TWI621612B - Use of tetramic acid derivatives for controlling pests by drenching, drip application, dip application or soil injection - Google Patents

Abstract

Compounds of formula (I) Among them, the meanings of A, B, G, W, X, Y and Z are explained in the description. Such compounds are applied by wet penetration, drip application, infiltration or injection into the soil, and are highly suitable for preventing and controlling animal harm. Organisms, such as insects and / or spider mites and / or nematodes.

Description

Pyrrolidone acid (tetramic acid) derivatives are applied by dripping, dripping, infiltrating or injecting into soil to control pests

The present invention relates to the use of tetramic acid derivatives for controlling insects and / or spider mites and / or nematodes by soaking, dripping, infiltrating or injecting into the soil.

The insecticidal and acaricidal activities of tetramic acid derivatives using spray application are disclosed in EP-A-456 063, EP-A-521 334, EP-A-596 298, EP-A-613 884, WO 95/01 997, WO 95/26 954, WO 95/20 572, EP-A-0 668 267, WO 96/25 395, WO 96/35 664, WO 97 / 01 535, WO 97/02 243, WO 97/36 868, WO 97/43 275, WO 98/05638, WO 98/06721, WO 98/25928, WO 99/16748, WO 99/24437, WO 99/43649 , WO 99/48869 and WO 99/55673, WO 01/09092, WO 01/17972, WO 01/23354, WO 01/74770, WO 03/013249, WO 04/007448, WO 04/024 688, WO 04 / 065366, WO 04/080962, WO 04/111042, WO 05/044 791, WO 05/044 796, WO 05/048 710, WO 05/049 596 and WO 05/066 125, WO 05/092897, WO 06 / 000355, WO 06/029799, WO 06/056281, WO 06/056282, WO 06/077071, WO 06/089633 and DE-A-05051325.

Surprisingly, it has been found that pyrrolidonic acid derivatives can also be applied to the soil by dripping, and infiltrated to the roots, tubers or bulbs according to the wet soil method known to the expert circle (refer to the expert circle) The infiltration application method used in the above), the hydroponic system, or the soil injection method known to experts is also highly suitable for controlling insects and / or spider mites and / or nematodes.

Therefore, the present invention relates to the use of pyrrolidonic acid derivatives for controlling insects and / or spider mites and / or nematodes, which are applied to the soil and infiltrated by dripping in an irrigation system by soaking the soil. Administered to the roots, tubers or bulbs or by injection into the soil; furthermore, the present invention pertains to these types of uses natural materials (soil) under open or closed systems (e.g. greenhouses or under film) ) Or artificial materials (e.g. rock wool, glass wool, quartz sand, gravel, expanded clay, vermiculite), and used in annual crops (e.g. vegetables, spices, ornamentals) or perennial crops (e.g. , Citrus, fruit, tropical crops, spices, nuts, vines, conifers and ornamentals).

The general crops that can be protected only outlined in the front will be explained in more detail and clearly later. Therefore, when referring to the use, vegetables refer to, for example, fruits and vegetables, such as bell peppers, peppers, tomatoes , Eggplant, cucumber, pumpkin, courgette, broad beans, vines and dwarf beans, peas, artichokes, corn; also includes leafy vegetables, head lettuce, chicory, endives, various types of cress (cress), cruciferous vegetables (rocket), lamb's lettuce, iceberg lettuce, leeks, spinach, Swiss chard; also includes tubers Vegetables, root vegetables and stem vegetables, for example, celeriac / celery, beets, carrots, radishes, mustard, scorzonera, Asparagus, beets for human use, palm hearts, bamboo shoots, also includes bulbous vegetables, such as onions, chives, Florence fennel, garlic; also includes cabbage, such as Cauliflower, broccoli, kohlrabi, red cabbage, white cabbage, curly kale, savoy cabbage, brussels sprouts (brussels sprouts) Brussels sprouts), Shandong cabbage (Chinese cabbage).

In terms of use, perennial crops refer to citrus, for example, oranges, grapefruits, tangerines, lemons, limes, Seville oranges, cumquats, and satsumas. ; Also includes pome fruit, such as apples, pears, and quinces, and stone fruits, such as peaches, nectarines, cherries, plums, and Alsace plums ( quetsch), apricots; also vines, hops, olives, tea trees and tropical crops, such as mango, papaya, figs, pineapples, dates, bananas, durians, kaki fruits, coconuts, cocoa, Coffee, avocado, lychee, maracujas, guava; also includes almonds and nuts such as hazelnut, walnuts, pistachios, cashew nuts, para nuts , Butternuts, chestnuts, hickory nuts, macadamia nuts, peanuts; also includes soft fruits such as currants, gooseberries ) Raspberries, blackberries, blueberries, strawberries, cranberries, kiwis, American cranberries; in terms of use, ornamental plants are annual and perennial Plants, for example, cut flowers, such as roses, carnations, gerbera, lilies, marguerites, tulips, narcissus, anemones, poppies, amaryllis (amaryllis), dahlias, azaleas, hibiscus; also includes, for example, wall plants, pot plants, and perennials, such as roses, marigolds (Tagetes), Dong Cai Genus (violas), geraniums (geraniums), fuchsias (hibiscus), hibiscus, chrysanthemum, balsam (busy lizzie), cyclamen, african violet, sunflower, begonia; In addition, for example, bushes and conifers, ficus, rhododendron, firs, spruces, pines, yews, duchess Pine (juniper), Japanese pine (umbrella pine), oleander; in terms of use, spice plants refer to annual and perennial plants, for example, aniseed, chilli pepper, paprika ), Pepper, vanilla, marjoram, thyme, cloves, juniper berries, cinnamon, tarragon, coriander, saffron, ginger.

