TWI679462B - Spacer for camera lens with reduced halo phenomenon and manufacturing method thereof - Google Patents

Spacer for camera lens with reduced halo phenomenon and manufacturing method thereof Download PDF

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Publication number
TWI679462B
TWI679462B TW107138020A TW107138020A TWI679462B TW I679462 B TWI679462 B TW I679462B TW 107138020 A TW107138020 A TW 107138020A TW 107138020 A TW107138020 A TW 107138020A TW I679462 B TWI679462 B TW I679462B
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coating
weight
parts
film substrate
spacer
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TW107138020A
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Chinese (zh)
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TW201937224A (en
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李承翰
Seunghan LEE
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南韓商可元有限公司
Kowon T&S Co., Ltd.
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B7/00Mountings, adjusting means, or light-tight connections, for optical elements
    • G02B7/02Mountings, adjusting means, or light-tight connections, for optical elements for lenses
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03BAPPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B11/00Filters or other obturators specially adapted for photographic purposes
    • G03B11/04Hoods or caps for eliminating unwanted light from lenses, viewfinders or focusing aids
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03BAPPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B17/00Details of cameras or camera bodies; Accessories therefor
    • G03B17/02Bodies
    • G03B17/12Bodies with means for supporting objectives, supplementary lenses, filters, masks, or turrets

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Lens Barrels (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Camera Bodies And Camera Details Or Accessories (AREA)

Abstract

本發明關於減少了光暈現象的相機透鏡用間隔件及其製造方法。該間隔件包含膜基材及塗覆在膜基材兩面的遮光層,遮光層包含底塗層和對於100重量份聚氨酯系黏結劑混合10~25重量份滑劑、3~5重量份黑色油性染料、200~300重量份有機溶劑而塗覆在底塗層表面的黑色塗層,貫穿膜基材和遮光層而形成中空部以使光向相機透鏡前進,誘發光暈現象的膜基材的中空部內側面藉由鹼性溶液經過了腐蝕處理。該間隔件的製造方法包含形成底塗層的第1次塗覆階段、形成黑色塗層的第2次塗覆階段、穿孔階段、使膜基材的中空部內側面腐蝕的腐蝕階段及乾燥階段。 The invention relates to a spacer for a camera lens with reduced halo phenomenon and a method for manufacturing the same. The spacer includes a film substrate and a light-shielding layer coated on both sides of the film substrate. The light-shielding layer includes an undercoat layer and a mixture of 10 to 25 parts by weight of a lubricant for 100 parts by weight of a polyurethane-based adhesive and 3 to 5 parts by weight of a black oiliness. A black coating applied on the surface of the undercoat layer with a dye, 200 to 300 parts by weight of an organic solvent, penetrates the film substrate and the light-shielding layer to form a hollow portion to advance the light to the camera lens, and induces a halo phenomenon. The inner surface of the hollow portion was subjected to an etching treatment with an alkaline solution. The manufacturing method of the spacer includes a first coating step for forming an undercoat layer, a second coating step for forming a black coating layer, a perforation step, an etching step for corroding the inner surface of a hollow portion of a film substrate, and a drying step.

Description

減少了光暈現象的相機透鏡用間隔件及其製造方法 Spacer for camera lens with reduced halo phenomenon and manufacturing method thereof

本發明關於減少了光暈(flare)現象的相機透鏡用間隔件及其製造方法。更詳細地,關於使膜基材的中空部內側面腐蝕而使光的反射最小化的減少了光暈現象的相機透鏡用間隔件及其製造方法。 The present invention relates to a spacer for a camera lens with reduced flare phenomenon and a method for manufacturing the same. More specifically, the present invention relates to a spacer for a camera lens and a method for manufacturing the same, which reduces the halo phenomenon by minimizing the reflection of light by corroding the inner surface of the hollow portion of the film substrate.

以將數位相機技術和手機技術融合了的新概念的手機,即所謂照相手機的普及為首,近年來在此混合了網路化功能的智慧手機變得大眾化。 Headed by the popularization of the so-called camera phone, a new concept that combines digital camera technology and mobile phone technology, smartphones that have network functions have become popular in recent years.

對於這樣的手機相機、緊湊式相機、攝像機等相機模組的小型化/輕量化正在持續性地進行,對此,主要由金屬製造的快門、光圈、間隔件等的遮光構件正被輕的高分子膜所代替。 The miniaturization and weight reduction of camera modules such as mobile phone cameras, compact cameras, and video cameras is being continuously carried out. In this regard, light-shielding members such as shutters, apertures, and spacers, which are mainly made of metal, are being made lighter. The molecular membrane is replaced.

在此,間隔件(Spacer)是為了維持多個透鏡間間隔及調節所有透鏡單元的解析度而將膜以甜甜圈形狀穿孔而製作的,也被稱為IRIS、MASK或遮光膜等。 Here, a spacer is made by donuting a film in the shape of a donut in order to maintain the interval between a plurality of lenses and adjust the resolution of all lens units. It is also called IRIS, MASK, or light-shielding film.

作為這樣的間隔件的一個例,在註冊專利第10-1592829號(“移動相機透鏡用導電性黑色膜”)中公開了將黑色材料塗覆在黑色膜基材的兩面上的間隔件,在公開專利第10-2017-0096661號(“相機透鏡單元用間隔件及該間隔件的製造方法”)中公開了在PET膜基材上形成用 於遮光的另外的塗層的方式的間隔件。 As an example of such a spacer, Registered Patent No. 10-1592829 ("Conductive Black Film for Mobile Camera Lens") discloses a spacer in which a black material is coated on both surfaces of a black film substrate. Japanese Laid-Open Patent No. 10-2017-0096661 ("A spacer for a camera lens unit and a method for manufacturing the spacer") discloses a method for forming on a PET film substrate. Spacer for additional coating mode for shading.

但是,使用這樣的塑膠材質的膜基材的間隔件在形成中空部的過程中,膜基材在中空部面上露出,因此存在產生如下光暈現象的問題:經由透鏡進入的光在膜基材的露出面被反射,在顯現於拍攝的圖像上的像太陽那樣的高輝度的物體周邊產生圓的輪廓,或者拍攝的圖像整體像起霧那樣模糊等。即,拍攝的圖像與用眼睛看到的完全不同。 However, when a spacer using such a film base material of plastic material is formed on the surface of the hollow portion in the process of forming the hollow portion, there is a problem that a halo phenomenon occurs as follows: light entering through the lens is on the film base The exposed surface of the material is reflected, and a round outline is generated around a high-luminance object such as the sun appearing on the captured image, or the captured image is blurred like fog as a whole. That is, the captured image is completely different from what you see with your eyes.

