TWI517746B - Electroluminescent device - Google Patents

Electroluminescent device Download PDF

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TWI517746B
TWI517746B TW099103046A TW99103046A TWI517746B TW I517746 B TWI517746 B TW I517746B TW 099103046 A TW099103046 A TW 099103046A TW 99103046 A TW99103046 A TW 99103046A TW I517746 B TWI517746 B TW I517746B
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substrate
electroluminescent device
electrode
substrate electrode
electrical
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TW201038112A (en
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赫柏特 弗瑞區 柏爾那
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皇家飛利浦電子股份有限公司
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/81Anodes
    • H10K50/814Anodes combined with auxiliary electrodes, e.g. ITO layer combined with metal lines
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/81Anodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/805Electrodes
    • H10K50/82Cathodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/85Arrangements for extracting light from the devices
    • H10K50/854Arrangements for extracting light from the devices comprising scattering means
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/88Terminals, e.g. bond pads
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00Metal working
    • Y10T29/49Method of mechanical manufacture
    • Y10T29/49002Electrical device making
    • Y10T29/49117Conductor or circuit manufacturing

Description

電致發光裝置Electroluminescent device

本發明係關於一種電致發光裝置,其包括一層系統,該層系統具有一基板頂部上之一基板電極及至少一個後續層堆疊,該至少一個後續層堆疊包括一反電極及具有至少一個有機電致發光層之一電致發光層堆疊,其中該電致發光層堆疊配置於該基板電極與該反電極之間。為改良該基板電極上之電流分佈,施加至少一個電分路構件至該基板電極頂部。此外,本發明係針對一種用於藉由一電分路構件分路一電致發光裝置之一基板電極之方法。The present invention relates to an electroluminescent device comprising a system having a substrate electrode on top of a substrate and at least one subsequent layer stack, the at least one subsequent layer stack comprising a counter electrode and having at least one organic One of the electroluminescent layer stacks, wherein the electroluminescent layer stack is disposed between the substrate electrode and the counter electrode. To improve the current distribution on the substrate electrode, at least one electrical shunt member is applied to the top of the substrate electrode. Furthermore, the present invention is directed to a method for shunting a substrate electrode of an electroluminescent device by an electrical branching member.

WO 2007/013 001 A2中闡述一種有機發光二極體(OLED)。該有機發光二極體由夾在兩個電極之間的約100 nm之有機物質之一薄層組成。該等電極層通常具有約等於該有機物質之厚度的一厚度。當在該兩個電極之間施加一電壓(通常在2伏與10伏之間)時,該等有機物質發射光。遺憾地,由於其小厚度,此等電極之電阻係高的,因此難以達成電壓在電極區域上之一均質分佈。為消除此缺點,施加導電柱至OLED之反電極。然而,該反電極係由一反射金屬製成,其具有一低電阻且因此其僅導致跨越該反電極區域之一較小電壓降。此一OLED之電流分佈主要係由未經該等柱改良之透明基板電極之性質確定。此等導電柱連接至囊封由電極及電致發光層形成之層堆疊之一囊封構件。遺憾地,有機層及反電極非常敏感。因此,將該等導電柱與該等反電極連接常常導致電短路。舉例而言,此等短路可因軟有機層之局部破壞從而使反電極與基板電極直接接觸而出現。An organic light emitting diode (OLED) is described in WO 2007/013 001 A2. The organic light-emitting diode consists of a thin layer of one of about 100 nm of organic material sandwiched between two electrodes. The electrode layers typically have a thickness approximately equal to the thickness of the organic material. When a voltage is applied between the two electrodes (typically between 2 volts and 10 volts), the organic species emit light. Unfortunately, due to their small thickness, the resistance of these electrodes is high, so it is difficult to achieve a homogeneous distribution of voltage on the electrode region. To eliminate this drawback, a conductive post is applied to the counter electrode of the OLED. However, the counter electrode is made of a reflective metal that has a low resistance and therefore only results in a small voltage drop across one of the counter electrode regions. The current distribution of this OLED is primarily determined by the nature of the transparent substrate electrode that has not been modified by such columns. The conductive posts are attached to one of the encapsulating members that encapsulate the layer stack formed by the electrodes and the electroluminescent layer. Unfortunately, the organic layer and the counter electrode are very sensitive. Therefore, connecting the conductive posts to the counter electrodes often results in an electrical short. For example, such shorts can occur due to localized destruction of the soft organic layer such that the counter electrode is in direct contact with the substrate electrode.

WO 2009/001241 A1中闡述一種其他有機發光二極體(OLED)。電致發光裝置包括具有一基板電極之一基板及複數個相互間隔開之電分路構件,每一電分路構件與該基板電極直接電接觸,其中一電致發光層堆疊提供於該基板電極及分路線路之頂部上,且一反電極配置於該電致發光層堆疊頂部上。將該等電分路構件提供成與該基板層直接電接觸以使得在該電致發光裝置之操作期間跨越該基板層之電壓分佈較為均質。在頂部上具有局部分路線路之平坦基板電極之所得拓撲偏離一平坦拓撲,從而因分路線路干擾覆蓋該基板電極之後續層之效能,最終導致毀壞該OLED裝置之短路。此外,應用材料沈積技術或材料印刷技術在基板電極之表面上製造電分路構件基本上係費力且昂貴的。One other organic light emitting diode (OLED) is described in WO 2009/001241 A1. The electroluminescent device comprises a substrate having a substrate electrode and a plurality of electrically spaced apart electrical branching members, each electrical branching member being in direct electrical contact with the substrate electrode, wherein an electroluminescent layer stack is provided on the substrate electrode And a top of the shunt line, and a counter electrode is disposed on top of the electroluminescent layer stack. The electrical shunt members are provided in direct electrical contact with the substrate layer such that the voltage distribution across the substrate layer during the operation of the electroluminescent device is relatively homogeneous. The resulting topology of a flat substrate electrode having a partial partial line on the top deviates from a flat topology, thereby dissipating the effectiveness of the subsequent layers of the substrate electrode due to shunting circuitry, ultimately resulting in a short circuit that destroys the OLED device. Furthermore, the application of material deposition techniques or material printing techniques to fabricate electrical shunt components on the surface of the substrate electrodes is substantially laborious and expensive.

因此,本發明出於其目標而須消除上述缺點。特定而言,本發明之一目標係提供一電致發光裝置,其揭示對電連接至基板電極之電分路構件之一經改良施加,從而導致一更可靠且更廉價之電致發光裝置。Therefore, the present invention has to eliminate the above disadvantages for its purpose. In particular, it is an object of the present invention to provide an electroluminescent device that reveals improved application of one of the electrical shunt members electrically connected to the substrate electrodes, resulting in a more reliable and less expensive electroluminescent device.

此目標係藉由一電致發光裝置達成,該電致發光裝置包括:一層系統,其具有一基板頂部上之一基板電極及至少一個後續層堆疊,該至少一個後續層堆疊包括一反電極及具有至少一個有機電致發光層之一電致發光層堆疊,其中該電致發光層堆疊配置於該基板電極與該反電極之間;及至少一個電分路構件,其施加至該基板電極頂部以改良該基板電極上之電流分佈,該電致發光裝置之特徵在於該電分路構件係經由至少一個電連接構件施加至該基板電極,而該電連接構件及該分路構件係配置於該後續層堆疊外側。The object is achieved by an electroluminescent device comprising: a layer system having a substrate electrode on a top of the substrate and at least one subsequent layer stack, the at least one subsequent layer stack comprising a counter electrode and An electroluminescent layer stack having at least one organic electroluminescent layer, wherein the electroluminescent layer stack is disposed between the substrate electrode and the counter electrode; and at least one electrical branching member applied to the top of the substrate electrode To improve the current distribution on the substrate electrode, the electroluminescent device is characterized in that the electrical branching member is applied to the substrate electrode via at least one electrical connection member, and the electrical connection member and the branching member are disposed in the Subsequent layers are stacked outside.

該電致發光裝置之有利實施例在附屬申請專利範圍中予以界定。Advantageous embodiments of the electroluminescent device are defined in the scope of the appended claims.

本發明揭示至少一個電分路構件,其係經由至少一個電連接構件施加至基板電極,而該電連接構件及該分路構件係配置於後續層堆疊外側。The present invention discloses at least one electrical shunt member that is applied to the substrate electrode via at least one electrical connection member, and the electrical connection member and the shunt member are disposed outside of the subsequent layer stack.

本發明之主導思想係將電連接構件及電分路構件施加於後續層堆疊(亦即,有機電致發光層及反電極)外側,從而維持此等層之一平坦拓撲。根據本發明,將該電連接構件及該電分路構件實施為施加至基板電極、配置於後續層堆疊外側之單導電元件。基本上,該電分路構件可在一電源與基板電極頂部上之一連接點之間形成一電連接。特定而言,電分路構件較佳地配置於兩個電連接構件之間,該兩個電連接構件配置於電致發光裝置之發射場及一邊界區域內,且而該基板電極之邊界區域之電壓係均等的。因此,使用單導電元件將該基板電極之邊界區域連接至該裝置之發射區域內之電連接構件導致跨越該基板電極之一較均質電壓分佈。因此,所發射光之強度亦比在無該分路構件之情形下更均質。The primary idea of the present invention is to apply an electrical connection member and an electrical branching member to the outside of the subsequent layer stack (i.e., the organic electroluminescent layer and the counter electrode) to maintain a flat topology of the layers. According to the invention, the electrical connection member and the electrical branching member are implemented as a single conductive element applied to the substrate electrode and disposed outside the subsequent layer stack. Basically, the electrical branching member can form an electrical connection between a power source and a connection point on the top of the substrate electrode. In particular, the electrical branching member is preferably disposed between two electrical connecting members disposed in the emission field and a boundary region of the electroluminescent device, and the boundary region of the substrate electrode The voltage is equal. Thus, the use of a single conductive element to connect the boundary region of the substrate electrode to the electrical connection member within the emission region of the device results in a more homogeneous voltage distribution across one of the substrate electrodes. Therefore, the intensity of the emitted light is also more homogeneous than in the absence of the shunt member.

在本發明之上下文中,概念電致發光(EL)層堆疊表示在基板電極與反電極之間所製備之所有層。在EL層堆疊之一個實施例中,其包括在基板電極與反電極之間所製備之至少一個發光有機電致發光層。在其他實施例中,該等層堆疊可包括在基板與反電極之間所製備之數個層。該數個層可係有機層,諸如一個或多個電洞傳輸層、電子阻擋層、電子傳輸層、電洞阻擋層、發射層,或有機及非有機層之一組合。該等非有機層可係在層堆疊內之兩個或更多個發光層及/或電荷注入層之情形下之額外電極。在一較佳實施例中,基板電極及/或反電極包括以下材料中之至少一者:ITO、鋁、銀、經摻雜之ZnO、氧化物層。In the context of the present invention, a conceptual electroluminescent (EL) layer stack represents all layers prepared between a substrate electrode and a counter electrode. In one embodiment of the EL layer stack, it includes at least one luminescent organic electroluminescent layer prepared between the substrate electrode and the counter electrode. In other embodiments, the layer stacks can include a plurality of layers prepared between the substrate and the counter electrode. The plurality of layers may be organic layers, such as one or more hole transport layers, electron blocking layers, electron transport layers, hole blocking layers, emissive layers, or a combination of organic and non-organic layers. The non-organic layers may be additional electrodes in the case of two or more luminescent layers and/or charge injection layers within the layer stack. In a preferred embodiment, the substrate electrode and/or the counter electrode comprise at least one of the following materials: ITO, aluminum, silver, doped ZnO, oxide layer.

