五、新型說明： 【新型所屬之技術領域】 玻璃 本創作是有㈣-種玻璃，特別是有_ —種有色 【先前技術】 純今之社會巾，人們叙的應用朗之製品 了建染之玻璃幕牆及窗戶外，姑 ^ 片又電子產0口外殼、燈具、桌面或其他裝飾之物品上。 =域人Γ常為了各式各樣之原因，而需要使用有顏色 2璃。為了使破璃產生顏色，習知之有色玻璃 幾種。 M 種為於玻璃之氧化狀態或還原狀態時，以約 Γ,Τ進/溫熱炼玻璃，再加入適當之金屬氧化 :發色或還原發色。另-種方法為將含 氧古π之螭次入含有硝酸銀或氧化銅之約攝氏400 #藉以使玻璃釋出鋰離子，並吸收銀離 Ϊ 错以形成有色玻璃。然而，習知之有色玻 璃：ίΐ'!高溫之環境，因此，習知之有色玻璃不僅 耗費此源且&成環境溫度升高。 【新型内容】 有4^於上述習知技藝之問題，本創作之其中一目的 M435455 就疋在提供一種有色玻璃，藉以降低能源損耗及節能 保。 緣疋，為達上述目的，依本創作之有色玻璃至少包 含經喷砂處理之玻璃基板及具有顏色之顯色層，甚至可 更包含透明之保護硬化層。其中，玻璃基板至少具有一 粗糙面，使得本創作之有色玻璃可例如藉由此粗糙面， 藉以降低顯色層之光反射率。詳言之，本創作之有色玻 璃可例如藉由砂材對玻璃基板之表面進行喷砂處理使 得玻璃基板之表面成為粗糙面。換言之，本創作之有色 玻璃可例如藉由砂材撞擊玻璃基板之表面，使得玻璃基 板之表面形成凹凸不平之粗糙面。其中，砂材可例如為 氧化鋁、金鋼砂、玻璃珠、塑膠噴砂粒、碳化矽、鍅砂、 鍅鋁砂、陶瓷珠、鋼礫、鋼珠、不銹鋼或其他適合之砂 材。而且，玻璃基板之材質可例如為青玻璃、白玻璃、 強力玻璃或其他適合之玻璃。 此外，具有顏色之顯色層例如覆蓋於玻璃基板之粗 縫面上，使件本創作之有色玻璃顯示顯色層之顏色。其 中，本創作之有色玻璃之顯色層之材質可例如為有色金 屬、有色金屬氧化物、有色金屬氮化物或其他適合之材 質。舉例而言，本創作之有色玻璃之顯色層之材質可例 ，為銅、鋁、銀、鎳、鉻、锆、鈦、氧化銅、氧化鋁、 氧化銀、氧化鎳、氧化鉻、氧化錯、氧化鈦、氮化鋁、 氮化鉻、氮化鍅、氮化鈦或其他適合之材質。而且，本 創作之有色玻璃之顯色層之顏色可例如為橘色、白色或 M435455 之顯色 其他所需之顏色。除此之外，本創作之有色玻璃 層之厚度可例如為約30奈米至55〇〇奈米之間。V. New description: [New technology field] The glass creation is made of (4)-glass, especially _-----[Previous technology] Pure-day social towel, the application of the product of Langzhi Outside the glass curtain wall and the window, the piece is electronically produced on a 0-port casing, lamp, table top or other decorative items. = Domain people often need to use color 2 glass for a variety of reasons. In order to make the glass produce color, there are several kinds of colored glass. When the M species is in the oxidized state or the reduced state of the glass, the glass is entangled/warmed by heat, and then added with appropriate metal oxidation: color development or reduction of color development. Another method is to pass the oxygen-containing ancient π into the silver nitrate or copper oxide containing about 400 ° C to release the lithium ions from the glass and absorb the silver to form a colored glass. However, the conventional colored glass: ίΐ'! The environment of high temperature, therefore, the conventional colored glass not only consumes this source but also increases the ambient temperature. [New content] There is a problem with the above-mentioned conventional skills. One of the objectives of this creation is that M435455 is now providing a colored glass to reduce energy consumption and energy conservation. For the above purposes, the colored glass according to the present invention includes at least a blasted glass substrate and a color chromogenic layer, and may even further comprise a transparent protective hard layer. Wherein, the glass substrate has at least a rough surface, so that the colored glass of the present invention can reduce the light reflectivity of the color developing layer, for example, by the rough surface. In detail, the colored glass of the present invention can be sandblasted on the surface of the glass substrate by sand, for example, so that the surface of the glass substrate becomes a rough surface. In other words, the inventive colored glass can strike the surface of the glass substrate by, for example, sand, so that the surface of the glass substrate forms an uneven surface. Among them, the sand material may be, for example, alumina, gold steel sand, glass beads, plastic grit blast, strontium carbide, strontium sand, strontium alumina, ceramic beads, steel boulder, steel balls, stainless