為了解決上述問題,公開專利第10-2017-0096661號公開了下述方法:藉由在膜基材進一步包含內面反射防止用珠,在加工間隔件的孔時顯露的中空部的截面上露出內面反射防止用珠,從而使光的反射最小化。但是,由於沒有包含面反射防止用珠的其餘區域無法避免光的反射,因此對防止光暈現象有限。 In order to solve the above-mentioned problem, Japanese Laid-Open Patent No. 10-2017-0096661 discloses a method in which a film substrate further includes beads for preventing internal reflections, and a cross section of a hollow portion exposed when a hole of a spacer is processed is exposed Beads for preventing internal reflections minimize the reflection of light. However, since the reflection of light cannot be avoided in the remaining areas that do not include the beads for preventing surface reflection, the prevention of halo is limited.

[先前技術文獻] [Prior technical literature]

[專利文獻] [Patent Literature]

專利文獻0001:大韓民國註冊專利第10-1592829號(2016年02月05日註冊公告,發明名稱:移動相機透鏡用導電性黑色膜)。 Patent Document 0001: Republic of Korea Registered Patent No. 10-1592829 (registered on February 05, 2016, Invention name: conductive black film for mobile camera lens).

專利文獻0002:大韓民國註冊專利第10-2017-0096661號(2017年08月25日公開公告,發明名稱:相機透鏡單元用間隔件及該間隔件的製造方法)。 Patent Document 0002: Republic of Korea Registered Patent No. 10-2017-0096661 (Published on August 25, 2017, Invention Name: Spacer for Camera Lens Unit and Method for Manufacturing the Spacer).

因此,本發明所欲解決的問題是解決上述先前技術的問題,提供能夠滿足遮光性、光澤除去性、黏接性等要求性能的全部,並能夠對誘發光暈現象的膜基材的中空部內側面集中地進行腐蝕處理的減少了光暈現象的相機透鏡用間隔件及其製造方法。 Therefore, the problem to be solved by the present invention is to solve the problems of the above-mentioned prior art, to provide all of the required performances such as light-shielding property, gloss-removing property, and adhesiveness, and to be able to fit inside the hollow portion of the film substrate that induces the halo phenomenon A spacer for a camera lens in which the side surface is collectively corroded and reduced in a halo phenomenon, and a method for manufacturing the same.

為了實現上述目的,本發明的一種減少了光暈現象的相機透鏡用間隔件的特徵在於,構成為包含塑膠材質的膜基材(100)及塗覆在上述膜基材的兩面的遮光層(200),上述遮光層(200)包含底塗層(210)和黑色塗層(220),上述底塗層(210)是為了提高上述膜基材(100)的表面的黏接力而第1次塗覆而成的,上述黑色塗層(220)是對於100重量份的聚氨酯系黏結劑混合10~25重量份的滑劑、3~5重量份的黑色油性染料、200~300重量份的有機溶劑而第2次塗覆在上述底塗層(210)的表面而成的,貫穿上述膜基材(100)及上述遮光層(200)而形成中空部(H)以使光向相機透鏡前進,誘發光暈現象的膜基材(100)的中空部內側面(H1)藉由鹼性溶液經過了腐蝕處理,上述滑劑是對於100重量份的由具有第1平均粒徑的粒子構成的第1滑劑混合150~250重量份的由具有大於上述第1平均粒徑的第2平均粒徑的粒子構成的第2滑劑的複合滑劑,在上述黑色塗 層(220)的表面形成有帶電塗層(230),上述帶電塗層(230)是將導電物質第3次塗覆而成的。 In order to achieve the above object, a spacer for a camera lens with reduced halation according to the present invention is characterized in that it comprises a film substrate (100) made of a plastic material and light-shielding layers (on both sides of the film substrate) 200). The light-shielding layer (200) includes an undercoat layer (210) and a black coating layer (220). The undercoat layer (210) is used for the first time to improve the adhesion of the surface of the film substrate (100). The black coating layer (220) is a mixture of 100 to 25 parts by weight of a polyurethane-based adhesive, 10 to 25 parts by weight of a lubricant, 3 to 5 parts by weight of a black oily dye, and 200 to 300 parts by weight of an organic compound. It is formed by coating the surface of the undercoat layer (210) for the second time with a solvent, penetrating the film substrate (100) and the light-shielding layer (200) to form a hollow portion (H) to advance the light toward the camera lens. The inner side surface (H1) of the hollow portion of the film substrate (100) that induces the halo phenomenon has been subjected to an etching treatment with an alkaline solution. The lubricant is the first to 100 parts by weight of particles having a first average particle size. One lubricant is composed of 150 to 250 parts by weight of particles having a second average particle diameter larger than the first average particle diameter. Compound 2 slip agent slip agent, in the black coating The surface of the layer (220) is formed with a charged coating layer (230), and the charged coating layer (230) is a third application of a conductive substance.

在本發明的減少了光暈現象的相機透鏡用間隔件中,上述鹼性溶液是在固定濃度的氫氧化鈉水溶液中以規定比率添加乙二胺(Ethylenediamine)而製成的,上述膜基材(100)是作為熱塑性塑膠的一種的PET(polyethylene terephthalate),藉由上述鹼性溶液,上述膜基材(100)比上述遮光層(200)腐蝕得更多。 In the spacer for a camera lens in which the halo phenomenon is reduced according to the present invention, the alkaline solution is prepared by adding ethylene diamine (Ethylenediamine) at a predetermined ratio to a fixed concentration sodium hydroxide aqueous solution, and the film substrate (100) is a polyethylene terephthalate (PET), which is a kind of thermoplastic plastic. With the alkaline solution, the film substrate (100) is corroded more than the light-shielding layer (200).

