TWI493690B - Improved bonding surfaces for direct bonding of semiconductor structures - Google Patents

Improved bonding surfaces for direct bonding of semiconductor structures Download PDF

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TWI493690B
TWI493690B TW101120333A TW101120333A TWI493690B TW I493690 B TWI493690 B TW I493690B TW 101120333 A TW101120333 A TW 101120333A TW 101120333 A TW101120333 A TW 101120333A TW I493690 B TWI493690 B TW I493690B
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semiconductor structure
dielectric material
semiconductor
bonding
component
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TW201308576A (en
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Mariam Sadaka
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Soitec Silicon On Insulator
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/48Arrangements for conducting electric current to or from the solid state body in operation, e.g. leads, terminal arrangements ; Selection of materials therefor
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/11Manufacturing methods

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  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
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Description

半導體構造直接鍵結之改良鍵結表面 Improved bond surface for direct bonding of semiconductor structures

本發明係關於將半導體結構直接鍵結在一起之方法及應用此等方法形成之鍵結半導體結構。 The present invention relates to a method of directly bonding semiconductor structures together and a bonded semiconductor structure formed using such methods.

兩個或更多半導體結構之三度空間集積(3D integration)可替微電子應用帶來許多好處。舉例而言,微電子構件之三度空間集積可以使電氣性能及電力消耗獲得改進,並同時減少元件所佔面積。相關資料可參見諸如P.Garrou等人所編之《The Handbook of 3D Integration》(Wiley-VCH出版,2008年)。 Three-dimensional integration of two or more semiconductor structures can bring many benefits to microelectronic applications. For example, a three-dimensional spatial accumulation of microelectronic components can improve electrical performance and power consumption while reducing component footprint. For related information, see The Handbook of 3D Integration, edited by P. Garrou et al. (Wiley-VCH Publishing, 2008).

半導體結構之三度空間集積可以透過以下方式或該些方式之組合而達到:將一半導體晶粒附著至其他的一個或多個半導體晶粒(亦即晶粒對晶粒(D2D)),將一半導體晶粒附著至一個或多個半導體晶圓(亦即晶粒對晶圓(D2W)),以及將一半導體晶圓附著至其他的一個或多個半導體晶圓(亦即晶圓對晶圓(W2W))。 The three-dimensional spatial accumulation of the semiconductor structure can be achieved by attaching a semiconductor die to other one or more semiconductor dies (ie, die-to-die (D2D)), A semiconductor die is attached to one or more semiconductor wafers (ie, die-to-wafer (D2W)), and a semiconductor wafer is attached to one or more other semiconductor wafers (ie, wafer-to-wafer Round (W2W)).

將一半導體結構鍵結至另一半導體結構所用之鍵結技術可以不同方式分類,一種是按兩個半導體結構間有無一層中間材料將其鍵結在一起而分類,第二種則是按鍵結界面是否允許電子(亦即電流)通過該界面而分類。所謂的「直接鍵結方法」係指在兩個半導體結構間建立直接的固體對固體化學鍵,以使其鍵結在一起而無需在該些半導體結構間使用中介鍵結材料之方法。目前已發展出金屬對金屬之直接鍵結方法,可將一第一半 導體結構中一表面上之金屬材料,鍵結至一第二半導體結構中一表面上之金屬材料。 The bonding technique used to bond a semiconductor structure to another semiconductor structure can be classified in different ways. One is to classify the two semiconductor structures by an intermediate material, and the second is the key interface. Whether electrons (ie, current) are allowed to be classified through the interface. By "direct bonding method" is meant a method of establishing a direct solid-to-solid chemical bond between two semiconductor structures to bond them together without the use of an intervening bonding material between the semiconductor structures. At present, a metal-to-metal direct bonding method has been developed, which can be a first half. A metal material on a surface of the conductor structure is bonded to a metal material on a surface of a second semiconductor structure.

金屬對金屬之直接鍵結方法亦可以按各方法操作時的溫度範圍加以分類。例如,一些金屬對金屬之直接鍵結方法是在相對高溫下進行,因此會造成鍵結界面處之金屬材料至少有部分熔化。此等直接鍵結製程可能不適合用於鍵結含有一個或多個元件結構之已處理半導體結構,因其相對高溫可能對之前形成之元件結構有不利影響。 The metal-to-metal direct bonding method can also be classified according to the temperature range at which each method operates. For example, some metal-to-metal direct bonding methods are performed at relatively high temperatures, thus causing at least partial melting of the metallic material at the bonding interface. Such direct bonding processes may not be suitable for bonding processed semiconductor structures containing one or more component structures, as their relatively high temperatures may adversely affect previously formed component structures.

「熱壓鍵結」方法為在介於攝氏200度(200℃)及大約攝氏500度(500℃)間之高溫下,通常為介於大約攝氏300度(300℃)及大約攝氏400度(400℃)之間,於鍵結表面間施加壓力之直接鍵結方法。 The "hot press bonding" method is at a high temperature between 200 degrees Celsius (200 ° C) and about 500 degrees Celsius (500 ° C), usually between about 300 degrees Celsius (300 ° C) and about 400 degrees Celsius ( A direct bonding method of applying pressure between the bonding surfaces between 400 ° C).

其他直接鍵結方法目前也已發展出來,該些方法可以在攝氏200度(200℃)或更低之溫度下進行。對於在攝氏200度(200℃)或更低溫度下進行之此等直接鍵結製程,本說明書稱為「超低溫」直接鍵結方法。超低溫直接鍵結方法可以經由仔細移除表面雜質及表面化合物(例如原生氧化層),以及經由在原子級尺度上增加兩個表面間緊密接觸之面積而實施。兩個表面間緊密接觸之面積通常經由以下方式達成:研磨該些鍵結表面以降低其表面粗度至接近原子級尺度之數值、於鍵結表面間施加壓力以造成塑性形變、或既研磨鍵結表面又對其施加壓力以達到此種塑性形變。 Other direct bonding methods have also been developed, which can be carried out at temperatures of 200 degrees Celsius (200 ° C) or lower. For such direct bonding processes performed at 200 degrees Celsius (200 ° C) or lower, this specification is referred to as an "ultra-low temperature" direct bonding process. The ultra-low temperature direct bonding process can be carried out by careful removal of surface impurities and surface compounds (eg, native oxide layers), and by increasing the area of intimate contact between the two surfaces on an atomic scale. The area of intimate contact between the two surfaces is typically achieved by grinding the bonding surfaces to reduce the surface roughness to a value close to the atomic scale, applying pressure between the bonding surfaces to cause plastic deformation, or both grinding keys. The surface of the junction is then stressed to achieve such plastic deformation.

一些超低溫直接鍵結方法可以不需在鍵結表面間之鍵結界面施加壓力而實施,但在其他超低溫直接鍵結方法中,為了在鍵結界面獲致合適的鍵結強度,可以在鍵結表面間之鍵結界面施加壓力。在本發明所屬技術領域中,在鍵結表面間施加壓力之超低溫直接鍵結方法通常被稱為「表面輔 助鍵結」或「SAB」方法。因此,在本說明書中「表面輔助鍵結」及「SAB」係指並包括在攝氏200度(200℃)或更低之溫度下,將第一材料緊靠第二材料,並在該些鍵結表面間之鍵結界面施加壓力,以使第一材料直接鍵結至第二材料之任何直接鍵結製程。 Some ultra-low temperature direct bonding methods can be carried out without applying pressure at the bonding interface between the bonding surfaces, but in other ultra-low temperature direct bonding methods, in order to obtain a suitable bonding strength at the bonding interface, the bonding surface can be applied. Pressure is applied to the bonding interface between the two. In the technical field of the present invention, an ultra-low temperature direct bonding method for applying pressure between bonding surfaces is generally referred to as "surface assisting". Help key or "SAB" method. Therefore, in the present specification, "surface auxiliary bonding" and "SAB" mean and include the first material against the second material at a temperature of 200 degrees Celsius (200 ° C) or lower, and at the keys Pressure is applied to the bonding interface between the junction surfaces to directly bond the first material to any direct bonding process of the second material.

在某些情況下,半導體結構中主動導電部件間的金屬對金屬直接鍵結,可能很容易在一段時間後發生機械故障或電氣故障,即便一開始已在該些半導體結構之導電部件間建立了可接受的金屬對金屬直接鍵結時亦然。雖然尚無法完全了解其原因,但據信此種故障可能至少部分是由三個相關機制中的一個或多個所造成。這三個相關機制為應變局部化,其可能由大晶粒所引起、與形變有關之晶粒生長、鍵結界面上之質量傳送。此種鍵結界面上之質量傳送可以至少部分歸因於電遷移、相分離等等。 In some cases, metal-to-metal bonding between active conductive components in a semiconductor structure can easily cause mechanical or electrical failures after a period of time, even if initially established between the conductive features of the semiconductor structures. Acceptable metals are also directly bonded to the metal. Although the cause is not fully understood, it is believed that such failure may be caused, at least in part, by one or more of the three related mechanisms. These three related mechanisms are strain localization, which may be caused by large grains, grain growth associated with deformation, and mass transfer at the bonding interface. Mass transfer at such bonding interfaces can be at least partially attributed to electromigration, phase separation, and the like.

電遷移為導電材料中之金屬原子因電流而造成遷移。改進互連結構之電遷移壽命之各種方法已於本發明所屬技術領域中有所討論。例如J.Gambino等人在2009年IEEE舉辦之Custom Integrated Circuits Conference(CICC)發表了〈Copper Interconnect Technology for the 32nm Node and Beyond〉(頁141-148),當中便討論了改進銅內連結之電磁壽命之方法。 Electromigration is the migration of metal atoms in a conductive material due to electrical current. Various methods of improving the electromigration lifetime of interconnect structures have been discussed in the art to which the present invention pertains. For example, J. Gambino et al. published the "Copper Interconnect Technology for the 32nm Node and Beyond" (Page 141-48) at the Custom Integrated Circuits Conference (CICC) held by IEEE in 2009, which discusses the improvement of the electromagnetic lifetime of copper connections. The method.

圖1A及1B呈現了在直接鍵結方法中可能遭遇到的一個問題。圖1A呈現一半導體結構10,其包含一元件層12,該元件層可以包含多個元件結構,不過這些結構並未顯示於此簡化圖式中。介電材料14則被配置為覆蓋於該元件層12上,且在欲形成諸如導電墊、跡線及通孔等導電組件之位置處,有多個凹槽16伸進該介電材料14。因此,該介電材料14上沉積覆蓋了一層導電金屬18(例如銅或銅合金),這樣,該導電金屬18便 會填滿該些凹槽16。導電金屬18通常會過量沉積,以使該層導電金屬18遍及該介電材料14之主要上表面15,如圖1A所示。 Figures 1A and 1B present a problem that may be encountered in a direct bonding method. 1A presents a semiconductor structure 10 that includes an element layer 12 that may comprise a plurality of element structures, although these structures are not shown in this simplified drawing. Dielectric material 14 is then disposed overlying the device layer 12, and a plurality of recesses 16 extend into the dielectric material 14 at locations where conductive components such as conductive pads, traces, and vias are to be formed. Therefore, the dielectric material 14 is deposited with a layer of conductive metal 18 (such as copper or copper alloy), so that the conductive metal 18 These grooves 16 will be filled. The conductive metal 18 is typically deposited in excess such that the layer of conductive metal 18 extends over the major upper surface 15 of the dielectric material 14, as shown in Figure 1A.

在沉積導電金屬18以形成圖1A所示之半導體結構10後,多餘的導電金屬18會從該介電材料14之主要上表面15移除,以形成圖1B所示之半導體結構20。多餘導電金屬18的移除會定義出元件結構22,其在該些凹槽16中含有該導電金屬18。舉例而言,一化學機械研磨(CMP)製程可以用於將多餘的導電金屬18從該介電材料14之主要上表面15移除,並定義出元件結構22。但是,將多餘導電金屬18從該介電材料14之主要上表面15移除所用之CMP製程,可能會致使該些元件結構22之曝露表面23相對於周圍介電材料14之主要上表面15而凹陷。該些曝露表面23可能具有如圖1B所示之弧線、內凹形狀。在本發明所屬技術領域中,此一現象通常通常稱為「碟形凹陷(dishing)」。此外,將多餘的導電金屬18從該介電材料14之主要上表面15移除所用之CMP製程還可能會在某些位置造成該介電材料14被過度移除,例如相隔很近之該些元件結構22間之位置26,以及該介電材料14之主要上表面15上之隨機位置,像是圖1B所示之該些位置28。在本發明所屬技術領域中,該介電材料14在主要上表面15之基準平面以下被過度移除之情況,通常稱為「磨蝕」。這些碟形凹陷及磨蝕現象可能是因CMP製程不均勻,及/或該層導電金屬18在介電材料14之主要上表面15上之初始厚度不均勻而引起。 After depositing the conductive metal 18 to form the semiconductor structure 10 of FIG. 1A, the excess conductive metal 18 is removed from the major upper surface 15 of the dielectric material 14 to form the semiconductor structure 20 of FIG. 1B. Removal of the excess conductive metal 18 defines an element structure 22 that contains the conductive metal 18 in the grooves 16. For example, a chemical mechanical polishing (CMP) process can be used to remove excess conductive metal 18 from the major upper surface 15 of the dielectric material 14 and define the component structure 22. However, the CMP process used to remove excess conductive metal 18 from the major upper surface 15 of the dielectric material 14 may result in the exposed surface 23 of the component structures 22 being opposite the major upper surface 15 of the surrounding dielectric material 14. Depression. The exposed surfaces 23 may have an arcuate, concave shape as shown in FIG. 1B. In the technical field to which the present invention pertains, this phenomenon is commonly referred to as "dishing". Moreover, the CMP process used to remove excess conductive metal 18 from the major upper surface 15 of the dielectric material 14 may also cause the dielectric material 14 to be excessively removed at certain locations, such as being closely spaced. The location 26 between the component structures 22, and the random locations on the major upper surface 15 of the dielectric material 14, are such locations 28 as shown in FIG. 1B. In the art to which the present invention pertains, the dielectric material 14 is excessively removed below the reference plane of the major upper surface 15, commonly referred to as "abrasive." These dishing and abrasion phenomena may be caused by non-uniform CMP processes and/or uneven initial thickness of the layer of conductive metal 18 on the major upper surface 15 of the dielectric material 14.

該些元件結構22之曝露表面23之碟形凹陷及該介電材料14之主要上表面15之局部磨蝕對於圖1B之半導體結構20與另一半導體結構(未 顯示)兩者間在後續之直接鍵結製程中所建立之鍵結強度及電氣連接而言,可能會造成負面影響。 The dishing of the exposed surface 23 of the component structures 22 and the local abrasion of the major upper surface 15 of the dielectric material 14 are for the semiconductor structure 20 of FIG. 1B and another semiconductor structure (not It can be shown that the bond strength and electrical connection established between the two in the subsequent direct bonding process may have a negative impact.

本概要係為了以簡要形式介紹一系列概念而提供,該些概念將於本發明之實施例中進一步詳述。本概要之用意並非指出本發明所主張專利標的之主要特點或基本特點,亦非用於限制所主張專利標的之範圍。 This summary is provided to introduce a series of concepts in a simplified form, which are further described in the embodiments of the invention. This summary is not intended to identify key features or essential features of the claimed subject matter, and is not intended to limit the scope of the claimed subject matter.

在一些實施例中,本發明包含將一第一半導體結構直接鍵結至一第二半導體結構之方法。提供一第一半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料(譬如一種金屬或一種非金屬導電材料,像是由不同微晶構成之矽,通常稱為「多晶矽」),該介電材料被配置為與該至少一個元件結構相鄰。該至少一個元件結構及該介電材料可以曝露在該第一半導體結構之一鍵結表面上。在該第一半導體結構之鍵結表面上,該介電材料之一曝露表面可以定義出該第一半導體結構之一鍵結平面。該第一半導體結構中該至少一個元件結構可以從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料。提供一第二半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料,該介電材料被配置為與該至少一個元件結構相鄰。該至少一個元件結構及該介電材料可以曝露在該第二半導體結構之一鍵結表面上。在該第二半導體結構之鍵結表面上,該介電材料之一曝露表面可以定義出該第二半導體結構之一鍵結平面。在金屬對金屬之一直接鍵 結製程中,該第一半導體結構中該至少一個元件結構可以直接鍵結至該第二半導體結構中該至少一個元件結構。 In some embodiments, the invention includes a method of directly bonding a first semiconductor structure to a second semiconductor structure. Providing a first semiconductor structure comprising at least one component structure and a dielectric material, the at least one component structure comprising a conductive material (such as a metal or a non-metallic conductive material, such as a crucible composed of different crystallites, Typically referred to as "polysilicon", the dielectric material is configured adjacent to the at least one component structure. The at least one element structure and the dielectric material may be exposed on a bonding surface of the first semiconductor structure. An exposed surface of the dielectric material may define a bonding plane of the first semiconductor structure on a bonding surface of the first semiconductor structure. The at least one element structure in the first semiconductor structure may protrude from the bonding plane of the first semiconductor structure a distance beyond the adjacent dielectric material. A second semiconductor structure is provided to include at least one component structure and a dielectric material, the at least one component structure comprising a conductive material, the dielectric material being disposed adjacent to the at least one component structure. The at least one component structure and the dielectric material may be exposed on a bonding surface of the second semiconductor structure. An exposed surface of the dielectric material may define a bonding plane of the second semiconductor structure on a bonding surface of the second semiconductor structure. Direct bond in one of metal to metal In the forming process, the at least one element structure in the first semiconductor structure may be directly bonded to the at least one element structure in the second semiconductor structure.

將第一半導體結構直接鍵結至第二半導體結構之方法之其他實施例包括提供一第一半導體結構、提供一第二半導體結構,並在導電材料對導電材料之一直接鍵結製程(例如金屬對金屬、多晶矽對多晶矽、多晶矽對金屬等等)中,將該第一半導體結構中至少一個元件結構之多個組成凸起(integral protrusion),直接鍵結至該第二半導體結構中至少一個元件結構之多個組成凸起。該第一半導體結構可以包括含有一導電材料之至少一個元件結構,以及被配置為與該至少一個元件結構相鄰之一介電材料。該至少一個元件結構包含自一基底結構延伸出來之多個組成凸起。該些組成凸起及該介電材料曝露在該第一半導體結構之一鍵結表面上。在該至少一個元件結構之該些組成凸起間,該介電材料覆蓋了該至少一個元件結構之一部分。在該第一半導體結構之鍵結表面上,該介電材料之一曝露表面定義出該第一半導體結構之一鍵結平面。該第二半導體結構亦包括含有一導電材料之至少一個元件結構,以及被配置為與該至少一個元件結構相鄰之一介電材料。該至少一個元件結構包含自一基底結構延伸出來之多個組成凸起。該些組成凸起及該介電材料曝露在該第二半導體結構之一鍵結表面上。在該第二半導體結構中該至少一個元件結構之該些組成凸起間,該第二半導體結構之介電材料覆蓋了該至少一個元件結構之一部分。在該第二半導體結構之鍵結表面上,該介電材料之一曝露表面定義出該第二半導體結構之一鍵結平面。 Other embodiments of the method of directly bonding a first semiconductor structure to a second semiconductor structure include providing a first semiconductor structure, providing a second semiconductor structure, and directly bonding a conductive material to one of the conductive materials (eg, metal In the case of a metal, a polycrystalline germanium, a polycrystalline germanium, a polycrystalline germanium, or the like, the plurality of constituent protrusions of at least one of the first semiconductor structures are directly bonded to at least one of the second semiconductor structures. A plurality of constituent protrusions of the structure. The first semiconductor structure can include at least one element structure including a conductive material, and a dielectric material disposed adjacent to the at least one element structure. The at least one component structure includes a plurality of constituent protrusions extending from a substrate structure. The constituent bumps and the dielectric material are exposed on a bonding surface of the first semiconductor structure. The dielectric material covers a portion of the at least one component structure between the constituent protrusions of the at least one component structure. An exposed surface of the dielectric material defines a bonding plane of the first semiconductor structure on a bonding surface of the first semiconductor structure. The second semiconductor structure also includes at least one element structure including a conductive material, and a dielectric material disposed adjacent to the at least one element structure. The at least one component structure includes a plurality of constituent protrusions extending from a substrate structure. The constituent bumps and the dielectric material are exposed on a bonding surface of the second semiconductor structure. Between the constituent protrusions of the at least one component structure in the second semiconductor structure, a dielectric material of the second semiconductor structure covers a portion of the at least one component structure. An exposed surface of the dielectric material defines a bonding plane of the second semiconductor structure on a bonding surface of the second semiconductor structure.

