TWI579963B - Semiconductor device structure and method of fabricating same - Google Patents

Semiconductor device structure and method of fabricating same Download PDF

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TWI579963B
TWI579963B TW103145308A TW103145308A TWI579963B TW I579963 B TWI579963 B TW I579963B TW 103145308 A TW103145308 A TW 103145308A TW 103145308 A TW103145308 A TW 103145308A TW I579963 B TWI579963 B TW I579963B
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layer
over
film
molding
bump
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TW103145308A
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TW201535597A (en
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呂文雄
陳威宇
郭炫廷
鄭明達
劉重希
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台灣積體電路製造股份有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods

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  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Description

半導體元件結構及其製造方法 Semiconductor element structure and method of manufacturing same

本發明是關於一種半導體元件結構及其製造方法,特別是有關於一種具有互連結構之半導體元件及其製造方法。 The present invention relates to a semiconductor device structure and a method of fabricating the same, and more particularly to a semiconductor device having an interconnect structure and a method of fabricating the same.

半導體工業因不斷地改善多種電子元件(例如:電晶體、二極體、電阻與電容等)的集成密度而經歷快速的成長。多半來說,改善集成密度係利用不斷減小最小型體尺寸來達成,如此便能增加特定面積中的元件數目。隨著近期對更微小電子裝置的需求不斷增加,對微小化或更有創意的半導體晶粒封裝技術的需求也日益增加。 The semiconductor industry has experienced rapid growth due to continuous improvement in the integration density of various electronic components such as transistors, diodes, resistors and capacitors. For the most part, improving the integration density is achieved by continuously reducing the minimum body size, which increases the number of components in a particular area. As the demand for smaller electronic devices continues to increase in the near future, there is an increasing demand for miniaturization or more innovative semiconductor die packaging technology.

隨著半導體技術的演進,晶圓級晶片尺寸封裝(WLCSP)結構亦成為減小半導體元件物理尺寸的有效替代方式。在晶圓級晶片尺寸封裝(WLCSP)結構中,像是電晶體及類似物的主動元件係形成於晶圓級晶片尺寸封裝(WLCSP)結構中基板的上表面。 As semiconductor technology evolves, wafer level wafer size packaging (WLCSP) structures are also an effective alternative to reducing the physical size of semiconductor components. In a wafer level wafer size package (WLCSP) structure, active devices such as transistors and the like are formed on the upper surface of the substrate in a wafer level wafer size package (WLCSP) structure.

現行WLCSP製程包含二層聚亞醯胺(polyimide)層、一重佈線路層(redistribution layer, RDL)及一凸塊下金屬層(under bump metallization,UBM)所組成之四道遮罩結構,且其為一種高成本結構。除此之外,晶圓級晶片尺寸封裝的大型晶粒結構沒有焊料凸塊保護。 The current WLCSP process consists of a two-layer polyimide layer and a redistribution layer. RDL) and an under bump metallization (UBM) consist of four mask structures, and it is a high cost structure. In addition, the large grain structure of wafer level wafer size packages is not protected by solder bumps.

在一實施方式中,一種結構包含:鈍化層,位於基板之上方;介電層,位於鈍化層之上方;及後鈍化互連結構,位於介電層之上方,且後鈍化互連結構延伸穿過介電層,並電性連接至導電墊。前述之結構更包含凸塊,位於後鈍化互連結構之上方,且凸塊電性連接至後鈍化互連結構;模塑層,位於後鈍化互連結構之上方;以及保護層,位於該模塑層之上方。 In one embodiment, a structure includes: a passivation layer over the substrate; a dielectric layer over the passivation layer; and a post-passivation interconnect structure over the dielectric layer, and the post-passivation interconnect structure extends through Passing through the dielectric layer and electrically connecting to the conductive pad. The foregoing structure further includes a bump located above the post-passivation interconnect structure, and the bump is electrically connected to the post-passivation interconnect structure; the molding layer is located above the post-passivation interconnect structure; and the protective layer is located at the mold Above the plastic layer.

在另一實施方式中,一種結構包含:導電墊,置於基板上;鈍化層,位位於基板上方,且鈍化層具有一開口位於導電墊之上方;及後鈍化互連(post passivation interconnect,PPI)結構,位於該鈍化層之上方,並電性連接至該導電墊。前述之結構更包含模塑層,位於後鈍化互連結構之上方;以及保護層,位於模塑層之上方。 In another embodiment, a structure includes: a conductive pad disposed on a substrate; a passivation layer positioned over the substrate; and the passivation layer having an opening over the conductive pad; and a post passivation interconnect (PPI) a structure above the passivation layer and electrically connected to the conductive pad. The foregoing structure further includes a molding layer positioned over the post-passivation interconnect structure; and a protective layer over the molding layer.

在又一實施方式中,一種方法包含:提供基板,而基板具有導電墊置於其上;形成鈍化層於基板之上方,且鈍化層具有一開口位於導電墊之至少一部份之上方;形成介電層位於鈍化層之上方;及形成後鈍化互連結構於介電層之上方,且後鈍化互連結構延伸穿過介電層,並電性連接至導 電墊。前述之方法更包含:形成凸塊於後鈍化互連結構之上方,且凸塊電性連接至後鈍化互連結構;形成模塑層於後鈍化互連結構之上方;以及形成保護層於模塑層之上方。 In still another embodiment, a method includes: providing a substrate, wherein the substrate has a conductive pad disposed thereon; forming a passivation layer over the substrate; and the passivation layer has an opening over at least a portion of the conductive pad; forming a dielectric layer is over the passivation layer; and a post-passivation interconnect structure is formed over the dielectric layer, and the post-passivation interconnect structure extends through the dielectric layer and is electrically connected to the conductive layer Electric pad. The foregoing method further includes: forming a bump over the post-passivation interconnect structure, and the bump is electrically connected to the post-passivation interconnect structure; forming a molding layer over the post-passivation interconnect structure; and forming a protective layer on the mold Above the plastic layer.

100‧‧‧半導體元件 100‧‧‧Semiconductor components

101‧‧‧基板 101‧‧‧Substrate

103‧‧‧元件 103‧‧‧ components

105‧‧‧內層介電層 105‧‧‧ Inner dielectric layer

107‧‧‧下金屬層 107‧‧‧Under metal layer

109‧‧‧第一互連結構 109‧‧‧First interconnect structure

111‧‧‧上金屬層 111‧‧‧Upper metal layer

113‧‧‧第二互連結構 113‧‧‧Second interconnect structure

115‧‧‧鈍化層 115‧‧‧ Passivation layer

117‧‧‧導電墊 117‧‧‧Electrical mat

119‧‧‧後鈍化互連(PPI)結構 119‧‧‧ Post Passivation Interconnect (PPI) Structure

121‧‧‧第一介電層 121‧‧‧First dielectric layer

123‧‧‧阻隔層 123‧‧‧Barrier

125‧‧‧導電線 125‧‧‧Flexible wire

127‧‧‧凸塊 127‧‧‧Bumps

201‧‧‧液態模塑混合物(LMC)材料 201‧‧‧Liquid Molding Mixture (LMC) Materials

203‧‧‧剝離膜 203‧‧‧Release film

205‧‧‧金屬板 205‧‧‧Metal sheet

401‧‧‧模塑層 401‧‧‧Molding layer

403‧‧‧角度 403‧‧‧ angle

501‧‧‧薄膜 501‧‧‧film

601‧‧‧保護層 601‧‧ ‧ protective layer

701‧‧‧薄膜 701‧‧‧film

703‧‧‧紫外光膠層 703‧‧‧UV adhesive layer

705‧‧‧基層 705‧‧‧ grassroots

801‧‧‧保護層 801‧‧‧protection layer

901‧‧‧薄膜 901‧‧‧film

903‧‧‧第一聚合物層 903‧‧‧First polymer layer

905‧‧‧紫外光脫膜層 905‧‧‧UV stripping layer

907‧‧‧紫外光膠層 907‧‧‧UV adhesive layer

1001‧‧‧保護層 1001‧‧‧Protective layer

1101‧‧‧薄膜 1101‧‧‧film

1103‧‧‧紫外光膠層 1103‧‧‧UV adhesive layer

1105‧‧‧第一聚合物層 1105‧‧‧First polymer layer

1107‧‧‧紫外光脫膜層 1107‧‧‧UV stripping layer

1109‧‧‧第二聚合物層 1109‧‧‧Second polymer layer

1201‧‧‧保護層 1201‧‧‧Protective layer

1301‧‧‧步驟 1301‧‧‧Steps

1303‧‧‧步驟 1303‧‧‧Steps

1305‧‧‧步驟 1305‧‧‧Steps

1307‧‧‧步驟 1307‧‧‧Steps

1309‧‧‧步驟 1309‧‧‧Steps

1311‧‧‧步驟 1311‧‧‧Steps

本發明內容的實施方式可從下面的詳細描述並結合參閱附圖得到最佳的理解。要強調的是,按照在業界的標準實務做法,各種特徵不一定是按比例繪製。事實上,為了清楚的討論各種特徵的尺寸可任意放大或縮小。 The embodiments of the present invention can be best understood from the following detailed description and appended claims. It is emphasized that, in accordance with standard practice practices in the industry, various features are not necessarily drawn to scale. In fact, the dimensions of the various features may be arbitrarily enlarged or reduced for clarity of discussion.

