TWI650407B - Refractory lamella - Google Patents
Refractory lamella Download PDFInfo
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- TWI650407B TWI650407B TW103145268A TW103145268A TWI650407B TW I650407 B TWI650407 B TW I650407B TW 103145268 A TW103145268 A TW 103145268A TW 103145268 A TW103145268 A TW 103145268A TW I650407 B TWI650407 B TW I650407B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
- E04B1/941—Building elements specially adapted therefor
- E04B1/943—Building elements specially adapted therefor elongated
- E04B1/944—Building elements specially adapted therefor elongated covered with fire-proofing material
Abstract
在將至少包含金屬箔層的外裝材料層積層在由難燃性纖維材料所組成的隔熱材料層而形成的耐火披覆材中，為了抑止在金屬箔層產生顯眼的皺褶、或造成金屬箔層破裂之情事，至少會在金屬箔層實施凹凸賦形加工。 In the refractory coating material formed by laminating an exterior material containing at least a metal foil layer on a heat insulating material layer composed of a flame retardant fiber material, in order to suppress occurrence of conspicuous wrinkles or formation in the metal foil layer When the metal foil layer is broken, at least the concave and convex forming process is performed on the metal foil layer.
Description
本發明係關於一種為了提高鋼構造建築物等的耐火性而被利用的耐火披覆材。 The present invention relates to a refractory covering material that is utilized to improve the fire resistance of a steel structure building or the like.
鋼骨構造的建築物，在火災時當其鋼骨製的樑或柱曝露在高溫下，鋼構件會軟化而無法承受荷重以致於地板掉落、或牆壁倒塌，會有使建物崩壞的危險。因此，利用耐火性的隔熱材料對鋼構件的表面進行披覆來提高建物的耐火性能之技術為眾人所周知，例如，在H型鋼所組成的鋼柱等，如專利文獻1的第1圖所示，使石棉等所組成的耐火披覆材沿著H型鋼的形狀進行捲附。 In a steel-framed building, when a steel-made beam or column is exposed to high temperatures during a fire, the steel member will soften and cannot withstand the load so that the floor falls or the wall collapses, and there is a danger of building damage. . Therefore, a technique for coating the surface of a steel member with a fire-resistant heat insulating material to improve the fire resistance of the building is well known, for example, a steel column composed of an H-shaped steel, etc., as shown in Fig. 1 of Patent Document 1. As shown, the refractory covering material composed of asbestos or the like is wound along the shape of the H-shaped steel.
[專利文獻1]特開平10-152913號公報 [Patent Document 1] Japanese Patent Publication No. Hei 10-152913
然而，雖然專利文獻1揭示有一種將鋁箔積層在由石棉所組成的毛氈而形成的耐火披覆材，但在進行移送、及保管時將上述耐火披覆材捲繞成捲筒狀、或進行施工作業時使其沿著H型鋼等的鋼構件之形狀進行捲附時，會有在鋁箔產生顯眼的皺褶等而造成施工後的外觀變差之情事。特別是，沿著H型鋼的凸緣部的前端部分將耐火披覆材折彎來進行捲附的情況下，不僅會有造成鋁箔破裂之情事，並且在上述情況下也必須製備新的耐火披覆材來重新進行施工。 However, Patent Document 1 discloses a refractory covering material in which an aluminum foil is laminated on a felt composed of asbestos, but the refractory covering material is wound into a roll shape or carried out during transfer and storage. When the steel sheet is wound in the shape of a steel member such as an H-shaped steel during the construction work, there is a case where the aluminum foil is conspicuously wrinkled or the like, and the appearance after the construction is deteriorated. In particular, in the case where the refractory coating material is bent and wound along the front end portion of the flange portion of the H-shaped steel, not only the aluminum foil may be broken, but also a new refractory shawl must be prepared in the above case. Cover the material to re-construct.
