TWI482864B - A composition having a damping characteristic, and a damper to which the composition is applied - Google Patents

A composition having a damping characteristic, and a damper to which the composition is applied Download PDF

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TWI482864B
TWI482864B TW102130310A TW102130310A TWI482864B TW I482864 B TWI482864 B TW I482864B TW 102130310 A TW102130310 A TW 102130310A TW 102130310 A TW102130310 A TW 102130310A TW I482864 B TWI482864 B TW I482864B
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composition
damper
weight
damping
indium
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TW201508068A (en
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Univ Nat Formosa
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Description

具有阻尼特性之組成物以及應用該組成物的阻尼器Composition having damping characteristics and damper applying the same

本發明有關於一種具有阻尼特性的組成物,特別是有關於一種可耐受阻尼器作動時產生之高溫而維持良好阻尼特性的組成物,以及一種應用該組成物的阻尼器。The present invention relates to a composition having damping characteristics, and more particularly to a composition which can withstand the high temperature generated when the damper is actuated to maintain good damping characteristics, and a damper to which the composition is applied.

一般的油壓阻尼器內部充填有黏滯性的流體,亦即阻尼油,當阻尼器作動時,其活塞桿會帶動活塞擠壓阻尼油進而產生阻尼力。The general hydraulic damper is filled with a viscous fluid, that is, a damping oil. When the damper is actuated, the piston rod drives the piston to squeeze the damping oil to generate a damping force.

常見的阻尼油為矽油,利用矽油具有高黏度的特性,使得阻尼器可以將機械能量轉換成其他形式的能量,例如熱能。然而,矽油也有著部分缺點,例如長時間作動的活塞不僅會使矽油產生氣泡,也會逐漸使矽油本身的溫度升高,使阻尼油的黏度降低,導致阻尼力減弱,造成“阻尼衰退(Shock Fade)”的現象。此外,由於阻尼油為有機物質,因此,溫度升高的阻尼油也容易發生化學變化,致使阻尼油劣化,影響油壓阻尼器的阻尼力。The common damping oil is eucalyptus oil, which utilizes the high viscosity of eucalyptus oil, allowing the damper to convert mechanical energy into other forms of energy, such as heat. However, eucalyptus oil also has some disadvantages. For example, a piston that is operated for a long time will not only cause bubbles in the sputum oil, but also gradually increase the temperature of the sputum oil itself, so that the viscosity of the damping oil is lowered, resulting in a weakening of the damping force, resulting in "damping decay (Shock Fade)" phenomenon. In addition, since the damping oil is an organic substance, the damping oil having an increased temperature is also liable to undergo a chemical change, thereby deteriorating the damping oil and affecting the damping force of the oil pressure damper.

為了克服前述問題,通常會在矽油中添加其他的成分,藉以改變矽油的特性,或者直接改用其他流體裝填在阻尼器。但是,這些方式都會增加阻尼器的成本,而且不易穩定地控制阻尼器的性能。In order to overcome the aforementioned problems, other components are usually added to the eucalyptus oil to change the characteristics of the eucalyptus oil, or directly switch to other dampers to load the damper. However, these methods increase the cost of the damper and make it difficult to stably control the performance of the damper.

本發明之主要目的在於提供一種具有阻尼特性的組成物,其可應用於阻尼器,並能夠維持阻尼器的阻尼力,避免阻尼衰退的現象發生。SUMMARY OF THE INVENTION A primary object of the present invention is to provide a composition having damping characteristics which can be applied to a damper and which can maintain the damping force of the damper and avoid the occurrence of damping degradation.

本發明之另一目的在於提供一種應用該組成物的阻尼器。Another object of the present invention is to provide a damper to which the composition is applied.

為達成前揭目的,本發明所提供具有阻尼特性的組成 物,主要包括有10wt%至40wt%的銦(indium,In);45wt%至80wt%的鎵(gallium,Ga);以及5wt%至25wt%的錫(tin,Sn)。In order to achieve the foregoing, the present invention provides a composition having damping characteristics. The composition mainly includes 10% by weight to 40% by weight of indium (Indium); 45% by weight to 80% by weight of gallium (Ga); and 5% by weight to 25% by weight of tin (tin, Sn).

