TWI529996B - Soft package lithium battery package structure - Google Patents
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- TWI529996B TWI529996B TW104112999A TW104112999A TWI529996B TW I529996 B TWI529996 B TW I529996B TW 104112999 A TW104112999 A TW 104112999A TW 104112999 A TW104112999 A TW 104112999A TW I529996 B TWI529996 B TW I529996B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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Description
本發明是關於一種鋰電池封裝結構,尤指一種軟包鋰電池的封裝結構。 The invention relates to a lithium battery package structure, in particular to a package structure of a soft lithium battery.
由於一般汽車、手機、筆記型電腦等需要高功率的電子產品以往都是採用鎳鎘電池或是鉛酸電池,但由於此類電池所產生的鉛以及鎘金屬容易造成環境汙染,因此現在大多以鋰離子電池作為取代。鋰電池可分為以鋰金屬或鋰合金為負極材料,使用非水電解質溶液的一次電池,以及依靠鋰離子在正極和負極之間移動來產生電的充電電池,而我們一般所用於3C產業以其汽車業的即為鋰離子電池,簡稱為鋰電池。 Since most high-power electronic products such as automobiles, mobile phones, and notebook computers have used nickel-cadmium batteries or lead-acid batteries in the past, lead and cadmium metals generated by such batteries are likely to cause environmental pollution, so most of them are now Lithium-ion batteries are substituted. Lithium batteries can be divided into primary batteries using lithium metal or lithium alloy as negative electrode materials, non-aqueous electrolyte solutions, and rechargeable batteries that rely on lithium ions to move between the positive and negative electrodes to generate electricity, and we generally use them in the 3C industry. Its automotive industry is a lithium-ion battery, referred to as a lithium battery.
請參閱圖1及圖2,為習知軟包鋰電池封裝結構之示意圖及剖面圖。按,習知的鋰電池主要包括有一軟殼包10,現行產品該軟殼包10多是由二片鋁塑膜11、12相對應接合所形成,一般使用的鋁塑膜11、12的內側具有黏合層,且黏合層遇熱融化後具有黏性,因此可透過熱壓合工序將二片鋁塑膜11、12周邊壓合。 Please refer to FIG. 1 and FIG. 2 , which are schematic diagrams and cross-sectional views of a conventional soft pack lithium battery package structure. According to the conventional lithium battery, there is mainly a soft case 10, and the current product of the soft case 10 is formed by the corresponding joining of two aluminum plastic films 11, 12, and the inner side of the commonly used aluminum plastic film 11, 12 The adhesive layer has an adhesive layer, and the adhesive layer has a viscosity after being melted by heat, so that the two aluminum plastic films 11 and 12 can be pressed together by a thermal compression bonding process.
該軟殼包10內包裹有電極片組20及做為正電極及負電極導電用的極柄21、22,且極柄21、22部分外露於該軟殼包10外。實施上,該電極片組20是由複數個正電極片與複數個負極片 所組成,而後將極柄21、22分別與電極片組20的正/負極耳電性連接,最後直接以熱壓合方式分別將二鋁塑膜11、12的四周以熱壓合方式壓合封裝。其中在正電極及負電極導電用的極柄21、22的上、下兩表面可以增設結合膠在極柄21、22二表面的封合部13,使鋁塑膜11、12在極柄21、22的壓合達氣密功能,或是鋁塑膜11、12直接以熱壓合方式,使二鋁塑膜11分別黏合在極柄21、22的上、下兩個表面的封合部13。 The soft case 10 is covered with an electrode sheet group 20 and pole tips 21 and 22 for conducting positive electrodes and negative electrodes, and the pole tips 21 and 22 are partially exposed outside the soft case 10. In practice, the electrode assembly 20 is composed of a plurality of positive electrode sheets and a plurality of negative electrode sheets. After being composed, the pole tips 21 and 22 are electrically connected to the positive/negative electrodes of the electrode sheet group 20, respectively, and finally, the circumferences of the two aluminum plastic films 11 and 12 are directly pressed by thermocompression in a thermocompression manner. Package. The upper and lower surfaces of the pole shanks 21 and 22 for conducting the positive and negative electrodes may be provided with a sealing portion 13 which is bonded to the surfaces of the pole shanks 21 and 22 so that the aluminum plastic films 11 and 12 are in the pole shank 21 22, the pressure is up to the airtight function, or the aluminum plastic film 11, 12 is directly pressed by heat, so that the two aluminum plastic film 11 is adhered to the sealing portions of the upper and lower surfaces of the pole shanks 21, 22, respectively. 13.