Tetramic acid derivatives of formula (I) Where X represents halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or cyano, and W, Y and Z each independently represent hydrogen, halogen, alkyl, alkoxy, haloalkenyl , Haloalkoxy or cyano, A represents halogen, or represents a halogen-substituted alkyl, alkoxyalkyl, saturated, optionally substituted cycloalkyl, each of which is optionally at least A ring atom is replaced by a heteroatom, B represents hydrogen or alkyl, or the carbon atom to which A and B are attached to each other represents a saturated or unsaturated, unsubstituted or substituted ring, which is optional Ground contains at least one heteroatom, G represents hydrogen (a) or one of the following groups E (f) or , Where E represents a metal ion or an ammonium ion, L represents oxygen or sulfur, M represents oxygen or sulfur, and R ¹ represents an alkyl group, an alkenyl group, an alkoxyalkyl group, and an alkylthio group each optionally substituted with halogen. Alkyl, polyalkoxyalkyl or optionally halogen-, alkyl- or alkoxy-substituted cycloalkyl, into which at least one heteroatom can be inserted, in each case a optionally substituted phenyl, Phenylalkyl, heteroaryl, phenoxyalkyl or heteroaryloxyalkyl, R ² represents an alkyl, alkenyl, alkoxyalkyl, polyalkoxy group each optionally halogen-substituted Alkyl or each is optionally substituted cycloalkyl, phenyl or benzyl, R ³ represents optionally halogen-substituted alkyl or optionally substituted phenyl, R ⁴ and R ⁵ are independently of each other Each represents an optionally substituted halogen-substituted alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio, cycloalkylthio, or represents each optionally substituted benzene Group, benzyl group, phenoxy group or phenylthio group, and R ⁶ and R ⁷ independently of each other represent hydrogen, and each is a halogen-substituted alkyl group, cycloalkyl group, alkenyl group, Alkoxy, alkoxyalkyl, optionally substituted phenyl, optionally substituted benzyl, or N atoms attached to them together represent a selectively substituted ring, where optionally inserted Oxygen or sulfur, they are their isomer mixtures or their pure isomers.

The aforementioned Tetramic acid derivatives of formula (I) are preferably used by those whose radicals have the following meanings: W preferably represents hydrogen, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, chlorine, bromine or fluorine, X preferably represents C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, C ₁ -C ₄ -haloalkyl , Fluorine, chlorine or bromine, Y and Z independently of one another preferably represent hydrogen, C ₁ -C ₄ -alkyl, halogen, C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -haloalkyl , A preferably represents hydrogen or halogen-substituted C ₁ -C ₆ -alkyl or C ₃ -C ₈ -cycloalkyl, B preferably represents hydrogen, methyl or ethyl, A, B And the carbon atom to which it is attached preferably represents a saturated C ₃ -C ₆ -cycloalkyl group, where one ring atom is optionally substituted with oxygen or sulfur and it is C _1- C ₄ -alkyl, trifluoromethyl or C ₁ -C ₄ -alkoxy substituted, G preferably represents hydrogen (a) or one of the following E (f) or In particular, (a), (b), (c) or (g) where E represents a metal ion or an ammonium ion, L represents oxygen or sulfur and M represents oxygen or sulfur, and R ¹ preferably represents each option. Halogen-substituted C ₁ -C ₁₀ -alkyl, C ₂ -C ₁₀ -alkenyl, C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkane Thio-C ₁ -C ₄ -alkyl, or C ₃ -C ₆ -cycloalkyl, optionally via fluorine, chlorine, C ₁ -C ₄ -alkyl or C ₁ -C ₂ -alkoxy Substituted with a substituent, or optionally substituted with fluorine, chlorine, bromine, cyano, nitro, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, trifluoromethyl or trifluoromethyl An oxy-substituted phenyl group, or a pyridyl group or a thienyl group each optionally substituted with chlorine or methyl, R ² preferably represents a C ₁ -C ₁₀ -alkyl group each substituted with fluorine- or chlorine- , C ₂ -C ₁₀ -alkenyl, C ₁ -C ₄ -alkoxy-C ₂ -C ₄ -alkyl, or C ₅ -C ₆ -optionally substituted by methyl- or methoxy- Cycloalkyl, or alternatively, each via fluorine, chlorine, bromine, cyano, nitro, C ₁ -C ₄ -alkyl, C ₁ -C ₄ -alkoxy, trifluoromethyl or trifluoromethyl the substituted phenyl or benzyl group, R ³ Best represents optionally fluorine - substituted C ₁ -C ₄ - alkyl, or represents optionally fluoro, chloro, bromo, C ₁ -C ₄ - alkyl, C ₁ -C ₄ - alkoxy, tri fluoromethyl, trifluoromethoxy, cyano or nitro substituent of the phenyl group, R ⁴ each preferably represents optionally fluoro - or chlorine - substituted C ₁ -C ₄ - alkyl, C ₁ - C ₄ -alkoxy, C ₁ -C ₄ -alkylamino, C ₁ -C ₄ -alkylthio or representatively selected via fluorine, chlorine, bromine, nitro, cyano, C ₁ -C _4- Alkoxy, trifluoromethoxy, C ₁ -C ₄ -alkylthio, C ₁ -C ₄ -haloalkylthio, C ₁ -C ₄ -alkyl or trifluoromethyl substituted phenyl, Phenoxy or phenylthio, R ⁵ preferably represents C ₁ -C ₄ -alkoxy or C ₁ -C ₄ -sulfanyl, R ⁶ preferably represents C ₁ -C ₆ -alkyl, C ₃ -C ₆ -cycloalkyl, C ₁ -C ₆ -alkoxy, C ₃ -C ₆ -alkenyl or C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl, R ⁷ is more Preferably it represents C ₁ -C ₆ -alkyl, C ₃ -C ₆ -alkenyl or C ₁ -C ₄ -alkoxy-C ₁ -C ₄ -alkyl, R ⁶ and R ⁷ together preferably represent Alternatively substituted with methyl - or ethyl - substituted C ₃ -C ₆ - alkylene, where a carbon atom may optionally be oxygen or Substituted isomer was the type of their pure isomers or their mixtures of the.