本發明係有鑑於上述實情而開發完成者，其目的為：提供一種耐火披覆材，是在至少積層有包含金屬箔層的外裝材料層而形成的耐火披覆材中，能夠抑止在金屬箔層產生顯眼的皺褶、或造成金屬箔層破裂之情事。 The present invention has been developed in view of the above circumstances, and an object of the present invention is to provide a refractory covering material which is capable of suppressing metal in a refractory covering material formed by laminating at least an outer layer of a material containing a metal foil layer. The foil layer produces conspicuous wrinkles or ruptures of the metal foil layer.
本發明所揭示之耐火披覆材，係將至少包含金屬箔層的外裝材料層積層在由難燃性纖維材料所組成的隔熱材料層而形成之耐火披覆材，其構成為：至少在前述金屬箔層實施凹凸賦形加工。 The refractory covering material disclosed in the present invention is a refractory covering material formed by laminating an exterior material containing at least a metal foil layer on a heat insulating material layer composed of a flame retardant fiber material, and is configured to be at least The concave-convex forming process is performed on the metal foil layer.
本發明的耐火披覆材，在進行移送、及保管時將其捲繞成捲筒狀、或進行施工作業時使其捲附於H型綱等的鋼構件時，能夠抑止在金屬箔層產生顯眼的皺褶。 另外，在沿著H型鋼的凸緣部的前端部分將其折彎來進行捲附的情況下，會使形成在金屬箔層的凹凸形狀延伸也能夠抑止金屬箔層的破裂。 When the refractory coating material of the present invention is wound into a roll shape during transportation and storage, or when it is wound around a steel member such as an H-type metal during construction work, it is possible to suppress generation of a metal foil layer. Conspicuous wrinkles. Further, when the front end portion of the flange portion of the H-shaped steel is bent and wound, the uneven shape formed on the metal foil layer can be prevented from being broken by the metal foil layer.
1‧‧‧耐火披覆材 1‧‧‧Refractory mulch
2‧‧‧隔熱材料層 2‧‧‧Insulation material layer
3‧‧‧外裝材料層 3‧‧‧ Exterior material layer
4‧‧‧熱可塑性樹脂薄膜層 4‧‧‧ thermoplastic resin film layer
5‧‧‧金屬箔層 5‧‧‧metal foil layer
6‧‧‧不織布層 6‧‧‧Non-woven layer
第1圖係表示本發明的實施方式所揭示之耐火披覆材的一例之概略的剖面圖。 Fig. 1 is a schematic cross-sectional view showing an example of a refractory covering material according to an embodiment of the present invention.
第2圖係表示本發明的實施方式所揭示之耐火披覆材的其他例子之概略的剖面圖。 Fig. 2 is a schematic cross-sectional view showing another example of the refractory sheathing material disclosed in the embodiment of the present invention.
以下，參考圖式來說明關於本發明的實施方式。 Hereinafter, embodiments related to the present invention will be described with reference to the drawings.
第1圖及第2圖係表示本實施方式所揭示之耐火披覆材的概略之剖面圖，而耐火披覆材1係具有：將外裝材料層3積層在隔熱材料層2所組成的積層構造。 1 and 2 are schematic cross-sectional views showing a refractory covering material according to the present embodiment, and the refractory covering material 1 has a laminate of the exterior material layer 3 on the heat insulating material layer 2. Laminated structure.
隔熱材料層2係由難燃性纖維材料所組成，例如能夠使用石棉氈(rock wool felt)、陶瓷纖維氈(ceramic fiber felt)等。 The heat insulating material layer 2 is composed of a flame retardant fiber material, and for example, a rock wool felt, a ceramic fiber felt, or the like can be used.
作為石棉氈，其化學組成是包含：SiO2：30~55重量%，較佳為35~45重量%，CaO：10~35重量%，較佳為15~32重量%，Al2O3：5~25重量%，較佳為10~22重量%，MgO：3~15重量%，較佳為5~12重量%，FeO：3~15 重量%，較佳為4~12重量%，並且上述成分的含有量合計在90重量%以上，較佳為在93重量%以上。 As the asbestos felt, the chemical composition thereof comprises: SiO 2 : 30 to 55% by weight, preferably 35 to 45% by weight, CaO: 10 to 35% by weight, preferably 15 to 32% by weight, and Al 2 O 3 : 5 to 25% by weight, preferably 10 to 22% by weight, MgO: 3 to 15% by weight, preferably 5 to 12% by weight, FeO: 3 to 15% by weight, preferably 4 to 12% by weight, and The total content of the above components is 90% by weight or more, preferably 93% by weight or more.
