M262645 八、新型說明： 【新型所屬之技術領域】 本創作係關於一種化學發光裝置，更定言之，係關 於一種可延長發光時間之化學發光裝置。 【先前技術】 化學發光原理，係藉由二種化學組成進行反應，產 生的反應熱係激發螢光體（Fluorophor)發出對應反應熱 之波長的色光。由於該些化學組成一接觸即發生反應直 到消耗殆盡，反應才結束，因此須將該些化學組成分別 放置，使用時再將化學組成混合反應。 目前已有數種利用上述化學發光原理之化學發光裝 置例如，美國專利第3,576, 987號揭露一種藉由二種液 體混合產生化學反應之發光裝置，化學發光裝置包括一 可撓性中空管體及一内置於可撓性中空管體之玻璃管， 其中，中空管體内含有第一溶液而玻璃管内含有第二溶 液。當使用者彎曲此中空管體時，内部的玻璃管將破裂 而釋出第二溶液，使之與第一溶液混合。另外，亦有將 該二種溶液暫時分離且存在於同一封閉容器中的二個隔 室，可藉由破碎、撕裂、旋轉或鬆夾方式消除中間分離 壁或利用反應產生的壓力衝破隔室界面等，使該些反應 物混合而發生反應。此類形之設計請參考美國專利第 3, 749, 620，3, 539, 794，3, 893, 938，3, 808, 414， 4, 061，910，3, 149, 943，3, 576, 987 及 5, 067, 051 號。該 5 I:\Patent\shih，chao-shu\000001TWN\Official^型專利申請書 Finai d〇c M262645 些揭露内容在此係以參考方式併入本案。 上述分隔放置該些反應物的結構不外乎包括分別設 置於内外部之二個隔室，為達到其中一反應物在欲使用 時容易釋出之目的，位於内部之隔室必須能輕易地由使 用者壓破、撕裂、轉開或鬆夾，以釋出内部隔室所含之 溶液。然而，上述混合二種反應物之結構設計在化學發 光完畢後，即因無利用價值而被丟棄，不僅浪費物質資 源’同時反應生成物及溶解該些反應物之溶劑也會造成 環境上的污染。 另一方面，利用化學發光原理可製得輕巧方便攜帶 使用的發光裝置，但是由於填充於該些結構之反應物的 劑量有限、使用壽命不長、且無法控制反應之終止，因 此使得化學發光的應用受到限制。 因此，亟需要一種可延長發光時間而又可達再利用 之環保目的的化學發光裝置結構。 【新型内容】 本創作之一目的在於提出一種延長發光時間之化學 發光裝置結構，其中溶解反應物之溶劑可重複利用。 本創作之另一目的在於提出一種延長發光時間之化 學發光裝置結構，其中藉由反應物可以適時適量補充以 延長其使用壽命。 為達上述及其他目的，本創作之化學發光裝置結構 包括一結構主體及至少一補充單元。結構主體包括一中 6 1:\?&1611偏1丨11，(^〇-81111\〇〇〇〇〇1了\\^〇01(^1\新型專利申請書 Final d〇c M262645 空管體及一置於該中空管體之隔室。至少一補充單元係 貼附在中空管體之外表面上。 中空管體含有一第一反應溶液’弟一反應〉谷液包括 溶於適當溶劑之酯類及螢光材料。螢光材料包括主要負 責發光的螢光體及加強顏色亮度之增光劑。 隔室内含有一第二反應溶液，其劑量大於其參與全 部發光反應之化學計量。釋放隔室内之溶液的方式包括 破碎、撕裂、旋轉或鬆夾方式或利用反應產生的壓力衝 破隔室界面的方式破壞隔室之物理詰構。 鲁 至少一補充單元貼附在中空管體之外表面上，包括 沿者中空管體之長度方向或兩端處。補充早元的位置分 佈可排列成預定圖案，以搭配外觀造型設計。補充單元 · 含有第一反應溶液，或另外配製第一反應溶液中反應物 溶於對應溶劑所得之補充反應溶液。補充單元的材料可 · 與中空管體的材料相同或不同。 每一個補充單元的劑量可以相同或不同，但是全部鲁 補充單元之反應物數量加上原中空管體所含第一反應溶 液之反應物數量不超過與隔室内第二反應溶液之反應物 反應的化學計量。 本創作之發光裝置可使發光時間較一般市售之榮光 棒或其他利用化學發光原理之發光裝置長，在實際使用 上更加方便。另外，本創作之化學發光裝置加設補充單 元，可在重複使用結構主體之下達延長發光時間之效； 相較於習知用完即丟的發光裝置，本創作之化學發光裝 7 IMatenMiih’chao-shiAOOOOOlTWNXOfficialXff型專利申請書 Finai.d〇c M262645 置亦收環境保護之實。 【實施方式】 本發明之化學發光裝置的發光原理係利用適當溶劍 之酯類與過氧化氫反應，提供螢光體能量，激發原處於 安定基態的螢光體變成不安定的電子激發態。當處於不 安定激發態的螢光體回復成基態時，就把多餘的能量以 光的形式放出，再藉由選擇使用不同顏色的螢光體，發 出所要的色光。 以下係以苯基草酸酯為酯類為例，說明化學發光之 反應機構： OH 0 0—0 I I yC— 0' 、〇 H2〇2 0—0 1 I + 螢光體-，螢光體* +2C〇2 ~、b 反應所發出的光色係視所使用的螢光體而定。例 如’利用Rhodamine B可發出紅色光，利用Rhodamine 6G 可發出橘色光，利用9，10-Diphenylantracene可發出藍色 光’利用 Rubrene 可發出黃色光 ， 9，10_Bis(phenylethynyl)_antracene，可發出綠色光等。 為研究藉由補充反應物與延長發光時間之間的關 係’分別針對黃光發光裝置與粉紅色光發光裝置進行實 8 I:\Patent\shih，chao-shu\0〇〇〇〇iTWN\Official^型專利申請書 Final.doc M262645 驗〆及實驗二。 實驗一： 取一市售之黃色螢光棒，使其發光完畢後’取出其 反應後之廢液直接混入尚未反應的黃色螢光棒原液中’ 再加入如表一所示數量之過氧化氫，觀察不同混合比例 下的發光情形。實驗結果如表一所示。 表 -、混合不同出你丨普色瑩光樁廢液的發光時間 -^ ------ |-----1 | Γ----------- 廢液體積 原液體積 相對廢液 發光時間 相對發光 (mL) (mL) 體積％ (小時）j 時間％ —-— 0 10 0 12 100 —--1 9 10 11 92 2 8 20 5 42 3 7 30 4 33 4 6 40 4 33 5 5 50 4 33 6 4 60 4 33 —----- 7 3 70 4 33 8 2 80 3 25 .-— — 8. 5 1.5 85 2 17 10 0 100 0 0 由上表可知：當不混入任何廢液時，螢光液的發光時 間 < 達100% ’而混入1 〇%的廢液後’發光時間減為原來 的92%，當混入20%以上時，發光時間快速遞減，廢液組 成從30%到70%時，發光時間維持在原來的三分之一，廢 液組成超過70%時，發光時間又快速遞減到零。 -aten滅⑽ao-shu__T 職 〇ffid崎麵 9 M262645 在提供夠量過氧化氫之下，不同混合組成的溶液中 有效酯類的量並不一樣。隨著混入廢液比例的提高，有 效酯類的量遞減，因此相對的發光時間也就變短了。由 本實驗的結果可知：雖然混入少量的（<ιο%)黃色螢光棒 廢液之發光時間無法如原始反應溶液之發光時間一樣 長，但可以回收再利用黃色螢光棒廢液。 實驗二 取一市售之粉紅色螢光棒，使其發光完畢後，取出 其反應後之廢液直接混入尚未反應的粉紅色螢光棒原液 中，廢液與原液之體積比請參考表二所示之反應溶液（三 氯苯基草酸酯溶液）。觀察各個混合液的發光情形。實驗 結果如表二所示。 表二、混合不同比例粉紅色螢光棒廢液的發光時間 廢液體積 原液體積 相對廢液 發光時間 相對發光 (mL) (mL) 體積％ (小時） 時間％ 0 5 0 12 100 1 4 20 12 100 1. 5 3. 5 30 12 100 2 3 40 12 100 2. 5 2. 5 50 11. 5 96 3 2 60 4. 5 38 3. 5 1. 5 70 4_ 5 38 4 1 80 3. 5 29 4. 5 0. 5 90 3 25 5 0 100 0 0 I:\Patent\shih，chao-shu\000001 TWN\Official\_jf型專利申請書 Final.doc 10 M262645 士 可看出，當廢液體積占到40%之時，發光的 S仍1原t的螢光棒原液—樣，當廢液體積超過5〇% 办 ^光守間快速縮短。從螢光棒廢液的再利用角度 "此入廢液體積到50%仍是可以接受的，但前提是要 加入等量的_反應物。 々第圖為加入兩種廢液對發光時間影響的比較，由 1可看出來··纟5⑽之前，加入粉紅色螢光棒廢液對 ^光守門的細短影響較小，但當廢液體積超過議之後， 兩條曲線很接近。 义由上述實驗可知，藉由補充適當反應物即可達到延 長毛光時間之目的，故本發明另提供一種可隨時補充反 應物以使化料光反應時間增長的化學發光裝置。 第一圖係為本創作之化學發光裝置結構的剖面示意 圖。化學發光裝置結構1包括一結構主體10及至少一補充 單元20。 結構主體10包括一中空管體11及一置於該中空管體 之隔室12。然而，在此所稱之”管體”不限於剖面為矩形 之結構，只要其可容置該隔室12者，皆屬本創作之範圍。 中空管體11係由透明或半透明且具撓性之材料，例 如聚烯烴或其共聚物做成。其製得方法例如包括射出成 型，擠型，模製等方法。 中空官體11含有一第一反應溶液，第一反應溶液佔 中空管體内容積不超過60%，較佳不超過40%，最佳不 超過30%。第一反應溶液包括溶於適當溶劑之酯類及螢 I:\Patent\shih，chao-shu\000001 丁\\^[\〇伍(^1\新型專利申請書 Rnal.doc 11 M262645 光材料。螢光材料包括主要負責發光的螢光體 (Fluorophor ) 及加強顏色亮度之增光劑 (sensitizer)。螢光體係根據所欲發出之顏色而選擇 之，例如白光螢光體、黃光螢光體、綠光螢光體及藍光 螢光體等。