TWI380054B - Parallax barrier for 2d/3d image swap, 2d/3d image switching device, and lc light valve - Google Patents

Parallax barrier for 2d/3d image swap, 2d/3d image switching device, and lc light valve Download PDF

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TWI380054B
TWI380054B TW97119335A TW97119335A TWI380054B TW I380054 B TWI380054 B TW I380054B TW 97119335 A TW97119335 A TW 97119335A TW 97119335 A TW97119335 A TW 97119335A TW I380054 B TWI380054 B TW I380054B
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dimensional image
alignment
liquid crystal
electrode layer
electrode
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TW97119335A
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TW200949293A (en
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Chia Wei Kuo
Shie Chang Jeng
Yan Rung Lin
Chi Chang Liao
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Ind Tech Res Inst
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I380Q54 九、發明說明: 【發明所屬之技術領域】 本發明係有關於一種視差屏障裝置,適用於二維影像 與三維影像之切換用。 ^ · 【先前技術】 傳統三維影像(3D)顯示裝置主要應用雙眼視差 (binocular disparity)達到立體化效果,亦即讓左、右眼分別 * 接受不同視角的平面影像,利用大腦的融像功能以產生立 體視覺。在商業化產品中,自動立體顯示器 (auto-stereoscopic display)不需配戴眼鏡,較常使用的方法 為視差屏障(parallax barrier)或是微透鏡陣列(lenticular lens)的輔助’使得左眼僅看到左眼影像,而右眼看到右眼 影像,達到空間多功(spatial multiplexed)。 第1圖係顯示傳統固定型視差屏障。一視差屏障2設 φ 置於2D影像顯示器4前,觀看者無需配戴辅助眼鏡,由 於視差屏障2的存在,使得左眼^僅看到左眼影像l,而 右眼£!^僅看到右眼影像R,達到顯示立體影像的效果。此 傳統的固定型視差屏障只適用於固定3D顯像而無法切換 為2D顯像。 美國專利第US 6,046,849號揭露一種2D/3D切換型顯 示器裝置。請參閱第2A圖,傳統2D/3D切換型顯示器裝 置10A包括一液晶顯示器面板u、一背光模組13、一圖 案化二分之一波長板12、一可切換式轉子(switchabie I380Q54 - rotator) 15及一外偏振板14,其中圖案化二分之一波長板 12可分為其光轴與外偏振板14光軸垂直的12B以及與外 偏振板14光輛夹一角度的12A。上述可切換式轉子15可 以切換的兩種狀態,分別是:四分之一波長板(quarter wave plate)的狀態和對穿透光偏振沒影響的狀態。當顯示3D影 ' 像時,可切換式轉子15切換為對穿透光偏振沒影響的狀 . 態,此時通過12人之影像之偏振方向會被旋轉而通過外偏 振板14,而經過12B之影像將被外偏振板14阻檔,因此 • 二分之一波長板12、可切換式轉子15及外偏振板14之組 合可視為一視差屏障。當顯示2D影像時,可切換式轉子 15切換為四分之一波長板,讓經過12 a與12B的影像變圓 偏振,而可通過外偏振板14,達到2D顯像效果。 第2B圖係顯示另一傳統的2D/3D切換型顯示器裝置 的示意圖。其結構與2 A相似,不同處在於2 A中的可切換 式轉子15更換為可切換式擴散板(switchable diffuser) 16。 藉由電的方式切換可切換式擴散板16以達到3D/2D影像I380Q54 IX. Description of the Invention: [Technical Field] The present invention relates to a parallax barrier device suitable for switching between two-dimensional images and three-dimensional images. ^ · [Prior Art] The traditional 3D image display device mainly uses binocular disparity to achieve stereoscopic effect, that is, let the left and right eyes respectively accept plane images of different viewing angles, and utilize the brain's fusion function. To produce stereo vision. In commercial products, auto-stereoscopic displays do not need to be worn with glasses. The more commonly used method is parallax barrier or lenticular lens to make the left eye look only. To the left eye image, and the right eye to see the right eye image, spatial multiplexed. Figure 1 shows a conventional fixed parallax barrier. A parallax barrier 2 is set to φ placed in front of the 2D image display 4, and the viewer does not need to wear the auxiliary glasses. Due to the presence of the parallax barrier 2, the left eye only sees the left eye image l, while the right eye only sees! The right eye image R achieves the effect of displaying a stereoscopic image. This conventional fixed parallax barrier is only suitable for fixed 3D imaging and cannot be switched to 2D imaging. A 2D/3D switching type display device is disclosed in U.S. Patent No. 6,046,849. Referring to FIG. 2A, the conventional 2D/3D switching display device 10A includes a liquid crystal display panel u, a backlight module 13, a patterned half-wavelength plate 12, and a switchable rotor (switchabie I380Q54 - rotator). 15 and an outer polarizing plate 14, wherein the patterned half-wave plate 12 is divided into 12B whose optical axis is perpendicular to the optical axis of the outer polarizing plate 14, and 12A which is at an angle with the outer polarizing plate 14. The two states in which the switchable rotor 15 can be switched are: a state of a quarter wave plate and a state in which the polarization of the transmitted light is not affected. When the 3D image is displayed, the switchable rotor 15 is switched to a state that does not affect the polarization of the transmitted light. At this time, the polarization direction of the image passing through 12 people is rotated to pass through the outer polarizing plate 14 and pass through the 12B. The image will be blocked by the outer polarizing plate 14, so that the combination of the half-wavelength plate 12, the switchable rotor 15 and the outer polarizing plate 14 can be regarded as a parallax barrier. When the 2D image is displayed, the switchable rotor 15 is switched to a quarter-wave plate, so that the images of 12 a and 12 B are circularly polarized, and the external polarizing plate 14 can be used to achieve 2D development. Fig. 2B is a schematic view showing another conventional 2D/3D switching type display device. The structure is similar to 2 A except that the switchable rotor 15 in 2 A is replaced with a switchable diffuser 16. Switching the switchable diffuser 16 electrically to achieve 3D/2D image