steel or other suitable sand materials. Moreover, the material of the glass substrate may be, for example, cyan glass, white glass, strong glass or other suitable glass. Further, the color-developing color layer covers, for example, the rough surface of the glass substrate, so that the colored glass of the present invention displays the color of the color-developing layer. The material of the chromogenic layer of the colored glass of the present invention may be, for example, a colored metal, a colored metal oxide, a non-ferrous metal nitride or other suitable material. For example, the material of the color developing layer of the colored glass of the present invention can be, for example, copper, aluminum, silver, nickel, chromium, zirconium, titanium, copper oxide, aluminum oxide, silver oxide, nickel oxide, chromium oxide, or oxidized. , titanium oxide, aluminum nitride, chromium nitride, tantalum nitride, titanium nitride or other suitable materials. Moreover, the color of the chromogenic layer of the inventive colored glass can be, for example, orange, white or M435455. In addition, the thickness of the colored glass layer of the present invention may be, for example, between about 30 nanometers and 55 nanometers.
另外，本創作之有色玻璃之保護硬化層例如覆蓋於 顯色層上，藉以保護本創作之有色玻璃之顯色層。此外， 為了加強保護顯色層之效果，保護硬化層可例如為較為 堅固之保護硬化層。而且’為了能於保護硬化層之方向 看到本創作之有色玻璃之顏色，㈣硬化相如為透明 之保護硬化層。因此，保護硬化層之材f可例如為氧化 矽（Si〇x)、氧化鋁（Α10χ)或其他適合之材質。除此之外， 本創作之有色玻璃之保護硬化層之厚度可例如為約10 奈米至約1000奈米之間。 除此之外，本創作之有色玻璃之顯色層可例如係藉 由濺鍍沉積法、蒸鍍沉積法、化學沉積法（Chemical Vap二In addition, the protective hardened layer of the colored glass of the present invention covers, for example, the color developing layer, thereby protecting the color developing layer of the colored glass of the present invention. Further, in order to enhance the effect of protecting the color developing layer, the protective hardened layer may be, for example, a relatively strong protective hardened layer. Moreover, in order to see the color of the colored glass of the present invention in the direction of protecting the hardened layer, (4) the hardened phase is a transparent protective hardened layer. Therefore, the material f of the protective hardened layer may be, for example, yttrium oxide (Si〇x), alumina (Α10χ) or other suitable material. In addition, the thickness of the protective hardened layer of the inventive colored glass may be, for example, between about 10 nm and about 1000 nm. In addition, the chromogenic layer of the inventive colored glass can be, for example, by sputtering deposition, vapor deposition, or chemical deposition (Chemical Vap II).
DeP〇Siti〇n，CVD)、電漿化學氣相沉積法（Plasma enhanced Chemical Vapor Deposition，PECVD)或塗佈 法，藉以覆蓋於基板之粗糙面上。而且，本創作之有色 玻璃之保護硬化層亦可例如藉由濺鍍沉積法、蒸鍍沉積 法、化學沉積法（CVD)、電漿化學氣相沉積法（pEC VD) 或塗佈法，藉以覆蓋於顯色層上。 承上所述，本創作之有色玻璃，其可具有一或多個 下述優點： (1)藉由例如噴砂處理以粗糙化玻璃基板之表面， 藉以降低本創作之有色玻璃之顯色層之光反射率，進而 使得本創作之有色玻璃之顏色更加精確。 M435455 、（2)藉由例如沉積或塗佈之方式取代高溫燒製之方 ^以=成本創作之有色玻璃’藉以降低成本，並且降低 能源損耗’進而達到節能環保之效果。 【實施方式】 以下將參照相關圖式’說明依本創作之有色玻璃之 實施例，為使便於理解，了述實施例中之相同元件係以 相同之符號標示來說明。 請參閱第1圖’第丨圖係為本創作之有色玻璃之結 構剖面示意圖’第2圖係為本創作之有色玻璃中經過^ 糙化處理之基板之剖面示意圖。如第1圖至第2圖所示， 本創作之有色玻璃100至少包含經噴砂處理之玻璃基板 110及具有顏色之顯色層120,甚至更可包含透明之保護 硬化層130。其中，玻璃基板11〇例如至少具有一粗糙 面in ’使得本創作之有色玻璃丨⑻可例如藉由此粗輪 面111以降低顯色層120之光反射率。而且，玻 11〇之材質可例如為青玻璃、白玻璃、強力玻璃或：他 適合之玻璃。 詳言之，玻璃基板110之粗糙面U1可例如於玻璃 基板110之至少一表面上進行喷砂處理，藉以使經喷砂 處理後之表面成為粗糙面lu。舉例而言，喷砂處理可 例如藉由-砂材撞擊玻璃基板11G之表面，藉以使玻璃 基板110之表面具有粗糙度。