TWI708929B - Pressure sensor with a grid structure - Google Patents

Pressure sensor with a grid structure Download PDF

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TWI708929B
TWI708929B TW108126781A TW108126781A TWI708929B TW I708929 B TWI708929 B TW I708929B TW 108126781 A TW108126781 A TW 108126781A TW 108126781 A TW108126781 A TW 108126781A TW I708929 B TWI708929 B TW I708929B
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layer
grid structure
sensing
pressure sensor
sensing layer
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TW202104859A (en
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潘正堂
莊承鑫
李大輝
顏仲崑
王紹宇
孫培原
翁子瑋
劉昭志
李浩然
洪國峻
戴詠旋
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國立中山大學
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Abstract

A pressure sensor with a grid structure is provided to improve upon the high cost of the conventional pressure sensor resulting from the multi-layered structure which leads to a high manufacturing cost. The pressure sensor includes a protective layer, a sensing layer coupled with a surface of the protective layer and including a grid structure formed by a plurality of threads interlacing in both the longitudinal and transverse directions, a conductive layer including an electrode area electrically connected to two ports and abutting the grid structure of the sensing layer, and a flexible substrate covering one face of the conductive layer facing away from the sensing layer. Each of the plurality of threads has a width. Two adjacent threads are spaced from each other at a distance. The protective layer and the sensing layer are stacked with each other at a height.

Description

具網格結構之壓力感測器Pressure sensor with grid structure

本發明係關於一種電子感測裝置,尤其是一種結構簡單的具網格結構之壓力感測器。The present invention relates to an electronic sensing device, especially a pressure sensor with a grid structure with a simple structure.

柔韌、薄型、具延展性且可以彎曲折疊的壓力感測器,係廣泛應用於穿戴裝置及各種軟性電子(Flexible Electronics)產品,該壓力感測器可以依據所承受之外力產生相對應的電性訊號,因此,藉由分析該電性訊號的生成位置及讀值變化,係可以得知外力作用的狀況。Flexible, thin, malleable and foldable pressure sensor, widely used in wearable devices and various flexible electronics (Flexible Electronics) products, the pressure sensor can generate corresponding electrical properties according to the external force Therefore, by analyzing the generation position and reading change of the electrical signal, the status of the external force can be known.

上述習知的壓力感測器可以分別透過電容、壓阻效應及壓電效應等機制進行感測,習知的壓力感測器係由柔性基底、導電材料、半導體及奈米碳管等不同材質及功能特性的元件疊合為多層結構,惟,為了兼顧感測靈敏度及薄型化需求,習知的壓力感測器需通過材料開發及繁複的製程,在有限厚度下組合多層結構並維持感測性能,係導致習知壓力感測器的製造成本增加。The above-mentioned conventional pressure sensors can sense through mechanisms such as capacitance, piezoresistive effect, and piezoelectric effect. The conventional pressure sensors are made of different materials such as flexible substrates, conductive materials, semiconductors, and carbon nanotubes. The components with functional characteristics are laminated into a multi-layer structure. However, in order to take into account the requirements of sensing sensitivity and thinness, the conventional pressure sensor requires material development and complicated manufacturing processes to combine the multi-layer structure with limited thickness and maintain the sensing The performance results in an increase in the manufacturing cost of the conventional pressure sensor.

有鑑於此,習知的壓力感測器確實仍有加以改善之必要。In view of this, the conventional pressure sensor does still need to be improved.

為解決上述問題,本發明的目的是提供一種具網格結構之壓力感測器,具有簡單結構係可以簡化製程,而降低製造成本。In order to solve the above problems, the object of the present invention is to provide a pressure sensor with a grid structure, which has a simple structure to simplify the manufacturing process and reduce the manufacturing cost.

本發明的次一目的是提供一種具網格結構之壓力感測器,係可以提升壓力感測靈敏度,及選擇壓力感測範圍,應用於不同的感測需求。The second objective of the present invention is to provide a pressure sensor with a grid structure, which can improve the pressure sensing sensitivity and select the pressure sensing range to be applied to different sensing requirements.