由於本發明之組成物為一種具有良好的黏稠度、導熱性與電特性但不具有發泡性的金屬合金,且屬於一種無機物質,所以當其應用於阻尼器時,不會因阻尼器長時間作動而產生氣泡,或是因阻尼器作動所產生的高溫而發生化學變化或黏度降低的情形,因此能夠維持阻尼器的阻尼力,避免阻尼衰退的現象發生。Since the composition of the present invention is a metal alloy having good viscosity, thermal conductivity and electrical properties but not foaming, and belongs to an inorganic substance, when it is applied to a damper, it is not long due to the damper. The time is generated to generate bubbles, or the chemical change or the viscosity is lowered due to the high temperature generated by the damper operation, so that the damping force of the damper can be maintained and the phenomenon of damping degradation can be avoided.

在本發明之組成物中,更可進一步包括有汞(mercury,Hg)、鉍(bismuth,Bi)、鋰(lithium,Li)、鈉(sodium,Na)、鉀(potassium,K)、銣(rubidium,Rb)或銫(cesium,Cs)至少一種元素。In the composition of the present invention, mercury (Hg), bismuth (Bi), lithium (lithium, Li), sodium (sodium, Na), potassium (potassium, K), strontium ( Rubidium, Rb) or cesium (Cs) at least one element.

另外,本發明之組成物於溫度10℃至30℃的條件下呈現液態。Further, the composition of the present invention exhibits a liquid state at a temperature of from 10 ° C to 30 ° C.

第1圖為利用原子力顯微鏡測量依據本發明一實施例之組成物所得正向力與阻力的關係圖;以及第2圖為利用接觸角分析儀測量該實施例之組成物所得的結果圖。Fig. 1 is a graph showing the relationship between the forward force and the resistance obtained by measuring the composition according to an embodiment of the present invention by an atomic force microscope; and Fig. 2 is a graph showing the results of measuring the composition of the embodiment by a contact angle analyzer.

現將本發明更詳予說明於下。The invention will now be described in greater detail.

本發明所提供之具有阻尼特性的組成物,較佳地包括有銦(indium,In)元素、鎵(gallium,Ga)元素、以及錫(tin,Sn)元素,並且前述銦元素的含量較佳為10wt%至40wt%,更佳為16wt%至26wt%。當該銦元素含量低於10wt%時,該組成物會出現析出物,影響阻尼特性;相反地,當該銦(In)元素含量高於40wt%時,該組成物的共晶溫度會超過30℃,使該組成物無法呈現液態,而不能應用於阻尼器中。其次,前述鎵元素的含量較佳為45wt%至80wt%,更佳為56wt%至75wt%。當該鎵元素含量低於45wt%或高於80wt%時,該組成物的共晶溫度會超過30℃,使該組成物無法呈現液態,而不能應用於阻尼器中。再者,前述錫元素的含量較佳為5wt%至25wt%,更佳為9wt%至18wt%。當該錫元素含量低於5wt%或高於25wt%時,該組成物的 共晶溫度會超過30℃,使該組成物無法呈現液態,而不能應用於阻尼器中。因此,前述銦元素、鎵元素以及錫元素的含量宜控制在上述範圍內。The composition having damping characteristics provided by the present invention preferably includes an indium (In) element, a gallium (Ga) element, and a tin (tin) element, and the content of the indium element is preferably. It is 10% by weight to 40% by weight, more preferably 16% by weight to 26% by weight. When the content of the indium element is less than 10% by weight, precipitates may occur in the composition, affecting damping characteristics; conversely, when the content of the indium (In) element is higher than 40% by weight, the eutectic temperature of the composition may exceed 30%. °C, the composition cannot be rendered liquid, and cannot be applied to the damper. Next, the content of the aforementioned gallium element is preferably from 45 wt% to 80 wt%, more preferably from 56 wt% to 75 wt%. When the gallium element content is less than 45 wt% or more than 80 wt%, the eutectic temperature of the composition may exceed 30 ° C, so that the composition cannot be in a liquid state, and cannot be applied to a damper. Further, the content of the aforementioned tin element is preferably from 5% by weight to 25% by weight, more preferably from 9% by weight to 18% by weight. When the tin element content is less than 5 wt% or more than 25 wt%, the composition The eutectic temperature will exceed 30 ° C, making the composition incapable of presenting a liquid state and not being applied to a damper. Therefore, the content of the aforementioned indium element, gallium element, and tin element is preferably controlled within the above range.