其中，此砂材可例如為氧 化鋁、金鋼砂、玻璃珠、塑膠喷砂粒、碳化矽、錯砂、 M435455 锆鋁砂、陶瓷珠、鋼礫、鋼珠、不銹鋼或其他適合之砂 材。此外，經噴砂處理後之玻璃基板110之粗輪面lu 之平均表面粗糙度（Ra)可例如為約0.7微米（μιη)至約4 5 微米之間，較佳為約0.8微米至約3微米之間，更佳為 約0.9微米至約2微米之間。 此外，本創作之有色玻璃1〇〇之玻璃基板11()上具 有顯色層120。其中’此顯色層12〇位於玻璃基板u〇 之粗糙面111上，且顯色層12〇具有顏色，使得本創作 之有色玻璃100顯示顯色層120之顏色。其中，顯色層 120之顏色可例如為顯色層12〇之材質本身之顏色。此 外，顯色層120可例如完全覆蓋於玻璃基板11〇之粗糙 面ill上。而且，本創作之有色玻璃100之顯色層12〇 可例如藉由濺鍍沉積法、蒸鍍沉積法、化學沉積法 (Chemical Vapor Deposition，CVD)、電漿化學氣相沉積法 (Plasma enhanced Chemical Vapor Depositi〇n，pECVD)或 塗佈法，藉以形成於玻璃基板11〇之粗糙面lu上。另 外，顯色層120之厚度可例如介於約3〇奈米（nm)至約 5500奈米之間，較佳之厚度可例如介於約1〇〇奈米至約 2000奈米之間，更佳之厚度可例如介於約35〇奈米至約 1500奈米之間°除此之外’顯色層120之材質可例如為 銅、鋁、銀、鎳、鉻 '鍅、鈦、氧化銅、氧化鋁、氧化 銀、氧化鎳、氧化鉻、氧化鍅、氧化鈦、氮化鋁、氮化 絡、氮化m鈦或其他適合之材f ’使得本創作之 有色玻璃⑽藉由不同之顯色層12G之材質，藉以顯示 不同之顏色。其中，其他適合之材質包括有色金屬、有 7 M435455 色金屬氧化物、有色金屬氮化物或其他之材質。舉例而 言，當顯色層120之材質為銅或可顯示橘色之材質時， 本創作之有色玻璃100之顏色為橘色。此外，當顯色層 之材質為銘、銀或可顯示白色之材質時，本創作之 有色玻璃100之顏色為白色。 因此，本創作之有色玻璃100之一特點在於，藉由 玻璃基板11〇之粗糙面m，藉以降低顯色層12〇之光 反射率，進而使得本創作之有色玻璃100之顏色更加精 確。 為了證實本創作之有色玻璃100確實可藉由玻璃基 板110之粗糙面111，藉以降低顯色層12〇之光反射率， 申叫人更提出實驗數據以佐證其效果。請接續參閱第4 圖，第4圖係為本創作之有色玻璃之顯色層之光反射率 =示意圖。如第1圖與第4圖所示，以顯色層12〇之材 貝係銀（Ag)為例，當有色玻璃之玻璃基板11〇未經喷砂 處理，即形成顯色層120於玻璃基板11()上，換言之， 亦即有色玻璃之玻璃基板Η 〇之表面較為光滑之情形 下，顯色層120之平均反射率約為94.84%。而當有色玻 璃之玻璃基板110經喷砂處理後，再形成顯色層12〇於 玻璃基板110上，換言之，此玻璃基板11〇亦即具有粗 糙面ill之本創作之有色玻璃100之玻璃基板11〇。於 此情形下，顯色層120之平均反射率約為72 59%。因此， 本創作之有色玻璃1〇〇確實可藉由玻璃基板11〇之粗糙 面111 ’藉以降低顯色層120之光反射率。 M435455 另外，如第1圖所示，本創作之有色玻璃1〇〇之保 ，硬化層13()位於顯色層12G上，藉以保護顯色層12〇。 砰言之，保護硬化層130可例如全面覆蓋於顯色層12〇 士’藉以保護全部之顯色層12()於大氣下或其^環境 中’不致發生氧化現线化學變化現象。或者 亦可例如依實際情況之需求，而僅覆蓋於= ^顯色層12G上。此外，保護硬化層13()可例如係藉由 歲鍍沉積法、驗沉積法、化學沉積法（c g =氣二目ECVD)或塗佈法以形成 水 二：之外，因保護硬㈣13〇係用以保護顯色声 ’因此為了加強保護之效果，保護硬: ==堅固之材質。並且，，了能夠從保= 層130之方向亦可看出本創作之有色玻璃 保:化層13。可例如為透明層。因此 =， :質質可:氧~)、氧—DeP〇Siti〇n, CVD), Plasma Enhanced Chemical Vapor Deposition (PECVD) or coating method to cover the rough surface of the substrate. Moreover, the protective hardened layer of the inventive colored glass can also be used, for example, by sputtering deposition, vapor deposition, chemical deposition (CVD), plasma chemical vapor deposition (pEC VD) or coating. Covered on the chromogenic layer. As described above, the inventive colored glass may have one or more of the following advantages: (1) roughening the surface of the glass substrate by, for example, sandblasting, thereby reducing the coloring layer of the inventive colored glass. The light reflectivity, in turn, makes the color of the colored glass of this creation more precise. M435455, (2) replaces the high-temperature firing by, for example, deposition or coating, to reduce the cost and reduce energy consumption, thereby achieving the effect of energy saving and environmental protection. [Embodiment] Hereinafter, embodiments of the colored glass according to the present invention will be described with reference to the related drawings. For the sake of easy understanding, the same elements in the embodiments are denoted by the same reference numerals. Please refer to Fig. 1. The figure is a schematic cross-sectional view of the structure of the colored glass of the present invention. Fig. 2 is a schematic cross-sectional view of the substrate which has been roughened in the colored glass of the present invention. As shown in Figs. 1 to 2, the inventive colored glass 100 includes at least a sandblasted glass substrate 110 and a colored color developing layer 120, and may even further