TWI407622B - Microbial fuel cell - Google Patents
Microbial fuel cell Download PDFInfo
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- TWI407622B TWI407622B TW098129348A TW98129348A TWI407622B TW I407622 B TWI407622 B TW I407622B TW 098129348 A TW098129348 A TW 098129348A TW 98129348 A TW98129348 A TW 98129348A TW I407622 B TWI407622 B TW I407622B
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Abstract
Description
本發明係有關於一種燃料電池,特別是指一種微生物燃料電池。 The present invention relates to a fuel cell, and more particularly to a microbial fuel cell.
隨著將垃圾轉變成能源的技術出現,能源持續減少所帶來的問題得以減緩,微生物燃料電池的使用為其中解決能源短缺的技術之一。 With the emergence of technologies that turn waste into energy, the problems caused by the continued reduction in energy are alleviated, and the use of microbial fuel cells is one of the technologies to address energy shortages.
微生物燃料電池利用細菌分解有機垃圾,將它們的化學鍵能量轉換為能量,如電力和氫氣等。利用微生物燃料電池處理廢水,可以將處理廢水所需的大部分能量節省下來,除了可以產生大量的電力,亦可減少晾乾廢水中活性淤泥的成本,用電量減少一半,而產生的需處理的固體物質亦減少了大部分。 Microbial fuel cells use bacteria to break down organic waste and convert their chemical bond energy into energy, such as electricity and hydrogen. The use of microbial fuel cells to treat wastewater can save most of the energy needed to treat wastewater. In addition to generating a large amount of electricity, it can also reduce the cost of active sludge in air-drying wastewater, reducing electricity consumption by half, and the resulting treatment needs to be treated. The solid matter is also reduced by a large part.
微生物燃料電池還可以成為世界上較落後地區的重要能源,或是將某些工業界還不能利用的物質轉化為能源,如海底沉澱物,或垃圾中的某些生物物質。 Microbial fuel cells can also be an important source of energy in the less developed regions of the world, or convert substances that are not available to certain industries into energy sources, such as sediments on the sea floor, or certain biological substances in waste.
現有技術之能量來源大多為醣類物質,會有與人爭食的問題,若以廢水做為來源,則機動性不足,廢水中之雜質又易影響產電效能。再者,一般微生物產電系統所採用之微生 物,大多必須額外添加電子傳遞媒,使其成本大大提昇。 Most of the energy sources of the prior art are sugar substances, and there is a problem of competing with people. If wastewater is used as a source, the mobility is insufficient, and the impurities in the wastewater are likely to affect the electricity production efficiency. Furthermore, the micro-generation used in general microbial power generation systems Most of the things must be added with additional electronic media, which greatly increases the cost.
因此,本發明提供一種微生物燃料電池,其係以光能為其能量供應者,將光能轉為電能,而且不需額外添加電子傳遞媒,即可有相當之電流反應,又可固定二氧化碳,如此可有效降低微生物燃料電池之成本,亦可降低二氧化碳排放量,以降低全球暖化之效益。 Therefore, the present invention provides a microbial fuel cell which converts light energy into electrical energy by using light energy as its energy supplier, and can have a relatively high current reaction and can fix carbon dioxide without additional electron transport medium. This can effectively reduce the cost of microbial fuel cells, and can also reduce carbon dioxide emissions to reduce the benefits of global warming.
本發明之主要目的,在於提供一種微生物燃料電池,其係藉由一光合微生物以吸收二氧化碳同時利用光能而產生電力,而且不需額外添加電子傳遞媒,即可有相當之電流反應,不但降低二氧化碳排放量,以增加產電之效益,更有效降低微生物燃料電池之成本,以降低全球暖化之效益。 The main object of the present invention is to provide a microbial fuel cell which generates electricity by absorbing carbon dioxide while utilizing light energy, and can generate a relatively large current reaction without further addition of an electron transport medium, which not only reduces Carbon dioxide emissions to increase the efficiency of electricity production, and more effectively reduce the cost of microbial fuel cells to reduce the benefits of global warming.
