TWI575079B - Composition of high heat dissipating aluminum and its manufacturing method - Google Patents

Composition of high heat dissipating aluminum and its manufacturing method Download PDF

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TWI575079B
TWI575079B TW105106072A TW105106072A TWI575079B TW I575079 B TWI575079 B TW I575079B TW 105106072 A TW105106072 A TW 105106072A TW 105106072 A TW105106072 A TW 105106072A TW I575079 B TWI575079 B TW I575079B
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aluminum
graphite
heat dissipation
powder
high heat
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TW201730350A (en
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yu-qing Luo
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yu-qing Luo
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高散熱鋁件之組成物及其製造方法 Composition of high heat dissipation aluminum member and manufacturing method thereof

本發明係關於一種高散熱鋁件之組成物及其製造方法,尤指將純鋁與石墨共架連結,使該鋁件組成物具有高散熱及低損耗之效益者。 The invention relates to a composition of a high heat dissipation aluminum member and a manufacturing method thereof, in particular to a joint of pure aluminum and graphite, so that the aluminum component has the advantages of high heat dissipation and low loss.

查,習知之鋁其於工業應用廣泛,且因其導熱性佳,被大量的應用於散熱器材使用,又為能增加鋁製散熱器之散熱效能,往往利用以其他加工方法(例如:模具鑄成或切銷加工)製成鰭片狀或其他形狀,以增加其接觸面積,來提升散熱效能;其實,上述存在有下列的缺點: It is known that aluminum is widely used in industry, and because of its good thermal conductivity, it is used in a large number of heat sink materials, and it can also increase the heat dissipation performance of aluminum heat sinks, often using other processing methods (for example: mold casting) Formed or cut into a fin shape or other shape to increase its contact area to improve heat dissipation; in fact, the above has the following shortcomings:

1.鋁雖有不錯之吸熱、導熱、散熱效能,但其導熱率因其材質為固定不變,並非最理想的導熱、散熱材質。 1. Although aluminum has good heat absorption, heat conduction and heat dissipation performance, its thermal conductivity is not the most ideal heat conduction and heat dissipation material because its material is fixed.

2.鋁片為求增加接觸面積,而使用的加工手段,雖是可以增加其散熱效益,但相對的需增加加工成本,實是鋁片散熱應用之一大問題。 2. In order to increase the contact area, the aluminum sheet can increase the heat dissipation efficiency, but the relative need to increase the processing cost is a big problem in the heat dissipation application of aluminum sheet.

另,遂有業者以鋁與石墨熔合,使鋁具有高導熱之散熱功效,惟,鋁熔點約攝氏660度,石墨於攝氏500度以下會開始氧化,將熱熔的鋁與石墨直接混合,其於攪拌混合過程中,使石墨與空氣接觸時造成氣化反應過快,石墨會因高溫逐漸氧化,造成大量的石墨損耗,使製造成本過高,難以堪稱實用。 In addition, the industry has aluminum and graphite fusion, so that aluminum has a high thermal conductivity of heat dissipation, but the melting point of aluminum is about 660 degrees Celsius, graphite will begin to oxidize below 500 degrees Celsius, the hot melt aluminum and graphite directly mixed, During the mixing and mixing process, when the graphite is in contact with air, the gasification reaction is too fast, and the graphite is gradually oxidized due to the high temperature, causing a large amount of graphite loss, which makes the manufacturing cost too high and is difficult to be practical.

本發明主要目的係在於解決上述問題,而提供一種高散熱鋁件之組成物及其製造方法,具有更佳實用之功效,主要技術、目的為: 將純鋁加熱熔成純鋁熔漿,在該純鋁熔漿中投入碳化鋁錠持續攪拌至該碳化鋁錠完全熔解;及將熔漿混合物導入模具待其自然降至常溫、冷卻成型;即得一含有石墨之鋁件組成物,藉含有石墨之特性,而使該鋁件組成物具有高導熱、散熱之功效;並藉由石墨與鋁二次熔合,使該石墨具有低損耗之功效。 The main object of the present invention is to solve the above problems, and to provide a composition of a high heat dissipation aluminum member and a manufacturing method thereof, which have better practical effects, and the main techniques and purposes are as follows: The pure aluminum is heated and melted into a pure aluminum melt, and the aluminum carbide ingot is poured into the pure aluminum melt to be continuously stirred until the aluminum carbide ingot is completely melted; and the molten mixture is introduced into the mold to be naturally cooled to a normal temperature and cooled to form; The composition of the aluminum component containing graphite has the characteristics of high thermal conductivity and heat dissipation by the characteristics of graphite, and the graphite has a low loss effect by secondary fusion of graphite and aluminum.

