TWI525190B - Coffee biolubricant - Google Patents

Coffee biolubricant Download PDF

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TWI525190B
TWI525190B TW103106777A TW103106777A TWI525190B TW I525190 B TWI525190 B TW I525190B TW 103106777 A TW103106777 A TW 103106777A TW 103106777 A TW103106777 A TW 103106777A TW I525190 B TWI525190 B TW I525190B
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oil
coffee
coffee raw
lubricating oil
mineral
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TW103106777A
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TW201533234A (en
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洪政豪
楊授印
王建評
沈孟穎
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國立虎尾科技大學
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Description

咖啡生質潤滑油 Coffee raw oil

本發明係關於一種潤滑油,特別係一種摻混咖啡生質油的咖啡生質潤滑油。 The present invention relates to a lubricating oil, and in particular to a coffee raw oil blended with a coffee green oil.

傳統潤滑油係包含基礎油及添加劑,其中基礎油係以礦物油為大宗,而添加劑則可以包含有防泡劑、擴散劑、抗氧化劑、清洗劑或防鏽劑等,傳統潤滑油主要係用以潤滑汽、機車引擎及各式機械,減少機件的磨耗,以降低機件更換之頻率。 Conventional lubricating oils include base oils and additives. The base oils are mainly mineral oils, while the additives may contain antifoaming agents, diffusing agents, antioxidants, cleaning agents or rust inhibitors. Lubricate the steam, locomotive engine and various types of machinery to reduce the wear of the parts to reduce the frequency of machine replacement.

礦物油係原油透過蒸餾與精煉所獲得的衍生物,主要成分為碳氫化合物,具有相當的黏度,可以使機件的運動界面於運轉時產生一油膜厚度,以保護機件不受磨損,但也由於礦物油之黏度,反而提升了傳統潤滑油的摩擦係數,進而造成機件長時間的運轉摩擦下,運作溫度過高。當機件長期處於高溫的環境之下,伴隨而來的是機件之磨損與使用壽命之降低。 The derivative of mineral oil is obtained by distillation and refining. The main component is hydrocarbon, which has a considerable viscosity. It can make the moving interface of the machine produce a film thickness during operation to protect the machine from wear and tear, but Also due to the viscosity of the mineral oil, the friction coefficient of the conventional lubricating oil is increased, and the operating temperature is too high under the long-term running friction of the machine. When the machine is in a high temperature environment for a long time, it is accompanied by the wear and tear of the machine and the service life.

此外,因礦物油係提煉自原油,然而現今石化能源因地球人口的逐日增加,過度的開採之下,原油正逐漸邁向枯竭,且提煉原油之過程必然會排放大量的二氧化碳,促使地球溫室效應之惡化,而影響地球的生態環境及氣候。 In addition, because mineral oil is extracted from crude oil, nowadays petrochemical energy is increasing due to the increasing population of the earth. Under excessive mining, crude oil is gradually depleting, and the process of refining crude oil will inevitably emit a large amount of carbon dioxide, which will promote the global warming effect. It deteriorates and affects the earth's ecological environment and climate.

有鑑於此,基於傳統潤滑油具有「較高的摩擦係數」及「破壞環境」的問題,因此仍然有必要提供一種改良的潤滑油,以解決上述問 題。 In view of this, based on the problem of "higher friction coefficient" and "damage to the environment", it is still necessary to provide an improved lubricating oil to solve the above problem. question.

本發明之主要目的係提供一種咖啡生質潤滑油,係可以藉由咖啡生質油的添加,降低傳統潤滑油之摩擦係數,以減少機件之磨耗者。 The main object of the present invention is to provide a coffee raw oil which can reduce the friction coefficient of the conventional lubricating oil by adding the coffee raw oil to reduce the wear of the machine.

本發明之再一目的係提供一種咖啡生質潤滑油,係可以減少礦物油之添加,降低提煉原油之頻率,以避免環境受危害者。 Still another object of the present invention is to provide a coffee raw oil which can reduce the addition of mineral oil and reduce the frequency of refining crude oil to avoid environmental hazards.

