TWI507255B - Electrolytic adsorption scale device for circulating water system of cooling water tower with electrolyzed water generation part - Google Patents
Electrolytic adsorption scale device for circulating water system of cooling water tower with electrolyzed water generation part Download PDFInfo
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- TWI507255B TWI507255B TW102139145A TW102139145A TWI507255B TW I507255 B TWI507255 B TW I507255B TW 102139145 A TW102139145 A TW 102139145A TW 102139145 A TW102139145 A TW 102139145A TW I507255 B TWI507255 B TW I507255B
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Description
本發明係有關一種具有電解水生成部之冷卻水塔循環水系統之電解吸附水垢裝置,尤指一種兼具溶垢效果佳對人體及環境皆無害、適合事業單位長期使用、可精確控制其鹼性水產生之條件,與可設定清除水垢的時間之具有電解水生成部之冷卻水塔循環水系統之電解吸附水垢裝置。The invention relates to an electrolytic adsorption scale device for a cooling water tower circulating water system with an electrolysis water generating part, in particular to a method which has good scale-dissolving effect and is harmless to the human body and the environment, is suitable for long-term use of a public institution, and can accurately control the alkalinity thereof. The conditions for the generation of water, and the electrolytic adsorption scale device of the cooling water tower circulating water system having the electrolyzed water generating portion, which can set the time for removing the scale.
現今多數之事業單位(如工廠、商業大樓、餐廳、大型商場、百貨公司、娛樂場所、圖書館、醫院等)皆有設置冷卻水塔(Cooling Tower),其目的是藉由水作為吸收熱之介質來使空調或冷卻負載之設備降溫。然而不當的操作維護,除了無法節省冷卻水塔之耗水量,亦引發其系統產生結垢(scaling),因而降低熱傳導效率,以致造成耗能,使冷卻循環水塔常需清洗或保養,每次的停機保養,都造成企業廠商一筆可觀的開銷。Most of today's business units (such as factories, commercial buildings, restaurants, large shopping malls, department stores, entertainment venues, libraries, hospitals, etc.) have cooling towers, which are designed to use water as a medium for absorbing heat. To cool the air conditioning or cooling load equipment. However, improper operation and maintenance, in addition to the inability to save water consumption of the cooling tower, also caused the system to generate scaling, thereby reducing the heat transfer efficiency, resulting in energy consumption, so that the cooling circuit tower often needs cleaning or maintenance, each time the shutdown Maintenance has caused a considerable amount of expenses for enterprise manufacturers.
當水加熱溫度昇高時,水中之鈣鹽,鎂鹽所生成之微小晶體沉降析出,累積附著在管壁和熱交換表面而形成水垢。據一般估計,當水垢厚度每增加0.3mm時,會多浪費10%之能量。為了節省能源,絕不可讓系統內積存水垢。When the water heating temperature rises, the calcium crystals formed in the water and the tiny crystals formed by the magnesium salts precipitate and precipitate, and accumulate on the tube wall and the heat exchange surface to form scale. It is generally estimated that when the scale thickness increases by 0.3 mm, 10% more energy is wasted. In order to save energy, there must be no accumulation of scale in the system.
表A為水垢厚度對於熱交換之影響程度,依水垢厚度的不同可以發現其熱交換程度、熱交換損失、電力損耗程度都有所變化。Table A shows the degree of influence of scale thickness on heat exchange. It can be found that the degree of heat exchange, heat exchange loss, and power loss vary according to the thickness of scale.
為解決目前水循環系統之水垢沉積問題,以往水循環系統之水垢處理方式,大都以化學投藥,達到殺菌、滅藻及除垢為主。In order to solve the problem of scale deposition in the current water circulation system, most of the scale treatment methods of the water circulation system have been chemically administered to achieve sterilization, algae elimination and descaling.
但是,使用化學投藥的背後,同時也造成了環境汙染及對於設備的侵蝕狀況,另外對於設備維護人員的健康也有所影響,且無法有效根治水垢本身沉積於之管壁問題。However, behind the use of chemical drugs, it also causes environmental pollution and erosion of equipment, and also affects the health of equipment maintenance personnel, and can not effectively cure the problem of the scale itself deposited on the wall.
因此,有必要研發新技術,以解決上述缺點及問題。Therefore, it is necessary to develop new technologies to solve the above shortcomings and problems.
本發明之目的,在於提供一種具有電解水生成部之冷卻水塔循環水系統之電解吸附水垢裝置,其兼具溶垢效果佳對人體及環境皆無害、適合事業單位長期使用、可精確控制其鹼性水產生之條件,與可設定清除水垢的時間等優點。特別是,本發明所欲解決之問題係在於傳統化學投藥方式易造成環境污境、有害人體健康,且無法有效根治水垢沉積於管壁等問題。An object of the present invention is to provide an electrolytic adsorption scale device for a cooling water tower circulating water system having an electrolyzed water generating portion, which has good scale-dissolving effect and is harmless to the human body and the environment, and is suitable for long-term use of a business unit, and can accurately control the alkalinity thereof. The conditions for the production of sexual water, and the time to set the scale removal. In particular, the problem to be solved by the present invention is that the conventional chemical administration method is liable to cause environmental pollution, harmful human health, and cannot effectively cure the problem of scale deposition on the tube wall.
