TWI844885B - Carbon dioxide purification device - Google Patents
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- TWI844885B TWI844885B TW111126135A TW111126135A TWI844885B TW I844885 B TWI844885 B TW I844885B TW 111126135 A TW111126135 A TW 111126135A TW 111126135 A TW111126135 A TW 111126135A TW I844885 B TWI844885 B TW I844885B
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Abstract
Description
本發明係關於二氧化碳淨化裝置，尤指一種能對低濃度的二氧化碳氣體進行光分解機制，以將二氧化碳轉化為可供後續利用之產物氣體的二氧化碳淨化裝置。The present invention relates to a carbon dioxide purification device, and more particularly to a carbon dioxide purification device capable of performing a photolysis mechanism on low-concentration carbon dioxide gas to convert carbon dioxide into product gas that can be subsequently utilized.
按，氣候變遷所造成的危機，一直是各國密切注意以及急欲解決的重大議題之一，隨著工業化的高速發展以及電力的需求上升，工廠、車輛甚至是火力發電廠等，都會產生大量的溫室氣體(如：二氧化碳)，前述溫室氣體會攫住原應散發到太空中的熱量，使得原來的溫室效應更加強化，導致了地球平均溫度的上升，進而影響了氣候與環境(例如，沙漠化、改變降雨量等)。The crisis caused by climate change has always been one of the major issues that all countries have paid close attention to and are eager to resolve. With the rapid development of industrialization and the increase in demand for electricity, factories, vehicles and even thermal power plants will produce a large amount of greenhouse gases (such as carbon dioxide). The aforementioned greenhouse gases will capture the heat that should have been dissipated into space, making the original greenhouse effect more enhanced, leading to an increase in the average temperature of the earth, which in turn affects the climate and environment (for example, desertification, changes in rainfall, etc.).
承上，目前自大氣中去除或降低溫室氣體的方法，大致如下： (1) 物理變化：透過凝結或降雨的方式，以消除大氣中的水蒸氣； (2) 大氣中的化學反應：透過天然存在的羥自由基(·OH)與甲烷氧化反應，以降解為二氧化碳與水蒸氣； (3) 大氣與地球的部分組成間的物理作用：大氣中的溫室氣體混合至海洋中； (4) 大氣地球的部分組成間的化學作用：二氧化碳透過植物的光合作用，而形成氧氣； (5) 光化學變化(photochemical change)。 As mentioned above, the current methods of removing or reducing greenhouse gases from the atmosphere are roughly as follows: (1) Physical changes: removing water vapor from the atmosphere through condensation or rainfall; (2) Chemical reactions in the atmosphere: degrading into carbon dioxide and water vapor through the oxidation reaction of naturally occurring hydroxyl radicals (·OH) and methane; (3) Physical interactions between the atmosphere and some components of the earth: greenhouse gases in the atmosphere are mixed into the ocean; (4) Chemical interactions between some components of the atmosphere and the earth: carbon dioxide is converted into oxygen through photosynthesis of plants; (5) Photochemical changes.
