1376355 2012年/月修正替換頁·非劃線版 九、發明說明： 【發明所屬之技術領域】 本發明係有關於一^水質淨化理系統’特別是有關於一種以流通電容器模組 所構成之去除水中離子之系統，可以淨質或是進行海水淡彳_理。 【先前技術】 用於制質之技術甚多’例如轉躲(RO)、離子交換法及電透析法均是。隨 著環保猶高漲’理想纷城瓣了技術本身必須可靠尚需財絲健且 不域污染。就Jl列錄淨7峨術而言’從杖前赋班惙備解蒦均需使用一或多種 化學藥劑，％欠污染謂加絲。電容去離子（CDI)技術則係一鱗環境有利 0·法’因為其较細電力断水質處舰設備維護，财需使耻鞠祕會祕 污染。電容去離子作業包括一流通電容器（FTC)之一連串充、放電過程，其中該流通 電容器雖一正電献一負電極。在該流通電容器之充電酿中，電極 场’而Pjiit過該>7lUi電容器之電;間時，該靜電場可輕易挪休中所子。由於 被吸附之m子將累積在電極表面，因此，若欲連續進行水處理’必須去除累積之離子， 使電極表面再生。在電容去離子作業中為電極充電以去除水中離子所消耗之電能&^。 詳言之’在生產等量、同水質从時，電容德子_消权電量鱗轉槪^分 ’ _^極係_：電方式再生，使吾人不但得以妙用電，尚可回收有用之 離子。因此’電容去離子法實為一財附祕值场倾術，其適麟象缺工業廢水、 絲齡難也下齡、及脉等含有離子林。電容去離子技術之商用可衍生主要取夫 於電容器之離子吸附力及再生之效果。 若與縣触鏡子交換法相比，電容去離子法問世較晚，且其齡水中總雜固 體量之能力尚鮮為从，因此’無鱗界或業界，對電容去離子法之研究均遠少珊逆 滲、離子交換法及電透析法之研究。而電樹如且態與電容去離子法球理能力， 均將影響以電容去離子技術作為一種用於處理多種水體及海水商用方法之成^ 〇 美國專利第5,980,718號揭示商用流通電容器之首例，其祕一由數百對串聯電酬觀 5 1376355 田 2012年/月修正替換頁-非劃線版 找疊體。該項專利係游一直流低電應至各電觸，其電連权複雜度聽㈣高。 猶美國專鄉 6,462^935 號揭; 已大幅簡化，但該流通電容器又面臨^^亏染之問題，尤纟 高離肅術時，交幻亏染之情形更為嚴重。在此情況下，流通電容器謝麵 力將顯著下降，使電容去離子作業之產出大受影響。 由於電容去離爾係透礙通繼其觸之間之，電場去_子，因此， 在流通電容器與一電源之間至少要有兩處電連接，亦即正、負軸子。此一電連接方式 恰為上開美國專利第6,462^號中流通電容器所用u式，其中僅由兩個電概以同心 子。由於該流通電容器係由電1376355 2012/Month Revision Replacement Page·Non-Line Edition 9. Description of the Invention: [Technical Field] The present invention relates to a water purification system, in particular, a flow capacitor module The system for removing ions from water can be cleaned or desalinated. [Prior Art] There are many techniques for quality control, such as transfer avoidance (RO), ion exchange, and electrodialysis. As the environment is still rising, the ideal city must be reliable and still need to be financially healthy and not polluted. As far as Jl is listed, it is necessary to use one or more chemicals from the front of the stick. Capacitance deionization (CDI) technology is advantageous for a scale environment. 0. The law is because the finer power cuts off the water and the ship equipment is maintained, and the financial needs make the shame secret. The capacitive deionization operation includes a series of charging and discharging processes of a flow capacitor (FTC), wherein the circulating capacitor positively supplies a negative electrode. In the charging of the flow capacitor, the electrode field 'Pjiit' passes through the power of the > 7lUi capacitor; during the interval, the electrostatic field can be easily moved. Since the adsorbed m will accumulate on the surface of the electrode, if the water treatment is to be continuously performed, it is necessary to remove the accumulated ions and regenerate the surface of the electrode. Charging the electrode in a capacitive deionization operation to remove the electrical energy & In detail, when the production is equal, the water quality is the same, the capacitor dezi _ 消 电量 电量 槪 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电 电. Therefore, the capacitive deionization method is a kind of secret value field field surgery, and it is suitable for industrial wastewater, silk age, age, and veins. The commercial derivatization of capacitive deionization technology is mainly based on the ion adsorption and regeneration effects of capacitors. Compared with the county touch mirror exchange method, the capacitive deionization method is late, and the ability of the total amount of solid solids in the water is still very