heat boilers To the discharge pipe. The length of the pipe can be less than 50 meters, preferably less than 25 meters. The apparatus may further comprise a reactor for producing a crude hydrogen cyanide product by contacting the ternary gas mixture with a catalyst. The catalyst may comprise platinum and rhodium. The apparatus may further comprise a condenser in the top of the hydrogen cyanide exhauster for partially condensing the hydrogen cyanide stream into a liquid reflux stream and a vapor stream. The apparatus may further comprise a hydrogen cyanide enricher for purifying the vapor stream to obtain a hydrogen cyanide product. The apparatus may further comprise a process to process heat exchanger for The lean stream is transferred to an ammonia rich stream. The absorption solution may comprise an aqueous solution of monoammonium hydrogen phosphate and diammonium hydrogen phosphate. The apparatus may further comprise a partial condenser for condensing the exhaust stream into a liquid stream and a vapor stream fed to the hydrogen cyanide absorber at different locations. The apparatus may further comprise an ammonia enricher for distilling the partially condensed exhauster overhead to recover ammonia.

10‧‧‧HCN Manufacturing System

12‧‧‧Reaction assembly

14‧‧‧Ammonia recovery system

16‧‧‧HCN refining system

18‧‧‧Oxygen-containing feed stream

20‧‧‧Methane-containing feed stream

22‧‧‧Ammonia feed stream

24‧‧‧ crude hydrogen cyanide product

26‧‧‧ pipeline

28‧‧‧ pipeline

30‧‧‧HCN refined feed stream

32‧‧‧ Purified HCN product

100‧‧‧Ammonia absorber

102‧‧‧Ammonia-rich phosphate stream

104‧‧‧ absorption solution

106‧‧‧Ammonia absorber feed tank

108‧‧‧Supply phosphate flow

110‧‧‧HCN/phosphate exhauster

112‧‧‧HCN/phosphate exhauster top flow

114‧‧‧Second ammonia-rich phosphate stream

120‧‧‧Ammonia exhaust

122‧‧‧Less phosphate flow

124‧‧‧ top stream

126‧‧‧Waste heat boiler

128‧‧‧Condensed liquid flow

129‧‧‧Vapor flow

130‧‧‧Ammonia enrichment

132‧‧‧ water flow

140‧‧‧Ammonia scrubber

142‧‧‧ diluted acid flow

144‧‧‧ scrubber tower top exhaust stream

146‧‧‧Washer wake

150‧‧‧HCN absorber

152‧‧‧HCN absorber wake

154‧‧‧At the top of the exhaust stream

160‧‧‧HCN exhaust

162‧‧‧HCN exhaust wake

164‧‧‧pipes

166‧‧‧HCN exhaust gas flow

167‧‧‧Liquid reflux

168‧‧‧HCN exhaust steam distillate logistics

170‧‧‧HCN enricher

172‧‧‧HCN enricher wake

174‧‧‧HCN enrichment tail sweep

176‧‧‧acid inhibitor flow

180‧‧‧heat transfer unit

1 is a simplified schematic flow diagram of an HCN manufacturing system in accordance with an embodiment of the presently claimed embodiments.

2 is a schematic flow diagram of an ammonia recovery system thermally integrated with an HCN refining system in accordance with an embodiment of the presently claimed embodiments.

The terminology used herein is for the purpose of the description of the particular embodiments The singular forms "a", "an" and "the" It should be further understood that the term "comprises" and "comprising" when used in this specification means the existence of the features, integers, steps, operations, components, and / or components, but does not exclude one The presence or addition of one or more other features, integers, steps, operations, group of elements, components, and/or groups thereof.

Languages such as "including", "comprising", "having", "comprising" or "comprising" and variations thereof are intended to be broadly construed, and are in the In addition, as long as the words "comprising", "including" or "including" are used in the context of the composition, the component group, the process or the method steps or any other expression, it should be understood that the reference to the composition, the component group, Before the process or method step or any other expression, the conjunction has the words "consisting essentially of", "consisting of" or "selected from a group consisting of" The same composition, group of elements, process or method steps or any other expression.

The corresponding structure and material of all the components or steps of the functional components in the scope of patent application The materials, acts, and equivalents are intended to include any structure, material, or action for the purpose of the combination. The description of the present invention has been presented for purposes of illustration and description, and is not intended to Many modifications and variations will be apparent to those skilled in the art without departing from the scope of the invention. The embodiments of the present invention have been chosen and described in order to best explain the principles of the invention, The invention of the example. Therefore, while the invention has been described in terms of the embodiments, it will be understood by those skilled in the art

Reference will now be made in detail to certain disclosed subject matter. The disclosure of the subject matter is to be construed as being limited by the scope of the appended claims. Rather, the invention is to cover all alternatives, modifications, and equivalents, which are included within the scope of the presently disclosed subject matter.

Hydrogen cyanide ("HCN") is manufactured on an industrial scale according to the Andrussow process or by the BMA process. In the Andrussow process, a raw material containing methane, ammonia and oxygen is reacted in the presence of a catalyst at a temperature higher than 1000 ° C to produce HCN, hydrogen, carbon monoxide, carbon dioxide, nitrogen, residual ammonia, residual methane and water. Crude hydrogen cyanide product. The catalyst is usually a wire mesh platinum/rhodium alloy or a wire mesh platinum/rhodium alloy. Other catalyst compositions can be used and include, but are not limited to, platinum group metals, platinum group metal alloys, supported platinum group metals, or supported platinum group metal alloys. Other catalyst configurations can also be used and include, but are not limited to, porous structures, screens, tablets, agglomerates, monoliths, foams, dip coatings, and washcoats. In the BMA process, a platinum catalyst, as described in U.S. Patent No. 7,429,370, incorporated herein by reference, which is incorporated herein by reference in its entirety, is incorporated herein by reference.

