TWI750668B - Heat treatment system for soil pollution - Google Patents

Heat treatment system for soil pollution Download PDF

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TWI750668B
TWI750668B TW109116927A TW109116927A TWI750668B TW I750668 B TWI750668 B TW I750668B TW 109116927 A TW109116927 A TW 109116927A TW 109116927 A TW109116927 A TW 109116927A TW I750668 B TWI750668 B TW I750668B
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unit
exhaust gas
pipeline
output end
heat exchange
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TW109116927A
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TW202144097A (en
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賈志中
陳建璋
周志忠
吳政勳
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中石化綠能科技股份有限公司
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Abstract

The invention relates to a heat treatment system for soil pollution. Primarily, the oil-contaminated soil is dried by a drying unit and then transported to a thermal desorption unit, where the soil is heated by high temperature, so that the oil contained in the soil is evaporated into a gaseous state and then separated from the soil to achieve soil purification effect. The dust, water gas and oil gas caused by the drying and thermal desorption process in the drying unit and the thermal desorption unit will be removed by a dust removal unit, and then the water gas and oil gas will be cooled to a liquid state by a heat exchange unit, and transported to an oil-water separation unit for oil-water separation. Furthermore, organic gas contained in the oil gas will be pyrolyzed into water and carbon dioxide by an exhaust gas treatment unit and then discharged into the environment. The residual heat generated by the operation of the thermal desorption unit can be used by the drying unit and a dirt pretreatment unit to save energy consumed by the overall system operation and achieve effective cost reduction and other benefits.

Description

土壤污染之熱處理系統Heat Treatment System for Soil Pollution

本發明係有關於一種土壤污染之熱處理系統,尤指一種可有效節省污染土壤於熱處理過程中所耗費能源,並可熱脫附產生的尾氣進行良好處理,以避免對環境造成二次污染的處理系統。 The present invention relates to a heat treatment system for soil pollution, in particular to a treatment that can effectively save the energy consumed by the polluted soil in the heat treatment process, and can properly treat the exhaust gas generated by thermal desorption to avoid secondary pollution to the environment. system.

按,目前石化業工廠、加油站及儲油槽等場所,在對油品的儲存及運輸上若處置不當時,將可能造成汽油、柴油、煤油及航空用油等滲入土壤,而導致土壤污染,進而危害人類生活環境,故必須對污染土壤進行整治,以維護環境安全。 According to the current petrochemical industry factories, gas stations and oil storage tanks, if the storage and transportation of oil products are not properly disposed of, it may cause gasoline, diesel oil, kerosene and aviation oil to penetrate into the soil, resulting in soil pollution. And then endanger the human living environment, it is necessary to remediate the contaminated soil to maintain environmental safety.

現有對含油污土等的整治作業,一般係藉由熱處理系統進行脫附,該熱脫附技術是指對污染土壤進行高溫加熱,使土壤中之油品等污染物通過熱脫附系統後,使該油品等污染物揮發成氣態後而與土壤分離,而達到整治淨化土壤目的。該現有熱處理系統雖可達到有效去除土壤中所含油品等污染物效果;然,卻對熱處理過程中污染物揮發所產生尾氣未有妥善處理,即排放至大氣中,而對環境造成二次污染,此外現有熱處理系統運作上係須耗費大量能源,故運作成本相當昂貴,以致於實施使用上仍不盡理想。 Existing remediation operations for oily soils, etc., are generally carried out by means of thermal treatment systems for desorption. The thermal desorption technology refers to heating the polluted soil at high temperature, so that the oil and other pollutants in the soil pass through the thermal desorption system. The oil and other pollutants are volatilized into a gaseous state and then separated from the soil, so as to achieve the purpose of remediating and purifying the soil. Although the existing heat treatment system can achieve the effect of effectively removing pollutants such as oil contained in the soil; however, the exhaust gas generated by the volatilization of pollutants during the heat treatment process is not properly treated, that is, it is discharged into the atmosphere, causing secondary pollution to the environment In addition, the operation of the existing heat treatment system requires a lot of energy, so the operation cost is quite expensive, so that the implementation and use are still not ideal.

緣是,本發明人有鑑於現有土壤污染之熱處理系統於使用上仍有上述缺失,乃藉其多年於相關領域的製造及設計經驗和知識的輔佐,並經多方巧思,研創出本發明。 The reason is that the inventors have developed the present invention with the help of years of manufacturing and design experience and knowledge in related fields, in view of the above-mentioned deficiencies in the use of the existing heat treatment systems for soil pollution.

本發明係有關於一種土壤污染之熱處理系統,其主要目的係為了提供一種可有效節省污染土壤於熱處理過程中所耗費能源,並可熱脫附產生的尾氣進行良好處理,以避免對環境造成二次污染的處理系統。 The present invention relates to a heat treatment system for soil pollution, and its main purpose is to provide a system that can effectively save the energy consumed by the polluted soil in the heat treatment process, and can properly treat the exhaust gas generated by thermal desorption, so as to avoid causing secondary pollution to the environment. Sub-contaminated treatment system.

