TWI458959B - LED fluorescent material light color and spectral detection method - Google Patents

LED fluorescent material light color and spectral detection method Download PDF

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TWI458959B
TWI458959B TW100140250A TW100140250A TWI458959B TW I458959 B TWI458959 B TW I458959B TW 100140250 A TW100140250 A TW 100140250A TW 100140250 A TW100140250 A TW 100140250A TW I458959 B TWI458959 B TW I458959B
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spectrum
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blue light
induced
color
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TW201319546A (en
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Chen Chi An
Chih Cheng Liu
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Zhao Neng Technology Co Ltd
Titan Electro Optics Co Ltd
Chen Chi An
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Description

LED螢光材料光色與光譜檢測方法LED fluorescent material light color and spectrum detection method

本發明為提供一種LED螢光材料光色與光譜檢測方法,尤指一種直接測試非破壞性及不改變任何LED螢光測試樣品型態,LED螢光材料轉換效率及光色特性定量光譜及光色檢測方式,且取樣快速,不消耗多餘的材料及製作樣品之人力,以及,有效過濾不良LED螢光材料進入生產,以減少不良光色產品產出的LED螢光材料光色與光譜檢測方法。The invention provides a method for detecting light color and spectrum of LED fluorescent materials, in particular to directly testing non-destructive and non-changing any LED fluorescent test sample type, LED fluorescent material conversion efficiency and light color characteristic quantitative spectrum and light Color detection method, and rapid sampling, no need to consume excess materials and manpower to make samples, and effective filtering of poor LED fluorescent materials into production to reduce the production of LED fluorescent materials by poor light color products .

按,先前LED業界在檢測LED螢光材料需要在接近實際產品結構下發光,才能去做進一步的分析。因此在樣品的測試光學路徑(Optical Path)必須與白光LED的發光路徑相同,並且其螢光的誘發光光譜也必須與白光LED的藍光晶片光譜近似。再以傳統的螢光光譜系統,是無法吻合以上光學環境要求,主要原因有二個:第一、傳統分析化學用的螢光光譜系統,主要在偵測螢光材料可誘發的光譜波長及受誘發後產生的螢光光譜波長訊號。化學的螢光光譜分析:主要是針對廣泛性螢光材料的螢光光譜分析,與白光LED的目的不相同。此其系統的光學路徑也不一樣;化學分析用的螢光光譜必須要將誘發光譜訊號與螢光光譜訊號完全分離,避免干擾。因此要採用90度誘發的光學路徑設計,讓螢光光譜訊號與誘發光的訊號成90度角,各自行進的方向前進,並只讓螢光訊號進入光譜儀處理其光譜訊號產出;第二、傳統化學分析用螢光光譜系統,主要功能是在於測試螢光材料與誘發光波長的關係,因此需要與偏紫外寬波長的高壓氙氣燈作為其誘發螢光產生的光源,並且須經過色散分光,將其誘發光源其光波寬變窄進行誘發。因此傳統化學螢光光譜系統,其誘發光源的光譜條件與白光LED螢光誘發條件有很大的差異。According to the previous LED industry, the LED fluorescent material needs to be illuminated under the actual product structure to perform further analysis. Therefore, the optical path of the sample must be the same as the light path of the white LED, and the fluorescence induced spectrum of the sample must also be similar to the blue light spectrum of the white LED. In the traditional fluorescence spectroscopy system, the above optical environment requirements cannot be matched. There are two main reasons: First, the fluorescence spectroscopy system used in traditional analytical chemistry is mainly used to detect the spectral wavelengths that can be induced by fluorescent materials. Fluorescence spectral wavelength signal generated after induction. Chemical Fluorescence Spectroscopy: Primarily for fluorescence spectroscopic analysis of a wide range of fluorescent materials, not the same as the purpose of white LEDs. The optical path of the system is also different; the fluorescence spectrum for chemical analysis must completely separate the induced spectral signal from the fluorescent spectral signal to avoid interference. Therefore, the 90-degree induced optical path design is adopted, so that the fluorescence spectrum signal and the light-inducing signal are at an angle of 90 degrees, and the direction of each advancement advances, and only the fluorescent signal enters the spectrometer to process the spectral signal output; The traditional fluorescence analysis system for chemical analysis, the main function is to test the relationship between the fluorescent material and the wavelength of the induced light. Therefore, a high-pressure xenon lamp with a wide ultraviolet wavelength is required as a light source for inducing fluorescence generation, and is subjected to dispersion spectrometry. The induced light source is induced by narrowing its light wavelength. Therefore, the traditional chemical fluorescence spectroscopy system, the spectral conditions of the induced light source and the white LED fluorescent induced conditions are very different.

再者,以往螢光樣品無法取材料直接檢驗,一直是白光LED品保檢驗上最大的困擾,主要是螢光材料無法直接取樣檢測。在檢測的過程中,需要搭配其它的材料:如矽膠(Silicon)或是樹酯(Epoxy)再加上晶片(Diode Chip)如此測出的螢光材料已受到其它材料的光學定性干擾,對於做出的樣品,其實已無法清楚的判定:單純的螢光材料,其光色品質不良的差異,這種樣品處理方式,不但本身所測出的光色數據因其它材料干擾的因素下數據變的完全沒有意義以外,也因樣品處裡的方式會導致材料及時間過於繁瑣,也造成人力物力與時間上的浪費。Furthermore, in the past, fluorescent samples could not be directly tested for materials, which has been the biggest problem in white light LED quality assurance testing, mainly because fluorescent materials cannot be directly sampled and tested. In the process of testing, it needs to be matched with other materials: such as silicone or Epoxy plus Diode Chip. The fluorescent material thus measured has been optically interfered by other materials. The sample is actually unable to be clearly judged: the pure fluorescent material, the difference in light color quality, this sample processing method, not only the measured light color data due to other materials interference factors It is completely meaningless, and because of the way in the sample, the material and time are too cumbersome, and the human and material resources and time are wasted.

又者,在取樣進行測試的過程中,必須要搭配其他材料,如上所述:會有材料在光學定性的干擾,另外最大的干擾是光學定量上的干擾,造成這種干擾的因素不外乎是材料本身在混合調整的過程裡面,會有各項材料相混濃度不均勻的困擾,因為各自材料其提供的濃度控制上就相當困難,而且很難保證在單一採樣上面其濃度會一致,甚至螢光材料是屬於無機結晶粉體的固態樣品,且不會均勻溶解在矽膠及樹酯等成型材料裡。一般其粉體就有粒徑大小不同的分布,約有5~20um的粉體粒徑,在膠體內呈現不均勻懸浮分布,須借用部分外力不斷均勻攪拌,如此就極有可能將空氣拌入到膠體裡面形成氣泡,這樣方式雖然使粉體會形成均勻的布郎運動狀態,但是卻有將空氣導入膠體內產生氣泡的風險,同樣的,這種方式因螢光粉體呈現分布狀態,其受藍光誘發也會無法有效均勻的與螢光材料作用,產生穩定的螢光訊號。In addition, in the process of sampling and testing, it must be matched with other materials, as mentioned above: there will be optical qualitative interference, and the biggest interference is optical quantitative interference, the factors causing such interference are nothing more than It is the material itself in the process of mixing adjustment, there will be troubles in the uneven concentration of various materials, because the concentration control provided by each material is quite difficult, and it is difficult to ensure that the concentration will be consistent on a single sample, even The fluorescent material is a solid sample of inorganic crystalline powder and is not uniformly dissolved in molding materials such as silicone and resin. Generally, the powder has a different particle size distribution, and has a particle size of about 5 to 20 um, which exhibits an uneven suspension distribution in the gel body, and must be uniformly stirred by a part of external force, so that it is highly likely to mix the air. The formation of bubbles into the colloid, in this way, the powder will form a uniform state of motion, but there is a risk of introducing air into the gel to generate bubbles. Similarly, this way, due to the distribution of the phosphor powder, it is subject to Blue light induction also does not effectively and uniformly interact with the fluorescent material to produce a stable fluorescent signal.

