TWI498289B - A forming die for glass forming, a glass forming apparatus, a glass forming method, and a manufacturing method of a mask substrate - Google Patents

A forming die for glass forming, a glass forming apparatus, a glass forming method, and a manufacturing method of a mask substrate Download PDF

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TWI498289B
TWI498289B TW100133680A TW100133680A TWI498289B TW I498289 B TWI498289 B TW I498289B TW 100133680 A TW100133680 A TW 100133680A TW 100133680 A TW100133680 A TW 100133680A TW I498289 B TWI498289 B TW I498289B
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glass
molding die
platen
glass forming
ingot
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TW100133680A
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Chinese (zh)
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TW201217279A (en
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中野史康
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尼康股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B11/00Pressing molten glass or performed glass reheated to equivalent low viscosity without blowing
    • C03B11/06Construction of plunger or mould
    • C03B11/08Construction of plunger or mould for making solid articles, e.g. lenses
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B20/00Processes specially adapted for the production of quartz or fused silica articles, not otherwise provided for
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2201/00Type of glass produced
    • C03B2201/02Pure silica glass, e.g. pure fused quartz
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2215/00Press-moulding glass
    • C03B2215/02Press-mould materials
    • C03B2215/05Press-mould die materials
    • C03B2215/07Ceramic or cermets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B2215/00Press-moulding glass
    • C03B2215/72Barrel presses or equivalent, e.g. of the ring mould type

Description

玻璃成形用之成形模具、玻璃成形裝置、玻璃成形方法及光罩基板之製造方法Mold for glass forming, glass forming device, glass forming method, and method for manufacturing photomask substrate

本發明係關於一種玻璃成形用之成形模具、玻璃成形裝置、玻璃成形方法及光罩基板之製造方法。The present invention relates to a molding die for glass forming, a glass forming device, a glass forming method, and a method of producing a photomask substrate.

本申請根據2010年9月21日申請之日本特願2010-210686號主張優先權,並將其內容援引於此。Priority is claimed on Japanese Patent Application No. 2010-210686, filed on Sep. 21, 2010, the content of which is incorporated herein.

近年來,為了獲得大型之透鏡或標線片、或大型之液晶顯示器等具有廣面積之面之光學構件,利用藉由將預先形成之玻璃錠等玻璃塊加熱加壓成形使其成為扁平形狀而擴大面積之成形方法(例如,參照專利文獻1)。In recent years, in order to obtain an optical member having a wide area such as a large lens or a reticle or a large liquid crystal display, a glass block such as a glass ingot formed in advance is formed into a flat shape by heat and pressure molding. A method of forming an enlarged area (for example, refer to Patent Document 1).

專利文獻1:日本特開2004-307265號公報Patent Document 1: Japanese Laid-Open Patent Publication No. 2004-307265

此處,將上述玻璃塊加熱加壓成形之情形,在使用成行模具在高溫下將玻璃塊加壓成形後,進行該玻璃塊之冷卻,接著取出至爐外。此冷卻時,在玻璃與成形模具之間產生溫度下降所伴隨之收縮量之差。亦即,使用線膨脹係數較成形對象即玻璃大之成形模具之情形,在冷卻時產生玻璃及成形模具之收縮時,因線膨脹係數之差外部之成形模具之收縮量較內部之玻璃大。其結果,施加過度之應力,產生成形模具破損或玻璃破損之現象。Here, in the case where the glass block is subjected to heat and pressure molding, after the glass block is press-formed at a high temperature using a row die, the glass block is cooled and then taken out of the furnace. At the time of this cooling, the difference in the amount of shrinkage accompanying the temperature drop occurs between the glass and the forming mold. In other words, in the case of using a molding die having a linear expansion coefficient larger than that of the glass to be molded, when the glass and the molding die are shrunk during cooling, the amount of shrinkage of the molding die outside the difference in linear expansion coefficient is larger than that of the inner glass. As a result, excessive stress is applied, and the molding die is broken or the glass is broken.

此外,作為防止此等破損之方法,由於成形模具之尺寸愈大從高溫時之收縮量愈大,因此有將助長該收縮量之間隙設在模具側之方法。然而,由於在成形模具設置間隙,因此會有在成形中成為黏性體之玻璃進入間隙而無法獲得必要形狀之情形。或者會有產生玻璃進入成形模具之連結部間隙使成形模具破損、或誘使成形模具破損等問題之情形。Further, as a method of preventing such damage, the larger the size of the molding die, the larger the amount of shrinkage from a high temperature, and therefore there is a method of providing a gap for promoting the amount of shrinkage on the side of the mold. However, since a gap is provided in the molding die, there is a case where the glass which becomes a viscous body enters the gap during molding, and the necessary shape cannot be obtained. Alternatively, there may be a problem that the gap between the glass and the joint portion of the forming mold is broken to cause the forming mold to be broken or the forming mold to be damaged.

本發明之形態之目的在於提供一種可避免玻璃或成形模具本體之破損並將玻璃成形為所欲形狀之成形模具、玻璃成形裝置、玻璃成形方法及光罩基板之製造方法。It is an object of the present invention to provide a molding die, a glass forming apparatus, a glass forming method, and a method of manufacturing a mask substrate which can prevent breakage of glass or a molding die body and shape the glass into a desired shape.

本發明第1形態之玻璃成形用之成形模具,具備:模具本體,用於玻璃之加熱加壓成形;以及支承構件,配置成可抵接該模具本體之可動構件,為了開放以該模具本體與該玻璃之間之線膨脹係數之差為依據之應力而可破壞。A molding die for glass molding according to a first aspect of the present invention includes: a mold main body for heating and press molding of glass; and a support member disposed so as to be movable against a movable member of the mold main body, and the mold main body is opened for opening The difference in linear expansion coefficient between the glasses is destructible based on the stress.