在其他實施例中,本發明包括鍵結半導體結構。該些鍵結半導體結構包含被鍵結至一第二半導體結構之一第一半導體結構。在該第一半導體結構之一鍵結表面上,該第一半導體結構包括至少一個導電元件結構,以及被配置為與該至少一個導電元件結構相鄰之一介電材料。在該第二半導體結構之一鍵結表面上,該第二半導體結構亦包括至少一個導電元件結構,以及被配置為與該至少一個導電元件結構相鄰之一介電材料。該第二半導體結構中該至少一個導電元件結構沿著兩個半導體結構之導電元件結構間之鍵結界面,直接鍵結至該第一半導體結構中該至少一個導電元件結構。該第二半導體結構之介電材料沿著一鍵結平面緊靠該第一半導體結構之介電材料。該第一半導體結構中該至少一個導電元件結構與該第二半導體結構中該至少一個導電元件結構兩者間之鍵結界面,與該鍵結平面相隔了一段距離。 In other embodiments, the invention includes bonded semiconductor structures. The bonded semiconductor structures include a first semiconductor structure bonded to one of the second semiconductor structures. On a bonding surface of the first semiconductor structure, the first semiconductor structure includes at least one conductive element structure, and a dielectric material disposed adjacent to the at least one conductive element structure. On a bonding surface of the second semiconductor structure, the second semiconductor structure also includes at least one conductive element structure, and a dielectric material disposed adjacent to the at least one conductive element structure. The at least one conductive element structure of the second semiconductor structure is directly bonded to the at least one conductive element structure of the first semiconductor structure along a bonding interface between the conductive element structures of the two semiconductor structures. The dielectric material of the second semiconductor structure abuts the dielectric material of the first semiconductor structure along a bonding plane. A bonding interface between the at least one conductive element structure and the at least one conductive element structure of the second semiconductor structure is spaced apart from the bonding plane by a distance.

在另外的實施例中,本發明包括其他鍵結半導體結構,該些鍵結半導體結構含有被鍵結至一第二半導體結構之一第一半導體結構。在該第一半導體結構之一鍵結表面上,該第一半導體結構包括至少一個導電元件結構,以及被配置為與該至少一個導電元件結構相鄰之一介電材料。該至少一個導電元件結構包含自一基底結構延伸出來之多個組成凸起,且該介電材料之至少一部分被配置在該至少一個導電元件結構之該些組成凸起間。在該第二半導體結構之一鍵結表面上,該第二半導體結構亦包括至少一個導電元件結構,以及被配置為與該至少一個導電元件結構相鄰之一介電材料。該至少一個導電元件結構包含自一基底結構延伸出來之多個組成凸起,且該介電材料之至少一部分被配置在該第二半 導體結構中該至少一個導電元件結構之該些組成凸起間。該第二半導體結構之介電材料係沿著一鍵結平面緊靠該第一半導體結構之介電材料。該第一半導體結構中該至少一個導電元件結構之該些組成凸起,沿著兩個半導體結構之該些組成凸起間之已鍵結界面,直接鍵結至該第二半導體結構中該至少一個導電元件結構之該些組成凸起。 In further embodiments, the invention includes other bonded semiconductor structures having a first semiconductor structure bonded to one of the second semiconductor structures. On a bonding surface of the first semiconductor structure, the first semiconductor structure includes at least one conductive element structure, and a dielectric material disposed adjacent to the at least one conductive element structure. The at least one electrically conductive element structure includes a plurality of constituent protrusions extending from a substrate structure, and at least a portion of the dielectric material is disposed between the constituent protrusions of the at least one electrically conductive element structure. On a bonding surface of the second semiconductor structure, the second semiconductor structure also includes at least one conductive element structure, and a dielectric material disposed adjacent to the at least one conductive element structure. The at least one conductive element structure includes a plurality of constituent protrusions extending from a base structure, and at least a portion of the dielectric material is disposed in the second half The constituent protrusions of the at least one conductive element structure in the conductor structure. The dielectric material of the second semiconductor structure abuts the dielectric material of the first semiconductor structure along a bonding plane. The constituent protrusions of the at least one conductive element structure in the first semiconductor structure are directly bonded to the second semiconductor structure along the bonded interface between the constituent bumps of the two semiconductor structures The constituent protrusions of a conductive element structure.

本說明書提出之闡釋,其用意並非對任何特定半導體結構、元件、系統或方法之實際意見,而僅是用來描述本發明實施例之理想化陳述。 The description of the present specification is not intended to be an actual description of any particular semiconductor structure, component, system or method, but is merely an idealized description for describing embodiments of the invention.

本說明書所用任何標題不應認定其用意在於限制本發明實施例之範圍,因該範圍係由以下之申請專利範圍及其法律同等效力所界定。在任何特定標題下所敘述之概念,通常亦適用於整份說明書之其他部分。 The use of any headings in this specification is not intended to limit the scope of the embodiments of the invention, which is defined by the scope of the following claims and their legal equivalents. The concepts described under any particular heading also generally apply to the rest of the specification.

本說明書引用了一些參考資料,為所有目的,該些參考資料之完整揭露茲以此參照方式納入本說明書。此外,相對於本發明主張之專利標的,該些引用之參考資料,不論本說明書如何描述其特點,均不予承認為習知技術。 This specification is hereby incorporated by reference. In addition, the cited references, regardless of how the description describes the features of the invention, are not admitted as prior art.

在本說明書中,「半導體結構」一詞係指並包括形成一半導體元件時所用之任何結構。半導體結構包括,舉例而言,晶粒和晶圓(例如載體底材、中介層、元件底材等),以及組裝或複合結構中含有以三度空間集積方式互相結合之兩個或更多晶粒、晶圓或晶粒與晶圓之組合者。半導體結構亦包括完全製作的半導體元件,以及製作半導體元件期間所形成之中間結構。 In the present specification, the term "semiconductor structure" means and includes any structure used in forming a semiconductor element. The semiconductor structure includes, for example, a die and a wafer (eg, a carrier substrate, an interposer, an element substrate, etc.), and two or more crystals in an assembled or composite structure that are combined with each other in a three-dimensional space. Particle, wafer or combination of die and wafer. The semiconductor structure also includes fully fabricated semiconductor components and intermediate structures formed during fabrication of the semiconductor components.

在本說明書中,「已處理半導體結構」一詞係指並包括任何半導體結構中含有至少已局部形成之一個或多個元件結構者。已處理半導體結構為半導體結構之一子集,所有已處理半導體結構均為半導體結構。 In the present specification, the term "processed semiconductor structure" means and includes any semiconductor structure having at least one or more component structures that have been partially formed. The processed semiconductor structure is a subset of the semiconductor structure, and all of the processed semiconductor structures are semiconductor structures.

在本說明書中,「鍵結半導體結構」一詞係指並包括任何結構中含有附著在一起之兩個或更多半導體結構者。鍵結半導體結構為半導體結構之一子集,所有鍵結半導體結構均為半導體結構。此外,鍵結半導體結構中含有一個或多個已處理半導體結構者,亦為已處理半導體結構。 In the present specification, the term "bonded semiconductor structure" means and includes any structure having two or more semiconductor structures attached thereto. The bonded semiconductor structure is a subset of the semiconductor structure, and all of the bonded semiconductor structures are semiconductor structures. In addition, one or more of the processed semiconductor structures in the bonded semiconductor structure are also processed semiconductor structures.

在本說明書中,「元件結構」一詞係指並包括一已處理半導體結構之任何部分,該部分為、包含、或定義出一半導體元件之一主動或被動組件之至少一部分,而該半導體元件將會形成於該半導體結構之上或之中。舉例而言,元件結構包含積體電路之主動及被動組件,像是電晶體、換能器、電容、電阻、導電線、導電通孔、導電接觸墊等。 In the present specification, the term "elemental structure" means and includes any portion of a processed semiconductor structure that is, includes, or defines at least a portion of an active or passive component of a semiconductor component. Will be formed on or in the semiconductor structure. For example, the component structure includes active and passive components of the integrated circuit, such as transistors, transducers, capacitors, resistors, conductive lines, conductive vias, conductive contact pads, and the like.

在本說明書中,「晶圓間透通連結」或「TWI」一詞係指並包括穿過一第一半導體結構至少一部分之任何導電通孔,其跨越該第一半導體結構與一第二半導體結構間之一界面,在該第一半導體結構與該第二半導體結構間提供一結構上及/或電氣上之互連。在本發明所屬技術領域中,晶圓間透通連結亦有其他名稱,像是「矽導通孔(through silicon vias)」、「底材導通孔(through substrate vias)」、「晶圓導通孔(through wafer vias)」,或前述名稱之英文簡稱,譬如「TSV」或「TWV」。TWI通常會在大致垂直於一半導體結構中該些大致平坦之主要表面之一方向上(亦即平行於「Z」軸之方向)穿過該半導體結構。 In the present specification, the term "through-wafer via" or "TWI" refers to and includes any conductive via that passes through at least a portion of a first semiconductor structure that spans the first semiconductor structure and a second semiconductor. An interface between the structures provides a structural and/or electrical interconnection between the first semiconductor structure and the second semiconductor structure. In the technical field of the present invention, there are other names for inter-wafer via connections, such as "through silicon vias", "through substrate vias", and "wafer vias". Through wafer vias), or the abbreviation of the above name, such as "TSV" or "TWV". The TWI typically passes through the semiconductor structure in a direction substantially perpendicular to one of the substantially planar major surfaces in a semiconductor structure (i.e., parallel to the "Z" axis).

本說明書中,「主動表面」一詞用於和已處理半導體結構有關的情況時,係指並包括該已處理半導體結構之一曝露主要表面,該表面已受到處理或將受到處理,以在該已處理半導體結構之曝露主要表面之中及/或之上,形成一個或多個元件結構。 In the present specification, the term "active surface" is used in relation to a processed semiconductor structure and refers to and includes one of the treated semiconductor structures exposed to a major surface that has been treated or will be processed to One or more component structures are formed in and/or on the exposed major surface of the semiconductor structure.

在本說明書中,「背表面」一詞用於和已處理半導體結構有關的情況時,係指並包括該已處理半導體結構之一曝露主要表面,其為該已處理半導體結構之主動表面之相反面。 In the present specification, the term "back surface" is used in relation to a processed semiconductor structure and refers to and includes one of the treated semiconductor structures exposed to the major surface, which is the opposite of the active surface of the processed semiconductor structure. surface.

在一些實施例中,本發明包括將一第一半導體結構直接鍵結至一第二半導體結構以形成一鍵結半導體結構之改進方法。具體而言,本發明之實施例可以包括形成一半導體結構之一鍵結表面,使其具有選定之形貌圖案,該形貌圖案係特意在原子尺度上作成非平坦狀,以在一直接鍵結製程,例如超低溫鍵結製程(例如表面輔助鍵結(SAB)製程)中,使該半導體結構之鍵結表面與另一半導體結構之鍵結表面間所建立之鍵結可獲得改善,而無需在兩個半導體結構之鍵結表面間使用中間黏著材料。 In some embodiments, the invention includes an improved method of directly bonding a first semiconductor structure to a second semiconductor structure to form a bonded semiconductor structure. In particular, embodiments of the invention may include forming a bonding surface of a semiconductor structure having a selected topographic pattern that is intentionally non-planar on an atomic scale to a direct bond Bonding processes, such as ultra-low temperature bonding processes (eg, surface assisted bonding (SAB) processes), provide bonding between the bonding surface of the semiconductor structure and the bonding surface of another semiconductor structure without the need for bonding An intermediate bonding material is used between the bonding surfaces of the two semiconductor structures.

茲參照圖2A至2K將本發明第一組示範性實施例敘述如下。具體而言,圖2A至2D呈現圖2D所示之一第一半導體結構130之製造,圖2E至2I呈現圖2I所示之一第二半導體結構240之製造,圖2J及2K則呈現該第一半導體結構130及該第二半導體結構240在一直接鍵結製程中被鍵結在一起,以形成圖2K所示之一鍵結半導體結構300。 A first set of exemplary embodiments of the present invention will now be described with reference to Figures 2A through 2K. Specifically, FIGS. 2A through 2D illustrate the fabrication of one of the first semiconductor structures 130 shown in FIG. 2D, and FIGS. 2E through 2I illustrate the fabrication of one of the second semiconductor structures 240 shown in FIG. 2I, and FIGS. 2J and 2K present the first A semiconductor structure 130 and the second semiconductor structure 240 are bonded together in a direct bonding process to form a bonded semiconductor structure 300 as shown in FIG. 2K.

參照圖2A,其呈現一半導體結構100,該半導體結構可以如上文參照圖1A及1B所述而形成。如同圖1A之半導體結構10,該半導體結構100 可以包括一介電材料102,其含有一個或多個元件結構,譬如電晶體、垂直延伸之導電通孔、水平延伸之導電跡線等等。該半導體結構100包含元件結構106,其係由配置在凹槽104內之一導電金屬105所定義並含有該導電金屬105,該些凹槽104係形成或以其他方式提供於該介電材料102中。 Referring to Figure 2A, a semiconductor structure 100 is presented which may be formed as described above with reference to Figures 1A and 1B. Like the semiconductor structure 10 of FIG. 1A, the semiconductor structure 100 A dielectric material 102 can be included that includes one or more component structures, such as a transistor, vertically extending conductive vias, horizontally extending conductive traces, and the like. The semiconductor structure 100 includes an element structure 106 defined by a conductive metal 105 disposed within the recess 104 and containing the conductive metal 105. The recess 104 is formed or otherwise provided to the dielectric material 102. in.

該導電材料105可以包含工業級的純金屬元素,譬如銅、鋁、鎢、鉭、鈦、鉻,或包含非金屬的導電材料,像是摻雜多晶矽等等,或者,該導電材料105可以包含以一種或多種前述金屬元素為主的一種合金或混合物。此外,該些元件結構106可以包含具有不同組成之不同區域。例如,該些凹槽104可以內襯一層或多層相對薄的金屬,以作為擴散阻隔層、種子層等等,而諸如銅或銅合金之主體導電金屬可以實質上填滿該些凹槽104內剩餘的主要空間。 The conductive material 105 may comprise industrial grade pure metal elements such as copper, aluminum, tungsten, tantalum, titanium, chromium, or a non-metallic conductive material such as doped polysilicon or the like, or the conductive material 105 may comprise An alloy or mixture of one or more of the foregoing metal elements. Moreover, the component structures 106 can comprise different regions having different compositions. For example, the recesses 104 may be lined with one or more layers of relatively thin metal to serve as a diffusion barrier layer, seed layer, etc., while a bulk conductive metal such as copper or copper alloy may substantially fill the recesses 104. The remaining main space.

如圖2A所示,透過該介電材料102而曝露出來之該些元件結構106之表面107,在一些實施例中或許有內凹之形狀,這可能是碟形凹陷現象所致,該現象已在進行化學機械研磨(CMP)製程以從該半導體結構100移除多餘之導電材料105並定義該些元件結構106時觀察到。因此,相較於相鄰之周圍介電材料102之表面103,該些元件結構106之表面107可以較為凹陷,如圖2A所示。 As shown in FIG. 2A, the surface 107 of the element structures 106 exposed through the dielectric material 102 may have a concave shape in some embodiments, which may be caused by a dishing phenomenon. Observed when a chemical mechanical polishing (CMP) process is performed to remove excess conductive material 105 from the semiconductor structure 100 and define the element structures 106. Thus, the surface 107 of the element structures 106 can be relatively recessed as compared to the surface 103 of the adjacent surrounding dielectric material 102, as shown in Figure 2A.

同樣如圖2A所示,該介電材料102之曝露主要表面103可能不是完全平坦,該表面上的某些位置可能有坑洞或凹陷。例如,該表面103在與該些元件結構106分開的一個位置上有一凹陷108。此等凹陷108同樣可能是用於從該半導體結構100移除多餘之導電材料105並定義該些元件結 構106之化學機械研磨(CMP)製程所致,由於其涉及不同材料的移除,因此獲致平坦表面的效果可能相對較差,不及只有涉及移除單一均質材料之CMP製程(亦即在CMP製程中所研磨的整個表面具有相同組成者)。 As also shown in FIG. 2A, the exposed primary surface 103 of the dielectric material 102 may not be completely flat, and certain locations on the surface may have pits or depressions. For example, the surface 103 has a recess 108 at a location separate from the component structures 106. Such recesses 108 may also be used to remove excess conductive material 105 from the semiconductor structure 100 and define the component junctions. Due to the chemical mechanical polishing (CMP) process of structure 106, the effect of achieving a flat surface may be relatively poor due to the removal of different materials, which is less than a CMP process involving removal of a single homogeneous material (ie, in a CMP process) The entire surface being ground has the same composition).

參照圖2B,經由在該介電材料102之表面103上提供一額外介電材料112,可以由圖2A之半導體結構100形成一半導體結構110。如圖2B所示,在該介電材料102上可以提供該額外介電材料112,並使其平均厚度足以填滿該凹陷108及該些元件結構106之內凹表面107所定義出之凹陷。在一些實施例中,該額外介電材料112可以覆蓋該介電材料102,以使該額外介電材料之曝露主要表面114與其下介電材料102之表面103兩者間之平均距離為至少大約10奈米(100nm),至少大約500奈米(500nm),或甚至至少大約1,000奈米(1,000nm)。 Referring to FIG. 2B, a semiconductor structure 110 can be formed from the semiconductor structure 100 of FIG. 2A by providing an additional dielectric material 112 on the surface 103 of the dielectric material 102. As shown in FIG. 2B, the additional dielectric material 112 can be provided on the dielectric material 102 and have an average thickness sufficient to fill the recesses 108 and the recesses defined by the concave surfaces 107 of the component structures 106. In some embodiments, the additional dielectric material 112 can cover the dielectric material 102 such that the average distance between the exposed major surface 114 of the additional dielectric material and the surface 103 of the lower dielectric material 102 is at least approximately 10 nm (100 nm), at least about 500 nm (500 nm), or even at least about 1,000 nm (1,000 nm).

該額外介電材料可以包含,舉例而言,一種氧化物材料,像是氧化矽、氮化矽、氮氧化矽等其中一項或多項,且該額外介電材料可以利用已知之化學氣相沉積(CVD)製程加以沉積。沉積該額外介電材料之溫度可予以選定,以避免破壞之前已製作好的元件。 The additional dielectric material may comprise, for example, an oxide material such as one or more of cerium oxide, cerium nitride, cerium oxynitride, etc., and the additional dielectric material may utilize known chemical vapor deposition. The (CVD) process is deposited. The temperature at which the additional dielectric material is deposited can be selected to avoid damaging previously fabricated components.

