TWI720695B - Filter material, water filter device, water purification system and biological water composition - Google Patents

Abstract

The invention provides a filter material, which is used to purify water and produce a biological water composition containing silicic acid and hydrogen. The filter material includes a carrier and an active silicon material, the active silicon material is attached to the carrier, and the size of the filter material is between 50 micrometers (μm) and 10 millimeters (mm).

Description

Filter material, water filter device, water purification system and biological water composition

The present invention relates to a filter material, a water filter device, a water purification system, and a biological water composition, in particular to a filter material that can be used to produce a biological water composition containing silicic acid (soluble silicon) and hydrogen.

In view of the fact that the hydrogen-dissolved drinking water is beneficial to neutralize the pathogenic active oxygen or free radical groups existing in the body after being consumed by the human body, so as to reduce organ damage. Therefore, related research on hydrogen-dissolved drinking water has become a hot research topic in recent years.

Most of the common hydrogen-dissolved drinking water in the market is to directly dissolve high-purity hydrogen in water, or use magnesium powder or magnesium ingot to react with pure water to generate hydrogen, which is called hydrogen-dissolved drinking water. However, the former method has the problems of difficulty in obtaining high-purity hydrogen, difficulty in dissolving hydrogen, and safety. The latter method, because the magnesium hydroxide remaining in pure water is classified as a medicine, it will conflict with some cardiovascular disease medicines. Once the content is too high, it will easily cause acute drug poisoning and acute renal failure. Or problems such as hypermagnesemia.

It can be seen from the above description that making drinking water capable of dissolving hydrogen and providing safe hydrogen-dissolving drinking water is a subject to be broken through by those skilled in the relevant technical fields of the present invention.

Therefore, the first objective of the present invention is to provide a filter material or filter material assembly for purifying water and producing a biological water composition containing silicic acid (soluble silicon) and hydrogen. Since the quantity unit of the term filter material of the present invention covers one or more, in order to understand more clearly, in this article, when the quantity unit is a filter material, it is still called "filter material"; when the quantity unit is a plurality of filter materials, it is referred to collectively. It is the "filter assembly".

Therefore, the filter material of the present invention includes a carrier and an active silicon material, the active silicon material is attached to the carrier, and the size of the filter material is between 50 μm and 10 mm.

The size of the filter material of the present invention may include any of 50 μm to 10 mm, 75.5 μm to 8 mm, 300 μm to 6 mm, 600 μm to 5 mm, and 900 μm to 4 mm. If the size of the filter material is too small, it may easily plug the non-woven fabric or fiber filter in the water filter device (for example, a sponge with 5μm~40μm pores), making the water flow in and out of the water unsmoothly. Furthermore, if the size of the filter material is too small, the overall surface area of the filter material reacting with water will become too large, and the rapid hydrogen generation rate may cause air locks, hindering the flow of water inside the filter material, and containing active silicon material. The reaction with water is quickly consumed, which shortens the service life of the filter material; on the other hand, if the size of the filter material is too large, the surface area that reacts with water becomes smaller, reducing the concentration of hydrogen and silicic acid, and the granulation time of the filter material is reduced. It is longer and the production cost is increased. Therefore, it is better to control the size of the filter material to 50μm~10mm, 75.5μm~8mm is more preferred, and 300μm~5mm is the best.

The active silicon material of the filter material of the present invention is attached to the carrier, and its aspect is, for example, but not limited to, the active silicon material covers more than 50% of the surface area of the carrier, or the active silicon material covers more than 80% of the surface of the carrier, or Even completely cover the surface of the carrier. The larger the coverage area, the tighter the bonding between the active silicon materials, and it is less likely to be separated from the carrier due to the washing of water, so the service life of the filter material is longer. The particle shape of the particulate material is not limited to a spherical shape, a flake shape or an irregular shape.

In the present invention, based on the weight percentage of the filter material, the content of the active silicon material is greater than 10 wt%, preferably, the content of the active silicon material is between 40 wt% and 95 wt%. The active silicon material is, for example, agglomeration of a plurality of silicon nano particles. When the content of the active silicon material is greater than 40wt%, a filter material with a long service life can be filled in a limited space, which means that the economic benefits are more obvious.

The carrier of the filter material of the present invention can be selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fibers, and a combination of the foregoing .

The carrier of the filter material of the present invention may contain a plurality of sub-carriers, and each sub-carrier is independently selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, Silicon particles, polymer fibers, and front A combination of the above. At this time, each filter material is agglomerated by a plurality of sub-carriers and a plurality of nano-silicon particles.

The size of each sub-carrier of at least part of the sub-carriers of the filter material of the present invention is between 0.2 μm and 2.5 mm, preferably 25 μm and 2.5 mm.

The filter material assembly of the present invention includes a plurality of filter materials. In other words, the filter material assembly includes at least one carrier and an active silicon material (such as a nanosilicon material containing a plurality of silicon nanoparticles) attached to the surface of the carrier. The carrier may be selected from the following groups: a single main carrier, a plurality of sub-carriers, a silicon particle, and a fiber material. The first three are classified as granular materials. For example, a filter material assembly contains three filter materials, the first is a filter material containing a single carrier (called the main carrier), the second is a filter material containing multiple carriers (called sub-carriers), and the third is a filter material containing silicon particles. Filter material, but the present invention is not limited to this.

The filter material assembly can also be a collection of two or four filter materials. For example, the filter materials include a plurality of first filter materials and a plurality of second filter materials. The size of the first filter materials is larger than the size of the second filter materials. The content of the first filter materials is different based on the weight percentage of the filter material assembly. In the content of the second filter material.

When the carrier in each filter material is selected from the main carrier, the sub-carriers, or the silicon particles, the size of the main carrier can be 25μm~2.5mm or at least part of the size of each sub-carrier of the sub-carriers It can be between 0.2μm~2.5mm. When the carrier in each filter material is selected from a main carrier, a plurality of sub-carriers, or silicon particles, the size of the filter materials may range from 50 μm to 10 mm.

The active silicon material of the present invention contains a plurality of nano-scale silicon nano-particles, and the size of each of the nano-silicon particles can range from 50 nanometers (nm) to 800 nanometers (nm), 100nm to 400nm, and 150nm to 350nm. , Or 200nm to 300nm.

When a carrier of the filter material of the present invention (such as a single main carrier, a plurality of sub-carriers, a silicon particle, or a fiber material) is completely covered by the active silicon material and forms an active layer (active layer), the The thickness can range from 200 nanometers (nm) to 3 millimeters (mm). The thicker the active layer, the tighter the combination of active silicon materials and the greater the amount, which can make the filter material have a longer life.

The filter material assembly of the present invention includes a plurality of filter materials and a bonding material for bonding the filter materials to each other. The filter materials are formed by a plurality of carriers and a nanosilicon material attached to the surface of the carriers and containing a plurality of nanosilicon particles. . The nanosilicon material covers more than 10% of the surface area of each carrier. That is, nano-silicon materials can completely cover the surface of a carrier or expose part of the surface of a carrier, each has its advantages. The advantage of the former is that the nanosilica particles are tightly combined, which can make the filter material have a longer service life. The advantage of the latter is that the adhesion between adjacent filter materials is improved, and it is less likely to peel off due to water erosion or pressure. The amount of nanosilicon used can be adjusted according to the needs of users.

The bonding material is selected from the group consisting of polyether, acrylic resin, styrene, polyamide, polyester, polyolefin, cellulose, polyethylene, glycerin, polyethylene glycol, polyvinyl alcohol and A combination of the foregoing.

The filter material assembly of the present invention includes a plurality of filter materials and a plurality of auxiliary filter materials. Each auxiliary filter material is selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles , Polymer fiber, and a combination of the foregoing.

A plurality of silver nano particles or a plurality of zinc nano particles are attached to the surface of each auxiliary filter material.

The second object of the present invention is to provide a water filter device using the filter material or filter material assembly described in the first object.

Therefore, the water filter device of the present invention includes a first carrier and a filter material or filter material assembly placed therein. The first carrier defines a first accommodating space and includes a first accommodating space communicating with the first accommodating space. A first water inlet and a first water outlet. The filter material or filter material assembly is located in the first accommodating space. After the water enters from the first water inlet, it is filtered by the filter material or filter material assembly, and then from the first water outlet Flow out water containing silicic acid and hydrogen.

The water filter device of the present invention may further include a bacteriostatic filter material assembly located in the first accommodating space of the first carrier. The bacteriostatic filter material assembly includes a plurality of bacteriostatic carriers and a bearing or adsorbed on the bacteriostatic carriers The antibacterial ingredients on the above, the antibacterial carrier is selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fibers, soluble glass, And a combination of the foregoing. The aforementioned antibacterial component can be a plurality of silver nano particles or a plurality of zinc nano particles.

The water filter device of the present invention may further include a hollow fiber membrane (or hollow fiber membrane) filter element, which is located in the first accommodating space of the first carrier, and is used to filter the water generated by the filter material or the filter material assembly. After the flow is filtered through the hollow fiber membrane filter element, it can ensure that the bacteria are further screened out.

The water filter device of the present invention further includes an elastic body with a plurality of pores, located in the first accommodating space and based on the water flow direction, the elastic body is arranged at an upstream position of the filter assembly, wherein the size of each pore Between 5μm~40μm.

The water filter device of the present invention further includes a partition for dividing the first accommodating space into a first sub-accommodating space and a second sub-accommodating space, wherein the filter material assembly is located in the first sub-accommodating space And the first sub-accommodating space is connected to the water inlet; and a hollow fiber membrane filter element is located in the second sub-accommodating space and the second sub-accommodating space is connected to the water outlet; wherein, the partition has a An opening to allow the biological water component to enter the second sub-accommodating space from the first sub-accommodating space.

The third object of the present invention is to provide a water purification system using the filter material or filter material assembly described in the aforementioned first object and the water filter device described in the aforementioned second object.

Therefore, the water purification system of the present invention includes at least one first water filter device using the aforementioned water filter device and a pipeline unit, and the pipeline unit includes a pipeline connecting the first water inlet and the first water outlet.

The water purification system of the present invention may further include a second water filter device and a hollow fiber membrane filter element. The second water filter device is arranged at a downstream position of the first water filter device, and the second water filter device includes a second carrier defining a second accommodating space and a first accommodating space communicating with the second accommodating space. Two water inlets and a second water outlet. The hollow fiber membrane filter element is located in the second accommodating space, and is used to allow the water generated after filtering by the filter material or the filter material assembly to pass through the hollow fiber membrane filter element to further screen out bacteria. The pipeline unit has at least one first delivery pipeline connecting the first water outlet and the second water inlet. The water purification system may further include a bacteriostatic filter material assembly located in the second accommodating space of the second carrier, and based on the water flow direction, at an upstream position of the hollow fiber membrane filter element.

The water purification system of the present invention may further include a third water filter device disposed on one side of the first water filter device, and the third water filter device includes a third carrier that defines a third accommodating space, and A third water inlet and a third water outlet communicating with the three accommodating spaces. In addition, the third accommodating space of the third water filter device contains a bacteriostatic filter material assembly as described above.

The water purification system of the present invention may further include an ultraviolet light sterilization unit, which is arranged at an upstream position of the first water filter device or at a downstream position of the second water filter device. When set at an upstream position of the first water filter device, it can be used to reduce the amount of bacteria entering the first water filter device in advance, which can effectively reduce the rapid growth of bacteria in the first water filter device and avoid causing the second water filter device located downstream. Hollow fiber membrane in the second water filtration device Excessive load on the filter element. When set at a downstream position of the second water filter device, it can be further sterilized to ensure the safety and sanitation of the produced biological water composition.

The water purification system of the present invention may further include a discharge unit, which is arranged on the aforementioned pipeline unit and located downstream of the first water filter device, or located after the second water filter device. The discharge unit communicates with the pipeline unit and is used to discharge liquid, gas, or a combination of liquid and gas. Wherein, the discharge unit may be set to discharge a predetermined amount of the liquid, gas, or a combination of liquid and gas every first predetermined time. For example, the drainage of 2 liters every three hours can be set according to actual needs and is not limited. For example, it can also be exhausted for 1 minute every 2 hours. The drainage process can be discharged (hydrogen) by the way. The advantage is that it can avoid excessive pressure in the delivery pipeline of the aforementioned pipeline unit to burst the pipe, and drain the water that has grown bacteria to maintain the first water filter device or the second water filter device. Second, the water quality in the water filter device is stable.

The fourth object of the present invention is to provide a biological water composition, which is produced by using the filter material or filter material assembly as described in the first object.

Therefore, in the biological water composition of the present invention, the concentration of the soluble silicon content in the biological water composition measured by the colorimetric method is between 8 mg/L to 90 mg/L, preferably 10 mg/L to 50 mg/L In between, the redox potential of the biological water composition is not higher than -100mV, preferably not higher than -300mV, more preferably not higher than -500mV, and not higher than -650mV is ideal.

