TWI649202B - Elastomeric film composite and manufacturing method thereof - Google Patents

Elastomeric film composite and manufacturing method thereof Download PDF

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TWI649202B
TWI649202B TW106116796A TW106116796A TWI649202B TW I649202 B TWI649202 B TW I649202B TW 106116796 A TW106116796 A TW 106116796A TW 106116796 A TW106116796 A TW 106116796A TW I649202 B TWI649202 B TW I649202B
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elastic
layer
surface layer
microporous
film composite
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TW106116796A
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TW201900397A (en
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邱正中
廖炳森
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衛普實業股份有限公司
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Abstract

本發明乃是一種彈性薄膜複合材料,其包含:至少一上表面層、至少一中間層及至少一下表面層;其特徵是利用各層材料表面相容性差異,以共押出製程或淋膜製程及延展程序製造,不經熱壓合程序即施予延展程序將層間表面間隙拉開,據以達成該彈性薄膜複合材料成為具衣料浮起般之表面結構。The present invention is an elastic film composite material comprising: at least one upper surface layer, at least one intermediate layer, and at least a lower surface layer; wherein the surface compatibility difference of each layer material is utilized to perform a co-extrusion process or a lamination process and The extension process is manufactured, and the interfacial surface gap is pulled apart without applying the thermal compression process, so as to achieve the surface structure of the elastic film composite material.

Description

彈性薄膜複合材料及其製造方法Elastic film composite material and manufacturing method thereof

本發明涉及用於個人衛生用品或覆蓋材料,尤應用於拋棄式衛生用品之彈性薄膜複合材料,其特徵是利用材料相容差異以延展程序將層間表面間隙拉開,具有無熱壓點結構提昇材料柔軟手感及易回收材料層間結構設計以降低廢料之特性。 The invention relates to an elastic film composite material for personal hygiene products or covering materials, in particular to disposable sanitary products, which is characterized in that the difference in material compatibility is used to extend the inter-layer surface gap by an extension procedure, and the structure has no hot pressing point structure. The soft feel of the material and the inter-layer structure of the easily recyclable material are designed to reduce the characteristics of the waste.

彈性薄膜複合材料主要使用彈性橡塑膠原料以押出製程製作不同外觀型態之彈性材料,以提供不同應用領域。彈性薄膜材料具回彈特性,能夠適應人體各種活動下之彈性變化,具有人體舒適性及合身固定可靠度,因此,尤其應用於個人衛生材料之彈性複合材料更是重要課題。 Elastomeric film composites mainly use elastic rubber and plastic materials to produce different elastic materials of different appearances to provide different application fields. The elastic film material has the resilient property, can adapt to the elastic changes under various activities of the human body, and has the human body comfort and the fixed reliability of the fit. Therefore, the elastic composite material especially applied to personal sanitary materials is an important subject.

先前技術針對彈性不織布研究,如中華民國專利公告號333569所揭露,係以熱及機械處理的一種製造縱橫向彈性不織布加工方法,係加工熱粘合的熱可塑性及一部份混合非熱可塑性不織布,以低拉伸率拉伸而達到增進布質柔軟度、舒適觸感及達成高度商業價值之彈性度,所製成的布極適用於必要使用柔軟度及伸縮性的不織布用途;處理後產生單方向的彈性,有兩種設計可以達到機械縱向或布寬橫向的彈性;而且幾乎是所有各種類的不織布,只要含有70%以上的熱可塑性纖維,均可應用此法處理而得柔軟度及伸縮彈性之效果。又如中華民國專利證書號I271455所揭露,一種彈性複合布材料,包含至少一不織 布,至少另一布料,以及彈性線的線帶,該線帶設在該不織布與該布料之間。該不織布與呈一預定圖案形式的另一布料熱熔接,而該彈性線係在張緊的狀態在選定的位置埋入該不織布與另一布料之間的熔接點。此複合材料可製造衛生物品,特別是尿布,包含尿褲。 The prior art is directed to the study of elastic nonwoven fabrics, as disclosed in the Republic of China Patent Publication No. 333569, which is a method for manufacturing longitudinal and transverse elastic nonwoven fabrics by thermal and mechanical processing, which is to process thermal bonding thermoplasticity and a part of mixed non-thermoplastic non-woven fabrics. Stretching at a low stretch rate to achieve a softness of fabric quality, a comfortable touch and a high degree of commercial value. The resulting fabric is extremely suitable for use in non-woven fabrics where softness and flexibility are required; Unidirectional elasticity, there are two designs that can achieve mechanical longitudinal or cloth width transverse elasticity; and almost all kinds of non-woven fabrics, as long as they contain more than 70% of thermoplastic fibers, can be applied to the softness and The effect of telescopic elasticity. As disclosed in the Republic of China Patent No. I271455, an elastic composite cloth material comprising at least one non-woven fabric a cloth, at least another cloth, and a tape of elastic threads disposed between the nonwoven fabric and the cloth. The nonwoven fabric is thermally welded to another fabric in the form of a predetermined pattern, and the elastic thread is embedded in the tensioned state at a selected location to join the fusion joint between the nonwoven fabric and the other fabric. This composite material can be used to make sanitary articles, particularly diapers, including diapers.

先前技術針對齒輪咬合形成表面凸起之方法研究,如中華民國專利證書號I282383所揭露,係將一以聚酯與聚烯烴心鞘型複合纖維所製成的複合纖維或完全採用聚酯纖維,於該毛圈纖維網層之底部,淋覆一層融熔的高分子薄膜,再利用相互喫合的齒輪壓合形成一毛氈不織布,其毛氈具有高抗壓縮性。 The prior art has studied the method of forming a surface protrusion by a gear bite. For example, as disclosed in the Republic of China Patent No. I282383, a composite fiber made of polyester and polyolefin core-sheath type composite fiber or completely made of polyester fiber is used. At the bottom of the loop fiber web layer, a layer of molten polymer film is sprayed, and then a felt non-woven fabric is formed by press-fitting with each other, and the felt has high compression resistance.

先前技術針對超音波接合區彈性不織布之製作方法研究,如中華民國專利證書號I405660所揭露,本發明係有關於包含其任一側已超音波性黏合至非織造織物之彈性薄膜的具有改良膨鬆性、改良柔軟性及手感並可提供較大的捲筒能力之彈性層合物,其中該等接合點具有一佔其等之總接合區之不超過約30%的平域接合區。先前技術需以超音波或熱點壓方式於膜或不織布表面壓出結合點或區域,再施以延伸程序,以結合點為固著點將非彈性材料拉延亦有人稱為活化製程,其結合點因為擠壓成壓合點,該位置緊實無彈性、低吸水性及手感硬等缺點,因此亟待改善。 The prior art is directed to a method for fabricating an elastic nonwoven fabric of an ultrasonic bonding region. As disclosed in the Republic of China Patent No. I405660, the present invention relates to an improved swelling comprising an elastic film which has been ultrasonically bonded to a nonwoven fabric on either side thereof. An elastic laminate that provides bulk, improved softness and feel and provides greater reelability, wherein the joints have a flat domain junction that does not exceed about 30% of the total joint area. In the prior art, it is necessary to press a bonding point or a region on the surface of a film or a non-woven fabric by ultrasonic or hot spot pressing, and then apply an extension procedure to draw the inelastic material with the bonding point as a fixing point, which is also called an activation process, and the bonding point thereof. Because it is extruded into a press-fit point, the position is tight, inelastic, low-absorbent, and hard to the touch, so it needs to be improved.