解決上述問題之技術手段係提供一種具有電解水生成部之冷卻水塔循環水系統之電解吸附水垢裝置,其包括: 一冷卻水塔循環水系統,係具有:一冷卻水塔,係設有一水塔入口、一通風部、一儲水部及一水塔出口;該水塔入口係供一水液流入該冷卻水塔;該通風部係用以使外部空氣流進與流出該冷卻水塔,而對該水塔入口流出之該水液進行冷卻,冷卻後之該水液係掉落該儲水部內,該水塔出口係供該儲水部內之水液排出;一冷卻水管路,係連通該水塔出口及該水塔入口,用以導出與導入該水液;一散熱部,係設於該冷卻水管路上,並介於該水塔出口及該水塔入口之間,用以藉流過之冷卻的水液進行散熱;一加壓裝置,係設於該冷卻水管路上,用以強制水液於該冷卻水管路內流動;一電解水生成部,係具有一電源裝置、一電解水反應器、一隔膜、一陰極、一陽極及一鹼性水供應部;該電源裝置係具有一正極及一負極,分別電性連接該陽極與該陰極,該電解水反應器係用以容納一工作液,該隔膜係插入該電解水反應器且接觸該工作液,用以將該電解水反應器間隔成一第一區及一第二區,該陽極係浸入該第一區,該陰極係浸入該第二區,該鹼性水供應部係連通該第二區及該冷卻水塔;該鹼性水供應部係具有一供應管路、一供電器及一第一網狀電極;該供應管路係連通該第二區及該儲水部,且浸入該水液中;該供電器具有一正極部及一負極部,該正極部電性連結該第一網狀電極,且該正極部與該冷卻水塔之水液概呈絕緣,該第一網狀電極係固定於該冷卻水塔 內,且伸入該儲水部而供該水液流通;一中央系統,係具有一管中pH值感知器、一電壓調整部及一控制部;該管中pH值感知器係伸入而用以即時偵測該冷卻水管路中之pH值,並產生一pH值訊號;該電壓調整部用以調整該電源裝置之電壓變大與變小,該控制部係擷取該pH值訊號,並依據該pH值訊號之變大與變小,而透過該電壓調整部,調整該電源裝置之電壓值;其中,該鹼性水供應部又包括:一第二網狀電極,該第一、該第二網狀電極概呈圓筒網結構,而可相互套設;該正、該負極部係分別電性連結該第一、該第二網狀電極,且該正極部、該負極部係分別與該冷卻水塔之水液概呈絕緣;該第一、該第二網狀電極係固定於該冷卻水塔內,且伸入該儲水部而供該水液流通;一上蓋板、一下蓋板及複數支撐柱;該上、該下蓋板,皆係具有一第一圓形凹槽及一第二圓形凹槽;該複數支撐柱係連結固定於該上、該下蓋板之間;該上蓋板具有一注液口,用以連通該供應管路;該第一網狀電極係被固定於該上、該下蓋板之其第一圓形凹槽中;該第二網狀電極係被固定於該上、該下蓋板之其第二圓形凹槽中;藉此,當該電源裝置供電後,該電解水反應器用以進行電解水反應,該第一區內之工作液概呈酸性之工作液,而該第二區內之工作液概呈鹼性之工作液;鹼性之工作液係透過該供應管路供入該儲水部中之該 第一、該第二網狀電極之圓筒網結構內,先利用鹼性水與水中金屬離子結合形成水垢,再透過該第一、該第二網狀電極,達到使該冷卻水塔內之水液的水垢電解吸附率提高而能夠降低冷卻水塔之水垢之產生機率。The technical means for solving the above problems is to provide an electrolytic adsorption scale device of a cooling water tower circulating water system having an electrolysis water generating portion, comprising: A cooling water tower circulating water system has: a cooling water tower, a water tower inlet, a ventilation part, a water storage part and a water tower outlet; the water tower inlet is for supplying a water liquid into the cooling water tower; the ventilation part is The water is flowed into and out of the cooling water tower, and the water flowing out from the inlet of the water tower is cooled, and the cooled liquid is dropped into the water storage portion, and the water tower outlet is provided in the water storage portion. The water liquid is discharged; a cooling water pipeline is connected to the water tower outlet and the water tower inlet for deriving and introducing the water liquid; a heat dissipating portion is disposed on the cooling water pipe, and is located at the water tower outlet and the water tower inlet Between the cooling water used for cooling; a pressurizing device is disposed on the cooling water pipe to force the water to flow in the cooling water pipe; an electrolysis water generating portion has a power supply device, an electrolyzed water reactor, a separator, a cathode, an anode, and an alkaline water supply portion; the power supply device has a positive electrode and a negative electrode electrically connected to the anode and the cathode, respectively The reactor is configured to receive a working fluid, the separator is inserted into the electrolyzed water reactor and contacts the working fluid, and the electrolyzed water reactor is partitioned into a first zone and a second zone, and the anode is immersed in the first In one zone, the cathode system is immersed in the second zone, the alkaline water supply unit is connected to the second zone and the cooling water tower; the alkaline water supply part has a supply pipeline, a power supply and a first network The supply line is connected to the second zone and the water storage part, and is immersed in the water liquid; the power supply device has a positive electrode portion and a negative electrode portion, and the positive electrode portion is electrically connected to the first mesh electrode. And the positive electrode portion is insulated from the water liquid of the cooling water tower, and the first mesh electrode is fixed to the cooling water tower And extending into the water storage portion for the liquid to circulate; a central system having a tube pH sensor, a voltage adjustment portion, and a control portion; the pH sensor in the tube is inserted into the tube The utility model is configured to detect the pH value in the cooling water pipeline and generate a pH signal; the voltage adjusting unit is configured to adjust the voltage of the power supply device to become larger and smaller, and the control unit captures the pH signal. And adjusting, according to the voltage signal, the voltage value of the power supply device, wherein the alkaline water supply unit further comprises: a second mesh electrode, the first The second mesh electrode has a cylindrical mesh structure and can be sleeved with each other; the positive and the negative electrode portions are electrically connected to the first and second mesh electrodes, respectively, and the positive electrode portion and the negative electrode portion are respectively Separatingly from the water liquid of the cooling water tower; the first and second mesh electrodes are fixed in the cooling water tower, and extend into the water storage portion for the liquid to circulate; a cover plate and a plurality of support columns; the upper and the lower cover plates each have a first circular groove and a first a circular groove; the plurality of support columns are fixedly connected between the upper and the lower cover; the upper cover has a liquid injection port for communicating with the supply line; the first mesh electrode is fixed In the first circular groove of the upper and lower covers; the second mesh electrode is fixed in the second circular groove of the upper and lower covers; thereby, when After the power supply device is powered, the electrolyzed water reactor is used for performing electrolysis water reaction, the working fluid in the first zone is acidic working fluid, and the working fluid in the second zone is alkaline working fluid; alkaline The working fluid is supplied to the water storage portion through the supply line First, in the cylindrical mesh structure of the second mesh electrode, firstly, alkaline water is combined with metal ions in the water to form scale, and then the first and second mesh electrodes are passed through to obtain water in the cooling water tower. The scale adsorption rate of the liquid is increased to reduce the probability of generation of scale in the cooling tower.