The above-mentioned pyrrolidone derivatives of formula (I) are particularly preferably used by those whose groups have the following meanings: W particularly preferably represents hydrogen, methyl, ethyl, chlorine, bromine or methoxy , X particularly preferably represents chlorine, bromine, methyl, ethyl, propyl, isopropyl, methoxy, ethoxy or trifluoromethyl, and Y and Z independently of each other particularly preferably represent hydrogen, fluorine, Chlorine, bromine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or methoxy, A particularly preferably represents methyl, ethyl, propyl, isopropyl, butyl, isobutyl , Second-butyl, third-butyl, cyclopropyl, cyclopentyl or cyclohexyl, B particularly preferably represents hydrogen, methyl or ethyl, or A, B and the carbon atoms to which it is attached, especially It preferably represents a saturated C ₆ -cycloalkyl group in which one ring atom is optionally substituted with oxygen and it is a methyl group, an ethyl group, a trifluoromethyl group, a methoxy group, an ethoxy group, Propoxy or butoxy substitution, G particularly preferably represents hydrogen (a) or one of the following Wherein M represents oxygen or sulfur, and R ¹ particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, ring Propyl, cyclopentyl or cyclohexyl, or represents 1 to 2 fluorine, chlorine, bromine, cyano, nitro, methyl, ethyl, methoxy, trifluoromethyl or trifluoromethyl An oxy-substituted phenyl group, or a pyridyl or thienyl group each optionally substituted with chlorine or methyl, R ² particularly preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, Methoxyethyl, ethoxyethyl, or phenyl or benzyl, R ⁶ and R ⁷ each independently particularly preferably represent methyl or ethyl or together represent a C ₅ -alkylene group where C _{The 3} -alkylene groups are substituted with oxygen and are in the form of their isomer mixtures or their pure isomers.

The above-mentioned pyrrolidone acid derivatives of formula (I) are most preferably used by those whose radicals have the following meanings: W represents hydrogen or methyl, and X represents chlorine, bromine or methyl. Groups, Y and Z, independently of one another, represent hydrogen, chlorine, bromine or methyl, and A, B and the carbon atoms to which they are attached perfectly represent a saturated C ₆ -cycloalkyl group, one of which is Optionally substituted with oxygen and which is optionally substituted with 1 methyl, trifluoromethyl, methoxy, ethoxy, propoxy or butoxy, G represents hydrogen (a) or better One of the bases Where M represents oxygen or sulfur, and R ¹ very preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxymethyl, ethoxymethyl, ethylthiomethyl, ring Propyl, cyclopentyl, cyclohexyl, or a substituent optionally substituted by fluorine, chlorine, bromine, methyl, methoxy, trifluoromethyl, trifluoromethoxy, cyano or nitro Substituted phenyl, or pyridyl or thienyl, each optionally substituted by chlorine or methyl, R ² very preferably represents C ₁ -C ₈ -alkyl, C ₂ -C ₄ -alkenyl, methoxy Ethyl, ethoxyethyl, phenyl or benzyl, R ⁶ and R ⁷ independently of one another represent methyl or ethyl very well or together represent a C ₅ -alkylene group in which C ₃ -alkylene The radicals are substituted by oxygen, either in their mixture of isomers or in their pure form.

The above-mentioned pyrrolidone acid derivatives of formula (I) are most preferably used by those whose radicals have the following meanings:

In their isomer mixtures or in their pure isomer form.

The compound of formula (I) is a known compound and its preparation method is disclosed in the patents / patent applications cited at the beginning (for reference, especially WO 97/01535, WO 97/36868 and WO 98/05 638) .

In terms of use, the pure cis isomers of compounds I-3 and I-4 can be particularly emphasized (WO 04/007448).

According to the present invention, the pyrrolidonic acid derivatives may be administered by themselves, but may be used in combination with other insecticidal and / or acaricidal active materials. Used in a wide range of different animal pests, these include: Anoplura (Phthiraptera) organisms, for example, Damalinia spp. , Haematopinus spp. , Linognathus spp .), louse is a louse (Pediculus spp.), is a hair lice (Trichodectes spp.).

Arachnida organisms, for example, Acarus siro , Aceria sheldoni , Aculops spp. , Aculus spp., Amblyomma spp. ), Argas spp. , Boophilus spp. , Brevipalpus spp., Bryobia praetiosa , Chorioptes spp. , Chicken prickles mite (Dermanyssus gallinae), spider mites (Eotetranychus spp.), jujube leaf rust mite (Epitrimerus pyri), brown leaf mite genus (Eutetranychus spp.), gall mite (Eriophyes spp.), damage wolfberry gall mite (Eriophyes spp. ), Hemitarsonemus spp. , Hyalomma spp. , Ixodes spp. , Latrodectus mactans , Red Spider (Metatetranychus spp.), Leaf Mite ( Oligonychus spp. ), Ornithodoros spp. , Panonychus spp. , Phyllocoptruta oleivora , Polyphagotarsonemus latus , Psoroptes spp. , Rhipicephalus spp. ), Rhizoglyphus spp. ( Sarcoptes spp. ), Scorpio ( Scorpio maurus ), Stenotarsonemus spp. , Tarsonemus spp. , Tetranychus spp. , Vasates lycopersici .

Bivalva organisms, for example, Dreissena spp.

Chilopoda organisms, for example, Geophilus spp. , Scutigera spp .

