TWI487074B - Flexible electronic device and manufacturing method of the same - Google Patents

Flexible electronic device and manufacturing method of the same Download PDF

Info

Publication number
TWI487074B
TWI487074B TW101138900A TW101138900A TWI487074B TW I487074 B TWI487074 B TW I487074B TW 101138900 A TW101138900 A TW 101138900A TW 101138900 A TW101138900 A TW 101138900A TW I487074 B TWI487074 B TW I487074B
Authority
TW
Taiwan
Prior art keywords
layer
interface layer
electronic device
flexible
flexible substrate
Prior art date
Application number
TW101138900A
Other languages
Chinese (zh)
Other versions
TW201417224A (en
Inventor
Ping I Shih
Yi Hao Peng
Original Assignee
Ind Tech Res Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ind Tech Res Inst filed Critical Ind Tech Res Inst
Priority to TW101138900A priority Critical patent/TWI487074B/en
Priority to CN201210489100.6A priority patent/CN103779379B/en
Publication of TW201417224A publication Critical patent/TW201417224A/en
Application granted granted Critical
Publication of TWI487074B publication Critical patent/TWI487074B/en

Links

Description

可撓式電子裝置及其製造方法Flexible electronic device and method of manufacturing same

本揭露內容是有關於一種可撓式電子裝置及其製造方法,且特別是有關於一種具有阻隔水氧的阻障結構之可撓式電子裝置及其製造方法。The present disclosure relates to a flexible electronic device and a method of fabricating the same, and more particularly to a flexible electronic device having a barrier structure for blocking water and oxygen and a method of manufacturing the same.

軟性有機發光二極體顯示器無法採用玻璃基板(硬式基板)對玻璃基板的封裝方式製作,必須採用可撓式基板封裝。然而,可撓式基板(例如是塑膠基板)對於阻隔水氣與氧氣的效果較差,有機發光二極體對於水氣又十分敏感,因此需要在有機發光二極體顯示器中增加阻隔水氣的結構。A flexible organic light-emitting diode display cannot be fabricated by using a glass substrate (hard substrate) for packaging a glass substrate, and a flexible substrate package must be used. However, the flexible substrate (for example, a plastic substrate) has a poor effect on blocking moisture and oxygen, and the organic light-emitting diode is very sensitive to moisture, so it is necessary to add a structure that blocks moisture in the organic light-emitting diode display. .

一般常見的方式是在可撓式基板上設置阻障層以達到阻隔水氣的效果。然而,若是設置厚度較高的單層阻障層,雖然具有良好的阻隔水氣的效果,但因為應力較強,顯示器彎曲時可能會發生斷裂。若是設置多層結構的阻障層,卻有製程繁雜且耗時較長的問題。因此,如何提供一種具有簡單結構、簡化製程且能保持良好阻隔水氣的效果之軟性有機發光二極體顯示器,乃為相關業者努力之課題之一。A common way is to provide a barrier layer on the flexible substrate to achieve the effect of blocking moisture. However, if a single-layer barrier layer having a relatively high thickness is provided, although it has a good effect of blocking moisture, the stress may be strong, and the display may be broken when bent. If a barrier layer of a multi-layer structure is provided, there is a problem that the process is complicated and time consuming. Therefore, how to provide a soft organic light-emitting diode display having a simple structure, simplifying the process, and maintaining a good moisture barrier effect is one of the subjects of the related industry.

本揭露內容係有關於一種可撓式電子裝置及其製造方法。可撓式電子裝置中,經由形成介面層於電子元件和 阻障層之間或可撓式基板和阻障層之間,可增加電子元件和阻障層之間或可撓式基板和阻障層之間的附著性,因此無須設置多層阻障層(例如是三層以上的阻障層)就能夠達到良好的阻隔水氣與氧氣的效果。The disclosure relates to a flexible electronic device and a method of fabricating the same. In a flexible electronic device, by forming an interface layer on an electronic component and Between the barrier layers or between the flexible substrate and the barrier layer, the adhesion between the electronic component and the barrier layer or between the flexible substrate and the barrier layer can be increased, so that it is not necessary to provide a multilayer barrier layer ( For example, a barrier layer of three or more layers can achieve a good effect of blocking moisture and oxygen.

根據本揭露內容之一實施例,係提出一種可撓式電子裝置。可撓式電子裝置包括一第一可撓式基板、一電子元件、一第一介面層以及一第一阻障(barrier)層。第一介面層之材質包括一或多種金屬元素及一或多種無機金屬氧化物之組合。電子元件設置於第一可撓式基板上,第一介面層形成於電子元件上,第一阻障層形成於第一介面層上。According to an embodiment of the present disclosure, a flexible electronic device is proposed. The flexible electronic device includes a first flexible substrate, an electronic component, a first interface layer, and a first barrier layer. The material of the first interface layer comprises a combination of one or more metal elements and one or more inorganic metal oxides. The electronic component is disposed on the first flexible substrate, the first interface layer is formed on the electronic component, and the first barrier layer is formed on the first interface layer.

根據本揭露內容之另一實施例,係提出一種可撓式電子裝置之製造方法。可撓式電子裝置之製造方法包括:提供一第一可撓式基板;設置一電子元件於第一可撓式基板上;以一熱蒸鍍製程(thermal evaporation process)形成一第一介面層於電子元件上;以及形成一第一阻障層於第一介面層上。According to another embodiment of the present disclosure, a method of fabricating a flexible electronic device is provided. The manufacturing method of the flexible electronic device includes: providing a first flexible substrate; disposing an electronic component on the first flexible substrate; forming a first interface layer by a thermal evaporation process And on the electronic component; and forming a first barrier layer on the first interface layer.

為了對本揭露內容之上述及其他方面有更佳的瞭解,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下:In order to better understand the above and other aspects of the present disclosure, the preferred embodiments are described below in detail with reference to the accompanying drawings.

本揭露內容之實施例中,可撓式電子裝置中,經由形成介面層於電子元件和阻障層之間或可撓式基板和阻障 層之間,可增加電子元件和阻障層之間或可撓式基板和阻障層之間的附著性,因此無須設置多層阻障層(例如是三層以上的阻障層)就能夠達到良好的阻隔水氣與氧氣的效果。以下係參照所附圖式詳細敘述本揭露內容之實施例。圖式中相同的標號係用以標示相同或類似之部分。需注意的是,圖式係已簡化以利清楚說明實施例之內容,實施例所提出的細部結構僅為舉例說明之用,並非對本揭露內容欲保護之範圍做限縮。具有通常知識者當可依據實際實施態樣的需要對該些結構加以修飾或變化。In an embodiment of the disclosure, in the flexible electronic device, the interface layer is formed between the electronic component and the barrier layer or the flexible substrate and the barrier Between the layers, the adhesion between the electronic component and the barrier layer or between the flexible substrate and the barrier layer can be increased, so that it is not necessary to provide a multilayer barrier layer (for example, a barrier layer of three or more layers). Good barrier to moisture and oxygen. Embodiments of the present disclosure will be described in detail below with reference to the accompanying drawings. The same reference numerals are used to designate the same or similar parts. It is to be noted that the drawings have been simplified to illustrate the details of the embodiments, and the detailed description of the embodiments is for illustrative purposes only and is not intended to limit the scope of the disclosure. Those having ordinary knowledge may modify or change the structures as needed in accordance with the actual implementation.