comprise a transparent protective hardened layer 130. Here, the glass substrate 11 has, for example, at least a rough surface in so that the inventive colored glass crucible (8) can be used to reduce the light reflectance of the color developing layer 120, for example, by the coarse wheel surface 111. Moreover, the material of the glass can be, for example, cyan glass, white glass, strong glass or: glass suitable for him. In detail, the rough surface U1 of the glass substrate 110 can be sandblasted, for example, on at least one surface of the glass substrate 110, whereby the surface after the blasting is roughened. For example, the blasting treatment can strike the surface of the glass substrate 11G by, for example, a sand material, whereby the surface of the glass substrate 110 has roughness. Among them, the sand material may be, for example, alumina, gold steel sand, glass beads, plastic sandblasted grain, tantalum carbide, sand, M435455 zirconium aluminum sand, ceramic beads, steel gravel, steel balls, stainless steel or other suitable sand materials. Further, the average surface roughness (Ra) of the coarse tread lu of the blasted glass substrate 110 may be, for example, between about 0.7 micrometers (μm) and about 45 micrometers, preferably about 0.8 micrometers to about 3 micrometers. More preferably, it is between about 0.9 microns and about 2 microns. Further, the glass substrate 11 () of the colored glass of the present invention has a color developing layer 120 thereon. Wherein the color developing layer 12 is located on the rough surface 111 of the glass substrate u, and the color developing layer 12 is colored, so that the colored glass 100 of the present invention displays the color of the color developing layer 120. The color of the color developing layer 120 may be, for example, the color of the material of the color developing layer 12〇. Further, the color developing layer 120 may, for example, completely cover the rough surface ill of the glass substrate 11A. Moreover, the chromogenic layer 12 of the inventive colored glass 100 can be, for example, by sputtering deposition, vapor deposition, chemical vapor deposition (CVD), plasma chemical vapor deposition (Plasma enhanced Chemical). Vapor Depositi〇n, pECVD) or coating method is formed on the rough surface lu of the glass substrate 11〇. In addition, the thickness of the color developing layer 120 may be, for example, between about 3 nanometers (nm) and about 5,500 nanometers, and preferably the thickness may be, for example, between about 1 nanometer and about 2000 nanometers. Preferably, the thickness can be between about 35 nanometers and about 1500 nanometers. In addition, the material of the color developing layer 120 can be, for example, copper, aluminum, silver, nickel, chromium, tantalum, titanium, copper oxide, Alumina, silver oxide, nickel oxide, chromium oxide, cerium oxide, titanium oxide, aluminum nitride, nitrided nitride, nitrided titanium or other suitable material f' makes the colored glass (10) of this creation different color development The material of layer 12G, in order to display different colors. Among other suitable materials include non-ferrous metals, 7 M435455 color metal oxides, non-ferrous metal nitrides or other materials. For example, when the material of the color developing layer 120 is copper or