本發明提供一種微生物燃料電池,其包含一第一容器、一第二容器、一培養基、一通透膜與一光源,第二容器與第一容器相接設;培養基設於第一容器與第二容器內,培養基具有一光合微生物;通透膜設於第一容器與第二容器之間;光源透設第一容器並照射光合微生物,光合微生物吸收一二氧化碳並吸收光能而產生一電力。本發明藉由光合微生物以吸收二氧化碳而產生電力,且不需額外添加電子傳遞媒,即可有相當之電流反應,不但降低二氧化碳排放量,更有效降低微生物燃料電池之成本,以降低全球暖化之效益。 The present invention provides a microbial fuel cell comprising a first container, a second container, a medium, a permeable membrane and a light source, the second container is connected to the first container; the medium is disposed in the first container and the first container In the second container, the medium has a photosynthetic microorganism; the permeable membrane is disposed between the first container and the second container; the light source is permeable to the first container and irradiates the photosynthetic microorganism, and the photosynthetic microorganism absorbs a carbon dioxide and absorbs the light energy to generate a power. The invention generates electric power by absorbing carbon dioxide by photosynthetic microorganisms, and has a considerable current reaction without additional addition of an electron transport medium, thereby reducing carbon dioxide emissions and reducing the cost of the microbial fuel cell to reduce global warming. Benefits.
10‧‧‧第一容器 10‧‧‧First container
12‧‧‧透氣口 12‧‧‧ venting port
14‧‧‧陽電極 14‧‧‧A positive electrode
20‧‧‧第二容器 20‧‧‧Second container
24‧‧‧陰電極 24‧‧‧negative electrode
30‧‧‧培養基 30‧‧‧ medium
32‧‧‧光合微生物 32‧‧‧Photosynthetic microorganisms
40‧‧‧通透膜 40‧‧‧Transparent membrane
50‧‧‧光源 50‧‧‧Light source
60‧‧‧定電位儀 60‧‧‧Constant potential meter
70‧‧‧電阻 70‧‧‧resistance
第一圖本發明較加實施例之微生物燃料電池之產電測試裝置的結構示意; 第二圖本發明較加實施例之微生物燃料電池之結構示意圖;第三圖為本發明較佳實施例之光合微生物產電之電流與時間的曲線圖;第四圖為本發明較佳實施例之光合微生物於開光、閉光之條件下的產電之電流與時間的曲線圖;以及第五圖為本發明較佳實施例之微生物燃料電池輸出功率之曲線圖。 1 is a schematic structural view of a power generation test device for a microbial fuel cell according to an embodiment of the present invention; 2 is a schematic view showing the structure of a microbial fuel cell according to a comparative example of the present invention; the third drawing is a graph showing the current and time of photosynthetic microorganism production according to a preferred embodiment of the present invention; and the fourth drawing is a preferred embodiment of the present invention. A graph of current and time of electricity production by photosynthetic microorganisms under conditions of light opening and closing; and a fifth graph showing a graph of microbial fuel cell output power according to a preferred embodiment of the present invention.
茲為使 貴審查委員對本發明之結構特徵及所達成之功效有更進一步之瞭解與認識,謹佐以較佳之實施例及配合詳細之說明,說明如後:請參閱第一圖與第二圖,其係為本發明較佳實施例之微生物燃料電池之產電測試裝置的結構示意與微生物燃料電池之結構示意圖;如圖所示,本發明之微生物燃料電池包含一第一容器10、一第二容器20、一培養基30、一通透膜40與一光源50,第二容器20與第一容器10相接設;培養基30設於第一容器10與第二容器20內,培養基30具有一光合微生物32;通透膜40設於第一容器10與第二容器20之間,第一容器10設有一透氣口12,以供透氣用,光源50設於第一容器10下方,第一容器10為一透光容器,光源50為一LED燈,光源50透設第一容器10並照射光合微生物32,光合微生物32吸收一二氧化碳並產生一電力。 For a better understanding and understanding of the structural features and efficacies of the present invention, please refer to the preferred embodiment and the detailed description. For the following: please refer to the first and second figures. The structure of the microbial fuel cell of the preferred embodiment of the present invention is schematically illustrated as a schematic diagram of the structure of the microbial fuel cell. As shown, the microbial fuel cell of the present invention comprises a first container 10, a first The second container 20, a medium 30, a permeable membrane 40 and a light source 50, the second container 20 is connected to the first container 10; the medium 30 is disposed in the first container 10 and the second container 20, and the medium 30 has a Photosynthetic microorganism 32; the permeable membrane 40 is disposed between the first container 10 and the second container 20, the first container 10 is provided with a venting opening 12 for ventilation, and the light source 50 is disposed under the first container 10, the first container 10 is a light-transmissive container, and the light source 50 is an LED lamp. The light source 50 is permeable to the first container 10 and irradiates the photosynthetic microorganism 32, and the photosynthetic microorganism 32 absorbs a carbon dioxide and generates a power.