第1A圖繪示本揭露內容之第一實施例之可撓式電子裝置之示意圖。請參照第1A圖,可撓式電子裝置100包括第一可撓式(flexible)基板110、電子元件120、第一介面層130及第一阻障(barrier)層140。電子元件120設置於第一可撓式基板上,第一介面層130形成於電子元件120上,第一阻障層140形成於第一介面層130上。第一介面層130之材質包括一或多種金屬元素及一或多種無機金屬氧化物之組合。第一介面層130形成於電子元件120和第一阻障層140之間,可以增加電子元件120和第一阻障層140之間的附著性,提高電子元件120和第一阻障層140的密封性,進而提升第一阻障層140阻隔水氣與氧氣的效果,延長電子元件120的使用壽命。並且,經由第一介面層130形成於電子元件120和第一阻障層140之間,無須設置多層阻障層(例如是三層以上的阻障層)就能夠達到良好的阻隔水氣與氧氣的效果。FIG. 1A is a schematic diagram of a flexible electronic device according to a first embodiment of the present disclosure. Referring to FIG. 1A , the flexible electronic device 100 includes a first flexible substrate 110 , an electronic component 120 , a first interface layer 130 , and a first barrier layer 140 . The electronic component 120 is disposed on the first flexible substrate, the first interface layer 130 is formed on the electronic component 120, and the first barrier layer 140 is formed on the first interface layer 130. The material of the first interface layer 130 includes a combination of one or more metal elements and one or more inorganic metal oxides. The first interface layer 130 is formed between the electronic component 120 and the first barrier layer 140, which can increase the adhesion between the electronic component 120 and the first barrier layer 140, and improve the electronic component 120 and the first barrier layer 140. The sealing property further enhances the effect of blocking the moisture and oxygen of the first barrier layer 140 and prolongs the service life of the electronic component 120. Moreover, the first interface layer 130 is formed between the electronic component 120 and the first barrier layer 140, and a multi-layer barrier layer (for example, a barrier layer of three or more layers) is not required to achieve good moisture and oxygen barrier. Effect.

實施例中,如第1A圖所示,第一介面層130例如是包覆電子元件120,第一阻障層140形成於第一介面層130且包覆第一介面層130及電子元件120。第一阻障層140並未接觸於電子元件120。In the embodiment, as shown in FIG. 1A , the first interface layer 130 is, for example, a coated electronic component 120 . The first barrier layer 140 is formed on the first interface layer 130 and covers the first interface layer 130 and the electronic component 120 . The first barrier layer 140 is not in contact with the electronic component 120.

實施例中,第一可撓式基板110例如是塑膠聚合物基板或具有可撓性之金屬基板。實施例中,電子元件120例如是有機發光二極體、有機電晶體或有機太陽能電池等等之有機電子元件。In the embodiment, the first flexible substrate 110 is, for example, a plastic polymer substrate or a flexible metal substrate. In an embodiment, the electronic component 120 is, for example, an organic electronic component such as an organic light emitting diode, an organic transistor, or an organic solar cell.

實施例中,金屬元素例如是金(Au)、銀(Ag)、銅(Cu)、鋁(Al)、鉬(Mo)、鎢(W)或前述任兩種以上之金屬的合金。實施例中,無機金屬氧化物例如是銦錫氧化物(ITO)、氧化銀(Ag2 O)、氧化銅(CuO)、氧化鉬(MoO3 )、氧化鎢(WO3 )、氧化鈦(TiO2 )、氧化釩(V2 O5 )或前述任兩種以上之材料的組合。實施例中,至少氧化鉬(MoO3 )、氧化鎢(WO3 )及氧化釩(V2 O5 )可以經由熱蒸鍍製程(thermal evaporation process形成於電子元件120上。In the examples, the metal element is, for example, gold (Au), silver (Ag), copper (Cu), aluminum (Al), molybdenum (Mo), tungsten (W), or an alloy of any two or more of the foregoing. In the examples, the inorganic metal oxide is, for example, indium tin oxide (ITO), silver oxide (Ag 2 O), copper oxide (CuO), molybdenum oxide (MoO 3 ), tungsten oxide (WO 3 ), titanium oxide (TiO). 2 ), vanadium oxide (V 2 O 5 ) or a combination of any two or more of the foregoing. In the embodiment, at least molybdenum oxide (MoO 3 ), tungsten oxide (WO 3 ), and vanadium oxide (V 2 O 5 ) may be formed on the electronic component 120 via a thermal evaporation process.

一實施例中,第一介面層130之材質例如更可包括一種或多種無機非金屬元素。實施例中,無機非金屬元素例如是硒(Se)、硫(S)、銻(Te)或前述任兩種以上之金屬的合金。In one embodiment, the material of the first interface layer 130 may, for example, further comprise one or more inorganic non-metallic elements. In the examples, the inorganic non-metal element is, for example, an alloy of selenium (Se), sulfur (S), tellurium (Te) or a metal of any two or more of the foregoing.

一實施例中,第一介面層130之材質例如更可包括一種或多種有機金屬化合物。實施例中,有機金屬化合物例如是銥錯合物(iridium complex)、鋨錯合物(osmium complex)、錸錯合物(rhenium complex)或前述任兩種以上之材料的組合。實施例中,有機金屬化合物係經由熱蒸鍍 製程形成於電子元件120上,如此則有機金屬化合物不會在形成第一介面層130的過程中分解,而能夠保持有機金屬化合物形成於電子元件120上所具有之化合物結構。In one embodiment, the material of the first interface layer 130 may include, for example, one or more organometallic compounds. In the examples, the organometallic compound is, for example, an iridium complex, an osmium complex, a rhenium complex, or a combination of any two or more of the foregoing. In the examples, the organometallic compound is subjected to thermal evaporation. The process is formed on the electronic component 120 such that the organometallic compound does not decompose during the formation of the first interfacial layer 130, and the compound structure of the organometallic compound formed on the electronic component 120 can be maintained.

實施例中,如前所述,第一介面層130之材質可以是包括多種前述材料的複合材料,因此除了可以增加電子元件120和第一阻障層140之間的附著性,尚能夠經由複合材料具有的不同材質而具有特殊的特性。舉例來說,第一介面層130所包括的複合材料亦可以具有導電特性,例如是氧化鉬/銀(MoO3 /Ag)複合材料、氧化鉬/銅(MoO3 /Cu)複合材料或氧化鋁/鋁(Al2 O3 /Al)複合材料。In the embodiment, as described above, the material of the first interface layer 130 may be a composite material including a plurality of the foregoing materials, so that in addition to increasing the adhesion between the electronic component 120 and the first barrier layer 140, it is still possible to The material has different materials and has special characteristics. For example, the composite material included in the first interface layer 130 may also have conductive properties, such as molybdenum oxide/silver (MoO 3 /Ag) composite material, molybdenum oxide/copper (MoO 3 /Cu) composite material or aluminum oxide. / Aluminum (Al 2 O 3 /Al) composite.

以電子元件120是上發光式有機發光二極體(organic light emitting diode,OLED)為例,如第1A圖所示,有機發光二極體最上層具有陰極(cathode)120a,其厚度較薄,結構較脆弱,導電特性亦較不佳。當第一介面層130之材質包括一導電材料時,例如是金、銀或銅之導電性金屬元素,或者是氧化鉬/銀、氧化鉬/銅或氧化鋁/鋁之導電性複合材料,則相當於增加了陰極120a的厚度,其導電特性提升,進而使得元件壽命大幅延長。Taking the electronic component 120 as an example of an organic light emitting diode (OLED), as shown in FIG. 1A, the uppermost layer of the organic light emitting diode has a cathode 120a, which is thinner. The structure is weak and the conductive properties are also poor. When the material of the first interface layer 130 comprises a conductive material, such as a conductive metal element of gold, silver or copper, or a conductive composite material of molybdenum oxide/silver, molybdenum oxide/copper or aluminum oxide/aluminum, Correspondingly, the thickness of the cathode 120a is increased, and the conductive property is improved, thereby further prolonging the life of the component.

一實施例中,亦可以選擇性地在第一介面層130和第一阻障層140之間再設置一層阻障層(未繪示),如此一來,兩層阻障層搭配一層介面層可以達到更佳的阻隔水氣與氧氣的效果。本揭露內容之實施例中,僅需一層或兩層阻障層搭配一層介面層,便可以達到良好的阻隔水氣與氧氣的效果In an embodiment, a barrier layer (not shown) may be further disposed between the first interface layer 130 and the first barrier layer 140. Thus, the two barrier layers are combined with a layer of the interface layer. Better moisture and oxygen barriers can be achieved. In the embodiment of the present disclosure, only one or two barrier layers are required to be combined with one layer of the interface layer, so that a good barrier effect of moisture and oxygen can be achieved.