The fifth object of the present invention is to provide a method for manufacturing a filter material assembly that is used to purify water and produce a biological water composition containing silicic acid and hydrogen. The steps include: (a) providing a plurality of carriers in In a container; and (b) adding a plurality of nanosilica particles to the container to form a filter material assembly containing a plurality of filter materials after being aggregated with the carriers, each filter material containing a carrier and a plurality of nanosilica particles. In the above step (b), for example, a stirrer is used to stir and mix the carriers and the active silicon material in the container, so that the active silicon material and the carriers are assembled to form a plurality of filter materials. In terms of weight percentage, the content of the active silicon material is between 40wt% and 95wt%.

The filter material (or filter material assembly), water filter device, water purification system and biological water composition of the present invention are composed of a highly active active silicon material reacting with biological water to produce a biological water containing silicic acid (soluble silicon) and hydrogen , So that both the amount of dissolved hydrogen and the amount of dissolved silicon in the biological water are increased, and a safe biological water composition is provided.

10: Filter material

102: carrier

104: Surface

106: active silicon material

11: Filter material

112: carrier

114: Surface

116: active silicon material

12: Filter material

121: sub-carrier

122: carrier

123: sub-carrier

124: Surface

125: Surface

126: active silicon material

13: Filter material

131: Child carrier

132: Carrier

133: sub-carrier

134: Surface

500: water treatment system

501: Water Supply System

502: Water Purification System

503: Water temperature control system

60: water filter

601: Carrier

6011: Spacer

6012: opening

602: accommodating space

6021: The first sub-accommodating space

6022: second sub-accommodating space

603: water inlet

604: water outlet

605: filter assembly

606: Hollow fiber membrane filter element

607: Antibacterial filter assembly

62: water filter

621: Carrier

6211: Spacer

6212: opening

135: Surface

136: active silicon material

14: Filter material

142: Silicon particles

144: Surface

146: active silicon material

15: filter material

152: polymer fiber

154: Surface

156: active silicon material

16: filter material

162: Carrier

164: Surface

166: active silicon material

17: Auxiliary filter material

18: Auxiliary filter material

19: Auxiliary filter material

20: The first water filter device

201: First Carrier

202: The first housing space

203: The first water inlet

204: The first outlet

205: Preliminary filter unit

206: filter assembly

622: accommodating space

6221: The first sub-accommodating space

6222: second sub-accommodating space

623: water inlet

624: water outlet

625: filter assembly

626: Hollow fiber membrane filter element

627: Antibacterial filter assembly

64: water filter

641: Carrier

6411: Spacer

6412: opening

642: accommodating space

6421: The first sub-accommodating space

6422: second sub-accommodating space

643: water inlet

644: water outlet

645: filter assembly

646: Hollow fiber membrane filter element

647: Antibacterial filter assembly

66: water filter

661: Carrier

6611: Spacer

6612: opening

207: Water Flow Channel

208: Antibacterial filter assembly

22: The first water filter device

30: The first water filter device

301: First Carrier

302: The first housing space

303: The first water inlet

304: first outlet

305: Preliminary filter unit

306: filter assembly

307: Water Flow Channel

308: Antibacterial filter assembly

309: inner tube wall

32: The first water filter device

40: Water purification system

401: The first water filter device

4011: First Carrier

4012: first housing space

4013: The first water inlet

4014: The first water outlet

4015: filter assembly

402: The second water filter device

4021: Second Carrier

4022: second housing space

662: accommodating space

6621: The first sub-accommodating space

6622: second sub-accommodating space

663: water inlet

664: water outlet

665: filter assembly

666: Hollow fiber membrane filter element

667: Antibacterial filter assembly

68: water filter

681: Carrier

6811: Spacer

6812: opening

682: accommodating space

6821: first sub-accommodating space

6822: second sub-accommodating space

683: water inlet

684: water outlet

685: filter assembly

686: Hollow fiber membrane filter element

687: Antibacterial filter assembly

688: Preliminary filter unit

70: water filter

701: Carrier

7011: Spacer

4023: second water inlet

4024: second outlet

4025: Hollow fiber membrane filter element

403: Piping unit

4031: Conveying pipeline

4032: Conveying pipeline

4033: Conveying pipeline

4034: Conveying pipeline

4035: Conveying pipeline

4036: Conveying pipeline

404: Third Water Filtering Device

4041: Third Carrier

4042: third housing space

4043: third water inlet

4044: third outlet

4045: Antibacterial filter assembly

405: UV sterilization unit

407: Discharge unit

408: Discharge unit

409: Total dissolved solids measurement unit

410: Total dissolved solids measurement unit

7012: opening

7013: Spacer

7014: Inlet runner

702: accommodating space

7021: The first sub-accommodating space

7022: second sub-accommodating space

703: water inlet

704: Outlet

705: filter assembly

706: Hollow fiber membrane filter element

707: Antibacterial filter assembly

72: water filter

721: Carrier

722: accommodating space

723: water inlet

724: water outlet

725: filter assembly

726: Hollow fiber membrane filter element

727: Antibacterial filter assembly

8(8 ' ): bonding material

9: Filter material

F: Water flow direction

Other features and effects of the present invention will be clearly presented in the embodiments with reference to the drawings, in which: FIG. 1A is a schematic diagram of a filter material, illustrating a first embodiment of the filter material of the present invention; FIG. 1B is a schematic diagram of a filter material , Illustrates a second embodiment of the filter material of the present invention; Figure 1C is a schematic diagram of a filter material, illustrating a third embodiment of the filter material of the present invention; Fig. 1D is a schematic diagram of a filter material, illustrating a fourth embodiment of the filter material of the present invention; Fig. 1E is a schematic diagram of a filter material, illustrating a fifth embodiment of the filter material of the present invention; Fig. 1F is a schematic diagram of a filter material, illustrating the filter material of the present invention Figure 1G is a partial magnified photo of a filter material under a scanning electron microscope, illustrating a seventh embodiment of the filter material of the present invention (without bonding material), in which the figure can represent the active silicon material covering 10% to 80% of the surface area of the carrier surface; Figure 1H is a partial enlarged photo of a filter material under a microscope, illustrating the second embodiment of the filter material of the present invention, where the diagram can represent 100% of the surface area of the active silicon material covering the surface of the carrier; Figure 2A is a schematic diagram illustrating that the filter material assembly of the present invention is composed of multiple filter materials of the first embodiment; Figure 2B is a schematic diagram illustrating that the filter material assembly of the present invention is composed of multiple filter materials of the second embodiment; Figure 2C It is a schematic diagram illustrating that the filter material assembly of the present invention is composed of a plurality of filter materials of the first embodiment and a plurality of filter materials of the second embodiment; FIG. 2D is a schematic diagram illustrating that the filter material assembly of the present invention is composed of a filter material of the second embodiment. , The filter material of the third embodiment and the filter material of the fourth embodiment are composed of three filter materials; Figure 2E is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the filter material of the second embodiment, the filter material of the third embodiment and the filter material of the fifth embodiment. Figure 2F is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the second embodiment The filter material and the filter material of the eighth embodiment are composed of two filter materials; Figure 2G is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the filter material of the second embodiment, the filter material of the third embodiment and the auxiliary filter material; Figure 2H is a Schematic diagram illustrating that the filter material assembly of the present invention is composed of four filter materials including the filter material of the second embodiment, the filter material of the third embodiment, the filter material of the fourth embodiment and the filter material of the fifth embodiment; Fig. 2I is a schematic diagram illustrating the filter material of the present invention The assembly is composed of two filter materials including the filter material of the first embodiment and the auxiliary filter material; Figure 2J is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the filter material of the second embodiment and the surface of which is attached with nanosilver or nanometer. The zinc auxiliary filter material is composed of two filter materials; Figure 2K is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the filter material of the first embodiment, the filter material of the second embodiment, the auxiliary filter material and a surface with nanosilver or nano The auxiliary filter material of rice zinc is composed of four kinds of filter materials; Figure 2L is a schematic diagram illustrating that the filter material assembly of the present invention is composed of the filter material of the second embodiment, the filter material of the fifth embodiment, the auxiliary filter material and the surface of which is attached with nano silver or nano The auxiliary filter material of Mizium is composed of four filter materials; Figure 2M is a schematic diagram illustrating that the filter material assembly of the present invention is composed of three filter materials including the filter material of the second embodiment, the filter material of the third embodiment, and the auxiliary filter material; Figure 2N is A schematic diagram illustrating that the filter material assembly of the present invention is composed of the sixth embodiment Figure 2O is a schematic diagram of a container, showing a stirrer mixing and stirring slurry to form the filter material assembly of the present invention; Figure 3 is a schematic diagram illustrating that the filter material assembly of the present invention is composed of a plurality of seventh embodiment of the filter material, the third The filter material of the embodiment, the filter material of the fifth embodiment, the auxiliary filter material and the binding material are composed; Fig. 4A is a schematic diagram of a water filter device, illustrating a first embodiment of the water filter device (first water filter device) of the present invention; Fig. 4B is A schematic diagram of a water filter device, illustrating a second embodiment of the water filter device (first water filter device) of the present invention; FIG. 4C is a diagram showing the performance of a filter material, illustrating the water output and the water output of the first embodiment of the water filter device of the present invention. The experimental values of soluble silicon content and oxidation-reduction potential; Figure 4D is a schematic diagram of a water filter device, illustrating a third embodiment of the water filter device (first water filter device) of the present invention; Figure 4E is a filter material in the scanning electronic The photo under the microscope shows the size and appearance of a single filter material of the present invention; Figure 4F is an enlarged photo of a partial area of Figure 4E, showing that the surface of the filter material has a large number of nanosilica particles aggregated; Figure 4G is a representation of the filter material, illustrating the use of The experimental values of the water output, the soluble silicon content and the oxidation-reduction potential of the third embodiment of the water filter device of the present invention; Figure 5A is a schematic diagram of the water filter device, illustrating the water filter device of the present invention (the first water filter Fig. 5B is a schematic diagram of a filter material, illustrating an embodiment in which the filter material of the present invention is shaped as a block; Fig. 6A is a schematic diagram of a water filter device, illustrating the water filter device of the present invention (the first water filter Fig. 6B is a schematic diagram of a filter material, illustrating another embodiment in which the filter material of the present invention is shaped as a block and contains a bacteriostatic filter material; Fig. 7 is a schematic diagram of a water purification system, illustrating the water purification of the present invention A first embodiment of the system; Figure 8 is a schematic diagram of a water purification system, illustrating a second embodiment of the water purification system of the present invention; Figure 9 is a schematic diagram of a water purification system, illustrating a third implementation of the water purification system of the present invention Example; Figure 10 is a schematic diagram of a water treatment system, illustrating an embodiment of the water treatment system of the present invention; Figure 11 is a schematic diagram of a water filter device; illustrates a first embodiment of the integrated water filter device of the present invention; Figure 12 is a Schematic diagram of the water filter device; illustrates a second embodiment of the integrated water filter device of the present invention; FIG. 13 is a schematic diagram of a water filter device; illustrates a second embodiment of the integrated water filter device of the present invention The third embodiment; FIG. 14 is a schematic diagram of a water filter device; illustrates a fourth embodiment of the integrated water filter device of the present invention; FIG. 15 is a schematic diagram of a water filter device; illustrates a fifth embodiment of the integrated water filter device of the present invention Example; Figure 16 is a schematic diagram of a water filter device; illustrates a sixth embodiment of the integrated water filter device of the present invention; and Figure 17 is a schematic diagram of a water filter device; illustrates a seventh embodiment of the integrated water filter device of the present invention example.

Before the present invention is described in detail, it should be noted that in the following description, similar elements are denoted by the same numbers. In addition, the quantity unit of the term filter material covers one or more. For a clearer understanding, in the following, the quantity unit of the filter material/bacteriostatic filter material is one; and the quantity unit of the filter material assembly/bacteriostatic filter material assembly is plural. A collection of filter media.

1A, the filter material 10 of the present invention (the first embodiment) includes a carrier 102, the active silicon material 106 is attached to the surface 104 of the carrier 102, and the active silicon material 106 covers the surface 104 of the carrier 102 by more than 50% of the surface area. Preferably, the active silicon material 106 covers the surface 104 of the carrier 102 by more than 80% of the surface area. Because active silicon material 106 The larger the coverage area of the active silicon material 106 is, the tighter the bonding between the active silicon materials 106 is, and it is less likely to be separated from the carrier 102 due to the washing of water, so the service life of the filter material 10 can be longer. If the active silicon material 106 (for example, containing a plurality of nanometer silicon particles of nanometer grade) is loosely distributed on the surface of the carrier 102, it is easy to be peeled off the carrier 102 due to water flow, which reduces the service life of the filter material 10.

1B, the filter material 11 of the present invention (the second embodiment) includes a carrier 112 (or called the main carrier), the active silicon material 116 is attached to the surface 114 of the carrier 112, and the active silicon material 116 (for example, containing nano-grade The plurality of nano-silicon particles) completely cover the carrier 112, that is, 100% of the surface area of the surface 114 of the carrier 112 is covered by the active silicon material 116, and the active silicon material 116 forms an active layer.