第1圖,係本發明製造方法之流程圖 Figure 1 is a flow chart of the manufacturing method of the present invention

為使 貴審查委員對本發明有更進一步瞭解,茲舉一較佳實施例並配合圖式,詳述如後:一種高散熱鋁件之組成物,其包括:重量百分比為20%~25%純鋁及重量百分比為75%~80%碳化鋁錠組成;其中,該碳化鋁錠係由石墨、鋁粉混合而成,其重量百分比如下:石墨:60%、鋁粉:40%。 In order to make the present invention more familiar with the present invention, a preferred embodiment and a drawing will be described in detail as follows: a composition of a high heat dissipation aluminum member comprising: 20% to 25% by weight pure The aluminum and the weight percentage are composed of 75% to 80% of aluminum carbide ingot; wherein the aluminum carbide ingot is made of graphite and aluminum powder, and the weight percentage thereof is as follows: graphite: 60%, aluminum powder: 40%.

請參閱第1圖所示,一種高散熱鋁件之製造方法,其步驟包括:(a)製備粉狀重量百分比60%石墨及重量百分比40%鋁粉於真空滾筒加熱爐,以10大氣壓氮氣加壓並加熱至680℃;(b)持續攪拌6-8小時,使達熔點而熔融的鋁粉可與該石墨燒結成碳化鋁粉,該碳化鋁粉再置於模內以200~300公噸沖壓成高密度之碳化鋁錠;(c)製備純鋁並加熱至680℃成熔漿,在該純鋁熔漿中投入該碳化鋁錠,並分別以重量百分比20%~25%純鋁及重量百分比75%~80%碳化鋁錠之混合比例持續攪拌至該碳化鋁錠完全熔入該純鋁熔漿;及(d)將混有該碳化鋁錠之純鋁熔漿導入模具並待其自然降至常溫、冷卻成 型;藉由上述方法,製得一含有石墨之鋁件組成物,並以二次熔合,使該鋁件組成物具有高散熱及石墨低損耗之功效。 Please refer to FIG. 1 , a method for manufacturing a high heat dissipation aluminum member, the steps comprising: (a) preparing a powdery weight percentage of 60% graphite and a weight percentage of 40% aluminum powder in a vacuum drum heating furnace, and adding 10 atmospheres of nitrogen gas. Press and heat to 680 ° C; (b) continue to stir for 6-8 hours, so that the melting point of molten aluminum powder can be sintered with the graphite into aluminum carbide powder, which is placed in the mold and stamped at 200 ~ 300 metric tons a high-density aluminum carbide ingot; (c) preparing pure aluminum and heating to 680 ° C to form a melt, and injecting the aluminum carbide ingot into the pure aluminum melt, and respectively, by weight of 20% to 25% pure aluminum and weight The mixing ratio of the percentage of 75% to 80% of the aluminum carbide ingot is continuously stirred until the aluminum carbide ingot is completely melted into the pure aluminum melt; and (d) the pure aluminum melt mixed with the aluminum carbide ingot is introduced into the mold and is naturally Drop to normal temperature and cool down By the above method, a composition of aluminum containing graphite is obtained and fused in two times, so that the aluminum component has the effects of high heat dissipation and low loss of graphite.