第1-12圖係根據一些實施方式,繪示出形成一具有晶片尺寸封裝結構之半導體元件的各個中間階段之剖面圖。 1-12 are cross-sectional views showing various intermediate stages of forming a semiconductor component having a wafer size package structure, in accordance with some embodiments.

第13圖係根據一些實施方式,繪示出一具有晶片尺寸封裝結構之半導體元件的製造方法流程圖。 Figure 13 is a flow chart showing a method of fabricating a semiconductor device having a wafer size package structure, in accordance with some embodiments.

應該理解到,以下揭露的內容提供多種不同的實施方式或實例,用於實現本發明內容的不同特徵。元件和配置的具體實例描述如下以簡化本發明內容。當然,這些僅僅是例子而沒有進行限制的目的。此外,下面某一第一特徵形成在一第二特徵之上的描述可包括的實施方式為第一和第二特徵直接接觸形成,也可包括其他特徵介於第一與第二特徵之間,使得第一和第二特徵可以不直接接觸。除此之外,本發明內容於各個實例中可能用到重複的參考符號及/或用字。這些重複符號或用字係為了簡化與清晰的目的,並非用 以限定各個實施方式及/或所述結構之間的關係。 It should be understood that the following disclosure provides various embodiments or examples for implementing different features of the present invention. Specific examples of components and configurations are described below to simplify the present invention. Of course, these are just examples and are not intended to be limiting. Furthermore, the description that one of the following first features is formed over a second feature may include embodiments in which the first and second features are formed in direct contact, and other features may be included between the first and second features, The first and second features may be made in direct contact. In addition, the present disclosure may use repeated reference symbols and/or words in the various examples. These repeated symbols or words are not used for the sake of simplicity and clarity. To define the relationship between various embodiments and/or the structures.

另外,空間相對用語,如「下」、「低」、「上」等,是用以方便描述一元件或特徵與其他元件或特徵在圖式中的相對關係。這些空間相對用語旨在包含除了圖式中所示之方位以外,裝置在使用或操作時的不同方位。裝置可被另外定位(例如旋轉90度或其他方位),而本文所使用的空間相對敘述亦可相對應地進行解釋。 In addition, spatial relative terms, such as "lower", "lower", "upper", etc., are used to describe the relative relationship of an element or feature to other elements or features in the drawings. These spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation shown in the drawings. The device can be otherwise positioned (e.g., rotated 90 degrees or other orientation), and the spatially relative descriptions used herein can also be interpreted accordingly.

本發明內容將針對在特定環境中所描述之實施方式。一種具有晶片尺寸封裝結構之半導體元件的結構及其製造步驟。然而,本發明之實施方式亦可應用於各種半導體元件。在下文中,將伴隨著圖式詳細說明各種實施方式。 This summary is directed to the embodiments described in the specific context. A structure of a semiconductor element having a wafer size package structure and a manufacturing step thereof. However, embodiments of the present invention are also applicable to various semiconductor elements. Hereinafter, various embodiments will be described in detail with reference to the drawings.

第1-12圖係根據一些實施方式,繪示出形成一具有晶片尺寸封裝結構之半導體元件的各個中間階段之剖面圖。首先,參照第1圖,半導體元件100包含基板101,基板101的材質可為矽、矽鍺、碳化矽或其他類似物。或者,基板101可為矽絕緣體(silicon-on-insulator,SOI)基板。矽絕緣體基板可包含一層半導體材料(例如:矽、鍺及其類似物)形成於絕緣體層(例如:埋入氧化物或其類似物)之上方,而該絕緣層則形成於矽基板中。除此之外,其他可用的基板包含多層基板、梯度基板、複合指向基板或其他類似基板。 1-12 are cross-sectional views showing various intermediate stages of forming a semiconductor component having a wafer size package structure, in accordance with some embodiments. First, referring to FIG. 1, the semiconductor device 100 includes a substrate 101 which may be made of tantalum, niobium, tantalum carbide or the like. Alternatively, the substrate 101 may be a silicon-on-insulator (SOI) substrate. The germanium insulator substrate may comprise a layer of a semiconductor material (e.g., germanium, germanium, and the like) formed over the insulator layer (e.g., buried oxide or the like), and the insulating layer is formed in the germanium substrate. In addition, other useful substrates include multilayer substrates, gradient substrates, composite pointing substrates, or other similar substrates.

基板101更可包含多種元件103,此多種元件在第1圖中表示為單一電晶體。然而,元件103可包含多種主動及被動元件,例如:電晶體、二極體、電容、電阻、電感 器及其他類似物,而該主動及被動元件可用來產生基板101在設計上想要的結構或功能性需求。元件103可用任何適當方法形成於基板101之上或其中、或於一覆蓋的介電層之中。所屬技術領域具有通常知識者將理解,以上例子僅僅是用於說明實施方式,並不以任何方式限制揭露。 The substrate 101 may further comprise a plurality of elements 103, which are represented in Figure 1 as a single transistor. However, component 103 can include a variety of active and passive components such as transistors, diodes, capacitors, resistors, inductors And other analogs, and the active and passive components can be used to create the desired structural or functional requirements of the substrate 101. Element 103 can be formed on or in substrate 101 or in a covered dielectric layer by any suitable method. It will be understood by those skilled in the art that the above examples are merely illustrative of the embodiments and are not intended to limit the disclosure.

內層介電層(interlayer dielectric layer,ILD)105形成於基板101及元件103之上表面上,用來隔離元件103與隨後形成之金屬層。內層介電層105形成於基板101及元件103之上方,用來隔離元件103與隨後形成之金屬層。內層介電層105可包含二氧化矽、低K介電材料(介電係數低於二氧化矽之材料),例如:氮氧化矽、矽酸磷玻璃(phosphosilicate glass,PSG)、矽硼玻璃(borophosphosilicate glass,BPSG)、氟化矽酸鹽玻璃(fluorinated silicate glass,FSG)、有機矽酸玻璃(organosilicate glass,OSG)、SiOxCy、旋塗式玻璃、旋塗式聚合物、碳矽材料、或其化合物、混合物、組合物或其他類似物,並利用適當方法沉積,例如:旋轉塗佈、化學氣相沉積(chemical vapor deposition,CVD)電漿輔助化學氣相沉積(plasma-enhanced CVD,PECVD)或其他類似方法。多孔性的上述材料亦可使用。這些材料與製程是當作舉例,其他材料或製程亦可被使用。值得注意的是,所屬技術領域中具有通常知識者將理解內層介電層105更可包含複數個介電層。 An interlayer dielectric layer (ILD) 105 is formed on the upper surface of the substrate 101 and the element 103 for isolating the element 103 from the subsequently formed metal layer. An inner dielectric layer 105 is formed over the substrate 101 and the component 103 for isolating the component 103 from the subsequently formed metal layer. The inner dielectric layer 105 may comprise cerium oxide, a low-k dielectric material (a material having a lower dielectric constant than cerium oxide), for example: cerium oxynitride, phosphosilicate glass (PSG), bismuth boron silicate glass. (borophosphosilicate glass, BPSG), fluorinated silicate glass (FSG), organosilicate glass (OSG), SiO x C y , spin-on glass, spin-on polymer, carbonium Materials, or compounds, mixtures, compositions or the like, and deposited by suitable methods, such as spin coating, chemical vapor deposition (CVD) plasma-assisted chemical vapor deposition (plasma-enhanced CVD) , PECVD) or other similar methods. The above materials of porosity can also be used. These materials and processes are given as examples, and other materials or processes may also be used. It should be noted that those of ordinary skill in the art will appreciate that the inner dielectric layer 105 may further comprise a plurality of dielectric layers.