增光劑係視所使用的螢光體種類搭配使用， 例如黃光螢光體發出的光帶有黃綠色，為使透過中空管 體11展現出來的顏色鮮豔亮麗，可添加黃色增光劑。增 光劑包括例如，但是不限於，Rhodamine B (紅色光）、 Rhodamine 6G (橘色光）、9，10-Diphenylantracene (藍色鲁 光）、Rubrene(黃色光）、9，l〇-Bis(phenylethynyl)-antracene (綠色光）等。酯類係選自草酸酯，例如雙（2,4-二硝基 苯基）草酸酯（DNPO)及雙(2,4,6-氯苯基）草酸酯等，_ 係視所欲發出之色光而對應選擇對應之。 隔室12内含有一第二反應溶液，第二反應溶液可充 · 滿或不充滿隔室12。第二反應溶液的反應物劑量大於其 參與全部發光反應之化學計量。第二反應溶液主要包括鲁 溶於適當溶劑之過氧化氫。釋放隔室内之溶液的方式包 括破碎、撕裂、旋轉或鬆夾或利用反應產生的壓力衝破 隔室界面的方式破壞隔室的物理結構。 上述之溶劑包括鄰苯二曱酸二丁酯，第三丁酯及其 組合。 為使隔室12得以破碎、撕裂、旋轉或鬆夾或利用反 應產生的壓力衝破隔室界面之方式破壞其物理結構而使 第二反應溶液釋出，隔室12之材質需能配合該些方式釋 ΓνΡ^ηΜΙήΙ^Ι^ο-ΑιΛΟΟΟΟΟΙΤλνΝ^Μα新型專利申請書 Final doc 12 M262645 出第二反應溶液，並且能夠保存第二反應溶液而不致使 第二反應溶液在尚未使用時提早釋出。 舉例而g，若隔室12係以破碎方式釋出第二反應， 則隔至12可以由例如玻璃等易碎材料做成。若隔室a可 以旋轉撕裂方式破壞其物理結構，則隔室12的材質需為 其壁膜的抗拉強度小於使用者旋轉中空管體丨丨時的轉力 或撕扯力1者。若隔室12乃為利用反應產生的壓力衝破 隔至界面之方式破壞其物理結構者，則隔室12的材料為 剛性或抗拉強度小於化學反應所產生的壓力。只要任何· 具有上述性質之材料需可用於本創作當作隔室丨2之材 料。 至少一補充單元20貼附在中空管體丨丨之外表面上， 包括沿著中空管體11之長度方向或兩端處。補充單元2〇 · 的位置分佈可排列成預定圖案，以搭配外觀造型設計。. 補充單元2G含有第-反應溶液’或另外配製第—反應溶 液中反應物溶於對應溶劑所得之補充反應溶液。補充單 元20的材料可與中空管體的材料相同或不同。 每一個補充單元20的劑量可以相同或不同，但是全 部補充單元20之反應物數量加上原中空管體丨丨所含第一 反應溶液之反應物數量;ί；超過與隔室12内第二反】溶液 之反應物反應的化學計量。 第二圖係為從第一圖I線方向所取得之補充單元2 〇 的立體示意體。第四圖係繪示當補充單元2〇被突起部13 戳進時的立體示意圖。雖然圖式以圓杈體緣示補充單元 I:\Patent\shih，chao-shu\000001 丁)\^[\0伍(^1\新型專利申請書 nnal.doc 13 M262645 20之構造，但是補充 其型㈣或 營髁η , 圖及弟四圖，補充單元2f)~k S體U外表面之第—表面21，及包括貼附中空 it未示出)。沿著補充單元2〇之V，側之第 内側有-分割線211。中空 表面21的邊 20之第-表面21處設有 -對應貼附補充單元 係野應分割線2U。通道^^13’通道Μ的邊緣 =附^空管體U那_側之寬度見^^補充單元2〇 ::=部131。當貼附於中空管^外^邊緣處設 20向中空管體U内部推擠時 卜表面之補充單 瞬間穿過該分割線，: = 之突 打開釋出補充單元割線晝 液，補充反應溶液再經 3之補充反應溶 補充單元20内的補充及 々,L入空管體u。為不使 出發光裝置丨之Γϋ錄錢❻部⑶戳穿而流 ^元別之厚度，較二超二充 ==1之突起部131得以輕“費力二M262645 8. Description of the new type: [Technical field to which the new type belongs] This creation is about a chemiluminescence device, and more specifically, it is about a chemiluminescence device that can prolong the luminous time. [Prior technology] The principle of chemiluminescence is based on the reaction of two chemical components. The generated reaction heat excites the fluorophor to emit colored light with a wavelength corresponding to the heat of reaction. Since these chemical compositions react as soon as they are consumed, the reaction ends until they are exhausted. Therefore, it is necessary to separate these chemical compositions, and then use the chemical compositions to mix and react. Currently, there are several kinds of chemiluminescence devices using the above chemiluminescence principle. For example, U.S. Patent No. 3,576,987 discloses a light-emitting device that generates a chemical reaction by mixing two liquids. The chemiluminescence device includes a flexible hollow tube body and A glass tube built into a flexible hollow tube body, wherein the hollow tube body contains a first solution and the glass tube contains a second solution. When the user bends the hollow tube body, the inner glass tube will break and release the second solution, mixing it with the first solution. In addition, there are two compartments that temporarily separate the two solutions and exist in the same closed container. The intermediate separation wall can be eliminated by crushing, tearing, rotating or loosening, or the compartment can be broken by the pressure generated by the reaction. Interface, etc., these reactants are mixed and reacted. Please refer to US Patent Nos. 3, 749, 620, 3, 539, 794, 3, 893, 938, 3, 808, 414, 4, 061, 910, 3, 149, 943, 3, 576, for the design of such shapes. 987 and 5, 067, 051. The disclosures of the 5 I: \ Patent \ shih, chao-shu \ 000001TWN \ Official ^ patent application Finai doc M262645 are incorporated herein by reference. The structure for placing the reactants separately includes nothing more than two compartments arranged inside and outside. In order to achieve the purpose of easily releasing one of the reactants when it is intended to be used, the compartments located inside must be easily accessible by The user crushes, tears, opens or loosens the clamp to release the solution contained in the internal compartment. However, the structural design of the above-mentioned mixed two reactants is discarded after the chemiluminescence is completed, because they are of no use