small. Therefore, there is little research on the capacitive deionization method. Studies on reverse osmosis, ion exchange and electrodialysis. The electrical tree-like state and the capacitive deionization process will affect the use of capacitive deionization technology as a commercial method for processing a variety of water bodies and seawater. The first example of commercial flow capacitors is disclosed in U.S. Patent No. 5,980,718. , its secret one by hundreds of pairs of electricity rewards view 5 1376355 Tian 2012 / month correction replacement page - non-dash version to find the stack. The patent system has been running low power to all electrical touches, and its electrical connection rights are complex (four) high. The United States, the United States, 6,462^935 unveiled; has been greatly simplified, but the flow capacitors are facing the problem of ^^ loss of dyeing, especially when the high-definition surgery, the situation of cross-terrorism is more serious. Under this circumstance, the passivation force of the circulating capacitor will be significantly reduced, which will greatly affect the output of the capacitor deionization operation. Since the capacitor is separated from the contact between the contacts and the electric field, there must be at least two electrical connections between the circulating capacitor and a power source, that is, positive and negative axes. This electrical connection is just the U type used in the flow capacitors of U.S. Patent No. 6,462, wherein only two of the wires are concentric. Because the flow capacitor is powered
贼緊密織而成，水往往歸留在該捲體内，因而在電容去離_f^業中重之交 叉π染。紐流通電容器之電極快速、有效再生，流通電容器之電錄面需以一淹緘 加以淋洗。此外，並列之流通電容器電極係以一經濟而有效率之方式連接至一電源，但 並非直接連接至該電源；而其餘^通電容器電_由穿過流通電容器電極陣列之水予 以電連接。在瓣細電狀間淑口一電位後’待處理嫩頂端電嫩開始帶電， 使電流開始赫。當電鱗侧達第一居間電極之第二面時，該极第二面將帶有與 頂端電極相同之極性。電極極性在電流/水流穿過電極陣列時同步交變之現象將不斷反 復發生，直到掀親電減出為止。各電獨均具有兩種不同極&:其串聯時跑吏流 通電容器電極成為雙極性電極，並聯時則使流通電容器電極成為單極電極。 雙樹生電極已衛穩用在許多雜不同目的之電化學方法中。舉例而言，雙極性電 秘美國專利第4,043,891號中係用練金屬在電轉作業中均勻_ ;在美國專利第 5322,97號、第6,787,009航第7,018，16號中係用槪學物之電合成;在美國專利第 5,439)77微第5,744,028號中細於权電解消毒;而在「純化學與應用化學撕奶^ andAppliedCto^)⑽）第73冊第號第1819至1837頁中貝j係用槪過再生性 燃料電:¾嫩亍負荷平桃。雙極性電極可財如美國專利第6>224,72〇號^示之可移除 性，而不需夹在兩柄電狀間，餅，雙樹生電極亦可採用__， 利第6306^270號中即為_。雙極J·生電鮮姻不同之電撕料，亦可應用於電容去離 6 1376355 • 2012年，月修正替換頁-非劃線版 子技術，而美國專利第6,788378號即為其中一例，其中電極係採串、並聯混合排列。就 , 電容去離子技術之觀點而言’上開美國專利第6,788378號之缺點在於使用 ： 1電極嫩蝴封。雜崎_ ' 之能懿度甚高，可舰級電容器成為-電能儲存裝置，然此-昂貴材料之電能鱗力 =來自表面编t-额顧，此—_^鋪需軒麵作狀電容德子作業而 έ ’並無助益。耕’外紅電域緣使杨得^^她^，而電流亦有可缺 該等邊緣附近外漏，造成歐姆加熱及其他損害。 因此’有毅先前技點，本發明提出一細於再生流通電容器模組續 • 穎系統及方法，期使電容去離子技術能以工業規模處理工業用水。 【發明内容】 本發明係觸-流通電容器模組之雜。一内雜製電極找成可用鱗成一流通 電，模組，使該模組嫩高之細吏用效率，而電極亦可快速、有效再生。該麵 電雜組可由触紅電_成’且該流通電嫌且可輕易終在新製或喊的水質淨 化設備中。 根躲綱之-主要目的，姚咖1麵力，咖製造流通電^^電献_系 • 選用概表面積爾，例如活_或奈来碳管。觸墙柯織雜合以形成碳 布、或由一適當^齡賴著在一金屬基社、抑或直接形极該金屬綠。此外， &等電極最好具有高透；木性及高導電性。 #_之另_綠目的，働__電極 分布猶有並列级通電容器電極之間。當流通電容器電極財一高導電度時，例如約 ⑽SIQn_或m m電鱗細均郷成一強電場。姐強電場下即可賴 尚離子·έ·|^·率。 本發明之再一主要目的，鑛電概内嵌在一密職牛内以密織通電容器電敗 邊緣，避細爾歡外漏而交妨染⑭理冰。同時，麵流通電容器電極 内錄密_件内之後’流通電容器電極臟可外加猶牛，使流通電容器模組更容 7 1376355 2012年〆月修正替換頁_非劃線版 易製造。 本發明_-主要目的’脊提供一種再生流通電容器電極之方法，其係利用超級電 容器使流通電容器電極快速#生。 目的’本發明首先提洪一種流通電容器（FTC)，係由複數個電極 板以及複數個絕緣件以交錯堆疊成一單體，每一單體配置於一末端電極對之 間’其中複數個電極板、複數個絕緣件以及末端電極對上均形成複數個穿孔。 本發明接著提供-種流通電容器（FTC)模組，包括：一絕緣外殼，具有 一頂端蓋及一底端蓋且以至少一介面板將絕緣外殼區分成複數個單元，其 中頂端蓋、底端蓋以及介面板上均形成複數個穿孔；以及至少一單體係 配置於每-該單元巾’該單體係倾油電極板以及複數個絕緣件以交錯 堆疊而成’且該每-單體之兩端上具一束端電極對，其中該複數個電極板、 該複數個絕緣件以及該末端電極對上均形成複數個穿孔。 