在本發明之上下文中,概念基板材料表示電致發光裝置之不同層所沈積至的一基底材料。通常,該基板係透明的且係由玻璃製成。此外,該基板係透明的可係較佳的,較佳地包括以下材料中之至少一者:銀、金、玻璃或陶瓷。其亦可係由具有一適合濕氣及氧氣障壁之透明聚合物薄片或箔片製成以實質上防止濕氣及/或氧氣進入電致發光裝置層堆疊。亦可使用類似金屬箔片之非透明材料作為基板。該基板可包括其他層,例如,用於類似光輸出耦合增強之光學目的或其他目的。該基板通常係平坦的,但其亦可成形為所期望之任一三維形狀。In the context of the present invention, the conceptual substrate material represents a substrate material to which different layers of the electroluminescent device are deposited. Typically, the substrate is transparent and made of glass. Furthermore, the substrate may be transparent, preferably comprising at least one of the following materials: silver, gold, glass or ceramic. It may also be made of a transparent polymer sheet or foil having a moisture and oxygen barrier to substantially prevent moisture and/or oxygen from entering the electroluminescent device layer stack. A non-transparent material like a metal foil can also be used as the substrate. The substrate can include other layers, for example, for optical purposes similar to light output coupling enhancement or for other purposes. The substrate is generally flat, but it can also be formed into any desired three-dimensional shape.

在本發明之上下文中,概念基板電極表示沈積於基板頂部上之一電極。通常,其由透明ITO(氧化銦錫)組成,該透明ITO視情況具有一SiO2或SiO底塗層以抑制行動原子或離子自玻璃擴散至電極中。對於具有ITO電極之一玻璃基板,該ITO通常係陽極,但在特殊情形下其亦可用作陰極。在某些情形下,單獨地或結合ITO使用薄Ag或Au層(8至15 nm厚)作為基板電極。若使用一金屬箔片作為基板,則其亦起到基板電極之作用,陽極或陰極。記法在...頂部上表示所列出層之序列。此記法明確地包括將層中間的其他層表示為位於彼此頂部上之可能性。舉例而言,基板電極與基板之間可配置有用以增強光輸出耦合之額外光學層。In the context of the present invention, a conceptual substrate electrode means one of the electrodes deposited on top of the substrate. Typically, it consists of transparent ITO (indium tin oxide) which optionally has a SiO 2 or SiO undercoat to inhibit diffusion of mobile atoms or ions from the glass into the electrode. For a glass substrate having one of the ITO electrodes, the ITO is usually an anode, but it can also be used as a cathode in special cases. In some cases, a thin Ag or Au layer (8 to 15 nm thick) is used as the substrate electrode, either alone or in combination with ITO. If a metal foil is used as the substrate, it also functions as a substrate electrode, an anode or a cathode. The notation indicates the sequence of the listed layers on top of. This notation explicitly includes the possibility of representing other layers in the middle of the layer as being on top of each other. For example, an additional optical layer useful to enhance light output coupling can be disposed between the substrate electrode and the substrate.

在本發明之上下文中,概念反電極表示遠離基板之一電極。其通常係非透明的且係由足夠厚度之Al或Ag層製成以使得該電極係反射性(通常,對於Al為100 nm且對於Ag為100至200 nm)。其通常係陰極,但其亦可被偏壓為陽極。對於頂部發射或透明電致發光裝置,反電極必須係透明的。透明反電極係由沈積於其他先前所沈積之層頂部上之薄Ag或Al層(5至15 nm)或由ITO層製成。In the context of the present invention, the conceptual counter electrode means one of the electrodes remote from the substrate. It is typically non-transparent and is made of a layer of Al or Ag of sufficient thickness to render the electrode system reflective (typically 100 nm for Al and 100 to 200 nm for Ag). It is usually a cathode, but it can also be biased as an anode. For top emission or transparent electroluminescent devices, the counter electrode must be transparent. The transparent counter electrode is made of a thin Ag or Al layer (5 to 15 nm) deposited on top of other previously deposited layers or from an ITO layer.

在本發明之上下文中,具有一透明基板、一透明基板電極及一非透明反電極(通常係反射性)之一組合從而發射光透過該基板之一電致發光裝置稱為「底部發射」。在包括其他電極之一電致發光裝置之情形下,在某些實施例中,當驅動內部電極作為陰極或陽極時,基板及反電極兩者可係兩個陽極或兩個陰極。此外,在本發明之上下文中,具有一非透明基板電極及一透明反電極之一組合從而發射光透過該反電極之一電致發光裝置稱為「頂部發射」。In the context of the present invention, an electroluminescent device having a combination of a transparent substrate, a transparent substrate electrode and a non-transparent counter electrode (usually reflective) to emit light through the substrate is referred to as "bottom emission." In the case of an electroluminescent device comprising one of the other electrodes, in some embodiments, when the internal electrode is driven as a cathode or anode, both the substrate and the counter electrode can be two anodes or two cathodes. Furthermore, in the context of the present invention, an electroluminescent device having a combination of a non-transparent substrate electrode and a transparent counter electrode for transmitting light through the counter electrode is referred to as "top emission".

在本發明之上下文中,概念透明電致發光裝置表示其中基板、基板電極、反電極及囊封構件係透明之一電致發光裝置。此處,電致發光裝置既係底部發射亦係頂部發射。在本發明之上下文中,若可見範圍中之光之透射多於50%而其餘部分被吸收或反射,則一層(一基板或一電極)稱為透明。此外,在本發明之上下文中,若可見範圍中之光之透射在10%與50%之間而其餘部分被吸收或反射,則一層(一基板或一電極)稱為半透明。另外,在本發明之上下文中,當光具有在450 nm與650 nm之間的一波長時,其稱為可見光。在本發明之上下文中,當光係由電致發光裝置之有機電致發光層發射時,其稱為人工光。In the context of the present invention, a conceptually transparent electroluminescent device means an electroluminescent device in which the substrate, substrate electrode, counter electrode and encapsulating member are transparent. Here, the electroluminescent device is both a bottom emission and a top emission. In the context of the present invention, a layer (a substrate or an electrode) is referred to as transparent if the transmission of light in the visible range is more than 50% and the remainder is absorbed or reflected. Moreover, in the context of the present invention, a layer (a substrate or an electrode) is referred to as translucent if the transmission of light in the visible range is between 10% and 50% and the remainder is absorbed or reflected. Further, in the context of the present invention, when light has a wavelength between 450 nm and 650 nm, it is called visible light. In the context of the present invention, when the light system is emitted by the organic electroluminescent layer of the electroluminescent device, it is referred to as artificial light.

此外,在本發明之上下文中,若一電致發光裝置之一層(連接器或構造元件)之電阻小於100000歐,則其稱為導電。在本發明之上下文中,被動電子組件包括電阻器、電容器及感應率。此外,在本發明之上下文中,主動電子組件包括二極體、電晶體及所有類型之積體電路。Furthermore, in the context of the present invention, if a layer (connector or construction element) of an electroluminescent device has a resistance of less than 100,000 ohms, it is said to be electrically conductive. In the context of the present invention, passive electronic components include resistors, capacitors, and inductivity. Moreover, in the context of the present invention, active electronic components include diodes, transistors, and all types of integrated circuits.

在本發明之上下文中,若入射於一電致發光裝置之一層(一基板、一電極或一構造元件)之介面上之光根據反射定律返回(宏觀入射角等於宏觀反射角),則該電致發光裝置之該層(基板、電極或構造元件)稱為反射性。此情形中亦使用術語鏡面反射。此外,在本發明之上下文中,若入射於一電致發光裝置之一層、一基板、一電極或一構造元件上之光不根據反射定律返回(宏觀入射角不等於返回光之宏觀角),則該電致發光裝置之該層(基板、電極或構造元件)稱為散射。亦存在返回光之一角度分佈。亦使用術語漫反射來替代散射。In the context of the present invention, if light incident on the interface of a layer (a substrate, an electrode or a structural element) of an electroluminescent device is returned according to the law of reflection (the macroscopic incident angle is equal to the macroscopic reflection angle), then the electricity This layer (substrate, electrode or structural element) of the electroluminescent device is referred to as reflective. The term specular reflection is also used in this case. Moreover, in the context of the present invention, if light incident on a layer, a substrate, an electrode or a structural element of an electroluminescent device is not returned according to the law of reflection (the macroscopic incident angle is not equal to the macroscopic angle of the returning light), This layer (substrate, electrode or structural element) of the electroluminescent device is then referred to as scattering. There is also an angular distribution of the return light. The term diffuse reflection is also used instead of scattering.

有利地,後續層堆疊包括一開放區域以便以藉由該後續層堆疊包圍電連接構件之一方式饋通分路構件。為避免基板電極與反電極之間的一短路,該基板電極頂部上之電連接構件與反電極以及有機電致發光層之間需要一距離。該等開放區域可形成為後續層堆疊中之圓圈,從而包圍電連接構件。此外,呈一導線、一金屬條帶或箔片形式之電分路構件可經過有機電致發光層及反電極。連接構件同時充當所施加之分路構件抵抗不期望移動之一機械穩定件以防止分路構件與反電極之間的一短路。將電連接構件及分路構件配置於後續層堆疊外側意味著在基板電極之與該後續層堆疊相關之遠側上(亦即,在OLED背側上而非該等層內)執行該配置,但儘管如此分路仍形成至該基板電極之一電連接。Advantageously, the subsequent layer stack includes an open area to feed the shunt member in such a manner as to surround the electrical connection member by the subsequent layer stack. In order to avoid a short circuit between the substrate electrode and the counter electrode, a distance is required between the electrical connection member on the top of the substrate electrode and the counter electrode and the organic electroluminescent layer. The open areas may be formed as circles in subsequent stacks of layers to surround the electrical connection members. Further, the electrical branching member in the form of a wire, a metal strip or a foil may pass through the organic electroluminescent layer and the counter electrode. The connecting member simultaneously acts as a mechanical stabilizer for the undesired movement of the applied shunt member to prevent a short between the shunt member and the counter electrode. Arranging the electrical connection member and the shunt member outside of the subsequent layer stack means that the configuration is performed on the far side of the substrate electrode associated with the subsequent layer stack (ie, on the back side of the OLED rather than within the layers), However, the shunt is still formed to electrically connect one of the substrate electrodes.

根據本發明之又一有利實施例,電連接構件包括用於將分路構件電接觸至基板電極之導電膠。形成該電連接構件之該導電膠包括一基質及一填充物,而該導電膠包括作為基質之有機材料及作為填充物之無機材料。在一個實施例中,該導電膠可包括以下基質中之至少一者:環氧樹脂、聚氨酯或聚矽氧。該填充物及/或該基質必須係導電的以將電流自電源傳導至反電極。In accordance with yet another advantageous embodiment of the present invention, the electrical connection member includes a conductive paste for electrically contacting the shunt member to the substrate electrode. The conductive paste forming the electrical connection member includes a substrate and a filler, and the conductive paste includes an organic material as a matrix and an inorganic material as a filler. In one embodiment, the conductive paste can include at least one of the following substrates: epoxy, polyurethane, or polyoxyxide. The filler and/or the substrate must be electrically conductive to conduct current from the power source to the counter electrode.

因此,該導電膠及/或該填充物包括導電片或粒子係較佳的。該等填充物粒子必須具有低電阻、穩定性及持久性。因此,該填充物包括以下至少一者之片或粒子係較佳的:銀、金、鎳、鉑、銅、鈀或其他金屬或者類似碳、玻璃碳、石墨、碳奈米管、經摻雜之ZnO、SnO、導電氮化物、導電硼化物之其他非金屬、金屬覆蓋之玻璃或塑膠珠、金屬覆蓋之玻璃或塑膠中空珠或者覆蓋有銅、金或銀之金屬或石墨粒子。Therefore, the conductive paste and/or the filler include conductive sheets or particles. These filler particles must have low electrical resistance, stability and durability. Therefore, the filler comprises at least one of the following sheets or particles: silver, gold, nickel, platinum, copper, palladium or other metals or similar carbon, glassy carbon, graphite, carbon nanotubes, doped ZnO, SnO, conductive nitride, other non-metal of conductive boride, metal-coated glass or plastic beads, metal-coated glass or plastic hollow beads or metal or graphite particles covered with copper, gold or silver.