然而,鋰電池在充/放電的過程將會因為過熱而使內部產生氣體使該軟殼包10膨脹,氣體將會形成一股向外的應力30,其中在該鋁塑膜11、12與極柄21、22連接的封合部13,該應力30將會不斷地衝擊封合部13,因為此時鋁塑膜11、12向外膨脹的方向與脫膠方向相同,該應力30將會直接衝擊鋁塑膜11、12在封合部13的接合效果,黏合劑也因為熱氣而軟化流動降低黏性,加上應力30的衝擊使該鋁塑膜11包覆在極柄21、22的封合部13容易產生孔隙,如此該軟殼包10內的電解液便會透過孔隙流出,外造成電池損壞,大大減損電池的使用壽命。 However, during the charging/discharging process of the lithium battery, the internal combustion of the soft shell will cause the soft shell 10 to expand due to overheating, and the gas will form an outward stress 30, wherein the aluminum plastic film 11, 12 and the pole The sealing portion 13 connected to the shank 21, 22, the stress 30 will continuously impact the sealing portion 13, because the direction in which the aluminum plastic film 11, 12 expands outward is the same as the direction of degumming, and the stress 30 will directly impact. The bonding effect of the aluminum plastic films 11 and 12 at the sealing portion 13 is also softened and flowed by the hot gas to reduce the viscosity, and the impact of the stress 30 causes the aluminum plastic film 11 to be coated on the poles 21 and 22. The portion 13 is easy to generate pores, so that the electrolyte in the soft shell 10 will flow out through the pores, causing damage to the battery, which greatly degrades the service life of the battery.
於是,為解決習知軟包鋰電池封裝結構在外露極柄的封合部應力不足的問題,本發明在在每個極柄的壓合處設有二片對應接合的接合片,增加極柄壓合處的接合效果,用以對應軟包鋰電池在充/放電的過程因為過熱而內部產生氣體的應力。 Therefore, in order to solve the problem that the conventional soft-pack lithium battery package structure has insufficient stress in the sealing portion of the exposed pole shank, the present invention provides two corresponding joint pieces at the press-fit of each pole shank, and the pole shank is added. The bonding effect at the nip is used to correspond to the stress of the gas generated inside the soft-packed lithium battery during the charging/discharging process due to overheating.
為達上述目的,本發明揭露一種軟包鋰電池封裝結 構,應用於二片包覆膜四週壓合組成一軟殼包用以包裹鋰電池的電極片組,及與該電極片組二極耳電性連接的二極柄,且二極柄部分外露於該軟殼包,其特徵在於前述包覆膜週邊壓合在每個極柄的壓合位置設有二片對應接合的接合片,其中,該接合片可與該包覆膜為相同材質所裁切而成。每個接合片分別具有一第一壓合區和一第二壓合區,二接合片的第一壓合區的接合面相對應接合且將該極柄夾固在中間,而該些第一壓合區的中段分別接合在該極柄的二表面;又,位於該第一壓合區上方的第二壓合區,該些第二壓合區分別遠離該極柄向下摺至該第一壓合區,且該些第二壓合區分別與二片鋁塑膜壓合連接固定。 In order to achieve the above object, the present invention discloses a soft lithium battery encapsulation junction. The structure is applied to a two-piece coating film to form a soft shell package for wrapping a lithium battery, and a two-pole handle electrically connected to the electrode tab group, and the two-pole handle portion is exposed. The soft case is characterized in that the periphery of the cover film is press-fitted at the pressing position of each pole shank to provide two correspondingly joined joint pieces, wherein the joint piece can be made of the same material as the cover film. Cut into pieces. Each of the engaging pieces has a first pressing area and a second pressing area, and the engaging faces of the first pressing areas of the two engaging pieces are correspondingly engaged and the poles are clamped in the middle, and the first pressures are The middle portion of the joint portion is respectively engaged on the two surfaces of the pole shank; and the second nip portion is located above the first nip portion, and the second nip portions are respectively folded away from the pole shank to the first The pressing area is respectively fixed, and the second pressing areas are respectively press-fitted and fixed with two pieces of aluminum plastic film.
其中,每個接合片的第一壓合區與第二壓合區係相同面績,每個接合片的第二壓合區的寬度與前述包覆膜四週壓合的寬度相同。 Wherein, the first nip of each of the engaging pieces is identical to the second nip, and the width of the second nip of each of the engaging pieces is the same as the width of the surrounding of the covering film.
