TWI711524B - Cladding type plastic injection molding method for thick lens - Google Patents
Cladding type plastic injection molding method for thick lens Download PDFInfo
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本發明有關於一種厚件透鏡之包覆式塑膠射出成型方法,尤指一種可有效減少分次成型之包覆結合線與品質缺陷(例如翹曲、收縮、包封等)問題,並可大幅縮短厚件透鏡之成型時間的包覆式塑膠射出成型方法。 The present invention relates to a coating plastic injection molding method for thick lenses, in particular to a method that can effectively reduce the problems of coating bonding lines and quality defects (such as warpage, shrinkage, encapsulation, etc.) that can be A covered plastic injection molding method that shortens the molding time of thick lenses.
現今塑膠產品的製造,多材質射出成型(Multi-Component Molding,MCM)製程已經廣泛地被應用於多元化的塑膠件設計與製程。MCM製程主要是利用兩種或多種材料射出注入模具內來生產產品,例如常見的電動工具於硬質塑膠外殼包覆軟質塑料,以提供足夠的結構強度與柔軟的手感。然現實生產中的MCM製程仍面臨許多問題與挑戰。如MCM製程可能牽涉到多種嵌件或多種不同材料,因此單一材料射出成型的設計與開發規則,常常不能直接套用於MCM。另外,由於MCM製程複雜性和多材質之物理機制,若以傳統的單一材料射出成型的經驗法則,無法有效對於關鍵成形條件進行優化或設計變更,造成品質控制上的不確定性。 Nowadays, in the manufacture of plastic products, the Multi-Component Molding (MCM) process has been widely used in diversified plastic part design and manufacturing processes. The MCM process mainly uses two or more materials to be injected and injected into a mold to produce products. For example, common electric tools are coated with soft plastic in a hard plastic shell to provide sufficient structural strength and soft feel. However, the MCM process in actual production still faces many problems and challenges. For example, the MCM process may involve multiple inserts or multiple different materials, so the design and development rules of single material injection molding often cannot be directly applied to MCM. In addition, due to the complexity of the MCM process and the physical mechanism of multiple materials, the traditional empirical rule of single-material injection molding cannot effectively optimize or design changes to key molding conditions, resulting in uncertainty in quality control.
將MCM製程歸納成為兩大類,第一類為當兩種材料複合成型時,將產生明確之中間界面(distinct interface),包括嵌入成型(insert molding)、包覆成型(over molding)、和多射依序成型(sequential multiple shot molding)。第二類則為當兩種材料複合成型時,將產生不確定之中間界面(uncertain interface),此類常見的製程,包括共射成型(co-injection),雙射成型(bi-injection)。 The MCM process is summarized into two categories. The first category is that when two materials are compounded and molded, a distinct distinct interface will be produced, including insert molding, over molding, and multi-shot Sequential molding (sequential multiple shot molding). The second type is that when two materials are compounded and molded, an uncertain interface will be produced. This type of common manufacturing process includes co-injection and bi-injection.
針對不確定之中間界面系統,產品設計者如何能正確推測出最佳澆口位置,以及材料比例,使其成品得以獲得理想的材料分佈與產品特性,對產品設計人員將是相當大的挑戰。 Regarding the uncertain intermediate interface system, how the product designer can correctly guess the best gate position and material ratio so that the finished product can obtain the ideal material distribution and product characteristics will be a considerable challenge for the product designer.
此外,就大尺寸塑膠射出厚件光學透鏡(例如,直徑大於60公厘(mm),厚度大於20公厘(mm))而言,由於注入模穴之熔融塑料的熱量過於集中,當外側塑料冷卻而使中心處的熱量不易向外傳導至模具,造成冷卻時間過長的問題。當使用既有直通式冷卻水路時,因傳統鑽孔加工方式限制而使水路不易靠近模穴進行冷卻,造成塑料與模具的溫差過大或冷卻速率不一的問題,產生成品之收縮率、翹曲與殘留應力等缺陷。 In addition, for large-size plastic injection of thick optical lenses (for example, a diameter greater than 60 mm (mm) and a thickness greater than 20 mm (mm)), because the heat of the molten plastic injected into the mold cavity is too concentrated, when the outer plastic Cooling makes the heat in the center difficult to conduct outward to the mold, causing the problem of excessive cooling time. When using the existing straight-through cooling water path, the water path is not easy to approach the mold cavity for cooling due to the limitation of the traditional drilling processing method, causing the problem of excessive temperature difference between the plastic and the mold or different cooling rates, resulting in shrinkage and warpage of the finished product Defects such as residual stress.
