TWI453764B - Thermal recovering method for enameled wire - Google Patents

Thermal recovering method for enameled wire Download PDF

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Publication number
TWI453764B
TWI453764B TW100115892A TW100115892A TWI453764B TW I453764 B TWI453764 B TW I453764B TW 100115892 A TW100115892 A TW 100115892A TW 100115892 A TW100115892 A TW 100115892A TW I453764 B TWI453764 B TW I453764B
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enameled wire
recovering
waste
wire
copper
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TW100115892A
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Chinese (zh)
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TW201246232A (en
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Jenn Shing Wang
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Univ Far East
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/82Recycling of waste of electrical or electronic equipment [WEEE]

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  • Processing Of Solid Wastes (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

火法回收漆包線之方法 Method for recovering enameled wire by fire method

本發明是有關於一種火法回收漆包線之方法,特別是有關於一種利用加熱一密閉空間以回收漆包線之方法。 The present invention relates to a method of recovering an enameled wire by a fire method, and more particularly to a method of recovering an enameled wire by heating a closed space.

漆包線係由一導體經由一特殊處理將一絕緣材質披覆於導體表面以形成一外漆層,由於此外漆層具有絕緣之功能,故此時導體可經由繞捲以形成線圈,如此可用於電磁感應的各種應用,例如:馬達或變壓器等。 The enameled wire is coated with an insulating material on the surface of the conductor by a special treatment to form an outer lacquer layer. Since the lacquer layer has an insulating function, the conductor can be wound to form a coil, so that it can be used for electromagnetic induction. Various applications, such as motors or transformers.

習知漆包線脫漆之方法係可藉由加熱此漆包線之外漆層使其軟化,再使用一刮除之動作將此漆包線之外漆層刮除。但此加熱之動作將使外漆層產生有害物質,此有害物質可能產生對人體的傷害以及對環境的汙染。 The conventional enamelled wire stripping method can be softened by heating the lacquer layer outside the enamel wire, and then scraping the lacquer layer by a scraping action. However, this heating action will cause the paint layer to produce harmful substances, which may cause harm to the human body and environmental pollution.

有鑑於習知技藝之各項問題,為了能夠兼顧解決之,本發明人基於多年研究開發與諸多實務經驗,提出一種火法回收漆包線之方法,以作為改善上述缺點之實現方式與依據。 In view of the problems of the prior art, in order to be able to solve the problem, the inventors have proposed a method for recovering the enameled wire by fire method based on years of research and development and many practical experiences, as an implementation method and basis for improving the above disadvantages.

有鑑於此,本發明之目的就是在提供一種火法回收漆包線之方法,以解決習知之問題。 In view of the above, it is an object of the present invention to provide a method of recovering an enameled wire by a fire method to solve the conventional problems.

根據本發明之目的,提出一種火法回收漆包線之方法,漆包線係包含一含銅導線及一外漆層,包含下列步驟:將一漆包線與一碳原子源置入一密閉空間,於加熱密閉空間至一特定溫度使該碳原子源產生還原氣氛,以使漆包線與該還原氣氛,包括一氧化碳氣體、碳原子及二氧化碳氣體產生作用,使外漆層形成廢棄物,以及分離廢棄物以回收含銅導線。其中,特定溫度係例如介於攝氏350度至1300度之間。 According to the object of the present invention, a method for recovering an enameled wire by a fire method is provided. The enamel wire comprises a copper-containing wire and an outer lacquer layer, comprising the steps of: placing an enameled wire and a source of carbon atoms in a sealed space to heat the sealed space. To a specific temperature, the carbon atom source generates a reducing atmosphere to cause the enameled wire to react with the reducing atmosphere, including carbon monoxide gas, carbon atoms and carbon dioxide gas, to form the outer paint layer into waste, and to separate the waste to recover the copper-containing wire. . Among them, the specific temperature is, for example, between 350 and 1300 degrees Celsius.

實際而言,上開所述之碳原子源可以是煤炭、焦炭、竹木炭、燃油、有機溶劑、碳氫化合物或其組合,因此當碳原子源被加熱之後可以產生還原氣氛,例如一氧化碳氣體、碳原子及該二氧化碳氣體。此外,吾人更特別提到,分離廢棄物的步驟中更包含排除廢氣及銅渣之一者或兩者,而廢棄物可以是氣體和殘碳。換言之,當外漆層與還原氣氛反應而產生廢棄物,其中廢棄物可能會以廢氣的型式產生,而殘碳係黏附於含銅導線表面。 In practice, the carbon atom source described above may be coal, coke, bamboo charcoal, fuel oil, organic solvent, hydrocarbon or a combination thereof, so that when the carbon atom source is heated, a reducing atmosphere such as carbon monoxide gas may be generated. Carbon atoms and the carbon dioxide gas. In addition, we have mentioned in particular that the step of separating the waste further comprises excluding one or both of the exhaust gas and the copper slag, and the waste may be a gas and a residual carbon. In other words, when the outer paint layer reacts with the reducing atmosphere to produce waste, the waste may be produced in the form of exhaust gas, and the residual carbon adheres to the surface of the copper-containing wire.