本發明之上述目的與優點,不難從下述所選用實施例之詳細說明與附圖中,獲得深入瞭解。The above objects and advantages of the present invention will be readily understood from the following detailed description of the preferred embodiments illustrated herein.
茲以下列實施例並配合圖式詳細說明本發明於後:The invention will be described in detail in the following examples in conjunction with the drawings:
10‧‧‧冷卻水塔循環水系統10‧‧‧Cooling tower circulating water system
11‧‧‧冷卻水塔11‧‧‧Cooling tower
111‧‧‧水塔入口111‧‧‧Water Tower Entrance
112‧‧‧通風部112‧‧‧ Ventilation Department
113‧‧‧儲水部113‧‧‧Water Storage Department
114‧‧‧水塔出口114‧‧‧Water tower exit
12‧‧‧冷卻水管路12‧‧‧Cooling water line
13‧‧‧散熱部13‧‧‧ Department of heat dissipation
14‧‧‧加壓裝置14‧‧‧ Pressurizing device
20‧‧‧電解水生成部20‧‧‧Electrolysis Water Generation Department
21‧‧‧電源裝置21‧‧‧Power supply unit
211‧‧‧正極211‧‧‧ positive
212‧‧‧負極212‧‧‧negative
22‧‧‧電解水反應器22‧‧‧ Electrolytic water reactor
221‧‧‧第一區221‧‧‧First District
222‧‧‧第二區222‧‧‧Second District
23‧‧‧隔膜23‧‧‧Separator
24‧‧‧陽極24‧‧‧Anode
25‧‧‧陰極25‧‧‧ cathode
26‧‧‧鹼性水供應部26‧‧‧Alkaline Water Supply Department
261‧‧‧供應管路261‧‧‧Supply pipeline
262‧‧‧供電器262‧‧‧Power supply
263‧‧‧第一網狀電極263‧‧‧First mesh electrode
264‧‧‧第二網狀電極264‧‧‧Second mesh electrode
265‧‧‧上蓋板265‧‧‧Upper cover
266‧‧‧下蓋板266‧‧‧Under cover
267‧‧‧支撐柱267‧‧‧Support column
26A‧‧‧正極部26A‧‧‧ positive part
26B‧‧‧負極部26B‧‧‧Negative part
26C‧‧‧閥26C‧‧‧ valve
26D‧‧‧第一圓形凹槽26D‧‧‧First circular groove
26E‧‧‧第二圓形凹槽26E‧‧‧Second circular groove
26F‧‧‧注液口26F‧‧‧ injection port
30‧‧‧中央系統30‧‧‧Central System
31‧‧‧管中pH值感知器31‧‧‧In-tube pH sensor
311‧‧‧pH值訊號311‧‧‧pH signal
32‧‧‧電壓調整部32‧‧‧Voltage adjustment department
33‧‧‧控制部33‧‧‧Control Department
91‧‧‧水液91‧‧‧Water
92‧‧‧工作液92‧‧‧ working fluid
L1‧‧‧第一曲線L1‧‧‧ first curve
L2‧‧‧第二曲線L2‧‧‧ second curve
L3‧‧‧第三曲線L3‧‧‧ third curve
L4‧‧‧第四曲線L4‧‧‧ fourth curve
第一圖係空調系統之散熱裝置之示意圖The first picture is a schematic diagram of the heat sink of the air conditioning system
第二圖係第一圖之冷卻液流通之示意圖The second figure is a schematic diagram of the coolant flow in the first figure.
第三圖係本發明之示意圖The third figure is a schematic view of the present invention
第四圖係本發明之主要裝置之示意圖The fourth figure is a schematic diagram of the main device of the present invention.
第五圖係第四圖之部分結構之放大之示意圖The fifth figure is an enlarged schematic view of a part of the structure of the fourth figure.
第六圖係本發明之鹼性水供應部之示意圖Figure 6 is a schematic view of the alkaline water supply portion of the present invention
第七圖係第六圖之部分結構之分解之示意圖The seventh figure is a schematic diagram of the decomposition of part of the structure of the sixth figure.
第八圖係以第一曲線L1表示暫時硬水水垢吸附水體總硬度趨勢之示意圖The eighth figure is a schematic diagram showing the trend of the total hardness of the temporary hard water scale adsorbing water body by the first curve L1.
第九圖係以第二曲線L2表示暫時硬水水垢吸附TDS趨勢之示意圖The ninth graph is a schematic diagram showing the tendency of temporary hard water scale adsorption TDS by the second curve L2.
第十A、第十B及第十C圖係分別為本發明之暫時硬水水垢吸附於陰極狀況在24小時、48小時及72小時之示意圖The tenth, tenth, and tenthth Cth drawings are schematic diagrams showing the temporary hard water scale adsorbed to the cathode in the present invention at 24 hours, 48 hours, and 72 hours, respectively.