an orange color material, the color of the colored glass 100 of the present invention is orange. In addition, when the material of the color developing layer is made of inscription, silver or white, the color of the colored glass 100 of the present invention is white. Therefore, one of the characteristics of the colored glass 100 of the present invention is that the light reflectance of the color developing layer 12 is lowered by the rough surface m of the glass substrate 11, thereby making the color of the colored glass 100 of the present invention more precise. In order to confirm that the colored glass 100 of the present invention can be reduced by the rough surface 111 of the glass substrate 110, thereby reducing the light reflectance of the color developing layer 12, the applicant has further proposed experimental data to prove its effect. Please refer to Figure 4 below. Figure 4 is the light reflectance of the color-developing layer of the created glass. As shown in Fig. 1 and Fig. 4, taking the silver (Ag) of the color developing layer 12 as an example, when the glass substrate 11 of the colored glass is not sandblasted, the color developing layer 120 is formed on the glass. In the case where the substrate 11 (), in other words, the surface of the glass substrate of the colored glass is relatively smooth, the average reflectance of the color developing layer 120 is about 94.84%. When the glass substrate 110 of the colored glass is sandblasted, the color developing layer 12 is formed on the glass substrate 110. In other words, the glass substrate 11 is a glass substrate of the original colored glass 100 having a rough surface ill. 11〇. In this case, the average reflectance of the color developing layer 120 is about 72 59%. Therefore, the colored glass of the present invention can surely reduce the light reflectance of the color developing layer 120 by the rough surface 111' of the glass substrate 11. M435455 In addition, as shown in Fig. 1, the colored glass of the present invention is protected, and the hardened layer 13 () is placed on the color developing layer 12G to protect the color developing layer 12A. In other words, the protective hardened layer 130 may, for example, be entirely covered by the color-developing layer 12's to protect all of the color-developing layer 12() from the atmosphere or its environment from occurring. Alternatively, it may be covered only on the = chromogenic layer 12G, for example, according to the actual situation. In addition, the protective hardened layer 13 () may be formed by, for example, a galvanic deposition method, a deposition method, a chemical deposition method (cg = gas binocular ECVD) or a coating method to form water two: in addition to protecting the hard (four) 13 〇 It is used to protect the color of the sound. Therefore, in order to enhance the effect of protection, protect the hard: == sturdy material. Further, it is also possible to see the colored glass layer of the present creation from the direction of the guarantee layer 130. It can be, for example, a transparent layer. Therefore =, : quality can be: oxygen ~), oxygen -