進一步參考第1圖,下金屬層107和上金屬層 111形成於內層介電層105之上方。而下金屬層107可包含第一互連結構109。同樣地,上金屬層111可包含第二互連結構113。第一互連結構109及第二互連結構113利用導電材料而形成,例如:銅、銀、金、鎢、鋁、其組合、其合金或其他類似導電材料。第一互連結構109及第二互連結構113可利用任何適當技術(例如:沉積、鑲嵌及其他類似方法)形成。為了說明目的,第1圖中所示之第一互連結構109及第二互連結構113係為單一導電線。在其他實施方式中,第一互連結構109及第二互連結構113可包含複數個導電線及通孔,且可具有符合半導體元件100設計規格的結構。通常來說,一或多內金屬介電層及相關的金屬層用來互連基板101中之每一元件103,以形成功能性電路及進一步提供外部電路的連接。 Further referring to FIG. 1, the lower metal layer 107 and the upper metal layer 111 is formed over the inner dielectric layer 105. The lower metal layer 107 can include a first interconnect structure 109. Likewise, the upper metal layer 111 can include the second interconnect structure 113. The first interconnect structure 109 and the second interconnect structure 113 are formed using a conductive material such as copper, silver, gold, tungsten, aluminum, combinations thereof, alloys thereof, or other similar conductive materials. The first interconnect structure 109 and the second interconnect structure 113 can be formed using any suitable technique (eg, deposition, damascene, and the like). For illustrative purposes, the first interconnect structure 109 and the second interconnect structure 113 shown in FIG. 1 are a single conductive line. In other embodiments, the first interconnect structure 109 and the second interconnect structure 113 may include a plurality of conductive lines and via holes, and may have a structure conforming to the design specifications of the semiconductor device 100. Generally, one or more inner metal dielectric layers and associated metal layers are used to interconnect each of the elements 103 in the substrate 101 to form a functional circuit and further provide a connection to an external circuit.

應該注意的是,當第1圖顯示下金屬層107與上金屬層111。所屬技術領域中具通常知識者將理解,一或多內金屬介電層(圖未顯示)及相關的金屬層(圖未顯示)可形成於下金屬層107及上金屬層111之間。特別地,介於下金屬層107與上金屬層111之間的各層可利用介電(舉例來說:極低K介電材料)或導電材料(舉例來說:銅)之替代層而形成。 It should be noted that the first metal layer 107 and the upper metal layer 111 are shown in FIG. It will be understood by those of ordinary skill in the art that one or more inner metal dielectric layers (not shown) and associated metal layers (not shown) may be formed between the lower metal layer 107 and the upper metal layer 111. In particular, the layers between the lower metal layer 107 and the upper metal layer 111 may be formed using a dielectric (for example, very low K dielectric material) or an alternative layer of a conductive material (for example, copper).

鈍化層115形成於上金屬層111之上表面。在一些實施方式中,鈍化層115可包含一或多層之二氧化矽、未參雜矽玻璃(undoped silicon glass,USG)、氮化矽(SiN)、氮氧化矽(SiON)、矽酸磷玻璃(PSG)、聚苯并噁唑 (polybenzoxazole,PBO)、苯并環丁烯(benzocyclobutene,BCB)、聚合物如聚醯亞胺、其化合物、其混和物、其組合物或其他類似物,並利用適當方法沉積,例如:旋轉塗佈、化學氣相沉積(CVD)與電漿輔助化學氣相沉積(PECVD)及其他類似方法。 A passivation layer 115 is formed on the upper surface of the upper metal layer 111. In some embodiments, the passivation layer 115 may comprise one or more layers of cerium oxide, undoped silicon glass (USG), tantalum nitride (SiN), cerium oxynitride (SiON), phosphoric acid phosphite glass. (PSG), polybenzoxazole (polybenzoxazole, PBO), benzocyclobutene (BCB), a polymer such as polyimine, a compound thereof, a mixture thereof, a composition thereof or the like, and deposited by a suitable method, for example, spin coating Cloth, chemical vapor deposition (CVD) and plasma assisted chemical vapor deposition (PECVD) and other similar methods.

進一步參考第1圖,一開口可形成於鈍化層115中。此開口用於容納鈍化層115中之導電墊117。特別地,導電墊117提供一個導電通道,位於半導體元件100中之第二互連結構113及後鈍化互連(PPI)結構119之間。此導電墊117可利用導電材料形成,例如:銅、銅合金、鋁、銀、金、任一其組合物及/或多層結構。導電墊117可用適當方法形成,例如:化學氣相沉積、濺鍍、電鍍及其他類似方法。 With further reference to FIG. 1, an opening may be formed in the passivation layer 115. This opening is for accommodating the conductive pad 117 in the passivation layer 115. In particular, the conductive pads 117 provide a conductive via between the second interconnect structure 113 and the post passivation interconnect (PPI) structure 119 in the semiconductor device 100. The conductive pads 117 can be formed using a conductive material such as copper, copper alloy, aluminum, silver, gold, any combination thereof, and/or multilayer structures. The conductive pads 117 can be formed by a suitable method such as chemical vapor deposition, sputtering, electroplating, and the like.

第一介電層121形成於鈍化層115之上表面。第一介電層121可利用環氧樹脂、聚醯亞胺及其他類似材料形成。另外,第一介電層121可用適當聚合物介電材料以形成,例如:聚苯并噁唑(PBO)及其類似材料。第一介電層121可用任何適當方法形成,例如:化學氣相沉積、旋轉塗佈及/或其類似方法。 The first dielectric layer 121 is formed on the upper surface of the passivation layer 115. The first dielectric layer 121 can be formed using an epoxy resin, a polyimide, and the like. Additionally, the first dielectric layer 121 may be formed of a suitable polymeric dielectric material, such as polybenzoxazole (PBO) and the like. The first dielectric layer 121 can be formed by any suitable method, such as chemical vapor deposition, spin coating, and/or the like.

如第1圖所示,後鈍化互連結構119形成於第一介電層121之上方。部分後鈍化互連結構119可延伸穿過第一介電層121以電連接到導電墊117。後鈍化互連結構119可包含阻隔層123和覆於阻隔層123之上的導電線125。後鈍化互連結構119連結半導體元件100輸入/輸出端點的導電墊117。特別地,後鈍化結構119提供一導電通道,介於 金屬層中之互連結構(例如:位於上金屬層111中之第二互連結構113)與半導體元件100之輸入/輸出端點間。在一些實施方式中,阻隔層123可利用像是化學氣相沉積、原子層沉積(atomic layer deposition,ALD)、其他類似方法或其組合而形成。阻隔層123可包含氮化物或氮氧化合物,例如氮化鈦、氮氧鈦化合物、氮化鉭、氮氧鉭化合物、氮化鎢、二氧化矽、其他類似物或其組合。導電線125可形成於阻隔層123之上方,其所利用之方法像是電化學電鍍製程(electro-chemical plating process)、化學氣相沉積、原子層沉積、物理氣相沉積(physical vapor deposition,PVD),其他類似方法或其組合。在一些實施方式中,導電線125可包含銅、鎢、鋁、銀、金、其他類似物或其組合。 As shown in FIG. 1, a post-passivation interconnect structure 119 is formed over the first dielectric layer 121. A portion of the post passivation interconnect structure 119 can extend through the first dielectric layer 121 to electrically connect to the conductive pads 117. The post passivation interconnect structure 119 can include a barrier layer 123 and a conductive line 125 overlying the barrier layer 123. The post passivation interconnect structure 119 connects the conductive pads 117 of the input/output terminals of the semiconductor device 100. In particular, the post passivation structure 119 provides a conductive path between An interconnection structure in the metal layer (for example, the second interconnection structure 113 located in the upper metal layer 111) is interposed between the input/output terminals of the semiconductor element 100. In some embodiments, the barrier layer 123 can be formed using, for example, chemical vapor deposition, atomic layer deposition (ALD), other similar methods, or a combination thereof. The barrier layer 123 may comprise a nitride or an oxynitride such as titanium nitride, a titanium oxynitride compound, tantalum nitride, an oxynitride compound, tungsten nitride, cerium oxide, the like, or a combination thereof. The conductive line 125 may be formed on the barrier layer 123 by a method such as an electro-chemical plating process, a chemical vapor deposition, an atomic layer deposition, or a physical vapor deposition (PVD). ), other similar methods or a combination thereof. In some embodiments, the conductive lines 125 can comprise copper, tungsten, aluminum, silver, gold, the like, or a combination thereof.

