M248458 五、創作說明（1) 新型說明： 【新型所屬之技術領域】 本創作疋有關於一種管式的光觸媒反應器，特別是有關於 種利用、務设備，以獲得微細顆粒狀液滴的一種反應器 設計’用來反應水中所含的有機物。 【先前技術】 ik著科技的進步，工業用水的需求越來越大，水回收成為 一個重要的用水來源，但因製程的日益精密，水質的要求 也不斷提升’其中比較困難的是水中微量有機物的去除。 另一方面，PU合成皮製造業、表面塗裝業、光電業和半導 體業等’這些工業的部分製程都有揮發性有機物（voc ) 排放造成空氣污染的困擾，濕式洗滌以除去空氣中的v〇C 是解決方法之一，但此技術的缺點是當洗滌液中有機物的 含I越來越高時，VOC的去除效果就越來越差，造成用水 和排放水量的增加，減低業者使用的意願，解決此問題的 關鍵技術就在於如何把洗滌液中的有機物質不斷移除，避 免累積，這樣就可以大大減低所需水量以及排放水的後續 處理問題，去除這些物質的方法之一是利用光觸媒來處 理’經由其特殊的反應機制可以礦化有機物，如此可提升 濕式洗滌技術應用於VOC處理的可行性。 在習知技術中已有利用光觸媒的裝置來淨化空氣，例如在 中華民國00390426 、 00405698 、 00427203 、 00497466和 〇 0 5 1 5 3 9 4等專利中，均是空氣濾清的裝置；而在中華民國 0 0 5 0 5 2 2 9和〇 〇 5 1 6 6 1 0專利中則是強調殺菌的空調裝置；另M248458 V. Creation description (1) New type description: [Technical field to which the new type belongs] This creation is about a tube-type photocatalyst reactor, especially about the utilization and service equipment to obtain fine granular droplets. A reactor design is used to react to organics contained in water. [Previous technology] With the advancement of science and technology, the demand for industrial water is increasing, and water recycling has become an important source of water. However, due to the increasingly sophisticated process, the water quality requirements have continued to increase. Among the more difficult is the trace organic matter in water. Removal. On the other hand, PU synthetic leather manufacturing, surface coating industry, optoelectronic industry and semiconductor industry, etc. Some of these industries have volatile organic compounds (voc) emissions that cause air pollution problems. Wet washing to remove air v〇C is one of the solutions, but the disadvantage of this technology is that when the I content of the organic matter in the washing liquid is getting higher and higher, the VOC removal effect becomes worse and worse, resulting in an increase in the amount of water and discharged water, reducing the use of industry The key technology to solve this problem is how to continuously remove the organic substances in the washing liquid to avoid accumulation, so that the required amount of water and the subsequent treatment of the discharged water can be greatly reduced. One of the methods to remove these substances is The use of photocatalyst to treat organic matter can be mineralized through its special reaction mechanism, which can improve the feasibility of wet washing technology applied to VOC treatment. In the prior art, devices using photocatalysts have been used to purify the air. For example, in the patents of the Republic of China on 00390426, 00405698, 00427203, 00497466, and 0 5 1 5 3 94, all are air filtration devices; while in China Republic of China's 0 0 5 0 5 2 2 9 and 0 05 1 6 6 1 0 patents are air conditioning devices that emphasize sterilization;
M248458 五、創作說明（2) 一方面，在V 0 c渴式、、*、攸u „ 專利，里内突強π先滌技術方面則有中爭民國004 603 1 2 專j /、内強§周以電解氧化法，將水溶液中的氣離+ $ 化成次氯酸，以此幺v n r ^ H雖子乳 為v〇c的洗條液，不断移除洗#、、奋φ 解的有機物，次氯酸氧化有機物後所產生的氣先^子液中口合 電解槽中繼續氧化產士 A ^ a 9 J乳離子則回到 a τ丄μ 屋生次氯酸，其缺點是次氣醏的气仆处 力不太夠’僅能氧化部分有機物。 仏的轧化成 【新型内容】 由既有資料知道雖辦本 但至今尚無人申請^ ^讲^知可以用來反應有機物質， 相關專利，主要原因θ : 衣置來反應水溶液中有機物的 穿透空氣達到光觸媒媒需靠光來協助反應，而光要 計，若要光穿透水達到来與反應的設備比較容易設 的因素需要考量，例如光盥，，並參與反應，則有較多 在在水溶液中的分散情形等1、谷液的接觸方式，光觸媒 本創作之設備乃是利用管型 設備，使光觸媒在在水溶液中^尸反應器，配合流體喷霧 大的反應面積可與光反應，而^:，好的分散，並提供極 光的穿透，如此可解決傳統水、、六〜的中務狀顆粒溶液利於 穿透效果不好等缺點。 & ;夜中光觸媒分散不佳，光 :據上述目的，本創作所提供 空污VOC處理的操作方式包括下歹啤媒反應器應用於 貯槽令，將水與光觸媒充分混合列^驟··首先在一光觸媒 酸鹼值；接著利用迴流泵將分2々、均勾分散並調整所需的 型光觸媒反應器頂端，藉由—:=的光觸媒水溶液打入管 當的噴嘴將溶液喷成霧M248458 V. Creation Instructions (2) On the one hand, in terms of V 0 c thirsty style, *, and y u „patents, the technology of lining up and strengthening π is the technology of the Republic of China 004 603 1 2 § The electrolytic oxidation method is used to ionize + $ in the aqueous solution to form hypochlorous acid, so that vnr ^ H is a voucher washing solution, and continuously remove the washed organic compounds. The gas produced after hypochlorous acid oxidizes organic matter, and the oxidized midwife A ^ a 9 J milk ion is returned to a τ 丄 μ housing hypochlorous acid. Its disadvantage is that I ’m not good enough in gas servants. 'I can only oxidize some organic compounds. The rolling of Ii [new content] It is known from the existing information that no one has applied for it, although it has been used to do this. The patent, the main reason θ: The reaction of the organic matter in the aqueous solution to penetrate the air to reach the photocatalyst requires light to assist the reaction, and the light must be counted. If the light penetrates the water to reach the reaction equipment, it is easier to set the factors. Considering, for example, light washing, and participating in the reaction, there are more points in the aqueous solution. Circumstances, etc. 1. The contact method of the valley liquid. The equipment of this photocatalyst is a tube-type device, so that the photocatalyst can react with light in the aqueous solution ^ reactor, and the large reaction area of the fluid spray, and ^ :, Good dispersion, and provides the penetration of aurora, which can solve the disadvantages of traditional water, six to the middle-sized particle solution is not good for the penetration effect. &Amp;; poor dispersion of photocatalyst at night, light: According to the above purpose, The operation method of air pollution VOC treatment provided by this creation includes the following application of the beer media reactor to the storage tank order, and the water and photocatalyst are fully mixed. ^ Steps · First, the photocatalyst pH value is used; 1. Disperse and adjust the top of the required photocatalyst reactor, and spray the solution into a mist with —: = photocatalyst aqueous solution into the tube nozzle.