如圖2B所示,在一些實施例中,該額外介電材料112可以保形(conformal)方式沉積於圖2A之半導體結構100上,這樣,該額外介電材料112之曝露主要表面114在相應於下方半導體結構100表面之凹陷之位置,亦包含一個或多個凹陷。舉例而言,在該額外介電材料112之曝露主要表面114上有一凹陷116,其位於下方介電材料102之表面103之凹陷108之上。雖然未顯示於圖2B,但在該些元件結構106之內凹表面107上方之額外介電材料112之曝露主要表面114中亦可以有其他凹陷形成。 As shown in FIG. 2B, in some embodiments, the additional dielectric material 112 can be deposited in a conformal manner on the semiconductor structure 100 of FIG. 2A such that the exposed major surface 114 of the additional dielectric material 112 is corresponding At the location of the depression of the surface of the lower semiconductor structure 100, one or more recesses are also included. For example, a recess 116 is formed on the exposed major surface 114 of the additional dielectric material 112 over the recess 108 of the surface 103 of the underlying dielectric material 102. Although not shown in FIG. 2B, other recesses may be formed in the exposed major surface 114 of the additional dielectric material 112 over the recessed surface 107 of the component structures 106.

參照圖2C,沉積該額外介電材料112後,便可將該額外介電材料112之曝露主要表面114平坦化,以形成另一半導體結構120。舉例而言,可以使該額外介電材料112之曝露主要表面114接受化學蝕刻製程、機械研磨製程、化學機械研磨(CMP)製程等其中一項或多項之處理,以使該額外介電材料112之曝露主要表面114變得平坦。用於使該曝露主要表面114平坦化的製程,可能涉及移除該額外介電材料112之一部分。因此,該額外介電材料112之原始輪廓剖面在圖2C中以一假想線表示。將該額外介電材料112之曝露主要表面114平坦化後,該曝露主要表面114至少實質上是平坦的(亦即平滑)。由於使該曝露主要表面114平坦化所使用之製程涉及將具有相同組成(亦即該額外介電材料112之組成)之整個表面平坦化,因此,相對於圖2A中半導體結構100之曝露主要表面之平滑度,經平坦化處理後之曝露主要表面114更為平滑。 Referring to FIG. 2C, after depositing the additional dielectric material 112, the exposed major surface 114 of the additional dielectric material 112 can be planarized to form another semiconductor structure 120. For example, the exposed main surface 114 of the additional dielectric material 112 may be subjected to a chemical etching process, a mechanical polishing process, a chemical mechanical polishing (CMP) process, or the like to process the additional dielectric material 112. The exposed main surface 114 becomes flat. The process for planarizing the exposed major surface 114 may involve removing a portion of the additional dielectric material 112. Thus, the original contour profile of the additional dielectric material 112 is represented by an imaginary line in Figure 2C. After planarizing the exposed major surface 114 of the additional dielectric material 112, the exposed major surface 114 is at least substantially planar (ie, smooth). Since the process used to planarize the exposed major surface 114 involves flattening the entire surface having the same composition (i.e., the composition of the additional dielectric material 112), the exposed major surface relative to the semiconductor structure 100 of FIG. 2A The smoothness of the exposed main surface 114 after smoothing is smoother.

在一些實施例中,該曝露主要表面114在平坦化製程後所具有之均方根(RMS)表面粗度可以為大約二分之一奈米(0.5nm)或更低、大約十分之二奈米(0.2nm)或更低,或甚至大約十分之一奈米(0.1nm)或更低。 In some embodiments, the exposed major surface 114 may have a root mean square (RMS) surface roughness after the planarization process of about one-half nanometer (0.5 nm) or less, about two tenths. Nano (0.2 nm) or lower, or even about one tenth of a nanometer (0.1 nm) or less.

如圖2D所示,將該額外介電材料112之曝露主要表面114平坦化後,便可以對圖2C之半導體結構120進行一蝕刻製程,以移除該額外介電材料112及其下方介電材料102之一部分,以致使該些元件結構106從該介電材料102之曝露表面103突出預先選定之一段距離D1,並形成前文述及之第一半導體結構130。 As shown in FIG. 2D, after the exposed main surface 114 of the additional dielectric material 112 is planarized, an etching process can be performed on the semiconductor structure 120 of FIG. 2C to remove the additional dielectric material 112 and the dielectric underneath. the portion of the material 102, to cause the plurality of structure elements 106,103 preselected one protruding segment distance D 1 from the exposed surface of the dielectric material 102 electrically, and a first semiconductor structure 130 is formed of the hereinbefore mentioned.

在一些實施例中,該距離D1可以介於大約二分之一奈米(0.5nm)及大約50奈米(50nm)之間、介於大約1奈米(1nm)及大約10奈米(10nm)之間,或甚至介於大約2奈米(2nm)及大約7奈米(7nm)之間。 In some embodiments, the distance D 1 can be between about one-half nanometer (0.5 nm) and about 50 nanometers (50 nm), between about 1 nanometer (1 nm) and about 10 nanometers ( Between 10 nm), or even between about 2 nm (2 nm) and about 7 nm (7 nm).

該些元件結構106之曝露表面及周圍介電材料102之曝露主要表面103一同定義出該第一半導體結構130之一鍵結表面,該鍵結表面將會緊靠並鍵結至圖2I所示之第二半導體結構240之一互補鍵結表面。 The exposed surface of the component structure 106 and the exposed major surface 103 of the surrounding dielectric material 102 together define a bonding surface of the first semiconductor structure 130, and the bonding surface will abut and bond to the surface shown in FIG. 2I. One of the second semiconductor structures 240 is complementary to the bonding surface.

繼續參照圖2D,該些元件結構106及配置為與該些元件結構106相鄰之介電材料102皆曝露在該第一半導體結構130之鍵結表面。該介電材料102之曝露主要表面103定義出該第一半導體結構之一鍵結平面132。該鍵結平面132可以包含該第一半導體結構130及該第二半導體結構240鍵結在一起後,該第一半導體結構130與該第二半導體結構240(圖2I)間之鍵結界面之至少大部分所沿著延伸之平面,如下文中參照圖2J及2K所詳述。 Continuing to refer to FIG. 2D , the component structures 106 and the dielectric material 102 disposed adjacent to the component structures 106 are exposed on the bonding surface of the first semiconductor structure 130 . The exposed primary surface 103 of the dielectric material 102 defines a bonding plane 132 of the first semiconductor structure. The bonding plane 132 may include at least the bonding interface between the first semiconductor structure 130 and the second semiconductor structure 240 (FIG. 2I) after the first semiconductor structure 130 and the second semiconductor structure 240 are bonded together. Most of the plane along the extension is as detailed below with reference to Figures 2J and 2K.

茲參照圖2E至2I,將可用於形成圖2I之第二半導體結構240之一示範性方法敘述如下。 Referring now to Figures 2E through 2I, an exemplary method that can be used to form the second semiconductor structure 240 of Figure 2I is described below.

參照圖2E,提供一半導體結構200。該半導體結構200實質上類似於圖2A之半導體結構100,且可以包含一元件層201,其含有一個或多個元件結構,譬如電晶體、垂直延伸之導電通孔、水平延伸之導電跡線等等。該半導體結構200包含一介電材料202及多個元件結構206,其中該介電材料係被配置於該元件層201上,該些元件結構由配置在凹槽204內之一導電金屬205所定義並含有該導電金屬205,該些凹槽204係形成或以其 他方式提供於該介電材料202中。該導電金屬205所具有之組成可以如前文中關於圖2A之導電材料105所述。 Referring to FIG. 2E, a semiconductor structure 200 is provided. The semiconductor structure 200 is substantially similar to the semiconductor structure 100 of FIG. 2A and may include an element layer 201 containing one or more element structures, such as a transistor, vertically extending conductive vias, horizontally extending conductive traces, etc. Wait. The semiconductor structure 200 includes a dielectric material 202 and a plurality of element structures 206, wherein the dielectric material is disposed on the element layer 201, and the element structures are defined by a conductive metal 205 disposed in the recess 204. And containing the conductive metal 205, the grooves 204 are formed or Other ways are provided in the dielectric material 202. The conductive metal 205 may have a composition as described above with respect to the conductive material 105 of FIG. 2A.

如圖2E所示,透過該介電材料202而曝露出來之該些元件結構206之表面207,在一些實施例中或許有內凹之形狀,這可能是碟形凹陷現象所致,該現象已在進行化學機械研磨(CMP)製程以從該半導體結構200移除多餘之導電材料205並定義該些元件結構206時觀察到。因此,相較於相鄰之介電材料202之表面203,該些元件結構206之表面207可以較為凹陷,如圖2E所示。 As shown in FIG. 2E, the surface 207 of the component structures 206 exposed through the dielectric material 202 may have a concave shape in some embodiments, which may be caused by a dishing phenomenon. Observed when a chemical mechanical polishing (CMP) process is performed to remove excess conductive material 205 from the semiconductor structure 200 and define the element structures 206. Thus, the surface 207 of the element structures 206 can be relatively recessed as compared to the surface 203 of the adjacent dielectric material 202, as shown in Figure 2E.

同樣如圖2E所示,該介電材料202之曝露主要表面203可能不是完全平坦,且該些表面上的某些位置可能有坑洞或凹陷。例如,該表面203在與該些元件結構206分開的一個位置上有一凹陷208。此等凹陷208同樣可能是用於從該半導體結構200移除多餘之導電材料205並定義該些元件結構206之化學機械研磨(CMP)製程所致,如前文所討論。 As also shown in FIG. 2E, the exposed major surface 203 of the dielectric material 202 may not be completely flat, and certain locations on the surfaces may have pits or depressions. For example, the surface 203 has a recess 208 at a location that is separate from the component structures 206. Such recesses 208 may also be caused by a chemical mechanical polishing (CMP) process for removing excess conductive material 205 from the semiconductor structure 200 and defining the component structures 206, as discussed above.

參照圖2F,經由在該介電材料202之表面203上提供一額外介電材料212,可以由圖2E之半導體結構200形成一半導體結構210。如圖2F所示,在該介電材料202上可以提供該額外介電材料212,使其平均厚度足以填滿該凹陷208及該些元件結構206之內凹表面207所定義出之凹陷。該額外介電材料212所具有之組成及組構(例如平均厚度),可以如前文中參照圖2B有關額外介電材料112之部分所揭露。 Referring to FIG. 2F, a semiconductor structure 210 can be formed from the semiconductor structure 200 of FIG. 2E by providing an additional dielectric material 212 on the surface 203 of the dielectric material 202. As shown in FIG. 2F, the additional dielectric material 212 can be provided on the dielectric material 202 to have an average thickness sufficient to fill the recess 208 and the recess defined by the concave surface 207 of the component structures 206. The composition and composition (e.g., average thickness) of the additional dielectric material 212 can be as disclosed above with respect to the additional dielectric material 112 of FIG. 2B.

如圖2F所示,在一些實施例中,該額外介電材料212可以保形方式沉積於圖2E之半導體結構200上,這樣,該額外介電材料212之曝露主要表面214在相應於下方半導體結構200表面之凹陷之位置處,亦包含一 個或多個凹陷。舉例而言,在該額外介電材料212之曝露主要表面214上有一凹陷216,其位於下方介電材料202之表面203之凹陷208上方。雖然未顯示於圖2F,但在該些元件結構206之內凹表面207上方之額外介電材料212之曝露主要表面214中亦可以有其他凹陷形成。 As shown in FIG. 2F, in some embodiments, the additional dielectric material 212 can be deposited in a conformal manner on the semiconductor structure 200 of FIG. 2E such that the exposed major surface 214 of the additional dielectric material 212 corresponds to the underlying semiconductor. The location of the depression of the surface of the structure 200 also includes a One or more depressions. For example, a recess 216 is formed over the exposed major surface 214 of the additional dielectric material 212 above the recess 208 of the surface 203 of the underlying dielectric material 202. Although not shown in FIG. 2F, other recesses may be formed in the exposed major surface 214 of the additional dielectric material 212 above the recessed surface 207 of the component structures 206.

參照圖2G,沉積該額外介電材料212後,便可以如同前文參照圖2C關於額外介電材料112部分所述之方式,將該額外介電材料212之曝露主要表面214平坦化,以形成另一半導體結構220。舉例而言,可以使該額外介電材料212之曝露主要表面214接受化學蝕刻製程、機械研磨製程、化學機械研磨(CMP)製程等其中一項或多項之處理,以使該額外介電材料212之曝露主要表面214變得平坦。用於使該曝露主要表面214平坦化的製程,可能涉及移除該額外介電材料212之一部分。因此,該額外介電材料212之原始輪廓剖面在圖2G中以一假想線表示。將該額外介電材料212之曝露主要表面214平坦化後,該曝露主要表面214至少實質上是平坦的(亦即平滑)。由於使該曝露主要表面214平坦化所使用之製程涉及將具有相同組成(亦即該額外介電材料212之組成)之整個表面平坦化,因此,相對於圖2E中半導體結構200之曝露主要表面之平滑度,經平坦化製程處理後之曝露主要表面214更為平滑。 Referring to FIG. 2G, after depositing the additional dielectric material 212, the exposed major surface 214 of the additional dielectric material 212 can be planarized as described above with respect to the additional dielectric material 112 portion of FIG. 2C to form another A semiconductor structure 220. For example, the exposed main surface 214 of the additional dielectric material 212 may be subjected to a chemical etching process, a mechanical polishing process, a chemical mechanical polishing (CMP) process, or the like to process the additional dielectric material 212. The exposed main surface 214 becomes flat. The process for planarizing the exposed major surface 214 may involve removing a portion of the additional dielectric material 212. Thus, the original profile profile of the additional dielectric material 212 is represented by an imaginary line in Figure 2G. After planarizing the exposed major surface 214 of the additional dielectric material 212, the exposed major surface 214 is at least substantially planar (ie, smooth). Since the process used to planarize the exposed major surface 214 involves planarizing the entire surface having the same composition (i.e., the composition of the additional dielectric material 212), the exposed major surface relative to the semiconductor structure 200 of FIG. 2E The smoothness, the exposed main surface 214 after the flattening process is smoother.

在一些實施例中,該曝露主要表面214在平坦化製程後所具有之均方根(RMS)表面粗度可以為大約二分之一奈米(0.5nm)或更低、大約十分之二奈米(0.2nm)或更低,或甚至大約十分之一奈米(0.1nm)或更低。 In some embodiments, the exposed major surface 214 may have a root mean square (RMS) surface roughness after the planarization process of about one-half nanometer (0.5 nm) or less, about two tenths. Nano (0.2 nm) or lower, or even about one tenth of a nanometer (0.1 nm) or less.

參照圖2H,將該額外介電材料212之曝露主要表面214平坦化後,便可以在經過平坦化之曝露主要表面214上提供一罩幕材料232。該罩幕材料232可以地毯式沉積在至少實質上整個曝露主要表面214,然後被賦予圖案,以形成穿過該罩幕材料232之孔隙234(例如洞口或其他開口)。該些孔隙234可以對準該些元件結構206,如圖2H所示。此外,該些孔隙234所具有之尺寸及形狀,可以對應於其下方該些元件結構206之尺寸及形狀。被賦予圖案之罩幕材料232有助於移除覆蓋在該些元件結構206上方之額外介電材料212區域,而不會移除該額外介電材料212之其他區域。 Referring to FIG. 2H, after the exposed major surface 214 of the additional dielectric material 212 is planarized, a masking material 232 can be provided over the planarized exposed major surface 214. The masking material 232 can be carpet-deposited over at least substantially the entire exposed major surface 214 and then patterned to form apertures 234 (eg, openings or other openings) through the masking material 232. The apertures 234 can be aligned with the component structures 206, as shown in Figure 2H. In addition, the apertures 234 have dimensions and shapes that correspond to the size and shape of the component structures 206 beneath them. The patterned mask material 232 helps to remove areas of the additional dielectric material 212 overlying the element structures 206 without removing other areas of the additional dielectric material 212.

該罩幕材料232可以包含,舉例而言,諸如聚甲基丙烯酸甲酯(PMMA)之一種高分子光阻(polymeric photoresist)材料,其可以旋轉方式沉積在一層未經固化之光阻材料上,然後透過帶有圖案之一遮罩,使該未經固化之光阻材料之某些選定區域受到電磁輻射,以使該未經固化之光阻材料中只有該些選定區域被固化。接著,可將該光阻材料中未被固化之區域移除,以形成有圖案之罩幕材料232,如圖2H所示。在其他實施例中,該罩幕材料232可以包含諸如氮化矽(Si3N4)之一種硬罩幕材料,並可以利用像是化學氣相沉積(CVD)製程加以沉積。接著可以利用微影技術,在所沉積之硬罩幕材料上賦予圖案,以形成有圖案之罩幕材料232,如圖2H所示。不同的罩幕材料及沉積此等罩幕材料並賦予其圖案之方法,已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。 The mask material 232 can comprise, for example, a polymeric photoresist material such as polymethyl methacrylate (PMMA) that can be rotatably deposited on an uncured photoresist material. Certain selected regions of the uncured photoresist material are then subjected to electromagnetic radiation through a mask with a pattern such that only selected regions of the uncured photoresist material are cured. The uncured regions of the photoresist material can then be removed to form a patterned mask material 232, as shown in Figure 2H. In other embodiments, the mask material 232 may comprise a hard mask material such as tantalum nitride (Si 3 N 4 ) and may be deposited using a chemical vapor deposition (CVD) process. A lithographic technique can then be used to impart a pattern on the deposited hard mask material to form a patterned mask material 232, as shown in Figure 2H. Different masking materials and methods of depositing such masking materials and imparting patterns thereto are known in the art to which the present invention pertains and may be employed in embodiments of the present invention.

在該額外介電材料212經過平坦化之曝露主要表面214上形成有圖案之罩幕材料232後,便可以移除覆蓋於該些元件結構206上,透過該有圖 案罩幕材料232之孔隙234而曝露出來之額外介電材料212區域,以形成圖2I所示之半導體結構240。舉例而言,在一濕式化學蝕刻製程或一乾式反應性離子蝕刻(RIE)製程中,圖2H之半導體結構230可以曝露在一種或多種蝕刻劑中。該一種或多種蝕刻劑之組成可予以選定,使其能夠蝕刻該額外介電材料212而不會移除該有圖案罩幕材料232及該些元件結構206,或是使其能夠以較高速率蝕刻該額外介電材料212,此乃相對於該一種或多種蝕刻劑蝕刻該有圖案罩幕材料232及該些元件結構206之速率而言,如此,覆蓋於該些元件結構206上之額外介電材料212至少實質上全部可以被該一種或多種蝕刻劑所移除,而該有圖案罩幕材料232則不至於被完全蝕穿。 After the additional dielectric material 212 is formed with the patterned mask material 232 on the planarized exposed main surface 214, it can be removed and overlaid on the component structures 206 through the patterned The aperture 234 of the mask material 232 exposes the additional dielectric material 212 region to form the semiconductor structure 240 shown in FIG. For example, the semiconductor structure 230 of FIG. 2H can be exposed to one or more etchants in a wet chemical etching process or a dry reactive ion etching (RIE) process. The composition of the one or more etchants can be selected to enable etching of the additional dielectric material 212 without removing the patterned mask material 232 and the component structures 206, or enabling them to be at a higher rate The additional dielectric material 212 is etched, relative to the rate at which the patterned mask material 232 and the element structures 206 are etched relative to the one or more etchants, such that additional layers overlying the element structures 206 At least substantially all of the electrical material 212 can be removed by the one or more etchants, and the patterned mask material 232 is not completely etched through.