1C, the carrier 122 of the filter material 12 (third embodiment) of the present invention includes sub-carriers 121 and 123, that is, the carrier can be composed of two or more sub-carriers, and the material of the sub-carriers is the same kind of material , Such as coconut shell activated carbon. An active layer formed by the active silicon material 126 completely covers the surface 124 of the sub-carrier 121 and the surface 125 of the sub-carrier 123. The sub-carriers 121 and 123 are selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, and polymer fibers. Generally speaking, the size of the filter medium 12 (the third embodiment) is larger than the size of the filter medium 11 (the second embodiment). In an embodiment, the sub-carrier may be split from the main carrier during the manufacturing process of the filter material of the present invention. For example, during the process of granulating the filter material, the carrier 112 (main carrier) of the filter material 11 is further split into a ruler. A plurality of sub-carriers 121 and 123 with relatively small dimensions form the filter medium 12. For example, the main carrier is 25μm~2.5mm activated carbon and then split into 2μm~1.4mm activated carbon as sub-carriers. Compared with the filter medium 11 containing only a single carrier (main carrier), the advantage of the filter medium 12 containing multiple sub-carriers is that the multiple sub-carriers have a larger surface area or a larger specific surface area, and can carry or absorb a larger amount of active silicon material (for example, A greater number of nanosilica particles), so it can continue to release hydrogen and silicic acid for a longer time. In addition, a relatively large-sized filter material can be manufactured more easily in the manufacturing process, and the overall stability of the filter material 12 is also improved, so the service life of the filter material 12 is prolonged compared with that of the filter material 11.

1D, the carrier 132 of the filter material 13 of the present invention (the fourth embodiment) includes sub-carriers 131, 133, that is, the carrier may be composed of two or more sub-carriers, and the materials of these sub-carriers include different Type, for example, the sub-carrier 131 is activated carbon and the sub-carrier 133 is ore. An active layer formed by the active silicon material 136 completely covers the surface 134 of the sub-carrier 131 and the surface 135 of the sub-carrier 133.

1E, the filter material 14 of the present invention (the fifth embodiment) includes a silicon particle 142 as a carrier and an active silicon material 146 covering it. Wherein, the active silicon material 146 may be a plurality of nano-silicon particles and completely cover the surface 144 of the silicon particle 142. The silicon particle 142 in this embodiment can be a single particle or a silicon aggregate formed by a large number of nanometer-grade nanosilica particles. The size of the silicon particle 142 can range from 0.2 millimeters (mm) to 2 Millimeters (mm), the size of nano-silicon particles belonging to the nano-level is no more than 800 nanometers. In this embodiment, the silicon content of the filter material 14 can reach 99wt% ~100wt%.

1F, the filter material 15 of the present invention (the sixth embodiment) includes at least one polymer fiber 152 and an active silicon material 156 covering the surface 154. The polymer fiber 152 can be, for example, electrospun or meltblown. The fiber produced by the process has a cross-sectional diameter ranging from 0.5 micrometers (μm) to 100 micrometers (μm).

The active silicon materials 106, 116, 126, 136, 146, and 156 mentioned in the first embodiment to the sixth embodiment may respectively contain a plurality of nano-scale nano-silicon particles with a particle size ranging from 50nm to Between 800 nm, preferably 100 nm to 400 nm, more preferably 150 nm to 350 nm or 200 nm to 300 nm. For example, a laser particle size analyzer (HORIBA LA950V2) can be used to measure the average particle size D50. It should be further explained that the smaller the particle size of the nanosilica particles, the greater the activity, and the faster the reaction rate between the nanosilica particles and the biological water, and the faster the reaction to produce silicic acid and hydrogen. fast. However, too fast reaction speed will cause the nanosilica particles to be quickly consumed. Therefore, the particle size of the nanosilica particles of the present invention should not be too small, and more preferably 50nm or more, preferably 100nm or more to 400nm. With a particle size in this range, the reaction rate of silicic acid and hydrogen is moderate, not too fast or too slow. However, the active silicon material in the foregoing embodiments of the present invention can also be silicon particles with a size of 800nm~1.5μm. Although the particle size is relatively large, the active silicon material reacts with water to produce hydrogen and silicic acid at a slower rate. It is still within the scope of the present invention.

When the active silicon material mentioned in the first embodiment to the sixth embodiment (Nanosilicon particles) 106~156 respectively completely cover the surface of the carrier 102~152 and form an active layer, the average thickness of the active layer is between 200 nanometers (nm) ~ 3 millimeters (mm) , Preferably 500 nanometers (nm) ~ 2.5 millimeters (mm), the content of nanosilica particles contained in such a thickness can make the service life of the filter material reach a predetermined time, such as three months or half a year. When the active layer is thicker, the agglomeration and bonding between the plural silicon nano particles contained in the active silicon material is tighter and the amount increases, so that the service life of the filter material is longer. If the thickness of the active layer is too thin, the ability to generate sufficient hydrogen and silicic acid will soon be lost in a short period of time, and the durability of the filter material will be insufficient. However, the thickness of the active layer should not be too thick, otherwise the surface area of the active silicon material per unit volume becomes smaller, resulting in too low production of hydrogen and silicic acid per unit time. If the content of active silicon material is more than 10wt% based on the weight percentage of the filter material, it is a relatively appropriate design, too little will make the life of the filter material insufficient. Except for the fifth embodiment, preferably, the content of the active silicon material is between 40wt% and 95wt%. The measurement method can be to etch the filter material or filter material assembly with organic solvents (such as TMAH) or lye (such as KOH, NaOH) to etch away the nanosilica particles to separate the carrier and the nanosilica particles, and then filter or dry them for measurement. The weight of the carrier can tell the content of the active silicon material.

The size of the filter material of the first embodiment to the sixth embodiment of the present invention may be in any range of 50 micrometers (μm) to 10 millimeters (mm), 75.5 μm to 8 mm, and 300 μm to 6 mm, preferably 600 μm ~5mm, more preferably 1mm~4mm; among them, the carrier (main carrier) and sub-carriers can be independently selected from the following Composition group: activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fiber, and a combination of the foregoing, and the carrier (main carrier) and sub-carriers The size can be 25μm~2.5mm, preferably 75μm~2mm, more preferably 125μm~1.5mm, most preferably 150μm~1.2mm. When the sub-carrier is split from the main carrier, the size of the sub-carrier may be between 0.2 μm and 2 mm, preferably 2 μm and 2 mm.

For example, the aforementioned carrier 102, 112 of the filter media 10, 11 and the sub-carriers 121, 123, 131 of the filter media 12, 13 may be activated carbon with a plurality of micropores distributed on the surface, such as the grade RWAP 1074 produced by Haycarb. (12×40mesh) activated carbon, most of the activated silicon material attached to the surface of each activated carbon is partially located in the micropores.

The specific manufacturing methods of the filter materials of the first embodiment to the sixth embodiment of the present invention are illustrated by taking activated carbon as the carrier as an example. The steps of making the filter material include: adding a solvent (such as alcohol) into a container with a stirring function. A nano-silicon slurry (slurry) formed with the active silicon material (e.g., nano-silicon particles) described in the foregoing embodiment, and an appropriate amount of activated carbon (e.g. Jacobi 60× 100mesh or Haycarb RWAP 1074 12×40mesh) is uniformly stirred, so that the active silicon materials can penetrate the turbulence caused by the stirring of the nanosilica slurry and be embedded in the micropores of the activated carbon to be adsorbed on the activated carbon. surface. After the activated carbon is uniformly stirred to the nanosilica slurry, it is dried to remove the alcohol, thereby preparing the first to sixth embodiments of the present invention. Example of the filter material.

Refer to Figure 1G, which shows a partial enlarged photo of a filter material under a scanning electron microscope. It is a seventh embodiment of the filter material 10 (without binder material), in which the carrier is a porous granular material of activated carbon, as can be seen from the figure Multiple pores (as indicated by the arrow), and the active silicon material (light-colored part) partially covers the surface of the carrier. This figure can be used to illustrate that the active silicon material covers between 10% and 80% of the surface area of the carrier. Any embodiment. With these micro-holes, the biological water composition with hydrogen dissolved in it has more contact area when flowing in the filter material.

Refer to Figure 1H, which shows a partial enlarged photo of a filter material under a scanning electron microscope. It can be seen from the picture that the active silicon material (many nano-grade nano-silicon particles) is densely covered on the active carbon carrier, so that you can see There are no micro-holes on the activated carbon, and the pattern can be used to represent an example in which the activated silicon material covers 100% of the surface area of the carrier. It can also be seen that when the nano-silicon particles are densely covered on the carrier, the bonding force between the nano-silicon particles will be better than when the nano-silicon particles are loosely covered on the carrier. The surface area of the nanosilica particles can be reduced, so they can be attached to the carrier for a longer time, increasing the life of the filter material.

The filter material assembly of the present invention includes a plurality of filter materials, and any one or more of the aforementioned first to seventh embodiments can be used in any combination, and even one or more auxiliary filter materials can be additionally used for further combination. The first to seventh embodiments and the mixing of auxiliary filter materials in quantity or weight The proportion can be designed according to the needs, not limited to the diagram. The following FIG. 2A to FIG. 2N and FIG. 3 are only examples, and other unlisted embodiments are all covered by the scope of the present invention without departing from the inventive concept of the present invention. Furthermore, if the content of the active silicon material is more than 10wt% based on the weight percentage of the filter material assembly, it is a relatively appropriate design. Preferably, the content of the active silicon material is between 40wt% and 95wt%.

Referring to FIG. 2A, there is shown a filter material assembly composed of a plurality of filter materials 10 of the first embodiment. The filter material 10 is, for example, composed of a plurality of activated carbon as a carrier and a plurality of nano-silicon particles as the active silicon material.

Referring to FIG. 2B, a filter material assembly composed of a plurality of filter materials 11 of the second embodiment is shown. Compared with the filter material assembly of FIG. 2A, the difference is that the plural nanosilicon particles in FIG. 2B completely cover each carrier and form an active layer with a certain thickness. Therefore, the service life of the filter material assembly of FIG. 2B will be more long.

2C, there is shown a filter material assembly composed of a plurality of filter materials of the first embodiment and a plurality of filter materials of the second embodiment. By mixing a plurality of filter materials 10 and a plurality of filter materials 11 with each other, the whole filter material assembly can be used The life span is adjusted. For example, when the active silicon material content of the filter material 10 is low, the filter material 11 can be added to increase the active silicon material content of the overall filter material.

Referring to FIG. 2D, a filter material assembly is shown, which is composed of three filter materials including a filter material 11, a filter material 12, and a filter material 13. In fact, the filter material assembly of the present invention can also be composed of a plurality of filter materials 11, a plurality of filter materials 12, and a plurality of filter materials 13. It can be combined arbitrarily without limitation.

Referring to FIG. 2E, a filter material assembly is shown, which is composed of three filter materials including filter material 11, filter material 12, and filter material 14. The filter material assembly of the present invention may be composed of a plurality of filter materials 11, a plurality of filter materials 12, and a plurality of filter materials 14, and the number and ratio can be combined arbitrarily without limitation. For example, if the filter material 11 is used as the main material, the filter material 14 and the filter material 12 may exist at the same time, or only one of them may be present, or both may not exist, depending on the result of the pelletizing process of the filter material. Another example is that the filter material 12 is the main material. The filter material 14 and the filter material 11 may exist at the same time, or only one of them may appear, or even neither of them may exist.

Referring to FIG. 2F, a filter material assembly is shown, which is composed of a mixture of two filter materials including a filter material 11 and a filter material 16. In the eighth embodiment represented by the filter material 16, the surface 164 of the carrier 162 is partially or completely covered by the active silicon material 166, wherein the material type of the carrier 162 is different from the material type of the carrier of the filter material 11. For example, the carrier of the filter material 11 is activated carbon, and the carrier 162 of the filter material 16 is ore. The ore can provide additional functions, such as emitting far-infrared rays. The molecular vibrations cause resonance to cut water molecular clusters and make the water molecular clusters more compact. Small and easy to absorb.

Refer to Figure 2G, which shows a filter material assembly consisting of three filter materials including filter material 11, filter material 12 and auxiliary filter material 17. The auxiliary filter material 17 can be selected from activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, and silicon. Algae earth, ore, zeolite, silica particles, polymer fibers. In fact, the filter material of the present invention can also be composed of multiple filter materials 11, A plurality of filter materials 12 and a plurality of auxiliary filter materials 17 are composed, and the number and ratio can be combined arbitrarily, and are not limited. The purpose of adding the auxiliary filter material 17 is to adjust the ratio of the filter material or to provide additional functions. For example, medical stone has strong ion exchange capacity and is rich in minerals such as iron, calcium, zinc, potassium, silicon, and aluminum. Therefore, in addition to adsorbing harmful substances in water, medical stone can also adjust the pH of the water, increase the oxygen content in the water, and dissolve appropriate minerals. Other above-mentioned materials capable of releasing trace elements (such as iodine and selenium) can also be used as auxiliary filter materials 17.