另外,當欲進行測試的過程中,必須將LED螢光材料與其它材料進行混合(即稱為破壞),才能進行測試,並當使用過後,則無法再次利用,意謂必須丟棄,非常不環保。In addition, when the test is to be carried out, the LED fluorescent material must be mixed with other materials (that is, called damage) in order to be tested, and when used, it cannot be reused, meaning that it must be discarded, which is very environmentally friendly. .

是以,要如何解決上述習用之問題與缺失,即為本發明之發明人與從事此行業之相關廠商所亟欲研究改善之方向所在者。Therefore, how to solve the above problems and deficiencies in the above-mentioned applications, that is, the inventors of the present invention and those involved in the industry are eager to study the direction of improvement.

故,本發明之發明人有鑑於上述缺失,乃蒐集相關資料,經由多方評估及考量,並以從事於此行業累積之多年經驗,經由不斷試作及修改,始設計出此種直接測試非破壞性及不改變任何LED螢光測試樣品型態,並且可完全模擬白光LED光學與光譜結構,並將測試樣品的白光LED光譜進行完整無缺的光譜分離,形成各自獨立的誘發藍光光譜及螢光光譜,又可以有效取代傳統化學檢測螢光光譜系統及相關之LED螢光材料檢測功能,且具有速度快、取樣方便、及操作容易的LED螢光材料光色與光譜檢測方法的發明專利者。Therefore, the inventors of the present invention have collected the relevant materials in view of the above-mentioned deficiencies, and through multi-party evaluation and consideration, and through years of experience accumulated in the industry, through continuous trial and modification, the direct test is designed to be non-destructive. And does not change any LED fluorescent test sample type, and can completely simulate the optical and spectral structure of the white LED, and perform a complete spectral separation of the white LED spectrum of the test sample to form independent induced blue light spectrum and fluorescence spectrum. It can effectively replace the traditional chemical detection fluorescence spectroscopy system and related LED fluorescent material detection functions, and has the invention patent of the light color and spectrum detection method of LED fluorescent material with high speed, convenient sampling and easy operation.

本發明之主要目的在於測試光學路徑與白光LED光學路徑一致,方便實際光色效果模擬,且為一種非破壞性檢測方式,確保樣品材料測試前後性質一致不變,更以固態LED光源誘發螢光材料產生螢光,以便模擬與白光LED相近似的白光、藍光及螢光光譜。The main purpose of the invention is to test the optical path consistent with the white LED optical path, to facilitate the simulation of the actual light color effect, and to be a non-destructive detection method to ensure that the properties of the sample material before and after the test are consistent, and the fluorescent light is induced by the solid LED light source. The material produces fluorescence to simulate white, blue, and fluorescent spectra similar to white LEDs.

本發明之次要目的在於LED螢光材料180度垂直受光(反射或穿透樣品)誘發,與白光LED百分百相近似的光學路徑,並以外置式樣品槽測試,可確保LED螢光材料有較大方便性的置換空間。The secondary objective of the present invention is that the LED fluorescent material is induced by 180 degrees of vertical light transmission (reflection or penetration of the sample), an optical path similar to that of the white LED, and an external sample cell test to ensure that the LED fluorescent material has Larger convenience replacement space.

本發明再一目的在於得以運算出光及色的比例,及得以判斷藍光晶片該有的大小,以及,可以選擇LED螢光材料於製造成品實驗做樣品的時候,可看出濃度的差異,來判定LED螢光材料之多寡。Another object of the present invention is to calculate the ratio of light and color, and to determine the size of the blue light wafer, and to select the LED fluorescent material to determine the difference in concentration when manufacturing the finished product sample. The amount of LED fluorescent materials.

為達上述優勢,本發明主要結構包括一檢測裝置,係藉由一起始光源及一光學積分球之配合予以檢測該LED螢光材料之光色與光譜,並經一分析裝置進行光譜分析,而主要分析係透過一分析模組進行操作,其分析模組包括一光譜載入單元、一光譜合成單元、一光譜計算單元、一光譜儲存單元及一色度座標產生單元;當起始光源(固態LED光源)照射出一誘發藍色光源並經過光學積分球時亦產生一初始誘發藍光光譜,並以180度垂直受光誘發LED螢光材料,形成與白光LED相同路徑,進而產生一個被LED螢光材料所吸收的被吸收藍光光譜,而後初始誘發藍光光譜及被吸收藍光光譜則由光譜載入單元顯示於光譜顯示單元上,同時將被吸收誘發藍光光譜所產生的螢光光譜顯示於光譜顯示單元上,此時透過光譜合成單元將被吸收誘發藍光光譜及螢光光譜進行合成以產生一白光光譜並顯示於光譜顯示單元上,而後即由光譜計算單元進行光譜加、減、乘、除之運算,首先將被吸收誘發藍光光譜及螢光光譜進行相加合成運算以產生一合成白光光譜並顯示於光譜顯示單元上,再將初始誘發藍光光譜及被吸收誘發藍光光譜進行相減運算以產生一螢光吸收量光譜並顯示於光譜顯示單元上,再將合成白光光譜進行光譜乘法倍率運算以產生一縮小倍率合成白光光譜並顯示於光譜顯示單元上,再將螢光光譜除上螢光吸收量光譜以產生該LED螢光材料之輻射轉換效率值,此後將合成白光光譜、螢光吸收量光譜、縮小倍率合成白光光譜及輻射轉換效率值儲存於一光譜儲存單元內,藉此即完成初步的檢測,而當完成上述步驟後,可藉由一色度座標產生單元將初始誘發藍光光譜、螢光光譜、合成白光光譜等經色彩函數轉換後分別產生誘發藍光光譜色度座標、螢光光譜色度座標及合成白光光譜色度座標,並將其顯示於螢幕上,進而產生補色線結構圖或色彩區域結構圖。In order to achieve the above advantages, the main structure of the present invention includes a detecting device for detecting the color and spectrum of the LED fluorescent material by a combination of a starting light source and an optical integrating sphere, and performing spectral analysis by an analyzing device. The main analysis system is operated by an analysis module, and the analysis module comprises a spectral loading unit, a spectral synthesis unit, a spectral calculation unit, a spectral storage unit and a chromaticity coordinate generation unit; when the starting light source (solid state LED) The light source) emits an induced blue light source and passes through the optical integrating sphere to generate an initial induced blue light spectrum, and the LED fluorescent material is induced by the vertical light receiving of 180 degrees to form the same path as the white light LED, thereby generating an LED fluorescent material. The absorbed blue light spectrum is absorbed, and then the initial induced blue light spectrum and the absorbed blue light spectrum are displayed on the spectral display unit by the spectral loading unit, and the fluorescence spectrum generated by the absorption induced blue light spectrum is displayed on the spectral display unit. At this time, the absorption-induced blue light spectrum and the fluorescence spectrum are synthesized by a spectrum synthesis unit to generate a The light spectrum is displayed on the spectral display unit, and then the spectral addition unit performs spectral addition, subtraction, multiplication, and division operations. First, the absorption-induced blue light spectrum and the fluorescence spectrum are added and combined to generate a synthetic white light spectrum. And displayed on the spectral display unit, and then the initial induced blue light spectrum and the absorbed induced blue light spectrum are subtracted to generate a fluorescence absorption spectrum and displayed on the spectral display unit, and then the synthesized white light spectrum is subjected to spectral multiplication magnification operation. The white light spectrum is synthesized and displayed on the spectral display unit, and the fluorescence spectrum is divided by the fluorescence absorption spectrum to generate a radiation conversion efficiency value of the LED fluorescent material, and then the white light spectrum and the fluorescent absorption are synthesized. The quantitative spectrum, the reduced magnification synthetic white light spectrum and the radiation conversion efficiency value are stored in a spectral storage unit, thereby completing preliminary detection, and when the above steps are completed, the initial induced blue spectrum can be induced by a chromaticity coordinate generating unit, Fluorescence spectrum, synthetic white light spectrum, etc. are converted by color function to generate induced blue light The spectral chromaticity coordinates, the fluorescence spectral chromaticity coordinates, and the synthesized white light spectral chromaticity coordinates are displayed on the screen to generate a complementary color line structure or a color area structure map.