« 7頁 M248458 五、創作說明（3) 狀’進入反應槽中’其中上述之 有適當之光源，使得反應大部份得以在==中間具 =，而待處理的VOC則以逆向方式由反應隹夜滴表面進 霧狀液滴充分接觸；之I，將處理過 ^曰底進入，與 、户入水妒，4 〜 ^ <水移出此反；® Μ , 飢入先觸媒貯槽中並循環使用。 α钇 【實施方式】 日:1。圖’以下就本創作之管型光觸媒反應器，作- 兒明本創作管型光觸媒反應器之裝置示意圖，立 為先觸媒水溶液貯槽，1〇為反應器，η為濾光器，u ;批二’ 1 3為喷嘴，1 4為授拌器，1 5為PH控制器，1 6為况 ==器，21、23、25、27為管路，22為電源線，31為:皿 3 3為泵浦。 κ 〇丄、 is:之ΐ法是在一噴霧反應槽10中進行’而此反應槽中 -ΐ ϊw水迴路23、25、27，可使反應槽中的部份水迴 教’而重複使用水溶液。 γ先，將水與光觸媒充分混合在一光觸媒貯槽2中， =當的攪拌器14來使光觸媒均勾分散，並使用一控制器ι :调整所需的酸驗值和溫度控制器i 6來控制所需的反^ ^適§的攪拌器包括均質機、超音波震盪器等。# 光觸媒貯槽2中的水經由管路25、27注入反應枰 ，亚啟動迴流泵3 3，依所使用噴嘴的種類和 適當的流速。 ^彳工制«Page 7 M248458 V. Creative Instructions (3) The form of" entering into the reaction tank "has the appropriate light source, so that most of the response can be in the middle of ==, and the VOC to be processed is reversed by the reaction. The surface of the night drop is fully in contact with the misty liquid droplets; I, the treated liquid enters at the end, and the household enters the water with jealousy, 4 ~ ^ < water moves out of this reaction; ® M, enter the first catalyst storage tank and recycle. α-yttrium [Embodiment] Day: 1. Figure 'The following is the creation of the tube-type photocatalyst reactor, as a schematic diagram of the device of Ermingben's creation of the tube-type photocatalyst reactor, which is the first catalyst aqueous solution storage tank, 10 is the reactor, η is the filter, u; Batch 2 '1 3 is a nozzle, 1 4 is a blender, 15 is a PH controller, 16 is a condition == device, 21, 23, 25, 27 are pipelines, 22 is a power cord, 31 is: a dish 3 3 is the pump. κ 〇 丄, is: The method is to carry out in a spray reaction tank 10 'and in this reaction tank-ΐ ϊ w water circuit 23, 25, 27, can make part of the water in the reaction tank islam' and reuse the aqueous solution . γ First, water and photocatalyst are fully mixed in a photocatalyst storage tank 2. The current agitator 14 is used to disperse the photocatalyst, and a controller is used: adjust the required acid value and temperature controller i 6 to The mixers required for control include: homogenizers, ultrasonic oscillators, etc. # The water in the photocatalyst storage tank 2 is injected into the reaction tank 管路 through the lines 25 and 27, and the reflux pump 3 3 is started, depending on the type of nozzle used and the appropriate flow rate. ^ Work system
第8頁 M248458 五、創作說明（4) 接著，適當氣體由反應槽10的底部注入，以進行光催化氧 化反應，其中適當氣體的來源可為空污VOC氣體、空氣或 純氧氣。 之後，在反應槽1 0中控制適當的pH值、氣體停留時間，以 完成所需反應，而處理後之氣體可由反應槽的頂部排出。 依據本創作之水處理法的應用領域相當廣泛，包括：（1) 空污VO C處理；（2 )飲用水中微量有機物處理；以及（3 )工 業廢水回收處理等。Page 8 M248458 V. Creative Instructions (4) Next, an appropriate gas is injected from the bottom of the reaction tank 10 to perform a photocatalytic oxidation reaction. The source of the appropriate gas may be air-contaminated VOC gas, air, or pure oxygen. After that, the appropriate pH value and gas residence time are controlled in the reaction tank 10 to complete the desired reaction, and the processed gas can be discharged from the top of the reaction tank. The application fields of the water treatment method based on this creation are quite wide, including: (1) air pollution VO C treatment; (2) trace organic matter treatment in drinking water; and (3) industrial wastewater recycling treatment.
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