實施例中,第一阻障層140之材質例如是無機陶瓷材 料,例如是金屬氧化物或金屬氮化物,且不具有導電性。舉例來說,第一阻障層140之材質例如是氧化矽、氮化矽或氮氧化矽。實施例中,第一阻障層140之材質與第一介面層130之材質係為不同。In an embodiment, the material of the first barrier layer 140 is, for example, an inorganic ceramic material. The material is, for example, a metal oxide or a metal nitride and has no conductivity. For example, the material of the first barrier layer 140 is, for example, hafnium oxide, tantalum nitride or hafnium oxynitride. In the embodiment, the material of the first barrier layer 140 is different from the material of the first interface layer 130.

如第1A圖所示,可撓式電子裝置100更可包括封裝膠材層(encapsulation adhesive layer)150及第二可撓式基板160,封裝膠材層150形成於第一阻障層140上,第二可撓式基板160形成於封裝膠材層150上。As shown in FIG. 1A, the flexible electronic device 100 further includes an encapsulation adhesive layer 150 and a second flexible substrate 160. The encapsulant layer 150 is formed on the first barrier layer 140. The second flexible substrate 160 is formed on the encapsulant layer 150.

實施例中,封裝膠材層150之材質是高分子材料,例如是聚甲基丙烯酸甲酯(polymethyl methacrylate,PMMS)、聚苯乙烯(polystyrene,PS)或環氧樹脂(epoxy),封裝膠材層150用以黏合第二可撓式基板160。實施例中,封裝膠材層150係由有機材質形成,因此亦可以視作一有機層,搭配單層結構之第一阻障層140時,有助於舒緩整體結構之應力,防止斷裂。In the embodiment, the material of the encapsulant layer 150 is a polymer material, such as polymethyl methacrylate (PMMS), polystyrene (PS) or epoxy resin, and the encapsulant The layer 150 is used to bond the second flexible substrate 160. In the embodiment, the encapsulant layer 150 is formed of an organic material, and thus can also be regarded as an organic layer. When the first barrier layer 140 of the single-layer structure is used, it helps to relieve the stress of the overall structure and prevent breakage.

實施例中,第二可撓式基板160例如是軟性蓋板,其材質例如塑膠聚合物或具有可撓性的金屬材料,可以是透明、半透明或不透明的。In an embodiment, the second flexible substrate 160 is, for example, a flexible cover plate made of a material such as a plastic polymer or a flexible metal material, which may be transparent, translucent or opaque.

第1B圖繪示本揭露內容之第二實施例之可撓式電子裝置之示意圖。請參照第1B圖,本實施例與第1A圖之實施例之差別在於,可撓式電子裝置100’中,第一介面層130’形成於電子元件120的上表面,第一介面層130’並未完全包覆電子元件120。第一阻障層140形成於第一介面層130’上且包覆第一介面層130’及電子元件120。第一阻障層140接觸於電子元件120之側面。實施例中,第一介 面層130’之材質同前述實施例中關於第一介面層130之敘述,在此不再贅述。FIG. 1B is a schematic diagram of a flexible electronic device according to a second embodiment of the present disclosure. Referring to FIG. 1B , the difference between the embodiment and the embodiment of FIG. 1A is that, in the flexible electronic device 100 ′, the first interface layer 130 ′ is formed on the upper surface of the electronic component 120 , and the first interface layer 130 ′ The electronic component 120 is not completely covered. The first barrier layer 140 is formed on the first interface layer 130' and covers the first interface layer 130' and the electronic component 120. The first barrier layer 140 is in contact with the side of the electronic component 120. In the embodiment, the first The material of the surface layer 130' is the same as that of the first interface layer 130 in the foregoing embodiment, and details are not described herein again.

第2圖繪示本揭露內容之第三實施例之可撓式電子裝置之示意圖。請參照第2圖,本實施例與第1A圖之實施例之差別在於,可撓式電子裝置200更包括第二介面層230及第二阻障層240,第二介面層230形成於第一可撓式基板110上,第二阻障層240形成於第二介面層230和電子元件120之間。FIG. 2 is a schematic diagram of a flexible electronic device according to a third embodiment of the present disclosure. Referring to FIG. 2, the difference between the embodiment and the embodiment of FIG. 1A is that the flexible electronic device 200 further includes a second interface layer 230 and a second barrier layer 240. The second interface layer 230 is formed on the first On the flexible substrate 110, a second barrier layer 240 is formed between the second interface layer 230 and the electronic component 120.

如第2圖所示,實施例中,第二介面層230形成於第一可撓式基板110和第二阻障層240之間,可以增加第一可撓式基板110和第二阻障層240之間的附著性,提高兩者的密封性,進而提升第二阻障層240阻隔水氣與氧氣的效果,延長電子元件120的使用壽命。並且,經由第二介面層230形成於第一可撓式基板110和第二阻障層240之間,無須設置多層阻障層於第一可撓式基板110上就能夠達到良好的阻隔水氣與氧氣的效果。本實施例中與前述實施例相同之元件係沿用同樣的元件標號,且相同元件之相關說明請參考前述,在此不再贅述。As shown in FIG. 2, in the embodiment, the second interface layer 230 is formed between the first flexible substrate 110 and the second barrier layer 240, and the first flexible substrate 110 and the second barrier layer may be added. The adhesion between the 240 improves the sealing property of the two, thereby improving the effect of the second barrier layer 240 blocking moisture and oxygen, and prolonging the service life of the electronic component 120. Moreover, the second interface layer 230 is formed between the first flexible substrate 110 and the second barrier layer 240, and a multi-layer barrier layer is disposed on the first flexible substrate 110 to achieve good moisture resistance. With the effect of oxygen. The same components as those in the foregoing embodiments are denoted by the same reference numerals, and the related descriptions of the same components are referred to the foregoing, and are not described herein again.

實施例中,第二介面層230之材質同前述實施例中關於第一介面層130之敘述,在此不再贅述。實際應用時,第一介面層130和第二介面層230可以選用相同或不同的材質。In the embodiment, the material of the second interface layer 230 is the same as that of the first interface layer 130 in the foregoing embodiment, and details are not described herein again. In practical applications, the first interface layer 130 and the second interface layer 230 may be of the same or different materials.

實施例中,第二阻障層240之材質同前述實施例中關於第一阻障層140之敘述,在此不再贅述。實施例中,第二阻障層240之材質與第二介面層230之材質係為不同。In the embodiment, the material of the second barrier layer 240 is the same as that of the first barrier layer 140 in the foregoing embodiment, and details are not described herein again. In the embodiment, the material of the second barrier layer 240 is different from the material of the second interface layer 230.

第3圖繪示本揭露內容之第四實施例之可撓式電子裝置之示意圖,第4圖繪示本揭露內容之第五實施例之可撓式電子裝置之示意圖。請參照第3~4圖,第四實施例及第五實施例與第2圖之實施例之差別在於,可撓式電子裝置300、300’更包括功能性膜(functional film)370,功能性膜370形成於第一可撓式基板110和電子元件120之間。3 is a schematic diagram of a flexible electronic device according to a fourth embodiment of the present disclosure, and FIG. 4 is a schematic diagram showing a flexible electronic device according to a fifth embodiment of the present disclosure. Referring to FIGS. 3 to 4, the fourth embodiment and the fifth embodiment differ from the embodiment of FIG. 2 in that the flexible electronic device 300, 300' further includes a functional film 370, which is functional. The film 370 is formed between the first flexible substrate 110 and the electronic component 120.

第四實施例中,如第3圖所示,功能性膜370形成於第二阻障層240和電子元件120之間。第五實施例中,如第4圖所示,功能性膜370形成於第一可撓式基板110和第二介面層230之間。實施例中,功能性膜370例如是彩色濾光片或觸控式面板。In the fourth embodiment, as shown in FIG. 3, the functional film 370 is formed between the second barrier layer 240 and the electronic component 120. In the fifth embodiment, as shown in FIG. 4, the functional film 370 is formed between the first flexible substrate 110 and the second interface layer 230. In an embodiment, the functional film 370 is, for example, a color filter or a touch panel.