將覆蓋於該些元件結構206上,透過該有圖案罩幕材料232之孔隙234而曝露出來之額外介電材料212區域在一蝕刻製程中移除後,該有圖案罩幕材料232便可予以移除,如圖2I所示。在一些實施例中,該額外介電材料212之曝露主要表面214在此蝕刻製程後所具有之均方根(RMS)表面粗度可以為大約二分之一奈米(0.5nm)或更低、大約十分之二奈米(0.2nm)或更低,或甚至大約十分之一奈米(0.1nm)或更低。 The patterned mask material 232 can be applied to the component structures 206 and the additional dielectric material 212 exposed through the apertures 234 of the patterned mask material 232 is removed in an etch process. Removed as shown in Figure 2I. In some embodiments, the exposed major surface 214 of the additional dielectric material 212 may have a root mean square (RMS) surface roughness of about one-half nanometer (0.5 nm) or less after the etching process. About two tenths of a nanometer (0.2 nm) or less, or even about one tenth of a nanometer (0.1 nm) or less.

此外,在一些實施例中,用於將覆蓋於該些元件結構206上,透過該有圖案罩幕材料232之孔隙234而曝露出來之額外介電材料212區域移除之蝕刻製程,可能致使該些元件結構206之曝露表面207相對於周圍額外介電材料212之曝露表面214而凹陷預先選定之一段距離D2,如圖2I所示。 Moreover, in some embodiments, an etch process for overlying the additional dielectric material 212 that is exposed over the element structures 206 and exposed through the apertures 234 of the patterned mask material 232 may result in the etching process. The exposed surface 207 of the component structures 206 is recessed a predetermined distance D 2 relative to the exposed surface 214 of the surrounding additional dielectric material 212, as shown in FIG. 2I.

在一些實施例中,當該些元件結構包含多晶矽時,用於移除氧化物之蝕刻製程可能會造成該些元件結構206之曝露表面207產生凹陷或淺碟之形狀。在其他實施例中,該些元件結構206可能會因為用於從該半導體結構100移除多餘之導電材料105並定義該些元件結構106之化學機械研磨(CMP)製程,而產生凹陷或淺碟之形狀,如前文參照圖2A所述者。 In some embodiments, when the element structures comprise polysilicon, an etch process for removing oxides may cause the exposed surface 207 of the element structures 206 to have a shape of a recess or a shallow dish. In other embodiments, the component structures 206 may be recessed or dished because of a chemical mechanical polishing (CMP) process for removing excess conductive material 105 from the semiconductor structure 100 and defining the component structures 106. The shape is as described above with reference to Figure 2A.

作為非限制性之範例,該距離D2可以介於大約十分之一奈米(0.1nm)及大約10奈米(10nm)之間、介於大約1奈米(1nm)及大約10奈米(10nm)之間,或甚至介於大約2奈米(2nm)及大約7奈米(7nm)之間。 As a non-limiting example, the distance D 2 can be between about one tenth of a nanometer (0.1 nm) and about 10 nanometers (10 nm), between about 1 nanometer (1 nm) and about 10 nm. Between (10 nm), or even between about 2 nm (2 nm) and about 7 nm (7 nm).

在一些實施例中,圖2I之距離D2可以至少實質上等於圖2D之距離D1。但在其他實施例中,圖2I之距離D2可以小於圖2D之距離D1。舉例而言,圖2I之距離D2可以介於圖2D之距離D1之大約80%至大約99%之間,或者,更具體而言,可以介於圖2D之距離D1之大約90%至大約98%之間。 In some embodiments, the distance D 2 of FIG. 2I can be at least substantially equal to the distance D 1 of FIG. 2D. However, in other embodiments, the distance D 2 of FIG. 2I may be less than the distance D 1 of FIG. 2D. For example, FIG. 2I can be interposed between the distance D 2 of FIG. 2D of the distance D 1 between about 80% to about 99%, or, more specifically, between the distance D 1 of FIG. 2D is about 90% To about 98%.

該些元件結構206之曝露表面207及周圍額外介電材料212之曝露主要表面214一同定義出該第二半導體結構240之一鍵結表面,該鍵結表面將會緊靠並鍵結至圖2D之第一半導體結構130之互補鍵結表面。 The exposed surface 207 of the component structures 206 and the exposed major surface 214 of the surrounding additional dielectric material 212 together define a bonding surface of the second semiconductor structure 240 that will abut and bond to Figure 2D. The complementary bonding surface of the first semiconductor structure 130.

繼續參照圖2I,該些元件結構206及配置為與該些元件結構206相鄰之額外介電材料212皆曝露在該第二半導體結構240之鍵結表面。該額外介電材料212之曝露主要表面214定義出該第二半導體結構240之一鍵結平面242。該鍵結平面242可以包含該第一半導體結構130及該第二半導體結構240鍵結在一起後,該第一半導體結構130(圖2D)與該第二半 導體結構240間之鍵結界面之至少大部分所沿著延伸之平面,如下文參照圖2J及2K所詳述。 With continued reference to FIG. 2I, the element structures 206 and additional dielectric material 212 disposed adjacent to the element structures 206 are exposed on the bonding surface of the second semiconductor structure 240. The exposed primary surface 214 of the additional dielectric material 212 defines a bonding plane 242 of the second semiconductor structure 240. The bonding plane 242 may include the first semiconductor structure 130 and the second semiconductor structure 240 being bonded together, the first semiconductor structure 130 (FIG. 2D) and the second half At least a majority of the bonding interface between conductor structures 240 is along the plane of extension, as described in more detail below with respect to Figures 2J and 2K.

參照圖2J,可以將該第一半導體結構130對準該第二半導體結構240,這樣,該第一半導體結構130之該些元件結構106便會對準該第二半導體結構240之該些元件結構206。如前所述,該些元件結構106之曝露表面及周圍介電材料102之曝露主要表面103一同定義出該第一半導體結構130之一鍵結表面,且該些元件結構206之曝露表面及周圍額外介電材料212之曝露主要表面214一同定義出該第二半導體結構240之一鍵結表面。在如此的組構下,該第一半導體結構130之鍵結表面之形貌具有凸形(公)組構,亦即該些元件結構106突出該第一半導體結構130,而該第二半導體結構240之鍵結表面之形貌則具有凹形(母)組構,亦即該些元件結構206被配置在伸入該第二半導體結構240之凹槽中。 Referring to FIG. 2J, the first semiconductor structure 130 can be aligned with the second semiconductor structure 240. Thus, the component structures 106 of the first semiconductor structure 130 are aligned with the component structures of the second semiconductor structure 240. 206. As described above, the exposed surface of the component structure 106 and the exposed major surface 103 of the surrounding dielectric material 102 together define a bonding surface of the first semiconductor structure 130, and the exposed surface and surrounding of the component structures 206 The exposed primary surface 214 of the additional dielectric material 212 together define a bonding surface of the second semiconductor structure 240. In such a configuration, the top surface of the bonding surface of the first semiconductor structure 130 has a convex (male) configuration, that is, the element structures 106 protrude from the first semiconductor structure 130, and the second semiconductor structure The top surface of the bonding surface of 240 has a concave (female) configuration, that is, the element structures 206 are disposed in recesses extending into the second semiconductor structure 240.

參照圖2K,將該第一半導體結構130中突出之該些元件結構106插入有該第二半導體結構240之該些元件結構206配置在其中之凹槽,該第一半導體結構130之鍵結表面便可以緊靠該第二半導體結構240之鍵結表面。在此組構中,該第一半導體結構130之該些元件結構106可以直接緊靠與其分別對應之該第二半導體結構240之該些元件結構206。在一些實施例中,毗連之該第一半導體結構130之該些元件結構106與該第二半導體結構240之該些元件結構206間,沒有提供任何中間鍵結材料(例如黏著劑)。 Referring to FIG. 2K, the component structures 106 protruding in the first semiconductor structure 130 are inserted into the recesses of the second semiconductor structures 240 in which the component structures 206 are disposed. The bonding surface of the first semiconductor structures 130 The bonding surface of the second semiconductor structure 240 can be abutted. In this configuration, the component structures 106 of the first semiconductor structure 130 can directly abut the component structures 206 of the second semiconductor structure 240 corresponding thereto. In some embodiments, between the plurality of element structures 106 of the first semiconductor structure 130 and the element structures 206 of the second semiconductor structure 240, no intermediate bonding material (eg, an adhesive) is provided.

接著,該第一半導體結構130之該些元件結構106便可以直接鍵結至該第二半導體結構240之該些元件結構206,以形成圖2K所示之鍵結 半導體結構300。此一鍵結製程會使鍵結導電結構形成,該些鍵結導電結構包含已鍵結在一起之該些元件結構106及206。該第二半導體結構240之該些元件結構206可以在導電材料對導電材料之超低溫直接鍵結製程中,直接鍵結至該第一半導體結構130之該些元件結構106,該鍵結製程係在溫度大約為攝氏200度(200℃)或更低之環境下,或甚至在溫度大約為攝氏100度(100℃)或更低之環境下實施。在一些實施例中,此種超低溫直接鍵結製程可以在溫度大約為室溫之環境下實施(亦即除周圍環境所提供之溫度外,不施加任何額外熱能)。 Then, the component structures 106 of the first semiconductor structure 130 can be directly bonded to the component structures 206 of the second semiconductor structure 240 to form the bond shown in FIG. 2K. Semiconductor structure 300. The bonding process results in the formation of a bond conductive structure comprising the component structures 106 and 206 that have been bonded together. The component structures 206 of the second semiconductor structure 240 may be directly bonded to the component structures 106 of the first semiconductor structure 130 in an ultra-low temperature direct bonding process of a conductive material to a conductive material, the bonding process being The temperature is about 200 degrees Celsius (200 ° C) or lower, or even at a temperature of about 100 degrees Celsius (100 ° C) or lower. In some embodiments, such an ultra-low temperature direct bonding process can be carried out at an ambient temperature of about room temperature (ie, without applying any additional thermal energy other than the temperature provided by the surrounding environment).

將該第一半導體結構130鍵結至該第二半導體結構240前,可對該第一半導體結構130及該第二半導體結構240進行處理,以移除表面雜質及不想要的表面化合物。 The first semiconductor structure 130 and the second semiconductor structure 240 may be processed to remove surface impurities and unwanted surface compounds prior to bonding the first semiconductor structure 130 to the second semiconductor structure 240.

在一些實施例中,該第一半導體結構130可以直接鍵結至該第二半導體結構240而不需在兩者之鍵結表面間之鍵結界面施加壓力。在其他實施例中,可以在某些超低溫直接鍵結方法中,於該些鍵結表面間之鍵結界面施加壓力,以在該鍵結界面獲致適合之鍵結強度。換言之,在本發明之一些實施例中,用於將該第一半導體結構130之該些元件結構106鍵結至該第二半導體結構240之該些元件結構206之直接鍵結方法,可以包含表面輔助鍵結(SAB)之鍵結方法。 In some embodiments, the first semiconductor structure 130 can be directly bonded to the second semiconductor structure 240 without applying pressure at the bonding interface between the bonding surfaces of the two. In other embodiments, pressure may be applied to the bonding interface between the bonding surfaces in certain ultra-low temperature direct bonding methods to achieve a suitable bonding strength at the bonding interface. In other words, in some embodiments of the present invention, the direct bonding method for bonding the component structures 106 of the first semiconductor structure 130 to the component structures 206 of the second semiconductor structure 240 may include a surface A bonding method for the auxiliary bond (SAB).

繼續參照圖2K,在一些實施例中,介於已鍵結在一起之該第一半導體結構130之該些元件結構106及該第二半導體結構240之該些元件結構206間,可以辨識出一鍵結界面302。此種鍵結界面302只有放大該鍵結半導體結構300事先準備之截面才能看見。在一些實施例中,鍵結製程完 成後有可能無法看到該鍵結界面302,即使借助於放大倍率亦然。但如圖2K所示,在本發明一些實施例中,介於已鍵結該第一半導體結構130之該些元件結構106及該第二半導體結構240之該些元件結構206間之該些鍵結界面302,可以與該第一半導體結構130與該第二半導體結構240間之一基準鍵結界面平面304分開。該基準鍵結界面平面304被定義為該第二半導體結構240之介電材料212之主要表面214緊靠該第一半導體結構130之介電材料102之主要表面103所沿著之平面。該些鍵結界面302可以與該基準鍵結界面平面304相隔一段距離,該距離至少實質上等於圖2D之距離D1及/或圖2I之距離D2Continuing to refer to FIG. 2K, in some embodiments, between the component structures 106 of the first semiconductor structure 130 and the component structures 206 of the second semiconductor structure 240 that are bonded together, one can be identified. Bonding interface 302. Such a bonding interface 302 can only be seen by amplifying the cross-section prepared by the bonding semiconductor structure 300 in advance. In some embodiments, the bonding interface 302 may not be visible after the bonding process is completed, even with the aid of magnification. However, as shown in FIG. 2K, in some embodiments of the present invention, the keys between the component structures 106 of the first semiconductor structure 130 and the component structures 206 of the second semiconductor structure 240 are bonded. The junction interface 302 can be separated from a reference bonding interface plane 304 between the first semiconductor structure 130 and the second semiconductor structure 240. The reference bonding interface plane 304 is defined as the plane along which the major surface 214 of the dielectric material 212 of the second semiconductor structure 240 abuts the major surface 103 of the dielectric material 102 of the first semiconductor structure 130. The bonding interfaces 302 may be spaced apart from the reference bonding interface plane 304 by a distance at least substantially equal to the distance D 1 of FIG. 2D and/or the distance D 2 of FIG. 2I.

如前所述,在一些實施例中,圖2I之距離D2可以大致等於圖2D之距離D1。使圖2I之距離D2大致等於圖2D之距離D1,直接鍵結製程期間,直接之實體接觸便可以在該第一半導體結構130之該些元件結構106及該第二半導體結構240之該些元件結構206間充分建立,[該實體接觸]並可獲得強化,而不會在後續之回火或其他熱處理製程(其可以改進前述元件結構間已建立鍵結)期間,因材料膨脹而發生任何問題。 As previously mentioned, in some embodiments, the distance D 2 of FIG. 2I may be substantially equal to the distance D 1 of FIG. 2D. The distance D 2 of FIG. 2I is substantially equal to the distance D 1 of FIG. 2D. During the direct bonding process, the direct physical contact may be performed on the component structures 106 and the second semiconductor structure 240 of the first semiconductor structure 130. These element structures 206 are sufficiently established that [the physical contact] can be strengthened without occurring during subsequent tempering or other heat treatment processes that can improve the bonding between the aforementioned component structures due to material expansion. any problem.

茲參照圖3A至3K,將本發明之其他實施例敘述如下。具體而言,圖3A至3E呈現圖3E所示之一第一半導體結構450之製造,圖3F至3I呈現圖3I所示之一第二半導體結構570之製造,圖3J及3K則呈現該第一半導體結構450及該第二半導體結構570在一直接鍵結製程中被鍵結在一起,以形成圖3K所示之一鍵結半導體結構600。 Referring now to Figures 3A through 3K, other embodiments of the invention are described below. Specifically, FIGS. 3A to 3E illustrate the fabrication of one of the first semiconductor structures 450 illustrated in FIG. 3E, and FIGS. 3F to 3I illustrate the fabrication of one of the second semiconductor structures 570 illustrated in FIG. 3I, and FIGS. 3J and 3K present the first A semiconductor structure 450 and the second semiconductor structure 570 are bonded together in a direct bonding process to form a bonded semiconductor structure 600 as shown in FIG. 3K.

參照圖3A,經由在如同圖2C之半導體結構120之一半導體結構上提供有圖案之一罩幕材料418,可以形成一半導體結構400。如此一來, 除該有圖案罩幕材料418之存在外,該半導體結構400至少實質上相似於該半導體結構120(圖2C)並包括一元件層401(其含有一個或多個元件結構,譬如電晶體、垂直延伸之導電通孔、水平延伸之導電跡線等等)、該元件層401上方之介電材料402,以及由配置在凹槽404內之一導電金屬405所定義並含有該導電金屬405之多個元件結構406,該些凹槽404係形成或以其他方式提供於該介電材料402中。將具有經過平坦化表面114之額外介電材料412提供於該介電材料402上,這樣,該額外介電材料412便會填滿該介電材料402之主要表面403中的任何凹陷408,以及由該些元件結構406之內凹表面407所定義之任何凹陷。該有圖案罩幕材料418可以配置在該額外介電材料412之主要表面414之上。 Referring to FIG. 3A, a semiconductor structure 400 can be formed via a mask material 418 provided on one of the semiconductor structures 120 of FIG. 2C. As a result, In addition to the presence of the patterned mask material 418, the semiconductor structure 400 is at least substantially similar to the semiconductor structure 120 (FIG. 2C) and includes an element layer 401 (which contains one or more component structures, such as a transistor, vertical An extended conductive via, a horizontally extending conductive trace, etc.), a dielectric material 402 over the component layer 401, and a conductive metal 405 disposed within the recess 404 and containing the conductive metal 405 The component structures 406 are formed or otherwise provided in the dielectric material 402. An additional dielectric material 412 having a planarized surface 114 is provided over the dielectric material 402 such that the additional dielectric material 412 fills any recess 408 in the major surface 403 of the dielectric material 402, and Any depression defined by the concave surface 407 of the element structures 406. The patterned mask material 418 can be disposed over the major surface 414 of the additional dielectric material 412.

該罩幕材料418可以地毯式沉積在該額外介電材料412之至少實質上整個主要表面414,然後被賦予圖案,以形成穿過該罩幕材料418之孔隙419(例如洞口或其他開口)。該些孔隙419可以對準該些元件結構406,如圖3A所示。在一些實施例中,該些孔隙419所具有之截面尺寸小到足以讓兩個或更多孔隙419被配置在單一元件結構406上方,並與該單一元件結構對準,如圖3A所示。該有圖案罩幕材料418有助於移除覆蓋在該些元件結構406上方之額外介電材料412之某些區域,而不會移除該額外介電材料412之其他區域。 The mask material 418 can be carpet deposited on at least substantially the entire major surface 414 of the additional dielectric material 412 and then patterned to form apertures 419 (eg, openings or other openings) through the mask material 418. The apertures 419 can be aligned with the component structures 406, as shown in Figure 3A. In some embodiments, the apertures 419 have a cross-sectional dimension that is small enough to allow two or more apertures 419 to be disposed over and aligned with the single component structure 406, as shown in FIG. 3A. The patterned mask material 418 helps to remove certain areas of the additional dielectric material 412 overlying the component structures 406 without removing other areas of the additional dielectric material 412.

該罩幕材料418可以包含,舉例而言,諸如聚甲基丙烯酸甲酯(PMMA)之一種高分子光阻材料,其可以旋轉方式沉積在一層未經固化之光阻材料上,然後透過帶有圖案之一遮罩,使該未經固化之光阻材料之某些選定區域受到電磁輻射,以使該未經固化之光阻材料中只有該些選定 區域被固化。接著,可將該光阻材料中未被固化之區域移除,以形成有圖案之罩幕材料418,如圖3A所示。在其他實施例中,該罩幕材料418可以包含諸如氮化矽(Si3N4)之一種硬罩幕材料,並可以利用像是化學氣相沉積(CVD)製程加以沉積。接著可以利用微影技術,在所沉積之硬罩幕材料上賦予圖案,以形成有圖案之罩幕材料418,如圖3A所示。不同的罩幕材料及沉積此等罩幕材料並賦予其圖案之方法,已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。 The mask material 418 can comprise, for example, a polymeric photoresist material such as polymethyl methacrylate (PMMA) that can be rotatably deposited on an uncured photoresist material and then passed through One of the patterns is masked such that certain selected areas of the uncured photoresist material are subjected to electromagnetic radiation such that only selected portions of the uncured photoresist material are cured. The uncured regions of the photoresist material can then be removed to form a patterned mask material 418, as shown in Figure 3A. In other embodiments, the mask material 418 may comprise a hard mask material such as tantalum nitride (Si 3 N 4 ) and may be deposited using a chemical vapor deposition (CVD) process. A pattern can then be applied to the deposited hard mask material using lithography to form a patterned mask material 418, as shown in Figure 3A. Different masking materials and methods of depositing such masking materials and imparting patterns thereto are known in the art to which the present invention pertains and may be employed in embodiments of the present invention.

