TWI779813B - Combustion method for reducing exhaust gas contents - Google Patents

Combustion method for reducing exhaust gas contents Download PDF

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TWI779813B
TWI779813B TW110132666A TW110132666A TWI779813B TW I779813 B TWI779813 B TW I779813B TW 110132666 A TW110132666 A TW 110132666A TW 110132666 A TW110132666 A TW 110132666A TW I779813 B TWI779813 B TW I779813B
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boiler
combustion
combustion method
liquid fuel
reducing exhaust
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TW202311664A (en
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邱灯松
洪文承
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泰鋒染化工業股份有限公司
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Abstract

A combustion method for reducing exhaust gas contents, comprising the following steps: providing a liquid fuel in a boiler and burning the liquid fuel under a normal pressure until a vapor pressure of the boiler reaches 3 Kg/cm 2; then adding a combustion improvement in the boiler and continuously burning the boiler and maintaining a vapor pressure of the boiler at 3-5 Kg/cm 2; and making the boiler heat a medium when the vapor pressure of the boiler is between 3-5 Kg/cm 2, and measuring exhaust gas contents of the boiler.

Description

降低廢氣排放的燃燒方法Combustion methods to reduce exhaust emissions

本發明係關於燃料領域,且特別是關於適用於鍋爐之一種降低廢氣排放的燃燒方法。The invention relates to the field of fuel, and in particular to a combustion method suitable for boilers to reduce exhaust emissions.

鍋爐是國民經濟中重要的熱能供應設備。電力、機械、冶金、化工、紡織、造紙、食品等行業,以及工業和民用採暖都會使用到鍋爐。Boilers are important heat supply equipment in the national economy. Boilers are used in electric power, machinery, metallurgy, chemical industry, textile, papermaking, food and other industries, as well as industrial and civil heating.

鍋爐主要係藉由燃燒燃料的過程,穩定且連續地將燃料中的化學能轉變為熱能,利用此熱能再將水或熱媒加熱,以作為乾燥或加熱的熱源,或是動力來源。The boiler mainly converts the chemical energy in the fuel into thermal energy stably and continuously through the process of burning fuel, and uses this thermal energy to heat water or heat medium as a heat source for drying or heating, or a power source.

然而,雖然鍋爐的使用帶來廠務運作的便利,但也伴隨環境問題的產生。舉例來說,於燃料的燃燒不完全情況下鍋爐所排放出的硫氧化物(SOx)、氮氧化物(NOx)、一氧化碳(CO)及二氧化碳(CO 2)等廢氣增加溫室效應導致全球暖化,造成環境的嚴重污染,且燃燒後產生的超細懸浮微粒(PM2.5)使得空氣品質下降,同時會危害人體健康。 However, although the use of boilers brings convenience to factory operations, it is also accompanied by environmental problems. For example, in the case of incomplete combustion of fuel, exhaust gases such as sulfur oxides (SOx), nitrogen oxides (NOx), carbon monoxide (CO) and carbon dioxide (CO 2 ) emitted by boilers increase the greenhouse effect and lead to global warming , causing severe environmental pollution, and the ultrafine suspended particles (PM2.5) produced after combustion degrades air quality and endangers human health.

因此,發展出符合環保法規且更低廢氣排放的燃燒方法成為當要之務。Therefore, it is imperative to develop combustion methods that comply with environmental regulations and have lower exhaust emissions.

有鑑於此,本發明提供了適用於鍋爐之一種降低廢氣排放的燃燒方法,藉由調整燃燒方法以提供符合環保法規、更低廢氣排放及兼顧公共安全的燃燒方法。In view of this, the present invention provides a combustion method suitable for boilers to reduce waste gas emissions. By adjusting the combustion method, a combustion method that complies with environmental protection regulations, lower waste gas emissions and public safety is provided.

依據一實施例,本發明之降低廢氣排放的燃燒方法,包括下列步驟: 於一鍋爐內提供一液態燃料,於常壓下燃燒該液態燃料至該鍋爐的蒸氣壓力至3 Kg/cm 2; 接著於該鍋爐內加入一燃燒改進劑,繼續於該鍋爐內進行燃燒,並維持該鍋爐的蒸氣壓力於3-5 Kg/cm 2;以及 於該鍋爐的蒸氣壓力介於3-5 Kg/cm 2下使該鍋爐加熱一介質,並量測該鍋爐之排放廢氣。 According to one embodiment, the combustion method for reducing exhaust emissions of the present invention includes the following steps: providing a liquid fuel in a boiler, and burning the liquid fuel under normal pressure until the steam pressure of the boiler reaches 3 Kg/cm 2 ; then Add a combustion improver to the boiler, continue to burn in the boiler, and maintain the steam pressure of the boiler at 3-5 Kg/cm 2 ; and the steam pressure of the boiler is between 3-5 Kg/cm 2 Let the boiler heat a medium, and measure the boiler exhaust gas.

