TWI556742B - A herbicidal composition - Google Patents

A herbicidal composition Download PDF

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TWI556742B
TWI556742B TW103124957A TW103124957A TWI556742B TW I556742 B TWI556742 B TW I556742B TW 103124957 A TW103124957 A TW 103124957A TW 103124957 A TW103124957 A TW 103124957A TW I556742 B TWI556742 B TW I556742B
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herbicidal composition
sodium
composition according
water
naoh
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TW103124957A
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TW201603709A (en
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Chin I Chen
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Chin I Chen
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一種除草劑組合物 Herbicide composition

本發明係一種除草劑組合物,屬一種以水為主要溶劑主體,混合添加小於52%的氫氧化鈉(NaOH)或氫氧化鉀(KOH)等強鹼性材料液,及少量的界面活性材料,共同組成一具高濃度的強鹼性無毒除草劑,除草使用時以水為調和用的溶劑,共同調合稀釋成具適當濃度的鹼性水溶液料,達到沾附於草類葉面,做為一種完全無毒環保性的除草劑的安全使用目的。 The invention relates to a herbicide composition, belonging to the main body of water as a main solvent, mixing and adding a strong alkaline material liquid such as sodium hydroxide (NaOH) or potassium hydroxide (KOH) of less than 52%, and a small amount of interface active materials. Together, they form a high-concentration, strong-alkaline non-toxic herbicide. When used in weeding, water is used as a solvent for blending. It is blended and diluted into an alkaline aqueous solution with appropriate concentration to adhere to the grass leaf surface. A safe use of a completely non-toxic and environmentally friendly herbicide.

一般市場上販售之除草劑,大多都是以化學材料做為相互混合組成,其中多含強效性的腐蝕性液料調劑,使構成對樹木、草葉或根部做組織完全破壞性的處理,以達到除草或枯葉等化學反應處理,如發明專利第101115054號「含磺酰胺游離酸活性成分的可溶性顆粒劑」發明公開前案,藉由多種添加劑的混合調劑,使製成顆粒狀,而以類似的化學藥劑式調處的除草劑使用,其不僅具強烈的有毒物質,其不僅會破壞草木的組織,在滲到土壤後,亦會在土壤中殘留累積有毒物質,故其影響極為深遠,更且對實際操作使用的人員,更會造成身體上的嚴重傷害,稍一不慎防護工作沒 完整時,輕者常會造成體膚的損傷,嚴重者更會產生中毒的疑慮,尤其對該施工局部地區大氣中的空氣及活動的鳥、昆蟲以致土壤內的小動物等,亦會產生不當的撲殺的情形,如何使除草的工作在簡易施工下,又可獲得輕毒或無毒的使用,以期對人員及大地都不會產生污染或損壞,此便是本發明開發最主要的創作原意,如何開發出具安全使用又符實用安全、衛生需要的除草劑,其實一直是業界所積極研究開發的目標。 Most of the herbicides sold on the market are made up of chemical materials, which contain a strong corrosive liquid material to make the treatment of trees, grass leaves or roots completely destructive. In order to achieve a chemical reaction treatment such as weeding or dead leaves, such as the invention patent No. 101115054 "soluble granule containing sulfonamide free acid active ingredient", the invention disclosed in the foregoing disclosure, by mixing and adjusting various additives, is made into granules, and Similar chemical agents are used in herbicides, which not only have strong toxic substances, but also not only destroy the structure of the vegetation, but also accumulate toxic substances in the soil after infiltration into the soil, so the impact is extremely far-reaching and more And for the actual use of the personnel, it will cause serious physical injury, a little careless work When it is intact, the lighter often causes damage to the skin. In severe cases, it may cause poisoning doubts. In particular, the air in the atmosphere and the active birds and insects in the local area of the construction may cause improper culling. In the case of how to make the work of weeding under the simple construction, it can be used lightly or non-toxicly, so as to avoid pollution or damage to the people and the earth. This is the main creative intention of the development of the invention, how to develop The introduction of herbicides for safe use and practical safety and sanitation needs has always been the active research and development target of the industry.