如第1圖所示,凸塊127安置在導電線125之上。在一些實施方式中,凸塊127可為焊球且可利用任何適當之材料形成,舉例來說,如SAC405。SAC405包含95.5%錫、4%銀與0.5%銅。在一些實施方式中,回流製程可應用於熔化凸塊127之下半部,以使凸塊127結合於導電線125上。 As shown in FIG. 1, the bumps 127 are disposed over the conductive lines 125. In some embodiments, the bumps 127 can be solder balls and can be formed using any suitable material, such as, for example, SAC405. SAC405 contains 95.5% tin, 4% silver and 0.5% copper. In some embodiments, a reflow process can be applied to the lower half of the bump 127 to bond the bump 127 to the conductive line 125.

將凸塊127安置在導電線125上的特色優勢是由於凸塊127直接結合於導電線125上可以減少晶圓級晶片尺寸封裝的製作成本。舉例來說,在傳統製作過程中,為了將凸塊安置於下凸塊金屬(under bump metallization,UBM)結構之上,依照一些實施方式可於後鈍化互連結構119的製作過程中形成四遮罩層。藉由使用前述之直接結合 技術,其用來形成下凸塊金屬層結構的遮罩層可被保留。進而達成可改善晶圓級晶片尺寸封裝的製作成本與信賴性之結果。 A special advantage of placing the bumps 127 on the conductive lines 125 is that the bumps 127 are directly bonded to the conductive lines 125 to reduce the fabrication cost of the wafer level wafer size package. For example, in a conventional fabrication process, in order to place the bumps on the under bump metallization (UBM) structure, four masks may be formed during the fabrication of the post-passivation interconnect structure 119 in accordance with some embodiments. Cover layer. Direct combination by using the aforementioned Techniques, the mask layer used to form the under bump metal layer structure can be retained. Further, the result is that the manufacturing cost and reliability of the wafer level wafer size package can be improved.

參考第2圖,一液態模塑混合物(liquid molding compound,LMC)材料201沉積於半導體元件100之上方。在一些實施方式中,液態模塑混合物材料201可包含,例如矽石混合環氧樹脂或其他類似物。依照一些實施方式,剝離膜203可用於壓製液態模塑混合物材料201。剝離膜203可用軟質材料形成,舉例來說,如乙烯-四氟乙烯共聚物(Ethylene Tetrafluoroethylene,ETFE)。在一些實施方式中,剝離膜203可貼覆於金屬板205上。 Referring to FIG. 2, a liquid molding compound (LMC) material 201 is deposited over the semiconductor device 100. In some embodiments, the liquid molding mixture material 201 can comprise, for example, a vermiculite mixed epoxy or the like. According to some embodiments, the release film 203 can be used to press the liquid molding mixture material 201. The release film 203 may be formed of a soft material such as, for example, Ethylene Tetrafluoroethylene (ETFE). In some embodiments, the release film 203 can be applied to the metal plate 205.

參照第3圖,當金屬板205被施加壓力,凸塊的一部分被壓製在剝離膜203之中。除此之外,剝離膜203可將部分液態模塑混合物材料201推離半導體元件100的上表面,結果使剝離膜203的下表面可低於凸塊127的上端。此外,液態模塑料混合材料201可被施加於固化製程。此固化製程可用於固化液態模塑混合物材料201以形成半導體元件100上方的模塑層。 Referring to Fig. 3, when the metal plate 205 is pressed, a part of the bump is pressed into the release film 203. In addition to this, the release film 203 can push the partial liquid molding mixture material 201 away from the upper surface of the semiconductor element 100, with the result that the lower surface of the release film 203 can be lower than the upper end of the bump 127. Further, the liquid molding compound mixed material 201 can be applied to a curing process. This curing process can be used to cure the liquid molding mixture material 201 to form a molding layer over the semiconductor component 100.

參照第4圖,將半導體元件100上方的剝離膜203移除以曝露出模塑層401與凸塊127。在一些實施方式中,凸塊127上表面可能有薄層的液態模塑混合物材料之殘留物(圖未顯示)。舉例來說,凸塊127上表面的液態模塑混合物材料之殘留物可藉由適當的蝕刻技術,如濕式或電漿蝕刻製程以將其移除。部份保留的模塑層401低於凸塊127的 最上表面。如第4圖所示,凸塊127被部分埋入在模塑層401之中。除了可能在凸塊127附近有斜面之外,模塑層401的上表面是近乎平坦。模塑層401平坦部分的形成厚度大約在40至150微米之間。模塑層401的斜面與上表面可形成一角度403。在一些實施方式中,角度403的範圍可在大約30至70度之間。 Referring to FIG. 4, the release film 203 over the semiconductor element 100 is removed to expose the molding layer 401 and the bumps 127. In some embodiments, the upper surface of the bump 127 may have a thin layer of residue of the liquid molding mixture material (not shown). For example, the residue of the liquid molding mixture material on the upper surface of the bump 127 can be removed by a suitable etching technique, such as a wet or plasma etching process. The partially retained molding layer 401 is lower than the bump 127 The top surface. As shown in Fig. 4, the bumps 127 are partially buried in the molding layer 401. The upper surface of the molding layer 401 is nearly flat except that there may be a bevel near the bumps 127. The flat portion of the molding layer 401 is formed to a thickness of between about 40 and 150 microns. The bevel of the molding layer 401 may form an angle 403 with the upper surface. In some embodiments, the angle 403 can range between about 30 and 70 degrees.

具有模塑層401的特色優勢是模塑層401可做為凸塊127及半導體元件100之其他部分的保護層,保護其不受熱、震動、濕氣與腐蝕之影響。除此之外,模塑層401亦可防止凸塊127在信賴性測試中龜裂,例如熱循環試驗。此外,模塑層401可幫助減少半導體元件100製作過程中的機械或熱應力。 A feature advantage of having the molding layer 401 is that the molding layer 401 can serve as a protective layer for the bumps 127 and other portions of the semiconductor component 100 to protect them from heat, vibration, moisture, and corrosion. In addition to this, the molding layer 401 can also prevent the bumps 127 from cracking in the reliability test, such as a thermal cycle test. Further, the molding layer 401 can help reduce mechanical or thermal stress during the fabrication of the semiconductor component 100.

在一些實施方式中,保護半導體元件100,仍需要模塑層401以外的保護層。舉例來說,模塑層401可具有讓水或其他汙染物通過至後鈍化互連結構119的空洞(圖未顯示),而此會造成例如腐蝕損傷,並導致附近的後鈍化互連層結構之間短路。在一些實施方式中,模塑層401可具有平均尺寸大約15微米的空洞。在一些實施方式中,模塑層401可具有平均尺寸大約40微米的空洞。半導體元件100可能沒通過信賴性測試,例如模擬嚴重溫度與濕氣環境的蒸汽鍋測試(Pressure Cooker Test,PCT)。在一些實施方式中,將半導體元件100浸入121℃ 168小時、相對濕度100%與2大氣壓力的蒸汽鍋測試。如下更詳細的描述中,保護膜可形成於模塑層之上方以封住模塑層401的空洞與 保護半導體元件100不受嚴苛環境效應的影響。 In some embodiments, protecting the semiconductor component 100 still requires a protective layer other than the molding layer 401. For example, the molding layer 401 can have voids (not shown) that pass water or other contaminants through the post-passivation interconnect structure 119, which can cause, for example, corrosion damage and result in a nearby post-passivation interconnect layer structure. Short circuit between. In some embodiments, the molding layer 401 can have voids having an average size of about 15 microns. In some embodiments, the molding layer 401 can have voids having an average size of about 40 microns. The semiconductor component 100 may not pass a reliability test, such as a Pressure Cooker Test (PCT) that simulates a severe temperature and humidity environment. In some embodiments, the semiconductor component 100 is immersed in a steam pot test at 121 ° C for 168 hours, relative humidity of 100% and 2 atmospheres. In a more detailed description below, a protective film may be formed over the molding layer to seal the voids of the molding layer 401. The semiconductor component 100 is protected from harsh environmental effects.