為了達到上述實施目的,本發明人乃研擬如下土壤污染之熱處理系統,係包含:一乾燥單元,乃使該乾燥單元形成有相對之一第一污土輸入端及一第一污土輸出端,又使該乾燥單元於該第一污土輸出端的同側設有一第一排塵端,另使該乾燥單元設有一第一餘熱接收端;一熱脫附單元,係使該熱脫附單元形成有相對之一第二污土輸入端及一第二污土輸出端,且使該乾燥單元之第一污土輸出端與該熱脫附單元之第二污土輸入端間以一第一污土輸送管路相連結,又使該熱脫附單元於其第二污土輸出端的同側設有一第二排塵端,另使該熱脫附單元設有一第一餘熱輸出端,以與該乾燥單元之第一餘熱接收端間以一第一熱回收管路相連結;二除塵單元,係包含一第一除塵單元及一第二除塵單元,乃使該第一除塵單元形成有相對之一第一輸入端及一第一輸出端,並使該第一除塵單元之第一輸入端與該乾燥單元之第一排塵端間以一第一集塵管路相連結,另使該第二除塵單元形成有相對之一第二輸入端及一第二輸出端,且使該第二除塵單元之第二輸入端與該熱脫附單元之第二排塵端間以一第二集塵管路相連結; 二熱交換單元,係包含一第一熱交換單元及一第二熱交換單元,乃使該第一熱交換單元設有一第一導入端,以與該第一除塵單元的第一輸出端間以一第一輸送管路相連結,另使該第二熱交換單元設有一第二導入端,以與該第二除塵單元的第二輸出端間以一第二輸送管路相連結,又使該第一熱交換單元與一第一冷凝模組間以一第一冷卻管路相連結,並使該第二熱交換單元與一第二冷凝模組間以一第二冷卻管路相連結,另使該第一熱交換單元及第二熱交換單元分別設有一第一尾氣輸出端及一第二尾氣輸出端;一污土前處理單元,乃使該污土前處理單元與該乾燥單元之第一污土輸入端間以一第二污土輸送管路相連結,又使該污土前處理單元設有一第二餘熱接收端,另於該乾燥單元設有一第二餘熱輸出端,且使該污土前處理單元之第二餘熱接收端與該乾燥單元之第二餘熱輸出端間以一第二熱回收管路相連結,另使該污土前處理單元與第一熱交換單元間以一熱交換管路相連結;二油水分離單元,係包含一第一油水分離單元及一第二油水分離單元,乃使該第一熱交換單元設有一第一廢液輸出端,以與該第一油水分離單元之輸入端間以一第一廢液管路相連結,另使該第二熱交換單元設有一第二廢液輸出端,以與該第二油水分離單元之輸入端間以一第二廢液管路相連結;一尾氣處理單元,係使該第一熱交換單元之第一尾氣輸出端與該尾氣處理單元間以一第一尾氣輸送管路相連結,另使該第二熱交換單元之第二尾氣輸出端與該尾氣處理單元間以一第二尾氣輸送管路相連結。 In order to achieve the above implementation purpose, the inventors have developed the following soil pollution heat treatment system, which includes: a drying unit, so that the drying unit is formed with a first sewage input end and a first sewage output end. , and the drying unit is provided with a first dust discharge end on the same side of the first dirt output end, and the drying unit is provided with a first waste heat receiving end; a thermal desorption unit, which makes the thermal desorption unit A second dirt input end and a second dirt output end are formed opposite, and a first dirt output end of the drying unit and the second dirt input end of the thermal desorption unit are formed with a first The sewage conveying pipeline is connected, and the thermal desorption unit is provided with a second dust discharge end on the same side of the second sewage output end, and the thermal desorption unit is provided with a first waste heat output end, so as to be connected with the second waste heat output end. The first waste heat receiving ends of the drying unit are connected by a first heat recovery pipeline; the two dedusting units include a first dedusting unit and a second dedusting unit, so that the first dedusting unit is formed with opposite A first input end and a first output end, the first input end of the first dust removal unit and the first dust discharge end of the drying unit are connected by a first dust collection pipeline, and the The two dust removal units are formed with a second input end and a second output end opposite to each other, and a second dust collection end is formed between the second input end of the second dust removal unit and the second dust discharge end of the thermal desorption unit connected to the pipeline; The two heat exchange units include a first heat exchange unit and a second heat exchange unit, so that the first heat exchange unit is provided with a first introduction end, so as to connect with the first output end of the first dust removal unit. A first conveying pipeline is connected, and the second heat exchange unit is provided with a second introduction end, so as to be connected with the second output end of the second dust removal unit by a second conveying pipeline, and the second heat exchange unit is connected with a second conveying pipeline. The first heat exchange unit and a first condensing module are connected by a first cooling pipeline, and the second heat exchange unit and a second condensing module are connected by a second cooling pipeline, and the other The first heat exchange unit and the second heat exchange unit are respectively provided with a first tail gas output end and a second tail gas output end; A sewage input end is connected with a second sewage conveying pipeline, and the sewage pretreatment unit is provided with a second waste heat receiving end, and the drying unit is provided with a second waste heat output end, and the The second waste heat receiving end of the soil pretreatment unit and the second waste heat output end of the drying unit are connected by a second heat recovery pipeline, and a second heat recovery pipe is connected between the soil pretreatment unit and the first heat exchange unit. The heat exchange pipelines are connected; the second oil-water separation unit includes a first oil-water separation unit and a second oil-water separation unit, so that the first heat exchange unit is provided with a first waste liquid output end to connect with the first oil-water separation unit. The input ends of the oil-water separation unit are connected by a first waste liquid pipeline, and the second heat exchange unit is provided with a second waste liquid output end, so as to connect with the input end of the second oil-water separation unit by a first waste liquid pipeline. Two waste liquid pipelines are connected; an exhaust gas treatment unit connects the first exhaust gas output end of the first heat exchange unit and the exhaust gas treatment unit with a first exhaust gas conveying pipeline, and the second heat exchange unit is connected by a first exhaust gas transmission pipeline. The second exhaust gas output end of the exchange unit is connected with the exhaust gas processing unit by a second exhaust gas conveying pipeline.

如上所述之土壤污染之熱處理系統,其中,該乾燥單元係為一間接加熱旋轉爐,主要包含有一第一內旋轉爐及一包覆該第一內旋轉爐之第一固定外爐,並使該乾燥單元之第一內旋轉爐相對二端各形成該第一污土輸入端及第一污土輸出端,又使該第一內旋轉爐於其第一污土輸出端的同側設有該第一排塵端,且於該第一固定外爐設有其第一餘熱接收端,另該熱脫附單元係為一 間接加熱旋轉爐,主要包含有一第二內旋轉爐及一包覆該第二內旋轉爐之第二固定外爐,乃使熱脫附單元之第二內旋轉爐相對二端各形成該第二污土輸入端及第二污土輸出端,又使該第二內旋轉爐於其第二污土輸出端的同側設有其第二排塵端,且於該第二固定外爐設有其第一餘熱輸出端。 The above-mentioned heat treatment system for soil pollution, wherein the drying unit is an indirect heating rotary furnace, which mainly includes a first inner rotary furnace and a first fixed outer furnace covering the first inner rotary furnace, and makes The opposite ends of the first inner rotary furnace of the drying unit respectively form the first soil input end and the first soil output end, and the first inner rotary furnace is provided with the first soil output end on the same side of the first soil output end. The first dust discharge end is provided with the first waste heat receiving end in the first fixed outer furnace, and the thermal desorption unit is a The indirect heating rotary furnace mainly includes a second inner rotary furnace and a second fixed outer furnace covering the second inner rotary furnace, so that the opposite ends of the second inner rotary furnace of the thermal desorption unit form the second inner rotary furnace. The dirt input end and the second dirt output end, and the second inner rotary furnace is provided with its second dust discharge end on the same side of its second dirt output end, and the second fixed outer furnace is provided with its second dust discharge end. The first waste heat output terminal.

如上所述之土壤污染之熱處理系統,其中,該乾燥單元之第一內旋轉爐的加熱溫度係設定為100~200℃,而該第一固定外爐的加熱溫度係設定為250~800℃,另該熱脫附單元之第二內旋轉爐的加熱溫度係設定為450~900℃,而該第二固定外爐的加熱溫度係設定為600~1050℃。 The heat treatment system for soil pollution as described above, wherein the heating temperature of the first inner rotary furnace of the drying unit is set to 100-200°C, and the heating temperature of the first fixed outer furnace is set to be 250-800°C, In addition, the heating temperature of the second inner rotary furnace of the thermal desorption unit is set at 450-900°C, and the heating temperature of the second fixed outer furnace is set at 600-1050°C.

如上所述之土壤污染之熱處理系統,其中,該尾氣處理單元係包含有一混合防爆器、一尾氣裂解模組及一煙囪,並使該混合防爆器、尾氣裂解模組及煙囪間分別以一輸氣管路依序連結,又使該第一熱交換單元的第一尾氣輸出端與該混合防爆器間以該第一尾氣輸送管路相連結,且使該第二熱交換單元的第二尾氣輸出端與該混合防爆器間以該第二尾氣輸送管路相連結,另使該混合防爆器連結有一第三惰氣輸入管路。 The heat treatment system for soil pollution as described above, wherein, the exhaust gas treatment unit comprises a mixed explosion-proof device, an exhaust gas cracking module and a chimney, and the mixed explosion-proof device, the exhaust gas cracking module and the chimney are respectively connected with a transmission line. The gas pipelines are connected in sequence, and the first exhaust gas output end of the first heat exchange unit and the hybrid explosion-proof device are connected by the first exhaust gas conveying pipeline, and the second exhaust gas of the second heat exchange unit is output. The end is connected with the mixed explosion-proof device by the second exhaust gas conveying pipeline, and the mixed explosion-proof device is connected with a third inert gas input pipeline.

如上所述之土壤污染之熱處理系統,其中,該尾氣處理單元係進一步包含有一尾氣還原模組,乃使該尾氣還原模組設於該尾氣裂解模組及煙囪間,並與該尾氣裂解模組及煙囪分別以一輸氣管路相連結。 The heat treatment system for soil pollution as described above, wherein, the exhaust gas treatment unit further includes an exhaust gas reduction module, so that the exhaust gas reduction module is arranged between the exhaust gas cracking module and the chimney, and is connected with the exhaust gas cracking module. and the chimney are respectively connected by a gas pipeline.