本發明第2形態之玻璃成形用之成形模具,係構成為具有收容玻璃錠之中空部,以台板、配置在其上之側板、及可在該側板彼此之內側上下動之頂板包圍該中空部,其特徵在於:在該台板以抵接該側板之外側之方式配置有支承構件,該側板係形成為可相對該台板往其外側方向相對移動,且藉由該支承構件從該側板之外側支承;該支承構件具有下述強度:在對收容在該中空部之玻璃錠加熱加壓使其變形時,從該玻璃錠經由該側板負載之載重所產生之剪切力無法破壞之強度;以及在將加熱加壓變形後之該玻璃錠冷卻時,因該成形模具與該玻璃錠之線膨脹係數之差而負載之載重所產生之剪切力可破壞之強度。A molding die for glass molding according to a second aspect of the present invention is configured to have a hollow portion for accommodating a glass ingot, and surround the hollow plate with a platen, a side plate disposed thereon, and a top plate movable up and down inside the side plate a support member configured to abut the outer side of the side plate, the side plate being formed to be relatively movable relative to the platen toward the outer side thereof, and the support member is from the side plate The support member has a strength that, when the glass ingot accommodated in the hollow portion is heated and pressurized to be deformed, the shear force generated from the load of the glass ingot via the side plate cannot be broken. And the strength at which the shear force generated by the load applied by the difference between the linear expansion coefficients of the molding die and the glass ingot can be broken when the glass ingot is heated and pressure-deformed.

又,本發明第3形態之玻璃成形裝置,具有:上述玻璃成形用之成形模具;以及玻璃錠之加熱手段及加壓手段。Moreover, the glass forming apparatus according to the third aspect of the present invention includes the molding die for glass forming, and a heating means and a pressurizing means for the glass ingot.

又,本發明第4形態之玻璃成形方法,係使用上述玻璃成形裝置,其特徵在於:在成形模具收容玻璃錠;藉由加熱手段及加壓手段對該玻璃錠加熱加壓使其變形;在將變形後之該玻璃錠冷卻時,藉由因該成形模具與該玻璃錠之線膨脹係數之差而負載之載重,使側板相對該台板往其外側方向相對移動,藉此剪切力作用於支承構件,與該剪切力對應使該支承構件破壞。Further, in the glass forming method according to the fourth aspect of the present invention, the glass forming apparatus is characterized in that the glass ingot is housed in a molding die, and the glass ingot is heated and pressurized by a heating means and a pressurizing means to be deformed; When the deformed glass ingot is cooled, the load is loaded by the difference between the linear expansion coefficient of the molding die and the glass ingot, and the side plate is relatively moved relative to the platen toward the outer side thereof, whereby the shearing force acts. The support member is broken by the shearing force in response to the shearing force.

又,本發明第5形態之光罩基板之製造方法,具有使用上述玻璃成形方法獲得玻璃成形體之步驟。Moreover, the method for producing a photomask substrate according to a fifth aspect of the present invention includes the step of obtaining a glass molded body by the glass forming method.

根據本發明之形態之成形模具,可避免玻璃或成形模具本體之破損並將玻璃成形為所欲形狀。According to the molding die of the embodiment of the present invention, the glass or the molding die body can be prevented from being damaged and the glass can be formed into a desired shape.

以下,說明本發明實施形態之例。Hereinafter, an example of an embodiment of the present invention will be described.

圖1係顯示本實施形態之玻璃成形裝置的剖面圖。圖2係顯示圖1之玻璃成形裝置之玻璃成形用之成形模具的俯視圖。圖3係圖2的A-A剖面圖。圖4係顯示圖3之玻璃成形用之成形模具中使玻璃錠變形之狀態的剖面圖。圖5係顯示圖4之玻璃成形用之成形模具中銷彎折後之狀態的剖面圖。圖6~圖9係顯示玻璃成形用之成形模具之另一例的立體圖。Fig. 1 is a cross-sectional view showing the glass forming apparatus of the embodiment. Fig. 2 is a plan view showing a molding die for glass forming of the glass forming apparatus of Fig. 1. Figure 3 is a cross-sectional view taken along line A-A of Figure 2; Fig. 4 is a cross-sectional view showing a state in which a glass ingot is deformed in a molding die for molding a glass of Fig. 3; Fig. 5 is a cross-sectional view showing a state in which a pin is bent in a molding die for molding a glass of Fig. 4; 6 to 9 are perspective views showing another example of a molding die for glass forming.

本實施形態之玻璃成形裝置1係從以矽化合物為原料製造之合成石英玻璃之錠使半導體用光罩等之光罩基板或液晶用光罩、光學用之大型透鏡材料等加熱成形成所欲形狀之裝置。The glass forming apparatus 1 of the present embodiment is formed by heating a mask substrate such as a semiconductor mask, a liquid crystal mask, or a large lens material for optics, from a composite quartz glass ingot made of a ruthenium compound. Shape device.

此玻璃成形裝置1,如圖1所示,在金屬製之真空室2之內壁具有遍布整面設置之隔熱材3與配置於該隔熱材3之壁之碳加熱器(加熱手段)5。在真空室2內部之中央部設置有碳石墨製之玻璃成形用之成形模具10(以下,稱為成形模具10),在其上部具有汽缸(加壓手段)4。As shown in FIG. 1, the glass forming apparatus 1 has a heat insulating material 3 provided over the entire surface and a carbon heater (heating means) disposed on the wall of the heat insulating material 3 on the inner wall of the vacuum chamber 2 made of metal. 5. A molding die 10 for forming a glass made of carbon graphite (hereinafter referred to as a molding die 10) is provided at a central portion of the inside of the vacuum chamber 2, and a cylinder (pressurizing means) 4 is provided at an upper portion thereof.

成形模具10在玻璃成形裝置1之真空室2內部配置在台座6之上,如圖2~圖5所示,具有具備台板14及底板17之底部。包含此台板14及底板17之成形模具10(模具本體)如上述為碳石墨製,為線膨脹係數較玻璃錠20A大之材質。具體而言,合成石英玻璃之線膨脹係數為5×10-7 /℃程度,碳石墨之線膨脹係數為2~5×10-6 /℃程度。The molding die 10 is placed on the pedestal 6 inside the vacuum chamber 2 of the glass forming apparatus 1, and has a bottom portion including the platen 14 and the bottom plate 17, as shown in Figs. 2 to 5 . The molding die 10 (mold main body) including the platen 14 and the bottom plate 17 is made of carbon graphite as described above, and has a material having a linear expansion coefficient larger than that of the glass ingot 20A. Specifically, the linear expansion coefficient of the synthetic quartz glass is about 5 × 10 -7 / ° C, and the linear expansion coefficient of the carbon graphite is about 2 to 5 × 10 -6 / ° C.