上述厚件光學透鏡使用直通式冷卻水路的生產時間極長,實務上可長達600~900秒,過長的冷卻時間會大幅減少生產效率與增加製造成本。 The production time of the above-mentioned thick optical lens using the straight-through cooling water circuit is extremely long, which can be as long as 600 to 900 seconds in practice. An excessively long cooling time will greatly reduce production efficiency and increase manufacturing costs.
據此,如何能有一種可有效減少分次成型之包覆結合線與品質缺陷(例如翹曲、收縮、包封等)問題,並可大幅縮短厚件透鏡之冷卻與生產時間之『厚件透鏡之包覆式塑膠射出成型方法』,是相關技術領域人士亟待解決之課題。 Based on this, how can there be a "thick part" that can effectively reduce the problems of the coating and bonding line and quality defects (such as warpage, shrinkage, encapsulation, etc.) of the step-by-step molding, and greatly shorten the cooling and production time of the thick lens The encapsulated plastic injection molding method of the lens" is an urgent issue to be solved by those in the relevant technical field.
於一實施例中,本發明提出一種厚件透鏡之包覆式塑膠射出成型方法,包括以下步驟:進行第一次射出成型,以具有第一熔膠體積之熔膠形成一第一射半成 品,第一射半成品包含一第一主體及至少一支撐腳,支撐腳凸伸於第一主體之側邊;以及進行第二次射出成型,以具有第二熔膠體積之熔膠包覆於第一射半成品的外部且包覆部分支撐腳,以形成一成品,第一熔膠體積與第二熔膠體積之和為該成品的總熔膠體積,第一熔膠體積占總熔膠體積之17~40%,成品沿一第一方向具有一總厚度,總厚度等於或大於20公厘(mm)。 In one embodiment, the present invention proposes a thick lens encapsulated plastic injection molding method, which includes the following steps: performing the first injection molding, and forming a first injection semi-finished product with a melt having a first melt volume The first injection semi-finished product includes a first main body and at least one supporting leg, the supporting leg protruding from the side of the first main body; and the second injection molding is performed, and the molten glue with the second molten glue volume is coated on The outside of the first semi-finished product is shot and part of the supporting feet is covered to form a finished product. The sum of the first melt volume and the second melt volume is the total melt volume of the finished product, and the first melt volume accounts for the total melt volume 17~40%, the finished product has a total thickness along a first direction, and the total thickness is equal to or greater than 20 millimeters (mm).
100:厚件透鏡之包覆式塑膠射出成型方法之流程 100: Process of coating plastic injection molding method for thick lens
102、104:厚件透鏡之包覆式塑膠射出成型方法之流程之步驟 102, 104: Steps of the process flow of the thick lens covered plastic injection molding method
10:第一射半成品 10: First shot semi-finished product
11、11A、11B:第一主體 11, 11A, 11B: the first body
111:第一側 111: first side
112:第二側 112: second side
12、12A、121B、122B、123B:支撐腳 12, 12A, 121B, 122B, 123B: supporting feet
121:第一面 121: The first side
122:第二面 122: second side
123:線性段 123: Linear segment
124:弧型段 124: arc section
20:熔膠 20: Melt glue
30、30A、30B:成品 30, 30A, 30B: finished product
31:第三側 31: third side
32:第四側 32: Fourth side
33、33A、33B:澆口 33, 33A, 33B: gate
40:模具 40: Mould
41:第一次射出成型區 41: The first injection molding area
42:第二次射出成型區 42: The second injection molding area
D:直徑 D: diameter
F1:第一方向 F1: First direction
R:圓角處理 R: Fillet treatment
T0:總厚度 T0: total thickness
T1:第一厚度 T1: first thickness
T2:第二厚度 T2: second thickness
T3:第三厚度 T3: third thickness
T12:厚度 T12: thickness
W:寬度 W: width
圖1為本發明之厚件透鏡之包覆式塑膠射出成型方法之流程圖。 FIG. 1 is a flow chart of the coating plastic injection molding method for thick lenses of the present invention.