，更進一步而言，X可例如二。 此外氧化鋁(Α10χ)之，可例如為有理 A X可例如為整數’而且x亦可例如為3 ;而二， 化層130之厚声力卜保濩硬 Η έ- ^ ν ^例如為、力10奈米至約1000夺_之 間，且較佳之保護硬化層13G之厚度可例 ^之 至約500奈米之間，而更佳之 ·、’、、、·勺20不米 例如為約30奈米至約11〇奈米之”間。“30之厚度可 因此，本創作之有色玻璃1〇〇之另— 為本創作之有色玻璃100 y ;，因 之』色層120與保護硬化層 9 料妁455 係例如藉由沉積法，藉以分別形成於基板110之粗 糙=111上與顯色層12〇上。由於例如為濺鍍之沉積法 =酿度為約攝氏40度至約攝氏11〇度之間，而習知之高 溫燒製之溫度為約攝氏400度以上，所以本創作之有色 玻璃100無需高溫燒製之處理，進而降低能源損耗以節 能環保。 ，請接續㈣第3 ®，第3圖係為本創作之有色玻璃 之製程流程圖。如第丨圖與第3圖所示，本創作之有色 玻璃1GG之製程首先進行步驟21()。提供基板，其中基 板可例如為玻縣板11G，且此玻璃基板UG之材質可 例如為青玻璃、白玻璃、強力玻璃或其他適合之玻璃。 =’進行粗經化步驟22〇以粗链化玻璃基板ιι〇之至 =表面’使付此表面成為粗糙®⑴，藉以降低顯色 之光反射率。其中，粗糙化步驟可例如係藉 ，玻璃餘UG進行切處理，藉峰糙化玻璃基板 此喷砂處理可例如藉由砂材撞 璃土板110之表面，藉以達到粗輪化玻璃基板11〇 t面之目的。其t，砂材可例如為氧化鋁、金鋼砂、 玻璃珠、《喷砂粒、碳切、#砂、純砂、陶究珠、 鋼礫、鋼珠、不銹鋼或其他適合之砂材。 23。Γ太=于第一形成步驟23〇。於此第-形成步驟 HI I二 色玻璃1〇0之製程形成具有顏色之 CL:玻璃基板…之粗趟面111上，使得本創 乍之有色玻璃100顯示顯色们20之顏色。其中，第一 形成步驟230可例如孫茲丰 戶120於㈣任一沉積法，藉以形成顯色 層120於玻璃基板11〇之粗輪面ι 。 法可例如為濺鍍沉積法、暮 中此/儿積 漿化學氣相沉積法或塗佈法法、化學沉積法、電 可例如係銅、心=此：’顯色層120之材質 如卜 錄銘'、錯、鈦、氧化銅、氣化 銘：Γ:二氧鉻、氧化錯、氧化鈦、氮化 頌色# 120之^声°、11化鈦或其他適合之材f。而且， Π120之厚度可例如為約30奈米至約55〇〇夺米之 間，且更佳之尸声可奈未至約2000奈米之 間。 厗度了例如為約350奈米至約测奈米之 接著，可選擇性進行第二形成 成步驟240係形成保護硬化声 0此弟一形 以保護顯色層120於大氣“ 層120上，藉 化現象或化學變化現象。不致發生氧 例如藉由任一沉積法，以 第一形成步驟240可 層120上。而且，此。^保護硬化層於顯色 鑛沉積法、化學沉積法、為賤鍍沉積法、蒸 質’藉以強化保護之功能。亦質戈:例=為堅硬之物 硬化層⑽之方向看出了保護 護硬化層130之材質可例 之顏色。因此，保 (Al〇x)或其他適合之材質。為乳化石夕⑽X)、氧化鋁 外，保護硬化層130之厚声可、X可例如為有理數。另 子度了例如為約10奈米至約1000 以製造橘色玻璃為例，首 著使璃基板110,4 表面進㈣砂處理^ 針對玻璃基板110 ^ 、隹u丄、、 稭以粗糙化玻璃基板110之表面： 進而形成玻璃基板11〇 ^ pD lL , 之粗糙面Ul，且X可例如為3/2 亦即此砂材可例如為三氧 n 虱化一鋁（八丨2〇3)。其中，粗糙3Further, X may be, for example, two. In addition, the alumina (Α10χ) may, for example, be a rational AX, for example, an integer ' and x may also be, for example, 3; and 2, the thick layer of the layer 130 is 声 濩 濩 ^ ^ - ^ ν ^ Between 10 nanometers and about 1000 liters, and preferably the thickness of the protective hardened layer 13G can be between about 500 nanometers, and more preferably, ',,,,,,,,,,,,,,, From nanometer to about 11 nanometers. "The thickness of 30 can be made, the color of the glass of this creation is the other one - the colored glass of the creation is 100 y;, because of the color layer 120 and the protective hardened layer The material 455 is formed on the rough layer=111 of the substrate 110 and the color developing layer 12, for example, by a deposition method. Since the deposition method is, for example, sputtering, the brewing degree is between about 40 degrees Celsius and about 11 degrees Celsius, and the conventional high temperature firing temperature is about 400 degrees Celsius or more, the colored glass 100 of the present invention does not need to be burnt at a high temperature. The treatment of the system, thereby reducing energy consumption to save energy and environmental protection. , please continue (4) 3 ®, 3 is the process flow chart of the created colored glass. As shown in the third and third figures, the process of the inventive colored glass 1GG first proceeds to step 21 (). The substrate is provided, wherein the substrate can be, for example, a glass plate 11G, and the material of the glass substrate UG can be, for example, cyan glass, white glass, strong glass or other suitable glass. = 'The roughening step 22 is performed to thicken the glass substrate to the surface = to make the surface rough® (1), thereby reducing the light reflectance of the color developed. Wherein, the roughening step can be performed, for example, by cutting the glass UG, and roughening the glass substrate by the peak. The sandblasting treatment can be performed on the surface of the glass plate 110 by sand, for example, to obtain the coarse-rounded glass