TWI774346B - Integrated circuit structure and method of forming the same - Google Patents

Integrated circuit structure and method of forming the same Download PDF

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Publication number
TWI774346B
TWI774346B TW110115422A TW110115422A TWI774346B TW I774346 B TWI774346 B TW I774346B TW 110115422 A TW110115422 A TW 110115422A TW 110115422 A TW110115422 A TW 110115422A TW I774346 B TWI774346 B TW I774346B
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Taiwan
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epitaxial
layer
backside
source
drain
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TW110115422A
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Chinese (zh)
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TW202209564A (en
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王培宇
黃禹軒
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台灣積體電路製造股份有限公司
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Priority claimed from US17/158,409 external-priority patent/US11652043B2/en
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Abstract

An integrated circuit (IC) structure includes a gate structure, a source epitaxial structure, a drain epitaxial structure, a front-side interconnection structure, a backside dielectric layer, an epitaxial regrowth layer, and a backside via. The source epitaxial structure and the drain epitaxial structure are respectively cn opposite sides of the gate structure. The front-side interconnection structure is over a front-side of the source epitaxial structure and a front-side of the drain epitaxial structure. The backside dielectric layer is over a backside of the source epitaxial structure and a backside of the drain epitaxial structure. The epitaxial regrowth layer is on the backside of a first one of the source epitaxial structure and the drain epitaxial structure. The backside via extends through the backside dielectric layer and overlaps the epitaxial regrowth layer.

Description

積體電路結構及其形成方法 Integrated circuit structure and method of forming the same

本揭露是有關於一種積體電路結構及其形成方法。 The present disclosure relates to an integrated circuit structure and a method for forming the same.

半導體工業進入奈米技術製程節點以追求更高的元件密度、更好的表現以及更低的成本,在製造與設計上遇到的挑戰導致了三維設計的發展,例如多閘極場效電晶體(field effect transistor,FET),包含鰭式場效電晶體(Fin FET)以及環繞式閘極電晶體(gate-all-around FET,GAA FET)。在Fin FET中,閘極電極鄰近通道區的三個表面,並且閘極介電層插入在兩者之間。因為閘極結構圍繞(包圍)三個表面之鰭片,電晶體本質上具有三個閘極控制穿過鰭片或通道區的電流。不幸地,第四側,通道的底部部分遠離閘極電極,並且因此不在鄰近閘極控制之下。相對地,在GAA FET中,通道層的全部表面被閘極電極圍繞,其允許通道區有 更充分的空乏並且由於陡峭的次臨界擺幅(sub-threshold current swing,SS)以及較小的汲極導引位能障降低(drain induced barrier lowering,DIBL)而導致較少的短通道效應。 The semiconductor industry moves into the nanotechnology process node in pursuit of higher component density, better performance, and lower cost. Manufacturing and design challenges have led to the development of 3D designs, such as multi-gate field effect transistors (field effect transistor, FET), including a fin field effect transistor (Fin FET) and a gate-all-around FET (GAA FET). In a Fin FET, the gate electrode is adjacent to three surfaces of the channel region, and the gate dielectric layer is interposed between the two. Because the gate structure surrounds (encloses) the fins on the three surfaces, the transistor essentially has three gates that control the current flow through the fin or channel region. Unfortunately, on the fourth side, the bottom portion of the channel is far from the gate electrode and is therefore not under adjacent gate control. In contrast, in a GAA FET, the entire surface of the channel layer is surrounded by the gate electrode, which allows the channel region to have Fuller depletion and less short channel effects due to steep sub-threshold current swing (SS) and smaller drain induced barrier lowering (DIBL).

一種積體電路結構包含閘極結構、源極磊晶結構、汲極磊晶結構、前側互連結構、後側介電層、磊晶再生長層以及後側通孔。源極磊晶結構與汲極磊晶結構分別位於閘極結構之相反兩側。前側互連結構位於源極磊晶結構的前側與汲極磊晶結構的前側上方。後側介電層位於源極磊晶結構的後側與汲極磊晶結構的後側上方。磊晶再生長層位於源極磊晶結構與汲極磊晶結構中之第一者的後側。後側通孔延伸穿過後側介電層至磊晶再生長層。 An integrated circuit structure includes a gate structure, a source epitaxial structure, a drain epitaxial structure, a front side interconnection structure, a back side dielectric layer, an epitaxial regrowth layer and a back side through hole. The source epitaxial structure and the drain epitaxial structure are respectively located on opposite sides of the gate structure. The front side interconnect structure is located above the front side of the source epitaxial structure and the front side of the drain epitaxial structure. The backside dielectric layer is located over the backside of the source epitaxial structure and the backside of the drain epitaxial structure. The epitaxial regrowth layer is located behind the first one of the source epitaxial structure and the drain epitaxial structure. The backside vias extend through the backside dielectric layer to the epitaxial regrowth layer.

一種積體電路結構包含通道層、閘極結構、源極磊晶結構、汲極磊晶結構、前側互連結構、後側通孔以及磊晶再生長層。通道層以分隔方式一個接一個地排列。閘極結構圍繞每一通道層。源極磊晶結構與汲極磊晶結構,分別位於通道層之相對的端面。前側互連結構位於源極磊晶結構之前側與汲極磊晶結構之前側上方。後側通孔位於源極磊晶結構與汲極磊晶結構中之第一者的後側上方。磊晶再生長層,位於後側通孔與源極磊晶結構與汲極磊晶結構中之第一者之間。 An integrated circuit structure includes a channel layer, a gate structure, a source epitaxial structure, a drain epitaxial structure, a front side interconnection structure, a back side through hole and an epitaxial regrowth layer. The channel layers are arranged one after the other in a spaced manner. A gate structure surrounds each channel layer. The source epitaxial structure and the drain epitaxial structure are respectively located on opposite end faces of the channel layer. The front side interconnection structure is located above the front side of the source epitaxial structure and the front side of the drain epitaxial structure. The backside via is located above the backside of the first one of the source epitaxial structure and the drain epitaxial structure. The epitaxial regrowth layer is located between the back side through hole and the first one of the source epitaxial structure and the drain epitaxial structure.

一種形成積體電路結構之方法包括:形成電晶體 在基材上方,電晶體包含第一源極/汲極磊晶結構、第二源極/汲極磊晶結構以及側向地位於第一源極/汲極磊晶結構與第二源極/汲極磊晶結構之閘極結構;移除基材之至少一部份以暴露電晶體的後側;形成後側介電層在電晶體之被暴露的後側;形成後側通孔開口在後側介電層中以暴露電晶體的第一源極/汲極磊晶結構的後側;形成磊晶再生長層在電晶體的源極/汲極磊晶結構的被暴露的後側上方;以及形成後側通孔在後側通孔開口中並且在磊晶再生長層上方。 A method of forming an integrated circuit structure comprising: forming a transistor Above the substrate, the transistor includes a first source/drain epitaxial structure, a second source/drain epitaxial structure, and laterally located on the first source/drain epitaxial structure and the second source/ gate structure of drain epitaxial structure; removing at least a part of the substrate to expose the back side of the transistor; forming a back side dielectric layer on the exposed back side of the transistor; forming a back side via opening in in the backside dielectric layer to expose the backside of the first source/drain epitaxial structure of the transistor; forming an epitaxial regrowth layer over the exposed backside of the source/drain epitaxial structure of the transistor ; and forming a backside via in the backside via opening and above the epitaxial regrowth layer.

100,100a,100b,100c:積體電路結構 100, 100a, 100b, 100c: Integrated Circuit Structures

102:凹槽 102: Groove

110:基材 110: Substrate

112:部分 112: Parts

119:開口 119: Opening

120:磊晶堆疊 120: Epitaxy stacking

122:磊晶層 122: epitaxial layer

124:磊晶層 124: epitaxial layer

130:鰭片 130: Fins

140:淺溝槽隔離結構 140: Shallow trench isolation structure

150:虛閘極結構 150: virtual gate structure

152:虛閘極介電層 152: virtual gate dielectric layer

154:虛閘極電極層 154: virtual gate electrode layer

156,912:氧化層 156,912: oxide layer

158,914:氮化層 158,914: Nitride layer

160:間隔物材料層 160: Spacer material layer

162,164:間隔物 162, 164: Spacer

170:間隔物材料層、內部間隔物 170: Spacer material layer, internal spacer

180:犧牲磊晶塞 180: Sacrificial epitaxial plug

190S:源極磊晶結構 190S: source epitaxial structure

190D:汲極磊晶結構 190D: Drain epitaxial structure

192,194:磊晶層 192,194: Epitaxy layer

200:接觸蝕刻停止層 200: Contact etch stop layer

210:層間介電層 210: Interlayer dielectric layer

220:閘極結構 220: Gate structure

222:介面層 222: interface layer

224:介電層 224: Dielectric Layer

226:閘極金屬層 226: gate metal layer

230:源極接點 230: source contact

240:汲極接點 240: drain contact

250:多層互連結構 250: Multilayer Interconnect Structure

252:前側金屬化層 252: Front side metallization

253:第一前側金屬介電層 253: first front side metal dielectric layer

254:第二前側金屬介電層 254: Second Front Metal Dielectric Layer

255:前側金屬線 255: Front side metal wire

256:前側金屬通孔 256: front side metal through hole

260:載體基板 260: Carrier substrate

270:介電層 270: Dielectric Layer

280,280’:磊晶再生長層 280, 280': epitaxial regrowth layer

290,290’:通孔間隔物 290, 290': Through hole spacers

300:後側通孔 300: Rear side through hole

310:多層互連多層互連結構 310: Multilayer Interconnection Multilayer Interconnection Structure

311:最底部後側金屬化層 311: Bottom-most backside metallization

312:上部後側金屬化層 312: Upper backside metallization

313:後側金屬間介電層 313: Backside Intermetal Dielectric Layer

314:第一後側金屬間介電層 314: first back side intermetal dielectric layer

315:金屬線 315: Metal Wire

316:第二後側金屬間介電層 316: Second rear intermetal dielectric layer

317:後側金屬線 317: rear metal wire

318:後側金屬通孔 318: Rear side metal through hole

320,320’:金屬層 320, 320': metal layer

330,330’:矽化物區 330, 330': silicide area

600:後側通孔 600: Rear side through hole

910:硬遮罩層 910: Hard mask layer

D:汲極區 D: drain region

GT1:閘極溝槽 GT1: Gate trench

M1,M2,M3,M4:方法 M1, M2, M3, M4: Method

O1,O4,O5,O5’:開口 O1, O4, O5, O5': opening

P3:遮罩 P3: Mask

R1,R2,R3:凹槽 R1, R2, R3: groove

S:源極區 S: source region

S101,S102,S103,S104,S105,S106,S107,S108,S109,S110,S111,S201,S202,S203,S204,S301,S302,S303,S304,S305,S401,S402,S403,S404,S405:方塊 S101,S102,S103,S104,S105,S106,S107,S108,S109,S110,S111,S201,S202,S203,S204,S301,S302,S303,S304,S305,S401,S402,S403,S404,S405: square

X-X,Y1-Y1,Y2-Y2,Y3-Y3:割面線 X-X, Y1-Y1, Y2-Y2, Y3-Y3: cutting line

當結合隨附諸圖閱讀時,得以自以下詳細描述最佳地理解本揭露之態樣。應注意,根據行業上之標準實務,各種特徵未按比例繪製。事實上,為了論述清楚,可任意地增大或減小各種特徵之尺寸。 Aspects of the present disclosure are best understood from the following detailed description when read in conjunction with the accompanying drawings. It should be noted that in accordance with standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or decreased for clarity of discussion.

第1圖、第2圖、第3圖、第4A圖、第5A圖、第6A圖至第7A圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的示意圖。 FIGS. 1 , 2, 3, 4A, 5A, 6A to 7A are schematic diagrams illustrating intermediate steps in manufacturing an integrated circuit structure according to one or more embodiments of the present disclosure. .

第4B圖、第5B圖、第6B圖、第7B圖、第8圖、第9圖、第10A圖、第11A圖、第12圖、第13A圖、第14A圖、第15A圖、第16A圖、第17A圖、第18A圖、第19A圖、第20A圖、第21A圖、第22A圖、第23A圖、第24A圖至第25圖為根據本揭露之一或更多個實施例之沿第一割面之製造積體電路結構的中間步驟的剖 面圖,其沿著通道的縱向方向並垂直基板的頂面。 4B, 5B, 6B, 7B, 8, 9, 10A, 11A, 12, 13A, 14A, 15A, 16A Figure 17A, Figure 18A, Figure 19A, Figure 20A, Figure 21A, Figure 22A, Figure 23A, Figure 24A to Figure 25 according to one or more embodiments of the present disclosure Section along the first section of the intermediate steps in the manufacture of the integrated circuit structure Plane view along the longitudinal direction of the channel and perpendicular to the top surface of the substrate.

第10B圖、第11B圖、第14B圖、第15B圖、第16B圖、第17B圖、第18B圖、第19B圖、第20B圖、第21B圖、第22B圖、第23B圖至第24B圖為根據本揭露之一或更多個實施例之沿第二割面之製造積體電路結構的中間步驟的剖面圖,其在源極區並且垂直通道的縱向方向。 10B, 11B, 14B, 15B, 16B, 17B, 18B, 19B, 20B, 21B, 22B, 23B to 24B Figure is a cross-sectional view of an intermediate step of fabricating an integrated circuit structure along a second cut plane, in the source region and perpendicular to the longitudinal direction of the channel, in accordance with one or more embodiments of the present disclosure.

第10C圖、第11C圖、第14C圖、第15C圖、第16C圖、第17C圖、第18C圖、第19C圖、第20C圖、第21C圖、第22C圖、第23C圖至第24C圖為根據本揭露之一或更多個實施例之沿第三割面之製造積體電路結構的中間步驟的剖面圖,其在汲極區並且垂直通道的縱向方向。 10C, 11C, 14C, 15C, 16C, 17C, 18C, 19C, 20C, 21C, 22C, 23C to 24C Figure is a cross-sectional view of an intermediate step of fabricating an integrated circuit structure along a third cut plane, which is in the drain region and perpendicular to the longitudinal direction of the channel, according to one or more embodiments of the present disclosure.

第13B圖為根據本揭露之一或更多個實施例之沿第四割面之製造積體電路結構的中間步驟的剖面圖,其在閘極區並且垂直通道的縱向方向。 13B is a cross-sectional view of an intermediate step of fabricating an integrated circuit structure along a fourth cut plane, in the gate region and perpendicular to the longitudinal direction of the channel, according to one or more embodiments of the present disclosure.

第23D圖至第24D圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的俯視圖。 FIGS. 23D-24D are top views of intermediate steps of fabricating an integrated circuit structure according to one or more embodiments of the present disclosure.

第26圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的流程圖。 26 is a flowchart of intermediate steps in fabricating an integrated circuit structure in accordance with one or more embodiments of the present disclosure.

第27A圖、第28A圖、第29A圖、第30A圖至第31圖為根據本揭露之一或更多個實施例之沿第一割面之製造積體電路結構的中間步驟的剖面圖,其沿著通道的縱向方向。 FIGS. 27A, 28A, 29A, 30A to 31 are cross-sectional views of intermediate steps of manufacturing an integrated circuit structure along a first cut plane according to one or more embodiments of the present disclosure, It is along the longitudinal direction of the channel.

第27B圖、第28B圖、第29B圖至第30B圖為根據本揭露之一或更多個實施例之沿第二割面之製造積體電路結構的中間步驟的剖面圖,其在源極區並且垂直通道的縱向方向。 FIGS. 27B , 28B, 29B to 30B are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a second cut plane according to one or more embodiments of the present disclosure. area and perpendicular to the longitudinal direction of the channel.

第27C圖、第28C圖、第29C圖至第30C圖為根據本揭露之一或更多個實施例之沿第三割面之製造積體電路結構的中間步驟的剖面圖,其在汲極區並且垂直通道的縱向方向。 FIGS. 27C, 28C, 29C to 30C are cross-sectional views of intermediate steps of manufacturing an integrated circuit structure along a third cut plane according to one or more embodiments of the present disclosure, which is at the drain electrode area and perpendicular to the longitudinal direction of the channel.

第28D圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的俯視圖。 FIG. 28D is a top view of an intermediate step of fabricating an integrated circuit structure in accordance with one or more embodiments of the present disclosure.

第32圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的流程圖。 32 is a flowchart of intermediate steps in fabricating an integrated circuit structure in accordance with one or more embodiments of the present disclosure.

第33A圖、第34A圖、第35A圖至第36圖為根據本揭露之一或更多個實施例之沿第一割面之製造積體電路結構的中間步驟的剖面圖,其沿著通道的縱向方向。 FIGS. 33A , 34A, 35A to 36 are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a first cut surface along a channel according to one or more embodiments of the present disclosure. portrait orientation.

第33B圖、第34B圖至第35B圖為根據本揭露之一或更多個實施例之沿第二割面之製造積體電路結構的中間步驟的剖面圖,其在源極區並且垂直通道的縱向方向。 FIGS. 33B , 34B to 35B are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a second cut plane, in the source region and vertical channel, according to one or more embodiments of the present disclosure. portrait orientation.

第33C圖、第34C圖至第35C圖為根據本揭露之一或更多個實施例之沿第三割面之製造積體電路結構的中間步驟的剖面圖,其在汲極區並且垂直通道的縱向方向。 FIGS. 33C , 34C to 35C are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a third cut plane, in the drain region and vertical channel, according to one or more embodiments of the present disclosure. portrait orientation.

第37圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的流程圖。 37 is a flow diagram of intermediate steps in fabricating an integrated circuit structure in accordance with one or more embodiments of the present disclosure.

第38A圖、第39A圖、第40A圖至第41圖為根據本 揭露之一或更多個實施例之沿第一割面之製造積體電路結構的中間步驟的剖面圖,其沿著通道的縱向方向。 Figure 38A, Figure 39A, Figure 40A to Figure 41 are based on the A cross-sectional view of an intermediate step of fabricating an integrated circuit structure along a first cut surface, along the longitudinal direction of the channel, is disclosed in one or more embodiments.

第38B圖、第39B圖至第40B圖為根據本揭露之一或更多個實施例之沿第二割面之製造積體電路結構的中間步驟的剖面圖,其在源極區並且垂直通道的縱向方向。 FIGS. 38B , 39B to 40B are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a second cut plane, in the source region and vertical channel, according to one or more embodiments of the present disclosure. portrait orientation.

第38C圖、第39C圖至第40C圖為根據本揭露之一或更多個實施例之沿第三割面之製造積體電路結構的中間步驟的剖面圖,其在汲極區並且垂直通道的縱向方向。 FIGS. 38C , 39C to 40C are cross-sectional views of intermediate steps of fabricating an integrated circuit structure along a third cut plane, in the drain region and vertical channel, according to one or more embodiments of the present disclosure. portrait orientation.

第42圖為根據本揭露之一或更多個實施例之製造積體電路結構的中間步驟的流程圖。 42 is a flowchart of intermediate steps in fabricating an integrated circuit structure in accordance with one or more embodiments of the present disclosure.

以下揭示內容提供用於實施所提供標的之不同特徵的許多不同實施例或實例。以下描述部件及佈置之特定實例以簡化本揭示案。當然,此些僅為實例,且並不意欲為限制性的。舉例而言,在如下描述中第一特徵在第二特徵之上或在第二特徵上形成可包括其中第一特徵與第二特徵形成為直接接觸之實施例,且亦可包括其中額外特徵可在第一特徵與第二特徵之間形成而使得第一特徵與第二特徵可不直接接觸的實施例。另外,本揭示案可在各種實例中重複元件符號及/或字母。此重複係出於簡化及清楚目的,且其自身並不表示所論述之各種實施例及/或配置之間的關係。 The following disclosure provides many different embodiments or examples for implementing different features of the provided subject matter. Specific examples of components and arrangements are described below to simplify the present disclosure. Of course, these are only examples and are not intended to be limiting. For example, in the following description a first feature is formed over or over a second feature may include embodiments in which the first feature and the second feature are formed in direct contact, and may also include embodiments in which additional features may be Embodiments formed between the first feature and the second feature such that the first feature and the second feature may not be in direct contact. Additionally, the present disclosure may repeat reference numerals and/or letters in various instances. This repetition is for simplicity and clarity, and does not in itself represent a relationship between the various embodiments and/or configurations discussed.

另外,為了描述簡單,可在本文中使用諸如 「在……下面」、「在……下方」、「下部」、「在……上方」、「上部」及其類似術語之空間相對術語,以描述如諸圖中所示的一個元件或特徵與另一(另外)元件或特徵的關係。除了諸圖中所描繪之定向以外,此些空間相對術語意欲涵蓋元件在使用中或操作中之不同定向。裝置可以其他方式定向(旋轉90度或以其他定向),且可同樣相應地解釋本文中所使用之空間相對描述詞。本文中使用的「大約」、「約」、「近似」或者「實質上」一般表示落在給定值或範圍的百分之20之中,或在百分之10之中,或在百分之5之中。本文中所給予的數字量值為近似值,表示使用的術語如「大約」、「約」、「近似」或者「實質上」在未明確說明時可以被推斷。 In addition, for simplicity of description, such as Spatially relative terms "below", "below", "lower", "above", "upper" and similar terms to describe an element or feature as shown in the figures Relationship to another (additional) element or feature. These spatially relative terms are intended to encompass different orientations of elements in use or operation in addition to the orientation depicted in the figures. The device may be otherwise oriented (rotated 90 degrees or at other orientations), and the spatially relative descriptors used herein should likewise be interpreted accordingly. As used herein, "about", "about", "approximately" or "substantially" generally means within 20 percent, or within 10 percent, or within 20 percent of a given value or range of 5. Numerical quantities given herein are approximations, indicating that the use of terms such as "about," "approximately," "approximately," or "substantially" can be inferred when not explicitly stated.

本揭露實質上有關於一種積體電路結構及其形成方法,特別是製造一種在環繞式閘極(gate-all-around,GAA)電晶體中具有位於源極區及/或汲極區下方的後側通孔之環繞式閘極電晶體。應當注意,本揭露之實施例為一種多閘極電晶體(multi-gate transistor)。多閘極電晶體包含這些閘極結構至少在通道區兩端被形成的電晶體。這些多閘極電晶體可以包含p型金屬氧化物半導體元件或n型金屬氧化物半導體元件。特定的一些實施例,基於他們的鰭狀結構,可以在本文被揭露以及介紹為鰭式場效電晶體(FinFET)。並且本文揭露的一些實施例為多閘極電晶體,被稱為環繞式閘極(GAA)元件。GAA元件包含任何具有閘極結構的元件,或部分具有閘極結構的元件,形 成在通道區的四側(例如,圍繞通道區的一部份)。本文所揭露的元件也包含一些實施例,其具有設置於(一或多個)奈米片通道、(一或多個)奈米線通道及/或其他合適之通道配置上方的通道區。本文所揭露的一些元件實施例可以具有一或多個通道區(例如,奈米片)與單一連續的閘極結構相關連。然而,本領域之技術人員應當理解本揭露之教示可以應用於單個通道(例如,單個奈米片)或任意數目的通道。本領域之技術人員應當注意其他半導體元件之實施例可以從本揭露之內容有所受益。 The present disclosure generally relates to an integrated circuit structure and a method of forming the same, and more particularly to the fabrication of a gate-all-around (GAA) transistor having a gate-all-around (GAA) transistor having a source region and/or a drain region below the Wrap-around gate transistor with backside through hole. It should be noted that the embodiment of the present disclosure is a multi-gate transistor. Multi-gate transistors include transistors in which these gate structures are formed at least across the channel region. These multi-gate transistors may comprise p-type metal oxide semiconductor elements or n-type metal oxide semiconductor elements. Certain embodiments, based on their fin structures, may be disclosed and described herein as Fin Field Effect Transistors (FinFETs). And some embodiments disclosed herein are multi-gate transistors, known as gate-all-around (GAA) devices. GAA components include any component with a gate structure, or some components with a gate structure, in the form of Formed on four sides of the channel area (eg, around a portion of the channel area). The devices disclosed herein also include embodiments having channel regions disposed over nanosheet channel(s), nanowire channel(s), and/or other suitable channel configurations. Some device embodiments disclosed herein may have one or more channel regions (eg, nanosheets) associated with a single continuous gate structure. However, those skilled in the art will understand that the teachings of the present disclosure can be applied to a single channel (eg, a single nanosheet) or any number of channels. Those skilled in the art should note that other semiconductor device embodiments may benefit from the teachings of this disclosure.

當鰭式場效電晶體(FinFET)中的鰭片寬度在縮減,通道寬度的改變可能造成遷移率損失。GAA電晶體,例如奈米片電晶體,被研究以做為鰭式場效電晶體的替代品。在奈米片電晶體中,電晶體的閘極被製作以環繞通道(例如,奈米片通道或奈米線通道)使得通道被閘極環繞或封裝。使得電晶體提升利用閘極靜電控制通道的優勢,也同時減少漏電流。 As fin widths in fin field effect transistors (FinFETs) are shrinking, the change in channel width can cause mobility loss. GAA transistors, such as nanochip transistors, are being studied as an alternative to fin-field effect transistors. In a nanochip transistor, the gate of the transistor is fabricated to surround a channel (eg, a nanochip channel or a nanowire channel) such that the channel is surrounded or encapsulated by the gate. This enables the transistor to take advantage of the gate electrostatic control channel and reduce leakage current at the same time.