第5圖繪示本揭露內容之第六實施例之可撓式電子裝置之示意圖。請參照第5圖,本實施例與第3圖之實施例之差別在於,可撓式電子裝置500更包括第三介面層530及第三阻障層540,第三介面層530形成於第二可撓式基板160上,第三阻障層540形成於第三介面層530和封裝膠材層150之間。FIG. 5 is a schematic diagram of a flexible electronic device according to a sixth embodiment of the present disclosure. Referring to FIG. 5, the difference between the embodiment and the embodiment of FIG. 3 is that the flexible electronic device 500 further includes a third interface layer 530 and a third barrier layer 540. The third interface layer 530 is formed in the second layer. On the flexible substrate 160, a third barrier layer 540 is formed between the third interface layer 530 and the encapsulant layer 150.

如第5圖所示,實施例中,第三介面層530形成於第二可撓式基板160和第三阻障層540之間,可以增加第二可撓式基板160和第三阻障層540之間的附著性,提高兩者的密封性,進而提升第三阻障層540阻隔水氣與氧氣的效果,延長電子元件120的使用壽命。並且,經由第三介面層530形成於第二可撓式基板160和第三阻障層540之間,無須設置多層阻障層於第二可撓式基板160上就能夠達到良好的阻隔水氣與氧氣的效果。本實施例中與前述實 施例相同之元件係沿用同樣的元件標號,且相同元件之相關說明請參考前述,在此不再贅述。As shown in FIG. 5, in the embodiment, the third interface layer 530 is formed between the second flexible substrate 160 and the third barrier layer 540, and the second flexible substrate 160 and the third barrier layer may be added. The adhesion between the 540 improves the sealing property of the two, thereby improving the effect of the third barrier layer 540 blocking moisture and oxygen, and prolonging the service life of the electronic component 120. Moreover, the third interface layer 530 is formed between the second flexible substrate 160 and the third barrier layer 540, and a multi-layer barrier layer is disposed on the second flexible substrate 160 to achieve good moisture resistance. With the effect of oxygen. In the present embodiment and the foregoing The same components are used for the same components, and the related descriptions of the same components are referred to the foregoing, and are not described herein again.

實施例中,第三介面層530之材質同前述實施例中關於第一介面層130之敘述,在此不再贅述。實際應用時,第一介面層130、第二介面層230及第三介面層530可以選用相同或不同的材質。In the embodiment, the material of the third interface layer 530 is the same as that of the first interface layer 130 in the foregoing embodiment, and details are not described herein again. In practical applications, the first interface layer 130, the second interface layer 230, and the third interface layer 530 may be the same or different materials.

實施例中,第三阻障層540之材質同前述實施例中關於第一阻障層140之敘述,在此不再贅述。實施例中,第三阻障層540之材質與第三介面層530之材質係為不同。In the embodiment, the material of the third barrier layer 540 is the same as that of the first barrier layer 140 in the foregoing embodiment, and details are not described herein again. In the embodiment, the material of the third barrier layer 540 is different from the material of the third interface layer 530.

第6圖繪示本揭露內容之第七實施例之可撓式電子裝置之示意圖,第7圖繪示本揭露內容之第八實施例之可撓式電子裝置之示意圖。請參照第6~7圖,第七實施例及第八實施例與第5圖之實施例之差別在於,可撓式電子裝置600、600’更包括功能性膜670,功能性膜670形成於第二可撓式基板160和封裝膠材層150之間。FIG. 6 is a schematic diagram of a flexible electronic device according to a seventh embodiment of the present disclosure, and FIG. 7 is a schematic diagram of a flexible electronic device according to an eighth embodiment of the present disclosure. Referring to FIGS. 6-7, the difference between the seventh embodiment and the eighth embodiment and the fifth embodiment is that the flexible electronic device 600, 600' further includes a functional film 670, and the functional film 670 is formed on Between the second flexible substrate 160 and the encapsulant layer 150.

第七實施例中,如第6圖所示,功能性膜670形成於第三阻障層540和封裝膠材層150之間。第八實施例中,如第7圖所示,功能性膜670形成於第二可撓式基板160和第三介面層530之間。實施例中,功能性膜670例如是彩色濾光片或觸控式面板。In the seventh embodiment, as shown in FIG. 6, a functional film 670 is formed between the third barrier layer 540 and the encapsulant layer 150. In the eighth embodiment, as shown in FIG. 7, a functional film 670 is formed between the second flexible substrate 160 and the third interface layer 530. In an embodiment, the functional film 670 is, for example, a color filter or a touch panel.

以下係就實施例作進一步說明。以下實施例及比較例1~2中,係列出簡化的結構配置,其中比較例1之結構不包括第一介面層130,比較例2之結構不包括第一介面層130及封裝膠材層150。然而以下之實施例僅為例示說明 之用,而不應被解釋為本揭露內容實施之限制。The following examples are further described. In the following examples and comparative examples 1 and 2, a simplified structural configuration is series, wherein the structure of the comparative example 1 does not include the first interface layer 130, and the structure of the comparative example 2 does not include the first interface layer 130 and the encapsulant layer 150. . However, the following examples are merely illustrative. It should not be construed as limiting the implementation of the disclosure.

(1)實施例之結構配置:第一可撓式基板110/電子元件120/第一介面層130/阻障層/第一阻障層140/封裝膠材層150。(1) Structural configuration of the embodiment: first flexible substrate 110 / electronic component 120 / first interface layer 130 / barrier layer / first barrier layer 140 / package adhesive layer 150.

(2)比較例1之結構配置:第一可撓式基板110/電子元件120/阻障層/第一阻障層140/封裝膠材層150。(2) Structural configuration of Comparative Example 1: First flexible substrate 110 / electronic component 120 / barrier layer / first barrier layer 140 / package adhesive layer 150.

(3)實施例之結構配置:第一可撓式基板110/電子元件120/阻障層/第一阻障層140。(3) Structural configuration of the embodiment: first flexible substrate 110 / electronic component 120 / barrier layer / first barrier layer 140.

以下表1中,實施例及比較例1~2之樣品的水氣穿透率(WVTR)數據係於60℃/90%相對濕度(relative humidity,RH)之條件下所測得,其中折彎操作(bending operation)之條件為折彎曲率半徑5公分且折彎次數為100次。In Table 1 below, the water vapor transmission rate (WVTR) data of the samples of Examples and Comparative Examples 1 and 2 were measured under conditions of 60 ° C / 90% relative humidity (RH), in which bending was performed. The conditions of the bending operation are a bending bending radius of 5 cm and a bending number of 100 times.

以下表2之數據係將實施例及比較例2之樣品靜置固定時間後測得之單位畫素發光區域面積縮小之比例。The data in the following Table 2 is the ratio of the area of the unit pixel light-emitting region measured after the samples of the examples and the comparative examples were allowed to stand for a fixed period of time.

從表1中可看出,比較例1~2中,折彎操作之前的水氣穿透率係為2.1 10-2 ~5.1 10-2 之間,且經過折彎操作之後,其水氣穿透率大幅上升。相較之下,本揭露內容之實施例中,折彎操作之前的水氣穿透率係為至少小於5.1 10-4 ,其阻隔水氣的效果是比較例1~2的100倍以上,並且即使經過折彎操作之後,其水氣穿透率亦未有明顯改變。換句話說,本揭露內容之實施例中的樣品,不但具有良好的阻隔水氣之效果,並且具有良好抗應力的能力。As can be seen from Table 1, in Comparative Examples 1 and 2, the water vapor transmission rate before the bending operation was between 2.1 * 10 -2 and 5.1 * 10 -2 , and after the bending operation, the water was The gas penetration rate has risen sharply. In contrast, in the embodiment of the present disclosure, the water vapor transmission rate before the bending operation is at least less than 5.1 * 10 -4 , and the effect of blocking moisture is more than 100 times that of the comparative examples 1 to 2, And even after the bending operation, the water vapor permeability did not change significantly. In other words, the sample in the embodiment of the present disclosure not only has a good moisture barrier effect, but also has good resistance to stress.