本發明再提供一種去除水中離子之水處理系統，挪：一個流通電容器模組，係由 I絕緣外殼以及至少-單體所組成，其帽緣外殼具有―頂端蓋及一底端 蓋且以至少一介面板將絕緣外殼區分成複數個單元，而頂端蓋、底端蓋以 及介面板上均形成複數個穿孔，以及至少一單體，係配置於每一單元中， 單體係由複數個電極板以及複數個絕緣件以交錯堆疊而成，且每一單體之 兩端上具一末端電極對’其中該複數個電極板、該複數個絕緣件以及該末端 電極對上卿成複數個f孔；—1；鱗，肖流; 少一個第一超級電容器’其係連接於電位源與流通電容器模組之間，用於放大電位源^ 供應之電能；至少一個第二超級電容器，其係連接至流通電容器模組，用於接收一來自 流通電容器模組技電電能；一控制器，用於調節水中離子去除率及流通電容器模组之 電能回收與再生。 【實施方式】 以下將說明本義中使雙樹生電撕形成之^通電容器级佳實施例。首先，請 2012年β月修正替換頁-非劃線版 參考第1圖，係根據本發明之流通電容器（100)示意圖。如第1圖所示，流通電容器 (100)由複數個並列且#成一ρ車列之電極（104)、複數個間隔件（106)以及末端電極 對（102'110)所組成’其中末端電極對d〇2、11〇)係分別經由導線（12〇、140)電 性連接至一電源。流通電容器（100)中的電極（104)及末端電;|^對（1Q2、110)為一 種由鎳、不錄鋼或钦等材料成之金屬基體，同時，各金屬基體上均g己置有複數個直 徑1公厘（1 mm)之孔·辦成之圖案，似,】掀中穿過；而此圖案以撒可缺細網 狀、網狀、篩網狀或線網狀等。此外，每一個金屬基體上可進一步塗佈端衣或由其他適 當含碳質材槪材質（例如：活性碳、奈米碳管或碳賴A)或導電金屬氧似勿⑽ 如：、鄭纖、經雜德谈或鄭瞒）所形成之塗層，藉以保護綠屬基 脸麵水中讀子〇 f線續#^第i圖，電極（104)與間_ (1〇6)係交錯堆疊排 列’亦即每-間麟（106)係夾在兩電極（1〇4)之間，以祕電極（1〇4)間形雜 路。電極（104)挪狀可與桃電樹子⑽、110)完全相同，或可由碳布（亦即活 性碳與^鱗之;·邑織物）製成。很明顯地，每一個間隔件（1〇6)可以是一種約〇·6至i公 塑膠或聚邑衡料，而間齡（106)之中間苦剛他可以為細網狀、 網狀、篩網狀或線網狀之圖案。 一直流電位係施滅南^電挺)· (1Q2、110)之間，而私細流經電極(1〇4)之 間。水流在電極⑽）間之電場作用下，將使途中經過之電極（104)帶電。舉例而言， 水係從圖1中舰電容器模組（1〇〇) 蛛^電極（1〇2)流减通電容器模 組（100) ’同時，由負極味^電極⑽）流出流通電容器模組⑽）。當私鋼達 第-中間電極（104)之第-面時，此第—面將會因電職應而形成—負極；而當水流 到中間電極（104)第二面（即相對第—面之另—面）時，則第二面被電場感應而形成 -疏；因此’當和施中間電極（1〇4)時均形成—雙極性之電極〇〇4)，故當 水流不_下穿麟通電容器模組⑽）中的每_個堆疊成蝴^之電極（1〇4)時每 電極（104)均透igj：述^電場感應而形雜倾使务_電極（1〇4)之兩面帶電。在 此同時’隨著減獻聽出备《雙極性電極（1〇4)，電流亦將穿過該流通電容器陣列。 當電容去離子（CDI)作業中使用如圖！所示之流通電容器模組⑽）組態時，其 1376355 2012年/月修正替換頁-非劃線版 至少具有兩項優點.其一，需以電容去離子技術處理之水可直接接觸流通電容器模組 (100)中之每一電極（104)。詳言之，由於電容去離子技術係用帶電電極之表面吸 附離子’藉以減少水中之總溶解固體量（TDS)，因此，水必須接觸電極方可獲得快速 ' 而有效之處理。另外’在電容去離子之過程中，水係以例如重力進洽之方式充滿整個流 ， 通電容器陣列，使電極(104)所有面樹句與;，因而提高流通電容器模組（1〇〇) 之電樹吏用效率，有利於電容去離子處理作業之產出女欠，流通電容器模組〇〇〇) 内之流路直接而無死角或滯留區’因此’水可從流通電容器模組（1〇〇)中輕易流出。 此外’由於電極吸附離子後將快速飽和’因此電極（1〇4)必須經常再生。而電極 再生所面臨之一技鋪卿，丨為交叉污染’且主要源於卡在流通電容器模組（1〇〇)内之 污染物尤其疋在》IL通電谷器模組（1QQ)中之流路長而运迴時，最常發生此一現象。 在一流通電容器模組⑽）中’任兩電極彼此^目對之砂蘇面與負極^面即構成一電 容器。當域水穿過流通電容器模組（1〇〇)時，則水中之陽離子將被吸附至正極表面， 而陰離子則被吸附至負極表面。上述之電容離子吸^寸作用恰為電化學電容器儲存電能之 鶴。在電極（104)之再生赚中，電極（1〇4)係由兩條導線⑽、14〇)連接至一 負载（例如一尚未儲存電敗淹級電容器）以断去觸，而該負削可儲存流通電容 窃楔組(100)之殘餘電能供後續使用。此時尚需利用一敝麟已經去觸德子從 流通電容器模組⑽）中沖走。流通電容器模組（100) ^妨構雜撇液與已去 吸附之離子得以完全排出，因而降低交又污染之可能性。 Z、 _ 應注意的是’減少紅賴至為重要，也因此，本發明使關断⑽）以_ βΜ理冰_電極⑽)間之電場而外狀可能性。錢因為一滴未贿理冰 可污染四饼已制咐，使其翊撕職^細詳。耕，驗亦有可祕雙 電極（1〇4)级物砸著财而流出。此一外紀電流^游「分路電流」，可在 又極性電極(104) 缘產生|^口熱，使的這些邊為流通電容器模組(1⑻)之 熱點，而祕錄飾業之電級率^峻緣魏亦有可能引伽牌， 固體量，妙電絲離子^。 4 接著、月##第2圖’係冰發明欲^麟标射路電流嫌圭實施例，其作法 2012年/月修正替換頁-非劃線版 係將雙極1±電極（104)内嵌在一密封構件（200)中，itbt封構件（200)包括複數條 沿徑向排列之條紋（205)及包圍此等條紋之邊緣密封元件（203)。條紋（205)及邊緣 密封元件（203 )可在單一射出成型製程中同時成型。條紋(205 )及邊緣密封元件（203 ) 可由絕緣材料構成，包括三元乙丙標夥（EPDM)、環氧改性有機石夕樹脂、乙稀一醋酸乙 烯共聚物(EVA)、尼龍及鐵氟龍(Teflon)。在將雙樹生電極(1〇4)内嵌於密封構件(2〇〇) 内之後’雙極ϋ電極（104) 為一自持構件（sdi^sustainedconponent)，如此一來， 如圖1所示之流通電容器模組（100)將更容易紐裝。換句話說，當使月密封構件（200) 將雙極性電極（104)嵌入後，即可以不需再使用間隔件（1〇6) ’因此，可以密封構件 (200)之條紋（205)及^緣密封元件（203)之度增加，例如：綱澈（2〇5) 緣密封元件（203)贼0.6至1公鱗之絶辦料。因此，密娜件（2〇〇)可在兩個 雙極電極（104)之間提供一間隙’例如1公^ (腕）之固定間隙，此間隙係決定流 通電容器模組（100)電壓分布之關鍵。詳言之，由於流通電容器模組（1〇〇)内之雙極 性電極（104)係形成串聯組態，故施加於末端電極對（1〇2'11〇)間之任何電壓均由 所有雙極眺極（104)共享。耕，顺<電壓務網自飾，否戦壓最高之雙極性 電極(104)將成為流通電容器模組(100)中強度最低低跋最高處。耕，固定之電 極間隙可使流通電谷器模組（1〇〇)具有均一之雙極性電極（104)電阻係數，有利於電 壓均勻分布。另一影響雙極性電極（104)電阻係數之因素則為雙極1±電極（104)之體 導電度’其值需視雙極性電極(104)幻撕(例如:祕離子爾媒介與金屬基體） 而定。雖然每Η固雙極性電極（104)均財一_電壓，但挪流通電容器模組^1〇〇) 中切有雙極性電極(104)均使用單一操作電流。秘直流電壓施用於流通電容器模 組⑽)時，纖電流可作為電極麵離子城率之指標。