If you are familiar with this technology, you should understand that the source of methane is variable and can be self-renewable. (eg garbage, farms, biogas from fermentation or fossil fuels (eg natural gas), oils accompanying gases and gas hydrates), as further explained below: VN Parmon, "Source of Methane for Sustainable Development", p. 273 -284 pages, and Derouane Editor, Sustainable Strategies for the Upgrading of Natural Gas: Fundamentals, Challenges, and Opportunities (2003). In some embodiments, the methane-containing source can comprise 90 vol.% methane and can be subjected to purification to recover purified methane.

HCN is typically made by using air as an oxygen source in the Andrussow process. To improve system efficiency and reduce capital and energy costs, oxygen enriched air or pure oxygen can be preferably used, as described herein. However, when using oxygen-enriched air or pure oxygen, there are several problems that arise during the reaction and separation. In particular, the use of oxygen-enriched air or pure oxygen changes the crude hydrogen cyanide product composition. Table 1 shows an exemplary composition (expressed in vol. %) of the crude hydrogen cyanide product when the ternary gas mixture contains at least 25 vol.% oxygen.

In addition to Table 1, the crude hydrogen cyanide product has a lower oxygen concentration, preferably less than 0.5 vol.%, This is because a higher amount can trigger a shutdown event or a purge. As shown in Table 1, when the oxygen Andrussow method was used, the HCN concentration increased, the water concentration increased simultaneously, and the concentration of unreacted ammonia (i.e., residual ammonia) increased. The residual ammonia is separated from the crude hydrogen cyanide product and recovered. However, the increased water concentration in the crude hydrogen cyanide product changes the ammonia separation and recovery process. Unlike the crude hydrogen cyanide product produced by the air process, the water of the crude hydrogen cyanide product is concentrated with ammonia instead of hydrogen cyanide. In the air process, the water of the crude product is concentrated with hydrogen cyanide and thus relatively little water is present during the ammonia separation process. The use of the crude hydrogen cyanide product of the present invention requires the removal of water from the ammonia. At increased water concentrations, higher temperatures are required during the ammonia separation process and thus there is an increased corrosion potential in the ammonia separation unit. Surprisingly and unexpectedly, it has been found that when using oxygen enriched air or pure oxygen Andrussow process, the overhead flow of the ammonia ventilator has an increased temperature that can be used to generate a flow by passing the flow through the waste heat boiler. This stream reduces corrosion by the waste heat boiler and also allows heat to be recovered from the stream that is to be integrated with the HCN refining portion of the process. In particular, the present invention recovers low pressure steam, for example, steam having a pressure of less than 400 kPa, such as less than 315 kPa. All pressures are absolute unless otherwise indicated. In some embodiments, the pressure of the steam is from 180 kPa to 400 kPa, for example, 180 kPa to 380 kPa, 180 kPa to 310 kPa, or 200 kPa to 280 kPa. It should be understood that the pressure of the low pressure steam is above atmospheric pressure but below 400 kPa. Low pressure steam, although generally less preferred, is suitable for use in thermal integration processes where the ammonia vent and HCN refinement are located close together. The length of the pipe required to transport the low pressure steam of the present invention (which may be less than 50 m or less than 25 m) may be suitable for ammonia venting and HCN refining in close proximity.

As used herein, the term "air" refers to a gas mixture that is substantially identical in composition to the natural composition of a gas taken from the atmosphere at ambient altitude. In some instances, air is taken from the surrounding environment. The composition of the air includes about 78 vol.% nitrogen, about 21 vol.% oxygen, about 1 vol.% argon, and about 0.04 vol.% carbon dioxide, and a small amount of other gases.

As used herein, the term "enriched air" means a composition comprising a gas mixture that exceeds the oxygen present in the air. The composition of the oxygen-enriched air includes more than 21 vol.% oxygen, less than 78 vol.% nitrogen, less than 1 vol.% argon and less than 0.04 vol.% carbon dioxide. The oxygen-enriched air may comprise greater than 21 vol.% to 100 vol.% oxygen, for example, greater than 21 vol.% to 99.5 vol.% oxygen, greater than 21 vol.% to 95 vol.% oxygen, or greater than 21 vol.% to 80 vol.% oxygen.

The formation of HCN in the Andrussow process is usually represented by the following generalized reaction: 2CH ₄ + 2NH ₃ + 3O ₂ → 2HCN + 6H ₂ O

However, it will be appreciated that the above reaction presents a simplification of a more complex kinetic sequence in which a portion of the hydrocarbon is first oxidized to produce the thermal energy required to support the synthesis of HCN from the remaining hydrocarbons and ammonia.

During the synthesis of HCN, three basic side reactions also occur: CH ₄ +H ₂ O → CO+3H ₂

2CH ₄ +3O ₂ → 2CO+4H ₂ O

4NH ₃ +3O ₂ → 2N ₂ +6H ₂ O

In addition to the generation of a certain amount of nitrogen in the side reaction, the source of oxygen is present and additional nitrogen may be present in the crude product. Although prior art has suggested that oxygen-enriched air or pure oxygen can be used as a source of oxygen, the advantages of using oxygen-enriched air or pure oxygen have not been fully explored. When air is used as a source of oxygen, the crude hydrogen cyanide product contains components of air (e.g., 78 vol.% nitrogen) and nitrogen produced in the side reactions of ammonia and oxygen.

Since the nitrogen content in the air is large, it is advantageous to use oxygen-enriched air (which contains less nitrogen than air) in the synthesis of HCN because of the use of air as a source of oxygen in the manufacture of HCN. The synthesis is carried out in the presence of a large volume of inert gas (nitrogen), which requires the use of larger equipment in the synthesis step and the production of lower concentrations of HCN in the product gas. In addition, due to the presence of inert nitrogen, more methane needs to be burned (compared to oxygen-enriched air when air is used) to raise the temperature of the ternary gas mixture component to a temperature at which HCN synthesis can be sustained. Therefore, the use of oxygen-enriched air or pure oxygen instead of air in the manufacture of HCN can provide several benefits, including an increase in the conversion of natural gas to HCN and a simultaneous reduction in the size of the process equipment. Therefore, the use of oxygen-enriched air or pure oxygen is reduced into the synthesis process. An inert compound to reduce the size of at least one component of the reactor and downstream gas processing equipment. The use of oxygen-enriched air or pure oxygen also reduces the energy consumption required to heat the oxygen-containing feed gas to the reaction temperature.