Referring to FIG. 2H, the difference between the filter material assembly of this embodiment and the embodiment disclosed in FIG. 2E is only that the filter material 13 is added, and other similarities will not be repeated.

Referring to FIG. 2I, the difference between the filter material assembly of this embodiment and the embodiment disclosed in FIG. 2A is only the additional auxiliary filter material 18, and the selection of the auxiliary filter material 17 is similar to the aforementioned auxiliary filter material 17, and other similarities will not be repeated. In addition, the auxiliary filter material 18 may be activated carbon, for example, as a way to adjust the content of the active silicon material in the filter material assembly. Furthermore, the average size of the auxiliary filter material 18 may be different from the average size of the carrier of the filter material 10.

Referring to Fig. 2J, a filter material assembly is shown, which is composed of a mixture of filter material 11 and auxiliary filter material 19 with a plurality of silver nano particles or zinc nano particles attached to the surface. The auxiliary filter material 19 is used as a bacteriostatic filter material, which can effectively prevent a large number of bacteria from growing in the filter material 11 or the biological water composition produced by it. The carrier for attaching the silver nano particles or zinc nano particles in the auxiliary filter material 19 (also referred to as a bacteriostatic carrier) can use the above auxiliary filter material 18 as the carrier.

Referring to FIGS. 2K to 2M, several other possible aspects of the filter material assembly are listed, and the remaining parts that are the same as the foregoing embodiment will not be repeated.

2N, a filter material assembly is shown, which is composed of a filter material 15. The carrier 152 of the filter material 15 is a polymer fiber produced by an electrospinning process. The active silicon material (for example, plural nano-silica particles) 156 is attached to the surface 154 of each polymer fiber. The preparation method is to mix the active silicon material 156 in the spinning solution (for example, N,N-dimethylformamide solvent containing polymer but not limited to polyacrylonitrile), and stir and disperse to obtain a plurality of nanometers. The electrospinning solution of silicon particles, followed by an electrospinning process, can produce polymer fibers with multiple nano-silicon particles attached. Furthermore, the polymer fiber with attached nanosilica particles can be pre-oxidized and then carbonized to obtain carbon fiber attached with nanosilica particles. Another point is that the size of the above-mentioned polymer fibers is not limited to the nanometer level. In other embodiments, it may also be micrometer level fibers.

Also referring to FIG. 2N, another embodiment of the filter material of the present invention is substantially the same as the foregoing embodiment, except that the carrier 152 is a fiber made by a melt-blown process. The preparation method is to mix the active silicon material 156 with resin (for example, including but not limited to PP, PET, PBT and PLA), then put it into the screw extruder, then pass through the melt filter, metering pump, etc., and then use the melt blow nozzle By spraying, a polymer fiber with a plurality of nanosilica particles attached can be obtained.

Refer to FIG. 20, which is a schematic diagram of a container of the present invention, showing a blender that mixes and agitates the slurry to form the filter material assembly of the present invention. Its manufacturing steps include: first provide A plurality of carriers are in a container 1. The carriers can be selected from any of the aforementioned embodiments. In this embodiment, activated carbon (for example, Jacobi 60×100 mesh or Haycarb RWAP 1074 12×40 mesh) is used. Next, an active silicon material is provided to mix with the carriers. A nanosilica slurry 2 formed from a solvent (for example, alcohol) and active silicon material (for example, a plurality of nanometer silicon particles) can be used as the source of the active silicon material. , And then a stirrer 3 is used to stir and mix the activated carbon in the container 1 and the nanosilica slurry 2 so that the nanosilica particles are attached to a surface of each activated carbon to form a plurality of filter materials (that is, the filter material assembly). 4) After the activated carbon and the nanosilica slurry are uniformly stirred, they are dried to facilitate the rapid removal of the solvent. During the drying, the temperature in the container 1 rises to between 50 and 300 degrees Celsius. The appropriate content of the active silicon material is based on the weight percentage of the filter material assembly 4 or a single filter material. The content of the active silicon material is between 40wt% and 95wt%. Based on the weight percentage of the nanosilica paste 2, the content of the active silicon material is between 10wt% and 40wt%. The agitator 3 may include a mixing blade (Impeller), whose main function is to provide appropriate shearing force between the activated silicon material and the activated carbon so as to facilitate their collision and agglomeration to form secondary particles. The rotation speed of the stirring blade can be adjusted, and can be selectively stirred continuously or discontinuously.

Referring to Fig. 3, the filter material assembly of the present invention is composed of a plurality of filter materials 9, filter materials 12, filter materials 14, auxiliary filter materials 18 and a bonding material 8 (8 ' ), wherein the bonding material 8 shows the shape after high temperature melting, The bonding material (8 ' ) is a shape that indicates that it has not melted or is incompletely melted. Figure 3 is only an example. In practice, the bonding material 8 (8 ' ) can be combined with the aforementioned first embodiment to the seventh embodiment arbitrarily, and even one or more auxiliary filter materials can be added for further combination, such as The filter material assembly of Fig. 2A to Fig. 2M is joined with a binding material 8 (8 ' ). The bonding material 8 (8 ' ) can be selected from the group consisting of polyether, acrylic resin, styrene, polyamide, polyester , Polyolefin, cellulose, polyethylene, Glycerol, polyethylene glycol (PEG), polyvinyl alcohol, and a combination of the foregoing.

In one embodiment, a plurality of nanosilica particles are used as the active silicon material, and activated carbon is used as the carrier. The bonding material combines a plurality of nanosilica particles and a plurality of activated carbons so that part of the active silicon material is attached to the activated carbon (carrier) to form the filter material 9 or the filter material 12, and the binder material 8 (8 ' ) and the filter materials 9, 12 together form a Sintered activated carbon (sintered activated carbon) or compressed activated carbon (compressed activated carbon), from the appearance point of view, is the so-called molding active carbon (molding active carbon). In other words, a nano-silicon material containing a plurality of nano-silicon particles is attached to the surfaces of the carriers, and the nano-silicon material covers more than 10% of the surface area of the surface of each carrier to form a plurality of filter materials together. Preferably, the nanosilicon material covers more than 40% of the surface area of the surface of each carrier. In detail, the filter material assembly of this embodiment is a mixture of activated carbon, nanosilica particles and bonding material 8 (8' ), and then hot press through a mold to form a green body. The green embryo is treated with a predetermined temperature to form the filter material. In other embodiments, the filter material or filter material assembly of the previous embodiments (as shown in FIG. 1A to FIG. 3) can also be mixed with the binding material and then pressed and sintered. In another derivative embodiment, the aforementioned filter material 9, activated carbon and binding material can also be mixed and then formed by hot pressing. It is worth mentioning that the hot-pressed bonding material will form multiple pores for biological water to flow through. In other words, using activated carbon with attached nanosilica particles as the filter medium 9 and using this as the main material, the filter medium 12 with multiple sub-carriers and the filter medium 14 with silicon particles may or may not exist, and the active Carbon as an auxiliary filter material 18 can be selectively added to the filter material 11 to enhance the strength of the overall filter material.

Refer to FIG. 4A, which is a schematic diagram of a first embodiment of a first water filter device 20 of the present invention, which is used to purify water and produce a biological water composition containing silicic acid and hydrogen. The first water filter device 20 has a first carrier 201, defines a first accommodating space 202 therein, and has a first water inlet 203 and a first water outlet communicating with the first accommodating space 202 204. The first water inlet 203 and the first water outlet 204 of this embodiment are located on the same side (top side) of the first carrier 201, and a first container is formed between the first water inlet 203 and the first water outlet 204 Set the water flow channel 207 in the space 202. One or more preliminary filtration units 205, such as non-woven fabrics or fiber filter screens, are also provided in the water flow channel 207 to initially filter out impurities in the water with larger particle diameters. A filter material assembly 206 is filled in the first accommodating space 202 and is located between the upper and lower preliminary filter units 205. This embodiment can use the filter material illustrated in FIGS. 1A to 1H, the filter material assembly illustrated in FIGS. 2A to 2N, or any combination of the foregoing, wherein the filter materials and auxiliary filter materials of the first to seventh embodiments are in number The mixing ratio of the upper or the weight can be changed according to the needs The design is not limited to the drawings of the present invention. Biological water flows into a predetermined amount of biological water from the first water inlet 203 along a water flow direction F. The predetermined amount of biological water flows through the preliminary filtration unit 205, the filter assembly 206, and then flows out from the first water outlet 204. The required amount of biological water containing silicic acid (dissolved silicon) and hydrogen. Another point is that although the filter material assembly 206 shown in FIG. 4A is filled between the upper and lower prefilter units 205, this is not necessarily the case; specifically, in a derivative embodiment, The filter material assembly 206 described in the first embodiment is only partially filled in the first accommodating space 202 of the first carrier 201. For example, the space between the upper and lower preliminary filter units 205 in FIG. 4A is only partially filled 40%~70% of the space is filled with the filter material assembly 206, so that when the biological water flow enters the first accommodating space 202, the filter material assembly 206 can be disturbed. In other words, the first accommodating space 202 can have extra space The filter material assembly 206 is flipped in it with the flow of water, thereby increasing the contact area between the biological water and the filter material assembly 206. As a result, more silicic acid and hydrogen can be produced in a shorter time. Further, in another derivative embodiment, a hollow fiber membrane filter element (not shown) can also be arranged in the first accommodating space 202 of the first carrier 201, for example, in the water flow channel 207 near the water outlet 204 .

Refer to FIG. 4B, which is a schematic diagram of a second embodiment of the first water filter device 22 of the present invention. The second embodiment is substantially the same as the first embodiment, and the difference is that a bacteriostatic filter assembly 208 is added in the first accommodating space 202. The antibacterial filter material assembly 208 includes a plurality of antibacterial carriers for carrying or adsorbing antibacterial components such as a plurality of silver nanoparticles or zinc nanoparticles, and the antibacterial carriers are selected from the group consisting of the following Group: activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fiber, soluble glass (such as sodium silicate Na ₂ SiO ₃ ), and a combination of the foregoing. The antibacterial filter assembly 208 is, for example, activated carbon with zinc nanoparticles adsorbed, or a mixture of soluble glass and activated carbon carrying zinc nanoparticles. After the antibacterial filter assembly 208 reacts with water, it can release silver ions or zinc ions to inhibit the growth of bacteria in the filter assembly 206 and the biological water composition in the first carrier 201. The antibacterial filter material assembly 208 shown in FIG. 4B is sandwiched between the two layers of filter material assembly 206, but the present invention is not limited to this. In another derivative embodiment, the antibacterial filter material assembly 208 may also be connected to the filter material assembly 206. The assembly 206 is fully mixed and evenly distributed in the filter assembly 206.

Referring to FIG. 4C, this filter material performance diagram illustrates the experimental data of the water output, the soluble silicon content, and the oxidation-reduction potential of the first embodiment of the first water filter device of the present invention. In the first embodiment with Figure 4C, the filter material assembly uses Haycarb's model RWAP 1074 12×40 mesh (1.7mm~0.425mm) activated carbon as the carrier, with a total weight of 4,587.5 grams, calculated as the weight percentage of the filter material assembly , The silicon content is 78.2wt%. It can be seen from Figure 4C that the initial soluble silicon content and oxidation-reduction potential were 30mg/L and -677mV, respectively. As the effluent volume of biological water increases to 477 liters, the soluble silicon content drops to approximately 12mg/L. The oxidation-reduction potential only rises slightly to -574mV.

Refer to FIG. 4D, which is a schematic diagram of a third embodiment of the first water filter device 24 of the present invention. The design spirit of the third embodiment is substantially the same as the previous embodiment, with the difference The placement position of the filter material assembly 206 is changed, so that the biological water has to travel a longer water flow channel 207 before it touches the filter material assembly 206, and the water flow has to go through a 180-degree turn and pass through the 2-layer preliminary filter unit 205' (For example, foam with a pore size of 10~20μm) will enter the filter assembly 206. This design can effectively buffer the water flow and directly wash the filter assembly 206, avoiding a large amount of active silicon material in the filter assembly 206 from falling off and making the output The biological water composition is obviously turbid, and even blocks the preliminary filter unit 205' (for example, a non-woven fabric with a pore size of 5 μm) near the water outlet 204, and the service life of the filter material assembly 206 is prolonged. In addition, as shown in the figure, an additional elastic element 209 (such as a spring) can be additionally provided to force the preliminary filter unit 205' to compress the filter material assembly 206.