麟電流較高時表示離 子吸附速率高，此時核理作業之產出亦高。雖然電容去離子作業係在恆定電壓下進 # 度 '及電極間隙 而定。扯列參數中，電極之導電鶊在製造雙極性電極⑽）南更予以最佳化，例 如：達到0.001 Siano^on或以上。 以-實施例而言’若要断每小時纖理_树，則流通電容器模組⑽） 1376355 2012年（月修正替換頁.非劃線版-· 必須財献之電極面積方可物需4理能力。流通電容器模組⑽）雖串歡 雙概電極(104) ’囉作驗係施祕^些串聯雙極性電極^，以處理穿過這些雙極 性電極（104)冰。舉例而言，若包含桃電蝴（1Q2 ; 11G)在内共有如個雙雛 . 電極(104)所組成綠通電容器模組⑽)，趾流通電容器模組⑽)要執機容 ： 去離飾業之目標電壓絲-雙極H電極（104)供應丨v〇c，則總觀喿作馳舰制' 在40VDC。耕，亦可整綠^個流通電容器模組（1〇〇)叫籌成一較九系統，俾倉谈 理feA 量 4l7jc 〇 如第3圖断’係本發明之另一實施^列技意圖。如第3圖所示，本實^例紐兩 個單斷組成的系統，此系統儀由一個絕緣介面板（311)健流通電容器加以隱成 兩個單體，很明顯地，备·個單體中祕一個流通電容器模組（1〇〇)。同時，這兩個單· 體中的麵電容器模組⑽;)均賊兩個可雜至其_通電容器^組 電瓣（102、110)。為簡化說明，在第3圖中係以-導線⑽）储^有電連 接。 魏續參考第3圖麻，傭兩個單體献兩個流通電容器模組(1⑻)配置在一 塑膠外殼⑽)内’並固定在一頂端蓋(3〇5)與一底端蓋⑽)之間。可概湖 口（3G1)及出水口（3〇2)則係分別錄於頂端蓋（⑽與底端蓋⑽）上^ 在《強調的是，林實施例中的^_個流通電容器模組⑽)中之雙樹生電極⑽） 並不40個’其可視需要處刻ς的速率細己置备_數量之雙樹生電極（⑽）。此外，· 流通電容器模組⑽)與外殼⑽亦爾倾尺寸以滿足容量需求。絕緣介面板 (311)可取謝洞，使树峨一個流通電容器模組⑽)紐另一侧鄰禮 通電谷器杈組(100)。如此一來，水便可^^^有電容器模組⑽)。 為將鱗電壓控做低位準，例如：會沈之下，則所有流通電容器模組（朗 係以鳥充電。扣卸制乍中，其總操作電流係各流通電容器模組（⑽）所需電流之 ，。若流通電容器模組⑽)纖狀寸獻，則總電流亦將隨心大。然而， j大電流（例如高於50Α)之商用電源斯費不貲，因此，為軸絲，可利用超級電 令器放大輸出功率’俾以具有絲Γ式滿猶有為流通電容器模組⑽）充電 12 1376355 2012月修正替換頁·非劃線版 之電力需求。右與使用數位電子裝置之現代電源相比，以超級電容器供電之複雜度較 低’供電能力則較高。因此’使用超級電容器不但符合成本效益亦十分可靠。 此^卜，在先前技術中’處理流通電容器模組（100)之電極齡；後之再生作業，一 般需要數分鐘至數小時之時間，端視流通電容器模組（100)之尺寸及處理之水量而定。 然而’流通電容器模組(100)之動^是否有效再生，對^電容去離子處理作業之產出、 奴電容去離子技術之商用可行而言’均非常重要。由於流通電容器模組（1〇〇)之 電極可能包含活Ji碳’因此’電極^再生實為一重練表面>ί钱徐其阶娜纖子污染 〇即使不獅；直流魏，漸蛾柳可麵水中緣子，此一天然麵待欧 使活性碳成為吾人在處理多種不同水體時最常用之濾材。然而，活性^不易再生，目 前業触實務上级共有四種使碳再生U法，祕溶劑春秘、麟紙缺、蒸氣 活紐及W生法。在W強調，本發明_紅電容去離子技術係一種不細匕學物 且可有效獅能源之桃縣，很明顯地’趙四種方法中德容劑衛秘綱於麵電 容器模組（100)之電極之再生。 ¥—個流通電容器模組（100)達到飽和時，其等同於一個完全充電之超級電容器。 知因為流通電容器模組(100)與超級電容器在充電時均係遂過韻離子而儲存電能， 而吸附於電極表面之離子所累積之電荷即為儲存之電能。此外，流通電容器模組⑽） 均可將所储電倉_釋^一負載，麟已麵德子自動去觸腑^ 電極表面。根據上述之放電原理’流通電容器模組（100)之電極係以「回收電能」之 方式再生。 若欲使流通電容器模組（100)再生，首失須關閉帶電之流通電容器模組及 水流’其次再令淋洗液連續通過流通電容器模組（1〇〇)，並將流通電容器模組。⑻） 之終端切換錢接至一負載(例如一尚未儲存電能域級電容器)，以利流通電容器模 組(100)釋出所儲電能’而已觸德子摘隨找^。由練級電容器釋出所儲電 此^^較-般電池陕，因此，一旦中止充電電位，槪口—通電容器模組⑽)將 以更快4^釋出電能。以跋計勒^測即可砂，流通電容器模組（卿中可回 收之殘餘電麟為原綠麟通t容辨顺_子而輸人之電缺^成。崎，流通 13 1376355 2012年/月修正替換頁-非劃線版 電容器陣列之大部分殘餘電能在^電之最初始階段即轉移至該負載，之後則有部分電能 回紐流通電容器陣列’而部分電能謂回赶超級電容器，直到流通電容||模組（1〇〇) 與超級電容器達到一平雜態為止。只要流通電容器模組（1〇〇)之殘餘電壓轉零， 殘餘之已刪離β更一直雜流通電容器之電極^面上，成為交幻亏染之綺。故本發 明將回收之電能快速轉移至其他電能儲存裝置，抑蝴用另一電能含量較低^級電容 器與流通電容器杈組（100)断電能交換’以便進一步去除流通電容器電極表面所吸 附續子》 在流通電容H模組（100)之電極⑽）之「再生」或「電能交換」驗中，電源 係處於關閉狀態’而流通電容器模組（100)之電極的極性則將以一預定之晦^交變。 因此，並聯妓通電容器模組（100)與超級電容器將輪欲1麟触充電。當流通 電容1§陣列仙鱒變為負極時’流通電容器模組⑽）之殘餘電能亦將變為負電能。 如此來，超級電谷器衡J字為流通電容器模組(100)充電，此一極，生交變可促使流通 電容器榼組（100)與超級童容器迅速達到平衡，在此過程中，殘留在流通電容器模組 〇00：)之電；^1之已^^離子^狀練贼排出，因而絲流通電容器電極之再生。 如前所述’為制峨^乍電壓，可將流通電容器模組（100)進行並聯充電，亦即以 同-電壓細^流通電容器之^單體(即流通電容器模組)上。另為加流通電容器模 組(100)之電極的再生，可將流通電容器模組⑽)串聯放電並獅較高之電壓以 提高放電速率。因此’超級電容器必須裝設在一高壓模組中，以因應再生礙呈中，所有 々丨L通電谷器模組（100)之電撕釋出之電壓值。若使战級電容器之單位工作電壓為 2.5 V，然後以美國專利第6,762鄉動满示之「單體内串聯」技術裝置在一高電腿 組中。如此-來，超級電容雜贼可具有一至少3QV作電壓奴少6ρ之電 谷。經由·式，流通電容器模組(100 )將可快速再生，而紗流通電容器模組(100 ) 於再生舰中所釋出之電酬可驗級電容器充電，舰級電容器可作電源使用。 ® ’係顯示本發明之一個内含^極^通電容器（BipolarFTC)之自動化 子式水處理系統之示意圖。為便於說明，本實施例將以處理海水淡來說 明。如第4圖所示，係由一水管將五個串聯#列之雙極氣通電容器模組(402、404、406、 14 1376355 2012 月修正替換頁·非劃線版 4〇8、410)加城接。_储指⑷q)内^身^可透過管路（411、4⑵並由一果⑷〇) 抽i轻流通電容器模組⑽)，纖一触下紐流通電容器模組⑷〇)。當制遂級 通駐個流通電容器模組（4〇2、賴、撕、舰、41〇)時，即接受一次又一次之去鹽 (即去離子）處理。處理後从則經由管路(413)收集在另__儲梢(47G)中。耕， 尚可女裝一線上感測器（圖4中未顯示）以判定所收集之水是否達到總溶解固體量之目 雜，絲需接受進一步之去離子處理。 續#4*第4圖’各流通電容器模組（4〇2、4〇4、4〇6、408、410)之電_疊 體均係密封在一外殼中，而每個流通電容器模組⑽ 、404、406、408、410)均各 自配置兩條導毅接至各自電鱗。各對導線均又分別透過電鏡(Α·卜α_2、α·3、 Α·4、Α-5)連接至-電源管職組（42〇)以断充、放電。