Coleoptera organisms, for example, Acanthoscelides obtectus , Adoretus spp. , Poplar Agelastica alni , Agriotes spp. , Potato gill beetle ( Amphimallon solstitialis ), Anobium punctatum , Anoplophora spp. , Anthonomus spp. , Anthrenus spp. , Apogonia spp. , Atomaria spp.), black carpet beetle genus (Attagenus spp.), bean weevil (Bruchidius obtectus), the genus bean weevil (Bruchus spp.), such as turtles stem (Ceuthorhynchus spp.), Cleonus mendicus , Conoderus spp., stem weevil ( Cosmopolites spp. ), Grasshopper ( Costelytra zealandica ), Weevil ( Curculio spp. ), Yang Qianxiang ( Cryptorhynchus lapathi ), Dermustes spp. , Diabrotica spp. ( Epilachna spp. ), Ladybug ( Epilachna spp. ), Faustinus cubae , Gibbium psylloides , Heteronychus arator , Hylamorpha elegans , Hylotrupes bajul us), alfalfa weevil (Hypera postica), coffee berry borer (Hypothenemus spp.), grubs (Lachnostrna consanguinea), Colorado potato beetle (Leptinotarsa decemlineata), rice water weevil (Lissorhoptrus oryzophilus), weevils (Lixus spp .), Lyctus spp., Canola flower tail tail ( Meligethes aeneus ), large chestnut gill horn beetle ( Melolontha melolontha ), monochamus ( Migdolus spp. ), Monochamus spp., Grape pupae Mite ( Naupactus xanthographus ), yellow beetle ( Niptus hololeucus ), rhinoceros beetle ( Oryctes rhinoceros ), saw valley rice ( Oryzaephilus surinamensis ), black grape ear beak ( Otiorrhynchus sulcatus ), small blue and white beetle ( Oxycetonia juncea ) ( Phaedon cochleariae ), Chafer ( Phyllophaga spp. ), Japanese Chafer ( Popillia japonica ), Small Elephant Carapace ( Premnotrypes spp. ), Brassica napus ( Psylliodes chrysocephala ), Ptinus spp. Ralis , Rhizobius vent Rhizopertha dominica , Sitophilus spp. , Sphenophorus spp. , Sternec hus spp. , Symphyletes spp. , Tenebrio molitor , Tribolium spp. , Trogoderma spp. , Tychius spp. , Xylotrechus spp. ), Zabrus spp .

Collembola organisms, for example, Onychiurus armatus .

Dcrmaptera organisms, such as Forficula auricularia .

Diplotopa organisms, for example, Blaniulus guttulatus .

Diptera organisms, for example, Aedes spp. , Anopheles spp. , Bibio hortulanus , Calliphora erythrocephala , Ceratitis capitata ), Chrysomyia spp. , Cochliomyia spp. , Cordylobia anthropophaga , Culex spp. , Cuterebra spp. , olive oil Dacus oleae , Dermatobia hominis , Drosophila spp. , Fannia spp. , Gastrophilus spp. , Hylemyia spp. ( Hyppobosca spp. ), Hypoderma spp. , Liriomyza spp. , Lucilia spp. , Musca spp. , Nezara spp. Oestrus spp.), Sweden straw flies (Oscinella frit), beet leaf-flower fly (Pegomyia hyoscyami), spring wheat (wheat species) Musca (Phorbia spp.), stable flies genus (Stomoxys spp.), Gadfly genus (Tabanus spp. ), Tannia spp. , Tipula paludosa , Wohlfahrtia spp. ).

Gastropoda organisms, for example, Arion spp. , Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp. , Lymnaea spp., Oncomelania spp., Succinea spp.

Worms (Helminths) organisms, for example, Ancylostoma duodenale (Ancylostoma duodenale), Ceylon hookworms (Ancylostoma ceylanicum), Brazil hookworms (Acylostoma braziliensis), Ancylostoma genus (Ancylostoma spp.), Roundworm (Ascaris lubricoides), Trichinella (of Ascaris spp. ), Brugia malayi , Brugia timori , Bunostomum spp. , nematodes ( Chabertia spp. ), Clonorchis spp. , Cooperia spp. Cooperia spp. ), Dicrocoelium spp. , Dictyocaulus filaria , Diphyllobothrium latum , Dracunculus medinensis , Echinococcus granulosus ( Echinococcus multilocularis ), Enterobius vermicularis , Faciola spp. , Haemonchus spp. , Heterakis spp. , Hymenolepis nana , Hyostrongulus spp. , Roa blood filarial (Loa Loa), nematodes belong to the duodenum (Nematodirus spp.), intestinal Oesophagostomum (Oesophagostomum spp.), Thailand Trematodes (Opisthorchis spp.), The end coil volvulus (Onchocerca volvulus), cow stomach filarial genus (Ostertagia spp.), And genital flukes (Paragonimus spp.), Schistosomen spp , Strongyloides fuellebomi, fecal nematode ( Strongyloides stercoralis), Stronyloides spp., no hook tapeworm (Taenia saginata), hook tapeworm (Taenia solium), swine Trichinella spiralis (Trichinella spiralis), Trichinella spiralis (Trichinella nativa), Trichinella spiralis (Trichinella britovi), Trichinella spiralis (Trichinella nelsoni ), Trichinella pseudopsiralis , Trichostrongulus spp. , Trichuris trichuria , Wuchereria bancrofti .

It may also be used to control protozoa, for example, Eimeria.

Heteroptera organisms, for example, Anasa tristis , Antestiopsis spp. , Blissus spp. , Calocoris spp. , Campylomma livida , Cavelerius spp. , Bed bug (Cimex spp.), peanut yellow bugs (Creontiades dilutus), pepper Rhamnomia (Dasynus piperis), Dichelops furcatus, Diconocoris hewetti, cotton, red bug (Dysdercus spp.), brown stink bug (Euschistus spp.), brown shield bug genus (Eurygaster spp.), Heliopeltis spp ., Horcias nobilellus, spider Rhamnomia (Leptocorisa spp.), leaf foot Rhamnomia (Leptoglossus phyllopus), tarnished plant bug genus (Lygus spp.), sugarcane black chinch bug (Macropes excavatus), Miridae , Nezara spp. , Oebalus spp. , Pentomidae , Piesma quadrata , Piezodorus spp. , Cotton pheasant (Psallus seriatus), Pseudacysta persea, nose cone insect (Rhodnius spp.), cocoa brown blind (Sahlbergella singularis), rice black bugs (Scotinophora spp.), lace bugs (Stephanitis nashi), Tibraca spp. , vampire Is a bug (Triatoma spp.)