本發明的又一目的是提供一種具網格結構之壓力感測器,將感測材料集中於感測表面,係可以降低材料成本。Another object of the present invention is to provide a pressure sensor with a grid structure that concentrates the sensing material on the sensing surface, which can reduce the material cost.

本發明全文所記載的元件及構件使用「一」或「一個」之量詞,僅是為了方便使用且提供本發明範圍的通常意義;於本發明中應被解讀為包括一個或至少一個,且單一的概念也包括複數的情況,除非其明顯意指其他意思。The elements and components described in the full text of the present invention use the quantifiers "one" or "one" for convenience and to provide the general meaning of the scope of the present invention; the present invention should be interpreted as including one or at least one, and single The concept of also includes the plural, unless it clearly implies other meanings.

本發明全文所述「結合」、「組合」或「組裝」等近似用語,主要包含連接後仍可不破壞構件地分離,或是連接後使構件不可分離等型態,係本領域中具有通常知識者可以依據欲相連之構件材質或組裝需求予以選擇者。The approximate terms such as "combination", "combination" or "assembly" mentioned in the full text of the present invention mainly include the types that can be separated without destroying the components after being connected, or the components can not be separated after being connected, which are common knowledge in the field Those can be selected based on the materials of the components to be connected or assembly requirements.

本發明的具網格結構之壓力感測器,包含:一保護層;一感測層,結合於該保護層之表面,該感測層由數個線條縱橫交錯形成的網格結構,各該線條的寬度係一線寬,相鄰二線條之間的距離係一線距,該保護層與該感測層疊加之高度為一厚度;一導電層,由一電極區分別導通二電連接埠,該電極區貼合於該感測層之網格結構;及一柔性基板,該柔性基板覆蓋該導電層相對於該感測層之另一側表面。The pressure sensor with a grid structure of the present invention includes: a protective layer; a sensing layer combined with the surface of the protective layer; the sensing layer is a grid structure formed by crisscrossing several lines, each The width of the line is a line width, and the distance between two adjacent lines is a line distance. The height of the protective layer and the sensing layer is a thickness; a conductive layer is connected to two electrical connection ports by an electrode area, the electrode The area is attached to the grid structure of the sensing layer; and a flexible substrate covering the other side surface of the conductive layer relative to the sensing layer.

據此,本發明的具網格結構之壓力感測器,藉由網格結構之感測層,係可以簡化多層結構並減少感測材料之用量,具有簡化製程及降低製造成本等功效,又,網格結構係可以增加受力的形變及阻值變化,還可以藉由改變網格結構的尺寸,調整壓力感測器的靈敏度、受力範圍及穩定性等感測能力,可適用於不同的壓力感測需求,係具有提升感測效能及增加應用範圍等功效。Accordingly, the pressure sensor with a grid structure of the present invention can simplify the multi-layer structure and reduce the amount of sensing materials through the sensor layer of the grid structure, and has the effects of simplifying the manufacturing process and reducing the manufacturing cost. , The grid structure can increase the deformation of the force and the change of the resistance value. It can also adjust the sensitivity, force range and stability of the pressure sensor by changing the size of the grid structure. It can be applied to different The pressure sensing requirement of the system has the functions of improving the sensing performance and increasing the application range.

其中,該保護層的材料是聚二甲基矽氧烷。如此,該保護層可以承受拉扯及彎折等外力作用及防止該感測層上的電性變化受到外界干擾,係具有保護感測層及提升壓力感測精確度的功效。Wherein, the material of the protective layer is polydimethylsiloxane. In this way, the protective layer can withstand external forces such as pulling and bending, and prevent electrical changes on the sensing layer from being interfered by the outside, which has the effect of protecting the sensing layer and improving the accuracy of pressure sensing.