Refer to Figure 4E. This is a photo of the size and appearance of a filter material under a scanning electron microscope (such as Hitachi S-400 SEM). In the photo, only the size of the filter material is about 1mm * 1.3mm, and the surface is made of active silicon material ( Nano-silicon particles), that is, the carrier or most of the sub-carriers should be covered by the active silicon material. Refer also to Fig. 4F, which is an enlarged photo of a partial area of Fig. 4E, which shows more clearly that there are many nano-silicon particles aggregated on the surface of the filter material, the size of which is approximately between 75 nm and 450 nm. The aforementioned filter material or nano-silicon particle size measurement can also use laser particle size analysis such as HORIBA LA-950 V2, which can measure the size of 10nm~3mm. For micron or millimeter-level sizes, common mesh screens can also be used to determine the size and filter out the desired filter material size.

Referring to Figure 4G, this filter material performance diagram illustrates the output of the third embodiment described above. Experimental data on water volume, soluble silicon content and oxidation-reduction potential. In the first embodiment with Figure 4E, the filter material assembly uses Haycarb's model RWAP 1074 12×40 mesh (1.7mm~0.425mm) activated carbon as the carrier, and the equipment shown in Figure 2O is used to make the filter material assembly. to make. Then use the screen to divide the finished filter material into three groups, namely the first group with the particle size of the filter material less than 30mesh (<0.55mm), the second group with 8~30mesh (0.55~2mm), and the 5~8mesh(2 ~4mm) the third group. Experiments have confirmed that the performance of the mixed filter material formed by mixing the above-mentioned three groups of filter material assemblies in a predetermined ratio will be better than the performance of the individual groups. For example, in terms of weight percentage, a mixed filter material assembly contains 14.3wt% of the first group, 47.6wt% of the second group, and 38.1wt% of the third group, and its performance is shown in FIG. 4G. From Figure 4G, it can be seen that the highest soluble silicon content is 90mg/L and the lowest oxidation-reduction potential is about -715mV. As the effluent volume of biological water increases to 3212 liters, the soluble silicon content remains at 38mg/L, and The oxidation-reduction potential is still -587mV, and the sampling method is to take water for 3 minutes per hour and take 90 liters of water per day. This is because adjusting the specific gravity of the filter media of different particle sizes can optimize the contact area of the filter media assembly with biological water, and it will perform better than the filter media assembly with only small, large, or random particle sizes. . In other words, as long as the following conditions are met: the composition of the filter material assembly is at least two groups of mixtures containing a plurality of first filter materials and a plurality of second filter materials, and the average size of the first filter materials is greater than the average size of the second filter materials , Based on the weight percentage of the filter material assembly, the preset content of the first filter media is different from the preset content of the second The composition of materials and water should be significantly improved.

Referring to FIGS. 5A and 5B, this is a schematic diagram of a fourth embodiment of the first water filter device 30 of the present invention. This embodiment has a first carrier 301, the first carrier 301 defines a first accommodating space 302, and has a first water inlet 303 and a first water outlet 304 communicating with the first accommodating space 302 . The first water inlet 303 and the first water outlet 304 of this embodiment are located on the same side (top side) of the first carrier 301, and a first container is formed between the first water inlet 303 and the first water outlet 304 Set the water flow channel 307 in the space 302. A preliminary filter unit 305 is also provided in the water flow channel 307, such as a non-woven fabric or a fiber filter screen. A filter assembly 306 is located in the first accommodating space 302 and is located behind the preliminary filter unit 305 along a water flow direction F. With reference to Figure 3 and its description, the filter material assembly 306 can be a block-shaped filter material assembly made of all types of filter materials mentioned in the previous embodiment, such as sintered activated carbon or compressed activated carbon as the filter material, and the binding material can be Optional or not to join. The filter material assembly 306 as shown in FIG. 5B uses two hollow cylindrical sintered activated carbon blocks, but it is also possible to use only one long-length hollow cylindrical sintered activated carbon block. Biological water flows into a predetermined amount of biological water from the first water inlet 303 along a water flow direction F. The predetermined amount of biological water flows through the preliminary filter unit 305, the filter assembly 306, and then flows out from the first water outlet 304. A required amount of biological water composition. The water flow direction of the biological water is from the outside of the sintered activated carbon block through the filter assembly 306 to produce a biological water composition containing silicic acid (soluble silicon) and hydrogen, and flow to the center of the first carrier 301. The biological water composition passes through the first carrier 301 After a plurality of holes (not shown in the figure) on an inner tube wall 309, it flows out to the first water outlet 304 through the water flow channel 307 at the center. Further, in another derivative embodiment, a hollow fiber membrane filter element (not shown) can also be arranged in the first accommodating space 302 of the first carrier 301, for example, in the water flow channel 307 near the water outlet 304 .

6A and 6B, this is a schematic diagram of a fifth embodiment of the first water filter device 32 of the present invention. This embodiment is basically the same as the third embodiment, except that the filter material (hollow cylindrical sintered activated carbon block) assembly 306 also includes a bacteriostatic filter material assembly 308, of which the bacteriostatic filter material assembly 308 uses The auxiliary filter material can refer to the auxiliary filter material described in the second embodiment above. The antibacterial filter material assembly 308 shown in FIG. 6B is an independent layer of filter material located inside the filter material assembly 306, but the present invention is not limited to this. In another derivative embodiment, the antibacterial filter material assembly 308 may also It is thoroughly mixed with the filter material assembly 306, and is evenly distributed in the filter material assembly 306.

Refer to FIG. 7, which is a schematic diagram of a first embodiment of the water purification system of the present invention. The water purification system 40 includes a first water filtering device 401, a second water filtering device 402 and a pipeline unit 403. The first water filtering device 401 may be the first water filtering device mentioned in any of the foregoing embodiments. The first water filter device 401 of this embodiment has a first carrier 4011, the first carrier 4011 defines a first accommodating space 4012, and has a first water inlet communicating with the first accommodating space 4012 4013 and a first outlet 4014. The first water inlet 4013 and the first water outlet 4014 are located on the same side (top side) of the first carrier 201, but the present invention is not limited to this. In other embodiments, the first inlet The water inlet 4013 and the first water outlet 4014 can also be located on the bottom side of the first carrier 4011, or the first water inlet 4013 and the first water outlet 4014 are respectively located on the opposite side, that is, on the top of the first carrier 4011. The side and bottom side, or are located on the bottom side and top side of the first carrier 4011, respectively. A filter material assembly 4015 is accommodated in the first accommodating space 4012, and this filter material assembly 4015 can use various filter material assemblies mentioned in the foregoing embodiments.

Along a water flow direction F (as shown by the arrow), the second water filter device 402 is arranged at a downstream position of the first water filter device 401. The second water filter device 402 includes a second carrier 4021 and defines a second Housing space 4022. The second carrier 4021 has a second water inlet 4023 and a second water outlet 4024 communicating with the second accommodating space 4022. A hollow fiber membrane filter element 4025 is located in the second accommodating space 4022, and a pipeline unit 403 includes a first water outlet 4014 of the first water filter device 401 and a second water filter device 402 in sequence along the water flow direction F. The first delivery pipe 4031 of the second water inlet 4023. The second water inlet 4023 and the second water outlet 4024 shown in FIG. 7 are located on the same side (top side) of the second carrier 4021, but the present invention is not limited to this. In other embodiments, the second water inlet 4023 The second water outlet 4024 and the second water outlet 4024 can also be located on the bottom side of the second carrier 4021, or the second water inlet 4023 and the second water outlet 4024 are respectively located on opposite sides, that is, on the top side and the second water outlet 4021 of the second carrier 4021, respectively. The bottom side or the bottom side and the top side of the second carrier 4021 are respectively located. In another embodiment, a bacteriostatic filter assembly (not shown) can be added to the second accommodating space 4022, and The water flow direction is the reference, and the antibacterial filter material assembly is located at the upstream position of the hollow fiber membrane filter element 4025. The advantage is that the biological water composition can be sterilized by the antibacterial filter assembly first, and then the hollow fiber membrane filter element can intercept some of the antibacterial ingredients (such as silver or zinc nanoparticles) contained in the antibacterial filter.

The biological water delivered by the pipeline unit 403 is first introduced into the first water filter device 401 from the first water inlet 4013, and flows through the filter assembly 4015 along the flow direction F of the biological water, and reacts with the active silicon material to generate silicic acid and Hydrogen, after forming a biological water composition with silicic acid and hydrogen dissolved in it, flows along the flow direction of the biological water composition from the first water outlet 4014 into the conveying pipe 4031, and then is introduced into the second water filter device from the second water inlet 4023 402 in. After being filtered through the micropores of the hollow fiber membrane 4025, it flows out from the second water outlet 4024. The hollow fiber membrane 4025 filter element is composed of many tubular structures and has micro-holes penetrating the tubular structure, and the size of the micro-holes is between 10 nm and 200 nm. Bacteria, active silicon materials (such as plural nano-silica particles), and silver/zinc nano-particles larger than this size range will be adsorbed and blocked on the surface of the tubular structure, avoiding the biological water composition from the second water outlet 4024 flows out.

The water purifier 40 of the first embodiment can optionally include at least one ultraviolet light sterilization unit 405. Preferably, a sterilization unit 405 is provided at an upstream position of the first water filter device 401 along the water flow direction F, but a sterilization unit 405 can also be added to the conveying pipe 4033 at a downstream position of the second water filter device 402. Unit 405, the first delivery pipe 4031 between the first water filter device 401 and the second water filter device 402 may also be provided with a A sterilization unit 405 (not shown); as shown in FIG. 7, it is on the conveying pipe 4032 at the upstream position of the first water filter device 401 and on the conveying pipe 4033 at a downstream position of the second water filter device 402 Each sterilization unit 405 is provided. The ultraviolet light sterilization unit 405 is used to sterilize the biological water or the composition of the biological water. The ultraviolet light sterilization unit 405 is preferably arranged at the upstream position of the first water filter device 401. The advantage is that the bacteria entering the first water filter device 401 has been greatly reduced, which can effectively avoid the use of active silicon in the first water filter device 401. The existence of materials can breed bacteria, and in addition, it can prevent the polymerization of silicic acid in the composition of biological water.

The water purifier 40 of the first embodiment can optionally include at least one discharge unit. In this embodiment, two discharge units 407 and 408 are provided on the pipeline unit 403, and more precisely, they are respectively provided in the conveying pipe. Road 4031 and the transportation pipeline 4033. Specifically, the discharge unit is a pressure relief valve (valve), which is used to communicate with the delivery pipeline of the pipeline unit 403 and to discharge liquid, gas, or a combination of liquid and gas. For example, the discharge unit 407 is used for exhaust, and the exhaust unit 408 is used for both drainage and exhaust. It should be supplemented that because the first water filter device 401 will continuously generate hydrogen gas, the conveying pipe 4031 continues to accumulate gas, which makes the pressure in the conveying pipe 4031 too high, which affects the liquid flow and even causes the conveying pipe 4031 to burst. . Therefore, the discharge unit (that is, the pressure relief valve) 407 in the water purification system 40 of the first embodiment is mainly used to eliminate the pressure value increased by the excessive accumulation of gas in the conveying pipe 4031, so as to increase the liquid The flow rate and avoid pipeline burst. The discharge unit 408 is mainly It is used to eliminate the biological water composition and hydrogen accumulated in the second water filter device 402, so as to avoid the continuous breeding of bacteria in the second water filter device and prevent the pipeline from bursting.

The water purification system 40 of the first embodiment may also include two total dissolved solids (TDS) measuring units 410 and 409, which are respectively arranged on the first water filter device 401 along the water flow direction F The upstream position and the downstream position, more specifically, the total dissolved solids measurement unit 409 is arranged at a downstream position of the second water filter device 402. In other embodiments, the total dissolved solids measurement unit 410 may be selectively provided only at an upstream position of the first water filter device 401, or the total dissolved solids measurement unit 410 may be selectively provided only at a downstream position of the second water filter device 402. Dissolved solids measurement unit 409. Specifically, the total dissolved solids measuring unit 410 located at the upstream position is set on the delivery pipe 4032 connecting a water supply system 501 (refer to FIG. 10) and the first water filter device 401 of the present invention. And the total dissolved solids measuring unit 409 located at the downstream position is arranged on the conveying pipe 4033 connecting the second water filter device 402 and the ultraviolet light sterilization unit 405. _{It should be noted that the total dissolved solids (V t} ) measured by the total dissolved solids measurement unit 409 located at the downstream position is greater than the total dissolved solids measurement unit 410 located at the upstream position. The measured total dissolved solids (V ₀ ) has a total dissolved solids difference (ΔV) between the two. Therefore, the purpose of adding the total dissolved solids measuring units 409, 410 to the water purification system 40 of the first embodiment of the present invention is to use the total dissolved solids measuring units 409, 410 to obtain the total dissolved solids. The difference (△V), once the total dissolved solids difference (△V) is less than the predetermined value set by the user, it means that the amount of silicic acid and hydrogen bubbles that can be dissolved in the biological water composition has been significantly reduced. Replace the The requirements of the filter material assembly 4015 of the first water filter device 401. The total dissolved solids measurement unit 409, 410 measured the conductivity value difference (total dissolved solids difference) controlled between 10~150μS/cm for normal operation, preferably controlled at 20~120μS/cm It is better to control between 30~90μS/cm. Usually 1ppm(TDS)=1mg/L=2μS/cm, but this linear relationship will vary slightly depending on the actual dissolved substances, that is to say, the long-term average value, the content of soluble silicon (silicic acid) of the present invention It should be controlled at 8~90mg/L as a normal operating state, preferably between 10mg/L and 50mg/L. The control of the numerical value is related to the size of the filter material of the present invention, the content of the active silicon material, the size of the nanosilica particles, the thickness of the active layer, etc.