在一些實施例中,後側電源線被應用,藉此為具有大量GAA電晶體的積體電路(integrated circuit,IC)結構創造更多布線空間。後側金屬通孔提供至GAA電晶體的電連接,例如連接至源極磊晶區。在本揭露的一些實施例中,在晶圓前側製程及載體晶圓連接製程之後,磊晶再生長層被形成在源極磊晶結構的後側。如此一來,磊晶再生長層相較於源極磊晶結構經歷較少熱製程,並且因此相較於源極磊晶結構具有更佳的品質,其有助於減少 位於後側通孔與磊晶再生長層之間的接觸電阻。 In some embodiments, backside power lines are applied, thereby creating more routing space for integrated circuit (IC) structures with a large number of GAA transistors. The backside metal vias provide electrical connection to the GAA transistor, eg, to the source epitaxial region. In some embodiments of the present disclosure, an epitaxial regrowth layer is formed on the backside of the source epitaxial structure after the wafer frontside process and the carrier wafer attach process. In this way, the epitaxial regrown layer undergoes less thermal process than the source epitaxial structure, and thus has better quality than the source epitaxial structure, which helps to reduce Contact resistance between the backside via and the epitaxial regrowth layer.

第1圖至第25圖繪示根據本揭露之多個實施例之形成具有多閘極元件之積體電路的中間步驟的是一圖及剖面圖。於第1圖至第25圖所呈現之步驟同時也示意性地反映在第26圖所繪示的流程圖中。本文所使用的術語「多閘極元件」被用以形容一種元件(例如,半導體電晶體),其為具有至少一些閘極材料設置於至少一通道的多個側面的元件。在一些實施例中,多閘極元件可以被稱為GAA元件或奈米片元件,其具有設置於元件的至少一通道的至少四個側面上方的閘極材料。通道區可以被稱為「奈米結構」,在本文被用以包含具有多種幾何形狀(例如,圓柱狀、棒狀、片狀,等)及多個維度的通道區。 FIGS. 1 to 25 are diagrams and cross-sectional views illustrating intermediate steps of forming an integrated circuit with multiple gate devices according to various embodiments of the present disclosure. The steps presented in FIGS. 1 to 25 are also schematically reflected in the flow chart shown in FIG. 26 . As used herein, the term "multi-gate device" is used to describe a device (eg, a semiconductor transistor) that has at least some gate material disposed on multiple sides of at least one channel. In some embodiments, a multi-gate element, which may be referred to as a GAA element or nanochip element, has gate material disposed over at least four sides of at least one channel of the element. Channel regions may be referred to as "nanostructures," as used herein to include channel regions having various geometries (eg, cylinders, rods, sheets, etc.) and dimensions.

第1圖、第2圖、第3圖、第4A圖、第5A圖、第6A圖至第7A圖為根據本揭露之一或更多個實施例之製造積體電路結構100的中間步驟的示意圖。第4B圖、第5B圖、第6B圖、第7B圖、第8圖、第9圖、第10A圖、第11A圖、第12圖、第13A圖、第14A圖、第15A圖、第16A圖、第17A圖、第18A圖、第19A圖、第20A圖、第21A圖、第22A圖、第23A圖、第24A圖至第25圖為根據本揭露之一或更多個實施例之沿第一割面(例如,第4A圖中割面線X-X)之製造積體電路結構100的中間步驟的剖面圖,其沿著通道的縱向方向並垂直基板的頂面。第10B圖、第11B圖、第14B圖、第15B圖、第16B圖、第17B圖、第18B圖、第19B圖、第 20B圖、第21B圖、第22B圖、第23B圖至第24B圖為根據本揭露之一或更多個實施例之沿第二割面(例如,第4A圖中割面線Y1-Y1)之製造積體電路結構100的中間步驟的剖面圖,其在源極區並且垂直通道的縱向方向。第10C圖、第11C圖、第14C圖、第15C圖、第16C圖、第17C圖、第18C圖、第19C圖、第20C圖、第21C圖、第22C圖、第23C圖至第24C圖為根據本揭露之一或更多個實施例之沿第三割面(例如,第4A圖中割面線Y2-Y2)之製造積體電路結構100的中間步驟的剖面圖,其在汲極區並且垂直通道的縱向方向。第13B圖為根據本揭露之一或更多個實施例之沿第四割面(例如,第4A圖中割面線Y3-Y3)之製造積體電路結構100的中間步驟的剖面圖,其在閘極區並且垂直通道的縱向方向。第23D圖至第24D圖為根據本揭露之一或更多個實施例之製造積體電路結構100的中間步驟的俯視圖。應當被理解的是,在第1圖至第25圖所表示的製程之前、過程中及之後,額外的操作可以被提供,並且以下所述的一些操作可以在方法的額外實施例中被替代或移除。操作/製程的順序是可被互換的。 FIGS. 1, 2, 3, 4A, 5A, 6A to 7A illustrate intermediate steps of fabricating an integrated circuit structure 100 according to one or more embodiments of the present disclosure. Schematic. 4B, 5B, 6B, 7B, 8, 9, 10A, 11A, 12, 13A, 14A, 15A, 16A Figure 17A, Figure 18A, Figure 19A, Figure 20A, Figure 21A, Figure 22A, Figure 23A, Figure 24A to Figure 25 according to one or more embodiments of the present disclosure A cross-sectional view of an intermediate step in the fabrication of the integrated circuit structure 100 along a first cut plane (eg, cut plane line X-X in FIG. 4A ), which is along the longitudinal direction of the channel and perpendicular to the top surface of the substrate. Fig. 10B, Fig. 11B, Fig. 14B, Fig. 15B, Fig. 16B, Fig. 17B, Fig. 18B, Fig. 19B, Fig. 19B Figure 20B, Figure 21B, Figure 22B, Figure 23B to Figure 24B are along the second secant plane (eg, the secant plane line Y1-Y1 in Figure 4A) according to one or more embodiments of the present disclosure A cross-sectional view of an intermediate step in the fabrication of the integrated circuit structure 100, in the source region and perpendicular to the longitudinal direction of the channel. 10C, 11C, 14C, 15C, 16C, 17C, 18C, 19C, 20C, 21C, 22C, 23C to 24C 4A is a cross-sectional view of an intermediate step of fabricating the integrated circuit structure 100 along a third cut plane (eg, cut plane line Y2-Y2 in FIG. 4A ), in accordance with one or more embodiments of the present disclosure. polar region and perpendicular to the longitudinal direction of the channel. 13B is a cross-sectional view of an intermediate step of manufacturing the integrated circuit structure 100 along a fourth secant plane (eg, secant line Y3-Y3 in FIG. 4A ) according to one or more embodiments of the present disclosure, which in the gate region and perpendicular to the longitudinal direction of the channel. FIGS. 23D-24D are top views of intermediate steps of fabricating an integrated circuit structure 100 according to one or more embodiments of the present disclosure. It should be understood that additional operations may be provided before, during, and after the processes represented in FIGS. 1-25 and that some of the operations described below may be substituted or substituted in additional embodiments of the method. remove. The sequence of operations/processes can be interchanged.

如本文所討論的其他方法的實施例及示例元件,應當理解部分的積體電路結構100可以藉由CMOS技術製程流程被製造,並且因此在本文中一些製程只被概略描述。進一步來說,示範性集成電路結構可以包含多種其他元件及特徵,例如其他類型的元件,例如額外的電晶體、 雙極接面電晶體、電阻、電容、電感、二極體、保險絲、靜態隨機儲存記憶體(static random access memory,SRAM)及/或其他邏輯電路等,但是其被簡化以更好地理解本揭露的概念。在一些實施例中,示範性集成電路結構包含多個半導體元件(例如,電晶體),包含PFET、NFET等,其可以被互相連接。進一步來說,應當注意製造積體電路結構100的製程步驟,包含根據第1圖至第25圖所給予的任何說明,以及本揭露所提供的方法及示例圖僅只於示意且並不旨在限制所附請求項中具體敘述的內容。 As with other method embodiments and example elements discussed herein, it should be understood that portions of the integrated circuit structure 100 may be fabricated by CMOS technology process flows, and thus some of the processes are only described in general terms herein. Further, the exemplary integrated circuit structure may include various other elements and features, such as other types of elements such as additional transistors, Bipolar junction transistors, resistors, capacitors, inductors, diodes, fuses, static random access memory (SRAM) and/or other logic circuits, etc., but are simplified for better understanding Expose concept. In some embodiments, an exemplary integrated circuit structure includes a plurality of semiconductor elements (eg, transistors), including PFETs, NFETs, etc., which may be interconnected. Further, it should be noted that the process steps for fabricating the integrated circuit structure 100, including any description given according to FIG. 1 to FIG. 25, and the method and example diagrams provided in the present disclosure are for illustration only and are not intended to be limiting The content specified in the attached claim.

第1圖為繪示初始結構的示意圖。初始結構包含磊晶堆疊120形成在基材110上方。在一些實施例中,基材110可以包含矽(Si)。另外,基材110可以包含鍺(Ge)、矽鍺(SiGe)、III-V族半導體(例如,GaAs、GaP、GaAsP、AlInAs、AlGaAs、GaInAs、InAs、GaInP、InP、InSb、及/或GaInAsP或其組合)或其他合適的半導體材料。在一些實施例中,基材110可以包含半導體上覆絕緣體(semiconductor-on-insulator,SOI)結構例如埋入式介電層。另外,基材110可以包含埋入式介電層,例如埋入式氧化(buried oxide,BOX)層,例如藉由利用稱為氧注入隔離(separation by implantation of oxygen,SIMOX)技術的方法、晶圓連接、SEG或其他合適的方法所形成之埋入式介電層。 FIG. 1 is a schematic diagram illustrating an initial structure. The initial structure includes an epitaxial stack 120 formed over the substrate 110 . In some embodiments, the substrate 110 may include silicon (Si). Additionally, the substrate 110 may include germanium (Ge), silicon germanium (SiGe), III-V semiconductors (eg, GaAs, GaP, GaAsP, AlInAs, AlGaAs, GaInAs, InAs, GaInP, InP, InSb, and/or GaInAsP or a combination thereof) or other suitable semiconductor materials. In some embodiments, the substrate 110 may include a semiconductor-on-insulator (SOI) structure such as a buried dielectric layer. Additionally, the substrate 110 may include a buried dielectric layer, such as a buried oxide (BOX) layer, such as by utilizing a method known as separation by implantation of oxygen (SIMOX), a crystal Buried dielectric layer formed by circular connection, SEG or other suitable methods.

磊晶層疊120包含被第二成分的磊晶層124插入之第一成分的磊晶層122。第一成分與第二成分可以不同。 在一些實施例中,磊晶層122為SiGe並且磊晶層124為矽(Si)。然而,其他實施例有機率包含具有不同氧化率及/或蝕刻選擇性的第一成分及第二成分。在一些實施例中,磊晶層122包含SiGe並且磊晶層124包含Si,磊晶層124的Si之氧化率小於磊晶層122的SiGe之氧化率。 The epitaxial stack 120 includes an epitaxial layer 122 of a first composition intercalated by an epitaxial layer 124 of a second composition. The first component and the second component may be different. In some embodiments, epitaxial layer 122 is SiGe and epitaxial layer 124 is silicon (Si). However, other embodiments may include first and second components having different oxidation rates and/or etch selectivities. In some embodiments, the epitaxial layer 122 includes SiGe and the epitaxial layer 124 includes Si, and the oxidation rate of Si of the epitaxial layer 124 is lower than the oxidation rate of SiGe of the epitaxial layer 122 .

多閘極電晶體的磊晶層124或其部分可以形成一或多個奈米通道。本文使用的術語「奈米結構」用以指稱奈米尺度的任何金屬部分,或至於微米尺度的任意金屬部分,並且其具有細長的形狀,不論此部分的截面形狀為何。因此,此術語同時指稱圓形及實質上為圓形的截面積之多個細長材料之部分(例如,多個奈米線)以及束或棒狀材料之部分(例如,奈米片、奈米棒)其包含,例如圓柱形狀或實質上為長方形的截面積。磊晶層124用以定義元件的單一通道或多個通道,其在下文將進一步討論。 The epitaxial layer 124 of the multi-gate transistor, or a portion thereof, may form one or more nanochannels. As used herein, the term "nanostructure" is used to refer to any metal portion on the nanoscale, or any metal portion on the micrometer scale, and which has an elongated shape, regardless of the cross-sectional shape of the portion. Thus, this term refers to both circular and substantially circular cross-sectional areas of elongated material portions (eg, nanowires) and portions of bundles or rods of material (eg, nanosheets, nanowires) rod) which comprises, for example, a cylindrical shape or a substantially rectangular cross-sectional area. The epitaxial layer 124 is used to define a single channel or multiple channels of the device, which are discussed further below.

應當注意,三層磊晶層122以及三層磊晶層124被如第1圖所繪示的交替排列,其僅出於說明性目的,並不旨在限制請求項中具體記載的內容。任意數目的磊晶層被形成在磊晶堆疊120中是可以被接受的;層的數目取決於理想的電晶體之通道區數目。在一些實施例中,磊晶層124的數目介於2至10之間。 It should be noted that the three-layer epitaxial layers 122 and the three-layer epitaxial layers 124 are alternately arranged as shown in FIG. 1 , which are only for illustrative purposes and are not intended to limit the content specifically described in the claims. It is acceptable for any number of epitaxial layers to be formed in the epitaxial stack 120; the number of layers depends on the desired number of channel regions of the transistor. In some embodiments, the number of epitaxial layers 124 is between two and ten.

在一些實施例中,每一磊晶層122具有介於約1奈米(nm)至約10nm之範圍的厚度,但也可以為其他在本揭露的各種實施例的範圍內之範圍。磊晶層122可以具有實質上平均的厚度。在一些實施例中,每一磊晶層124 具有介於約1奈米(nm)至約10nm之範圍的厚度,但也可以為其他在本揭露的各種實施例的範圍內之範圍。在一些實施例中,磊晶層124可以具有實質上平均的厚度。如下文更詳細地描述,磊晶層124可以做為(一或多個)通道區以實質上形成多閘極元件並且其厚度基於元件表現而被考量。磊晶層122在(一或多個)通道區可以最終被移除並且做為定義介於(一或多個)通道區之間的垂直距離以實質上形成多閘極元件,並且其厚度基於元件表現而被考量。因此,磊晶層122也可以被稱為犧牲層,並且磊晶層124也可以被稱為通道層。 In some embodiments, each epitaxial layer 122 has a thickness ranging from about 1 nanometer (nm) to about 10 nm, although other ranges are possible within the scope of various embodiments of the present disclosure. The epitaxial layer 122 may have a substantially average thickness. In some embodiments, each epitaxial layer 124 Has a thickness in the range of about 1 nanometer (nm) to about 10 nm, although other ranges are possible within the scope of the various embodiments of the present disclosure. In some embodiments, epitaxial layer 124 may have a substantially average thickness. As described in more detail below, epitaxial layer 124 may serve as channel region(s) to substantially form a multi-gate device and its thickness is considered based on device performance. The epitaxial layer 122 can be finally removed in the channel region(s) and used to define the vertical distance between the channel region(s) to substantially form a multi-gate device, and its thickness is based on component performance is considered. Therefore, the epitaxial layer 122 may also be referred to as a sacrificial layer, and the epitaxial layer 124 may also be referred to as a channel layer.

舉例來說,堆疊120之多個層的磊晶生長可以藉由原子束磊晶(molecular beam epitaxy,MBE)製程、有機金屬化學氣相沉積(metalorganic chemical vapor deposition,MOCVD)製程及/或其他合適的磊晶生長製程而被實施。在一些實施例中,磊晶生長層例如,磊晶層124包含與基材110相同之材料。在一些實施例中,磊晶生長層122及124包含與基材110不同的材料。如上所述,在至少一些實施例中,磊晶層122包含磊晶生長矽鍺(SiGe)層並且磊晶層124包含磊晶生長矽(Si)層。因此,在一些實施例中,磊晶層122及124皆可以具有包含其他材料,例如鍺、半導體化合物,如碳化矽、砷化鎵、磷化鎵、磷化銦、砷化銦及/或銻化銦、一種半導體合金,如SiGe、GaAsP、AlInAs、AlGaAs、InGaAs、GaInP、及/或GaInAsP或其組合。如前述討論,磊晶 層122及124的材料可以基於提供不同的氧化態及/或選擇性蝕刻特性而被選擇。在一些實施例中,磊晶層122及124為實質上不含摻雜劑(例如,具有外部摻雜濃度介於約0cm-3至約1×1018cm-3之間),舉例來說,在磊晶生長製程中沒有故意摻雜被實施。 For example, the layers of stack 120 may be epitaxially grown by a molecular beam epitaxy (MBE) process, a metalorganic chemical vapor deposition (MOCVD) process, and/or other suitable processes The epitaxial growth process is implemented. In some embodiments, an epitaxial growth layer such as epitaxial layer 124 includes the same material as substrate 110 . In some embodiments, epitaxial growth layers 122 and 124 comprise different materials than substrate 110 . As described above, in at least some embodiments, epitaxial layer 122 includes an epitaxially grown silicon germanium (SiGe) layer and epitaxial layer 124 includes an epitaxially grown silicon (Si) layer. Therefore, in some embodiments, both epitaxial layers 122 and 124 may include other materials such as germanium, semiconductor compounds such as silicon carbide, gallium arsenide, gallium phosphide, indium phosphide, indium arsenide and/or antimony Indium oxide, a semiconductor alloy such as SiGe, GaAsP, AlInAs, AlGaAs, InGaAs, GaInP, and/or GaInAsP or combinations thereof. As discussed above, the materials of epitaxial layers 122 and 124 may be selected based on providing different oxidation states and/or selective etch characteristics. In some embodiments, epitaxial layers 122 and 124 are substantially free of dopants (eg, have external dopant concentrations between about 0 cm −3 to about 1×10 18 cm −3 ), for example , no intentional doping is performed during the epitaxial growth process.

第2圖為繪示形成多個半導體鰭片130自基材110延伸之示意圖。在多種實施例中,每一鰭片130包含形成自基材110的基材部分112以及磊晶堆疊120中每一磊晶層的一部分,包含磊晶層122及124。 FIG. 2 is a schematic diagram illustrating forming a plurality of semiconductor fins 130 extending from the substrate 110 . In various embodiments, each fin 130 includes substrate portion 112 formed from substrate 110 and a portion of each epitaxial layer in epitaxial stack 120 , including epitaxial layers 122 and 124 .

在第1圖及第2圖所繪示之一些實施例中,硬遮罩(hard mask,HM)層910在圖案化鰭片130之前被形成在磊晶堆疊120上方。在一些實施例中,HM層910包含氧化層912(例如,平板氧化層可以包含SiO2)以及氮化層914(例如,平板氮化層可以包含Si3N4)形成在氧化層上方。氧化層912可以做為介於磊晶堆疊120及氮化層914之間的黏著層,並且做為蝕刻氮化層914之蝕刻終止層。在一些實施例中,HM氧化層912包含熱生長氧化物、化學氣相沉積(chemical vapor deposition,CVD)沉積氧化物及/或原子層沉積(atomic layer deposition,ALD)沉積氧化物。在一些實施例中,HM氮化層914藉由CVD及/或其他合適的技術被沉積在HM氧化層912上方。 In some embodiments shown in FIGS. 1 and 2, a hard mask (HM) layer 910 is formed over the epitaxial stack 120 before the fins 130 are patterned. In some embodiments, the HM layer 910 includes an oxide layer 912 (eg, the slab oxide layer may include SiO 2 ) and a nitride layer 914 (eg, the slab nitride layer may include Si 3 N 4 ) is formed over the oxide layer. The oxide layer 912 can serve as an adhesion layer between the epitaxial stack 120 and the nitride layer 914 and as an etch stop layer for etching the nitride layer 914 . In some embodiments, the HM oxide layer 912 includes thermally grown oxide, chemical vapor deposition (CVD) deposited oxide, and/or atomic layer deposition (ALD) deposited oxide. In some embodiments, the HM nitride layer 914 is deposited over the HM oxide layer 912 by CVD and/or other suitable techniques.

鰭片130可以實質上被以合適的製程製造,包含光微影及蝕刻製程。光微影製程可以包含形成光阻層(未示 出)在HM層910上方,暴露光阻層於圖案下,實施預暴露烘烤製程,並且顯影光阻以形成圖案化遮罩包含此光阻。在一些實施例中,圖案化光阻以形成圖案化遮罩元素可以利用電子束(electron beam,e-beam)微影製程或利用位於極紫外光(extreme ultraviolet,EUV)區的光,具有波長位於,例如約1-100nm,之極紫外光微影製程被實施。圖案化遮罩可以接著被用於保護基材110的區域,並且在區域上方形成多個層,同時蝕刻製程在未被保護區域形成凹槽102,並且其穿過HM層910、穿過磊晶堆疊120並且進入基材110,藉此留下多個延伸鰭片130。凹槽102可以利用乾式蝕刻(例如,反應離子蝕刻)、濕式蝕刻及/或其組合被蝕刻。在基材上方形成鰭片之眾多其他方法的實施例也可以被用於包含,例如,定義鰭片區域(例如,藉由遮罩或隔離區)以及在形成鰭片130時磊晶生長磊晶堆疊120。鰭片130可以利用合適的製程包含雙圖案化或多圖案化製程被製造。一般來說,雙圖案化或多圖案化結合光微影及自對準製程,允許被創造之圖案具有,例如小於利用單次、直接的光微影製程所取得之間隙的間隙。舉例來說,在一個實施例中,犧牲層被形成在基材上方並且利用光微影製程被圖案化。間隔物利用自對準製程在圖案化的犧牲層上被並排形成。犧牲層接著被移除,並且留下間隔物、或心軸,可以接著藉由蝕刻初始磊晶堆疊120被用以圖案化鰭片130。蝕刻製程可以包含乾式蝕刻、濕式蝕刻、反應離子蝕刻(reactive ion etching,RIE)及/ 或其他合適的製程。 The fins 130 may be substantially fabricated by suitable processes, including photolithography and etching processes. The photolithography process may include forming a photoresist layer (not shown) OUT) Over the HM layer 910, the photoresist layer is exposed under the pattern, a pre-exposure bake process is performed, and the photoresist is developed to form a patterned mask including the photoresist. In some embodiments, patterning photoresist to form patterned mask elements may utilize an electron beam (e-beam) lithography process or utilize light in the extreme ultraviolet (EUV) region, having wavelengths At, eg, about 1-100 nm, an EUV lithography process is performed. A patterned mask can then be used to protect regions of the substrate 110 and form multiple layers over the regions while the etch process forms recesses 102 in the unprotected regions and through the HM layer 910, through the epitaxial Stack 120 and enter substrate 110, thereby leaving a plurality of extended fins 130. The grooves 102 may be etched using dry etching (eg, reactive ion etching), wet etching, and/or combinations thereof. Embodiments of numerous other methods of forming fins over a substrate may also be used including, for example, defining fin regions (eg, by masks or isolation regions) and epitaxially growing epitaxial layers when forming fins 130 Stack 120. The fins 130 may be fabricated using suitable processes including dual patterning or multi-patterning processes. In general, dual-patterning or multi-patterning combined with photolithography and self-alignment processes allows patterns to be created with, for example, gaps smaller than those achieved with a single, direct photolithography process. For example, in one embodiment, a sacrificial layer is formed over the substrate and patterned using a photolithography process. Spacers are formed side-by-side on the patterned sacrificial layer using a self-aligned process. The sacrificial layer is then removed, leaving spacers, or mandrels, which can then be used to pattern the fins 130 by etching the initial epitaxial stack 120 . The etching process may include dry etching, wet etching, reactive ion etching (RIE) and/or or other suitable process.

第3圖繪示形成淺溝槽隔離(shallow trench isolation,STI)結構140側向地圍繞鰭片130的下部分的示意圖。做為示例而非限制本揭露之內容,介電層首先被沉積在基材110上方,利用介電材料填充凹槽102。在一些實施例中,介電層可以包含氧化矽、氮化矽、氮氧化矽、氟摻雜矽酸鹽玻璃(fluorine-doped silicate glass,FSG)、低k介電質、其組合及/或其他合適的材料。在多種示例中,介電層可以藉由CVD製程、低於大氣壓的CVD(subatmospheric CVD,SACVD)製程、可流動CVD製程、ALD製程、物理氣相沉積(physical vapor deposition,PVD)製程及/或其他合適的製程被沉積。在一些實施例中,沉積介電層之後積體電路結構100可以被退火,例如,為了提升介電層的品質。在一些實施例中,介電層(及實質上形成之STI結構140)可以包含多層結構,例如,具有一或多個襯墊層。 FIG. 3 is a schematic diagram of forming a shallow trench isolation (STI) structure 140 laterally surrounding the lower portion of the fin 130 . By way of example and not limitation of the present disclosure, a dielectric layer is first deposited over substrate 110, filling recess 102 with a dielectric material. In some embodiments, the dielectric layer may include silicon oxide, silicon nitride, silicon oxynitride, fluorine-doped silicate glass (FSG), low-k dielectrics, combinations thereof, and/or other suitable materials. In various examples, the dielectric layer may be formed by a CVD process, a subatmospheric CVD (SACVD) process, a flowable CVD process, an ALD process, a physical vapor deposition (PVD) process, and/or Other suitable processes are deposited. In some embodiments, the integrated circuit structure 100 may be annealed after deposition of the dielectric layer, eg, to improve the quality of the dielectric layer. In some embodiments, the dielectric layer (and substantially formed STI structure 140 ) may comprise a multi-layer structure, eg, with one or more liner layers.