另外,光譜計算單元更得以進一步計算出其亮度與色彩的比例,及LED晶片的亮度與螢光濃度的倍率,俾讓使用者更可清楚掌握製造LED各個相關的參考參數。In addition, the spectral calculation unit can further calculate the ratio of brightness to color, and the brightness of the LED chip and the magnification of the fluorescence concentration, so that the user can clearly grasp the relevant reference parameters of the LED.

藉由上述技術,可針對習用LED螢光材料檢測技術所存在之LED螢光材料需要在接近實際產品結構下發光,才能去做一步的分析,而螢光材料無法直接取樣檢測,因此測出的螢光材料亦受到其它材料的光學定性干擾,對於做出的樣品,其實無法清楚的判定,另外所測出的光色數據因其它材料干擾的因素下數據變的完全沒有意義以外,也因樣品處裡的方式會導致材料及時間過於繁瑣,也造成人力物力與時間上的浪費,更重要的一點,習用技術必須先行破壞LED螢光材料(即跟其它材料進行混合)才能進行測試,且並不環保,使用過後即不能回收再利用的問題點加以突破,達到本發明如上述優點之實用進步性。With the above technology, the LED fluorescent material existing in the conventional LED fluorescent material detecting technology needs to be illuminated under the actual product structure, so that one step analysis can be performed, and the fluorescent material cannot be directly sampled and detected, so the measured Fluorescent materials are also subject to optical qualitative interference of other materials. In fact, the samples to be made cannot be clearly determined. In addition, the measured light color data is completely meaningless due to the interference of other materials, and also due to the sample. The way in the place will lead to too cumbersome materials and time, as well as waste of manpower, material and time. More importantly, the conventional technology must first destroy the LED fluorescent material (that is, mix with other materials) to test, and It is not environmentally friendly, and the problem that cannot be recycled and reused after use is broken, and the practical progress of the present invention as the above advantages is achieved.

為達成上述目的及功效,本發明所採用之技術手段及構造,茲繪圖就本發明較佳實施例詳加說明其特徵與功能如下,俾利完全了解。In order to achieve the above objects and effects, the technical means and the structure of the present invention will be described in detail with reference to the preferred embodiments of the present invention.

請參閱第一圖及第二圖所示,係為本發明較佳實施例之方塊示意圖一及二,由圖中可清楚看出本發明檢測系統主要包括:一檢測裝置1,係藉由一供發射出藍色光源的起始光源裝置2及一光學積分球3之配合予以檢測該LED螢光材料4(黃色螢光材料)之光色與光譜(藍光光譜、螢光光譜或白光光譜);一分析裝置5,係藉由一分析模組6與該檢測裝置1資訊連結,該分析模組6包括:一光譜載入單元61,係供載入各種被LED螢光材料4吸收或未被吸收的光譜檔案,並予以顯示光譜波形於一光譜顯示單元62上;一光譜合成單元63,係用於將各種顯示於光譜顯示單元62上的光譜波形進行合成並予以顯示於該光譜顯示單元62上;一光譜計算單元64,係用於將各種顯示於光譜顯示單元62上之光譜進行加法、減法、乘法或除法的數學式合成運算;一光譜儲存單元65,係將經光譜計算單元64合成運算的光譜進行儲存;一色度座標產生單元66,係將上述各種光譜以座標方式顯示於一色度座標顯示單元67上。1 and 2 are block diagrams 1 and 2 of a preferred embodiment of the present invention. It can be clearly seen from the figure that the detection system of the present invention mainly comprises: a detecting device 1 by means of a The light source color and spectrum (blue light spectrum, fluorescent spectrum or white light spectrum) of the LED fluorescent material 4 (yellow fluorescent material) are detected by the combination of the starting light source device 2 and the optical integrating sphere 3 for emitting a blue light source. An analysis device 5 is connected to the detection device 1 by an analysis module 6. The analysis module 6 includes a spectral loading unit 61 for loading various LED fluorescent materials 4 or not. The absorbed spectral file is displayed on the spectral display unit 62; a spectral synthesis unit 63 is configured to synthesize and display various spectral waveforms displayed on the spectral display unit 62 to the spectral display unit. 62. A spectral calculation unit 64 is used for mathematical synthesis operations of adding, subtracting, multiplying or dividing the various spectra displayed on the spectral display unit 62; a spectral storage unit 65 is to be subjected to a spectral calculation Synthesis computing spectrum 64 for storage; a chromaticity coordinates generating unit 66, the above-described various spectral lines are displayed in a coordinate manner on the display unit 67 on the chromaticity coordinates.

再者,上述的LED螢光材料4係由一為直接採樣非破壞性之盒體所收容(盒體未顯示於圖示中),且該盒體表面係設有一高穿透率之石碤玻璃,而於底部處則由一高反射率漫射性材料為主。Furthermore, the above-mentioned LED fluorescent material 4 is housed in a box which is directly sampled and non-destructive (the case is not shown in the drawing), and the surface of the case is provided with a high transmittance stone. Glass, while at the bottom is dominated by a highly reflective diffuse material.