It has been found that by providing an oxygen-rich gas rich in oxygen and by adjusting the molar ratio of ammonia to methane to a significantly high value, both the productivity and manufacturing efficiency of HCN can be significantly improved while partially maintaining stable operation. In one embodiment, the ternary gas mixture has an ammonia to oxygen molar ratio of 1.2 to 1.6, an ammonia to m molar ratio of 1 to 1.5 (eg, 1.1 to 1.45), and 1 to 1.25 (eg, 1.05 to 1.15). The molar ratio of methane to oxygen. For example, the ternary gas mixture can have an ammonia to oxygen ratio of 1.3 and a methane to oxygen molar ratio of 1.2. In another exemplary embodiment, the ternary gas mixture may have an ammonia to oxygen ratio of 1.5 and a methane to oxygen molar ratio of 1.15. The concentration of oxygen in the ternary gas mixture can vary depending on the molar ratio. It should be understood that the molar ratio is temperature and pressure compensated. Further, the ternary gas mixture comprises at least 25 vol.% oxygen, for example, at least 28 vol.% oxygen. In some embodiments, the ternary gas mixture comprises from 25 vol.% to 32 vol.% oxygen, for example, 26 vol.% to 30 vol.% oxygen.

In general, Figure 1 shows an HCN manufacturing system 10. Typically, HCN is produced in reaction assembly 12, ammonia recovery system 14, and HCN purification system 16. The reactant gases include an oxygen-containing feed stream 18, a methane-containing feed stream 20, and an ammonia-containing feed stream 22 which are introduced into the reaction assembly 12. In one aspect, the methane-containing gas can be obtained from a source containing less than 90% methane and can be purified as needed. The reaction assembly can have a mixer comprising one or more static mixers for making a mixture of ternary gases that are thoroughly mixed through the bed of the catalyst.

The crude hydrogen cyanide product 24 is withdrawn from the reaction assembly 12 and introduced into the ammonia recovery system 14. Preferably, oxygen enriched air or pure oxygen is used as the reactant gas to form the crude hydrogen cyanide product 24. A higher water concentration is produced in the crude hydrogen cyanide product 24 due to an oxygen concentration of at least 25 vol.% in the ternary gas mixture. In one embodiment, the crude hydrogen cyanide product 24 can comprise at least 25 vol.% water, such as at least 30 vol.% water. In terms of ranges, the crude hydrogen cyanide product 24 may comprise from 25 vol.% to 50 vol.% water, for example, from 30 vol.% to 40%. Vol.% water. In contrast, when air is used as the reactant gas to form the crude hydrogen cyanide product 24, the water system is present in an amount of less than 25 vol.% (e.g., 20 vol.% to 24 vol.%). The ammonia recovery system 14 operates at a higher temperature to recover ammonia recycled to the reactor assembly 12 via line 26 due to the higher water concentration in the oxygen enriched air or the exhaust gas produced in the pure oxygen process. Without being bound by theory, it is believed that the corrosion effect of ammonia on process equipment increases with increasing temperature. To prevent corrosion in the ammonia recovery system 14, the heated stream can be cooled by trapping excess heat. Some of the heat used in the ammonia recovery system 14 can be recovered using a waste heat boiler and directed to the HCN refining system 16 in vapor form via line 28. For the purposes of the present invention, the recovered steam is at a pressure of less than 400 kPa (eg, a pressure of 180 kPa to 380 kPa, 180 kPa to 310 kPa, or 200 kPa to 280 kPa) of low pressure steam. Steam is tightly integrated with the HCN refining system 16 due to the low pressure of steam and the cost and infrastructure to deliver low pressure steam.

Advantageously, the heat recovered from the ammonia recovery system can be used to refine the HCN refined feed stream 30 to a purified HCN product 32. The HCN refinery operates at a specific temperature to avoid fouling and plugging and polymerization of the equipment caused by the nitrile in the HCN refining system 16. Maintaining a suitable temperature in the HCN refining reduces or prevents autocatalytic HCN polymerization. In addition, the increased heat required to remove water from the ammonia vent column can be effectively captured and passed through the HCN purification system at various locations for reuse, thereby improving the economics of manufacturing HCN.

A waste heat boiler is typically used in reaction assembly 12 to rapidly quench the product gas to avoid decomposition of HCN. The reaction is carried out at a temperature of from 1000 ° C to 1200 ° C and the product gas needs to be rapidly quenched to less than 600 ° C, for example, less than 400 ° C or less than 300 ° C. The utility model uses another waste heat boiler to recover heat from the ammonia recovery system 14. The recovered heat, preferably in the form of low pressure steam, can be integrated with the HCN refining system 16 to reduce the energy cost of manufacturing the HCN product 32.

For the purposes of the present invention, a waste heat boiler can be used to partially condense the ammonia containing stream of ammonia recovery system 14. However, desirable thermal integration can be achieved in which the steam in line 28 is less than 400 kPa (eg, 180 kPa to 380 kPa, 180 kPa to 310 kPa, or 200). The ammonia recovery system 14 is derived from a pressure of kPa to 280 kPa). The vapor pressure can be as low as the lower pressure required for consumption in the HCN refining system 16. In one embodiment, the steam recovered from the ammonia recovery system 14 is available to drive the separation of the HCN refining system 16 and specifically to drive 40% to 60% of the energy of the hydrogen cyanide vent.