在該額外介電材料412經過平坦化之主要表面414上形成有圖案之罩幕材料418後,便可以移除覆蓋在該些元件結構406上,透過該有圖案罩幕材料418之孔隙419而曝露出來之額外介電材料412區域,以形成圖3B所示之半導體結構420。舉例而言,在一濕式化學蝕刻製程或一乾式反應性離子蝕刻(RIE)製程中,圖3A之半導體結構400可以曝露在一種或多種蝕刻劑中。該一種或多種蝕刻劑之組成可予以選定,使其能夠蝕刻該額外介電材料412而不會移除該有圖案罩幕材料418及該導電材料405,或是使其能夠以較高速率蝕刻該額外介電材料412,此乃相對於該一種或多種蝕刻劑蝕刻該有圖案罩幕材料418及該導電材料405之速率而言,如此,該一種或多種蝕刻劑便可以移除覆蓋在該些元件結構406上,並透過該些孔隙419而曝露出來之額外介電材料412,而不至於完全蝕穿該有圖案罩幕材料418。 After the additional dielectric material 412 is patterned on the planarized major surface 414, the patterned mask material 418 can be removed over the component structures 406 through the apertures 419 of the patterned mask material 418. The additional dielectric material 412 regions are exposed to form the semiconductor structure 420 shown in FIG. 3B. For example, the semiconductor structure 400 of FIG. 3A can be exposed to one or more etchants in a wet chemical etching process or a dry reactive ion etching (RIE) process. The composition of the one or more etchants can be selected to etch the additional dielectric material 412 without removing the patterned mask material 418 and the conductive material 405, or to enable etching at a higher rate The additional dielectric material 412 is etched relative to the rate at which the patterned mask material 418 and the conductive material 405 are etched relative to the one or more etchants, such that the one or more etchants can be removed over the The additional dielectric material 412 is exposed over the component structures 406 and through the apertures 419 without completely etching through the patterned mask material 418.

繼續參照圖3B,在上文參照圖3A所述之蝕刻製程後,該有圖案罩幕材料418便可以從該半導體結構移除,以形成圖3B之半導體結構420。如該圖所示,該蝕刻製程係用於形成多個開口422,每個開口會從該額外 介電材料412之曝露主要表面414穿過該額外介電材料412,並延伸至該些元件結構406之表面407。形成該些凹槽422後,導電材料便可以提供於該些凹槽422內。 With continued reference to FIG. 3B, after the etching process described above with reference to FIG. 3A, the patterned mask material 418 can be removed from the semiconductor structure to form the semiconductor structure 420 of FIG. 3B. As shown in the figure, the etching process is used to form a plurality of openings 422, each opening from which additional The exposed primary surface 414 of the dielectric material 412 passes through the additional dielectric material 412 and extends to the surface 407 of the component structures 406. After the recesses 422 are formed, a conductive material may be provided in the recesses 422.

參照圖3C,一導電材料432可以沉積在該些凹槽422內,以形成該圖所示之半導體結構430。在一些實施例中,可以沉積過量之導電材料432,這樣,該額外介電材料412之主要表面414便會覆蓋一層導電材料432,如圖3C所示。 Referring to FIG. 3C, a conductive material 432 may be deposited in the recesses 422 to form the semiconductor structure 430 shown in the figure. In some embodiments, excess conductive material 432 can be deposited such that the major surface 414 of the additional dielectric material 412 is covered with a layer of conductive material 432, as shown in Figure 3C.

在一些實施例中,該導電材料432所具有之組成,可以至少實質上與該些元件結構406之導電材料405之組成相同。作為非限制性質之範例,該導電材料432可以包含工業級的純金屬元素,譬如銅、鋁、鎢、鉭、鈦、鉻等等,或者該導電材料432可以包含以一種或多種前述金屬元素為主的一種合金或混合物,或者該導電材料432可以包含一種導電的半導體材料(例如多晶矽)。此外,該導電材料432可以包含具有不同組成之不同區域。例如,該些開口422可以內襯一層或多層相對薄的金屬,以作為擴散阻隔層、種子層等等,而諸如銅或銅合金之主體導電金屬,則可以沉積在該薄層或該些薄層上。 In some embodiments, the conductive material 432 has a composition that is at least substantially the same as the composition of the conductive material 405 of the element structures 406. As an example of non-limiting properties, the electrically conductive material 432 may comprise industrial grade pure metal elements such as copper, aluminum, tungsten, tantalum, titanium, chromium, etc., or the electrically conductive material 432 may comprise one or more of the foregoing metallic elements. An alloy or mixture of the master, or the conductive material 432 may comprise a conductive semiconductor material (eg, polysilicon). Additionally, the electrically conductive material 432 can comprise different regions having different compositions. For example, the openings 422 may be lined with one or more layers of relatively thin metal to serve as a diffusion barrier layer, seed layer, etc., while a host conductive metal such as copper or copper alloy may be deposited on the thin layer or the thin layers. On the floor.

該導電材料432可以利用無電電鍍製程、電解電鍍製程、物理沉積製程(PVD)、化學氣相沉積(CVD)製程(包含低壓CVD或LPCVD製程)等其中一項或多項加以沉積。 The conductive material 432 can be deposited by one or more of an electroless plating process, an electrolytic plating process, a physical deposition process (PVD), a chemical vapor deposition (CVD) process (including a low pressure CVD or LPCVD process).

參照圖3D,在沉積額外之導電材料432後,便可以利用諸如化學蝕刻製程、機械研磨製程,或化學機械研磨(CMP)製程等其中一項或多項,將配置在該額外介電材料412之主要表面414上之過量導電材料432移 除,以形成圖3D所示之半導體結構440。舉例而言,該過量之導電材料432可以經由對其進行化學機械研磨(CMP)製程而移除,該製程可以進行到至少該額外介電材料412之主要表面414透過該導電材料432而曝露出來為止,如圖3D所示。過量之導電材料432移除後,該導電材料432仍有部分留在之前所形成,穿過該額外介電材料412之該些開口422內。該導電材料432之該些餘留部分形成該些元件結構406之組成凸起442(integral protrusion)。換言之,過量之導電材料432一經移除,每個元件結構406便會包含由該些開口422內之導電材料432所定義之多個組成凸起442,該些組成凸起442係自該些凹槽404內之導電材料405所定義之一基底結構延伸出來。 Referring to FIG. 3D, after depositing additional conductive material 432, one or more of such as a chemical etching process, a mechanical polishing process, or a chemical mechanical polishing (CMP) process may be utilized to configure the additional dielectric material 412. Excess conductive material 432 on major surface 414 Divide to form the semiconductor structure 440 shown in FIG. 3D. For example, the excess conductive material 432 can be removed by performing a chemical mechanical polishing (CMP) process thereon, and the process can be performed until at least the major surface 414 of the additional dielectric material 412 is exposed through the conductive material 432. So far, as shown in FIG. 3D. After the excess conductive material 432 is removed, the conductive material 432 remains partially formed prior to passing through the openings 422 of the additional dielectric material 412. The remaining portions of the electrically conductive material 432 form integral protrusions 442 of the element structures 406. In other words, once the excess conductive material 432 is removed, each of the component structures 406 includes a plurality of constituent protrusions 442 defined by the conductive material 432 in the openings 422, the constituent protrusions 442 being from the recesses. One of the base structures defined by conductive material 405 in trench 404 extends.

用於移除過量導電材料432之化學機械研磨(CMP)製程,亦可以將該額外介電材料412之曝露主要表面414變得平坦。 A chemical mechanical polishing (CMP) process for removing excess conductive material 432 may also flatten the exposed major surface 414 of the additional dielectric material 412.

參照圖3E,移除過量之導電材料432後,便可將從側面圍繞著該些組成凸起442之額外介電材料412之至少一部分移除,以致使該些組成凸起442從該介電材料402之曝露表面403及/或該額外介電材料412之曝露表面414突出預先選定之一段距離D3,如圖3E所示,並形成前文提及之第一半導體結構450。 Referring to FIG. 3E, after removing the excess conductive material 432, at least a portion of the additional dielectric material 412 surrounding the constituent protrusions 442 may be removed from the side to cause the constituent protrusions 442 to be removed from the dielectric. the exposed surface of material 403 402, and / or the further dielectric material 412, the exposed surface 414 projecting one of the preselected segment distance D 3, as shown in FIG 3E, the first semiconductor structure 450 and the previously mentioned is formed.

在一些實施例中,該距離D3可以介於大約二分之一奈米(0.5nm)及大約50奈米(50nm)之間、介於大約1奈米(1nm)及大約10奈米(10nm)之間,或甚至介於大約2奈米(2nm)及大約7奈米(7nm)之間。 In some embodiments, the distance D 3 can be between about one-half nanometer (0.5 nm) and about 50 nanometers (50 nm), between about 1 nanometer (1 nm) and about 10 nanometers ( Between 10 nm), or even between about 2 nm (2 nm) and about 7 nm (7 nm).

該些元件結構406之組成凸起442之曝露表面、周圍介電材料402之曝露主要表面403,及/或該額外介電材料412之曝露表面414一同定義出該第一半導體結構450之一鍵結表面,該鍵結表面將會緊靠並鍵結至圖3I所示之第二半導體結構570之一互補鍵結表面。 The exposed surface of the component 442, the exposed surface of the protrusion 442, the exposed major surface 403 of the surrounding dielectric material 402, and/or the exposed surface 414 of the additional dielectric material 412 together define a bond of the first semiconductor structure 450. At the junction surface, the bonding surface will abut and bond to the complementary bonding surface of one of the second semiconductor structures 570 shown in FIG.

繼續參照圖3E,該些元件結構406之組成凸起442、被配置為與該些組成凸起442相鄰之介電材料402,及被配置為與該些組成凸起442相鄰之額外介電材料412,均曝露在該第一半導體結構450之鍵結表面。此外,如圖3E所示,該額外介電材料412之部分被配置為與該些元件結構406相鄰,並在該些組成凸起442間覆蓋住該些元件結構406之一部分。該介電材料402之曝露主要表面403及該額外介電材料412之曝露主要表面414定義出該第一半導體結構450之一鍵結平面452。該鍵結平面452可以包含該第一半導體結構450及該第二半導體結構570鍵結在一起後,該第一半導體結構450與該第二半導體結構570(圖3I)間之鍵結界面之至少大部分所沿著延伸之平面,如下文參照圖3J及3K所詳述。 Continuing to refer to FIG. 3E, the constituent structures 406 of the component structures 406, the dielectric material 402 disposed adjacent to the constituent bumps 442, and the additional dielectrics disposed adjacent to the constituent bumps 442 Electrical material 412 is exposed to the bonding surface of the first semiconductor structure 450. In addition, as shown in FIG. 3E, portions of the additional dielectric material 412 are disposed adjacent to the component structures 406 and cover a portion of the component structures 406 between the constituent bumps 442. The exposed major surface 403 of the dielectric material 402 and the exposed major surface 414 of the additional dielectric material 412 define a bonding plane 452 of the first semiconductor structure 450. The bonding plane 452 can include at least the bonding interface between the first semiconductor structure 450 and the second semiconductor structure 570 (FIG. 3I) after the first semiconductor structure 450 and the second semiconductor structure 570 are bonded together. Most of the plane along the extension is as detailed below with reference to Figures 3J and 3K.

茲參照圖3F至3I,將可用於形成圖3I之第二半導體結構570之一示範性方法敘述如下。 Referring now to Figures 3F through 3I, an exemplary method that can be used to form the second semiconductor structure 570 of Figure 3I is described below.

參照圖3F,提供一半導體結構500,該半導體結構至少實質上類似於圖3D之半導體結構440。因此,該半導體結構500可以包含一元件層501,其含有一個或多個元件結構,譬如電晶體、垂直延伸之導電通孔、水平延伸之導電跡線等等。該半導體結構500包含被配置於該元件層501上之一介電材料502,以及至少局部被該介電材料502所圍繞之元件結構506。 該導電金屬505所具有之組成,可以如前文中關於圖2A之導電材料105所述。 Referring to FIG. 3F, a semiconductor structure 500 is provided that is at least substantially similar to the semiconductor structure 440 of FIG. 3D. Thus, the semiconductor structure 500 can include an element layer 501 that contains one or more element structures, such as a transistor, vertically extending conductive vias, horizontally extending conductive traces, and the like. The semiconductor structure 500 includes a dielectric material 502 disposed on the element layer 501 and an element structure 506 at least partially surrounded by the dielectric material 502. The conductive metal 505 has a composition as described above with respect to the conductive material 105 of FIG. 2A.

該半導體結構500更包含配置在該介電材料502之表面503上之一額外介電材料512。該些元件結構506中的每一個元件結構,均包含自一基底結構延伸出來之多個組成凸起542,該基底結構係由伸入該介電材料502之凹槽504內之導電材料505所定義。該些組成凸起542係由配置在開口522內之導電材料532所定義,該些開口522穿過該額外介電材料512。該導電材料532之組成,可以與該導電材料505之組成相同或不同。如圖3F所示,該額外介電材料512之一主要表面514及該些元件結構506之組成凸起542均曝露在該半導體結構500上。 The semiconductor structure 500 further includes an additional dielectric material 512 disposed on a surface 503 of the dielectric material 502. Each of the element structures 506 includes a plurality of constituent protrusions 542 extending from a substrate structure, the substrate structure being formed by a conductive material 505 extending into the recess 504 of the dielectric material 502. definition. The constituent protrusions 542 are defined by conductive material 532 disposed within openings 522 that pass through the additional dielectric material 512. The composition of the conductive material 532 may be the same as or different from the composition of the conductive material 505. As shown in FIG. 3F, one of the main surface 514 of the additional dielectric material 512 and the constituent protrusions 542 of the element structures 506 are exposed on the semiconductor structure 500.

參照圖3G,經由在該額外介電材料512之表面514上提供一額外介電材料552,可以由圖3F之半導體結構500形成一半導體結構550。如圖3G所示,在該額外介電材料512上可以提供另一層額外介電材料552至所需之平均厚度。該額外介電材料552所具有之組成及組構(例如平均厚度),可以如前文中參照圖2B有關額外介電材料112部分所揭露。 Referring to FIG. 3G, a semiconductor structure 550 can be formed from the semiconductor structure 500 of FIG. 3F by providing an additional dielectric material 552 over the surface 514 of the additional dielectric material 512. As shown in FIG. 3G, another layer of additional dielectric material 552 may be provided on the additional dielectric material 512 to the desired average thickness. The composition and composition (e.g., average thickness) of the additional dielectric material 552 can be as disclosed above with respect to the additional dielectric material 112 portion of FIG. 2B.

沉積該額外介電材料552後,可以選擇性地將該額外介電材料552之曝露主要表面554加以平坦化。舉例而言,可以對該額外介電材料552之曝露主要表面554進行化學蝕刻製程、機械研磨製程,或化學機械研磨(CMP)製程的其中一項或多項,以使該額外介電材料552之曝露主要表面554變得平坦。在一些實施例中,該曝露主要表面554在平坦化製程後所具有之均方根(RMS)表面粗度可以為大約二分之一奈米(0.5nm)或 更低、大約十分之二奈米(0.2nm)或更低,或甚至大約十分之一奈米(0.1nm)或更低。 After depositing the additional dielectric material 552, the exposed major surface 554 of the additional dielectric material 552 can be selectively planarized. For example, the exposed main surface 554 of the additional dielectric material 552 may be subjected to one or more of a chemical etching process, a mechanical polishing process, or a chemical mechanical polishing (CMP) process to cause the additional dielectric material 552 The exposed major surface 554 becomes flat. In some embodiments, the exposed major surface 554 may have a root mean square (RMS) surface roughness of about one-half nanometer (0.5 nm) after the planarization process or Lower, about two tenths of a nanometer (0.2 nm) or less, or even about one tenth of a nanometer (0.1 nm) or less.

參照圖3H,該額外介電材料552之曝露主要表面554平坦化之後,便可以在經過平坦化之曝露主要表面554上提供帶有圖案之一罩幕材料562,以形成圖3H所示之半導體結構560。該罩幕材料562可以地毯式沉積在至少實質上整個曝露主要表面554上,然後被賦予圖案,以形成穿過該罩幕材料562之孔隙564(例如洞口或其他開口)。該些孔隙564可以對準該些元件結構506之組成凸起542,如圖3H所示。此外,該些孔隙564所具有之尺寸及形狀,可以對應於其下方該些元件結構506之組成凸起542之尺寸及形狀。被賦予圖案之罩幕材料562有助於移除覆蓋在該些元件結構506之組成凸起542上方之額外介電材料552區域,而不會移除該額外介電材料552之其他區域及該些元件結構506。 Referring to FIG. 3H, after the exposed main surface 554 of the additional dielectric material 552 is planarized, a patterned mask material 562 may be provided on the planarized exposed main surface 554 to form the semiconductor shown in FIG. 3H. Structure 560. The masking material 562 can be carpet deposited over at least substantially the entire exposed major surface 554 and then patterned to form apertures 564 (eg, openings or other openings) through the masking material 562. The apertures 564 can be aligned with the constituent protrusions 542 of the component structures 506, as shown in Figure 3H. In addition, the apertures 564 have dimensions and shapes that correspond to the size and shape of the constituent protrusions 542 of the component structures 506 beneath them. The patterned mask material 562 facilitates removal of additional dielectric material 552 overlying the constituent bumps 542 of the component structures 506 without removing other regions of the additional dielectric material 552 and These component structures 506.

該罩幕材料562可以包含,舉例而言,諸如聚甲基丙烯酸甲酯(PMMA)之一種高分子光阻材料,其可以旋轉方式沉積在一層未經固化之光阻材料上,然後透過帶有圖案之一遮罩,使該未經固化之光阻材料之某些選定區域受到電磁輻射,以使該未經固化之光阻材料中只有該些選定區域被固化。接著,可將該光阻材料中未被固化之區域移除,以形成有圖案之罩幕材料562,如圖3H所示。在其他實施例中,該罩幕材料562可以包含諸如氮化矽(Si3N4)之一種硬罩幕材料,並可以利用像是化學氣相沉積(CVD)製程加以沉積。接著可以利用微影技術,在所沉積之硬罩幕材料上賦予圖案,以形成有圖案之罩幕材料562,如圖3H所示。不同的 罩幕材料及沉積此等罩幕材料並賦予其圖案之方法,已為本發明所屬技術領域所知,且可以為本發明之實施例所採用。 The mask material 562 can comprise, for example, a polymeric photoresist material such as polymethyl methacrylate (PMMA) that can be rotatably deposited on an uncured photoresist material and then passed through One of the patterns is masked such that certain selected areas of the uncured photoresist material are subjected to electromagnetic radiation such that only selected portions of the uncured photoresist material are cured. The uncured regions of the photoresist material can then be removed to form a patterned mask material 562, as shown in Figure 3H. In other embodiments, the mask material 562 may comprise a hard mask material such as tantalum nitride (Si 3 N 4 ) and may be deposited using a chemical vapor deposition (CVD) process. A lithographic technique can then be used to impart a pattern on the deposited hard mask material to form a patterned mask material 562, as shown in Figure 3H. Different masking materials and methods of depositing such masking materials and imparting patterns thereto are known in the art to which the present invention pertains and may be employed in embodiments of the present invention.