• 顯示。上述可切換式擴散板16可以切換的兩種狀態,分別 是··散射的狀態(scattering state)和對穿透光偏振沒影響的 狀態。當顯示3D影像時,可切換式擴散板16切換為對穿 透光偏振沒影響的狀態,此時通過12A之影像之偏振方向 會被旋轉而通過外偏振板14,而經過12B之影像將被外偏 振板14阻擋,因此二分之一波長板12、可切換式擴散板 16及外偏振板14之組合可視為一視差屏障。當顯示2D影 像時,可切換式擴散板16切換為散射狀態,讓經過12A 7 Ι38〇ΰ54 -與12Β❺影像偏振被打氣變成隨機態(random),使部份影 像可經過外偏振板14 ’達到2D顯像效果。 【發明内容】 本發明提供-種液晶控制的圖案化光閥,#由圖案化 •之極性(polar)電極層吸附配向物質,在電場施加與否的作 訂,造案化之區域之光線通過與不通過,產生視差 屏障之功能開啟或關閉,搭配二維影像的顯示器模組,可 Φ 以達到影像切換的功能。 【實施方式】 第3A和3B圖分別顯示本發明之影像切換裝置於電壓 關與開狀態的剖面示意圖。 第3A圖為本發明之光閥a區'域與b區域分別呈現暗_ 党狀態。圖案化的光電開關元件100包括一第一基板110 與一第二基板130。一第一電極112全面性地形成於第一 籲基板110上,一第二電極132全面性地形成於第二基板13〇 上。第一電極112與第二電極132以氧化銦錫(Indium Tin Oxides, IT0)為例’於區域A經過圖案化表面處理,例如氧 電漿處理(oxygen plasma treatment) ’ 根據參考文獻”Surface modification of indium tin oxide by plasma treatment: An effective method to improve the efficiency, brightness, and reliability of organic light emitting devices” Appl. Phys. Lett. 70, 17, (1997),經過氧電漿處理之氧化銦錫表面的錫 原子濃度降低,氧原子濃度上升,在區域A造成一極性氧 1380054 - 化銦錫(極性ιτο)表面,在氧化銦錫電極層i12、132表面 形成一組多條且間隔排列的「極性電極層」(區域A)及另 一組未經過表面處理的ITO(區域B)。 本實施例之液晶層120為包含負型液晶分子121與配 向物質122的混合溶液,其中配向物質122係為具有極性 - 之材料,例如多面體矽氧烷寡聚物(Polyhedral oligomeric . silsesquioxanes,POSS)或是其衍生物’其會吸附於極性電 極層(區域A),形成本實施例之多條且間隔排列的配向電 φ 極層113、133,較佳係以平行間隔之型態存在,而對液晶 分子121產生配向效果。第3A圖顯示介於配向電極層 113、133之間的液晶分子(區域A)會自然呈現整齊垂直於 上下基板之排列,然而,於區域B ’液晶分子無整齊排列。 為達到光電元件開關效果,在主動光電開關元件的第 一基板110與第二基板130外側貼附光軸相互垂直的偏振 片105和135。由於區域A的液晶層内的液晶分子呈整齊 排列’並不改變入射光的偏振方向,入射光無法通過第二 • 偏振片,因而對觀察者呈現暗態(dark state)。然而,於區 域B,液晶分子混亂排列而改變入射光偏振方向,致使入 射光部分可以通過第二偏振片因而呈現亮態(bright state)。 第3B圖為本實施例之光閥A區域與B區域分別呈現 亮-亮狀態。當施加一大於液晶分子起始電壓(threshold voltage)於電極層112、132上,區域A和B的液晶分子皆 呈整齊平行於上下基板之排列而旋轉入射光之偏振方向, 導致此光電開關元件全部區域都呈現亮態(bright state),即 I380Q54 ' 是區域A與區域B的光線都可以通過,如第3B圖所示。 這種特疋區域讓光線通過與不通過的特性,使其可以作為 視差屏障(parallax barrier)啟用或是關閉之用。 本實施例的光電開關元件可進一步搭配其他型式的光 學板’例如圓形極化偏光板或相位補償膜(phase - compensation film) ’以提升光學效能並因應不同類型的用 . 途。 第4A和4B圖分別顯示本發明另一實施例的影像切換 鲁 裝置於電壓關與開狀態的剖面示意圖。 第4A圖為本實施例之光閥A區域與B區域分別呈現 壳-暗狀態。第4A圖中的影像切換裝置2〇〇的結構實質上 相似於第3A圖中的影像切換裝置1〇〇,不同之處在於,液 日曰層220的材質為主客式液晶(Guest/h〇st liquid crystal)混 合溶液’其包含正型液晶分子221、配向物質222與雙色 性染料(dichroic dye)分子223的混合溶液。 第一電極212與第二電極232的區域A經過表面處理 ❿ 而具有極性電極層於表面區域,且配向物質222會吸附於 極性電極層之表面。本實施例便是形成多條且間隔排列的 配向電極層213、233於上下層之間,較佳係以平行間隔之 型態存在。此時,介於配向電極層213與233間的液晶分 子與雙色性染料自然呈現整齊排列,然而,於區域B,液 晶分子與雙色性染料分子無整齊排列。由於區域A的液晶 層内的液晶分子與雙色性染料分子呈整齊垂直於上下基板 排列,雙色性染料分子並不吸收入射光,即是光線可通過 10 的狀態’因而呈現亮態(bright state)。然而,於區域B,液 晶分子與雙色性染料分子無整齊排列而吸收入射光,即是 光線不可通過的狀態,因而呈現暗態(dark state)。 第4B圖為本實施例之光閥a區域與b區域分別呈現 亮-亮狀態。 富把加一大於液晶分子起始電麼(threshold voltage)於 電極層212、232上,區域A和B的液晶分子與雙色性染 料分子皆呈整齊垂直於上下基板排列而導致此光電開關元 件全部區域都呈現亮態(bright state),即是區域A與區域B 的光線都可以通過,如第4B圖所示。 第5A和5B圖分別顯示本發明另一實施例的影像切換 裝置於電壓關與開狀態的剖面示意圖。第5A圖為本實施 例之光閥A區域與B區域分別呈現暗·亮狀態。影像切換 裝置300包括材質可為聚對苯二曱酸乙二醇酯 (Polyethylene Terephthalate)的第一基板 310 與相同或不同 材質的第二基板330,一圖案化電極層312、332分別形成 於310、330的區域a。配向電極層313、333,分別製作 於電極層312、332之表面。 液晶層320為包含負型液晶分子321與配向物質322 的混合溶液’配向物質322可吸附於區域A上,形成多條 且間隔排列的配向電極層313、333於上下層間,較佳係以 平行間隔之型態存在。介於配向電極層333、313間的液晶 分子自然呈現整齊垂直於上下基板排列,然而,於區域B, 液晶分子無整齊排列。為達到光電元件開關效果,在主動 I380Q54 - 光電開關元件的第一基板310與第二基板330外側貼附光 轴相互垂直的偏振片305和335。由於區域A的液晶分子 呈整齊垂直於上下基板排列,並不改變入射光的偏振方 向,入射光無法通過第二偏振片,因而對觀察者呈現暗態 (dark state)。然而,於區域B ’液晶分子無整齊排列而改變 " 入射光的偏振方向’致使部分光線可以通過第二偏振片因 . 而呈現亮態(bright state)。 第5B圖為本實施例之光閥a區域與B區域分別呈現 φ 亮-亮狀態。 當施加一大於液晶分子起始電壓(thresh〇ld voltage)於 電極層312、332上’區域A的液晶分子呈整齊平行於上 下基板排列而呈現亮態(bright state),此時將造成區域A與 區域B同時呈現亮態,如第5B圖所示。 本實施例的光電開關裝置可進一步搭配其他型式的光 學板,例如圓形極化偏光板或相位補償膜(phase compensation film) ’以提升光學效能並因應不同類型的用 鲁途。 第6A和6B圖為根據本發明之一實施例所製作的視差 屏障正視圖。當作3D影像顯示器的視差屏障(parallax barrier)時,利用多條且間隔排列之配向電極層來配向液晶 分子’並以外加電壓切換兩種狀態,分別為不透光42〇A、 透光420B的暗亮條紋,如圖6A,此為本實施例之光闊用 來當作視差屏障時的狀態;以及整片區域420A和420B皆 透光呈全亮狀態如圖6B,此為本實施例之光閥解除視差屏 (S ) 12 I380Q54 - 障功能時的狀態。 第7A圖顯示本發明之視差屏障之設置位置一。視差屏 障520設置在顯示器模組510和背光源530之間的位置。 由背光源530提供的光線先經過二維影像與三維影像切換 用視差屏障520,再進入顯示器模組510。 • 第7B圖顯示本發明之視差屏障之設置位置二。視差屏 障520設置在顯示器模組510之一側。由背光源530提供 的光線先經過顯示器模組510,再由視差屏障520轉換進 • 入觀看者的眼睛形成3D影像。 本發明各實施例中混於液晶溶液中而形成配向電極層 的多面體矽氧烷寡聚物奈米粒子,也可用其衍生物替換 之。如第8A圖所示的苯乙基的多面體矽氧烷寡聚物 (phenethyl-POSS)、第8B圖所示的八甲基的多面體石夕氧 烧寡聚物(octamethyl-POSS)以及第8C圖所示的2乙胺-3 丙基胺7異丙基取代的多面體矽氧烷寡聚物 ((3-(2-Aminoethyl)-amino)propyl-Hepta-isobutyl substituted • P0SS)等材料。此外,根據參考文獻,Tilted Alignment of MBBA Induced by Short-Chain surfactant” J. Phys. (Paris), 37,1245,(1976)以及”New Electro-Optic Effect in a Room-Temperature Nematic LC^ Phys. Rev. Lett., 25, 1326, (1970)所揭露之内容,此配向物質也可以是非環狀羧酸 (acyclic carboxylic acids)、芳香酸(aromatic acids)等物質。 再者於本發明之實施例,配向物質的含量佔總體液晶層質 量的 0.01%-20%。 1380054 • 基板的材質可以是玻璃基板、或是高分子基板(例如聚 對苯二甲酸乙二醇酯)。電極材料可以是氧化銦錫、氧化銦 鋅(indium zinc oxide)、厚度小於300nm之金屬材料或3,4-乙烯二氧噻吩/聚苯乙烯磺酸 (Poly (3,4-ethylenedioxythiophene) poly (styrenesulfonate))等導 * 電高分子材料。 - 本發明各實施例中的液晶材料的物性並不限定於正型 液晶(positive dielectric isotropy)或負型液晶(negative dielectric isotropy)。再者,驅動液晶元件的電場亦不限定 於垂直電場驅動型,其他水平電場驅動型(如IPS型、FFS 型)皆可應用於本發明。再者,液晶操作模式可為扭轉向 歹|J 型(Twisted Nematic, TN),垂直配向型(Vertical Alignment, VA),水平配向模式(Homogeneous)、混合配向 向列型(Hybrid Aligned Nematic, HAN)、光學補償彎曲型 (Optical Compensated Bend, OCB)或電場控制雙折射型 (Electrically Controlled Birefringence,ECB)皆可應用於本 • 發明。 本發明各實施例中的表面處理方法包含電漿、離子 束、電子束、紫外光照射、電暈放電(Corona Discharge)、 酸蝕(Acid Etching)、表面摩擦以及火燄處理等表面改質處 理,或塗佈一圖案化表面改質層,其表面改質層包括聚亞 醯胺(polyimide),六甲基二矽氮烷(Hexmethyldisilane)或 十八基三氯石夕烧(Octadecyltrichlorosilane)等材料。 本發明雖以實施例揭露如上,然其並非用以限定本發 C £ 14 I380Q54 明的權利範圍,任何本發明所屬技術領域中具有通常知識 者,在不脫離本發明之精神所作的更動與潤飾,均為本發 明所欲保護之範圍。