第十一圖係暫時與永久硬水水垢吸附水體總硬度趨勢之示意圖The eleventh figure is a schematic diagram of the trend of total hardness of temporary water and permanent hard water scale adsorption
第十二圖係暫時與永久硬水水垢吸附TDS趨勢之示意圖The twelfth map is a schematic diagram of the tendency of temporary and permanent hard water scale adsorption TDS
第十三A、第十三B及第十三C圖係分別為本發明之暫時與永久硬水水垢 吸附於陰極狀況在24小時、48小時及72小時之示意圖The thirteenth, thirteenth and thirteenth Cth drawings are the temporary and permanent hard water scales of the present invention, respectively. Schematic diagram of adsorption to cathode conditions at 24 hours, 48 hours, and 72 hours
參閱第一、第二及第三圖,本發明係為一種具有電解水生成部之冷卻水塔循環水系統之電解吸附水垢裝置,其包括:一冷卻水塔循環水系統10,係具有:一冷卻水塔11,係設有一水塔入口111、一通風部112、一儲水部113及一水塔出口114;該水塔入口111係供一水液91流入該冷卻水塔11;該通風部112係用以使外部空氣流進與流出該冷卻水塔11,而對該水塔入口111流出之該水液91進行冷卻,冷卻後之該水液91係掉落該儲水部113內,該水塔出口114係供該儲水部113內之水液91排出;一冷卻水管路12,係連通該水塔出口114及該水塔入口111,用以導出與導入該水液91;一散熱部13,係設於該冷卻水管路12上,並介於該水塔出口114及該水塔入口111之間,用以藉流過之冷卻的水液91進行散熱;一加壓裝置14,係設於該冷卻水管路12上,用以強制水液91於該冷卻水管路12內流動;一電解水生成部20,係具有一電源裝置21、一電解水反應器22、一隔膜23、一陽極24、一陰極25及一鹼性水供應部26;該電源裝置21係具有一正極211及一負極212,分別電性連接該陽極24與該陰極25,該電解水反應器22係用以容納一工作液92,該隔膜23係插入該電解水反應器22且接觸該工作液221,用以將該電解水反應器22間隔成一第一區221及一第二區222,該陽極24係浸入該第一區221,該陰極25係浸入該第二區222,該鹼性 水供應部26係連通該第二區222及該冷卻水塔10;該鹼性水供應部26係具有一供應管路261、一供電器262及一第一網狀電極263(參閱第四圖,本案之第一實施例);該供應管路261係連通該第二區222及該儲水部113,且浸入該水液91中;該供電器262具有一正極部26A及一負極部26B,該正極部26A電性連結該第一網狀電極263,且該正極部26A與該冷卻水塔10之水液91概呈絕緣,該第一網狀電極263係固定於該冷卻水塔10內,且伸入該儲水部113而供該水液91流通;藉此,當該電源裝置21供電後,該電解水反應器22用以進行電解水反應,該第一區221內之工作液92概呈酸性之工作液,而該第二區222內之工作液92概呈鹼性之工作液;鹼性之工作液92係透過該供應管路261供入該儲水部113中,又,該供電器262對該第一網狀電極263供電,達到使該冷卻水塔10內之水液91的水垢電解吸附率提高而能夠降低冷卻水塔10之水垢之產生機率。Referring to the first, second and third figures, the present invention is an electrolytic adsorption scale device for a cooling water tower circulating water system having an electrolysis water generating portion, comprising: a cooling water tower circulating water system 10 having: a cooling water tower 11, a water tower inlet 111, a venting portion 112, a water storage portion 113 and a water tower outlet 114; the water tower inlet 111 is for a water liquid 91 to flow into the cooling water tower 11; the venting portion 112 is for external The air flows into and out of the cooling water tower 11, and the water liquid 91 flowing out of the water tower inlet 111 is cooled, and the cooled liquid liquid 91 is dropped into the water storage portion 113, and the water tower outlet 114 is used for the storage. The water liquid 91 in the water portion 113 is discharged; a cooling water pipe 12 is connected to the water tower outlet 114 and the water tower inlet 111 for guiding and introducing the water liquid 91; a heat radiating portion 13 is disposed in the cooling water pipe 12, and between the water tower outlet 114 and the water tower inlet 111, for cooling by the cooled water liquid 91; a pressurizing device 14 is disposed on the cooling water pipeline 12 for The forced water liquid 91 flows in the cooling water pipe 12; The water-splitting unit 20 has a power supply unit 21, an electrolysis water reactor 22, a diaphragm 23, an anode 24, a cathode 25 and an alkaline water supply unit 26; the power supply unit 21 has a positive electrode 211 and An anode 212 electrically connected to the anode 24 and the cathode 25, respectively, the electrolytic water reactor 22 is configured to receive a working fluid 92, the diaphragm 23 is inserted into the electrolysis water reactor 22 and contacts the working fluid 221, The electrolysis water reactor 22 is partitioned into a first zone 221 and a second zone 222. The anode 24 is immersed in the first zone 221, and the cathode 25 is immersed in the second zone 222. The water supply unit 26 is connected to the second area 222 and the cooling water tower 10; the alkaline water supply unit 26 has a supply line 261, a power supply 262 and a first mesh electrode 263 (see the fourth figure, In the first embodiment of the present invention, the supply line 261 is connected to the second area 222 and the water storage part 113, and is immersed in the water liquid 91. The power supply unit 262 has a positive electrode portion 26A and a negative electrode portion 26B. The positive electrode portion 26A is electrically connected to the first mesh electrode 263, and the positive electrode portion 26A is substantially insulated from the water liquid 91 of the cooling water tower 10, and the first mesh electrode 263 is fixed in the cooling water tower 10, and The water storage unit 113 is inserted into the water storage unit 113 for circulation; thereby, after the power supply unit 21 supplies power, the electrolysis water reactor 22 is used to perform an electrolysis water reaction, and the working fluid 92 in the first area 221 is An acidic working fluid, and the working fluid 92 in the second zone 222 is an alkaline working fluid; the alkaline working fluid 92 is supplied into the water storage part 113 through the supply line 261, and The power supply device 262 supplies power to the first mesh electrode 263, so that the scale electrolysis rate of the water liquid 91 in the cooling water tower 10 can be increased. Reducing the probability of generation of the scale 10 of the cooling towers.
實務上,該通風部112概呈網狀結構。In practice, the venting portion 112 has a mesh structure.
該散熱部13可為空調系統之散熱裝置(如第第三圖所示),或是任何需要散熱之裝置均可。The heat dissipating portion 13 can be a heat dissipating device of the air conditioning system (as shown in the third figure), or any device that needs to dissipate heat.
該加壓裝置14可為公知抽水馬達,並介於該水塔出口114與該散熱部13之間。The pressurizing device 14 can be a known pumping motor and interposed between the water tower outlet 114 and the heat radiating portion 13.
該電源裝置21可為電池或是電源供應器。The power supply unit 21 can be a battery or a power supply.
該鹼性水供應部26又包括:一閥26C,可為機械閥結構或是電子閥結構,用以啟動與關閉該鹼性水供應部26,並可依實際需求而控制酸性之工作液92之供應量。The alkaline water supply unit 26 further includes a valve 26C, which may be a mechanical valve structure or an electronic valve structure, for starting and closing the alkaline water supply portion 26, and controlling the acidic working fluid 92 according to actual needs. The supply.