在該額外介電材料552之曝露主要表面554上形成有圖案之罩幕材料562後,便可以移除覆蓋在該些元件結構506之組成凸起542上,透過該有圖案罩幕材料562之孔隙564而曝露出來之額外介電材料552區域,如圖3I之半導體結構570所示。舉例而言,在一濕式化學蝕刻製程或一乾式反應性離子蝕刻(RIE)製程中,圖3H之半導體結構560可以曝露在一種或多種蝕刻劑中。該一種或多種蝕刻劑之組成可予以選定,使其能夠蝕刻該額外介電材料552而不會移除該有圖案罩幕材料562及該些元件結構506,或是使其能夠以較高速率蝕刻該額外介電材料552,此乃相對於該一種或多種蝕刻劑蝕刻該有圖案罩幕材料562及該些元件結構506之速率而言,如此,該一種或多種蝕刻劑便可以移除覆蓋在該些元件結構506之組成凸起542上之額外介電材料552,而不至於完全蝕穿該有圖案罩幕材料562。 After the patterned mask material 562 is formed on the exposed major surface 554 of the additional dielectric material 552, the constituent protrusions 542 overlying the component structures 506 can be removed and transmitted through the patterned mask material 562. The additional dielectric material 552 regions exposed by the voids 564 are shown in the semiconductor structure 570 of FIG. 3I. For example, the semiconductor structure 560 of FIG. 3H can be exposed to one or more etchants in a wet chemical etching process or a dry reactive ion etching (RIE) process. The composition of the one or more etchants can be selected to enable etching of the additional dielectric material 552 without removing the patterned mask material 562 and the component structures 506, or enabling them to be at a higher rate Etching the additional dielectric material 552 in relation to the rate at which the patterned mask material 562 and the element structures 506 are etched relative to the one or more etchants, such that the one or more etchants can be removed and covered. The additional dielectric material 552 on the features 542 of the component structures 506 is not completely etched through the patterned mask material 562.

將覆蓋於該些元件結構506之組成凸起542上,透過該有圖案罩幕材料562之孔隙564而曝露出來之額外介電材料552區域在一蝕刻製程中移除後,該有圖案罩幕材料562便可予以移除,如圖3I所示。在一些實施例中,該額外介電材料552之曝露主要表面554在此蝕刻製程後所具有之均方根(RMS)表面粗度可以為大約二分之一奈米(0.5nm)或更低、大約十分之二奈米(0.2nm)或更低,或甚至大約十分之一奈米(0.1nm)或更低。 The patterned mask will be overlaid on the constituent protrusions 542 of the component structures 506, and the additional dielectric material 552 exposed through the apertures 564 of the patterned mask material 562 is removed in an etching process. Material 562 can be removed, as shown in Figure 3I. In some embodiments, the exposed major surface 554 of the additional dielectric material 552 has a root mean square (RMS) surface roughness of about one-half nanometer (0.5 nm) or less after the etching process. About two tenths of a nanometer (0.2 nm) or less, or even about one tenth of a nanometer (0.1 nm) or less.

此外,用於將覆蓋於該些元件結構506之組成凸起542上,透過該有圖案罩幕材料562之孔隙564而曝露出來之額外介電材料552區域移除之蝕刻製程,可以致使該些元件結構506之組成凸起542之曝露表面相對於周圍額外介電材料552之曝露表面554而凹陷預先選定之一段距離D4,如圖3I所示。 In addition, an etching process for covering the constituent bumps 542 of the component structures 506 and removing the additional dielectric material 552 exposed through the voids 564 of the patterned mask material 562 may result in the etching process. The exposed surface of the component bump 542 of the component structure 506 is recessed a predetermined distance D 4 relative to the exposed surface 554 of the surrounding additional dielectric material 552, as shown in FIG. 3I.

作為非限制性之範例,該距離D4可以介於大約二分之一奈米(0.5nm)及大約50奈米(50nm)之間、介於大約1奈米(1nm)及大約10奈米(10nm)之間,或甚至介於大約2奈米(2nm)及大約7奈米(7nm)之間。 As a non-limiting example, the distance D 4 can be between about one-half nanometer (0.5 nm) and about 50 nanometers (50 nm), between about 1 nanometer (1 nm) and about 10 nm. Between (10 nm), or even between about 2 nm (2 nm) and about 7 nm (7 nm).

在一些實施例中,圖3I之距離D4可以至少實質上等於圖3E之距離D3。但在其他實施例中,圖3I之距離D4可以大於圖3E之距離D3。舉例而言,圖3E之距離D3可以介於圖3I之距離D4之大約80%至大約99%之間,或者,更具體而言,可以介於圖3I之距離D4之大約90%至大約98%之間。 In some embodiments, the distance D 4 of FIG. 3I can be at least substantially equal to the distance D 3 of FIG. 3E. However, in other embodiments, the distance D 4 of FIG. 3I may be greater than the distance D 3 of FIG. 3E. For example, the distance D in FIG. 3 3E may be interposed between the distance D of FIG. 3I 4 of about 80% to about 99%, or, more specifically, the distance D between FIG. 3I 4 of about 90% To about 98%.

該額外介電材料552之曝露主要表面554及該些元件結構506之組成凸起542之曝露表面一同定義出該第二半導體結構570之一鍵結表面,該鍵結表面將會緊靠並鍵結至圖3E之第一半導體結構450之互補鍵結表面。 The exposed major surface 554 of the additional dielectric material 552 and the exposed surface of the constituent protrusions 542 of the component structures 506 together define a bonding surface of the second semiconductor structure 570, the bonding surface will be close to the bonding key The junction is bonded to the complementary bonding surface of the first semiconductor structure 450 of FIG. 3E.

繼續參照圖3I,該些元件結構506之組成凸起542及該額外介電材料552均曝露在該第二半導體結構570之鍵結表面。該額外介電材料552之曝露主要表面554定義出該第二半導體結構570之一鍵結平面572。該鍵結平面572可以包含該第一半導體結構450及該第二半導體結構570鍵結 在一起後,該第一半導體結構450(圖3E)與該第二半導體結構570間之鍵結界面之至少大部分所沿著延伸之平面,如下文參照圖3J及3K所詳述。 Continuing to refer to FIG. 3I, the constituent bumps 542 of the element structures 506 and the additional dielectric material 552 are exposed on the bonding surface of the second semiconductor structure 570. The exposed primary surface 554 of the additional dielectric material 552 defines a bonding plane 572 of the second semiconductor structure 570. The bonding plane 572 can include the first semiconductor structure 450 and the second semiconductor structure 570 bonded Together, at least a majority of the bonding interface between the first semiconductor structure 450 (Fig. 3E) and the second semiconductor structure 570 is along the plane of extension, as described in more detail below with respect to Figures 3J and 3K.

參照圖3J,可以將該第一半導體結構450對準該第二半導體結構570,這樣,該第一半導體結構450中該些元件結構406之組成凸起442便會對準該第二半導體結構570中該些元件結構506之組成凸起542。如前所述,該些元件結構406之組成凸起442之曝露表面及周圍介電材料402之曝露主要表面403一同構成該第一半導體結構450之鍵結表面,且該些元件結構506之組成凸起542之曝露表面及周圍額外介電材料552之曝露主要表面554一同構成該第二半導體結構570之鍵結表面。在如此的組構下,該第一半導體結構450之鍵結表面之形貌具有凸形(公)組構,亦即該些元件結構406之組成凸起442突出該第一半導體結構450,而該第二半導體結構570之鍵結表面之形貌則具有凹形(母)組構,亦即該些元件結構506之組成凸起542被配置在伸入該第二半導體結構570之凹槽中。 Referring to FIG. 3J, the first semiconductor structure 450 can be aligned with the second semiconductor structure 570 such that the constituent protrusions 442 of the element structures 406 in the first semiconductor structure 450 are aligned with the second semiconductor structure 570. The component structures 506 are formed by protrusions 542. As described above, the exposed surface of the component 442 and the exposed main surface 403 of the surrounding dielectric material 402 together form the bonding surface of the first semiconductor structure 450, and the components 506 are formed. The exposed surface of the bump 542 and the exposed major surface 554 of the additional dielectric material 552 together form the bonding surface of the second semiconductor structure 570. In such a configuration, the top surface of the bonding surface of the first semiconductor structure 450 has a convex (male) configuration, that is, the constituent protrusions 442 of the element structures 406 protrude from the first semiconductor structure 450. The top surface of the bonding surface of the second semiconductor structure 570 has a concave (female) configuration, that is, the constituent protrusions 542 of the element structures 506 are disposed in the recesses of the second semiconductor structure 570. .

參照圖3K,將該第一半導體結構450中該些元件結構406之突出組成凸起442插入有該第二半導體結構570中該些元件結構506之組成凸起542配置在其中之凹槽,該第一半導體結構450之鍵結表面便可以緊靠該第二半導體結構570之鍵結表面。在此組構中,該第一半導體結構450中該些元件結構406之突出組成凸起442可以直接緊靠與其分別對應之該第二半導體結構570中該些元件結構506之組成凸起542。在一些實施例中,毗連之該第一半導體結構450中該些元件結構406之突出組成凸起442與該第二半導體結構570中該些元件結構506之組成凸起542間,沒有提供任何中間鍵結材料(例如黏著劑)。 Referring to FIG. 3K, the protruding features 442 of the element structures 406 in the first semiconductor structure 450 are inserted into the recesses of the second semiconductor structure 570 in which the constituent protrusions 542 of the element structures 506 are disposed. The bonding surface of the first semiconductor structure 450 can abut the bonding surface of the second semiconductor structure 570. In this configuration, the protruding constituent protrusions 442 of the element structures 406 in the first semiconductor structure 450 may directly abut the constituent protrusions 542 of the element structures 506 in the second semiconductor structure 570 corresponding thereto. In some embodiments, the protruding constituents 442 of the component structures 406 in the first semiconductor structure 450 and the constituent bumps 542 of the component structures 506 in the second semiconductor structure 570 are not provided with any intermediate portions. Bonding material (eg adhesive).

接著,該第一半導體結構450中該些元件結構406之組成凸起442便可以直接鍵結至該第二半導體結構570中該些元件結構506之組成凸起542,以形成圖3K所示之鍵結半導體結構600。此一鍵結製程會使鍵結導電結構形成,該些鍵結導電結構包含已鍵結在一起之該些元件結構406及506。該第二半導體結構570中該些元件結構506之組成凸起542可以在導電材料對導電材料之超低溫直接鍵結製程中,直接鍵結至該第一半導體結構450中該些元件結構406之組成凸起442,該鍵結製程係在溫度大約為攝氏200度(200℃)或更低之環境下,或甚至在溫度大約為攝氏100度(100℃)或更低之環境下實施。在一些實施例中,此種超低溫直接鍵結製程可以在溫度大約為室溫之環境下實施(亦即除周圍環境所提供之溫度外,不施加任何額外熱能)。 Then, the constituent protrusions 442 of the element structures 406 in the first semiconductor structure 450 can be directly bonded to the constituent protrusions 542 of the element structures 506 in the second semiconductor structure 570 to form the structure shown in FIG. 3K. The semiconductor structure 600 is bonded. The bonding process results in the formation of a bond conductive structure comprising the component structures 406 and 506 that have been bonded together. The constituent protrusions 542 of the component structures 506 in the second semiconductor structure 570 can be directly bonded to the components of the component structures 406 in the first semiconductor structure 450 in an ultra-low temperature direct bonding process of conductive materials to conductive materials. The bumps 442 are implemented in an environment having a temperature of about 200 degrees Celsius (200 ° C) or less, or even at a temperature of about 100 degrees Celsius (100 ° C) or less. In some embodiments, such an ultra-low temperature direct bonding process can be carried out at an ambient temperature of about room temperature (ie, without applying any additional thermal energy other than the temperature provided by the surrounding environment).

將該第一半導體結構450鍵結至該第二半導體結構570前,可對該第一半導體結構450及該第二半導體結構570進行處理,以移除表面雜質及不想要的表面化合物。 Prior to bonding the first semiconductor structure 450 to the second semiconductor structure 570, the first semiconductor structure 450 and the second semiconductor structure 570 can be processed to remove surface impurities and unwanted surface compounds.

在一些實施例中,該第一半導體結構450可以直接鍵結至該第二半導體結構570而不需在兩者之鍵結表面間之鍵結界面施加壓力。在其他實施例中,可以在某些超低溫直接鍵結方法中,於該些鍵結表面間之鍵結界面施加壓力,以在該鍵結界面獲致適合之鍵結強度。換言之,在本發明之一些實施例中,用於將該第一半導體結構中該些元件結構406之組成凸起442鍵結至該第二半導體結構570中該些元件結構506之組成凸起542之直接鍵結方法,可以包含表面輔助鍵結(SAB)之鍵結方法。 In some embodiments, the first semiconductor structure 450 can be directly bonded to the second semiconductor structure 570 without applying pressure at the bonding interface between the bonding surfaces of the two. In other embodiments, pressure may be applied to the bonding interface between the bonding surfaces in certain ultra-low temperature direct bonding methods to achieve a suitable bonding strength at the bonding interface. In other words, in some embodiments of the present invention, the constituent protrusions 442 of the element structures 406 in the first semiconductor structure are bonded to the constituent protrusions 542 of the element structures 506 in the second semiconductor structure 570. The direct bonding method may include a surface assist bonding (SAB) bonding method.

繼續參照圖3K,在一些實施例中,介於已鍵結在一起之該第一半導體結構450中該些元件結構406之組成凸起442及該第二半導體結構570中該些元件結構506之組成凸起542間,可以辨識出一鍵結界面602。此種鍵結界面602只有放大該鍵結半導體結構600事先準備之截面才能看見。在一些實施例中,鍵結製程完成後有可能無法看到該些鍵結界面602,即使借助於放大倍率亦然。但如圖3K所示,在本發明一些實施例中,介於已鍵結在一起之該第一半導體結構450中該些元件結構406之組成凸起442及該第二半導體結構570中該些元件結構506之組成凸起542間之該些鍵結界面602,可以與該第一半導體結構450與該第二半導體結構570間之一基準鍵結界面平面604分開。該基準鍵結界面平面604被定義為該第二半導體結構570之介電材料552之主要表面554緊靠該第一半導體結構450之介電材料402之主要表面403所沿著之平面。該些鍵結界面602可以與該基準鍵結界面平面604相隔一段距離,該距離至少實質上等於圖3E之距離D3及/或圖3I之距離D4With continued reference to FIG. 3K, in some embodiments, the constituent protrusions 442 of the element structures 406 and the element structures 506 of the second semiconductor structure 570 are interposed in the first semiconductor structure 450 that has been bonded together. Between the protrusions 542, a bonding interface 602 can be identified. Such a bonding interface 602 can only be seen by amplifying the cross-section prepared by the bonding semiconductor structure 600 in advance. In some embodiments, the bonding interfaces 602 may not be visible after the bonding process is completed, even with the aid of magnification. However, as shown in FIG. 3K, in some embodiments of the present invention, the constituent protrusions 442 of the element structures 406 and the second semiconductor structures 570 in the first semiconductor structure 450 that have been bonded together The bonding interfaces 602 between the constituent protrusions 542 of the component structure 506 may be separated from the reference bonding interface plane 604 between the first semiconductor structure 450 and the second semiconductor structure 570. The reference bonding interface plane 604 is defined as the plane along which the major surface 554 of the dielectric material 552 of the second semiconductor structure 570 abuts the major surface 403 of the dielectric material 402 of the first semiconductor structure 450. The bonding interfaces 602 can be spaced apart from the reference bonding interface plane 604 by a distance at least substantially equal to the distance D 3 of FIG. 3E and/or the distance D 4 of FIG. 3I.

在本發明之額外實施例中,該第一及第二半導體結構中直接鍵結在一起之導電元件結構間之已鍵結界面,可以至少實質上與該第一及第二半導體結構間之基準鍵結界面共平面。茲參照圖4A及4B,將此等實施例之非限制性質範例敘述如下。具體而言,圖4A及4B呈現一第一半導體結構440(如前文關於圖3D所述者)及一第二半導體結構500(如前文關於圖3F所述者,其在一些實施例中可以至少實質上類似於該第一半導體結構440)之直接鍵結,以形成圖4B所示之鍵結半導體結構700。 In an additional embodiment of the present invention, the bonded interface between the conductive element structures directly bonded together in the first and second semiconductor structures may be at least substantially substantially between the first and second semiconductor structures. The bonding interface is coplanar. 4A and 4B, examples of non-limiting properties of these embodiments are described below. In particular, Figures 4A and 4B present a first semiconductor structure 440 (as previously described with respect to Figure 3D) and a second semiconductor structure 500 (as previously described with respect to Figure 3F, which in some embodiments may be at least The direct bonding is substantially similar to the first semiconductor structure 440) to form the bonded semiconductor structure 700 shown in FIG. 4B.

參照圖4A,可以將該第一半導體結構440對準該第二半導體結構500,這樣,該第一半導體結構440中該些元件結構406之組成凸起442便會對準該第二半導體結構500中該些元件結構506之組成凸起542。該些元件結構406之組成凸起442之曝露表面及周圍額外介電材料412之曝露主要表面414一同定義出該第一半導體結構440之至少實質上平坦之一鍵結表面,且該些元件結構506之組成凸起542之曝露表面及周圍額外介電材料512之曝露主要表面514一同定義出該第二半導體結構500之至少實質上平坦之一鍵結表面。 Referring to FIG. 4A, the first semiconductor structure 440 can be aligned with the second semiconductor structure 500. Thus, the constituent protrusions 442 of the element structures 406 in the first semiconductor structure 440 are aligned with the second semiconductor structure 500. The component structures 506 are formed by protrusions 542. The exposed surface of the component 442 and the exposed major surface 414 of the additional dielectric material 412 together define at least one substantially flat bonding surface of the first semiconductor structure 440, and the component structures The exposed surface of the raised protrusion 542 of 506 and the exposed primary surface 514 of the surrounding additional dielectric material 512 together define at least one substantially flat bonding surface of the second semiconductor structure 500.

參照圖4B,可以將該第一半導體結構440之鍵結表面緊靠該第二半導體結構500之鍵結表面,這樣,該第一半導體結構440中該些元件結構406之組成凸起442便會直接緊靠並直接實體接觸該第二半導體結構500中該些元件結構506之組成凸起542,而無任何中間鍵結材料(例如黏著劑)在兩者之間。 Referring to FIG. 4B, the bonding surface of the first semiconductor structure 440 may be in close contact with the bonding surface of the second semiconductor structure 500. Thus, the constituent protrusions 442 of the component structures 406 in the first semiconductor structure 440 will be The constituent protrusions 542 of the element structures 506 in the second semiconductor structure 500 are directly abutted and directly in physical contact without any intermediate bonding material (such as an adhesive) therebetween.

接著,可以將該第一半導體結構440中該些元件結構406之組成凸起442直接鍵結至該第二半導體結構500中該些元件結構506之組成凸起542,以形成圖4B之鍵結半導體結構700。該鍵結製程之實施,可以如前文中參照圖2K及3K所述。 Then, the constituent protrusions 442 of the element structures 406 in the first semiconductor structure 440 can be directly bonded to the constituent protrusions 542 of the element structures 506 in the second semiconductor structure 500 to form the bonding of FIG. 4B. Semiconductor structure 700. The bonding process can be implemented as described above with reference to Figures 2K and 3K.