• Display. The two states in which the switchable diffusion plate 16 can be switched are respectively a scattering state and a state in which the polarization of the transmitted light is not affected. When the 3D image is displayed, the switchable diffuser 16 is switched to a state that does not affect the polarization of the transmitted light. At this time, the polarization direction of the image passing through 12A is rotated to pass through the outer polarizing plate 14, and the image after 12B is to be The outer polarizing plate 14 is blocked, so that the combination of the half-wavelength plate 12, the switchable diffusing plate 16, and the outer polarizing plate 14 can be regarded as a parallax barrier. When the 2D image is displayed, the switchable diffuser 16 is switched to a scattering state, so that after 12A 7 Ι 38 〇ΰ 54 - and 12 Β❺ image polarization is aerated into a random state, a portion of the image can be reached through the outer polarizing plate 14 ' 2D imaging effect. SUMMARY OF THE INVENTION The present invention provides a liquid crystal-controlled patterned light valve, in which a polarized electrode layer of a pattern is adsorbed to an alignment substance, and light is applied in an area where the electric field is applied or not. If the function of the parallax barrier is turned on or off, the display module with the two-dimensional image can be Φ to achieve the image switching function. [Embodiment] Figs. 3A and 3B are schematic cross-sectional views showing the image switching device of the present invention in a voltage off state and an on state, respectively. Fig. 3A is a view showing a dark_party state of the area a and the b area of the light valve of the present invention. The patterned photoelectric switching element 100 includes a first substrate 110 and a second substrate 130. A first electrode 112 is formed on the first substrate 110 in a comprehensive manner, and a second electrode 132 is formed on the second substrate 13A in a comprehensive manner. The first electrode 112 and the second electrode 132 are exemplified by Indium Tin Oxides (IT0), which is subjected to a patterned surface treatment in the region A, such as an oxygen plasma treatment 'according to the reference'. Indium tin oxide by plasma treatment: An effective method to improve the efficiency, brightness, and reliability of organic light emitting devices" Appl. Phys. Lett. 70, 17, (1997), the surface of indium tin oxide treated by oxygen plasma The concentration of tin atoms decreases, the concentration of oxygen atoms rises, and a polar oxygen 1380054 - indium tin (polar ιτο) surface is formed in region A, and a plurality of spaced-apart "polar electrodes" are formed on the surface of the indium tin oxide electrode layers i12, 132. Layer" (Zone A) and another set of ITO (Zone B) that have not been surface treated. The liquid crystal layer 120 of the present embodiment is a mixed solution containing the negative liquid crystal molecules 121 and the alignment material 122, wherein the alignment material 122 is a material having polarity - such as polyhedral oligomeric silsesquioxanes (POSS). Or a derivative thereof which is adsorbed to the polar electrode layer (region A) to form a plurality of spaced-apart aligning electrical φ pole layers 113, 133 of the present embodiment, preferably in a parallel spaced configuration. An alignment effect is produced on the liquid crystal molecules 121. Fig. 3A shows that the liquid crystal molecules (region A) interposed between the alignment electrode layers 113, 133 naturally appear aligned neatly to the upper and lower substrates, however, the liquid crystal molecules are not aligned in the region B'. In order to achieve the photoelectric element switching effect, polarizing plates 105 and 135 whose optical axes are perpendicular to each other are attached to the outside of the first substrate 110 and the second substrate 130 of the active photoelectric switching element. Since the liquid crystal molecules in the liquid crystal layer of the region A are arranged neatly, the polarization direction of the incident light is not changed, and the incident light cannot pass through the second polarizing plate, thereby presenting a dark state to the observer. However, in the region B, the liquid crystal molecules are disorderly arranged to change the polarization direction of the incident light, so that the incident light portion can pass through the second polarizing plate and thus exhibit a bright state. In Fig. 3B, the light valve A area and the B area of the present embodiment respectively show a bright-light state. When a threshold voltage greater than the threshold voltage of the liquid crystal molecules is applied to the electrode layers 112, 132, the liquid crystal molecules of the regions A and B are aligned parallel to the arrangement of the upper and lower substrates to rotate the polarization direction of the incident light, resulting in the photoelectric switching element. All areas are in a bright state, that is, I380Q54' is the light of both area A and area B, as shown in Figure 3B. This characteristic area allows light to pass and fail, allowing it to be enabled or disabled as a parallax barrier. The photoelectric switching element of this embodiment can be further combined with other types of optical plates 'e.g., circularly polarized polarizing plates or phase-compensation films' to enhance optical performance and to respond to different types of applications. 4A and 4B are cross-sectional views showing the image switching device in a voltage off state and an on state, respectively, according to another embodiment of the present invention. Fig. 4A is a view showing a shell-dark state of the light valve A area and the B area of the present embodiment, respectively. The structure of the image switching device 2A in FIG. 4A is substantially similar to the image switching device 1 in FIG. 3A, except that the material of the liquid corrugated layer 220 is a guest crystal (Guest/h).