value, not only wasting material resources, but the reaction products and the solvents that dissolve these reactants will also cause environmental pollution. . On the other hand, light-emitting devices that are light and portable can be made using the principle of chemiluminescence, but the dose of the reactants filled in these structures is limited, the life is not long, and the termination of the reaction cannot be controlled, so the chemiluminescence Application is restricted. Therefore, there is an urgent need for a chemiluminescence device structure that can prolong the light emission time and can achieve the environmental protection purpose of reuse. [New content] One of the objectives of this creation is to propose a chemiluminescence device structure that prolongs the light emission time, in which the solvent in which the reactants are dissolved can be reused. Another purpose of this creation is to propose a chemical light emitting device structure that prolongs the luminous time, in which the reactant can be supplemented in a timely and appropriate amount to extend its service life. To achieve the above and other objectives, the structure of the chemiluminescence device of the present invention includes a structure main body and at least one supplementary unit. The main body of the structure includes 6: 1: \? &Amp; 1611 partial 1 丨 11, (^ 〇-81111 \ 〇〇〇〇〇〇1 ^^ 01 (^ 1 \ new patent application Final doc 0262) empty The tube body and a compartment placed in the hollow tube body. At least one supplementary unit is attached to the outer surface of the hollow tube body. The hollow tube body contains a first reaction solution 'brother-reaction> Esters and fluorescent materials dissolved in appropriate solvents. Fluorescent materials include phosphors that are mainly responsible for emitting light and brighteners that enhance color brightness. The compartment contains a second reaction solution whose dose is greater than the chemistry that participates in all the light-emitting reactions Metering. The methods of releasing the solution in the compartment include crushing, tearing, rotating or loosening, or using the pressure generated by the reaction to break the interface of the compartment to destroy the physical structure of the compartment. Lu at least one supplementary unit is attached to the hollow On the outer surface of the pipe body, including along the length or both ends of the hollow pipe body. The position distribution of the supplementary element can be arranged in a predetermined pattern to match the appearance design. The supplementary unit contains the first reaction solution, or Also prepare the first reaction solution The supplementary reaction solution obtained by dissolving the reactant in the corresponding solvent. The material of the supplementary unit may be the same as or different from the material of the hollow tube body. The dosage of each supplementary unit may be the same or different, but the amount of reactants in all supplementary units is increased. Uehara's hollow tube contains no more than the stoichiometric amount of reactants in the first reaction solution and the reactants in the second reaction solution in the compartment. The light-emitting device of this creation can make the light-emitting time longer than ordinary commercially available glory rods or other The light-emitting device using the principle of chemiluminescence is long, which is more convenient in practical use. In addition, the supplementary unit is added to the chemiluminescence device of this creation, which can extend the light-emitting time under the repeated use of the structure body; Disposable light-emitting device, the chemiluminescence device 7 IMatenMiih'chao-shiAOOOOOlTWNXOfficialXff type patent application Finai.doc M262645 of this creation is also environmental protection. [Embodiment] The light-emitting principle of the chemiluminescence device of the present invention Use the appropriate soluble sword esters to react with hydrogen peroxide to provide phosphor energy to excite The fluorescent body in the stable ground state becomes the unstable