一第二網狀電極264(參閱第五、第六及第七圖,係本案之第二實施例),該第一、該第二網狀電極263與264概呈圓筒網結構,而可相互套設;該正、該負極部26A與26B係分別電性連結該第一、該第二網狀電極263與264,且該正極部26A、該負極部26B係分別與該冷卻水塔10之水液91概呈絕緣;該第一、該第二網狀電極263與264係固定於該冷卻水塔10內,且伸入該儲水部113而供該水液91流通,達到使該冷卻水塔10內之水液91的水垢電解吸附率提高而能夠降低冷卻水塔10之水垢之產生機率。a second mesh electrode 264 (refer to the fifth, sixth and seventh figures, which is the second embodiment of the present invention), wherein the first and second mesh electrodes 263 and 264 are in a cylindrical network structure, but The positive and the negative electrode portions 26A and 26B are electrically connected to the first and second mesh electrodes 263 and 264, respectively, and the positive electrode portion 26A and the negative electrode portion 26B are respectively associated with the cooling water tower 10 The water liquid 91 is substantially insulated; the first and second mesh electrodes 263 and 264 are fixed in the cooling water tower 10, and extend into the water storage portion 113 for the water liquid 91 to flow to reach the cooling water tower. The scale electrolysis rate of the aqueous liquid 91 in 10 is increased, and the generation rate of the scale of the cooling water tower 10 can be reduced.
更進一步來講,該鹼性水供應部26再包括一上蓋板265、一下蓋板266及複數支撐柱267;該上、該下蓋板265與266,皆係具有一第一圓形凹槽26D及一第二圓形凹槽26E;該複數支撐柱267係連結固定於該上、該下蓋板265與266之間;該上蓋板265具有一注液口26F,用以連通該供應管路261;該第一網狀電極263係被固定於該上、該下蓋板265與266之其第一圓形凹槽26D中;該第二網狀電極264係被固定於該上、該下蓋板265與266之其第二圓形凹槽26E中。Further, the alkaline water supply unit 26 further includes an upper cover 265, a lower cover 266 and a plurality of support columns 267; the upper and lower covers 265 and 266 each have a first circular concave a groove 26D and a second circular groove 26E; the plurality of support columns 267 are fixedly coupled between the upper and lower covers 265 and 266; the upper cover 265 has a liquid inlet 26F for communicating a supply line 261; the first mesh electrode 263 is fixed in the first circular groove 26D of the upper and lower covers 265 and 266; the second mesh electrode 264 is fixed thereto The lower cover plates 265 and 266 are in their second circular recesses 26E.
當然,本案可以再包括:一中央系統30,係具有一管中pH值感知器31、一電壓調整部32及一控制部33;該管中pH值感知器31係伸入而用以即時偵測該冷卻水管路12中之pH值,並產生一pH值訊號311;該電壓調整部32用以調整該電源裝置21之電壓變大與變小,該控制部33係擷取該pH值訊號311,並依據該pH值訊號311之變大與變小,而透過該電壓調整部32,調整該電源裝置21之電壓 值。舉例來講,當該pH值訊號311變大(代表該工作液92酸性變強)與變小(代表該工作液92酸性變弱),則分別控該電源裝置21之電壓變小(降低電解反應,減少酸性)與變大(增加電解反應,增加酸性)。Of course, the present invention may further include: a central system 30 having a tube pH sensor 31, a voltage adjustment unit 32, and a control unit 33; the pH sensor 31 of the tube is extended for instant detection The pH value of the cooling water pipe 12 is measured, and a pH signal 311 is generated. The voltage adjusting unit 32 is configured to adjust the voltage of the power supply device 21 to become larger and smaller, and the control unit 33 extracts the pH signal. 311, according to the pH signal 311 becoming larger and smaller, and adjusting the voltage of the power supply device 21 through the voltage adjusting portion 32 value. For example, when the pH signal 311 becomes larger (representing that the working fluid 92 becomes acidic) and becomes smaller (representing that the working fluid 92 is weakened), the voltage of the power supply device 21 is controlled to be smaller (reduction of electrolysis). The reaction, which reduces the acidity) and becomes larger (increasing the electrolytic reaction and increasing the acidity).
更佳的是,當該冷卻水管路12中之pH值低於一目標區間時,該控制部33係透過該電壓調整部32,使該電源裝置21之電壓升高,以使該冷卻水管路12中之pH值升高至該目標區間;當該冷卻水管路12中之pH值高於該目標區間時,該控制部33係透過該電壓調整部32,使該電源裝置21之電壓降低,以使該冷卻水管路12中之pH值降低至該目標區間;又,該目標區間係為pH值介於3至6之間;當然,更優選的範圍是pH值介於4至5之間。More preferably, when the pH value in the cooling water pipe 12 is lower than a target interval, the control unit 33 transmits the voltage of the power supply device 21 through the voltage adjusting portion 32 to make the cooling water pipe. The pH value of 12 is raised to the target section; when the pH value of the cooling water line 12 is higher than the target section, the control unit 33 transmits the voltage of the power supply unit 21 through the voltage adjustment unit 32. So that the pH in the cooling water line 12 is lowered to the target interval; in addition, the target interval is between pH 3 and 6; of course, the more preferred range is between 4 and 5 pH. .
在本實施例下,本案可以透過回饋機制而自動維持該冷卻水管路12之pH值於一較佳溶解率之情況,有利於自動穩定的控制水垢之生成機率。Under the present embodiment, the present invention can automatically maintain the pH value of the cooling water pipe 12 at a preferred dissolution rate through a feedback mechanism, which is advantageous for automatically and stably controlling the generation rate of scale.