如上所述之土壤污染之熱處理系統,其中,該尾氣處理單元之混合防爆器與尾氣裂解模組係於其相連結的輸氣管路間設有一最低爆炸極限分析儀。 In the above heat treatment system for soil pollution, wherein the mixed explosion-proof device of the exhaust gas treatment unit and the exhaust gas cracking module are connected with a gas pipeline with a minimum explosion limit analyzer.

如上所述之土壤污染之熱處理系統,其中,該尾氣處理單元之尾氣裂解模組係為直燃式焚化爐或蓄熱式焚化爐。 In the thermal treatment system for soil pollution as described above, the exhaust gas cracking module of the exhaust gas treatment unit is a direct-fired incinerator or a regenerative incinerator.

如上所述之土壤污染之熱處理系統,其中,該乾燥單元係於其第一污土輸入端的同側連結有一第一惰氣輸入管路,另使該熱脫附單元於其第二污土輸入端的同側連結有一第二惰氣輸入管路。 The thermal treatment system for soil pollution as described above, wherein the drying unit is connected to a first inert gas input pipeline on the same side of the first sewage input end, and the thermal desorption unit is connected to the second sewage input of the thermal desorption unit. The same side of the end is connected with a second inert gas input pipeline.

藉此,當本發明於使用實施時,係使含油污土經乾燥單元將土壤乾燥後再輸送至熱脫附單元,以於熱脫附單元通過高溫加熱,使土壤所含油品揮發成氣態後與土壤分離,達到淨化土壤效果,而含油污土在乾燥單元及熱脫附單元進行乾燥與熱脫附過程中引起的粉塵、水氣及油氣等係會通過除塵單元將粉塵去除,再經熱交換單元將水氣及油氣冷卻成液態後,輸送至油水分離單元處進行油水分離,另油氣所含有機氣體則會經尾氣處理單元加熱裂解成水及二氧化碳後排放於環境中,而熱脫附單元運作產生的餘熱則可提供乾燥單元及污土前處理單元等使用,以節省整體系統運作所耗費能源,達到有效降低成本等效益。 Therefore, when the present invention is used and implemented, the oily soil is dried by the drying unit and then sent to the thermal desorption unit, so that the oil contained in the soil is volatilized into a gaseous state after being heated at a high temperature in the thermal desorption unit. It is separated from the soil to achieve the effect of purifying the soil, and the dust, water vapor and oil and gas caused by the drying and thermal desorption of the oily soil in the drying unit and the thermal desorption unit will be removed by the dust removal unit. The exchange unit cools the water gas and oil and gas into a liquid state, and then transports it to the oil-water separation unit for oil-water separation. In addition, the organic gas contained in the oil and gas will be heated and cracked into water and carbon dioxide by the tail gas treatment unit and then discharged into the environment. The waste heat generated by the operation of the unit can be used for the drying unit and the sewage pre-treatment unit, so as to save the energy consumed by the operation of the overall system and effectively reduce the cost.