為達到前述發明目的,本發明所運用之技術手段及藉由該技術手段所能達到之功效包含有: 一種咖啡生質潤滑油,係包含:以重量百分比計為60~70%之礦物油、16~20%之咖啡生質油及14~20%之活性劑;其中該咖啡生質油係為400~550℃之溫度下,咖啡裂解所產製之油,且該咖啡生質油於經過裂解時進行加氮處理,以去除該咖啡生質油中的雜質。 In order to achieve the foregoing object, the technical means utilized by the present invention and the achievable effects by the technical means include: A coffee raw oil comprising: 60-70% by weight of mineral oil, 16-20% of coffee green oil and 14-20% active agent; wherein the coffee raw oil is 400 At a temperature of ~550 ° C, the coffee is cracked by the produced oil, and the coffee green oil is subjected to nitrogen treatment during the cracking to remove impurities in the coffee green oil.

本發明之咖啡生質潤滑油,其中,係包含以重量百分比計為65%之礦物油、16%之咖啡生質油及19%之活性劑。 The coffee biomass lubricating oil of the present invention comprises 65% by weight of mineral oil, 16% of coffee green oil and 19% of active agent.

本發明之咖啡生質潤滑油,其中,該咖啡生質油於40℃之黏度係為60~70cSt。 The coffee raw material lubricating oil of the present invention, wherein the coffee raw oil has a viscosity at 40 ° C of 60 to 70 cSt.

本發明之咖啡生質潤滑油,其中,該礦物油係為礦油、機械油、白油或石蠟油。 The coffee raw oil of the present invention, wherein the mineral oil is mineral oil, mechanical oil, white oil or paraffin oil.

本發明之咖啡生質潤滑油,其中,該活性劑係為聚氧化烯烷基醚(polyoxyalkylene alkyl ether)及山梨坦油酸酯(sorbitan oleate),且重量比例係為6:1~15:10。 The coffee raw material lubricating oil of the present invention, wherein the active agent is polyoxyalkylene alkyl ether and sorbitan oleate, and the weight ratio is from 6:1 to 15:10. .

本發明咖啡生質潤滑油,係可以有效改善傳統潤滑油之黏度,降低機件因摩擦所產生之熱,避免機件長期運作於高溫下,達到延緩機件的使用壽命之功效。 The coffee raw material lubricating oil of the invention can effectively improve the viscosity of the traditional lubricating oil, reduce the heat generated by the friction of the machine parts, avoid the long-term operation of the machine parts under high temperature, and achieve the effect of delaying the service life of the machine parts.

本發明咖啡生質潤滑油,係降低礦物油之用量,進而減緩原 油過度的開採且減少原油的提煉,達到節省能源及減輕空氣汙染之功效。 The coffee raw material lubricating oil of the invention reduces the amount of mineral oil, thereby slowing down the original Excessive oil extraction and reduction of crude oil refining can save energy and reduce air pollution.

第1圖係本發明之咖啡生質油於40℃下之黏度與時間關係圖。 Fig. 1 is a graph showing the relationship between viscosity and time of the coffee green oil of the present invention at 40 °C.

第2圖係比較本發明咖啡生質潤滑油與LPS68潤滑油於負荷20N與80rpm下之摩擦係數及機件溫度示意圖。 Fig. 2 is a schematic view showing the friction coefficient and the temperature of the machine parts of the coffee raw oil and the LPS68 lubricating oil of the present invention under load of 20 N and 80 rpm.

第3圖係比較本發明咖啡生質潤滑油與LPS68潤滑油於負荷40N與80rpm下之摩擦係數、機件溫度示意圖。 Fig. 3 is a schematic view showing the friction coefficient and the temperature of the machine parts of the coffee raw material lubricating oil of the present invention and the LPS68 lubricating oil at a load of 40 N and 80 rpm.

第4圖係比較本發明咖啡生質潤滑油與LPS68潤滑油於負荷60N與320rpm下之摩擦係數及機件溫度示意圖。 Fig. 4 is a graph showing the friction coefficient and the temperature of the machine parts of the coffee raw oil and LPS68 lubricating oil of the present invention at a load of 60 N and 320 rpm.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,並配合所附圖式,作詳細說明如下:本發明之咖啡生質潤滑油,係包含以重量百分比計為60~70%之礦物油、16~20%之咖啡生質油及14~20%之活性劑。 The above and other objects, features and advantages of the present invention will become more <RTIgt; Containing 60 to 70% by weight of mineral oil, 16 to 20% of coffee green oil and 14 to 20% of active agent.