又,成形模具10(模具本體)係構成為具有收容玻璃錠20A之中空部19,以台板14及底板17、配置在其上之側板11、及可在該側板11彼此之內側上下動之頂板13包圍該中空部19。詳細言之,在成形模具10(模具本體)設置有形成為可相對台板14相對移動之側板11(可動構件)。與該側板11以螺栓等固定之側板導件12將直接加壓成形對象即玻璃錠20A之頂板13之自由(移動)限制在上下方向。此外,本實施形態中,如圖2所示,在台板14設有軌道18,在該軌道18載置有側板11。使側板11可相對台板14往該軌道18之方向(亦即,側板11之外側方向)移動。Further, the molding die 10 (mold main body) is configured to have a hollow portion 19 for accommodating the glass ingot 20A, and the table 14 and the bottom plate 17, the side plates 11 disposed thereon, and the upper side of the side plates 11 can be moved up and down The top plate 13 surrounds the hollow portion 19. In detail, the molding die 10 (mold body) is provided with a side plate 11 (movable member) formed to be relatively movable with respect to the platen 14. The side plate guide 12 fixed to the side plate 11 by bolts or the like restricts the freedom (movement) of the top plate 13 of the glass ingot 20A which is a direct pressure forming target in the vertical direction. Further, in the present embodiment, as shown in FIG. 2, a rail 18 is provided on the platen 14, and the side plate 11 is placed on the rail 18. The side plates 11 are movable relative to the platen 14 in the direction of the rails 18 (i.e., the outer side of the side panels 11).

又,在台板14之側板11之外側,以抵接該側板11之方式配置有銷(支承構件)15。此外,此銷15從外側支承且限制側板11。尤其是,本實施形態中,如圖2所示,在台板14沿著抵接側板11之外側之位置形成有複數個插入孔16。銷15可插脫於該複數個插入孔16。再者,本實施形態中,銷15係分別相對配置成俯視大致方形狀之成形模具10之4個側壁11配置複數個。此處,在各側板11分別配置2個銷15。Further, on the outer side of the side plate 11 of the platen 14, a pin (support member) 15 is disposed to abut against the side plate 11. Further, this pin 15 is supported from the outside and restricts the side plate 11. In particular, in the present embodiment, as shown in FIG. 2, a plurality of insertion holes 16 are formed in the platen 14 at a position on the outer side of the abutting side plate 11. The pin 15 can be inserted into the plurality of insertion holes 16. Further, in the present embodiment, the pin 15 is disposed in plural numbers on the four side walls 11 of the molding die 10 which are arranged in a substantially square shape in plan view. Here, two pins 15 are disposed on each of the side plates 11 .

又,銷15係相同種類配置複數個亦可。或者,銷15係依據必要強度等組合配置不同材質或形狀、直徑者亦可。複數個插入孔16係構成為所有插入孔16可對應不同形狀或直徑(例如,孔之直徑構成為從表面側階段性變小等)亦可。或者,複數個插入孔16係構成為可插入之形狀或直徑彼此不同亦可。或者,使在各側板11配置之銷15之數量變化亦可(亦即,在某個側板11與另一個側板11之間銷15之數量不同亦可)。Further, the pin 15 may be arranged in a plurality of the same type. Alternatively, the pin 15 may be configured by a combination of different materials, shapes, and diameters depending on the required strength. The plurality of insertion holes 16 are configured such that all of the insertion holes 16 can correspond to different shapes or diameters (for example, the diameter of the holes is configured to be gradually reduced from the surface side). Alternatively, the plurality of insertion holes 16 may be formed into an insertable shape or a diameter different from each other. Alternatively, the number of the pins 15 disposed on the side plates 11 may be changed (that is, the number of the pins 15 may be different between one of the side plates 11 and the other side plate 11).

銷15具有下述強度:在對收容在中空部19之玻璃錠20A加熱加壓使其變形時,從玻璃錠20A經由側板11負載之載重所產生之剪切力無法破壞之強度;以及在將加熱加壓變形後之玻璃錠20B冷卻時,因成形模具10之線膨脹係數與玻璃錠20A之線膨脹係數之差而負載之載重所產生之剪切力可破壞之強度。此外,本實施形態中,設構成成形模具10之構件之線膨脹係數皆相等。此情形,由於台板14之橫寬最大,因此冷卻時產生之剪切力之大小實質上係藉由台板14與玻璃錠20A之線膨脹係數之差決定。The pin 15 has a strength that when the glass ingot 20A accommodated in the hollow portion 19 is heated and pressurized to be deformed, the shear force generated from the load of the glass ingot 20A via the side plate 11 cannot be broken; and When the glass ingot 20B after the heat and pressure deformation is cooled, the shear force generated by the load applied by the difference between the linear expansion coefficient of the molding die 10 and the linear expansion coefficient of the glass ingot 20A can be broken. Further, in the present embodiment, the members constituting the molding die 10 have the same linear expansion coefficients. In this case, since the width of the platen 14 is the largest, the magnitude of the shear force generated upon cooling is substantially determined by the difference in linear expansion coefficients between the platen 14 and the glass ingot 20A.

亦即,銷15具有在對收容在中空部19之玻璃錠20A加熱加壓使其變形時,從變形之玻璃錠20A對側板11作用之壓力無法破壞可承受之強度。在將變形後之玻璃錠20B冷卻時,由於碳石墨製之成形模具10之台板14之線膨脹係數較該玻璃錠20B大,因此台板14之橫方向之收縮量較大。其結果,產生收縮量較小之玻璃錠20B將配置在收縮量較大之台板14上之側板11向外側相對擠壓之載重。銷15具有此時負載之載重所產生之剪切力可彎折之強度。藉由玻璃錠20B冷卻時與成形模具10之台板14之線膨脹係數之差負載載重,藉由該載重產生之剪切力使銷15彎折。其結果,可防止該玻璃或成形模具10破損。In other words, when the pin 15 has a heating and pressurizing deformation of the glass ingot 20A accommodated in the hollow portion 19, the pressure acting on the side plate 11 from the deformed glass ingot 20A cannot be broken and the strength can be withstood. When the glass ingot 20B after the deformation is cooled, since the linear expansion coefficient of the platen 14 of the carbon graphite-made molding die 10 is larger than that of the glass ingot 20B, the amount of shrinkage of the platen 14 in the lateral direction is large. As a result, the glass ingot 20B having a small amount of shrinkage is caused to load the side plate 11 disposed on the platen 14 having a large amount of contraction to the outside. The pin 15 has the strength at which the shear force generated by the load of the load can be bent. The load is loaded by the difference in linear expansion coefficient between the glass ingot 20B and the platen 14 of the forming mold 10, and the pin 15 is bent by the shear force generated by the load. As a result, the glass or the molding die 10 can be prevented from being damaged.