混合st liquid crystal) A mixed solution containing a mixed solution of a positive liquid crystal molecule 221, an alignment substance 222, and a dichroic dye molecule 223. The region A of the first electrode 212 and the second electrode 232 is surface-treated to have a polar electrode layer in the surface region, and the alignment substance 222 is adsorbed on the surface of the polar electrode layer. In this embodiment, a plurality of spaced-apart alignment electrode layers 213, 233 are formed between the upper and lower layers, preferably in a parallel spaced pattern. At this time, the liquid crystal molecules interposed between the alignment electrode layers 213 and 233 and the dichroic dye are naturally arranged neatly, however, in the region B, the liquid crystal molecules and the dichroic dye molecules are not aligned. Since the liquid crystal molecules in the liquid crystal layer of the region A are aligned with the dichroic dye molecules perpendicularly to the upper and lower substrates, the dichroic dye molecules do not absorb the incident light, that is, the light can pass through the state of 10' and thus present a bright state. . However, in the region B, the liquid crystal molecules and the dichroic dye molecules are not aligned to absorb the incident light, that is, the state in which the light is impermeable, and thus the dark state is exhibited. In Fig. 4B, the light valve a area and the b area of the present embodiment respectively show a bright-light state. The rich one is greater than the threshold voltage of the liquid crystal molecules on the electrode layers 212, 232, and the liquid crystal molecules of the regions A and B and the dichroic dye molecules are aligned perpendicularly to the upper and lower substrates, resulting in all of the photoelectric switching elements. The regions all show a bright state, that is, the light of both region A and region B can pass, as shown in Fig. 4B. 5A and 5B are cross-sectional views showing the image switching device according to another embodiment of the present invention in a voltage off state and an on state, respectively. Fig. 5A shows a light-bright state of the light valve A area and the B area, respectively, in the present embodiment. The image switching device 300 includes a first substrate 310 made of polyethylene terephthalate and a second substrate 330 of the same or different materials. A patterned electrode layer 312 and 332 are respectively formed at 310. , area a of 330. The alignment electrode layers 313 and 333 are formed on the surfaces of the electrode layers 312 and 332, respectively. The liquid crystal layer 320 is a mixed solution containing the negative liquid crystal molecules 321 and the alignment material 322. The alignment material 322 can be adsorbed on the region A, and a plurality of spaced-apart alignment electrode layers 313 and 333 are formed between the upper and lower layers, preferably in parallel. The type of interval exists. The liquid crystal molecules interposed between the alignment electrode layers 333 and 313 are naturally aligned neatly perpendicular to the upper and lower substrates, however, in the region B, the liquid crystal molecules are not aligned. In order to achieve the photoelectric element switching effect, polarizing plates 305 and 335 whose optical axes are perpendicular to each other are attached to the outside of the first substrate 310 and the second substrate 330 of the active I380Q54 - photoelectric switching element. Since the liquid crystal molecules of the region A are aligned perpendicularly to the upper and lower substrates, the polarization direction of the incident light is not changed, and the incident light cannot pass through the second polarizing plate, thereby presenting a dark state to the observer. However, the liquid crystal molecules in the region B' are not aligned and change "the polarization direction of the incident light' so that part of the light can pass through the second polarizer to present a bright state. In Fig. 5B, the light valve a area and the B area of the present embodiment respectively exhibit a φ bright-bright state. When a liquid crystal molecule which is larger than the liquid crystal molecule starting voltage (Thresh〇ld voltage) on the electrode layer 312, 332 is aligned in parallel with the upper and lower substrates to exhibit a bright state, the region A will be caused. Simultaneously appearing with region B, as shown in Figure 5B. The photoelectric switch device of this embodiment can be further combined with other types of optical plates, such as circularly polarized polarizers or phase compensation films, to enhance optical performance and to respond to different types of use. 6A and 6B are elevational views of a parallax barrier made in accordance with an embodiment of the present invention. When used as a parallax barrier for a 3D image display, a plurality of spaced-apart alignment electrode layers are used to align liquid crystal molecules with two voltage-switching states: opaque 42 〇 A, light 420 B The dark light stripe is as shown in FIG. 6A, which is the state when the light width is used as the parallax barrier; and the whole area 420A and 420B are all light-transmitted and fully illuminated as shown in FIG. 6B, which is the embodiment. Light