請參閱第三圖所示,係為本發明較佳實施例之方塊流程圖,由圖中可清楚看出,其檢測步驟為樣品光譜訊號擷取A,定量校正轉換光譜訊號或呼叫定量光譜檔案B,轉換定量光譜為輻射功率參數及視覺光色參數C,光譜四則運算分析及模擬光色運算,或直接存入光色光譜資料庫建檔D,將分析與模擬完成的光譜及視覺光色資料存入光譜檔案資料庫E。(光譜可為藍光光譜、螢光光譜或白光光譜)Referring to the third embodiment, which is a block diagram of a preferred embodiment of the present invention, it can be clearly seen from the figure that the detection step is sample spectral signal acquisition A, quantitative correction conversion spectrum signal or call quantitative spectrum file. B, the conversion quantitative spectrum is the radiant power parameter and the visual light color parameter C, the spectral four arithmetic analysis and the simulated light color operation, or directly stored in the light color spectrum database file file D, the analysis and simulation of the completed spectrum and visual light color The data is stored in the spectral file database E. (The spectrum can be blue, fluorescent, or white)

請同時參閱第四圖~第十三圖所示,係為本發明較佳實施例之光源路徑示意圖一、二及系統畫面示意圖一~八,其檢測方法同時參閱圖示,詳細步驟如下:Please refer to the fourth to thirteenth drawings at the same time, which are schematic diagrams of the light source path of the preferred embodiment of the present invention, and the schematic diagrams of the system screens one to eight. The detection method is also referred to the illustration, and the detailed steps are as follows:

(a)透過一為藍色光源之起始光源照射出一誘發藍色光源並經過一光學積分球而產生一初始誘發藍光光譜7;(參閱第四圖)(a) generating an initial induced blue light spectrum 7 by illuminating an induced blue light source through a starting source of a blue light source and passing an optical integrating sphere; (see Figure 4)

(b)經過光學積分球之誘發藍色光源照射於一為黃色螢光材料之LED螢光材料上,再180度反射回光學積分球內,而產生一被吸收誘發藍光光譜71;(參閱第五圖)(b) the blue light source is irradiated onto the LED fluorescent material of the yellow fluorescent material by the optical integrating sphere, and then reflected back into the optical integrating sphere by 180 degrees to generate an absorbed induced blue light spectrum 71; Five maps)

(c)其初始誘發藍光光譜7及被吸收誘發藍光光譜71由一分析裝置所接收,並透過一內建於內之分析模組進行分析;(c) its initial induced blue spectrum 7 and the absorbed induced blue spectrum 71 are received by an analysis device and analyzed by an internal analysis module;

(d)藉由一包含於分析模組內的光譜載入單元61將初始誘發藍光光譜7及被吸收誘發藍光光譜71顯示於一光譜顯示單元62上;(參閱第六圖)(d) displaying the initial induced blue light spectrum 7 and the absorbed induced blue light spectrum 71 on a spectral display unit 62 by a spectral loading unit 61 included in the analysis module; (see the sixth figure)

(e)再透過光譜載入單元61將被吸收誘發藍光光譜71所產生的螢光光譜72顯示於光譜顯示單元62上;(參閱第七圖)(e) re-transmitting the fluorescence spectrum 72 generated by the absorption-induced blue light spectrum 71 on the spectral display unit 62 through the spectral loading unit 61; (see the seventh figure)

(f)透過光譜合成單元將被吸收誘發藍光光譜及螢光光譜進行合成以產生一白光光譜73並顯示於光譜顯示單元62上;(參閱第八圖)(f) synthesizing the absorbed induced blue light spectrum and the fluorescent spectrum through a spectral synthesis unit to generate a white light spectrum 73 and displaying it on the spectral display unit 62; (see the eighth figure)

(g)透過一光譜計算單元將被吸收誘發藍光光譜及螢光光譜進行相加合成運算以產生一合成白光光譜74並顯示於光譜顯示單元62上;(參閱第九圖)(g) performing an additive synthesis operation on the absorption-induced blue light spectrum and the fluorescence spectrum through a spectral calculation unit to generate a composite white light spectrum 74 and displaying it on the spectral display unit 62; (see FIG. 9)

(h)再透過光譜計算單元將初始誘發藍光光譜7及被吸收誘發藍光光譜71進行相減運算以產生一螢光吸收量光譜75並顯示於光譜顯示單元62上;(參閱第十圖)(h) performing a subtraction operation on the initial induced blue light spectrum 7 and the absorbed induced blue light spectrum 71 by the spectral calculation unit to generate a fluorescence absorption amount spectrum 75 and displaying it on the spectral display unit 62; (refer to the tenth figure)

(i)再一次透過光譜計算單元將合成白光光譜74進行光譜乘法倍率運算以產生一縮小倍率合成白光光譜76並顯示於光譜顯示單元62上;(參閱第十一圖)(i) again performing a spectral multiplication magnification operation through the spectral calculation unit to generate a reduced magnification synthetic white light spectrum 76 and displaying it on the spectral display unit 62; (see FIG. 11)

(j)再一次透過光譜計算單元將螢光光譜72除上螢光吸收量光譜75以產生該LED螢光材料之輻射轉換效率值77;(參閱第十二圖)(j) again dividing the fluorescence spectrum 72 by the spectral absorption unit by the fluorescence absorption spectrum 75 to produce a radiation conversion efficiency value of the LED fluorescent material 77; (see Figure 12)

(k)將合成白光光譜、螢光吸收量光譜、縮小倍率合成白光光譜及輻射轉換效率值儲存於一光譜儲存單元78內。(參閱第十三圖)(k) The synthetic white light spectrum, the fluorescence absorption amount spectrum, the reduced magnification synthetic white light spectrum, and the radiation conversion efficiency value are stored in a spectral storage unit 78. (See figure 13)

再者,其上述的光譜運算,其係以絕對光譜輻射功率校正與定量技術為技術基礎,將LED螢光材料及誘發藍光所偵測到的光譜訊號轉換為定量的絕對光譜輻射功率,如此將光譜轉換後就可進行相關的運算分析,例如:白光光譜分離或是合成誘發藍光與LED螢光材料之螢光等。Furthermore, the above spectral operation is based on the absolute spectral radiation power correction and quantification technology, and the spectral signals detected by the LED fluorescent material and the induced blue light are converted into quantitative absolute spectral radiation power, thus After the spectral conversion, relevant operational analysis can be performed, for example, white light spectral separation or synthesis-induced blue light and fluorescent light of LED fluorescent materials.

當上述步驟完成後,即可透過一色度座標產生單元將其進行顯示出補色線結構圖或色彩區域結構,請參閱第十四圖~第十八圖所示,係為本發明較佳實施例之色度座標圖一~五,由圖中可清楚看出,其欲顯示色度座標圖之方法為:After the above steps are completed, the chromaticity coordinate generating unit can display the complementary color line structure or the color area structure. Referring to FIG. 14 to FIG. 18, it is a preferred embodiment of the present invention. The chromaticity coordinates of the graphs 1-5, as can be clearly seen from the figure, the method for displaying the chromaticity coordinate map is:

(l)透過一色度座標產生單元79將初始誘發藍光光譜7經色彩函數轉換後產生一誘發藍光光譜色度座標80;(參閱第十四圖)(1) generating an induced blue light spectral chromaticity coordinate 80 by converting the initially induced blue light spectrum 7 by a color function through a chromaticity coordinate generating unit 79; (refer to FIG. 14)

(m)再透過色度座標產生單元79將螢光光譜72經色彩函數轉換後產生一螢光光譜色度座標81;(參閱第十五圖)(m) the chromaticity coordinate generating unit 79 converts the fluorescence spectrum 72 by a color function to generate a fluorescence spectral chromaticity coordinate 81; (refer to the fifteenth figure)

(n)再透過色度座標產生單元79將合成白光光譜74經色彩函數轉換後產生一合成白光光譜色度座標82;(參閱第十六圖)(n) again through the chromaticity coordinate generation unit 79 to convert the synthesized white light spectrum 74 by a color function to produce a synthetic white light spectral chromaticity coordinate 82; (see Figure 16)