本創作之創作人從事薄膜複合材料產業工作多年,深知其彈性薄膜複合材料之製程簡化仍有不足之處須解,乃致力於發展彈性薄膜複合材料及其製程之開發。本發明乃是一種彈性薄膜複合材料,其包含:至少一上表面層、至少一中間層及至少一下表面層;其利用各層材料表面相容性差異,以共押出製程或淋膜製程及延展程序製造,不經熱壓合程序即施予延展程序將層間表面間隙 拉開,據以達成該彈性薄膜複合材料成為具衣料浮起般之表面結構。本發明具簡化製程及彈性特性有別於過去習知技藝具差異化,其新穎、進步及實用效益無誤。有關本創作所採用之技術、手段及其功效,茲舉一較佳實施例並配合圖式詳細說明於後,相信本創作上述之目的、構造及特徵,當可由之得一深入而具體的瞭解。 The creator of this creation has been working in the film composites industry for many years. He is well aware that there are still deficiencies in the process simplification of the elastic film composites. He is committed to the development of elastic film composites and their processes. The invention is an elastic film composite material comprising: at least one upper surface layer, at least one intermediate layer and at least a lower surface layer; wherein the surface compatibility difference of each layer material is used to co-extend the process or the lamination process and the extension process Manufacture, without the thermocompression procedure, the extension procedure is applied to the interlayer gap Pulling open, according to the elastic film composite material, the surface structure of the floating material is obtained. The invention has a simplified process and elastic characteristics which are different from the prior art, and the novelty, the progress and the practical benefit are correct. With regard to the techniques, means and functions of the present invention, a preferred embodiment is described in detail with reference to the drawings, and it is believed that the above objects, structures and features of the present invention can be obtained from an in-depth and specific understanding. .

1a‧‧‧未延展前彈性中間層微多孔/無孔薄膜複合材料 1a‧‧‧Pre-extended elastic intermediate layer microporous/non-porous film composite

1b‧‧‧延展後彈性中間層微多孔/無孔薄膜複合材料 1b‧‧‧Extended elastic intermediate layer microporous/non-porous film composite

101‧‧‧上表面層-未延展之非彈性微多孔/無孔薄膜 101‧‧‧Upper surface layer - unstretched inelastic microporous/non-porous film

102‧‧‧上表面層-延展之非彈性微多孔/無孔薄膜 102‧‧‧Upper surface layer-extended non-elastic microporous/non-porous film

201‧‧‧中間層-彈性微多孔/無孔薄膜 201‧‧‧Intermediate layer - elastic microporous / non-porous film

301‧‧‧下表面層-未延展之非彈性微多孔/無孔薄膜 301‧‧‧Under surface layer - unstretched inelastic microporous/non-porous film

302‧‧‧下表面層-延展之非彈性微多孔/無孔薄膜 302‧‧‧Under surface layer-extended non-elastic microporous/non-porous film

2a‧‧‧未延展前彈性下表面層微多孔/無孔薄膜複合材料 2a‧‧‧Unfabricated elastic lower surface layer microporous/non-porous film composite

2b‧‧‧延展後彈性下表面層微多孔/無孔薄膜複合材料 2b‧‧‧After extension of the elastic lower surface layer microporous/non-porous film composite

202‧‧‧中間層-未延展之非彈性微多孔/無孔薄膜 202‧‧‧Intermediate layer - unstretched inelastic microporous/non-porous film

203‧‧‧中間層-延展之非彈性微多孔/無孔薄膜 203‧‧‧Intermediate-extended non-elastic microporous/non-porous film

303‧‧‧下表面層-彈性微多孔/無孔薄膜 303‧‧‧ Lower surface layer - elastic microporous / non-porous film

3a‧‧‧破壞性延展後彈性中間層微多孔/無孔薄膜複合材料 3a‧‧‧Destructively stretched elastic intermediate layer microporous/non-porous film composite

3b‧‧‧破壞性延展後彈性下表面層微多孔/無孔薄膜複合材料 3b‧‧‧After destructive extension of the elastic lower surface layer microporous/non-porous film composite

304‧‧‧下表面層-破壞性延展之非彈性微多孔/無孔薄膜 304‧‧‧Under surface layer - destructively extended non-elastic microporous/non-porous film

204‧‧‧中間層-破壞性延展之非彈性微多孔/無孔薄膜 204‧‧‧Intermediate layer - destructively extended non-elastic microporous/non-porous film

4a‧‧‧未延展前彈性中間層不織布之微多孔/無孔薄膜複合材料 4a‧‧‧Microporous/non-porous film composites with non-woven elastic intermediate layers before stretching

4b‧‧‧延展後彈性中間層不織布之微多孔/無孔薄膜複合材料 4b‧‧‧Microporous/non-porous film composites with elastic intermediate layer non-woven after stretching

205‧‧‧中間層-彈性不織布 205‧‧‧Intermediate layer - elastic non-woven fabric

5a‧‧‧未延展前彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料 5a‧‧‧Microporous/non-porous film composites with non-elastic non-woven fabrics in the elastic intermediate layer and the lower layer before stretching

5b‧‧‧延展後彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料 5b‧‧‧Microporous/non-porous film composites with elastic intermediate layers and non-elastic non-woven fabrics

305‧‧‧下表面層-未延展之非彈性不織布 305‧‧‧Under surface layer - unstretched inelastic nonwoven

306‧‧‧下表面層-延展之非彈性不織布 306‧‧‧Under surface layer-extended non-elastic non-woven fabric

6a‧‧‧未延展前彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料 6a‧‧‧Microporous/non-porous film composites with non-elastic non-woven fabrics in front of the elastic intermediate layer and the upper and lower layers

6b‧‧‧延展後彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料 6b‧‧‧Microporous/non-porous film composites with elastic intermediate layer and upper and lower layers of non-elastic non-woven fabric

103‧‧‧上表面層-未延展之非彈性不織布 103‧‧‧Upper surface layer - unstretched non-elastic non-woven fabric

104‧‧‧上表面層-延展之非彈性不織布 104‧‧‧Upper surface layer - extended non-elastic non-woven fabric

7a‧‧‧未延展前彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料 7a‧‧‧Microporous/non-porous film composites with unfolded elastic underlayer and intermediate non-elastic nonwoven fabric

7b‧‧‧延展後彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料 7b‧‧‧Microporous/non-porous film composites with elastic underlayer and intermediate layer inelastic nonwoven

206‧‧‧中間層-未延展之非彈性不織布 206‧‧‧Intermediate layer - unstretched non-elastic non-woven fabric

207‧‧‧中間層-延展之非彈性不織布 207‧‧‧Intermediate layer - extended non-elastic non-woven fabric