然而，藉由自然界的作用去除或降低溫室氣體，顯然趕不上人為增加溫室氣體的速度，研究指出截至 2021 年為止，地球的大氣中，二氧化碳濃度比工業化前水平高出近50%。有鑑於此，部分業者開始嘗試利用二氧化碳來產生其他產物，藉此達到降低二氧化碳濃度的效果，同時還能得到足以作為它用(如：燃料)的其他產物。舉例而言，中國第CN113797866號專利案，係公開了一種無揮發性有機物(VOC)排放的內循環式有機合成反應櫃，其係能夠對VOC進行吸附和降解，以得到降解氣體，其中，前述降解氣體包含較多的二氧化碳，之後，將降解氣體通入二氧化碳濃縮器分離濃縮，以形成濃縮氣體，再將前述濃縮氣體通入二氧化碳電催化反應器中進行電還原反應，最終生成甲醇與甲酸。或者，中國第101428223號專利案，其能夠將二氧化碳水溶液進行光催化還原，以形成甲酸、甲醛與氫氣。However, the removal or reduction of greenhouse gases by natural processes cannot keep up with the rate of man-made greenhouse gas increases. Studies have shown that as of 2021, the concentration of carbon dioxide in the Earth's atmosphere is nearly 50% higher than the pre-industrial level. In view of this, some companies have begun to try to use carbon dioxide to produce other products, thereby achieving the effect of reducing carbon dioxide concentrations, while also obtaining other products that can be used for other purposes (such as fuel). For example, Chinese Patent No. CN113797866 discloses an internal circulation organic synthesis reactor without volatile organic compounds (VOC) emission, which can adsorb and degrade VOC to obtain degraded gas, wherein the degraded gas contains more carbon dioxide, and then the degraded gas is passed into a carbon dioxide concentrator for separation and concentration to form concentrated gas, and then the concentrated gas is passed into a carbon dioxide electrocatalytic reactor for electroreduction reaction to finally generate methanol and formic acid. Alternatively, Chinese Patent No. 101428223 can photocatalytically reduce a carbon dioxide aqueous solution to form formic acid, formaldehyde and hydrogen.
惟，現有以物理方式(如：活性碳、沸石、金屬氧化物或金屬碳化物等)或化學方式(如：氨水、碳酸鹽溶液、鹼金屬溶液等)處理二氧化碳的技術，大多是針對工廠廢氣中的高濃度二氧化碳(二氧化碳約佔氣體體積3%含量以上)，但是，前述方式並不適合用於僅有低濃度二氧化碳的一般大氣(二氧化碳約佔一般大氣體積之350至450ppm)或其他氣體源，因此，如何有效解決前述問題，即為本發明之相關業者的重要課題。However, the existing technologies for treating carbon dioxide by physical means (such as activated carbon, zeolite, metal oxides or metal carbides, etc.) or chemical means (such as ammonia water, carbonate solution, alkaline metal solution, etc.) are mostly aimed at high-concentration carbon dioxide in factory exhaust gas (carbon dioxide accounts for about 3% or more of the gas volume). However, the above methods are not suitable for general atmosphere with only low concentration of carbon dioxide (carbon dioxide accounts for about 350 to 450 ppm of the general atmosphere volume) or other gas sources. Therefore, how to effectively solve the above problems is an important issue for the relevant industry of the present invention.
有鑑於前述習知的問題，申請人秉持精益求精的研究精神，在經過長久的努力研究與實驗後，終於研發出本發明之一種二氧化碳淨化系統，其中，光分解的機制係光照射至光觸媒組合物，透過光觸媒組合物催化產生電子或電洞激化，進而達到分解二氧化碳的功能。In view of the above-mentioned known problems, the applicant has adhered to the spirit of continuous improvement in research and, after long-term research and experiments, finally developed a carbon dioxide purification system of the present invention, in which the mechanism of photodecomposition is that light irradiates the photocatalyst composition, and the photocatalyst composition catalyzes the generation of electrons or holes to be excited, thereby achieving the function of decomposing carbon dioxide.
本發明之目的，係提供一種二氧化碳淨化裝置，包含一本體及一光觸媒組合物，其中，該光觸媒組合物係選自氮化物、碳化物、氧化物或鹽類之至少其中一種或二種以上與粉體或其它佐劑的組合，且該光觸媒組合物係為一未改質型光觸媒組合物及/或一改質型光觸媒組合物。The purpose of the present invention is to provide a carbon dioxide purification device, comprising a body and a photocatalyst composition, wherein the photocatalyst composition is selected from at least one or a combination of two or more of nitrides, carbides, oxides or salts and powders or other adjuvants, and the photocatalyst composition is an unmodified photocatalyst composition and/or a modified photocatalyst composition.
可選地，該光觸媒組合物之成分中，氮化物為氮化碳。Optionally, in the components of the photocatalyst composition, the nitride is carbon nitride.