圖2為圖1之方法形成之第一射半成品之實施例結構示意圖。 FIG. 2 is a schematic structural diagram of an embodiment of the first semi-finished product formed by the method of FIG. 1. FIG.
圖3為圖1之方法形成之成品之實施例結構示意圖。 FIG. 3 is a schematic structural diagram of an embodiment of the finished product formed by the method of FIG. 1.
圖4為圖3實施例之俯視結構圖。 Fig. 4 is a top view of the structure of the embodiment in Fig. 3;
圖5為圖4之A-A剖面結構圖。 Fig. 5 is a cross-sectional structural view of A-A in Fig. 4;
圖6A至圖6D為本發明之厚件透鏡之包覆式塑膠射出成型方法之製程實施例示意圖。 6A to 6D are schematic diagrams of manufacturing process embodiments of the coating plastic injection molding method for thick lenses of the present invention.
圖7為圖1之方法形成之成品具有二支撐腳之實施例結構示意圖。 FIG. 7 is a structural diagram of an embodiment in which the finished product formed by the method of FIG. 1 has two supporting legs.
圖8為圖1之方法形成之成品具有三支撐腳之實施例結構示意圖。 Fig. 8 is a schematic structural view of an embodiment in which the finished product formed by the method of Fig. 1 has three supporting legs.
請參閱圖1至圖5所示,本發明所提供之一種厚件透鏡之包覆式塑膠射出成型方法之流程100,包括以下步驟:
步驟102:進行第一次射出成型,以具有第一熔膠體積之熔膠形成一第一射半成品10,第一射半成品10包含一第一主體11及一支撐腳12,支撐腳12凸伸於第一主體11之側邊;以及步驟104:進行第二次射出成型,以具有第二熔膠體積之熔膠20包覆於第一射半成品10的外部且包覆部分支撐腳12,以形成一成品30,第一熔膠體積與第二熔膠體積之和為該成品30的總熔膠體積,第一熔膠體積占總熔膠體積之17~40%,成品30沿一第一方向F1具有一總厚度T0,總厚度T0等於或大於20公厘(mm)。
Please refer to FIG. 1 to FIG. 5, the
請參閱圖2至圖5所示,本實施例之厚件透鏡為魚眼透鏡,但亦可為其他態樣,如方塊透鏡或錐形透鏡等。第一主體11沿第一方向F1具有相對之一第一側111及一第二側112,成品30沿第一方向F1具有相對之一第三側31與一第四側32,第三側31相對應設置於第一側111之外,第四側32相對應設置於第二側112之外,未被熔膠20包覆之其他部分之支撐腳12凸伸於成品30之外側且靠近第三側31。
Please refer to FIG. 2 to FIG. 5, the thick lens of this embodiment is a fisheye lens, but it can also be in other forms, such as a square lens or a cone lens. The
如圖5所示,該第一射半成品10的外型與成品30相似,以使熔膠20充填時可以順利流動並包覆於第一射半成品10的外部。於本實施例中,第一主體11的第一側111與第二側112皆為凸弧面,但亦可為其他態樣,例如,第一側111可為一平面,第二側112可為一規則或不規則之錐形面,或是由多段直線連成的曲面。
As shown in FIG. 5, the appearance of the first
於本實施例中,第三側31為一圓型平面,第四側32為一凸弧面。第三側31的直徑D等於或大於60公厘(mm),第四側32的弧度依魚眼透鏡的焦距、曲率與第三側31的直徑D而定,且依循前述總厚度T0等於
或大於20公厘(mm)的原則,例如,第三側31的直徑D若為75公厘(mm),總厚度T0可為27.5公厘(mm)。
In this embodiment, the
請參閱圖4至圖5所示,第四側32與第二側112間沿第一方向F1具有一第一厚度T1,第一主體11沿第一方向F1具有一第二厚度T2,第一側111與第三側31間沿第一方向F1具有一第三厚度T3,第一厚度T1與第三厚度T3小於第二厚度T2,第二厚度T2占總厚度T0之40~62%。
4 to 5, the
第一厚度T1與第三厚度T3的比例視實際所需而設計,例如,第一厚度T1可占總厚度T0之16~40%,第三厚度T3可占總厚度T0之14~40%,但不限於此。 The ratio of the first thickness T1 to the third thickness T3 is designed according to actual needs. For example, the first thickness T1 may account for 16-40% of the total thickness T0, and the third thickness T3 may account for 14-40% of the total thickness T0. But it is not limited to this.