上述石棉氈，係藉由調配高爐爐渣、轉爐爐渣、玄武岩、角閃岩、輝綠岩、矽石、白雲石、蠟石、長石、陶石等，再利用熔鐵爐對上述混合物加熱並且藉由轉子方式等的任意方式來使熔融後的熔融物纖維化，接著一邊吹送黏結劑(例如，酚樹脂等)一邊進行紡紗而積層為軟墊狀，之後再予以加熱使黏結劑硬化而能夠形成為上述化學組成，較佳是形成為體積密度在70~130kg/m3左右，並且厚度在20~65mm左右的氈狀。 The above asbestos felt is prepared by mixing blast furnace slag, converter slag, basalt, amphibolite, diabase, vermiculite, dolomite, wax stone, feldspar, pottery, etc., and then heating the mixture by using a molten iron furnace In any manner, such as a rotor method, the melted melt is fibrillated, and then a binder (for example, a phenol resin) is blown to form a cushion, and then heated to solidify the binder to form a molten material. The above chemical composition is preferably formed into a felt having a bulk density of about 70 to 130 kg/m 3 and a thickness of about 20 to 65 mm.
雖然本實施方式的耐火披覆材1係將外裝材料層3積層在由上述難燃性纖維材料所組成的隔熱材料層2，但外裝材料層3至少會包含金屬箔層5，其在第1圖及第2圖所示的實施例中，係作成為由熱可塑性樹脂薄膜層4/金屬箔層5/不織布層6所組成的三層構造。 In the refractory coating material 1 of the present embodiment, the exterior material layer 3 is laminated on the heat insulating material layer 2 composed of the flame retardant fiber material, but the exterior material layer 3 at least includes the metal foil layer 5 In the examples shown in Figs. 1 and 2, the three-layer structure composed of the thermoplastic resin film layer 4/metal foil layer 5/non-woven layer 6 is used.
熱可塑性樹脂薄膜層4係能夠使用例如：聚乙烯、聚丙烯、聚氯乙烯、聚偏二氯乙烯、聚對苯二甲酸乙二酯、乙烯-乙烯醇共聚物、聚乙烯醇、聚醯胺、聚丙烯酸、離子聚合物、纖維素、乙烯-醋酸乙烯共聚物、乙烯-甲基丙烯酸共聚物、聚苯乙烯等的熱可塑性樹脂所組成的薄膜。用於熱可塑性樹脂薄膜層4的薄膜較佳為：厚度在8~18μm，上述薄膜係柔軟且靭性高而不易破裂者為佳。 The thermoplastic resin film layer 4 can be, for example, polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride, polyethylene terephthalate, ethylene-vinyl alcohol copolymer, polyvinyl alcohol, polyamine. A film composed of a thermoplastic resin such as polyacrylic acid, an ionic polymer, cellulose, an ethylene-vinyl acetate copolymer, an ethylene-methacrylic acid copolymer, or a polystyrene. The film for the thermoplastic resin film layer 4 preferably has a thickness of 8 to 18 μm, and the film is soft and has high toughness and is not easily broken.
金屬箔層5係能夠使用例如：將鋁等的金屬 延展成厚度在5~10μm的金屬箔。藉由使外裝材料層3含有上述金屬箔層5能夠賦予耐火披覆材1不透過微粒子性、不透氣性等的各種機能。 The metal foil layer 5 can use, for example, a metal such as aluminum. Extends into a metal foil with a thickness of 5 to 10 μm. By including the metal foil layer 5 in the exterior material layer 3, the refractory coating material 1 can impart various functions such as impermeability, impermeability, and the like.
另外，不織布層6係能夠使用聚酯製、聚乙烯製、聚丙烯製等的不織布，並且其基重係在10~50g/m2為佳。 Further, the nonwoven fabric layer 6 may be a nonwoven fabric made of polyester, polyethylene or polypropylene, and preferably has a basis weight of 10 to 50 g/m 2 .