另外,為了將該組成物的共晶溫度降低至10℃至30℃,以維持其阻尼特性,該組成物最好還可進一步包括有汞(mercury,Hg)、鉍(bismuth,Bi)、鋰(lithium,Li)、鈉(sodium,Na)、鉀(potassium,K)、銣(rubidium,Rb)或銫(cesium,Cs)至少一種元素,且其含量宜為1至5wt%。Further, in order to lower the eutectic temperature of the composition to 10 ° C to 30 ° C to maintain its damping characteristics, the composition may further preferably include mercury (mercury, Hg), bismuth (Bi), lithium. (lithium, Li), sodium (sodium, Na), potassium (potassium, K), rubidium (Rb) or cesium (Cs), at least one element, and its content is preferably from 1 to 5 wt%.

本發明之另一方面係提供一種應用上述組成物的阻尼器,該組成物可利用任何習知方式充填至一般阻尼器的套筒中,而製成一種長時間作動後仍能維持良好阻尼力且不會有阻尼衰退現象的阻尼器。Another aspect of the present invention provides a damper using the above composition, which can be filled into a sleeve of a general damper by any conventional means to maintain a good damping force after a long period of operation. There is no damper that damps the decay phenomenon.

以下透過一實驗例來說明本發明之組成物與阻尼器的製造過程,然而,下列敘述僅用來說明本發明,本發明之組成物與阻尼器的製造過程並不受限於此。The manufacturing process of the composition and the damper of the present invention will be described below by way of an experimental example. However, the following description is only for explaining the present invention, and the manufacturing process of the composition and the damper of the present invention is not limited thereto.

首先將具有不同比例的銦、鎵、及錫放置於煉熔爐內,接著在真空環境下以高溫或其他能夠達成熔合的方式,例如磁振、加壓等方式,將前述材料熔合,即可製得本發明之組成物。依前述方式製得的組成物,係充填並密封於一套筒中即可製得阻尼器。First, indium, gallium, and tin having different ratios are placed in a melting furnace, and then the materials are fused by a high temperature or other means capable of achieving fusion in a vacuum environment, such as magnetic vibration, pressure, or the like. The composition of the present invention is obtained. The damper prepared by the above method is filled and sealed in a sleeve to obtain a damper.

將由上述方式製得之組成物利用原子力顯微鏡(Atomic Force Microscopy,AFM,型號Solver P47H,NT-MDT公司供售)測量其正向力與阻力,以及利用接觸角分析儀(Contact Angle Analyzer,型號FTA125)測量組成物的接觸角,如第一圖與下表所示分別為5種不同比例的組成物以及推算出組成物的摩擦阻力係數。The composition obtained by the above method was measured for its forward force and resistance by an atomic force microscope (AFM, model Agil, model Solver P47H, available from NT-MDT), and a contact angle analyzer (Model Angle FRA125) was used. The contact angle of the composition was measured, as shown in the first figure and the table below, respectively, for five different ratios of composition and the frictional resistance coefficient of the composition.

由上表可知,本發明所提供組成物之摩擦阻力係數約在1.5~4之間,挑選其中第III種組成比例測試的接觸角約為4.72度(如第二圖所示),相較於習用阻尼油的接觸角皆大於40度,因此可知當本發明之組成物應用於阻尼器時不易因長期作用而升溫,阻尼器的阻尼力也比較不會衰減。It can be seen from the above table that the friction resistance coefficient of the composition provided by the present invention is about 1.5 to 4, and the contact angle of the third composition ratio test is about 4.72 degrees (as shown in the second figure), as compared with Since the contact angle of the conventional damping oil is more than 40 degrees, it is understood that when the composition of the present invention is applied to the damper, it is not easy to be heated by the long-term action, and the damping force of the damper is relatively not attenuated.