請參閱圖2及圖3所示,支撐腳12具有一厚度T12與一寬度W,厚度T12為平行第一方向F1之尺寸,寬度W為垂直於第一方向F1之尺寸,厚度T12與寬度W之尺寸比例大致為1:2至1:4。
Please refer to Figures 2 and 3, the supporting
支撐腳12具有相對之一第一面121與一第二面122,第一面121相對應於第一主體11之第二側112且經過圓角處理R,第二面122相對應於第一主體11之第一側111且為平面。支撐腳12之圓角處理R設計,調整支撐腳12的形狀以減少塑料波前流動阻力,降低發生包封的機會。
The supporting
請參閱圖4及圖5所示,支撐腳12由一線性段123與一弧型段124構成。線性段123的第二面122相對應與成品30的第三側31齊平。線性段123藉由弧型段124與第一主體11相連接。線性段123的長度與弧型段124的弧度不限,依成品30的尺寸而定,換言之,支撐腳12能符合前述厚度T12與寬度W之尺寸比例大致為1:2至1:4,能被熔膠20部分包覆且部分凸伸於成品30之外側之設計原則即可。
Please refer to FIG. 4 and FIG. 5, the supporting
於本實施例中,成品30具有一支撐腳12,於成品30相對於支撐腳12之另一側為進行第二次射出成型時所形成之澆口33,該澆口33用於充填熔膠20。
In this embodiment, the
請參閱圖6A至圖6D所示,說明本發明所提供之一種厚件透鏡之包覆式塑膠射出成型方法之製程實施例。 Please refer to FIG. 6A to FIG. 6D, which illustrate an embodiment of the manufacturing process of a thick lens encapsulated plastic injection molding method provided by the present invention.
請參閱圖6A所示,備置一模具40,該模具40具有一第一次射出成型區41及一第二次射出成型區42。模具40閉合後於第一次射出成型區41進行第一次射出成型,以具有第一熔膠體積之熔膠形成一第一射半成品10(圖1所示步驟102)。於本實施例中,是以第一次射出成型區41的流道經冷卻後形成所述支撐腳12。
Please refer to FIG. 6A, a
請參閱圖6B所示,打開模具40,將第一射半成品10由第一次射出成型區41移至第二次射出成型區42。第一射半成品10的支撐腳12是朝上設置,第二次射出成型時的澆口33是設於支撐腳12的另一側。
Referring to FIG. 6B, the
請參閱圖6C所示,闔上模具40,於第二次射出成型區42進行第二次射出成型,形成一成品30(圖1所示步驟104),同時於第一次射出成型區41進行另一次第一次射出成型並形成另一第一射半成品10。
6C, the
請參閱圖6D所示,打開模具40,將成品30由第二次射出成型區42取出,再將第一射半成品10由第一次射出成型區41移至第二次射出成型區42進行第二次射出成型,以形成另一成品30。
6D, the
依此,重複進行圖6C、圖6D所示製程,即可進行成品30的量產。
Accordingly, by repeating the manufacturing processes shown in FIG. 6C and FIG. 6D, mass production of the
請參閱圖7所示,於本實施例中,第一射半成品10A包含二支撐腳12A,二支撐腳12A對稱設置於第一主體11A之相對二側邊。於成品
30A之一側具有一澆口33A,二支撐腳12A以澆口33A為中心對稱設置。該些支撐腳12A的配置方式可使由澆口33A進入之熔膠在充填過程具有相同的路徑長度與相同的阻力(支撐腳12A與第一主體11A)。
Please refer to FIG. 7. In this embodiment, the first
請參閱圖8所示,於本實施例中,第一射半成品10B包含第一支撐腳121B、第二支撐腳122B及第三支撐腳123B,其中第二支撐腳122B與第三支撐腳123B以第一支撐腳121B為中心對稱設置於第一主體11B之相對二側邊。於成品30B相對於第一支撐腳121B之另一側具有一澆口33B。於本實施例中,第一支撐腳121B、第二支撐腳122B、第三支撐腳123B以第一主體11B之中心為圓心等角度設置於第一主體11B之側邊,除此之外,第一支撐腳121B、第二支撐腳122B、第三支撐腳123B與澆口33B可等角度相距設置。該些支撐腳121B、122B、123B的配置方式可使由澆口33B進入之熔膠在充填過程具有相同的路徑長度與相同的阻力(支撐腳122B、123B與第一主體11B),以使熔膠之流動波前於支撐腳121B處完整結合並包覆該支撐腳121B。
Please refer to FIG. 8, in this embodiment, the first
圖4、圖7及圖8所示實施例顯示,藉由本發明所提供之厚件透鏡之包覆式塑膠射出成型方法所形成的成品可依所需成型不同數量的支撐腳,藉由支撐腳數量與位置之變化與設計,可避免流動波前於支撐腳處提早交會或結合,減少發生包封的機會。 The embodiments shown in Figure 4, Figure 7 and Figure 8 show that the finished product formed by the thick-piece lens covered plastic injection molding method provided by the present invention can be molded into different numbers of supporting legs according to the requirements. The change and design of quantity and position can prevent the flow wave front from meeting or combining early at the supporting foot and reduce the chance of encapsulation.