在將外裝材料層3積層在隔熱材料層2時，雖然亦可分別一層一層地依序將熱可塑性樹脂薄膜層4、金屬箔層5、不織布層6予以積層，但從生產性的觀點考量，藉由為公眾所知的層合技術對上述層進行積層來作成為層合薄片後，再將其接著在隔熱材料層2來進行積層為佳。當將上述層合薄片接著在隔熱材料層2來進行積層時，亦可是使不織布層6與隔熱材料層2呈對向，而將耐火披覆材1作成為從表面側依序對熱可塑性樹脂薄膜層4/金屬箔層5/不織布層6/隔熱材料層2進行積層而成的積層構造(參照第1圖)，或者是使熱可塑性樹脂薄膜層4與隔熱材料層2呈對向，而將耐火披覆材1作成為從表面側依序對不織布層6/金屬箔層5/熱可塑性樹脂薄膜層4/隔熱材料層2進行積層而成的積層構造亦可(參照第2圖)。 When the exterior material layer 3 is laminated on the heat insulating material layer 2, the thermoplastic resin film layer 4, the metal foil layer 5, and the non-woven layer 6 may be laminated one by one, but from the viewpoint of productivity. It is preferable to laminate the layers by laminating techniques known to the public to form a laminated sheet, and then to laminate the layers in the heat insulating material layer 2. When the laminated sheet is subsequently laminated on the heat insulating material layer 2, the nonwoven fabric layer 6 may be opposed to the heat insulating material layer 2, and the refractory covering material 1 may be sequentially heated from the surface side. The laminated structure of the plastic resin film layer 4 / the metal foil layer 5 / the nonwoven fabric layer 6 / the heat insulating material layer 2 is laminated (see Fig. 1), or the thermoplastic resin film layer 4 and the heat insulating material layer 2 are formed. In the opposite direction, the refractory coating material 1 may be a laminated structure in which the non-woven fabric layer 6 / the metal foil layer 5 / the thermoplastic resin film layer 4 / the heat insulating material layer 2 are sequentially laminated from the surface side (refer to Figure 2).
本實施方式中，係對積層在隔熱材料層2的外裝材料層3實施凹凸賦形加工。藉此，雖然利用凹凸賦形加工所形成之凹凸形狀在外裝材料層3的表面會形成為規則或不規則的圖案，但作為凹凸賦形加工也能夠例舉：壓花加工、折皺加工、表紋加工、粗糙化加工等。 In the present embodiment, the uneven material forming process is performed on the exterior material layer 3 laminated on the heat insulating material layer 2. Therefore, although the uneven shape formed by the embossing forming process is formed into a regular or irregular pattern on the surface of the exterior material layer 3, the embossing process, crease processing, and table can be exemplified as the embossing process. Pattern processing, roughening processing, etc.
又，在繪圖上係在第1圖及第2圖中省略凹凸形狀的圖式。 Moreover, in the drawing, the pattern of the uneven shape is omitted in the first drawing and the second drawing.
利用凹凸賦形加工所形成之凹凸形狀，在相鄰的凹部與凸部中，該凹部的最深部與該凸部的最頂部之平均高低差在0.01~0.5mm為佳，更佳為在0.01~0.2mm。 The concave-convex shape formed by the concave-convex forming process is preferably 0.01 to 0.5 mm, more preferably 0.01, in the adjacent concave portion and the convex portion, and the average height difference between the deepest portion of the concave portion and the top portion of the convex portion is 0.01 to 0.5 mm. ~0.2mm.
另外，雖然凹凸賦形加工係只要至少有對金屬箔層5實施即可，但考量加工時的操作較佳為：對用以形成外裝材料層3的層合薄片實施凹凸賦形加工，之後再將其積層在隔熱材料層2。在對用以形成外裝材料層3的層合薄片實施凹凸賦形加工的情況下，該層合薄片，其沿著任意方向的長度相較於實施凹凸賦形加工之前的狀態係收縮0.05~1.0%為佳，更佳為收縮0.1~0.3%。 Further, the embossing forming process may be performed on at least the metal foil layer 5, but it is preferable to perform the embossing process on the laminated sheet for forming the exterior material layer 3 after the processing in consideration of the processing. It is laminated on the heat insulating material layer 2. In the case where the laminated sheet for forming the exterior material layer 3 is subjected to the embossing forming process, the laminated sheet has a length in any direction which is 0.05 mm in comparison with the state before the embossing forming process is performed. 1.0% is better, and more preferably 0.1 to 0.3% shrinkage.