electronic excited state. When the fluorescent body in the unstable ground state returns to the ground state, the excess energy is released in the form of light, and by using different colors of fluorescent The light body emits the desired colored light. The following is a description of the chemiluminescence reaction mechanism using phenyloxalate as an ester: OH 0 0-0 II yC-0 ', 〇H2〇2 0-0 1 I + Phosphor-, phosphor * + 2C〇2 ~, b The color of the light emitted depends on the phosphor used. For example, 'Rhodamine B can emit red light, and Rhodamine 6G can emit orange light. With 9,10-Diphenylantracene, blue light can be emitted. With Rubrene, yellow light can be emitted. With 9,10_Bis (phenylethynyl) _antracene, green light can be emitted. In order to study the relationship between supplementing the reactants and prolonging the luminous time ', I performed the yellow light emitting device and the pink light emitting device respectively. 8 I: \ Patent \ shih, chao-shu \ 0〇〇〇〇〇TWNOfOf ^ Type Patent Application Final.doc M262645 Inspection and Experiment II. Experiment 1: Take a commercially available yellow fluorescent rod and let it emit light. 'Remove the reacted waste liquid directly into the unreacted yellow fluorescent rod stock solution' and add the amount of hydrogen peroxide shown in Table 1. , Observe the light emission under different mixing ratios. The experimental results are shown in Table 1. Table-, Mixing is different to make you 丨 Luminous time of the waste liquid of the universal color pile-^ ------ | ----- 1 | Γ ----------- Volume of original liquid Volume relative to luminous time of waste liquid (mL) (mL) Volume% (hours) j Time% —-— 0 10 0 12 100 —-- 1 9 10 11 92 2 8 20 5 42 3 7 30 4 33 4 6 40 4 33 5 5 50 4 33 6 4 60 4 33 —----- 7 3 70 4 33 8 2 80 3 25 .-— — 8. 5 1.5 85 2 17 10 0 100 0 0 From the table above, we can know: When no waste liquid is mixed, the luminous time of the fluorescent liquid < reaches 100% ', and after mixing with 10% of the waste liquid, the luminous time is reduced to 92%. When mixed with more than 20%, the luminous time is rapidly decreased. When the composition of the waste liquid is from 30% to 70%, the luminous time is maintained at one third of the original, and when the composition of the waste liquid exceeds 70%, the luminous time is rapidly reduced to zero. -aten 灭 ⑽ao-shu__T Position 〇ffid 面面 9 M262645 The amount of effective esters in different mixed composition solutions is not the same under the provision of sufficient hydrogen peroxide. As the proportion of mixed waste liquid increases, the amount of effective esters decreases, so the relative luminous time becomes shorter. From the results of this experiment, it can be seen that although a small amount of (<%) yellow fluorescent rod waste liquid can not emit light for as long as the original reaction solution, the yellow fluorescent rod waste liquid can be recovered and reused. In experiment two, a commercially available pink fluorescent rod was taken. After the light was emitted, the reacted waste liquid was directly mixed into the unreacted pink fluorescent rod stock solution. For the volume ratio of the waste liquid to the stock solution, please refer to Table 2. The reaction solution shown (trichlorophenyl oxalate solution). Observe the luminescence of each mixed solution. The experimental results are shown in Table II. Table 2. Luminous time of mixing pink fluorescent rod waste liquid in different proportions. Volume of waste liquid relative to light emission time of waste liquid. Relative luminescence (mL) (mL) Volume% (hours) Time% 0 5 0 12 100 1 4 20 12 100 1. 5 3. 5 30 12 100 2 3 40 12 100 2. 5 2. 5 50 11. 5 96 3 2 60 4. 5 38 3. 5 1. 5 70 4_ 5 38 4 1 80 3. 5 29 4. 5 0. 5 90 3 25 5 0 100 0 0 I: \ Patent \ shih, chao-shu \ 000001 TWN \ Official \ _jf type patent application Final.doc 10 M262645 It can be seen that when the volume of waste liquid accounts for At 40%, the luminous S is still the original liquid solution of the fluorescent rod—like, when the volume of the waste liquid exceeds 50%, the light beam will be shortened quickly. From the perspective of the reuse of the fluorescent rod waste liquid " This waste liquid volume to 50% is still acceptable, but the premise is to add the same amount of _ reactant. 