可選地，該光觸媒組合物之成分中，碳化物為碳化矽或活性碳。Optionally, in the components of the photocatalyst composition, the carbide is silicon carbide or activated carbon.
可選地，該光觸媒組合物之成分中，氧化物為二氧化鈦(TiO 2)、Ni/La 2O 2CO 3、硼六氧(B 6O)、ZnGeO 2或CoGeO 2。 Optionally, in the components of the photocatalyst composition, the oxide is titanium dioxide (TiO 2 ), Ni/La 2 O 2 CO 3 , boron hexaoxide (B 6 O), ZnGeO 2 or CoGeO 2 .
可選地，該光觸媒組合物之成分中，鹽類較佳為矽酸鹽或金屬鈦酸鹽。Optionally, the salt in the photocatalyst composition is preferably a silicate or a metal titanium salt.
可選地，該光觸媒組合物中，該改質型光觸媒組合物與未改質型光觸媒組合物的比例為10：90至90：10。Optionally, in the photocatalyst composition, the ratio of the modified photocatalyst composition to the unmodified photocatalyst composition is 10:90 to 90:10.
可選地，該改質型光觸媒組合物之經改質處理為一醇化改質或一金屬化改質，該醇化改質係利用未改質型光觸媒組合物與乙二醇進行反應處理，該金屬化改質係利用未改質型光觸媒組合物與硝酸金屬化合物進行反應處理。Optionally, the modified photocatalyst composition is modified by alcoholization or metallization. The alcoholization is carried out by reacting the unmodified photocatalyst composition with ethylene glycol, and the metallization is carried out by reacting the unmodified photocatalyst composition with a metal nitrate compound.
可選地，該光觸媒組合物進一步添加一抗菌組成物。Optionally, an antibacterial composition is further added to the photocatalyst composition.
可選地，該二氧化碳淨化裝置之本體為一燈具裝置之殼體；較佳地，該光觸媒組合物係局部塗佈於該燈具裝置之殼體外側。Optionally, the main body of the carbon dioxide purification device is a shell of a lamp device; preferably, the photocatalyst composition is partially coated on the outer side of the shell of the lamp device.
可選地，該二氧化碳淨化裝置進一步包含一光電轉換裝置；較佳地，該二氧化碳淨化裝置係局部設置於該光電轉換裝置的表面；於另一較佳實施例中，該光電轉換裝置係進一步電氣連接至一照明裝置，且該光電轉換裝置將光能轉換成電能，以傳輸電能至一照明裝置。Optionally, the carbon dioxide purification device further includes a photoelectric conversion device; preferably, the carbon dioxide purification device is locally disposed on the surface of the photoelectric conversion device; in another preferred embodiment, the photoelectric conversion device is further electrically connected to a lighting device, and the photoelectric conversion device converts light energy into electrical energy to transmit the electrical energy to a lighting device.
為便 貴審查委員能對本發明目的、技術特徵及其功效，做更進一步之認識與瞭解，茲舉實施例配合圖式，詳細說明如下：In order to help you, the review committee, to have a deeper understanding of the purpose, technical features and effects of the present invention, the following embodiments are provided with accompanying drawings for detailed description:
為使本發明之目的、技術內容與優點更加清楚明白，以下結合具體實施方式，並參照附圖，對本發明所公開的實施方式進一步詳細說明。本領域之技藝人士可由本說明書所公開的內容瞭解本發明的優點與效果，且本發明可通過其他不同的具體實施例加以施行或應用，本說明書中的各項細節也可基於不同觀點與應用，在不悖離本發明的構思下進行各種修改與變更。另外事先聲明，本發明的附圖僅為簡單示意說明，並非依實際尺寸進行描繪。此外，除非上下文有明確指出或定義，否則本發明之“一”、“該”之含義包括複數。又，以下的實施方式將進一步詳細說明本發明的相關技術內容，但所公開的內容並非用以限制本發明的保護範圍。In order to make the purpose, technical content and advantages of the present invention more clearly understood, the following is a further detailed description of the disclosed embodiments of the present invention in combination with specific embodiments and with reference to the attached drawings. The technical personnel in this field can understand the advantages and effects of the present invention from the contents disclosed in this specification, and the present invention can be implemented or applied through other different specific embodiments. The details in this specification can also be modified and changed in various ways based on different viewpoints and applications without deviating from the concept of the present invention. In addition, it is stated in advance that the attached drawings of the present invention are only for simple schematic illustration and are not drawn according to the actual size. In addition, unless the context clearly indicates or defines otherwise, the meaning of "one" and "the" in the present invention includes the plural. In addition, the following implementation methods will further illustrate the relevant technical contents of the present invention in detail, but the disclosed contents are not intended to limit the protection scope of the present invention.