(o)再將誘發藍光光譜色度座標80、螢光光譜色度座標81及合成白光光譜色度座標82共同載入以產生一補色線結構圖或色彩區域結構圖。(參閱第十七及第十八圖)(o) The induced blue light chrominance chromaticity coordinates 80, the fluorescence spectral chromaticity coordinates 81, and the synthetic white light spectral chromaticity coordinates 82 are then co-loaded to produce a complementary color line structure map or a color area structure map. (See Figures 17 and 18)

更重要的一點,本發明測試系統及其方法係以建構在普郎克量子轉換定則(Planck‘s law;波長越短,能量越高)下其螢光材料吸收能量較高的光譜波長,轉換成能量較低的光譜波長,依此定則所形成的螢光光譜定量檢測技術基礎,並需經過國際追朔標準校正(朔源:National Institute Technology Standard,NIST),除做樣品的定性檢測外,也可以快速定量樣品濃度大小作為定量之用。系統中相關的光譜參數皆已經過分光輻射光功率校正,以標準的校正技術方法進行。More importantly, the test system and method of the present invention are constructed by using the Planck's law (the shorter the wavelength, the higher the energy), the higher the spectral wavelength of the fluorescent material, and the conversion. The lower the spectral wavelength of the energy, the basis of the quantitative spectroscopic detection technology formed by this rule, and subject to the international tracking standard correction (NIST), in addition to the qualitative detection of the sample, It is also possible to quickly quantify the sample concentration as a quantification. The relevant spectral parameters in the system have been corrected for the optical radiation optical power, using standard calibration techniques.

可見光(Visible)光譜數據可以透過系統軟件進行相關的定量算術運算,並可以定量光譜運算調整透過C.I.E.(視覺人眼照明協會)所制定的人眼三刺激值函數(1931 Color Matching Functions,Tristimulus values)轉換至C.I.E1931色度座標(C.I.E. 1931 Chromaticity Diagram)相關色彩參數(色度座標、色溫、演色指數、主域波長色相及彩純度)及視覺流明(Luminous Flux,lumen)亮度參數,藉此可設計出不同LED的視覺光色。此方法基礎運算方式,技術領域在絕對分光輻射光譜功率整合C.I.E.視覺色彩函數的轉換為技術基礎。並藉此引導使用者以絕動光譜的輻射強度及光譜波長的變化,作為其視覺光色特性改變的線性當量變化參數。Visible spectrum data can be correlated with quantitative arithmetic operations through system software, and quantitative spectral operations can be adjusted through the CIE (Visual Human Eye Illumination Association) to establish the 1931 Color Matching Functions (Tristimulus values). Convert to the CIE1931 Chromaticity Diagram for color parameters (chromaticity coordinates, color temperature, color rendering index, primary wavelength hue and color purity) and Luminous Flux (lumen) brightness parameters, which can be designed The visual light color of different LEDs. The basic operation method of this method, the technical field in the absolute splitting radiation spectrum power integration C.I.E. visual color function conversion into the technical basis. And thereby guiding the user to change the radiation intensity of the absolute spectrum and the wavelength of the spectrum as a linear equivalent change parameter of the change of the visual light color characteristic.

請同時參考第十九圖及第二十圖所示,係為本發明CIE三刺激值函數之示意圖及1931色度座標之示意圖,由圖可看出如上述人眼三刺激值函數(1931Color Matching Functions,Tristimulus values)與C.I.E1931色度座標(C.I.E. 1931Chromaticity Diagram)。Please refer to the 19th and 20th drawings at the same time, which is a schematic diagram of the CIE tristimulus value function and a schematic diagram of the 1931 chromaticity coordinate. The figure can be seen as the above-mentioned human eye tristimulus value function (1931Color Matching). Functions, Tristimulus values) and CIE 1931 Chromaticity Diagram (CIE 1931 Chromaticity Diagram).

又者,螢光光譜資料庫的材料可於抽樣測量完後跟光譜資料庫內的標準樣品光譜作定性與定量的比對,另外可以三種三組螢光效率(量子(光子)轉換效率、輻射(光譜)轉換效率、視覺(流明或其他視覺光度單位)轉換效率)值作參考指標,同時一併注意LED螢光材料的吸收誘發藍光光譜的吸收收量及吸收率參考LED螢光材料吸收藍光光譜與產出螢光之定量光譜變化。若在成品與半成品品質管控上,其主要在LED螢光材料與其他成型材料混合,其LED螢光材料的絕對光譜強度會與LED螢光材料濃度大小成一正比線性關係,可由此一正比變化作為LED螢光材料濃度控制的參數,以穩定製程材料在成型過程與LED螢光材料保持穩定的濃度。同理烘烤完成的成品其LED螢光材料的濃度,也會隨其螢光光譜強度大小與濃度大小一致成正比。In addition, the material of the fluorescence spectrum database can be qualitatively and quantitatively compared with the standard sample spectrum in the spectral database after sampling, and three sets of fluorescence efficiency (quantum (photon) conversion efficiency, radiation can be used. (Spectral) conversion efficiency, visual (lumen or other visual luminosity unit) conversion efficiency) value as a reference indicator, while paying attention to the absorption of the blue fluorescent spectrum induced by the absorption of the LED fluorescent material and the absorption rate reference LED fluorescent material absorbs blue light Quantitative spectral changes in spectra and output fluorescence. In the quality control of finished and semi-finished products, the LED fluorescent material is mainly mixed with other molding materials, and the absolute spectral intensity of the LED fluorescent material is proportional to the linear concentration of the LED fluorescent material, which can be used as a proportional change. The LED phosphor concentration control parameters are used to stabilize the process material during the molding process to maintain a stable concentration with the LED phosphor material. The concentration of the LED fluorescent material in the finished product of the same baking is also proportional to the intensity of the fluorescence spectrum and the concentration.

若以產品研發來說,目標規格視覺光色為參考基準,再配合晶片相對應的誘發藍光光譜在螢光光譜資料庫內的螢光光譜配合:找出最接近其光色的補色線色彩結構,其第十四圖~第十八圖進一步說明補色線色彩結構與光譜變化組合。在LED的螢光材料並非可線性找到對應的補色結構時,可以找到相近的二種LED螢光材料(二種以上)去合成最接近的LED螢光光譜,與目標規格的LED光色接近。新合成的LED螢光光譜座標可以調整LED螢光光譜的絕對強度比例去調整,會產生最佳的螢光色度座標點。這方式也適用在補色線上合成白光,其白光的光色條件也會隨螢光與誘發藍光光譜的強度不同在補色線上移動,變化出最接近模擬的LED白光光色參數。In terms of product development, the target specification visual light color is used as a reference reference, and the fluorescence spectrum of the induced blue light spectrum corresponding to the wafer in the fluorescence spectrum database is matched: finding the complementary color line color structure closest to its light color. The fourteenth to eighteenth figures further illustrate the combination of the color structure and the spectral change of the complementary color line. When the fluorescent material of the LED is not linearly able to find the corresponding complementary color structure, two similar LED fluorescent materials (two or more) can be found to synthesize the closest LED fluorescence spectrum, which is close to the target LED color. The newly synthesized LED fluorescence spectral coordinates can be adjusted to adjust the absolute intensity ratio of the LED fluorescence spectrum to produce the best fluorescent chromaticity coordinate points. This method is also applicable to the synthesis of white light on the complementary color line, and the light color condition of the white light also moves on the complementary color line with the intensity of the fluorescent light and the induced blue light spectrum, and changes the color parameter of the LED white light closest to the simulation.