為了實現上述目的,本發明的減少了光暈現象的相機透鏡用間隔件的製造方法的特徵在於,包含以下階段:第1次塗覆階段(S1),在塑膠材質的膜基材(100)的兩面塗覆底塗液,形成底塗層(210);第2次塗覆階段(S2),將功能性塗料塗覆在上述底塗層的表面,形成黑色塗層(220),上述功能性塗料是對於100重量份的聚氨酯系黏結劑混合10~25重量份的滑劑、3~5重量份的黑色油性染料、200~300重量份的有機溶劑而成的;穿孔階段(S3),將經過了第2次塗覆的膜基材(100)以具有中空部(H)的間隔件形狀裁斷;腐蝕階段(S4),將裁斷的膜基材(100)在具有固定溫度的鹼性溶液中浸漬固定時間,使誘發光暈現象的上述膜基材(100)的中空部內側面(H1)腐蝕;以及乾燥階段(S5),用水將腐蝕了的膜基材(100)清洗,之後乾燥固定時間,在上述第1次塗覆階段(S1)中,上述膜基材(100)是作為熱塑性塑膠的一種的聚對苯二甲酸乙二酯(polyethylene terephthalate;PET),在上述第2次塗覆階段(S2)中,上述 滑劑是對於100重量份的由具有第1平均粒徑的粒子構成的第1滑劑混合150~250重量份的由具有大於上述第1平均粒徑的第2平均粒徑的粒子構成的第2滑劑的複合滑劑,還包含第3次塗覆階段(S6),其在上述第2次塗覆階段(S2)中進行,將導電性物質第3次塗覆在上述黑色塗層(220)的表面,形成帶電塗層(230),在上述腐蝕階段(S4)中,上述鹼性溶液是在固定濃度的氫氧化鈉水溶液中以規定比率添加乙二胺而製成的。 In order to achieve the above object, the method for manufacturing a spacer for a camera lens with reduced halation according to the present invention is characterized by including the following steps: a first coating step (S1), and a plastic film substrate (100) Primer coating solution is applied on both sides to form an undercoat layer (210); in the second coating stage (S2), a functional coating is applied to the surface of the above undercoat layer to form a black coating layer (220). Based on 100 parts by weight of a polyurethane-based adhesive, 10 to 25 parts by weight of a lubricant, 3 to 5 parts by weight of a black oily dye, and 200 to 300 parts by weight of an organic solvent are formed; the perforation stage (S3), The film substrate (100) after the second coating is cut in the shape of a spacer having a hollow portion (H); in the corrosion stage (S4), the cut film substrate (100) is alkaline at a fixed temperature Immersion in the solution for a fixed time to corrode the inside surface (H1) of the hollow portion of the film substrate (100) that induces the halo phenomenon; and in the drying stage (S5), the corroded film substrate (100) is washed with water and then dried For a fixed time, in the first coating step (S1), the film substrate (100) is used as a thermoplastic. A polyethylene terephthalate (polyethylene terephthalate; PET), is coated in the second time stage (S2), the aforementioned The lubricant is prepared by mixing 150 to 250 parts by weight of a first lubricant composed of particles having a first average particle diameter and 100 to parts by weight of particles having a second average particle diameter larger than the first average particle diameter. The two-lubricant composite lubricant further includes a third coating step (S6), which is performed in the second coating step (S2), and a conductive material is applied to the black coating (for the third time) 220), a charged coating layer (230) is formed on the surface, and in the above-mentioned corrosion stage (S4), the alkaline solution is prepared by adding ethylenediamine at a predetermined ratio in a fixed concentration sodium hydroxide aqueous solution.

根據本發明的減少了光暈現象的相機透鏡用間隔件及其製造方法,藉由使對光的反射脆弱的膜基材的中空部內側面向兩側彎曲地腐蝕,從而能夠獲得能夠提供顯著減少光暈現象的高品質的間隔件的效果。 According to the spacer for a camera lens and a method for manufacturing the same, in which the halo phenomenon is reduced, the inside of the hollow portion of the film substrate that is vulnerable to the reflection of light is curvedly corroded toward both sides, so that a significant reduction can be obtained. The effect of high-quality spacers with the halo phenomenon.

此外,本發明藉由使用能夠選擇性地腐蝕膜基材的特定鹼性溶液,從而具有能夠滿足遮光性、光澤除去性、黏接性等要求性能的全部,並有效地阻斷光暈現象的優點。 In addition, by using a specific alkaline solution that can selectively etch the film substrate, the present invention has all the properties that can meet the requirements of light shielding, gloss removal, adhesion, etc., and effectively blocks the halo phenomenon. advantage.

特別是,藉由在膜基材與黑色塗層之間形成底塗層,從而能夠在腐蝕過程中防止黑色塗層剝離,藉由使用複合滑劑,從而能夠以一種成分同時獲得兩種效果(滑動性和無光性)。 In particular, by forming an undercoat layer between the film substrate and the black coating layer, the black coating layer can be prevented from peeling off during the corrosion process, and by using a composite lubricant, two effects can be obtained with one component at the same time ( Sliding and matt).

100‧‧‧膜基材 100‧‧‧ film substrate

200‧‧‧遮光層 200‧‧‧ shading layer

210‧‧‧底塗層 210‧‧‧undercoat

220‧‧‧黑色塗層 220‧‧‧ black coating

230‧‧‧帶電塗層 230‧‧‧ charged coating

L‧‧‧光 L‧‧‧light

H‧‧‧中空部 H‧‧‧Hollow

H1‧‧‧中空部內側面 H1‧‧‧ Inner side of hollow section

圖1為概略地表示本發明的一個實施例的減少了光 暈現象的相機透鏡用間隔件的截面的圖。 FIG. 1 is a schematic view showing reduced light in an embodiment of the present invention. A cross-sectional view of a spacer for a camera lens with a halo phenomenon.

圖2為表示圖1的間隔件所包含的膜基材被鹼性溶液較嚴重地腐蝕的圖。 FIG. 2 is a view showing that the film substrate included in the spacer of FIG. 1 is severely corroded by an alkaline solution.

圖3為用於說明藉由圖1的間隔件而減少光暈現象的原理的圖。 FIG. 3 is a diagram for explaining a principle of reducing a halo phenomenon by the spacer of FIG. 1.

圖4為示意性表示本發明的一個實施例的減少了光暈現象的相機透鏡用間隔件的製造方法的流程圖。 FIG. 4 is a flowchart schematically showing a method of manufacturing a spacer for a camera lens with reduced halo phenomenon according to an embodiment of the present invention.

圖5為表示對本發明的一個實施例的間隔件的光暈測試結果進行比較的圖。 FIG. 5 is a diagram showing a comparison of a halo test result of a spacer according to an embodiment of the present invention.

以下,參照本發明的減少了光暈現象的相機透鏡用間隔件及其製造方法的實施例的圖式進行詳細說明。在對與本發明相關的公知的技術的說明判斷為使本發明的要旨不清楚的情況下,省略對公知技術的具體說明。 Hereinafter, the embodiment of the spacer for a camera lens and a method of manufacturing the same for reducing a halo phenomenon according to the present invention will be described in detail. When it is determined that the description of the known technology related to the present invention makes the gist of the present invention unclear, the detailed description of the known technology is omitted.

圖1為概略地表示本發明的一個實施例的減少了光暈現象的相機透鏡用間隔件的截面的圖,圖2為表示圖1的間隔件所包含的膜基材被鹼性溶液較嚴重地腐蝕的圖,圖3為用於說明藉由圖1的間隔件而減少光暈現象的原理的圖,圖4為示意性表示本發明的一個實施例的減少了光暈現象的相機透鏡用間隔件的製造方法的流程圖,圖5為表示對本發明的一個實施例的間隔件的光暈測試結果進行比較的圖。 FIG. 1 is a diagram schematically showing a cross section of a spacer for a camera lens in which the halo phenomenon is reduced according to an embodiment of the present invention. FIG. 2 is a diagram showing that a film substrate included in the spacer in FIG. FIG. 3 is a diagram for explaining the principle of reducing the halo phenomenon by the spacer of FIG. 1, and FIG. 4 is a schematic view showing a camera lens with reduced halo phenomenon according to an embodiment of the present invention. A flowchart of a method of manufacturing a spacer. FIG. 5 is a diagram showing a comparison of a halo test result of a spacer according to an embodiment of the present invention.