茲為使 貴審查委員對本發明之技術特徵及所達到之功效有更進一步之瞭解與認識,謹佐以較佳之實施例及配合詳細之說明如後。 For a better understanding and understanding of the technical features and the efficacies of the present invention, the preferred embodiments and the detailed description are as follows.

S11至S13‧‧‧步驟流程 S11 to S13‧‧‧ step procedure

第1圖 係為本發明之火法回收漆包線之方法之步驟流程圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a flow chart showing the steps of a method for recovering an enameled wire by a fire method of the present invention.

以下將參照相關圖式,說明依本發明實施例之火法回收漆包線之方法,為使便於理解,下述實施例中之相同元件係以相同之符號標示來說明。 Hereinafter, the method of recovering the enameled wire by the fire method according to the embodiment of the present invention will be described with reference to the related drawings. For the sake of understanding, the same components in the following embodiments are denoted by the same reference numerals.

請參閱第1圖,其係為本發明之火法回收漆包線之方法之步驟流程圖,漆包線係包含一含銅導線及一外漆層。圖中,火法回收漆包線之方法包含:步驟S11:置入至少一碳原子源及漆包線於一密閉空間中:步驟S12:加熱密閉空間至一特定溫度,以使漆包線與該碳原子源所產生的還原氣氛產生作用,還原氣氛係例如包括一氧化碳氣體、碳原子及二氧化碳氣體,使外漆層與還原氣氛形成廢棄物;以及步驟S13:分離廢棄物以回收含銅導線。 Please refer to FIG. 1 , which is a flow chart of the method for the method for recovering an enameled wire by a fire method according to the present invention. The enamel wire comprises a copper-containing wire and an outer lacquer layer. In the figure, the method for recovering the enameled wire by fire method comprises: step S11: placing at least one source of carbon atoms and an enameled wire in a sealed space: step S12: heating the sealed space to a specific temperature to generate the enameled wire and the source of the carbon atom. The reducing atmosphere acts, for example, including carbon monoxide gas, carbon atoms, and carbon dioxide gas to cause the outer lacquer layer to form a waste with the reducing atmosphere; and step S13: separating the waste to recover the copper-containing wire.

其中,一氧化碳氣體、碳原子及二氧化碳高溫氣體係使外漆層進行分解和碳化還原,同時防止銅材表面高溫氧化,造成回收困難,特定溫度之範圍可在350度至1300度之間。 Among them, the carbon monoxide gas, carbon atom and carbon dioxide high temperature gas system decompose and carbonize and reduce the outer paint layer, and prevent the high temperature oxidation of the copper surface, which causes difficulty in recovery. The specific temperature range can be between 350 and 1300 degrees.

更進一步來說,本發明係將漆包線置入一密閉空間,此密閉空間內部係具有至少一碳原子源,其特徵在於加熱密閉空間至一特定溫度,以使漆包線與該還原氣氛,包括一氧化碳氣體、碳原子及該二氧化碳氣體產生作用,使外漆層形成廢棄物,並分離廢棄物以回收含銅導線,此特定溫度係可在350度至1300度之間,此外漆層為一單層和多層高分子層,碳原子來源為煤炭、焦炭、竹木炭、燃油、有機溶劑、碳氫化合物之一及其組合。 Furthermore, the present invention places the enamel wire into a sealed space having at least one source of carbon atoms inside, which is characterized by heating the sealed space to a specific temperature so that the enamel wire and the reducing atmosphere, including carbon monoxide gas, The carbon atom and the carbon dioxide gas act to cause the outer paint layer to form waste, and separate the waste to recover the copper-containing wire. The specific temperature may be between 350 degrees and 1300 degrees, and the paint layer is a single layer and The multi-layer polymer layer, the carbon atom source is one of coal, coke, bamboo charcoal, fuel oil, organic solvent, hydrocarbon and a combination thereof.

步驟S13中,外漆層碳化而分解成氣體,或產生殘碳黏附於銅材表面,前者只需將廢氣排出,溫度係可在350度至1200度之間,後者則需使溫度高於銅材熔點以上,溫度係可在1200度至1350度之間,殘碳因密度遠較銅液低而懸浮於液面,此銅渣經刮取或撈 取而分離,達到回收銅材的效果。 In step S13, the outer paint layer is carbonized and decomposed into a gas, or residual carbon is adhered to the surface of the copper material. The former only needs to discharge the exhaust gas, and the temperature may be between 350 degrees and 1200 degrees, and the latter needs to make the temperature higher than copper. Above the melting point of the material, the temperature can be between 1200 and 1350 degrees. The residual carbon is suspended in the liquid surface because the density is much lower than that of the copper liquid. The copper residue is scraped or scraped. Separate and take off to achieve the effect of recycling copper.