The reactant gas is supplied to the reaction assembly and, more specifically, to the mixing vessel to provide a ternary gas mixture having at least 25 vol.% oxygen. The ternary gas mixture is thoroughly mixed, and the well-mixed ternary gas used for the purposes of the present invention has a coefficient of variation (CoV) that is less than 0.1 or better than 0.1 and preferably less than 0.01 across the diameter of the catalyst bed. In terms of range, the CoV may be from 0.001 to 0.1 or more preferably from 0.001 to 0.05. Low CoV beneficially increases the productivity of the reactants converted to HCN. CoV is defined as the ratio of the standard deviation σ to the average μ . Ideally, the CoV will be as low as possible, for example less than 0.1, for example, 0.05. The HCN unit can be operated at a CoV higher than 0.1, and the CoV of 0.2 is not abnormal, that is, in the range of 0.01 to 0.2 or 0.02 to 0.15, but above 0.1, the operation cost is high and the HCN yield is low. For example, 2% to 7% lower, this is likely to cost millions of dollars per year under continuous commercial operation.

Various control systems can be used to regulate the reactant gas flow. For example, a flow meter that measures the flow rate, temperature, and pressure of the reactant gas feed stream and allows the control system to provide "instant" feedback to the operator and/or control device of pressure and temperature compensated flow rates.

Those skilled in the art should appreciate that the above-described functions and/or processes may be embodied as systems, methods or computer program products. For example, the functions and/or processes may be implemented as computer executable program instructions recorded in a computer readable storage device that, when retrieved and executed by a computer processor, controls the computing system to perform the functions of the embodiments described herein And / or process. In one embodiment, the computer system can include one or more central processing units, computer memory (eg, read-only memory, random access memory), and data storage devices (eg, a hard disk drive). Computer executable instructions can be encoded using any suitable computer programming language (eg, C++, JAVA, etc.). Therefore, the aspect of the present invention can be implemented as a completely software body. Examples (including firmware, resident software, microcode, etc.) or combinations of software and hardware aspects.

The catalyst suitable for the Andrussow process contains a Group VIII metal. The Group VIII metal includes platinum, rhodium, ruthenium, palladium, iridium or ruthenium and the catalyst can be the metal, a mixture of such metals or an alloy of two or more of the metals. In many cases of manufacturing HCN, a catalyst containing 50 wt.% (i.e., "% by weight") up to 100 wt.% platinum based on the total weight of the catalyst is employed. Metals, mixtures or alloys containing 90 wt.% platinum and 10 wt.% rhodium or 85 wt.% platinum and 15 wt.% rhodium based on the total weight of the catalyst are often preferred catalysts. The catalyst may also include one or more wire mesh, mesh or layers of other filled or oriented structures suitable for carrying out the reaction. The catalyst should be strong enough to withstand the rate of increase, and the catalyst can be used in combination with a ternary gas mixture comprising at least 25 vol.% oxygen. Therefore, the 85/15 platinum/rhodium alloy can be used on a flat catalyst support. The 90/10 platinum/rhodium alloy can be used with a wave support having an increased surface area compared to a flat catalyst support.

The composition of the crude hydrogen cyanide product can vary depending on the molar ratio of the feed stream and the reaction conditions. For the purposes of the present invention, the crude hydrogen cyanide product contains a higher concentration of water than found in HCN manufacturing processes that typically use only air. In fact, the crude hydrogen cyanide product contains HCN and may also include by-product hydrogen, methane combustion by-products (e.g., carbon dioxide, carbon monoxide, and water), nitrogen, residual methane, and residual ammonia, as shown in Table 1. The Andrussow process has potentially recoverable residual ammonia in the crude hydrogen cyanide product when practiced under optimal conditions. Since those skilled in the art are aware that the rate of HCN polymerization will increase with increasing pH, residual ammonia must be removed to avoid HCN polymerization. HCN polymerization not only represents process productivity problems, but is also an operational challenge because polymerized HCN can cause production line blockage, which can cause pressure increase and related process control problems. Typically, ammonia is separated from the crude hydrogen cyanide product in a first step of the refining process and is immediately reacted by reacting the HCN reactor effluent stream with an excess of acid (eg, H ₂ SO ₄ or H ₃ PO ₄ ) Ammonia is captured by an acid as an ammonium salt and the pH of the solution remains acidic to inhibit HCN polymerization. The formic acid and oxalic acid in the crude hydrogen cyanide product are captured in the form of formate and oxalate in an aqueous solution in an ammonia recovery system. In one embodiment, the formate can be converted to carbon dioxide and hydrogen using an electrolytic cell, as described in U.S. Patent No. 6,872,296, the disclosure of which is incorporated herein in its entirety by reference.

HCN is intended to be used as a feed stream in a hydrocyanation process such as 1,3-butadiene (sometimes referred to herein as "butadiene") and hydrocyanation of pentenenitrile to produce adiponitrile. The need for low water and high purity requires the manufacture and handling of methods that do not inhibit HCN. For the purposes of the present invention, "unsuppressed" is used herein to mean that HCN is substantially free of stable polymerization inhibitors. Such inhibitors may require, for example, hydrocyanation (for example, hydrocyanation of 1,3-butadiene and hydrocyanation of pentenenitrile to produce adiponitrile) and those skilled in the art have It is known that other conversion processes are removed before using HCN.

2 represents a flow chart of the ammonia recovery system 14 and HCN refining system 16 of the present invention. The heat system is produced in ammonia recovery 14 and transferred via line 28 to HCN refining system 16. The ammonia recovery system 14 includes an ammonia absorber 100, an HCN/phosphate vent 110, an ammonia vent 120, and an ammonia enricher 130. In reactor assembly 12, the crude hydrogen cyanide product can be cooled to a temperature greater than the dew point of the composition (e.g., greater than 150 ° C or greater than 200 ° C). The crude hydrogen cyanide product 24 is fed to the lower portion of the ammonia absorber 100 and brought into contact with an absorption solution 104 (e.g., a phosphate-lean feed stream) to produce an ammonia-rich phosphate stream 102 and an absorber overhead stream (also known as a top stream). As HCN refined feed stream 30). In one embodiment, the ammonia rich phosphate stream 102 has a reduced hydrogen cyanide concentration compared to the crude hydrogen cyanide product 24. The absorber overhead stream 30 contains hydrogen cyanide and is directed to the HCN refining system 16 to produce a purified HCN product 32, as discussed herein.