在形成淺溝槽(STI)特徵的一些實施例中,在沉積介電層之後,沉積的介電材料被薄化並且被平坦化,例如,藉由化學機械拋光(chemical mechanical polishing,CMP)製程。在一些實施例中,HM層910(如第2圖所繪示)用於做為CMP停止層。圍繞鰭片130的STI結構140被凹入。根據第3圖之示例,STI結構140凹入提供鰭片130在STI結構140上方延伸。在一些實施例中,凹入製程可以包含乾式蝕刻製程、濕式蝕刻製程 及/或其組合。HM層910也可以在STI結構140凹入之前、進行中及/或之後被移除。HM層910之氮化層914可以被移除,例如,藉由利用H3PO4或其他合適蝕刻劑之濕式蝕刻。在一些實施例中,HM層910之氧化層912可以藉由用以凹入STI結構140之相同蝕刻劑而被移除。在一些實施例中,凹入深度被控制(例如,藉由控制蝕刻時間)以在最終獲得理想之暴露的鰭片130上部分之高度。在繪示的實施例中,理想高度暴露鰭片130之每一磊晶堆疊120中的多個層。 In some embodiments where shallow trench (STI) features are formed, after depositing the dielectric layer, the deposited dielectric material is thinned and planarized, eg, by a chemical mechanical polishing (CMP) process . In some embodiments, the HM layer 910 (as shown in Figure 2) is used as a CMP stop layer. The STI structures 140 surrounding the fins 130 are recessed. According to the example of FIG. 3 , the STI structure 140 is recessed to provide the fins 130 extending over the STI structure 140 . In some embodiments, the recessing process may include a dry etching process, a wet etching process, and/or a combination thereof. The HM layer 910 may also be removed before, during, and/or after the STI structure 140 is recessed. The nitride layer 914 of the HM layer 910 can be removed, for example, by wet etching with H3PO4 or other suitable etchant. In some embodiments, oxide layer 912 of HM layer 910 may be removed by the same etchant used to recess STI structure 140 . In some embodiments, the recess depth is controlled (eg, by controlling the etch time) to ultimately obtain the desired height of the exposed upper portion of the fins 130 . In the illustrated embodiment, the desired height exposes multiple layers in each epitaxial stack 120 of fins 130 .

根據第4A圖及第4B圖,閘極結構150被形成。在一些實施例中,閘極結構150為虛(犧牲)閘極結構,其可以被實質上移除。因此,在一些實施例中利用後閘極製程,閘極結構150為虛閘極結構並且在積體電路結構100的後續製程步驟會被最終閘極結構取代。特別提到,虛閘極結構150可以在後續製程步驟被高k介電層(high-k dielectric layer,HK)以及金屬閘極電極(metal gata electrode,MG)取代,如下文討論。在一些實施例中,虛閘極結構150被形成在基材110上方並且至少部分地設置於鰭片130上方。在虛閘極結構下方部分的鰭片130可以被稱為通道區。虛閘極結構150也可以定義鰭片130的源極/汲極(source/drain,S/D)區,例如,鰭片130的區域鄰近並且在通道區的相對兩側面。 According to FIGS. 4A and 4B, the gate structure 150 is formed. In some embodiments, gate structure 150 is a dummy (sacrificial) gate structure, which can be substantially removed. Therefore, in some embodiments using the last gate process, the gate structure 150 is a dummy gate structure and is replaced by the final gate structure in subsequent process steps of the integrated circuit structure 100 . Specifically, the dummy gate structure 150 may be replaced by a high-k dielectric layer (HK) and a metal gate electrode (MG) in subsequent process steps, as discussed below. In some embodiments, dummy gate structures 150 are formed over substrate 110 and at least partially disposed over fins 130 . The portion of the fin 130 under the dummy gate structure may be referred to as a channel region. The dummy gate structure 150 may also define source/drain (S/D) regions of the fin 130 , eg, the regions of the fin 130 are adjacent to and on opposite sides of the channel region.

在繪示的實施例中,虛閘極製造首先形成虛閘極介電層152在鰭片130上方。在一些實施例中,虛閘極 介電層152可以包含SiO2、氮化矽、高k介電材料及/或其他合適的材料。在多種實施例中,虛閘極介電層152可以藉由CVD製程、低於大氣壓的CVD(subatmospheric CVD,SACVD)製程、可流動CVD製程、ALD製程、物理氣相沉積(physical vapor deposition,PVD)製程或其他合適的製程被沉積。通過示例,虛閘極介電層152可以藉由後續製程(例如,後續製造虛閘極結構)避免鰭片130的損壞。隨後,其他閘極電極結構150的部分被形成,包含虛閘極電極層154及硬遮罩,其可以包含多個層156及158(例如,氧化層156及氮化層158)。在一些實施例中,虛閘極結構150藉由多種製程步驟例如層沉積、圖案化、蝕刻、其他合適製程步驟被形成。示例性層沉積製程包含CVD(同時包含低壓CVD及電漿增強CVD)、PVD、ALD、熱氧化、e-beam蒸鍍或其他合適的沉積技術,或其組合。在形成閘極結構之示例中,圖案化製程包含微影製程(例如,光微影或e-beam微影)其可以進一步包含光阻塗布(例如,旋塗),軟烘烤、遮罩對準、曝光、預曝光烘烤、光阻顯影、潤洗、乾燥(例如,甩乾及/或硬烘烤)、其他合適微影技術及/或其組合。在一些實施例中,蝕刻製程可以包含乾式蝕刻(例如,RIE蝕刻)、濕式蝕刻及/或其他蝕刻方法。在一些實施例中,虛閘極電極層154可以包含多晶矽(ploysilicon)。在一些實施例中,硬遮罩包含氧化層156例如平板氧化層,其可包含SiO2,以及氮化層158 例如平板氮化層,其可包含Si3N4及/或氮氧化矽。在一些實施例中,在圖案化虛閘極電極層154之後,虛閘極介電層152自鰭片130的S/D區移除。蝕刻製程可以包含濕式蝕刻、乾式蝕刻及/或其組合。蝕刻製程被選擇以選擇性蝕刻虛閘極介電層152並且不實質上蝕刻鰭片130、虛閘極電極層154、氧化層156及氮化層158。 In the illustrated embodiment, dummy gate fabrication begins by forming a dummy gate dielectric layer 152 over the fins 130 . In some embodiments, the dummy gate dielectric layer 152 may include SiO 2 , silicon nitride, high-k dielectric materials, and/or other suitable materials. In various embodiments, the dummy gate dielectric layer 152 may be formed by a CVD process, a subatmospheric CVD (SACVD) process, a flowable CVD process, an ALD process, or a physical vapor deposition (PVD) process. ) process or other suitable process is deposited. By way of example, the dummy gate dielectric layer 152 can avoid damage to the fins 130 through subsequent processes (eg, subsequent fabrication of the dummy gate structure). Subsequently, portions of other gate electrode structures 150 are formed, including a dummy gate electrode layer 154 and a hard mask, which may include multiple layers 156 and 158 (eg, oxide layer 156 and nitride layer 158). In some embodiments, the dummy gate structure 150 is formed by various process steps such as layer deposition, patterning, etching, and other suitable process steps. Exemplary layer deposition processes include CVD (including both low pressure CVD and plasma enhanced CVD), PVD, ALD, thermal oxidation, e-beam evaporation, or other suitable deposition techniques, or combinations thereof. In the example of forming the gate structure, the patterning process includes a lithography process (eg, photolithography or e-beam lithography), which may further include photoresist coating (eg, spin coating), soft bake, mask pairing calibration, exposure, pre-exposure bake, photoresist development, rinse, drying (eg, spin and/or hard bake), other suitable lithography techniques, and/or combinations thereof. In some embodiments, the etching process may include dry etching (eg, RIE etching), wet etching, and/or other etching methods. In some embodiments, the dummy gate electrode layer 154 may include polysilicon. In some embodiments, the hard mask includes an oxide layer 156, such as a slab oxide layer, which may include SiO2 , and a nitride layer 158, such as a slab nitride layer, which may include Si3N4 and/or silicon oxynitride. In some embodiments, after patterning the dummy gate electrode layer 154 , the dummy gate dielectric layer 152 is removed from the S/D regions of the fins 130 . The etching process may include wet etching, dry etching, and/or combinations thereof. The etch process is selected to selectively etch dummy gate dielectric layer 152 and not substantially etch fin 130 , dummy gate electrode layer 154 , oxide layer 156 and nitride layer 158 .

第4A圖及第4B圖繪示形成閘極間隔物162在區閘極結構150的側壁上方以及鰭片間隔物164在半導體鰭片130的側壁上方。在形成這些間隔物162、164的一些實施例中間隔物材料層160首先被沉積在基材110上方。間隔物材料層160可以為保形層,其實質上被蝕刻以形成閘極側壁間隔物162以及鰭片側壁間隔物164。在繪示的實施例中,間隔物材料層160被保形地沉積在虛閘極結構150以及鰭片130的頂部及側壁上方。在一些實施例中,間隔物材料層160包含多個層,例如第一間隔物層以及形成在第一間隔物層上方的第二間隔物層。間隔物材料層160可以包含一或多種介電材料,例如氧化矽、氮化矽、碳化矽、氮氧化矽、SiCN薄膜、碳氧化矽、SiOCN薄膜及/或其組合。通過示例,在虛閘極結構150上方沉積介電材料以形成間隔物材料層160可以藉由利用製程例如,CVD製程、低於大氣壓的CVD(subatmospheric CVD,SACVD)製程、可流動CVD製程、ALD製程、物理氣相沉積(physical vapor deposition,PVD)或其他合適製程。非等向蝕刻製程接 著被實施在沉積之間隔物材料層160上,以暴露鰭片130未被虛閘極結構150覆蓋的部分(例如,在鰭片130的源極/汲極區)。間隔物材料層160直接位於虛閘極結構150上方的部分可以藉由此非等向蝕刻製程完全被移除。間隔物材料層160位於虛閘極結構150之側壁的部分被保留以做為閘極間隔物162,並且間隔物材料層160位於半導體鰭片130之側壁的下部分被保留以做為鰭片間隔物164。 FIGS. 4A and 4B illustrate the formation of gate spacers 162 over the sidewalls of the regional gate structures 150 and fin spacers 164 over the sidewalls of the semiconductor fins 130 . In some embodiments where these spacers 162 , 164 are formed, a layer of spacer material 160 is first deposited over the substrate 110 . Spacer material layer 160 may be a conformal layer that is substantially etched to form gate sidewall spacers 162 and fin sidewall spacers 164 . In the illustrated embodiment, a layer of spacer material 160 is conformally deposited over the dummy gate structures 150 and the tops and sidewalls of the fins 130 . In some embodiments, the spacer material layer 160 includes multiple layers, such as a first spacer layer and a second spacer layer formed over the first spacer layer. The spacer material layer 160 may include one or more dielectric materials, such as silicon oxide, silicon nitride, silicon carbide, silicon oxynitride, SiCN films, silicon oxycarbide, SiOCN films, and/or combinations thereof. By way of example, a dielectric material is deposited over the dummy gate structure 150 to form the spacer material layer 160 by utilizing a process such as a CVD process, a subatmospheric CVD (SACVD) process, a flowable CVD process, ALD process, physical vapor deposition (PVD) or other suitable processes. Anisotropic etching process connection This is implemented on the layer of spacer material 160 before deposition to expose portions of the fins 130 not covered by the dummy gate structures 150 (eg, in the source/drain regions of the fins 130 ). The portion of the spacer material layer 160 directly above the dummy gate structure 150 can be completely removed by this anisotropic etching process. The portion of the spacer material layer 160 located on the sidewall of the dummy gate structure 150 is reserved as the gate spacer 162, and the lower portion of the spacer material layer 160 located on the sidewall of the semiconductor fin 130 is reserved as the fin spacer Object 164.

根據第5A圖及第5B圖,半導體鰭片130暴露的部分側向地在閘極間隔物162(例如,在源極/汲極區的鰭片130)上方延伸並且藉由利用虛閘極結構150與閘極間隔物162做為蝕刻遮罩之非等向蝕刻製程被蝕刻,最終在半導體鰭片130中以及相應的虛閘極結構150之間形成凹槽R1。在非等向蝕刻製程之後,因為非等向蝕刻之效果,犧牲層(磊晶層122)及通道層(磊晶層124)的終端表面與相應之閘極間隔物162最外側的側壁對齊。在一些實施例中,非等向蝕刻可以藉由具有電漿源及反應氣體之乾式化學蝕刻被實施。電漿源可以是電感耦合電漿(inductively coupled plasma,ICR)源、變壓器耦合電漿(transformer coupled plasma,TCP)源、電子迴旋共振(electron cyclotron resonance,ECR)源或其類似者,並且反應氣體可以是,例如,氟基氣體(例如SF6、CH2F2、CH3F、CHF3或其類似者)、氯基氣體(例如,Cl2)、溴化氫氣體(HBr)、氧氣(O2)、其類似者 或其組合。 According to FIGS. 5A and 5B, the exposed portions of the semiconductor fins 130 extend laterally over the gate spacers 162 (eg, the fins 130 in the source/drain regions) and by utilizing the dummy gate structure 150 and the gate spacer 162 are etched in an anisotropic etching process as an etching mask, and finally a groove R1 is formed in the semiconductor fin 130 and between the corresponding dummy gate structures 150 . After the anisotropic etching process, the termination surfaces of the sacrificial layer (epitaxy layer 122 ) and the channel layer (epitaxy layer 124 ) are aligned with the outermost sidewalls of the corresponding gate spacers 162 due to the effect of the anisotropic etching. In some embodiments, anisotropic etching can be performed by dry chemical etching with a plasma source and reactive gases. The plasma source can be an inductively coupled plasma (ICR) source, a transformer coupled plasma (TCP) source, an electron cyclotron resonance (ECR) source, or the like, and the reactive gas Can be, for example, fluorine based gas (eg SF6 , CH2F2 , CH3F , CHF3 or the like ) , chlorine based gas (eg Cl2), hydrogen bromide gas (HBr), oxygen ( O 2 ), the like or a combination thereof.

接著,根據第6A圖及第6B圖,犧牲層(磊晶層122)藉由合適的蝕刻製程側向地或水平地凹入,最終在相應的每一通道層(磊晶層124)之間垂直地形成側向的凹槽R2。此步驟可以藉由選擇性蝕刻製程被實施。作為示例而非限制本揭露之內容,犧牲層(磊晶層122)為SiGe並且通道層(磊晶層124)為矽允許犧牲層(磊晶層122)的選擇性蝕刻。在一些實施例中,選擇性濕式蝕刻包含APM蝕刻(例如,氫氧化氨-過氧化氨-水的混和物),其以相較於蝕刻Si更快的蝕刻率蝕刻SiGe。在一些實施例中,選擇性蝕刻包含SiGe的氧化然後去除SiGeOx。舉例來說,氧化可以藉由提供O3清潔再接續以蝕刻劑例如NH4OH以移除SiGeOx,其以相較於蝕刻Si更快的蝕刻率蝕刻SiGeOx。進一步來說,因為Si之氧化率遠小於(有時達30倍小於)SiGe之氧化率,通道層(磊晶層124)在側向凹入犧牲層(磊晶層122)的過程中實質上完好無損的被保留。最終,通道層(磊晶層124)側向地延伸通過犧牲層(磊晶層122)相對的終端表面。 Next, according to FIGS. 6A and 6B , the sacrificial layer (epitaxial layer 122 ) is recessed laterally or horizontally by a suitable etching process, finally between each corresponding channel layer (epitaxial layer 124 ) The lateral grooves R2 are formed vertically. This step can be performed by a selective etching process. By way of example and not limitation of the present disclosure, the sacrificial layer (epitaxial layer 122 ) is SiGe and the channel layer (epitaxial layer 124 ) is silicon allowing selective etching of the sacrificial layer (epitaxial layer 122 ). In some embodiments, the selective wet etch includes an APM etch (eg, an ammonium hydroxide-ammonia peroxide-water mixture) that etches SiGe at a faster etch rate than etching Si. In some embodiments, the SiGe-containing oxide is selectively etched and then SiGeOx is removed. For example, oxidation can remove SiGeOx by providing an O3 clean followed by an etchant such as NH4OH , which etches SiGeOx at a faster etch rate than etching Si. Further, since the oxidation rate of Si is much smaller (sometimes 30 times smaller) than that of SiGe, the channel layer (epitaxial layer 124 ) is substantially in the process of recessing the sacrificial layer (epitaxial layer 122 ) laterally. It is kept intact. Ultimately, the channel layer (epitaxial layer 124 ) extends laterally through the opposite terminal surface of the sacrificial layer (epitaxial layer 122 ).

接著,根據第7A圖及第7B圖,內部間隔物材料層170被形成以填充上述根據第6A圖及第6B圖所討論的犧牲層(磊晶層122)的側向蝕刻所遺留的凹槽R2。內部間隔物材料層170可以是低k介電材料,例如SiO2、SiN、SiCN或SiOCN並且可以藉由合適的沉積方法,例如ALD被形成。在內部間隔物材料層170的沉積之後, 非等向蝕刻製程可以被實施以修整被沉積的內部間隔物材料層170,使得內部間隔物材料層170只填充透過犧牲層(磊晶層122)的側向蝕刻所遺留的凹槽R2的一部分被保留。在修整製程之後,為了簡單起見,被沉積的內部間隔物材料層170被保留的部分被標示為內部間隔物170。內部間隔物170做為隨後製程中形成之源極/汲極磊晶結構的隔離金屬閘極。在第7A圖及第7B圖中之示例中,內部間隔物170的側壁與通道層(磊晶層124)的側壁對齊。 Next, according to FIGS. 7A and 7B , an internal spacer material layer 170 is formed to fill the recesses left by the side etching of the sacrificial layer (epitaxial layer 122 ) discussed above with respect to FIGS. 6A and 6B R2. The inner spacer material layer 170 may be a low-k dielectric material such as SiO 2 , SiN, SiCN or SiOCN and may be formed by a suitable deposition method such as ALD. After the deposition of the inner spacer material layer 170, an anisotropic etch process may be performed to trim the deposited inner spacer material layer 170 so that the inner spacer material layer 170 fills only through the sacrificial layer (epitaxy layer 122). A portion of the groove R2 left by the side etching remains. After the trimming process, the portion of the deposited inner spacer material layer 170 that remains is designated as inner spacer 170 for simplicity. The internal spacers 170 serve as isolation metal gates for source/drain epitaxial structures formed in subsequent processes. In the example of Figures 7A and 7B, the sidewalls of the internal spacers 170 are aligned with the sidewalls of the channel layer (epitaxial layer 124).

在一些實施例中,根據第8圖鰭片130的源極區S被進一步凹入,使得犧牲磊晶塞可以實質上地形成在凹入的源極區S中,並且接著被隨後製程的後側通孔取代。在源極區凹入步驟的一些實施例中,圖案化遮罩P3首先被形成以覆蓋鰭片130的汲極區D,但不覆蓋鰭片130的源極區S,並且接著鰭片130的源極區S被凹入,導致鰭片130的源極區凹槽R3。在一些實施例中,圖案化遮罩P3可以是藉由合適光微影製程形成的光阻遮罩。舉例來說,光微影製程可以包含如在第7A圖及第7B圖中繪示的結構上方旋塗光阻層,實施預暴露烘烤製程,以及顯影光阻層以形成圖案化遮罩P3。在一些實施例中,圖案化光阻以形成圖案化遮罩元素可以利用電子束(electron beam,e-beam)微影製程或極紫外(extreme ultraviolet,EUV)微影製程被實施。 In some embodiments, the source regions S of the fins 130 according to FIG. 8 are further recessed, so that a sacrificial epitaxial plug can be substantially formed in the recessed source regions S, and then processed by a later stage of the subsequent process. side vias are replaced. In some embodiments of the source region recessing step, the patterned mask P3 is first formed to cover the drain region D of the fin 130 but not the source region S of the fin 130 , and then the The source region S is recessed, resulting in a source region groove R3 of the fin 130 . In some embodiments, the patterned mask P3 may be a photoresist mask formed by a suitable photolithography process. For example, a photolithography process may include spin-coating a photoresist layer over the structures as depicted in Figures 7A and 7B, performing a pre-exposure bake process, and developing the photoresist layer to form the patterned mask P3 . In some embodiments, patterning the photoresist to form the patterned mask elements may be performed using an electron beam (e-beam) lithography process or an extreme ultraviolet (EUV) lithography process.

當圖案化遮罩P3被形成之後,源極區凹槽R3可 以利用,例如,非等向蝕刻製程被形成在源極區S中。在一些實施例中,非等向蝕刻可以藉由具有電漿源及反應氣體之乾式化學蝕刻被實施。作為示例而非限制本揭露之內容,電漿源可以是電感耦合電漿(inductively coupled plasma,ICR)源、變壓器耦合電漿(transformer coupled plasma,TCP)源、電子迴旋共振(electron cyclotron resonance,ECR)源或其類似者,並且反應氣體可以是,例如,氟基氣體(例如SF6、CH2F2、CH3F、CHF3或其類似者)、氯基氣體(例如,Cl2)、溴化氫氣體(HBr)、氧氣(O2)、其類似者或其組合。 After the patterned mask P3 is formed, the source region groove R3 may be formed in the source region S using, for example, an anisotropic etching process. In some embodiments, anisotropic etching can be performed by dry chemical etching with a plasma source and reactive gases. By way of example and not limitation of the present disclosure, the plasma source may be an inductively coupled plasma (ICR) source, a transformer coupled plasma (TCP) source, an electron cyclotron resonance (ECR) source ) source or the like, and the reactive gas may be, for example, a fluorine - based gas (eg, SF6 , CH2F2 , CH3F , CHF3, or the like), a chlorine - based gas (eg, Cl2 ) , Hydrogen bromide gas (HBr), oxygen ( O2 ), the like, or a combination thereof.

第9圖繪示犧牲磊晶塞180形成在源極區凹槽R3中。在此步驟的一些實施例中,以圖案化遮罩P3定位,磊晶生長製程被實施以在源極區凹槽R3中生長磊晶材料,直到磊晶材料建立犧牲磊晶塞180填充源極區凹槽R3。磊晶材料與基材110具有不同組成,因此導致犧牲磊晶塞180及基材110之間的不同蝕刻選擇性。舉例來說,基材110是矽並且犧牲磊晶塞180是SiGe。在一些實施例中,犧牲磊晶塞180是不具有p型摻雜物(例如,硼)及n型摻雜物(例如,磷)之SiGe,其原因在於犧牲磊晶塞180將在隨後製程中被移除並且不作為最終IC產品的電晶體之源極端。當犧牲磊晶塞180形成完成之後,圖案化遮罩P3藉由,例如,灰化被移除。 FIG. 9 shows that the sacrificial epitaxial plug 180 is formed in the source region groove R3. In some embodiments of this step, with the patterned mask P3 positioned, an epitaxial growth process is performed to grow epitaxial material in the source region recess R3 until the epitaxial material creates a sacrificial epitaxial plug 180 to fill the source Area groove R3. The epitaxial material and the substrate 110 have different compositions, thus resulting in different etch selectivities between the sacrificial epitaxial plug 180 and the substrate 110 . For example, the substrate 110 is silicon and the sacrificial epitaxial plug 180 is SiGe. In some embodiments, the sacrificial epitaxial plug 180 is SiGe without p-type dopants (eg, boron) and n-type dopants (eg, phosphorus) because the sacrificial epitaxial plugs 180 will be processed later in the process is removed from the fuse and does not serve as the source terminal of the transistor in the final IC product. After the formation of the sacrificial epitaxial plug 180 is completed, the patterned mask P3 is removed by, for example, ashing.