如下更詳細的描述中,保護膜形成於模塑層401之上方。在一些實施方式中,塗佈一薄膜在模塑層401與凸塊127之上方。隨後移除此薄膜並將殘留物留置於模塑層401上方以形成保護層。在一些實施方式中,保護層可填補模塑層401的空洞並可防止水或其他汙染物穿過模塑層401至後鈍化互連結構119。此薄膜可具有一或多層、或一或多組態的材料各別塗佈而成,並可包含非導電材料,例如聚合物、樹脂、絕緣體、或其他類似物。在一些實施方式中,薄膜可為紫外光型。紫外光型的薄膜更可包含紫外光剝離膠層。通常來說,紫外光剝離膠曝露於紫外光下後,其黏合強度會降低,於是可輕易移除此薄膜,舉例來說,將其從半導體元件100上剝離。 In a more detailed description below, a protective film is formed over the molding layer 401. In some embodiments, a film is applied over molding layer 401 and bumps 127. This film is then removed and the residue is left over the molding layer 401 to form a protective layer. In some embodiments, the protective layer can fill the voids of the molding layer 401 and can prevent water or other contaminants from passing through the molding layer 401 to the post-passivation interconnect structure 119. The film may be coated with one or more layers, or one or more configurations, and may comprise a non-conductive material such as a polymer, resin, insulator, or the like. In some embodiments, the film can be of the ultraviolet light type. The ultraviolet light type film may further comprise an ultraviolet light release adhesive layer. In general, when the ultraviolet light-peeling adhesive is exposed to ultraviolet light, its adhesive strength is lowered, so that the film can be easily removed, for example, by peeling it off from the semiconductor element 100.

在其他實施方式中,薄膜可為非紫外光型。舉例來說,在一些實施方式中,薄膜包含熱塑性聚合物層。非紫外光型的薄膜可用高溫(60℃~80℃)製程塗佈於半導體元件100之上方以軟化熱塑性聚合物層。當溫度下降至室溫,薄膜可穩固的附著於半導體元件100之上方。在一些實施方式中,薄膜501可為背面減薄膠帶(紫外光或非紫外光型),而其可在基板減薄過程中用來保護半導體元件100不受磨碎碎片之傷害。使用包含背面減薄膠帶之薄膜的特色優點是,僅需利用同一薄膜即可用於晶圓薄化製程與形成保護層之步驟上。組合上述製作過程可減少半導體製作的成本。 In other embodiments, the film can be of a non-ultraviolet light type. For example, in some embodiments, the film comprises a layer of thermoplastic polymer. The non-UV type film can be applied over the semiconductor element 100 by a high temperature (60 ° C to 80 ° C) process to soften the thermoplastic polymer layer. When the temperature is lowered to room temperature, the film can be firmly attached over the semiconductor element 100. In some embodiments, the film 501 can be a backside thinned tape (ultraviolet or non-UV type) that can be used to protect the semiconductor component 100 from grinding debris during substrate thinning. The advantage of using a film comprising a backside thinned tape is that the same film can be used for the wafer thinning process and the step of forming a protective layer. Combining the above fabrication process can reduce the cost of semiconductor fabrication.

首先參照第5、6圖,其係根據一些實施方式繪 示出形成保護層之第一種方法,第5圖繪示出薄膜501,如熱塑性聚合物,利用如滾柱(圖未顯示)塗佈於半導體元件100之上方。對於薄膜501,前述滾柱可提供一介於約0.3兆帕(MPa)至約0.5兆帕(MPa)之壓力,及一介於約30℃至約100℃之溫度。在一些實施方式中,如第5圖所示,薄膜501可具有足夠的厚度,以完全地覆蓋凸塊127。 Referring first to Figures 5 and 6, which are drawn in accordance with some embodiments A first method of forming a protective layer is shown, and FIG. 5 illustrates a film 501, such as a thermoplastic polymer, coated over the semiconductor component 100 using, for example, a roller (not shown). For film 501, the roller can provide a pressure of between about 0.3 megapascals (MPa) and about 0.5 megapascals (MPa), and a temperature of between about 30 ° C and about 100 ° C. In some embodiments, as shown in FIG. 5, the film 501 can have a sufficient thickness to completely cover the bumps 127.

參照第6圖,舉例來說,利用剝離位於膜塑料層401之薄膜501,以移除半導體元件100上之部分的薄膜(見第5圖)。在一些實施方式中,薄膜501留下之殘留物包含熱塑性聚合物,置於膜塑料層401及凸塊127上。前述薄膜501之殘留物密封膜塑料層401的空洞,以形成膜塑料層401之上方之保護層601。前述保護層601保護膜塑料層401,並使其下方各層不受環境效應(如潮濕)之影響。 Referring to Fig. 6, for example, the film 501 located on the film plastic layer 401 is peeled off to remove a portion of the film on the semiconductor element 100 (see Fig. 5). In some embodiments, the residue left by film 501 comprises a thermoplastic polymer disposed on film plastic layer 401 and bumps 127. The residue of the film 501 seals the void of the film plastic layer 401 to form a protective layer 601 above the film plastic layer 401. The protective layer 601 protects the film plastic layer 401 and protects the layers below it from environmental effects such as moisture.

在一些實施方式中,電漿清潔的製程是選擇性塗佈於凸塊127以移除位於凸塊127上表面之所有薄膜501的殘留材料(見第5圖)。電漿清潔製程亦可移除保護層601的部分上表面。在一實施方式中,電漿清潔製程係利用氧氣電漿或其他相似製程,在鈍氣環境,例如氮氣、氬氣、或其他相似氣體中進行。在一些實施方式中,保護層601包含熱塑性聚合物且可形成一介於約0.5微米至約50微米的厚度。 In some embodiments, the plasma cleaning process is selectively applied to the bumps 127 to remove residual material from all of the films 501 located on the upper surface of the bumps 127 (see Figure 5). The plasma cleaning process also removes a portion of the upper surface of the protective layer 601. In one embodiment, the plasma cleaning process is performed in an inert gas environment, such as nitrogen, argon, or the like, using oxygen plasma or other similar process. In some embodiments, the protective layer 601 comprises a thermoplastic polymer and can form a thickness of between about 0.5 microns and about 50 microns.

參照第7、8圖,根據一些實施方式,繪示出形成保護層的第二種方法。進一步參照第7圖,薄膜701包含厚度大約40微米的紫外光膠層703與厚度大約50微米的基層705位於紫外光膠層703之上方。在一些實施方式中,薄 膜701更可包含一大約350微米厚度之選擇性樹脂層(圖未顯示),介於紫外光膠層703與基層705之間。基層705可包含聚合物材料如聚酯纖維、聚丙烯(polypropylene,PP)、聚對苯二甲酸乙二醇酯(polyethylene terephthalate,PET)、與其他類似物。 Referring to Figures 7 and 8, a second method of forming a protective layer is illustrated in accordance with some embodiments. With further reference to FIG. 7, film 701 comprises a UV adhesive layer 703 having a thickness of about 40 microns and a base layer 705 having a thickness of about 50 microns above the UV adhesive layer 703. In some embodiments, thin The film 701 may further comprise an optional resin layer (not shown) having a thickness of about 350 microns between the ultraviolet adhesive layer 703 and the base layer 705. The base layer 705 may comprise a polymeric material such as polyester fibers, polypropylene (PP), polyethylene terephthalate (PET), and the like.

舉例來說,薄膜701可利用滾柱(圖未顯示)塗佈於半導體元件100之上方。對於薄膜701,前述滾柱可提供一介於約0.3兆帕(MPa)至約0.5兆帕(MPa)之壓力,及一介於約30℃至約100℃之溫度。前述薄膜701可被壓入模塑層401的空洞,且紫外光膠層703之紫外光膠材可填補模塑層401的空洞。如第7圖所示,薄膜701可具有足夠的厚度,以完全地覆蓋凸塊127。 For example, the film 701 can be coated over the semiconductor component 100 using rollers (not shown). For film 701, the rollers can provide a pressure of between about 0.3 MPa to about 0.5 MPa and a temperature of between about 30 ° C and about 100 ° C. The foregoing film 701 can be pressed into the void of the molding layer 401, and the ultraviolet adhesive of the ultraviolet adhesive layer 703 can fill the void of the molding layer 401. As shown in FIG. 7, the film 701 may have a sufficient thickness to completely cover the bumps 127.