々The figure shows the comparison of the effect of the two kinds of waste liquid on the luminous time, which can be seen from 1. · 纟 5⑽, the pink fluorescent rod waste liquid has a small effect on the light gate, but when the waste liquid After the volume exceeds the two, the two curves are very close. It can be seen from the above experiments that the purpose of extending the hair light time can be achieved by supplementing appropriate reactants, so the present invention also provides a chemiluminescence device that can supplement the reactants at any time to increase the photochemical reaction time of the chemical. The first figure is a schematic cross-sectional view of the structure of the chemiluminescence device of this creation. The chemiluminescence device structure 1 includes a structure body 10 and at least one supplementary unit 20. The structural body 10 includes a hollow pipe body 11 and a compartment 12 placed in the hollow pipe body. However, the "pipe body" referred to herein is not limited to a structure with a rectangular cross section, as long as it can accommodate the compartment 12, it is within the scope of this creation. The hollow pipe body 11 is made of a transparent or translucent and flexible material such as polyolefin or a copolymer thereof. The preparation method includes, for example, injection molding, extrusion molding, and molding. The hollow body 11 contains a first reaction solution, and the first reaction solution occupies not more than 60% of the volume of the hollow tube body, preferably not more than 40%, and most preferably not more than 30%. The first reaction solution includes esters dissolved in a suitable solvent and fluorescent materials: I: \ Patent \ shih, chao-shu \ 000001, Ding \ ^ [\ 〇 伍 (^ 1 \ new patent application Rnal.doc 11 M262645 light material). Fluorescent materials include phosphors that are mainly responsible for emitting light and sensitizers that enhance color brightness. Fluorescent systems are selected according to the desired color, such as white light phosphors, yellow light phosphors, and green light Phosphors, blue light phosphors, etc. The brightener is used in combination with the type of phosphor used, for example, the light emitted by the yellow light phosphor is yellowish green, in order to make the color displayed through the hollow tube 11 bright and beautiful. A yellow brightener can be added. Brighteners include, for example, but are not limited to, Rhodamine B (red light), Rhodamine 6G (orange light), 9,10-Diphenylantracene (blue luguang), Rubrene (yellow light), 9, l〇-Bis (phenylethynyl) -antracene (green light), etc. The esters are selected from oxalates, such as bis (2,4-dinitrophenyl) oxalate (DNPO) and bis (2,4, 6-chlorophenyl) oxalate, etc., _ is selected according to the color light Correspondingly, the compartment 12 contains a second reaction solution, and the second reaction solution may be filled or not filled in the compartment 12. The reactant dose of the second reaction solution is greater than the stoichiometry of its participation in all luminescence reactions. The second reaction The solution mainly includes hydrogen peroxide dissolved in a suitable solvent. The method of releasing the solution in the compartment includes breaking, tearing, rotating or loosening or using the pressure generated by the reaction to break the interface of the compartment to destroy the physical structure of the compartment. Solvents include dibutyl phthalate, tertiary butyl ester, and combinations thereof. In order to cause the compartment 12 to be broken, torn, rotated, or loosened, or to break the interface of the compartment by using the pressure generated by the reaction, the physical properties of the compartment 12 are destroyed. Structure to release the second reaction solution, the material of the compartment 12 must be able to cooperate with these methods to release ΓνΡ ^ ηΜΙήΙ ^ Ι ^ ο-ΑιΛΟΟΟΟΟΙΙλλνΝ ^ Μα new patent application