M355120 五、新型說明： 【新型所屬之技術領域】 本創作係有關於一種水錦基材之吸附體（三 •曰將水綿經脫色、製粉等前 特別 試片，用以檢測1吸附4 佼丹肝」塗衣成吸附 【先前技術】㈣續製成各類產品。 目前由於工業發達，以致污水排放量 歇重影響到水庫、河川及溪、、ώ 而會 >污水進行處理。 、4料生悲’因此必需對 -般習知污水處理方法係利 之方法分離出水中之污毕铷# a 乳化還原 作同眸… 其具有反應快速之優點， 问時亦產生以下缺點： > 1.不具備生物工法之自主吸附淨化效能且會 加淨化所需之化學物質，對 θ /yj、、 7貝對％境造成二次污染。 2 :法有效利用大量繁殖之藻類，加工轉化 害物質之具高附加經濟價值之產物。 因水綿具有生物吸附之被動 不需要消耗能量，且不產生：該吸附過程 台匕人/于杂而是透過細胞壁官 b團與重金屬離子和微量難 瓦取丄 難降解有機物分子之間的凡得 瓦爾力、靜電作用力和毛細作 仵 程，其吸㈣理如下：作用所進行的物理吸附過 1.細胞外吸附機制： ^物具有分泌諸如糖蛋白、脂多糖等細胞外 的月b力，而這些物質普遍含有一 3有疋數量能夠吸附重金屬 M355120 的負電荷基團。 2·細胞表面吸附機制： 生物吸附劑的細胞壁是包在細胞表面最外層的、 韌而略帶彈性的薄膜’其主要成分包括聚糖、蛋 脂，酸鹽等。從分子架構層面來看，當生物吸附劑處 .於環境污染暴露時，重金屬離子和微量難降解有機物分 子遇到的第一層生物屏障就是細胞壁，而細胞壁中含= 眾多能夠與之進行配位絡合的官能團，例如，羧基、羥 基、羰基、胺基、磷基、硫酸酯基..等等，此種細 面吸附機制為靜電吸附。 而水綿藻體之比表面積與孔隙結構決定了去除吸附 質之大小及類型，利用上述之作用力，將重金屬吸附於表 面及孔隙中，一般比表面積愈大’其吸附量愈大，故可將 其加工製成各類吸收污染物產品，但由於水綿來源不同 且生產過程如脫色、製粉步驟之誤差，造成其吸附能力 鲁不同，為檢測該水綿藻粉體吸附能力，必須以定量之水 綿藻粉體配合定量之水體’以準確檢測水綿藻粉體之吸 附能力。 【新型内容】 爰此，故本創作提供一種水綿基材之吸附體（三）， 包括有： 包裝盒，其内部設有容置空間；吸附試片，係置入 於收納盒之容置空間内，其係以水綿藻粉體為基材壓製 而成之片體。 4 M355120 上述該水綿藻粉體係將水綿經由清洗、風乾、脫色、 «周pH值、過;慮再清洗、再風乾、磨碎及筛網過筛等製 程所製成。 上述該吸附試片遇水分子會分解成微細的水綿議粉 體。 上述該包裝盒係為防潮之盒體。 上述該水綿藻粉體之粒徑在〇59〇mm〜〇1〇4_之 間。 ® 本創作具有下列優點： 1.本創作係為定量之片體之水綿吸附試片，其係可 投=定量之π水中，用以檢測水錦經由脫色、製粉步驟 之前處理後之吸附能力，以利後續製成各類吸收污染物 產品。 2·本創作中已吸附飽和含有污染物之水綿藻粉體， 其後續可以再經由脫附處理而再生重覆使用，故可減少 鲁廢棄物之產生，而不會有二次拋棄污染之環保問題。 3.本創作特製防潮之收納盒可避免吸附試片遇空氣 中水分而潮解，影響使用時之吸附功效，達到保存該吸 附试片之功效。 〆4. f創作預先將水綿藻粉體以定量製成，檢測時不 需每次量測水綿藻粉體之使用份量。 【實施方式】 首先，請參閱第一圖所示，本創作係為一種水输 材之吸附體（三），其包括有包裝盒（1 )及吸附試片（2 ) 土， 5 M355120 其中： 包裳盒（1)，係為防潮之盒體，其内部設有容置空 間（11)。 吸附試片（2 )’係置入於包裝盒（1 )之容置空間 (11 )，其係以水綿藻粉體（21)為基材壓製而成之片體， 該水綿藻粉體（21 )遇水分子會分解成微細的水綿藻粉 體（21 )’其水綿藻粉體（2丨）會吸附其中所含之重金屬 等污染物（B)。本實施例中，水綿藻粉體（21 )之粒徑在 0. 590mm〜〇. 1〇4_之間。 清參閱第二圖，係為本實施例之吸附試片（2 )製作 流程圖，該製作吸附試片（2)之水綿藻粉體（21)其主 要之來源係為採擷自水庫、河川或溪流中所存在新鮮之 水，：藻藻體，經由清洗、風乾、脫色、調邱值、過濾、 再清洗、再風乾、磨碎及篩網過篩等過程所製成〔請同 時參閱第一圖〕。 其步驟如下： A.清洗：係將採擷自水庫、河川或溪流中新鮮之水 綿藻體’經過清水反覆清洗乾淨，徹底去除雜質後 以二段蒸鶴水沖洗。 B.風乾：然後將清洗過後之水綿藻體置於室溫下， 經過兩天自然風乾後予以備用。 c.脫色.將亞氯酸鈉（NaC1〇2)經過調配成為〇指 之濃度’以醋酸溶液為緩衝溶液，以藻重ig藻量對_ 溶劑之比例，將水綿藻加入濃度^ 〇4M之亞氣酸鈉 6 M355120 a 1，^溶液中’經過邱值測定確認水耗藻體係 处於@夂„衣境中’❿且在室溫Μ。。的條件了，攪拌 至2为釦，使水綿藻體可以均勻分散且與溶 :，'當靜置：至3小時後，可產生完全脫色之反應1 八脫色後，澡體產生許多空隙，而該藻體之比表面積盘 孔隙結構可以增加所吸附重金屬等污染物⑻之容納； 間。 、六 周PH值：以清水沖洗至接近中性，並以驗性溶 化鈉（NaOH)溶液浸潰過夜 :夜調至，7〔酸驗中和成中性〕，再將藻體以〇 化钿 nntn、、办、、士^ ^ E.過f .遽去先前步驟之溶液，取出水綿藻藻體。 、再巧洗.再次以二段蒸餾水清洗，以去除表面所 殘留之溶劑，並經由n H枯、Βι丨—Λ Α 工左由ΡΗ值測定碡認殘留之溶劑已完全去 除。 G.再風乾.水綿藻體置於室溫下自然風乾，並於風 • c過程中經適當整理及裁剪簾體，得到呈現純白片狀之 〜Η·磨碎··將純白片狀之水料體置於磨碎機中，以 巧轉速磨碎後取出，即得粉狀之水綿藻粉體（21)基材。 I · 4 4過自$ ‘利用篩網篩選粒徑範圍在G.州丽〜 .4_之間的水綿藻粉體（21)〔即藻粉〕。 •J·製作吸Κ片（2 ):將水轉藻粉體⑺）壓製成 片體之吸附試片（2 )。 自此成為由水綿藻類所製成之吸附試片（2)，該吸 7 M355120 附試片⑴具有溶於水，並具有吸 之特性。 里|屬等〉可染物（B) 使用時，如第三圖及第四圖所示 水庫内之水體（C)盛裝定量於燒杯、，將湖泊、河川或 片數之水綿吸附試片（2 )置於該焊D )内，並取適當 .之吸附試片（2 )遇水體（C)中之水八（D )内，该片體 解成水綿藻粉體（21)並 7 /7子（A)即迅速溶 靜置適^年Η德仏物（β)。將燒杯（D) 靜置週田時間後，檢測水體 个、〜 量，即可得知該定量之水_粉⑴含 吸附速度’亦可利用相同檢测條件檢：此力及 水綿藻粉體⑺），以得知不同生產抵A 批次之 (21)之吸附能力，以利後續：：：水綿藻粉體 士 β θ表风各類吸收污举必j r r、 產品或調整製程參數。 叹6杀物（Β) 另’吸附試片υ备罢 容置介門f⑴出） 防潮之包裝盒（1)之 及雜； 内，該防潮包裝盒⑴可阻隔外界水氣 影響檢測結果。 ⑺吸收空氣中之水氣而潮解， (21 Γ, 1 ^ ^述已吸附飽和含有重金屬之水綿藻粉體 i卢再經由過濾、處理，以進行脫附處理， 共题理方式如同法地 再生處理〔因其並非本創作之申 iV 述〕，藉以減少廢棄物之產生，而避免有 二次抛棄污染之環保問題。 避免有 【圖式簡單說明】 第圖係為本創作之整體構造示意圖。 8 M355120 第二圖係為本創作之吸附試片製作流程示意圖。 第三圖係為本創作之吸附試片置於盛裝水體之燒杯 内用以檢測吸附能力示意圖。 第四圖係為本創作之吸附試片溶解於盛裝水體之燒 杯内並吸附污染物示意圖。 