本發明者有鑑於傳統化學調製的除草劑使用材料配方複雜且不符實用安全衛生使用需要之缺失,依多年來於無毒性化學材料的研發設計經驗,綜合實際雜草清除使用需要,終於開發出本發明之一種除草劑組合物,以一般無毒的水為主要溶劑主體,混合添加適量的氫氧化鈉(NaOH)或氫氧化鉀(KOH)等強鹼性材料液,及少量的界面活性材料,共同組成一具高濃度的強鹼性無毒除草劑等為原材料使用,以水為調和稀釋使用,構成安全的除草劑,有效克服傳統除草劑不符安全實用需要的缺失。本創作之創作目的在於:以無毒原材料氫氧化鈉(NaOH)或氫氧化鉀(KOH)等強鹼性材料液,及少量的界面活性材料,加水混合製成安全的除草劑,透過適當比例水的調合,使除草劑可以強鹼性的材料液,在噴灑在清理的雜草上,會自然形成適當均勻的附著,自然清理各式雜草,不會產生安全疑慮,又可達到簡便的除草功效,達到安全無毒的便利除草使用目的。 The inventors have in view of the fact that the conventional chemically prepared herbicides have complicated formulas for materials and are not suitable for practical safety and sanitation use. Based on years of experience in research and development of non-toxic chemical materials, comprehensive practical weed removal needs, and finally developed this The herbicide composition of the invention adopts generally non-toxic water as the main solvent main body, and mixes and adds a proper amount of a strong alkaline material liquid such as sodium hydroxide (NaOH) or potassium hydroxide (KOH), and a small amount of interface active materials. It is composed of a high-concentration, strong-alkaline non-toxic herbicide, which is used as a raw material, and is diluted with water to form a safe herbicide, effectively overcoming the lack of traditional herbicides that are incompatible with safety and practical needs. The purpose of this creation is to use a non-toxic raw material such as sodium hydroxide (NaOH) or potassium hydroxide (KOH) and a small amount of interface material, add water to make a safe herbicide, through the appropriate proportion of water The blending, so that the herbicide can be strongly alkaline material liquid, sprayed on the cleaned weeds, will naturally form a proper and uniform adhesion, naturally clean all kinds of weeds, will not create safety concerns, and can achieve simple weeding Efficacy, to achieve safe and non-toxic convenience for weeding purposes.

本發明一種除草劑組合物,尤指一種無毒的除草用稀釋除草液,其透過無毒的化學環保材料氫氧化鈉(NaOH)或氫氧化鉀(KOH)等強鹼性材料液,佔總重量比介於1~23%,及少量的界面活性材料添加,約佔總重量1~5%間,以水為主要調合的主材料,其佔用全部重量比達到75~98%,共同調製成強鹼狀的除草劑,使用時調和加水稀釋,達到強鹼性的噴灑於雜草的草面或葉面,使葉面上的蠟質水解達到草葉片失去保水能力,進而因為脫水而乾枯死亡,以達到除草的使用目的。 The herbicide composition of the present invention, especially a non-toxic herbicidal diluted herbicidal solution, which passes through a non-toxic chemical environmentally friendly material such as sodium hydroxide (NaOH) or potassium hydroxide (KOH), which accounts for the total weight ratio. Between 1~23%, and a small amount of interface active material added, about 1~5% of the total weight, with water as the main blending main material, which takes up 75~98% of the total weight ratio, and prepares a strong base together. The herbicide is diluted with water and diluted with water to achieve a strong alkaline spray on the grass surface or leaf surface of the weed, so that the waxy surface on the leaf surface is hydrolyzed to lose the water retention capacity of the grass blade, and then dry and die due to dehydration. Achieve the purpose of weeding.