valve release parallax screen (S) 12 I380Q54 - Status when the function is disabled. Fig. 7A shows the position 1 of the parallax barrier of the present invention. The parallax barrier 520 is disposed at a position between the display module 510 and the backlight 530. The light provided by the backlight 530 is first passed through the parallax barrier 520 for switching the two-dimensional image and the three-dimensional image, and then enters the display module 510. • Fig. 7B shows the setting position 2 of the parallax barrier of the present invention. The parallax barrier 520 is disposed on one side of the display module 510. The light provided by backlight 530 passes through display module 510 and is then converted into a viewer's eye by parallax barrier 520 to form a 3D image. The polyhedral siloxane oligomer nanoparticles which are mixed in the liquid crystal solution to form the alignment electrode layer in each embodiment of the present invention may also be replaced by derivatives thereof. a polyhedral alkane oligo (phenethyl-POSS) of phenethyl group shown in Fig. 8A, a polyhedral oxy-oxyl octet (octamethyl-POSS) of octamethyl group shown in Fig. 8B, and 8C The material shown in the figure is 2 ethylamine-3 propylamine 7 isopropyl substituted polyhedral alkoxysilane oligomer ((3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted • P0SS). In addition, according to the reference, Tilted Alignment of MBBA Induced by Short-Chain surfactant" J. Phys. (Paris), 37, 1245, (1976) and "New Electro-Optic Effect in a Room-Temperature Nematic LC^ Phys. Rev In Lett., 25, 1326, (1970), the alignment material may also be acyclic carboxylic acids, aromatic acids, and the like. Further in the embodiment of the invention, the content of the alignment material is from 0.01% to 20% by mass of the total liquid crystal layer. 1380054 • The material of the substrate can be a glass substrate or a polymer substrate (for example, polyethylene terephthalate). The electrode material may be indium tin oxide, indium zinc oxide, a metal material having a thickness of less than 300 nm or a poly(3,4-ethylenedioxythiophene) poly (styrenesulfonate). )) isometric * electrical polymer material. - The physical properties of the liquid crystal material in the respective embodiments of the present invention are not limited to a positive dielectric isotropy or a negative dielectric isotropy. Further, the electric field for driving the liquid crystal element is not limited to the vertical electric field driving type, and other horizontal electric field driving type (e.g., IPS type, FFS type) can be applied to the present invention. Furthermore, the liquid crystal operation mode can be Twisted Nematic (TN), Vertical Alignment (VA), Homogeneous, Hybrid Aligned Nematic (HAN). Optical Compensated Bend (OCB) or Electrostatically Controlled Birefringence (ECB) can be applied to this invention. The surface treatment method in each embodiment of the present invention includes surface modification treatments such as plasma, ion beam, electron beam, ultraviolet light irradiation, corona discharge, acid etching, surface friction, and flame treatment. Or coating a patterned surface modifying layer, the surface modifying layer comprising a material such as polyimide, Hexmethyldisilane or Octadecyltrichlorosilane. The present invention has been disclosed in the above embodiments, but it is not intended to limit the scope of the present invention, and any one of ordinary skill in the art to which the present invention pertains can be modified and retouched without departing from the spirit of the invention. All are within the scope of the invention to be protected.

< S ) 15 I380Q54 【圖式簡單說明】 第1圖係顯示傳統的固定型視差屏障; 第2A圖係傳統的2D/3D切換型顯示器裝置; 第2B圖係另一傳統的2D/3D切換型顯示器; 第3A和3B圖分別顯示本發明之一實施例的圖案化的 光電開關裝置於電壓關與開狀態的剖面示意圖; 第4A和4B圖分別顯示本發明另一實施例的圖案化的 | 光電開關裝置於電壓關與開狀態的剖面示意圖; 第5A和5B圖分別顯示本發明另一實施例的圖案化的 光電開關裝置於電壓關與開狀態的剖面示意圖; 第6A和6B圖為根據本發明之一實施例所製作的視差 屏障正視圖; 第7A圖顯示本發明之視差屏障之設置位置一; 第7B圖顯示本發明之視差屏障之設置位置二;。 第8A、8B和8C圖分別顯示本發明各實施例中的奈米 φ 粒子化學結構。 【主要元件符號說明】 習知部分(第1〜2B圖) 2〜視差屏障; 4〜2D影像顯示器;< S ) 15 I380Q54 [Simple description of the drawing] Fig. 1 shows a conventional fixed type parallax barrier; Fig. 2A shows a conventional 2D/3D switching type display device; Fig. 2B shows another conventional 2D/3D switching Type 3D and 3B are respectively schematic cross-sectional views showing a patterned photoelectric switch device in a voltage off state and an open state according to an embodiment of the present invention; FIGS. 4A and 4B are respectively showing patterned patterns according to another embodiment of the present invention; FIG. 5A and FIG. 5B are cross-sectional views showing the patterned photoelectric switchgear according to another embodiment of the present invention in a voltage off state and an open state, respectively; FIGS. 6A and 6B are diagrams. A front view of a parallax barrier made in accordance with an embodiment of the present invention; FIG. 7A shows a set position 1 of the parallax barrier of the present invention; and FIG. 7B shows a set position 2 of the parallax barrier of the present invention; Figures 8A, 8B and 8C show the chemical structures of the nanoparticles φ in the respective embodiments of the present invention. [Description of main component symbols] Conventional part (Fig. 1~2B) 2~ Parallax barrier; 4~2D image display;

El〜觀看者的左眼,El ~ viewer's left eye,