參照圖1至圖5,本發明的一個實施例的減少 了光暈現象的相機透鏡用間隔件藉由使膜基材的中空部內側面腐蝕,從而使光的反射最小化,上述間隔件構成為包含膜基材(100)和遮光層(200),該間隔件的製造方法包含第1次塗覆階段(S1)、第2次塗覆階段(S2)、穿孔階段(S3)、腐蝕階段(S4)和乾燥階段(S5)。 1 to 5, a reduction of one embodiment of the present invention The spacer for a camera lens with a halo phenomenon minimizes reflection of light by corroding the inner surface of the hollow portion of the film substrate. The spacer includes a film substrate (100) and a light-shielding layer (200). The manufacturing method of the spacer includes a first coating step (S1), a second coating step (S2), a piercing step (S3), a corrosion step (S4), and a drying step (S5).

為了不重複說明,將間隔件的構成及其對應的製造階段一起說明。 In order not to repeat the description, the configuration of the spacer and its corresponding manufacturing stages will be described together.

對於上述膜基材(100)而言,作為具有大約20~30μm厚度的薄膜形狀的材質,能夠使用透明、價格低廉且加工性優異的PET、PA、PC、PI、PMMA或TAC膜(tri-acetyl-cellulose film)等膜基材(100)的材料。 As for the film substrate (100), as a material having a film shape with a thickness of about 20 to 30 μm, a transparent, low-cost, and excellent processability PET, PA, PC, PI, PMMA, or TAC film (tri- Material of film substrate (100) such as acetyl-cellulose film.

膜基材(100)發揮使間隔件的重量降低、維持強度和剛性的作用。 The film substrate (100) functions to reduce the weight of the spacer and maintain strength and rigidity.

遮光層(200)為如圖1或圖5所示塗覆於膜基材(100)的兩面的層,構成為包含底塗層(210)和黑色塗層(220)。 The light-shielding layer (200) is a layer coated on both sides of the film substrate (100) as shown in FIG. 1 or FIG. 5, and is configured to include an undercoat layer (210) and a black coating layer (220).

首先,底塗層(210)藉由下述第1次塗覆階段(S1)而形成:將底塗液以大約1μm的厚度塗覆在膜基材(100)的兩面,形成底塗層(210)。 First, the undercoat layer (210) is formed by the following first coating step (S1): an undercoat liquid is applied to both sides of the film substrate (100) to a thickness of about 1 μm to form an undercoat layer ( 210).

PE、PP這樣的塑膠由於具有低的表面能,因此顯示特有的疏水性(低的潤濕性)。這樣的疏水性是使塑膠與黏接劑間的黏接力降低的要素,因此為了提高塗覆黏接力,需要事先提高塑膠表面的潤濕性。 PE, PP and other plastics have low surface energy and therefore exhibit unique hydrophobicity (low wettability). Such hydrophobicity is a factor that reduces the adhesion between the plastic and the adhesive. Therefore, in order to improve the adhesion of the coating, it is necessary to improve the wettability of the plastic surface in advance.

底塗液具有下述特性:與膜基材易於形成氫 鍵,由於分子大小小因此良好地滲入到多孔質的膜基材,在膜基材之間形成共價鍵。因此,底塗層(210)發揮使疏水性的膜基材(100)的表面與黑色塗層(220)間的結合力提高的黏接介質的作用。 The primer solution has the following characteristics: it is easy to form hydrogen with the film substrate Since the bonds have a small molecular size, they penetrate well into the porous film substrate, and form covalent bonds between the film substrates. Therefore, the undercoat layer (210) functions as an adhesive medium that improves the bonding force between the surface of the hydrophobic film substrate (100) and the black coating layer (220).

黑色塗層(220)為發揮選擇性地阻斷經由相機透鏡進入的光的作用的層。本實施例的黑色塗層(220)藉由將功能性塗料塗覆於底塗層(210)的表面的第2次塗覆階段(S2)而形成,上述功能性塗料是對於100重量份的聚氨酯系黏結劑混合10~25重量份的滑劑、3~5重量份的黑色油性染料、200~300重量份的有機溶劑而成的。 The black coating layer (220) is a layer that functions to selectively block light entering through the camera lens. The black coating layer (220) of this embodiment is formed by applying a functional coating on the surface of the undercoat layer (210) in the second coating step (S2). The functional coating is for 100 parts by weight. Polyurethane-based adhesives are made by mixing 10 to 25 parts by weight of a lubricant, 3 to 5 parts by weight of a black oily dye, and 200 to 300 parts by weight of an organic solvent.

黏結劑(液相的樹脂)除了發揮在底塗層(210)上形成具有強韌的物性(耐候性、耐蝕性、耐藥品性等)的塗膜的基本的作用以外,還發揮提供滑劑及黑色油性染料的分散性的作用。此時,作為用於防止在後述的腐蝕階段(S4)中的黑色塗層(220)剝離的黏接力強化手段,黏結劑較佳使用與底塗層(210)的化學性結構類似的聚氨酯系列。 The adhesive (liquid phase resin) plays a basic role in forming a coating film with strong physical properties (weather resistance, corrosion resistance, chemical resistance, etc.) on the undercoat layer (210), and also provides a lubricant. And the dispersibility of black oily dyes. At this time, as an adhesive force strengthening means for preventing peeling of the black coating layer (220) in the corrosion stage (S4) described later, it is preferable to use a polyurethane series similar to the chemical structure of the undercoat layer (210) as the adhesive. .

滑劑作為為了提供黑色塗層(220)表面的滑動性而添加的要素,能夠使用聚四氟乙烯(PTFE)、聚三氟氯乙烯(PCTFE)、聚偏氟乙烯(PVDF)、聚氟乙烯(PVF)、乙烯-四氟乙烯共聚物(ETFE)等。 The lubricant can be used as an element added to provide the blackness of the surface of the black coating (220). Polytetrafluoroethylene (PTFE), polytrifluorochloroethylene (PCTFE), polyvinylidene fluoride (PVDF), and polyvinyl fluoride can be used. (PVF), ethylene-tetrafluoroethylene copolymer (ETFE), and the like.

在此,滑劑能夠使用對於100重量份的由具有1~5μm的第1平均粒徑的粒子構成的第1滑劑混合150~250重量份的由具有大於第1平均粒徑的6~10μm的第2平均粒徑的粒子構成的第2滑劑的複合滑劑。 Here, the lubricant can be used by mixing 100 to 250 parts by weight of a first lubricant composed of particles having a first average particle diameter of 1 to 5 μm, and mixing 150 to 250 parts by weight of 6 to 10 μm having a larger average particle diameter. A second lubricant composed of particles of a second average particle size.