又,在玻璃成形裝置1之上部,如上述,設置有直接加壓頂板13之汽缸(加壓手段)4。藉由此汽缸4將玻璃錠20A加壓成形至任意之厚度為止。Further, in the upper portion of the glass forming apparatus 1, as described above, a cylinder (pressurizing means) 4 for directly pressing the top plate 13 is provided. The glass ingot 20A is pressure-molded by the cylinder 4 to an arbitrary thickness.

接著,說明此成形模具10及具備此成形模具10之玻璃成形裝置1進行之玻璃成形方法及光罩基板之製造方法。Next, a glass forming method and a method of manufacturing a mask substrate by the molding die 10 and the glass forming apparatus 1 including the molding die 10 will be described.

首先,如圖1及圖3所示,在玻璃成形裝置1之真空室2內部之台座6上組合配置台板14、底板17、側板11、側板導件12。接著,將既定銷15(此處,在每1個側板11配置2個銷15)插入至形成在台板14之插入孔16。藉此,形成安裝成以銷15從外側支承側板11之狀態之成形模具10。又,對該成形模具10將玻璃錠20A配置在成形模具10之中空部19,在其上部配置頂板13,接著使汽缸4抵接頂板13之上面。First, as shown in FIGS. 1 and 3, the platen 14, the bottom plate 17, the side plates 11, and the side plate guides 12 are arranged in combination on the pedestal 6 inside the vacuum chamber 2 of the glass forming apparatus 1. Next, the predetermined pin 15 (here, two pins 15 are disposed on each of the side plates 11) is inserted into the insertion hole 16 formed in the platen 14. Thereby, the molding die 10 mounted in a state in which the side plates 11 are supported from the outside by the pins 15 is formed. Further, in the molding die 10, the glass ingot 20A is placed in the hollow portion 19 of the molding die 10, the top plate 13 is placed on the upper portion, and then the cylinder 4 is brought into contact with the upper surface of the top plate 13.

接著,進行以上述方式安裝後之玻璃成形裝置1之真空室2內部之排氣後,以惰性氣體填充真空室2內部。接著,藉由碳加熱器5加熱成形模具10之中空部19內之玻璃錠20A,升溫至結晶化溫度以上軟化點以下。此時,以一定溫度保持至玻璃錠20A之內部成為均勻之溫度為止亦可。Next, after the inside of the vacuum chamber 2 of the glass forming apparatus 1 mounted as described above is exhausted, the inside of the vacuum chamber 2 is filled with an inert gas. Next, the glass ingot 20A in the hollow portion 19 of the molding die 10 is heated by the carbon heater 5, and the temperature is raised to a temperature equal to or higher than the crystallization temperature and the softening point. At this time, it may be maintained at a constant temperature until the inside of the glass ingot 20A becomes a uniform temperature.

到達既定溫度後,使汽缸4作動以使頂板13往下方移動,將玻璃錠20A加壓成形。此外,在此加壓成形開始時點,成形模具10顯示以環境溫度為準之膨脹。又,隨著玻璃錠20A之加壓程序之進行,玻璃錠20A逐漸成為扁平形狀,成為實質上無間隙地密合於側板11之狀態。After reaching a predetermined temperature, the cylinder 4 is actuated to move the top plate 13 downward, and the glass ingot 20A is press-formed. Further, at the point of the start of the press forming, the forming mold 10 exhibits expansion in accordance with the ambient temperature. In addition, as the pressurization procedure of the glass ingot 20A progresses, the glass ingot 20A gradually becomes a flat shape, and is in a state of being in close contact with the side plate 11 substantially without a gap.

隨著藉由頂板13將玻璃錠20A加壓,頂板13之按壓力經由玻璃錠20A在側板11作用為外周方向(外方向)之應力。由於側板11被銷15限制往外方向移動之自由,因此移動不易。此時,因玻璃成形產生之應力,經由玻璃錠20A及側板11傳至銷15。此處,因上述應力使銷15彎折之情形,側板11之限制解除且同時因從玻璃錠20A承受之力往玻璃錠20A流動之外周方向移動。其結果,玻璃錠20A往側板11包圍之區域外流出,成為無法獲得仿效側板11之內側面之形狀。因此,銷15必須要能抵抗因玻璃成形產生之應力之強度,構成為有此強度。As the glass ingot 20A is pressurized by the top plate 13, the pressing force of the top plate 13 acts on the side plate 11 via the glass ingot 20A as a stress in the outer circumferential direction (outer direction). Since the side plate 11 is restricted from being moved outward by the pin 15, the movement is not easy. At this time, the stress due to the glass forming is transmitted to the pin 15 via the glass ingot 20A and the side plate 11. Here, when the pin 15 is bent by the above-described stress, the restriction of the side plate 11 is released, and at the same time, the glass ingot 20A flows in the circumferential direction due to the force received from the glass ingot 20A. As a result, the glass ingot 20A flows out of the area surrounded by the side plate 11, and the shape of the inner side surface of the side panel 11 cannot be obtained. Therefore, the pin 15 must be able to withstand the strength of the stress generated by the glass forming, and is configured to have such strength.

接著,如圖4所示,藉由上述加熱加壓成形將玻璃錠20A加壓至密合於成形模具10之底板17、頂板13及側板11之狀態而成為薄板狀之玻璃錠20B後,進行冷卻步驟。隨著此冷卻,成形模具10與玻璃錠20B顯示以環境溫度為準之收縮。此處,成形模具10相較於玻璃錠20B線膨脹係數較大。再者,成形模具10之中尤其是台板14相較於側板11橫方向之尺寸較大。因此,台板14之收縮量相對於側板11變大,冷卻伴隨之收縮變顯著。是以,相對觀之,隨著冷卻在玻璃錠20B膨脹之方向、亦即在將側板11往外周方向(外方向)擠出之方向產生載重。Then, as shown in FIG. 4, the glass ingot 20A is pressed to the bottom plate 17, the top plate 13, and the side plate 11 of the molding die 10, and the glass ingot 20B is formed into a thin plate shape. Cooling step. With this cooling, the forming mold 10 and the glass ingot 20B show shrinkage in accordance with the ambient temperature. Here, the forming mold 10 has a larger coefficient of linear expansion than the glass ingot 20B. Further, among the forming dies 10, in particular, the platen 14 has a larger dimension in the lateral direction than the side plate 11. Therefore, the contraction amount of the platen 14 becomes larger with respect to the side plate 11, and the shrinkage accompanying the cooling becomes remarkable. Therefore, in the opposite direction, the load is generated in the direction in which the glass ingot 20B is expanded, that is, in the direction in which the side plate 11 is extruded in the outer circumferential direction (outer direction).