在一較佳實施例中,該導電膠係無水及/或不含水的。在本發明之上下文中,概念不含水及/或無水闡述藉由肉眼可觀察不到在一電致發光裝置之平均壽命期間由於水分含量所致的降級之事實。由於擴散至層堆疊中之水分所致的有機電致發光層之一可見降級可呈現生長黑點或發射區自邊緣收縮之形式。概念不含水及/或無水不僅取決於導電膠自身且亦取決於可由該有機電致發光層吸收而不損壞其之水分量。In a preferred embodiment, the conductive paste is anhydrous and/or non-aqueous. In the context of the present invention, the concept of no water and/or no water clarifies the fact that degradation due to moisture content during the average lifetime of an electroluminescent device is not observable by the naked eye. One of the organic electroluminescent layers that is diffused into the layer stack can be visually degraded to exhibit a growth black spot or a form in which the emitter region shrinks from the edge. The concept that no water and/or water is not only depends on the conductive glue itself but also on the amount of moisture that can be absorbed by the organic electroluminescent layer without damaging it.

在一其他較佳實施例中,該電致發光裝置可包括濕氣及/或氧氣障壁。在本發明之上下文中,防止濕氣及/或氧氣至層堆疊中之有害擴散之層稱為濕氣及/或氧氣障壁。若可觀察到所發射光之一顯著壽命減少,則一擴散表示為有害。根據目前工藝水平之標準OLED裝置達成約100000小時或更多之擱置壽命。一顯著減少表示約二分之一或更多之一減少之壽命。In a further preferred embodiment, the electroluminescent device can include a moisture and/or oxygen barrier. In the context of the present invention, a layer that prevents moisture and/or oxygen from diffusing into the layer stack is referred to as a moisture and/or oxygen barrier. If one of the emitted light is observed to have a significant decrease in lifetime, then a diffusion is indicated as detrimental. A shelf life of approximately 100,000 hours or more is achieved according to standard OLED devices of the current state of the art. A significant reduction represents a life reduction of about one-half or more.

在其較佳實施例中,電連接構件嵌入於施加至基板電極之一非導電保護構件中,而該保護構件較佳包括非導電膠。當將電連接構件嵌入於一非導電保護構件內時,避免了一電短路之發生。當電連接構件包括導電膠且保護構件包括非導電膠時,不同膠層施加至彼此上。In a preferred embodiment, the electrical connection member is embedded in a non-conductive protective member applied to one of the substrate electrodes, and the protective member preferably includes a non-conductive adhesive. When an electrical connection member is embedded in a non-conductive protective member, an electrical short circuit is prevented from occurring. When the electrical connection member includes a conductive paste and the protective member includes a non-conductive paste, different glue layers are applied to each other.

基板電極之特徵可係一接觸區域,其配置於該電致發光裝置之邊界區域中。因此,電連接構件可在該接觸區域內施加至基板電極。該接觸區域可包括一另外施加之導電材料以增加該基板電極在該接觸區域中之導電性。此外,可經由該接觸區域執行基板電極至一外部電源之電連接。當將該接觸區域係配置成包圍該電致發光裝置之發光場時,該基板電極周圍處之電壓係均勻的。當電分路構件包括發光區域與接觸區域內之數個接觸柱之間的電互連時,亦即,當連接構件係施加於額外施加之導電材料上時,跨越整個發光場之電壓分佈均勻得多。The substrate electrode can be characterized by a contact area disposed in a boundary region of the electroluminescent device. Therefore, an electrical connection member can be applied to the substrate electrode in the contact area. The contact region can include an additional electrically conductive material to increase the conductivity of the substrate electrode in the contact region. Furthermore, the electrical connection of the substrate electrode to an external power source can be performed via the contact area. When the contact region is configured to surround the illumination field of the electroluminescent device, the voltage at the periphery of the substrate electrode is uniform. When the electrical branching member includes an electrical interconnection between the light-emitting region and the plurality of contact posts in the contact region, that is, when the connecting member is applied to the additionally applied conductive material, the voltage distribution across the entire light-emitting field is evenly distributed. Much more.

在其較佳實施例中,電分路構件包括一金屬導線、一金屬條帶或一金屬箔片,其較佳地由銅、金及/或銀、一經沈積之導電材料或一印刷電路板製成。形成電分路構件之銅可在如熟習此項技術者已知的用於電導體之常見的基於銅之合金內選擇。當該等導電元件係藉由模切製造時,可使用一廉價的規模化生產技術來形成分路構件,特定而言,當該等分路構件係配置成一格柵形式時,整個格柵可藉由僅幾個模衝程或特定而言僅一個模衝程完成。In a preferred embodiment, the electrical branching member comprises a metal wire, a metal strip or a metal foil, preferably of copper, gold and/or silver, a deposited conductive material or a printed circuit board. production. The copper forming the electrical shunt member can be selected within the common copper-based alloys known to those skilled in the art for electrical conductors. When the conductive elements are manufactured by die cutting, an inexpensive mass production technique can be used to form the branching members. Specifically, when the branching members are configured in a grid form, the entire grid can be This is done by only a few die strokes or, in particular, only one die stroke.

在其較佳實施例中,該電致發光裝置可包括用於將反電極電接觸至一電源之至少一個接觸構件,而該接觸構件較佳地實施為施加至該反電極之導電膠,且進而一保護構件較佳地配置於該基板電極上,其中該保護構件係非導電膠且至少完全覆蓋該接觸構件下面之區域。In a preferred embodiment, the electroluminescent device can include at least one contact member for electrically contacting the counter electrode to a power source, and the contact member is preferably implemented as a conductive paste applied to the counter electrode, and Further, a protective member is preferably disposed on the substrate electrode, wherein the protective member is a non-conductive paste and at least completely covers a region under the contact member.

導電膠在其初始狀態中係軟的,因此可在不向反電極施加局部高壓力之情形下將其施加至該反電極。因此,不存在於施加該膠期間在反電極與基板電極之間出現一短路之風險。此導致提供具有一最小短路風險之一三維接觸模式之優點。The conductive paste is soft in its original state, so it can be applied to the counter electrode without applying a local high pressure to the counter electrode. Therefore, there is no risk of a short circuit occurring between the counter electrode and the substrate electrode during application of the glue. This results in the advantage of providing a three-dimensional contact mode with a minimum risk of short circuit.

通常,導電膠由具有呈導電片或粒子形式之導電填充物之有機膠組成。在膠之凝固期間,該膠可顯示某一收縮性,且此導致迫使某些填充物粒子進入下伏層中,從而在基板電極與反電極之間形成短路。為防止此情形,使用之具有一較小收縮性及一較高彈性之膠(如聚矽氧)及/或使反電極較厚係有利的。Typically, the conductive paste consists of an organic glue having a conductive filler in the form of a conductive sheet or particle. During gelation of the glue, the glue may exhibit some shrinkage, and this results in forcing certain filler particles into the underlying layer, thereby creating a short between the substrate electrode and the counter electrode. To prevent this, it is advantageous to use a rubber having a small shrinkage and a relatively high elasticity (e.g., polyfluorene) and/or making the counter electrode thicker.

藉由使用導電膠作為一接觸構件所達成之一其他優點係可使用僅具有一個連續電極之一基板,該連續電極充當電致發光裝置之一基板電極。在習知OLED中,將基板上之電極至少結構化成兩個電分離之區:一者充當基板電極且另一者連接至反電極。因此,基板及反電極兩者係在一個平面中被引導至基板邊沿,可藉由標準構件使該兩者在該邊沿處接觸。此2維接觸模式之缺點係基板電極以及反電極必須共享OLED之周邊來接觸,因此需要將基板上之電極分割成至少兩個分開之區(基板電極及欲與反電極接觸之第二電極)以避免短接該裝置。所揭示之3維接觸消除2維接觸之此嚴重缺點。One other advantage achieved by the use of a conductive paste as a contact member is the use of a substrate having only one continuous electrode, which serves as one of the substrate electrodes of the electroluminescent device. In conventional OLEDs, the electrodes on the substrate are at least structured into two regions of electrical separation: one acts as a substrate electrode and the other is connected to the counter electrode. Thus, both the substrate and the counter electrode are directed to the edge of the substrate in one plane, which can be contacted at the edge by standard members. The disadvantage of this two-dimensional contact mode is that the substrate electrode and the counter electrode must share the periphery of the OLED to contact, so the electrode on the substrate needs to be divided into at least two separate regions (the substrate electrode and the second electrode to be in contact with the counter electrode) To avoid shorting the device. The disclosed 3-dimensional contact eliminates this serious drawback of 2-dimensional contact.

非導電保護構件至少完全覆蓋接觸構件下面之區域之配置導致在硬化該膠期間避免基板電極與反電極之間的短路之優點。The configuration in which the non-conductive protective member at least completely covers the area under the contact member results in the advantage of avoiding a short circuit between the substrate electrode and the counter electrode during hardening of the glue.

若不期望限制膠之類型,且若無法使反電極更厚,則施加該非導電保護構件至基板電極以防止由於導電膠所致的一可能短路。使用至少一個保護構件使得該電致發光裝置對導電膠之特定性質係完全不敏感。因此,所有習知導電膠皆可用於將反電極接觸至一電源。保護構件必須覆蓋其中施加接觸構件至反電極之全部區域,此乃因此可係短路源,但其亦可大於該接觸構件區域。為防止反電極與基板電極之間的一直接接觸,保護構件具有確保接觸構件不無法與基板電極形成電接觸之一厚度及/或一硬度係較佳的。為達成此目標,該保護構件可包括非導電膠及/或一光阻劑及/或一漆及/或一塗料及/或由再熔玻璃料製成之一玻璃層。該保護構件亦可包括類似陽極氧化鋁之一經氧化金屬層。熟習此項技術者可選擇本發明範疇內之其他非導電材料。If it is not desired to limit the type of glue, and if the counter electrode cannot be made thicker, the non-conductive protective member is applied to the substrate electrode to prevent a possible short circuit due to the conductive paste. The use of at least one protective member renders the electroluminescent device completely insensitive to the specific properties of the conductive paste. Therefore, all conventional conductive adhesives can be used to contact the counter electrode to a power source. The protective member must cover the entire area in which the contact member is applied to the counter electrode, which may therefore be a short circuit source, but it may also be larger than the contact member region. In order to prevent a direct contact between the counter electrode and the substrate electrode, the protective member has a thickness and/or a hardness which ensures that the contact member is not in electrical contact with the substrate electrode. To achieve this goal, the protective member may comprise a non-conductive glue and/or a photoresist and/or a lacquer and/or a coating and/or a glass layer made of a remelted glass frit. The protective member may also comprise an oxidized metal layer similar to one of anodized aluminum. Other non-conductive materials within the scope of the present invention may be selected by those skilled in the art.

該保護構件必須具有一方面確保其不導電之性質。此外,其必須係足夠厚及/或硬以遮蔽基板電極免受接觸構件之影響。精確厚度及硬度取決於由接觸構件施加之實際壓力,但通常1至100微米厚度即充足。已藉助1.5微米厚度之光阻劑層以及藉助10至200微米厚度之非導電膠層達成了所期望之保護,但亦可使用更厚之層。此外,必須確保該保護構件不損壞基板電極、有機電致發光層及不損壞反電極。在其較佳實施例中,該保護構件包括非導電膠。此外,該保護構件之非導電膠無水及/或不含水係較佳的。此外,該保護構件之非導電膠無水及/或不含水係較佳的。The protective member must have the property of ensuring that it is not electrically conductive on the one hand. In addition, it must be sufficiently thick and/or hard to shield the substrate electrodes from contact members. The exact thickness and hardness depend on the actual pressure applied by the contact member, but typically a thickness of 1 to 100 microns is sufficient. The desired protection has been achieved with a 1.5 micron thick photoresist layer and with a 10 to 200 micron thick non-conductive adhesive layer, but thicker layers can also be used. In addition, it is necessary to ensure that the protective member does not damage the substrate electrode, the organic electroluminescent layer, and does not damage the counter electrode. In a preferred embodiment, the protective member comprises a non-conductive glue. Further, the non-conductive glue of the protective member is preferably anhydrous and/or non-aqueous. Further, the non-conductive glue of the protective member is preferably anhydrous and/or non-aqueous.