在圖4A及4B之該些實施例中,介於已鍵結之該第一半導體結構440中該些元件結構406之組成凸起442及該第二半導體結構500中該些元件結構506之組成凸起542間之該些鍵結界面702,可以至少實質上與該第一半導體結構440及該第二半導體結構500間之一基準鍵結界面平面704共平面,如圖4B所示。該基準鍵結界面平面704被定義為該第二半 導體結構500之介電材料512之主要表面514緊靠該第一半導體結構440之介電材料412之主要表面414所沿著之平面。 In the embodiments of FIGS. 4A and 4B, the constituent protrusions 442 of the component structures 406 and the components of the component structures 506 of the second semiconductor structure 500 in the bonded first semiconductor structure 440 The bonding interfaces 702 between the protrusions 542 may be at least substantially coplanar with a reference bonding interface plane 704 between the first semiconductor structure 440 and the second semiconductor structure 500, as shown in FIG. 4B. The reference keying interface plane 704 is defined as the second half The major surface 514 of the dielectric material 512 of the conductor structure 500 abuts the plane along the major surface 414 of the dielectric material 412 of the first semiconductor structure 440.

茲將本發明其他非限制性質之示範性實施例敘述如下: Exemplary embodiments of other non-limiting properties of the invention are described below:

實施例1:一種將一第一半導體結構直接鍵結至一第二半導體結構之方法,其包括:提供一第一半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料且曝露在該第一半導體結構之一鍵結表面上,該介電材料亦曝露在該第一半導體結構之鍵結表面上且被配置為與該第一半導體結構之該至少一個元件結構相鄰,在該第一半導體結構之鍵結表面上,該介電材料之一曝露表面定義出該第一半導體結構之一鍵結平面;致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料;提供一第二半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料且曝露在該第二半導體結構之一鍵結表面上,該介電材料亦曝露在該第二半導體結構之鍵結表面上且被配置為與該第二半導體結構之該至少一個元件結構相鄰,在該第二半導體結構之鍵結表面上,該介電材料之一曝露表面定義出該第二半導體結構之一鍵結平面;以及在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 Embodiment 1 : A method of directly bonding a first semiconductor structure to a second semiconductor structure, comprising: providing a first semiconductor structure including at least one device structure and a dielectric material, the at least one component The structure includes a conductive material and is exposed on a bonding surface of the first semiconductor structure, the dielectric material also being exposed on the bonding surface of the first semiconductor structure and configured to be at least with the first semiconductor structure An element structure is adjacent, on an bonding surface of the first semiconductor structure, an exposed surface of the dielectric material defines a bonding plane of the first semiconductor structure; causing the at least one element in the first semiconductor structure The structure protrudes from the bonding plane of the first semiconductor structure a distance beyond the adjacent dielectric material; providing a second semiconductor structure including at least one component structure and a dielectric material, the at least one component structure including Conductive material and exposed on a bonding surface of the second semiconductor structure, the dielectric material also exposed to the bond of the second semiconductor structure a surface of the junction and configured to be adjacent to the at least one element structure of the second semiconductor structure, on an bonding surface of the second semiconductor structure, an exposed surface of the dielectric material defines the second semiconductor structure a bonding plane; and in the direct bonding process of the conductive material to the conductive material, the at least one element structure in the first semiconductor structure is directly bonded to the at least one element structure in the second semiconductor structure.

實施例2:如實施例1之方法,其中致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料包含從該第一半導體結構移除該介電材料之一部分。 Embodiment 2: The method of Embodiment 1, wherein the at least one element structure in the first semiconductor structure is caused to protrude from the bonding plane of the first semiconductor structure by a distance beyond the adjacent dielectric material from the first The semiconductor structure removes a portion of the dielectric material.

實施例3:如實施例2之方法,其中從該第一半導體結構移除該介電材料之一部分包含蝕刻該介電材料。 Embodiment 3. The method of Embodiment 2 wherein removing a portion of the dielectric material from the first semiconductor structure comprises etching the dielectric material.

實施例4:如實施例1至3中任一項之方法,其中致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離包含致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出預先選定之一段距離。 The method of any one of embodiments 1 to 3, wherein causing the at least one element structure in the first semiconductor structure to protrude from a bonding plane of the first semiconductor structure a distance comprises causing the first semiconductor structure The at least one component structure protrudes from the bonding plane of the first semiconductor structure by a predetermined distance.

實施例5:如實施例1至4中任一項之方法,其更包括致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷一段距離,凹入伸進相鄰介電材料之一凹槽。 The method of any one of embodiments 1 to 4, further comprising causing the at least one element structure in the second semiconductor structure to be recessed from the bonding plane of the second semiconductor structure by a distance, recessed into One of the adjacent dielectric materials is a groove.

實施例6:如實施例5之方法,其中致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷一段距離,凹入伸進相鄰介電材料之一凹槽包括:在該第二半導體結構中該至少一個元件結構上沉積該介電材料;以及蝕穿該介電材料直至該至少一個元件結構。 Embodiment 6: The method of Embodiment 5, wherein the at least one element structure in the second semiconductor structure is caused to be recessed from the bonding plane of the second semiconductor structure by a distance, recessed into a recess of the adjacent dielectric material The trench includes: depositing the dielectric material on the at least one component structure in the second semiconductor structure; and etching the dielectric material up to the at least one component structure.

實施例7:如實施例5或實施例6之方法,其中致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷一段距離,凹入伸進相鄰介電材料之一凹槽包括致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷預先選定之一段距離。 Embodiment 7: The method of Embodiment 5 or Embodiment 6, wherein the at least one element structure in the second semiconductor structure is caused to be recessed from the bonding plane of the second semiconductor structure by a distance, recessed into the adjacent dielectric One of the grooves of the material includes a pre-selected distance of the at least one element structure of the second semiconductor structure from the bonding plane of the second semiconductor structure.

實施例8:如實施例5至7中任一項之方法,其中將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括將該第一半導體結構中該至少一個元件結構插入該第二半導體結構之介電材料中之凹槽。 The method of any one of embodiments 5 to 7, wherein the at least one element structure of the first semiconductor structure is directly bonded to the second semiconductor structure, the at least one element structure comprising the first The at least one component structure of the semiconductor structure is inserted into a recess in the dielectric material of the second semiconductor structure.

實施例9:如實施例1至8中任一項之方法,其更包括形成該第一半導體結構中該至少一個元件使之包含多個組成凸起,該些組成凸起中的各個組成凸起均從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料。 The method of any one of embodiments 1 to 8, further comprising forming the at least one component of the first semiconductor structure to include a plurality of constituent protrusions, each of the constituent protrusions Both protrude from the bonding plane of the first semiconductor structure a distance beyond the adjacent dielectric material.

實施例10:如實施例9之方法,其更包括:在該第二半導體結構中該至少一個元件結構上提供介電材料;及蝕刻穿透該介電材料以形成多個凹槽,該些凹槽穿過該介電材料延伸至該第二半導體結構中該至少一個元件結構。 Embodiment 10: The method of Embodiment 9, further comprising: providing a dielectric material on the at least one component structure in the second semiconductor structure; and etching through the dielectric material to form a plurality of recesses, A recess extends through the dielectric material to the at least one component structure in the second semiconductor structure.

實施例11:如實施例10之方法,其中將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括將該第一半導體結構中該至少一個元件結構之多個組成凸起中的各個組成凸起,插入該第二半導體結構中穿過該介電材料延伸至該至少一個元件結構之多個凹槽中的一個相應互補凹槽。 The method of embodiment 10, wherein the at least one element structure in the first semiconductor structure is directly bonded to the second semiconductor structure, the at least one element structure comprising the at least one of the first semiconductor structures Each of the plurality of constituent protrusions of the component structure is inserted into the second semiconductor structure and extends through the dielectric material to a corresponding complementary recess of the plurality of recesses of the at least one component structure.

實施例12:如實施例1至11中任一項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在非熱壓之直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of any one of embodiments 1 to 11, wherein the at least one component structure of the first semiconductor structure is directly bonded to the first semiconductor structure in a direct bonding process of a conductive material to a conductive material The at least one element structure in the second semiconductor structure includes direct bonding of the at least one element structure in the first semiconductor structure to the at least one element structure in the second semiconductor structure in a direct bonding process that is not hot pressing.

實施例13:如實施例1至12中任一項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在超低溫直接 鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of any one of embodiments 1 to 12, wherein the at least one element structure in the first semiconductor structure is directly bonded to the first semiconductor structure in a direct bonding process of a conductive material to a conductive material The at least one component structure in the second semiconductor structure includes direct In the bonding process, the at least one component structure in the first semiconductor structure is directly bonded to the at least one component structure in the second semiconductor structure.

實施例14:如實施例1至13中任一項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在表面輔助之直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of any one of embodiments 1 to 13, wherein the at least one component structure of the first semiconductor structure is directly bonded to the first semiconductor structure in a direct bonding process of a conductive material to a conductive material The at least one element structure in the second semiconductor structure includes direct bonding of the at least one element structure in the first semiconductor structure to the at least one element structure in the second semiconductor structure in a surface assisted direct bonding process.

實施例15:一種將一第一半導體結構直接鍵結至一第二半導體結構之方法,其包括:提供一第一半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料及自一基底結構延伸出來之多個組成凸起,該些組成凸起曝露在該第一半導體結構之一鍵結表面上,該介電材料亦曝露在該第一半導體結構之鍵結表面上,且該介電材料被配置為與該第一半導體結構中該至少一個元件結構相鄰,並在該第一半導體結構中該至少一個元件結構之該些組成凸起間覆蓋住該至少一個元件結構之一部分,在該第一半導體結構之鍵結表面上,該介電材料之一曝露表面定義出該第一半導體結構之一鍵結平面;提供一第二半導體結構,使之包含至少一個元件結構及一介電材料,該至少一個元件結構含有一導電材料及自一基底結構延伸出來之多個組成凸起,該些組成凸起曝露在該第二半導體結構之一鍵結表面上,該介電材料亦曝露在該第二半導體結構之鍵結表面上,且該介電材料被配置為與該第二半導體結構中該至少一個元件結構相鄰,並在該第二半導體結構中該至少一個元件結構之該些組成凸起間覆蓋住該至少一個元件結構之一部分,在該第二半導體結構之鍵結 表面上,該介電材料之一曝露表面定義出該第二半導體結構之一鍵結平面;以及在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起。 Embodiment 15: A method of directly bonding a first semiconductor structure to a second semiconductor structure, comprising: providing a first semiconductor structure including at least one component structure and a dielectric material, the at least one component The structure comprises a conductive material and a plurality of constituent protrusions extending from a base structure, the constituent protrusions are exposed on a bonding surface of the first semiconductor structure, and the dielectric material is also exposed on the first semiconductor structure a bonding surface, and the dielectric material is disposed adjacent to the at least one element structure of the first semiconductor structure, and the constituent bumps of the at least one element structure are covered in the first semiconductor structure Holding a portion of the at least one component structure, on an interface surface of the first semiconductor structure, an exposed surface of the dielectric material defines a bonding plane of the first semiconductor structure; providing a second semiconductor structure The method comprises at least one component structure and a dielectric material, the at least one component structure comprising a conductive material and a plurality of extending from a base structure Forming a protrusion, the constituent protrusions are exposed on a bonding surface of the second semiconductor structure, the dielectric material is also exposed on the bonding surface of the second semiconductor structure, and the dielectric material is configured to The at least one element structure of the second semiconductor structure is adjacent, and in the second semiconductor structure, the constituent protrusions of the at least one element structure cover a portion of the at least one element structure, and the second semiconductor structure Bond Surface, the exposed surface of the dielectric material defines a bonding plane of the second semiconductor structure; and the at least one component of the first semiconductor structure in a direct bonding process of the conductive material to the conductive material A plurality of constituent protrusions of the structure are directly bonded to a plurality of constituent protrusions of the at least one element structure in the second semiconductor structure.

實施例16:如實施例15之方法,其中提供該第一半導體結構包括形成自該第一半導體結構中該至少一個元件結構之基底結構延伸出來之多個組成凸起,而形成該些組成凸起包括:在該第一半導體結構中該至少一個元件結構之基底結構上提供該介電材料;蝕刻穿透該介電材料以形成多個凹槽,該些凹槽穿過該介電材料並延伸至該第一半導體結構中該至少一個元件結構之基底結構;以及在該些凹槽內提供導電材料,以形成自該第一半導體結構中該至少一個元件結構之基底結構延伸出來之多個組成凸起。 The method of embodiment 15, wherein the providing the first semiconductor structure comprises forming a plurality of constituent protrusions extending from a base structure of the at least one element structure in the first semiconductor structure to form the constituent protrusions The method includes: providing the dielectric material on a base structure of the at least one element structure in the first semiconductor structure; etching through the dielectric material to form a plurality of grooves, the grooves passing through the dielectric material and Extending to a base structure of the at least one component structure in the first semiconductor structure; and providing a conductive material within the recesses to form a plurality of regions extending from the base structure of the at least one component structure in the first semiconductor structure Make up the bulge.

實施例17:如實施例15或實施例16之方法,其中在導電材料對導電材料之一直接鍵結製程中將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起包括在超低溫直接鍵結製程及表面輔助直接鍵結製程至少其中一項製程中,將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起。 The method of embodiment 15 or embodiment 16, wherein the plurality of constituent protrusions of the at least one element structure in the first semiconductor structure are directly bonded in a direct bonding process of the conductive material to the conductive material And constituting the plurality of constituent protrusions of the at least one component structure in the second semiconductor structure, the at least one component in the first semiconductor structure in at least one of an ultra-low temperature direct bonding process and a surface assisted direct bonding process A plurality of constituent protrusions of the structure are directly bonded to a plurality of constituent protrusions of the at least one element structure in the second semiconductor structure.

實施例18:一鍵結半導體結構,其包括一第一半導體結構及一第二半導體結構,該第一半導體結構包含:該第一半導體結構之一鍵結表面上之至少一個導電元件結構,以及被配置為與該第一半導體結構之鍵結表面 上之至少一個導電元件結構相鄰之一介電材料;該第二半導體結構包含:該第二半導體結構之一鍵結表面上之至少一個導電元件結構,該第二半導體結構中該至少一個導電元件結構沿著兩個半導體結構之導電元件結構間之鍵結界面,直接鍵結至該第一半導體結構中該至少一個導電元件結構,以及被配置為與該第二半導體結構之鍵結表面上之該至少一個導電元件結構相鄰之一介電材料,該第二半導體結構之介電材料沿著一鍵結平面緊靠該第一半導體結構之介電材料;在該鍵結半導體結構中,該第一半導體結構中該至少一個導電元件結構與該第二半導體結構中該至少一個導電元件結構間之鍵結界面與該鍵結平面相隔一段距離。 Embodiment 18: A bonding semiconductor structure comprising a first semiconductor structure and a second semiconductor structure, the first semiconductor structure comprising: at least one conductive element structure on a bonding surface of one of the first semiconductor structures, and Configuring a bonding surface with the first semiconductor structure The at least one conductive element is adjacent to one of the dielectric materials; the second semiconductor structure comprises: at least one conductive element structure on a bonding surface of the second semiconductor structure, the at least one conductive material in the second semiconductor structure An element structure is bonded directly to the at least one conductive element structure of the first semiconductor structure along a bonding interface between the conductive element structures of the two semiconductor structures, and is configured to be bonded to the bonding surface of the second semiconductor structure The at least one conductive element structure is adjacent to a dielectric material, and the dielectric material of the second semiconductor structure abuts a dielectric material of the first semiconductor structure along a bonding plane; in the bonded semiconductor structure, The bonding interface between the at least one conductive element structure and the at least one conductive element structure of the second semiconductor structure is spaced apart from the bonding plane by a distance.

實施例19:如實施例18之鍵結半導體結構,其中該第一半導體結構中該至少一個導電元件結構與該第二半導體結構中該至少一個導電元件結構皆至少實質上由銅或一種銅合金構成。 Embodiment 19: The bonded semiconductor structure of Embodiment 18, wherein the at least one conductive element structure of the first semiconductor structure and the at least one conductive element structure of the second semiconductor structure are at least substantially copper or a copper alloy Composition.

實施例20:如實施例18或實施例19之鍵結半導體結構,其中該第一半導體結構中該至少一個導電元件結構包含自一基底結構延伸出來之多個組成凸起。 Embodiment 20: The bonded semiconductor structure of Embodiment 18 or Embodiment 19, wherein the at least one conductive element structure of the first semiconductor structure comprises a plurality of constituent protrusions extending from a base structure.

實施例21:如實施例20之鍵結半導體結構,其中該第一半導體結構中該至少一個導電元件結構之該些組成凸起穿過該第二半導體結構之介電材料中多個凹槽。 Embodiment 21: The bonded semiconductor structure of Embodiment 20, wherein the constituent protrusions of the at least one conductive element structure in the first semiconductor structure pass through a plurality of recesses in a dielectric material of the second semiconductor structure.

實施例22:如實施例21之鍵結半導體結構,其中該第二半導體結構中該至少一個導電元件結構包含自一基底結構延伸出來之多個組成凸起,該第二半導體結構中該至少一個導電元件結構之該些組成凸起被直接鍵結至該第一半導體結構中該至少一個導電元件結構之該些組成凸起。 Embodiment 22: The bonded semiconductor structure of Embodiment 21, wherein the at least one conductive element structure of the second semiconductor structure comprises a plurality of constituent protrusions extending from a base structure, the at least one of the second semiconductor structures The constituent protrusions of the conductive element structure are directly bonded to the constituent protrusions of the at least one conductive element structure of the first semiconductor structure.

實施例23:一鍵結半導體結構,其包括一第一半導體結構及一第二半導體結構;該第一半導體結構包含至少一個導電元件結構及一介電材料,該至少一個導電元件結構在該第一半導體結構之一鍵結表面上且包含自一基底結構延伸出來之多個組成凸起,該介電材料被配置為與該第一半導體結構之鍵結表面上之至少一個導電元件結構相鄰,且該介電材料之至少一部分被配置在該第一半導體結構中該至少一個導電元件結構之該些組成凸起之間;該第二半導體結構包含至少一個導電元件結構及一介電材料,該至少一個導電元件結構在該第二半導體結構之一鍵結表面上且包含自一基底結構延伸出來之多個組成凸起,該介電材料被配置為與該第二半導體結構之鍵結表面上之至少一個導電元件結構相鄰,且該介電材料之至少一部分被配置在該第二半導體結構中該至少一個導電元件結構之該些組成凸起之間,該第二半導體結構之介電材料沿著一鍵結平面緊靠該第一半導體結構之介電材料;在該鍵結半導體結構中,該第一半導體結構中該至少一個導電元件結構之該些組成凸起,沿著兩個半導體結構之該些組成凸起間之已鍵結界面,直接鍵結至該第二半導體結構中該至少一個導電元件結構之該些組成凸起。 Embodiment 23: A bonding semiconductor structure comprising a first semiconductor structure and a second semiconductor structure; the first semiconductor structure comprising at least one conductive element structure and a dielectric material, wherein the at least one conductive element structure is a plurality of constituent protrusions extending from a surface of a semiconductor structure and extending from a substrate structure, the dielectric material being disposed adjacent to at least one conductive element structure on a bonding surface of the first semiconductor structure And at least a portion of the dielectric material is disposed between the constituent protrusions of the at least one conductive element structure in the first semiconductor structure; the second semiconductor structure includes at least one conductive element structure and a dielectric material, The at least one conductive element structure is on a bonding surface of the second semiconductor structure and includes a plurality of constituent protrusions extending from a substrate structure, the dielectric material being configured to bond surface with the second semiconductor structure At least one of the conductive elements is adjacent, and at least a portion of the dielectric material is disposed in the second semiconductor structure Between the constituent protrusions of one less conductive element structure, the dielectric material of the second semiconductor structure abuts the dielectric material of the first semiconductor structure along a bonding plane; in the bonded semiconductor structure, The constituent protrusions of the at least one conductive element structure in the first semiconductor structure are directly bonded to the at least one of the second semiconductor structures along the bonded interfaces between the constituent bumps of the two semiconductor structures The constituent protrusions of the conductive element structure.