根據本揭露的一些實施例,為了防止SiGe被不經意地形成在Si通道層(磊晶層124)之終端表面,SiGe 犧牲磊晶塞180可以以由下而上的方式被生長。作為示例而非限制本揭露之內容,SiGe犧牲磊晶塞180可以藉由經沉積/部分蝕刻製程被生長,其至少重複一次沉積/部分蝕刻製程。此重複的沉積/部分蝕刻製程也稱為循環沉積蝕刻(cyclic deposition-etch,CDE)製程。在一些實施例中,SiGe犧牲磊晶塞180藉由選擇性磊晶生長(selective epitaxial growth,SEG)被生長,其中蝕刻氣體被添加以提升自具有第一晶面之源極區凹槽R3底部的矽鍺的選擇性生長,而非自具有與第一晶面不同的第二晶面之通道層(磊晶層124)的垂直終端表面的矽鍺的選擇性生長。舉例來說,SiGe犧牲磊晶塞180利用反應氣體,例如HCl作為蝕刻氣體、GeH4作為Ge前驅氣體、DSC及/或SiH4作為Si前驅氣體、H2及/或N2作為載體氣體而被磊晶生長。在一些實施例中,蝕刻氣體可以為其他含氯氣體或含溴氣體例如Cl2、BCl3、BiCl3、BiBr3或其類似者。 According to some embodiments of the present disclosure, in order to prevent SiGe from being inadvertently formed on the termination surface of the Si channel layer (the epitaxial layer 124 ), the SiGe sacrificial epitaxial plug 180 may be grown in a bottom-up manner. By way of example and not limitation of the present disclosure, the SiGe sacrificial epitaxial plug 180 may be grown by a deposition/partial etch process that repeats the deposition/partial etch process at least once. This repeated deposition/partial etch process is also referred to as a cyclic deposition-etch (CDE) process. In some embodiments, the SiGe sacrificial epitaxial plug 180 is grown by selective epitaxial growth (SEG), in which etching gas is added to lift from the bottom of the source region groove R3 having the first crystal plane Selective growth of silicon germanium rather than the selective growth of silicon germanium from the vertical termination surface of the channel layer (epitaxial layer 124 ) having a second crystal plane different from the first crystal plane. For example, the SiGe sacrificial epitaxial plug 180 is prepared using reactive gases such as HCl as an etching gas, GeH4 as a Ge precursor gas, DSC and/or SiH4 as a Si precursor gas, and H2 and/or N2 as a carrier gas. Epitaxial growth. In some embodiments, the etching gas may be other chlorine-containing gas or bromine-containing gas such as Cl 2 , BCl 3 , BiCl 3 , BiBr 3 , or the like.

SiGe的沉積狀態是被控制的(例如,藉由調整Ge前驅氣體、Si前驅氣體及載體氣體之流率比例)如此一來,SiGe在源極區凹槽R3底部的生長率相較於SiGe在通道層(磊晶層124)的垂直終端表面的生長率來的更快,其原因在於,源極區凹槽R3底部與通道層(磊晶層124)的垂直終端表面具有不同晶體取向面。因此,SiGe沉積步驟合併蝕刻步驟提升由下而上的SiGe生長。舉例來說,SiGe自源極區凹槽R3底部之生長相較於自通道層(磊晶 層124)的垂直終端表面之生長具有較快速率。蝕刻氣體以相同的蝕刻率同時蝕刻自通道層(磊晶層124)的垂直終端表面生長的SiGe以及自源極區凹槽R3底部生長的SiGe。然而,因為自源極區凹槽R3底部生長的SiGe之生長率快過自通道層(磊晶層124)的垂直終端表面生長的SiGe之生長率,淨效應使得SiGe將實質上以由下而上的方式自源極區凹槽R3底部生長。作為示例而非限制本揭露之內容,在CDE製程的每一沉積蝕刻循環中,當通道層(磊晶層124)之終端表面被暴露時蝕刻步驟將停止,並且自源極區凹槽R3底部被生長之SiGe將被保留在源極區凹槽R3中,因為其厚於自通道層(磊晶層124)的垂直終端表面生長之SiGe。如此一來,由下而上的生長可以被實現。上述討論的CDE製程僅只是解釋如何在源極區凹槽R3中而非自通道層(磊晶層124)的垂直終端表面形成SiGe犧牲磊晶塞180的一個示例,並且其他合適的技術也可以被用以形成SiGe犧牲磊晶塞180。 The deposition state of SiGe is controlled (for example, by adjusting the flow rate ratio of Ge precursor gas, Si precursor gas and carrier gas) so that the growth rate of SiGe at the bottom of the source region groove R3 The growth rate of the vertical terminal surface of the channel layer (epitaxial layer 124 ) is faster because the bottom of the source region groove R3 and the vertical terminal surface of the channel layer (epitaxial layer 124 ) have different crystal orientation planes. Therefore, the SiGe deposition step combined with the etching step promotes bottom-up SiGe growth. For example, the growth of SiGe from the bottom of the source region groove R3 is compared with that from the channel layer (epitaxy). The vertical termination surface of layer 124) grows at a faster rate. The etching gas simultaneously etches the SiGe grown from the vertical terminal surface of the channel layer (epitaxy layer 124 ) and the SiGe grown from the bottom of the source region groove R3 at the same etching rate. However, since the growth rate of SiGe grown from the bottom of source region recess R3 is faster than that of SiGe grown from the vertical termination surface of the channel layer (epitaxial layer 124), the net effect is that SiGe will grow substantially from the bottom to the bottom. It grows from the bottom of the groove R3 in the source region. By way of example and not limitation of the present disclosure, in each deposition etch cycle of the CDE process, the etch step will stop when the terminal surface of the channel layer (epitaxial layer 124 ) is exposed, and the bottom of the groove R3 from the source region will be stopped. The grown SiGe will remain in the source region recess R3 because it is thicker than the SiGe grown from the vertical termination surface of the channel layer (epitaxial layer 124). In this way, bottom-up growth can be achieved. The CDE process discussed above is only one example to explain how to form the SiGe sacrificial epitaxial plug 180 in the source region recess R3 rather than from the vertical termination surface of the channel layer (epitaxial layer 124 ), and other suitable techniques may also be used is used to form the SiGe sacrificial epitaxial plug 180 .

第10A圖至第10C圖繪示源極/汲極磊晶結構190S/190D的形成。更細節來說,源極磊晶結構190S被形成在鰭片130之凹入源極區S中的犧牲磊晶塞180上方,並且汲極磊晶結構190D被形成在鰭片130之汲極區D上方。源極/汲極磊晶結構190S/190D可以藉由實施磊晶生長以在犧牲磊晶塞180與鰭片130上方提供磊晶材料而被形成。在磊晶生長製程的過程中,虛閘極結構150及閘極側壁間隔物162限制源極/汲極磊晶結構 190S/190D限制在源極/汲極區S/D。合適的磊晶製程包含CVD沉積技術(例如,氣相磊晶(vapor-phase epitaxy,VPE)及/或超高真空CVD(ultra-high vacuum CVD,UHV-CVD))、分子束磊晶及/或其他合適製程。磊晶生長製程可以利用氣態及/或液態前驅物,其與鰭片130、犧牲磊晶塞180及通道層(磊晶層124)之半導體材料的組合作用。 10A to 10C illustrate the formation of the source/drain epitaxial structures 190S/190D. In more detail, the source epitaxial structure 190S is formed over the sacrificial epitaxial plug 180 in the recessed source region S of the fin 130 , and the drain epitaxial structure 190D is formed in the drain region of the fin 130 Above D. The source/drain epitaxial structures 190S/190D may be formed by performing epitaxial growth to provide epitaxial material over the sacrificial epitaxial plug 180 and the fin 130 . During the epitaxial growth process, the dummy gate structure 150 and gate sidewall spacers 162 confine the source/drain epitaxial structure 190S/190D is limited to source/drain region S/D. Suitable epitaxial processes include CVD deposition techniques (eg, vapor-phase epitaxy (VPE) and/or ultra-high vacuum CVD (UHV-CVD)), molecular beam epitaxy, and/or or other suitable process. The epitaxial growth process may utilize gaseous and/or liquid precursors that act in combination with the semiconductor materials of the fins 130, the sacrificial epitaxial plugs 180, and the channel layer (the epitaxial layer 124).

在一些實施例中,源極/汲極磊晶結構190S/190D可以包含Ge、Si、GaAs、AlGaAs、SiGe、GaAsP、SiP或其他合適材料。源極/汲極磊晶結構190S/190D可以為在磊晶製程的過程中藉由導入摻雜物種包含:p型摻雜物,例如硼或BF2、n型摻雜物,例如磷或砷及/或其他合適摻雜物包含其組合被原位摻雜。如果源極/汲極磊晶結構190S/190D並非原位摻雜,布植製程(例如,介面布植製程)被實施以摻雜源極/汲極磊晶結構190S/190D。在一些示範性實施例中,在NFET元件之源極/汲極磊晶結構190S/190D包含SiP,並且在PFET元件之源極/汲極磊晶結構190S/190D包含GeSnB及/或SiGeSnB。 In some embodiments, the source/drain epitaxial structures 190S/190D may comprise Ge, Si, GaAs, AlGaAs, SiGe, GaAsP, SiP, or other suitable materials. The source/drain epitaxial structures 190S/190D may be formed by introducing dopant species during the epitaxial process including: p-type dopants such as boron or BF 2 , n-type dopants such as phosphorus or arsenic and/or other suitable dopants, including combinations thereof, are doped in situ. If the source/drain epitaxial structures 190S/190D are not doped in-situ, an implantation process (eg, an interface implantation process) is performed to dope the source/drain epitaxial structures 190S/190D. In some exemplary embodiments, the source/drain epitaxial structures 190S/190D of the NFET devices include SiP, and the source/drain epitaxial structures 190S/190D of the PFET devices include GeSnB and/or SiGeSnB.

在一些實施例中,每一源極/汲極磊晶結構190S/190D包含第一磊晶層192及在第一磊晶層192上方的第二磊晶層194。第一磊晶層192及第二磊晶層194可以至少在鍺原子百分比(Ge%)或磷濃度(P%)的其中一者中不相同。在描繪的實施例中,第一磊晶層192可 以不僅只自犧牲磊晶塞180與鰭片130之頂面生長,也可以自通道層(磊晶層124)的終端表面生長。這是因為源極/汲極磊晶結構190S/190D的形成不必要具有根據前述討論的犧牲磊晶塞180之由下而上的方法。 In some embodiments, each source/drain epitaxial structure 190S/ 190D includes a first epitaxial layer 192 and a second epitaxial layer 194 over the first epitaxial layer 192 . The first epitaxial layer 192 and the second epitaxial layer 194 may be different in at least one of germanium atomic percentage (Ge %) or phosphorus concentration (P %). In the depicted embodiment, the first epitaxial layer 192 may be In order to grow not only from the top surface of the sacrificial epitaxial plug 180 and the fin 130, but also from the terminal surface of the channel layer (the epitaxial layer 124). This is because the formation of the source/drain epitaxial structures 190S/190D does not necessarily have to have a bottom-up approach according to the sacrificial epitaxial plug 180 discussed above.

在一些具有GeSnB及/或SiGeSnB之源極/汲極磊晶結構190S/190D以形成PFET,第一磊晶層192及第二磊晶層194至少在鍺原子百分比(Ge%)中不相同。在特定一些實施例中,第一SiGe磊晶層192具有相較於第二SiGe磊晶層194更低之鍺原子百分比。第一SiGe磊晶層192之較低的鍺原子百分比可以幫助降低在鰭片130中未被摻雜的Si之蕭基能障。第二SiGe磊晶層194中的高鍺原子百分比可以幫助降低源極/汲極接觸電阻。作為示例而非限制本揭露之內容,第一SiGe磊晶層192中之鍺原子百分比在約10%至約20%的範圍,並且第二SiGe磊晶層194之鍺原子百分比在約20%至約60%的範圍,但在不超出本揭露之各種實施例的其他範圍也可被使用。在一些實施例中,第二SiGe磊晶層194可以具有梯度之鍺原子百分比。舉例來說,第二SiGe磊晶層194之鍺原子百分比隨著與第一SiGe磊晶層192的距離增加而增加。 In some source/drain epitaxial structures 190S/190D with GeSnB and/or SiGeSnB to form PFETs, the first epitaxial layer 192 and the second epitaxial layer 194 differ at least in germanium atomic percent (Ge%). In certain embodiments, the first SiGe epitaxial layer 192 has a lower atomic percentage of germanium than the second SiGe epitaxial layer 194 . The lower atomic percentage of germanium in the first SiGe epitaxial layer 192 can help lower the Schottky barrier of undoped Si in the fins 130 . A high atomic percentage of germanium in the second SiGe epitaxial layer 194 can help reduce source/drain contact resistance. By way of example and not limitation of the present disclosure, the atomic percentage of germanium in the first SiGe epitaxial layer 192 is in the range of about 10% to about 20%, and the atomic percentage of germanium in the second SiGe epitaxial layer 194 is in the range of about 20% to about 20%. A range of about 60%, but other ranges without departing from the various embodiments of the present disclosure, may also be used. In some embodiments, the second SiGe epitaxial layer 194 may have a gradient of atomic percent germanium. For example, the germanium atomic percentage of the second SiGe epitaxial layer 194 increases as the distance from the first SiGe epitaxial layer 192 increases.

在一些實施例中,源極/汲極磊晶結構190S/190D包含SiP以形成NFET,第一SiP磊晶層192與第二SiP磊晶層194至少在磷濃度(P%)中不相同。在特定一些實施例中,第一SiP磊晶層192具有相較於 第二SiP磊晶層194更低之磷濃度。第一SiP磊晶層192之低磷濃度可以幫助降低在鰭片130中未被摻雜的Si之蕭基能障。第二SiGe磊晶層194的高磷濃度可以幫助降低源極/汲極接觸電阻。作為示例而非限制本揭露之內容,第一SiP磊晶層192之磷濃度在約5×1019cm-3至約1×1021cm-3的範圍,並且第二SiP磊晶層194之磷濃度在約1×1021cm-3至約3×1021cm-3的範圍,但在不超出本揭露之各種實施例的其他範圍也可被使用。在一些實施例中,第二SiP磊晶層194可以具有梯度之磷濃度。舉例來說,第二SiP磊晶層194之磷濃度隨著與第一SiP磊晶層192的距離增加而增加。 In some embodiments, the source/drain epitaxial structure 190S/190D includes SiP to form an NFET, and the first SiP epitaxial layer 192 and the second SiP epitaxial layer 194 differ at least in phosphorus concentration (P%). In certain embodiments, the first SiP epitaxial layer 192 has a lower phosphorus concentration than the second SiP epitaxial layer 194 . The low phosphorous concentration of the first SiP epitaxial layer 192 can help lower the Schottky barrier of undoped Si in the fins 130 . The high phosphorus concentration of the second SiGe epitaxial layer 194 can help reduce the source/drain contact resistance. By way of example and not limitation of the present disclosure, the phosphorus concentration of the first SiP epitaxial layer 192 is in the range of about 5×10 19 cm −3 to about 1×10 21 cm −3 , and the second SiP epitaxial layer 194 has a phosphorus concentration in the range of about 5×10 19 cm −3 to about 1×10 21 cm −3 . Phosphorus concentrations are in the range of about 1×10 21 cm −3 to about 3×10 21 cm −3 , but other ranges may be used without departing from the various embodiments of the present disclosure. In some embodiments, the second SiP epitaxial layer 194 may have a gradient phosphorous concentration. For example, the phosphorus concentration of the second SiP epitaxial layer 194 increases as the distance from the first SiP epitaxial layer 192 increases.

當源極/汲極磊晶結構190S/190D被形成之後,退火製程可以被實施以活化在源極/汲極磊晶結構190S/190D中的p型摻雜物或n型摻雜物。退火製程可以是,舉例來說,快速熱退火(rapid thermal anneal,RTA)、雷射退火、毫秒熱退火(millisecond thermal annealing,MTA)製程或其類似者。 After the source/drain epitaxial structures 190S/190D are formed, an annealing process may be performed to activate p-type dopants or n-type dopants in the source/drain epitaxial structures 190S/190D. The annealing process may be, for example, a rapid thermal anneal (RTA), laser annealing, millisecond thermal annealing (MTA) process, or the like.

第11A圖至第11C圖繪示在基材110上方的前側層間介電(front-side interlayer dielectric,ILD)層210的形成。ILD層210在本文被稱為「前側」ILD層是因為其形成在多閘極電晶體的前側(例如,多閘極電晶體之閘極自源極/汲極區190S/190D的側面凸出)。在一些實施例中,接觸蝕刻停止層(contact etch stop layer,CESL)200也在形成ILD層210之前被形成。在一些實 施例中,CESL 200包含氮化矽層、氧化矽層、氮氧化矽層及/或其他相較於前側ILD層210具有不同蝕刻選擇性之合適材料。CESL 200可以藉由電漿增強化學氣相沉積(plasma-enhanced chemical vapor deposition,PECVD)製程及/或其他合適之沉積或氧化製程被形成。在一些實施例中,前側ILD層210包含材料例如,原矽酸四乙酯(tetraethylorthosilicate,TEOS)氧化物、未摻雜之矽酸鹽玻璃或摻雜的氧化矽,例如硼磷矽酸鹽玻璃(borophosphosilicate glass,BPSG)、熔融石英玻璃(fused silica glass,FSG)、磷矽酸鹽玻璃(phosphosilicate glass,PSG)、硼摻雜矽玻璃(boron doped silicon glass,BSG)及/或其他相較於CESL 200具有不同蝕刻選擇性之合適介電材料。前側ILD層210可以藉由PECVD製程或其他合適沉積技術被沉積。在一些實施例中,在形成前側ILD層210之前,積體電路結構100可能受制於高熱預算製程以退火前側ILD層210。 FIGS. 11A to 11C illustrate the formation of a front-side interlayer dielectric (ILD) layer 210 over the substrate 110 . The ILD layer 210 is referred to herein as the "front-side" ILD layer because it is formed on the front side of the multi-gate transistor (eg, the gate of the multi-gate transistor protrudes from the sides of the source/drain regions 190S/190D ). In some embodiments, a contact etch stop layer (CESL) 200 is also formed before forming the ILD layer 210 . in some real In an embodiment, the CESL 200 includes a silicon nitride layer, a silicon oxide layer, a silicon oxynitride layer, and/or other suitable materials having different etch selectivities than the front side ILD layer 210 . CESL 200 may be formed by a plasma-enhanced chemical vapor deposition (PECVD) process and/or other suitable deposition or oxidation processes. In some embodiments, the front side ILD layer 210 includes a material such as tetraethylorthosilicate (TEOS) oxide, undoped silicate glass, or doped silicon oxide, such as borophosphosilicate glass (borophosphosilicate glass, BPSG), fused silica glass (fused silica glass, FSG), phosphosilicate glass (phosphosilicate glass, PSG), boron doped silicon glass (boron doped silicon glass, BSG) and/or other comparable CESL 200 has suitable dielectric materials with different etch selectivities. The front side ILD layer 210 may be deposited by a PECVD process or other suitable deposition techniques. In some embodiments, the integrated circuit structure 100 may be subject to a high thermal budget process to anneal the front side ILD layer 210 prior to forming the front side ILD layer 210 .

在一些實施例中,在沉積前側ILD層210之後,平坦化製程可以被實施以移除前側ILD層210之多餘材料。舉例來說,平坦化製程包含化學機械拋光(chemical mechanical planarization,CMP)製程,其移除前側ILD層210(及CESL 200層,如果存在的話)在虛閘極結構150上方的部分以及平坦化積體電路結構100的頂表面。在一些實施例中,CMP製程也移除硬遮罩層156、 158(如第10A圖所示)以及虛閘極電極層154。 In some embodiments, after depositing the front side ILD layer 210 , a planarization process may be performed to remove excess material of the front side ILD layer 210 . For example, the planarization process includes a chemical mechanical planarization (CMP) process that removes the portion of the front side ILD layer 210 (and CESL 200 layer, if present) over the dummy gate structure 150 and the planarization product The top surface of the bulk circuit structure 100 . In some embodiments, the CMP process also removes the hard mask layer 156, 158 (shown in FIG. 10A ) and a dummy gate electrode layer 154 .

接著,在虛閘極電極結構150被移除,隨後移除犧牲層(磊晶層122)。最終結構被繪示於第12圖中。在繪示的實施例中,虛閘極結構150藉由利用選擇性製程(例如,選擇性乾式蝕刻、選擇性濕式蝕刻或其組合)被形成,其以相較於其他材料(例如,閘極側壁間隔物162、CESL 200及/或前側ILD層210)具有更快蝕刻率蝕刻虛閘極結構150中的材料,因此導致位於對應地閘極側壁間隔物162之間的閘極溝槽GT1,且犧牲層(磊晶層122)暴露在閘極溝槽GT1中。隨後,在閘極溝槽GT1中之犧牲層(磊晶層122)利用其他選擇性蝕刻製程,其在蝕刻犧牲層(磊晶層122)時相較於蝕刻通道層(磊晶層124)時具有較快蝕刻速率被暴露,因此在鄰近通道層(磊晶層124)之間形成開口O1。如此一來,通道層(磊晶層124)變成奈米結構懸浮在基材110上方並且介於源極/汲極磊晶結構190S/190D之間。此步驟也稱為通道釋放製程。在此臨時製程步驟,介於奈米結構(磊晶層124)之間的開口119可以在大氣環境下(例如,空氣、氮氣等)被填充。在一些實施例中,奈米結構(磊晶層124)可以被可互換地稱為奈米線、奈米片、奈米板及奈米環,根據其幾何形狀。舉例來說,在一些其他實施例中,通道層(磊晶層124)可以被修整以具有實質上的圓角形狀(例如,圓柱體),其利用選擇性蝕刻製程以完整移除犧牲層(磊晶層122)。在此案例中,結果之通道層(磊晶層124)可以被稱為奈米線。 Next, the dummy gate electrode structure 150 is removed, followed by removal of the sacrificial layer (epitaxial layer 122). The final structure is shown in Figure 12. In the illustrated embodiment, the dummy gate structure 150 is formed by utilizing a selective process (eg, selective dry etching, selective wet etching, or a combination thereof), which is superior to other materials (eg, gate The gate sidewall spacers 162 , CESL 200 and/or the front side ILD layer 210 ) have faster etch rates to etch the material in the dummy gate structure 150 , thus resulting in gate trenches GT1 between the corresponding gate sidewall spacers 162 , and the sacrificial layer (the epitaxial layer 122 ) is exposed in the gate trench GT1 . Then, the sacrificial layer (epitaxial layer 122 ) in the gate trench GT1 is etched using other selective etching processes, which is compared to etching the channel layer (epitaxial layer 124 ) when etching the sacrificial layer (epitaxial layer 122 ) It is exposed with a faster etch rate, thus forming openings O1 between adjacent channel layers (epitaxy layer 124). As a result, the channel layer (epitaxial layer 124 ) becomes the nanostructure suspended above the substrate 110 and between the source/drain epitaxial structures 190S/190D. This step is also known as the channel release process. During this interim process step, the openings 119 between the nanostructures (the epitaxial layers 124 ) can be filled in an atmospheric environment (eg, air, nitrogen, etc.). In some embodiments, the nanostructures (epitaxy layer 124) may be referred to interchangeably as nanowires, nanosheets, nanoplates, and nanorings, depending on their geometry. For example, in some other embodiments, the channel layer (epitaxial layer 124 ) may be trimmed to have a substantially rounded shape (eg, a cylinder) that utilizes a selective etch process to completely remove the sacrificial layer ( epitaxial layer 122). In this case, the resulting channel layer (epitaxial layer 124) can be referred to as a nanowire.

在一些實施例中,犧牲層(磊晶層122)藉由利用選擇性濕式蝕刻製程被移除。在一些實施例中,犧牲層(磊晶層122)為SiGe並且通道層(磊晶層124)為矽,其允許選擇性地移除犧牲層(磊晶層122)。在一些實施例中,選擇性濕式蝕刻包含APM蝕刻(例如,氫氧化氨-過氧化氨-水的混和物)。在一些實施例中,選擇性移除包含SiGe氧化隨後移除SiGeOx。舉例來說,氧化可以藉由提供O3清潔再接續以蝕刻劑例如NH4OH以移除SiGeOx,其以相較於蝕刻Si更快的蝕刻率蝕刻SiGeOx。進一步來說,因為矽之氧化率遠低於(有時可達30倍低於)SiGe之氧化率,通道層(磊晶層124)可以在通道釋放製程中保持實質上地完好無損。在一些實施例中,通道釋放步驟及側向地凹陷犧牲層的前一步驟(即,繪示於第6A圖及第6B圖之步驟)皆利用具有相較於Si之更快蝕刻率蝕刻SiGe之選擇性蝕刻製程並且因此此兩步驟可以使用相同蝕刻劑化學反應在一些實施例中。在此例中,通道釋放製程之蝕刻時間/過程長於側向地凹陷犧牲層的前一步驟之蝕刻時間/過程,以便完整移除犧牲SiGe層。 In some embodiments, the sacrificial layer (epitaxial layer 122 ) is removed by utilizing a selective wet etch process. In some embodiments, the sacrificial layer (epitaxial layer 122 ) is SiGe and the channel layer (epitaxial layer 124 ) is silicon, which allows for selective removal of the sacrificial layer (epitaxial layer 122 ). In some embodiments, the selective wet etch includes an APM etch (eg, a mixture of ammonium hydroxide-ammonia peroxide-water). In some embodiments, the selective removal includes SiGe oxidation followed by removal of SiGeOx . For example, oxidation can remove SiGeOx by providing an O3 clean followed by an etchant such as NH4OH , which etches SiGeOx at a faster etch rate than etching Si. Furthermore, because the oxidation rate of silicon is much lower (sometimes up to 30 times lower) than that of SiGe, the channel layer (epitaxial layer 124) can remain substantially intact during the channel release process. In some embodiments, both the channel release step and the previous step of laterally recessing the sacrificial layer (ie, the steps shown in Figures 6A and 6B) etch SiGe with a faster etch rate compared to Si The selective etch process and thus the two steps can use the same etchant chemistry in some embodiments. In this example, the etch time/process of the channel release process is longer than the etch time/process of the previous step of laterally recessing the sacrificial layer in order to completely remove the sacrificial SiGe layer.