詳言而之,礦物油較佳係可以選為礦油、機械油、白油或石蠟油,由於該礦物油成本較低,且可耐受之溫度係介於110~130℃之間,因此廣泛應用於工業機械間的潤滑油,是以於本發明中,該礦物油係作為咖啡生質潤滑油之主要基礎油。 In particular, mineral oil is preferably selected from mineral oil, mechanical oil, white oil or paraffin oil. Since the mineral oil is low in cost and can withstand a temperature between 110 and 130 ° C, The lubricating oil widely used in industrial machinery is the main base oil of the coffee raw material lubricating oil in the present invention.

上述咖啡生質油係可以經由以下方式製備獲得,取1公斤之咖啡,於400~550℃溫度下進行裂解,以獲得該咖啡生質油,較佳係另可以使該咖啡生質油經過裂解時進行加氮處理,以去除該咖啡生質油中的雜質,最終產油率係為25wt%,其中裂解咖啡之溫度以450℃為佳,且所獲得之咖啡生質油40℃下黏度係可以維持於60~70cSt(如第1圖所示),90天內黏度變化皆不大;由於該咖啡生質油取得之方式為本領域技術人員可 以理解,在此不加以贅述。 The above-mentioned coffee biomass oil can be obtained by the following method, taking 1 kg of coffee and lysing at 400-550 ° C to obtain the coffee green oil, preferably, the coffee raw oil can be cracked. Nitrogen treatment is carried out to remove impurities in the coffee raw oil, and the final oil production rate is 25 wt%, wherein the temperature of the cracked coffee is preferably 450 ° C, and the obtained coffee biomass oil is 40 ° C viscosity system. It can be maintained at 60~70cSt (as shown in Figure 1), and the viscosity change is not great within 90 days; the way the coffee green oil is obtained is available to those skilled in the art. For the sake of understanding, it will not be repeated here.

上述活性劑可以係任何具有增溶效果的添加物,較佳係選為聚氧化烯烷基醚(polyoxyalkylene alkyl ether)及山梨坦油酸酯(sorbitan oleate),用以與該咖啡生質油結合,藉此使該咖啡生質油與礦物油充分混和,其中,聚氧化烯烷基醚及山梨坦油酸酯之重量比例係可以為6:1~15:10,以13:6為佳。 The above active agent may be any additive having a solubilizing effect, preferably selected from the group consisting of polyoxyalkylene alkyl ether and sorbitan oleate for binding to the coffee raw oil. Thereby, the coffee biomass oil is thoroughly mixed with the mineral oil, wherein the weight ratio of the polyoxyalkylene alkyl ether and the sorbitan oleate may be 6:1 to 15:10, preferably 13:6.

本發明咖啡生質潤滑油係利用咖啡生質油摻混礦物油,以減少礦物油用量,其中以重量百分比計為65%之礦物油、16%之咖啡生質油及19%之活性劑為佳;透過咖啡生質油代替部分礦物油可以提高表面接觸角,降低表面黏附力,進而改善傳統潤滑油具有較高摩擦係數的問題,使機件不易摩擦生熱,達到保護機件較不受磨損之功效。 The coffee raw material lubricating oil of the invention is a mineral oil blended with coffee raw oil to reduce the amount of mineral oil, wherein 65% by weight of mineral oil, 16% of coffee raw oil and 19% of active agent are Better; replacing some mineral oil with coffee green oil can increase the surface contact angle and reduce the surface adhesion, thus improving the problem of the high friction coefficient of the traditional lubricating oil, so that the machine is not easy to rub and heat, so that the protection of the machine is less The effect of wear and tear.

為證實本發明咖啡生質潤滑油係具有上述之功效,遂進行以下試驗: In order to confirm that the coffee biomass lubricating oil of the present invention has the above-mentioned effects, the following tests were carried out:

(A)黏度試驗(A) Viscosity test

本試驗係以雷氏黏度計(Redwood viscosimeter)測試本發明咖啡生質潤滑油的黏度,該咖啡生質潤滑油之配比係為以重量百分比計為65%之礦物油、16%之咖啡生質油、13%之聚氧化烯烷基醚及6%之山梨坦油酸酯,並使用LPS68潤滑油作為對照組,LPS68係以礦物油為主的潤滑油,其結果如第1表所示。 This test tests the viscosity of the coffee raw oil of the present invention by a Redwood viscosimeter, which is a blend of 65% by weight of mineral oil and 16% of coffee. A lubricating oil, 13% polyoxyalkylene alkyl ether and 6% sorbitan oleate, and LPS68 lubricating oil was used as a control group, and LPS68 was a mineral oil-based lubricating oil. The results are shown in Table 1. .