以上所述僅為舉例性,而非為限制性者。任何未脫離本發明之精神與範疇,而對其進行之等效修改或變更,均應包含於後附之申請專利範圍中。 The above is intended to be illustrative only and not limiting. Any equivalent modifications or alterations to the spirit and scope of the invention are intended to be included in the scope of the appended claims.

S11至S13‧‧‧步驟流程 S11 to S13‧‧‧ step procedure

Claims (9)

一種火法回收漆包線之方法,該漆包線係包含一含銅導線及一外漆層,其包含:置入至少一碳原子源以及該漆包線於一密閉空間中;加熱該密閉空間至一特定溫度以使該碳原子源產生一還原氣氛,藉此,該外漆層與該還原氣氛產生作用形成一廢棄物;以及分離該廢棄物以回收該含銅導線。 A method for recovering an enameled wire by a fire method, the enamel wire comprising a copper-containing wire and an outer lacquer layer, comprising: placing at least one source of carbon atoms and the enamel wire in a sealed space; heating the sealed space to a specific temperature The carbon atom source is caused to generate a reducing atmosphere, whereby the outer paint layer and the reducing atmosphere act to form a waste; and the waste is separated to recover the copper-containing wire. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該特定溫度之範圍係介於攝氏350度至1300度之間。 The method of claim 1, wherein the specific temperature ranges from 350 to 1300 degrees Celsius. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該外漆層為一單層和多層高分子層。 The method for recovering an enameled wire by a fire method according to claim 1, wherein the outer paint layer is a single layer and a plurality of polymer layers. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該碳原子源為煤炭、焦炭、竹木炭、燃油、有機溶劑、碳氫化合物或其組合。 The method of claim 1, wherein the source of carbon atoms is coal, coke, bamboo charcoal, fuel oil, organic solvent, hydrocarbon or a combination thereof. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該分離該廢棄物之步驟更包含排除廢氣及銅渣之一者或兩者。 The method of recovering the enameled wire by the fire method of claim 1, wherein the step of separating the waste further comprises excluding one or both of the exhaust gas and the copper slag. 如申請專利範圍第5項所述之火法回收漆包線之方法,其中該分離該廢棄物之步驟中,密閉空間之溫度介於攝氏350度至1200度之間以去除該廢氣。 The method for recovering an enameled wire by a fire method according to claim 5, wherein in the step of separating the waste, the temperature of the sealed space is between 350 and 1200 degrees Celsius to remove the exhaust gas. 如申請專利範圍第5項所述之火法回收漆包線之方法,其中該分離該廢棄物之步驟中,密閉空間之溫度介於攝氏1200度至1350度之間以去除該銅渣。 The method for recovering an enameled wire by a fire method according to claim 5, wherein in the step of separating the waste, the temperature of the sealed space is between 1200 and 1350 degrees Celsius to remove the copper residue. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該廢棄物為氣體和殘碳。 The method of claim 1, wherein the waste is a gas and residual carbon. 如申請專利範圍第1項所述之火法回收漆包線之方法,其中該還原氣氛包含一氧化碳氣體、碳原子、二氧化碳氣體或其組合。 A method of recovering an enameled wire by a fire method according to claim 1, wherein the reducing atmosphere comprises carbon monoxide gas, carbon atoms, carbon dioxide gas or a combination thereof.
TW100115892A 2011-05-06 2011-05-06 Thermal recovering method for enameled wire TWI453764B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11188335A (en) * 1997-12-26 1999-07-13 Nippon Mining & Metals Co Ltd Method for treating waste copper wire
TW553906B (en) * 2002-03-21 2003-09-21 Amia Co Ltd A method for the treatment of waste tin-lead stripping solution
TW201025776A (en) * 2008-12-31 2010-07-01 Univ Far East Preprocessing process of recovering enamelled wire by quenching method
TW201024427A (en) * 2008-12-31 2010-07-01 Univ Far East Method for recycling waste slag containing copper carbon

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11188335A (en) * 1997-12-26 1999-07-13 Nippon Mining & Metals Co Ltd Method for treating waste copper wire
TW553906B (en) * 2002-03-21 2003-09-21 Amia Co Ltd A method for the treatment of waste tin-lead stripping solution
TW201025776A (en) * 2008-12-31 2010-07-01 Univ Far East Preprocessing process of recovering enamelled wire by quenching method
TW201024427A (en) * 2008-12-31 2010-07-01 Univ Far East Method for recycling waste slag containing copper carbon

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