8a‧‧‧未延展前彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材料 8a‧‧‧Microporous/non-porous film composites with unfolded elastic underlayer and upper surface inelastic nonwoven

8b‧‧‧延展後彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材料 8b‧‧‧Microporous/non-porous film composites with elastic underlayer and upper surface non-elastic nonwoven

9‧‧‧彈性中間層微多孔薄膜複合材料表面結構顯微鏡圖 9‧‧‧Microscopy of surface structure of elastic intermediate layer microporous film composites

9a‧‧‧層間表面間隙小之薄膜表面結構狀態 9a‧‧‧Surface surface structure state with small interfacial surface gap

9b‧‧‧層間表面間隙居中之薄膜表面結構狀態 9b‧‧‧The state of the film surface structure centered on the interfacial surface gap

9c‧‧‧層間表面間隙大之薄膜表面結構狀態 9c‧‧‧The state of the surface structure of the film with large surface gap between layers

第1圖係顯示本創作彈性中間層微多孔/無孔薄膜複合材料結構圖。 Fig. 1 is a structural view showing the microporous/non-porous film composite of the elastic intermediate layer of the present invention.

第2圖係顯示本創作彈性下表面層微多孔/無孔薄膜複合材料結構圖。 Fig. 2 is a structural view showing the microporous/non-porous film composite of the lower surface layer of the present invention.

第3圖係顯示本創作破壞性延展彈性微多孔/無孔薄膜複合材料示意圖。 Figure 3 is a schematic diagram showing the destructively stretched elastic microporous/non-porous film composite of the present invention.

第4圖係顯示本創作彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖。 Figure 4 is a structural view showing the microporous/non-porous film composite of the elastic intermediate layer and the non-elastic nonwoven fabric of the lower layer.

第5圖係顯示本創作彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖。 Figure 5 is a structural view showing the microporous/non-porous film composite of the elastic intermediate layer and the non-elastic nonwoven fabric of the lower layer.

第6圖係顯示本創作彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖。 Figure 6 is a structural view showing the microporous/non-porous film composite of the elastic intermediate layer and the upper and lower layers of the non-elastic nonwoven fabric.

第7圖係顯示本創作彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料結構圖。 Figure 7 is a structural view showing the microporous/non-porous film composite of the elastic top layer and the intermediate layer non-elastic nonwoven fabric.

第8圖係顯示本創作彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材 料結構圖。 Figure 8 shows the microporous/non-porous film composite of the elastic top layer and the upper surface non-elastic non-woven fabric. Material structure diagram.

第9圖係顯示本創作彈性中間層微多孔薄膜複合材料表面結構顯微鏡圖。 Fig. 9 is a micrograph showing the surface structure of the elastic intermediate layer microporous film composite of the present invention.

以下係藉由特定的具體實施例說明本創作之實施方式,熟習此技藝之人士可由本說明書所揭示之內容輕易地了解本創作之其他優點與功效。本創作亦可藉由其他不同的具體實施例加以施行或應用,本說明書中的各項細節亦可基於不同觀點與應用,在不悖離本創作之精神下進行各種修飾與變更。 The embodiments of the present invention are described below by way of specific embodiments, and those skilled in the art can readily appreciate other advantages and effects of the present invention from the disclosure herein. The present invention can also be implemented or applied by various other specific embodiments. The details of the present specification can also be modified and changed without departing from the spirit of the present invention.

首先敬請閱第1圖係顯示本創作彈性中間層微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性中間層微多孔/無孔薄膜複合材料1a,包含:上表面層-未延展之非彈性微多孔/無孔薄膜101,其與中間層之第一表面相鄰;中間層-彈性微多孔/無孔薄膜201,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-未延展之非彈性微多孔薄膜301。未延展前彈性中間層微多孔/無孔薄膜複合材料1a經延展程序後,其結構改變成延展後彈性中間層微多孔/無孔薄膜複合材料1b,延展後去除外部張力使中間層-彈性微多孔/無孔薄膜201回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及下表面層-延展之非彈性微多孔/無孔薄膜302,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。中間層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選用Hytrel(Polyester elastomer)、TPU(Thermoplastic Polyurethane)、SEBS(Styrene Ethylene Butylene Styrene)、SIS(Styrene Isoprene Styrene)、SBS(Styrene Butadiene Styrene)、彈性PP(Polypropylene Elastomer)、彈性PE(Polyethylene elastomer)、彈性Nylon(Polyamide Elastomer)或以上材料之混合體。上表面層或下表面層非彈性材料之型態為非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET(Polyester)、PP(Polypropylene)、PE(polyethylene)、PS(Polystyrene)、Nylon(Polyamide)或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP或PP材料之混合體為佳。又,上表面層、中間層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 First of all, please refer to Figure 1 for the structural diagram of the micro-porous/non-porous film composite of the elastic intermediate layer, showing the non-extended elastic intermediate layer microporous/non-porous film composite 1a, including: upper surface layer - unstretched a non-elastic microporous/non-porous film 101 adjacent to the first surface of the intermediate layer; an intermediate layer-elastic microporous/non-porous film 201 having a first surface and a second surface disposed on the upper surface and the lower surface Between the skin layers; and the lower surface layer - the non-stretched non-elastic microporous film 301. After the unexpanded elastic intermediate layer microporous/non-porous film composite 1a is extended, the structure is changed into a stretched elastic intermediate layer microporous/non-porous film composite 1b, and the external tension is removed after stretching to make the intermediate layer-elastic micro The porous/non-porous film 201 rebounds in a stable state without the elastic layer above the surface layer-extended non-elastic microporous/non-porous film 102 and the lower surface layer-extended non-elastic microporous/non-porous film 302, Then, it is stretched and deformed by the stretching force, and the surface compatibility difference of each layer material is utilized, and the interfacial surface gap is opened by the extension process without the thermal pressing process, and the upper surface layer and the intermediate layer are partially delaminated and the lower layer is The layer is partially delaminated from the intermediate layer, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material has a floating surface structure. The type of the intermediate layer elastic material is an elastic non-porous film, an elastic microporous film or an elastic perforated film, and Hytrel (Polyester elastomer) and TPU (Thermoplastic) may be selected. Polyurethane), SEBS (Styrene Ethylene Butylene Styrene), SIS (Styrene Butadiene Styrene), SBS (Styrene Butadiene Styrene), Elastic PP (Polypropylene Elastomer), Elastic PE (Polyethylene Elastomer), Elastic Nylon (Polyamide Elastomer) or a mixture of the above materials body. The non-elastic non-porous film of the upper surface layer or the lower surface layer is a non-elastic non-porous film, a non-elastic microporous film or a non-elastic perforated film may be selected from PET (Polyester), PP (Polypropylene), PE (polyethylene), PS ( Polystyrene), Nylon (Polyamide) or a mixture of the above materials. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP or PP materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer, the intermediate layer or the lower surface layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