應理解，本文所使用的術語通常具有本領域的普通含義，在有衝突的情況下，以本文所給出的任何定義為準。由於同一件事可以用多種方式表達，替代詞語與同義詞可用於本文所討論或敘述的任何術語，且在本文是否闡述或討論術語方面沒有特殊限定，一個或多個同義詞的使用並不能排除其他同義詞。在本發明之說明書中任何地方所使用的實施例，包括任何術語的使用，都僅是說明性，絕不限制本發明或任何術語的範圍與含義。同樣地，本發明並不侷限於說明書所揭露的各種實施例。It should be understood that the terms used herein generally have the ordinary meaning in the art, and in the event of a conflict, any definition given herein shall prevail. Since the same thing can be expressed in multiple ways, alternative words and synonyms may be used for any term discussed or described herein, and there is no special limitation on whether the term is elaborated or discussed herein, and the use of one or more synonyms does not exclude other synonyms. The embodiments used anywhere in the specification of the present invention, including the use of any term, are merely illustrative and in no way limit the scope and meaning of the present invention or any term. Similarly, the present invention is not limited to the various embodiments disclosed in the specification.
本發明係一種二氧化碳淨化裝置，請參閱圖1所示，該二氧化碳淨化裝置1包含一本體11與一光觸媒組合物12，其中，在本發明之一第一實施例中，該本體11包含一頂板111與一底板112，該頂板111的頂面係設置有該光觸媒組合物12，該底板112能為一種多孔性材料(如：熱沸石、硅藻土…等)，其係能設於該頂板111的底側，故，該頂板111與該底板112能結合為一體(但不以此為限)；在本發明之其它實施例中，該本體11亦能僅包含該底板112，該光觸媒組合物12能直接設置於該底板112上。The present invention is a carbon dioxide purification device. Please refer to FIG. 1 . The carbon dioxide purification device 1 includes a
該光觸媒組合物12係選自氮化物、碳化物、氧化物或鹽類之至少其中一種或二種以上與粉體或其它佐劑的組合(但不以此為限)，且經發明人重複試驗及測試，證實氮化物、碳化物、氧化物或鹽類任一者，皆能作為光催化劑，以將二氧化碳轉化為甲烷(CH
4)、甲醇(CH
3OH)、甲酸(CH₂O₂)、甲醛(CH
2O)、一氧化碳(CO)、或水(H
2O)，其轉化後的生成物係根據催化劑的不同而改變，其中，氮化物為氮化碳；碳化物能為碳化矽或活性碳；氧化物能為二氧化鈦(TiO
2)、鍺鋅氧化物、鈷鍺氧化物、Ni/La
2O
2CO
3、硼六氧(B
6O)之其中一種，其中，鍺鋅氧化物能為ZnGeO
2，鈷鍺氧化物能為CoGeO
2，前述氧化物能作為光催化劑，以光催化二氧化碳還原及水分解；鹽類能為矽酸鹽或金屬鈦酸鹽。
The
承上，在該實施例中，該光觸媒組合物12能接收來自大氣或其他氣體源之低濃度的二氧化碳(CO
2)氣體(即，二氧化碳約為佔該一般大氣或其他氣體源體積之350至450ppm；又，本文中術語所稱之「低濃度的二氧化碳」，代表在一定體積的氣體中，該二氧化碳之濃度為0.001%~1%，例如但不限於0.005%、0.01%、0.05%、0.1%、0.15%、0.20%、0.25%、0.3%、0.35%、0.4%、0.45%、0.5%、0.55%、0.6%、0.65%、0.7%、0.75%、0.8%、0.85%、0.9%、0.95%或1%)，在該二氧化碳淨化裝置接收光能的情況下，該光觸媒組合物12會進行光催化反應，使得該二氧化碳氣體會因光催化反應而進行分解。若以二氧化鈦 (TiO
2) 作為該光觸媒組合物12為例，經由光催化反應，可將二氧化碳轉化形成甲烷(CH
4)、一氧化碳(CO)與水(H
2O)，其反應式如下：
CO
2→ CH
4+ H
2O
承上，二氧化鈦(TiO
2)能因光照催化而形成電子(
e -)與電洞(
h +)，其反應式如下：
TiO
2 h ++
e - As mentioned above, in this embodiment, the
再者，大氣中或氣體源中的水(H 2O)會與催化產物反應，最終形成氫自由基(radicals)，其反應式如下： H 2O + h +→ OH· + H +H ++ e -→ H· Furthermore, water (H 2 O) in the atmosphere or in the gas source will react with the catalyst to eventually form hydrogen radicals. The reaction equation is as follows: H 2 O + h + → OH· + H + H + + e - → H·