從表2中可看出,比較例2中,經過靜置之後,其發光區域面積大幅縮小,顯示其阻隔水氣的能力不佳。相較之下,本揭露內容之實施例中,即使經過靜置1000小時,其發光區域面積幾乎沒有改變,顯示其阻隔水氣的能力良好。換句話說,本揭露內容之實施例中的樣品,即使經過長時間靜置仍具有良好的阻隔水氣之效果。As can be seen from Table 2, in Comparative Example 2, after standing, the area of the light-emitting area was greatly reduced, indicating that the ability to block moisture was poor. In contrast, in the embodiment of the present disclosure, even after standing for 1000 hours, the area of the light-emitting area hardly changes, indicating that the ability to block moisture is good. In other words, the sample in the embodiment of the present disclosure has a good effect of blocking moisture even after standing for a long time.

以下係提出實施例之一種可撓式電子裝置之製造方法,然該些步驟僅為舉例說明之用,並非用以限縮本發明。具有通常知識者當可依據實際實施態樣的需要對該些 步驟加以修飾或變化。請參照第8A圖至第8D圖、第9A圖至第9CA圖及第10A圖至第10C圖。第8A圖至第8D圖繪示依照本發明之一實施例之一種可撓式電子裝置之製造方法示意圖。第9A圖至第9CA圖繪示依照本發明之另一實施例之一種可撓式電子裝置之製造方法示意圖。第10A圖至第10C圖繪示依照本發明之又一實施例之一種可撓式電子裝置之製造方法示意圖。The following is a method for manufacturing a flexible electronic device according to an embodiment. However, the steps are for illustrative purposes only and are not intended to limit the present invention. Those who have the usual knowledge can use these according to the actual implementation. The steps are modified or changed. Please refer to FIGS. 8A to 8D, 9A to 9CA, and 10A to 10C. 8A to 8D are schematic views showing a manufacturing method of a flexible electronic device according to an embodiment of the present invention. 9A to 9CA are schematic views showing a manufacturing method of a flexible electronic device according to another embodiment of the present invention. 10A to 10C are schematic views showing a manufacturing method of a flexible electronic device according to still another embodiment of the present invention.

以下係說明第1A圖之半導體結構100之製造過程。請參照第8A圖至第8D圖。The manufacturing process of the semiconductor structure 100 of Fig. 1A will be described below. Please refer to Figures 8A to 8D.

請參照第8A圖,提供第一可撓式基板110。接著,請參照第8B圖,設置電子元件120於第一可撓式基板110上。Referring to FIG. 8A, a first flexible substrate 110 is provided. Next, referring to FIG. 8B, the electronic component 120 is disposed on the first flexible substrate 110.

請參照第8C圖,以熱蒸鍍製程形成第一介面層130於電子元件120上,以及形成第一阻障層140於第一介面層130上。實施例中,第一阻障層140需具有緻密的結構以達到阻隔水氣與氧氣的效果,第一阻障層140例如是以濺鍍(sputtering)製程、化學氣相沈積(chemical vapor deposition,CVD)製程或任何其他適於形成緻密結構膜層的製程方式形成於第一介面層130上。Referring to FIG. 8C, the first interface layer 130 is formed on the electronic component 120 by a thermal evaporation process, and the first barrier layer 140 is formed on the first interface layer 130. In the embodiment, the first barrier layer 140 needs to have a dense structure to achieve the effect of blocking moisture and oxygen. The first barrier layer 140 is, for example, a sputtering process, chemical vapor deposition (chemical vapor deposition, A CVD) process or any other process suitable for forming a dense structural film layer is formed on the first interface layer 130.

一般而言,阻障層必須具有緻密的結構以達到阻隔水氣與氧氣的效果,因此通常以例如是濺鍍或化學氣相沈積的方式製作。然而,化學氣相沈積製程與濺鍍製程都會產生電漿,當阻障層直接形成於電子元件上(例如是有機發光二極體)時,製程中產生的電漿可能會破壞電子元件。本揭 露內容之實施例中,先以熱蒸鍍製程形成第一介面層130於電子元件120上,再形成第一阻障層140於第一介面層130上,可以利用第一介面層130保護電子元件120,達到使電子元件120免於受到電漿破壞的效果。In general, the barrier layer must have a dense structure to achieve the effect of blocking moisture and oxygen, and thus is usually produced by, for example, sputtering or chemical vapor deposition. However, both the chemical vapor deposition process and the sputtering process generate plasma. When the barrier layer is formed directly on the electronic component (for example, an organic light-emitting diode), the plasma generated in the process may damage the electronic component. This disclosure In the embodiment of the disclosure, the first interface layer 130 is formed on the electronic component 120 by a thermal evaporation process, and the first barrier layer 140 is formed on the first interface layer 130. The first interface layer 130 can be used to protect the electrons. Element 120 achieves the effect of protecting electronic component 120 from plasma damage.

再者,以電子元件120為有機發光二極體為例,有機發光二極體基本上係以熱蒸鍍製程製作,因此同樣以熱蒸鍍製程形成第一介面層130於有機發光二極體(電子元件120)上,可以和有機發光二極體的製作在同一個製程腔體中進行,不需使用額外的設備,可以簡化製程步驟以及縮短製程時間。Furthermore, taking the electronic component 120 as an organic light-emitting diode as an example, the organic light-emitting diode is basically formed by a thermal evaporation process, so that the first interface layer 130 is formed in the organic light-emitting diode by a thermal evaporation process. (Electronic component 120) can be fabricated in the same process chamber as the organic light-emitting diode. No additional equipment is required, which simplifies the process steps and shortens the process time.

接著,請參照第8D圖,形成封裝膠材層150於第一阻障層上140,以及形成第二可撓式基板160於封裝膠材層150上。至此,形成如第8D圖(第1A圖)所示之可撓式電子裝置100。Next, referring to FIG. 8D, the encapsulation layer 150 is formed on the first barrier layer 140, and the second flexible substrate 160 is formed on the encapsulation layer 150. Thus far, the flexible electronic device 100 as shown in Fig. 8D (Fig. 1A) is formed.

以下係說明第2圖之半導體結構200之製造過程。請同時參照第8C圖至第8D圖及第9A圖至第9C圖。The manufacturing process of the semiconductor structure 200 of Fig. 2 will be described below. Please refer to the 8C to 8D and 9A to 9C drawings at the same time.

請參照第9A圖,提供第一可撓式基板110。接著,形成第二介面層230於第一可撓式基板110上,以及形成第二阻障層240於第二介面層230上。實施例中,第二介面層230例如是以濺鍍製程、化學氣相沈積製程、熱蒸鍍製程、或其他任何適合的製程方式形成於第一可撓式基板110上。實施例中,第二阻障層240例如是以濺鍍製程、化學氣相沈積製程或任何其他適於形成緻密結構膜層的製程方式形成於第二介面層230上。Referring to FIG. 9A, a first flexible substrate 110 is provided. Next, a second interface layer 230 is formed on the first flexible substrate 110, and a second barrier layer 240 is formed on the second interface layer 230. In an embodiment, the second interface layer 230 is formed on the first flexible substrate 110 by, for example, a sputtering process, a chemical vapor deposition process, a thermal evaporation process, or any other suitable process. In an embodiment, the second barrier layer 240 is formed on the second interface layer 230, for example, by a sputtering process, a chemical vapor deposition process, or any other process suitable for forming a dense structural film layer.

請參照第9B圖,設置電子元件120於第二阻障層240上。實施例中,第二阻障層240形成於第二介面層230和電子元件120之間。Referring to FIG. 9B, the electronic component 120 is disposed on the second barrier layer 240. In an embodiment, the second barrier layer 240 is formed between the second interface layer 230 and the electronic component 120.