粒子小的第1滑劑分布在第2滑劑間,發揮賦予黑色塗層(220)的無光性(無光澤)的作用,粒子大的第2滑劑在黑色塗層(220)的表面部分地露出,發揮提供黑色塗層(220)的滑動性的作用。 The first lubricant having small particles is distributed between the second lubricants, and plays a role of imparting matteness (matte) to the black coating layer (220). The second lubricant having large particles is on the surface of the black coating layer (220). Partially exposed, it functions to provide the sliding properties of the black coating (220).

以100重量份的聚氨酯系黏結劑為基準,如果滑劑的含量小於10重量份,則滑動性會降低,如果滑劑的含量超過25重量份,則黏結劑的黏接性及剩餘成分的特性會降低。 Based on 100 parts by weight of a polyurethane-based adhesive, if the content of the lubricant is less than 10 parts by weight, the sliding properties will decrease. If the content of the lubricant exceeds 25 parts by weight, the adhesiveness of the adhesive and the characteristics of the remaining components will be reduced. Will decrease.

黑色油性染料作為油性染料系的著色劑,發揮對黑色塗層(220)賦予遮光性及黑色敏感性的作用。黑色油性染料為不溶於有機溶劑等介質的白色或有色的無機、有機化合物,是微粒狀態的染料,藉助黏結劑,微細地分散/著色,對黑色塗層(220)賦予美麗的色感。 The black oil-based dye, as an oil-based dye-based colorant, exerts a function of imparting light-shielding properties and black sensitivity to the black coating layer (220). Black oily dyes are white or colored inorganic and organic compounds that are insoluble in media such as organic solvents. They are particulate dyes. They are dispersed / colored finely with a binder to give a beautiful color to the black coating (220).

如果黑色油性染料的含量小於上述下限值,則黑色塗層(220)的遮光性及黑色敏感性會降低,如果超過上述上限值,則黏結劑的黏接性及剩餘成分的特性會降低。 If the content of the black oily dye is less than the above-mentioned lower limit value, the light-shielding property and black sensitivity of the black coating (220) will decrease. If it exceeds the above-mentioned upper limit value, the adhesiveness of the adhesive and the characteristics of the remaining components will decrease. .

揮發性強的有機溶劑(Solvent)用來調節功能性塗料的合適的黏度,塗覆後蒸發,不會殘留在塗膜中。如果有機溶劑的含量小於上述下限值,則由於功能性塗料的過度的黏度,塗覆品質會下降,如果有機溶劑的含量超過上述上限值,則黏結劑的黏接性及剩餘成分的特性會降低。 A highly volatile organic solvent (Solvent) is used to adjust the appropriate viscosity of the functional coating. It will evaporate after coating and will not remain in the coating film. If the content of the organic solvent is less than the above lower limit, the coating quality will decrease due to the excessive viscosity of the functional coating. If the content of the organic solvent exceeds the above upper limit, the adhesiveness of the adhesive and the characteristics of the remaining components Will decrease.

在上述第2次塗覆階段(S2)以後能夠進行第3次塗覆階段(S6)。第3次塗覆階段(S6)為為了防止產生於膜 的靜電而將導電性物質第3次塗覆在黑色塗層(220)的表面從而形成帶電塗層(230)的階段。 The third coating step (S6) can be performed after the second coating step (S2). The third coating stage (S6) is to prevent Step of applying a conductive substance to the surface of the black coating layer (220) for the third time to form a charged coating layer (230).

其後進行的穿孔階段(S3)為將包含膜基材(100)及遮光層(200)的膜以間隔件形狀裁斷的階段。在該階段中,貫穿形成中空部(H)以使光能夠向相機透鏡進行。 The subsequent perforation step (S3) is a step of cutting the film including the film base material (100) and the light-shielding layer (200) into a spacer shape. In this stage, a hollow portion (H) is formed so as to allow light to be directed toward the camera lens.

在該過程中,誘發光暈現象的膜基材(100)的中空部內側面(H1)露出,為了處理對圖像品質產生惡劣影響的中空部內側面(H1),進行腐蝕階段(S4)。 In this process, the inner surface (H1) of the hollow portion of the film substrate (100) that induces the halo phenomenon is exposed. In order to deal with the inner surface (H1) of the hollow portion that adversely affects the image quality, an etching step is performed (S4).

腐蝕階段(S4)為將以間隔件形狀裁斷的多個膜基材(100)在具有固定溫度的鹼性溶液中浸漬固定時間而使膜基材(100)的中空部內側面(H1)腐蝕的階段。 The corrosion stage (S4) is a process in which a plurality of film substrates (100) cut in the shape of a spacer are immersed in an alkaline solution having a fixed temperature for a fixed time to etch the inner side (H1) of the hollow portion of the film substrate (100). stage.

為了使成為光暈現象的直接原因的膜基材(100)的中空部內側面(H1)比遮光層(200)腐蝕得更多,上述鹼性溶液是在10~25%濃度的氫氧化鈉水溶液中以規定比率(較佳為10:1的比率)添加乙二胺(Ethylenediamine)而製成的。 In order to make the inner side (H1) of the hollow portion of the film substrate (100), which is a direct cause of the halo phenomenon, more corroded than the light-shielding layer (200), the above-mentioned alkaline solution is a 10-25% concentration sodium hydroxide aqueous solution. It is produced by adding ethylenediamine at a predetermined ratio (preferably a ratio of 10: 1).

膜基材(100)比遮光層(200)腐蝕得更多的原因推測為上述鹼性溶液集中地與比遮光層(200)空隙相對多、潤濕性低的膜基材(100)反應。 The reason why the film substrate (100) corrodes more than the light-shielding layer (200) is presumably that the above-mentioned alkaline solution concentratedly reacts with the film substrate (100) having relatively more voids than the light-shielding layer (200) and having low wettability.

此時,在氫氧化鈉水溶液的濃度比基準低、處理溫度為60℃以下或浸漬時間小於10分鐘的情況下,腐蝕不能高效進行,相反在氫氧化鈉水溶液的濃度比基準高、處理溫度為80℃以上或浸漬時間超過60分鐘的情況下,腐蝕過度進行,遮光層(200)的物性會降低,因此不較 佳。 At this time, when the concentration of the sodium hydroxide aqueous solution is lower than the reference, the treatment temperature is 60 ° C or lower, or the immersion time is less than 10 minutes, the corrosion cannot be performed efficiently. On the contrary, the concentration of the sodium hydroxide aqueous solution is higher than the reference and the processing temperature is When the temperature is above 80 ° C or the immersion time exceeds 60 minutes, the corrosion progresses excessively, and the physical properties of the light-shielding layer (200) are reduced. good.