又，二氧化碳會因光還原反應(photoreduction)，最終形成甲烷(CH 4)與水(H 2O)，其反應式如下： CO 2+ 2H· → CO+ H 2O ·CO 2 -+ 8H· + h +→ CH 4+ H 2O In addition, carbon dioxide will eventually form methane (CH 4 ) and water (H 2 O) due to photoreduction. The reaction equation is as follows: CO 2 + 2H· → CO+ H 2 O ·CO 2 - + 8H· + h + → CH 4 + H 2 O
另外，該光觸媒組合物12還能選自二氧化鈦(TiO
2)、碳化物、氧化物或鹽類之至少其中一種或二種以上的成分與粉體(如：麵粉、藕粉…等)或其它佐劑的組合。
In addition, the
如此，前述最終形成的產物氣體(即，甲烷、一氧化碳)能夠排出該二氧化碳淨化裝置1，並能被收集，以進行其它用途，例如，作為燃料以提供動力、照明、取暖等，或是作為顏料或染料等；且產物液體(即，水)能夠被該底板112所吸收，而不會四處溢流。In this way, the product gas (i.e., methane, carbon monoxide) finally formed can be discharged from the carbon dioxide purification device 1 and can be collected for other purposes, for example, as a fuel to provide power, lighting, heating, etc., or as a pigment or dye, etc.; and the product liquid (i.e., water) can be absorbed by the
在本發明之一第二實施例中，該光觸媒組合物12係為一未改質型光觸媒組合物及/或一改質型光觸媒組合物，且改質型光觸媒組合物與未改質型光觸媒組合物的比例為10：90至90：10，較佳地，改質型光觸媒組合物與未改質型光觸媒組合物的比例能為30：70至70：30，更佳地，改質型光觸媒組合物與未改質型光觸媒組合物的比例還能為50：50，其中，改質型光觸媒組合物能增加其在可見光波長範圍下的催化反應活性，改質型光觸媒組合物之經改質處理能為一醇化改質或一金屬化改質，該醇化改質係將二氧化鈦改質為單斜相二氧化鈦，其係利用四氯化鈦(TiCl
4)與乙二醇(C
2H
4(OH)
2)混合而得，以提供該光觸媒組合物12具有更高的比表面積，在本發明之另一實施例中，醇化改質亦能利用未改質型光觸媒組合物與乙二醇進行反應處理；金屬化改質係利用四異丙基化鈦、硝酸與金屬(如：銅、鉻、鐵…等)混合形成，以降低電子-電洞分離時所需要的激發光子能量，在本發明之另一實施例中，金屬化改質亦能利用未改質型光觸媒組合物與硝酸金屬化合物進行反應處理，如此，該二氧化碳淨化裝置1在可見光環境促進改質型光觸媒組合物進行催化反應，在紫外光環境對於未改質型光觸媒組合物增加催化反應活性，大幅提升了二氧化碳光分解機制的效率；在本發明之一第三實施例中，該光觸媒組合物12還能添加一抗菌組成物，而能進一步提供抗菌功效；本文中術語「抗菌組成物」係指以該物質可直接與病毒或是細菌構造產生反應，使該病毒或是細菌無法自行表現出生命現象者；其包含但不限於石墨烯、二硫化鉬、二硫化鎢、三氧化鉬、二氧化釕、二氧化錳、硒化鉍和金屬奈米粒子；其中，金屬奈米粒子可包含功能性金屬奈米粒子；於較佳實施例中，該金屬奈米粒子較佳為銀奈米粒子與氧化鋅奈米粒子；功能性金屬奈米粒則係將上述金屬奈米粒子進行表面修飾，使能進一步有更佳之抗菌效果，例如但不限於表面修飾抗菌胜肽。
In a second embodiment of the present invention, the
請參閱圖2所示，該二氧化碳淨化裝置1還包含一光電轉換裝置2，該光電轉換裝置2能為一太陽能板；於此實施態樣中該光電轉換裝置2係為該二氧化碳淨化裝置1之本體11，該光觸媒組合物12 係局部設置於該光電轉換裝置2的表面，且集中設置於該光電轉換裝置2表面之中央區域(但不以此為限)，該光電轉換裝置2能將光能轉換成電能，以在該二氧化碳淨化裝置1分解淨化二氧化碳的同時，光電轉換裝置2能產生淨化能源(即，電能)，達到兼顧環境永續的功效；再者，在本發明之另一實施例中，該光觸媒組合物12局部設置於該光電轉換裝置2的表面，該光電轉換裝置2能將光能轉換成電能，且電氣連接至該本體1或傳輸至一額外之儲電裝置(圖中未示)，以傳輸電能至該二氧化碳淨化裝置1或該儲電裝置中；在本發明之又一實施例中，該光電轉換裝置2位於該頂板111與該底板112之間，該光觸媒組合物12則局部設置於該光電轉換裝置2的表面。請參閱圖3所示，該光觸媒組合物12還設置於該光電轉換裝置2表面之鄰近相對兩側的位置，且能間隔設置，以能增加不同位置的接觸表面積。