本發明之使用方式係如下所述:The mode of use of the present invention is as follows:
參閱第一圖,該冷卻水塔循環水系統10,主要是以該水液91於冷卻水管路12內循環流動而用以散熱,其散熱流程:啟動該加壓裝置14→強制水液91從該水塔出口114被導入冷卻水管路12→水液91從該水塔出口114經該加壓裝置14流向該散熱部13→水液91於散熱部13吸收熱而降低散熱部13之熱量→水液91從散熱部13流向水塔入口11→水液91從冷卻水管路12經水塔入口111流進冷卻水塔11→水液91流進冷卻水塔11的過程由通風部112進行散熱冷卻→散熱冷卻後的水液91掉落於儲水部113內,以供被導出而進行循環散熱。Referring to the first figure, the cooling water tower circulating water system 10 mainly uses the water liquid 91 circulating in the cooling water pipe 12 for heat dissipation, and the heat dissipation process: starting the pressing device 14 → forcing the water liquid 91 from the The water tower outlet 114 is introduced into the cooling water pipe 12 → the water liquid 91 flows from the water tower outlet 114 through the pressurizing device 14 to the heat radiating portion 13 → the water liquid 91 absorbs heat in the heat radiating portion 13 to reduce the heat of the heat radiating portion 13 → water liquid 91 Flow from the heat radiating portion 13 to the water tower inlet 11 → the water liquid 91 flows from the cooling water pipe 12 through the water tower inlet 111 into the cooling water tower 11 → the water liquid 91 flows into the cooling water tower 11 by the ventilating portion 112 for heat dissipation and cooling The liquid 91 is dropped into the water storage portion 113 for being discharged to perform heat dissipation.
而水液91於該冷卻水管路12內流動一段時間,便會產生水垢 (長時間下來會堵塞冷卻水管路12),此時可依實際狀況(例如經設備廠商實驗,每隔一個月供入鹼性液以去除或是減少水垢),啟動該電源裝置21,使該電解水反應器22進行電解水反應,使該第二區222內之工作液92呈鹼性,再啟動該閥261,對該冷卻水管路12適用供入鹼性之工作液92,藉水液91流通帶動,達到提高該冷卻水管路12內部之水垢溶解率而能降低該冷卻水管路12中之水垢之產生機率。When the water liquid 91 flows in the cooling water pipe 12 for a certain period of time, scale is generated. (The cooling water pipe 12 will be blocked for a long time). At this time, the power supply device 21 can be activated according to actual conditions (for example, by adding an alkaline liquid every other month to remove or reduce scale). The electrolyzed water reactor 22 performs an electrolysis water reaction to make the working fluid 92 in the second zone 222 alkaline, and then activates the valve 261, and applies the alkaline working fluid 92 to the cooling water pipe 12, When the flow rate is 91, the scale dissolution rate inside the cooling water pipe 12 is increased, and the generation rate of the scale in the cooling water pipe 12 can be reduced.
在此要特別說明的部分,是關於本案之運作原理與實驗之佐證:The part to be specifically explained here is the evidence of the operation principle and experiment of this case:
關於電解水之生成過程,如第三圖所示,在該電源裝置21輸出之直流電流的作用下,兩極會發生化學反應,這種過程稱之為電解。電解是將電能轉化成化學能的過程。電解水處理過程中所發生的化學變化與水中的化學組成、物質濃度、電極材料等因素密切相關,兩極上析出物質的量和通過電量成正比。Regarding the formation process of the electrolyzed water, as shown in the third figure, under the action of the direct current output from the power supply unit 21, a chemical reaction occurs between the two poles, and this process is called electrolysis. Electrolysis is the process of converting electrical energy into chemical energy. The chemical changes that occur during the treatment of electrolyzed water are closely related to the chemical composition, material concentration, electrode material and other factors in the water. The amount of precipitated substances on the two poles is proportional to the amount of electricity passing through.
在水處理中,針對具有不同化學組成的水質條件,通過改變不同的電極材料、電極佈置方式、反應室結構、電極作用過程和催化氧化還原措施等,可以獲得不同的電解淨水效果。In water treatment, different water purification conditions can be obtained by changing different electrode materials, electrode arrangement, reaction chamber structure, electrode action process and catalytic redox measures for water quality conditions with different chemical compositions.
電解過程中典型的化學反應如下(習知技術):Typical chemical reactions during electrolysis are as follows (known techniques):
陰極附近生成氫氣:Hydrogen is generated near the cathode:
2H2 O+2e-=H2 +2OH-2H 2 O+2e-=H 2 +2OH-
CO2 +OH-=HCO3 - CO 2 +OH-=HCO 3 -
HCO3 - +OH-=CO3 2 -+H2 OHCO 3 - +OH-=CO 3 2 -+H 2 O
Ca2+ 鈣離子可能形成Ca 2+ calcium ions may form
氫氧化鈣:Ca(OH)2 (水垢)Calcium hydroxide: Ca(OH) 2 (scale)
碳酸鈣:CaCO3 (水垢)Calcium carbonate: CaCO 3 (scale)
陽極附近生成氧氣Oxygen generation near the anode
4OH- =O2 +2H2 O+4e-4OH - =O 2 +2H 2 O+4e-
於電解水反應過程中可以得知水體中造成水體硬度之主要因子為鈣、鎂離子,於水中將形成氫氧化鈣(鎂)、碳酸鈣(鎂)、碳酸氫鈣(鎂)。此外,可以從水化學(Water Chemistry)之教科書中可以得知:其碳酸水溶液於pH值較小之狀況下,其水溶液中之碳酸鈣、鎂(所謂之水垢)解離為碳酸、鈣、鎂、碳酸氫根離子狀態,也就等同於暫時硬水解離之狀態,故將酸性水注入系統,將其水循環設備之管路水垢溶解,使其碳酸鈣解離為碳酸氫鈣之暫時硬水。During the electrolysis water reaction process, it can be known that the main factors causing the water body hardness in the water body are calcium and magnesium ions, and calcium hydroxide (magnesium), calcium carbonate (magnesium) and calcium hydrogencarbonate (magnesium) are formed in the water. In addition, it can be known from the textbook of Water Chemistry that the aqueous solution of carbonic acid is dissociated from calcium carbonate and magnesium (so-called scale) in aqueous solution to carbonic acid, calcium and magnesium at a low pH. The state of bicarbonate ion is equivalent to the state of temporary hard hydrolysis. Therefore, acidic water is injected into the system to dissolve the scale of the water circulation equipment, and the calcium carbonate is dissociated into temporary hard water of calcium hydrogencarbonate.