本發明一種除草劑組合物,尤指一種無毒的除草用稀釋除草液,其透過強鹼的調製和加水簡便稀釋,達到強鹼性的噴灑於雜草的草面或葉面,使其達到草葉片失去保水能力,進而因為脫水而乾枯死亡,以達到除草的使用目的,整個無毒性的除草劑的配方組合,主要包含以水為主要調合的主材料,其佔用全部重量比達到75~98%,再以無毒的化學環保材料氫氧化鈉(NaOH)或氫氧化鉀(KOH)等強鹼性材料液,佔總重量比介於1~23%,及少量的界 面活性材料添加,約佔總重量1~5%間,其中界面活性材料的部份,主要為無毒的脂肪酸鈉(即俗稱:肥皂)、直鏈烷基苯磺酸鈉(一般洗衣粉)、烷基聚乙二醇(一般用洗衣精)或十二烷醚硫酸鈉,而界面活性材料的添加,其目的在於使混合的強鹼性的劑料的「表面張力」降低,可適當的增加該鹼液的「潤濕性」,使其較均勻的分散在葉片上,不會凝結成水滴,以致滴落到地面,達到附著較確實的輔助。 The invention relates to a herbicide composition, in particular to a non-toxic herbicidal diluted herbicidal solution, which is prepared by the preparation of a strong base and the simple dilution of water to achieve a strong alkaline spray on the grass surface or leaf surface of the weed to reach the grass. The leaves lose their water retention capacity, and then die dry due to dehydration, in order to achieve the purpose of weeding, the whole non-toxic herbicide formula combination mainly includes water as the main blending main material, which takes up 75~98% of the total weight ratio. And non-toxic chemical environmentally friendly materials such as sodium hydroxide (NaOH) or potassium hydroxide (KOH), such as strong alkaline materials, the total weight ratio of 1 to 23%, and a small number of boundaries The surface active material is added, which accounts for about 1~5% of the total weight, wherein the part of the interface active material is mainly non-toxic sodium fatty acid (commonly known as soap), linear sodium alkylbenzene sulfonate (general washing powder), Alkyl polyethylene glycol (usually laundry detergent) or sodium lauryl ether sulfate, and the addition of the interface active material, the purpose of which is to reduce the "surface tension" of the mixed strongly alkaline agent, and may appropriately increase The "wettability" of the lye makes it more evenly dispersed on the blade, and does not condense into water droplets, so that it drops to the ground, and the adhesion is more reliable.

本發明的實施例,以較經濟使用的實施例做說明,即以氫氧化鈉(NaOH)做為強鹼液的添加混合材料,其取材較簡易,且成本相較於氫氧化鉀(KOH)材料,具有倍數以上的低廉使用經濟特性,故而較符合一般使用需要,按以一般咸豐草植物的除草為例,通常將氫氧化鈉(NaOH)原料液以5%予以添加5%的界面活性材料,一般通常可以洗衣粉做簡易泡製添加,加水稀釋成所需的強鹼性的殺草液料,透過噴灑處理,使其得以沾附於草皮的葉面上,便可達到使葉面蠟質被水解喪失保水性因而脫水乾枯死亡的效果,而其整個氫氧化鈉(NaOH)液料添加量,可依草皮的草長及成熟度做適當的調整添加比例,以一般新生的草面時,則可稍降其添加數量在1~2%,即可達到相對的殺草的功效,一般成長在10天內的咸豐草而言,約可以2%的氫氧化鈉(NaOH)混合添加,便可完整的清除處理,對於一般闊葉雜草及10天內的平行葉脈草,則可提升混合量達到10%,便可簡易達到除殺草的功效,如下列附表所 示的測試表列參考。 The embodiment of the present invention is described by using a more economical embodiment, that is, sodium hydroxide (NaOH) is used as a mixed material of a strong alkali liquid, which is simpler to obtain and has a cost compared with potassium hydroxide (KOH). The material has more than double the economical characteristics of use, so it is more suitable for general use. According to the weeding of the common salty grass plant, the sodium hydroxide (NaOH) raw material solution is usually added with 5% of the interface active material at 5%. Generally, it can usually be added by washing powder, and diluted with water to form the desired strong alkaline herbicide liquid. By spraying, it can be adhered to the leaf surface of the turf to achieve the foliar wax. The quality of the water is lost due to hydrolysis, and the effect of dehydration and dryness is lost. The amount of the whole sodium hydroxide (NaOH) liquid material can be appropriately adjusted according to the length and maturity of the turf, so that the fresh grass surface is generally used. , you can slightly reduce the amount of addition in 1~2%, you can achieve the relative killing effect, generally grown in 10 days of salty grass, about 2% sodium hydroxide (NaOH) mixed, Complete cleaning process, right General broadleaf weeds and grasses parallel veins within 10 days, you can enhance the mixing amount of 10%, can achieve the effect of a simple addition to the herbicide, as in the following Schedule The test list shown is for reference.