1:乾燥單元 1: Drying unit

11:第一內旋轉爐 11: The first inner rotary furnace

12:第一固定外爐 12: The first fixed outer furnace

13:第一惰氣輸入管路 13: The first inert gas input line

2:熱脫附單元 2: Thermal desorption unit

21:第二內旋轉爐 21: Second inner rotary furnace

22:第二固定外爐 22: Second fixed outer furnace

23:第一污土輸送管路 23: The first sewage conveying pipeline

24:第二惰氣輸入管路 24: Second inert gas input line

25:第一熱回收管路 25: The first heat recovery line

3:除塵單元 3: Dust removal unit

31:第一除塵單元 31: The first dust removal unit

32:第二除塵單元 32: Second dust removal unit

33:第一集塵管路 33: The first dust collection pipeline

34:第二集塵管路 34: The second dust collection pipeline

35:第一輸送管路 35: The first delivery pipeline

36:第二輸送管路 36: Second delivery pipeline

4:熱交換單元 4: heat exchange unit

41:第一熱交換單元 41: The first heat exchange unit

42:第二熱交換單元 42: Second heat exchange unit

43:熱交換管路 43: heat exchange pipeline

44:第一冷凝模組 44: The first condensation module

45:第一冷卻管路 45: The first cooling line

46:第二冷凝模組 46: Second condensing module

47:第二冷卻管路 47: Second cooling line

5:油水分離單元 5: Oil-water separation unit

51:第一油水分離單元 51: The first oil-water separation unit

52:第二油水分離單元 52: Second oil-water separation unit

53:第一廢液管路 53: The first waste liquid pipeline

54:第二廢液管路 54: Second waste liquid pipeline

6:尾氣處理單元 6: Exhaust gas treatment unit

61:混合防爆器 61: Hybrid explosion-proof device

611:第三惰氣輸入管路 611: Third inert gas input line

62:尾氣裂解模組 62: Exhaust gas cracking module

63:尾氣還原模組 63: Exhaust gas reduction module

64:煙囪 64: Chimney

65:輸氣管路 65: Gas pipeline

66:第一尾氣輸送管路 66: The first exhaust gas delivery pipeline

67:第二尾氣輸送管路 67: Second exhaust gas delivery pipeline

68:抽引模組 68: Extraction module

69:最低爆炸極限分析儀 69: Minimum Explosive Limit Analyzer

7:第一污土前處理單元 7: The first sewage pretreatment unit

71:第二污土輸送管路 71: Second sewage conveying pipeline

72:第二熱回收管路 72: Second heat recovery line

8:待驗土壤處理單元 8: Soil treatment unit to be tested

81:第三污土輸送管路 81: The third sewage conveying pipeline

第一圖:本發明之架構圖 The first picture: the structure diagram of the present invention

而為令本發明之技術手段及其所能達成之效果,能夠有更完整且清楚的揭露,茲詳細說明如下,請一併參閱揭露之圖式及圖號:首先,請參閱第一圖所示,為本發明之土壤污染之熱處理系統,係包含:一乾燥單元(1),係為一間接加熱旋轉爐,包含有一第一內旋轉爐(11)及一包覆該第一內旋轉爐(11)之第一固定外爐(12),該第一內旋轉爐(11)的加熱溫度係設定為100~200℃,另該第一固定外爐(12)的加熱溫度係設定為250~ 800℃,並使該第一內旋轉爐(11)形成有相對之一第一污土輸入端及一第一污土輸出端,且使該第一內旋轉爐(11)之第一污土輸入端與一第一污土前處理單元(7)間以一第二污土輸送管路(71)相連結,又使該第一內旋轉爐(11)於其第一污土輸入端的同側連結有一第一惰氣輸入管路(13),且使該第一內旋轉爐(11)於其第一污土輸出端的同側設有一第一排塵端,另使該第一固定外爐(12)設有一第二餘熱輸出端,以與該污土前處理單元(7)之第二餘熱接收端間以一第二熱回收管路(72)相連結;一熱脫附單元(2),係為一間接加熱旋轉爐,包含有一第二內旋轉爐(21)及一包覆該第二內旋轉爐(21)之第二固定外爐(22),該第二內旋轉爐(21)的加熱溫度係設定為450~900℃,另該第二固定外爐(22)的加熱溫度係設定為600~1050℃,並使該第二內旋轉爐(21)形成有相對之一第二污土輸入端及一第二污土輸出端,且使該第二內旋轉爐(21)之第二污土輸入端與該乾燥單元(1)其第一內旋轉爐(11)之第一污土輸出端間以一第一污土輸送管路(23)相連結,又使該第二內旋轉爐(21)於其第二污土輸入端的同側連結有一第二惰氣輸入管路(24),另使該第二內旋轉爐(11)的第二污土輸出端與一待驗土壤處理單元(8)間以一第三污土輸送管路(81)相連結,又使該第二內旋轉爐(21)於其第二污土輸出端的同側設有一第二排塵端,另使該第二固定外爐(22)設有一第一餘熱輸出端,以與該乾燥單元(1)其第一固定外爐(12)所設之第一餘熱接收端間以一第一熱回收管路(25)相連結;二除塵單元(3),係包含一第一除塵單元(31)及一第二除塵單元(32),乃使該第一除塵單元(31)形成有相對之一第一輸入端及一第一輸出端,並使該第一除塵單元(31)的第一輸入端與該乾燥單元(1)其第一排塵端間以一第一集塵管路(33)相連結,另使該第二除塵單元(32)形成有相對之一第二輸入端及一 第二輸出端,且使該第二除塵單元(32)的第二輸入端與該熱脫附單元(2)其第二排塵端間以一第二集塵管路(34)相連結;二熱交換單元(4),係包含一第一熱交換單元(41)及一第二熱交換單元(42),乃使該第一熱交換單元(41)設有一第一導入端,以與該第一除塵單元(31)第一輸出端間以一第一輸送管路(35)相連結,另使該第二熱交換單元(42)設有一第二導入端,以與該第二除塵單元(32)第二輸出端間以一第二輸送管路(36)相連結,又使該第一熱交換單元(41)與該污土前處理單元(7)間以一熱交換管路(43)相連結,且使該第一熱交換單元(41)經由該熱交換管路(43)而與一第一冷凝模組(44)之第一冷卻管路(45)相連結,另使該第二熱交換單元(42)與一第二冷凝模組(46)間以一第二冷卻管路(47)相連結;二油水分離單元(5),係包含一第一油水分離單元(51)及一第二油水分離單元(52),乃使該第一熱交換單元(41)設有一第一廢液輸出端,以與該第一油水分離單元(51)之輸入端間以一第一廢液管路(53)相連結,另使該第二熱交換單元(42)設有一第二廢液輸出端,以與該第二油水分離單元(52)之輸入端間以一第二廢液管路(54)相連結;一尾氣處理單元(6),係包含有一混合防爆器(61)、一尾氣裂解模組(62)、一尾氣還原模組(63)及一煙囪(64),乃使該混合防爆器(61)、尾氣裂解模組(62)、尾氣還原模組(63)及煙囪(64)間分別以一輸氣管路(65)依序連結,又使該第一熱交換單元(41)設有一第一尾氣輸出端,以與該混合防爆器(61)間以一第一尾氣輸送管路(66)相連結,且使該第二熱交換單元(42)設有一第二尾氣輸出端,以與該混合防爆器(61)間以一第二尾氣輸送管路(67)相連結,而於該第一尾氣輸送管路(66)及第二尾氣輸送管路(67)上係各設有至少一風車等抽引模組(68),又於該混合防爆器(61)連結有一第三惰氣輸入管路(611),另於該混合防爆器(61)與尾 氣裂解模組(62)相連結的輸氣管路(65)間係設有一最低爆炸極限分析儀(69),而該尾氣裂解模組(62)係可為直燃式焚化爐〔TO〕或蓄熱式焚化爐〔RTO〕。 In order to make the technical means of the present invention and the effects that can be achieved, more complete and clear disclosure, the detailed description is as follows, please refer to the disclosed drawings and drawing numbers: First, please refer to the first figure. Shown, the heat treatment system for soil pollution of the present invention comprises: a drying unit (1), which is an indirect heating rotary furnace, including a first inner rotary furnace (11) and a coating of the first inner rotary furnace (11) The first fixed outer furnace (12), the heating temperature of the first inner rotary furnace (11) is set to 100-200°C, and the heating temperature of the first fixed outer furnace (12) is set to 250°C ~ 800 ° C, and the first inner rotary furnace (11) is formed with a first dirt input end and a first dirt output end opposite, and the first dirt of the first inner rotary furnace (11) is formed. The input end is connected with a first sewage pre-processing unit (7) by a second sewage conveying pipeline (71), and the first inner rotary furnace (11) is connected to the same first sewage input end. A first inert gas input pipeline (13) is connected to the side, and the first inner rotary furnace (11) is provided with a first dust discharge end on the same side of the first dirt output end, and the first fixed outer The furnace (12) is provided with a second waste heat output end to be connected with the second waste heat receiving end of the soil pretreatment unit (7) by a second heat recovery pipeline (72); a thermal desorption unit (72) 2), is an indirect heating rotary furnace, comprising a second inner rotary furnace (21) and a second fixed outer furnace (22) covering the second inner rotary furnace (21), the second inner rotary furnace (22) The heating temperature of (21) is set at 450~900°C, and the heating temperature of the second fixed outer furnace (22) is set at 600~1050°C, and the second inner rotary furnace (21) is formed with a relative A second dirt input end and a second dirt output end, and connect the second dirt input end of the second inner rotary furnace (21) with the first inner rotary furnace (11) of the drying unit (1) The first sewage output end is connected with a first sewage conveying pipeline (23), and the second inner rotary furnace (21) is connected with a second inert gas on the same side of the second sewage input end an input pipeline (24), and a third sewage conveying pipeline (81) is connected between the second sewage output end of the second inner rotary furnace (11) and a soil processing unit (8) to be tested , and the second inner rotary furnace (21) is provided with a second dust discharge end on the same side of its second dirt output end, and the second fixed outer furnace (22) is provided with a first waste heat output end, so as to A first heat recovery pipeline (25) is connected with the first waste heat receiving end of the first fixed outer furnace (12) of the drying unit (1); two dust removal units (3) include a first heat recovery pipe (25). A dust removal unit (31) and a second dust removal unit (32), so that the first dust removal unit (31) is formed with a first input end and a first output end opposite, and the first dust removal unit (31) is formed with a first input end and a first output end opposite. 31) The first input end of the drying unit (1) is connected with the first dust discharge end of the drying unit (1) by a first dust collection pipeline (33), and the second dust removal unit (32) is formed with an opposite one. the second input terminal and a the second output end, and the second input end of the second dust removal unit (32) and the second dust discharge end of the thermal desorption unit (2) are connected by a second dust collection pipeline (34); The two heat exchange units (4) comprise a first heat exchange unit (41) and a second heat exchange unit (42), so that the first heat exchange unit (41) is provided with a first introduction end to communicate with The first output end of the first dust removal unit (31) is connected with a first conveying pipeline (35), and the second heat exchange unit (42) is provided with a second inlet end to connect with the second dust removal unit The second output end of the unit (32) is connected by a second conveying pipeline (36), and a heat exchange pipeline is connected between the first heat exchange unit (41) and the soil pretreatment unit (7) (43) are connected, and the first heat exchange unit (41) is connected with the first cooling line (45) of a first condensing module (44) through the heat exchange line (43), and the other is The second heat exchange unit (42) and a second condensing module (46) are connected by a second cooling pipeline (47); the second oil-water separation unit (5) includes a first oil-water separation unit (51) and a second oil-water separation unit (52), so that the first heat exchange unit (41) is provided with a first waste liquid output end, so as to connect with the input end of the first oil-water separation unit (51) A first waste liquid pipeline (53) is connected, and the second heat exchange unit (42) is provided with a second waste liquid output end, so as to connect with the input end of the second oil-water separation unit (52) by a The second waste liquid pipeline (54) is connected; an exhaust gas treatment unit (6) includes a mixed explosion-proof device (61), an exhaust gas cracking module (62), an exhaust gas reduction module (63) and a chimney (64), so that the mixed explosion-proof device (61), the exhaust gas cracking module (62), the exhaust gas reduction module (63) and the chimney (64) are respectively connected with a gas pipeline (65) in sequence, and the The first heat exchange unit (41) is provided with a first exhaust gas output end, which is connected with the hybrid explosion-proof device (61) by a first exhaust gas conveying pipeline (66), and makes the second heat exchange unit ( 42) A second exhaust gas output end is provided to connect with the hybrid explosion-proof device (61) by a second exhaust gas delivery pipeline (67), and between the first exhaust gas delivery pipeline (66) and the second exhaust gas The conveying pipelines (67) are each provided with at least one extraction module (68) such as a windmill, and a third inert gas input pipeline (611) is connected to the mixed explosion-proof device (61). device (61) with tail A minimum explosion limit analyzer (69) is arranged between the gas transmission pipelines (65) connected to the gas cracking module (62), and the exhaust gas cracking module (62) can be a direct-fired incinerator (TO) or Regenerative incinerator (RTO).