關於本案之水垢吸附將利用小型電解實驗進行硬水電解沉積實驗,分析評估電極材料與調配操作參數對電解效率之影響,並針對暫時、永久硬水做實際測試,量測並分析水質檢測項目,評估其水質改善效率。The scale adsorption in this case will use small electrolysis experiments to conduct hard water electroplating experiments, analyze and evaluate the influence of electrode materials and blending operation parameters on electrolysis efficiency, and conduct actual tests on temporary and permanent hard water, measure and analyze water quality testing items, and evaluate them. Water quality improves efficiency.
本實驗中之電解水體使用硫酸鈣CaSO4 與碳酸氫鈉NaHCO3 調配為暫時硬水與暫時永久硬水共存,兩種水體進行實驗,陽極電極部分採用鈦鍍白金網,而陰極電極部分採用不鏽鋼網。在固定電解面積下進行72小時連續實驗,每12小時採樣水體進行檢測,主要測定指標為pH值、溶解固定總量(total dissolved solids,簡稱TDS)、水體總硬度、導電度、電阻率、鹽度。每24小時取下陰極網,烘乾陰極網除去水分,進行陰極網吸附水垢之重量量測,量測完畢繼續進行實驗。The electrolyzed water in this experiment was prepared by using calcium sulfate CaSO 4 and sodium hydrogencarbonate NaHCO 3 as temporary hard water and temporary permanent hard water. Two kinds of water bodies were tested. The anode electrode part was made of titanium plated platinum wire, and the cathode electrode part was made of stainless steel mesh. The continuous experiment was carried out for 72 hours under the fixed electrolysis area, and the water sample was tested every 12 hours. The main measurement indexes were pH value, total dissolved solids (TDS), total water hardness, electrical conductivity, electrical resistivity, and salt. degree. The cathode mesh was taken every 24 hours, the cathode mesh was dried to remove moisture, and the weight of the scale adsorbed by the cathode mesh was measured, and the measurement was continued.
關於水垢吸附效率數據分析:Data analysis on scale adsorption efficiency:
首先,有關暫時硬水水垢吸附部份:First, regarding the temporary hard water scale adsorption part:
經由實驗數據結果顯示(如表1所示),於暫時硬水之水垢吸附量及水質硬度改善趨勢,可以得知其電解吸附水垢之效果於72小時連續實驗後均有效達到其TDS下降。此外,也透過量測陰極電極吸附鈣、鎂離子之重量,與水體之TDS數據及水體總硬度呈現正相關之現象。According to the experimental data (as shown in Table 1), in the temporary hard water scale adsorption amount and water hardness improvement trend, it can be known that the effect of electrolytic adsorption of scale is effective to achieve a decrease in TDS after 72 hours of continuous experiment. In addition, by measuring the weight of calcium and magnesium ions adsorbed by the cathode electrode, it is positively correlated with the TDS data of the water body and the total hardness of the water body.
第八圖係以第一曲線L1表示暫時硬水水垢吸附水體總硬度趨勢之示意圖The eighth figure is a schematic diagram showing the trend of the total hardness of the temporary hard water scale adsorbing water body by the first curve L1.
第九圖係以第二曲線L2表示暫時硬水水垢吸附TDS趨勢之示意圖The ninth graph is a schematic diagram showing the tendency of temporary hard water scale adsorption TDS by the second curve L2.
第十A、第十B及第十C圖係分別為暫時硬水水垢吸附於陰極狀況在24小時、48小時及72小時之示意圖,顯示已有效吸附許多水垢。The tenth, tenth, and tenth Cth drawings are schematic diagrams showing that the temporary hard water scale is adsorbed to the cathode at 24 hours, 48 hours, and 72 hours, respectively, indicating that many scales have been effectively adsorbed.
其次,有關暫時與永久硬水水垢吸附部份(如表2、第十一、第十二、第十三A、第十三B及第三C圖所示):Secondly, the temporary and permanent hard water scale adsorption parts (as shown in Table 2, 11th, 12th, 13th, 13th and 3rd C):
第十一圖係以第三曲線表示暫時與永久硬水水垢吸附水體總硬度趨勢之示意圖。The eleventh figure is a schematic diagram showing the tendency of the temporary and permanent hard water scale to adsorb the total hardness of the water body in a third curve.
第十二圖係以第四曲線表示暫時與永久硬水水垢吸附TDS趨勢之示意圖。The twelfth graph is a schematic diagram showing the tendency of temporary and permanent hard water scale adsorption TDS by a fourth curve.
第十三A、第十三B及第十三C圖係分別為暫時與永久硬水水垢吸附於陰極狀況在24小時、48小時及72小時之示意圖。其分別顯示已有效吸附許多水垢。Figures 13A, 13B and 13C are schematic diagrams showing the temporary and permanent hard water scale adsorption to the cathode at 24 hours, 48 hours and 72 hours, respectively. They respectively show that many scales have been effectively adsorbed.
由上述兩組實驗可知,不論是「暫時硬水水垢吸附」或是「暫時與永久硬水水垢吸附」均可適用。It can be seen from the above two experiments that either "temporary hard scale adsorption" or "temporary and permanent hard scale adsorption" can be applied.
此外,由於本案之電解水生成部可產生鹼性水,並藉由鹼性 水供應部係將此鹼性水供入該冷卻水塔之水中,此時,若水中存在鈣離子或鎂離子(或類似之金屬離子),此鹼性水將可有效的與鈣離子或鎂離子結合(即水垢)。In addition, since the electrolyzed water generating part of the present case can generate alkaline water and is alkaline The water supply unit supplies the alkaline water into the water of the cooling water tower. At this time, if calcium ions or magnesium ions (or similar metal ions) are present in the water, the alkaline water can be effectively combined with calcium ions or magnesium ions. Combine (ie scale).
由於本案之鹼性水供應部設有第一網狀電極,其係可有效的吸附這些水垢,所以,經過一段時間後,只要將已吸附水垢之第一網狀電極取出並更換即可。Since the alkaline water supply portion of the present invention is provided with the first mesh electrode, the scale can be effectively adsorbed. Therefore, after a period of time, the first mesh electrode having adsorbed scale can be taken out and replaced.