Homoptera organisms, for example, Acyrthosipon spp. , Aeneolamia spp. , Agoniscena spp. , Aleurodes spp. , Aleurolobus barodensis , Aleurothrixus spp .), Amrasca spp., Anuraphis cardui, red pitysophila (Aonidiella spp.), pear Myzus (Aphanostigma piri), apple aphid (Aphis spp.), Arboridia apicalis , Aspidiella spp., pitysophila (Aspidiotus spp.), Atanus spp. , Aulacorthum solani , Bemisia spp. , Brachycaudus helichrysii , Brachycolus spp. , Braviccolyne spp. , Brevicoryne brassicae , Small rice brown planthopper ( Calligypona marginata ), night cicada ( Carneocephala fulgida ), cotton aphid ( Ceratovacuna lanigera ), Cercopidae, Ceroplastes spp. , Strawberry capillary aphid ( Chaetosiphon fragaefolii ), cane yellow snow shield 蚧 ( Chionaspis tegalensis ), leafhopper ( Chlorita onukii ), walnut black spot aphid ( Chromaphis juglandicola ), tea brown round owl ( Chrysomphalus ficus ), leafhopper ( Cicadul ina mbila ), Coccomytilus halli , Coccus spp. , Cryptomyzus ribis , Dalbulus spp. , Whiteflies ( Dialeurodes spp. ), Psyllid ( Diaphorina spp. ), Diaspis spp. , Doralis spp . , Drosicha spp. , Dysaphis spp. , Dysmicoccus spp. , Empoasca spp. , Eriosoma spp. Erythroneura spp. ), Leafhopper ( Euscelis bilobatus ), root pupae ( Geococcus coffeae ), glazed leafhopper ( Homalodisca coagulata ), peach big-tailed aphid ( Hyalopterus arundinis ), cotton moth ( Icerya spp. ), Leafhopper ( Idiocerus spp. ), Idioscopus spp. , Laodelphax striatellus , Lecanium spp. , Lepidosaphes spp. , Lipaphis erysimi , Macrosiphum spp. , Mahanarva fimbola sorghum, millet aphid (Melanaphis sacchari), Metcalfiella spp. , rose Valley aphid (Metopolophium dirhodum), black-winged edge flat spotted aphid (Monellia costalis), Monelliopsis pecanis, tumor volume aphid genus (Myzus spp.), lettuce aphid (Nasonov ia ribisnigri ), black-tailed leafhopper ( Nephotettix spp. ), rice brown planthopper ( Nilaparvata lugens ), Oncometopia spp. , Orthezia praelonga , Parabemisia myricae , Paratrioza spp. , star Parrotia spp. , Pemphigus spp. , Peregrinus maidis , Phenacoccus spp. , Phloeomyzus passerinii , Phorodon humuli , Phorodon humuli Phylloxera spp. ), Pinnaspis aspidistrae , Planococcus spp. , Protopulvinaria pyriformis , Pseudaulacaspis pentagona , Pseudococcus spp. Psylla spp. ), Pteromalus spp. , Pyrilla spp. , Quadraspidiotus spp. , Quesada gigas , Rastrococcus spp. , Rhopalosiphum spp. , Saissetia .), Scaphoides titanus, Ercha wheat aphid (Schizaphis graminum), West Indian fine buckler Kuwana (Selenaspidus articulatus), planthopper (Sogata spp.), white-backed planthopper (Sogatell a furcifera ), planthopper ( Sogatodes spp. ), horn cicada ( Stictocephala festina ), Tenalaphara malayensis , black walnut aphid ( Tinocallis caryaefoliae ), mochi ( Tomaspis spp. ), Toxoptera spp. Lice ( Trialeurodes vaporariorum ), psyllid ( Trioza spp. ), Small leafhopper ( Typhlocyba spp. ), Shield cricket ( Unaspis spp. ), Grape root nodule ( Viteus vitifolii ).

Hymenoptera organisms, for example, Diprion spp. , Hoplocampa spp. , Lasius spp. , Monomorium pharaonis, Vespa Vespa spp. ).

Isopoda organisms, for example, Armadillidium vulgare , Oniscus asellus , Porcellio scaber .

Isoptera organisms, for example, Reticulitermes spp. , Odontotermes spp .

Lepidoptera organisms, for example, Acronicta major , Aedia leucomelas, Spodoptera frugiperda ( Agrotis spp. ), Alabama argillacea , Anticasia spp. ), Cabbage night moth ( Barathra brassicae ), cotton leaf perforation latent moth ( Bucculatrix thurberiella ), pine palm borer ( Bupalus piniarius ), leaf roller moth ( Cacoecia podana ), leaf roller moth ( Capua reticulana ), apple moth ( Carpocapsa pomonella ), Cheimatobia brumat Chilo spp. , Choristoneura fumiferana , Clysia ambiguella , Cnaphalocerus spp. , Earias insulana , Ephestia kuehniella , Euproctis chrysorrhoea , Euxoa spp. , Feltia spp. , Galleria mellonella , Helicoverpa spp. , Heliothis spp. , Brown weave Hofmannophila pseudospretella , Homona magnanima , Hyponomeuta padella , Laphygma spp. , Lithocolle tis blancardella), green fruit armyworm (Lithophane antennata), Loxagrotis albicosta, dance [drug] moth (Lymantria spp.), tent caterpillar (Malacosoma neustria), cabbage armyworm (Mamestra brassicae), Inage chamber armyworm (Mocis repanda ), Mythimna separata , Oria spp. , Oulema oryzae , Panolis flammea , (Cotton) red worm ( Pectinophora gossypiella ), Phyllocnistis citrella , Pieris spp. , Plutella xylostella , Prodenia spp. , Pseudaletia spp. , Pseudoplusia includens , Pyrausta nubilalis , ) Spodoptera spp. , Thermesia gemmatalis , Tinea pellionella , Tineola bisselliella , Tortrix viridana , Trichoplusia spp .