Please refer to FIG. 2 , the carbon dioxide purification device 1 further includes a photoelectric conversion device 2, which can be a solar panel; in this embodiment, the photoelectric conversion device 2 is the body 11 of the carbon dioxide purification device 1, and the photocatalyst composition 12 is locally disposed on the surface of the photoelectric conversion device 2, and is centrally disposed in the central area of the surface of the photoelectric conversion device 2 (but not limited thereto), and the photoelectric conversion device 2 can convert light energy into electrical energy, so that when the carbon dioxide purification device 1 decomposes and purifies carbon dioxide, the photoelectric conversion device 2 can generate purification energy (i.e., electrical energy), thereby achieving the effect of taking into account environmental sustainability; furthermore, in another embodiment of the present invention, the photocatalyst composition 12 is locally disposed on the surface of the photoelectric conversion device 2, and is centrally disposed in the central area of the surface of the photocatalyst 2 (but not limited thereto), and the photocatalyst composition 12 can convert light energy into electrical energy, so that when the carbon dioxide purification device 1 decomposes and purifies carbon dioxide, the photocatalyst composition 2 can generate purification energy (i.e., electrical energy), thereby achieving the effect of taking into account environmental sustainability; furthermore, in another embodiment of the present invention, the photocatalyst composition 12 is locally disposed on the surface of the photocatalyst 12, and the photocatalyst composition 12 is locally disposed on the surface of the photocatalyst ... The photoelectric conversion device 2 is disposed on the surface of the photoelectric conversion device 2, and the photoelectric conversion device 2 can convert light energy into electrical energy, and is electrically connected to the body 1 or transmitted to an additional power storage device (not shown in the figure) to transmit the electrical energy to the carbon dioxide purification device 1 or the power storage device; in another embodiment of the present invention, the photoelectric conversion device 2 is located between the