接著,請參照第9C圖,以類似於第8C圖至第8D圖所示之方式,以熱蒸鍍製程形成第一介面層130於電子元件120上、形成第一阻障層140於第一介面層130上、形成封裝膠材層150於第一阻障層上140,以及形成第二可撓式基板160於封裝膠材層150上。至此,形成如第9C圖(第2圖)所示之可撓式電子裝置200。Next, referring to FIG. 9C, the first interface layer 130 is formed on the electronic component 120 by a thermal evaporation process in a manner similar to that shown in FIGS. 8C to 8D to form the first barrier layer 140. On the interface layer 130, the encapsulation layer 150 is formed on the first barrier layer 140, and the second flexible substrate 160 is formed on the encapsulation layer 150. Thus far, the flexible electronic device 200 as shown in Fig. 9C (Fig. 2) is formed.

一實施例中,亦可選擇性地形成功能性膜370於第一可撓式基板110和電子元件120之間,以形成如第3圖所示之可撓式電子裝置300或如第4圖所示之可撓式電子裝置300’。In an embodiment, the functional film 370 may be selectively formed between the first flexible substrate 110 and the electronic component 120 to form the flexible electronic device 300 as shown in FIG. 3 or as shown in FIG. The flexible electronic device 300' is shown.

以下係說明第5圖之半導體結構500之製造過程。請同時參照第8C圖、第9A圖至第9B圖及第10A圖至第10C圖。The manufacturing process of the semiconductor structure 500 of Fig. 5 will be described below. Please refer to FIG. 8C, FIG. 9A to FIG. 9B, and FIGS. 10A to 10C simultaneously.

請參照第10A圖,以類似於第8C圖及第9A圖至第9B圖所示之方式,提供第一可撓式基板110、形成第二介面層230於第一可撓式基板110上、形成第二阻障層240於第二介面層230上、設置電子元件120於第二阻障層240上、以熱蒸鍍製程形成第一介面層130於電子元件120上以及形成第一阻障層140於第一介面層130上。Referring to FIG. 10A, a first flexible substrate 110 is formed, and a second interface layer 230 is formed on the first flexible substrate 110, in a manner similar to that shown in FIG. 8C and FIGS. 9A to 9B. Forming a second barrier layer 240 on the second interface layer 230, disposing the electronic component 120 on the second barrier layer 240, forming a first interface layer 130 on the electronic component 120 by a thermal evaporation process, and forming a first barrier layer Layer 140 is on first interface layer 130.

接著,請參照第10B~10C圖,形成封裝膠材層150於第一阻障層上140,形成第二可撓式基板160於封裝膠 材層150上,形成第三介面層530於第二可撓式基板160上,以及形成第三阻障層540於第三介面層530和封裝膠材層150之間。實施例中,第三介面層530例如是以濺鍍製程、化學氣相沈積製程、熱蒸鍍製程、或其他任何適合的製程方式形成於第二可撓式基板160。實施例中,第三阻障層540例如是以濺鍍製程、化學氣相沈積製程或任何其他適於形成緻密結構膜層的製程方式形成於第三介面層530上。Next, please refer to FIGS. 10B-10C to form a package adhesive layer 150 on the first barrier layer 140 to form a second flexible substrate 160 on the package adhesive. On the material layer 150, a third interface layer 530 is formed on the second flexible substrate 160, and a third barrier layer 540 is formed between the third interface layer 530 and the encapsulant layer 150. In an embodiment, the third interface layer 530 is formed on the second flexible substrate 160 by, for example, a sputtering process, a chemical vapor deposition process, a thermal evaporation process, or any other suitable process. In an embodiment, the third barrier layer 540 is formed on the third interface layer 530, for example, by a sputtering process, a chemical vapor deposition process, or any other process suitable for forming a dense structural film layer.

實施例中,形成第三阻障層540於第三介面層530和封裝膠材層150之間的製造方法例如包括以下步驟:如第10B圖所示,提供第二可撓式基板160,形成第三介面層530於第二可撓式基板160上,以及形成第三阻障層540於第三介面層530上。接著,如第10C圖所示,接合第三阻障層540和封裝膠材層150。至此,形成如第10C圖(第5圖)所示之可撓式電子裝置500。In an embodiment, the manufacturing method for forming the third barrier layer 540 between the third interface layer 530 and the encapsulant layer 150 includes, for example, the following steps: as shown in FIG. 10B, providing the second flexible substrate 160 to form The third interface layer 530 is on the second flexible substrate 160, and the third barrier layer 540 is formed on the third interface layer 530. Next, as shown in FIG. 10C, the third barrier layer 540 and the encapsulant layer 150 are bonded. Thus far, the flexible electronic device 500 as shown in Fig. 10C (Fig. 5) is formed.

一實施例中,亦可選擇性地形成功能性膜670於第二可撓式基板160和封裝膠材層150之間,以形成如第6圖所示之可撓式電子裝置600或如第7圖所示之可撓式電子裝置600’。In an embodiment, the functional film 670 can also be selectively formed between the second flexible substrate 160 and the encapsulant layer 150 to form the flexible electronic device 600 as shown in FIG. Figure 7 shows a flexible electronic device 600'.

綜上所述,雖然本揭露內容已以實施例揭露如上,然其並非用以限定本揭露內容之保護範圍。本揭露內容所屬技術領域中具有通常知識者,在不脫離本揭露內容之精神和範圍內,當可作各種之更動與潤飾。因此,本揭露內容之保護範圍當視後附之申請專利範圍所界定者為準。In summary, although the disclosure has been disclosed in the above embodiments, it is not intended to limit the scope of the disclosure. Those skilled in the art can make various changes and modifications without departing from the spirit and scope of the disclosure. Therefore, the scope of protection of this disclosure is subject to the definition of the scope of the appended claims.

100、100’、200、300、300’、500、600、600’‧‧‧可撓式電子裝置100, 100', 200, 300, 300', 500, 600, 600' ‧ ‧ flexible electronic devices

110‧‧‧第一可撓式基板110‧‧‧First flexible substrate

120‧‧‧電子元件120‧‧‧Electronic components

120a‧‧‧陰極120a‧‧‧ cathode

130、130’‧‧‧第一介面層130, 130’‧‧‧ first interface layer

140‧‧‧第一阻障層140‧‧‧First barrier layer

150‧‧‧封裝膠材層150‧‧‧Package layer

160‧‧‧第二可撓式基板160‧‧‧Second flexible substrate

230‧‧‧第二介面層230‧‧‧Second interface layer

240‧‧‧第二阻障層240‧‧‧second barrier layer

370、670‧‧‧功能性膜370, 670‧‧‧ functional film

530‧‧‧第三介面層530‧‧‧ third interface layer

540‧‧‧第三阻障層540‧‧‧ third barrier layer

第1A圖繪示本揭露內容之第一實施例之可撓式電子裝置之示意圖。FIG. 1A is a schematic diagram of a flexible electronic device according to a first embodiment of the present disclosure.

第1B圖繪示本揭露內容之第二實施例之可撓式電子裝置之示意圖。FIG. 1B is a schematic diagram of a flexible electronic device according to a second embodiment of the present disclosure.

第2圖繪示本揭露內容之第三實施例之可撓式電子裝置之示意圖。FIG. 2 is a schematic diagram of a flexible electronic device according to a third embodiment of the present disclosure.

第3圖繪示本揭露內容之第四實施例之可撓式電子裝置之示意圖。FIG. 3 is a schematic diagram of a flexible electronic device according to a fourth embodiment of the present disclosure.

第4圖繪示本揭露內容之第五實施例之可撓式電子裝置之示意圖。FIG. 4 is a schematic diagram of a flexible electronic device according to a fifth embodiment of the present disclosure.

第5圖繪示本揭露內容之第六實施例之可撓式電子裝置之示意圖。FIG. 5 is a schematic diagram of a flexible electronic device according to a sixth embodiment of the present disclosure.