Orthoptera organisms, for example, Acheta domesticus , Blatta orientalis , Blattella germanica , Gryllotalpa spp. , Leucophaea maderae , Locusta spp. , Melanoplus spp. , Periplaneta Americana , Schistocerca gregaria .

Siphonaptera organisms, for example, Ceratophyllus spp. , Xenopsylla cheopis .

Symphyla organisms, for example, Scutigerella immaculata .

Thysanoptera organisms, for example, Baliothrips biformis , Enneothrips flavens , alfalfa thrips ( Frankliniella spp. ), Thrips ( Heliothrips spp. ), Greenhouse thrips ( Hercinothrips femoralis ), Kakothrips spp. , Thrips ( Rhipiphorothrips cruentatus ), thrips ( Scirtothrips spp. ), Thrips ( Taeniothrips cardamoni ), thrips (thrips spp. ).

Thysanura organisms, for example, Lepisma saccharina .

Plant parasitic nematodes include, for example, Anguina spp. , Aphelenchoides spp. , Belonoaimus spp. , Bursaphelenchus spp. , Ditylenchus dipsaci , ( Globodera spp. ), Heliocotylenchus spp. , Heterodera spp. , Needleworm ( Longidorus spp. ), Meloidogyne spp. , Pratylenchus spp. Radopholus similes ), Rotylenchus spp. , Trichodorus spp. , Tylenchorhynchus spp. , Tylenchulus spp. , Tylenchulus semipenetrans , sword Nematode ( Xiphinema spp. ).

Arachnida organisms, for example, Acarus siro , Aceria sheldoni , Aculops spp. , Aculus spp., Amblyomma spp. ), Argas spp. , Boophilus spp. , Brevipalpus spp. , Bryobia praetiosa , Chorioptes spp. , Chicken prickles mite (Dermanyssus gallinae), spider mites (Eotetranychus spp.), jujube leaf rust mite (Epitrimerus pyri), brown leaf mite genus (Eutetranychus spp.), gall mite (Eriophyes spp.), damage wolfberry gall mite (Eriophyes spp. ), Hemitarsonemus spp. , Hyalomma spp. , Ixodes spp. , Latrodectus mactans , Red Spider ( Metatetranychus spp. ), Oligonychus spp. , Ornithodoros spp. , Panonychus spp. , Phyllocoptruta oleivora , Polyphagotarsonemus latus , Psoroptes spp. , Rhipicephalus spp.), root mite (Rhizoglyphus spp.), scabies Genus (Sarcoptes spp.), Scorpion (Scorpio maurus), Stenotarsonemus spp. , Tetranychus spp line (Tarsonemus spp.), The genus mite (Tetranychus spp.), Vasates lycopersici .

It is preferably used for controlling the following organisms from the family Aphididae (Pemphigidae): Eriosoma spp., Pemphigus spp., Anuraphis spp., Brachycaudus spp. .), Used in, for example, pome fruit, conifers, vegetables and ornamental crops.

Organisms from the family Psyllidae, more suitable for control are: Psylla spp. , Paratrioza spp., Trioza spp., Used in the following crops, for example, citrus, vegetables, potatoes, pears Fruit tree.

Organisms from the Coccidae family, more suitable for control are: Ceroplastes spp., Drosicha spp., Pulvinaria spp., Protopulminaria spp., Saissetia spp .), Coccus spp., Used in perennial crops, such as citrus, vines, tea trees, prunus and stone fruit trees, tropical crops, ornamentals, conifers, and vegetables.

Organisms from the family Diaspididae, more suitable for control are: Quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Aspis spp., Diaspis spp., Parlatoria spp., Pseudaulacaspis spp., Unaspis spp., Pinnaspis spp., Selenaspidus spp., using In, for example, crops of citrus, tea trees, ornamentals, conifers, nuts and stone trees, vines, tropical crops.

From Pseudococcidae organisms, more suitable for control are: Percererga, Pseudococcus spp. , Planococcus spp., Phenacoccus spp., Powder Dysmicoccus spp. Is used in, for example, citrus, prunus and stone fruit trees, tea trees, vines, vegetables, ornamental plants, conifers, spices and tropical crops.

Other suitable organisms for control are organisms from the family Aleyrodidae: Bemisia argentifolii , Bemisia tabaci , Trialeurodes vaporariorum , Aleurothrixus floccosus , Aleurodes spp., Dialeurodes spp., Parabemisia myricae , used in crops, for example, vegetables, melon, potatoes, tobacco, soft fruit trees, citrus, ornamental plants, conifers, cotton, potatoes and tropical crops.

Others are preferred for controlling aphids of the genus Aphidae of the following families:

Also preferred are the following genera from the Tetranychidae family: Tetranychus spp., Brevipalpus spp., Panonychus spp., Oligonychus spp., Eotetranychus spp., Bryobia spp., Used in, for example, vegetables, ornamental plants, spices, conifers, citrus, stone fruits and prunus trees, vines, cotton, soft fruit trees, muskmelons, potato crops.

Preferred are the following genus organisms for controlling the family Tarsonemidae: Hermitarsonemus batus , Stenotarsonemus spp., Polyphagotarsonemus spp., Stenotarsonemus spinky , for use in, for example, vegetables, ornamental plants, spices, conifers, Tea trees, citrus, muskmelon and other crops.

Also preferred are the following genera for controlling Thripidae: Anaphothrips spp., Baliothrips spp., Caliothrips spp., Frankliniella spp., Heliothrips spp., Hercinothrips spp., Rhipiphorothrips spp., Scirtothrips spp., Selenothrips spp., and Thrips spp., for use in, for example, fruit trees, cotton, vines, soft fruit, vegetables, melons, ornamentals, spices, conifers, tropical crops, tea and other crops.