據此,當使用實施時,係將遭汽油、柴油、煤油或航空用油等油品污染的土壤置於該污土前處理單元(7)內預熱至40~80℃,再將該含油污土經第二污土輸送管路(71)輸送進該乾燥單元(1)之第一內旋轉爐(11)中,以使該含油污土於該第一內旋轉爐(11)內以約100~200℃的溫度加熱乾燥約20~60分鐘,而將該含油污土中所含水分及低沸點油品蒸出。 Accordingly, when using and implementing, the soil polluted by gasoline, diesel, kerosene or aviation oil is placed in the sewage pre-treatment unit (7) to be preheated to 40~80°C, and then the soil containing The oily soil is transported into the first inner rotary furnace (11) of the drying unit (1) through the second soil transportation pipeline (71), so that the oily soil is transported in the first inner rotary furnace (11) to the first inner rotary furnace (11). Heating and drying at a temperature of about 100-200°C for about 20-60 minutes, and steaming out the water and low-boiling oil products contained in the oily soil.

續將該乾燥後的含油污土經第一污土輸送管路(23)輸送至該熱脫附單元(2)的第二內旋轉爐(21)中,以使該含油污土於該第二內旋轉爐(21)以約450~900℃的高溫加熱約20~60分鐘,以使土壤中所含水分及各種油品全部蒸出,而與土壤完全脫附分離,達到淨化土壤效果,該淨化後的土壤係經第三污土輸送管路(81)輸送至待驗土壤處理單元(8),以檢查該土壤內是否還含有油品等污染物。而值得一提的是本發明之第一內旋轉爐(11)及第二內旋轉爐(21)係為密閉負壓環境,且會視該含油污土的含油濃度而定,分別從第一內旋轉爐(11)及第二內旋轉爐(21)之第一惰氣輸入管路(13)與第二惰氣輸入管路(24)將氮等惰氣打入第一內旋轉爐(11)及第二內旋轉爐(21)內,以確保油品蒸發、脫附時不會發生爆炸危險。 Continue to transport the dried oily soil to the second inner rotary furnace (21) of the thermal desorption unit (2) through the first soil conveying pipeline (23), so that the oily soil can be transported to the second inner rotary furnace (21) of the thermal desorption unit (2). The second inner rotary furnace (21) is heated at a high temperature of about 450~900°C for about 20~60 minutes, so that all the water and various oil products in the soil are evaporated, and completely desorbed and separated from the soil, so as to achieve the effect of purifying the soil. The purified soil is transported to the soil processing unit (8) to be tested through the third soil transport pipeline (81) to check whether the soil still contains oil and other pollutants. It is worth mentioning that the first inner rotary furnace (11) and the second inner rotary furnace (21) of the present invention are closed negative pressure environments, and will depend on the oil concentration of the oily soil. The first inert gas input pipeline (13) and the second inert gas input pipeline (24) of the inner rotary furnace (11) and the second inner rotary furnace (21) inject inert gas such as nitrogen into the first inner rotary furnace ( 11) and the second inner rotary furnace (21) to ensure that there is no danger of explosion when the oil is evaporated and desorbed.

再者,當該含油污土於該第一內旋轉爐(11)內旋轉加熱時,所引起的粉塵、水氣及油氣等係會經第一集塵管路(33)進入第一除塵單元(31)中,另該含油污土於該第二內旋轉爐(21)內旋轉加熱時所引起的粉塵、水氣及油氣等也會經第二集塵管路(34)進入第二除塵單元(32)中,該粉塵等粒狀污染物係會留置於第一除塵單元(31)及第二除塵單元(32),另水氣及油氣等則會分別經由第一輸送管路(35)及第二輸送管路(36)輸送往第一熱交換單元(41)及第二熱交換單元(42),此時,該第一除塵單元(31)輸出的水氣及油氣約為150℃,而第二除塵單元 (32)輸出的水氣及油氣則約為450℃,在分別輸入該第一熱交換單元(41)及第二熱交換單元(42)後,藉由第一熱交換單元(41)及第二熱交換單元(42)所連結的第一冷凝模組(44)及第二冷凝模組(46)降溫至約10~60℃後,該水氣及油氣係會凝結成液體,以分別由該第一熱交換單元(41)及第二熱交換單元(42)連結的第一廢液管路(53)及第二廢液管路(54)輸送至第一油水分離單元(51)及第二油水分離單元(52)進行油水分離,該分離出的廢水及混合油係可回收再利用。 Furthermore, when the oily soil is heated by rotation in the first inner rotary furnace (11), the resulting dust, water vapor and oil and gas will enter the first dust removal unit through the first dust collection pipeline (33). In (31), the dust, water vapor and oil and gas, etc. caused by the oily soil during the rotary heating in the second inner rotary furnace (21) will also enter the second dust removal through the second dust collection pipeline (34). In the unit (32), the particulate pollutants such as dust will remain in the first dust removal unit (31) and the second dust removal unit (32), and the water vapor and oil and gas will pass through the first conveying pipeline (35) respectively. ) and the second conveying pipeline (36) are conveyed to the first heat exchange unit (41) and the second heat exchange unit (42). °C, while the second dust removal unit (32) The output water vapor and oil and gas are about 450°C. After being input to the first heat exchange unit (41) and the second heat exchange unit (42) respectively, the first heat exchange unit (41) and the second heat exchange unit (42) After the first condensing module (44) and the second condensing module (46) connected to the two heat exchange units (42) are cooled to about 10-60° C., the water vapor and the oil and gas system will condense into liquid, so that the The first waste liquid pipeline (53) and the second waste liquid pipeline (54) connecting the first heat exchange unit (41) and the second heat exchange unit (42) are transported to the first oil-water separation unit (51) and The second oil-water separation unit (52) performs oil-water separation, and the separated waste water and mixed oil system can be recovered and reused.