第13A圖及第13B圖繪示替代閘極結構220的形成。替代閘極結構220被相應地形成在閘極溝槽GT1中以圍繞懸浮在閘極溝槽GT1中的每一奈米結構(磊晶層124)。閘極結構220可以作為GAA FET之最終閘極。最終閘極結構可以為高k/金屬閘極堆疊,然而其他組合也是有可能的。在一些實施例中,每一閘極結構220形成藉 由多個奈米結構(磊晶層124)而與多通道相關聯之閘極。舉例來說,高k/金屬閘極結構220被形成在於釋放奈米結構(磊晶層124)所提供之開口O1中(如第12圖所繪示)。在多種實施例中,高k/金屬閘極結構220包含界面層222形成在奈米結構(磊晶層124)周圍以及高k閘極介電層224圍繞地形成在閘極金屬層226周圍並且填充剩餘的閘極溝槽GT1。高k/金屬閘極結構220的形成可以包含一或多次沉積製程以形成多種閘極材料,隨後接續CMP製程以移除多餘閘極材料,導致高k/金屬閘極結構220所具有之頂面與前側ILD層之頂面在相同水平面。如第13B圖所繪示之沿高k/金屬閘極結構220之縱軸的剖面圖,高k/金屬閘極結構220圍繞每一奈米結構(磊晶層124)並且因此稱為GAA FET的閘極。 13A and 13B illustrate the formation of the alternate gate structure 220 . A replacement gate structure 220 is correspondingly formed in the gate trench GT1 to surround each nanostructure (epitaxial layer 124 ) suspended in the gate trench GT1 . The gate structure 220 can serve as the final gate of the GAA FET. The final gate structure can be a high-k/metal gate stack, although other combinations are possible. In some embodiments, each gate structure 220 is formed by Gates associated with multiple channels by multiple nanostructures (epitaxial layers 124). For example, the high-k/metal gate structure 220 is formed in the opening O1 provided by the release nanostructure (the epitaxial layer 124) (as shown in FIG. 12). In various embodiments, the high-k/metal gate structure 220 includes an interface layer 222 formed around the nanostructure (epitaxial layer 124 ) and a high-k gate dielectric layer 224 formed around the gate metal layer 226 and Fill the remaining gate trench GT1. The formation of the high-k/metal gate structure 220 may include one or more deposition processes to form various gate materials, followed by a CMP process to remove excess gate material, resulting in the top of the high-k/metal gate structure 220 having The surface is at the same level as the top surface of the front side ILD layer. A cross-sectional view along the longitudinal axis of the high-k/metal gate structure 220 as depicted in FIG. 13B, the high-k/metal gate structure 220 surrounds each nanostructure (epitaxial layer 124) and is therefore referred to as a GAA FET gate.

在一些實施例中,介面層222為氧化矽形成在閘極溝槽GT1之半導體材料的暴露表面,其利用,例如,熱氧化、化學氧化、濕式氧化或其類似者被形成。最終,暴露在閘極溝槽GT1中的奈米結構(磊晶層124)表面部分以及基材部分112被氧化成氧化矽以形成介面層222。因此,在閘極溝槽GT1中的剩餘部分的奈米結構(磊晶層124)相較於不在閘極溝槽GT1中之奈米結構(磊晶層124)的其他部分更薄,如第13A圖中所繪示。 In some embodiments, the interface layer 222 is silicon oxide formed on the exposed surface of the semiconductor material of the gate trench GT1, which is formed using, for example, thermal oxidation, chemical oxidation, wet oxidation, or the like. Finally, the surface portion of the nanostructure (the epitaxial layer 124 ) exposed in the gate trench GT1 and the substrate portion 112 are oxidized to silicon oxide to form the interface layer 222 . Therefore, the remaining part of the nanostructure (epitaxial layer 124 ) in the gate trench GT1 is thinner than the other part of the nanostructure (the epitaxial layer 124 ) not in the gate trench GT1 , such as the As shown in Figure 13A.

在一些實施例中,高k閘極介電層224包含具有高介電常數之介電材料,例如,大於熱氧化矽之介電常數(~3.9)。舉例來說,高k閘極介電層224可以包含二氧 化鉿(HfO2)、氧化矽鉿(HfSiO)、氮氧化鉿矽(HfSiON)、氧化鉿鉭(HfTaO)、氧化鉿鈦(HfTiO)、氧化鉿鋯(HfZrO)、氧化鑭(LaO)、氧化鋯(ZrO)、氧化鈦(TiO)、氧化鉭(Ta2O5)、氧化釔(Y2O3)、鍶鈦氧化物(SrTiO3、STO)、鈦酸鋇(BaTiO3、BTO)、氧化鋯鋇(BaZrO)、氧化鉿鑭(HfLaO)、氧化鑭矽(LaSiO)、鋁矽氧化物(AlSiO)、氧化鋁(Al2O3)、氮化矽(Si3N4)、氮氧化物(SiON)、其類似者或其組合。 In some embodiments, the high-k gate dielectric layer 224 includes a dielectric material with a high dielectric constant, eg, greater than that of thermal silicon oxide (~3.9). For example, the high-k gate dielectric layer 224 may include hafnium dioxide (HfO 2 ), hafnium silicon oxide (HfSiO), hafnium silicon oxynitride (HfSiON), hafnium tantalum oxide (HfTaO), hafnium titanium oxide (HfTiO) , Hafnium zirconium oxide (HfZrO), lanthanum oxide (LaO), zirconium oxide (ZrO), titanium oxide (TiO), tantalum oxide (Ta 2 O 5 ), yttrium oxide (Y 2 O 3 ), strontium titanium oxide (SrTiO 3 , STO), barium titanate (BaTiO 3 , BTO), barium zirconium oxide (BaZrO), hafnium lanthanum oxide (HfLaO), lanthanum silicon oxide (LaSiO), aluminum silicon oxide (AlSiO), aluminum oxide (Al 2 O 3 ), silicon nitride (Si 3 N 4 ), oxynitride (SiON), the like or a combination thereof.

在一些實施例中,閘極金屬層226包含一或多個金屬層。舉例來說,閘極金屬層226可以包含一或多個功函數金屬層相互堆疊並且填充金屬填充閘極溝槽GT1的剩餘部分。閘極金屬層226中的一或多個功函數金屬層為高k/金屬閘極結構220提供合適的功函數。對於n型GAA FET,閘極金屬層226可以包含一或多個n型功函數金屬(N-metal)層。n型功函數金屬可以示範性地包含,但並不僅限於,鋁化鈦(TiAl)、氮化鋁鈦(TiAlN)、碳氮化鉭(TaCN)、鉿(Hf)、鋯(Zr)、鈦(Ti)、鉭(Ta)、鋁(Al)、金屬碳化物(例如,碳化鉿(HfC)、碳化鋯(ZrC)、碳化鈦(TiC)、碳化鋁(AlC))、鋁化物及/或其他合適材料。另一方面,對於p型GAA FET,閘極金屬層226可以包含一或多個p型功函數金屬(P-metal)層。p型功函數金屬可以示範性地包含,但並不僅限於,氮化鈦(TiN)、氮化鎢(WN)、鎢(W)、釕(Ru)、鈀(Pd)、鉑(Pt)、鈷(Co)、鎳(Ni)、導電金屬氧化物及/或其他合適材料。在 一些實施例中,閘極金屬層226之填充金屬可以示範性地包含,但並不僅限於,鎢、鋁、銅、鎳、鈷、鈦、鉭、氮化鈦、氮化鉭、矽化鎳、矽化鈷、TaC、TaSiC、TaCN、TiAl、TiAlN或其他合適材料。 In some embodiments, gate metal layer 226 includes one or more metal layers. For example, gate metal layer 226 may include one or more work function metal layers stacked on top of each other and fill metal to fill the remainder of gate trench GT1. One or more work function metal layers in gate metal layer 226 provide a suitable work function for high-k/metal gate structure 220 . For n-type GAA FETs, gate metal layer 226 may include one or more n-type work function metal (N-metal) layers. The n-type work function metal may exemplarily include, but is not limited to, titanium aluminide (TiAl), titanium aluminum nitride (TiAlN), tantalum carbonitride (TaCN), hafnium (Hf), zirconium (Zr), titanium (Ti), tantalum (Ta), aluminum (Al), metal carbides (eg, hafnium carbide (HfC), zirconium carbide (ZrC), titanium carbide (TiC), aluminum carbide (AlC)), aluminides and/or other suitable materials. On the other hand, for p-type GAA FETs, gate metal layer 226 may include one or more p-type work function metal (P-metal) layers. The p-type work function metal may exemplarily include, but is not limited to, titanium nitride (TiN), tungsten nitride (WN), tungsten (W), ruthenium (Ru), palladium (Pd), platinum (Pt), Cobalt (Co), Nickel (Ni), conductive metal oxides and/or other suitable materials. exist In some embodiments, the filling metal of the gate metal layer 226 can exemplarily include, but is not limited to, tungsten, aluminum, copper, nickel, cobalt, titanium, tantalum, titanium nitride, tantalum nitride, nickel silicide, silicide Cobalt, TaC, TaSiC, TaCN, TiAl, TiAlN or other suitable materials.

第14A圖至第14C圖為繪示位於源極磊晶結構190S上方之源極接點230以及位於汲極磊晶結構190D上方之汲極接點240。在一些實施例中,此步驟首先透過合適之光微影及蝕刻技術在前側ILD層210及CESL 200暴露源極/汲極磊晶結構190S/190D,以形成源極/汲極接點開口。隨後,源極/汲極接點之形成步驟將沉積一或多個金屬材料(例如,鎢、鈷、銅、其類似者或其組合)並藉由合適沉積技術(例如CVD、PVD、ALD、其類似者或其組合)以填充源極/汲極接點開口,隨後藉由CMP製程以移除位於源極/汲極接點開口之外的多餘金屬材料,同時留下位於源極/汲極接點中的金屬材料以做為源極/汲極接點230及240。 FIGS. 14A to 14C illustrate the source contact 230 over the source epitaxial structure 190S and the drain contact 240 over the drain epitaxial structure 190D. In some embodiments, this step first exposes the source/drain epitaxial structures 190S/190D in the front side ILD layer 210 and CESL 200 by suitable photolithography and etching techniques to form source/drain contact openings. Subsequently, the step of forming the source/drain contacts will deposit one or more metallic materials (eg, tungsten, cobalt, copper, the like, or combinations thereof) by suitable deposition techniques (eg, CVD, PVD, ALD, its like or a combination thereof) to fill the source/drain contact openings, followed by a CMP process to remove excess metal material outside the source/drain contact openings while leaving the source/drain contact openings The metal material in the pole contacts serves as the source/drain contacts 230 and 240 .

第15A圖至第15C圖繪示位於基材110上方的前側多層互連(MLI)結構250之形成。前側MLI結構250可以包含多個前側金屬化層252。前側金屬化層252的數目可以根據積體電路結構100的設計特性而變化。為了簡單起見,在第15A圖至第15C圖中只繪示兩個前側金屬化層252。每一前側金屬化層252包含第一前側金屬間介電(IMD)層253以及第二前側IMD層254。第二前側IMD層254被形成在對應第一前側IMD層253上方。 前側金屬化層252包含一或多個水平方向互聯,例如前側金屬線255,相應地水平或側向延伸在第二前側IMD層254中並且垂直方向互聯,例如前側金屬通孔256,相應地垂直延伸在第一前側IMD層253中。 FIGS. 15A-15C illustrate the formation of a front-side multilevel interconnect (MLI) structure 250 over substrate 110 . The front-side MLI structure 250 may include a plurality of front-side metallization layers 252 . The number of front-side metallization layers 252 may vary according to the design characteristics of the integrated circuit structure 100 . For simplicity, only two front side metallization layers 252 are shown in FIGS. 15A to 15C. Each front side metallization layer 252 includes a first front side intermetal dielectric (IMD) layer 253 and a second front side IMD layer 254 . The second front side IMD layer 254 is formed over the corresponding first front side IMD layer 253 . Front side metallization layer 252 includes one or more horizontally oriented interconnects, such as front side metal lines 255, respectively extending horizontally or laterally in second front side IMD layer 254 and vertically oriented interconnects, such as front side metal vias 256, respectively vertical Extends in the first front side IMD layer 253 .

在一些實施例中,最底部前側金屬化層252中具有前側金屬通孔256者,並且其連接汲極接點240以和汲極磊晶結構190D形成電連接。在一些實施例中,最底部前側金屬化層252中不具有金屬通孔者,其與源極接點230連接。取而代之的,源極磊晶結構190S將會與隨後形成的後側通孔電性地連接。 In some embodiments, the bottom-most front-side metallization layer 252 has front-side metal vias 256 therein and is connected to the drain contact 240 to form an electrical connection with the drain epitaxial structure 190D. In some embodiments, the bottommost front side metallization layer 252 does not have metal vias, which are connected to the source contact 230 . Instead, the source epitaxial structure 190S will be electrically connected to the backside vias formed later.

前側金屬線255及前側金屬通孔256可以利用,例如,單鑲嵌製程、雙鑲嵌製程、其類似者或組合被形成。在一些實施例中,前側IMD層253、254可以包含具有k值,例如,低於約4.0或甚至2.0之低k介電材料設置介於導電特徵之間。在一些實施例中,前側IMD層253、254可以由例如,磷矽酸鹽玻璃(phosphosilicate glass,PSG)、硼磷矽酸鹽玻璃(borophosphosilicate glass,BPSG)、熔融石英玻璃(fused silica glass,FSG)、SiOxCy、旋塗玻璃、旋塗聚合物、氧化矽、氮氧化矽、其組合或其類似者,以任何合適的方法,例如旋塗、化學氣相沉積(CVD)、電漿增強CVD(plasma-enhanced CVD,PECVD)或其類似者被做成。前側金屬線255及前側金屬通孔256可以包含銅、鋁、鎢、其組合或其類似者。在一些實施例中,前側 金屬線255及前側金屬通孔256可以進一步具有一或多個阻擋/黏著層(未示出)以保護對應的前側IMD層253、254以避免金屬擴散(例如,銅擴散)以及金屬中毒。一或多個阻擋/黏著層可以包含鈦、氮化鈦、鉭、氮化鉭或其類似者並且可以利用物理氣相蝕刻(physical vapor deposition,PVD)、CVD、ALD或其類似者而被形成。 The front side metal lines 255 and the front side metal vias 256 may be formed using, for example, a single damascene process, a dual damascene process, the like, or a combination thereof. In some embodiments, the front-side IMD layers 253, 254 may include a low-k dielectric material having a k value, eg, below about 4.0 or even 2.0, disposed between the conductive features. In some embodiments, the front side IMD layers 253, 254 may be made of, for example, phosphosilicate glass (PSG), borophosphosilicate glass (BPSG), fused silica glass (FSG) ), SiOxCy , spin -on glass, spin-on polymer, silicon oxide, silicon oxynitride, combinations thereof, or the like, by any suitable method, such as spin coating, chemical vapor deposition (CVD), plasma Enhanced CVD (plasma-enhanced CVD, PECVD) or the like is made. Front side metal lines 255 and front side metal vias 256 may include copper, aluminum, tungsten, combinations thereof, or the like. In some embodiments, the front side metal lines 255 and the front side metal vias 256 may further have one or more barrier/adhesion layers (not shown) to protect the corresponding front side IMD layers 253, 254 from metal diffusion (eg, copper diffusion) and metal poisoning. One or more barrier/adhesion layers may comprise titanium, titanium nitride, tantalum, tantalum nitride or the like and may be formed using physical vapor deposition (PVD), CVD, ALD or the like .

根據第16A圖至第16C圖,根據本揭露的一些實施例,載體基板260被連接至前側MLI結構250。載體基板260可以是矽,摻雜或未摻雜、或者可以包含其他半導體材料,例如鍺、半導體化合物或其組合。載體基板260可以在隨後製程的積體電路結構100的後側提供結構支撐,並且在一些實施例中,可以被保留在最終產品中。在一些其他實施例中,載體基板260可以在隨後之積體電路結構100的後側製程完成後被移除。在一些實施例中,載體基板260藉由,例如,熔合結合,連接至MLI結構250的最頂部介電層。當載體基板260連接至前側MLI結構250之後,積體電路結構100被前後翻轉,使得基材110的後側表面朝向上方,如第17A圖至第17C圖所繪示。 According to FIGS. 16A-16C , the carrier substrate 260 is connected to the front-side MLI structure 250 according to some embodiments of the present disclosure. The carrier substrate 260 may be silicon, doped or undoped, or may contain other semiconductor materials, such as germanium, semiconductor compounds, or combinations thereof. The carrier substrate 260 may provide structural support on the backside of the integrated circuit structure 100 for subsequent processing and, in some embodiments, may remain in the final product. In some other embodiments, the carrier substrate 260 may be removed after subsequent backside processing of the integrated circuit structure 100 is completed. In some embodiments, the carrier substrate 260 is connected to the topmost dielectric layer of the MLI structure 250 by, for example, fusion bonding. After the carrier substrate 260 is connected to the front MLI structure 250 , the integrated circuit structure 100 is turned back and forth so that the back surface of the substrate 110 faces upward, as shown in FIGS. 17A to 17C .

接著,如第18A圖至第18C圖所繪示,基材110被薄化以暴露犧牲磊晶塞180。在一些實施例中,薄化步驟藉由CMP製程、研磨製程或其類似者被完成。在薄化步驟完成之後,基材部分112被留下以覆蓋汲極磊晶結構190D的後側。 Next, as shown in FIGS. 18A to 18C , the substrate 110 is thinned to expose the sacrificial epitaxial plugs 180 . In some embodiments, the thinning step is accomplished by a CMP process, a polishing process, or the like. After the thinning step is complete, the substrate portion 112 is left to cover the backside of the drain epitaxial structure 190D.

接著,如第19A圖至第19C圖繪示,基材部分112被移除。在一些實施例中,Si基材部分112藉由相較於蝕刻SiGe犧牲磊晶塞180在蝕刻Si時有更快蝕刻率之選擇性蝕刻製程而被移除。在一些實施例中,為了選擇性移除Si基材之選擇性蝕刻製程可以是利用濕式蝕刻溶液例如氫氧化四甲胺(TMAH)、氫氧化鉀(KOH)、NH4OH、其類似者或其組合之濕式蝕刻製程。濕式蝕刻製程最終導致開口O4被形成在STI結構140中並且暴露汲極磊晶結構190D的後側,同時犧牲磊晶塞180被留在STI結構140並且自源極磊晶結構190S凸出。 Next, as shown in FIGS. 19A to 19C, the substrate portion 112 is removed. In some embodiments, the Si substrate portion 112 is removed by a selective etch process that has a faster etch rate when etching Si compared to etching the SiGe sacrificial epitaxial plug 180 . In some embodiments, the selective etching process for selectively removing Si substrates may utilize wet etching solutions such as tetramethylamine hydroxide (TMAH), potassium hydroxide (KOH), NH4OH , and the like or a wet etching process of its combination. The wet etch process eventually results in opening O4 being formed in STI structure 140 and exposing the backside of drain epitaxial structure 190D, while sacrificial epitaxial plug 180 is left in STI structure 140 and protrudes from source epitaxial structure 190S.

第20A圖至第20C圖繪示STI結構140中之開口O4中的後側介電層270的形成並且其側向地環繞犧牲磊晶塞180。在一些實施例中,第20A圖至第20C圖之步驟首先藉由合適的沉積技術例如CVD,沉積後側介電層270之介電材料以過度填充STI結構140中的開口O4。隨後,被沉積的介電材料藉由利用,例如,回蝕製程、CMP製程或其類似者被薄化,直到犧牲磊晶塞180被暴露。介電層270在本文被稱為「後側」介電層是因為其形成在與多閘極電晶體之前側所對應的多閘極電晶體之後側,替代閘極220在後側處由源極/汲極區190S/190D凸出。 FIGS. 20A-20C illustrate the formation of the backside dielectric layer 270 in the opening O4 in the STI structure 140 and which laterally surrounds the sacrificial epitaxial plug 180 . In some embodiments, the steps of FIGS. 20A-20C first deposit the dielectric material of the backside dielectric layer 270 to overfill the opening O4 in the STI structure 140 by a suitable deposition technique such as CVD. Subsequently, the deposited dielectric material is thinned by using, for example, an etch-back process, a CMP process, or the like, until the sacrificial epitaxial plug 180 is exposed. Dielectric layer 270 is referred to herein as a "rear side" dielectric layer because it is formed on the rear side of the multi-gate transistor corresponding to the front side of the multi-gate transistor, replacing gate 220 at the rear side by the source. The pole/drain regions 190S/190D protrude.

在一些實施例中,後側介電層270包含材料例如,原矽酸四乙酯(tetraethylorthosilicate,TEOS)氧化物、未摻雜之矽玻璃或摻雜之氧化矽,例如硼磷矽玻璃(borophosphosilicate glass,BPSG)、熔融石英玻 璃(fused silica glass,FSG)、磷矽酸鹽玻璃(phosphosilicate glass,PSG)、硼摻雜矽玻璃(boron doped silicon glass,BSG)及/或其他合適介電材料。在一些實施例中,後側介電層270具有與前側ILD層210相同的材料。 In some embodiments, the backside dielectric layer 270 includes a material such as tetraethylorthosilicate (TEOS) oxide, undoped silica glass, or doped silica such as borophosphosilicate glass glass, BPSG), fused silica glass fused silica glass (FSG), phosphosilicate glass (PSG), boron doped silicon glass (BSG) and/or other suitable dielectric materials. In some embodiments, the backside dielectric layer 270 has the same material as the frontside ILD layer 210 .

接著,如第21A圖至第21C圖所繪示,犧牲磊晶塞180被移除以形成後側通孔開口O5,其延伸自後側介電層270以暴露源極磊晶結構190S的後側。在一些實施例中,犧牲磊晶塞180利用相較於蝕刻後側介電層270之介電材料在蝕刻SiGe犧牲磊晶塞180有更快蝕刻率之選擇性蝕刻被移除。換句話說,選擇性蝕刻製程利用會同時攻擊SiGe並且更強烈攻擊後側介電層270之蝕刻劑。因此,在選擇性蝕刻製程完成之後,後側汲極磊晶結構190D被後側介電層270所覆蓋處被保留。做為示例而非限制本揭露之內容,犧牲磊晶塞180藉由選擇性濕式蝕刻例如APM蝕刻(例如,氫氧化氨-過氧化氨-水的混和物),其相較於蝕刻介電材料在蝕刻SiGe有更快蝕刻率而被移除。 Next, as shown in FIGS. 21A to 21C , the sacrificial epitaxial plug 180 is removed to form a backside via opening O5 extending from the backside dielectric layer 270 to expose the backside of the source epitaxial structure 190S side. In some embodiments, the sacrificial epitaxial plug 180 is removed using a selective etch that has a faster etch rate in etching the SiGe sacrificial epitaxial plug 180 than etching the dielectric material of the backside dielectric layer 270 . In other words, the selective etch process utilizes an etchant that attacks both SiGe and backside dielectric layer 270 more strongly. Therefore, after the selective etching process is completed, the backside drain epitaxial structure 190D is retained where the backside dielectric layer 270 is covered. By way of example and not limitation of the present disclosure, the sacrificial epitaxial plug 180 is etched by selective wet etching such as APM (eg, a mixture of ammonium hydroxide-ammonia peroxide-water), which is compared to etching dielectrics. Material is removed at a faster etch rate when etching SiGe.

在所描繪的實施例中,源極磊晶結構190S的後側藉由SiGe的選擇性蝕刻被凹陷。在此案例中,源極磊晶結構190S之第一磊晶層192在後側通孔開口O5之底部可以被蝕穿,使得第二磊晶層194(其相較於第一磊晶層192具有較高Ge%或P%)可以被暴露在後側通孔開口O5之底部。 In the depicted embodiment, the backside of the source epitaxial structure 190S is recessed by selective etching of SiGe. In this case, the first epitaxial layer 192 of the source epitaxial structure 190S can be etched through the bottom of the backside via opening O5, so that the second epitaxial layer 194 (compared to the first epitaxial layer 192) with higher Ge% or P%) can be exposed at the bottom of the backside via opening O5.