【主要元件符號說明】 (1) 包裝盒 (11) 容置空間 (2) 吸附試片 (21) 水綿藻粉體 (A) 水分子 (B) 污染物 (C) 水體 (D) 燒杯M355120 V. New description: [New technical field] This creation department is about the adsorption of a water-based substrate (three 曰 曰 水 水 水 脱 脱 脱 脱 脱 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别 特别"Dangan" is coated into adsorption [prior art] (4) Continued to produce various types of products. At present, due to the industrial development, the discharge of sewage will affect the reservoirs, rivers and streams, and the sewage will be treated. It is necessary to isolate the effluent from the water by the method of the conventional sewage treatment method. # a emulsification reduction is the same as the 眸... It has the advantage of rapid reaction, and also has the following disadvantages when asked: > 1. It does not have the chemical adsorption and purification efficiency of the biotechnology method and will increase the chemical substances required for purification. It will cause secondary pollution to θ / yj, and 7 shells to the % environment. 2 : The method effectively utilizes the mass-produced algae and processes the transformed harmful substances. A product with high added economic value. Because the sponge has bio-adsorption, it does not need to consume energy, and does not produce: the adsorption process is caused by the human body/heterogeneous but through the cell wall b group and heavy metals. The van der Waals force, the electrostatic force and the capillary process between the sub- and the micro-hard-to-degraded organic molecules are as follows: the physical adsorption by the action 1. The extracellular adsorption mechanism: It has a monthly b-force that secretes extracellular substances such as glycoproteins, lipopolysaccharides, etc., and these substances generally contain a number of negatively charged groups capable of adsorbing heavy metal M355120. 2. Cell surface adsorption mechanism: The cell wall of the biosorbent is a package The outermost layer of the cell surface, the tough and slightly elastic film's main components include glycans, egg fats, acid salts, etc. From the molecular structure level, when the biosorbent is exposed to environmental pollution, heavy metal ions The first layer of biological barrier encountered with micro-refractory organic molecules is the cell wall, and the cell wall contains a number of functional groups capable of coordinating with it, for example, carboxyl, hydroxyl, carbonyl, amine, phosphorus, sulfate Base.. etc., the fine surface adsorption mechanism is electrostatic adsorption. The specific surface area and pore structure of the water worms determine the size and type of adsorbate removal. Using the above-mentioned force, the heavy metal is adsorbed on the surface and the pores, and the larger the specific surface area is, the larger the adsorption amount is, so it can be processed into various types of absorbing pollutant products, but the source of the water wadding is different and the production process For example, the error of the decolorization and milling steps causes the adsorption capacity to be different. In order to detect the adsorption capacity of the A. sphaeroides powder, it is necessary to accurately quantify the adsorption of the Hydrilla verticillata powder with a quantitative amount of water-maize algae powder combined with a quantitative water body. [New content] Therefore, this creation provides a absorbing body (3) of a water-waist substrate, including: a packaging box having an accommodating space therein; and an adsorption test piece which is placed in the storage box In the accommodating space, it is a sheet made of water-smoky algae powder as a substrate. 