以本發明所提供的厚件透鏡之包覆式塑膠射出成型方法進行多次試驗,結果如下表一所示:
於表一中,厚度T0代表代表圖5中的總厚度T0。厚度T1、T2、T3分別代表圖5中的第一厚度T1、第二厚度T2、第三厚度T3。「熔膠體積」欄中的「第一射」代表利用本發明所提供的厚件透鏡之包覆式塑膠射出成型方法於進行第一次射出成型形成以第一射半成品10所使用的第一熔膠體積。「熔膠體積」欄中的「第二射」代表利用本發明所提供的厚件透鏡之包覆式塑膠射出成型方法於進行第二次射出成型所使用的第二熔膠體積。「冷卻時間」欄中的「第一射」代表完成第一射半成品10後所需要的冷卻時間。「冷卻時間」欄中的「第二射」代表完成成品30後所需要的冷卻時間。
In Table 1, the thickness T0 represents the total thickness T0 in FIG. 5. The thicknesses T1, T2, and T3 respectively represent the first thickness T1, the second thickness T2, and the third thickness T3 in FIG. 5. The “first shot” in the “melt volume” column represents the first shot used for the first shot of the
組別中的「單射」代表習知一次射出成型的方法,組別中的1~9代表以本發明所提供之厚件透鏡之包覆式塑膠射出成型方法進行二次分射的
九次試驗的九組結果。
The "single shot" in the group represents the conventional one-shot injection molding method, and the
表一所形成的成品如圖5所示之成品30,第三側31的直徑D為75公厘(mm),總厚度T0為27.5公厘(mm)。
The finished product formed in Table 1 is the
就「單射」而言,所使用的總熔膠體積為63.86立方公分(cm3),冷卻時間為900秒。 In terms of "single shot", the total volume of melt used is 63.86 cubic centimeters (cm 3 ), and the cooling time is 900 seconds.
九組結果顯示,利用本發明所提供的厚件透鏡之包覆式塑膠射出成型方法,即使各組的厚度T1、T2、T3不同,第一射與第二射的熔膠體積不同,第一射與第二射的冷卻時間不同,但是皆可大幅節省冷卻時間16~33%。例如,相較於單射所需的900秒,第6組冷卻時間為761秒,第7組冷卻時間為603秒,分別節省時間比例為16%(節省139秒)、33%(節省297秒)。且試驗結果顯示可提高成品品質,減少成品收縮、變型、包封。 Nine sets of results show that using the coating plastic injection molding method for thick lenses provided by the present invention, even if the thicknesses T1, T2, and T3 of each group are different, the volume of the first shot and the second shot are different, and the first shot The cooling time of shot and the second shot are different, but both can significantly save the cooling time by 16~33%. For example, compared to the 900 seconds required for a single shot, the cooling time of the sixth group is 761 seconds, and the cooling time of the seventh group is 603 seconds. The time saving ratio is 16% (saving 139 seconds) and 33% (saving 297 seconds) ). And the test results show that the quality of the finished product can be improved, and the shrinkage, deformation, and encapsulation of the finished product can be reduced.