電源⑷可將—電壓（例 如.40 V)經由電纜（c)供應至電源管雜組（42〇)，以便為五個雙極總電容器模 組（402、404、406、顿、41〇)並聯充電。各流通電容器模組經由電源管^_^ (42〇) 接制電源（43G)顺應之充電駿後，便可將穿齡流通電容離纹絲中所含 1 子嫌。因此’當制c向下穿過各流通電容器模組找叠電極時，财中之衡瓣 固體量亦將迅喊少。當流通電容器電極因吸附離子而飽和時，便需進行電極再生作 t 。4¾¾¾再生之作法係先停止經由管路（412)對流通電容器 陣列進水’同時中斷由電源（43〇)供應至流通電容器電極之充電電壓。然後，將流通 電容器電極之殘餘電能放電至一尚未緒存電能之超級電容器組（44〇)，例如：15v之額 定工作電壓及一 4〇F之超級電容器組，並藉以為超級電容器組充電，其中超級電容器組 係透過電纜（R-l、R-2)連接至電源管街莫組（42〇)。耕，為加速釋出殘餘電能，五 個流通電容器係串聯放電，而殘餘電能亦為流通電容器電極上殘留離子量之一指標。此 外’為因應流通電容器模組（1〇〇)之充、放電所需之高壓、高電容，超級電容器組可 為串聯、並聯、或同時採用串/並聯方式形成，對此本發明並不加以限制。此外，在進行 「去除水中離子」與「再生流通電容器模組」在内之所有電容去離子作業，均係透過可 制（PLC)齡。 接著’將以下列之實施例來說明本發明通電容器模組〇〇〇) 4理過程。 15 1376355 2012 $5月修正替換頁·非劃線版 實例1 本實例係使用4第1圖麻之流通電容器模組⑽），其紐末端電極對（1〇2、 110)及20個堆疊在级通電容器電極⑽），其中各流通電容器電極 (104>句為-直徑約54公厘抑形。鱗，本實例係游自祕穿職通電容器模組(_ 以嫌自絲中、在奴2)雜子。 流通電容m组（100)切_靖⑽、11G)均係由塗有活性碳之不錄鋼盤構 成’其直酬與流通電容器電極（1〇4)之直徑相…桃電赠（1〇2、⑽）係分別 '職^直徑2公厘之金屬桿上，其中此等金屬桿可將流通電容器模組⑽）中之雙 極嶋(104)夾合蝴電瓣(1〇2、11〇)之間，亦可作為連接至一電糊子。 雙樹生電極（104)可由活性補魏a猶電度為麵之碳布峨成。密 謝冓件（200)與雙極性電極（104)係交錯堆疊排列，因而可在雙極性電極（1〇4)之 間形成-約1公厘之固定間隙。流通電容器模組⑽)係放置在一塑膠外殼中，並覆 以W孔洞樣W蓋作為〜級出水口。供域金屬桿（亦即流通電容器模組⑽子） 使用之孔洞係突出餅殼。一鎖定鶴可將秘|桿固定在外殼(3〇〇)内之一適當深 度，並使雙極I生電極（104)均勻受壓。 接著，將150毫升原本總;辦固體量為15Q 之自^^，以_^^5〇毫升 度送入流通電容器模組（100)»當自來水接觸第一末端電極時，一個35 V之直流電壓 則胁^^電鱗之間’因而在雙雛電極（1〇4)之間形成一電場，藉以去除離子， 亦即離子雜麵;^極性電極（104)技面。在去離子^^中，搔(乍電流之量測 值為0·5A，而操作電壓則維持不變。 祕±麟理後之自棘中之麟細體量為8〇啊。此一言嫩結果呈現下列優 點： 1·達到電極之最大使用效率，且未親察到漏水現象，因此，已處理之水並未受到漏 水之交又污染。; 2·由於流通電容器（1〇〇)中的雙極性電極（1〇4)係串聯，因此，所施電壓係由如 均分。此外，總著減少，顯示處理過程中並未發生水解現象；而處 1376355 2012韦万月修正替換頁·非劃線版 理後之水仍’維持在環境溫度，亦暗示並無歐姆加熱之現象。 3.雙極f·生電極(104)皮後接至電源，此一設計刺過表面娜才作用制冰 中總溶解固體量之電容去離子技街。The thief is closely woven, and the water tends to stay in the body of the volume, so the capacitor is removed from the _f^ industry. The electrodes of the new flow capacitors are quickly and effectively regenerated, and the electric recording surface of the circulating capacitors needs to be drowned. In addition, the parallel flow capacitor electrodes are connected to a power source in an economical and efficient manner, but are not directly connected to the power source; and the remaining capacitors are electrically connected by water passing through the array of flow capacitor electrodes. After the potential of the valve is fine, the front end of the tenderness is electrified, and the current begins to rise. When the scale is adjacent to the second side of the first intervening electrode, the second side of the pole will have the same polarity as the tip electrode. The phenomenon that the polarity of the electrodes alternates as the current/water flow passes through the electrode array will continue to occur until the electrolysis is reduced. Each electric power has two different poles &: when it is connected in series, the flow capacitor electrode becomes a bipolar electrode, and when connected in parallel, the flow capacitor electrode becomes a monopolar electrode. Double-tree bioelectrodes have been used in many electrochemical methods with different purposes. For example, in U.S. Patent No. 4,043,891, the use of tempered metal is uniform in electro-transfer operations. In U.S. Patent Nos. 5,322,97, 6,787,009, U.S. Patent No. 7,018,16, Synthetic; in the US Patent No. 5, 439) 77 micro 5, 744, 028 in the fine electrolytic disinfection; and in the "Purification and Applied Chemical Tearing ^ and