側板11承受之載重傳至設置在側板11之外側之銷15。若因從側板11賦予之收縮產生之應力超過銷15之強度限界,則如圖5所示,銷15向外側破壞。接著,與銷15之破壞同時側板11之限制解除,同時側板11往玻璃錠20B流動之外周方向(外方向)移動而開放應力。此時,由於玻璃錠20B因冷卻已固化,因此不會往側板11包圍之區域外流出。之後,降溫至室溫溫度,從真空室2內取出成形模具10,玻璃之成形完成。The load carried by the side panel 11 is transmitted to the pin 15 provided on the outer side of the side panel 11. When the stress caused by the contraction from the side plate 11 exceeds the strength limit of the pin 15, the pin 15 is broken outward as shown in Fig. 5 . Then, the restriction of the side plate 11 is released simultaneously with the destruction of the pin 15, and the side plate 11 is moved in the circumferential direction (outer direction) to the glass ingot 20B to open the stress. At this time, since the glass ingot 20B is solidified by cooling, it does not flow out to the area surrounded by the side plate 11. Thereafter, the temperature was lowered to room temperature, and the molding die 10 was taken out from the vacuum chamber 2, and the formation of the glass was completed.

之後,對使用上述玻璃成形方法獲得之玻璃成形體,適當進行用以加工成既定尺寸之研削加工或裁割加工、用以將端面部作成R形狀之去角加工、用以使用研磨劑等對表面施加精加工之研磨步驟等之加工。其結果,可獲得所欲之光罩基板。Then, the glass molded body obtained by the above-described glass forming method is appropriately subjected to a grinding process or a cutting process for a predetermined size, a cornering process for forming an end face into an R shape, and an abrasive or the like. The surface is subjected to processing such as a grinding step of finishing. As a result, a desired photomask substrate can be obtained.

如上述,根據本實施形態之玻璃成形用之成形模具10、玻璃成形裝置1、玻璃成形方法及光罩基板之製造方法,藉由設置成形後之冷卻所產生之應力可破壞之銷(支承構件)15,不會對成形對象即玻璃施加過多之應力,又,能不使成形對象即玻璃破損地開放應力,又,能將成形對象即玻璃與成形模具10之台板14之線膨脹係數差所產生之應力導致之對成形模具10之負載抑制在最小限,能將玻璃成形為所欲形狀。As described above, according to the molding die 10 for glass molding of the present embodiment, the glass molding apparatus 1, the glass molding method, and the method of manufacturing the photomask substrate, the stress which can be broken by the stress generated by the cooling after forming (support member) (15) The excessive stress is applied to the glass to be formed, and the stress can be opened without breaking the glass, which is the object to be formed, and the linear expansion coefficient of the glass to be formed and the platen 14 of the molding die 10 can be made. The resulting stress causes the load on the forming mold 10 to be suppressed to a minimum, and the glass can be formed into a desired shape.

又,本實施形態中,作為支承構件使用銷15(銷狀構件、棒狀構件),此銷15可插脫於形成在台板14之複數個插入孔16。因此,只要改變配置之銷15之數量或種類即可簡單地改變其強度。例如,本實施形態中,對1個側板配置2個相同種類之銷15。若增加配置之銷之數量,則能提升銷整體之強度(相反地,若減少配置之銷之數量,則能降低銷整體之強度)。又,配置複數個銷時,藉由僅使用複數個直徑粗者、僅使用複數個直徑細者、混合使用直徑粗者與細者、或者混合使用直徑或形狀不同之複數種類者,能使其強度變化。此外,配置複數個銷時,以載重均勻地施加於各銷之方式配置成大致一列抵接側板亦可。又,以載重均勻地施加於各銷之方式將複數個銷僅可能配置成等間隔亦可。追加地及/或替代地能將銷配置成非一列或非等間隔。Further, in the present embodiment, the pin 15 (pin-shaped member, rod-shaped member) is used as the supporting member, and the pin 15 can be inserted into and removed from the plurality of insertion holes 16 formed in the platen 14. Therefore, the strength can be simply changed by changing the number or type of the configured pins 15. For example, in the present embodiment, two pins 15 of the same type are disposed on one side plate. If the number of configured pins is increased, the strength of the pin as a whole can be increased (conversely, if the number of configured pins is reduced, the strength of the pin as a whole can be reduced). Further, when a plurality of pins are arranged, it is possible to use only a plurality of thick diameters, only a plurality of diameters, a mixture of diameters and thinners, or a mixture of plural diameters or shapes. Strength changes. Further, when a plurality of pins are disposed, the load may be uniformly applied to the respective pins so as to be arranged in a substantially one row to abut the side plates. Further, it is also possible to arrange a plurality of pins at equal intervals so that the load is uniformly applied to the respective pins. Additionally and/or alternatively, the pins can be configured to be non-column or non-equal.

又,如上述,本實施形態中,作為支承構件,使用可插脫於形成在台板14之插入孔16之銷15。因此,能使銷15彎折後之處理變簡單。例如,在玻璃成形後,從插入孔16拔出彎折後之銷15,將新的銷15重新插入插入孔16即可。因此,能提升玻璃及光罩基板之製造效率。Further, as described above, in the present embodiment, the pin 15 which can be inserted and removed into the insertion hole 16 formed in the platen 14 is used as the supporting member. Therefore, the process of bending the pin 15 can be simplified. For example, after the glass is formed, the bent pin 15 is pulled out from the insertion hole 16 and the new pin 15 is reinserted into the insertion hole 16. Therefore, the manufacturing efficiency of the glass and the photomask substrate can be improved.

此外,在決定銷之強度時,例如,能預先藉由力學模擬求出施加於側板之載重及產生於銷之剪切力,以成形時之載重所產生之剪切力無法破壞且冷卻時之載重所產生之剪切力可破壞之方式決定銷之強度。若以此方式決定銷所需之強度,則能從預先測定強度之各種銷之內選擇具有所需強度者來使用。Further, when determining the strength of the pin, for example, the load applied to the side plate and the shear force generated on the pin can be obtained by mechanical simulation in advance, so that the shear force generated by the load at the time of molding cannot be broken and cooled. The strength of the pin can be determined by the way the shear force generated by the load can be broken. If the strength required for the pin is determined in this way, it can be used by selecting a desired strength from among various pins of the pre-measured strength.