第2圖係顯示本創作彈性下表面層微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性下表面層微多孔/無孔薄膜複合材料2a,包含:上表面層-未延展之非彈性微多孔/無孔薄膜101,其與中間層之第一表面相鄰;中間層-未延展之非彈性微多孔/無孔薄膜202,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-彈性微多孔/無孔薄膜303。未延展前彈性下表面層微多孔/無孔薄膜複合材料2a經延展程序後,其結構改變成延展後彈性下表面層微多孔/無孔薄膜複合材料2b,延展後去除外部張力使下表面層-彈性微多孔/無孔薄膜303回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及中間層-延展之非彈性微多孔/無孔薄膜203,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。下表面層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄 膜或彈性打孔膜,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。上表面層或中間層非彈性材料之型態為非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP、彈性PP或以上材料之混合體為佳。又,上表面層、中間層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Figure 2 is a structural diagram showing the micro-porous/non-porous film composite of the lower elastic layer of the present invention, illustrating the non-extended elastic lower surface layer microporous/non-porous film composite 2a, including: upper surface layer - unstretched An elastic microporous/non-porous film 101 adjacent to the first surface of the intermediate layer; an intermediate layer-unstretched non-elastic microporous/non-porous film 202 having a first surface and a second surface disposed on the upper surface layer Between the lower layer and the lower surface layer - an elastic microporous/non-porous film 303. After the unexpanded elastic lower surface layer microporous/non-porous film composite 2a is stretched, its structure is changed into a post-elastic elastic lower surface layer microporous/non-porous film composite 2b, and the outer tension is removed after stretching to lower the surface layer. - Elastic microporous/non-porous film 303 rebounds in a stable state without a resilience above the surface layer - extended non-elastic microporous / non-porous film 102 and intermediate layer - extended non-elastic microporous / non-porous film 203, which is stretched and deformed by the stretching force, and utilizes the difference in surface compatibility of the layers of the material, and the stretching process is performed to extend the interlayer gap without the thermal pressing process, and the upper surface layer and the intermediate layer are partially delaminated and The lower layer and the intermediate layer are partially delaminated, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material has a floating surface structure. The shape of the elastic material of the lower surface layer is an elastic non-porous film, elastic microporous thin For membrane or elastic perforated film, Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or a mixture of the above materials may be used. The non-elastic non-porous film of the upper surface layer or the intermediate layer may be a non-elastic non-porous film, a non-elastic microporous film or a non-elastic perforated film may be selected from a mixture of PET, PP, PE, PS, Nylon or the like. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP, elastic PP or the above materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer, the intermediate layer or the lower surface layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

為使審查委員更進一步了解本創作實際應用狀態,舉例破壞性延展之結構說明,如第3圖係顯示本創作破壞性延展彈性微多孔/無孔薄膜複合材料示意圖,說明破壞性延展後彈性中間層微多孔/無孔薄膜複合材料3a,經延展程序後其結構改變,延展後去除外部張力使中間層-彈性微多孔/無孔薄膜201回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及下表面層-破壞性延展之非彈性微多孔/無孔薄膜304,則受延展力而拉伸產生形變,其中下表面層-破壞性延展之非彈性微多孔/無孔薄膜304乃因內含低延伸率特性之材料,而產生破孔現。再者,破壞性延展後彈性下表面層微多孔/無孔薄膜複合材料3b,亦為經延展程序後其結構改變,延展後去除外部張力使下表面層-彈性微多孔/無孔薄膜303回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及中間層-破壞性延展之非彈性微多孔/無孔薄膜204,則受延展力而拉伸產生形變,其中中間層-破壞性延展之非彈性微多孔/無孔薄膜204乃因內含低延伸率特性之材料,而產生破孔現。並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,以致使該彈性薄膜複合材料成為具衣料浮起般之大凸起之表面結構。中間層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選 用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。表面層或中間層非彈性材料之型態為非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP、彈性PP或以上材料之混合體為佳。又,上表面層、中間層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 In order to make the review committee further understand the actual application state of the creation, for example, the structural description of the destructive extension, such as the third figure shows the schematic diagram of the destructively stretched elastic microporous/non-porous film composite material, indicating the elastic intermediate after the destructive extension. The layer microporous/non-porous film composite 3a has a structural change after the stretching process, and the external tension is removed after stretching to make the intermediate layer-elastic microporous/non-porous film 201 rebound in a stable state without the surface of the elastic upper surface. The layer-extended non-elastic microporous/non-porous film 102 and the lower surface layer-destructively stretched non-elastic microporous/non-porous film 304 are stretched and deformed by the stretching force, wherein the lower surface layer-destructive extension The non-elastic microporous/non-porous film 304 is formed by the inclusion of a material having a low elongation property. Furthermore, the destructively stretched elastic lower surface layer microporous/non-porous film composite 3b is also structurally changed after the elongation process, and the external tension is removed after stretching to make the lower surface layer-elastic microporous/non-porous film 303 back. The elastic state of the elastic, non-resilient upper surface layer-extended non-elastic microporous/non-porous film 102 and the intermediate layer-destructively extended non-elastic microporous/non-porous film 204 are stretched by the stretching force The deformation occurs in which the intermediate layer-destructively stretched non-elastic microporous/non-porous film 204 is created by the inclusion of a material having a low elongation property. And utilizing the difference in surface compatibility of each layer of material, the interfacial surface gap is pulled apart without applying a thermal pressing procedure, so that the elastic film composite material becomes a surface structure having a large convexity like a floating material. The type of the intermediate layer elastic material is an elastic non-porous film, an elastic microporous film or an elastic perforated film, which is optional A mixture of Hytrel, TPU, SEBS, SIS, SBS, elastomeric PP, elastomeric PE, elastomeric Nylon or the like. The non-elastic non-porous film of the surface layer or the intermediate layer may be a non-elastic non-porous film, a non-elastic microporous film or a non-elastic perforated film may be selected from a mixture of PET, PP, PE, PS, Nylon or the like. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP, elastic PP or the above materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer, the intermediate layer or the lower surface layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