Applied Cto ^ (10)) 73rd, No. 1819 to 1837 Used for regenerative fuel: 3⁄4 亍 亍 load flat peach. The bipolar electrode can be removed as shown in US Patent No. 6 224, 72 ,, without being sandwiched between two handles. Cakes, double-tree raw electrodes can also be used __, Lie 6306^270 is _. Bipolar J · electric power different wedding electric tearing material, can also be applied to the capacitor to leave 6 1376355 • 2012, month Corrected the replacement page-non-dashing version of the technology, and US Patent No. 6,788,378 is one of them, in which the electrodes are arranged in series and in parallel. In terms of capacitive deionization technology, the US patent is opened. The disadvantage of 6,788378 is to use: 1 electrode tender butterfly seal. Miscellaneous _ ' can be very high, can be class The container becomes an electric energy storage device, but the energy scale of the expensive material = from the surface of the t-make, this - _ ^ shop needs Xuan face as a capacitor deer operation and έ 'no help. The red electric field makes Yang get ^^ her^, and the current is also lacking in the leakage near the edges, causing ohmic heating and other damage. Therefore, the invention has a finer regenerative flow capacitor module. Group Continuation • Ying system and method, the capacitor deionization technology can process industrial water on an industrial scale. SUMMARY OF THE INVENTION The present invention is a hybrid of a touch-flow capacitor module. , the module makes the module more efficient and the electrode can be quickly and effectively regenerated. The surface of the electric group can be touched by red and the current electricity can be easily completed in the new or Shouting water purification equipment. Roots of the main purpose, Yao coffee 1 face force, coffee manufacturing circulation electricity ^ ^ electric contribution _ system • Select the surface area, such as live _ or Nailai carbon tube. Hybrid to form a carbon cloth, or by a suitable age at a metal base Or directly, the metal green is directly formed. In addition, the electrodes such as & preferably have high permeability; woodiness and high electrical conductivity. #_的__Green purpose, 働__ electrode distribution is still between the parallel-level capacitor electrodes. When the capacitor electrode is high in conductivity, for example, about (10) SIQn_ or mm scales are uniformly converted into a strong electric field. Under the electric field, the singular ion έ···· rate can be used. The mine is embedded in a densely-owned cattle to densely smash the capacitor to defeat the edge, avoiding the thinning of the outer layer and avoiding the 14 ice. At the same time, the surface of the capacitor is recorded inside the capacitor. The capacitor electrode is dirty and can be added to the cow, so that the flow capacitor module is more suitable. 