其中,該感測層為經酸化學改質的多壁奈米碳管。如此,係可以簡化該感測層的製程,係具有降低製造成本的功效。Wherein, the sensing layer is a multi-walled carbon nanotube chemically modified by acid. In this way, the manufacturing process of the sensing layer can be simplified, and the manufacturing cost can be reduced.

其中,該電極區係指叉式結構。如此,指叉式電極係可以感應網格結構的任何微小變化,係具有提升壓力感測靈敏度的功效。Among them, the electrode area is a finger-like structure. In this way, the interdigitated electrode system can sense any small changes in the grid structure, and has the effect of improving the pressure sensing sensitivity.

其中,該柔性基板的材料是聚對苯二甲酸乙二酯。如此,該柔性基板係可以防潮、抗腐蝕及耐彎折,係具有保護感測層及導電層的功效。Wherein, the material of the flexible substrate is polyethylene terephthalate. In this way, the flexible substrate can be moisture-proof, corrosion-resistant, and bend-resistant, and has the effect of protecting the sensing layer and the conductive layer.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式,作詳細說明如下:In order to make the above and other objects, features and advantages of the present invention more comprehensible, the preferred embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings:

請參照第1圖所示,其係本發明具網格結構之壓力感測器的較佳實施例,係包含一保護層1、一感測層2、一導電層3及一柔性基板4,該感測層2位於該保護層1之表面,該導電層3結合該感測層2,使該感測層2夾於該保護層1及該導電層3之間,該柔性基板4係覆蓋該導電層3相對於該感測層2之另一側表面。Please refer to Figure 1, which is a preferred embodiment of the pressure sensor with a grid structure of the present invention, which includes a protective layer 1, a sensing layer 2, a conductive layer 3 and a flexible substrate 4. The sensing layer 2 is located on the surface of the protective layer 1, the conductive layer 3 is combined with the sensing layer 2, so that the sensing layer 2 is sandwiched between the protective layer 1 and the conductive layer 3, and the flexible substrate 4 covers The conductive layer 3 is opposite to the other side surface of the sensing layer 2.

請參照第1圖所示,該保護層1較佳具有高堅韌性及絕緣性,使該保護層1可以承受拉扯及彎折等外力作用,該保護層1還可以防止該感測層2上的電性變化受到外界干擾,在本實施例中,該保護層1的材料是聚二甲基矽氧烷(Polydimethylsiloxane, PDMS),其材料成本低且製程快速,還可以使該保護層1容易在室溫與其他材料接合,且化學活性低而生物相容性良好,係適合應用於穿戴裝置中。Please refer to Figure 1, the protective layer 1 preferably has high toughness and insulation, so that the protective layer 1 can withstand external forces such as pulling and bending, the protective layer 1 can also prevent the sensing layer 2 The electrical changes of the protective layer 1 are interfered by the outside. In this embodiment, the material of the protective layer 1 is polydimethylsiloxane (PDMS), which has low material cost and fast manufacturing process, and can also make the protective layer 1 easy It is bonded to other materials at room temperature, has low chemical activity and good biocompatibility, and is suitable for use in wearable devices.

該感測層2結合於該保護層1之表面,使該感測層2可以隨該保護層1做各種彎曲折疊的變形,該感測層2較佳為高電導率之薄膜材料,在本實施例中,該感測層2為經酸化學改質的多壁奈米碳管(Multi-Walled Carbon Nanotubes, MWCNTs),係可以提升該感測層2的電性、簡化其製程及降低其材料成本,該感測層2還可以是單壁奈米碳管(Carbon Nanotube, CNT)、碳黑(Carbon Black)、石墨烯(Graphene)或其複合材料,本發明不以此為限。The sensing layer 2 is bonded to the surface of the protective layer 1, so that the sensing layer 2 can undergo various bending and folding deformations with the protective layer 1. The sensing layer 2 is preferably a high-conductivity thin film material. In an embodiment, the sensing layer 2 is a multi-walled carbon nanotubes (Multi-Walled Carbon Nanotubes, MWCNTs) chemically modified by acid, which can improve the electrical properties of the sensing layer 2, simplify its manufacturing process, and reduce its Material cost, the sensing layer 2 can also be a single-walled carbon nanotube (CNT), carbon black (carbon black), graphene (Graphene) or a composite material thereof, and the present invention is not limited thereto.