此外,以上說明之實施形態係為了容易理解本發明而記載者,並非為了限定本發明而記載。The embodiments described above are described in order to facilitate the understanding of the present invention and are not intended to limit the present invention.

例如,上述實施形態中,作為成形之玻璃舉例石英玻璃,作為成形模具之材質舉例碳(碳石墨)來說明,但本發明並不限於此。例如,作為成形之其他玻璃,可舉出硼矽酸玻璃或碳酸鈉石灰玻璃等。作為成形模具之材質,為氧化鋁等可在高溫使用之其他材質亦可。For example, in the above-described embodiment, quartz glass is exemplified as the glass to be molded, and carbon (carbon graphite) is exemplified as the material of the molding die. However, the present invention is not limited thereto. For example, as another glass to be molded, borosilicate glass, soda lime glass, or the like can be given. The material of the molding die may be other materials such as alumina which can be used at a high temperature.

此處,在選擇玻璃與成形模具之材質時,考慮玻璃之組成或成形條件等來決定即可。玻璃之線膨脹係數只要為較成形模具(尤其是台板)之材質之線膨脹係數小(破壞支承構件能發揮本發明之成形模具之功能之條件)之組合即可獲得本實施形態之效果。然而,作為成形模具(模具本體)之材質,由於碳較氧化鋁強度、耐熱衝擊性優異,因此以使用碳較佳之情形較多。Here, when selecting the material of the glass and the molding die, it may be determined in consideration of the composition of the glass, the molding conditions, and the like. The effect of the present embodiment can be obtained by a combination of a linear expansion coefficient of the glass which is smaller than a linear expansion coefficient of a material of a molding die (especially a platen) and a condition that the supporting member can exhibit the function of the molding die of the present invention. However, as a material of a molding die (mold main body), since carbon is excellent in alumina strength and thermal shock resistance, it is preferable to use carbon.

又,本實施形態中,作為銷15之材料使用碳石墨。作為銷15之材料,使用碳石墨以外之材料亦可,例如,使用氧化鋁等在高溫亦可使用之材料亦可。Further, in the present embodiment, carbon graphite is used as the material of the pin 15. As the material of the pin 15, a material other than carbon graphite may be used. For example, a material which can be used at a high temperature such as alumina may be used.

又,上述實施形態中,作為支承構件使用銷15(銷狀構件、棒狀構件),但本發明並不限於此。只要為具有所需強度以既定載重能破壞之構成之構件,則使用銷15以外亦可。作為銷15以外之支承構件,例如,如圖6所示,可舉出在長板狀構件115a之下方形成有可插脫於形成在台板114之複數個插入孔116之複數個插入構件115b之帶有插入構件之長板狀構件115。在使用此帶有插入構件之長板狀構件115之成形模具,藉由抵接側板111之長板狀構件115a在冷卻時往外周方向(外方向)按壓,該長板狀構件115a與插入構件115b之間之部分可破壞。Further, in the above embodiment, the pin 15 (pin-shaped member or rod-shaped member) is used as the supporting member, but the present invention is not limited thereto. It is also possible to use a pin 15 as long as it is a member having a required strength and capable of being destroyed by a predetermined load. As the supporting member other than the pin 15, for example, as shown in FIG. 6, a plurality of insertion members 115b which are insertable and detached from the plurality of insertion holes 116 formed in the platen 114 are formed below the long plate-shaped member 115a. The long plate member 115 with the insertion member. In the molding die using the long plate member 115 with the insertion member, the long plate member 115a abutting against the side plate 111 is pressed in the outer circumferential direction (outward direction) upon cooling, and the long plate member 115a and the insertion member are pressed. The part between 115b can be destroyed.

又,作為銷15以外之支承構件,可舉出圖7所示之形態。圖7中,替代插入孔16,在台板214中沿著側板211之位置形成有槽216,可插脫於此槽216之薄板狀構件215係使用為支承構件。在使用此薄板狀構件215之成形模具,薄板狀構件215之一部分(抵接部)抵接側板211,此在冷卻時往外周方向(外方向)按壓。又,薄板狀構件215之另一部分(插入部)插入槽216而實質上固定。其結果,薄板狀構件215之抵接部與插入部之間之部分可破壞。Moreover, as a support member other than the pin 15, the form shown in FIG. 7 is mentioned. In Fig. 7, instead of the insertion hole 16, a groove 216 is formed in the platen 214 along the position of the side plate 211, and the thin plate member 215 which can be inserted and removed from the groove 216 is used as a support member. In the molding die using the thin plate-shaped member 215, one portion (abutting portion) of the thin plate-shaped member 215 abuts against the side plate 211, and is pressed in the outer circumferential direction (outward direction) upon cooling. Further, the other portion (insertion portion) of the thin plate-shaped member 215 is inserted into the groove 216 to be substantially fixed. As a result, the portion between the abutting portion of the thin plate-shaped member 215 and the insertion portion can be broken.

又,作為銷15以外之支承構件,可舉出圖8所示之形態。圖8中,大致L字狀構件315為支承構件。一例中,大致L字狀構件315之L字之底邊部分315b以其長邊方向為外周方向(外方向)而固定於台板314。例如,在台板314形成有固定此底邊部分315b之凹陷316。又,側板311抵接L字之上部分315a。亦即,一例中,大致L字狀構件315具有插入設在台板314之凹陷316而實質上固定於台板314之底邊部分315b、與以底邊部分315b之一端為基部並在與底邊部分315b之延伸方向正交之方向延伸之上部分315a,上部分315a之一面抵接側板311。在使用此大致L字狀構件315之成形模具,藉由在冷卻時側板311按壓該大致L字狀構件315之上部分315a,L字之上部分315a與底邊部分315b之間之部分可破壞。Moreover, as a support member other than the pin 15, the form shown in FIG. 8 is mentioned. In Fig. 8, the substantially L-shaped member 315 is a supporting member. In one example, the L-shaped bottom side portion 315b of the substantially L-shaped member 315 is fixed to the platen 314 with the longitudinal direction thereof being the outer circumferential direction (outer direction). For example, a recess 316 is formed in the platen 314 to fix the bottom edge portion 315b. Further, the side plate 311 abuts against the L-shaped upper portion 315a. That is, in one example, the substantially L-shaped member 315 has a recess 316 which is inserted into the platen 314 and is substantially fixed to the bottom edge portion 315b of the platen 314, and one end of the bottom edge portion 315b is the base portion and the bottom portion. The upper portion 315a extends in a direction in which the extending direction of the side portion 315b is orthogonal, and one of the upper portions 315a abuts against the side plate 311. In the molding die using the substantially L-shaped member 315, by pressing the upper portion 311a of the substantially L-shaped member 315 at the time of cooling, the portion between the upper portion 315a and the bottom portion 315b of the L-shape can be broken. .