另一實施例如第4圖係顯示本創作彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性中間層不織布之微多孔/無孔薄膜複合材料4a,包含:上表面層-未延展之非彈性微多孔/無孔薄膜101,其與中間層之第一表面相鄰;中間層-彈性不織布205,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-未延展之非彈性微多孔/無孔薄膜301。未延展前彈性中間層不織布之微多孔/無孔薄膜複合材料4a經延展程序後,其結構改變成延展後彈性中間層不織布之微多孔/無孔薄膜複合材料4b,延展後去除外部張力使中間層-彈性不織布205回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及下表面層-延展之非彈性微多孔/無孔薄膜302,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具衣料浮起般之薄膜表面結構。中間層彈性材料之型態為彈性不織布,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。表面層或下表面層非彈性材料之型態為非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選 用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP或PP材料之混合體為佳。又,上表面層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Another embodiment, for example, Fig. 4 is a structural view of a microporous/non-porous film composite material of the present elastic intermediate layer and the underlying layer non-elastic nonwoven fabric, illustrating the microporous/non-porous film composite material 4a of the elastic intermediate layer non-woven fabric before stretching. Comprising: an upper surface layer - an unstretched non-elastic microporous/non-porous film 101 adjacent to the first surface of the intermediate layer; an intermediate layer - an elastic nonwoven fabric 205 having a first surface and a second surface, disposed on Between the upper surface layer and the lower surface layer; and a lower surface layer - an unstretched non-elastic microporous/non-porous film 301. After the microporous/non-porous film composite 4a which is not stretched before the elastic intermediate layer is stretched, its structure is changed into a microporous/non-porous film composite 4b which is stretched after the elastic intermediate layer is not stretched, and the external tension is removed after stretching. The layer-elastic nonwoven fabric 205 rebounds in a stable state without the elastic layer above the surface layer-extended non-elastic microporous/non-porous film 102 and the lower surface layer-extended non-elastic microporous/non-porous film 302. Stretching and deformation by stretching force, and utilizing the difference in surface compatibility of each layer of material, the interfacial surface gap is opened by a stretching procedure without a thermocompression procedure, and the upper surface layer and the intermediate layer are partially delaminated and the lower layer is The intermediate layer exhibits partial delamination, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material becomes a film surface structure with a floating material. The type of the intermediate layer elastic material is an elastic non-woven fabric, and a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like may be selected. The surface layer or the lower surface layer is made of a non-elastic non-porous film, a non-elastic microporous film or an inelastic perforated film. Use a mixture of PET, PP, PE, PS, Nylon or a combination of the above. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP or PP materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer or the lower surface layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

第5圖係顯示本創作彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料5a,包含:上表面層-未延展之非彈性微多孔/無孔薄膜101,其與中間層之第一表面相鄰;中間層-彈性微多孔/無孔薄膜201,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-未延展之非彈性不織布305。未延展前彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料5a經延展程序後,其結構改變成延展後彈性中間層及下表層非彈性不織布之微多孔/無孔薄膜複合材料5b,延展後去除外部張力使中間層-彈性微多孔/無孔薄膜201回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及下表面層-延展之非彈性不織布306,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具一面衣料浮起般之薄膜表面結構及一面不織布之雙面效果。中間層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。表面層或下表面層非彈性材料之型態為不織布、非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP或PP材料之混合體為佳。 又,上表面層或中間層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Figure 5 is a structural diagram showing the microporous/non-porous film composite of the elastic intermediate layer and the non-elastic nonwoven fabric of the lower layer, showing the microporous/non-porous film composite of the elastic intermediate layer and the non-elastic nonwoven fabric before the extension. 5a, comprising: an upper surface layer-unstretched non-elastic microporous/non-porous film 101 adjacent to the first surface of the intermediate layer; an intermediate layer-elastic microporous/non-porous film 201 having a first surface and The second surface is disposed between the upper surface layer and the lower surface layer; and the lower surface layer - the non-stretched non-elastic non-woven fabric 305. The microporous/non-porous film composite 5a, which is not stretched before the elastic intermediate layer and the non-elastic non-woven fabric of the lower layer, is subjected to a stretching procedure, and its structure is changed into a microporous/nonporous film composite of the elastic intermediate layer and the non-elastic nonwoven fabric under the extension. The material 5b, after stretching, removes the external tension to cause the intermediate layer-elastic microporous/non-porous film 201 to rebound in a stable state without the elastic layer above the surface layer-extended non-elastic microporous/non-porous film 102 and the lower surface The layer-extended non-elastic non-woven fabric 306 is stretched and deformed by the stretching force, and the difference in surface compatibility of the materials of each layer is utilized, and the inter-layer surface gap is opened without the thermal pressing procedure, and the upper surface layer is opened. The intermediate layer is partially delaminated and the lower layer and the intermediate layer are partially delaminated, and the interlaminar surface gap size is 0.5-1000 micrometers, so that the elastic film composite material becomes a double-film surface structure and a non-woven fabric. Surface effect. The type of the intermediate layer elastic material is an elastic non-porous film, an elastic microporous film or an elastic perforated film, and a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like may be selected. The non-woven fabric, non-elastic non-porous film, non-elastic microporous film or inelastic perforated film of the surface layer or the lower surface layer may be selected from a mixture of PET, PP, PE, PS, Nylon or the like. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP or PP materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer or the intermediate layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

第6圖係顯示本創作彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料6a,包含:上表面層-未延展之非彈性不織布103,其與中間層之第一表面相鄰;中間層-彈性微多孔/無孔薄膜201,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-未延展之非彈性不織布305。未延展前彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料6a經延展程序後,其結構改變成延展後彈性中間層及上下表層非彈性不織布之微多孔/無孔薄膜複合材料6b,延展後去除外部張力使中間層-彈性微多孔/無孔薄膜201回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性不織布104及下表面層-延展之非彈性不織布306,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具雙面蓬鬆不織布之表面效果。中間層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。上表面層或下表面層非彈性材料之型態為不織布、可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP或PP材料之混合體為佳。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Figure 6 is a structural diagram showing the microporous/non-porous film composite of the elastic intermediate layer and the upper and lower layers of the non-elastic nonwoven fabric, illustrating the microporous/non-porous film composite material of the elastic intermediate layer and the upper and lower layers of the non-elastic nonwoven fabric before stretching. 6a, comprising: an upper surface layer - an unstretched non-elastic nonwoven fabric 103 adjacent to the first surface of the intermediate layer; an intermediate layer - an elastic microporous / non-porous film 201 having a first surface and a second surface, Between the upper surface layer and the lower surface layer; and the lower surface layer - the non-stretched non-elastic nonwoven fabric 305. The microporous/non-porous film composite 6a, which is not stretched before the elastic intermediate layer and the upper and lower layers of the non-elastic non-woven fabric, is subjected to a stretching procedure, and its structure is changed into a microporous/nonporous film composite of the elastic intermediate layer and the upper and lower layers of the non-elastic nonwoven fabric. Material 6b, after stretching, removes external tension so that the intermediate layer-elastic microporous/non-porous film 201 rebounds in a stable state without the elastic layer above the surface layer-extended non-elastic non-woven fabric 104 and the lower surface layer-extension The elastic non-woven fabric 306 is stretched and deformed by the stretching force, and the difference in surface compatibility of the materials of the respective layers is utilized, and the inter-layer surface gap is opened by the stretching procedure without the thermal pressing process, and the upper surface layer and the intermediate layer are partially removed. The layer and the lower layer and the intermediate layer are partially delaminated, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material has a surface effect of a double-sided fluffy non-woven fabric. The type of the intermediate layer elastic material is an elastic non-porous film, an elastic microporous film or an elastic perforated film, and a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like may be selected. The type of the upper surface layer or the lower surface layer non-elastic material is a non-woven fabric, and a mixture of PET, PP, PE, PS, Nylon or the like may be selected. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP or PP materials. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