請參照第2圖所示,該感測層2係由數個線條縱橫交錯形成的網格結構,各該線條的寬度係一線寬W,相鄰二線條之間的距離係一線距S,該保護層1與該感測層2疊加之高度為一厚度D。Please refer to Figure 2, the sensing layer 2 is a grid structure formed by a number of lines crisscrossing each other, the width of each line is a line width W, the distance between two adjacent lines is a line distance S, the The overlapping height of the protective layer 1 and the sensing layer 2 is a thickness D.

請參照第1及3圖所示,該導電層3係由指叉式結構之一電極區31分別導通二電連接埠32,該電極區31係貼合於該感測層2之網格結構,係可以由該電極區31測量該感測層2的電阻值變化,並由該二電連接埠32輸出測量結果。Please refer to Figures 1 and 3, the conductive layer 3 is connected to two electrical connection ports 32 by an electrode region 31 of the interdigitated structure, and the electrode region 31 is attached to the grid structure of the sensing layer 2 , The electrode area 31 can measure the change in the resistance of the sensing layer 2 and the two electrical connection ports 32 can output the measurement result.

該柔性基板4較佳具有抗拉伸強度、耐磨性及電絕緣性,在本實施例中,該柔性基板4的材料是聚對苯二甲酸乙二酯(Polyethylene Terephthalate, PET),該柔性基板4係可以防止該導電層3上的訊號傳遞受到外界干擾,並具有防潮、抗腐蝕及耐彎折等作用。The flexible substrate 4 preferably has tensile strength, abrasion resistance, and electrical insulation. In this embodiment, the material of the flexible substrate 4 is polyethylene terephthalate (PET). The substrate 4 can prevent the signal transmission on the conductive layer 3 from being interfered by the outside, and has the functions of moisture resistance, corrosion resistance and bending resistance.

據由前述結構,當一外力作用於該保護層1及該感測層2時,該感測層2的電阻值產生變化,係可以藉由該導電層3測量一感測電壓,該感測電壓係對應該感測層2的電阻值變化,請參照第4~6圖所示,其係該感測電壓與該外力的關係圖,又,調整該線寬W、該線距S及該厚度D的規格,係可以觀察到不同趨勢之該感測電壓與該外力的關係圖。According to the aforementioned structure, when an external force acts on the protective layer 1 and the sensing layer 2, the resistance of the sensing layer 2 changes, and a sensing voltage can be measured by the conductive layer 3. The sensing The voltage corresponds to the change in the resistance value of the sensing layer 2. Please refer to Figures 4 to 6, which is the relationship between the sensing voltage and the external force. Also, adjust the line width W, the line distance S and the The thickness D specification can be observed in different trends of the relationship between the sensing voltage and the external force.

請參照第4圖所示,將該線寬W固定為1毫米及該厚度D固定為1毫米,而該線距S分別為1毫米、1.5毫米及2毫米的感測器,以0.5~10牛頓的外力做壓力感測,由關係圖可知,該線距S為1毫米及1.5毫米的感測器,測量到的感測電壓變化對外力變化的比值較大,係具有較佳的靈敏度,惟,感測電壓的變化對於7牛頓以上的外力較不明顯,導致感測器的穩定性差且適用的測量範圍較窄;該線距S為2毫米的感測器,測量到的感測電壓變化對外力變化的比值較小,但感測電壓的變化較穩定,係適用於大範圍的外力感測。Please refer to Figure 4, the line width W is fixed to 1 mm and the thickness D is fixed to 1 mm, and the line spacing S is respectively 1 mm, 1.5 mm, and 2 mm for the sensors, with 0.5~10 Newton’s external force is used for pressure sensing. It can be seen from the relationship diagram that the sensor with a line spacing S of 1 mm and 1.5 mm has a larger ratio of the measured sensing voltage change to the external force change, which has better sensitivity. However, the change of the sensing voltage is less obvious to the external force above 7 Newtons, resulting in poor stability of the sensor and a narrow applicable measurement range; the sensor with a line spacing S of 2 mm, the measured sensing voltage The ratio of change to external force change is small, but the change of sensing voltage is relatively stable, which is suitable for a wide range of external force sensing.