Refer to FIG. 8, which is a schematic diagram of a second embodiment of the water purification system of the present invention. The water purification system 42 of the second embodiment is substantially the same as the first embodiment, except that a third water filter device 404 is added, which is located at an upstream position of the first water filter device 401, but the present invention is not limited. In other embodiments, the third water filter device 404 may also be provided at a downstream position of the first water filter device 401 (not shown). The third water filter device 404 of this embodiment has a third carrier 4041. The third carrier 4041 defines a third accommodating space 4042 and has a third inlet communicating with the third accommodating space 4042. Water outlet 4043 and a third water outlet 4044. The third accommodating space 4042 of the third water filter device 404 contains a bacteriostatic filter material assembly 4045, wherein the bacteriostatic filter material The bacteriostatic component of the assembly 4045 may include, for example, a plurality of silver nanoparticles or a plurality of zinc nanoparticles (such as zinc oxide nanoparticles), and the bacteriostatic filter assembly 4045 may adopt all the foregoing embodiments of the present invention. Any kind of antibacterial filter material that has arrived will not be repeated here. The pipeline unit 403 has a delivery pipeline (second delivery pipeline) 4034 that sequentially connects the third water filter device 404 and the first water filter device 401 along the water flow direction F, and connects the first water filter device 401 and A delivery pipeline (first delivery pipeline) 4031 of the second water filter device 402. Biological water enters the third water filter device 404 from the third water inlet 4043 and is filtered by the antibacterial filter assembly 4045, then flows out from the third water outlet 4044 to the conveying pipe 4034, and then enters from the first water inlet 4013 The first water filter device 401 is filtered by the filter material assembly 4015 and converted into a biological water composition, and then flows out from the first water outlet 4014 to the conveying pipeline 4031. The rest are the same as the first embodiment and will not be repeated. The third water inlet 4043 and the third water outlet 4044 shown in FIG. 8 are located on the same side (top side) of the third carrier 4041, but the present invention is not limited to this. In other embodiments, the third water inlet 4043 The third water outlet 4044 and the third water outlet 4044 can also be located on the bottom side of the third carrier 4041, or the third water inlet 4043 and the third water outlet 4044 are respectively located on the opposite side, that is, on the top side and the third carrier 4041 respectively. The bottom side or the bottom side and the top side of the third carrier 4041 are respectively located.

Refer to Figure 9, which is a schematic diagram of a third embodiment of the water purification system of the present invention. The water purification system 44 of the third embodiment is substantially the same as that of the second embodiment, except that the transmission pipelines of some sections of the pipeline unit 403 are designed in parallel. I.e. use two A first water filter device 401 replaces a first water filter device 401 and a third water filter device 403, and a predetermined amount of biological water is transferred from the first water inlet 4013 and the third water inlet through the common conveying pipe 4035 4043 enters the first water filtering devices 401, and then discharges a required amount of biological water from the first water outlet 4014 and the third water outlet 4044, and flows into the common delivery pipeline 4036. The advantage is that two or more first water filter devices 401 are connected in parallel at the same time, which can cope with the demand when the water consumption is large, so that the same amount of biological water can react with more filter materials in the same time and avoid the active silicon of the filter materials. The material is discharged out of the first water filter 401 before it can fully react with the biological water to avoid the low content of silicic acid and hydrogen composed of the biological water produced, and solve the problem that may cause non-compliance with the demand. Furthermore, one or more third water filtering devices (not shown in the figure) can be connected in series at any position of the pipeline unit 403, which is not limited by the present invention.

10, an embodiment of the water treatment system 500 of the present invention includes a water supply system 501, a water purification system 502, and a water temperature control system 503. The water supply system 501 may be a commercially available Nai filtration or reverse osmosis (reverse osmosis; hereinafter referred to as R.O.) water purifier or other water purification equipment. Of course, other unfiltered biological water such as natural water, mineral water, groundwater, etc. can also be used directly. The water purification system 502 can adopt the possible implementation of the water purification system mentioned in the previous embodiment, and the water temperature control system 503 can be optionally installed, so that cold, hot or normal temperature biological water composition (also Called silicohydrogen water). In addition, an additional delivery pipeline can also be provided to bypass the water purification system 502, so that cold and hot biological water can be directly obtained. Specifically, In the water purification system 502 of the present invention, under appropriate conditions (for example, an R.O. water purifier is used as the water supply system 501), only a single first water filter device 401 is required to produce the required biological water composition. Furthermore, an ion exchange resin water filter device or oxides or hydroxides of multivalent cations can also be added to the water purification system 502 to remove/adsorb silicic acid to obtain hydrogen water.

Referring to FIG. 11, this is a schematic diagram illustrating a first embodiment of an integrated water filter device. The water filter device 60 includes a carrier 601 and a water inlet 603 and a water inlet 603 on the bottom and top sides of the carrier 601, respectively.出水口604。 The outlet 604. The carrier 601 defines an accommodating space 602, and the accommodating space 602 is divided into two sub-accommodating spaces, a first sub-accommodating space 6021 and a second sub-accommodating space 6022, respectively. The first sub-accommodating space 6021 is connected to the water inlet 603, and the second sub-accommodating space 6022 is connected to the water outlet 604. A filter material assembly 605 is filled to be located in the first sub-accommodating space 6021, and a hollow fiber membrane filter element 606 is set to be located in the second sub-accommodating space 6022. The first sub-accommodating space 6021 also contains a bacteriostatic filter material assembly 607. As shown in FIG. 11, the bacteriostatic filter material assembly 607 is sandwiched by the filter material assembly 605. A spacer 6011 is provided between the first sub-accommodating space 6021 and the second sub-accommodating space 6022. The spacer 6011 has at least one opening 6012 for communicating the first sub-accommodating space 6021 and the second sub-accommodating space 6022 is used to allow the biological water composition to pass through, and the size of the opening 6012 is not limited. A predetermined amount of biological water enters the first accommodating space 6021 from the water inlet 603 along a water flow direction F (shown by the arrow), and produces silicic acid and hydrogen gas through the filter assembly 605 Then the biological water composition enters the second sub-accommodating space 6022, passes through the sieve of the hollow fiber membrane filter element 606, and finally flows out from the water outlet 604.

It is worth mentioning that, in a derivative embodiment, the antibacterial filter assembly 607 may be an optional option, that is, the water filter device 60 does not need to have the antibacterial filter assembly 607. Or, in another derivative embodiment, the antibacterial filter material assembly 607 is fully mixed with the filter material assembly 605 and dispersed in the first sub-accommodating space 6021 (not shown), and it does not need to be as shown in FIG. 11 It shows that the antibacterial filter material assembly 607 is sandwiched between the filter material assembly 605.

Refer to FIG. 12, which is a schematic diagram illustrating a second embodiment of an integrated water filter device. The water filter device 62 includes a carrier 621 and a water inlet 623 and a water outlet 624 located on the bottom side of the carrier 621. The carrier 621 defines an accommodating space 622, and the accommodating space 622 is divided into two sub-accommodating spaces, a first sub-accommodating space 6221 and a second sub-accommodating space 6222, respectively. The first sub-accommodating space 6221 is connected to the water inlet 623, and the second sub-accommodating space 6222 is connected to the water outlet 624. A filter material assembly 625 is filled to be located in the first sub-accommodating space 6221, and a hollow fiber membrane filter element 626 is set to be located in the second sub-accommodating space 6222. The first sub-accommodating space 6221 also contains a bacteriostatic filter material assembly 627. As shown in FIG. 12, the bacteriostatic filter material assembly 627 is sandwiched by the filter material assembly 625. A spacer 6211 is provided between the first sub-accommodating space 6221 and the second sub-accommodating space 6222, and the second sub-accommodating space 6222 is defined by the spacer 6211, leaving only the space close to the top side of the carrier 621 At least one opening 6212 serves as a channel connecting the first sub-accommodating space 6221 and the second sub-accommodating space 6222 for biological use The water composition passes through, and the size of the opening 6212 is not limited. Since the second sub-accommodating space 6222 defined by the partition 6211 is arranged along the length direction of the carrier 621, the hollow fiber membrane filter element 626 of the second embodiment is longer than the hollow fiber membrane filter element 606 of the first embodiment As a result, the biological water composition must travel a relatively long distance in the hollow fiber membrane filter element 626 along a water flow direction F (shown by the arrow), so the effect of filtering bacteria or impurities will be better. The selection and configuration of the antibacterial filter assembly 627 can be compared to the aforementioned first embodiment, and will not be repeated here.

Refer to FIG. 13, which is a schematic diagram illustrating a third embodiment of an integrated water filter device. The water filter device 64 includes a carrier 641 and an inlet 643 on the top side of the carrier 641 and an outlet on the bottom side. Water port 644. The carrier 641 defines an accommodating space 642, and the accommodating space 642 is divided into two sub-accommodating spaces, a first sub-accommodating space 6421 and a second sub-accommodating space 6422, respectively. The first sub-accommodating space 6421 is connected to the water inlet 643, and the second sub-accommodating space 6422 is connected to the water outlet 644. The first sub-accommodating space 6421 is filled with a filter material assembly 645, and a hollow fiber membrane filter element 646 is disposed in the second sub-accommodating space 6422. A bacteriostatic filter material assembly 647 is also provided in the first sub-accommodating space 6421. As shown in FIG. 13, the bacteriostatic filter material assembly 647 is sandwiched by the filter material assembly 645. A spacer 6411 is provided between the first sub-accommodating space 6421 and the second sub-accommodating space 6422, and the second sub-accommodating space 6422 is defined by the spacer 6411. The spacer 6411 is located near the bottom of the carrier 641 There is at least one opening 6412 at the side for connecting the first sub-accommodating space 6421 and the second sub-accommodating space 6422 to allow The biological water composition passes through, and the size of the opening 6412 is not limited. After the biological water composition enters the opening 6412 along a water flow direction F (shown by the arrow), it first travels upward to the top in the hollow fiber membrane filter element 646, and then reverses and travels downward to the water outlet 644. Such a design can allow the biological water composition to travel a longer path in the hollow fiber membrane filter element 646. Therefore, compared with the foregoing second embodiment, the third embodiment has a better effect of filtering bacteria or impurities. The selection and configuration of the antibacterial filter assembly 647 can be compared to the aforementioned first embodiment, and will not be described again.

Referring to FIG. 14, this is a schematic diagram illustrating a fourth embodiment of an integrated water filter device. The water filter device 66 of this embodiment includes a carrier 661 and a water inlet 663 on the bottom side of the carrier 661 and the top An outlet 664 on the side. The carrier 661 defines an accommodating space 662, and the accommodating space 662 is divided into two sub-accommodating spaces, a first sub-accommodating space 6621 and a second sub-accommodating space 6622, respectively. The first sub-accommodating space 6621 is connected to the water inlet 663, and the second sub-accommodating space 6622 is connected to the water outlet 664. The first sub-accommodating space 6621 is filled with a filter material assembly 665, and a hollow fiber membrane filter element 666 is disposed in the second sub-accommodating space 6622. A bacteriostatic filter material assembly 667 is also provided in the first sub-accommodating space 6621. As shown in FIG. 14, the bacteriostatic filter material assembly 667 is sandwiched by the filter material assembly 665. A partition 6611 is provided between the first sub-accommodating space 6621 and the second sub-accommodating space 6622, and the second sub-accommodating space 6622 is defined by the partition 6611. The partition 6611 is close to the top of the carrier 661 There is at least one opening 6612 at the side, and the opening 6612 is very close to the water outlet 664 to communicate with the first The sub-accommodating space 6621 and the second sub-accommodating space 6622 cause the biological water to travel a longer path in the hollow fiber membrane filter element 646 from the opening 6612 to the water outlet 664, and the size of the opening 6412 is not limited. . The selection and configuration of the antibacterial filter assembly 667 can be compared to the aforementioned first embodiment, and will not be repeated.