In one embodiment, the phosphate-depleted solution is stored in an ammonia absorber feed tank 106, wherein a supplemental phosphate stream 108 can be added to the phosphate-depleted solution, which is then fed as a lean phosphate feed stream 104. To the upper part of the ammonia absorber 100. The feed tank 106 is sized to accommodate all of the ammonium phosphate solution contained in the ammonia recovery system 14 thereby providing evacuation capability and process power buffering between the ammonia vent 120 and the ammonia absorber 100. The ammonia absorber feed tank 106 can be heated or cooled to maintain the temperature of the phosphate-depleted solution in the ammonia absorber 100. Absorbed at the desired temperature. The surface of the ammonia absorber feed tank 106 in contact with the ammonium phosphate solution may be comprised of 304SS. The pH of the phosphate-depleted feed stream 104 ranges from 5 to 6.1 (e.g., 5.3 to 6.0).

The phosphate-depleted feed stream 104 comprises monoammonium hydrogen phosphate (NH ₄ H ₂ PO ₄ ) having a NH ₄ ⁺ /PO ₄ ^-3 ratio ranging from 1.2 to 1.7 and diammonium hydrogen phosphate ((NH ₄ ) ₂ HPO ₄ An aqueous solution. In some embodiments, the phosphate-depleted feed stream 104 is introduced into the ammonia absorber 100 at different locations and/or at different NH ₄ ⁺ /PO ₄ ^-3 ratios, as more fully described in U.S. Patent No. 3,718,731. The entire contents and disclosure of this case are incorporated herein by reference. In one embodiment, the temperature of the phosphate-depleted feed stream 104 can range from 50 °C to 60 °C to achieve good absorption of ammonia from the crude hydrogen cyanide product 24 to the ammonia-rich phosphate stream 102.

An ammonia-rich phosphate stream 102 having a reduced hydrogen cyanide concentration is introduced into the HCN/phosphate ventilator 110 as compared to the crude hydrogen cyanide product 24, wherein the ammonia-rich phosphate stream 102 is heated to remove residual hydrogen cyanide present. . Depending on the HCN concentration, in some embodiments, the ammonia rich phosphate stream 102 can be fed directly to the ammonia vent 120 via an optional line 103.

The HCN/phosphate vent 110 produces a HCN/phosphate vent overhead stream 112 and a second ammonia rich phosphate stream 114 comprising hydrogen cyanide. The second ammonia rich phosphate stream 114 has a reduced hydrogen cyanide concentration that is less than the hydrogen cyanide concentration of the ammonia rich phosphate stream 102. In one embodiment, a particulate filter unit (not shown) may be used to remove any HCN polymer or other particulates that may be present in the second ammonia-rich phosphate stream 114, and thereby provide a substantially polymer free stream. . The second ammonia rich phosphate stream 114 is passed to an ammonia vent 120 where the ammonia and water present in the second ammonia rich phosphate stream 114 are separated to produce an ammonia vent overhead stream 124 and a phosphate depleted stream 122.

In one embodiment, the phosphate depleted stream 122 exits the ammonia vent 120 at a temperature ranging from 160 °C to 165 °C and a pressure ranging from 580 kPa to 620 kPa. The lean phosphate stream 122 is returned to the ammonia absorber feed tank 106. In one embodiment, the phosphate depleted stream 122 can be cooled by a process to process heat exchanger. For example, process to process heat exchangers The phosphate depleted stream 122 can be cooled by heating the ammonia rich phosphate stream 102 and/or the second ammonia rich phosphate stream 114 fed to the ammonia vent 120. It may be desirable to further cool the lean phosphate stream 122 to achieve the desired ammonia uptake in the ammonia absorber 100.

The heat system for the ammonia vent 120 is provided by the heat transfer unit 180. The heat transfer unit 180 can be a natural circulation tube that uses, for example, 1300 kPa of steam on the shell side of the tube. The tube can be a single pass shell and tube bundle heat exchanger. The heat supplied by unit 180 produces water vapor which forces ammonia to desorb from the ammonia rich phosphate stream 102 and/or the second ammonia rich phosphate stream 114. By this action, the ammonia rich phosphate stream 102 and/or the second ammonia rich phosphate stream 114 are converted back to the phosphate depleted solution in the bottom of the ammonia vent 120.

Acceptable materials of construction of the ammonia in the exhaust 120 includes (but not limited to) a substantially corrosion resistant metal, zirconium, DuPlex 2205 and FERRALIUM ^TM 255. At lower temperatures, 316 stainless steel is acceptable.

The ammonia vent 120 condenses ammonia and water into an overhead stream 124. The overhead stream 124 is condensed by feeding it directly into the waste heat boiler 126. Waste heat boiler 126 produces steam that is transferred to line HCN refining system 16 in line 28. By operating the ammonia ventilator 120 at elevated pressure and thus at elevated temperatures, it may be advantageous to generate a condensed liquid stream 128 and a vapor stream 129 from the overhead stream 124 by partially condensing it in, for example, a steam-generating waste heat boiler 126. Recover heat. The generated steam can be used to provide at least a portion of the necessary heat input to one or more of the other columns in the HCN refining system 16, as discussed herein.

The overhead stream 124 (which contains ammonia in the range of 5 vol.% to 20 vol.%, such as 7 vol.% to 17 vol.%) at a pressure in the range of 400 kPa to 600 kPa (eg, 550 kPa to 600 kPa) and between 140 The ammonia vent 120 is exited at a temperature in the range of °C to 175 °C (eg, 155 °C to 170 °C). Operating at a lower pressure can cause an entrainment in the phosphate overhead stream 124.