4 M355120 The above-mentioned water ash algae powder system cleans, air-drys, decolorizes, «circumference pH value, over; It is made by processes such as cleaning, air drying, grinding and screening. The above-mentioned adsorption test piece is decomposed into fine water-like powder by water molecules. The above package is a moisture-proof case. The particle size of the above-mentioned water-weed algae powder is between 〇59〇mm~〇1〇4_. ® This creation has the following advantages: 1. This creation is a quantitative piece of water-smoke adsorption test piece, which can be used to measure the quantitative π water, to detect the adsorption capacity of water hydrazine after treatment through decolorization and milling steps. In order to facilitate the subsequent production of various types of pollutant absorption products. 2. In this creation, the saturated water-sweet algae powder containing contaminants has been adsorbed, and the subsequent can be re-used and reused by desorption treatment, so that the generation of Lu waste can be reduced without the second disposal of pollution. Environmental issues. 3. The special moisture-proof storage box of this creation can avoid the deliquescence of the adsorption test piece in the air, affecting the adsorption effect during use, and achieving the effect of preserving the adsorption test piece. 〆4. f Creation pre-measures the water-maize algae powder in a quantitative manner. It is not necessary to measure the amount of the water-weed algae powder used each time. [Embodiment] First, as shown in the first figure, the creation is a sorbent body (3) of a water-transporting material, which comprises a packaging box (1) and an adsorption test piece (2) soil, 5 M355120 wherein: The bag box (1) is a moisture-proof box body with an accommodation space (11) inside. The adsorption test piece (2)' is placed in the accommodating space (11) of the packaging box (1), which is a sheet obtained by pressing the Hydrilla verticilla powder (21) as a substrate, and the kelp powder The body (21) will decompose into water molecules (21), and its watery algae powder (2丨) will adsorb pollutants such as heavy metals contained in it (B). In the present embodiment, the particle size of the A. sinensis powder (21) is between 0.55 mm and 〇. Referring to the second figure, it is a flow chart of the adsorption test piece (2) of the present embodiment, and the main source of the water-mist algae powder (21) for preparing the adsorption test piece (2) is the pick-and-sink from the reservoir and the river. Or fresh water in the stream: algae, produced by washing, air drying, bleaching, adjusting the value of the seed, filtering, re-cleaning, air drying, grinding and screening. [Please also refer to A picture]. The steps are as follows: A. Cleaning: The fresh water from the reservoir, river or stream is cleaned by clear water, thoroughly removed, and rinsed with two sections of steamed crane water. B. Air drying: The washed water wormwood body is then placed at room temperature, and after two days of natural air drying, it is reserved. c. Decolorization. Sodium chlorite (NaC1〇2) is formulated into the concentration of 〇 finger. Using acetic acid solution as the buffer solution, the ratio of algae weight ig algae to _ solvent is used to add Cyclosporium to concentration ^ 〇 4M Sodium sulfite 6 M355120 a 1, ^ in the solution 'after the determination of the water value of the algae system in the @夂„ clothing environment '❿ and at room temperature Μ. Conditions, stir to 2 for the buckle, The water worms can be uniformly dispersed and dissolved: 'When left to stand: after 3 hours, a complete decolorization reaction can be produced. 