即使在為了藉由實施上述凹凸賦形加工來獲得被賦予不透過微粒子性、不透氣性等的各種機能之耐火披覆材1，而使外裝材料層3含有金屬箔層5的情況下，在進行移送、及保管時將耐火披覆材1捲繞成捲筒狀、或進行施工作業時使其捲附在H型鋼等的鋼構件時，也能夠抑止在金屬箔層5產生顯眼的皺褶。另外，在沿著H型鋼的凸緣部的前端部分將耐火披覆材1折彎來進行捲附的情況下，會使形成在金屬箔層5的凹凸形狀延伸而能夠抑止金屬箔層5的破裂。 In the case where the refractory coating material 1 having various functions such as impermeability, impermeability, and the like is obtained by performing the above-described embossing forming process, and the exterior material layer 3 contains the metal foil layer 5, When the refractory coating material 1 is wound into a roll shape during transportation and storage, or when it is wound around a steel member such as an H-section steel during construction work, it is possible to suppress occurrence of conspicuous wrinkles in the metal foil layer 5 Pleats. In addition, when the refractory coating material 1 is bent and wound along the tip end portion of the flange portion of the H-shaped steel, the uneven shape formed on the metal foil layer 5 is extended to suppress the metal foil layer 5 rupture.
並且，在將耐火披覆材1作成為從表面側依序對熱可塑性樹脂薄膜層4/金屬箔層5/不織布層6/隔熱材料層2進行積層而形成的積層構造之實施方式時，被積 層為與隔熱材料層2呈對向的不織布層6係會抑制隔熱材料層2的表面之難燃性纖維材料的震動，而能夠使得纖維或灰塵不會從隔熱材料層2脫離。另外，金屬箔層5係藉由其不透過微粒子性、不透氣性來防止因為用以形成隔熱材料層2的難燃性纖維材料所引起的微粒子或氣體(從黏結劑遊離的有機氣體等)朝向外部飛散、及擴散。又，積層在金屬箔層5上的熱可塑性樹脂薄膜層4係能夠提高預防金屬箔層5產生缺損之作業性，並且用以預防外部氣體從金屬箔層5的缺損處侵入所造成之凝結而能夠防止隔熱材料層2因為水分所造成的劣化。 In addition, when the refractory coating material 1 is an embodiment in which a laminated structure is formed by sequentially laminating the thermoplastic resin film layer 4 / the metal foil layer 5 / the nonwoven fabric layer 6 / the heat insulating material layer 2 from the surface side, Accumulated The non-woven fabric layer 6 whose layer faces the heat insulating material layer 2 suppresses the vibration of the flame-retardant fiber material on the surface of the heat insulating material layer 2, and can prevent the fibers or dust from being detached from the heat insulating material layer 2. Further, the metal foil layer 5 prevents microparticles or gases (organic gases free from the binder, etc.) caused by the flame retardant fiber material for forming the heat insulating material layer 2 by being impervious to microparticles and gas impermeability. ) scatters and spreads toward the outside. In addition, the thermoplastic resin film layer 4 laminated on the metal foil layer 5 can improve the workability of preventing the metal foil layer 5 from being defective, and can prevent the condensation of external air from the defect of the metal foil layer 5. It is possible to prevent deterioration of the heat insulating material layer 2 due to moisture.
以上，雖然針對本發明表示且說明了較佳的實施方式，但本發明並非限定於上述實施方式，當然能夠在本發明的申請專利範圍內對實施方式進行各種變更。 The present invention has been described with reference to the preferred embodiments of the invention, and the invention is not limited to the embodiments described above, and various modifications may be made without departing from the scope of the invention.