本發明之組成,細節說明如下:如第1圖所示,係本發明之製造方法之流程圖,係將粉狀石墨先行乾燥作業(石墨為塊狀,需先於水中研磨成粉狀,水中研磨係避免粉狀石墨產生劇烈氧化作用),再將粉狀石墨置入電熱真空加熱爐中加熱,以180℃~220℃乾燥,加熱時間需5~7小時,可使粉狀石墨呈乾燥狀態(乾燥不含水份的粉狀石墨,可避免後續與鋁粉反應時,因含水分而助燃),再以重量百分比60%石墨及重量百分比40%鋁粉,置於真空滾筒加熱爐中,將其加熱升溫至680℃,並施以10大氣壓力之氮氣,使真空滾筒加熱爐之壓力上升,爐內壓力之增加會進而使真空滾筒加熱爐內溫度劇烈昇高,亦因氮氣之不助燃特性,使真空滾筒加熱爐內無助燃氣體,可不致使粉狀石墨與鋁粉因氧化產生質變;且持續保持加熱以維持溫度並於期間持續滾動攪拌8小時,該粉狀石墨與鋁粉會燒結成碳化鋁粉,待碳化鋁粉自然降至常溫後,將該碳化鋁粉置於沖壓模具,以200公噸~300公噸沖壓成碳化鋁錠,該經加以大壓力沖壓成型的碳化鋁錠其密度會大幅提升。 The composition of the present invention is described in detail as follows: As shown in Fig. 1, a flow chart of the manufacturing method of the present invention is a method in which powdered graphite is first dried (the graphite is in the form of a block and needs to be ground into water prior to water, in water). The grinding system avoids the violent oxidation of the powdered graphite), and then the powdered graphite is placed in an electric vacuum heating furnace for heating, and dried at 180 ° C to 220 ° C, and the heating time takes 5-7 hours to make the powdery graphite dry. (Drying the non-aqueous powdered graphite to avoid the subsequent combustion with aluminum powder, and supporting it due to water content), and then placing it in a vacuum drum heating furnace with 60% by weight of graphite and 40% by weight of aluminum powder. Heating it to 680 ° C, and applying nitrogen gas at 10 atmospheres, the pressure of the vacuum drum heating furnace is increased, and the increase of the pressure in the furnace will further increase the temperature in the vacuum drum heating furnace, and also the non-combustion of nitrogen gas. The characteristic is that the vacuum drum is heated in the furnace without the help of the gas, so that the powdery graphite and the aluminum powder are not oxidized to produce a qualitative change; and the heating is continuously maintained to maintain the temperature and the rolling and stirring is continued for 8 hours during the period, the powdery graphite and the powdery graphite The powder will be sintered into aluminum carbide powder. After the aluminum carbide powder is naturally lowered to normal temperature, the aluminum carbide powder is placed in a stamping die and punched into an aluminum carbide ingot from 200 metric tons to 300 metric tons, which is subjected to high pressure stamping of aluminum carbide. The density of the ingots will increase dramatically.

再接著,將純鋁(成份為純鋁塊)在常壓常溫下加熱高於鋁熔點680℃呈純鋁熔漿狀態,在該純鋁熔漿中投入該碳化鋁錠,並分別以重量百分比20%~25%純鋁及重量百分比75%~80%碳化鋁錠之比例持續攪拌,而該高密度之碳化鋁錠,會於該純鋁熔漿中緩慢熔解,不致因熔解速度太快,使石墨與空氣接觸時造成氣化反應過快,而產生石墨過度損耗之現象;以本發明製造方法產生氣化的石墨損耗會低於總重之5%;例如300公斤(重量百分比:23%)純鋁熔漿中投入1000公斤碳化鋁錠(重量百分比:77%),其所 得成品約為1250公斤(損耗約總重3.8%重量百分比),待該純鋁熔漿內之碳化鋁錠完全熔解,並與鋁熔漿完全混合,再將其混合熔漿倒入模具,待其冷卻致常溫,可得一鋁件之組成物,該鋁件組成物所含石墨之比例,可使其應力強度較純鋁強;並使該鋁件組成物具有高導熱、散熱特性之功效。 Then, the pure aluminum (ingredients are pure aluminum blocks) is heated at a normal temperature and normal temperature higher than the melting point of the aluminum 680 ° C in a pure aluminum melt state, and the aluminum carbide ingot is put into the pure aluminum melt, and respectively, by weight percentage The proportion of 20%~25% pure aluminum and 75%~80% by weight of aluminum carbide ingot is continuously stirred, and the high-density aluminum carbide ingot will slowly melt in the pure aluminum melt, so that the melting speed is too fast. When the graphite is brought into contact with air, the gasification reaction is too fast, and the graphite is excessively depleted; the loss of graphite produced by the manufacturing method of the present invention is less than 5% of the total weight; for example, 300 kg (% by weight: 23%) ) 1000 kg of aluminum carbide ingot (weight percentage: 77%) is put into pure aluminum melt. The finished product is about 1,250 kg (loss is about 3.8% by weight of total weight), and the aluminum carbide ingot in the pure aluminum melt is completely melted and completely mixed with the aluminum melt, and then the mixed melt is poured into the mold, and the mixture is poured into the mold. The cooling is caused by normal temperature, and a composition of an aluminum member can be obtained. The proportion of graphite contained in the aluminum component can make the stress intensity stronger than that of pure aluminum; and the aluminum component has high heat conduction and heat dissipation characteristics. .

