TWI455986B - A transparent rubber-modified polystyrenic resin - Google Patents

A transparent rubber-modified polystyrenic resin Download PDF

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Publication number
TWI455986B
TWI455986B TW101151179A TW101151179A TWI455986B TW I455986 B TWI455986 B TW I455986B TW 101151179 A TW101151179 A TW 101151179A TW 101151179 A TW101151179 A TW 101151179A TW I455986 B TWI455986 B TW I455986B
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TW
Taiwan
Prior art keywords
rubber
weight
modified styrene
based resin
copolymer
Prior art date
Application number
TW101151179A
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Chinese (zh)
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TW201425440A (en
Inventor
Jui Hsi Hsu
Ming Chou Kao
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Chi Mei Corp
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Publication date
Application filed by Chi Mei Corp filed Critical Chi Mei Corp
Priority to TW101151179A priority Critical patent/TWI455986B/en
Priority to CN201310185766.7A priority patent/CN103910834B/en
Publication of TW201425440A publication Critical patent/TW201425440A/en
Application granted granted Critical
Publication of TWI455986B publication Critical patent/TWI455986B/en

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Claims (8)

一種透明橡膠變性苯乙烯系樹脂,該透明橡膠變性苯乙烯系樹脂包含:一橡膠狀共聚物(A)所形成橡膠粒子之分散相,及一共聚物(B)所形成之連續相;該分散相中之橡膠粒子之重量平均粒徑為0.25至0.6 μm,且粒徑分佈寬幅為1.2至2.1,膨潤指數為7.5至17,粒徑分佈寬幅與膨潤指數相乘之數值為10至21;以該連續相中之共聚物(B)重量為100重量%計,該共聚物(B)包括10至49重量%之苯乙烯系單體單元、50至80重量%之(甲基)丙烯酸酯系單體單元,及1至10重量%之丙烯腈系單體單元。A transparent rubber-modified styrene-based resin comprising: a dispersed phase of rubber particles formed by a rubbery copolymer (A), and a continuous phase formed by a copolymer (B); The rubber particles in the phase have a weight average particle diameter of 0.25 to 0.6 μm, a particle size distribution width of 1.2 to 2.1, a swelling index of 7.5 to 17, and a particle size distribution width multiplied by a swelling index of 10 to 21 The copolymer (B) comprises 10 to 49% by weight of styrene monomer units and 50 to 80% by weight of (meth)acrylic acid based on 100% by weight of the copolymer (B) in the continuous phase. An ester monomer unit, and 1 to 10% by weight of an acrylic monomer unit. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,該透明橡膠變性苯乙烯系樹脂包含5至25重量%之分散相及75至95重量%之連續相。The transparent rubber-modified styrene-based resin according to claim 1, wherein the transparent rubber-modified styrene-based resin contains 5 to 25% by weight of a dispersed phase and 75 to 95% by weight of a continuous phase. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,該橡膠粒子之重量平均粒徑為0.3至0.5μm。The transparent rubber-modified styrene-based resin according to claim 1, wherein the rubber particles have a weight average particle diameter of 0.3 to 0.5 μm. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,該橡膠粒子的膨潤指數範圍為8至15。The transparent rubber-modified styrene-based resin according to claim 1, wherein the rubber particles have a swelling index ranging from 8 to 15. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,橡膠粒子之粒徑分佈寬幅為1.3至2.0。The transparent rubber-modified styrene-based resin according to claim 1, wherein the rubber particles have a particle size distribution of from 1.3 to 2.0. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,橡膠粒子之粒徑分佈寬幅為1.3至1.8。The transparent rubber-modified styrene-based resin according to claim 1, wherein the rubber particles have a particle size distribution of from 1.3 to 1.8. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,該橡膠狀共聚物為嵌段共聚物,且苯乙烯與丁二烯之重 量比率為10至50/50至90。 The transparent rubber-modified styrene resin according to claim 1, wherein the rubbery copolymer is a block copolymer, and the weight of styrene and butadiene is The ratio is from 10 to 50/50 to 90. 如請求項1所述之透明橡膠變性苯乙烯系樹脂,其中,該共聚物(B)與該橡膠狀共聚合物(A)之屈折率差小於0.005。The transparent rubber-modified styrene-based resin according to claim 1, wherein a difference in yield of the copolymer (B) and the rubber-like copolymer (A) is less than 0.005.
TW101151179A 2012-12-28 2012-12-28 A transparent rubber-modified polystyrenic resin TWI455986B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
TW101151179A TWI455986B (en) 2012-12-28 2012-12-28 A transparent rubber-modified polystyrenic resin
CN201310185766.7A CN103910834B (en) 2012-12-28 2013-05-17 Transparent rubber modified styrene resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW101151179A TWI455986B (en) 2012-12-28 2012-12-28 A transparent rubber-modified polystyrenic resin

Publications (2)

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TW201425440A TW201425440A (en) 2014-07-01
TWI455986B true TWI455986B (en) 2014-10-11

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CN (1) CN103910834B (en)
TW (1) TWI455986B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI580720B (en) * 2015-12-10 2017-05-01 奇美實業股份有限公司 Thermoplastic resin composition and molding product made therefrom
TWI580721B (en) * 2015-12-11 2017-05-01 奇美實業股份有限公司 Thermoplastic resin composition and molding product made therefrom
CN105418830A (en) * 2015-12-22 2016-03-23 长春工业大学 SBS elastomer modified transparent styrene resin composition and preparation method thereof
TWI607065B (en) * 2016-12-30 2017-12-01 奇美實業股份有限公司 Resin composition for three-dimensional printing
TWI636085B (en) * 2017-08-01 2018-09-21 奇美實業股份有限公司 Rubber modified styrene-based resin composition and molding product made therefrom
US20190048120A1 (en) 2017-08-11 2019-02-14 Sumitomo Bakelite Europe N. V. Resorcinol resins and compositions derived thereform

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW562839B (en) * 2000-07-11 2003-11-21 Chi Mei Corp Transparent rubber-modified styrenic resin composition
TWI302538B (en) * 2001-10-11 2008-11-01 Denki Kagaku Kogyo Kk

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200825130A (en) * 2006-12-15 2008-06-16 Chi Mei Corp The rubber composition of modified polystyrene-based resin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW562839B (en) * 2000-07-11 2003-11-21 Chi Mei Corp Transparent rubber-modified styrenic resin composition
TWI302538B (en) * 2001-10-11 2008-11-01 Denki Kagaku Kogyo Kk

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CN103910834A (en) 2014-07-09
CN103910834B (en) 2016-09-21
TW201425440A (en) 2014-07-01

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