例如，雖然前述實施方式中，係例舉將由熱可塑性樹脂薄膜層4/金屬箔層5/不織布層6所組成的外裝材料層3積層在隔熱材料層2的其中一邊的面，但外裝材料層3只要至少包含金屬箔層5即可，並且亦可例如將其他的不織布層積層在隔熱材料層2的另一邊的面。再者，亦可作成為利用用以形成外裝材料層3的層合薄片的至少一部分的層來包覆隔熱材料層2，使得該層合薄片積層在隔熱材料層2的表裏兩面，本發明所揭示之之耐熱披覆材的積層構造並不限定於前述實施方式。 For example, in the above-described embodiment, the exterior material layer 3 composed of the thermoplastic resin film layer 4/metal foil layer 5/non-woven layer 6 is laminated on one side of the heat insulating material layer 2, but outside The material layer 3 may include at least the metal foil layer 5, and other non-woven fabric layers may be laminated on the other side of the heat insulating material layer 2, for example. Furthermore, the heat insulating material layer 2 may be coated with a layer of at least a portion of the laminated sheet for forming the exterior material layer 3 such that the laminated film is laminated on both sides of the heat insulating material layer 2, The laminated structure of the heat-resistant covering material disclosed in the present invention is not limited to the above embodiment.
本發明係一種能夠利用來作為用以提高鋼構造建築物等的耐火性之耐火披覆材。 The present invention is a refractory covering material which can be utilized as a fire resistance for improving a steel structure building or the like.
Claims (6)
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|---|---|---|---|
| ??PCT/JP2014/000181 | 2014-01-16 | ||
| PCT/JP2014/000181 WO2015107566A1 (en) | 2014-01-16 | 2014-01-16 | Refractory coating material |
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| TW201536902A TW201536902A (en) | 2015-10-01 |
| TWI650407B true TWI650407B (en) | 2019-02-11 |
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| TW103145268A TWI650407B (en) | 2014-01-16 | 2014-12-24 | Refractory lamella |
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| MY (1) | MY182162A (en) |
| SG (1) | SG11201605829YA (en) |
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| JP6307282B2 (en) * | 2014-01-17 | 2018-04-04 | 大成建設株式会社 | Fireproof coating structure |
| US9984794B1 (en) | 2017-11-28 | 2018-05-29 | Imae Industry Co., Ltd. | Refractory insulating sheet |
| CN209652653U (en) * | 2019-01-28 | 2019-11-19 | 昆山鸣朋纸业有限公司 | A kind of fire-retarded corrugated paper |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6067147A (en) * | 1983-09-21 | 1985-04-17 | 第一レ−ス株式会社 | Laminated material |
| CN202115020U (en) * | 2011-06-03 | 2012-01-18 | 常州市宏发纵横新材料科技股份有限公司 | Multi-axial reinforced thermoplastic composite plate with continuous fibers |
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| JPS58210233A (en) * | 1982-06-01 | 1983-12-07 | 凸版印刷株式会社 | Ceiling panel and production thereof |
| JPH0332642Y2 (en) * | 1985-11-13 | 1991-07-11 | ||
| JPH10152913A (en) * | 1996-11-21 | 1998-06-09 | Nichias Corp | Fire-resistant coating material |
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2014
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- 2014-01-16 MY MYPI2016702477A patent/MY182162A/en unknown
- 2014-01-16 JP JP2015557579A patent/JP6378212B2/en active Active
- 2014-01-16 WO PCT/JP2014/000181 patent/WO2015107566A1/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6067147A (en) * | 1983-09-21 | 1985-04-17 | 第一レ−ス株式会社 | Laminated material |
| CN202115020U (en) * | 2011-06-03 | 2012-01-18 | 常州市宏发纵横新材料科技股份有限公司 | Multi-axial reinforced thermoplastic composite plate with continuous fibers |
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| TW201536902A (en) | 2015-10-01 |
| WO2015107566A1 (en) | 2015-07-23 |
| SG11201605829YA (en) | 2016-08-30 |
| JPWO2015107566A1 (en) | 2017-03-23 |
| JP6378212B2 (en) | 2018-08-22 |
| MY182162A (en) | 2021-01-18 |
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