7 1376355 2012 Haoyue correction replacement page _ non-line version easy to manufacture. The present invention has a method of regenerating a capacitor electrode which utilizes a supercapacitor to make the flow capacitor electrode fast. OBJECTIVE: The present invention firstly provides a flow capacitor (FTC) which is formed by stacking a plurality of electrode plates and a plurality of insulating members in a staggered manner, and each cell is disposed between a pair of terminal electrodes. A plurality of perforations are formed on the plurality of insulating members and the pair of end electrodes. The invention further provides a flow capacitor (FTC) module comprising: an insulative housing having a top end cover and a bottom end cover and dividing the insulative housing into a plurality of units by at least one interface panel, wherein the top end cover and the bottom end cover And forming a plurality of perforations on the interface panel; and at least one single system is disposed on each of the unit towels 'the single system of the oil electrode plate and the plurality of insulating members are staggered and stacked' and the per-unit A pair of end electrode pairs are disposed on the two ends, wherein the plurality of electrode plates, the plurality of insulating members and the pair of end electrodes form a plurality of perforations. The invention further provides a water treatment system for removing ions in water, wherein: a flow capacitor module is composed of an I-insulated outer casing and at least a single body, and the brim outer casing has a top end cover and a bottom end cover and at least A panel divides the insulating casing into a plurality of units, and the top cover, the bottom end cover and the interface panel form a plurality of perforations, and at least one single body is disposed in each unit, and the single system is composed of a plurality of electrode plates And a plurality of insulating members are stacked in a staggered manner, and each end of the unit has a pair of end electrodes, wherein the plurality of electrode plates, the plurality of insulating members, and the pair of terminal electrodes are formed into a plurality of f holes ;-1; scale, Xiaoliu; one less first supercapacitor' is connected between the potential source and the flow capacitor module for amplifying the power supplied by the potential source; at least one second supercapacitor is connected a flow-through capacitor module for receiving electrical energy from a flow-through capacitor module; a controller for regulating ion removal rate in water and electrical energy recovery and re-flow of the capacitor module Health. [Embodiment] Hereinafter, a preferred embodiment of the capacitor-passing stage in which the double-tree is formed by electric tearing will be described. First, please correct the replacement page of the beta month of 2012 - the non-dash version. Referring to Fig. 1, a schematic diagram of the flow capacitor (100) according to the present invention. As shown in Fig. 1, the flow capacitor (100) is composed of a plurality of electrodes (104), a plurality of spacers (106), and a pair of terminal electrodes (102'110) which are juxtaposed and arranged in a row. The pair d2, 11〇) are electrically connected to a power source via wires (12〇, 140), respectively. The electrode (104) and the terminal electric current in the circulating capacitor (100); |^ (1Q2, 110) is a metal substrate made of nickel, non-recorded steel or Qin, and at the same time, each metal substrate is placed on the metal substrate. There are a plurality of holes with a diameter of 1 mm (1 mm), which are like a pattern, which can be seen through the sputum; and the pattern