請參照第1表所示,於高溫下,本發明咖啡生質潤滑油之黏度係明顯比LPS68潤滑油低,代表透過咖啡生質油之添加,係可以有效降低黏度,以維持潤滑效果。 Please refer to Table 1. At high temperature, the viscosity of the coffee raw oil of the present invention is significantly lower than that of the LPS68 lubricating oil, which means that the addition of the coffee raw oil can effectively reduce the viscosity to maintain the lubricating effect.

(B)磨耗試驗(B) Abrasion test

本試驗係利用一並聯式磨潤試驗機依照ASTM D-2782進行磨耗試驗,以於不同負荷量及轉速運轉下,測量咖啡生質潤滑油與LPS68潤滑油之磨耗性質,如摩擦係數、機件溫度及接觸電阻,其結果如第2~4圖所示,於各圖中之代號係如第2表所示。 This test uses a parallel type grinding tester to perform the abrasion test according to ASTM D-2782 to measure the wear properties of coffee raw oil and LPS68 lubricating oil under different load and speed, such as friction coefficient and mechanical parts. The temperature and contact resistance are shown in Figures 2 to 4, and the symbols in the respective figures are shown in Table 2.

請參照第2圖所示,係為於負荷為20N且轉速為80rpm下,隨時間變化所測得之摩擦係數與機件溫度;於各時間下,本發明咖啡生質潤滑油的摩擦係數皆低於LPS68潤滑油,進而影響機件溫度;對應於摩擦係數之結果,由於使用該咖啡生質潤滑油所造成的摩擦較小,機件溫度之上升幅度亦顯著低於LPS68潤滑油。 Please refer to Fig. 2, which is the friction coefficient measured with time under the load of 20N and the rotation speed of 80 rpm and the temperature of the machine. At each time, the friction coefficient of the coffee raw oil of the present invention is Lower than LPS68 lubricating oil, which affects the temperature of the machine; corresponding to the friction coefficient, the friction caused by the use of the coffee raw oil is smaller, and the temperature rise of the machine is also significantly lower than that of the LPS68 lubricating oil.

請參照第3圖所示,係為於負荷40N且轉速為80rpm下,隨時間變化所測得之摩擦係數及機件溫度;於各時間下,本發明咖啡生質潤滑油的摩擦係數皆明顯低於LPS68潤滑油,且咖啡生質潤滑油的機件溫度亦均低於LPS68潤滑油,前述結果係符合摩擦係數較小,所對應之機件溫度亦較低之結果。 Please refer to the third figure, which is the friction coefficient measured by time and the temperature of the machine under the load of 40N and the rotation speed of 80rpm. At each time, the friction coefficient of the coffee raw oil of the present invention is obvious. It is lower than LPS68 lubricating oil, and the temperature of the coffee raw material lubricating oil is also lower than that of LPS68 lubricating oil. The above results are consistent with the lower friction coefficient and the lower temperature of the corresponding parts.

請參照第4圖所示,係為於負荷60N及轉速320rpm下,隨時間變化所測得之摩擦係數與機件溫度;雖本發明咖啡生質潤滑油之摩擦係數一開始係高於LPS68潤滑油,但隨著時間增長,於第10分鐘時,摩擦係數逐漸下降且低於LPS68潤滑油;對應於摩擦係數結果,使用該咖啡生質潤滑油所測得的初始機件溫度雖高於LPS68潤滑油,然而隨著後續摩擦係數相對較低的情形下,溫度上升幅度亦遠低於LPS68潤滑油,是以,該咖啡生質潤滑油係可以降低機件所產生的摩擦熱,避免機件運作溫度過高。 Please refer to Fig. 4, which is the friction coefficient measured with time at 60N and 320rpm, and the temperature of the machine. Although the friction coefficient of the coffee raw oil of the present invention is higher than LPS68. Lubricating oil, but as time goes by, the friction coefficient gradually decreases and is lower than LPS68 lubricating oil at the 10th minute; corresponding to the friction coefficient result, the initial mechanical temperature measured by using the coffee raw lubricating oil is higher than LPS68 lubricating oil, however, with the subsequent lower friction coefficient, the temperature rise is much lower than that of LPS68 lubricating oil. Therefore, the coffee raw lubricating oil can reduce the friction heat generated by the machine and avoid the machine. The operating temperature of the piece is too high.