第7圖係顯示本創作彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料結構圖,說明未延展前彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料7a,包含:上表面層-未延展之非彈性微多孔/無孔薄膜101,其與中間層之第一表面相鄰;中間層-未延展之非彈性不織布206,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-彈性微多孔/無孔薄膜303。未延展前彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料7a經延展程序後,其結構改變成延展後彈性下表層及中間層非彈性不織布之微多孔/無孔薄膜複合材料7b,延展後去除外部張力使下表面層-彈性微多孔/無孔薄膜303回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性微多孔/無孔薄膜102及中間層-延展之非彈性不織布207,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具衣料浮起般之大凸起表面結構。下表面層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。上表面層或中間層非彈性材料之型態為不織布、非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP、彈性PP或以上材料之混合體為佳。又,上表面層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Figure 7 is a structural diagram showing the microporous/non-porous film composite of the elastic underlayer and the intermediate layer of non-elastic nonwoven fabric, illustrating the microporous/non-porous film composite of the elastic underlayer and the intermediate non-elastic nonwoven before stretching. 7a, comprising: an upper surface layer - an unstretched non-elastic microporous/non-porous film 101 adjacent to the first surface of the intermediate layer; an intermediate layer - an unstretched non-elastic nonwoven fabric 206 having a first surface and The two surfaces are disposed between the upper surface layer and the lower surface layer; and the lower surface layer - an elastic microporous/non-porous film 303. The microporous/non-porous film composite 7a, which is not stretched before the elastic first layer and the intermediate layer, is inferior to the microporous/nonporous film composite of the elastic lower surface layer and the intermediate layer non-elastic non-woven fabric. Material 7b, after stretching, removes external tension so that the lower surface layer-elastic microporous/non-porous film 303 rebounds in a stable state without the elastic layer above the surface layer-extended non-elastic microporous/non-porous film 102 and the middle The layer-extended non-elastic non-woven fabric 207 is stretched and deformed by the stretching force, and the difference in surface compatibility of the materials of each layer is utilized, and the inter-layer surface gap is opened by the extension process without the thermal pressing process, and the upper surface layer is The intermediate layer is partially delaminated and the lower layer and the intermediate layer are partially delaminated, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material becomes a large convex surface structure with a floating material. The elastic material of the lower surface layer is an elastic non-porous film, an elastic microporous film or an elastic perforated film, and a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like may be selected. . The upper surface layer or the intermediate layer non-elastic material may be a non-woven fabric, a non-elastic non-porous film, a non-elastic microporous film or a non-elastic perforated film, and a mixture of PET, PP, PE, PS, Nylon or the like may be used. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP, elastic PP or the above materials. Further, an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight is added to the upper surface layer or the lower surface layer material. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

第8圖係顯示本創作彈性下表層及上表層非彈性不織布之微多孔/無孔薄 膜複合材料結構圖,說明未延展前彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材料8a,包含:上表面層-未延展之非彈性不織布101,其與中間層之第一表面相鄰;中間層-未延展之非彈性微多孔/無孔薄膜202,其具有第一表面及第二表面,設置於上表層與下表層之間;及下表面層-彈性微多孔/無孔薄膜303。未延展前彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材料8a經延展程序後,其結構改變成延展後彈性下表層及上表層非彈性不織布之微多孔/無孔薄膜複合材料8b,延展後去除外部張力使下表面層-彈性微多孔/無孔薄膜303回彈呈穩定狀態,而不具回彈性質之上表面層-延展之非彈性不織布104及中間層-延展之非彈性微多孔/無孔薄膜203,則受延展力而拉伸產生形變,並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,上表層與中間層呈現部分脫層且下表層與中間層呈現部分脫層,層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具一面蓬鬆不織布及一面彈性薄膜之雙面結構。下表面層彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜,可選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。上表面層或中間層非彈性材料之型態為不織布、非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜可選用PET、PP、PE、PS、Nylon或以上材料之混合體。更進一步,上表面層或下表面層材料選用PP、彈性PP或以上材料之混合體為佳。又,中間層或下表面層材料添加重量百分比1~75%之碳酸鈣、碳酸鎂、氧化鋁或氧化鈦等無機粉體材料。其中,上表面層厚度佔整體厚度5~70%之間;中間層厚度佔整體厚度5~70%之間;下表面層厚度佔整體厚度5~70%之間。 Figure 8 shows the microporous/non-porous thin layer of the elastic underlayer and the upper surface of the inelastic non-woven fabric. A structural view of a film composite material, illustrating a microporous/non-porous film composite material 8a of an unfolded elastic underlayer and an upper surface non-elastic nonwoven fabric, comprising: an upper surface layer-unstretched inelastic nonwoven fabric 101, which is the same as the intermediate layer a surface adjacent; an intermediate layer - an unexpanded non-elastic microporous/non-porous film 202 having a first surface and a second surface disposed between the upper surface layer and the lower surface layer; and a lower surface layer - elastic microporous / Non-porous film 303. The microporous/non-porous film composite 8a, which is not stretched before the elastic top layer and the upper surface non-elastic non-woven fabric, is subjected to a stretching procedure, and its structure is changed into a microporous/nonporous film composite of the elastic lower surface layer and the upper surface inelastic nonwoven fabric. Material 8b, after stretching, removes external tension so that the lower surface layer-elastic microporous/non-porous film 303 rebounds in a stable state without the elastic layer above the surface layer-extended non-elastic nonwoven fabric 104 and the intermediate layer-extension The elastic microporous/non-porous film 203 is stretched and deformed by the stretching force, and the difference in surface compatibility of the materials of each layer is utilized, and the interfacial surface gap is opened by the stretching procedure without the thermal pressing process, and the upper surface layer is The intermediate layer is partially delaminated and the lower layer and the intermediate layer are partially delaminated, and the interlaminar surface gap size is 0.5 to 1000 μm, so that the elastic film composite material has a double-sided structure with a fluffy non-woven fabric and an elastic film. The elastic material of the lower surface layer is an elastic non-porous film, an elastic microporous film or an elastic perforated film, and a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like may be selected. . The upper surface layer or the intermediate layer non-elastic material may be a non-woven fabric, a non-elastic non-porous film, a non-elastic microporous film or a non-elastic perforated film, and a mixture of PET, PP, PE, PS, Nylon or the like may be used. Further, the upper surface layer or the lower surface layer material is preferably a mixture of PP, elastic PP or the above materials. Further, the intermediate layer or the lower surface layer material is added with an inorganic powder material such as calcium carbonate, magnesium carbonate, aluminum oxide or titanium oxide in an amount of 1 to 75% by weight. Wherein, the thickness of the upper surface layer accounts for 5~70% of the overall thickness; the thickness of the intermediate layer accounts for 5~70% of the overall thickness; the thickness of the lower surface layer accounts for 5~70% of the overall thickness.