Final doc 12 M262645, and it can be stored The second reaction solution does not cause the second reaction solution to be released early when it has not been used. For example, if the compartment 12 is released in a broken manner, the second reaction is released. The compartment 12 can be made of fragile materials such as glass. If the compartment a can be rotated and torn to destroy its physical structure, the material of the compartment 12 needs to have a tensile strength less than that of the user's rotating hollow wall The turning or tearing force of the pipe body 1 is 1. If the compartment 12 is to destroy its physical structure by using the pressure generated by the reaction to break through the interface to the interface, the material of the compartment 12 is rigid or the tensile strength is less than Pressure from chemical reactions. As long as any material with the above-mentioned properties needs to be used in this creation as the material of the compartment 2. At least one supplementary unit 20 is attached to the outer surface of the hollow pipe body, including along the length direction or at both ends of the hollow pipe body 11. The position distribution of the supplementary unit 20 may be arranged in a predetermined pattern to match the appearance design. The supplementary unit 2G contains a -reaction solution 'or a supplementary reaction solution obtained by dissolving the reactants in the corresponding -reaction solution in the corresponding solvent. The material of the supplementary unit 20 may be the same as or different from that of the hollow pipe body. The dosage of each supplementary unit 20 may be the same or different, but the amount of reactants in all supplementary units 20 plus the amount of reactants in the first hollow solution contained in the original hollow body; ί; more than the second in the compartment 12 Inverse] The stoichiometry of the reactants of the solution. The second figure is a three-dimensional schematic diagram of the supplementary unit 20 obtained from the direction of the line I in the first figure. The fourth figure is a schematic perspective view when the supplementary unit 20 is poked by the protruding portion 13. Although the figure shows the structure of the supplementary unit I: \ Patent \ shih, chao-shu \ 000001 丁) \ ^ [\ 0 伍 (^ 1 \ new patent application nnal.doc 13 M262645 20), the structure is supplemented by the edge of the round branch, but it supplements Its shape ㈣ or 髁, η, figure and four figures, supplementary unit 2f) ~ the first surface 21 of the outer surface of the KS body U, and including the attached hollow it (not shown). Along the V of the supplementary unit 20, there is a -dividing line 211 on the inner side of the side. The side of the hollow surface 21-the surface 21 is provided at-corresponding to the attachment supplementary unit. Channel ^^ 13 'The edge of channel M = the width of the side of the attached empty tube U, see ^^ supplementary unit 20 :: = section 131. When the 20 attached to the outer edge of the hollow tube ^ is pushed toward the inside of the hollow tube body U, the supplementary sheet on the surface passes through the dividing line in a moment: The reaction solution is replenished into the empty tube body u through the replenishment and replenishment in the replenishment replenishment unit 20 of 3. In order to prevent the light emitting device, the Γϋrecording money section ⑶ piercing and flowing, the thickness of the element is different, which is lighter than the protrusion 131 of the two super two charge == 1.