1 After decolorization, the bath body produces a lot of voids, and the specific surface area of the algae disk pore structure Can increase the absorption of heavy metals such as adsorbed (8); between, six weeks PH value: rinse with water to near neutral, and impregnated with sodium chloride (NaOH) solution overnight: night adjustment, 7 [acid test Neutralization into neutral], and then the algae body to 〇 钿 钿 nntn,, do, and ^ ^ E. over f. 遽 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前 先前Two sections of distilled water are washed to remove the solvent remaining on the surface, and are measured by n H, Βι丨-Λ The residual solvent has been completely removed. G. Re-drying. The water ash algae body is naturally air-dried at room temperature, and is properly finished and cut in the wind and c process to obtain a pure white sheet. Grinding · The pure white flake water body is placed in the grinder, and then ground and crushed at a good speed to obtain the powdery water ash algae powder (21) substrate. I · 4 4 over $ 'Using a sieve to screen the water particle size range of G. sylvestris ~ .4_ between the water ash algae powder (21) [namely algae powder]. J. Making a sucking piece (2): water to algae powder The body (7) is pressed into a sheet of the adsorption test piece (2). Since then, it has been made into an adsorption test piece (2) made of A. sylvestris, and the sample 7 (1) is soluble in water and has a suction. Characteristics. Li|Yes, etc.> Dyed matter (B) When used, as shown in the third and fourth figures, the water body (C) in the reservoir is packed in a beaker, and the water, cotton, or the number of pieces of water is adsorbed. The sheet (2) is placed in the welding D), and the appropriate adsorption test piece (2) is in the water (C) in the water body (C), and the sheet is decomposed into the water-weed algae powder (21) and 7 /7 sub (A) is rapidly dissolved After the beaker (D) is placed in Zhoutian time, the amount of water is measured, and the amount of water is determined. The amount of water (1) containing the adsorption rate can also be used. Test condition test: This force and the water-maize algae powder (7)), in order to know the adsorption capacity of different production (A) to the batch A, in order to facilitate the follow-up::: Aphis sinensis powder body β θ wind Class absorption of dirt must be jrr, product or adjustment process parameters. Sigh 6 killings (Β) Another 'adsorption test piece preparation to replace the door f (1) out) moisture-proof packaging box (1) and miscellaneous; inside, the moisture The packaging box (1) can block the outside water and moisture from affecting the test results. (7) Absorbing moisture in the air and deliquescent, (21 Γ, 1 ^ ^ said that it has been adsorbed and saturated with heavy metal, and it is filtered and treated for desorption treatment. Recycling treatment (because it is not the application of this creation iV), in order to reduce the generation of waste, and to avoid the environmental problem of secondary abandonment of pollution. Avoid [simplified description of the diagram] The diagram is the overall structure of the creation 8 M355120 The second picture is a schematic diagram of the production process of the adsorption test piece for this creation. The third picture is a schematic diagram of the adsorption test piece of the creation in the beaker containing the water body for detecting the adsorption capacity. Schematic diagram of the adsorption test piece dissolved in the beaker containing the water body and adsorbing the contaminant. [Description of main components] (1) Packing box (11) accommodating space (2) Adsorption test piece (21) Hydrangea powder (A) Water molecules (B) pollutants (C) water bodies (D) beakers