以上實施例一種彈性薄膜複合材料製造方法,其包含:一共押出製程,以複數押出機喂入複數原料利用多層共押模頭押出一體成形之多層薄膜;及一延展程序,共押出之多層膜經輪速差或壓延方式產生層間表面間隙;並利用各 層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。另一製造一種彈性薄膜複合材料之方法,其包含:至少一淋膜製程,以熱熔方式將熱可塑性材料融熔押出並同時與不織布底材相互熱黏著;及一延展程序,共押出之多層膜經輪速差或壓延方式產生層間表面間隙;並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。其中,施予延展程序透過輪速差牽伸、拉伸、壓輪壓延或齒輪咬合方式。施予延展程序選擇機械方向(MD,Machine Direction)、橫向方向(CD,Cross Direction)或雙向延伸。其施予延展程序前其彈性薄膜複合材料之基重介於30~100gsm之間。施予延展程序後其彈性薄膜複合材料之基重介於30~500gsm之間。施予延展程序其延展倍率具非破壞性及破壞性使彈性薄膜複合材料之薄膜呈非破裂或破裂狀態。施予延展程序其延展倍率介於≧0倍至≦10倍之間。施予延展程序後其複合材料之延伸狀態透濕度(M.V.T.,ASTM E96-BW)介於≧50g/m2.24hrs至≦15000g/m2.24hrs之間。施予延展程序後其複合材料之延伸狀態耐水壓(W.R.S.,AATCC 127)介於≧12mmH2O至≦2000mmmH2O之間。施予延展程序後其複合材料之整體厚度介於≧10微米至≦2000微米之間。施予延展程序後其複合材料之抗張強度(ASTM-D5034,Grab抓式)介於≧1Kgf至≦160Kgf之間;延伸率(ASTM-D5034,Grab抓式)介於≧40%至≦600%之間。 The above embodiment is a method for manufacturing an elastic film composite material, comprising: a total extrusion process, feeding a plurality of raw materials by using a multi-layer co-mold die by a plurality of extruders; and an extension process, a total of the multilayer film The wheel speed difference or the calendering method produces the interfacial surface gap; and the surface compatibility difference of each layer material is utilized, and the interfacial surface gap is opened without applying the thermal pressing procedure, so that the elastic film composite material becomes a cloth floating material. As a surface structure. Another method for manufacturing an elastic film composite material comprising: at least one coating process for thermally melting a thermoplastic material and simultaneously bonding to a non-woven substrate; and a stretching process for a plurality of layers The film is subjected to inter-layer surface gap by wheel speed difference or calendering method; and the difference in surface compatibility of each layer material is utilized, and the inter-layer surface gap is opened by a stretching procedure without a thermocompression procedure, so that the elastic film composite material becomes The surface structure of the fabric floats. Among them, the extension process is carried out by means of wheel speed difference drafting, stretching, pressure roller rolling or gear meshing. The extension program is selected to select the machine direction (MD, Machine Direction), the lateral direction (CD, Cross Direction) or the two-way extension. The basis weight of the elastic film composite material before the extension process is between 30 and 100 gsm. The elastic film composite has a basis weight of between 30 and 500 gsm after the extension process. The extension process is applied to the extension process with non-destructive and destructive properties such that the film of the elastic film composite is non-ruptured or broken. The extension procedure is applied between ≧0 times and ≦10 times. The extended state moisture permeability (MVT, ASTM E96-BW) of the composite after application of the elongation procedure is between ≧50 g/m 2 .24 hrs to ≦15000 g/m 2 .24 hrs. The extended state water pressure resistance (WRS, AATCC 127) of the composite after application of the elongation procedure is between ≧12 mmH 2 O and ≦2000 mmH 2 O. The overall thickness of the composite after application of the elongation procedure is between ≧10 microns and ≦2000 microns. The tensile strength (ASTM-D5034, Grab grip) of the composite after the extension procedure is between ≧1Kgf and ≦160Kgf; the elongation (ASTM-D5034, Grab) is between ≧40% and ≦600 %between.

第9圖係顯示本創作彈性中間層微多孔薄膜複合材料表面結構顯微鏡圖,說明層間表面間隙小之薄膜表面結構狀態9a,其表面蓬鬆度較小呈現平滑微細凸起狀態,製程中可調控延展程序之延展倍率較小,或調控層間材料之相容性較佳,使層間表面間隙乃不易相分離者;層間表面間隙居中之薄膜表面結 構狀態9b,其表面蓬鬆度較稍大呈現平滑稍大細凸起狀態,製程中可調控延展程序之延展倍率增加,或調控層間材料之相容性較差,使層間表面間隙呈現相分離現象增加者;層間表面間隙大之薄膜表面結構狀態9c,其表面蓬鬆度巨大呈現凹凸表面狀態,製程中可調控延展程序之延展倍率大,或調控層間材料之相容性較差,使層間表面間隙乃易於相分離者。 Fig. 9 is a micrograph showing the surface structure of the elastic intermediate layer microporous film composite. The surface structure state of the film with small interlaminar surface gap is 9a. The surface bulk is small and smooth and fine, and the process can be controlled and extended. The extension ratio of the program is small, or the compatibility of the materials between the layers is better, so that the interfacial surface gap is not easily separated; the film surface junction with the interlayer gap between the layers is intermediate. In the state of 9b, the surface bulkiness is slightly larger and smoother and slightly finer, and the expansion ratio of the adjustable extension process in the process is increased, or the compatibility of the materials between the layers is poor, so that the interfacial surface gap exhibits phase separation. The surface structure state of the film with a large gap between the layers is 9c, the surface has a large bulkiness and a concave and convex surface state, the expansion ratio of the adjustable extension process in the process is large, or the compatibility of the materials between the layers is poor, so that the interlayer gap is easy. Phase separator.

本發明乃是一種彈性薄膜複合材料,其包含:至少一上表面層、至少一中間層及至少一下表面層;並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。本發明據特殊彈性薄膜複合材料之表面型態特徵,有別於過去習知技藝具差異化,其新穎、進步及實用效益無誤。故可有效改進習知缺失,使用上有相當大之實用性。 The invention relates to an elastic film composite material comprising: at least one upper surface layer, at least one intermediate layer and at least one lower surface layer; and using the difference in surface compatibility of each layer material, the extension procedure is applied without a thermocompression procedure The interlaminar surface gap is pulled apart to cause the elastic film composite to be a floating surface structure. According to the surface type characteristics of the special elastic film composite material, the invention is different from the prior art, and the novelty, the progress and the practical benefit are correct. Therefore, the lack of conventional knowledge can be effectively improved, and the utility is quite practical.

綜觀上述,本創作實施例所揭露之具體構造,確實能提供差異化之特殊彈性薄膜複合材料之應用,以其整體結構而言,既未曾見諸於同類產品中,申請前亦未見公開,誠已符合專利法之法定要件,爰依法提出發明專利申請。 In view of the above, the specific structure disclosed in the present embodiment can indeed provide the application of the differentiated special elastic film composite material, and in terms of its overall structure, it has not been seen in the similar products, and has not been disclosed before the application. Cheng has already complied with the statutory requirements of the Patent Law and has filed an invention patent application in accordance with the law.

惟以上所述者,僅為本創作之一較佳實施例而已,當不能以此限定本創作實施之範圍,即大凡依本創作申請專利範圍及創作說明書內容所作之等效變化與修飾,皆應仍屬本創作專利涵蓋之範圍內。 However, the above is only a preferred embodiment of the present invention. When it is not possible to limit the scope of the creation of the present invention, that is, the equivalent changes and modifications made by the applicant in accordance with the scope of the patent application and the content of the creation specification are all It should remain within the scope of this creation patent.