Also preferred system for controlling the following Agromyzidae (Agromyzidae) genera of organisms: (. Liriomyza spp). Leafminer, Pegomya spp, used, for example, vegetables, melons class, ornamental plants and potato On the crop.

It is also a better line for controlling various leaf nematodes of the Aphelenchoididae family, such as Aphelenchoides ritzemabosi , A. fragariae , and A. besseyi. ), A.blastophthorus , used in, for example, crops of soft fruit trees and ornamental plants.

The following examples are provided to illustrate the present invention and are not intended to limit the present invention in any way to that.

Use case Aphididae and Pemphigidae

Excellent for controlling various organisms from the family Aphididae and Pemphigidae in the following crops:

Example 1

In an irrigation experiment in a 0.5-liter pot, Shandong cabbage, Savoy cabbage, sweet pepper, and broad bean that had been planted 3 days ago were watered, and repeated in 50 ml containing The active substance solution of the active substance I-4 (cis isomer) at the application rate was treated at a temperature of 20 ° C in the greenhouse, and infected with MYZUPE on the 7th and 14th days after the active substance was administered. Abbott's formula evaluates the activity 7 days after each infection.

Example 2

Cuc. "Delikatess", a cucumber plant that has grown on rockwool one week after transplantation, is soaked, repeated six times, with 100 ml each of the active substance I-4 (cis isomer, formula: 240 SC) active substance solution treatment, the temperature of the greenhouse was 20 ° C, and infection was performed with APHIGO on the 7th and 14th days after the active substance was administered, and the activity was evaluated 7 days after each infection with the aid of Abbott's formula.

Example 3

Violet plant cv. "Ladies delight" (approximately 15 cm in height) planted in 4-inch pots, repeated four times, and those who have been infected with Aphis craccivora two weeks before treatment, containing the application rate The active substance solution of the active substance I-4 (cis isomer, formulation: 240 SC) was soaked, and for comparison, a commercially available standard imidacloprid (240 SC) containing the application rate was also applied. ), The temperature of the greenhouse was 27-33 ° C. After 7, 14, 22 and 35 days after the active substance was applied, the activity against the tadpoles on the leaves was tested by means of the Henderson-Tilton method.

Tetranychidae and Tarsonemidae

In addition, it is excellent for controlling various organisms in the families Tetranychus and Acarina in the following crops:

Example 4

The eggplant planted in a 0.5 liter pot for 25 days was repeated three times and soaked with 50 ml of an active substance solution containing the active substance I-4 (cis isomer, formula: 3240 SC) at the application rate. The temperature of the greenhouse was 20 ° C. On the 7th and 14th days after the application of the active substance, infection was performed with cotton aphid (APHIGO), peach aphid (MYZUPE) and two-spot spider mite (TETRUR). The activity was evaluated 7 days after each infection.

Example 5

Gardenia plants cv. ("Cape jasmine") planted in 6-inch pots, who had been infected with Tetranor mites (TETRUR) two weeks before treatment, repeated three times with 100 ml each Activity of the active substance I-4 (cis isomer, formulation: 240 SC) containing the application rate The solution of the substance was soaked, and for comparison, a commercially available standard imidacloprid (240 SC) containing the application rate was also applied, and the temperature of the greenhouse was 25-30 ° C. After 15 days, and 22 days, the activity against the pupae on the leaves was tested by means of the Henderson-Tilton method.

Thrips (Thrips)

Another excellent line is used to control various thrips in Thripidae in the following crops:

Example 6

Has been infected with Western flower thrips (FRANOC), a verbena plant in a 6-inch-pot (about 13 cm high), fourfold, containing the active substance I-4 (cis isomer, formula: 240 SC) of the active substance solution was soaked. For comparison, a commercially available standard imidacloprid (240 SC) containing the application rate was also applied. The temperature of the greenhouse was 27-33 ° C. After 7, 14, 21, and 28 days after inoculation, the activity against the pupae on the leaves was tested by means of the Henderson-Tilton method.

Example 7

On a small piece of cultivated land about 5 square meters in size that has been planted with cucumber plants, it is used in triplicate to combat southern yellow thrips with an active substance containing active substance I-4 (cis isomer, formula: 240 SC) The solution was soaked, and for comparison, a commercially-available standard imidacloprid (100 SL) containing the application rate was also applied, which corresponds to a water application rate of 300 liters / ha, with an interval of 10 days between the two applications, On the 9th day after the administration of the active substance and 7 and 13 days after the second treatment, the efficacy was tested by means of Abbott's formula.

Whitefly (Aryrodidae)

It is also excellent for controlling various whiteflies from the family Aleyrodidae in the following crops:

Example 8

Tropical sage plant cv. "Scarlet sage" (about 29 cm high), planted in a 6-inch pot and infected with Bemisia argentifolii (BEMIAR), tripled to contain active substance I -4 (cis-isomer, formulation: 240 SC) of the active substance solution is soaked, and for comparison, a commercially available standard imidacloprid (240 SC) containing the application rate is also applied, the temperature of the greenhouse At 27-33 ° C, after 9, 13, 20, 34, and 41 days after application of the active substance, the activity against tadpoles on leaves was tested by means of the Henderson-Tilton method.

Example 9

On a small piece of cultivated land about 12 square meters in size that has been planted (47 days after sowing) with courgette plants, it is used in triplicate to combat Trialeurodes vaporarium (TRIAVA) in 100 ml of active substance I -4 (cis-isomer, formulation: 240 SC) drenches each plant, and for comparison, a commercially available standard imidacloprid (200 SL) containing the stated application rate is also applied, The application was performed four times at intervals of 10 days, and after 21, 31, 38, and 45 days after the first application of the active substance, its effectiveness was tested by means of Abbott's formula.