第22A圖至第22C圖繪示磊晶再生長層280在源極磊晶結構190S的後側之上方的形成。磊晶再生長結構280可以藉由實施在源極磊晶結構190S的後側提供磊晶材料磊晶之再生長製程被形成。在磊晶成長製程過程中,內部間隔物170、鰭片間隔物164、後側介電層270及/或STI結構140通過開口O5將磊晶再生長層280限制在後側。合適磊晶製程包含CVD沉積技術(例如,氣相磊晶(vapor-phase epitaxy,VPE)及/或超高真空CVD(UHV-CVD))、分子束磊晶及/或其他合適製程。磊晶生長製程可以利用氣態及/或液態前驅物,其與源極磊晶結構190S之半導體材料的化合物相互作用。汲極磊晶結構190D之後側不具有任何磊晶再生長層,因為其在磊晶生長製程的過程中被後側介電層270覆蓋。 FIGS. 22A-22C illustrate the formation of an epitaxial regrowth layer 280 over the backside of the source epitaxial structure 190S. The epitaxial regrowth structure 280 may be formed by performing a regrowth process to provide epitaxial material epitaxial on the backside of the source epitaxial structure 190S. During the epitaxial growth process, the internal spacers 170 , the fin spacers 164 , the backside dielectric layer 270 and/or the STI structure 140 confine the epitaxial regrowth layer 280 to the backside through the opening O5 . Suitable epitaxy processes include CVD deposition techniques (eg, vapor-phase epitaxy (VPE) and/or ultra-high vacuum CVD (UHV-CVD)), molecular beam epitaxy, and/or other suitable processes. The epitaxial growth process may utilize gaseous and/or liquid precursors that interact with compounds of the semiconductor material of the source epitaxial structure 190S. The backside of the drain epitaxial structure 190D does not have any epitaxial regrowth layer because it is covered by the backside dielectric layer 270 during the epitaxial growth process.

在一些實施例中,磊晶再生長層280可以包含Ge、Si、GaAs、AlGaAs、SiGe、GaAsP、SiP或其他合適材料。磊晶再生長層280可以在磊晶製程的過程中藉由導入摻雜物種包含:p型摻雜物,例如硼或BF2、n型摻雜物,例如磷或砷及/或其他合適摻雜物包含其組合被原位摻雜。如果磊晶再生長層280不是被原位摻雜,布植製程(即,介面布植製程)被實施以摻雜磊晶再生長層280。在示範性的一些實施例中,在NFET元件中的磊晶再生長層280包含SiP,同時在PFET元件中包含GeSnB及/或SiGeSnB。 In some embodiments, the epitaxial regrowth layer 280 may include Ge, Si, GaAs, AlGaAs, SiGe, GaAsP, SiP, or other suitable materials. The epitaxial regrown layer 280 may include p-type dopants such as boron or BF 2 , n-type dopants such as phosphorus or arsenic and/or other suitable dopants by introducing dopant species during the epitaxial process. Impurities including combinations thereof are doped in situ. If the epitaxial regrowth layer 280 is not doped in-situ, an implantation process (ie, an interface implantation process) is performed to dope the epitaxial regrowth layer 280 . In some exemplary embodiments, epitaxial regrowth layer 280 includes SiP in NFET devices, while GeSnB and/or SiGeSnB are included in PFET devices.

在一些實施例中,磊晶再生長層280以和源極磊 晶結構190S相同之材料被形成。舉例來說,在PFET元件中的磊晶再生長層280及源極磊晶結構190S包含GeSnB及/或SiGeSnB,同時磊晶再生長層280及源極磊晶結構190S包含SiP。在一些實施例中,磊晶再生長層280可以與第一磊晶層192與第二磊晶層194具有至少在鍺原子百分比(Ge%)或磷濃度(P%)中之一者的差異。 In some embodiments, the epitaxial regrowth layer 280 and the source epitaxy The crystal structure 190S is formed of the same material. For example, epitaxial regrowth layer 280 and source epitaxial structure 190S in a PFET device include GeSnB and/or SiGeSnB, while epitaxial regrowth layer 280 and source epitaxial structure 190S include SiP. In some embodiments, the epitaxial regrowth layer 280 may have a difference from the first epitaxial layer 192 and the second epitaxial layer 194 by at least one of germanium atomic percent (Ge %) or phosphorus concentration (P %) .

拿PFET元件舉例來說,磊晶再生長層280相較於第一磊晶層192具有較高的鍺原子百分比,其會幫助減少介於磊晶再生長層280及隨後形成的後側通孔之間的源極接觸電阻。做為示例而非限制本揭露之內容,磊晶再生長層280與第一磊晶層192之鍺原子百分比之比率大於1:1。在一些實施例中,磊晶再生長層280之鍺原子百分比也大於第二磊晶層194。做為示例而非限制本揭露之內容,磊晶再生長層280之鍺原子百分比在介於約20%至約70%的範圍之間。在一些實施例中,磊晶再生長層280具有梯度分布的鍺原子百分比。舉例來說,磊晶再生長層280之鍺原子百分比隨著與源極磊晶結構190S的距離增加而增加,並且磊晶再生長層280之最大鍺原子百分比大於第一磊晶層192及/或第二磊晶層194。 Taking a PFET device as an example, the epitaxial regrowth layer 280 has a higher atomic percentage of germanium than the first epitaxial layer 192, which helps to reduce the backside vias formed between the epitaxial regrowth layer 280 and the subsequent formation source contact resistance between. By way of example and not limitation of the present disclosure, the ratio of the germanium atomic percentage of the epitaxial regrowth layer 280 to the first epitaxial layer 192 is greater than 1:1. In some embodiments, the germanium atomic percentage of the epitaxial regrowth layer 280 is also greater than that of the second epitaxial layer 194 . By way of example and not limitation of the present disclosure, the germanium atomic percent of the epitaxial regrowth layer 280 is in the range of about 20% to about 70%. In some embodiments, the epitaxial regrowth layer 280 has a gradient distribution of atomic percent germanium. For example, the germanium atomic percentage of the epitaxial regrowth layer 280 increases as the distance from the source epitaxial structure 190S increases, and the maximum germanium atomic percentage of the epitaxial regrowth layer 280 is greater than that of the first epitaxial layer 192 and/or or the second epitaxial layer 194 .

另一方面,在NFET元件的一些實施例中,磊晶再生長層280相較於第一磊晶層192具有較高的磷濃度,其幫助減少磊晶再生長層280與隨後形成之後側通孔的源極接觸電阻。做為示例而非限制本揭露之內容,磊晶再 生長層280與第一磊晶層192之磷濃度比大於1:1。在一些實施例中,磊晶再生長層280之磷濃度也大於第二磊晶層194。做為示例而非限制本揭露之內容,磊晶再生長層280之磷濃度在介於約1×1021cm-3至約5×1021cm-3的範圍之間。在一些實施例中,磊晶再生長層280具有梯度分布的磷濃度。舉例來說,磊晶再生長層280之磷濃度隨著與源極磊晶結構190S的距離增加而增加,並且磊晶再生長層280之最大磷濃度大於第一磊晶層192及/或第二磊晶層194。 On the other hand, in some embodiments of the NFET device, the epitaxial regrown layer 280 has a higher phosphorous concentration than the first epitaxial layer 192, which helps reduce side pass through the epitaxial regrown layer 280 and subsequent formation The source contact resistance of the hole. By way of example and not limitation of the present disclosure, the phosphorus concentration ratio of the epitaxial regrowth layer 280 to the first epitaxial layer 192 is greater than 1:1. In some embodiments, the phosphorus concentration of the epitaxial regrowth layer 280 is also greater than that of the second epitaxial layer 194 . By way of example and not limitation of the present disclosure, the phosphorus concentration of the epitaxial regrowth layer 280 is in the range of about 1×10 21 cm −3 to about 5×10 21 cm −3 . In some embodiments, the epitaxial regrowth layer 280 has a gradient profile of phosphorus concentration. For example, the phosphorus concentration of the epitaxial regrowth layer 280 increases as the distance from the source epitaxial structure 190S increases, and the maximum phosphorus concentration of the epitaxial regrowth layer 280 is greater than that of the first epitaxial layer 192 and/or the second epitaxial structure 190S. Two epitaxial layers 194 .

在一些實施例中,磊晶再生長層280的生長溫度與源極/汲極磊晶結構190S/190D不同。舉例來說,磊晶再生長層280的生長溫度可以低於源極/汲極磊晶結構190S/190D的生長溫度,以減少源極/汲極磊晶結構190S/190D因為高溫生長所產生的負面影響。做為示例而非限制本揭露之內容,磊晶再生長層280的生長溫度藉由介於約100℃至約300℃之間的非零溫差,而低於源極/汲極磊晶結構190S/190D的生長溫度。 In some embodiments, the growth temperature of the epitaxial regrowth layer 280 is different from the source/drain epitaxial structures 190S/190D. For example, the growth temperature of the epitaxial regrowth layer 280 may be lower than the growth temperature of the source/drain epitaxial structures 190S/190D, so as to reduce the source/drain epitaxial structures 190S/190D caused by high temperature growth. Negative impact. By way of example and not limitation of the present disclosure, the growth temperature of the epitaxial regrowth layer 280 is lower than the source/drain epitaxial structure 190S/ 190D growth temperature.

在一些實施例中,在磊晶生長完成之後,退火製程可以被實施以活化位於磊晶再生長層280中的p型摻雜物或n型摻雜物。退火製程可以是,例如,快速熱退火(rapid thermal anneal,RTA)、雷射退火、毫秒熱退火(millisecond thermal annealing,MTA)製程或其類似者。 In some embodiments, after epitaxial growth is complete, an annealing process may be performed to activate p-type dopants or n-type dopants in the epitaxial regrowth layer 280 . The annealing process may be, for example, a rapid thermal anneal (RTA), laser annealing, millisecond thermal annealing (MTA) process, or the like.

第23A圖至第23D圖繪示通孔間隔物290襯裡 後側通孔開口O5的側壁。在一些實施例中,後側間隔材料層首先被沉積在載體積材260上方。通孔間隔物材料層可以是保形層,其隨後被蝕刻以形成通孔間隔物290。在繪示的實施例中,通孔間隔物材料層被保形地沉積以襯裡後側通孔開口O5的底部以及側壁。做為示例而非限制本揭露之內容,通孔間隔物材料層可以透過沉積介電材料再載體基材260上方並藉由CVD製程、低於大氣壓的CVD(subatmospheric CVD,SACVD)製程、可流動CVD製程、ALD製程、物理氣相沉積(physical vapor deposition,PVD)製程或其他合適製程被形成。非等向蝕刻製程接著被實施在沉積的通孔間隔物材料層上以自磊晶再生長層280的後側表面以及後側介電層270的後側表面移除通孔間隔物材料層之水平部分,同時通過開口O5在後側的垂直側壁和傾斜側壁上留下垂直及傾斜部分。這些在後側通孔開口O5中的通孔間隔物材料層的剩餘部分被總和稱作通孔間隔物290。其原因在於,通孔間隔物290在形成磊晶再生長層280之後被形成,通孔間隔層290藉由磊晶再生長層280與源極磊晶結構190S被間隔開。 Figures 23A-23D illustrate via spacer 290 liners The side wall of the rear side through hole opening O5. In some embodiments, a layer of backside spacer material is first deposited over carrier volume 260 . The via spacer material layer may be a conformal layer that is subsequently etched to form via spacers 290 . In the illustrated embodiment, a layer of via spacer material is conformally deposited to line the bottom and sidewalls of the backside via opening O5. By way of example and not limitation of the present disclosure, the via spacer material layer may be deposited over the carrier substrate 260 by depositing a dielectric material by a CVD process, a subatmospheric CVD (SACVD) process, flowable. A CVD process, an ALD process, a physical vapor deposition (PVD) process, or other suitable processes are formed. An anisotropic etch process is then performed on the deposited via spacer material layer to remove the via spacer material layer from the backside surface of the epitaxial regrowth layer 280 and the backside surface of the backside dielectric layer 270. The horizontal part, while leaving vertical and inclined parts on the vertical and inclined side walls of the rear side through the opening O5. The remainder of these via spacer material layers in backside via opening O5 are collectively referred to as via spacer 290 . The reason for this is that the via spacer 290 is formed after the epitaxial regrowth layer 280 is formed, and the via spacer 290 is spaced apart from the source epitaxial structure 190S by the epitaxial regrowth layer 280 .

自第23A圖之截面圖定義隔開通孔間隔層290之垂直部分,並且自第23B圖之截面圖定義隔開通孔間隔層290之傾斜部分。舉例來說,當從後側上方觀察時,通孔O5是正方形/長方形(請參見第23D圖),那麼當通孔間隔物290在剖面圖中被描繪時,通孔間隔物290的垂直部分與傾斜部分指的是單個連續通孔間隔物290的本 體。 The vertical portion separating the via spacer layer 290 is defined from the cross-sectional view of FIG. 23A, and the inclined portion separating the via spacer layer 290 is defined from the cross-sectional view of FIG. 23B. For example, via O5 is square/rectangular when viewed from above the rear side (see Figure 23D), then when via spacer 290 is depicted in cross-section, the vertical portion of via spacer 290 and the sloped portion refers to the present of a single continuous via spacer 290 body.

通孔間隔物290可以包含與後側介電材料層270不同的一或多個介電材料。舉例來說,在一些實施例中,其後側介電材料層270為氧化矽層,通孔間隔物290包含氮化矽、碳化矽、氮氧化矽、SiCN、碳氧化矽及/或其組合。材料差異導致介於通孔間隔物290與後側介電材料層270之不同的蝕刻選擇性,並且因此通孔間隔物290可以保護後側通孔開口O5以避免因為,例如,蝕刻製程用於後續之矽化製程而造成意外擴張,其將在後續更詳細被討論。 Via spacer 290 may include one or more dielectric materials different from backside dielectric material layer 270 . For example, in some embodiments, the backside dielectric material layer 270 is a silicon oxide layer, and the via spacer 290 includes silicon nitride, silicon carbide, silicon oxynitride, SiCN, silicon oxycarbide, and/or combinations thereof . The material differences result in different etch selectivities between via spacers 290 and backside dielectric material layer 270, and thus via spacers 290 can protect backside via openings O5 from being used by, for example, etching processes for Unexpected expansion due to the subsequent silicidation process, which will be discussed in more detail later.

第24A圖至第24D圖繪示位於後側開口O5中的後側通孔300的形成。在一些形成後側通孔的實施例中,一或多個金屬層首先被沉積,其藉由合適沉積製程,例如CVD、PVD、ALD、其類似者或組合以過度填充後側通孔開口O5。隨後,CMP製程被實施以薄化一或多個金屬層直到後側介電材料層270被暴露,同時在後側通孔開口O5中留下一或多個金屬層的部分,做為後側通孔300。在一些實施例中,一或多個金屬層包含,例如,鎢、鈷、銅、氮化鈦、氮化鉭、其類似者或其組合。 24A to 24D illustrate the formation of the rear through hole 300 in the rear opening O5. In some backside via-forming embodiments, one or more metal layers are first deposited by a suitable deposition process, such as CVD, PVD, ALD, the like, or a combination thereof to overfill the backside via opening O5 . Subsequently, a CMP process is performed to thin the one or more metal layers until the backside dielectric material layer 270 is exposed, while leaving portions of the one or more metal layers in the backside via opening O5 as the backside Via 300. In some embodiments, the one or more metal layers include, for example, tungsten, cobalt, copper, titanium nitride, tantalum nitride, the like, or combinations thereof.

第25圖繪示後側多層互連MLI結構310形成在後側通孔600及後側介電層270的上方。多層互連MLI結構310可以包含最底部後側金屬化層311(也稱為後側M0層)以及位於最底部後側金屬化層311上方的多個上部後側金屬化層312。上部後側金屬化層312的數目可以 根據積體電路結構100的設計特性而變化。為了簡單起見,第25圖中僅只繪示兩個後側金屬化層312(也稱為後側M1及後側M2層)。 FIG. 25 shows that the backside MLI structure 310 is formed over the backside via 600 and the backside dielectric layer 270 . The multilayer interconnect MLI structure 310 may include a bottommost backside metallization layer 311 (also referred to as a backside M0 layer) and a plurality of upper backside metallization layers 312 overlying the bottommost backside metallization layer 311 . The number of upper backside metallization layers 312 can be It varies according to the design characteristics of the integrated circuit structure 100 . For simplicity, only two backside metallization layers 312 (also referred to as backside M1 and backside M2 layers) are shown in FIG. 25 .

最底部後側金屬化層311包含位於後側介電層270上方的後側IMD層313以及一或多個水平內部互連物,例如後側金屬線315,對應地在後側IMD層313中水平或側向地延伸。位於最底部後側金屬化層311中的金屬線315為延伸跨越並且與一或多個後側通孔300連接之電源線,以使一或多個源極磊晶結構190S電連接。因為電源線被形成在後側MLI結構310中,更多佈線空間可以被提供給積體電路元件100。 Bottom-most backside metallization layer 311 includes backside IMD layer 313 over backside dielectric layer 270 and one or more horizontal internal interconnects, such as backside metal lines 315 , correspondingly in backside IMD layer 313 Extend horizontally or laterally. The metal lines 315 in the bottommost backside metallization layer 311 are power lines that extend across and are connected to one or more backside vias 300 to electrically connect one or more source epitaxial structures 190S. Since the power supply lines are formed in the rear-side MLI structure 310 , more wiring space can be provided to the integrated circuit element 100 .

每一上部後側金屬化層(例如,後側M1層及M2層)312包含第一後側金屬間介電(inter-metal dielectric,IMD)層314以及第二後側IMD層316。第二後側IMD層316被形成在相應的第一後側IMD層314上方。上部後側金屬化層312包含一或多個水平內部互連物,例如後側金屬線317,相應地在第二後側IMD層316中水平地或側向地延伸,以及垂直內部互連物,例如後側金屬通孔318,相應地在第一後側IMD層314中垂直地延伸。在一些實施例中,後側金屬通孔318具有錐形輪廓,其具有隨著與後側介電層270之間的距離減小而隨之減小的寬度,此結果是由於在將IC結構100上下翻面之後蝕刻在後側IMD層314中的通孔開口之自然結果。 Each upper backside metallization layer (eg, backside M1 and M2 layers) 312 includes a first backside inter-metal dielectric (IMD) layer 314 and a second backside IMD layer 316 . The second backside IMD layers 316 are formed over the corresponding first backside IMD layers 314 . The upper backside metallization layer 312 includes one or more horizontal internal interconnects, such as backside metal lines 317, extending horizontally or laterally in the second backside IMD layer 316, respectively, and vertical internal interconnects , such as backside metal vias 318 , correspondingly extend vertically in the first backside IMD layer 314 . In some embodiments, the backside metal via 318 has a tapered profile with a decreasing width as the distance from the backside dielectric layer 270 decreases, which results from the A natural consequence of the via openings etched in the backside IMD layer 314 after flipping 100 upside down.

第26圖為繪示根據本揭露的一些實施例所形成之積體電路結構的方法M1的流程圖。雖然方法M1被繪示及/或描述為一連串的行為或活動,但此方法並不用以限制本揭露之內容為繪示之順序或行為。因此,在一些實施例中,行為可以被以與繪示之不同順序而被執行。進一步來說,在一些實施例中,繪示的行為或活動可以被細分為多個行為或活動,其可以在其他時間或與其他行為或子行為同時進行。在一些實施例中,一些繪示的行為或活動可以被省略並且其他未繪示的行為或活動可以被包含其中。 FIG. 26 is a flowchart illustrating a method M1 of forming an integrated circuit structure according to some embodiments of the present disclosure. Although method M1 is shown and/or described as a series of acts or activities, this method is not intended to limit the disclosure to the order or acts shown. Thus, in some embodiments, acts may be performed in a different order than shown. Further, in some embodiments, a depicted act or activity may be subdivided into multiple acts or activities, which may be performed at other times or concurrently with other acts or sub-acts. In some embodiments, some illustrated acts or activities may be omitted and other non-illustrated acts or activities may be included.

在方塊S101,電晶體被形成在前側的基板上方。第1圖至第14C圖為繪示根據方塊S101的一些實施例之GAA電晶體的形成的示意圖及剖面圖。 At block S101, transistors are formed over the substrate on the front side. 1 to 14C are schematic diagrams and cross-sectional views illustrating the formation of GAA transistors according to some embodiments of block S101.

在方塊S102,前側MLI結構被形成在電晶體上方。第15A圖至第15C圖為繪示根據方塊S101的一些實施例之剖面圖。 At block S102, a front-side MLI structure is formed over the transistor. 15A to 15C are cross-sectional views illustrating some embodiments according to block S101.

在方塊S103,載體基材被連接至前側MLI結構。第16A圖至第16C圖為繪示根據方塊S103的一些實施例之剖面圖。 At block S103, the carrier substrate is attached to the front-side MLI structure. 16A to 16C are cross-sectional views illustrating some embodiments according to block S103.

在方塊S104,基材被翻面使得基材的後側面朝上方。第17A圖至第17C圖為繪示根據方塊S104的一些實施例之剖面圖。 At block S104, the substrate is turned over so that the rear side of the substrate faces upward. 17A to 17C are cross-sectional views illustrating some embodiments according to block S104.

在方塊S105,基材被移除。第18A圖至第18C圖以及第19A圖至第19C圖為繪示根據方塊S105的一些實施例之剖面圖。 At block S105, the substrate is removed. FIGS. 18A to 18C and FIGS. 19A to 19C are cross-sectional views illustrating some embodiments according to block S105 .

在方塊S106,後側介電層被形成在電晶體的後側上方。第20A圖至第20C圖為繪示根據方塊S106的一些實施例之剖面圖。 At block S106, a backside dielectric layer is formed over the backside of the transistor. FIGS. 20A to 20C are cross-sectional views illustrating some embodiments according to block S106.

在方塊S107,後側通孔開口被形成在後側介電層中並且暴露電晶體的源極磊晶結構的後側。第21A圖至第21C圖為繪示根據方塊S107的一些實施例之剖面圖。 At block S107, backside via openings are formed in the backside dielectric layer and expose the backside of the source epitaxial structure of the transistor. 21A to 21C are cross-sectional views illustrating some embodiments according to block S107.

在方塊S108,磊晶再生長層被形成在源極磊晶結構的後側上方。第22A圖至第22C圖為繪示根據方塊S108的一些實施例之剖面圖。 At block S108, an epitaxial regrowth layer is formed over the backside of the source epitaxial structure. 22A to 22C are cross-sectional views illustrating some embodiments according to block S108.

在方塊S109,通孔間隔物在後側通孔開口的側壁被形成為襯裡並且形成在磊晶再生長層上方。第23A圖至第23D圖為繪示根據方塊S109的一些實施例之剖面圖。 At block S109, via spacers are formed to line the sidewalls of the backside via openings and over the epitaxial regrowth layer. 23A to 23D are cross-sectional views illustrating some embodiments according to block S109.

在方塊S110,後側通孔被形成在後側通孔開口中。第24A圖至第24C圖為繪示根據方塊S110的一些實施例之剖面圖。 At block S110, backside vias are formed in the backside via openings. 24A to 24C are cross-sectional views illustrating some embodiments according to block S110.

在方塊S111,後側MLI結構被形成在後側通孔上方。第25圖為繪示根據方塊S111的一些實施例之剖面圖。 At block S111, backside MLI structures are formed over the backside vias. FIG. 25 is a cross-sectional view illustrating some embodiments according to block S111.

第27A圖至第31圖為繪示根據本揭露的一些實施例之具有多閘極元件之積體電路的形成之中間步驟的多個階段之剖面圖。第27A圖至第31圖中所繪示的步驟也反映第32圖中所示之步驟。應當被理解的是,額外操作可以在第27A圖至第31圖所繪示之製成之前、過程中或 之後被提供,並且一些下文敘述之操作可以在額外的一些實施例之方法中被取代或淘汰。操作/製成的順序是可以相互交換的。 FIGS. 27A-31 are cross-sectional views illustrating stages of intermediate steps in the formation of an integrated circuit having a multi-gate device in accordance with some embodiments of the present disclosure. The steps shown in FIGS. 27A to 31 also mirror the steps shown in FIG. 32 . It should be understood that additional operations may be performed before, during, or during the fabrication of those depicted in FIGS. are then provided, and some of the operations described below may be replaced or eliminated in additional methods of some embodiments. The order of operations/makes is interchangeable.