其中,每個接合片的第一壓合區中段沿該極柄向下延申設有一第三壓合區,且該第三壓合區之寬度大於該極柄的寬度,使位於該極柄二表面之接合片的第三壓合區相對應接合且將該極柄夾固在中間,用以增加接合固定效果。 Wherein the middle portion of the first nip of each of the engaging pieces is extended downwardly along the pole shank to have a third nip area, and the width of the third nip area is greater than the width of the pole shank so that the pole shank is located The third nip of the two surface engaging sheets is correspondingly engaged and the pole shank is clamped in the middle for increasing the joint fixing effect.
其中,該包覆膜係鋁塑複合膜或塑膠複合膜,該包覆膜內側具有黏合層,且黏合層遇熱融化後具有黏性,可透過熱壓合工序將對應的二包覆膜壓合。 Wherein, the coating film is an aluminum-plastic composite film or a plastic composite film, and the inner side of the coating film has an adhesive layer, and the adhesive layer has a viscosity after being melted by heat, and the corresponding two coating film can be pressed through a thermal compression bonding process. Hehe.
本發明的優點在於,透過在包覆膜週邊在每個極柄的壓合處設有二片對應接合的接合片,藉由每片接合片的第一壓 合區與第二壓合區間的凹摺處對應軟殼包內的熱氣,因為接合片的第一壓合區與第二壓合區是一體成型的,所以凹摺處將有較習知技術更佳的物理結構,增加包覆膜在極柄壓合處的應力,因此抵制了電池放電時產生的熱氣向上方的應力,避免軟包鋰電池電解液流出問題,延長了電池的使用壽命。 The invention has the advantages that two pieces of correspondingly joined engaging pieces are provided at the nip of each pole shank at the periphery of the covering film, by the first pressure of each piece of the engaging pieces The concave fold of the joint zone and the second press-fit section corresponds to the hot gas in the soft shell, because the first press-fit area of the joint piece and the second press-fit area are integrally formed, so the concave fold will have a more conventional technique. The better physical structure increases the stress of the coating film at the pinch of the pole shank, thus resisting the upward stress of the hot gas generated when the battery is discharged, avoiding the problem of electrolyte outflow of the soft-packed lithium battery, and prolonging the service life of the battery.
10‧‧‧軟殼包 10‧‧‧Soft shell
11、12‧‧‧鋁塑膜 11, 12‧‧‧Aluminum plastic film
20‧‧‧電極片組 20‧‧‧electrode sheet
21、22‧‧‧極柄 21, 22‧‧‧
13‧‧‧封合部 13‧‧‧Fitting Department
30‧‧‧應力 30‧‧‧ stress
100‧‧‧軟殼包 100‧‧‧Soft shell
101、102‧‧‧壓合處 101, 102‧‧‧ Press
110、120‧‧‧包覆膜 110, 120‧‧‧ coating film
200‧‧‧電極片組 200‧‧‧electrode sheet
210、220‧‧‧極柄 210, 220‧‧‧ pole
300‧‧‧接合片 300‧‧‧Joint piece
310‧‧‧第一壓合區 310‧‧‧First nip
320‧‧‧第二壓合區 320‧‧‧Second nip
330‧‧‧第三壓合區 330‧‧‧ Third nip
400‧‧‧應力 400‧‧‧ stress
圖1為習知鋰電池封裝結構之示意圖。 1 is a schematic view of a conventional lithium battery package structure.
圖2為習知鋰電池封裝結構之剖面圖。 2 is a cross-sectional view showing a conventional lithium battery package structure.
圖3為本發明鋰電池封裝結構之分解示意圖一。 3 is an exploded perspective view of the lithium battery package structure of the present invention.
圖4為本發明鋰電池封裝結構之分解示意圖二。 4 is an exploded perspective view of the lithium battery package structure of the present invention.
圖5為本發明鋰電池封裝結構之立體示意圖。 FIG. 5 is a schematic perspective view of a lithium battery package structure of the present invention.
圖6為本發明鋰電池封裝結構之剖面示意圖。 6 is a schematic cross-sectional view showing a lithium battery package structure of the present invention.
茲有關本發明之詳細內容及技術說明,現以實施例來作進一步說明,但應瞭解的是,該等實施例僅為例示說明之用,而不應被解釋為本發明實施之限制。 The detailed description of the present invention and the technical description of the present invention are further illustrated by the embodiments, but it should be understood that these embodiments are for illustrative purposes only and are not to be construed as limiting.