substrate. The purpose of t face. The sand material may be, for example, alumina, gold steel sand, glass beads, sandblasted grain, carbon cut, #砂, pure sand, ceramic beads, steel gravel, steel ball, stainless steel or other suitable sand material. twenty three. Γ too = in the first formation step 23 〇. In this first-forming step, the process of HI I dichroic glass 1〇0 is formed on the rough surface 111 of the color CL:glass substrate, so that the colored glass 100 of the present invention displays the colors of the color-developing colors 20. The first forming step 230 may be performed, for example, by the Sunzun household 120 in any of the deposition methods, thereby forming the color developing layer 120 on the rough surface ι of the glass substrate 11 . The method can be, for example, a sputtering deposition method, a sputum chemical vapor deposition method or a coating method, a chemical deposition method, an electric current such as copper, a heart=this: the material of the color developing layer 120 such as Bu Luming ', wrong, titanium, copper oxide, gasification Ming: Γ: chrome oxide, oxidation fault, titanium oxide, tantalum # color # 120 ^ ^ ° °, 11 titanium or other suitable material f. Moreover, the thickness of the crucible 120 can be, for example, between about 30 nanometers and about 55 millimeters of rice, and more preferably between about 2,000 nanometers. The second formation step 240 is selectively performed to form a protective hardening sound to protect the color developing layer 120 on the atmosphere layer 120, for example, from about 350 nm to about nanometer. Borrowing phenomenon or chemical change phenomenon. Oxygen is not generated, for example, by any deposition method, in the first forming step 240 on the layer 120. Moreover, the protective hardened layer is formed by a chromogenic ore deposit method, a chemical deposition method,贱plating deposition method, steaming property 'strengthen the function of strengthening protection. Also quality: Example = for the hardened hardened layer (10) direction, the material of the protective hard layer 130 can be seen as a color. Therefore, Bao (Al〇 x) or other suitable material. For the emulsified stone (10) X), alumina, the thick layer of the protective hardened layer 130, X may be, for example, a rational number. The degree of, for example, about 10 nm to about 1000 to produce orange For example, in the case of the colored glass, the surface of the glass substrate 110, 4 is first subjected to (four) sand treatment. For the glass substrate 110^, 隹u丄, and straw, the surface of the glass substrate 110 is roughened: a glass substrate 11〇PD lL is formed. Rough surface Ul, and X can be, for example, 3/2, that is, the sand material For example, a trioxide of aluminum lice n (eight Shu 2〇3). Wherein, rough 3
袓^^ 粗糖度队)例如為〇.9微米（，）。此外 粗糙面111可例如降低顯色層12〇之光反射率。 +者’於此粗縫面U1上藉由例如濺鍍之沉積方 式，猎以形成材質例如為銅之顯色層120。其中，沉積 之溫度例如為約攝氏40度至約攝氏110度之間，沉積之 時間例如為約3分鐘至2 〇分鐘之間，沉積之壓力例如為 約1微托（mtorr)至10微托之間。此外，顯色層！之厚 度可例如為約30奈米至約55〇〇奈米之間。最後，藉由 例如濺鍍之沉積方式，藉以形成保護硬化層130於色 層1上。其中，保護硬化層130可例如為透明硬化層。 此外’保護硬化層13〇之材質可例如為氧化矽（Si〇x)或氧 化鋁（A10x)。而且，保護硬化層13〇之厚度可例如為約 10奈米至約1000奈米之間。因此，不論從玻璃基板11〇 之方向或從保護硬化層130之方向觀看此有色玻璃 100，此有色玻璃丨00皆係例如顯示橘色。所以，此有色 玻璃100為一橘色玻璃。 12 M435455 總言之，本創作之有色玻璃⑽例如藉由噴 以粗糖化玻璃基板no之表面，藉以降低本創作 玻璃_之顯色層m之光反射率’進而使得本創= 有色玻璃H)0之顏色更加精確。此夕卜，本創作之 璃1〇〇例如藉由沉積之方式取代高溫燒製之方式 降低成本，並且降低能源損耗，進而達節能環保^ 果。 