UtenM^chao-shiAOOGOOlTWMOffK^新型專利申請書 Final— 2打開，苐一表面21的厚度較佳比第一表面 之，他部分薄’厚度差異則視所採用的材料而定。最佳 的疋’第表面21之分割線211的厚度盡可能薄到所含 之補充反應溶液不會在刻意戳破之前流出。分判線 可盡量靠近補充單元20之邊緣，以使補充單元^2〇所含 之補充反應溶液盡快且完全地流進中空管體u。然而， 14 M262645 大起邛131的位置必須在突起部13戳進時補充單元的那 側邊緣不致於貼住補充單元邊緣2〇内側，以避免突起 部13不小心戳破補充單元2〇。 由於酯類一接觸到過氧化氫即發生反應，所以需將 過氧化氫單獨放置於隔室12内。酯類，以及同色系螢光 體和增光劑則溶於酯類溶劑，形成第一反應溶液後填充 於中空官體11。由於過氧化氫與酯類不相溶，因此必須 利用界面活性劑，方能使過氧化氫溶解於與第 一反應溶 液相同之酯類溶劑。界面活性劑包括烷醇類，例如丁醇 或戊醇。 螢光體係根據所欲發出之顏色而選擇之，例如白光 螢光體、黃光螢光體、綠光螢光體及藍光螢光體等。增 光劑係視所使用的螢光體種類搭配使用，例如黃光螢光 體發出的光帶有黃綠色，為使透過中空管體11展現出來 的顏色鮮豔亮麗，可添加黃色增光劑。其他顏色則以此 類推。 使用時，先依照含第二反應溶液之隔室12的構造以 破碎、撕裂、旋轉或鬆夾或利用反應產生的壓力破壞隔 室之物理結構，釋出第二反應溶液與第一反應溶液反 應，並發出所要的色光。當反應完畢時、反應後、反應 期間’尤其是發光強度開始變弱時，將貼附於中空管體 11外表面上之補充單元20往中空管體11按壓，使對應補 充單元20之第一表面21的突起部131迫使補充單元2〇之 活蓋212打開，讓補充單元20内的補充反應溶液經通道13 I:\Patent\shih，chao-shu\000001 TWN\Official^型專利申請書 Hnal.doc M262645 流入補充單元20，以維持發光反應之進行。 本創作另提出一種化學發光組合，其包括數個上述 化學發光裝置1。本具體實施例裡，每個化學發光裝置可 藉由填充不同色系之酯類反應物及螢光材料，發出不同 顏色之色光，透過不同的結構組裝排列，可任意組裝出 所要造型之多色發光組合。必須注意的是，所有補充單 元與結構主體内的所有反應溶液體積必須不大於中寬管 體的内容積。例如’化學發光組合可包括黃色、粉紅色、 白色及藍色發光裝置’每個發光裝置的中空管體及補充鲁 單元填充其對應顏色之第一反應溶液，藉由交錯時間使 中空管體與隔室之反應溶液混合發光及/或使補充單元 之補充反應溶液與中空管體内經第一次反應的溶液混合 -反應，呈現出多彩多變的發光效果’不僅提供照明功能’ 亦可達到營造氣氱之效。 由於近年來輕巧的化學發光裝置，例如螢光棒，逐 漸被大量使用於例如演唱會或夜間活動’或者是警示用籲 途之照明設備上，本創作之發光裝置可使發光時間較一 般市售之螢光棒或其他利用化學發光原理之發光裝置 長，在實際使用上更加方便。另外，本創作之化學發光 裝置加設補充單元，可在重複使用結構主體之下達延長 發光時間之功效；相較於習知用完即丟的發光裝置，本 創作之化學發光裝置亦收環境保護之實。 雖然本創作係已參照較佳實施例來加以描述，將為 吾人所暸解的是’本創作並未受限於其詳細描述内容。 I:\Patent\shih，chao-shu\000001 TWNXOfficial^型專利申請書 Final.doc M262645 替換方式及修改樣式係已於先 他替換方f及修改樣式將為熟；項2議，並且其 及。特別是，根據本創作之裝置妗、身之人士所思 相同於本創作之組件結合而達成；本創：：具有實質上 果者皆不脫離本創作之精神範疇。因 貝質上相同結 方式及修改樣式係意欲落在本創作有此等替換 及其均等物所界定的範疇之中。 < 清專利範圍 【圖式簡單說明】 光棒發 弟一圖係顯示加入廢液的體積對不同〜 光時間的影響； 》鸯 圖UtenM ^ chao-shiAOOGOOlTWMOffK ^ New patent application Final-2 is opened. The thickness of the first surface 21 is preferably better than that of the first surface. The difference in thickness is partially depending on the material used. The thickness of the dividing line 211 of the optimum? 'Surface 21 is as thin as possible so that the supplementary reaction solution contained therein does not flow out before deliberately puncturing. The dividing line can be as close as possible to the edge of the replenishing unit 20, so that the replenishing reaction solution contained in the replenishing unit ^ 20 can flow into the hollow tube body u as quickly and completely as possible. However, the position of the 14 M262645 large lifting pin 131 must be such that the edge of the side of the supplementary unit does not stick to the inside of the edge 20 of the supplementary unit when the protrusion 13 is poked, so as to avoid the projection 13 accidentally puncturing the supplementary unit 20. Since the esters react as soon as they come into contact with hydrogen peroxide, the hydrogen peroxide needs to be placed in the compartment 12 alone. Ester, as well as phosphors and brighteners of the same color, are dissolved in the ester solvent, form the first reaction solution, and fill the hollow body 11. Since hydrogen peroxide is incompatible with esters, a surfactant must be used to dissolve hydrogen peroxide in the same ester solvent as the first reaction solution. Surfactants include alkanols, such as butanol or pentanol. The fluorescent system is selected according to the desired color, such as white phosphor, yellow phosphor, green phosphor, and blue phosphor. The brightener is used in combination depending on the type of phosphor used. For example, the yellow phosphor emits yellow-green light. In order to make the color displayed through the hollow tube 11 bright and bright, a yellow brightener can be added. And so on for other colors. In use, the physical structure of the compartment is broken by breaking, tearing, rotating or loosening according to the structure of the compartment 12 containing the second reaction solution, and the second reaction solution and the first reaction solution are released. React and emit the desired color. When the reaction is completed, after the reaction, and during the reaction period, especially when the luminous intensity starts to weaken, the supplementary unit 20 attached to the outer surface of the hollow tube body 11 is pressed against the hollow tube body 11 so that the corresponding supplementary unit 20 The protrusion 131 of the first surface 21 forces the flap 212 of the supplementary unit 20 to open, and allows the supplementary reaction solution in the supplementary unit 20 to pass through the channel 13 I: \ Patent \ shih, chao-shu \ 000001 TWN \ Official ^ type patent application Book Hnal.doc M262645 flows into the supplementary unit 20 to maintain the progress of the luminescence reaction. This creation also proposes a chemiluminescence