有利地,該電致發光裝置包括一囊封構件,其經配置以用於囊封至少該電致發光層堆疊,而電接觸構件較佳地配置於該囊封構件與反電極之間以用於將該反電極電接觸至該囊封構件。該囊封構件亦可囊封該電致發光裝置之整個層堆疊或僅囊封形成該整個層堆疊之一部分之複數個層。較佳地,將該囊封構件提供為覆蓋至少有機電致發光層及反電極之一氣密元件。藉由使用一氣密囊封構件,防止類似水分或氧氣之環境因素損壞經囊封之層。該囊封構件可形成一氣密蓋。此蓋可係由玻璃或金屬形成。亦可由供應至該電致發光裝置或僅其之部分之一個或複數個層形成該囊封構件。該等層可包括矽、氧化矽、氮化矽、氧化鋁或氧氮化矽。所有指定囊封構件防止機械及/或環境因素不利地影響該電致發光裝置之層堆疊。作為一實例,囊封構件可係由金屬、玻璃、陶瓷或此等材料之組合製成。其藉由導電或非導電膠、熔融玻璃料或金屬焊料附接至基板。因此,亦可為該電致發光裝置提供機械穩定性,同時施加在該等層與該囊封構件之間的膠之至少部分導電以用於接觸反電極。Advantageously, the electroluminescent device comprises an encapsulation member configured to encapsulate at least the electroluminescent layer stack, and the electrical contact member is preferably disposed between the encapsulation member and the counter electrode for use The counter electrode is electrically contacted to the encapsulation member. The encapsulating member may also encapsulate the entire layer stack of the electroluminescent device or only enclose a plurality of layers forming part of the entire layer stack. Preferably, the encapsulating member is provided to cover at least one of the organic electroluminescent layer and the counter electrode. By using a hermetic encapsulating member, environmental factors such as moisture or oxygen are prevented from damaging the encapsulated layer. The encapsulation member can form an airtight cover. This cover may be formed of glass or metal. The encapsulating member may also be formed from one or more layers supplied to the electroluminescent device or only a portion thereof. The layers may include tantalum, niobium oxide, tantalum nitride, aluminum oxide or hafnium oxynitride. All of the specified encapsulating members prevent mechanical and/or environmental factors from adversely affecting the layer stack of the electroluminescent device. As an example, the encapsulating member can be made of metal, glass, ceramic, or a combination of such materials. It is attached to the substrate by conductive or non-conductive glue, molten frit or metal solder. Thus, the electroluminescent device can also be provided with mechanical stability while at least a portion of the glue applied between the layers and the encapsulating member is electrically conductive for contacting the counter electrode.

根據另一較佳實施例,該囊封構件包括一囊封構件頂部及一囊封構件側,其使接觸構件與基板電極電絕緣,而較佳地將該反電極藉由該接觸構件至該囊封構件之電接觸提供至至少部分導電之囊封構件頂部。該囊封構件頂部形成一蓋,且該囊封構件之側包圍電致發光裝置之層系統。該囊封構件側可電連接至基板電極,且該囊封構件之頂部藉助該電接觸構件構成一電互連。因此,絕緣構件在該囊封構件之頂部與該囊封構件之側之間形成一電絕緣。為將電致發光裝置連接至一電源,必須施加一電流至該囊封構件之頂部及側以操作該電致發光裝置。According to another preferred embodiment, the encapsulation member includes an encapsulation member top and an encapsulation member side that electrically insulates the contact member from the substrate electrode, and preferably the counter electrode is passed to the contact member Electrical contact of the encapsulating member is provided to the top of the at least partially electrically conductive encapsulating member. A cover is formed on the top of the encapsulation member, and the side of the encapsulation member surrounds the layer system of the electroluminescent device. The encapsulating member side can be electrically connected to the substrate electrode, and the top of the encapsulating member forms an electrical interconnection by the electrical contact member. Thus, the insulating member forms an electrical insulation between the top of the encapsulating member and the side of the encapsulating member. In order to connect the electroluminescent device to a power source, a current must be applied to the top and sides of the encapsulating member to operate the electroluminescent device.

為確保該電致發光裝置之準確操作,該等電極必須彼此絕緣。當經由該囊封構件之至少一部分(例如)藉由囊封構件頂部與反電極之間的一接觸構件給至少一個電極供應電力時,該囊封構件之剩餘部分必須與另一電極絕緣。當將該囊封構件頂部電接觸至反電極時,該囊封構件側必須(例如)藉由一絕緣邊沿與基板電極絕緣。當該囊封構件側係導電時,該囊封構件頂部之特徵可係一絕緣材料或至少一經局部配置之饋通線,以使一導電元件穿過該囊封結構頂部,該導電元件接觸至反電極。在該囊封構件側電互連至基板電極且另外反電極電接觸至該囊封構件頂部之情形下,該囊封構件可在囊封構件頂部與側之間包括一絕緣構件。To ensure accurate operation of the electroluminescent device, the electrodes must be insulated from each other. When at least one electrode is supplied with electrical power via at least a portion of the encapsulating member, for example, by a contact member between the top of the encapsulating member and the counter electrode, the remaining portion of the encapsulating member must be insulated from the other electrode. When the top of the encapsulation member is in electrical contact with the counter electrode, the encapsulation member side must be insulated from the substrate electrode, for example by an insulating rim. When the side of the encapsulating member is electrically conductive, the top of the encapsulating member may be characterized by an insulating material or at least one locally configured feedthrough line such that a conductive element passes through the top of the encapsulating structure, the conductive element contacting Counter electrode. In the case where the encapsulation member side is electrically interconnected to the substrate electrode and the counter electrode is electrically contacted to the top of the encapsulation member, the encapsulation member may include an insulating member between the top and the side of the encapsulation member.

在一個實施例中,該囊封構件側藉助一接合構件配置於基板電極上,而該接合構件包括導電膠。因此,該囊封構件之側可包括具有高導電性之一導電材料,且基板電極沿著該基板電極之由該接合構件形成之接觸區域具有一均勻電壓。In one embodiment, the encapsulation member side is disposed on the substrate electrode by a bonding member, and the bonding member includes a conductive paste. Therefore, the side of the encapsulation member may include one of electrically conductive materials having high conductivity, and the contact region of the substrate electrode formed by the bonding member along the substrate electrode has a uniform voltage.

藉由將囊封構件配置於基板電極之表面上面,給出分路構件之不同接觸可能性。僅作為一實例,一分路構件可係配置於電致發光裝置之發光區域內之一電連接構件與接合構件之間,從而將囊封構件側接合至基板電極。在此情形下,該接合構件實現電致發光裝置之邊界區域中之一電連接構件之功能。By arranging the encapsulating member over the surface of the substrate electrode, different contact possibilities of the shunt member are given. As just one example, a shunt member may be disposed between one of the electrical connection members and the engagement member in the illumination region of the electroluminescent device to bond the encapsulation member side to the substrate electrode. In this case, the joining member realizes the function of one of the electrical connection members in the boundary region of the electroluminescent device.

根據又一實施例,至少一個電分路構件係配置於電連接構件與囊封構件之間以延伸至該囊封構件之至少部分導電之內表面用於經由該囊封構件之內表面來電接觸該基板電極,較佳地該分路構件具有一尖釘形式且更佳地該分路構件附接至該囊封構件。此分路構件之特徵可係一尖釘或一針形式,從而較佳地基本上垂直於囊封構件頂部之內表面朝向電連接構件延伸以用於電接觸基板電極。當分路構件具有一尖釘或一針形式時,該分路構件可穿透至可由導電膠組成之電連接構件中。藉助此配置,可實現呈液體導電膠滴形式之一個或較佳地複數個連接構件在基板電極之表面上之一容易接觸方法。當分路構件係配置於囊封構件中時,可在施加該囊封構件至電致發光裝置之背側上時在專用柱處執行使該複數個分路構件穿透至複數個專用導電膠滴中。In accordance with yet another embodiment, at least one electrical branching member is disposed between the electrical connection member and the encapsulation member to extend to at least a portion of the electrically conductive inner surface of the encapsulation member for inductive contact via an inner surface of the encapsulation member The substrate electrode, preferably the shunt member, has a spike form and more preferably the shunt member is attached to the encapsulation member. The shunt member can be in the form of a spike or a needle that preferably extends substantially perpendicular to the inner surface of the top of the encapsulation member toward the electrical connection member for electrical contact with the substrate electrode. When the shunt member has a spike or a needle form, the shunt member can penetrate into an electrical connection member that can be composed of a conductive paste. With this configuration, it is possible to realize an easy contact method of one or preferably a plurality of connecting members in the form of liquid conductive glue on the surface of the substrate electrode. When the branching member is disposed in the encapsulating member, the plurality of branching members may be penetrated to the plurality of dedicated conductive adhesives at the dedicated column when the encapsulating member is applied to the back side of the electroluminescent device Drop in.

當囊封構件頂部(下文中稱為蓋)(例如)藉助內表面中之所施加導電構件(例如,鋁線)而係導電或特徵係一導電內表面時,可跨越整個蓋或至少跨越該蓋之主要部分(較佳地除用於接觸反電極之饋通線以外)執行電分路。該蓋可(例如)藉助施加於基板電極圓周中之一導電膠而在該圓周中電連接至基板電極。導電構件可(例如)藉由配置於該導電構件與基板電極之間的導電膠滴以離散斑點形式連接至該基板電極。然後,該等膠滴可配置於後續層堆疊之開放區域中。When the top of the encapsulating member (hereinafter referred to as a cover) is electrically conductive or characterized by a conductive member (eg, aluminum wire) by means of an applied conductive member (eg, aluminum wire) in the inner surface, the entire cover may be spanned or at least spanned The main portion of the cover (preferably except for the feedthrough line for contacting the counter electrode) performs an electrical shunt. The cover can be electrically connected to the substrate electrode in the circumference, for example by means of a conductive paste applied to the circumference of the substrate electrode. The conductive member can be connected to the substrate electrode in discrete spots, for example, by a conductive glue disposed between the conductive member and the substrate electrode. The droplets can then be placed in the open area of the subsequent layer stack.

在根據本發明之保護範疇內,分路構件可配置於由囊封構件形成且由囊封構件之內部區域及電致發光裝置之層系統界定之囊封腔內。此意味著分路構件以及連接構件完全配置於由囊封構件形成之腔內。特定而言,分路構件以及連接構件配置於該分路構件與後續層堆疊之間。反電極與囊封構件頂部之間的間隔必須以呈一導線、一金屬箔片、一金屬條帶或一經摻雜之導電材料或一印刷電路板形式之電分路構件可配置於該間隙內之一方式來定尺寸。Within the scope of the protection according to the invention, the branching member can be arranged in an encapsulation chamber which is formed by the encapsulation member and which is defined by the inner region of the encapsulation member and the layer system of the electroluminescent device. This means that the branching member and the connecting member are completely disposed within the cavity formed by the encapsulating member. In particular, the shunt member and the connecting member are disposed between the shunt member and the subsequent layer stack. The spacing between the counter electrode and the top of the encapsulating member must be disposed in the gap in the form of a wire, a metal foil, a metal strip or a doped conductive material or an electrical branching member in the form of a printed circuit board. One way to size it.

有利地,形成電連接構件之導電膠及/或該保護構件包括至少用於散射由有機電致發光層產生之光之至少一個散射構件。端視用於保護構件之材料,實驗已顯示保護構件所施加至的區域可在該電致發光裝置之正常操作時顯得暗,此乃因阻擋了自反電極至基板電極之直接電流注入。因此,另一較佳實施例之特徵在於保護構件包括用於散射由有機電致發光層產生之光之至少一個散射構件,較佳地該散射構件係嵌入於該保護構件中。此散射構件散射及/或反射由基板導引之人工光之部分。此導致原本為非發射區域之一發亮。由於基板通常用作一種光導,因此保護構件之散射構件使得此光能夠自該電致發光裝置中被散射及反射出去。該散射構件可由嵌入於保護構件中之複數個顏料及/或片形成。舉例而言,此等顏料及/或片可包括:鋁、雲母效應顏料、二氧化鈦粒子或熟習此項技術者已知的散射及/或反射有機電致發光裝置之人工光之其他片或粒子。Advantageously, the electrically conductive paste forming the electrical connection member and/or the protective member comprises at least one scattering member for scattering at least light generated by the organic electroluminescent layer. Looking at the material used to protect the member, experiments have shown that the area to which the protective member is applied may appear dark during normal operation of the electroluminescent device by blocking direct current injection from the counter electrode to the substrate electrode. Accordingly, another preferred embodiment is characterized in that the protective member comprises at least one scattering member for scattering light generated by the organic electroluminescent layer, preferably the scattering member is embedded in the protective member. The scattering member scatters and/or reflects portions of the artificial light directed by the substrate. This causes one of the originally non-emissive areas to illuminate. Since the substrate is typically used as a light guide, the scattering member of the protective member enables this light to be scattered and reflected from the electroluminescent device. The scattering member may be formed of a plurality of pigments and/or sheets embedded in the protective member. For example, such pigments and/or flakes may comprise: aluminum, mica effect pigments, titanium dioxide particles or other flakes or particles known to those skilled in the art to scatter and/or reflect artificial light of organic electroluminescent devices.