綜上所述,由於該組成物為無機物質,於溫度10℃至30℃為液態且具有良好的黏稠度、導熱性與電特性,所以當其應用於阻尼器時,阻尼器不會因長時間作動而產生特性變化,或是因阻尼器作動所產生的高溫而發生黏度降低的情形,因此能夠維持阻尼器的阻尼力,避免阻尼衰退的現象發生。In summary, since the composition is an inorganic substance, it is liquid at a temperature of 10 ° C to 30 ° C and has good viscosity, thermal conductivity and electrical properties, so when it is applied to a damper, the damper is not long. When the time is activated and the characteristic changes, or the viscosity is lowered due to the high temperature generated by the damper operation, the damping force of the damper can be maintained to avoid the occurrence of damping degradation.

Claims (10)

一種具有阻尼特性的組成物,包含有:(a)10wt%至40wt%的銦(In);(b)45wt%至80wt%的鎵(Ga);以及(c)5wt%至25wt%的錫(Sn)。A composition having damping characteristics comprising: (a) 10% by weight to 40% by weight of indium (In); (b) 45% by weight to 80% by weight of gallium (Ga); and (c) 5wt% to 25% by weight of tin (Sn). 如請求項1所述之具有阻尼特性的組成物,其包含有:(a)16wt%至26wt%的銦(In);(b)56wt%至75wt%的鎵(Ga);以及(c)9wt%至18wt%的錫(Sn)。The composition having damping characteristics according to claim 1, comprising: (a) 16 wt% to 26 wt% of indium (In); (b) 56 wt% to 75 wt% of gallium (Ga); and (c) 9 wt% to 18 wt% of tin (Sn). 如請求項1所述之具有阻尼特性的組成物,更包含有選自汞(Hg)、鉍(Bi)、鋰(Li)、鈉(Na)、鉀(K)、銣(Rb)以及銫(Cs)所構成之族群中的至少一種添加元素。The composition having damping characteristics according to claim 1 further comprising a component selected from the group consisting of mercury (Hg), bismuth (Bi), lithium (Li), sodium (Na), potassium (K), ruthenium (Rb), and ruthenium. (Cs) at least one of the added elements of the group. 如請求項3所述之具有阻尼特性的組成物,其中該添加元素的含量為1wt%至5wt%。A composition having damping properties as described in claim 3, wherein the additive element is contained in an amount of from 1% by weight to 5% by weight. 如請求項1所述之具有阻尼特性的組成物,其於溫度10℃至30℃的條件下為液態。A composition having damping properties as described in claim 1 which is liquid at a temperature of from 10 ° C to 30 ° C. 一種阻尼器,係包含有如請求項1所述之具有阻尼特性的組成物。A damper comprising a composition having damping characteristics as described in claim 1. 如請求項6所述之阻尼器,其中該具有阻尼特性的組成物係包含有(a)16wt%至26wt%的銦(In);(b)56wt%至75wt%的鎵(Ga);以及(c)9wt%至18wt%的錫(Sn)。The damper according to claim 6, wherein the composition having damping characteristics comprises (a) 16 wt% to 26 wt% of indium (In); (b) 56 wt% to 75 wt% of gallium (Ga); (c) 9 wt% to 18 wt% of tin (Sn). 如請求項6所述之阻尼器,其中該具有阻尼特性的組成物更包含有選自汞(Hg)、鉍(Bi)、鋰(Li)、鈉(Na)、鉀(K)、銣(Rb)以及銫(Cs)所構成之族群中的至少一種添加元素。The damper according to claim 6, wherein the composition having damping characteristics further comprises a component selected from the group consisting of mercury (Hg), bismuth (Bi), lithium (Li), sodium (Na), potassium (K), and strontium ( At least one of the group consisting of Rb) and 铯(Cs) is an additive element. 如請求項8所述之阻尼器,其中該添加元素的含量為1wt%至5 wt%。The damper according to claim 8, wherein the content of the additive element is 1 wt% to 5 Wt%. 如請求項6所述之阻尼器,其中該具有阻尼特性的組成物於溫度10℃至30℃的條件下為液態。The damper according to claim 6, wherein the composition having the damping property is a liquid at a temperature of 10 ° C to 30 ° C.
TW102130310A 2013-08-23 2013-08-23 A composition having a damping characteristic, and a damper to which the composition is applied TWI482864B (en)

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