請參閱圖3及圖4,為本發明軟包鋰電池封裝結構的示意圖。本發明揭露一種軟包鋰電池封裝結構,應用於二片包覆膜110、120四週的壓合處101、102相對應接合組成一軟殼包100,該些包覆膜110、120係鋁塑複合膜或塑膠複合膜,該些包覆膜110、120的內側係具有黏合層的接合面,黏合層遇熱融化後具有黏性,因此二 片包覆膜110、120四週相對應接觸的接合面可以藉由熱壓合接合固定。 Please refer to FIG. 3 and FIG. 4 , which are schematic diagrams showing the package structure of the soft lithium battery of the present invention. The invention discloses a soft-package lithium battery package structure, which is applied to the nips 101 and 102 around the two cover films 110 and 120 to form a soft shell 100, and the cover films 110 and 120 are aluminum-plastic. a composite film or a plastic composite film, wherein the inner sides of the coating films 110 and 120 have a bonding surface of an adhesive layer, and the adhesive layer has a viscosity after being melted by heat, so The joint faces that are in contact with each other around the sheet coating films 110, 120 may be fixed by thermocompression bonding.
該軟殼包100用以包裹鋰電池的電極片組200,及與該電極片組200二極耳電性連接的二極柄210、220,且二極柄210、220部分外露於該軟殼包100。本實施說明例以二極柄210、220在該軟殼包100同一側為說明例。 The soft case 100 is used to wrap the electrode sheet set 200 of the lithium battery, and the two pole handles 210 and 220 electrically connected to the two poles of the electrode sheet set 200, and the two pole handles 210 and 220 are partially exposed to the soft shell. Package 100. In the present embodiment, the two pole shanks 210 and 220 are illustrated on the same side of the soft package 100.
本發明特徵在於前述包覆膜110、120週邊壓合處101、102在每個極柄210、220的壓合位置設有二片對應接合的接合片300,其中,最佳實施方式係該些接合片300與前述包覆膜110、120相同材質所裁切而成。 The present invention is characterized in that the peripheral nips 101, 102 of the cover film 110, 120 are provided with two correspondingly engaging engaging sheets 300 at the pressing positions of each of the pole shanks 210, 220, wherein the preferred embodiment is The bonding sheet 300 is cut out from the same material as the coating films 110 and 120.
每個接合片300分別具有一第一壓合區310和一第二壓合區320,每個極柄210、220二表面分別被二接合片300的第一壓合區310的夾住,二接合片300的第一壓合區310由具有黏合層的接合面相對應接合且將該極柄210(220)夾固在中間,而該些第一壓合區310的中段分別接合在該極柄210(220)的二表面;又,位於該第一壓合區310上方的第二壓合區320,該些第二壓合區320分別遠離該極柄210(220)向下摺至該第一壓合區310,即該第一壓合區310與該第二壓合區320間形成凹部向下的形態,且此時二接合片300的第二壓合區320具有黏合層的接合面向外,第二壓合區320恰可分別對應前述包覆膜110、120四週的壓合處101、102壓合固定。 Each of the engaging pieces 300 has a first pressing area 310 and a second pressing area 320. The two surfaces of each of the pole pieces 210 and 220 are respectively clamped by the first pressing area 310 of the two engaging pieces 300. The first nip 310 of the bonding piece 300 is correspondingly engaged by the bonding surface having the bonding layer and the pole shank 210 (220) is clamped in the middle, and the middle sections of the first nips 310 are respectively engaged with the pole shank a second surface of the 210 (220); and a second nip 320 above the first nip 310, the second nip 320 is folded away from the pole shank 210 (220) to the first a pressing portion 310, that is, a shape in which the concave portion is formed downward between the first pressing portion 310 and the second pressing portion 320, and at this time, the second pressing portion 320 of the two bonding sheets 300 has a bonding surface of the bonding layer. In addition, the second nip area 320 can be pressed and fixed corresponding to the nips 101, 102 around the coating films 110, 120, respectively.
其中,每個接合片300的第一壓合區310中段沿該極柄210(220)向下延申設有一第三壓合區330(如圖4所示),且該第三 壓合區330之寬度大於該極柄210(220)的寬度,使位於該極柄210(220)二表面之接合片300的第三壓合區330相對應接合,且將該極柄210(220)夾固在中間,用以增加接合固定效果。 Wherein, a middle portion of the first nip 310 of each of the engaging pieces 300 extends downwardly along the pole shank 210 (220) to form a third nip 330 (shown in FIG. 4), and the third The width of the nip 330 is greater than the width of the pole shank 210 (220), so that the third nip 330 of the bonding piece 300 on the two surfaces of the pole shank 210 (220) is correspondingly engaged, and the pole shank 210 is 220) is clamped in the middle to increase the joint fixing effect.