15, this is a schematic diagram illustrating a fifth embodiment of an integrated water filter device. The water filter device 68 includes a carrier 681 and at least one water inlet 683 and a water outlet also located on the bottom side of the carrier 681 684. The carrier 681 defines an accommodating space 682, and the accommodating space 682 is divided into two sub-accommodating spaces, a first sub-accommodating space 6821 and a second sub-accommodating space 6822, respectively. The first sub-accommodating space 6821 is connected to the water inlet 683, and the second sub-accommodating space 6822 is connected to the water outlet 684. A filter material assembly 685 is filled to be located in the first sub-accommodating space 6821, a hollow fiber membrane filter element 686 is set to be located in the second sub-accommodating space 6822, and a preliminary filter unit 688 is located in the filter material assembly Between 685 and the hollow fiber membrane filter element 686, it is used to filter out larger particles. The first sub-accommodating space 6821 also contains a bacteriostatic filter material assembly 687. As shown in FIG. 15, the bacteriostatic filter material assembly 687 is sandwiched by the filter material assembly 685. A spacer 6811 is provided between the first sub-accommodating space 6821 and the second sub-accommodating space 6822. The spacer 6811 has at least one opening 6812 close to the top side of the carrier 681 and forms a water outlet 6813. The opening 6812 is used to connect the first sub-accommodating space 6821 and the second sub-accommodating space 6822, and the water outlet channel 6813 connects the second sub-accommodating space 6822 and the water outlet 684. The size of the opening 6812 is not limited. As for the antibacterial filter The selection and configuration of the material assembly 687 can be compared to the foregoing first embodiment, and will not be repeated.

The filter material used in the first embodiment to the fifth embodiment of the aforementioned integrated water filter device may adopt any one of the first embodiment to the seventh embodiment of the filter material of the present invention or any combination of multiple embodiments, or even One or more auxiliary filter materials can be added for further combination. In other derivative embodiments, the filter material assemblies 605, 625, 645, 665, and 685 described in the above embodiments may be only partially filled in the first accommodating space 6021 of the carrier 601, 621, 641, 661, and 681, respectively. , 6221, 6421, 6621, 6821, for example, only occupy 40% to 80% of the first accommodating space, and it is not necessary to completely fill the first accommodating space. Furthermore, the foregoing embodiments of FIGS. 11 to 15 can all be provided with a preliminary filtration unit at the water inlet to filter impurities or to buffer the flow rate of the water flow, which is omitted here and is not shown.

Refer to FIG. 16, which is a schematic diagram illustrating a sixth embodiment of an integrated water filter device. The water filter device 70 includes a carrier 701 and a water inlet 703 and a water inlet 703 on the bottom and top sides of the carrier 701, respectively.出水口704。 Water outlet 704. The carrier 701 defines an accommodating space 702, and the accommodating space 702 is divided into two sub-accommodating spaces, a first sub-accommodating space 7021 and a second sub-accommodating space 7022, respectively. The first sub-accommodating space 7021 is connected to the water inlet 703, and the second sub-accommodating space 7022 is connected to the water outlet 704. As shown in FIG. 5B or FIG. 6B, a hollow cylindrical filter material assembly 705 is located in the first sub-accommodating space 7021, and a hollow fiber membrane filter element 706 is disposed in the second sub-accommodating space 7022. The hollow cylindrical filter material assembly 705 can be the one mentioned in the previous embodiment of the present invention The molded block filter material (as shown in FIG. 3) and possible implementations, such as molded activated carbon, can be further classified into sintered activated carbon or compressed activated carbon from the manufacturing process. As shown in Figure 16, a bacteriostatic filter material assembly 707 is located inside the filter material assembly 705, but the present invention is not limited. The bacteriostatic filter material assembly 707 can also be evenly dispersed in the filter material assembly 705, or it is not necessary to use inhibitors. Bacteria filter assembly 707. A spacer 7011 is provided between the first sub-accommodating space 7021 and the second sub-accommodating space 7022, and the spacer 7011 has at least one opening 7012 connecting the first sub-accommodating space 7021 and the second sub-accommodating space 7022, The size of the opening 7012 is not limited. The other partition 7013 is arranged at a position close to the water inlet 703, and the filter material assembly 705 is sandwiched between the partition 7011 and the partition 7013, and the first sub-accommodating space 7021 forms a water inlet flow channel 7014. The biological water travels along the inlet flow channel 7014 from the side of the filter assembly 705 to the center (in the direction indicated by the arrow), is converted into biological water, and then enters the hollow fiber membrane filter element 706 through the opening 7012.

Refer to FIG. 17, which is a schematic diagram illustrating a seventh embodiment of an integrated water filter device. The water filter device 72 includes a carrier 721 and a water inlet 723 and a water outlet 724 also located on the top side of the carrier 721 . A hollow cylindrical filter material assembly 725 similar to the hollow cylindrical filter material assembly 705 described in the aforementioned sixth embodiment is used and arranged in the accommodating space 722 defined by the carrier 721, and then a hollow cylindrical filter material assembly 725 is used. A hollow fiber membrane filter element 726 in the shape of a hollow part of the filter material assembly 725 is arranged in the hollow part of the filter material assembly 725. The biological water travels along the water flow direction F from the side of the filter assembly 725 to the center (in the direction indicated by the arrow), and is converted into biological water composition. Then enter the hollow fiber membrane filter element 726, and finally flow out from the water outlet 724. The selection and configuration of the antibacterial filter material assembly 727 can be compared with the antibacterial filter material assembly 707 of the aforementioned sixth embodiment, and will not be repeated here.

The first to seventh embodiments of the integrated water filter device shown in FIGS. 11 to 17 can also be applied to replace the first water filter device 401 in the water purification system as shown in FIGS. 7 to 9 At this time, the third water filtering device 403 can be omitted.

For the biological water composition obtained in any one of the foregoing embodiments of the present invention, if the soluble silicon content measured by the colorimetric method is used, the concentration of the biological water composition can be between 8 mg/L and 90 mg/L. The best concentration is controlled between 10mg/L and 50mg/L, the oxidation-reduction potential (ORP) of the biological water composition is not higher than -100mV, preferably not higher than -300mV, more preferably not too high At -550mV, not higher than -650mV is a more ideal condition. The hydrogen concentration of the biological water composition can be between 0.6~1.6mg/L (ppm), the preferred concentration is controlled between 0.8mg/L to 1.6mg/L, and the more preferred concentration is controlled at medium Between 1mg/L to 1.6mg/L. The oxidation-reduction potential is measured by the electrode (manufacturer: JAQUA; model: EO221) and the oxidation-reduction potential analysis host (manufacturer: Horiba). The content of silicic acid (soluble silicon) is measured by Merck colorimetric method.

In addition to being used as drinking water, the biological water composition produced in the foregoing embodiments of the present invention can be added to an item or an animal (collectively referred to as the object) to slow down the oxidation rate of the item. Or conducive to the formation of connective tissue of the animal (It should be noted here that the above biological water composition can be directly added to the animal, or the animal can indirectly absorb the biological water composition by using the article). The article is, for example, selected from a skin care product or a beverage. The animal may be a vertebrate, but the present invention is not limited thereto. It can be used for internal and external use of all organisms.

The skin care product can be a lotion, a moisturizing lotion, an essence, a make-up milk, a whitening lotion, a whitening cream, or a moisturizing cream. The biological water composition can be matched with the existing ingredients of the above-mentioned skin care products. It is also worth mentioning that it can also be used in combination with a facial mask. Specifically, a facial mask (such as non-woven fabric) can be directly composed of biological water and can be optionally combined with other known facial mask components (such as: L-C, Fruit acid, placenta, various plant extracts, etc.); more preferably, the biological water composition can replace at least one of the many antioxidant and moisturizing ingredients in the known facial mask ingredients; among them, the antioxidant ingredients are, for example, Vitamin C, Vitamin E, carnosine, CoQ _10, etc., and moisturizing ingredients are, for example, polyhydric alcohols such as hyaluronic acid and glycerin, and collagen. The moistened mask can be packaged in an air-tight manner to avoid hydrogen loss. In other embodiments, a facial mask set can also be provided, which includes a bottled jar (preferably a glass bottle) filled with biological water, and a dry facial mask or a mask with other known ingredients (such as whitening agent). , Plant extracts, enzymes, etc.); only use the biological water to moisten the mask when actually used.

In addition, all beverages that are prone to oxidation, such as apple juice, can be used as the beverage, and acidic juices are more suitable for the presence of silicic acid in the composition of biological water. In addition, for example, sparkling water, beer, coffee, tea, yogurt, functional drinks And so on, can add its flavor with its hydrogen and silicic acid. The above-mentioned beverage is preferably packaged in an airtight manner, preferably packaged in a glass bottle. Taking beer as an example, the biological water composition can be used to adjust its original silicic acid content to change its flavor, and hydrogen can also add taste. Taking yogurt as an example, the low redox potential system composed of biological water can activate facultative or obligate anaerobic bacteria, such as lactic acid bacteria. Taking bubble water as an example, the hydrogen composed of biological water can synergize with the gas of the bubble water to produce different levels of bubble taste. In addition, the bubble water contains more important nutrients in beer (ie silicic acid), so users can avoid drinking alcohol. , You can enjoy the benefits of beer on the human body. Taking coffee as an example, the silicic acid in the composition of biological water, the silicate ions dissolved in coffee, will neutralize with the acidic molecules of coffee, causing it to lose its acidity. The sour taste in coffee usually comes from lactic acid and malic acid, the sweet taste usually comes from citric acid, the pungent taste usually comes from quinic acid and chlorogenic acid, and the aroma usually comes from eugenol; in addition, there are tartaric acid. Therefore, when the concentration of silicic acid is between 10mg/L~20mg/L, the sourness of coffee can be moderately diminished. If you need to further remove more sourness, you can use biological materials with a concentration of silicic acid between 20mg/L~40mg/L. Composition with water. Biological water can also be extended to any application field that requires water. Except that the application must not contain hydrogen and/or silicic acid components, other fields can be the application fields of the present invention. For example, the biological water composition of the present invention can also be used for beer brewing. Specifically, the beer manufacturing process generally includes: step a) mashing malt and adding water and saccharification, step b) filtering, and step c) adding hops And boiling, step d) cooling, step e) adding yeast for fermentation (generally including pre-fermentation and post-fermentation), step f) aseptic filtration, and step g) filling and packaging; Wherein, the biological water composition can be added in at least one of step a), step c), and step e), so that the concentration of silicic acid originally derived from malt can be adjusted and the fermentation process can be ensured under anaerobic conditions. get on. Similarly, in other embodiments, the biological water composition of the present invention can also be used for the production of fermented beverages such as yogurt and lactic acid bacteria beverages. Specifically, the production process of yogurt generally includes: step a) milk sterilization, Step b) Putting strains into fermentation, step c) uniform stirring, step d) filtering, and step e) filling and packaging; wherein, the biological water composition can be added in at least one of steps a) and b), This can help the fermentation of the bacteria.

In addition, in the fields of agriculture, fishery and animal husbandry, the biological water composition of the present invention can also be used; for example, in aquaculture ponds, some algae, such as diatoms, if the biological water composition is used, the silicic acid in it can be beneficial to silicon The growth of algae; in addition, it is also conducive to the reproduction of microorganisms or increase the metabolism. Furthermore, the biological water composition can also provide an initial environment with low redox potential to facilitate the growth of some facultative or obligate anaerobic bacteria. However, because it is in an atmospheric environment, the redox potential of the biological water composition will still change. Gradually rise, so the breeding pond will not be dominated by anaerobic bacteria. The user can add the corresponding amount of biological water composition and the required number of times according to the desired environment of the breeding pond. For another example, in the agricultural field, the biological water composition of the present invention can be used to provide an oxidation-reduction potential similar to that of cells in crops, and silicon required for crop growth, thereby improving crop disease resistance and yield. For example, the user can inject biological water into the soil and cover it with water so that the soil has a low oxidation-reduction potential and can absorb The silicic acid (soluble silicon) in the biological water composition is collected to achieve the above-mentioned purpose.

It is also worth mentioning that in the field of health care, including but not limited to oxidative stress-derived diseases, nervous system diseases, and skeletal system diseases, the soluble silicon (silicic acid) in the biological water composition of the present invention Together with hydrogen (the main contributor to low oxidation-reduction potential), it can work together to protect the focus of the disease through different mechanisms. For example, currently known diseases related to oxidative stress include aging, chronic inflammation, cancer, neurodegenerative diseases, cardiovascular diseases, arthritis, diabetes, gout, allergies, autoimmune diseases, and kidney diseases. Therefore, monitoring the oxidative pressure and avoiding the increase of oxidative pressure is the key to delaying aging and preventing diseases. Among them, the soluble silicon in the composition of biological water can be used to regulate the production and function of metal ions in cells. This is very important to maintain the balance of oxidative pressure. Specifically, silicic acid can form with inorganic ions. Complex compounds to safely isolate iron in tissues and reduce its ability to produce active oxygen. As for the hydrogen in the biological water composition, it can neutralize free radicals including active oxygen. Therefore, the biological water composition of the present invention can synergistically protect diseases derived from oxidative stress.