於一實施例中,該液態燃料為低硫燃料油。In one embodiment, the liquid fuel is low sulfur fuel oil.

於一實施例中,該燃燒改進劑為水蒸氣。In one embodiment, the combustion modifier is water vapor.

於一實施例中,該低硫燃料油為包含如棕櫚油之植物性油脂的燃料油。In one embodiment, the low-sulfur fuel oil is a fuel oil comprising vegetable oil such as palm oil.

於一實施例中,該液態燃料是於介於100-120公升/小時的速率提供,而該燃燒改進劑是於介於30-40 公斤/小時的速率提供。In one embodiment, the liquid fuel is provided at a rate of 100-120 liters/hour, and the combustion improver is provided at a rate of 30-40 kg/hour.

請參照表一,顯示了行政院環境保護署所公布的自中華民國一百零九年七月一日起適用於新設鍋爐與既存鍋爐所應遵守的鍋爐空氣污染物排放標準。Please refer to Table 1, which shows the boiler air pollutant emission standards that should be complied with by new boilers and existing boilers since July 1, 2009, announced by the Environmental Protection Agency of the Executive Yuan.

表一: 鍋爐空氣污染物排放標準 空氣污染物 排放管道標準 粒狀污染物 三十 mg/Nm 3 硫氧化物 五十 ppm 氮氧化物 一百 ppm Table 1: Boiler Air Pollutant Emission Standards air pollutants Discharge Pipeline Standards particulate pollutants 30 mg/Nm 3 SOx fifty ppm Nitrogen oxides one hundred ppm

請參考圖1,顯示了依據本發明一實施例的一種降低廢氣排放的燃燒方法。如圖1所示,本發明的降低廢氣排放的燃燒方法適用於鍋爐中燃燒使用,包括下列步驟:Please refer to FIG. 1 , which shows a combustion method for reducing exhaust emissions according to an embodiment of the present invention. As shown in Figure 1, the combustion method for reducing waste gas emission of the present invention is suitable for combustion use in the boiler, comprises the following steps:

步驟S10:於一鍋爐內提供一液態燃料,於常壓下燃燒該液態燃料至該鍋爐的蒸氣壓力至3 Kg/cm 2Step S10: providing a liquid fuel in a boiler, burning the liquid fuel under normal pressure until the steam pressure of the boiler reaches 3 Kg/cm 2 ;

步驟S20: 接著於該鍋爐內加入一燃燒改進劑,繼續於該鍋爐內進行燃燒,並維持該鍋爐的蒸氣壓力於3-5 Kg/cm 2;以及 Step S20: Then add a combustion improver to the boiler, continue to burn in the boiler, and maintain the steam pressure of the boiler at 3-5 Kg/cm 2 ; and

步驟S30:於該鍋爐的蒸氣壓力介於3-5 Kg/cm 2下使該鍋爐加熱一介質,並量測該鍋爐之排放廢氣。 Step S30: Heat a medium in the boiler when the steam pressure of the boiler is 3-5 Kg/cm 2 , and measure the exhaust gas of the boiler.

於一實施例中,本發明的該液態燃料為低硫燃料油,該燃燒改進劑為水蒸氣,該介質為水。較佳的,該低硫燃料油為包含如棕櫚油之植物性油脂的燃料油。In one embodiment, the liquid fuel of the present invention is low-sulfur fuel oil, the combustion improver is water vapor, and the medium is water. Preferably, the low-sulfur fuel oil is fuel oil containing vegetable oil such as palm oil.

於一實施例中,於步驟S10中,該液態燃料是於介於100-120公升/小時的速率提供,而於步驟S20中,該燃燒改進劑是於介於30-40 公斤/小時的速率提供。In one embodiment, in step S10, the liquid fuel is provided at a rate of 100-120 liters/hour, and in step S20, the combustion improver is provided at a rate of 30-40 kg/hour supply.

於一實施例中,該液態燃料是用於燃燒以加熱該介質的作用,而該燃燒改進劑是用於降低該鍋爐內火焰溫度,藉以減少燃燒過程中硫氧化物(SOx)與氮氧化物(NOx)的生成。In one embodiment, the liquid fuel is used for combustion to heat the medium, and the combustion improver is used to reduce the flame temperature in the boiler, thereby reducing sulfur oxides (SOx) and nitrogen oxides in the combustion process (NOx) formation.

以下,將藉由數種實施例示例說明本發明之燃燒方法的具體實施方式,熟習此技藝者可經由本說明書之內容輕易地了解本發明所能達成之優點與功效,並且於不悖離本發明之精神下進行各種修飾與變更,以施行或應用本發明之內容。Below, several examples will be used to illustrate the specific implementation of the combustion method of the present invention. Those skilled in the art can easily understand the advantages and effects that the present invention can achieve through the contents of this specification, and without departing from this specification Various modifications and changes are made under the spirit of the invention to implement or apply the content of the invention.