在另一較佳實施例中,給該保護構件染色。此可藉由給該保護構件自身著色或藉由施加彩色顏料至該保護構件來完成。In another preferred embodiment, the protective member is dyed. This can be done by coloring the protective member itself or by applying a color pigment to the protective member.

本發明亦係關於一種用於電分路一電致發光裝置之一基板電極之方法,該電致發光裝置包括一層系統,其具有一基板頂部上之一基板電極及至少一個後續層堆疊,該至少一個後續層堆疊包括一反電極及具有至少一個有機電致發光層之一電致發光層堆疊,其中該電致發光層堆疊配置於該基板電極與該反電極之間,且進而該方法包括至少以下步驟:在該基板電極頂部上沈積該後續層堆疊;經由該後續層堆疊外側之至少一個連接構件施加至少一個電分路構件至該基板電極;及將該分路構件配置於該後續層堆疊外側。在一實施例中,該方法進一步包括以下步驟:施加特徵係導電膠之至少一個其他電連接構件至該基板電極;及隨後將該分路構件配置於該至少兩個電連接構件之間。以配置於該基板電極頂部上之層之經改良施加達成該方法之優點。該等層之沈積不受分路構件干擾,該等分路構件直接配置於該基板電極頂部上且其將導致一不平坦拓撲。因此,分路構件以及電連接構件不會在該等層所施加至的表面中導致邊緣及陰影效應。可在執行分路之前完成用於製造電致發光裝置之分層。將分路構件施加於後續層堆疊外側意味著將該分路構件配置於該後續層堆疊關於基板之後面。The present invention also relates to a method for electrically shunting a substrate electrode of an electroluminescent device, the electroluminescent device comprising a system having a substrate electrode on a top of a substrate and at least one subsequent layer stack, The at least one subsequent layer stack includes a counter electrode and an electroluminescent layer stack having at least one organic electroluminescent layer, wherein the electroluminescent layer stack is disposed between the substrate electrode and the counter electrode, and the method further comprises At least the following steps: depositing the subsequent layer stack on top of the substrate electrode; applying at least one electrical branching member to the substrate electrode via at least one connecting member outside the subsequent layer stack; and arranging the branching member in the subsequent layer Stack the outside. In one embodiment, the method further includes the steps of: applying at least one other electrical connection member of the feature conductive paste to the substrate electrode; and subsequently disposing the shunt member between the at least two electrical connection members. The improved application of the layer disposed on top of the substrate electrode achieves the advantages of the method. The deposition of the layers is not disturbed by the shunt members, which are disposed directly on top of the substrate electrode and which will result in an uneven topology. Thus, the shunt member and the electrical connection member do not cause edge and shadow effects in the surface to which the layers are applied. The layering used to fabricate the electroluminescent device can be completed prior to performing the shunt. Applying the shunt member to the outside of the subsequent layer stack means that the shunt member is disposed on the subsequent layer stack with respect to the back surface of the substrate.

針對該電致發光裝置所闡述之特徵及細節亦適用於該方法且反之亦然。前述電致發光裝置及/或方法以及所主張之組件及根據本發明欲用於所闡述實施例之組件在大小、形狀、材料選擇方面不受任何特殊例外。在無限制之情形下,可應用相關領域中已知的選擇準則之技術概念。本發明目標之額外細節、特性及優點揭示於附屬申請專利範圍及各別圖之以下說明中,該等圖僅係一實例性方式,顯示根據本發明之電致發光裝置之複數個較佳實施例。The features and details set forth for the electroluminescent device also apply to the method and vice versa. The foregoing electroluminescent devices and/or methods, as well as the claimed components, and the components to be used in the illustrated embodiments in accordance with the present invention are not subject to any particular exception in terms of size, shape, material selection. In the unrestricted case, the technical concept of the selection criteria known in the related art can be applied. Additional details, features, and advantages of the present invention are disclosed in the following description of the claims and the accompanying drawings, which are merely by way of example, showing a plurality of preferred embodiments of the electroluminescent device in accordance with the present invention. example.

在圖1中,顯示根據本發明之一實施例之一電致發光裝置10。電致發光裝置10包括一基板電極20、一反電極30及一有機電致發光層50(表示此實例及以下實例中之電致發光層堆疊)。有機電致發光層50配置於基板電極20與該反電極之間以形成一層堆疊。此層堆疊配置於基板40上,從而形成電致發光裝置10之載體材料。在所示實施例中,基板電極20係由一約100 nm厚之ITO層形成,ITO係一透明且導電材料。將有機電致發光層50沈積至此基板電極20上。若在基板電極20與反電極30之間施加一電壓,則激發有機電致發光層50內之有機分子中之某些有機分子,從而導致由電致發光層50發射之人工光之發射。反電極30係由一鋁層形成,從而用作一鏡且反射該人工光透過基板電極20及基板40。為將光發射至周圍環境中,此實施例中之基板40係由玻璃製成。因此,電致發光裝置10係一底部發射OLED。以下各圖中所示之電致發光裝置10以及其組件及根據本發明所使用之組件並非係按真實比例顯示。尤其係電極20、30、有機電致發光層50及基板40之厚度並非係按真實比例繪製。所有圖僅用於闡明本發明。In Fig. 1, an electroluminescent device 10 in accordance with an embodiment of the present invention is shown. The electroluminescent device 10 includes a substrate electrode 20, a counter electrode 30, and an organic electroluminescent layer 50 (representing an electroluminescent layer stack in this and the following examples). The organic electroluminescent layer 50 is disposed between the substrate electrode 20 and the counter electrode to form a stack. This layer is stacked on the substrate 40 to form a carrier material for the electroluminescent device 10. In the illustrated embodiment, substrate electrode 20 is formed from an approximately 100 nm thick layer of ITO, which is a transparent and electrically conductive material. The organic electroluminescent layer 50 is deposited onto the substrate electrode 20. If a voltage is applied between the substrate electrode 20 and the counter electrode 30, some of the organic molecules in the organic molecules in the organic electroluminescent layer 50 are excited, resulting in the emission of artificial light emitted by the electroluminescent layer 50. The counter electrode 30 is formed of an aluminum layer to serve as a mirror and reflects the artificial light through the substrate electrode 20 and the substrate 40. In order to emit light into the surrounding environment, the substrate 40 in this embodiment is made of glass. Therefore, the electroluminescent device 10 is a bottom emitting OLED. The electroluminescent device 10 shown in the following figures, as well as the components thereof and the components used in accordance with the present invention, are not shown in true scale. In particular, the thicknesses of the electrode electrodes 20, 30, the organic electroluminescent layer 50, and the substrate 40 are not drawn in true scale. All figures are only intended to illustrate the invention.

如圖1中所示,反電極30由一連接構件93接觸且基板電極20由一連接構件93'接觸以藉由在連接構件93與93'之間施加一電壓而給電致發光裝置10供電。為均質化跨越電致發光裝置10之整個發射場之電壓,將一電分路構件122配置於基板電極20之頂部上。電分路構件122配置於至少兩個電連接構件120之間。電連接構件120中之至少一者配置於基板電極20之邊界區域上,同時至少下一電連接構件120配置於電致發光裝置10之發射場內(例如,在電致發光裝置10之中心)。基板電極20之此分路導致跨越基板電極20之電壓之一均質化,即使基板電極20具有一高比電阻。As shown in FIG. 1, the counter electrode 30 is contacted by a connecting member 93 and the substrate electrode 20 is contacted by a connecting member 93' to supply power to the electroluminescent device 10 by applying a voltage between the connecting members 93 and 93'. To homogenize the voltage across the entire emission field of the electroluminescent device 10, an electrical shunt member 122 is disposed on top of the substrate electrode 20. The electrical shunt member 122 is disposed between the at least two electrical connection members 120. At least one of the electrical connection members 120 is disposed on a boundary region of the substrate electrode 20 while at least the next electrical connection member 120 is disposed within the emission field of the electroluminescent device 10 (eg, at the center of the electroluminescent device 10) . This shunting of the substrate electrode 20 causes homogenization of one of the voltages across the substrate electrode 20 even if the substrate electrode 20 has a high specific resistance.

為將至少一個電連接構件120配置至基板電極20,至少包括有機電致發光層50及反電極30之層系統之特徵係一開放區域140。此開放區域140使得電分路構件122能夠繞過此處亦表示為後續層堆疊之有機電致發光層50及反電極30。此外,沿橫向方向將電連接構件120與反電極30間隔開以防止發生短路。基本上,電連接構件120之特徵可係導電膠,且將該膠以(例如)一液體膠滴形式施加至基板電極20上。當執行有機電致發光層50及反電極30中之開放區域140時,僅須將液體膠滴定位於該開放區域140內以用於電接觸電分路構件122。In order to dispose the at least one electrical connection member 120 to the substrate electrode 20, the layer system including at least the organic electroluminescent layer 50 and the counter electrode 30 is characterized by an open region 140. This open region 140 enables the electrical shunt member 122 to bypass the organic electroluminescent layer 50 and the counter electrode 30, also referred to herein as a subsequent layer stack. Further, the electrical connection member 120 is spaced apart from the counter electrode 30 in the lateral direction to prevent a short circuit from occurring. Basically, the electrical connection member 120 can be characterized as a conductive paste and the glue is applied to the substrate electrode 20 in the form of, for example, a liquid glue. When the open regions 140 in the organic electroluminescent layer 50 and the counter electrode 30 are performed, only liquid droplets must be positioned within the open region 140 for electrically contacting the electrical shunt member 122.

圖2顯示包括兩個電分路構件122之電致發光裝置10之另一實施例。兩個分路構件122自電致發光裝置10之一邊界區域(形成發射場之外部區或至少該發射場旁邊之區域)延伸至電致發光裝置10之一內部區域,而基板電極20內之發光場之邊界區域中以及內部區域中之每一電接觸包括一電連接構件120。電致發光裝置10之發光區域內之每一電連接構件120定位於一專用開放區域140內。如圖所示,電分路構件122被導引至至少包括反電極30及有機電致發光層50之後續層堆疊外側。因此,電分路構件122包括實施為連接基板電極20頂部上之至少兩個電柱之一種電跨接線之單導電元件。FIG. 2 shows another embodiment of an electroluminescent device 10 that includes two electrical shunt members 122. The two branching members 122 extend from one of the boundary regions of the electroluminescent device 10 (the outer region forming the emission field or at least the region beside the emission field) to an inner region of the electroluminescent device 10, and the substrate electrode 20 Each electrical contact in the boundary region of the illuminating field and in the inner region includes an electrical connection member 120. Each of the electrical connection members 120 within the illumination region of the electroluminescent device 10 is positioned within a dedicated open area 140. As shown, the electrical shunt member 122 is directed to the outside of the stack of subsequent layers including at least the counter electrode 30 and the organic electroluminescent layer 50. Accordingly, the electrical shunt member 122 includes a single conductive element that is implemented as an electrical jumper that connects at least two of the posts on the top of the substrate electrode 20.