關於冷卻時間的計算,係依據下列公式:
其中: among them:
t k :冷卻時間 d:厚度 T M :熔膠溫度 t k : cooling time d : thickness T M : melting temperature
T W :模具溫度 T D :脫模溫度 n:產品分層測出次數 T W : Mold temperature T D : Demold temperature n : Number of times of product delamination measurement
上述公式顯示,當厚度減少時,冷卻時間也隨之減少。 The above formula shows that when the thickness decreases, the cooling time also decreases.
以及,關於射出成型熱傳速率的計算,係依據下列公式:
其中: among them:
Q:熱傳速率 T m :熔膠溫度 T W :模具溫度 Q : Heat transfer rate T m : Melting temperature T W : Mold temperature
K I :塑料熱傳導係數 K II :模具熱傳導係數 K I : Plastic thermal conductivity coefficient K II : Mold thermal conductivity coefficient
h:熱對流係數 S:厚度 A I :產品表面積 h : heat convection coefficient S : thickness A I : product surface area
上述公式顯示,當分母的數值越小時,熱傳導速率也隨之升高。 The above formula shows that the smaller the value of the denominator, the higher the heat transfer rate.
綜上所述,本發明所提供之厚件透鏡之包覆式塑膠射出成型方法,針對厚件透鏡之熔膠流動特性與模具散熱效能設計包覆式射出成型方法,技術特徵包含塑料之分層厚度比例、支撐腳結構、澆口位置及其射出成型方式,確實可有效減少分次成型時因波前流動差異造成之包覆結合線與品質缺陷(例如翹曲、收縮、包封等)問題,並可透過降低各次射出熔膠的熱量,大幅縮短厚件透鏡之冷卻與生產時間。 In summary, the covered plastic injection molding method for thick lenses provided by the present invention is designed for the melt flow characteristics of thick lenses and the heat dissipation efficiency of the mold. The technical features include the layering of plastics. Thickness ratio, supporting foot structure, gate location and its injection molding method can indeed effectively reduce the coating bond line and quality defects (such as warpage, shrinkage, encapsulation, etc.) caused by the difference in wavefront flow during fractional molding And by reducing the heat of each injection of the melt, the cooling and production time of thick lenses can be greatly shortened.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field can make some changes and modifications without departing from the spirit and scope of the present invention. The scope of protection of the present invention shall be determined by the scope of the attached patent application.
100:厚件透鏡之包覆式塑膠射出成型方法之流程 100: Process of coating plastic injection molding method for thick lens
102、104:厚件透鏡之包覆式塑膠射出成型方法之流程之步驟 102, 104: Steps of the process flow of the thick lens covered plastic injection molding method
Claims (15)
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CN2568397Y (en) * | 2002-09-19 | 2003-08-27 | 鸿富锦精密工业(深圳)有限公司 | Multi-colour composite plastic ejecting making-up equipment |
CN1483565A (en) * | 2002-09-19 | 2004-03-24 | 鸿富锦精密工业(深圳)有限公司 | Multi-color plastic injection moulding equpment and method |
WO2015017929A1 (en) * | 2013-08-05 | 2015-02-12 | Dbm Reflex Enterprises Inc. | Injection molding device for thick lenses and method of manufacturing |
TWM519214U (en) * | 2015-09-23 | 2016-03-21 | 正能光電股份有限公司 | Beam control element |
WO2019164723A1 (en) * | 2018-02-20 | 2019-08-29 | Ticona Llc | Thermally conductive polymer composition |
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CN2568397Y (en) * | 2002-09-19 | 2003-08-27 | 鸿富锦精密工业(深圳)有限公司 | Multi-colour composite plastic ejecting making-up equipment |
CN1483565A (en) * | 2002-09-19 | 2004-03-24 | 鸿富锦精密工业(深圳)有限公司 | Multi-color plastic injection moulding equpment and method |
WO2015017929A1 (en) * | 2013-08-05 | 2015-02-12 | Dbm Reflex Enterprises Inc. | Injection molding device for thick lenses and method of manufacturing |
TWM519214U (en) * | 2015-09-23 | 2016-03-21 | 正能光電股份有限公司 | Beam control element |
WO2019164723A1 (en) * | 2018-02-20 | 2019-08-29 | Ticona Llc | Thermally conductive polymer composition |
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