Claims (10)

一種彈性薄膜複合材料,其包含:至少一上表面層,其與中間層之第一表面相鄰;至少一中間層,其具有第一表面及第二表面,設置於上表層與下表層之間;至少一下表面層,其與中間層之第二表面相鄰;並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,其層間表面間隙尺寸為0.5~1000微米,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構。 An elastic film composite material comprising: at least one upper surface layer adjacent to a first surface of the intermediate layer; at least one intermediate layer having a first surface and a second surface disposed between the upper surface layer and the lower surface layer At least one surface layer adjacent to the second surface of the intermediate layer; and utilizing the difference in surface compatibility of the materials of each layer, the interfacial surface gap is opened without the thermal pressing procedure, and the interlaminar surface gap size is It is 0.5 to 1000 μm, so that the elastic film composite material has a floating surface structure. 如請求項1所述之彈性薄膜複合材料,其中,上表面層、中間層或下表面層為彈性材料,且該彈性材料之型態為彈性無孔薄膜、彈性微多孔薄膜或彈性打孔膜;該彈性材料選用Hytrel、TPU、SEBS、SIS、SBS、彈性PP、彈性PE、彈性Nylon或以上材料之混合體。 The elastic film composite material according to claim 1, wherein the upper surface layer, the intermediate layer or the lower surface layer is an elastic material, and the elastic material is in the form of an elastic non-porous film, an elastic microporous film or an elastic perforated film. The elastic material is a mixture of Hytrel, TPU, SEBS, SIS, SBS, elastic PP, elastic PE, elastic Nylon or the like. 如請求項1所述之彈性薄膜複合材料,其中,上表面層、中間層或下表面層為非彈性材料,且該非彈性材料之型態為非彈性無孔薄膜、非彈性微多孔薄膜或非彈性打孔膜;該非彈性材料選用PET、PP、PE、PS、Nylon或以上材料之混合體。 The elastic film composite material according to claim 1, wherein the upper surface layer, the intermediate layer or the lower surface layer is a non-elastic material, and the non-elastic material is in a non-elastic non-porous film, a non-elastic microporous film or a non-elastic material. Elastic perforated film; the non-elastic material is selected from a mixture of PET, PP, PE, PS, Nylon or the like. 如請求項1所述之彈性薄膜複合材料,更進一步,上表面層、中間層或下表面層材料添加重量百分比1~75%之無機粉體材料;其無機粉體材料選用碳酸鈣、碳酸鎂、氧化鋁或氧化鈦。 The elastic film composite material according to claim 1, wherein the upper surface layer, the intermediate layer or the lower surface layer material is added with an inorganic powder material in a weight percentage of 1 to 75%; and the inorganic powder material is selected from calcium carbonate and magnesium carbonate. , alumina or titanium oxide. 如請求項1所述之彈性薄膜複合材料,其中,上表層與中間層呈現部 分脫層、下表層與中間層呈現部分脫層至少一脫層現象。 The elastic film composite material according to claim 1, wherein the upper surface layer and the middle layer presentation portion are The delamination layer, the lower layer and the intermediate layer exhibit partial delamination and at least one delamination phenomenon. 如請求項1所述之彈性薄膜複合材料,其中,上表面層厚度、中間層厚度或下表面層厚度佔整體厚度5~70%之間。 The elastic film composite material according to claim 1, wherein the thickness of the upper surface layer, the thickness of the intermediate layer or the thickness of the lower surface layer is between 5 and 70% of the total thickness. 一種彈性薄膜複合材料製造方法,其包含:一共押出製程,以複數押出機喂入複數原料利用多層共押模頭押出一體成形之多層薄膜;一延展程序,共押出之多層膜經輪速差或壓延方式產生層間表面間隙,其延展倍率具非破壞性及破壞性使彈性薄膜複合材料之薄膜呈非破裂或破裂狀態,其延展倍率介於≧0倍至≦10倍之間;並利用各層材料表面相容性差異,不經熱壓合程序即施予延展程序將層間表面間隙拉開,以致使該彈性薄膜複合材料成為具衣料浮起般之表面結構,施予延展程序後其複合材料之整體厚度介於≧10微米至≦2000微米之間。 The invention relates to a method for manufacturing an elastic film composite material, comprising: a total extrusion process, feeding a plurality of raw materials by using a multi-layer co-mold die by a plurality of extruders; and an extension process, a total of multi-layer film passing speed difference or The calendering method produces interlayer gaps, and the stretching ratio is non-destructive and destructive, so that the film of the elastic film composite material is non-ruptured or broken, and the stretching ratio is between ≧0 times and ≦10 times; and each layer material is utilized. The difference in surface compatibility is to extend the interlaminar surface gap without the thermal compression process, so that the elastic film composite material becomes a floating surface structure of the fabric, and the composite material is applied after the extension process. The overall thickness is between ≧10 microns and ≦2000 microns. 如請求項7所述之彈性薄膜複合材料製造方法,其中,施予延展程序前其彈性薄膜複合材料之基重介於30~100gsm之間;施予延展程序後其彈性薄膜複合材料之基重介於30~500gsm之間。 The method for manufacturing an elastic film composite material according to claim 7, wherein the basis weight of the elastic film composite material before the stretching process is between 30 and 100 gsm; the basis weight of the elastic film composite material after the extension process is applied Between 30~500gsm. 如請求項7所述之彈性薄膜複合材料製造方法,其中,施予延展程序後其複合材料之延伸狀態透濕度(M.V.T.,ASTM E96-BW)介於≧50g/m2.24hrs至≦15000g/m2.24hrs之間,耐水壓(W.R.S.,AATCC 127)介於≧12mmH2O至≦2000mmH2O之間。 The method for producing an elastic film composite according to claim 7, wherein the extended state moisture permeability (MVT, ASTM E96-BW) of the composite material after the extension process is between ≧50g/m 2 .24hrs to ≦15000g/ Between m 2 and 24 hrs, the water pressure resistance (WRS, AATCC 127) is between ≧12 mmH 2 O and ≦2000 mmH 2 O. 如請求項7所述之彈性薄膜複合材料製造方法,其中,施予延展程序 後其複合材料之抗張強度(ASTM-D5034,Grab抓式)介於≧1Kgf至≦160Kgf之間,延伸率(ASTM-D5034,Grab抓式)介於≧40%至≦600%之間。The method for producing an elastic film composite according to claim 7, wherein the extension program is applied The tensile strength of the composite material (ASTM-D5034, Grab grip) is between ≧1Kgf and ≦160Kgf, and the elongation (ASTM-D5034, Grab grip) is between ≧40% and ≦600%.
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CN101077643A (en) * 2006-04-10 2007-11-28 屈德加薄膜产品股份有限公司 Elastic film laminates prepared by multiple stretching steps
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CN101077643A (en) * 2006-04-10 2007-11-28 屈德加薄膜产品股份有限公司 Elastic film laminates prepared by multiple stretching steps
CN101951863A (en) * 2008-01-24 2011-01-19 宝洁公司 Extrusion bonded laminates for absorbent articles

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