另於該第一熱交換單元(41)及第二熱交換單元(42)處未凝結成液態的有機氣體〔voc〕則會分別經由第一尾氣輸送管路(66)及第二尾氣輸送管路(67)輸送往尾氣處理單元(6)之混合防爆器(61),再將氮等惰氣經該第三惰氣輸入管路(611)打入混合防爆器(61)內,以與有機氣體相混合,續該混合有惰氣之有機氣體係會經輸氣管路(65)輸送往尾氣裂解模組(62),而於輸送往尾氣裂解模組(62)前會通過最低爆炸極限分析儀(69)檢測其濃度,以確定該混合惰氣之有機氣體不會產生爆炸後,再送進該尾氣裂解模組(62),以於該尾氣裂解模組(62)內以約1050℃的高溫將該有機氣體裂解成水蒸氣及二氧化碳,假設該有機氣體中含有硫及鹵素等成分則藉由該增設之尾氣還原模組(63)去除其臭味等後,再經煙囪(64)排放於大氣中,若未含有硫及鹵素等成分則於經尾氣裂解模組(62)高溫裂解後直接經煙囪(64)排放於大氣。 In addition, the organic gas (voc) that is not condensed into liquid at the first heat exchange unit (41) and the second heat exchange unit (42) will pass through the first exhaust gas conveying pipe (66) and the second exhaust gas conveying pipe, respectively. The pipeline (67) is transported to the mixed explosion-proof device (61) of the exhaust gas treatment unit (6), and then inert gas such as nitrogen is injected into the mixed explosion-proof device (61) through the third inert gas input pipeline (611), so as to be combined with the explosion-proof device (61). The organic gas is mixed, and the organic gas system mixed with the inert gas will be transported to the exhaust gas cracking module (62) through the gas transmission pipeline (65), and will pass the minimum explosion limit before being transported to the exhaust gas cracking module (62). The analyzer (69) detects its concentration to determine that the organic gas mixed with the inert gas will not explode, and then is sent to the tail gas cracking module (62), so that the temperature is about 1050° C. in the tail gas cracking module (62). The high temperature of the organic gas is decomposed into water vapor and carbon dioxide. Assuming that the organic gas contains components such as sulfur and halogen, the odor, etc., are removed by the additional exhaust gas reduction module (63), and then passed through the chimney (64). It is discharged into the atmosphere, and if it does not contain components such as sulfur and halogen, it is directly discharged into the atmosphere through the chimney (64) after being pyrolyzed by the exhaust gas cracking module (62).

而值得一提的是,本發明係於熱脫附單元(2)之第二固定外爐(22)與乾燥單元(1)之第一固定外爐(12)間以一第一熱回收管路(25)相連結,以將該熱脫附單元(2)運作產生餘熱經由第一熱回收管路(25)供應予乾燥單元(1),即可提供該乾燥單元(1)進行土壤乾燥所需的熱能,又該乾燥單元(1)運作所剩餘熱,則可經由第二熱回收管路(72)輸送至污土前處理單元(7),以作為污染土壤預熱使用,另該污土前處理單元(7)亦可經由熱交換管路(43)與第一熱交換單元(41)進行熱交換,以維持其土壤預熱所需熱源,故本發明僅須於熱脫附單元(2)燃燒柴油等燃 料加熱,而於乾燥單元(1)及污土前處理單元(7)處皆無須再使用燃料加熱,以有效節省能源使用。另本發明之尾氣裂解模組(62)於採用蓄熱式焚化爐進行有機氣體的裂解時,該有機氣體於燃燒過程會因氧化產生高熱量,該熱量係會由該蓄熱式焚化爐內所設蓄熱元件回收後,再供應予該蓄熱式焚化爐加熱使用,以降低該蓄熱式焚化爐所需熱能燃料用量,據此,本發明係可大幅節省整體系統運作所需耗費能源,而達到有效降低燃料費用等效益。 It is worth mentioning that the present invention uses a first heat recovery pipe between the second fixed outer furnace (22) of the thermal desorption unit (2) and the first fixed outer furnace (12) of the drying unit (1). The road (25) is connected to supply the waste heat generated by the operation of the thermal desorption unit (2) to the drying unit (1) through the first heat recovery pipeline (25), and the drying unit (1) can be provided for soil drying. The required heat energy and the residual heat from the operation of the drying unit (1) can be transported to the soil pre-treatment unit (7) through the second heat recovery pipeline (72) for preheating the polluted soil. The soil pretreatment unit (7) can also conduct heat exchange with the first heat exchange unit (41) through the heat exchange pipeline (43) to maintain the heat source required for soil preheating, so the present invention only needs to be used for thermal desorption Unit (2) burns diesel fuel etc. Therefore, the drying unit (1) and the soil pre-processing unit (7) do not need to use fuel for heating, so as to effectively save energy. In addition, when the exhaust gas cracking module (62) of the present invention uses a regenerative incinerator to crack organic gas, the organic gas will generate high heat due to oxidation during the combustion process, and the heat will be generated by the regenerative incinerator. After the regenerative element is recovered, it is then supplied to the regenerative incinerator for heating, so as to reduce the amount of thermal energy and fuel required by the regenerative incinerator. Accordingly, the present invention can greatly reduce the energy consumption required for the operation of the overall system, thereby effectively reducing the benefits such as fuel costs.

前述之實施例或圖式並非限定本發明之土壤污染之熱處理系統實施態樣,凡所屬技術領域中具有通常知識者所為之適當變化或修飾,皆應視為不脫離本發明之專利範疇。 The foregoing embodiments or drawings do not limit the implementation of the heat treatment system for soil pollution of the present invention, and any appropriate changes or modifications made by those with ordinary knowledge in the technical field should be considered as not departing from the scope of the present invention.

由上述結構及實施方式可知,本發明係具有如下優點: As can be seen from the above structure and implementation, the present invention has the following advantages:

1.本發明之土壤污染之熱處理系統係將熱脫附單元運作產生的餘熱經熱回收管路依序供應予乾燥單元及污土前處理單元等使用,故僅須於熱脫附單元使用燃料加熱,而於乾燥單元及污土前處理單元處則無須再使用燃料,藉此,以節省整體系統運作耗費能源,達到有效降低成本效益。 1. The heat treatment system for soil pollution of the present invention supplies the waste heat generated by the operation of the thermal desorption unit to the drying unit and the soil pre-treatment unit in sequence through the heat recovery pipeline, so only fuel needs to be used in the thermal desorption unit. Heating, and no need to use fuel at the drying unit and the sewage pre-treatment unit, thereby saving the energy consumption of the overall system operation and effectively reducing the cost efficiency.

2.本發明之土壤污染之熱處理系統係設有尾氣處理單元,以將土壤熱脫附後產生的尾氣,經由尾氣處理單元之混合防爆器及尾氣裂解模組等裂解成水蒸氣及二氧化碳後再排放於大氣,依此,以避免有機氣體對環境造成二次污染。 2. The heat treatment system for soil pollution of the present invention is provided with a tail gas treatment unit, so that the tail gas generated after the thermal desorption of the soil is decomposed into water vapor and carbon dioxide through the mixed explosion-proof device and the tail gas cracking module of the tail gas treatment unit. It is discharged into the atmosphere, so as to avoid secondary pollution caused by organic gases to the environment.

3.本發明之土壤污染之熱處理系統係設有除塵單元及熱交換單元,以將含油污土於乾燥及熱脫附過程中引起的粉塵、水氣及油氣等經過除塵單元去除粉塵後,再由熱交換單元將高溫之水氣及油氣等冷凝成液體後,經油水分離單元分離出廢水及混合油後,以利回收再利用。 3. The heat treatment system for soil pollution of the present invention is provided with a dust removal unit and a heat exchange unit, so that the dust, water vapor and oil and gas caused by the drying and thermal desorption of the oily soil are removed by the dust removal unit, and then regenerated. After the heat exchange unit condenses the high-temperature water vapor and oil and gas into liquid, the waste water and mixed oil are separated by the oil-water separation unit for recycling and reuse.

綜上所述,本發明之實施例確能達到所預期功效,又其所揭露之具體構造,不僅未曾見諸於同類產品中,亦未曾公開於申請前,誠已完全符合 專利法之規定與要求,爰依法提出發明專利之申請,懇請惠予審查,並賜准專利,則實感德便。 To sum up, the embodiments of the present invention can indeed achieve the expected effects, and the specific structures disclosed have not only not been seen in similar products, but also have not been disclosed before the application. In accordance with the provisions and requirements of the Patent Law, it is truly grateful to file an application for an invention patent in accordance with the law.