The overhead stream 124 is partially condensed in the waste heat boiler 126 and extracted in the liquid stream 128. The vapor stream 129 may also be withdrawn from the waste heat boiler 126 and condensed separately using cooling water or air. will Liquid stream 128 and condensed vapor stream 129 are combined and fed to ammonia enricher 130. In the ammonia enricher 130, ammonia is present in the overhead stream 124 of the distillation column to produce an anhydrous ammonia stream and a purgable water stream 132 that are returned to the reaction assembly via line 26. In one embodiment, ammonia enricher 130 recovers 85% to 99% ammonia and recycles the recovered ammonia in line 26 to the reaction assembly.

In one embodiment, the air/nitrogen mixture can be fed to ammonia ventor 120 and/or ammonia concentrator 130 to reduce corrosion. The air/nitrogen mixture can have less than 9 vol.% oxygen.

Returning to the HCN refined feed stream 30 from the top stream of the absorber, this stream is fed to the HCN refining system 16 to recover the purified HCN product 32. The HCN refining system 16 includes an ammonia scrubber 140, an HCN absorber 150, an HCN exhauster 160, and an HCN enricher 170. The HCN refined feed stream 30 is introduced into the lower portion of the ammonia scrubber 140 where it is scrubbed with one or more recycled dilute acid streams 142 to remove any residual traces of ammonia from the ammonia absorber overhead stream. The dilute acid stream 142 can comprise phosphoric acid or sulfuric acid. Acid can be added to the recycle dilute acid stream 142 to maintain a pH of 1.7 to 2.0 in the scrubber wake 146. The ammonia scrubber 140 is designed to remove substantially all of the free ammonia present in the ammonia absorber overhead stream 30 before the scrubber overhead gas stream 144 enters the HCN absorber 150. The ammonia scrubber overhead off-gas stream 144 should be substantially free of ammonia as free ammonia (i.e., un-neutralized ammonia) will raise the pH in the HCN refining system 16, thereby increasing the potential for HCN polymerization. The overhead ammonia scrubber off-gas stream 144 after ammonia removal comprises less than 1000 mpm (e.g., less than 500 mpm or less than 300 mpm) of ammonia. Since the rate of HCN polymerization increases with increasing pH, residual ammonia must be removed to avoid HCN polymerization. HCN polymerization not only represents process productivity problems, but is also an operational challenge because polymerized HCN can cause production line blockage, which can cause pressure increase and related process control problems.

The ammonia scrubber wake 146 can be removed from the lower portion of the scrubber 140 and returned to the ammonia absorber 100, as shown in FIG. Preferably, phosphoric acid is used in the dilute acid stream 142 to allow the scrubber wake 146 to be recycled to the ammonia absorber 100. In addition to thermal integration, the ammonia recovery system 14 is integrated with the HCN refining system by using the same acid throughout the process. For example, the use of phosphoric acid (in the form of ammonium hydrogen phosphate) in the ammonia recovery system 14 and the phosphoric acid in the HCN refining system 16 allows for recycle The flexibility of the effluent (e.g., purge) stream produces a more valuable ammonium phosphate by-product than ammonium sulphate, eliminating the need to handle sulphate and enabling the use of less expensive construction materials. In one embodiment, the two ammonia removal steps are combined into a single step. However, in other embodiments, the use of two different ammonia removal steps reduces the risk of leaving residual ammonia in the HCN reactor emissions. Operating two different ammonia removal steps with common phosphoric acid allows fresh phosphoric acid to be replenished to the second step, where stronger acid addition is most useful, and the resulting aqueous solution of ammonium phosphate and excess phosphoric acid (ie, dilute acid) can then be recycled To the first step.

The overhead gas stream 144 of the ammonia scrubber 140 contains HCN, water, carbon monoxide, nitrogen, hydrogen, carbon dioxide, and methane. In one embodiment, the overhead gas stream 144 is fed to a partial condenser where the stream is cooled to a temperature of 40 °C using cooling water to form a cooled vapor stream and a condensed liquid stream. Dilute phosphoric acid can be sprayed into the condenser and cooled vapor stream to inhibit HCN polymerization. The condensed liquid stream and the cooled vapor stream of the overhead gas stream 144 can be independently fed to the lower portion of the HCN absorber 150. HCN is recovered by absorption into dilute acidified water to produce HCN absorber wake 152. The overhead gas stream 154 is also withdrawn from the HCN absorber 150. The HCN absorber wake 152 includes acidified water and a microconcentration (eg, 2 vol.% to 8 vol.%) HCN. To remove substantially all of the HCN, a cooled HCN exhaustor wake 162 can be fed to the upper portion of the HCN absorber 150. Additionally, HCN absorber 150 can feed HCN enricher makeup sweep 174, which is the "discharge" portion of HCN enricher wake 172. This "exhaust stream" is recycled to the HCN absorber 150 to remove medium boiling impurities such as acetonitrile, propionitrile and acrylonitrile in the HCN absorber overhead gas stream 154, which may otherwise be in the HCN exhaust-enricher Accumulated in the tower.

The HCN absorber overhead gas stream 154 can contain carbon monoxide, nitrogen, hydrogen, carbon dioxide, methane, argon, and trace nitriles. The main fuel components are hydrogen and carbon monoxide with some methane. If sufficient hydrogen is present, a pressure swing absorption unit can be used to recover hydrogen. Alternatively, the HCN absorber overhead gas stream 154 can be combusted or used as a boiler fuel in a steam manufacturing boiler for recycling energy. The nitrile of HCN enricher 170 can be removed in overhead overhead stream 154 via HCN enricher purge sweep 174.