Er〜觀看者的右眼, < S ) 16 1380054 10A、10B〜傳統2D/3D切換型顯示器裝置; 11〜液晶顯不器面板; 12〜圖案化二分之一波長板; 13〜背光模組; 14〜外偏振板; 15〜可切換式轉子(switchable rotator); 16〜可切換式擴散板(switchable diffuser)。 • 本案部分(第3A〜7B圖) 100、200、300〜圖案化光電開關元件; 105和135、305和335〜偏振板; 110、210、310〜第一基板; 112、 212、312〜第一電極層; 113、 133、213、233、313、333〜配向電極層; 120、 220、320〜液晶層; 121、 321〜負型液晶分子; • 122、222、322〜配向物質; 130、230、330〜第二基板; 132、232、332〜第二電極層; 221〜正型液晶分子; 223〜雙色性染料(dichroic dye); A〜區域A, B〜區域B ; 500A、500B〜2D/3D影像切換型顯示器裝置;Er ~ viewer's right eye, < S ) 16 1380054 10A, 10B ~ traditional 2D / 3D switching display device; 11 ~ liquid crystal display panel; 12 ~ patterned half-wave plate; 13 ~ backlight mode Group; 14~ outer polarizing plate; 15~ switchable rotator; 16~ switchable diffuser. • This part (Figs. 3A to 7B) 100, 200, 300~ patterned photoelectric switching elements; 105 and 135, 305 and 335 to polarizing plates; 110, 210, 310 to first substrate; 112, 212, 312~ An electrode layer; 113, 133, 213, 233, 313, 333~ alignment electrode layer; 120, 220, 320~ liquid crystal layer; 121, 321~ negative liquid crystal molecule; • 122, 222, 322~ alignment material; 230, 330~ second substrate; 132, 232, 332~ second electrode layer; 221~positive liquid crystal molecule; 223~ dichroic dye; A~ area A, B~ area B; 500A, 500B~ 2D/3D image switching type display device;

17 1380054 510〜顯示器模組; 520〜圖案化光電開關元件; 420A、420B〜圖案化光電開關元件100的區域A和B ; 530〜背光源。 (S ) 1817 1380054 510 ~ display module; 520 ~ patterned photoelectric switching element; 420A, 420B ~ patterned photoelectric switch element 100 areas A and B; 530 ~ backlight. (S ) 18

Claims (1)

1380054 修正本 包含: 第 97119335 號 十、申請專利範圍 1. 種一維影像與三維影像切翻視差屏障, -第-基板’具有—電極層安置於其上; 一第一基板,具有一電極層安置於其上; -配向物質混合液晶分子,安置於前述之第—和第二基板 之間;1380054 Amendment includes: No. 97119335 X. Patent application scope 1. One-dimensional image and three-dimensional image cut-off parallax barrier, - the first substrate 'with electrode layer disposed thereon; a first substrate with an electrode layer Arranging thereon; - aligning materials to mix liquid crystal molecules, disposed between the first and second substrates; 極〖生電極層女置於前述電極層表面,且前述之配向物質 吸附於前述之極性電極層上,以形成—配向電極; 一第一組多條且間隔排列之配向電極,安置於第一基板内 側; -第二組多條且間隔排狀配向電極,安置於第二基板内 側,且與前述之第一組間隔排列之配向電極,—對應安置, 其中 &amp; 。别述配向物質混合液晶分子位於前述配向電極所在之第 一區域且位於前述配向電極以外之第二區域; 剛述之配向電極帶動前述第一區域之複數個液晶分子呈 現第一狀態之排列;以及 ^當前述之電極層施加電壓時,前述第一區域與第二區域之 複數個液晶分子呈現第二狀態之排列。 2. 如申请專利範圍第1項所述之二維影像與三維影像切 換用視差屏障,更包含: 一第一偏光片,安置於所述之第一基板之外側;以及 一第二偏光片’安置於所述之第二基板之外側。 3. 如申請專利範圍第1項所述之二維影像與三維影像切 19 第 97119335 號 修正本 換用視差屏障’更包含: 一染料分子’摻雜於前述之液晶分子與配向物質中。 換用轉利範㈣1項所述之與三維影像切 ^ 手’其中所述之電極層,係選自於下述族群t的一 種:氧化銦錫、氧化銦鋅、厚度小於300nm之金屬材料、以 ^ 3,4-乙烯二氧噻吩/聚苯乙烯磺酸 /〇ly(3,4_ethylenedi〇xythiophene)㈣咖刪祕耶 而分子0 5_如申請專·圍第丨項所述之二維影像與三維影像切 換用視差屏障,其中騎之極性電_,係·表面處理方法 直接對電極層之表面改質所獲得者。 6. 如申請專利範圍第5項所述之二維影像與三維影像切 換用視差聯’其中該表面處理方法係選自於下述族群中的一 種,電漿、離子束、電子束、紫外光照射、㈣放電(c_a Discharge)、酸蝕(Acid Etching)、表面摩擦以及火燄處理。 7. 如申請專利範圍第5項所述之二維影像與三維影像切 換用視差屏障,其中該表面處理方法係塗佈一表面改質層,且 其中該表面改質層係選自於下述族群中的一種:聚亞醯胺 (polyimide)、六甲基二石夕氮烧(Hexmethyldisilane)以及十八基三 氣石夕烧(Octadecyltrichlorosilane)等材料。 8. 如申請專利範圍第1項所述之二維影像與三維影像切 換用視差屏障’其中所述之配向物質係選自於下述族群中的一 種·多面體石夕氡烧寡聚物(polyhedral oligomeric silsesquioxanes, POSS)、含苯乙基的多面體石夕氧烧寡聚物(phenethyl-P〇SS)、 20 1380054 第97119335號 修正日期:101.10.16 修正本 含八曱基的多面體矽氧烧寡聚物(〇ctamethyl p〇ss)、2乙胺_3 丙基胺7異丙基取代的多面體矽氧烷寡聚物 (3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS、非環狀羧酸(acyciic carb〇xylic adds)、以及芳香酸 (aromatic acids)。 9. 一種二維影像與三維影像切換裝置,包含: 一顯不器模組,根據一輸入訊號以顯示一影像;以及 φ 一二維影像與三維影像切換用視差屏障,包括: 一第一基板,且一電極層安置於其上; 一第二基板,且一電極層安置於其上; 一配向物質混合液晶分子,安置於前述之兩組基板之間; -極性電極層安置於前述電極層表面,且前述之配向物質 吸附於前述之極性電極層上,形成配向電極; 、 第一組多條且間隔排列之配向電極,安置於第一基板 侧; 鲁第二組多條j_間隔排列之配向電極,安置於第二基板内 侧’且與前述之第一組間隔排列之配向電極,一—對應安置, 其中 &amp; i述配向物質⑨合液晶分子位於前述配向電極所在之第 -區域且位於前述配向電極以外之第二區域; 前述第一區域之複數個液晶分子呈 前述之配向電極帶動 現第一狀態之排列;以及 複數與第,之 21 1380054 第 97119335 號 修正日期:101.10.16 修正本 1〇.如中請專利範圍第9項所述之二維影像與三維影 換裝置,更包含: :弟一偏光片,安置於所述之第一基板之外侧;以及 一第二偏光片,安置於所述之第二基板之外側。 ㈣L1.如中請專概㈣9項所叙二維縣與三維影像切 換裒置’更包含: 木料刀子,摻雜於前述之液晶分子與配向物質中。The electrode layer is disposed on the surface of the electrode layer, and the foregoing alignment material is adsorbed on the polar electrode layer to form an alignment electrode; a first plurality of spaced-apart alignment electrodes are disposed in the first The inside of the substrate; a second plurality of spaced-apart alignment electrodes disposed on the inner side of the second substrate, and correspondingly arranged with the first group of the alignment electrodes arranged in the foregoing, wherein &amp; The aligning substance mixing liquid crystal molecules are located in a first region where the alignment electrode is located and located in a second region other than the alignment electrode; the alignment electrode just described drives the plurality of liquid crystal molecules of the first region to exhibit a first state arrangement; When a voltage is applied to the electrode layer, the plurality of liquid crystal molecules of the first region and the second region exhibit an arrangement of the second state. 2. The parallax barrier for two-dimensional image and three-dimensional image switching according to claim 1, further comprising: a first polarizer disposed on an outer side of the first substrate; and a second polarizer And disposed on an outer side of the second substrate. 