而以氫氧化鈉(NaOH)的添加使用,其當濃度較高時,由於其含有鹽份較高,當濃度較高且多次使用後,為防止土壤的鹽化損壞,故當需濃度較高使用時,便會將其改以氫氧化鉀(KOH)材料做替換使用,而以一般野外大面積的除草使用時,會建議以氫氧化鈉(NaOH)的添加使用,而當較小面積且為特殊作物使用的地表做高濃度使用時,則建議改以氧化鉀(KOH)材料使用,可以達到 真正安全無毒且不會有損壞性的除草使用,確保土地表層清理後,真正符合清淨安全無毒環保維護的使用目的。 The addition of sodium hydroxide (NaOH), when the concentration is higher, because of its higher salt content, when the concentration is higher and after multiple uses, in order to prevent soil salinization damage, when the concentration is required When it is used at high level, it will be replaced by potassium hydroxide (KOH) material. When it is used in large field weeding, it is recommended to use sodium hydroxide (NaOH) instead. When the surface used for special crops is used at a high concentration, it is recommended to use potassium oxide (KOH) material to achieve It is truly safe, non-toxic and does not have damaging weeding, ensuring that the surface of the soil is cleaned and truly meets the purpose of clean, safe, non-toxic and environmentally friendly maintenance.

本發明的一種除草劑組合物的開發,其運用極簡易取得的無毒材料氫氧化鈉(NaOH)或氫氧化鉀(KOH)材料做為強鹼液的添加混合材料,通過適當比例界面活性材料的調配選擇,便可混合製作出適當濃度的除草用液料,而通過無毒的原材料的相互混合,使達到除草劑的無毒及環保安全使用功效,提供除草噴灑使用,其更可以固定濃度比例的劑料預先調製,提供使用者使用時再依除種類需要,適當的加水稀釋成適當濃度使用,確保安全環保使用。 The invention relates to the development of a herbicide composition, which uses the non-toxic material sodium hydroxide (NaOH) or potassium hydroxide (KOH) material which is very simple to obtain as a mixed material of strong alkali liquid, through an appropriate ratio of interface active materials. By blending and selecting, the appropriate concentration of the herbicidal liquid material can be mixed, and the non-toxic raw materials are mixed with each other to achieve the non-toxic and environmentally safe use effect of the herbicide, and the herbicide spraying is provided, and the agent can be fixed in a concentration ratio. The material is pre-modulated and provided for the user to use according to the type, and the appropriate water is diluted to the appropriate concentration to ensure safe and environmentally friendly use.

綜上所述,本發明一種除草劑組合物,以簡易的化學原材料,通過適量的界面活性材料的混合添加入固定比例的水中,便可調整製出無毒安全使用的除草劑,其創新實用安全及便利取用的特性與環保經濟價值,實已符合發明專利之申請要件,依法提出專利申請。 In summary, the herbicide composition of the present invention can be adjusted to produce a non-toxic and safe herbicide by adding a suitable amount of interface active material into a fixed proportion of water with a simple chemical raw material, and the invention is innovative and practical. And the convenience of access to the characteristics and environmental economic value, has been in line with the application requirements of the invention patent, filed a patent application according to law.