又,作為銷15以外之支承構件,可舉出圖9所示之形態。圖9中,大致L字狀長板狀構件415為支承構件,該大致L字狀長板狀構件415之L字之底邊部分415b固定於台板414。例如,在台板414形成有固定此底邊部分415b之凹陷416。又,側板411抵接L字之上部分415a。亦即,一例中,大致L字狀長板狀構件415具有插入設在台板414之凹陷416而實質上固定於台板414之底邊部分415b。底邊部分415b具有沿著側板411延伸之長邊。又,大致L字狀長板狀構件415具有以底邊部分415b之一長邊為基部並延伸之上部分415a,上部分415a之一面抵接側板411。底邊部分415b與上部分415a之間之角度為例如90°。在使用此大致L字狀長板狀構件415之成形模具,藉由在冷卻時側板411按壓該大致L字狀長板狀構件415之上部分415a,上部分415a與底邊部分415b之間之部分可破壞。Moreover, as a support member other than the pin 15, the form shown in FIG. 9 is mentioned. In FIG. 9, the substantially L-shaped long plate-shaped member 415 is a support member, and the L-shaped bottom side portion 415b of the substantially L-shaped long plate-shaped member 415 is fixed to the platen 414. For example, a recess 416 is formed in the platen 414 to fix the bottom edge portion 415b. Further, the side plate 411 abuts against the L-shaped upper portion 415a. That is, in an example, the substantially L-shaped long plate-shaped member 415 has a recess 416 inserted in the platen 414 and is substantially fixed to the bottom side portion 415b of the platen 414. The bottom edge portion 415b has a long side that extends along the side plate 411. Further, the substantially L-shaped long plate-shaped member 415 has a portion 415a extending from one of the long sides of the bottom portion 415b, and one of the upper portions 415a abuts against the side plate 411. The angle between the bottom edge portion 415b and the upper portion 415a is, for example, 90°. In the molding die using the substantially L-shaped long plate-like member 415, the upper portion 415a and the bottom portion 415b are pressed between the upper portion 415a and the bottom portion 415b by pressing the upper L-shaped long plate-like member 415 at the time of cooling. Part can be destroyed.

此外,本實施形態中,雖說明以結晶化溫度以上軟化點溫度以下之溫度使玻璃錠20A成形之例,但並不限於此。成形溫度只要為玻璃錠20A之結晶化溫度以上即可。例如,以較玻璃錠20A之軟化點高之溫度成形亦可。In the present embodiment, the glass ingot 20A is molded at a temperature equal to or lower than the crystallization temperature and the softening point temperature, but the invention is not limited thereto. The molding temperature may be at least the crystallization temperature of the glass ingot 20A. For example, it may be formed at a temperature higher than the softening point of the glass ingot 20A.

1...玻璃成形裝置1. . . Glass forming device

2...真空室2. . . Vacuum chamber

3...隔熱材3. . . Insulation material

4...汽缸(加壓手段)4. . . Cylinder (pressure means)

5...碳加熱器(加熱手段)5. . . Carbon heater (heating means)

6...台座6. . . Pedestal

10...玻璃成形用之成形模具10. . . Forming mold for glass forming

11,111,211,311,411...側板11,111,211,311,411. . . Side panel

12...側板導件12. . . Side plate guide

13...頂板13. . . roof

14,114,214,314,414...台板14,114,214,314,414. . . Platen

15...銷(支承構件)15. . . Pin (support member)

115...帶有插入構件之長板狀構件(支承構件)115. . . Long plate member (support member) with insert member

215...薄板狀構件(支承構件)215. . . Thin plate member (support member)

315...大致L字狀棒狀構件(支承構件)315. . . R-shaped rod-shaped member (support member)

415...大致L字狀長板構件(支承構件)415. . . R-shaped long plate member (support member)

16,116...插入孔16,116. . . Insertion hole

216...槽216. . . groove

316,416...凹陷316,416. . . Depression

17...底板17. . . Bottom plate

18...軌道18. . . track

20A,20B...玻璃錠20A, 20B. . . Glass ingot

圖1係顯示本實施形態之玻璃成形裝置的剖面圖。Fig. 1 is a cross-sectional view showing the glass forming apparatus of the embodiment.

圖2係顯示圖1之玻璃成形裝置之玻璃成形用之成形模具的俯視圖。Fig. 2 is a plan view showing a molding die for glass forming of the glass forming apparatus of Fig. 1.

圖3係圖2的A-A剖面圖。Figure 3 is a cross-sectional view taken along line A-A of Figure 2;

圖4係顯示圖3之玻璃成形用之成形模具中使玻璃錠變形之狀態的剖面圖。Fig. 4 is a cross-sectional view showing a state in which a glass ingot is deformed in a molding die for molding a glass of Fig. 3;

圖5係顯示圖4之玻璃成形用之成形模具中銷彎折後之狀態的剖面圖。Fig. 5 is a cross-sectional view showing a state in which a pin is bent in a molding die for molding a glass of Fig. 4;

圖6係顯示玻璃成形用之成形模具之另一例的立體圖。Fig. 6 is a perspective view showing another example of a molding die for glass forming.

圖7係顯示玻璃成形用之成形模具之另一例的立體圖。Fig. 7 is a perspective view showing another example of a molding die for glass forming.

圖8係顯示玻璃成形用之成形模具之另一例的立體圖。Fig. 8 is a perspective view showing another example of a molding die for glass forming.

圖9係顯示玻璃成形用之成形模具之另一例的立體圖。Fig. 9 is a perspective view showing another example of a molding die for glass forming.