3. The two-dimensional image and the three-dimensional image cut as described in claim 1 of the patent application No. 97119335, the replacement of the parallax barrier 'includes: a dye molecule' is doped into the aforementioned liquid crystal molecules and the alignment material. The electrode layer described in the following description is directed to one of the following groups t: indium tin oxide, indium zinc oxide, metal material having a thickness of less than 300 nm, ^ 3,4-ethylenedioxythiophene/polystyrenesulfonic acid/〇ly(3,4_ethylenedi〇xythiophene) (4) coffee deletion and numerator 0 5_ as applied for the two-dimensional image described in the article A parallax barrier for three-dimensional image switching, in which the polar polarity of the riding, the surface treatment method directly obtains the surface modification of the electrode layer. 6. The parallax for 2D image and 3D image switching as described in claim 5, wherein the surface treatment method is selected from one of the following groups: plasma, ion beam, electron beam, ultraviolet light Irradiation, (c) discharge (c_a Discharge), acid etching (Acid Etching), surface friction, and flame treatment. 7. The parallax barrier for two-dimensional image and three-dimensional image switching according to claim 5, wherein the surface treatment method applies a surface modification layer, and wherein the surface modification layer is selected from the following One of the ethnic groups: polyimide, Hexmethyldisilane, and Octadecyltrichlorosilane. 8. The parallax barrier for two-dimensional image and three-dimensional image switching as described in claim 1, wherein the alignment substance is selected from one of the following groups: polyhedral polyhedral (polyhedral) Isomorphic silsesquioxanes, POSS), phenethyl-containing polyhedral oxime-oxygen oligo (phenethyl-P〇SS), 20 1380054 No. 97119335 Revised: 101.10.16 Amendment to the polyhedral oxime Polymer (〇ctamethyl p〇ss), 2 ethylamine _3 propylamine 7 isopropyl substituted polyhedral oxyalkylene oligomer (3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS, Acyciic carb〇xylic adds, and aromatic acids. 9. A two-dimensional image and three-dimensional image switching device, comprising: a display module, displaying an image according to an input signal; and φ a parallax barrier for two-dimensional image and three-dimensional image switching, comprising: a first substrate And an electrode layer disposed thereon; a second substrate, and an electrode layer disposed thereon; an alignment material mixing liquid crystal molecules disposed between the two sets of substrates; - a polar electrode layer disposed on the electrode layer a surface, and the foregoing alignment material is adsorbed on the polar electrode layer to form a alignment electrode; and a plurality of first and spaced alignment alignment electrodes are disposed on the first substrate side; The alignment electrode is disposed on the inner side of the second substrate and is disposed correspondingly to the alignment electrode of the first group, wherein the alignment liquid 9 molecules are located at the first region where the alignment electrode is located and a second region other than the alignment electrode; the plurality of liquid crystal molecules in the first region are in the first state by the alignment electrode Columns; and plural and the first, 21 1380054, No. 97119335, date of amendment: 101.10.16 Amendment to this paragraph. The two-dimensional image and three-dimensional image changing device described in item 9 of the patent scope, including: a polarizer disposed on an outer side of the first substrate; and a second polarizer disposed on an outer side of the second substrate. (4) L1. For example, please refer to the two-dimensional county and three-dimensional image switching device in the 9th item. The more includes: Wood knife, doped in the aforementioned liquid crystal molecules and alignment materials. 拖駐12.如申請專利範圍第9項所述之二維影像與三維影像切 才、其中該顯不器模組包括—背光模組以及—顯示器岛 八中°亥一維影像與三維影像切換用視差屏障設置於該背光 模組與該顯示器面板之間。 另I3.如申請專利範圍第9項所述之二維影像與三維影像切 換破置,其中該顯示器模組包括一背光模組以及一顯示器面 ^其中該顯不器面板設置於該背光模組與該二維影像與三維 影像切換用視差屏障之間。 14.如申請專利範圍第9項所述之二維影像與三維影像切 換裝置’其中所述之電極層,係選自於下述族群中的一種:氣 化鋼锡、氧化銦鋅、厚度小於300nm之金屬材料、以及3,4、 乙烯二氧噻吩 / 聚苯乙烯磺醆 (Poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate))導電 高分子。 15.如申請專利範圍第9項所述之二維影像與三維影像切 換裝置’其中所述之極性電極層,係利用表面處理方法直接對 電極層之表面改質所獲得者。 22 1380054 第97119335號 修正日期:101.10.16 修正本 16. 如申請專利範圍第15項所述之二維影像與三維影像 切換裝置’其中該表面處理方法係選自於下述族群中的一種: 電漿、離子束、電子束、紫外光照射、電暈放電(C〇rona Discharge)、酸餘(Acid Etching)、表面摩擦以及火敲處理。 17. 如申請專利範圍第15項所述之二維影像與三維影像 切換裝置’其令該表面處理方法係塗佈一表面改質層,且其中 表面改質層係選自於下述族群中的一種:聚亞II胺 鲁 (polyimide)、六甲基二石夕氮烧(Hexmethyldisilane)以及十八基三 氣矽烧(Octadecyltrichlorosilane)等材料。 18. 如申請專利範圍第9項所述之二維影像與三維影像切 換裝置’其中所述之配向物質係選自於下述族群中的一種:多 面體石夕氧烧寡聚物(polyhedral oligomeric silsesquioxanes, poss)、含苯乙基的多面體矽氧烷寡聚物(phenethyl_P0SS)、 含八甲基的多面體石夕氧烧寡聚物(〇ctamethyi_p〇ss)、2乙胺-3 丙基胺7異丙基取代的多面體矽氧烷募聚物 # (3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS、非環狀敌酸(acyclic carboxylic acids)、以及芳香酸 (aromatic acids)。 19. 一種液晶光閥,包含: 第一電極層; 第二電極層,與前述之第一電極層,對應安置; 配向物質混合液晶分子,安置於前述之兩組電極層之間; 一極性電極層安置於前述之電極層表面,且前述之配向物 質吸附於前述之極性電極層上,形成配向電極,其中 23 1JOUUJ4 第 97119335 號 修正日期:101.10.10 ,* τ , -區合液晶分子位於前述配向電極所在之第 &amp;域且位於則述配向電極以外之第二區域;以及 前=配:電極帶動前述第一區域之複數個液晶分子呈 現弟一狀態之排列。 、、2〇·如申°月專利圍第19項所述之液晶光閥,其中,所 述之電極層施加電壓日卑,治_ +,哲 T別述弟一區域與弟二區域之複數個液 日日y刀子呈現第二狀態之排列。