Claims (7)

一種除草劑組合物,包括水、強鹼性材料液及界面活性材料所組成,其特徵在於:以水為調合的主材料,佔用總重量比達到75~98%,再以氫氧化鈉(NaOH)或氫氧化鉀(KOH)強鹼性材料液,佔總重量比介於1~23%,及界面活性材料,佔總重量1~5%間,共同調劑成除草劑。 A herbicide composition comprising water, a strong alkaline material liquid and an interface active material, characterized in that: water is used as a main material to be blended, occupying a total weight ratio of 75 to 98%, and then using sodium hydroxide (NaOH) ) or potassium hydroxide (KOH) strong alkaline material liquid, the total weight ratio of 1 to 23%, and interface active materials, accounting for 1 to 5% of the total weight, together to adjust the herbicide. 如申請專利範圍第1項所述之一種除草劑組合物,其中界面活性材料,主要為脂肪酸鈉、直鏈烷基苯磺酸鈉、烷基聚乙二醇或十二烷醚硫酸鈉。 A herbicidal composition according to claim 1, wherein the interface active material is mainly sodium fatty acid, sodium linear alkylbenzene sulfonate, alkyl polyethylene glycol or sodium lauryl ether sulfate. 如申請專利範圍第1項所述之一種除草劑組合物,其中氫氧化鈉(NaOH)可以氫氧化鉀(KOH)材料液替代使用或合併使用。 A herbicidal composition according to claim 1, wherein the sodium hydroxide (NaOH) may be used in place of or in combination with a potassium hydroxide (KOH) material solution. 如申請專利範圍第2項所述之一種除草劑組合物,其中脂肪酸鈉,即為肥皂。 A herbicidal composition according to claim 2, wherein the sodium fatty acid is soap. 如申請專利範圍第2項所述之一種除草劑組合物,其中直鏈烷基苯磺酸鈉,即為一般洗衣粉。 A herbicidal composition according to claim 2, wherein the sodium linear alkylbenzene sulfonate is a general laundry detergent. 如申請專利範圍第2項所述之一種除草劑組合物,其中烷基聚乙二醇,即為一般用洗衣精。 A herbicidal composition according to claim 2, wherein the alkyl polyethylene glycol is a general laundry detergent. 如申請專利範圍第1項所述之一種除草劑組合物,其中氫氧化鈉(NaOH)可以氫氧化鉀(KOH)材料液固定濃度,視需求加水稀釋。 A herbicidal composition according to claim 1, wherein the sodium hydroxide (NaOH) is fixed in a concentration of potassium hydroxide (KOH) material and diluted with water as needed.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW314449B (en) * 1995-06-06 1997-09-01 American Cyanamid Co
US6258752B1 (en) * 1997-04-04 2001-07-10 W. Neudorff Gmbh Kg Non-staining herbicidal soap
UA35619U (en) * 2008-05-07 2008-09-25 Общество С Ограниченной Ответственностью "Компания "Укравит" Herbicidal composition
CN1829441B (en) * 2003-07-28 2011-10-19 拜尔作物科学股份公司 Liquid formulation

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW314449B (en) * 1995-06-06 1997-09-01 American Cyanamid Co
US6258752B1 (en) * 1997-04-04 2001-07-10 W. Neudorff Gmbh Kg Non-staining herbicidal soap
CN1829441B (en) * 2003-07-28 2011-10-19 拜尔作物科学股份公司 Liquid formulation
UA35619U (en) * 2008-05-07 2008-09-25 Общество С Ограниченной Ответственностью "Компания "Укравит" Herbicidal composition

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王喻其等人所著,"農藥使用手冊",民國101年12月 *

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