綜合上述,本發明咖啡生質潤滑油,係可以有效改善傳統潤滑油之黏度,降低機件因摩擦所產生之熱,避免機件長期運作於高溫下,達到延緩機件的使用壽命之功效。 In summary, the coffee raw material lubricating oil of the invention can effectively improve the viscosity of the traditional lubricating oil, reduce the heat generated by the friction of the machine parts, avoid the long-term operation of the machine parts under high temperature, and achieve the effect of delaying the service life of the machine parts.

再者,本發明咖啡生質潤滑油,係降低礦物油之用量,進而減緩原油過度的開採且減少原油的提煉,達到節省能源及減輕空氣汙染之功效。 Furthermore, the coffee raw material lubricating oil of the invention reduces the amount of mineral oil, thereby slowing the excessive exploitation of crude oil and reducing the refining of crude oil, thereby achieving the effects of saving energy and reducing air pollution.

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described in connection with the preferred embodiments described above, it is not intended to limit the scope of the invention. The technical scope of the invention is protected, and therefore the scope of the invention is defined by the scope of the appended claims.

Claims (5)

一種咖啡生質潤滑油,係包含:以重量百分比計為60~70%之礦物油、16~20%之咖啡生質油及14~20%之活性劑;其中該咖啡生質油係為400~550℃之溫度下,咖啡裂解所產製之油,且該咖啡生質油於經過裂解時進行加氮處理,以去除該咖啡生質油中的雜質。 A coffee raw oil comprising: 60-70% by weight of mineral oil, 16-20% of coffee green oil and 14-20% active agent; wherein the coffee raw oil is 400 At a temperature of ~550 ° C, the coffee is cracked by the produced oil, and the coffee green oil is subjected to nitrogen treatment during the cracking to remove impurities in the coffee green oil. 如申請專利範圍第1項所述之咖啡生質潤滑油,其中,係包含以重量百分比計為65%之礦物油、16%之咖啡生質油及19%之活性劑。 The coffee raw oil according to claim 1, wherein the mineral oil comprises 65% by weight of mineral oil, 16% of coffee green oil and 19% of active agent. 如申請專利範圍第1或2項所述之咖啡生質潤滑油,其中,該咖啡生質油於40℃之黏度係為60~70cSt。 The coffee raw material lubricating oil according to claim 1 or 2, wherein the coffee raw oil has a viscosity at 40 ° C of 60 to 70 cSt. 如申請專利範圍第1或2項所述之咖啡生質潤滑油,其中,該礦物油係為礦油、機械油、白油或石蠟油。 The coffee raw oil according to claim 1 or 2, wherein the mineral oil is mineral oil, mechanical oil, white oil or paraffin oil. 如申請專利範圍第1或2項所述之咖啡生質潤滑油,其中,該活性劑係為聚氧化烯烷基醚(polyoxyalkylene alkyl ether)及山梨坦油酸酯(sorbitan oleate),且重量比例係為6:1~15:10。 The coffee raw material lubricating oil according to claim 1 or 2, wherein the active agent is polyoxyalkylene alkyl ether and sorbitan oleate, and the proportion by weight The system is 6:1~15:10.
TW103106777A 2014-02-27 2014-02-27 Coffee biolubricant TWI525190B (en)

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TWI673356B (en) * 2018-11-14 2019-10-01 National Formosa University Whole grain coffee lubricant
TWI664284B (en) * 2018-12-03 2019-07-01 National Formosa University Nano Granulated Coffee Lubricants
US10920168B2 (en) 2019-05-29 2021-02-16 National Formosa University Coffee lubricant having nanoparticles
CN110373244B (en) * 2019-08-22 2021-12-24 宿州市杰牌化学有限公司 Production process for preparing lubricating oil by using coffee residual oil

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