如果,使用並不是像本實施例那樣能夠選擇性腐蝕的鹼性溶液的普通的鹼性溶液,則雖然膜基材(100)和遮光層(200)產生相似的腐蝕而防止光暈現象,但包含遮光性的剩餘的要求性能降低,因此不較佳。 If an ordinary alkaline solution that is not an alkaline solution capable of being selectively etched as in this embodiment is used, although the film substrate (100) and the light-shielding layer (200) cause similar corrosion to prevent the halo phenomenon, but The remaining required performance including light-shielding properties is reduced, which is not preferable.

藉由這樣的腐蝕階段(S4),膜基材(100)的中空部內側面(H1)如圖2所示向兩側彎曲地腐蝕,其表面經過了粗糙處理。 In this etching step (S4), the inner side surface (H1) of the hollow portion of the film base material (100) is corroded and curved to both sides as shown in FIG. 2, and the surface is roughened.

這樣的話,如圖3所示,經由透鏡進入的光(L)藉由被粗糙處理過的膜基材(100)的中空部內側面(H1)散射,從而光初次被阻斷。此外,中空部內側面(H1)以彎曲的形狀被腐蝕,因此,光的通路以無法反射的入射角碰撞到中空部內側面(H1)。因此,光不會向圖像感測器側前進,一部分光向其相反方向反射,從而不會產生光暈現象。 In this case, as shown in FIG. 3, the light (L) entering through the lens is scattered by the inner surface (H1) of the hollow portion of the film substrate (100) that has been roughened, and the light is blocked for the first time. In addition, the inner surface (H1) of the hollow portion is corroded in a curved shape, and therefore, the light path collides with the inner surface (H1) of the hollow portion at an incident angle at which reflection cannot be reflected. Therefore, the light does not advance toward the image sensor side, and a part of the light is reflected in the opposite direction, so that a halo phenomenon does not occur.

對於現有的間隔件而言,在中空部形成過程中露出的膜基材的中空部面不被蝕刻,因此頻繁產生如下光暈現象:由於在膜基材的露出面反射的光,圖像上產生圓的輪廓、圖像整體像起霧那樣模糊等。 In the conventional spacer, the surface of the hollow portion of the film base material exposed during the formation of the hollow portion is not etched, so the following halo phenomenon frequently occurs: due to the light reflected on the exposed surface of the film base material, A round outline is generated, and the entire image is blurred like fog.

本發明藉由使膜基材(100)的中空部內側面(H1)集中地腐蝕,從而能夠解決現有的光暈現象問題,由此能夠獲得能夠提供高品質的間隔件的效果。 According to the present invention, the inner surface (H1) of the hollow portion of the film base material (100) is collectively corroded, so that the existing halo phenomenon can be solved, and the effect of providing a high-quality spacer can be obtained.

腐蝕階段(S4)結束後,如圖4所示,進行用水清洗腐蝕了的膜基材(100),乾燥10分鐘至60分鐘的乾燥階段(S6),從而完成間隔件的製造。 After the etching step (S4) is completed, as shown in FIG. 4, the etched film substrate (100) is washed with water, and the drying step (S6) is performed for 10 to 60 minutes to complete the manufacture of the spacer.

總而言之,作為相機透鏡的輔助構件的間隔件基本上要求強的黏接性、耐磨損性、滑動性、遮光性、無光性、帶電性及防光暈現象能力。本發明藉由如下的緊密組合,滿足上述要求條件。 In short, the spacer as an auxiliary member of the camera lens basically requires strong adhesion, abrasion resistance, sliding property, light shielding property, matte property, electrification property, and ability to prevent halo phenomenon. The present invention satisfies the above-mentioned requirements by close combination as follows.

1)黏接性:底塗層,聚氨酯系黏結劑。 1) Adhesiveness: primer, polyurethane-based adhesive.

2)耐磨損性:聚氨酯系黏結劑,使用特定鹼性溶液。 2) Abrasion resistance: Polyurethane-based adhesives using specific alkaline solutions.

3)滑動性:第2滑劑,使用特定鹼性溶液。 3) Sliding property: The second lubricant is a specific alkaline solution.

4)遮光性:黑色油性染料。 4) Light-shielding property: black oily dye.

5)無光性:黑色油性染料,第1滑劑,使用特定鹼性溶液。 5) Matte: black oily dye, first lubricant, using specific alkaline solution.

6)帶電性:帶電塗層。 6) Chargeability: Charged coating.

7)防光暈現象能力:使膜基材向兩側彎曲地腐蝕,使用特定的鹼性溶液。 7) Ability to prevent halo phenomenon: The film substrate is corroded and bent to both sides, and a specific alkaline solution is used.

以下,對本發明的具體的實施例進行說明,對各評價項目的公認及自身評價結果進行說明。 Hereinafter, specific examples of the present invention will be described, and the recognition of each evaluation item and the results of self-evaluation will be described.

[實施例1] [Example 1]

1.首先,將聚氨酯系列的樹脂、異氰酸鹽系列的固化劑、阻礙固化劑和樹脂的激烈反應的緩固劑以固定比率進行混合,將其以500RPM左右的速度攪拌30分鐘以上,製成底塗液,將該底塗液第1次塗覆在厚度為0.25μm的PET膜基材上。 1. First, the polyurethane series resin, the isocyanate series curing agent, the retarder that hinders the intense reaction between the curing agent and the resin are mixed at a fixed ratio, and they are stirred at a speed of about 500 RPM for more than 30 minutes to prepare A primer solution was prepared, and the primer solution was applied to a PET film substrate having a thickness of 0.25 μm for the first time.

此時,就塗覆方法而言,作為填充在網輥的網眼空隙的溶液轉印到膜上而被塗覆的方式,利用能夠塗覆1μm以下的薄膜、厚度偏差相對小的微型凹版塗覆法 (Micro Gavure Coating)。在本實施例中使用Media Engineering公司製作的M200 Mesh。 At this time, as for the coating method, as a solution filled in the mesh voids of the screen roll is transferred onto the film and applied, a micro gravure coating capable of coating a film of 1 μm or less with relatively small thickness deviation is used. Overlay (Micro Gavure Coating). In this embodiment, M200 Mesh manufactured by Media Engineering is used.

2.接著,藉由微型凹版塗覆法,將功能性塗料以4μm左右第2次塗覆在底塗層的表面,形成黑色塗層(220),上述功能性塗料是以100重量份的聚氨酯黏結劑為基準,對其混合15重量份的無定型滑劑、4重量份的黑色油性染料、250重量份的有機溶劑而成的。在此,滑劑使用將具有5μm和10μm的不同平均粒徑的聚四氟乙烯(PTFE)以1:2的比率混合而成的滑劑,有機溶劑使用甲乙酮(MEK)。 2. Next, a functional coating was applied to the surface of the undercoat layer at a thickness of about 4 μm for a second time by a micro gravure coating method to form a black coating layer (220). The functional coating is 100 parts by weight of polyurethane. Based on the binder, 15 parts by weight of an amorphous lubricant, 4 parts by weight of a black oily dye, and 250 parts by weight of an organic solvent were mixed. Here, the lubricant is a lubricant obtained by mixing polytetrafluoroethylene (PTFE) having different average particle diameters of 5 μm and 10 μm at a ratio of 1: 2, and methyl ethyl ketone (MEK) is used as an organic solvent.