培養基30包含一碳酸鹽,碳酸鹽為一無機碳之培養基30,而光合微生物32為由溫泉篩選並命名之一藍綠菌( Thermosynechococcus sp.CL-1),以碳酸鹽之培養基30來進行培養。第一容器10設有一陽電極14,陽電極材料為碳纖維布,陽電極14與第一容器10內的培養基30相接觸,第二容器20設有一陰電極24,陰電極24與第二容器20內之培養基30相接觸,陰電極24之材料包含白金。 The medium 30 contains a carbonate, the carbonate is an inorganic carbon medium 30, and the photosynthetic microorganism 32 is selected from a hot spring and named one of the blue-green bacteria ( Thermosynechococcus sp. CL-1) was cultured in a carbonate medium 30. The first container 10 is provided with an anode electrode 14, the anode electrode material is a carbon fiber cloth, the anode electrode 14 is in contact with the medium 30 in the first container 10, and the second container 20 is provided with a cathode electrode 24, the cathode electrode 24 and the second container 20 The medium 30 is in contact with each other, and the material of the cathode electrode 24 contains platinum.
本發明利用提供電壓之設備,做為產電能力測試之工具,如一定電位儀60連接陽電極14與陰電極24,以提供電壓於培養基30內,並將培養基30以光源50照射光合微生物32,而且本發明不需要於培養基30內添加電子傳遞媒,即可顯現固碳及產生電流之現象。將定電位儀60改為電阻70,電阻70分別接設於第一容器10與第二容器20內之陽電極14與陰電極24,以組合成以光源50為能量之微生物燃料電池,如圖二所示。此實施例之碳酸鹽之無機碳濃度為47mM,以提供光合微生物32一較佳反應環境。 The invention utilizes a device for providing voltage as a tool for power generation capability testing, such as a certain potentiometer 60 connecting the anode electrode 14 and the cathode electrode 24 to provide a voltage in the medium 30, and irradiating the medium 30 with the light source 50 to irradiate the photosynthetic microorganism 32. Moreover, the present invention does not require the addition of an electron transport medium to the medium 30, thereby exhibiting carbon sequestration and current generation. The potentiometer 60 is changed to a resistor 70, and the resistor 70 is respectively connected to the anode electrode 14 and the cathode electrode 24 in the first container 10 and the second container 20 to be combined into a microbial fuel cell with the light source 50 as an energy, as shown in the figure. The second is shown. The carbonate of this example has an inorganic carbon concentration of 47 mM to provide a photosynthetic microorganism 32 as a preferred reaction environment.
請參閱第三圖,其係為本發明較佳實施例之光合微生物產電之電流與時間的曲線圖,由圖可知,當本發明以適量之無機碳進行培養時,在固定之施加電壓下照光,隨著細胞之生長,其反應電流隨之升高,此實施例以施加電壓0.2V及照光,即可有效地將碳固定下來,而隨著細胞之增長,電流值亦隨之升高。 Please refer to the third figure, which is a graph of current and time of photosynthetic microorganism production according to a preferred embodiment of the present invention. It can be seen from the figure that when the present invention is cultured with an appropriate amount of inorganic carbon, under a fixed applied voltage. According to the light, as the cell grows, the reaction current increases. In this embodiment, the applied voltage is 0.2V and the light is applied, so that the carbon can be effectively fixed, and as the cell grows, the current value also increases. .
請參閱第四圖,其係為本發明較佳實施例之光合微生物於開光、閉光之條件下的產電之電流與時間的曲線圖;如圖所示,光合微生物32產電量於開光時較多,於閉光時較少,由此可知,光合微生物32產電是以光能為其能源之供應者。 當電流升高至18μA時,則進行關燈,如此電流便開始下降;當再次開燈後,電流值開始上升,反覆測試之結果,證明其電流與光之相關性。圖四中,A、B、C與D分別表示關燈、開燈、關燈與開燈四個狀態下的電流量測情形。 Please refer to the fourth figure, which is a graph showing the current and time of electricity production of the photosynthetic microorganism under the conditions of opening and closing light according to a preferred embodiment of the present invention; as shown in the figure, the photosynthetic microorganism 32 generates electricity when the light is turned on. There are many, and there are fewer when the light is closed. It can be seen that the photosynthetic microorganism 32 produces electricity by supplying light energy as its energy source. When the current rises to 18μA, the light is turned off, and the current begins to decrease. When the light is turned on again, the current value starts to rise, and the result of the repeated test proves the correlation between the current and the light. In Figure 4, A, B, C and D respectively indicate the current measurement in the four states of turning off the light, turning on the light, turning off the light and turning on the light.