實施例24:如實施例23之鍵結半導體結構,其中介於該第一半導體結構中該至少一個導電元件結構之該些組成凸起及該第二半導體結構中該至少一個導電元件結構之該些組成凸起間之該些已鍵結界面與該鍵結平面是分開的。 Embodiment 24: The bonded semiconductor structure of Embodiment 23, wherein the constituent protrusions of the at least one conductive element structure in the first semiconductor structure and the at least one conductive element structure of the second semiconductor structure The bonded interfaces between the constituent bumps are separated from the bonding plane.

實施例25:如實施例23之鍵結半導體結構,其中介於該第一半導體結構中該至少一個導電元件結構之該些組成凸起及該第二半導體結構中 該至少一個導電元件結構之該些組成凸起間之該些已鍵結界面至少實質上與該鍵結平面共平面。 Embodiment 25: The bonded semiconductor structure of Embodiment 23, wherein the constituent bumps of the at least one conductive element structure and the second semiconductor structure are in the first semiconductor structure The bonded interfaces between the constituent protrusions of the at least one conductive element structure are at least substantially coplanar with the bonding plane.

前文所述之示範性實施例並不會限制本發明之範圍,因為這些實施例僅為本發明實施例之範例,而本發明係由所附之申請專利範圍及其法律同等效力所界定。任何等同之實施例均在本發明之範圍內。事實上,對於本發明所屬技術領域具有通常知識者而言,除本說明書所示及所述者外,對於本發明之各種修改,例如替換所述元件之有用組合,都會因本說明書之敘述而變得顯而易見。換言之,本說明書所述任一示範性實施例之一項或多項特點,可以與本說明書所述另一示範性實施例之一項或多項特點結合,而成為本發明之額外實施例。此等修改及實施例亦落在所附之申請專利範圍內。 The exemplified embodiments described above are not intended to limit the scope of the invention, and the invention is intended to be limited by the scope of the accompanying claims. Any equivalent embodiments are within the scope of the invention. In fact, various modifications of the invention, such as a substitute for a useful combination of the elements, in addition to those shown and described herein, will be apparent from the description of the specification. Become obvious. In other words, one or more of the features of any one of the exemplary embodiments described herein may be combined with one or more features of another exemplary embodiment described herein as an additional embodiment of the invention. Such modifications and embodiments are also within the scope of the appended claims.

100、110、120、200、210、220、230、420、430、440、550、560‧‧‧半導體結構 100, 110, 120, 200, 210, 220, 230, 420, 430, 440, 550, 560‧ ‧ semiconductor structure

201、401、501‧‧‧元件層 201, 401, 501‧‧‧ component layers

104、204、404、504‧‧‧凹槽 104, 204, 404, 504‧‧‧ grooves

105、205、405、505‧‧‧導電金屬 105, 205, 405, 505‧‧‧ conductive metal

106、206、406、506‧‧‧元件結構 106, 206, 406, 506‧‧‧ component structure

103、203、503‧‧‧表面 103, 203, 503‧‧‧ surface

107、207、407‧‧‧元件結構之表面 107, 207, 407‧‧‧ surface of component structure

108、208、408‧‧‧下方介電材料之表面之凹陷 Depression of the surface of the dielectric material below 108, 208, 408‧‧

116、216‧‧‧曝露主要表面上之凹陷 116, 216‧‧‧ exposure to the main surface of the depression

112、212、412、552‧‧‧額外介電材料 112, 212, 412, 552‧‧‧ additional dielectric materials

114、214、554‧‧‧曝露主要表面 114, 214, 554‧‧‧ exposed main surface

130、400、450、500‧‧‧第一半導體結構 130, 400, 450, 500‧‧‧ first semiconductor structure

132、242、452、572‧‧‧鍵結平面 132, 242, 452, 572‧‧ ‧ bonding plane

102、202、402、502、512‧‧‧介電材料 102, 202, 402, 502, 512‧‧‧ dielectric materials

232、418、562‧‧‧罩幕材料 232, 418, 562 ‧ ‧ mask material

234、419、564‧‧‧罩幕材料之孔隙 234, 419, 564‧‧ ‧ pores of the curtain material

240、570‧‧‧第二半導體結構 240, 570‧‧‧second semiconductor structure

300、600、700‧‧‧鍵結半導體結構 300, 600, 700‧‧‧bonded semiconductor structure

302、602、702‧‧‧鍵結界面 302, 602, 702‧‧‧ bonding interface

304、604、704‧‧‧基準鍵結界面平面 304, 604, 704‧‧‧ benchmark key interface plane

414、514‧‧‧主要表面 414, 514‧‧‧ main surface

432、532‧‧‧導電材料 432, 532‧‧‧ conductive materials

442、542‧‧‧凸起 442, 542‧‧ ‧ raised

422、522‧‧‧開口 422, 522‧‧ ‧ openings

經由參照以下本發明示範性實施例之詳細說明,可更充分了解本發明,該些示範性實施例呈現於所附圖式內,其中:圖1A及1B為半導體結構之簡化截面圖,其係用於呈現在將半導體結構直接鍵結在一起之直接鍵結製程前,於準備半導體結構之鍵結表面期間可能發生之碟形凹陷及磨蝕現象;圖2A至2K為半導體結構之簡化截面圖,其呈現本發明中將半導體結構直接鍵結在一起之直接鍵結製程之實施例;圖3A至3K為半導體結構之簡化截面圖,其呈現本發明中直接鍵結製程之其他實施例;以及 圖4A及4B為半導體結構之簡化截面圖,其呈現本發明中直接鍵結製程之另外實施例。 The invention will be more fully understood from the following detailed description of exemplary embodiments of the invention, which are illustrated in the accompanying drawings in which: FIGS. 1A and 1B are simplified cross-sectional views of a semiconductor structure For presenting dishing and abrading that may occur during preparation of the bonding surface of the semiconductor structure prior to direct bonding processes in which the semiconductor structures are directly bonded together; FIGS. 2A through 2K are simplified cross-sectional views of the semiconductor structure, It presents an embodiment of a direct bonding process in which the semiconductor structures are directly bonded together in the present invention; FIGS. 3A to 3K are simplified cross-sectional views of the semiconductor structure, showing other embodiments of the direct bonding process of the present invention; 4A and 4B are simplified cross-sectional views of a semiconductor structure showing additional embodiments of the direct bonding process of the present invention.

100‧‧‧半導體結構 100‧‧‧Semiconductor structure

102‧‧‧介電材料 102‧‧‧ dielectric materials

103‧‧‧表面 103‧‧‧ surface

104‧‧‧凹槽 104‧‧‧ Groove

105‧‧‧導電金屬 105‧‧‧Conductive metal

106‧‧‧元件結構 106‧‧‧Component structure

108‧‧‧凹陷 108‧‧‧ dent

107‧‧‧元件結構之表面 107‧‧‧ Surface of component structure

Claims (15)

一種將一第一半導體結構直接鍵結至一第二半導體結構之方法,該方法包括:提供一第一半導體結構,其包括:含有一導電材料之至少一個元件結構,該至少一個元件結構曝露在該第一半導體結構之一鍵結表面上;及曝露在該第一半導體結構之鍵結表面上之一介電材料,該介電材料被配置為與該第一半導體結構之該至少一個元件結構相鄰,該介電材料之一曝露表面在該第一半導體結構之鍵結表面上定義出該第一半導體結構之一鍵結平面;致使該第一半導體結構之該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料;提供一第二半導體結構,其包括:含有一導電材料之至少一個元件結構,該至少一個元件結構曝露在該第一半導體結構之一鍵結表面上;及曝露在該第二半導體結構之鍵結表面上之一介電材料,該介電材料被配置為與該第二半導體結構之該至少一個元件結構相鄰,該介電材料之一曝露表面在該第二半導體結構之鍵結表面上定義出該第二半導體結構之一鍵結平面;致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷一段距離,凹入伸進相鄰介電材料之一凹槽,其包括: 在該第二半導體結構中該至少一個元件結構上沉積一額外介電材料;在該額外介電材料上進行一平坦化步驟;及蝕穿該額外介電材料直至該至少一個元件結構;以及在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 A method of directly bonding a first semiconductor structure to a second semiconductor structure, the method comprising: providing a first semiconductor structure comprising: at least one element structure comprising a conductive material, the at least one element structure being exposed a bonding surface on a bonding surface of the first semiconductor structure; and a dielectric material exposed on a bonding surface of the first semiconductor structure, the dielectric material being configured to be associated with the at least one component structure of the first semiconductor structure Adjacent, an exposed surface of the dielectric material defines a bonding plane of the first semiconductor structure on a bonding surface of the first semiconductor structure; causing the at least one component structure of the first semiconductor structure to be from the first a bonding plane of a semiconductor structure protruding a distance beyond the adjacent dielectric material; providing a second semiconductor structure comprising: at least one component structure including a conductive material, the at least one component structure being exposed to the first semiconductor a bonding surface on one of the structures; and a dielectric material exposed on the bonding surface of the second semiconductor structure, the dielectric A material is disposed adjacent to the at least one element structure of the second semiconductor structure, and an exposed surface of the dielectric material defines a bonding plane of the second semiconductor structure on a bonding surface of the second semiconductor structure Causing the at least one element structure of the second semiconductor structure to be recessed from the bonding plane of the second semiconductor structure by a distance, recessed into a recess of the adjacent dielectric material, comprising: Depositing an additional dielectric material on the at least one component structure in the second semiconductor structure; performing a planarization step on the additional dielectric material; and etching through the additional dielectric material up to the at least one component structure; The at least one element structure of the first semiconductor structure is directly bonded to the at least one element structure of the second semiconductor structure in a direct bonding process of the conductive material to one of the conductive materials. 如申請專利範圍第1項之方法,其中致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料包含從該第一半導體結構移除該介電材料之一部分。 The method of claim 1, wherein the at least one element structure in the first semiconductor structure protrudes from the bonding plane of the first semiconductor structure by a distance beyond the adjacent dielectric material from the first semiconductor The structure removes a portion of the dielectric material. 如申請專利範圍第2項之方法,其中從該第一半導體結構移除該介電材料之一部分包含蝕刻該介電材料。 The method of claim 2, wherein removing a portion of the dielectric material from the first semiconductor structure comprises etching the dielectric material. 如申請專利範圍第1項之方法,其中致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出一段距離包含致使該第一半導體結構中該至少一個元件結構從該第一半導體結構之鍵結平面突出預先選定之一段距離。 The method of claim 1, wherein causing the at least one element structure in the first semiconductor structure to protrude from the bonding plane of the first semiconductor structure a distance comprises causing the at least one element structure in the first semiconductor structure to The bonding plane of the first semiconductor structure protrudes a predetermined distance of a segment. 如申請專利範圍第1項之方法,其中致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷一段距離,凹入伸進相鄰介電材料之一凹槽包括致使該第二半導體結構中該至少一個元件結構從該第二半導體結構之鍵結平面凹陷預先選定之一段距離。 The method of claim 1, wherein the at least one element structure in the second semiconductor structure is recessed from the bonding plane of the second semiconductor structure by a distance, recessed into a recess of the adjacent dielectric material The method includes causing the at least one element structure in the second semiconductor structure to be pre-selected a distance from the bonding plane of the second semiconductor structure. 如申請專利範圍第1項之方法,其中將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括將該第一半導體結構中該至少一個元件結構插入該第二半導體結構之介電材料中之凹槽。 The method of claim 1, wherein the at least one element structure in the first semiconductor structure is directly bonded to the second semiconductor structure, the at least one element structure comprising the at least one element in the first semiconductor structure A structure is inserted into the recess in the dielectric material of the second semiconductor structure. 如申請專利範圍第1項之方法,其更包括形成該第一半導體結構中該至少一個元件使之包含多個組成凸起(integral protrusion),該些組成凸起中的各個組成凸起均從該第一半導體結構之鍵結平面突出一段距離而超出相鄰之介電材料。 The method of claim 1, further comprising forming the at least one component of the first semiconductor structure to include a plurality of constituent protrusions, each of the constituent protrusions The bonding plane of the first semiconductor structure protrudes a distance beyond the adjacent dielectric material. 如申請專利範圍第7項之方法,其更包括:在該第二半導體結構中該至少一個元件結構上提供介電材料;及蝕刻穿透該介電材料以形成多個凹槽,該些凹槽穿過該介電材料延伸至該第二半導體結構中該至少一個元件結構。 The method of claim 7, further comprising: providing a dielectric material on the at least one component structure in the second semiconductor structure; and etching through the dielectric material to form a plurality of recesses, the recesses A trench extends through the dielectric material to the at least one component structure in the second semiconductor structure. 如申請專利範圍第8項之方法,其中將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括將該第一半導體結構中該至少一個元件結構之多個組成凸起中的各個組成凸起,插入該第二半導體結構中穿過該介電材料延伸至該至少一個元件結構之多個凹槽中的一個相應互補凹槽。 The method of claim 8, wherein the at least one element structure of the first semiconductor structure is directly bonded to the second semiconductor structure, the at least one element structure comprising the at least one element of the first semiconductor structure Each of the plurality of constituent protrusions of the structure is inserted into the second semiconductor structure and extends through the dielectric material to a corresponding complementary recess of the plurality of recesses of the at least one component structure. 如申請專利範圍第1項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在非熱壓直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of claim 1, wherein the at least one element structure in the first semiconductor structure is directly bonded to the at least one of the second semiconductor structures in a direct bonding process of the conductive material to the conductive material The component structure includes bonding the at least one component structure in the first semiconductor structure directly to the at least one component structure in the second semiconductor structure in a non-thermal compression direct bonding process. 如申請專利範圍第1項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在超低溫直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of claim 1, wherein the at least one element structure in the first semiconductor structure is directly bonded to the at least one of the second semiconductor structures in a direct bonding process of the conductive material to the conductive material The component structure includes bonding the at least one component structure in the first semiconductor structure directly to the at least one component structure in the second semiconductor structure in an ultra-low temperature direct bonding process. 如申請專利範圍第1項之方法,其中在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構包括在表面輔助之直接鍵結製程中,將該第一半導體結構中該至少一個元件結構直接鍵結至該第二半導體結構中該至少一個元件結構。 The method of claim 1, wherein the at least one element structure in the first semiconductor structure is directly bonded to the at least one of the second semiconductor structures in a direct bonding process of the conductive material to the conductive material The component structure includes direct bonding of the at least one component structure in the first semiconductor structure to the at least one component structure in the second semiconductor structure in a surface assisted direct bonding process. 一種將一第一半導體結構直接鍵結至一第二半導體結構之方法,其包括:提供一第一半導體結構,其包括:含有一導電材料之至少一個元件結構,該至少一個元件結構包含自一基底結構延伸出來之多個組成凸起,該些組成凸起曝露在該第一半導體結構之一鍵結表面上;及曝露在該第一半導體結構之鍵結表面上之一介電材料,該介電材料被配置為與該第一半導體結構中該至少一個元件結構相鄰,並在該第一半導體結構中該至少一個元件結構之該些組成凸起間覆蓋住該至少一個元件結構之一部分,該介電材料之一曝露表面在該第一半導體結構之鍵結表面上定義出該第一半導體結構之一鍵結平面;提供一第二半導體結構,其包括:含有一導電材料之至少一個元件結構,該至少一個元件結構包含自一基底結構延伸出來之多個組成凸起,該些組成凸起曝露在該第二半導體結構之一鍵結表面上;及曝露在該第二半導體結構之鍵結表面上之一介電材料,該介電材料被配置為與該第二半導體結構中該至少一個元件結構相鄰,並在該第二半導體結構中該至少一個元件結構之該些組成凸起間覆蓋住該至少一個元件結構之一部分,該介電材料之一曝露表面在該第二半導體結構之鍵結表面上定義出該第二半導體結構之一鍵結平面;以及 在導電材料對導電材料之一直接鍵結製程中,將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起。 A method of directly bonding a first semiconductor structure to a second semiconductor structure, comprising: providing a first semiconductor structure comprising: at least one element structure including a conductive material, the at least one element structure comprising a plurality of constituent protrusions extending from the base structure, the constituent protrusions being exposed on a bonding surface of the first semiconductor structure; and a dielectric material exposed on the bonding surface of the first semiconductor structure, the A dielectric material is disposed adjacent to the at least one element structure of the first semiconductor structure, and wherein the portion of the at least one element structure of the at least one element structure covers a portion of the at least one element structure An exposed surface of the dielectric material defines a bonding plane of the first semiconductor structure on a bonding surface of the first semiconductor structure; and a second semiconductor structure is provided, comprising: at least one conductive material An element structure, the at least one element structure comprising a plurality of constituent protrusions extending from a base structure, the constituent protrusions being exposed a bonding surface on one of the second semiconductor structures; and a dielectric material exposed on the bonding surface of the second semiconductor structure, the dielectric material being configured to be associated with the at least one component structure of the second semiconductor structure Adjacent, and in the second semiconductor structure, the constituent protrusions of the at least one element structure cover a portion of the at least one element structure, and one of the dielectric materials is exposed on the bonding surface of the second semiconductor structure Defining a bonding plane of the second semiconductor structure; And a plurality of constituent protrusions of the at least one element structure in the first semiconductor structure are directly bonded to the plurality of at least one element structure in the second semiconductor structure in a direct bonding process of the conductive material to the conductive material Make up the bulge. 如申請專利範圍第13項之方法,其中提供該第一半導體結構包括形成自該第一半導體結構中該至少一個元件結構之基底結構延伸出來之多個組成凸起,形成該些組成凸起包括:在該第一半導體結構中該至少一個元件結構之基底結構上提供該介電材料;蝕刻穿透該介電材料以形成多個凹槽,該些凹槽穿過該介電材料並延伸至該第一半導體結構中該至少一個元件結構之基底結構;以及在該些凹槽內提供導電材料,以形成自該第一半導體結構中該至少一個元件結構之基底結構延伸出來之多個組成凸起。 The method of claim 13, wherein the providing the first semiconductor structure comprises forming a plurality of constituent protrusions extending from the base structure of the at least one element structure in the first semiconductor structure, and forming the constituent protrusions comprises Providing the dielectric material on a base structure of the at least one component structure in the first semiconductor structure; etching through the dielectric material to form a plurality of recesses, the recesses extending through the dielectric material and extending to a base structure of the at least one element structure in the first semiconductor structure; and providing a conductive material in the recesses to form a plurality of constituent protrusions extending from a base structure of the at least one element structure in the first semiconductor structure Start. 如申請專利範圍第13項之方法,其中在導電材料對導電材料之一直接鍵結製程中將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起包括在超低溫直接鍵結製程及表面輔助直接鍵結製程至少其中一項製程中,將該第一半導體結構中該至少一個元件結構之多個組成凸起直接鍵結至該第二半導體結構中該至少一個元件結構之多個組成凸起。 The method of claim 13, wherein the plurality of constituent protrusions of the at least one element structure in the first semiconductor structure are directly bonded to the second semiconductor in a direct bonding process of the conductive material to the conductive material The plurality of constituent protrusions of the at least one component structure in the structure comprise at least one of the at least one component structure in the first semiconductor structure in at least one of the ultra-low temperature direct bonding process and the surface assisted direct bonding process The bumps are directly bonded to the plurality of constituent bumps of the at least one component structure in the second semiconductor structure.
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