第27A圖、第28A圖、第29A圖、第30A圖及第31圖為製造積體電路結構100a之中間階段沿第一割面線(例如,第4A圖中的割面線X-X)之剖面圖,其沿著通道的縱向方向。第27B圖、第28B圖、第29B圖及第30B圖為製造積體電路結構100a之中間階段沿第二割面線(例如,第4A圖中的割面線Y1-Y1)之剖面圖,其在源極區並且垂直通道的縱向方向。第27C圖、第28C圖、第29C圖及第30C圖為製造積體電路結構100a之中間階段沿第三割面線(例如,第4A圖中的割面線Y2-Y2)之剖面圖,其在汲極區並且垂直通道的縱向方向。第28D圖為根據本揭露的一些實施例中製造積體電路結構100a之中間階段的俯視圖。 FIGS. 27A , 28A, 29A, 30A and 31 are cross-sections taken along a first secant line (eg, secant line X-X in FIG. 4A ) at an intermediate stage of manufacturing the integrated circuit structure 100 a Figure, which is along the longitudinal direction of the channel. FIGS. 27B, 28B, 29B, and 30B are cross-sectional views taken along a second secant line (eg, secant line Y1-Y1 in FIG. 4A) in an intermediate stage of manufacturing the integrated circuit structure 100a, It is in the source region and perpendicular to the longitudinal direction of the channel. FIGS. 27C, 28C, 29C, and 30C are cross-sectional views taken along a third secant line (eg, secant line Y2-Y2 in FIG. 4A) in an intermediate stage of manufacturing the integrated circuit structure 100a, It is in the drain region and perpendicular to the longitudinal direction of the channel. 28D is a top view of an intermediate stage of fabricating the integrated circuit structure 100a in accordance with some embodiments of the present disclosure.

第27A圖至第27C圖為繪示根據第20A圖至第20C圖中之步驟隨後步驟的一些實施例。細節上來說,在後側介電層270如前述第20A圖至第20C圖所形容的被形成之後,犧牲磊晶塞180藉由合適的蝕刻製程被移除以形成後側通孔開口O5’。最終結構被繪示在第27A圖至第27C圖。後側通孔開口O5’的形成細節於前述分別在第21A圖至第21C圖中的後側通孔開口O5’被討論,並且為了簡單起見因此不在此重複。 Figures 27A to 27C illustrate some embodiments of subsequent steps according to the steps of Figures 20A to 20C. In detail, after the backside dielectric layer 270 is formed as described above in FIGS. 20A-20C, the sacrificial epitaxial plug 180 is removed by a suitable etching process to form the backside via opening O5' . The final structure is shown in Figures 27A to 27C. The details of the formation of the backside via opening O5' are discussed above with respect to the backside via opening O5' in Figures 21A to 21C, respectively, and are therefore not repeated here for the sake of simplicity.

接著,通孔間隔物290’被形成以在後側通孔開口 O5’的側壁襯裡,如第28A圖至第28D圖所繪示。因為通孔間隔物290’在源極磊晶結構190S的後側上方形成磊晶再生長結構層之前被形成,通孔間隔物290’連接源極磊晶結構190S的後側。通孔間隔物260’之材料與形成製成的細節於前述被繪示分別在第23A圖至第23D圖中的通孔間隔物290被討論,並且為了簡單起見因此不在此重複。 Next, via spacers 290' are formed to open vias on the rear side Sidewall lining of O5', as depicted in Figures 28A-28D. Because the via spacer 290' is formed prior to forming the epitaxial regrowth structure layer over the backside of the source epitaxial structure 190S, the via spacer 290' connects the backside of the source epitaxial structure 190S. Details of the material and formation of via spacer 260' are discussed above with via spacer 290 depicted in FIGS. 23A-23D, respectively, and are therefore not repeated here for simplicity.

在形成通孔間隔物290’被形成以在後側通孔開口O5’的側壁襯裡之後,磊晶再生長層280’在後側通孔開口O5’中,如第29A圖至第29C圖中所繪示。如此一來,通孔間隔物290’可以將磊晶生長層280’限制在後側通孔O5’中的期望區域中。在一些實施例中,通孔間隔物290’側向地環繞磊晶再生長層280’。磊晶再生長層280’之材料與形成製成的細節於前述分別在根據第22A圖至第22C圖中的磊晶再生長層280被討論,並且為了簡單起見因此不在此重複。 After via spacers 290' are formed to line the sidewalls of backside via opening O5', epitaxial regrowth layer 280' is in backside via opening O5', as shown in Figures 29A-29C shown. As such, the via spacers 290' may confine the epitaxial growth layer 280' to desired areas in the backside via O5'. In some embodiments, via spacer 290' laterally surrounds epitaxial regrowth layer 280'. Details of the material and formation of the epitaxial regrown layer 280' are discussed previously in the epitaxial regrown layer 280 according to Figures 22A to 22C, respectively, and are therefore not repeated here for the sake of simplicity.

接著,後側通孔300被形成以填充後側通孔開口O5’的剩餘部分,如第30A圖至第30C圖繪示。隨後,後側MLI結構310被形成在後側通孔300上方,如第31圖所繪示。後側通孔300以及後側MLI結構310之材料與形成製成的細節於前述分別在第24A圖至第24C圖及第25圖時被討論,並且為了簡單起見因此不在此重複。 Next, the backside via 300 is formed to fill the remaining portion of the backside via opening O5', as shown in FIGS. 30A to 30C. Subsequently, a backside MLI structure 310 is formed over the backside via 300 , as shown in FIG. 31 . Details of the material and formation of the backside vias 300 and the backside MLI structures 310 are discussed above in FIGS. 24A-24C and 25, respectively, and are therefore not repeated here for simplicity.

第32圖為繪示根據本揭露的一些實施例所形成 之積體電路結構的方法M2的流程圖。雖然方法M2被繪示及/或描述為一連串的行為或活動,但此方法並不用以限制本揭露之內容為繪示之順序或行為。因此,在一些實施例中,行為可以被以與繪示之不同順序而被執行及/或可以被同時進行。進一步來說,在一些實施例中,繪示的行為或活動可以被細分為多個行為或活動,其可以在其他時間或與其他行為或子行為同時進行。在一些實施例中,一些繪示的行為或活動可以被省略並且其他未繪示的行為或活動可以被包含其中。 FIG. 32 is a diagram illustrating the formation according to some embodiments of the present disclosure. The flow chart of the method M2 of the integrated circuit structure. Although method M2 is shown and/or described as a series of acts or activities, this method is not intended to limit the disclosure to the order or acts shown. Thus, in some embodiments, acts may be performed in a different order than shown and/or may be performed concurrently. Further, in some embodiments, a depicted act or activity may be subdivided into multiple acts or activities, which may be performed at other times or concurrently with other acts or sub-acts. In some embodiments, some illustrated acts or activities may be omitted and other non-illustrated acts or activities may be included.

方法M2可以從前述描述的方法M1之方塊S107分支出來,並且因此方法M2可以包含所有前述方法M1的方塊(例如方塊S101至S106)。第27A圖至第27C圖繪示根據方塊S107的一些實施例之剖面圖。 The method M2 may branch from the previously described block S107 of the method M1, and thus the method M2 may include all of the previously described blocks of the method M1 (eg blocks S101 to S106). 27A to 27C illustrate cross-sectional views according to some embodiments of block S107.

方法M2的方塊S201,通孔間隔物被形成以在後側通孔開口的側壁襯裡。第28A圖至第28C圖繪示根據方塊S201的一些實施例之剖面圖。 Block S201 of method M2, via spacers are formed to line the sidewalls of the backside via openings. 28A to 28C illustrate cross-sectional views according to some embodiments of block S201.

方法M2的方塊S202,磊晶再生長層被形成在源極磊晶結構的後側上方並且側向地被通孔間隔物環繞。第29A圖至第29C圖繪示根據方塊S202的一些實施例之剖面圖。 Block S202 of method M2, an epitaxial regrowth layer is formed over the backside of the source epitaxial structure and laterally surrounded by via spacers. 29A to 29C illustrate cross-sectional views according to some embodiments of block S202.

方法M2的方塊S203,後側通孔被形成在後側通孔開口中。第30A圖至第30C圖繪示根據方塊S203的一些實施例之剖面圖。 Block S203 of method M2, backside vias are formed in backside via openings. 30A to 30C illustrate cross-sectional views according to some embodiments of block S203.

方法M2的方塊S204,後側MLI結構被形成在 後側通孔上方。第31圖繪示根據方塊S204的一些實施例之剖面圖。 At block S204 of method M2, the backside MLI structure is formed in above the rear through hole. FIG. 31 shows a cross-sectional view according to some embodiments of block S204.

第33A圖至第36圖為繪示根據本揭露的一些實施例之具有多閘極元件之積體電路的形成之中間步驟的多個階段之剖面圖。第33A圖至第36圖中所繪示的步驟也反映第37圖中所示之步驟。應當被理解的是,額外操作可以在第33A圖至第36圖所繪示之製成之前、過程中或之後被提供,並且一些下文敘述之操作可以在額外的一些實施例之方法中被取代或淘汰。操作/製成的順序是可以相互交換的。 FIGS. 33A-36 are cross-sectional views illustrating stages of intermediate steps in the formation of an integrated circuit having a multi-gate device in accordance with some embodiments of the present disclosure. The steps shown in FIGS. 33A-36 also mirror the steps shown in FIG. 37 . It should be understood that additional operations may be provided before, during, or after the fabrication depicted in Figures 33A-36, and that some of the operations described below may be substituted in additional methods of some embodiments or eliminated. The order of operations/makes is interchangeable.

第33A圖、第34A圖、第35A圖及第36圖為製造積體電路結構100b之中間階段沿第一割面線(例如,第4A圖中的割面線X-X)之剖面圖,其沿著通道的縱向方向。第33B圖、第34B圖及第35B圖為製造積體電路結構100b之中間階段沿第二割面線(例如,第4A圖中的割面線Y1-Y1)之剖面圖,其在源極區並且垂直通道的縱向方向。第33C圖、第34C圖及第35C圖為製造積體電路結構100b之中間階段沿第三割面線(例如,第4A圖中的割面線Y2-Y2)之剖面圖,其在汲極區並且垂直通道的縱向方向。 FIGS. 33A, 34A, 35A, and 36 are cross-sectional views taken along a first secant line (eg, secant line X-X in FIG. 4A) at an intermediate stage of manufacturing the integrated circuit structure 100b, the longitudinal direction of the channel. 33B, 34B, and 35B are cross-sectional views along a second secant line (eg, secant line Y1-Y1 in area and perpendicular to the longitudinal direction of the channel. FIGS. 33C , 34C and 35C are cross-sectional views along a third secant line (eg, secant line Y2-Y2 in FIG. 4A ) at an intermediate stage of manufacturing the integrated circuit structure 100b, which is at the drain electrode area and perpendicular to the longitudinal direction of the channel.

第33A圖至第33C圖為繪示第29A圖至第29C圖所示之步驟的隨後步驟的一些實施例。細節上來說,在磊晶再生長層280’被形成在後側通孔開口O5’並且被禿恐間隔物290’側向地環繞之後,金屬層320藉由合適的 陳基技術,例如CVD、PVD、ALD、其類似者或其組合被形成在載體基材260上方。金屬層320包含有能力與底部磊晶再生長層280’半導體材料反應之金屬,以在隨後製程中在磊晶再生長層280’中形成矽化物區域。舉例來說,金屬層320包含鎳、鈷、鈦、鉭、鉑、鎢、其他貴金屬、其他難熔金屬、稀土金屬或其合金。 Figures 33A-33C illustrate some embodiments of subsequent steps to the steps shown in Figures 29A-29C. In detail, after the epitaxial regrowth layer 280' is formed at the backside via opening O5' and is laterally surrounded by the bald spacer 290', the metal layer 320 is formed by a suitable Chen-based techniques such as CVD, PVD, ALD, the like, or combinations thereof are formed over carrier substrate 260 . The metal layer 320 includes a metal capable of reacting with the semiconductor material of the bottom epitaxial regrown layer 280' to form silicide regions in the epitaxial regrown layer 280' in a subsequent process. For example, the metal layer 320 includes nickel, cobalt, titanium, tantalum, platinum, tungsten, other noble metals, other refractory metals, rare earth metals, or alloys thereof.

在沉積金屬層320之後,退火製程被實施使得金屬層320與在磊晶再生長層280’中的矽(以及鍺,如果存在的話)反應以在磊晶再生長層280’中形成金屬矽化物(以及鍺化物,如果鍺存在於磊晶再生長層280’中的話)區330,並且金屬層320中未反應部分藉由蝕刻製程被移除。最終結構被繪示於第34A圖至第34C圖中。在一些實施例中,矽化物區330包含,例如,矽化鈦、矽化鈷、矽化鎳、其類似者或其組合。如前述討論,通孔間隔物290及後側介電層270具有不同蝕刻選擇性,並且因此移除未反應金屬層320之蝕刻製程可以利用相較於蝕刻後側介電層270更慢蝕刻通孔間隔物290之蝕刻劑,其在移除未反應金屬層320時防止後側通孔開口O5’被意外擴張。換句話說,通孔間隔物290’相較於後側介電層270對於移除未反應金屬層320之蝕刻製程具有較高蝕刻阻抗。 After depositing metal layer 320, an annealing process is performed such that metal layer 320 reacts with silicon (and germanium, if present) in epitaxial regrowth layer 280' to form a metal silicide in epitaxial regrowth layer 280' (and germanide, if germanium is present in epitaxial regrowth layer 280') region 330, and unreacted portions of metal layer 320 are removed by an etching process. The final structure is shown in Figures 34A to 34C. In some embodiments, the silicide region 330 includes, for example, titanium silicide, cobalt silicide, nickel silicide, the like, or combinations thereof. As discussed above, the via spacers 290 and the backside dielectric layer 270 have different etch selectivities, and thus the etch process that removes the unreacted metal layer 320 can utilize a slower etch through than etching the backside dielectric layer 270 An etchant for hole spacers 290 that prevents unintentional expansion of backside via openings O5 ′ when removing unreacted metal layer 320 . In other words, the via spacer 290' has a higher etch resistance to the etch process for removing the unreacted metal layer 320 than the backside dielectric layer 270.

接著,後側通孔300被形成以填充後側通孔開口O5’的剩餘部分,如第35A圖至第35C圖中所繪示。隨後,後側MLI結構310被形成在後側通孔300上方,如第36圖所繪示。後側通孔300與後側MLI結構310之 材料與形成製成的細節於前述分別在根據第24A圖至第24C圖及第25圖中被討論,並且為了簡單起見因此不在此重複。如第36圖所繪示,矽化物區域330位於磊晶再生長層280’與後側通孔300之間,並且通孔間隔物290’延伸穿過後側介電層270並且側向地環繞矽化物區域330。 Next, the backside via 300 is formed to fill the remaining portion of the backside via opening O5', as shown in FIGS. 35A-35C. Subsequently, the rear side MLI structure 310 is formed over the rear side via hole 300 , as shown in FIG. 36 . Between the rear side through hole 300 and the rear side MLI structure 310 Details of materials and fabrication are discussed previously in accordance with Figures 24A to 24C and 25, respectively, and are therefore not repeated here for the sake of simplicity. As shown in FIG. 36, silicide region 330 is located between epitaxial regrowth layer 280' and backside via 300, and via spacer 290' extends through backside dielectric layer 270 and laterally surrounds the silicide Object area 330.

第37圖為繪示根據本揭露的一些實施例所形成之積體電路結構的方法M3的流程圖。雖然方法M3被繪示及/或描述為一連串的行為或活動,但此方法並不用以限制本揭露之內容為繪示之順序或行為。因此,在一些實施例中,行為可以被以與繪示之不同順序而被執行及/或可以被同時進行。進一步來說,在一些實施例中,繪示的行為或活動可以被細分為多個行為或活動,其可以在其他時間或與其他行為或子行為同時進行。在一些實施例中,一些繪示的行為或活動可以被省略並且其他未繪示的行為或活動可以被包含其中。 FIG. 37 is a flowchart illustrating a method M3 of forming an integrated circuit structure according to some embodiments of the present disclosure. Although method M3 is shown and/or described as a series of acts or activities, this method is not intended to limit the disclosure to the order or acts shown. Thus, in some embodiments, acts may be performed in a different order than shown and/or may be performed concurrently. Further, in some embodiments, a depicted act or activity may be subdivided into multiple acts or activities, which may be performed at other times or concurrently with other acts or sub-acts. In some embodiments, some illustrated acts or activities may be omitted and other non-illustrated acts or activities may be included.

方法M3可以從前述描述的方法M2之方塊S202分支出來,並且因此方法M3可以包含所有前述方法M2的方塊(例如方法M2的方塊S107及方塊S201)。第29A圖至第29C圖繪示根據方塊S202的一些實施例之剖面圖。 Method M3 may branch from block S202 of method M2 described above, and thus method M3 may include all of the blocks of method M2 previously described (eg, block S107 and block S201 of method M2). 29A to 29C illustrate cross-sectional views according to some embodiments of block S202.

方法M3的方塊S301,金屬層被形成在磊晶再生長層中。第33A圖至第33C圖繪示根據方塊S301的一些實施例之剖面圖。 At block S301 of method M3, a metal layer is formed in the epitaxial regrowth layer. 33A to 33C illustrate cross-sectional views according to some embodiments of block S301.

方法M3的方塊S302,金屬層與磊晶再生長層反應以在磊晶再生長層中形成矽化物區域。方法M3的方塊S303,未反應金屬層被移除。第34A圖至第34C圖繪示根據方塊S302及S303的一些實施例之剖面圖。 At block S302 of method M3, the metal layer is reacted with the epitaxial regrowth layer to form a silicide region in the epitaxial regrowth layer. At block S303 of method M3, the unreacted metal layer is removed. 34A-34C illustrate cross-sectional views according to some embodiments of blocks S302 and S303.

方法M3的方塊S304,後側通孔被形成在後側通孔開口中並且在矽化物區域上方。第35A圖至第35C圖繪示根據方塊S304的一些實施例之剖面圖。 Block S304 of method M3, a backside via is formed in the backside via opening and over the silicide region. 35A-35C illustrate cross-sectional views according to some embodiments of block S304.

方法M3的方塊S305,後側MLI結構被形成在後側通孔上方。第36圖繪示根據方塊S305的一些實施例之剖面圖。 At block S305 of method M3, a backside MLI structure is formed over the backside via. FIG. 36 shows a cross-sectional view according to some embodiments of block S305.

第38A圖至第41圖為繪示根據本揭露的一些實施例之具有多閘極元件之積體電路的形成之中間步驟的多個階段之剖面圖。第38A圖至第41圖中所繪示的步驟也反映第42圖中所示之步驟。應當被理解的是,額外操作可以在第38A圖至第41圖所繪示之製成之前、過程中或之後被提供,並且一些下文敘述之操作可以在額外的一些實施例之方法中被取代或淘汰。操作/製成的順序是可以相互交換的。 FIGS. 38A-41 are cross-sectional views illustrating stages of intermediate steps in the formation of an integrated circuit with a multi-gate device in accordance with some embodiments of the present disclosure. The steps shown in FIGS. 38A to 41 also mirror the steps shown in FIG. 42 . It should be understood that additional operations may be provided before, during, or after the fabrication depicted in Figures 38A-41, and that some of the operations described below may be substituted in additional methods of some embodiments or eliminated. The order of operations/makes is interchangeable.

第38A圖、第39A圖、第40A圖及第41圖為製造積體電路結構100c之中間階段沿第一割面線(例如,第4A圖中的割面線X-X)之剖面圖,其沿著通道的縱向方向。第38B圖、第39B圖及第40B圖為製造積體電路結構100c之中間階段沿第二割面線(例如,第4A圖中的割面線Y1-Y1)之剖面圖,其在源極區並且垂直通道的縱 向方向。第38C圖、第39C圖及第40C圖為製造積體電路結構100c之中間階段沿第三割面線(例如,第4A圖中的割面線Y2-Y2)之剖面圖,其在汲極區並且垂直通道的縱向方向。 FIGS. 38A , 39A, 40A and 41 are cross-sectional views taken along a first secant line (eg, secant line X-X in FIG. 4A ) at an intermediate stage of manufacturing the integrated circuit structure 100 c . the longitudinal direction of the channel. FIGS. 38B , 39B and 40B are cross-sectional views along a second secant line (eg, secant line Y1-Y1 in FIG. 4A ) at an intermediate stage of manufacturing the integrated circuit structure 100c, which is at the source area and vertical channel direction. FIGS. 38C , 39C and 40C are cross-sectional views along a third secant line (eg, secant line Y2-Y2 in FIG. 4A ) at an intermediate stage of manufacturing the integrated circuit structure 100c, which is at the drain electrode area and perpendicular to the longitudinal direction of the channel.

第38A圖至第38C圖為繪示第23A圖至第23C圖所示之步驟的隨後步驟的一些實施例。細節上來說,在通孔間隔物290被形成在後側通孔開口O5中並在磊晶再生長層280上方,金屬層320’藉由合適的沉積技術,例如CVD、PVD、ALD、其類似者或其組合被形成在載體基材260上方。金屬層320’包含有能力與底部磊晶再生長層280之半導體材料反應之金屬,以在隨後製程中在磊晶再生長層280中形成矽化物區域。舉例來說,金屬層320’包含鎳、鈷、鈦、鉭、鉑、鎢、其他貴金屬、其他難熔金屬、稀土金屬或其合金。 Figures 38A-38C illustrate some embodiments of subsequent steps to the steps shown in Figures 23A-23C. In detail, after via spacer 290 is formed in backside via opening O5 and over epitaxial regrowth layer 280, metal layer 320' is deposited by a suitable deposition technique, such as CVD, PVD, ALD, the like Either or a combination thereof are formed over the carrier substrate 260 . The metal layer 320' includes a metal capable of reacting with the semiconductor material of the bottom epitaxial regrowth layer 280 to form silicide regions in the epitaxial regrowth layer 280 in a subsequent process. For example, the metal layer 320' includes nickel, cobalt, titanium, tantalum, platinum, tungsten, other noble metals, other refractory metals, rare earth metals, or alloys thereof.

在沉積金屬層320’之後,退火製程被實施使得金屬層320’與在磊晶再生長層280中的矽(以及鍺,如果存在的話)反應以在磊晶再生長層280中形成金屬矽化物(以及鍺化物,如果鍺存在於磊晶再生長層280中的話)區330’,並且金屬層320’中未反應部分藉由蝕刻製程被移除。最終結構被繪示於第39A圖至第39C圖中。在所描繪的實施例中,矽化物區330’被鑲嵌在磊晶再生長層280中。細節上來說,磊晶再生長層280的外圍區域未轉換成矽化物,原因在於磊晶再生長層280在矽化製程中被通孔間隔物290所覆蓋。取而代之的是,磊晶再生長層 280的外圍區域側向地圍繞矽化物區域330’。在一些實施例中,矽化物區330’包含,例如,矽化鈦、矽化鈷、矽化鎳、其類似者或其組合。如前述討論,通孔間隔物290及後側介電層270具有不同蝕刻選擇性,並且因此移除未反應金屬層320之蝕刻製程可以利用相較於蝕刻後側介電層270更慢蝕刻通孔間隔物290之蝕刻劑,其在移除未反應金屬層320’時防止後側通孔開口O5被意外擴張。 After depositing the metal layer 320 ′, an annealing process is performed to allow the metal layer 320 ′ to react with the silicon (and germanium, if present) in the epitaxial regrowth layer 280 to form a metal silicide in the epitaxial regrowth layer 280 (and germanide, if germanium is present in epitaxial regrowth layer 280) region 330', and unreacted portions of metal layer 320' are removed by an etching process. The final structure is shown in Figures 39A to 39C. In the depicted embodiment, silicide region 330' is embedded in epitaxial regrowth layer 280. In detail, the peripheral region of the epitaxial regrowth layer 280 is not converted to silicide because the epitaxial regrowth layer 280 is covered by the via spacer 290 during the silicidation process. Instead, the epitaxial regrowth layer The peripheral region 280 laterally surrounds the silicide region 330'. In some embodiments, the silicide region 330' includes, for example, titanium silicide, cobalt silicide, nickel silicide, the like, or combinations thereof. As discussed above, the via spacers 290 and the backside dielectric layer 270 have different etch selectivities, and thus the etch process that removes the unreacted metal layer 320 can utilize a slower etch through than etching the backside dielectric layer 270 An etchant for hole spacer 290 that prevents unintentional expansion of backside via opening O5 when removing unreacted metal layer 320'.

接著,後側通孔300被形成以填充後側通孔開口O5的剩餘部分,如第40A圖至第40C圖所繪示。隨後,後側MLI結構310被形成在後側通孔310上方,如第41圖中所繪示。後側通孔300以及後側MLI結構310之材料與形成製成的細節於前述分別在第24A圖至第24C圖及第25圖時被討論,並且為了簡單起見因此不在此重複。 Next, the backside via 300 is formed to fill the remaining portion of the backside via opening O5 , as shown in FIGS. 40A to 40C . Subsequently, the rear side MLI structure 310 is formed over the rear side via hole 310 as shown in FIG. 41 . Details of the material and formation of the backside vias 300 and the backside MLI structures 310 are discussed above in FIGS. 24A-24C and 25, respectively, and are therefore not repeated here for simplicity.