另外以光譜計算單元為例,其得以運算出亮度及色彩的比例,及得以判斷藍光晶片該有的亮度大小,以及,可以選擇LED螢光材料於製造成品實驗做樣品的時候,可看出濃度的差異,來判定LED螢光材料之多寡,而為達成該些優勢,請同時參閱第二十一圖~二十三圖所示,係為本發明藍光光譜及螢光光譜之波形圖一、二、三,其主要之計算方式如下:In addition, taking the spectral calculation unit as an example, it is possible to calculate the ratio of brightness and color, and to determine the brightness of the blue light wafer, and to select the LED fluorescent material to produce a sample for the finished product, and the concentration can be seen. The difference is to determine the amount of LED fluorescent material, and in order to achieve these advantages, please also refer to the twenty-first to twenty-three figures, which are the waveforms of the blue spectrum and the fluorescence spectrum of the present invention. Second and third, the main calculation methods are as follows:

一、先假設一標準色度為0.33,而光譜合成後為140流明(如二十二圖),而某一產品之亮度為7流明(亮度),換言之,欲算出其該產品亮度色彩比例則如下述公式可算出(同時參閱二十一及二十二圖):First, assume a standard chromaticity of 0.33, and after the spectrum is synthesized, it is 140 lumens (such as 22), and the brightness of a certain product is 7 lumens (brightness). In other words, to calculate the brightness ratio of the product. It can be calculated by the following formula (see also 21 and 22):

(B×1/20)+(Y×1/20)=(W×1/20)(B×1/20)+(Y×1/20)=(W×1/20)

(B/140)+(Y/140)=140(B/140)+(Y/140)=140

其(B/140)=3%,(Y/140)=97%其中,先將藍光B及螢光Y各縮小1/20,同時合成光譜W也縮小1/20;藉此3%即為第一個藍光條件,97%即為第二個藍光條件而3%+97%即為達到的亮度及色彩比例為100%倘若假使另一產品之亮度非140流明,但想要上述之色彩值,即可按照前述的百分比去製造。(B/140)=3%, (Y/140)=97%, wherein the blue light B and the fluorescent light Y are first reduced by 1/20, and the synthesized spectrum W is also reduced by 1/20; The first blue light condition, 97% is the second blue light condition and 3%+97% is the achieved brightness and color ratio of 100%. If the brightness of another product is not 140 lumens, but the above color value is desired. , can be manufactured according to the aforementioned percentage.

因此,使用者只須按照上述的百分比例即可得到前述之色彩。Therefore, the user only needs to obtain the aforementioned color according to the above percentage.

二、當選擇LED晶片時亦得以透過一參考值來選擇欲想使用的LED晶片,而該參考值即由下列公式算出(請同時參閱第一圖):(BB-B)×1/20=AB/20(被吸收後)2. When selecting the LED chip, the LED chip to be used can also be selected through a reference value, and the reference value is calculated by the following formula (please refer to the first figure at the same time): (BB-B)×1/20= AB/20 (after being absorbed)

(B×1/20)+(AB×1/20)=C(晶片亮度)(B × 1 / 20) + (AB × 1 / 20) = C (wafer brightness)

其中,BB為未被螢光吸收前之藍光光譜,B為被螢光吸收後之藍光光譜,Y為螢光光譜;因此,即可將原本(B×1/20)加上被吸收掉的(AB×1/20),即可得到晶片所須的亮度功率及波長“C”藉此使用者即可自行挑選欲製作的LED晶片。Among them, BB is the blue light spectrum before being absorbed by the fluorescent light, B is the blue light spectrum absorbed by the fluorescent light, and Y is the fluorescent spectrum; therefore, the original (B×1/20) can be absorbed. (AB × 1 / 20), the brightness power and wavelength "C" required for the wafer can be obtained, whereby the user can select the LED chip to be fabricated.

三、此時欲求螢光粉之濃度時,首先欲挑選一個LED晶片(請同時參閱第二十三圖),倘若假設其螢光粉濃度太濃或太淡時,即會產生藍光強度B跟螢光粉W之高度無法相配,因此得以由先前所算出的螢光粉基準值WS為基準,再行假設濃度過淡的螢光粉為W1,即可將(WS÷W1)而得知螢光濃度相差之倍數,以供使用者進行修正。3. At this time, when you want the concentration of the phosphor powder, you first need to select an LED chip (please refer to the 23rd picture at the same time). If the phosphor powder concentration is too thick or too light, the blue intensity B will be generated. Since the height of the phosphor powder W cannot be matched, it is possible to use the previously calculated phosphor powder reference value WS as a reference, and then assume that the phosphor powder having a too low concentration is W1, and the (WS÷W1) can be known. The multiple of the light concentration difference for the user to correct.

是以,本發明之LED螢光材料光色與光譜檢測方法為可改善習用之技術關鍵在於:Therefore, the key to improving the light color and spectral detection method of the LED fluorescent material of the present invention is that:

一、測試光學路徑與白光LED光學路徑一致,方便實際光色效果模擬。First, the test optical path is consistent with the white LED optical path, which is convenient for the actual light color effect simulation.

二、本發明與習知技術不同地方在於係採用非破壞性檢測方式,確保樣品材料測試前後性質一致不變。Second, the difference between the present invention and the prior art is that non-destructive testing is adopted to ensure that the properties of the sample materials are consistent before and after testing.

三、以固態LED光源誘發螢光材料產生螢光,以便模擬與白光LED相近似的白光、藍光及螢光光譜。Third, the fluorescent material is induced by the solid-state LED light source to generate fluorescence, so as to simulate the white light, blue light and fluorescent spectrum similar to the white LED.

四、樣品180度垂直受光(反射或穿透樣品)誘發,與白光LED百分百相近似的光學路徑。並以外置式樣品槽測試;可確保樣品有較大方便性樣品置換空間。4. The sample is 180 degrees vertically exposed to light (reflected or penetrated by the sample) and is optically approximate to the white LED. And the external sample tank test; to ensure a more convenient sample replacement space for the sample.

五、白光光譜分解(Curve Fittng)以便白光做色彩結構分解及白光調色模擬在其色彩結構補色線上變化。Fifth, the white light spectral decomposition (Curve Fittng) so that the white light color structure decomposition and white light coloring simulation changes in the color structure complementary color line.

六、可取得量子(光子)轉換效率、輻射(光譜)轉換效率及視覺(流明或其他視覺光度單位)轉換效率。Sixth, quantum (photon) conversion efficiency, radiation (spectral) conversion efficiency and visual (lumen or other visual luminosity unit) conversion efficiency can be obtained.

七、可將白光、藍光及螢光光譜定量化數位儲存,建立數位光譜資料庫。7. The white light, blue light and fluorescent spectrum can be quantified and digitally stored to establish a digital spectral database.

八、定量光譜運算:可計算出LED螢光材料對應誘發藍光的絕對吸收量及相對吸收率。Eight, quantitative spectral operation: can calculate the absolute absorption and relative absorption rate of blue light induced by LED fluorescent materials.

九、提供絕對定量光譜算術運算,作為定量光譜資料庫的視覺光色模擬效果運算。Nine, provide absolute quantitative spectral arithmetic operation, as a visual light color simulation effect calculation of quantitative spectral database.