換言之,本案係先利用鹼性水有利用捕捉水中之鈣離子或鎂離子,使其結合為鈣化合物或鎂化合物(即水垢);再利用鄰近之鹼性水供應部之第一網狀電極當成是一浸在冷卻水塔之水中之耗材,用來吸附水垢,只要定期更換即可有效將水垢移除。In other words, the case first uses alkaline water to capture calcium ions or magnesium ions in the water to combine it into a calcium compound or a magnesium compound (ie, scale); and then use the first mesh electrode of the adjacent alkaline water supply portion. It is a consumable that is immersed in the water of the cooling tower to absorb the scale. It can effectively remove the scale as long as it is replaced regularly.
當然,第一網狀電極(及/或第二電極網)可為平板狀或捲曲成圓柱狀或其他形狀,均不影響本案之功能。Of course, the first mesh electrode (and/or the second electrode mesh) may be flat or curled into a cylindrical shape or other shapes, and does not affect the function of the present case.
本發明之優點及功效係如下所述:The advantages and functions of the present invention are as follows:
[1]溶垢效果佳對人體及環境皆無害。由於本案利用電解水生成之鹼性水,可食用,對人體無害、亦不污染環境。本案之鹼性水可導入冷卻水塔中,再搭配第一網狀電極(及/或第二電極網),可有效降低水垢,同時又可避免習知投藥方式對環境汙染與對於設備維護人員的健康也有所影響。[1] Good segregation effect is harmless to human body and environment. Since the case uses alkaline water generated by electrolyzed water, it is edible, harmless to the human body, and does not pollute the environment. The alkaline water in the case can be introduced into the cooling water tower, and then matched with the first mesh electrode (and/or the second electrode mesh), which can effectively reduce the scale, and at the same time avoid the environmental pollution caused by the conventional administration method and the maintenance personnel for the equipment. Health also has an impact.
[2]適合事業單位長期使用。由於本案之第一網狀電極(及/或第二電極網)係為耗材,當吸附之水垢過多時,只要更換即可,適合事業單位長期使用,產業之應用層面高。[2] Suitable for long-term use by institutions. Since the first mesh electrode (and/or the second electrode mesh) of the present invention is a consumable material, when there is too much scale to be adsorbed, it can be replaced as long as it is suitable for long-term use by the institution, and the application level of the industry is high.
[3]可精確控制其鹼性水產生之條件。由於本案之電解水生 成部之電壓高低十分容易控制,因此,鹼性水之導入量與pH值可以精確的控制。[3] Precise control of the conditions under which alkaline water is produced. Due to the electrolysis of the case The voltage level of the part is very easy to control, so the introduction amount and pH value of the alkaline water can be precisely controlled.
[4]可設定清除水垢的時間。本發明可將鹼性水供應部上之閥設為電子式(當然,機械式亦可控制,端視實際設備之設計而定),配合時間自動啟動清除水垢。[4] The time to remove scale can be set. The invention can set the valve on the alkaline water supply part to be electronic (of course, the mechanical type can also be controlled, depending on the design of the actual equipment), and the time is automatically started to remove the scale.
以上僅是藉由較佳實施例詳細說明本發明,對於該實施例所做的任何簡單修改與變化,皆不脫離本發明之精神與範圍。The present invention has been described in detail with reference to the preferred embodiments of the present invention, without departing from the spirit and scope of the invention.
10‧‧‧冷卻水塔循環水系統10‧‧‧Cooling tower circulating water system
11‧‧‧冷卻水塔11‧‧‧Cooling tower
111‧‧‧水塔入口111‧‧‧Water Tower Entrance
112‧‧‧通風部112‧‧‧ Ventilation Department
113‧‧‧儲水部113‧‧‧Water Storage Department
114‧‧‧水塔出口114‧‧‧Water tower exit
12‧‧‧冷卻水管路12‧‧‧Cooling water line
13‧‧‧散熱部13‧‧‧ Department of heat dissipation
14‧‧‧加壓裝置14‧‧‧ Pressurizing device
20‧‧‧電解水生成部20‧‧‧Electrolysis Water Generation Department
21‧‧‧電源裝置21‧‧‧Power supply unit
211‧‧‧正極211‧‧‧ positive
212‧‧‧負極212‧‧‧negative
22‧‧‧電解水反應器22‧‧‧ Electrolytic water reactor
221‧‧‧第一區221‧‧‧First District
222‧‧‧第二區222‧‧‧Second District
23‧‧‧隔膜23‧‧‧Separator
24‧‧‧陽極24‧‧‧Anode
25‧‧‧陰極25‧‧‧ cathode
26‧‧‧鹼性水供應部26‧‧‧Alkaline Water Supply Department
261‧‧‧供應管路261‧‧‧Supply pipeline
262‧‧‧供電器262‧‧‧Power supply
263‧‧‧第一網狀電極263‧‧‧First mesh electrode
26A‧‧‧正極部26A‧‧‧ positive part
26B‧‧‧負極部26B‧‧‧Negative part
26C‧‧‧閥26C‧‧‧ valve
30‧‧‧中央系統30‧‧‧Central System
31‧‧‧管中pH值感知器31‧‧‧In-tube pH sensor
311‧‧‧pH值訊號311‧‧‧pH signal
32‧‧‧電壓調整部32‧‧‧Voltage adjustment department
33‧‧‧控制部33‧‧‧Control Department
91‧‧‧水液91‧‧‧Water
92‧‧‧工作液92‧‧‧ working fluid
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007263533A (en) * | 2006-03-30 | 2007-10-11 | Miura Co Ltd | Operating method for cooling tower |
CN201201909Y (en) * | 2008-03-05 | 2009-03-04 | 保定威加利能科技开发有限公司 | Boiler feed water processing unit capable of optimizing water quality |
TWM458406U (en) * | 2013-01-10 | 2013-08-01 | Qing-Yuan Ye | Improved diaphragm of electrolytic tank |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007263533A (en) * | 2006-03-30 | 2007-10-11 | Miura Co Ltd | Operating method for cooling tower |
CN201201909Y (en) * | 2008-03-05 | 2009-03-04 | 保定威加利能科技开发有限公司 | Boiler feed water processing unit capable of optimizing water quality |
TWM458406U (en) * | 2013-01-10 | 2013-08-01 | Qing-Yuan Ye | Improved diaphragm of electrolytic tank |
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