為固定電分路構件122,可在基板40頂部上完成包括該開放區域140之層系統。在用於電分路基板電極20之方法之一後續步驟中,經由可由包括導電膠之膠滴形成之連接構件120施加電分路構件122至基板電極20。結果,可將電分路構件122實施為層系統外側之簡單導電元件且至少有機電致發光層50及反電極30之分層不受根據先前技術係直接施加於基板電極20之表面上之電分路構件122之干擾。To secure the electrical shunt member 122, a layer system including the open region 140 can be completed on top of the substrate 40. In a subsequent step of the method for electrically shunting the substrate electrode 20, the electrical branching member 122 is applied to the substrate electrode 20 via a connecting member 120 that may be formed of a droplet of a conductive paste. As a result, the electrical shunt member 122 can be implemented as a simple conductive element outside the layer system and at least the delamination of the organic electroluminescent layer 50 and the counter electrode 30 is not directly applied to the surface of the substrate electrode 20 according to the prior art. The interference of the shunt member 122.

如圖3a中所示,有機電致發光層50及反電極30係由一囊封構件90囊封。囊封構件90包括覆蓋層系統背側之一蓋狀形狀。囊封構件90必須係氣密的以防止環境大氣損壞囊封於囊封構件90內之有機電致發光層50或兩個電極20及30中之任一者。此外,所示之電致發光裝置10可包括配置於囊封構件90內之一吸收劑170。此吸收劑170用於吸收往往擴散至囊封構件90內之一受保護區域(亦即,囊封腔99內)中之濕氣或其他損壞氣體。因此,分路構件122以及連接構件120完全配置於腔99內。吸收劑170可包括CaO或沸石。熟習此項技術者已知用以形成一吸收劑170之其他材料。As shown in FIG. 3a, the organic electroluminescent layer 50 and the counter electrode 30 are encapsulated by an encapsulation member 90. The encapsulation member 90 includes a lid-like shape on the back side of the cover system. The encapsulation member 90 must be airtight to prevent environmental atmosphere damage to the organic electroluminescent layer 50 or both of the electrodes 20 and 30 encapsulated within the encapsulation member 90. Additionally, the illustrated electroluminescent device 10 can include an absorbent 170 disposed within the encapsulation member 90. This absorbent 170 serves to absorb moisture or other damaging gases that tend to diffuse into one of the protected regions (i.e., within the encapsulation chamber 99) within the encapsulation member 90. Therefore, the branching member 122 and the connecting member 120 are completely disposed within the cavity 99. The absorbent 170 can include CaO or a zeolite. Other materials known to those skilled in the art to form an absorbent 170 are known.

如圖所示,在基板電極20頂部上施加一接觸區域21,該接觸區域之特徵係一高導電性材料。此另外施加之導電材料22導致包圍電致發光裝置10之發光場之一導電框架。因此,接觸區域21導致跨越電致發光裝置10之邊界邊緣之一均質化電壓。如圖所示,外部電連接構件120在囊封腔99內定位於接觸區域21頂部上。電分路構件122係配置於電致發光裝置10之發光場之中心之一電連接構件120與接觸區域21頂部上之該電連接構件120之間。因此,電連接構件120在電致發光裝置10之中心感應出與電致發光裝置10之邊界邊緣中之接觸區域21之電壓相同之電位。此外,接觸區域21適於形成自囊封構件90之外側至囊封腔99中之一經改良電流路徑以用於藉助該電連接構件120接觸電分路構件122。As shown, a contact region 21 is applied on top of the substrate electrode 20, the contact region being characterized by a highly conductive material. This additionally applied conductive material 22 results in a conductive frame surrounding one of the illumination fields of the electroluminescent device 10. Thus, the contact area 21 causes the voltage to be homogenized across one of the boundary edges of the electroluminescent device 10. As shown, the outer electrical connection member 120 is positioned over the top of the contact area 21 within the encapsulation chamber 99. The electrical branching member 122 is disposed between the electrical connection member 120 of one of the centers of the illumination fields of the electroluminescent device 10 and the electrical connection member 120 on the top of the contact region 21. Therefore, the electrical connection member 120 induces a potential at the center of the electroluminescent device 10 that is the same as the voltage of the contact region 21 in the boundary edge of the electroluminescent device 10. Furthermore, the contact region 21 is adapted to form an improved current path from the outer side of the encapsulation member 90 to the encapsulation chamber 99 for contacting the electrical shunt member 122 by the electrical connection member 120.

此外,一接觸構件60經配置以用於將反電極30電接觸至一電源。因此,接觸構件60係自反電極30通向該電源之電流路徑之部分。在已知的先前技術中,接觸柱用作施加至反電極30之接觸構件60。此等接觸柱具有其常常導致反電極30與基板電極20之間的短路之缺點。為克服此缺點,接觸構件60包括施加至反電極30之導電膠。導電膠可以一和緩方式施加至反電極30以使得不存在對反電極30及有機電致發光層50及/或電致發光層堆疊的通常導致兩個指定電極20與30之間的一短路之損壞。Additionally, a contact member 60 is configured for electrically contacting the counter electrode 30 to a power source. Thus, contact member 60 is part of the current path from counter electrode 30 to the power source. In the known prior art, a contact post is used as the contact member 60 applied to the counter electrode 30. These contact posts have the disadvantage that they often cause a short circuit between the counter electrode 30 and the substrate electrode 20. To overcome this disadvantage, the contact member 60 includes a conductive paste applied to the counter electrode 30. The conductive paste can be applied to the counter electrode 30 in a gentle manner such that there is no short circuit between the counter electrode 30 and the organic electroluminescent layer 50 and/or the electroluminescent layer stack which typically results in a gap between the two designated electrodes 20 and 30. damage.

接觸構件60可實施為配置成與反電極30以及囊封構件90之內表面直接接觸之導電膠。因此,易於經由該囊封構件90將反電極30電連接至一電源。使用者僅須施加一導電構件(顯示為一連接構件93)至囊封構件90。然後,囊封構件90與反電極30之間的導電膠將電流引導至反電極30。在所示之實施例中,囊封構件90配置於另外施加之導電材料22之頂部上,該另外施加之導電材料經配置以用於給基板電極20供應電力。因此,使用一絕緣邊沿91將囊封構件90以一電隔離方式配置於該另外施加之導電材料22之頂部上。The contact member 60 may be implemented as a conductive paste that is configured to be in direct contact with the counter electrode 30 and the inner surface of the encapsulation member 90. Therefore, it is easy to electrically connect the counter electrode 30 to a power source via the encapsulation member 90. The user only has to apply a conductive member (shown as a connecting member 93) to the encapsulating member 90. Then, the conductive paste between the encapsulation member 90 and the counter electrode 30 conducts current to the counter electrode 30. In the illustrated embodiment, the encapsulation member 90 is disposed on top of a further applied electrically conductive material 22 that is configured for supplying electrical power to the substrate electrode 20. Thus, the encapsulating member 90 is disposed in an electrically isolating manner on top of the additionally applied electrically conductive material 22 using an insulating rim 91.

當使用導電膠來形成用於電接觸反電極30之電接觸構件60時,所揭示電致發光裝置10之一較佳實施例包括一非導電保護構件70。非導電保護構件70經配置以至少完全覆蓋接觸構件60下面之區域。保護構件70配置於基板電極20上且可保護接觸構件60下面之區域。在所繪示之電致發光裝置10中,施加三個不同種類之膠:電連接構件120包括導電膠,而該保護構件70由非導電膠組成以隔離接觸構件60下面之區域,接觸構件60形成第三次導電膠施加。藉助電分路構件122對基板電極20之分路及接觸構件60兩者皆係在由囊封構件90形成之囊封腔99內施加的。One preferred embodiment of the disclosed electroluminescent device 10 includes a non-conductive protective member 70 when a conductive paste is used to form the electrical contact member 60 for electrically contacting the counter electrode 30. The non-conductive protective member 70 is configured to at least completely cover the area under the contact member 60. The protective member 70 is disposed on the substrate electrode 20 and can protect a region under the contact member 60. In the illustrated electroluminescent device 10, three different kinds of glue are applied: the electrical connection member 120 comprises a conductive paste, and the protective member 70 is composed of a non-conductive glue to isolate the area under the contact member 60, the contact member 60 A third conductive paste application is formed. Both the shunting of the substrate electrode 20 and the contact member 60 by means of the electrical shunt member 122 are applied within the encapsulation chamber 99 formed by the encapsulation member 90.

圖3b顯示將反電極30接觸至一電源之另一實施例。在此實施例中,該囊封構件包括一導電氣密饋通線92。此饋通線92連接至接觸構件60。此可─如圖所示─藉由一連接構件93完成,該連接構件一方面連接饋通線92而另一方面與接觸構件60連接。連接構件93可係一導線、一箔片或熟習此項技術者已知的另一導電元件。亦可係饋通線92與接觸構件60直接接觸。因此,在將囊封構件90安裝至層堆疊上期間,可將氣密饋通線92擠壓至接觸構件60之未經乾燥之導電膠中。在硬化之後,氣密饋通線92與接觸構件60之間存在一電接觸。在囊封構件90之外側上,氣密饋通線92可接觸至一電源。在所示實施例中,假定整個囊封構件90係導電的。因此,氣密饋通線92包括一絕緣構件97係適當的。此絕緣構件97防止饋通線92(連接至反電極30)與囊封構件90(連接至基板電極20)之間的任何短路。此絕緣構件97可係由陶瓷、玻璃形成或係由再熔玻璃料製成。若不存在用於氣密饋通線92之絕緣構件97,則囊封構件90之頂部95亦可係絕緣的。因此,亦防止兩個電極20、30之間的一短路。Figure 3b shows another embodiment of contacting the counter electrode 30 to a power source. In this embodiment, the encapsulation member includes a conductive airtight feedthrough 92. This feedthrough line 92 is connected to the contact member 60. This can be done, as shown, by a connecting member 93 which connects the feedthrough 92 on the one hand and the contact member 60 on the other hand. The connecting member 93 can be a wire, a foil or another conductive element known to those skilled in the art. It is also possible that the feedthrough 92 is in direct contact with the contact member 60. Thus, during installation of the encapsulation member 90 onto the layer stack, the gas tight feedthrough 92 can be extruded into the undried conductive paste of the contact member 60. After hardening, there is an electrical contact between the hermetic feedthrough 92 and the contact member 60. On the outer side of the encapsulation member 90, the airtight feedthrough 92 can be contacted to a power source. In the illustrated embodiment, it is assumed that the entire encapsulation member 90 is electrically conductive. Therefore, the airtight feedthrough 92 includes an insulating member 97 which is suitable. This insulating member 97 prevents any short circuit between the feedthrough line 92 (connected to the counter electrode 30) and the encapsulation member 90 (connected to the substrate electrode 20). This insulating member 97 may be formed of ceramic, glass or made of a remelted frit. If there is no insulating member 97 for the airtight feedthrough 92, the top portion 95 of the encapsulating member 90 can also be insulated. Therefore, a short circuit between the two electrodes 20, 30 is also prevented.

圖4顯示根據本發明之一電致發光裝置10之又一實施例。將一保護構件71施加於開放區域140內且將電連接構件120嵌入於包括非導電膠之保護構件71中。因此,提供一膠中膠配置且使電分路構件122饋通保護構件71。Figure 4 shows yet another embodiment of an electroluminescent device 10 in accordance with the present invention. A protective member 71 is applied into the open region 140 and the electrical connection member 120 is embedded in the protective member 71 including the non-conductive adhesive. Therefore, a glue intermediate configuration is provided and the electrical branching member 122 is fed through the protective member 71.