以上所述僅為舉例性，而非為限制性者。任 ，本創作之精神與範鳴，而對其進行之等效修改或變 更，均應包含於後附之申請專利範圍中。 【圖式簡單說明】 第1圖係、為本創作之有色玻璃之結構剖面示意圖。 第2圖係為本創作之有色玻璃中經過粗糖化處理之 基板之剖面示意圖。 第3圖係為本創作有色玻璃之製程流程圖。 第4圖#、為本創作之有色玻璃之顯色層之光反射率 之不意圖。 【主要元件符號說明】 10G I有色玻璃 110 :玻璃基板 m :粗糙面 13 M435455 120 :顯色層 130 :保護硬化層 210 :提供基板 220 :進行粗糙化步驟 230 :進行第一形成步驟 240 :進行第二形成步驟 14袓^^ The crude sugar team) is, for example, 〇.9 μm (,). Further, the rough surface 111 can, for example, lower the light reflectance of the color developing layer 12A. The + color is formed on the rough surface U1 by, for example, sputtering deposition to form a color developing layer 120 of a material such as copper. Wherein, the deposition temperature is, for example, between about 40 degrees Celsius and about 110 degrees Celsius, and the deposition time is, for example, between about 3 minutes and 2 minutes, and the deposition pressure is, for example, about 1 microtorr (mtorr) to 10 microtorr. between. In addition, the color layer! The thickness can be, for example, between about 30 nanometers and about 55 nanometers. Finally, a protective hardened layer 130 is formed on the color layer 1 by, for example, sputtering deposition. The protective hardened layer 130 may be, for example, a transparent hardened layer. Further, the material of the protective hardened layer 13 can be, for example, yttrium oxide (Si〇x) or aluminum oxide (A10x). Moreover, the thickness of the protective hardened layer 13 can be, for example, between about 10 nm and about 1000 nm. Therefore, the colored glass 00 is displayed, for example, in an orange color, regardless of whether the colored glass 100 is viewed from the direction of the glass substrate 11 or from the direction of the protective hardened layer 130. Therefore, the colored glass 100 is an orange glass. 12 M435455 In summary, the colored glass (10) of the present invention is reduced by, for example, by spraying the surface of the glass substrate of the coarsely saccharified glass substrate, thereby reducing the light reflectance of the coloring layer m of the glass of the present invention, thereby making the original glass = colored glass H) The color of 0 is more precise. In addition, the glass of the creation, for example, replaces the high-temperature firing by means of deposition to reduce costs and reduce energy consumption, thereby achieving energy saving and environmental protection. The above is intended to be illustrative only and not limiting. Ren, the spirit of this creation and Fan Ming, and equivalent modifications or changes to it, should be included in the scope of the patent application attached. [Simple description of the drawing] Figure 1 is a schematic cross-sectional view of the structure of the colored glass. Fig. 2 is a schematic cross-sectional view of a substrate subjected to rough saccharification in the colored glass of the present invention. Figure 3 is a flow chart of the process for creating colored glass. Fig. 4 is a schematic view of the light reflectance of the color-developing layer of the colored glass of the present invention. [Description of main component symbols] 10G I colored glass 110: glass substrate m: rough surface 13 M435455 120: color developing layer 130: protective hardening layer 210: providing substrate 220: roughening step 230: performing first forming step 240: performing Second forming step 14