The HCN absorber wake 152 can be preheated to a temperature of 80 ° C to 100 ° C prior to introduction into the HCN vent 160 . A process to process heat exchanger can be used that integrates another stream (e.g., HCN exhaustor wake 162). The HCN vent 160 has two feed streams, a preheated HCN absorber wake 152 and a portion of the HCN richer wake 172, both fed to the upper portion of the HCN vent 160. The HCN enricher wake 172 includes a large amount (eg, from about 30% to 60% by weight) of HCN and a minor inhibitor (eg, less than 1% by weight phosphate) with the balance being water.

Heat is introduced into the lower portion of the HCN vent 160 via a steam heated heat transfer unit (eg, 164). For the purposes of the present invention, steam from the waste heat boiler 126 is used to drive the exhaust pipe 164 and it can provide at least a portion of the energy required to drive the separation in the HCN exhauster 160, preferably 40% to 60% of the energy. %. In some embodiments, additional energy may be supplied from the waste heat boiler of the reactor or from a dedicated facility. The drain 164 can use low pressure steam generated by the waste heat boiler 126. The vapor pressure in line 28 can be higher and can be as low as the lower pressure suitable for consumption in tube 164. Low pressure steam may be fed directly from waste heat boiler 126 to drain 164 via a line represented by line 28. In one embodiment, the conduit is less than 50 m long, such as less than 25 m long. This is enough for the transmission of low pressure steam.

Additionally, the manufacturing rates of the ammonia ventilator 120 and the HCN vent 160 are matched so that the steam generated from the ammonia vent 120 can be used by the HCN vent 160.

The HCN exhaustor wake 162 is discharged from the lower portion of the HCN exhauster 160 at a temperature of 110 °C to 120 °C. The HCN exhauster wake 162 is substantially free of HCN acidified water, which is cooled to a temperature between 30 ° C and 65 ° C and recycled to the HCN absorber 150. In some embodiments, the HCN exhauster wake 162 may be purged as needed.

The HCN exhaust gas stream 166 (which is an intermediate stream enriched in HCN containing a large amount of HCN and traces of water and nitrile) is passed through a HCN exhauster partial condenser using cooling water to provide Liquid reflux stream 167 (primarily water) and HCN exhaust vapor distillation stream 168. The temperature and, therefore, the purity of the HCN exhaust vapor distillate stream 168 is controlled to be consistent with the separation capabilities of the HCN enricher 170. The liquid return stream 167 is returned to the top of the HCN vent 160. The HCN vent vapor distillate stream 168 is passed to the lower portion of the HCN enricher 170. In one embodiment, the HCN vent vapor distillate stream 168 is controlled at a pressure of from 120 kPa to 140 kPa and a temperature of from 45 °C to 67 °C. The HCN vent vapor distillate stream 168 contains 70 vol.% to 99 vol.% HCN, such as 80 vol.% to 90 vol.% HCN.

The HCN vent vapor distillate stream 168 is introduced into the lower portion of the HCN enricher 170. In addition to the feed stream of HCN enricher 170, HCN exhaust vapor distillate stream 168 also provides heat to HCN enricher 170. Thus, thermal integration of ammonia recovery system 14 can be used in both HCN exhauster 160 and HCN enricher 170 via line 28. Since the HCN enricher 170 is coupled to the HCN vent 160 and does not require additional heat to distill the HCN/water mixture, the performance of the HCN enricher 170 is highly correlated with the HCN vent 160 and the HCN vent section condenser. The acid (preferably phosphoric acid) is fed to one or more locations in the upper portion of the HCN enricher 170 below the uppermost position by acid inhibitor stream 176 to further inhibit HCN polymerization. Uninhibited HCN is susceptible to autocatalytic (ie, fast/explosive) polymerization. The HCN enricher wake 172 can include HCN, water, and various organic compounds that are returned to the absorber 150 and the vent 160.

A portion of the HCN enricher wake 172 can be recycled to the HCN absorber 150 as a HCN enricher makeup sweep 174 to remove medium boiling impurities such as acetonitrile, propionitrile, and acrylonitrile, which would otherwise be available in the HCN vent. - Accumulated in the accumulator tower. Without being bound by theory, the additional heat integrated from the ammonia recovery system 14 can also be accumulated in the HCN enricher 170 by reducing the concentration of nitrile impurities in the lower portion of the HCN enricher 170. This allows a continuous or intermittent nitrile purge to be used to remove medium boiling impurities from the HCN richer wake 172. In another embodiment, the side draw (not shown) may be removed from HCN enricher 170 or HCN vent 160 at any height that provides a sufficient nitrile purge rate to prevent nitrile buildup.

The purified HCN product 32 is withdrawn at the top of the column and refluxed as needed. The purified HCN product 32 can be collected in a pump tank and the gas present in the pump tank can be drained as needed. The HCN enricher overhead stream contains substantially pure HCN and traces (preferably less than 100 ppm by weight or more preferably less than 10 ppm by weight) of water.

The distillation column of the present invention may use a packing and/or a tray, such as a bubble tray, a valve tray or a sieve tray. Blister trays, valve trays, and sieve trays are well known in the art. Valve trays are well known in the art and tray designs are selected to achieve good circulation, prevent stagnant zones and prevent polymerization and corrosion. The distillation column used herein can also incorporate an annulus separator above the top tray to minimize carryover. Tape separators typically include techniques such as reduction rates, centrifugation, dehumidifiers, screens or fillers, or combinations thereof.

It should be understood that a plurality of towers and associated equipment may be used in conjunction with the ammonia recovery system 14 and the HCN refining system 16 without departing from the scope of the invention. It should also be understood that a plurality of different designs, internal components, construction materials, flow kinetics, etc., may be utilized to construct a tower as shown graphically in the figures, as long as the towers are sufficiently repeatable or at least not to be described and claimed herein. A significantly different way can work.

In view of the foregoing, it will be apparent that the present invention is well adapted to the embodiments and the advantages of the present invention and the advantages of the present disclosure. Although the preferred embodiment of the invention has been described for purposes of the present invention, it will be understood that modifications may be

The invention can be further understood by reference to the following examples.