請參閱圖4所示，該光電轉換裝置2還能與一照明裝置3相連接，該照明裝置3能為紫外光或可見光燈具；且於較佳之實施態樣中在該光電轉換裝置2係與該照明裝置3電氣連接，因此該光電轉換裝置2能將光能轉換成電能，以提供該照明裝置3電能，使得該光電轉化裝置2能在具有日照的時間，將光能轉換成電能，以對於該照明裝置3在不具日照的時間，藉由該光電轉化裝置2提供的電能發光，進而在不具日照的情況下，該二氧化碳淨化裝置1亦能對二氧化碳進行光分解反應。Please refer to Figure 4. The photoelectric conversion device 2 can also be connected to a lighting device 3, and the lighting device 3 can be an ultraviolet light or visible light lamp; and in a preferred embodiment, the photoelectric conversion device 2 is electrically connected to the lighting device 3, so that the photoelectric conversion device 2 can convert light energy into electrical energy to provide electrical energy to the lighting device 3, so that the photoelectric conversion device 2 can convert light energy into electrical energy during the sunshine period, so that the lighting device 3 can emit light by the electrical energy provided by the photoelectric conversion device 2 during the absence of sunshine, and thus the carbon dioxide purification device 1 can also perform a photodecomposition reaction on carbon dioxide in the absence of sunshine.
請參閱圖5所示，此為本發明之另一實施態樣；在此實施態樣中，該二氧化碳淨化裝置1可為一燈具裝置4，該燈具裝置4為一燈泡，且該燈泡的波長範圍能為紫外光或可見光範圍，其中，作為該二氧化碳淨化裝置1之本體11者為該燈具裝置4之一殼體41，且該光觸媒組合物12係局部塗佈於該燈具裝置4之殼體41外側，以形成一燈泡塗層，令該燈具裝置4發光時，該光觸媒組合物12能接收到光能，以對於二氧化碳進行光分解反應；再者，燈具裝置4亦能如同前實施態樣之照明裝置3一般，其能進一步與一光電轉換裝置電氣連接(圖中未示)，使得光電轉換裝置傳輸電能至燈具裝置4，此外，同前實施態樣，如於該光電轉換裝置局部設置有光觸媒組合物且燈具裝置4之殼體41外側亦局部塗佈有光觸媒組合物的情況下，能大幅提升該二氧化碳淨化裝置的光分解作用表面積，並藉由燈具裝置4，在可見光及/或紫外光的環境下，能分別增加改質型光觸媒組合物或未改質型光觸媒組合物的催化反應活性。Please refer to FIG. 5 , which is another embodiment of the present invention. In this embodiment, the carbon dioxide purification device 1 can be a lamp device 4, and the lamp device 4 is a bulb, and the wavelength range of the bulb can be ultraviolet light or visible light. The
綜上所述，透過本發明的二氧化碳淨化裝置1，無論在紫外光或可見光波長範圍，皆能提供二氧化碳光催化反應，進而生成甲烷與水，且光觸媒組合物12經改質處理後，能夠克服習知之光觸媒物質大多需在紫外光的環境下進行催化反應，本發明之二氧化碳淨化裝置1能在可見光環境及紫外光環境下均能提升催化反應活性，故，本發明的二氧化碳淨化裝置1還大幅提升二氧化碳光分解機制的效率。按，以上所述，僅係本發明之較佳實施例，惟，本發明所主張之權利範圍，並不侷限於此，按凡熟悉該項技藝人士，依據本發明所揭露之技術內容，可輕易思及之等效變化，均應屬不脫離本發明之保護範疇。In summary, the carbon dioxide purification device 1 of the present invention can provide a photocatalytic reaction of carbon dioxide in either the ultraviolet light or visible light wavelength range to generate methane and water. After the
1:二氧化碳淨化裝置 11:本體 111:頂板 112:底板 12:光觸媒組合物 2:光電轉換裝置 3:照明裝置 4:燈具裝置 41:殼體 1: Carbon dioxide purification device 11: Main body 111: Top plate 112: Bottom plate 12: Photocatalyst composition 2: Photoelectric conversion device 3: Lighting device 4: Lamp device 41: Casing
圖1係本發明之二氧化碳淨化裝置的爆炸示意圖。FIG. 1 is a schematic diagram of an explosion of the carbon dioxide purification device of the present invention.