請參照第5圖所示,將該線寬W固定為1毫米及該線距S固定為1.5毫米,而該厚度D分別為1毫米及2毫米的感測器,以0.5~10牛頓的外力做壓力感測,由關係圖可知,該厚度D為1毫米的感測器相較於該厚度D為2毫米的感測器,測量到的感測電壓變化較穩定,具有較佳的穩定性。Please refer to Figure 5, the line width W is fixed to 1 mm and the line spacing S is fixed to 1.5 mm, and the thickness D is 1 mm and 2 mm, respectively, with an external force of 0.5~10 Newton For pressure sensing, it can be seen from the relationship graph that the sensor with a thickness D of 1 mm has a more stable sensing voltage change than a sensor with a thickness D of 2 mm, and has better stability .

請參照第6圖所示,將該線距S固定為1.5毫米及該厚度D固定為1毫米,而該線寬W分別為1毫米及2毫米的感測器,以0.5~10牛頓的外力做壓力感測,由關係圖可知,該線寬W為1毫米的感測器相較於該線寬W為2毫米的感測器,測量到的感測電壓變化較穩定,具有較佳的穩定性。Please refer to Figure 6, the line spacing S is fixed to 1.5 mm and the thickness D is fixed to 1 mm, and the line width W is 1 mm and 2 mm, respectively, with an external force of 0.5~10 Newton For pressure sensing, it can be seen from the relationship diagram that the sensor with a line width W of 1 mm has a more stable sensing voltage change than the sensor with a line width W of 2 mm, and has better stability.

綜上所述,本發明的具網格結構之壓力感測器,藉由網格結構之感測層,係可以簡化多層結構並減少感測材料之用量,具有簡化製程及降低製造成本等功效,又,網格結構係可以增加受力的形變及阻值變化,還可以藉由改變網格結構的尺寸,調整壓力感測器的靈敏度、受力範圍及穩定性等感測能力,可適用於不同的壓力感測需求,係具有提升感測效能及增加應用範圍等功效。In summary, the pressure sensor with a grid structure of the present invention can simplify the multi-layer structure and reduce the amount of sensing materials through the sensor layer of the grid structure, which has the effects of simplifying the manufacturing process and reducing the manufacturing cost. In addition, the grid structure can increase the deformation of the force and the change of the resistance value. It can also adjust the sensitivity, force range and stability of the pressure sensor by changing the size of the grid structure. For different pressure sensing needs, it has the functions of improving sensing performance and increasing application range.

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed using the above-mentioned preferred embodiments, it is not intended to limit the present invention. Anyone who is familiar with the art without departing from the spirit and scope of the present invention may make various changes and modifications relative to the above-mentioned embodiments. The technical scope of the invention is protected. Therefore, the scope of protection of the invention shall be subject to the scope of the attached patent application.

1:保護層 2:感測層 3:導電層 31:電極區 32:電連接埠 4:柔性基板 W:線寬 S:線距 D:厚度1: protective layer 2: Sensing layer 3: conductive layer 31: Electrode area 32: electrical connection port 4: Flexible substrate W: line width S: line spacing D: thickness

[第1圖] 本發明一較佳實施例的分解立體圖。 [第2圖] 本發明一較佳實施例的局部組合立體圖。 [第3圖] 本發明一較佳實施例的剖面圖。 [第4圖] 不同線距之感測器的感測電壓與外力的關係圖。 [第5圖] 不同厚度之感測器的感測電壓與外力的關係圖。 [第6圖] 不同線寬之感測器的感測電壓與外力的關係圖。 [Figure 1] An exploded perspective view of a preferred embodiment of the present invention. [Figure 2] A partially assembled perspective view of a preferred embodiment of the present invention. [Figure 3] A cross-sectional view of a preferred embodiment of the present invention. [Figure 4] The relationship between the sensing voltage and the external force of the sensors with different line distances. [Figure 5] The relationship between the sensing voltage and external force of sensors with different thicknesses. [Figure 6] The relationship between the sensing voltage and external force of sensors with different line widths.