實施上,在該些極柄210、220的上、下兩個表面可以增加結合膠,結合膠設置於每個接合片300的第一壓合區310中段及第三壓合區330,使每個極柄210、220上接合片300的接合達氣密功能。 In practice, the bonding glue may be added to the upper and lower surfaces of the pole shanks 210 and 220, and the bonding glue is disposed on the middle portion of the first nip 310 and the third nip region 330 of each of the bonding sheets 300, so that each The joints of the engaging pieces 300 on the pole shanks 210, 220 are airtight.
其中,實施上每個接合片300的第一壓合區310與第二壓合區320最佳為相同面績,每個接合片300的第二壓合區320的寬度最佳係與前述二片包覆膜110、120周邊壓合處101、102的寬度相同。 Wherein, the first nip 310 and the second nip 320 of each of the bonding sheets 300 are optimally the same, and the width of the second nip 320 of each of the bonding sheets 300 is optimally the same as the foregoing two The widths of the peripheral nips 101, 102 of the sheet covering films 110, 120 are the same.
請再參閱圖5及圖6,本發明按照已知的壓合工序進行熱壓合,即可完成軟殼包100的封裝,完成軟包鋰電池封裝結構。如此一來,在軟殼包100周邊二極柄210、220外露處,在包覆膜110、120週邊在每個極柄210、220的壓合處設有二片對應接合的接合片300。 Referring to FIG. 5 and FIG. 6 , the present invention performs thermal compression bonding according to a known pressing process, thereby completing the packaging of the soft package 100 and completing the package structure of the soft lithium battery. In this way, at the exposed portions of the peripheral poles 210 and 220 of the soft package 100, two sheets of correspondingly joined engaging sheets 300 are provided at the press-fit portions of the pole pieces 210 and 220 around the covering films 110 and 120.
當鋰電池在充/放電的過程將會因為過熱而使內部產生氣體使該軟殼包100膨脹時,軟殼包100內的氣體將會形成一股向外衝的應力400,其中在極柄210、220的壓合處(圖6以極柄210為說明例),藉由接合片300的第一壓合區310和第二壓合區320的凹折,在第一壓合區310和第二壓合區320所造成結構上的的凹處將有相較於習知直接接合有更好的結合效果,使該接合片300與極 柄210、220及包覆膜110、120接合處的脫膠方向與前述應力400方向相反,且該接合片300透過第一壓合區310和一第二壓合區320分別與該極柄210、220及包覆膜110、120結合,相較於現有技術具有更大的接合面積;如此,包覆膜110、120在每個極柄210、220的壓合處,因為設有互相接合的二接合片300將得到最好的結構加強,透過該些接合片300的結構加強,該軟殼包100在每個極柄210、220處將更能阻擋軟殼包100膨脹時向外擴張的力量,降低了電池放電時產生的氣體向外施力產生空隙,導致電解液流出問題,延長了電池的使用壽命。 When the lithium battery is charged/discharged due to overheating and internal gas is generated to expand the soft package 100, the gas in the soft package 100 will form an outward pressure 400, wherein the pole shank The nip of 210, 220 (FIG. 6 is illustrated by the pole shank 210), by the first nip 310 of the bonding piece 300 and the concave fold of the second nip 320, in the first nip 310 and The structural recess formed by the second nip 320 will have a better bonding effect than the conventional direct bonding, so that the bonding piece 300 and the pole The debonding direction of the joint of the shank 210, 220 and the covering film 110, 120 is opposite to the direction of the stress 400, and the bonding piece 300 passes through the first nip 310 and the second nip 320, respectively. 220 and the cover film 110, 120 combined, having a larger joint area than the prior art; thus, the cover film 110, 120 at the press-fit of each pole shank 210, 220, because of the mutual engagement of two The gusset 300 will provide the best structural reinforcement through the structure of the gussets 300. The soft hull 100 will more effectively block the outward expansion of the soft crust 100 as it expands at each pole shank 210, 220. It reduces the gas generated by the discharge of the battery and generates a gap by external force, which causes the electrolyte to flow out and prolongs the service life of the battery.
惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及發明說明內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 The above is only the preferred embodiment of the present invention, and the scope of the invention is not limited thereto, that is, the simple equivalent changes and modifications made by the scope of the invention and the description of the invention are All remain within the scope of the invention patent.
100‧‧‧軟殼包 100‧‧‧Soft shell
101、102‧‧‧壓合處 101, 102‧‧‧ Press
110、120‧‧‧包覆膜 110, 120‧‧‧ coating film
200‧‧‧電極片組 200‧‧‧electrode sheet
210、220‧‧‧極柄 210, 220‧‧‧ pole
300‧‧‧接合片 300‧‧‧Joint piece
310‧‧‧第一壓合區 310‧‧‧First nip
320‧‧‧第二壓合區 320‧‧‧Second nip
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