Example 10

Twelve tomato plants cv. "Briljant" each growing on rock wool were treated in quadruplicate and applied by drip application to combat Trialeurodes vaporarium (TRIAVA), using the active substance I-4 ( Cis isomer, formulation: 100 OD) of active substance solution, compared to the standard imidacloprid (70 WG) commercially available at the stated application rate, at a greenhouse temperature of 20 ° C, at intervals of 7 and 14 Treatment was performed three times a day, and after 14, 21, 28, 36, and 43 days after the first administration of the active substance, its efficacy was tested by means of Abbott's formula.

Scale insects

Excellent for controlling various scale insects from the family Coccidae in the following crops, preferably by foliar application:

Example 11

Coccus viridis , a gardenia flower plant cv. "Cape jasmine" (28 cm seedlings) planted in a 6-inch pot, has been infected three times with 150 ml of active substance I-4 (cis Formula isomers, formula: 240 SC) of active substance solution drenched, and commercially available standard imidacloprid (240 SC) and dinotefuran (20G) containing the application rate were also compared for comparison The temperature in the greenhouse was 27 ° C. After 7, 15, 21 and 35 days after the active substance was applied, the activity against the tadpoles on the leaves was tested by means of the Henderson-Tilton method.

Mealybugs and woollybugs (Pygmyidae)

Excellent for controlling various Mealybugs and woollybugs from the Pseudococcidae family in the following crops:

Example 12

Coleus plants in a 6-inch pot (approximately 29 cm in height) who had been infected with Pseudococcus citri (PSECCI) four weeks before being treated in triplicate to contain the active substance I- The active substance solution of 4 (cis isomer, formulation: 240 SC) was soaked. For comparison, a commercially available standard imidacloprid (240 SC) containing the application rate was also applied. The temperature of the greenhouse was At 29 ° C, after 7, 14, 21 and 28 days after administration of the active substance, the efficacy was tested by means of Abbott's formula.

Example 13

A Coleus plant (height about 29 cm) in a 6-inch pot, who had been infected with Madeira Phenacoccus madeirensis four weeks before the start of the experiment, in triplicate , containing the active substance I-4 ( Cis isomer, formula: 240 SC) The active substance solution was soaked. For comparison, a commercially available standard imidacloprid (240 SC) containing the application rate was also applied. The temperature in the greenhouse was 29 ° C. After 7, 14, 21 and 28 days after administration of the active substance, the efficacy was tested by means of Abbott's formula.

Leaf-mining flies (Flyidae)

Excellently used for controlling various kinds of larvae from the family Agromyzidae in the following crops:

Example 14

Treat small arable land about 2 x 5 meters in size with sweet peppers, in triplicate, to fight various larvae, wet with active substance solution containing active substance example (I-4) cis isomer (240 SC) The application rate of water was 700 liters per hectare. Three treatments were performed at intervals of 7 and 14 days, 7 days after the 2nd and 3rd treatments, and 14 days after the 3rd treatment. Kill rate of larvae.

Example 15

Treats small arable land about 2 x 5 meters in size with sweet peppers, in triplicate, for combating various whitefly ( Bemisia sp.) To contain active substance example (I-4) cis isomer (240 SC) The active substance solution was soaked, the application rate of water was 700 liters per hectare, and three treatments were performed at intervals of 7 and 14 days. After the 3rd treatment, each of the 7, 14, 21, and 28 days was evaluated on the leaves Of larvae killed.

Leaf bud nematodes (leaf nematodes)

It is also excellently used to control various organisms from the family Aphelenchoididae in the following crops:

Example 16

The bulbs of 15 lily plants cv. "LAGlow" (growth stage 14/16) were repeated four times, soaked in the desired concentration of the active substance containing the active substance I-4 (cis isomer, formula: 240 SC) The material solution was then implanted into a box of 40 x 60 cm. The bulbs were taken from a field that had been uniformly infected with Aphelenchoides fragariae . The number of infected plants was 92 days after the infiltration treatment. Determination.

Claims (18)

Use of a compound of formula (I), It is a mixture of their isomers or their pure isomers, in which the active substance is applied to the soil by drip, or dips to the roots, bulbs, or bulbs for the purpose of preventing Animal pests of the following groups: Aphididae, Pemphigidae, Tetranychidae, Tarsonemidae, Thripidae, Whiteflies (Aleyrodidae), Coccidae, Pseudococcidae, Agromyzidae, and Aphelenchoididae. Use according to claim 1, wherein the compound of formula (I) has the following structure Use according to claim 1, wherein the compound has the structure Use according to claim 1, wherein the compound has the structure Use according to any one of claims 1 to 4, wherein the treated plant line is grown on an artificial growth substrate. According to the application of claim 6, the artificial growth substrate is selected from the group consisting of rock wool, glass wool, quartz sand, gravel, expanded clay and vermiculite. The use according to any one of claims 1 to 4, wherein the treated plant line is planted in a closed system. Use according to any one of claims 1 to 4, wherein the plants to be treated are selected from the group consisting of vegetables, spices, ornamentals, conifers, cotton, citrus plants, fruit trees, tropical crops, nuts and vines . The use according to any one of claims 1 to 4 for controlling pests of the family Aphididae. The use according to any one of claims 1 to 4 for controlling pests of the family Aphididae (Pemphigidae). The use according to any one of claims 1 to 4 for controlling pests of the family Tetranychidae. The use according to any one of claims 1 to 4 for controlling pests of the family Tarsonemidae. The use according to any one of claims 1 to 4 for preventing pests of the Thripidae family. The use according to any one of claims 1 to 4 for controlling pests of the family Aleyrodidae. The use according to any one of claims 1 to 4 for controlling pests of the Coccidae family. The use according to any one of claims 1 to 4 for controlling pests of the family Pseudococcidae. Use according to any one of claims 1 to 4 for controlling pests of the family Agromyzidae. The use according to any one of claims 1 to 4 for controlling pests of the family Aphelenchoididae.