十、確保誘發光源光功率穩定,以確保螢光光譜功率穩定一致。10. Ensure that the optical power of the induced source is stable to ensure stable and consistent fluorescence spectral power.

十一、使用與與藍光LED晶片相同之光譜,直接誘發螢光材料產生與實際白光LED相同之結構的螢光光譜。11. Using the same spectrum as the blue LED chip, the fluorescent material is directly induced to produce a fluorescent spectrum of the same structure as the actual white LED.

十二、以光譜定量運算為基礎,可將數種不同螢光材料在光譜資料庫運算模式下,直接在分析軟件上混合各自光譜模擬特定光色之光譜。12. Based on the quantitative operation of the spectrum, a plurality of different fluorescent materials can be mixed in the spectral database operation mode, and the spectrum of the specific light color is simulated by directly mixing the respective spectra on the analysis software.

十三、不同誘發波長之晶片藍光光譜與LED螢光材料光譜,也可建立光譜資料庫做為LED光色調整模擬之用。Thirteen, different wavelengths of the blue light spectrum of the wafer and the spectrum of the LED fluorescent material, can also be established as a spectral data library for LED light color adjustment simulation.

十四、利用螢光光譜參數與誘發藍光光譜相互比配之光色,可在完全不浪費任何材料的條件下判定其LED螢光材料適合表現的光色特性。14. Using the color spectrum of the fluorescence spectral parameters and the induced blue light spectrum, the light color characteristics suitable for the LED fluorescent material can be determined without wasting any material at all.

十五、直接取樣螢光樣品測試載具:需具備高穿透性及高耐磨石英玻璃及固定量的樣品放置區,並配合測試光學路徑,樣品載具表面需可做漫射反射之白色表面。Fifteen, direct sampling fluorescent sample test vehicle: need to have high penetration and high wear-resistant quartz glass and a fixed amount of sample placement area, and with the test optical path, the sample carrier surface needs to be diffuse reflection white surface.

惟,以上所述僅為本發明之較佳實施例而已,非因此即拘限本發明之專利範圍,故舉凡運用本發明說明書及圖式內容所為之簡易修飾及等效結構變化,均應同理包含於本發明之專利範圍內,合予陳明。However, the above description is only for the preferred embodiment of the present invention, and thus the scope of the present invention is not limited thereto, so that the simple modification and equivalent structural changes that are made by using the specification and the contents of the present invention should be the same. It is included in the scope of the patent of the present invention and is combined with Chen Ming.

綜上所述,本發明之LED螢光材料光色與光譜檢測方法於使用時,為確實能達到其功效及目的,故本發明誠為一實用性優異之發明,為符合發明專利之申請要件,爰依法提出申請,盼 審委早日賜准本發明,以保障發明人之辛苦發明,倘若 鈞局審委有任何稽疑,請不吝來函指示,發明人定當竭力配合,實感公便。In summary, the LED fluorescent material light color and spectrum detecting method of the present invention can achieve its efficacy and purpose when used, so the invention is an invention with excellent practicability, and is an application for conforming to the invention patent. The application is made in accordance with the law, and the audit committee is expected to grant the invention as soon as possible to protect the inventor's hard work. If the audit committee has any doubts, please do not hesitate to give instructions, the inventor will try his best to cooperate and feel polite.

1...檢測裝置1. . . Testing device

2...起始光源裝置2. . . Starting light source device

3...光學積分球3. . . Optical integrating sphere

4...LED螢光材料4. . . LED fluorescent material

5...分析裝置5. . . Analytical device

6...分析模組6. . . Analysis module

61...光譜載入單元61. . . Spectral loading unit

62...光譜顯示單元62. . . Spectral display unit

63...光譜合成單元63. . . Spectral synthesis unit

64...光譜計算單元64. . . Spectral calculation unit

65...光譜儲存單元65. . . Spectral storage unit

66...色度座標產生單元66. . . Chroma coordinate generation unit

67...色度座標顯示單元67. . . Chroma coordinate display unit

7...初始誘發藍光光譜7. . . Initial induced blue light spectrum

71...被吸收誘發藍光光譜71. . . Absorbed induced blue light spectrum

72...螢光光譜72. . . Fluorescence spectrum

73...白光光譜73. . . White light spectrum

74...合成白光光譜74. . . Synthetic white light spectrum

75...螢光吸收量光譜75. . . Fluorescence absorption spectrum

76...縮小倍率合成白光光譜76. . . Reduced magnification synthetic white light spectrum

77...輻射轉換效率值77. . . Radiation conversion efficiency value

78...光譜儲存單元78. . . Spectral storage unit

79...色度座標產生單元79. . . Chroma coordinate generation unit

80...誘發藍光光譜色度座標80. . . Induced blue light spectrum chromaticity coordinates

81...螢光光譜色度座標81. . . Fluorescence spectral chromaticity coordinates

82...合成白光光譜色度座標82. . . Synthetic white light spectral chromaticity coordinates

第一圖 係為本發明較佳實施例之方塊示意圖一。The first figure is a block diagram of a preferred embodiment of the present invention.

第二圖 係為本發明較佳實施例之方塊示意圖二。The second figure is a block diagram 2 of a preferred embodiment of the present invention.

第三圖 係為本發明較佳實施例之方塊流程圖。The third diagram is a block flow diagram of a preferred embodiment of the invention.

第四圖 係為本發明較佳實施例之光源路徑示意圖一。The fourth figure is a schematic diagram of a light source path according to a preferred embodiment of the present invention.

第五圖 係為本發明較佳實施例之光源路徑示意圖二。The fifth figure is a schematic diagram 2 of the light source path of the preferred embodiment of the present invention.

第六圖 係為本發明較佳實施例之系統畫面示意圖一。Figure 6 is a schematic diagram of a system screen according to a preferred embodiment of the present invention.

第七圖 係為本發明較佳實施例之系統畫面示意圖二。The seventh figure is a schematic diagram 2 of the system screen of the preferred embodiment of the present invention.

第八圖 係為本發明較佳實施例之系統畫面示意圖三。The eighth figure is a schematic diagram 3 of the system screen of the preferred embodiment of the present invention.

第九圖 係為本發明較佳實施例之系統畫面示意圖四。The ninth diagram is a schematic diagram of a system screen according to a preferred embodiment of the present invention.

第十圖 係為本發明較佳實施例之系統畫面示意圖五。Figure 10 is a schematic diagram 5 of a system screen according to a preferred embodiment of the present invention.

第十一圖 係為本發明較佳實施例之系統畫面示意圖六。Figure 11 is a schematic diagram 6 of the system screen of the preferred embodiment of the present invention.

第十二圖 係為本發明較佳實施例之系統畫面示意圖七。Figure 12 is a schematic diagram of a system screen according to a preferred embodiment of the present invention.

第十三圖 係為本發明較佳實施例之系統畫面示意圖八。Figure 13 is a schematic diagram of a system screen according to a preferred embodiment of the present invention.

第十四圖 係為本發明較佳實施例之色度座標圖一。Figure 14 is a chromaticity coordinate diagram 1 of a preferred embodiment of the present invention.

第十五圖 係為本發明較佳實施例之色度座標圖二。The fifteenth diagram is a chromaticity coordinate diagram 2 of the preferred embodiment of the present invention.