請參照表二、表三與表四,分別顯示了在以下實施例1-2中,採用本發明的燃燒方法中使用包括低壓式油泵與燃燒機的6噸臥式煙管鍋爐燃燒實施例1-2的燃料油時透過手提式偵測儀器量測未經過廢氣處裡設備(如洗滌塔)處理的煙氣中的污染物數據。Please refer to Table 2, Table 3 and Table 4, respectively showing in the following embodiments 1-2, adopting the combustion method of the present invention to use 6 tons of horizontal smoke tube boiler combustion embodiment 1- comprising low-pressure oil pump and burner 2. When fuel oil is used, a portable detection instrument is used to measure the pollutant data in the flue gas that has not been treated by exhaust gas treatment equipment (such as a scrubber).

所用設備型號 : 1. 6噸臥式煙管鍋爐:隆全鍋爐產製; 2. 油泵: 合永興機械廠產製; 3. 手提式偵測儀器:  法國KIMO產製(型號KGAZ310)。 Device model used: 1. 6-ton horizontal smoke tube boiler: Manufactured by Longquan Boiler; 2. Oil pump: Manufactured by Heyongxing Machinery Factory; 3. Portable detection instrument: Manufactured by KIMO, France (model KGAZ310).

所使用的燃料組成物中成分: 1. 特種低硫燃料油: 購自台灣中油股份有限公司;以及 2. 工業用低硫燃料油:購自環宇國際能源股份有限公司(油品編號UNI-65527864)。 Components of the fuel composition used: 1. Special low-sulfur fuel oil: purchased from Taiwan Petroleum Corporation; and 2. Industrial low-sulfur fuel oil: purchased from Universal International Energy Co., Ltd. (oil number UNI-65527864).

實施例1:Example 1:

於本實施例中,採用前述6噸臥式煙管鍋爐執行圖1所示的燃燒方法,並提供前述特種低硫燃料油作為液態燃料,該液態燃料是於110公升/小時的速率提供,該燃燒改進劑是於30 公斤/小時的速率提供,並藉由前述手提式偵測儀器測得下述表二的空氣物染物數據。In this embodiment, the above-mentioned 6-ton horizontal smoke tube boiler is used to implement the combustion method shown in Figure 1, and the above-mentioned special low-sulfur fuel oil is provided as the liquid fuel, and the liquid fuel is provided at a rate of 110 liters/hour. The improver is provided at a rate of 30 kg/hour, and the air pollutant data in the following Table 2 are measured by the aforementioned portable detection equipment.

表二: 空氣污染物項目 數據 硫氧化物 19 ppm 氮氧化物 45 ppm Table II: Air Pollutant Project data SOx 19 ppm Nitrogen oxides 45 ppm

實施例2:Example 2:

於本實施例中,採用前述6噸臥式煙管鍋爐執行圖1所示的燃燒方法,並提供前述工業用低硫燃料油作為液態燃料,該液態燃料是於110公升/小時的速率提供,該燃燒改進劑是於30 公斤/小時的速率提供,並藉由前述手提式偵測儀器測得下述表二的空氣物染物數據。In this embodiment, the aforementioned 6-ton horizontal smoke tube boiler is used to implement the combustion method shown in Figure 1, and the aforementioned industrial low-sulfur fuel oil is provided as the liquid fuel, and the liquid fuel is provided at a rate of 110 liters/hour. The combustion improver was provided at a rate of 30 kg/hour, and the air pollutant data in Table 2 below was measured by the aforementioned portable detection instrument.

表三: 空氣污染物項目 數據 硫氧化物 0 ppm 氮氧化物 30   ppm Table three: Air Pollutant Project data SOx 0 ppm Nitrogen oxides 30 ppm

綜合上述表二至表三的廢氣排放的數據可知,本發明的燃燒方法提供了適用於降低廢氣排放的一種燃燒方法,其可減少燃燒後的硫氧化物(SOx)與氮氧化物(NOx)等空氣物染物的生成,使得量測廢氣排放中硫氧化物(SOx)與氮氧化物(NOx)等的數據符合行政院環境保護署所公布最新鍋爐空氣污染物排放標準。如此可解決傳統鍋爐的操作方法所遭遇的空氣汙染物超標和超排放超細懸浮微粒的問題,達到減少燃燒後的黑煙排放的排放量。Based on the exhaust emission data in the above Tables 2 to 3, it can be seen that the combustion method of the present invention provides a combustion method suitable for reducing exhaust emissions, which can reduce sulfur oxides (SOx) and nitrogen oxides (NOx) after combustion. The generation of air pollutants, such as sulfur oxides (SOx) and nitrogen oxides (NOx) in the exhaust gas emissions, makes the data in line with the latest boiler air pollutant emission standards announced by the Environmental Protection Agency of the Executive Yuan. In this way, the problems of excessive air pollutants and super-emission of ultra-fine suspended particles encountered in the operation method of traditional boilers can be solved, and the emission of black smoke after combustion can be reduced.