根據所示實施例,接觸構件60下面之保護構件70及開放區域140內之保護構件71之特徵係用於散射由有機電致發光層50產生之光的至少一個散射構件180,較佳地散射構件180分別嵌入於保護構件70及71內。散射構件180散射及/或反射由基板40導引之人工光之部分。此導致由保護構件70、71形成之原本為非發射區域之一發亮。由於基板40常常用作一種光導,因此保護構件70、71之散射構件180使得此光能夠自電致發光裝置10中被散射及反射出去。散射構件180可係由嵌入於保護構件70及71中之複數個顏料及/或片形成。舉例而言,此等片及/或顏料可包括:鋁、雲母效應顏料、二氧化鈦粒子或熟習如散射及/或反射有機電致發光裝置10之人工光之技術者已知的其他片或粒子。因此,跨越電致發光裝置10之整個發光場之光發射係均質化的且開放區域140(非自發射)變得不可見。分別形成保護構件70及71之非導電膠以及形成電連接構件120之導電膠兩者可包括該散射構件180。According to the illustrated embodiment, the protective member 70 beneath the contact member 60 and the protective member 71 in the open region 140 are characterized by at least one scattering member 180 for scattering light generated by the organic electroluminescent layer 50, preferably scattering The members 180 are embedded in the protective members 70 and 71, respectively. The scattering member 180 scatters and/or reflects portions of the artificial light that are directed by the substrate 40. This causes one of the originally non-emission regions formed by the protective members 70, 71 to illuminate. Since the substrate 40 is often used as a light guide, the scattering members 180 of the protective members 70, 71 enable this light to be scattered and reflected from the electroluminescent device 10. The scattering member 180 may be formed of a plurality of pigments and/or sheets embedded in the protective members 70 and 71. For example, such sheets and/or pigments may include aluminum, mica effect pigments, titanium dioxide particles, or other sheets or particles known to those skilled in the art of scattering and/or artificial light that reflects organic electroluminescent device 10. Thus, the light emission system across the entire illumination field of the electroluminescent device 10 is homogenized and the open region 140 (not self-emission) becomes invisible. Both the non-conductive glue forming the protective members 70 and 71 and the conductive paste forming the electrical connection member 120 may include the scattering member 180.

圖5a顯示電致發光裝置10之又一實施例。如圖所示,分路構件122'係藉助電連接構件120施加至基板電極20,電連接構件120可由一膠滴在開放區域140內及基板電極20圓周處形成於基板電極20之頂部上。分路構件122'配置於電連接構件120與施加於囊封構件90之內表面中之至少一個分路構件122"之間。此等分路構件122"可實施為囊封構件90之內表面中之導電條帶。分路構件122'之特徵可係一尖釘形式,較佳地垂直於囊封構件90之內表面朝電連接構件120延伸,且分路構件122'電連接至分路構件122"。當施加囊封構件90至電致發光裝置10時,尖釘形式之電分路構件122'穿透至特徵係一彈性導電膠滴之電連接構件120中,且完成分路。Figure 5a shows a further embodiment of an electroluminescent device 10. As shown, the shunt member 122' is applied to the substrate electrode 20 by means of an electrical connection member 120 that can be formed on the top of the substrate electrode 20 by a glue drop in the open region 140 and at the circumference of the substrate electrode 20. The branching member 122' is disposed between the electrical connection member 120 and at least one of the inner side surfaces of the encapsulation member 90. The shunt members 122" can be implemented as inner surfaces of the encapsulation member 90. Conductive strips in the middle. The shunt member 122' can be in the form of a spike, preferably extending perpendicular to the inner surface of the encapsulation member 90 toward the electrical connection member 120, and the shunt member 122' is electrically coupled to the shunt member 122". When the member 90 is encapsulated to the electroluminescent device 10, the electrical branching member 122' in the form of a spike penetrates into the electrical connection member 120 of the feature-elastic conductive droplet and completes the shunt.

特定而言,囊封構件90內表面中之分路構件122"可形成一印刷電路板,其藉助所示之呈一尖釘或針形式之分路構件122'分路至基板電極20。In particular, the shunt member 122" in the inner surface of the encapsulation member 90 can form a printed circuit board that is shunted to the substrate electrode 20 by means of a shunt member 122' shown in the form of a spike or needle.

在圖5b中,分路構件122"之施加限定為囊封構件90內表面中之至少一個分路構件122"。在此實施例中,電連接構件120'係由導電膠(較佳地以膠滴形式)製成。膠滴在基板電極20與囊封構件90內側之間延伸,其中顯示一分路構件122"。當將至少一個電連接構件120'施加於電致發光裝置10之發射場內且將至少另一電連接構件120施加於基板電極20圓周中時,分路係在每一電連接構件120'電接觸至囊封構件90內表面中之分路構件122"時可靠地執行。In Figure 5b, the application of the shunt member 122" is defined as at least one of the shunt members 122" of the inner surface of the encapsulation member 90. In this embodiment, the electrical connection member 120' is made of a conductive paste, preferably in the form of a glue drop. A glue droplet extends between the substrate electrode 20 and the inside of the encapsulation member 90, wherein a shunt member 122" is shown. When at least one electrical connection member 120' is applied to the emission field of the electroluminescent device 10 and at least another When the electrical connection member 120 is applied in the circumference of the substrate electrode 20, the shunt is reliably performed when each of the electrical connection members 120' electrically contacts the shunt member 122" in the inner surface of the encapsulation member 90.

特定而言,在此實施例中,囊封構件90內表面中之分路構件122"亦可形成一印刷電路板,其藉助所示之電連接構件120'電連接至基板電極20。In particular, in this embodiment, the shunt member 122" in the inner surface of the encapsulation member 90 can also form a printed circuit board that is electrically coupled to the substrate electrode 20 by the electrical connection member 120' shown.

根據圖6中所示之電致發光裝置10之實施例,電分路構件122以一替代方式接觸至基板電極20之外部區域。囊封構件90包括形成電致發光裝置10頂部側之一蓋之一囊封構件頂部95及一囊封構件側96。為在囊封構件頂部95與囊封構件側96之間形成一電隔離,頂部及側95、96包封一絕緣構件98。因此,可藉助所示之連接構件93及93'施加用以操作電致發光裝置10之電流至囊封構件90之頂部95及側96。結果,連接構件93'藉助所示之接合構件94電連接至基板電極20,接合構件94包括(例如)由導電膠製成之一導電劑。囊封構件頂部95藉助所示之接觸構件60電連接至反電極30。為分路基板電極20,將一分路構件122配置於電致發光裝置10之發射場中心之一電連接構件120與接合構件94之間。電分路構件122在接合構件94內側終止,且電分路構件122之端可膠合至接合構件94中。以此方式,執行分路構件122在電致發光裝置10之外部區域中之一簡單電連接。According to an embodiment of the electroluminescent device 10 shown in Figure 6, the electrical shunt member 122 contacts the outer region of the substrate electrode 20 in an alternative manner. The encapsulation member 90 includes an encapsulation member top 95 and an encapsulation member side 96 that form one of the top sides of the electroluminescent device 10. To form an electrical isolation between the encapsulation member top 95 and the encapsulation member side 96, the top and sides 95, 96 enclose an insulating member 98. Thus, the current to operate the electroluminescent device 10 to the top 95 and side 96 of the encapsulation member 90 can be applied by means of the connecting members 93 and 93' shown. As a result, the connecting member 93' is electrically connected to the substrate electrode 20 by means of the bonding member 94 shown, which includes, for example, a conductive agent made of a conductive paste. The encapsulation member top 95 is electrically connected to the counter electrode 30 by means of the contact member 60 as shown. For the shunt substrate electrode 20, a shunt member 122 is disposed between the electrical connection member 120 of the center of the emission field of the electroluminescent device 10 and the bonding member 94. The electrical shunt member 122 terminates inside the engagement member 94 and the end of the electrical shunt member 122 can be glued into the engagement member 94. In this way, the branching member 122 is simply electrically connected in one of the outer regions of the electroluminescent device 10.

圖7顯示具有較佳地配置於反電極30之邊緣中之複數個保護構件70之一電致發光裝置10。此等保護構件70可包括非導電膠,從而防止反電極30與基板電極20之間的一短路。特定而言,開放區域140之邊界線可由保護構件70保護,而可施加額外保護構件71以將電連接構件120嵌入於開放區域140內。FIG. 7 shows an electroluminescent device 10 having a plurality of protective members 70 preferably disposed in the edges of the counter electrode 30. These protective members 70 may include a non-conductive paste to prevent a short circuit between the counter electrode 30 and the substrate electrode 20. In particular, the boundary line of the open area 140 may be protected by the protective member 70, and an additional protective member 71 may be applied to embed the electrical connection member 120 within the open area 140.

圖8顯示電致發光裝置10之一背側視圖。基板電極20之分路包括電致發光裝置10之發光場中心之一第一電連接構件120。該電連接構件120連接至電致發光裝置10之邊緣中之四個不同電連接構件120。因此,四個不同電分路構件122配置於外部電連接構件120與電致發光裝置10中心(特定而言,在開放區域140內)之電連接構件120之間。Figure 8 shows a back side view of one of the electroluminescent devices 10. The shunt of the substrate electrode 20 includes one of the first electrical connection members 120 of the center of the illumination field of the electroluminescent device 10. The electrical connection member 120 is connected to four different electrical connection members 120 in the edge of the electroluminescent device 10. Thus, four different electrical shunt members 122 are disposed between the external electrical connection member 120 and the electrical connection member 120 at the center of the electroluminescent device 10 (specifically, within the open region 140).

圖9顯示包括基板電極20之發光場內之四個電連接構件120之電致發光裝置10之另一實施例。基板電極20之發光場內之電連接構件120中之每一者包括一電分路構件122以用於將電連接構件120連接至電致發光裝置10之外部區域中之電連接構件120。FIG. 9 shows another embodiment of an electroluminescent device 10 that includes four electrical connection members 120 within the illumination field of substrate electrode 20. Each of the electrical connection members 120 within the illumination field of the substrate electrode 20 includes an electrical shunt member 122 for connecting the electrical connection member 120 to the electrical connection member 120 in an outer region of the electroluminescent device 10.

圖10顯示包括具有四個不同反電極段31之一反電極之電致發光裝置10之一實施例。顯示反電極段31呈一正方形配置,且有機電致發光層50並非由跨越整個電致發光裝置10之反電極段31覆蓋。在電致發光裝置10之中心,反電極段31形成有機電致發光層50之不具有反電極段31之覆蓋之一區域。一開放區域140配置於有機電致發光層50之此區域內,且電連接構件120定位於開放區域140內。此電連接構件120藉助電分路構件122接觸至電致發光裝置10之外部區域中之一電連接構件120且連接至內部電連接構件120。反電極段31可藉由施加至每一反電極段31之接觸構件60個別地連接至一電源。Figure 10 shows an embodiment of an electroluminescent device 10 comprising a counter electrode having one of four different counter electrode segments 31. The counter electrode segments 31 are shown in a square configuration, and the organic electroluminescent layer 50 is not covered by the counter electrode segments 31 spanning the entire electroluminescent device 10. At the center of the electroluminescent device 10, the counter electrode segment 31 forms a region of the organic electroluminescent layer 50 that does not have the coverage of the counter electrode segment 31. An open region 140 is disposed in this region of the organic electroluminescent layer 50, and the electrical connection member 120 is positioned within the open region 140. This electrical connection member 120 is contacted to one of the outer regions of the electroluminescent device 10 by the electrical branching member 122 and to the internal electrical connection member 120. The counter electrode segments 31 can be individually connected to a power source by the contact members 60 applied to each of the counter electrode segments 31.

作為一實例,所闡述之實施例包括層堆疊內之一有機電致發光層50。在本發明範疇內之替代實施例中,除有機電致發光層50以外,電致發光層堆疊亦可包括諸如電洞透明層、電洞阻擋層、電子傳輸層、電子阻擋層、電荷注入層、其他導電層等層。As an example, the illustrated embodiment includes an organic electroluminescent layer 50 within a layer stack. In an alternative embodiment within the scope of the present invention, in addition to the organic electroluminescent layer 50, the electroluminescent layer stack may also include, for example, a hole transparent layer, a hole blocking layer, an electron transport layer, an electron blocking layer, and a charge injection layer. , other conductive layers and other layers.