3.使用上述微型凹版塗覆法,將ENG Soft公司製作的CNT乳液系列的ING-45PJ溶液以0.1μm的厚度塗覆在黑色塗層(220)上,形成帶電塗層(230)。 3. Using the micro gravure coating method described above, the ING-45PJ solution of the CNT emulsion series made by ENG Soft was coated on the black coating (220) with a thickness of 0.1 μm to form a charged coating (230).

4.將塗覆的膜以具有中空部(H)的間隔件形狀裁斷,將其在70℃的鹼性溶液中浸漬20分鐘,上述鹼性溶液是在20%濃度的氫氧化鈉水溶液中以10:1的比率添加乙二胺(Ethylenediamine)而成的。 4. The coated film was cut in the shape of a spacer having a hollow portion (H), and it was immersed in an alkaline solution at 70 ° C for 20 minutes. The basic solution was a 20% strength sodium hydroxide aqueous solution. 10: 1 ratio is made by adding ethylene diamine (Ethylenediamine).

5.對腐蝕了的間隔件進行清洗及乾燥,完成間隔件的製造。 5. Wash and dry the corroded spacer to complete the manufacture of the spacer.

對於像這樣製作的間隔件的強的黏接性(表面粗糙度)、耐磨損性(表面電阻)、無光性(光澤度),如<附件1>所述委託國際公認試驗機關的韓國高分子試驗研究所(株),對產品是否滿足最小要求條件進行了測試。 For the strong adhesion (surface roughness), abrasion resistance (surface resistance), and matteness (gloss) of the spacers made in this way, Korea, which commissioned an internationally recognized test organization as described in <Annex 1> The Polymer Test Institute Co., Ltd. tested whether the product meets the minimum requirements.

結果能夠確認到:如下表所述,本實施例的間隔件的表面粗糙度0.435(μm)、表面電阻 2.33*10^7(Ω/sq)、光澤度0.3,其滿足最小要求條件。 As a result, it was confirmed that the surface roughness of the spacer of this example is 0.435 (μm) and the surface resistance are described in the following table. 2.33 * 10 ^ 7 (Ω / sq), gloss 0.3, which meets the minimum requirements.

此外,為了確認實施例1的間隔件的防光暈現象能力,進行了光暈測試。 In addition, in order to confirm the anti-halo phenomenon ability of the spacer of Example 1, a halo test was performed.

[比較例1] [Comparative Example 1]

1.~3.的階段與上述實施例1的1.~3.的階段同樣地進行,4.將塗覆的膜以具有中空部(H)的間隔件形狀裁斷,由此完成間隔件的製造。 The steps from 1. to 3. are performed in the same manner as the steps from 1. to 3. in the above-mentioned Example 1. 4. The coated film is cut into a spacer shape having a hollow portion (H), thereby completing the spacer. Manufacturing.

光暈測試以下述方式進行:將上述實施例1及上述比較例1的間隔件分別在三星電子Galaxy S7智慧手機模組上交替安裝,在暗室用LED照明照射強光,在各個角度進行實際拍攝,確認拍攝的圖像上是否出現光暈現象。 The halo test was performed in the following manner: The spacers of the above-mentioned Example 1 and the above-mentioned Comparative Example 1 were separately installed on a Samsung Galaxy S7 smartphone module, and LED light was used to illuminate the strong light in a dark room, and actual shooting was performed at various angles. To confirm whether halo appears on the captured image.

結果,如圖5左側所示,在安裝了實施例1的間隔件的智慧手機拍攝的圖像上,由於光向光源周邊以放射狀均勻地散開,所以沒有出現光暈現象,然而在安裝了比較例1的間隔件的智慧手機拍攝的圖像上,如右側所示,出現了不明的紫色部分,並且出現了明顯的、光向光源周邊無規地散開的光暈現象的一種即shower現象。由此可推測膜基材(100)的中空部內側面(H1)是否腐蝕會對光暈現象的產生造成直接的影響。 As a result, as shown on the left side of FIG. 5, in the image captured by the smartphone equipped with the spacer of Example 1, since the light spreads evenly to the periphery of the light source, there is no halo phenomenon. As shown on the right, an image taken by the smartphone of the spacer of Comparative Example 1 shows an unidentified purple portion, and a visible phenomenon of a halo phenomenon, in which light is scattered randomly around the light source, is shown. . From this, it can be inferred that whether the inner surface (H1) of the hollow portion of the film base material (100) is corroded will directly affect the occurrence of the halo phenomenon.

上述的本發明的減少了光暈現象的相機透鏡用間隔件及其製造方法藉由使對光的反射脆弱的膜基材的中空部內側面向兩側彎曲地腐蝕,從而能夠獲得能夠提供顯著減少光暈現象的高品質的間隔件的效果。 The above-mentioned spacer for a camera lens with reduced halo of the present invention and a method for manufacturing the same, by corroding the inside of the hollow portion of the film substrate that is vulnerable to the reflection of light to both sides, can obtain a significant reduction that can be provided. The effect of high-quality spacers with the halo phenomenon.

此外,本發明藉由使用能夠選擇性地腐蝕膜基材的特徵鹼性溶液,從而具有能夠滿足遮光性、光澤除去性、黏接性等要求性能的全部,並有效地阻斷光暈現象的優點。 In addition, by using a characteristic alkaline solution that can selectively etch a film substrate, the present invention has all of the required properties such as light shielding, gloss removal, and adhesion, and effectively blocks the halo phenomenon. advantage.

特別是,藉由在膜基材與黑色塗層之間形成底塗層,從而能夠在腐蝕過程中防止黑色塗層剝離,藉由使用複合滑劑,從而能夠以一種成分同時獲得兩種效果(滑動性和無光性)。 In particular, by forming an undercoat layer between the film substrate and the black coating layer, the black coating layer can be prevented from peeling off during the corrosion process, and by using a composite lubricant, two effects can be obtained with one component at the same time ( Sliding and matt).

本發明請求保護的範圍並不限定於上述實施例及變形例,在請求保護的範圍內能夠以多樣的形態的實施例來體現。在不脫離本發明請求保護的本發明的要旨的情況下,本案所屬技術領域中具有通常知識者能夠變形的各種範圍也包含在本發明的請求保護範圍內。 The scope of protection claimed by the present invention is not limited to the above-mentioned embodiments and modifications, and can be embodied in various forms of embodiments within the scope of protection claimed. Without departing from the gist of the present invention claimed by the present invention, various scopes that can be deformed by a person having ordinary knowledge in the technical field to which this application belongs are also included in the claimed scope of the present invention.