Drag and drop 12. The two-dimensional image and the three-dimensional image cut according to claim 9 of the patent application scope, wherein the display module includes a backlight module and a display island eight-dimensional one-dimensional image and three-dimensional image switching A parallax barrier is disposed between the backlight module and the display panel. The I2. The two-dimensional image and the three-dimensional image switching device described in claim 9 include a backlight module and a display surface. The display panel is disposed on the backlight module. Between the two-dimensional image and the parallax barrier for three-dimensional image switching. 14. The two-dimensional image and three-dimensional image switching device according to claim 9, wherein the electrode layer is selected from one of the group consisting of: vaporized steel tin, indium zinc oxide, and thickness less than 300 nm metal material, and 3,4, ethylene (3,4-ethylenedioxythiophene) poly (styrenesulfonate) conductive polymer. 15. The two-dimensional image and three-dimensional image switching device according to claim 9 of the invention, wherein the polar electrode layer is obtained by directly modifying the surface of the electrode layer by a surface treatment method. </ RTI> </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Plasma, ion beam, electron beam, ultraviolet light irradiation, corona discharge (C〇rona Discharge), acid residue (Acid Etching), surface friction, and fire knocking treatment. 17. The two-dimensional image and three-dimensional image switching device of claim 15, wherein the surface treatment method is coated with a surface modifying layer, and wherein the surface modifying layer is selected from the group consisting of One type: polyimine, hexamethyl hexahydrate (Hexmethyldisilane) and octadecyl trichlorosilane (Octadecyltrichlorosilane) and other materials. 18. The two-dimensional image and three-dimensional image switching device of claim 9, wherein the alignment material is selected from one of the group consisting of: polyhedral oligomeric silsesquioxanes , poss), phenethyl-containing polyhedral alkane oligo (phenethyl_P0SS), octamethyl-containing polyhedral oxalate oligomer (〇ctamethyi_p〇ss), 2 ethylamine-3 propylamine 7 Propyl-substituted polyhedral alkoxylates #(3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS, acyclic carboxylic acids, and aromatic acids. 19. A liquid crystal light valve comprising: a first electrode layer; a second electrode layer disposed corresponding to the first electrode layer; an alignment substance mixing liquid crystal molecules disposed between the two sets of electrode layers; The layer is disposed on the surface of the electrode layer, and the aligning substance is adsorbed on the polar electrode layer to form a aligning electrode, wherein 23 1JOUUJ4 No. 97119335 is amended: 101.10.10, * τ, - the merging liquid crystal molecule is located in the foregoing The first &amp; field of the alignment electrode is located in a second region other than the alignment electrode; and the front/distribution: the electrode drives the plurality of liquid crystal molecules in the first region to exhibit an arrangement of the states. The liquid crystal light valve of claim 19, wherein the electrode layer is applied with a voltage, and the _T, Zhe T, the plural of the region and the second region The liquid y knife shows the arrangement of the second state. 21•如中請專利範圍第19項所述之液晶光閥,其中所述 之配向電極,係以平行間隔之型態存在。 22.如申請專利範圍第Θ項所述之液晶光閥,其中所述 之極f生電極層’係利用表面處理方法直接對電極之表面改質所 獲得者。 ' 23. 如申請專利範圍第22項所述之液晶光閥,其中該表 面處理方法,係選自於下述族群中的一種:電漿、離子束、電 子束、备'外光照射、電暈放電(c〇r〇na Discharge)、酸触(Acid # Etching)、表面摩擦以及火燄處理。 24. 如申請專利範圍第22項所述之液晶光閥,其中該表 面處理方法係塗佈一表面改質層,且其中表面改質層係選自於 下述族群中的一種:聚亞醯胺(p〇lyimide)、六曱基二矽氮烷 (Hexmethyldisilane)以及十八基三氣矽烷 (Octadecyltrichlorosilane)等材料。 25_如申請專利範圍第19項所述之液晶光閥,其中所述 之配向物質係選自於下述族群中的一種:多面體矽氧烷寡聚物 (polyhedral oligomeric silsesquioxanes,P0SS)、含苯乙基的多面 24 1380054 第97119335號 修正日期:101.10.16 修正本 體矽氧烧寡聚物(phenethyl-POSS)、含八曱基的多面體矽氧 燒寡聚物(octamethyl-POSS)、2乙胺-3丙基胺7異丙基取代的 多面體石夕氧烧寡聚物(3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS、非環狀缓酸(acyclic carboxylic acids)、以及芳香酸(aromatic acids)。The liquid crystal light valve of claim 19, wherein the alignment electrode is present in a parallel spaced configuration. The liquid crystal light valve according to claim 2, wherein the electrode layer is directly obtained by modifying a surface of the electrode by a surface treatment method. The liquid crystal light valve of claim 22, wherein the surface treatment method is selected from the group consisting of: plasma, ion beam, electron beam, external light irradiation, electricity Halo discharge (c〇r〇na Discharge), acid touch (Acid # Etching), surface friction and flame treatment. 24. The liquid crystal light valve of claim 22, wherein the surface treatment method coats a surface modification layer, and wherein the surface modification layer is selected from one of the group consisting of: polythene Materials such as p〇lyimide, Hexmethyldisilane, and Octadecyltrichlorosilane. The liquid crystal light valve of claim 19, wherein the alignment material is selected from one of the group consisting of: polyhedral oligomeric silsesquioxanes (P0SS), benzene-containing Multifaceted Ethylene 24 1380054 Revision No. 97119335 Revision Date: 101.10.16 Corrected bulk oxime oxy-oligomer (phenethyl-POSS), octadecyl-containing polyhedral oxyalkylene oligomer (octamethyl-POSS), 2 ethylamine -3propylamine 7 isopropyl-substituted polyhedral poly (3-(2-Aminoethyl)-amino) propyl-Hepta-isobutyl substituted POSS, acyclic carboxylic acids, and Aromatic acids. 2525
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