第6圖繪示本揭露內容之第七實施例之可撓式電子裝置之示意圖。FIG. 6 is a schematic diagram of a flexible electronic device according to a seventh embodiment of the present disclosure.

第7圖繪示本揭露內容之第八實施例之可撓式電子裝置之示意圖。FIG. 7 is a schematic diagram of a flexible electronic device according to an eighth embodiment of the present disclosure.

第8A圖至第8D圖繪示依照本發明之一實施例之一種可撓式電子裝置之製造方法示意圖。8A to 8D are schematic views showing a manufacturing method of a flexible electronic device according to an embodiment of the present invention.

第9A圖至第9C圖繪示依照本發明之另一實施例之一種可撓式電子裝置之製造方法示意圖。9A to 9C are schematic views showing a manufacturing method of a flexible electronic device according to another embodiment of the present invention.

第10A圖至第10C圖繪示依照本發明之又一實施例之一種可撓式電子裝置之製造方法示意圖。10A to 10C are schematic views showing a manufacturing method of a flexible electronic device according to still another embodiment of the present invention.

100‧‧‧可撓式電子裝置100‧‧‧Flexible electronic devices

110‧‧‧第一可撓式基板110‧‧‧First flexible substrate

120‧‧‧電子元件120‧‧‧Electronic components

120a‧‧‧陰極120a‧‧‧ cathode

130‧‧‧第一介面層130‧‧‧First interface layer

140‧‧‧第一阻障層140‧‧‧First barrier layer

150‧‧‧封裝膠材層150‧‧‧Package layer

160‧‧‧第二可撓式基板160‧‧‧Second flexible substrate

Claims (18)

一種可撓式(flexible)一種可撓式(flexible)電子裝置,包括:一第一可撓式基板;一電子元件設置於該第一可撓式基板上;一第一介面層形成於該電子元件上,其中該第一介面層之材質包括一或多種金屬元素及一或多種無機金屬氧化物之組合,該第一介面層為一單層結構;以及一第一阻障(barrier)層形成於該第一介面層上,且該第一介面層之下表面與該電子元件接觸,該第一介面層之上表面與該第一阻障層接觸。 A flexible electronic device includes: a first flexible substrate; an electronic component disposed on the first flexible substrate; a first interface layer formed on the electronic In the component, the material of the first interface layer comprises a combination of one or more metal elements and one or more inorganic metal oxides, the first interface layer is a single layer structure; and a first barrier layer is formed On the first interface layer, the lower surface of the first interface layer is in contact with the electronic component, and the upper surface of the first interface layer is in contact with the first barrier layer. 如申請專利範圍第1項所述之可撓式電子裝置,其中該金屬元素係選自於由金(Au)、銀(Ag)、銅(Cu)、鋁(Al)、鉬(Mo)、鎢(W)及其組合所構成之群組,該無機金屬氧化物係選自於由銦錫氧化物(ITO)、氧化銀、氧化銅、氧化鉬、氧化鎢、氧化鈦、氧化釩及其組合所構成之群組。 The flexible electronic device of claim 1, wherein the metal element is selected from the group consisting of gold (Au), silver (Ag), copper (Cu), aluminum (Al), molybdenum (Mo), a group of tungsten (W) and a combination thereof selected from the group consisting of indium tin oxide (ITO), silver oxide, copper oxide, molybdenum oxide, tungsten oxide, titanium oxide, vanadium oxide, and the like The group formed by the combination. 如申請專利範圍第1項所述之可撓式電子裝置,其中該第一介面層之材質更包括一或多種無機非金屬元素,該無機非金屬元素係選自於由硒(Se)、硫(S)、銻(Te)及其組合所構成之群組。 The flexible electronic device of claim 1, wherein the material of the first interface layer further comprises one or more inorganic non-metal elements selected from the group consisting of selenium (Se) and sulfur. A group consisting of (S), 锑 (Te), and combinations thereof. 如申請專利範圍第1項所述之可撓式電子裝置,其中該第一介面層之材質更包括一或多種有機金屬化合物,該有機金屬化合物係選自於由銥錯合物(iridium complex)、鋨錯合物(osmium complex)、錸錯合物(rhenium complex)及其組合所構成之群組。 The flexible electronic device of claim 1, wherein the material of the first interface layer further comprises one or more organometallic compounds selected from the group consisting of iridium complexes. , a group of osmium complexes, rhenium complexes, and combinations thereof. 如申請專利範圍第1項所述之可撓式電子裝置, 其中該第一介面層之材質包括一導電材料。 The flexible electronic device according to claim 1, The material of the first interface layer comprises a conductive material. 如申請專利範圍第1項所述之可撓式電子裝置,更包括一功能性膜形成於該第一可撓式基板和該電子元件之間。 The flexible electronic device of claim 1, further comprising a functional film formed between the first flexible substrate and the electronic component. 如申請專利範圍第1項所述之可撓式電子裝置,更包括:一第二介面層形成於該第一可撓式基板上;以及一第二阻障層形成於該第二介面層和該電子元件之間。 The flexible electronic device of claim 1, further comprising: a second interface layer formed on the first flexible substrate; and a second barrier layer formed on the second interface layer and Between the electronic components. 如申請專利範圍第1項所述之可撓式電子裝置,更包括:一封裝膠材層(encapsulation adhesive layer)形成於該第一阻障層上;以及一第二可撓式基板形成於該封裝膠材層上。 The flexible electronic device of claim 1, further comprising: an encapsulation adhesive layer formed on the first barrier layer; and a second flexible substrate formed thereon Encapsulated on the layer of glue. 如申請專利範圍第8項所述之可撓式電子裝置,更包括:一第三介面層形成於該第二可撓式基板上;以及一第三阻障層形成於該第三介面層和該封裝膠材層之間。 The flexible electronic device of claim 8, further comprising: a third interface layer formed on the second flexible substrate; and a third barrier layer formed on the third interface layer and The encapsulant is between the layers of the glue. 如申請專利範圍第8項所述之可撓式電子裝置,更包括一功能性膜形成於該第二可撓式基板和該封裝膠材層之間。 The flexible electronic device of claim 8, further comprising a functional film formed between the second flexible substrate and the encapsulant layer. 一種可撓式電子裝置之製造方法,包括:提供一第一可撓式基板;設置一電子元件於該第一可撓式基板上; 以一熱蒸鍍製程(thermal evaporation process)形成一第一介面層於該電子元件上,其中該第一介面層為一單層結構;以及形成一第一阻障層於該第一介面層上,且該第一介面層之下表面與該電子元件接觸,該第一介面層之上表面與該第一阻障層接觸。 A method for manufacturing a flexible electronic device, comprising: providing a first flexible substrate; and disposing an electronic component on the first flexible substrate; Forming a first interface layer on the electronic component by a thermal evaporation process, wherein the first interface layer is a single layer structure; and forming a first barrier layer on the first interface layer And a lower surface of the first interface layer is in contact with the electronic component, and an upper surface of the first interface layer is in contact with the first barrier layer. 如申請專利範圍第11項所述之可撓式電子裝置之製造方法,其中該第一介面層之材質包括一或多種金屬元素、一或多種無機非金屬元素、一或多種無機金屬氧化物、一或多種有機金屬化合物或前述任兩種以上之組合。 The method for manufacturing a flexible electronic device according to claim 11, wherein the material of the first interface layer comprises one or more metal elements, one or more inorganic non-metal elements, one or more inorganic metal oxides, One or more organometallic compounds or a combination of any two or more of the foregoing. 如申請專利範圍第12項所述之可撓式電子裝置之製造方法,其中該無機金屬氧化物係選自於由銦錫氧化物(ITO)、氧化銀、氧化銅、氧化鉬、氧化鎢、氧化鈦、氧化釩及其組合所構成之群組。 The method for manufacturing a flexible electronic device according to claim 12, wherein the inorganic metal oxide is selected from the group consisting of indium tin oxide (ITO), silver oxide, copper oxide, molybdenum oxide, tungsten oxide, A group of titanium oxide, vanadium oxide, and combinations thereof. 如申請專利範圍第11項所述之可撓式電子裝置之製造方法,更包括:形成一功能性膜於該第一可撓式基板和該電子元件之間。 The method for manufacturing a flexible electronic device according to claim 11, further comprising: forming a functional film between the first flexible substrate and the electronic component. 如申請專利範圍第11項所述之可撓式電子裝置之製造方法,更包括:形成一第二介面層於該第一可撓式基板上;以及形成一第二阻障層於該第二介面層和該電子元件之間。 The method of manufacturing the flexible electronic device of claim 11, further comprising: forming a second interface layer on the first flexible substrate; and forming a second barrier layer on the second Between the interface layer and the electronic component. 如申請專利範圍第11項所述之可撓式電子裝置之製造方法,更包括: 形成一封裝膠材層於該第一阻障層上;以及形成一第二可撓式基板於該封裝膠材層上。 The method for manufacturing a flexible electronic device according to claim 11, further comprising: Forming a package adhesive layer on the first barrier layer; and forming a second flexible substrate on the package adhesive layer. 如申請專利範圍第16項所述之可撓式電子裝置之製造方法,更包括:形成一第三介面層於該第二可撓式基板上;以及形成一第三阻障層於該第三介面層和該封裝膠材層之間。 The method for manufacturing a flexible electronic device according to claim 16, further comprising: forming a third interface layer on the second flexible substrate; and forming a third barrier layer on the third Between the interface layer and the encapsulant layer. 如申請專利範圍第16項所述之可撓式電子裝置之製造方法,更包括:形成一功能性膜於該第二可撓式基板和該封裝膠材層之間。The method for manufacturing a flexible electronic device according to claim 16, further comprising: forming a functional film between the second flexible substrate and the encapsulant layer.
TW101138900A 2012-10-22 2012-10-22 Flexible electronic device and manufacturing method of the same TWI487074B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
TW101138900A TWI487074B (en) 2012-10-22 2012-10-22 Flexible electronic device and manufacturing method of the same
CN201210489100.6A CN103779379B (en) 2012-10-22 2012-11-27 Flexible electronic device and manufacturing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW101138900A TWI487074B (en) 2012-10-22 2012-10-22 Flexible electronic device and manufacturing method of the same