惟,以上所述者,僅為本發明之較佳實施例而已,並非用以侷限本發明之特徵,舉凡利用本發明相關之技術手段、創設原理之再創作,仍屬本發明等效結構創意範疇。 However, the above description is only a preferred embodiment of the present invention, and is not intended to limit the features of the present invention. The re-creation of the technical means and the creation principle of the present invention is still an equivalent structural idea of the present invention. category.

綜上所述,本發明之結構,極具產業上利用價值;且又未見有相同或類似之發明出現於國內外刊物或公開使用,確實具有極佳之實用性與增進功效,誠符合專利法之規定,爰依法俱文提出申請。 In summary, the structure of the present invention is extremely industrially useful; and it has not been found that the same or similar inventions appear in domestic and foreign publications or in public use, and indeed have excellent practicality and enhanced efficacy, and are in line with patents. The provisions of the law, the application of the law.

Claims (4)

一種高散熱鋁件之製造方法,其步驟包括:(a)製備粉狀重量百分比60%石墨及重量百分比40%鋁粉於真空滾筒加熱爐,並注入氮氣加壓並加熱至680℃;(b)持續攪拌6-8小時,使達熔點而熔融的鋁粉可與該石墨燒結成碳化鋁粉,該碳化鋁粉再置於模內以200~300公噸沖壓成高密度之碳化鋁錠;(c)製備純鋁並加熱至680℃成熔漿,在該純鋁熔漿中投入該碳化鋁錠,並分別以重量百分比20%~25%純鋁及重量百分比75%~80%碳化鋁錠之混合比例持續攪拌至該碳化鋁錠完全熔入該純鋁熔漿;及(d)將混有該碳化鋁錠之純鋁熔漿導入模具並待其自然降至常溫、冷卻成型;藉由上述方法,製得一含有石墨之鋁件組成物,並以二次熔合,使該鋁件組成物具有高導熱、散熱及石墨低損耗之功效。 A method for manufacturing a high heat dissipation aluminum member, comprising the steps of: (a) preparing a powdery weight percentage of 60% graphite and a weight percentage of 40% aluminum powder in a vacuum drum heating furnace, and injecting nitrogen gas pressure and heating to 680 ° C; Continuously stirring for 6-8 hours, so that the melting point of the molten aluminum powder can be sintered with the graphite into aluminum carbide powder, and the aluminum carbide powder is placed in a mold and punched into a high-density aluminum carbide ingot at 200 to 300 metric tons; c) preparing pure aluminum and heating to 680 ° C to obtain a slurry, and injecting the aluminum carbide ingot into the pure aluminum melt, and respectively, using 20% to 25% pure aluminum by weight and 75% to 80% by weight of aluminum carbide ingot The mixing ratio is continuously stirred until the aluminum carbide ingot is completely melted into the pure aluminum melt; and (d) the pure aluminum melt mixed with the aluminum carbide ingot is introduced into the mold and naturally cooled to a normal temperature and cooled; In the above method, a composition of aluminum containing graphite is obtained and fused in two times, so that the composition of the aluminum member has high heat conduction, heat dissipation and low loss of graphite. 如請求項1所述之高散熱鋁件之製造方法,其中,該氮氣注入10大氣壓力。 A method of manufacturing a high heat dissipation aluminum member according to claim 1, wherein the nitrogen gas is injected at 10 atmospheres. 一種如請求項1之製造方法製造的高散熱鋁件之組成物,其包括:重量百分比為20%~25%純鋁及重量百分比為75%~80%碳化鋁錠組成。 A composition of a high heat dissipation aluminum member manufactured by the manufacturing method of claim 1, comprising: 20% to 25% by weight of pure aluminum and 75% to 80% by weight of aluminum carbide ingot. 如請求項3所述之高散熱鋁件之組成物,其中,該碳化鋁錠係由石墨、鋁粉混合而成,其重量百分比如下:石墨:60%、鋁粉:40%。 The composition of the high heat dissipation aluminum member according to claim 3, wherein the aluminum carbide ingot is a mixture of graphite and aluminum powder, and the weight percentage thereof is as follows: graphite: 60%, aluminum powder: 40%.
TW105106072A 2016-02-26 2016-02-26 Composition of high heat dissipating aluminum and its manufacturing method TWI575079B (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796589A (en) * 2004-12-23 2006-07-05 中国科学院金属研究所 Duplexing sized high temperature resisting aluminium based composite material enhanced by granules of ceramics

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1796589A (en) * 2004-12-23 2006-07-05 中国科学院金属研究所 Duplexing sized high temperature resisting aluminium based composite material enhanced by granules of ceramics

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