另外,鑒於本發明所提供的燃燒方法適用於既存鍋爐使用,不須額外建置新的設備,也無須對既有鍋爐進行改造,因而避免了將鍋爐系統改成採用如天然氣之易燃易爆閃火點低的新型燃料時所遭遇的新管線或儲槽的建置所可能遭遇的如使用不慎、天然氣洩漏等額外工安問題,進而提供了工廠於新設鍋爐或使用既存鍋爐一種安全、方便與經濟的降低廢氣排放的燃燒方法。In addition, in view of the fact that the combustion method provided by the present invention is suitable for use in existing boilers, there is no need to build additional new equipment, and it is not necessary to modify existing boilers, thus avoiding changing the boiler system to use flammable and explosive fuels such as natural gas. The construction of new pipelines or storage tanks may encounter additional industrial safety problems such as careless use and natural gas leakage when using new fuels with low flash points, thus providing a safe and A convenient and economical combustion method for reducing exhaust emissions.

綜上所述,雖然本發明已用較佳實施例揭露如上,然其並非用以限定本發明,本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。In summary, although the present invention has been disclosed as above with preferred embodiments, it is not intended to limit the present invention. Those with ordinary knowledge in the technical field of the present invention can, without departing from the spirit and scope of the present invention, Various changes and modifications are made, so the scope of protection of the present invention should be defined by the scope of the appended patent application.

S10:步驟 S20:步驟 S30:步驟S10: step S20: step S30: step

圖1為依據本發明一實施例的一種降低廢氣排放的燃燒方法。Fig. 1 is a combustion method for reducing exhaust emissions according to an embodiment of the present invention.

S10:步驟 S10: step

S20:步驟 S20: step

S30:步驟 S30: step

Claims (5)

一種降低廢氣排放的燃燒方法,包括下列步驟: 於一鍋爐內提供一液態燃料,於常壓下燃燒該液態燃料至該鍋爐的蒸氣壓力至3 Kg/cm 2; 接著於該鍋爐內加入一燃燒改進劑,繼續於該鍋爐內進行燃燒,並維持該鍋爐的蒸氣壓力於3-5 Kg/cm 2;以及 於該鍋爐的蒸氣壓力介於3-5 Kg/cm 2下使該鍋爐加熱一介質,並量測該鍋爐之排放廢氣。 A combustion method for reducing waste gas emissions, comprising the following steps: providing a liquid fuel in a boiler, burning the liquid fuel at normal pressure until the vapor pressure of the boiler reaches 3 Kg/cm 2 ; then adding a combustion gas in the boiler Improver, continue to burn in the boiler, and maintain the steam pressure of the boiler at 3-5 Kg/cm 2 ; and make the boiler heat a medium when the steam pressure of the boiler is 3-5 Kg/cm 2 , and measure the exhaust gas of the boiler. 如請求項1所述的降低廢氣排放的燃燒方法,其中該液態燃料為低硫燃料油。The combustion method for reducing exhaust emissions as claimed in claim 1, wherein the liquid fuel is low-sulfur fuel oil. 如請求項2所述的降低廢氣排放的燃燒方法,其中該低硫燃料油為包含棕櫚油的燃料油。The combustion method for reducing exhaust emissions according to claim 2, wherein the low-sulfur fuel oil is fuel oil containing palm oil. 如請求項1所述的降低廢氣排放的燃燒方法,其中該燃燒改進劑為水蒸氣。The combustion method for reducing exhaust emissions as claimed in claim 1, wherein the combustion improver is water vapor. 如請求項1所述的降低廢氣排放的燃燒方法,其中該液態燃料是於介於100-120公升/小時的速率提供,而該燃燒改進劑是於介於30-40 公斤/小時的速率提供。The combustion method for reducing exhaust emissions as claimed in claim 1, wherein the liquid fuel is provided at a rate of 100-120 liters/hour, and the combustion improver is provided at a rate of 30-40 kg/hour .
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TWI848585B (en) * 2023-02-24 2024-07-11 泰鋒染化工業股份有限公司 Combustion method for controlling and monitoring exhaust gas emissions in boilers
EP4421383A1 (en) * 2023-02-24 2024-08-28 Oriental Giant Dyes & Chemical Ind. Corp. Combustion method for controlling and monitoring exhaust gas emissions in boilers

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