參照第8圖,舉例來說,將薄膜701曝露於紫外光輻射後,利用剝離位於膜塑料層401與凸塊127之薄膜701,以移除半導體元件100上之部分的薄膜701(見第7圖)。在一些實施方式中,薄膜701留下之殘留物,包含在模塑層401與凸塊127上之紫外光膠層703的紫外光膠材料。薄膜701可在模塑層401上留下比在凸塊127上更大量的殘留物,因為紫外光膠層703與模塑層401的黏合強度遠大於紫外光膠層703與凸塊127的黏合強度。如第8圖所示,前述薄膜701之殘留物密封膜塑料層401的空洞,以形成膜塑料層401之上方之保護層801。前述保護層801會保護膜塑料層401,並使其下方各層不受環境效應(如潮濕)之影響。 Referring to FIG. 8, for example, after exposing the film 701 to ultraviolet radiation, the film 701 located on the film plastic layer 401 and the bump 127 is peeled off to remove a portion of the film 701 on the semiconductor device 100 (see section 7). Figure). In some embodiments, the film 701 remains as a residue, comprising an ultraviolet gel material of the UV adhesive layer 703 on the molding layer 401 and the bumps 127. The film 701 can leave a larger amount of residue on the molding layer 401 than on the bumps 127 because the adhesion strength of the ultraviolet adhesive layer 703 to the molding layer 401 is much greater than the adhesion of the ultraviolet adhesive layer 703 to the bumps 127. strength. As shown in Fig. 8, the residue of the film 701 seals the void of the film plastic layer 401 to form a protective layer 801 above the film plastic layer 401. The protective layer 801 protects the film plastic layer 401 and protects the layers below it from environmental effects such as moisture.

在一些實施方式中,電漿清潔的製程是選擇性塗佈於凸塊127以移除所有薄膜701的殘留材料。電漿清潔製程亦可移除保護層801的部分上表面。在一實施方式中,電漿清潔製程係利用氧氣電漿或其他相似製程,在鈍氣環境,例如氮氣、氬氣、或其他相似氣體中進行。在一些實施方式中,保護層801包含紫外光膠材且可形成一介於約0.5微米至約50微米的厚度。 In some embodiments, the plasma cleaning process is selectively applied to the bumps 127 to remove residual material from all of the films 701. The plasma cleaning process also removes a portion of the upper surface of the protective layer 801. In one embodiment, the plasma cleaning process is performed in an inert gas environment, such as nitrogen, argon, or the like, using oxygen plasma or other similar process. In some embodiments, the protective layer 801 comprises an ultraviolet light gel and can form a thickness of between about 0.5 microns and about 50 microns.

參照第9、10圖,根據一些實施方式,繪示出形成保護層的第三種方法。進一步參照第9圖,薄膜901可包含紫外光脫膜層905,介於第一聚合物層903與第二聚合物層907之間。紫外光脫膜層905可包含與前述第7圖所述之紫外光膠層703相似之材料。在一些實施方式中,第一聚合物層903為熱塑性聚合物材料,而第二聚合物層907則為聚合物材料如聚酯纖維、聚丙烯(polypropylene,PP)、聚對苯二甲酸乙二醇酯(polyethylene terephthalate,PET)、與其他類似物。 Referring to Figures 9, 10, a third method of forming a protective layer is illustrated in accordance with some embodiments. Referring further to FIG. 9, the film 901 can include an ultraviolet light release layer 905 between the first polymer layer 903 and the second polymer layer 907. The ultraviolet light release layer 905 may comprise a material similar to the ultraviolet light adhesive layer 703 described in the aforementioned seventh embodiment. In some embodiments, the first polymer layer 903 is a thermoplastic polymer material, and the second polymer layer 907 is a polymer material such as polyester fiber, polypropylene (PP), polyethylene terephthalate. Polyethylene terephthalate (PET), and other analogs.

舉例來說,薄膜901可利用滾柱(圖未顯示)塗佈於半導體元件100之上方。對於薄膜901,前述滾柱可提供一介於約0.3兆帕(MPa)至約0.5兆帕(MPa)之壓力,及一介於約30℃至約100℃之溫度。前述薄膜901可被壓入模塑層401的空洞,且第一聚合物層903之熱塑性材料可填補模塑層401的空洞。如第9圖所示,薄膜901可具有足夠的厚度,以完全地覆蓋凸塊127。在一些實施方式中,如第9圖所示,第一聚合物層903不存在於凸塊127及紫外光脫膜層905之 間,且凸塊127之上表面可與紫外光脫膜層905接觸。 For example, the film 901 can be coated over the semiconductor component 100 using a roller (not shown). For film 901, the roller can provide a pressure of between about 0.3 megapascals (MPa) and about 0.5 megapascals (MPa), and a temperature of between about 30 ° C and about 100 ° C. The foregoing film 901 can be pressed into the void of the molding layer 401, and the thermoplastic material of the first polymer layer 903 can fill the void of the molding layer 401. As shown in Fig. 9, the film 901 may have a sufficient thickness to completely cover the bumps 127. In some embodiments, as shown in FIG. 9, the first polymer layer 903 is not present in the bump 127 and the ultraviolet light release layer 905. Meanwhile, the upper surface of the bump 127 may be in contact with the ultraviolet light release layer 905.

參照第10圖,舉例來說,將薄膜901曝露於紫外光輻射後,利用剝離位於第一聚合物層903及凸塊127之第二聚合物層907,以移除半導體元件100上薄膜901中之第二聚合物層907(見第9圖)。如第10圖所示,薄膜901所留下之第一聚合物層903會形成保護層1001於模塑層401之上方。前述保護層1001會保護膜塑料層401,並使其下方各層不受環境效應(如潮濕)之影響。 Referring to FIG. 10, for example, after exposing the film 901 to ultraviolet radiation, the second polymer layer 907 located on the first polymer layer 903 and the bumps 127 is peeled off to remove the film 901 on the semiconductor device 100. The second polymer layer 907 (see Figure 9). As shown in FIG. 10, the first polymer layer 903 left by the film 901 forms a protective layer 1001 over the molding layer 401. The protective layer 1001 protects the film plastic layer 401 and protects the layers below it from environmental effects such as moisture.

在一些實施方式中,電漿清潔的製程是選擇性塗佈於凸塊127以移除所有薄膜901的殘留材料,例如紫外光脫膜層905的材料及第一聚合物層903的材料。電漿清潔製程亦可移除保護層1001的部分上表面。因此,對於電漿清潔製程所損失的材料,薄膜901中之第一聚合物層903可提供一初始厚度足以補償前述所損失的材料。在一實施方式中,電漿清潔製程係利用氧氣電漿或其他相似製程,在鈍氣環境,例如氮氣、氬氣、或其他相似氣體中進行。在一些實施方式中,如前述第9圖所述之薄膜901的多層結構,可於模塑層401之上方提供一個較好控制厚度之保護層1001。在一些實施方式中,保護層1001包含熱塑性聚合物且可形成一介於約0.5微米至約50微米的厚度。 In some embodiments, the plasma cleaning process is selectively applied to bumps 127 to remove residual material from all of the film 901, such as the material of the ultraviolet light release layer 905 and the material of the first polymer layer 903. The plasma cleaning process also removes a portion of the upper surface of the protective layer 1001. Thus, for materials lost by the plasma cleaning process, the first polymer layer 903 in the film 901 can provide an initial thickness sufficient to compensate for the aforementioned loss of material. In one embodiment, the plasma cleaning process is performed in an inert gas environment, such as nitrogen, argon, or the like, using oxygen plasma or other similar process. In some embodiments, the multilayer structure of the film 901 as described in the above-mentioned FIG. 9 can provide a protective layer 1001 of a better thickness control over the molding layer 401. In some embodiments, the protective layer 1001 comprises a thermoplastic polymer and can form a thickness of between about 0.5 microns and about 50 microns.

參照第11、12圖,根據一些實施方式,繪示出形成保護層的第四種方法。進一步參照第11圖,薄膜1101可包含紫外光膠層1103、於紫外光膠層1103上方之第一聚合物層1105、於第一聚合物層1105上方之紫外光脫膜層 1107,及於紫外光脫膜層1107上方之第二聚合物層1109。紫外光脫膜層1107可包含與前述第7圖所述之紫外光膠層703相似之材料。在一些實施方式中,第一聚合物層1105及第二聚合物層1109可包含聚酯纖維、聚丙烯(polypropylene,PP)、聚對苯二甲酸乙二醇酯(polyethylene terephthalate,PET)、與其他類似物。 Referring to Figures 11 and 12, a fourth method of forming a protective layer is illustrated in accordance with some embodiments. Referring further to FIG. 11, the film 1101 may include an ultraviolet adhesive layer 1103, a first polymer layer 1105 over the ultraviolet adhesive layer 1103, and an ultraviolet light release layer over the first polymer layer 1105. 1107, and a second polymer layer 1109 above the ultraviolet light release layer 1107. The ultraviolet light release layer 1107 may comprise a material similar to the ultraviolet light adhesive layer 703 described in the aforementioned seventh embodiment. In some embodiments, the first polymer layer 1105 and the second polymer layer 1109 may comprise polyester fibers, polypropylene (PP), polyethylene terephthalate (PET), and Other analogues.