Claims (3)

一種減少了光暈現象的相機透鏡用間隔件,其構成為包含塑膠材質的膜基材(100)以及塗覆在前述膜基材的兩面的遮光層(200);前述遮光層(200)包含底塗層(210)和黑色塗層(220),前述底塗層(210)是為了提高前述膜基材(100)的表面的黏接力而第1次塗覆而成的,前述黑色塗層(220)是對於100重量份的聚氨酯系黏結劑混合10~25重量份的滑劑、3~5重量份的黑色油性染料、200~300重量份的有機溶劑而第2次塗覆在前述底塗層(210)的表面而成的;貫穿前述膜基材(100)和前述遮光層(200)而形成中空部(H)以使光向相機透鏡前進,誘發光暈現象的前述膜基材(100)的中空部內側面(H1)藉由鹼性溶液經過了腐蝕處理;前述滑劑是對於100重量份的由具有第1平均粒徑的粒子構成的第1滑劑混合150~250重量份的由具有大於前述第1平均粒徑的第2平均粒徑的粒子構成的第2滑劑的複合滑劑;在前述黑色塗層(220)的表面形成有帶電塗層(230),前述帶電塗層(230)是將導電性物質第3次塗覆而成的。A spacer for a camera lens with reduced halo, comprising a film substrate (100) made of a plastic material and light-shielding layers (200) coated on both sides of the film substrate; the light-shielding layer (200) includes The undercoat layer (210) and the black coating layer (220). The undercoat layer (210) is applied for the first time in order to improve the adhesion of the surface of the film substrate (100). The black coating layer (220) 100% by weight of a polyurethane-based adhesive is mixed with 10 to 25 parts by weight of a lubricant, 3 to 5 parts by weight of a black oily dye, and 200 to 300 parts by weight of an organic solvent. The surface of the coating (210); the film substrate (100) that penetrates the film substrate (100) and the light-shielding layer (200) to form a hollow portion (H) to advance the light to the camera lens and induce a halo phenomenon The inside surface (H1) of the hollow portion (H1) of (100) has been subjected to corrosion treatment with an alkaline solution; the lubricant is mixed with 150 to 250 parts by weight of 100 parts by weight of a first lubricant composed of particles having a first average particle diameter. A composite lubricant of a second lubricant composed of particles having a second average particle diameter larger than the first average particle diameter; A surface layer (220) is formed with a charged coating layer (230), the charged coating (230) is a third conductive material formed by coating. 如請求項1所記載之減少了光暈現象的相機透鏡用間隔件,其中,前述鹼性溶液是在固定濃度的氫氧化鈉水溶液中以規定比率添加乙二胺而製成的;前述膜基材(100)是作為熱塑性塑膠的一種的聚對苯二甲酸乙二酯(PET);藉由前述鹼性溶液,前述膜基材(100)比前述遮光層(200)腐蝕得更多。The spacer for a camera lens in which the halo phenomenon is reduced as described in claim 1, wherein the alkaline solution is prepared by adding ethylenediamine at a predetermined ratio in a fixed concentration sodium hydroxide aqueous solution; the film base The material (100) is polyethylene terephthalate (PET), which is a kind of thermoplastic plastic; with the aforementioned alkaline solution, the film substrate (100) is corroded more than the light-shielding layer (200). 一種減少了光暈現象的相機透鏡用間隔件的製造方法,包含以下階段:第1次塗覆階段(S1),在塑膠材質的膜基材(100)的兩面塗覆底塗液,形成底塗層(210);第2次塗覆階段(S2),將功能性塗料塗覆在前述底塗層的表面,形成黑色塗層(220),前述功能性塗料是對於100重量份的聚氨酯系黏結劑混合10~25重量份的滑劑、3~5重量份的黑色油性染料、200~300重量份的有機溶劑而成的;穿孔階段(S3),將經過了第2次塗覆的前述膜基材(100)以具有中空部(H)的間隔件形狀裁斷;腐蝕階段(S4),將裁斷的前述膜基材(100)在具有固定溫度的鹼性溶液中浸漬固定時間,使誘發光暈現象的前述膜基材(100)的中空部內側面(H1)腐蝕;以及乾燥階段(S5),用水清洗腐蝕了的前述膜基材(100),之後乾燥固定時間;在前述第1次塗覆階段(S1)中,前述膜基材(100)是作為熱塑性塑膠的一種的聚對苯二甲酸乙二酯(PET);在前述第2次塗覆階段(S2)中,前述滑劑是對於100重量份的由具有第1平均粒徑的粒子構成的第1滑劑混合150~250重量份的由具有大於前述第1平均粒徑的第2平均粒徑的粒子構成的第2滑劑的複合滑劑;前述製造方法還包含第3次塗覆階段(S6),其在前述第2次塗覆階段(S2)中進行,將導電性物質第3次塗覆在前述黑色塗層(220)的表面,形成帶電塗層(230);在前述腐蝕階段(S4)中,前述鹼性溶液是在固定濃度的氫氧化鈉水溶液中以規定比率添加乙二胺而製成的。A method for manufacturing a spacer for a camera lens with reduced halo, including the following steps: a first coating step (S1), applying a primer solution on both sides of a plastic film substrate (100) to form a primer Coating layer (210); in the second coating stage (S2), a functional coating is applied on the surface of the aforementioned undercoat layer to form a black coating layer (220). The aforementioned functional coating is based on 100 parts by weight of a polyurethane system. The binder is made by mixing 10 to 25 parts by weight of a lubricant, 3 to 5 parts by weight of a black oily dye, and 200 to 300 parts by weight of an organic solvent. The perforation stage (S3) is performed after the second coating. The film base material (100) is cut in the shape of a spacer having a hollow portion (H); in the corrosion stage (S4), the cut film base material (100) is dipped in an alkaline solution having a fixed temperature for a fixed time to induce the The inside surface (H1) of the hollow portion of the film base material (100) with a halo phenomenon is corroded; and in the drying stage (S5), the corroded film base material (100) is washed with water and then dried for a fixed time; in the first time In the coating stage (S1), the film substrate (100) is a poly (terephthalic acid) which is a kind of thermoplastic plastic. Diester (PET); in the second coating stage (S2), the lubricant is mixed with 150 to 250 parts by weight of 100 parts by weight of the first lubricant composed of particles having a first average particle size. A composite lubricant of a second lubricant composed of particles having a second average particle diameter larger than the first average particle diameter; the manufacturing method further includes a third coating step (S6), which is performed during the second coating. In the coating step (S2), a conductive substance is applied to the surface of the black coating layer (220) for the third time to form a charged coating layer (230). In the corrosion step (S4), the alkaline solution is It is prepared by adding ethylenediamine to a predetermined concentration of an aqueous sodium hydroxide solution at a predetermined ratio.
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