請一併參閱第五圖,其係為本發明較佳實施例之微生物燃料電池輸出功率之曲線圖;如圖所示,本發明所組成不須添加電子傳遞酶之微生物燃料電池最大輸出功率為0.95mW m-2。光合微生物32在此一程序中不須添加電子傳遞媒,在照光條件下,可有效去除二氧化碳及具有產電潛能,可做為環保及綠能之工具。 Please refer to the fifth figure, which is a graph of the output power of the microbial fuel cell according to the preferred embodiment of the present invention; as shown in the figure, the maximum output power of the microbial fuel cell of the present invention which does not require the addition of an electron transfer enzyme is 0.95mW m-2. The photosynthetic microorganism 32 does not need to add an electron transport medium in this process, and can effectively remove carbon dioxide and have potential for generating electricity under illumination conditions, and can be used as an environmental protection and green energy tool.
由上述可知,本發明利用藍綠菌之光合微生物32以吸收二氧化碳,可同時有產電之效益,藍綠菌兼具耐高鹼性及高溫特性,可有效利用最大宗之二氧化碳排放源(煙道氣),故亦有降低二氧化碳排放量及產電之效益。針對生質能源的日益重要及二氧化碳對全球暖化之效應,藉由光合微生物32在固碳同時得到電能為一舉二得的作法。 It can be seen from the above that the present invention utilizes the photosynthetic microorganism 32 of blue-green fungus to absorb carbon dioxide, and has the benefit of producing electricity at the same time. The blue-green bacteria have both high alkali resistance and high temperature characteristics, and can effectively utilize the largest carbon dioxide emission source (flue) Gas), so there are also benefits of reducing carbon dioxide emissions and electricity production. In view of the increasing importance of biomass energy and the effect of carbon dioxide on global warming, it is a two-pronged approach to obtain electricity from carbon fixation by photosynthetic microorganisms 32.
綜上所述,本發明提供一種微生物燃料電池,其包含一第一容器、一第二容器、一培養基與一光源;培養基設於第一容器與第二容器內,培養基具有一光合微生物;光源透設第一容器並照射光合微生物,光合微生物吸收一二氧化碳並產生一電力。本發明藉由光合微生物以吸收二氧化碳而產生電力,且不需額外添加電子傳遞媒,即可有相當之電流反應,不但降低二氧化碳排放量,更有效降低微生物燃料電池之成本,以降低全球暖化之效益。 In summary, the present invention provides a microbial fuel cell comprising a first container, a second container, a medium and a light source; the medium is disposed in the first container and the second container, the medium has a photosynthetic microorganism; the light source The first container is permeable and irradiated with photosynthetic microorganisms, and the photosynthetic microorganism absorbs a carbon dioxide and generates a power. The invention generates electric power by absorbing carbon dioxide by photosynthetic microorganisms, and has a considerable current reaction without additional addition of an electron transport medium, thereby reducing carbon dioxide emissions and reducing the cost of the microbial fuel cell to reduce global warming. Benefits.
故本發明係實為一具有新穎性、進步性及可供產業利用者,應符合我國專利法所規定之專利申請要件無疑,爰依法提出發明專利申請,祈 鈞局早日賜准專利,至感為禱。 Therefore, the present invention is a novelty, progressive and available for industrial use. It should be in accordance with the patent application requirements stipulated in the Patent Law of China, and the invention patent application is filed according to law, and the prayer bureau will grant the patent as soon as possible. For prayer.
惟以上所述者,僅為本發明之一較佳實施例而已,並非用來限定本發明實施之範圍,舉凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 However, the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and the shapes, structures, features, and spirits described in the claims are equivalently changed. Modifications are intended to be included in the scope of the patent application of the present invention.
10‧‧‧第一容器 10‧‧‧First container
12‧‧‧透氣口 12‧‧‧ venting port
14‧‧‧陽電極 14‧‧‧A positive electrode
20‧‧‧第二容器 20‧‧‧Second container
24‧‧‧陰電極 24‧‧‧negative electrode
30‧‧‧培養基 30‧‧‧ medium
32‧‧‧光合微生物 32‧‧‧Photosynthetic microorganisms
40‧‧‧通透膜 40‧‧‧Transparent membrane
50‧‧‧光源 50‧‧‧Light source
70‧‧‧電阻 70‧‧‧resistance
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US20060251959A1 (en) * | 2003-06-27 | 2006-11-09 | Dimitre Karamanev | Biofuel cell |
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張恩愷-成大化工博士論文-以藍菌結合聚苯胺碳纖維電極開發光合作用代謝生物燃料電池之研究-Jun 2008。 * |
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