舉例來說,薄膜1101可利用滾柱(圖未顯示)塗佈於半導體元件100之上方。對於薄膜1101,前述滾柱可提供一介於約0.3兆帕(MPa)至約0.5兆帕(MPa)之壓力,及一介於約30℃至約100℃之溫度。前述薄膜1101可被壓入模塑層401的空洞,且紫外光膠層1103之紫外光膠材可填補模塑層401的空洞。如第11圖所示,薄膜1101可具有足夠的厚度,以完全地覆蓋凸塊127。在一些實施方式中,如第11圖所示,紫外光膠層1103及第一聚合物層1105不存在於凸塊127及紫外光脫膜層1107之間,且凸塊127之上表面可與紫外光脫膜層1107接觸。 For example, the film 1101 can be coated over the semiconductor component 100 using a roller (not shown). For film 1101, the roller can provide a pressure of between about 0.3 MPa to about 0.5 MPa and a temperature of between about 30 ° C and about 100 ° C. The foregoing film 1101 can be pressed into the void of the molding layer 401, and the ultraviolet adhesive of the ultraviolet adhesive layer 1103 can fill the void of the molding layer 401. As shown in FIG. 11, the film 1101 may have a sufficient thickness to completely cover the bumps 127. In some embodiments, as shown in FIG. 11, the ultraviolet adhesive layer 1103 and the first polymer layer 1105 are not present between the bump 127 and the ultraviolet light release layer 1107, and the upper surface of the bump 127 can be The ultraviolet light release layer 1107 is in contact.

參照第12圖,舉例來說,將薄膜1101曝露於紫外光輻射並固化紫外光脫膜層1107後,利用剝離位於第一聚合物層1105及凸塊127之第二聚合物層1109,以移除半導體元件100上薄膜1101中之第二聚合物層1109(見第11圖)。如第12圖所示,薄膜1101所留下之紫外光膠層1103及第一聚合物層1105會形成保護層1201於模塑層401之上方。前述保護層1201會保護膜塑料層401,並使其下方各層不受環境效應(如潮濕)之影響。 Referring to FIG. 12, for example, after the film 1101 is exposed to ultraviolet radiation and the ultraviolet light release layer 1107 is cured, the second polymer layer 1109 located on the first polymer layer 1105 and the bumps 127 is peeled off to be removed. In addition to the second polymer layer 1109 in the film 1101 on the semiconductor component 100 (see Figure 11). As shown in FIG. 12, the ultraviolet adhesive layer 1103 and the first polymer layer 1105 left by the film 1101 form a protective layer 1201 over the molding layer 401. The protective layer 1201 protects the film plastic layer 401 and protects the layers below it from environmental effects such as moisture.

電漿清潔的製程是選擇性塗佈於凸塊127以移除所有薄膜1101的殘留材料,例如紫外光膠層1103的材料、紫外光脫膜層1107的材料,及第一聚合物層1105。電漿清潔製程亦可移除保護層1201的部分上表面。因此,對於電漿清潔製程所損失的材料,薄膜1101中之第一聚合物層1105可提供一初始厚度足以補償前述所損失的材料。在一實施方式中,電漿清潔製程係利用氧氣電漿或其他相似製程,在鈍氣環境,例如氮氣、氬氣、或其他相似氣體中進行。在一些實施方式中,如前述第11圖所述之薄膜1101的多層結構,可於模塑層401之上方提供一個較好控制厚度之保護層1201。在一些實施方式中,保護層1201包含紫外光膠層1103及第一聚合物層1105,並可形成一介於約0.5微米至約50微米的厚度。 The plasma cleaning process is selectively applied to the bumps 127 to remove residual material of all of the thin films 1101, such as the material of the ultraviolet adhesive layer 1103, the material of the ultraviolet light release layer 1107, and the first polymer layer 1105. The plasma cleaning process can also remove portions of the upper surface of the protective layer 1201. Thus, for materials lost by the plasma cleaning process, the first polymer layer 1105 in the film 1101 can provide an initial thickness sufficient to compensate for the aforementioned loss of material. In one embodiment, the plasma cleaning process is performed in an inert gas environment, such as nitrogen, argon, or the like, using oxygen plasma or other similar process. In some embodiments, the multilayer structure of the film 1101 as described in the aforementioned FIG. 11 can provide a protective layer 1201 of a better thickness control over the molding layer 401. In some embodiments, the protective layer 1201 comprises a UV adhesive layer 1103 and a first polymer layer 1105 and can form a thickness of between about 0.5 microns and about 50 microns.

第13圖係根據一些實施方式,繪示出一具有晶片尺寸封裝結構之半導體元件的製造方法流程圖。此方法開始於步驟1301,其中後鈍化互連結構(PPI)形成於半導體元件基板之上(參照前述第1圖之說明)。在步驟1303,凸塊形成於後鈍化互連結構之上方(參照前述第1圖之說明)。在步驟1305,液態模塑混合物材料(LMC)塗佈於後鈍化互連結構及凸塊之上方(參照前述第2圖之說明)。隨後,進行液態模塑混合物材料的壓製過程及固化製程,以形成模塑層於後鈍化互連結構之上方(參照前述第2-4圖之說明)。在步驟1307,使用滾柱將薄膜塗佈於模塑層及凸塊之上方(參照前述第5、7、9、11圖之說明)。在步驟1309,將位於模塑層 及凸塊上方之薄膜或部份薄膜移除,使位於模塑層上剩餘之薄膜材料形成保護層(參照前述第6、8、10、12圖之說明)。最後,在步驟1311,進行電漿清潔以移除凸塊上表面剩餘之薄膜材料(參照前述第6、8、10、12圖之說明)。 Figure 13 is a flow chart showing a method of fabricating a semiconductor device having a wafer size package structure, in accordance with some embodiments. The method begins in step 1301, in which a post-passivation interconnect structure (PPI) is formed over a semiconductor device substrate (see the description of FIG. 1 above). At step 1303, a bump is formed over the post-passivation interconnect structure (see the description of FIG. 1 above). At step 1305, a liquid molding mixture material (LMC) is applied over the post-passivation interconnect structure and over the bumps (see description of Figure 2 above). Subsequently, a pressing process and a curing process of the liquid molding mixture material are performed to form a molding layer over the post-passivation interconnect structure (refer to the description of Figures 2-4 above). At step 1307, the film is applied over the molding layer and the bumps using rollers (see the description of Figures 5, 7, 9, and 11 above). At step 1309, the mold layer will be located. And removing the film or part of the film above the bump to form a protective layer on the film material remaining on the molding layer (refer to the description of Figures 6, 8, 10, and 12 above). Finally, in step 1311, plasma cleaning is performed to remove the remaining film material on the upper surface of the bump (see the description of Figures 6, 8, 10, and 12 above).

前面已概述了一些實施方式的特徵,使得本技術領域中具有通常知識者可以更佳理解其中的詳細描述。本技術領域中具有通常知識者應當理解,其可以容易使用本發明內容作為用於實現相同目的及/或實現本文中所介紹的實施方式中相同的優點設計或修改其他過程和結構基礎。本技術領域中具有通常知識者也應該認識到,此類等效構造不脫離本發明內容中所揭露的精神和範圍,並且可以對其進行各種改變,替代和變更,而不脫離本發明內容之精神和範圍。 The features of some embodiments have been summarized above, so that those skilled in the art can better understand the detailed description. It will be appreciated by those of ordinary skill in the art that the present invention can be readily utilized as a basis for the same purpose and/or implementation of the same advantages in the embodiments described herein. It is also to be understood by those skilled in the art that such equivalents are not to be Spirit and scope.