第十六圖 係為本發明較佳實施例之色度座標圖三。Figure 16 is a third embodiment of the chromaticity coordinate of the preferred embodiment of the present invention.

第十七圖 係為本發明較佳實施例之色度座標圖四。Figure 17 is a chromaticity coordinate diagram 4 of a preferred embodiment of the present invention.

第十八圖 係為本發明較佳實施例之色度座標圖五。Figure 18 is a chromaticity coordinate diagram 5 of a preferred embodiment of the present invention.

第十九圖 係為本發明CIE三刺激值函數之示意圖。The nineteenth figure is a schematic diagram of the CIE tristimulus value function of the present invention.

第二十圖 係為本發明1931色度座標之示意圖。Figure 20 is a schematic view of the 1931 chromaticity coordinates of the present invention.

第二十一圖 係為本發明藍光光譜及螢光光譜之波形圖一。The twenty-first figure is a waveform diagram 1 of the blue spectrum and the fluorescence spectrum of the present invention.

第二十二圖 係為本發明藍光光譜及螢光光譜之波形圖二。The twenty-second diagram is the waveform diagram 2 of the blue spectrum and the fluorescence spectrum of the present invention.

第二十三圖 係為本發明藍光光譜及螢光光譜之波形圖三。The twenty-third figure is a waveform diagram 3 of the blue spectrum and the fluorescence spectrum of the present invention.

1...檢測裝置1. . . Testing device

6...分析模組6. . . Analysis module

61...光譜載入單元61. . . Spectral loading unit

62...光譜顯示單元62. . . Spectral display unit

63...光譜合成單元63. . . Spectral synthesis unit

64...光譜計算單元64. . . Spectral calculation unit

65...光譜儲存單元65. . . Spectral storage unit

66...色度座標產生單元66. . . Chroma coordinate generation unit

67...色度座標顯示單元67. . . Chroma coordinate display unit

Claims (4)

一種LED螢光材料光色與光譜檢測方法,其檢測方法為:(a)透過一起始光源照射出一誘發藍色光源並經過一光學積分球而產生一初始誘發藍光光譜;(b)經過光學積分球之誘發藍色光源照射於一LED螢光材料上,再180度反射回光學積分球內,而產生一被吸收誘發藍光光譜;(c)其初始誘發藍光光譜及被吸收藍光光譜由一分析裝置所接收,並透過一內建於內之分析模組進行分析;(d)藉由一包含於分析模組內的光譜載入單元將初始誘發藍光光譜及被吸收誘發藍光光譜顯示於一光譜顯示單元上;(e)再透過光譜載入單元將被吸收誘發藍光光譜所產生的螢光光譜顯示於光譜顯示單元上;(f)透過光譜合成單元將被吸收誘發藍光光譜及螢光光譜進行合成以產生一白光光譜並顯示於光譜顯示單元上;(g)透過一光譜計算單元將被吸收誘發藍光光譜及螢光光譜進行相加合成運算以產生一合成白光光譜並顯示於光譜顯示單元上;(h)再透過光譜計算單元將初始誘發藍光光譜及被吸收誘發藍光光譜進行相減運算以產生一螢光吸收量光譜並顯示於光譜顯示單元上;(i)再一次透過光譜計算單元將合成白光光譜進行光譜乘法倍率運算以產生一縮小倍率合成白光光譜並顯示於光譜顯示單元上;(j)再一次透過光譜計算單元將螢光光譜除上螢光吸收量光譜以產生該LED螢光材料之輻射轉換效率值;(k)將合成白光光譜、螢光吸收量光譜、縮小倍率合成白光光譜及輻射轉換效率值儲存於一光譜儲存單元內。 A method for detecting color and spectrum of LED fluorescent materials, wherein the detection method comprises: (a) emitting an induced blue light source through an initial light source and generating an initial induced blue light spectrum through an optical integrating sphere; (b) passing through the optical The blue light source induced by the integrating sphere is irradiated onto an LED fluorescent material, and then reflected back into the optical integrating sphere by 180 degrees to generate an absorbed induced blue light spectrum; (c) its initial induced blue light spectrum and the absorbed blue light spectrum are The analysis device receives and analyzes through an internal analysis module; (d) displays the initial induced blue spectrum and the absorbed induced blue spectrum by a spectral loading unit included in the analysis module. (e) re-transmitting the spectral loading unit to display the fluorescence spectrum generated by the absorption-induced blue light spectrum on the spectral display unit; (f) transmitting the induced blue light spectrum and the fluorescent spectrum through the spectral synthesis unit Synthesizing to generate a white light spectrum and displaying it on the spectral display unit; (g) adding and absorbing the absorbed blue light spectrum and the fluorescence spectrum through a spectral calculation unit Generating a synthetic white light spectrum and displaying it on the spectral display unit; (h) re-transmission of the spectral spectrum calculation unit to subtract the initial induced blue light spectrum and the absorbed induced blue light spectrum to generate a fluorescence absorption spectrum and display it on the spectral display unit (i) again performing a spectral multiplication magnification operation through the spectral calculation unit to generate a reduced magnification synthetic white light spectrum and displaying it on the spectral display unit; (j) dividing the fluorescent spectrum by the spectral calculation unit again A fluorescent absorption spectrum is generated to generate a radiation conversion efficiency value of the LED fluorescent material; (k) storing the synthesized white light spectrum, the fluorescence absorption spectrum, the reduced magnification synthetic white light spectrum, and the radiation conversion efficiency value in a spectral storage unit . 如申請專利範圍第1項所述之LED螢光材料光色與光譜檢測方法,其中檢測方法更包括: (l)透過一色度座標產生單元將初始誘發藍光光譜經色彩函數轉換後產生一誘發藍光光譜色度座標;(m)再透過色度座標產生單元將螢光光譜經色彩函數轉換後產生一螢光光譜色度座標;(n)再透過色度座標產生單元將合成白光光譜經色彩函數轉換後產生一合成白光光譜色度座標;(o)再將誘發藍光光譜色度座標、螢光光譜色度座標及合成白光光譜色度座標共同載入以產生一補色線結構圖或色彩區域結構圖。 The method for detecting the color and spectrum of the LED fluorescent material according to the first aspect of the patent application, wherein the detecting method further comprises: (1) converting the initially induced blue light spectrum by a color function through a colorimetric coordinate generating unit to generate an induced blue light spectral chromaticity coordinate; (m) transmitting the fluorescent spectrum by a color function through a chromaticity coordinate generating unit to generate a firefly The optical spectral chromaticity coordinates; (n) the chromaticity coordinate generating unit converts the synthesized white light spectrum by a color function to generate a synthetic white light spectral chromaticity coordinate; (o) the blue spectral chromaticity coordinate and the fluorescent spectral color are induced again. The coordinate coordinates and the synthetic white light spectral chromaticity coordinates are co-loaded to produce a complementary color line structure or a color area structure map. 如申請專利範圍第1項所述之LED螢光材料光色與光譜檢測方法,其中該起始光源係為藍色光源。 The LED fluorescent material light color and spectrum detecting method according to claim 1, wherein the starting light source is a blue light source. 如申請專利範圍第1項所述之LED螢光材料光色與光譜檢測方法,其中該LED螢光材料係為黃色螢光材料。 The LED fluorescent material light color and spectrum detecting method according to claim 1, wherein the LED fluorescent material is a yellow fluorescent material.
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