1:保護層 1: protective layer

2:感測層 2: Sensing layer

3:導電層 3: conductive layer

31:電極區 31: Electrode area

32:電連接埠 32: electrical connection port

4:柔性基板 4: Flexible substrate

Claims (5)

一種具網格結構之壓力感測器,包含: 一保護層; 一感測層,結合於該保護層之表面,該感測層由數個線條縱橫交錯形成的網格結構,各該線條的寬度係一線寬,相鄰二線條之間的距離係一線距,該保護層與該感測層疊加之高度為一厚度; 一導電層,由一電極區分別導通二電連接埠,該電極區貼合於該感測層之網格結構;及 一柔性基板,該柔性基板覆蓋該導電層相對於該感測層之另一側表面。 A pressure sensor with a grid structure, including: A protective layer A sensing layer is combined with the surface of the protective layer. The sensing layer is formed by a grid structure of several lines crisscrossing each other. The width of each line is one line width, and the distance between two adjacent lines is one line pitch. The overlapping height of the protective layer and the sensing layer is a thickness; A conductive layer, two electrical connection ports are respectively connected by an electrode area, the electrode area is attached to the grid structure of the sensing layer; and A flexible substrate covering the other side surface of the conductive layer opposite to the sensing layer. 如申請專利範圍第1項所述之具網格結構之壓力感測器,其中,該保護層的材料是聚二甲基矽氧烷。The pressure sensor with a grid structure as described in item 1 of the scope of patent application, wherein the material of the protective layer is polydimethylsiloxane. 如申請專利範圍第1項所述之具網格結構之壓力感測器,其中,該感測層為經酸化學改質的多壁奈米碳管。The pressure sensor with a grid structure as described in item 1 of the scope of patent application, wherein the sensing layer is a multi-walled carbon nanotube that has been chemically modified by acid. 如申請專利範圍第1項所述之具網格結構之壓力感測器,其中,該電極區係指叉式結構。The pressure sensor with a grid structure as described in item 1 of the scope of patent application, wherein the electrode area is a finger structure. 如申請專利範圍第1項所述之具網格結構之壓力感測器,其中,該柔性基板的材料是聚對苯二甲酸乙二酯。The pressure sensor with a grid structure as described in item 1 of the scope of patent application, wherein the material of the flexible substrate is polyethylene terephthalate.
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CN102564657A (en) * 2012-01-16 2012-07-11 江苏物联网研究发展中心 Graphene-based array type flexible pressure distribution sensor and preparation method thereof
CN104949779A (en) * 2015-07-21 2015-09-30 中国科学技术大学 Pressure sensor and preparation method thereof
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CN109883583A (en) * 2019-03-28 2019-06-14 中国科学院长春应用化学研究所 A kind of elastomer thin film and preparation method thereof and the pliable pressure sensor comprising the elastomer thin film

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102564657A (en) * 2012-01-16 2012-07-11 江苏物联网研究发展中心 Graphene-based array type flexible pressure distribution sensor and preparation method thereof
CN104949779A (en) * 2015-07-21 2015-09-30 中国科学技术大学 Pressure sensor and preparation method thereof
CN106840483A (en) * 2017-03-31 2017-06-13 北京工业大学 Carbon nano-tube/poly aniline laminated film flexible force sensitive sensor and preparation method thereof
CN109883583A (en) * 2019-03-28 2019-06-14 中国科学院长春应用化学研究所 A kind of elastomer thin film and preparation method thereof and the pliable pressure sensor comprising the elastomer thin film

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