100‧‧‧半導體元件 100‧‧‧Semiconductor components

101‧‧‧基板 101‧‧‧Substrate

103‧‧‧元件 103‧‧‧ components

105‧‧‧內層介電層 105‧‧‧ Inner dielectric layer

107‧‧‧下金屬層 107‧‧‧Under metal layer

109‧‧‧第一互連結構 109‧‧‧First interconnect structure

111‧‧‧上金屬層 111‧‧‧Upper metal layer

113‧‧‧第二互連結構 113‧‧‧Second interconnect structure

115‧‧‧鈍化層 115‧‧‧ Passivation layer

117‧‧‧導電墊 117‧‧‧Electrical mat

119‧‧‧後鈍化互連(PPI)結構 119‧‧‧ Post Passivation Interconnect (PPI) Structure

121‧‧‧第一介電層 121‧‧‧First dielectric layer

123‧‧‧阻隔層 123‧‧‧Barrier

125‧‧‧導電線 125‧‧‧Flexible wire

127‧‧‧凸塊 127‧‧‧Bumps

401‧‧‧模塑層 401‧‧‧Molding layer

601‧‧‧保護層 601‧‧ ‧ protective layer

Claims (9)

一種半導體元件結構,包含:一鈍化層,位於一基板之上方;一介電層,位於該鈍化層之上方;一後鈍化互連結構,位於該介電層之上方,且該後鈍化互連結構延伸穿過該介電層,並電性連接至一導電墊;一凸塊,位於該後鈍化互連結構之上方,且該凸塊直接接觸並電性連接該後鈍化互連結構;一模塑層,位於該後鈍化互連結構之上方;以及一保護層,位於該模塑層之上方。 A semiconductor device structure comprising: a passivation layer over a substrate; a dielectric layer over the passivation layer; a post passivation interconnect structure over the dielectric layer, and the post passivation interconnect The structure extends through the dielectric layer and is electrically connected to a conductive pad; a bump is located above the back passivation interconnect structure, and the bump directly contacts and electrically connects the post passivation interconnect structure; a molding layer over the post passivation interconnect structure; and a protective layer over the molding layer. 一種半導體元件結構,包含:一導電墊,置於一基板上;一鈍化層,位於該基板上方,且該鈍化層具有一開口位於該導電墊之上方;一後鈍化互連結構,位於該鈍化層之上方,並電性連接至該導電墊;一凸塊,位於該後鈍化互連結構之上方,且該凸塊直接接觸並電性連接該後鈍化互連結構;一模塑層,位於該後鈍化互連結構之上方;以及一保護層,位於該模塑層之上方。 A semiconductor device structure comprising: a conductive pad disposed on a substrate; a passivation layer over the substrate; and the passivation layer having an opening over the conductive pad; a post passivation interconnect structure located in the passivation Above the layer, and electrically connected to the conductive pad; a bump above the back passivation interconnect structure, and the bump directly contacts and electrically connects the post passivation interconnect structure; a molding layer is located Above the passivation interconnect structure; and a protective layer over the mold layer. 如申請專利範圍第2項之結構,更包含一介電層,位於該鈍化層及該後鈍化互連結構之間。 The structure of claim 2, further comprising a dielectric layer between the passivation layer and the post passivation interconnect structure. 如申請專利範圍第2項之結構,其中該凸塊延伸穿過該模塑層及該保護層。 The structure of claim 2, wherein the bump extends through the molding layer and the protective layer. 如申請專利範圍第1或2項之結構,其中該保護層包含一紫外光膠材、一熱塑性聚合物層或其組合。 The structure of claim 1 or 2, wherein the protective layer comprises an ultraviolet glue, a thermoplastic polymer layer or a combination thereof. 一種製造半導體元件之方法,包含:提供一基板,而該基板具有一導電墊置於其上;形成一鈍化層於該基板之上方,且該鈍化層具有一開口位於該導電墊之至少一部份之上方;形成一介電層位於該鈍化層之上方;形成一後鈍化互連結構於該介電層之上方,且該後鈍化互連結構延伸穿過該介電層,並電性連接至該導電墊;形成一凸塊於該後鈍化互連結構之上方,且該凸塊電性連接至該後鈍化互連結構;形成一模塑層於該後鈍化互連結構之上方,其中形成該模塑層於該後鈍化互連結構之上方,包含:塗佈一液態模塑混合物材料於該後鈍化互連結構及該凸塊之上方;壓製該液態模塑混合物材料,直至該液態模塑混合物材料之上表面低於該凸塊之上表面;固化該液態模塑混合物材料,以形成該模塑層;以及進行電漿清潔,以移除位於該凸塊上之該液態模塑混合物材料的殘留物;以及 形成一保護層於該模塑層之上方。 A method of fabricating a semiconductor device, comprising: providing a substrate having a conductive pad disposed thereon; forming a passivation layer over the substrate, and the passivation layer has an opening at least one of the conductive pads a dielectric layer is formed over the passivation layer; a post-passivation interconnect structure is formed over the dielectric layer, and the post-passivation interconnect structure extends through the dielectric layer and is electrically connected To the conductive pad; forming a bump above the passivation interconnect structure, and the bump is electrically connected to the post passivation interconnect structure; forming a molding layer over the post passivation interconnect structure, wherein Forming the molding layer over the post passivation interconnect structure comprises: coating a liquid molding mixture material over the post passivation interconnect structure and the bump; pressing the liquid molding mixture material until the liquid a surface of the molding mixture material having a surface lower than the upper surface of the bump; curing the liquid molding mixture material to form the molding layer; and performing plasma cleaning to remove the liquid molding on the bump The residue polymer material; and A protective layer is formed over the molding layer. 如申請專利範圍第6項之方法,其中形成該保護層之步驟包含:塗佈一薄膜於該模塑層及該凸塊之上方,且該薄膜包含一紫外光膠層;暴露該薄膜於紫外線幅射下;移除位於該模塑層及該凸塊上方之該薄膜,其中該薄膜之一殘留物位於該模塑層之上方,以形成位該於模塑層上方之該保護層,且該殘留物包含一部分之該紫外光膠層;以及進行電漿清潔,以移除位於該凸塊上之該薄膜的該殘留物。 The method of claim 6, wherein the step of forming the protective layer comprises: coating a film over the molding layer and the bump, and the film comprises an ultraviolet glue layer; exposing the film to ultraviolet rays Radiating; removing the film over the molding layer and the bump, wherein a residue of the film is over the molding layer to form the protective layer over the molding layer, and The residue comprises a portion of the UV adhesive layer; and plasma cleaning is performed to remove the residue of the film on the bump. 如申請專利範圍第6項之方法,其中形成該保護層之步驟包含:塗佈一薄膜於該模塑層及該凸塊之上方,且該薄膜包含一熱塑性聚合物層;移除位於該模塑層及該凸塊上方之該薄膜,其中該薄膜之一殘留物位於該模塑層之上方,以形成位該於模塑層上方之保護層,且該殘留物包含一部分之該熱塑性聚合物層;以及進行電漿清潔,以移除位於該凸塊上之該薄膜的該殘留物。 The method of claim 6, wherein the step of forming the protective layer comprises: coating a film over the molding layer and the bump, and the film comprises a thermoplastic polymer layer; a plastic layer and the film over the bump, wherein a residue of the film is over the molding layer to form a protective layer over the molding layer, and the residue comprises a portion of the thermoplastic polymer a layer; and performing a plasma cleaning to remove the residue of the film on the bump. 如申請專利範圍第6項之方法,其中形成該保護層之步驟包含:塗佈一薄膜於該模塑層及該凸塊之上方,且該薄膜包含:一第一聚合物層,一紫外光脫膜層,位於該第一聚合物層之上方,及一第二聚合物層,位於該紫外線脫膜層之上方;暴露該薄膜於紫外線幅射下;移除位於該模塑層及該凸塊上方之該紫外光脫膜層及該第二聚合物層,其中該第一聚合物層形成該保護層於該模塑層之上方;以及進行電漿清潔,以移除位於該凸塊上之該薄膜的該殘留物。 The method of claim 6, wherein the step of forming the protective layer comprises: coating a film over the molding layer and the bump, and the film comprises: a first polymer layer, an ultraviolet light a release layer, above the first polymer layer, and a second polymer layer above the ultraviolet release layer; exposing the film to ultraviolet radiation; removing the molding layer and the protrusion The ultraviolet light release layer and the second polymer layer above the block, wherein the first polymer layer forms the protective layer over the molding layer; and plasma cleaning to remove the bump This residue of the film.
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TW201246540A (en) * 2011-02-09 2012-11-16 Fujitsu Ltd Semiconductor device and method for producing the same, and power supply
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