Publications (2)

Publication Number Publication Date
TW201417224A TW201417224A (en) 2014-05-01
TWI487074B true TWI487074B (en) 2015-06-01

Family

ID=50571443

Family Applications (1)

Application Number Title Priority Date Filing Date
TW101138900A TWI487074B (en) 2012-10-22 2012-10-22 Flexible electronic device and manufacturing method of the same

Country Status (2)

Country Link
CN (1) CN103779379B (en)
TW (1) TWI487074B (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9935289B2 (en) 2010-09-10 2018-04-03 Industrial Technology Research Institute Institute Environmental sensitive element package and encapsulation method thereof
CN104393187B (en) * 2014-11-17 2018-09-11 合肥鑫晟光电科技有限公司 A kind of package substrate and preparation method thereof, OLED display
CN104538557A (en) * 2014-12-23 2015-04-22 深圳市华星光电技术有限公司 Flexible OLED displaying device and manufacturing method thereof
US9847509B2 (en) 2015-01-22 2017-12-19 Industrial Technology Research Institute Package of flexible environmental sensitive electronic device and sealing member
CN108630822B (en) * 2017-03-24 2020-06-30 京东方科技集团股份有限公司 Assembly of top-emitting OLED device and top-emitting OLED device
JP6709007B2 (en) * 2018-12-28 2020-06-10 国立大学法人山形大学 Method for sealing organic electroluminescence element
US20220209188A1 (en) * 2019-04-25 2022-06-30 Applied Materials, Inc. Moisture barrier film having low refraction index and low water vapor tramission rate
CN110943183A (en) * 2019-11-27 2020-03-31 深圳市华星光电半导体显示技术有限公司 Display panel and manufacturing method thereof
CN112670300A (en) * 2020-12-23 2021-04-16 武汉华星光电半导体显示技术有限公司 Display module, preparation method and display device

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200629974A (en) * 2005-02-02 2006-08-16 Au Optronics Corp Encapsulation structure of organic electroluminescence device
US7187119B2 (en) * 2001-03-29 2007-03-06 Universal Display Corporation Methods and structures for reducing lateral diffusion through cooperative barrier layers
US7205718B2 (en) * 2004-06-24 2007-04-17 Eastman Kodak Company OLED display having thermally conductive adhesive
TW200829070A (en) * 2006-12-27 2008-07-01 Ind Tech Res Inst Organic electroluminescent device
TW201110281A (en) * 2009-09-15 2011-03-16 Ind Tech Res Inst Package of environmental sensitive element
TW201117368A (en) * 2009-02-25 2011-05-16 Global Oled Technology Llc Flexible OLED display with chiplets

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7015640B2 (en) * 2002-09-11 2006-03-21 General Electric Company Diffusion barrier coatings having graded compositions and devices incorporating the same
CN101131440B (en) * 2006-08-21 2010-07-14 宣茂科技股份有限公司 Optical diaphragm structure with light scattering and concentration function

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7187119B2 (en) * 2001-03-29 2007-03-06 Universal Display Corporation Methods and structures for reducing lateral diffusion through cooperative barrier layers
US7205718B2 (en) * 2004-06-24 2007-04-17 Eastman Kodak Company OLED display having thermally conductive adhesive
TW200629974A (en) * 2005-02-02 2006-08-16 Au Optronics Corp Encapsulation structure of organic electroluminescence device
TW200829070A (en) * 2006-12-27 2008-07-01 Ind Tech Res Inst Organic electroluminescent device
TW201117368A (en) * 2009-02-25 2011-05-16 Global Oled Technology Llc Flexible OLED display with chiplets
TW201110281A (en) * 2009-09-15 2011-03-16 Ind Tech Res Inst Package of environmental sensitive element

Also Published As

Publication number Publication date
TW201417224A (en) 2014-05-01
CN103779379B (en) 2016-07-13
CN103779379A (en) 2014-05-07

Similar Documents

Publication Publication Date Title
TWI487074B (en) Flexible electronic device and manufacturing method of the same
JP6073130B2 (en) Thin film encapsulation for an optoelectronic device, method of manufacturing the same, and optoelectronic device
KR101648016B1 (en) Organic optoelectronic device and a method for encapsulating said device
JP5335909B2 (en) Electroluminescent display device, lighting device or display device, and manufacturing process thereof
WO2018086191A1 (en) Oled display and manufacturing method thereof
TWI514564B (en) Display panel and method of making the same
US20120064278A1 (en) Package of environmental sensitive element and encapsulation method thereof
WO2016026225A1 (en) Organic light-emitting display device and method for packaging organic light-emitting diode
US9935289B2 (en) Environmental sensitive element package and encapsulation method thereof
US20130127335A1 (en) Electroluminescent display device
TW201222885A (en) Light emitting device
CN105247701A (en) Organic light-emitting device and method for manufacturing same
TWI514565B (en) Organic light emitting device and manufacturing method thereof
WO2010074748A1 (en) Multilayer devices on flexible supports
KR101740628B1 (en) Thin film for encapsulation
WO2019153831A1 (en) Electroluminescent element package structure, fabrication method thereof, and display device
US20180006262A1 (en) Organic light-emitting device
JP2013545230A5 (en)
CN105762298B (en) Organic light-emitting diode packaging structure, organic light emitting display and its manufacturing method
TWI260944B (en) Display device with passivation structure
WO2017154482A1 (en) Sealing structure and light emitting device
KR101668273B1 (en) Led interior walls for improving lamp efficiency and method for manufacturing the same
KR102343768B1 (en) Barrier film structure and organic electronic device having the same
US20200251684A1 (en) Light-emitting device
KR20160141535A (en) Organic light emitting display device and method for manufacturing the same