For the skeletal system, the silicic acid in the biological water composition of the present invention helps the human body to absorb calcium and vitamin D, thereby preventing bone loss, while the hydrogen in the biological water composition can treat joints. Inflammation and inhibition of osteoclast (osteoclast) differentiation. Therefore, the biological water composition of the present invention can synergistically protect the skeletal system. For another example, for the nervous system, in the biological water composition of the present invention, Soluble silicon and hydrogen can inhibit the neuronal toxicity caused by aluminum through different mechanisms, such as reducing the risk of Alzheimer's disease.

It is also worth mentioning that in the above embodiments of the water purification system, a circulating return device (not shown) can be added downstream of the first water filter device 401, so that the water flow can return to the first filter device again. The water device 401 reacts with the active silicon material again, and can more quickly and/or produce a biological water composition with a higher concentration of silicic acid and hydrogen. In this way, the user can determine the required concentration of the biological water composition by controlling the recirculation frequency of the circulating recirculation device. In a derivative embodiment, a switch can also be added, which can control the water flow through different numbers of first water filter devices 401, which can be used to control the concentration, that is, the more first water filter devices flow through 401, the biological water composition with higher concentration of silicic acid and hydrogen can be produced more quickly and/or. Specifically, for example, if you want to produce a lighter concentration, you can use the switch to flow through only one first water filter 401, and if you want to produce a medium concentration, you can use the switch to flow through a first water filter 401 and match it. Control the recirculation device to make the water flow through the first water filter device 401 to circulate multiple times. If you want to obtain a higher concentration, you can control the water flow through the two first water filter devices 401 through the switch and control the recirculation device 401 together. The device makes the water flow through the first water filter device 401 to circulate multiple times. In other derivative embodiments, the user can also select the desired concentration through the control panel. In addition to controlling the recirculation frequency of the circulating recirculation device, the microcomputer can also control the corresponding flow of general drinking water alone or in combination with the biological water composition. Mix to make a biological water composition of the selected concentration.

In addition, in the above embodiments of the water purification system, four water outlets can be provided in the water purification system, and the biological water composition of the water for drinking is pure water, and the biological water composition containing both silicic acid and hydrogen (hereinafter referred to as silicon Hydrogen water), biological water composition containing silicic acid but no hydrogen (hereinafter referred to as silica water), and biological water composition containing hydrogen but not containing silicic acid (hereinafter referred to as hydrogen water). Among them, the way to make silicon water is to add a degassing device/water filter device to the water purification system to remove hydrogen; the way to make hydrogen water is to add an ion exchange resin water filter device or more in the water purification system. Oxides or hydroxides of valence cations are used to remove/adsorb silicic acid. Therefore, the user can control whether the biological water should flow through the first water filter device 401, the second water filter device 402, The degassing water filter device and the exchange resin water filter device provide different biological water composition according to the different needs of users. It is worth mentioning that the concentration of the silicon-hydrogen water of the present invention can be further used in conjunction with the method described in the previous paragraph to adjust the concentration of the effluent water.

To sum up, the filter material (or filter material assembly), water filter device, water purification system and biological water composition of the present invention are composed of highly active active silicon material and biological water to generate silicic acid (soluble silicon) and The biological water composition of hydrogen can increase both the amount of dissolved hydrogen and the amount of dissolved silicon in the biological water and provide a safe biological water composition, so it can indeed achieve the purpose of the invention.

However, the above are only examples of the present invention. When the scope of implementation of the present invention cannot be limited by this, all simple equivalent changes and modifications made in accordance with the scope of the patent application of the present invention and the content of the patent specification still belong to The scope of the invention patent Inside.

11: Filter material

112: carrier

114: Surface

116: active silicon material

Claims (39)

A filter material used to purify water and produce a biological water composition containing silicic acid and hydrogen, which includes: A carrier; and An active silicon material attached to the carrier; Among them, the size of the filter material is between 50 μm and 10 mm. The filter material according to claim 1, wherein the carrier is selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, and polymer Fiber, and a combination of the foregoing. The filter material according to claim 2, wherein the carrier comprises a plurality of sub-carriers, and each sub-carrier is independently selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, and diatomaceous earth , Ore, zeolite, silica particles, polymer fibers, and a combination of the foregoing. The filter medium according to claim 3, wherein the size of each sub-carrier of at least some of the sub-carriers is between 0.2 μm and 2.5 mm. The filter material according to claim 2, wherein the carrier is activated carbon with a plurality of micropores distributed on the surface, and the activated silicon material is a plurality of nano-silicon particles and completely covers the surface of the activated carbon. The filter material according to claim 2, wherein the carrier is a silicon particle formed by aggregation of a plurality of nano-silicon particles, and the active silicon material is a plurality of nano-silicon particles and completely covers the silicon particles. The filter material according to claim 1, wherein the active silicon material contains a plurality of nano-silicon particles, and the size of each of the nano-silicon particles is between 50 nm and 800 nm. The filter material according to claim 1, wherein, based on the weight percentage of the filter material, the content of the active silicon material is between 40 wt% and 95 wt%. The filter material of claim 1, wherein the carrier is selected from a particulate material, a fiber material, or a combination of the foregoing, the active silicon material covers the carrier and forms an active layer, and the active layer has a thickness of 200 nm～3 mm. A filter material assembly comprising a plurality of filter materials as described in claim 1, wherein the filter materials include a plurality of first filter materials and a plurality of second filter materials, and the size of the first filter materials is larger than the size of the second filter materials, and the The content of the first filter material is different from the content of the second filter material based on the weight percentage of the filter material assembly. A filter material assembly comprising a plurality of filter materials as described in claim 1 and a plurality of auxiliary filter materials, each auxiliary filter material is selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth , Ore, zeolite, silica particles, polymer fibers, and a combination of the foregoing. A filter material assembly includes a plurality of filter materials as described in claim 1 and a bonding material, the bonding material is used to bond the filter materials to each other, wherein the active silicon material contains a plurality of nano-silicon particles. The filter material assembly according to claim 12, wherein the binding material is selected from the group consisting of polyether, acrylic resin, styrene, polyamide, polyester, polyolefin, cellulose, polyethylene , Glycerin, polyethylene glycol, polyvinyl alcohol and a combination of the foregoing. The filter material assembly according to claim 12, wherein, in each filter material, the active silicon material completely covers the carrier. The filter material assembly described in claim 12 further includes: A plurality of auxiliary filter materials, selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fibers, and a combination of the foregoing, these auxiliary The filter material is bonded with the filter materials through the binding material. The filter material assembly according to claim 15, wherein a plurality of silver nanoparticles or a plurality of zinc nanoparticles are attached to the surface of each auxiliary filter material. The filter material assembly of claim 12, wherein the size of the nanosilica particles is between 50 nm and 800 nm, and in each filter material, the carrier is activated carbon with a plurality of micropores distributed on the surface. These nano-silicon particles and the carrier undergo a heating and pressure process to form a shaped activated carbon. The filter material assembly described in claim 12 further includes: A silicon particle, the silicon particle is formed by agglomeration of nano-silicon materials and has a size ranging from 0.2 mm to 2 mm. A filter material assembly used to purify water and produce a biological water composition containing silicic acid and hydrogen. It includes a plurality of filter materials, and each filter material includes: At least one carrier, the carrier is selected from the group consisting of a main carrier, a plurality of sub-carriers, a silicon particle and a fiber material; and A plurality of nano-silicon particles are attached to the carrier; Wherein, the carriers of at least two of the filter materials are different. The filter material assembly according to claim 19, wherein when the carrier in each filter material is selected from the main carrier, the sub-carriers or the silicon particles, the size of the filter material is between 50 μm and 10 mm, The size of the main carrier is between 25 μm and 2.5 mm, and the size of each sub-carrier of at least some of the sub-carriers is between 0.2 μm and 2.5 mm. A water filter device is used to purify water and produce biological water composition containing silicic acid and hydrogen, including: A first carrier, defining a first accommodating space, and including a first water inlet and a first water outlet communicating with the first accommodating space; and A plurality of filter materials such as any one of claim items 1 to 9 or a filter material assembly such as any one of claim items 10 to 20, the filter material or the filter material assembly is located in the first accommodating space. The water filter device according to claim 21, comprising: a bacteriostatic filter material assembly, located in the first accommodating space of the first carrier, and including: The plural antibacterial carriers are selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fibers, soluble glass, and a combination of the foregoing ;and A bacteriostatic component is carried or attached to these bacteriostatic carriers. The water filter device according to claim 21, comprising: A hollow fiber membrane filter element is located in the first accommodating space of the first carrier. The water filter device according to claim 23, wherein the first water inlet flows in a predetermined amount of biological water, and the predetermined amount of biological water passes through the filter materials or the filter material assembly and the hollow fiber membrane filter element in sequence, Then a required amount of biological water composition flows out from the first water outlet. The water filter device described in claim 21 further includes: An elastic body with a plurality of pores is located in the first accommodating space and based on the water flow direction. The elastic body is arranged at an upstream position of the filter assembly, wherein the size of each pore is between 5 μm and 40 μm . The water filter device described in claim 21 further includes: A spacer for dividing the first accommodating space into a first sub-accommodating space and a second sub-accommodating space, wherein the filter material assembly is located in the first sub-accommodating space and the first sub-accommodating space The set space is connected to the water inlet; and A hollow fiber membrane filter element located in the second sub-accommodating space and the second sub-accommodating space is connected to the water outlet; Wherein, the partition has an opening to allow the biological water component to enter the second sub-accommodating space from the first sub-accommodating space. A water purification system is used to produce biological water components containing silicic acid and hydrogen. The water purification system includes: At least one first water filter device uses the water filter device described in claim 21; and A pipeline unit includes a pipeline connecting the first water inlet and the first water outlet. The water purification system described in claim 27 further includes: A second water filter device is disposed at a downstream position of the first water filter device, and includes a second carrier defining a second accommodating space, and the second carrier has a connection with the second accommodating space A second water inlet and a second water outlet that are connected; and A hollow fiber membrane filter element located in the second accommodating space; Wherein, the pipeline unit has at least one first delivery pipeline connecting the first water outlet and the second water inlet. The water purification system described in claim 28 further includes: A bacteriostatic filter material assembly is located in the second accommodating space of the second carrier, and based on the water flow direction, is located at an upstream position of the hollow fiber membrane filter element. The water purification system as described in claim 28, further comprising: A third water filter device is arranged on one side of the first water filter device, and includes a third carrier defining a third accommodating space, the third carrier having communication with the third accommodating space A third water inlet and a third water outlet of; and A bacteriostatic filter assembly is located in the third accommodating space of the third water filter device and contains a bacteriostatic component and a plurality of bacteriostatic carriers for carrying or adsorbing the bacteriostatic component, the bacteriostatic carriers are Selected from the group consisting of activated carbon, ceramics, bamboo charcoal, medical stone, quartz sand, diatomaceous earth, ore, zeolite, silica particles, polymer fiber, soluble glass, and a combination of the foregoing; Wherein, the pipeline unit has at least one second delivery pipeline connecting the third water outlet and the first water inlet. The water purification system as described in claim 28, further comprising: An ultraviolet light sterilization unit is arranged at an upstream position of the first water filter device or at a downstream position of the second water filter device. The water purification system as described in claim 28, further comprising: At least one total dissolved solids measurement unit is arranged at an upstream position of the first water filter device or at a downstream position of the second water filter device. The water purification system as described in claim 27, further comprising: A discharge unit is located downstream of the first water filter device and communicates with the pipeline unit for discharging liquid, gas, or a combination of liquid and gas. The water purification system according to claim 27, wherein the number of the at least one first water filter device is two, and the two first water filter devices receive a predetermined amount of biological water from the same pipeline unit, and It is composed of the same pipeline unit that simultaneously discharges a required amount of biological water. A biological water composition prepared by filtering a biological water using the filter material as described in claim 1, wherein the concentration of the soluble silicon content measured by the colorimetric method in the biological water composition is between 8 mg/L To 90 mg/L, the redox potential of the biological water composition is not higher than −100 mV. A method for manufacturing a filter material assembly, which is used to purify water and produce a biological water composition containing silicic acid and hydrogen. The steps include: (a) Provide multiple carriers in a container; and (b) Add a plurality of nanosilica particles to the container to form a filter material assembly containing a plurality of filter materials after aggregating with the carriers. Each filter material contains a carrier and a plurality of nanosilica particles, Wherein, based on the weight percentage of the filter material assembly, the content of the nanosilica particles is between 40 wt% and 95 wt%. The method for manufacturing a filter material assembly according to claim 36, wherein, in step (b), the nanosilica particles are mixed with a solvent and prepared into a slurry before being added to the container, and the total weight of the slurry is Based on 100 wt%, the content of these nano-silicon particles ranges from 10 wt% to 40 wt%. According to claim 36, the method for manufacturing the filter material assembly further includes a step (c) after the step (b): (c) Raise the temperature of the container so that the temperature in the container is between 50 and 300 degrees Celsius. The method for manufacturing a filter material assembly according to claim 36, wherein the carriers and the nanosilica particles in the step (b) are stirred and mixed by a stirrer.

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