10...電致發光裝置10. . . Electroluminescent device

20...基板電極20. . . Substrate electrode

21...接觸區域twenty one. . . Contact area

22...額外施加之導電材料twenty two. . . Additional applied conductive material

30...反電極30. . . Counter electrode

31...反電極段31. . . Counter electrode segment

40...基板40. . . Substrate

50...有機電致發光層50. . . Organic electroluminescent layer

60...接觸構件60. . . Contact member

70...保護構件70. . . Protective member

71...保護構件71. . . Protective member

72...連續間隙72. . . Continuous gap

90...囊封構件90. . . Encapsulation member

91...絕緣邊沿91. . . Insulated edge

92...氣密饋通線92. . . Airtight feedthrough

93...連接構件93. . . Connecting member

93'...連接構件93'. . . Connecting member

94...接合構件94. . . Joint member

95...囊封構件頂部95. . . Capsule top

96...囊封構件側96. . . Encapsulation member side

97...絕緣構件97. . . Insulating member

98...絕緣構件98. . . Insulating member

99...囊封腔99. . . Capsule

120...連接構件120. . . Connecting member

120'...連接構件120'. . . Connecting member

122...分路構件122. . . Shunt component

122'...分路構件122'. . . Shunt component

122"...分路構件122"...divide member

140...開放區域140. . . Open area

170...吸收劑170. . . Absorbent

180...散射構件180. . . Scattering member

將針對以下各圖闡述本發明之進一步實施例,該等圖顯示:Further embodiments of the present invention will be described with respect to the following figures, which show:

圖1 根據本發明具有顯示於兩個電連接構件之間的一分路構件之一電致發光裝置之一實施例;1 is an embodiment of an electroluminescent device having a shunt member shown between two electrical connection members in accordance with the present invention;

圖2 包括兩個分路構件之一電致發光裝置;Figure 2 includes an electroluminescent device comprising one of two branching members;

圖3a 包括一囊封構件及電接觸至囊封構件頂部之一接觸構件之一電致發光裝置;Figure 3a includes an encapsulating member and an electroluminescent device electrically contacting one of the contact members of the top of the encapsulating member;

圖3b 一電致發光裝置,而接觸構件係施加至與囊封構件頂部隔離之一氣密饋通線;Figure 3b is an electroluminescent device with a contact member applied to a hermetic feedthrough that is isolated from the top of the encapsulation member;

圖4 具有不同膠施加物之一電致發光裝置,該等膠施加物包括散射構件;Figure 4 is an electroluminescent device having one of different glue applicators, the glue applicator comprising a scattering member;

圖5a 具有實施為一尖釘形式分路構件之一分路構件之一電致發光裝置;Figure 5a has an electroluminescent device embodied as one of the shunt members of a shunt form of the shunt member;

圖5b 具有施加於囊封構件內表面中之一分路構件之一電致發光裝置;Figure 5b has an electroluminescent device applied to one of the shunt members in the inner surface of the encapsulation member;

圖6 藉助囊封構件及基板電極具有一接觸之一電致發光裝置;Figure 6 is an electroluminescent device having a contact by means of an encapsulation member and a substrate electrode;

圖7 包括數個保護構件之一電致發光裝置;Figure 7 includes an electroluminescent device comprising one of a plurality of protective members;

圖8 電致發光裝置之一俯視圖,其在該裝置之發光場內之一電連接構件與邊界區域之間包括分路構件;Figure 8 is a top plan view of an electroluminescent device comprising a branching member between an electrical connection member and a boundary region within the illumination field of the device;

圖9 在發光場內具有數個電連接構件之電致發光裝置之一俯視圖;及Figure 9 is a top plan view of an electroluminescent device having a plurality of electrical connection members within the illumination field;

圖10 包括數個反電極段之電致發光裝置之一俯視圖。Figure 10 is a top plan view of an electroluminescent device comprising a plurality of counter electrode segments.

10...電致發光裝置10. . . Electroluminescent device

20...基板電極20. . . Substrate electrode

30...反電極30. . . Counter electrode

40...基板40. . . Substrate

50...有機電致發光層50. . . Organic electroluminescent layer

93...連接構件93. . . Connecting member

93'...連接構件93'. . . Connecting member

120...連接構件120. . . Connecting member

122...分路構件122. . . Shunt component

140...開放區域140. . . Open area

Claims (13)

一種電致發光(electroluminescent)裝置(10),其包括:一層系統,其具有一基板(40)頂部上之一基板電極(20)及至少一個後續層堆疊(stack of subsequent layers),該至少一個後續層堆疊包括一反(counter)電極(30)及具有至少一個有機電致發光層(50)之一電致發光層堆疊,其中該電致發光層堆疊配置於該基板電極(20)與該反電極(30)之間;及至少一個電分路構件(electrical shunt means)(122、122'、122"),其施加至該基板電極(20)頂部以改良該基板電極(20)上之電流分佈,其中該電分路構件(122、122'、122")係經由至少一個電連接構件(120)施加至該基板電極(20),而該電連接構件(120)及該電分路構件(122、122'、122")係配置於該後續層堆疊外側,其中該電連接構件(120)嵌入於施加至該基板電極(20)之一保護構件(71)中,而其中該保護構件(71)包含非導電膠(glue)及至少一散射構件(180),該至少一散射構件(180)用於散射由該有機電致發光層(50)產生的光。 An electroluminescent device (10) comprising: a layer system having a substrate electrode (20) on top of a substrate (40) and at least one stack of subsequent layers, the at least one The subsequent layer stack includes a counter electrode (30) and an electroluminescent layer stack having at least one organic electroluminescent layer (50), wherein the electroluminescent layer stack is disposed on the substrate electrode (20) and the Between the counter electrodes (30); and at least one electrical shunt means (122, 122', 122") applied to the top of the substrate electrode (20) to improve the substrate electrode (20) Current distribution, wherein the electrical branching member (122, 122', 122") is applied to the substrate electrode (20) via at least one electrical connection member (120), and the electrical connection member (120) and the electrical shunt The member (122, 122', 122") is disposed outside the subsequent layer stack, wherein the electrical connection member (120) is embedded in a protective member (71) applied to the substrate electrode (20), wherein the protection The member (71) includes a non-conductive glue and at least one scattering member (180), the at least one scattering member ( 180) for scattering light generated by the organic electroluminescent layer (50). 如請求項1之電致發光裝置(10),其中該後續層堆疊具有一開放區域(140)以便以藉由該後續層堆疊包圍該電連接構件(120、120')之一方式饋通該電分路構件(122、122')。 The electroluminescent device (10) of claim 1, wherein the subsequent layer stack has an open region (140) for feeding through the one of the electrical connection members (120, 120') by the subsequent layer stack Electrical branching members (122, 122'). 如請求項1或2之電致發光裝置(10),其中該電連接構件(120、120')包括用於將該電分路構件(122、122')電接觸至該基板電極(20)之一導電膠。 The electroluminescent device (10) of claim 1 or 2, wherein the electrical connection member (120, 120') comprises means for electrically contacting the electrical branching member (122, 122') to the substrate electrode (20) One of the conductive adhesives. 如請求項3之電致發光裝置(10),其中形成至少該電連接構件(120、120')之該導電膠包括一基質及一填充物,而該導電膠包括作為該基質之有機材料及作為該填充物之無機材料。 The electroluminescent device (10) of claim 3, wherein the conductive paste forming at least the electrical connection member (120, 120') comprises a substrate and a filler, and the conductive paste comprises an organic material as the substrate and As an inorganic material of the filler. 如請求項1之電致發光裝置(10),其中該電分路構件(122、122")包括以下構件中之至少一者:一導線、一金屬箔片、一經沈積之導電材料或一印刷電路板。 The electroluminescent device (10) of claim 1, wherein the electrical branching member (122, 122") comprises at least one of the following: a wire, a metal foil, a deposited conductive material, or a printing Circuit board. 如請求項1之電致發光裝置(10),其中該基板電極(20)具有一接觸區域(21),而該其他電連接構件(120)係在該接觸區域(21)內施加至該基板電極(20)。 The electroluminescent device (10) of claim 1, wherein the substrate electrode (20) has a contact region (21), and the other electrical connection member (120) is applied to the substrate in the contact region (21) Electrode (20). 如請求項6之電致發光裝置(10),其中該接觸區域(21)包括一額外施加之導電材料(22),該額外施加之導電材料(22)經實施以增加該接觸區域(21)中該基板電極(20)之導電性。 The electroluminescent device (10) of claim 6, wherein the contact region (21) comprises an additional applied conductive material (22), the additionally applied conductive material (22) being implemented to increase the contact region (21) The conductivity of the substrate electrode (20). 如請求項1之電致發光裝置(10),進一步包括用於將該反電極(30)電接觸至一電源之至少一個接觸構件(60),及一額外保護構件(70)配置於該基板電極(20)上,該額外保護構件(70)係非導電膠且至少完全覆蓋該接觸構件(60)下面之區域。 An electroluminescent device (10) according to claim 1, further comprising at least one contact member (60) for electrically contacting the counter electrode (30) to a power source, and an additional protective member (70) disposed on the substrate On the electrode (20), the additional protective member (70) is a non-conductive glue and at least completely covers the area under the contact member (60). 如請求項8之電致發光裝置(10),其中一囊封構件(90)經配置以用於囊封至少該電致發光層堆疊。 An electroluminescent device (10) according to claim 8, wherein an encapsulating member (90) is configured to encapsulate at least the electroluminescent layer stack. 如請求項9之電致發光裝置(10),其中該囊封構件(90)包括使該接觸構件(60)與該基板電極電絕緣之一囊封構件頂部(95)及一囊封構件側(96)。 The electroluminescent device (10) of claim 9, wherein the encapsulating member (90) comprises electrically insulating the contact member (60) from the substrate electrode, an encapsulating member top (95) and an encapsulating member side (96). 如請求項9或10之電致發光裝置(10),其中至少一個電分路構件(122')配置於該電連接構件(120)與該囊封構件(90)之間以延伸至該囊封構件(90)之至少部分導電之內表面,以用於經由該囊封構件之該內表面電接觸該基板電極(20)。 An electroluminescent device (10) according to claim 9 or 10, wherein at least one electrical branching member (122') is disposed between the electrical connecting member (120) and the encapsulating member (90) to extend to the bladder An at least partially electrically conductive inner surface of the encapsulating member (90) for electrically contacting the substrate electrode (20) via the inner surface of the encapsulating member. 一種用於電分路(electrically shunting)一電致發光裝置(10)之一基板電極(20)之方法,該電致發光裝置(10)包括一層系統,該層系統具有一基板(40)頂部上之一基板電極(20)及至少一個後續層堆疊,該至少一個後續層堆疊包括一反電極(30)及具有至少一個有機電致發光層(50)之一電致發光層堆疊,其中該電致發光層堆疊配置於該基板電極(20)與該反電極(30)之間,該方法包括至少以下步驟:在該基板電極(20)頂部上沈積該後續層堆疊,經由該後續層堆疊外側之至少一個連接構件(120、120')施加至少一個電分路構件(122、122'、122")至該基板電極(20),及將該電分路構件(122、122'、122")配置於該後續層堆疊外側,及將該電連接構件(120)嵌入於施加至該基板電極(20)之一保護構件(71)中,其中該保護構件(71)包含非導電膠及至少一散射構件(180),該至少一散射構件(180)用於散射由該有機電致發光層(50)產生的光。 A method for electrically shunting a substrate electrode (20) of an electroluminescent device (10), the electroluminescent device (10) comprising a system having a substrate (40) top a top substrate electrode (20) and at least one subsequent layer stack, the at least one subsequent layer stack comprising a counter electrode (30) and an electroluminescent layer stack having at least one organic electroluminescent layer (50), wherein An electroluminescent layer stack is disposed between the substrate electrode (20) and the counter electrode (30), the method comprising at least the step of depositing the subsequent layer stack on top of the substrate electrode (20), via the subsequent layer stacking At least one of the outer connecting members (120, 120') applies at least one electrical branching member (122, 122', 122") to the substrate electrode (20), and the electrical branching member (122, 122', 122) ") disposed outside the stack of subsequent layers, and embedding the electrical connection member (120) in a protective member (71) applied to the substrate electrode (20), wherein the protective member (71) comprises a non-conductive paste and At least one scattering member (180) for scattering from the organic A photoluminescent layer (50) produced. 如請求項12之方法,其包括以下其他步驟: 施加特徵係導電膠之至少一個其他電連接構件(120、120')至該基板電極(20),將該電分路構件(122、122'、122")配置於該至少兩個電連接構件(120、120')之間。 The method of claim 12, which includes the following additional steps: Applying at least one other electrical connection member (120, 120') characteristically of a conductive paste to the substrate electrode (20), the electrical branching member (122, 122', 122") being disposed on the at least two electrical connection members Between (120, 120').
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