combination, which includes several chemiluminescence devices 1 described above. In this specific embodiment, each chemiluminescence device can be filled with ester reactants and fluorescent materials of different colors to emit colored light of different colors, and assembled and arranged through different structures to assemble any desired color. Glowing combination. It must be noted that the volume of all supplementary units and all reaction solutions in the structure body must not be greater than the inner volume of the medium-wide tube. For example, 'the chemiluminescence combination may include yellow, pink, white, and blue light emitting devices' The hollow tube body and the supplementary Lu unit of each light emitting device are filled with a first reaction solution of its corresponding color, and the hollow tube is made by staggering time And the reaction solution of the body and the compartment are mixed to emit light and / or the supplementary reaction solution of the supplementary unit is mixed with the solution that undergoes the first reaction in the hollow tube body to react and present a colorful and varied luminous effect 'not only provides lighting functions' Can also achieve the effect of discouragement. In recent years, light-weight chemiluminescence devices, such as fluorescent sticks, have gradually been widely used in lighting equipment such as concerts or night events, or warning lights. The light-emitting device of this creation can make the light-emitting time longer than the general market. The fluorescent rod or other light emitting device using the chemiluminescence principle is long, which is more convenient in practical use. In addition, the chemiluminescence device of this creation is provided with a supplementary unit, which can extend the luminous time under the repeated use of the structure body. Compared with the conventional light-emitting device that is thrown away, the chemiluminescence device of this creation also receives environmental protection True. Although this creation has been described with reference to a preferred embodiment, what I will understand is that this creation is not limited to its detailed description. I: \ Patent \ shih, chao-shu \ 000001 TWNXOfficial ^ type patent application Final.doc M262645 Replacement methods and modification styles have been replaced by other parties f and modification styles; item 2 is discussed, and it is. In particular, according to the installation of this creation, the thinking of the body is the same as the combination of the components of this creation; Original Creation: Anyone with substantial results does not depart from the spiritual scope of this creation. Because of the same quality and modification style, it is intended to fall into the category defined by these substitutions and their equivalents in this creation. < Clear patent scope [Simplified illustration of the diagram] The first photo of the light stick showing the effect of the volume of the waste liquid added on the different ~ light time;
第二圖係為本創作之化學發光裝置結構的I 面示意 第二圖係為從第一圖I線方向所取得 的立體示意體；及 <補充單 元20 第四圖係緣示當補充單元20被突起部13 體不意圖 戳 進時的 立 【主要元件符號說明】 結構主體1 中空管體11 隔室12 通道13 突起部131 I:\Patent\shih，chao-shu\000001 TWN\Official\ff型專利申請書 Final.doc M262645 補充單元20 第一表面21 分割線211 活蓋212 1:\?3〖6!1偏1丨11，(^〇41111\000001丁\\^\(^1(^1\新型專利申請書 Final.docThe second diagram is a schematic diagram of the I side of the structure of the chemiluminescence device of the creation. The second diagram is a three-dimensional schematic diagram taken from the direction of the first line of the first diagram; and < Supplementary unit 20 The fourth diagram is a marginal supplementary unit. 20 Standing position when the protrusion 13 body is not intended to be pierced [Description of the main component symbols] Structural body 1 Hollow pipe body 11 Compartment 12 Channel 13 Protrusion 131 I: \ Patent \ shih, chao-shu \ 000001 TWN \ Official \ ff type patent application Final.doc M262645 supplementary unit 20 first surface 21 dividing line 211 flap 212 1: \? 3 〖6! 1 partial 1 丨 11, (^ 〇41111 \ 000001 丁 \\ ^ \ (^ 1 (^ 1 \ new patent application Final.doc