第42圖為繪示根據本揭露的一些實施例所形成之積體電路結構的方法M4的流程圖。雖然方法M4被繪示及/或描述為一連串的行為或活動,但此方法並不用以限制本揭露之內容為繪示之順序或行為。因此,在一些實施例中,行為可以被以與繪示之不同順序而被執行及/或可以被同時進行。進一步來說,在一些實施例中,繪示的行為或活動可以被細分為多個行為或活動,其可以在其他時間或與其他行為或子行為同時進行。在一些實施例中,一些繪示的行為或活動可以被省略並且其他未繪示的行為或活 動可以被包含其中。 FIG. 42 is a flowchart illustrating a method M4 of forming an integrated circuit structure according to some embodiments of the present disclosure. Although method M4 is shown and/or described as a series of acts or activities, this method is not intended to limit the disclosure to the order or acts shown. Thus, in some embodiments, acts may be performed in a different order than shown and/or may be performed concurrently. Further, in some embodiments, a depicted act or activity may be subdivided into multiple acts or activities, which may be performed at other times or concurrently with other acts or sub-acts. In some embodiments, some illustrated acts or activities may be omitted and others not illustrated Actions can be included.

方法M4可以從前述描述的方法M1之方塊S109分支出來,並且因此方法M4可以包含所有前述方法M1的方塊(例如方塊S107-S108)。第23A圖至第23D圖繪示根據方塊S109的一些實施例之剖面圖及俯視圖。 The method M4 may branch from the previously described block S109 of the method M1, and thus the method M4 may include all of the previously described blocks of the method M1 (eg, blocks S107-S108). FIGS. 23A to 23D illustrate cross-sectional and top views according to some embodiments of block S109.

方法M4的方塊S401,金屬層被形成在磊晶再生長層上方。第38A圖至第38C圖繪示根據方塊S401的一些實施例之剖面圖。 At block S401 of method M4, a metal layer is formed over the epitaxial regrowth layer. 38A to 38C illustrate cross-sectional views according to some embodiments of block S401.

方法M4的方塊S402,金屬層與磊晶再生長層反應以在磊晶再生長層中形成矽化物區域。方法M4的方塊S403,未反應金屬層被移除。第39A圖至第39C圖繪示根據方塊S402及S403的一些實施例之剖面圖。 At block S402 of method M4, the metal layer is reacted with the epitaxial regrowth layer to form a silicide region in the epitaxial regrowth layer. At block S403 of method M4, the unreacted metal layer is removed. 39A-39C illustrate cross-sectional views according to some embodiments of blocks S402 and S403.

方法M4的方塊S404,後側通孔被形成在後側通孔開口中並且在矽化物區域上方。第40A圖至第40C圖繪示根據方塊S404的一些實施例之剖面圖。 Block S404 of method M4, a backside via is formed in the backside via opening and over the silicide region. Figures 40A-40C illustrate cross-sectional views according to some embodiments of block S404.

方法M4的方塊S405,後側MLI結構被形成在後側通孔上方。第41圖繪示根據方塊S405的一些實施例之剖面圖。 At block S405 of method M4, a backside MLI structure is formed over the backside via. FIG. 41 shows a cross-sectional view according to some embodiments of block S405.

根據上文討論,可以理解的是本揭露提供了以下優點。然而,應當被理解的是,其他實施例可能提供額外附加的優點,並且本文不必公開所有優點,並且對於所有實施例而言皆不需要具有特定優點。一個優點為後側通孔及後側金屬線(例如,後側電源線)可以形成在電晶體的後側,其允許更多布線空間並且因此提升布線密度。另一個 優點是形成在源極磊晶結構後側的磊晶再生長層相較於源極磊晶結構經歷較少熱製程,使得磊晶再生長層可以具有比源極磊晶結構更好的品質,其幫助減少介於後側通孔及磊晶再生長層之間的接觸電阻。 From the above discussion, it can be appreciated that the present disclosure provides the following advantages. It should be understood, however, that other embodiments may provide additional additional advantages, and that not all advantages are necessarily disclosed herein, and no particular advantage is required for all embodiments. One advantage is that backside vias and backside metal lines (eg, backside power lines) can be formed on the backside of the transistor, which allows more wiring space and thus increases wiring density. another The advantage is that the epitaxial regrowth layer formed on the back side of the source epitaxial structure undergoes less thermal process than the source epitaxial structure, so that the epitaxial regrowth layer can have better quality than the source epitaxial structure. It helps reduce the contact resistance between the backside via and the epitaxial regrowth layer.

在一些實施例中,積體電路(integrated circuit,IC)結構包含閘極結構、源極磊晶結構、汲極磊晶結構、前側內部互連結構、後側介電層、磊晶再生長層以及後側通孔。源極磊晶結構與汲極磊晶結構相應地位於閘極結構對應的側面。前側內部互連結構在前側源極磊晶結構以及前側汲極磊晶結構上方。後側介電層在後側源極磊晶結構及後側汲極磊晶結構上方。磊晶再生長層在源極磊晶結構及汲極磊晶結構之第一者的後側上方。後側通孔延伸穿過後側介電層並且與磊晶再生長層重疊。在一些實施例中,積體電路結構進一步包含通孔間隔物延伸穿過後側介電層並且側向地圍繞後側通孔。在一些實施例中,通孔間隔物藉由磊晶再生長層而與源極磊晶結構中之第一者與汲極磊晶結構中之第一者分隔開。在一些實施例中,通孔間隔物與源極磊晶結構與汲極磊晶結構中之第一者的後側連接。在一些實施例中,通孔間隔物也側向地圍繞磊晶再生長層。在一些實施例中,積體電路結構進一步包含矽化物區域位於磊晶再生長層與後側通孔之間。在一些實施例中,積體電路結構進一步包含通孔間隔物延伸穿過後側介電層並且側向地圍繞矽化物區域。在一些實施例中,矽化物區域鑲嵌入磊晶再生長層中。在一些實施例中,源極 磊晶結構與汲極磊晶結構中之第一者為源極磊晶結構。在一些實施例中,源極磊晶結構與汲極磊晶結構中之第二者之後側不具有磊晶再生長層。在一些實施例中,源極磊晶結構與汲極磊晶結構中之第二者之後側為汲極磊晶結構。 In some embodiments, an integrated circuit (IC) structure includes a gate structure, a source epitaxial structure, a drain epitaxial structure, a front side internal interconnect structure, a back side dielectric layer, and an epitaxial regrowth layer and rear through holes. The source epitaxial structure and the drain epitaxial structure are correspondingly located on the corresponding side surfaces of the gate structure. The front-side internal interconnect structure is above the front-side source epitaxial structure and the front-side drain epitaxial structure. The backside dielectric layer is over the backside source epitaxial structure and the backside drain epitaxial structure. The epitaxial regrowth layer is over the backside of the first of the source epitaxial structure and the drain epitaxial structure. The backside vias extend through the backside dielectric layer and overlap the epitaxial regrowth layer. In some embodiments, the integrated circuit structure further includes via spacers extending through the backside dielectric layer and laterally surrounding the backside vias. In some embodiments, the via spacers are separated from the first of the source epitaxial structures and the first of the drain epitaxial structures by epitaxial regrowth layers. In some embodiments, the via spacer is connected to the backside of the first of the source epitaxial structure and the drain epitaxial structure. In some embodiments, the via spacers also laterally surround the epitaxial regrowth layer. In some embodiments, the integrated circuit structure further includes a silicide region between the epitaxial regrowth layer and the backside via. In some embodiments, the integrated circuit structure further includes via spacers extending through the backside dielectric layer and laterally surrounding the silicide region. In some embodiments, the silicide regions are embedded in the epitaxial regrowth layer. In some embodiments, the source The first of the epitaxial structure and the drain epitaxial structure is the source epitaxial structure. In some embodiments, the rear side of the second one of the source epitaxial structure and the drain epitaxial structure does not have an epitaxial regrowth layer. In some embodiments, the backside of the second one of the source epitaxial structure and the drain epitaxial structure is a drain epitaxial structure.

在一些實施例中,IC結構包含多個通道層、閘極結構、源極磊晶結構、汲極磊晶結構、前側內部互連結構、後側通孔以及磊晶再生長層。多個通道層以分隔方式一個接一個地排列。閘極結構圍繞每一通道層。源極磊晶結構與汲極磊晶結構分別位於通道層相對的端面。前側互連結構位於源極磊晶結構之前側與汲極磊晶結構之前側上方。後側通孔位於源極磊晶結構與汲極磊晶結構中之第一者的後側上方。磊晶再生長層位於後側通孔與源極磊晶結構與汲極磊晶結構中之第一者之間。在一些實施例中,磊晶再生長層具有最大鍺原子百分比,其大於源極磊晶結構與汲極磊晶結構中之第一者的最大鍺原子百分比。在一些實施例中,磊晶再生長層具有最大磷濃度,其大於源極磊晶結構與汲極磊晶結構中之第一者的最大磷濃度。在一些實施例中,積體電路結構進一步包含後側介電層由後側通孔延伸穿過,後側介電層與源極磊晶結構與汲極磊晶結構中之第二者的後側接觸。在一些實施例中,積體電路結構進一步包含通孔間隔物側向地分隔後側通孔與後側介電層。 In some embodiments, the IC structure includes a plurality of channel layers, gate structures, source epitaxial structures, drain epitaxial structures, front side internal interconnect structures, back side vias, and epitaxial regrowth layers. A plurality of channel layers are arranged one after the other in a spaced manner. A gate structure surrounds each channel layer. The source epitaxial structure and the drain epitaxial structure are respectively located on opposite end faces of the channel layer. The front side interconnection structure is located above the front side of the source epitaxial structure and the front side of the drain epitaxial structure. The backside via is located above the backside of the first one of the source epitaxial structure and the drain epitaxial structure. The epitaxial regrowth layer is located between the backside through hole and the first one of the source epitaxial structure and the drain epitaxial structure. In some embodiments, the epitaxial regrowth layer has a maximum atomic percent germanium that is greater than the maximum atomic percent germanium of the first of the source epitaxial structure and the drain epitaxial structure. In some embodiments, the epitaxial regrowth layer has a maximum phosphorus concentration that is greater than the maximum phosphorus concentration of the first of the source epitaxial structure and the drain epitaxial structure. In some embodiments, the integrated circuit structure further includes a backside dielectric layer extending through the backside via, the backside dielectric layer and the second one of the source epitaxial structure and the drain epitaxial structure. side contact. In some embodiments, the integrated circuit structure further includes via spacers to laterally separate the backside vias and the backside dielectric layer.

在一些實施例中,一種方法包括形成電晶體在基材上方,電晶體包含第一源極/汲極磊晶結構、第二源極/汲極磊晶結構以及側向地位於第一源極/汲極磊晶結構與 第二源極/汲極磊晶結構之閘極結構;移除基材之至少一部份以暴露電晶體的後側;形成後側介電層在電晶體之被暴露的後側;形成後側通孔開口在後側介電層中以暴露電晶體的第一源極/汲極磊晶結構的後側;形成磊晶再生長層在電晶體的源極/汲極磊晶結構被暴露的後側上方;以及形成後側通孔在後側通孔開口中並且在磊晶再生長層上方。在一些實施例中,形成積體電路結構之方法進一步包含在形成磊晶在生長層之前,形成通孔間隔物襯裏後側通孔開口的複數個側壁。在一些實施例中,形成積體電路結構之方法進一步包含在形成磊晶再生長層之後以及形成後側通孔之前,形成通孔間隔物襯裏後側通孔開口的複數個側壁。在一些實施例中,形成積體電路結構之方法進一步包含形成通孔間隔物襯裏後側通孔開口的複數個側壁以及在形成通孔間隔物之後,形成矽化物區域在磊晶再生長層中。 In some embodiments, a method includes forming a transistor over a substrate, the transistor including a first source/drain epitaxial structure, a second source/drain epitaxial structure, and laterally positioned on the first source /drain epitaxial structure with gate structure of the second source/drain epitaxial structure; removing at least a portion of the substrate to expose the backside of the transistor; forming a backside dielectric layer on the exposed backside of the transistor; after forming Side vias are opened in the backside dielectric layer to expose the backside of the first source/drain epitaxial structure of the transistor; an epitaxial regrowth layer is formed where the source/drain epitaxial structure of the transistor is exposed and forming a backside via in the backside via opening and over the epitaxial regrowth layer. In some embodiments, the method of forming an integrated circuit structure further includes forming a via spacer lining the plurality of sidewalls of the backside via opening prior to forming the epitaxial growth layer. In some embodiments, the method of forming an integrated circuit structure further includes forming a via spacer lining the plurality of sidewalls of the backside via opening after forming the epitaxial regrowth layer and before forming the backside via. In some embodiments, the method of forming an integrated circuit structure further includes forming a via spacer lining a plurality of sidewalls of the backside via opening and after forming the via spacer, forming a silicide region in the epitaxial regrowth layer .

前文概述了若干實施例之特徵,使得熟習此項技術者可較佳地理解本揭示案之態樣。熟習此項技術者應瞭解,他們可容易地使用本揭示案作為設計或修改用於實現相同目的及/或達成本文中所介紹之實施例之相同優勢的其他製程及結構的基礎。熟習此項技術者亦應認識到,此些等效構造不脫離本揭示案之精神及範疇,且他們可在不脫離本揭示案之精神及範疇的情況下於本文作出各種改變、代替及替換。 The foregoing has outlined features of several embodiments so that those skilled in the art may better understand aspects of the disclosure. Those skilled in the art should appreciate that they may readily use the present disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments described herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the present disclosure, and that they can make various changes, substitutions, and alterations herein without departing from the spirit and scope of the present disclosure .

100:積體電路結構 100: Integrated Circuit Structure

124:磊晶層、通道層、奈米結構 124: Epitaxial layer, channel layer, nanostructure

162:間隔物 162: Spacer

170:間隔物材料層、內部間隔物 170: Spacer material layer, internal spacer

190S:源極磊晶結構 190S: source epitaxial structure

190D:汲極磊晶結構 190D: Drain epitaxial structure

192,194:磊晶層 192,194: Epitaxy layer

200:接觸蝕刻停止層 200: Contact etch stop layer

210:層間介電層 210: Interlayer dielectric layer

220:閘極結構 220: Gate structure

222:介面層 222: interface layer

224:介電層 224: Dielectric Layer

226:閘極金屬層 226: gate metal layer

230:源極接點 230: source contact

240:汲極接點 240: drain contact

250:多層互連結構 250: Multilayer Interconnect Structure

253:第一前側金屬介電層 253: first front side metal dielectric layer

254:第二前側金屬介電層 254: Second Front Metal Dielectric Layer

255:前側金屬線 255: Front side metal wire

256:前側金屬通孔 256: front side metal through hole

260:載體基板 260: Carrier substrate

270:介電層 270: Dielectric Layer

280:磊晶再生長層 280: epitaxial regrowth layer

290:通孔間隔物 290: Through Hole Spacer

300:後側通孔 300: Rear side through hole

310:多層互連多層互連結構 310: Multilayer Interconnection Multilayer Interconnection Structure

311:最底部後側金屬化層 311: Bottom-most backside metallization

312:上部後側金屬化層 312: Upper backside metallization

313:後側金屬間介電層 313: Backside Intermetal Dielectric Layer

314:第一後側金屬間介電層 314: first back side intermetal dielectric layer

315:金屬線 315: Metal Wire

316:第二後側金屬間介電層 316: Second rear intermetal dielectric layer

317:後側金屬線 317: rear metal wire

318:後側金屬通孔 318: Rear side metal through hole

Claims (10)

一種積體電路結構,包含:一閘極結構;一源極磊晶結構與一汲極磊晶結構,分別位於該閘極結構之相反兩側;一前側互連結構,位於該源極磊晶結構的一前側與該汲極磊晶結構的一前側上方;一後側介電層,位於該源極磊晶結構的一後側與該汲極磊晶結構的一後側上方;一磊晶再生長層,位於該源極磊晶結構與該汲極磊晶結構中之一第一者的一後側,其中該磊晶再生長層朝向該源極磊晶結構與該汲極磊晶結構中之該第一者的該後側突出;以及一後側通孔,延伸穿過該後側介電層至該磊晶再生長層。 An integrated circuit structure, comprising: a gate structure; a source epitaxial structure and a drain epitaxial structure, respectively located on opposite sides of the gate structure; a front side interconnection structure, located on the source epitaxial structure a front side of the structure is above a front side of the drain epitaxial structure; a back side dielectric layer is located above a back side of the source epitaxial structure and a back side of the drain epitaxial structure; an epitaxial layer a regrowth layer located at a back side of the first one of the source epitaxial structure and the drain epitaxial structure, wherein the epitaxial regrowth layer faces the source epitaxial structure and the drain epitaxial structure The backside protrusion of the first one of them; and a backside through hole extending through the backside dielectric layer to the epitaxial regrowth layer. 如請求項1所述之積體電路結構,進一步包含:一通孔間隔物,延伸穿過該後側介電層並且側向地圍繞該後側通孔。 The integrated circuit structure of claim 1, further comprising: a via spacer extending through the backside dielectric layer and laterally surrounding the backside via. 如請求項1所述之積體電路結構,進一步包含:一矽化物區域,位於該磊晶再生長層與該後側通孔之 間。 The integrated circuit structure of claim 1, further comprising: a silicide region located between the epitaxial regrowth layer and the backside via between. 如請求項1所述之積體電路結構,其中該源極磊晶結構與該汲極磊晶結構中之該第一者為該源極磊晶結構。 The integrated circuit structure of claim 1, wherein the first one of the source epitaxial structure and the drain epitaxial structure is the source epitaxial structure. 一種積體電路結構,包含:複數個通道層,以一分隔方式一個接一個地排列;一閘極結構,圍繞每一該些通道層;一源極磊晶結構與一汲極磊晶結構,分別位於該些通道層之相對的端面;一前側互連結構,位於該源極磊晶結構之一前側與該汲極磊晶結構之一前側上方;一後側通孔,位於該源極磊晶結構與該汲極磊晶結構中之一第一者的一後側上方;以及一磊晶再生長層,位於該後側通孔與該源極磊晶結構與該汲極磊晶結構中之該第一者之間,其中該磊晶再生長層的底面與該後側通孔的底面位於不同高度。 An integrated circuit structure, comprising: a plurality of channel layers arranged one after another in a separated manner; a gate structure surrounding each of the channel layers; a source epitaxial structure and a drain epitaxial structure, are respectively located on opposite end faces of the channel layers; a front side interconnection structure is located above a front side of the source epitaxial structure and a front side of the drain epitaxial structure; a back side through hole is located on the source epitaxy over a backside of a first one of the crystal structure and the drain epitaxial structure; and an epitaxial regrowth layer located in the backside via and the source epitaxial structure and the drain epitaxial structure Between the first one, the bottom surface of the epitaxial regrowth layer and the bottom surface of the backside through hole are located at different heights. 如請求項5所述之積體電路結構,其中該磊晶再生長層具有一最大鍺原子百分比,其大於該源極磊晶結構與該汲極磊晶結構中之該第一者的一最大鍺原子百分比。 The integrated circuit structure of claim 5, wherein the epitaxial regrowth layer has a maximum germanium atomic percentage greater than a maximum of the first one of the source epitaxial structure and the drain epitaxial structure Atom percent of germanium. 如請求項5所述之積體電路結構,其中該磊晶再生長層具有一最大磷濃度,其大於該源極磊晶結構與該汲極磊晶結構中之該第一者的一最大磷濃度。 The integrated circuit structure of claim 5, wherein the epitaxial regrowth layer has a maximum phosphorus concentration that is greater than a maximum phosphorus concentration of the first one of the source epitaxial structure and the drain epitaxial structure concentration. 一種形成積體電路結構之方法,包括:形成一電晶體在一基材上方,該電晶體包含一第一源極/汲極磊晶結構、一第二源極/汲極磊晶結構以及側向地位於該第一源極/汲極磊晶結構與該第二源極/汲極磊晶結構之一閘極結構;移除該基材之至少一部份以暴露該電晶體的一後側;形成一後側介電層在該電晶體之被暴露的該後側;形成一後側通孔開口在該後側介電層中以暴露該電晶體的該第一源極/汲極磊晶結構的一後側;形成一磊晶再生長層在該電晶體的該第一源極/汲極磊晶結構的被暴露的該後側上方,其中該磊晶再生長層朝向該第一源極/磊晶結構的該後側突出;以及形成一後側通孔在該後側通孔開口中並且在該磊晶再生長層上方。 A method of forming an integrated circuit structure, comprising: forming a transistor over a substrate, the transistor comprising a first source/drain epitaxial structure, a second source/drain epitaxial structure and side grounding a gate structure of the first source/drain epitaxial structure and the second source/drain epitaxial structure; removing at least a portion of the substrate to expose a rear portion of the transistor side; forming a backside dielectric layer on the exposed backside of the transistor; forming a backside via opening in the backside dielectric layer to expose the first source/drain of the transistor a backside of the epitaxial structure; forming an epitaxial regrowth layer over the exposed backside of the first source/drain epitaxial structure of the transistor, wherein the epitaxial regrowth layer faces the first The backside of a source/epitaxial structure protrudes; and a backside via is formed in the backside via opening and over the epitaxial regrowth layer. 如請求項8所述之形成積體電路結構之方法,進一步包含:在形成該磊晶在生長層之前,形成一通孔間隔物襯裏該後側通孔開口的複數個側壁。 The method of forming an integrated circuit structure as recited in claim 8, further comprising: forming a via spacer lining a plurality of sidewalls of the backside via opening before forming the epitaxial growth layer. 如請求項8所述之形成積體電路結構之方法,進一步包含:在形成該磊晶再生長層之後以及形成該後側通孔之前,形成一通孔間隔物襯裏該後側通孔開口的複數個側壁。 The method of forming an integrated circuit structure as claimed in claim 8, further comprising: after forming the epitaxial regrowth layer and before forming the backside via, forming a via spacer lining the plurality of backside via openings a side wall.
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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12062692B2 (en) 2021-08-27 2024-08-13 Taiwan Semiconductor Manufacturing Company, Ltd. Tapered dielectric layer for preventing electrical shorting between gate and back side via
US20230061857A1 (en) * 2021-08-30 2023-03-02 Taiwan Semiconductor Manufacturing Company, Ltd. Source/drain structures
US20230178653A1 (en) * 2021-12-04 2023-06-08 International Business Machines Corporation Gate all around semiconductor device with strained channels

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201742224A (en) * 2016-02-29 2017-12-01 Advantest Corp Semiconductor device and method for manufacturing same
TWI655722B (en) * 2017-11-13 2019-04-01 穩懋半導體股份有限公司 AN IMPROVED PASSIVATION STRUCTURE FOR GaN FIELD EFFECT TRANSISTOR
US20190157310A1 (en) * 2016-07-01 2019-05-23 Intel Corporation Backside contact resistance reduction for semiconductor devices with metallization on both sides
TW201937605A (en) * 2018-01-29 2019-09-16 美商雷森公司 Method for forming gate structures for Group III-V Field Effect Transistors
US20200013900A1 (en) * 2018-07-03 2020-01-09 International Business Machines Corporation Formation of wrap-around-contact to reduce contact resistivity

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5487625B2 (en) * 2009-01-22 2014-05-07 ソニー株式会社 Semiconductor device
US9911748B2 (en) * 2015-09-28 2018-03-06 Sandisk Technologies Llc Epitaxial source region for uniform threshold voltage of vertical transistors in 3D memory devices
US9997607B2 (en) * 2016-06-30 2018-06-12 International Business Machines Corporation Mirrored contact CMOS with self-aligned source, drain, and back-gate
CN107689329B (en) * 2016-08-03 2020-03-13 中芯国际集成电路制造(上海)有限公司 Fin field effect transistor and manufacturing method thereof
US10586765B2 (en) * 2017-06-22 2020-03-10 Tokyo Electron Limited Buried power rails
US10670641B2 (en) * 2017-08-22 2020-06-02 Taiwan Semiconductor Manufacturing Co., Ltd. Semiconductor test device and manufacturing method thereof
US10818543B2 (en) * 2018-07-30 2020-10-27 Taiwan Semiconductor Manufacturing Co., Ltd. Source/drain contact spacers and methods of forming same
CN109065542B (en) * 2018-08-10 2023-12-05 无锡新洁能股份有限公司 Shielded gate power MOSFET device and manufacturing method thereof
US11538806B2 (en) * 2018-09-27 2022-12-27 Intel Corporation Gate-all-around integrated circuit structures having high mobility
US11462536B2 (en) * 2018-09-28 2022-10-04 Intel Corporation Integrated circuit structures having asymmetric source and drain structures
US10748901B2 (en) * 2018-10-22 2020-08-18 International Business Machines Corporation Interlayer via contacts for monolithic three-dimensional semiconductor integrated circuit devices

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201742224A (en) * 2016-02-29 2017-12-01 Advantest Corp Semiconductor device and method for manufacturing same
US20190157310A1 (en) * 2016-07-01 2019-05-23 Intel Corporation Backside contact resistance reduction for semiconductor devices with metallization on both sides
TWI655722B (en) * 2017-11-13 2019-04-01 穩懋半導體股份有限公司 AN IMPROVED PASSIVATION STRUCTURE FOR GaN FIELD EFFECT TRANSISTOR
TW201937605A (en) * 2018-01-29 2019-09-16 美商雷森公司 Method for forming gate structures for Group III-V Field Effect Transistors
US20200013900A1 (en) * 2018-07-03 2020-01-09 International Business Machines Corporation Formation of wrap-around-contact to reduce contact resistivity

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