1...玻璃成形裝置1. . . Glass forming device

2...真空室2. . . Vacuum chamber

3...隔熱材3. . . Insulation material

4...汽缸(加壓手段)4. . . Cylinder (pressure means)

5...碳加熱器(加熱手段)5. . . Carbon heater (heating means)

6...台座6. . . Pedestal

10...玻璃成形用之成形模具10. . . Forming mold for glass forming

11...側板11. . . Side panel

12...側板導件12. . . Side plate guide

13...頂板13. . . roof

14...台板14. . . Platen

15...銷(支承構件)15. . . Pin (support member)

17...底板17. . . Bottom plate

19...中空部19. . . Hollow part

20A...玻璃錠20A. . . Glass ingot

Claims (12)

一種玻璃成形用之成形模具,具備:模具本體,用於玻璃之加熱加壓成形;以及支承構件,配置成可抵接該模具本體之可動構件,為了開放以該模具本體與該玻璃之間之線膨脹係數之差為依據之應力而可破壞。 A molding die for glass forming, comprising: a mold body for heat and pressure forming of glass; and a support member disposed to abut against a movable member of the mold body, for opening between the mold body and the glass The difference in coefficient of linear expansion is destructible based on the stress. 如申請專利範圍第1項之玻璃成形用之成形模具,其中,該模具本體具有該支承構件之一部分可插入之複數個孔及/或複數個槽。 A molding die for glass forming according to the first aspect of the invention, wherein the die body has a plurality of holes and/or a plurality of grooves into which one of the support members can be inserted. 如申請專利範圍第1或2項之玻璃成形用之成形模具,其中,該支承構件具有在加熱加壓步驟經由該可動構件負載之載重所產生之剪切力無法破壞之強度,且具有在冷卻步驟因該模具本體與該玻璃之間之線膨脹係數之差而負載之載重所產生之剪切力可破壞之強度。 The molding die for glass forming according to the first or second aspect of the invention, wherein the support member has a strength that cannot be broken by a shearing force generated by a load carried by the movable member in a heating and pressurizing step, and has a cooling property. The shearing force generated by the load carried by the load due to the difference in linear expansion coefficient between the mold body and the glass may destroy the strength. 如申請專利範圍第1或2項之玻璃成形用之成形模具,其中,該支承構件之材質包含碳。 A molding die for glass forming according to claim 1 or 2, wherein the material of the support member contains carbon. 如申請專利範圍第1或2項之玻璃成形用之成形模具,其中,該模具本體,具有:台板;可上下動之頂板;以及作為該可動構件之側板,係配置在該台板上,可相對該台板相對移動。 The molding die for glass forming according to claim 1 or 2, wherein the die body has: a platen; a top plate that can be moved up and down; and a side plate as the movable member is disposed on the platen. It can move relative to the platen. 一種玻璃成形用之成形模具,係構成為具有收容玻璃錠之中空部,以台板、配置在其上之側板、及可在該側板 彼此之內側上下動之頂板包圍該中空部,其特徵在於:在該台板以抵接該側板之外側之方式配置有支承構件,該側板係形成為可相對該台板往其外側方向相對移動,且藉由該支承構件從該側板之外側支承;該支承構件具有下述強度:在對收容在該中空部之玻璃錠加熱加壓使其變形時,從該玻璃錠經由該側板負載之載重所產生之剪切力無法破壞之強度;以及在將加熱加壓變形後之該玻璃錠冷卻時,因該成形模具與該玻璃錠之線膨脹係數之差而負載之載重所產生之剪切力可破壞之強度。 A molding die for glass forming is configured to have a hollow portion for accommodating a glass ingot, a platen, a side plate disposed thereon, and a side plate The top plate that moves up and down on the inner side surrounds the hollow portion, and is characterized in that a support member is disposed on the outer side of the platen to abut the outer side of the side plate, and the side plate is formed to be relatively movable relative to the platen toward the outer side thereof And supporting the outer side of the side plate by the supporting member; the supporting member has a strength to load the glass ingot from the glass ingot when the glass ingot accommodated in the hollow portion is heated and pressurized to be deformed The strength at which the shear force generated cannot be broken; and the shear force generated by the load carried by the difference between the linear expansion coefficients of the forming mold and the glass ingot after cooling the glass ingot after heating and pressurizing deformation Destructible strength. 如申請專利範圍第6項之玻璃成形用之成形模具,其中,在該台板沿著抵接該側板之外側之位置形成有複數個插入孔;該支承構件係以可插脫於該複數個插入孔之銷構成。 The molding die for glass forming according to claim 6, wherein a plurality of insertion holes are formed in the platen at a position abutting the outer side of the side plate; the support member is detachable from the plurality of The pin of the insertion hole is formed. 如申請專利範圍第6或7項之玻璃成形用之成形模具,其中,該玻璃錠為石英玻璃。 A molding die for glass forming according to claim 6 or 7, wherein the glass ingot is quartz glass. 如申請專利範圍第6或7項之玻璃成形用之成形模具,其中,該成形模具係以碳構成。 A molding die for glass forming according to claim 6 or 7, wherein the molding die is made of carbon. 一種玻璃成形裝置,具有:申請專利範圍第1至9項中任一項之玻璃成形用之成形模具;以及玻璃錠之加熱手段及加壓手段。 A glass forming apparatus comprising: a molding die for glass forming according to any one of claims 1 to 9; and a heating means and a pressurizing means for the glass ingot. 一種玻璃成形方法,係使用申請專利範圍第10項之 玻璃成形裝置,其特徵在於:在成形模具收容玻璃錠;藉由加熱手段及加壓手段對該玻璃錠加熱加壓使其變形;在將變形後之該玻璃錠冷卻時,藉由因該成形模具與該玻璃錠之線膨脹係數之差而負載之載重,使側板相對該台板往其外側方向相對移動,藉此剪切力作用於支承構件,與該剪切力對應使該支承構件破壞。 A glass forming method using the tenth item of the patent application scope A glass forming apparatus for accommodating a glass ingot in a molding die; heating and pressurizing the glass ingot by a heating means and a pressurizing means; and deforming the glass ingot after the deformation, by forming the glass ingot The difference between the linear expansion coefficient of the mold and the glass ingot and the load of the load, the side plate is relatively moved relative to the platen toward the outer side thereof, whereby the shearing force acts on the supporting member, and the supporting member is destroyed corresponding to the shearing force . 一種光罩基板之製造方法,具有使用申請專利範圍第11項之玻璃成形方法獲得玻璃成形體之步驟。A method for producing a photomask substrate, comprising the step of obtaining a glass molded body by using the glass forming method of claim 11 of the patent application.
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