圖2係本發明之二氧化碳淨化裝置應用於太陽能板之第一實施例的俯視示意圖。FIG. 2 is a schematic top view of a first embodiment of the carbon dioxide purification device of the present invention applied to a solar panel.
圖3係本發明之二氧化碳淨化裝置應用於太陽能板之第二實施例的平面示意圖。FIG3 is a schematic plan view of a second embodiment of the carbon dioxide purification device of the present invention applied to a solar panel.
圖4係本發明之二氧化碳淨化裝置應用於太陽能板並與照明裝置相連接之第三實施例的平面示意圖。FIG4 is a schematic plan view of a third embodiment of the carbon dioxide purification device of the present invention applied to a solar panel and connected to a lighting device.
圖5係本發明之二氧化碳淨化裝置應用於燈具裝置的示意圖。FIG5 is a schematic diagram showing the carbon dioxide purification device of the present invention being applied to a lighting device.
1:二氧化碳淨化裝置 1: Carbon dioxide purification device
11:本體 11: Body
111:頂板 111: Top plate
112:底板 112: Base plate
12:光觸媒組合物 12: Photocatalyst composition
Claims (6)
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| TW111126135A TWI844885B (en) | 2022-07-12 | 2022-07-12 | Carbon dioxide purification device |
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| TW111126135A TWI844885B (en) | 2022-07-12 | 2022-07-12 | Carbon dioxide purification device |
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| TWI844885B true TWI844885B (en) | 2024-06-11 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004209359A (en) * | 2002-12-27 | 2004-07-29 | Toshiba Lighting & Technology Corp | Photocatalyst, lamp, and lighting equipment |
| CN104607039A (en) * | 2015-01-20 | 2015-05-13 | 济南木齐健康科技有限公司 | Composite material with anti-bacterial and purifying functions and preparation method of composite material |
| CN107088397A (en) * | 2017-05-02 | 2017-08-25 | 常州大学 | A kind of silicate clay/small size nitridation carbon composite and preparation method thereof |
| CN111659434A (en) * | 2020-05-08 | 2020-09-15 | 东北大学 | CuO nanosheet/g-C3N4Preparation method and application of nanosheet heterojunction composite material |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004209359A (en) * | 2002-12-27 | 2004-07-29 | Toshiba Lighting & Technology Corp | Photocatalyst, lamp, and lighting equipment |
| CN104607039A (en) * | 2015-01-20 | 2015-05-13 | 济南木齐健康科技有限公司 | Composite material with anti-bacterial and purifying functions and preparation method of composite material |
| CN107088397A (en) * | 2017-05-02 | 2017-08-25 | 常州大学 | A kind of silicate clay/small size nitridation carbon composite and preparation method thereof |
| CN111659434A (en) * | 2020-05-08 | 2020-09-15 | 东北大学 | CuO nanosheet/g-C3N4Preparation method and application of nanosheet heterojunction composite material |
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| TW202402392A (en) | 2024-01-16 |
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