1:乾燥單元 11:第一內旋轉爐 12:第一固定外爐 13:第一惰氣輸入管路 2:熱脫附單元 21:第二內旋轉爐 22:第二固定外爐 23:第一污土輸送管路 24:第二惰氣輸入管路 25:第一熱回收管路 3:除塵單元 31:第一除塵單元 32:第二除塵單元 33:第一集塵管路 34:第二集塵管路 35:第一輸送管路 36:第二輸送管路 4:熱交換單元 41:第一熱交換單元 42:第二熱交換單元 43:熱交換管路 44:第一冷凝模組 45:第一冷卻管路 46:第二冷凝模組 47:第二冷卻管路 5:油水分離單元 51:第一油水分離單元 52:第二油水分離單元 53:第一廢液管路 54:第二廢液管路 6:尾氣處理單元 61:混合防爆器 611:第三惰氣輸入管路 62:尾氣裂解模組 63:尾氣還原模組 64:煙囪 65:輸氣管路 66:第一尾氣輸送管路 67:第二尾氣輸送管路 68:抽引模組 69:最低爆炸極限分析儀 7:第一污土前處理單元 71:第二污土輸送管路 72:第二熱回收管路 8:待驗土壤處理單元 81:第三污土輸送管路 1: Drying unit 11: The first inner rotary furnace 12: The first fixed outer furnace 13: The first inert gas input line 2: Thermal desorption unit 21: Second inner rotary furnace 22: Second fixed outer furnace 23: The first sewage conveying pipeline 24: Second inert gas input line 25: The first heat recovery line 3: Dust removal unit 31: The first dust removal unit 32: Second dust removal unit 33: The first dust collection pipeline 34: The second dust collection pipeline 35: The first conveying pipeline 36: Second delivery pipeline 4: heat exchange unit 41: The first heat exchange unit 42: Second heat exchange unit 43: Heat Exchange Line 44: The first condensation module 45: The first cooling line 46: Second condensing module 47: Second cooling line 5: Oil-water separation unit 51: The first oil-water separation unit 52: Second oil-water separation unit 53: The first waste liquid pipeline 54: Second waste liquid pipeline 6: Exhaust gas treatment unit 61: Hybrid explosion-proof device 611: Third inert gas input line 62: Exhaust gas cracking module 63: Exhaust gas reduction module 64: Chimney 65: Gas pipeline 66: The first exhaust gas delivery pipeline 67: Second exhaust gas delivery pipeline 68: Extraction module 69: Minimum Explosive Limit Analyzer 7: The first sewage pretreatment unit 71: Second sewage conveying pipeline 72: Second heat recovery line 8: Soil treatment unit to be tested 81: The third sewage conveying pipeline

Claims (8)