Example 1

A ternary gas mixture is formed by combining pure oxygen, an ammonia-containing gas, and a methane-containing gas. The ammonia to oxygen molar ratio in the ternary gas mixture is 1.3:1 and the methane to oxygen molar ratio in the ternary gas mixture is 1.2:1. A ternary gas mixture containing 27 vol.% to 29.5 vol.% oxygen was reacted in the presence of a platinum/ruthenium catalyst to form a crude hydrogen cyanide product having the composition shown in Table 2.

The crude hydrogen cyanide product is removed from the reactor and fed to an ammonia recovery system having an ammonia absorber and an ammonia vent. The crude hydrogen cyanide product is first contacted with an ammonia absorber to produce an ammonia-rich phosphate stream containing ammonia and water and an absorber overhead stream containing hydrogen cyanide. The absorber overhead stream is then separated in a hydrogen cyanide vent to further purify the hydrogen cyanide product. The ammonia rich phosphate stream is then sent to an ammonia vent to vaporize the ammonia and water into a top stream of the ventilator and a lean stream. The top of the vent column is partially condensed in a waste heat boiler to produce steam having a pressure of 180 kPa to 380 kPa. The steam is transferred to a hydrogen cyanide refining system where it provides 40% to 60% of the energy used to operate the hydrogen cyanide vent.

Comparison example A

A ternary gas mixture is formed by combining air, ammonia, and methane-containing gas. The ternary gas mixture contains less than 25 vol.% oxygen. The separation process as in Example 1 was used except that no steam was recovered. The steam is not recovered because the water content of the crude hydrogen cyanide product is too low to render the steam recovery cost effective.

14‧‧‧Ammonia recovery system

16‧‧‧HCN refining system

24‧‧‧ crude hydrogen cyanide product

26‧‧‧ pipeline

28‧‧‧ pipeline

30‧‧‧HCN refined feed stream

32‧‧‧ Purified HCN product

100‧‧‧Ammonia absorber

102‧‧‧Ammonia-rich phosphate stream

104‧‧‧ absorption solution

106‧‧‧Ammonia absorber feed tank

108‧‧‧Supply phosphate flow

110‧‧‧HCN/phosphate exhauster

112‧‧‧HCN/phosphate exhauster top flow

114‧‧‧Second ammonia-rich phosphate stream

120‧‧‧Ammonia exhaust

122‧‧‧Less phosphate flow

124‧‧‧ top stream

126‧‧‧Waste heat boiler

128‧‧‧Condensed liquid flow

129‧‧‧Vapor flow

130‧‧‧Ammonia enrichment

132‧‧‧ water flow

140‧‧‧Ammonia scrubber

142‧‧‧ diluted acid flow

144‧‧‧ scrubber tower top exhaust stream

146‧‧‧Washer wake

150‧‧‧HCN absorber

152‧‧‧HCN absorber wake

154‧‧‧At the top of the exhaust stream

160‧‧‧HCN exhaust

162‧‧‧HCN exhaust wake

164‧‧‧pipes

166‧‧‧HCN exhaust gas flow

167‧‧‧Liquid reflux

168‧‧‧HCN exhaust steam distillate logistics

170‧‧‧HCN enricher

172‧‧‧HCN enricher wake

174‧‧‧HCN enrichment tail sweep

176‧‧‧acid inhibitor flow

180‧‧‧heat transfer unit

Claims (11)

A heat integration device comprising: an ammonia absorber (100) for contacting a crude hydrogen cyanide product comprising hydrogen cyanide, ammonia and water with an absorption solution to produce an ammonia-rich stream containing ammonia and water and containing An ammonia absorber overhead stream of hydrogen cyanide; an ammonia vent (120) for separating at least a portion of the ammonia-rich stream to vaporize ammonia and water into an ammonia venturator overhead stream and a lean stream; a waste heat boiler (126) for generating steam by passing the exhauster overhead, wherein the steam has a pressure of less than 400 kPa; and for partially condensing the ammonia vent overhead to a liquid stream; An ammonia scrubber (140) for removing residual ammonia from at least a portion of the ammonia absorber overhead stream to produce an exhaust stream; a hydrogen cyanide absorber (150) for contacting a portion of the exhaust stream with dilute acidified water To generate a hydrogen cyanide absorber off-gas stream and a hydrogen cyanide absorber wake containing hydrogen cyanide; a hydrogen cyanide vent (160) for separating at least a portion of the hydrogen cyanide absorber wake to obtain cyanide a hydrogen stream, wherein the hydrogen cyanide vent (160) has a drain (164); and a conduit (28) for Guiding the steam from the waste heat boiler (126) to the discharge pipe (164). The device of claim 1 wherein the conduit has a length of less than 50 meters. The device of claim 1 wherein the conduit has a length of less than 25 meters. The apparatus of claim 1 further comprising a reactor for producing the crude hydrogen cyanide product by contacting the ternary gas mixture with a catalyst. The device of claim 4, wherein the catalyst comprises platinum and rhodium. The apparatus of claim 1 further comprising a condenser located in the top of the hydrogen cyanide venting column for partially condensing the hydrogen cyanide stream into a liquid reflux stream and a vapor stream. The apparatus of claim 6 further comprising a hydrogen cyanide enricher for purifying the vapor stream to obtain a hydrogen cyanide product. The apparatus of claim 1 further comprising a process to process heat exchanger for transferring heat from the lean stream to the ammonia rich stream. The device of claim 1, wherein the absorbing solution comprises an aqueous solution of monoammonium hydrogen phosphate and diammonium hydrogen phosphate. The apparatus of claim 1 further comprising a partial condenser for condensing the exhaust stream into a liquid stream and a vapor stream fed to the hydrogen cyanide absorber at different locations. The apparatus of claim 1 further comprising an ammonia enricher for distilling the partially condensed exhauster overhead to recover ammonia.