一種土壤污染之熱處理系統,係包含:一乾燥單元,乃使該乾燥單元形成有相對之一第一污土輸入端及一第一污土輸出端,又使該乾燥單元於該第一污土輸出端的同側設有一第一排塵端,另使該乾燥單元設有一第一餘熱接收端;一熱脫附單元,係使該熱脫附單元形成有相對之一第二污土輸入端及一第二污土輸出端,且使該乾燥單元之第一污土輸出端與該熱脫附單元之第二污土輸入端間以一第一污土輸送管路相連結,又使該熱脫附單元於其第二污土輸出端的同側設有一第二排塵端,另使該熱脫附單元設有一第一餘熱輸出端,以與該乾燥單元之第一餘熱接收端間以一第一熱回收管路相連結;二除塵單元,係包含一第一除塵單元及一第二除塵單元,乃使該第一除塵單元形成有相對之一第一輸入端及一第一輸出端,並使該第一除塵單元之第一輸入端與該乾燥單元之第一排塵端間以一第一集塵管路相連結,另使該第二除塵單元形成有相對之一第二輸入端及一第二輸出端,且使該第二除塵單元之第二輸入端與該熱脫附單元之第二排塵端間以一第二集塵管路相連結;二熱交換單元,係包含一第一熱交換單元及一第二熱交換單元,乃使該第一熱交換單元設有一第一導入端,以與該第一除塵單元的第一輸出端間以一第一輸送管路相連結,另使該第二熱交換單元設有一第二導入端,以與該第二除塵單元的第二輸出端間以一第二輸送管路相連結,又使該第一熱交換單元與一第一冷凝模組間以一第一冷卻管路相連結,並使該第二熱交換單元與一第二冷凝模組間以一第二 冷卻管路相連結,另使該第一熱交換單元及第二熱交換單元分別設有一第一尾氣輸出端及一第二尾氣輸出端;一污土前處理單元,乃使該污土前處理單元與該乾燥單元之第一污土輸入端間以一第二污土輸送管路相連結,又使該污土前處理單元設有一第二餘熱接收端,另於該乾燥單元設有一第二餘熱輸出端,且使該污土前處理單元之第二餘熱接收端與該乾燥單元之第二餘熱輸出端間以一第二熱回收管路相連結,另使該污土前處理單元與第一熱交換單元間以一熱交換管路相連結;二油水分離單元,係包含一第一油水分離單元及一第二油水分離單元,乃使該第一熱交換單元設有一第一廢液輸出端,以與該第一油水分離單元之輸入端間以一第一廢液管路相連結,另使該第二熱交換單元設有一第二廢液輸出端,以與該第二油水分離單元之輸入端間以一第二廢液管路相連結;一尾氣處理單元,係使該第一熱交換單元之第一尾氣輸出端與該尾氣處理單元間以一第一尾氣輸送管路相連結,另使該第二熱交換單元之第二尾氣輸出端與該尾氣處理單元間以一第二尾氣輸送管路相連結。 A heat treatment system for soil pollution, comprising: a drying unit, so that the drying unit is formed with a first sewage input end and a first sewage output end opposite, and the drying unit is connected to the first sewage The same side of the output end is provided with a first dust discharge end, and the drying unit is provided with a first waste heat receiving end; a heat desorption unit is formed with a second dirt input end opposite to the heat desorption unit and A second sewage output end, and the first sewage output end of the drying unit and the second sewage input end of the thermal desorption unit are connected by a first sewage conveying pipeline, and the heat The desorption unit is provided with a second dust discharge end on the same side of the second dirt output end, and the thermal desorption unit is provided with a first waste heat output end, so as to be connected with the first waste heat receiving end of the drying unit by a The first heat recovery pipeline is connected; the two dedusting units include a first dedusting unit and a second dedusting unit, so that the first dedusting unit is formed with a first input end and a first output end opposite to each other, The first input end of the first dust removal unit and the first dust discharge end of the drying unit are connected by a first dust collection pipeline, and the second dust removal unit is formed with an opposite second input end and a second output end, and the second input end of the second dust removal unit and the second dust discharge end of the thermal desorption unit are connected by a second dust collection pipeline; two heat exchange units, including A first heat exchange unit and a second heat exchange unit, so that the first heat exchange unit is provided with a first introduction end, so as to be connected with the first output end of the first dust removal unit through a first conveying pipeline In addition, the second heat exchange unit is provided with a second inlet end to be connected with the second output end of the second dust removal unit by a second conveying pipeline, and the first heat exchange unit is connected to a The first condensing modules are connected by a first cooling pipeline, and the second heat exchange unit and a second condensing module are connected by a second The cooling pipes are connected, and the first heat exchange unit and the second heat exchange unit are respectively provided with a first exhaust gas output end and a second exhaust gas output end; a sewage pretreatment unit is used to preprocess the sewage The unit and the first sewage input end of the drying unit are connected by a second sewage conveying pipeline, and the sewage pretreatment unit is provided with a second waste heat receiving end, and the drying unit is provided with a second The waste heat output end is connected with a second heat recovery pipeline between the second waste heat receiving end of the soil pre-treatment unit and the second waste heat output end of the drying unit, and the soil pre-treatment unit is connected with the second waste heat output end. A heat exchange unit is connected by a heat exchange pipeline; a second oil-water separation unit includes a first oil-water separation unit and a second oil-water separation unit, so that the first heat exchange unit is provided with a first waste liquid output A first waste liquid pipeline is connected with the input end of the first oil-water separation unit, and the second heat exchange unit is provided with a second waste liquid output end to connect with the second oil-water separation unit The input ends are connected by a second waste liquid pipeline; an exhaust gas treatment unit is connected with a first exhaust gas conveying pipeline between the first exhaust gas output end of the first heat exchange unit and the exhaust gas treatment unit In addition, the second exhaust gas output end of the second heat exchange unit and the exhaust gas processing unit are connected by a second exhaust gas conveying pipeline. 如請求項1所述之土壤污染之熱處理系統,其中,該乾燥單元係為一間接加熱旋轉爐,主要包含有一第一內旋轉爐及一包覆該第一內旋轉爐之第一固定外爐,並使該乾燥單元之第一內旋轉爐相對二端各形成該第一污土輸入端及第一污土輸出端,又使該第一內旋轉爐於其第一污土輸出端的同側設有該第一排塵端,且於該第一固定外爐設有其第一餘熱接收端,另該熱脫附單元係為一間接加熱旋轉爐,主要包含有一第二內旋轉爐及一包覆該第二內旋轉爐之第二固定外爐,乃使熱脫附單元之 第二內旋轉爐相對二端各形成該第二污土輸入端及第二污土輸出端,又使該第二內旋轉爐於其第二污土輸出端的同側設有其第二排塵端,且於該第二固定外爐設有其第一餘熱輸出端。 The heat treatment system for soil pollution according to claim 1, wherein the drying unit is an indirect heating rotary furnace, which mainly includes a first inner rotary furnace and a first fixed outer furnace covering the first inner rotary furnace , and make the first inner rotary furnace of the drying unit form the first dirt input end and the first dirt output end respectively, and make the first inner rotary furnace on the same side of its first dirt output end The first dust discharge end is provided, and the first stationary outer furnace is provided with its first waste heat receiving end. In addition, the thermal desorption unit is an indirect heating rotary furnace, which mainly includes a second inner rotary furnace and a second inner rotary furnace. The second fixed outer furnace covering the second inner rotating furnace is to allow the thermal desorption unit to The opposite ends of the second inner rotary furnace respectively form the second dirt input end and the second dirt output end, and the second inner rotary furnace is provided with its second dust discharge end on the same side of the second dirt output end. The second fixed outer furnace is provided with its first waste heat output end. 如請求項2所述之土壤污染之熱處理系統,其中,該乾燥單元之第一內旋轉爐的加熱溫度係設定為100~200℃,而該第一固定外爐的加熱溫度係設定為250~800℃,另該熱脫附單元之第二內旋轉爐的加熱溫度係設定為450~900℃,而該第二固定外爐的加熱溫度係設定為600~1050℃。 The heat treatment system for soil pollution according to claim 2, wherein the heating temperature of the first inner rotary furnace of the drying unit is set to 100-200°C, and the heating temperature of the first fixed outer furnace is set to 250-250°C 800°C, the heating temperature of the second inner rotary furnace of the thermal desorption unit is set to 450-900°C, and the heating temperature of the second fixed outer furnace is set to 600-1050°C. 如請求項1所述之土壤污染之熱處理系統,其中,該尾氣處理單元係包含有一混合防爆器、一尾氣裂解模組及一煙囪,並使該混合防爆器、尾氣裂解模組及煙囪間分別以一輸氣管路依序連結,又使該第一熱交換單元的第一尾氣輸出端與該混合防爆器間以該第一尾氣輸送管路相連結,且使該第二熱交換單元的第二尾氣輸出端與該混合防爆器間以該第二尾氣輸送管路相連結,另使該混合防爆器連結有一第三惰氣輸入管路。 The heat treatment system for soil pollution according to claim 1, wherein the exhaust gas treatment unit comprises a mixed explosion-proof device, an exhaust gas cracking module and a chimney, and the mixing explosion-proof device, the exhaust gas cracking module and the chimney are separated from each other. Connect a gas transmission pipeline in sequence, and connect the first exhaust gas output end of the first heat exchange unit and the hybrid explosion-proof device with the first exhaust gas transmission pipeline, and make the first exhaust gas transmission pipeline of the second heat exchange unit. The two exhaust gas output ends are connected with the mixed explosion-proof device by the second exhaust gas conveying pipeline, and the mixed explosion-proof device is connected with a third inert gas input pipeline. 如請求項4所述之土壤污染之熱處理系統,其中,該尾氣處理單元係進一步包含有一尾氣還原模組,乃使該尾氣還原模組設於該尾氣裂解模組及煙囪間,並與該尾氣裂解模組及煙囪分別以一輸氣管路相連結。 The heat treatment system for soil pollution according to claim 4, wherein the exhaust gas treatment unit further comprises an exhaust gas reduction module, so that the exhaust gas reduction module is arranged between the exhaust gas cracking module and the chimney, and is connected with the exhaust gas The cracking module and the chimney are respectively connected with a gas pipeline. 如請求項4所述之土壤污染之熱處理系統,其中,該尾氣處理單元之混合防爆器與尾氣裂解模組係於其相連結的輸氣管路間設有一最低爆炸極限分析儀。 The heat treatment system for soil contamination according to claim 4, wherein the mixed explosion-proof device of the exhaust gas treatment unit and the exhaust gas cracking module are connected with a gas pipeline with a minimum explosion limit analyzer. 如請求項4所述之土壤污染之熱處理系統,其中,該尾氣處理單元之尾氣裂解模組係為直燃式焚化爐或蓄熱式焚化爐。 The thermal treatment system for soil pollution according to claim 4, wherein the exhaust gas cracking module of the exhaust gas treatment unit is a direct-fired incinerator or a regenerative incinerator. 如請求項1所述之土壤污染之熱處理系統,其中,該乾燥單元係於其第一污土輸入端的同側連結有一第一惰氣輸入管路,另使該熱脫附單元於其第二污土輸入端的同側連結有一第二惰氣輸入管路。 The heat treatment system for soil pollution as claimed in claim 1, wherein the drying unit is connected to a first inert gas input pipeline on the same side of the first sewage input end, and the thermal desorption unit is connected to the second A second inert gas input pipeline is connected to the same side of the sewage input end.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3841275B2 (en) * 2001-12-03 2006-11-01 有限会社テイエム産業 Contaminated soil treatment system
JP5478141B2 (en) * 2009-08-04 2014-04-23 株式会社ジー・イーテクノス Purification device and purification method for soil or sludge contaminated with volatile specified harmful substances
TW201536441A (en) * 2014-03-24 2015-10-01 Enrestec Inc Merger processing system for oil sludge cracking and contaminated soil thermal desorption
TWM600208U (en) * 2020-05-21 2020-08-21 中石化綠能科技股份有限公司 Soil pollution heat treatment system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3841275B2 (en) * 2001-12-03 2006-11-01 有限会社テイエム産業 Contaminated soil treatment system
JP5478141B2 (en) * 2009-08-04 2014-04-23 株式会社ジー・イーテクノス Purification device and purification method for soil or sludge contaminated with volatile specified harmful substances
TW201536441A (en) * 2014-03-24 2015-10-01 Enrestec Inc Merger processing system for oil sludge cracking and contaminated soil thermal desorption
TWM600208U (en) * 2020-05-21 2020-08-21 中石化綠能科技股份有限公司 Soil pollution heat treatment system

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