can be sag-like mesh, mesh, mesh or wire mesh. In addition, each metal substrate may be further coated with an end coat or other suitable carbonaceous material (for example: activated carbon, carbon nanotubes or carbon ray A) or conductive metal oxygen (10), such as: Zheng Fiber The coating formed by Zao De Tan or Zheng Yu) protects the green basal surface water reading 〇 f line continued #^ i, the electrode (104) and the inter_ _ (1〇6) are staggered The arrangement 'that is, each of the linings (106) is sandwiched between the two electrodes (1〇4) to form a miscellaneous path between the electrodes (1〇4). The electrode (104) may be identical to the peach tree (10), 110) or may be made of carbon cloth (i.e., activated carbon and scale; 邑 fabric). Obviously, each spacer (1〇6) can be a plastic or polythene material of about 〇·6 to i, and the middle of the age (106) can be fine mesh, mesh, A mesh or wire mesh pattern. A DC potential is applied between the south and the (1Q2, 110), and the private flow is between the electrodes (1〇4). The flow of water between the electrodes (10)) will charge the electrode (104) passing through it. For example, the water system flows from the ship capacitor module (1〇〇) of the ship's capacitor module (1〇〇2) to the capacitor module (100). At the same time, the negative electrode (electrode) electrode (10) flows out of the flow capacitor module. Group (10)). When the private steel reaches the first side of the first-middle electrode (104), the first surface will be formed by the electric field - the negative electrode; and when the water flows to the second side of the intermediate electrode (104) (ie, the opposite side) When the other side is the same, the second side is induced by the electric field to form - sparse; therefore, 'when the intermediate electrode (1〇4) is applied, the bipolar electrode 〇〇4) is formed, so when the water flow is not _ Each electrode (104) in each of the lining capacitor modules (10) is stacked into a butterfly electrode (1〇4), and each electrode (104) is igj: the electric field is induced to form a miscellaneous charge _electrode (1〇4) ) The two sides are charged. At the same time, the current will also pass through the flow capacitor array as the bipolar electrode (1〇4) is heard. Use as shown in the capacitor deionization (CDI) operation! When the flow capacitor module (10) shown is configured, its 1376355 2012/month correction replacement page-non-dash version has at least two advantages. First, the water to be treated by capacitive deionization can directly contact the flow capacitor. Each electrode (104) in the module (100). In particular, since the capacitive deionization technique uses the surface of the charged electrode to adsorb ions to reduce the total dissolved solids (TDS) in the water, the water must be in contact with the electrode for a fast and efficient treatment. In addition, in the process of capacitive deionization, the water system fills the entire flow in a manner such as gravity, and the capacitor array is used to make all the surface of the electrode (104); thus, the flow capacitor module is improved (1〇〇). The efficiency of the electric tree is beneficial to the output of the capacitor deionization operation, the flow capacitor circuit 〇〇〇) the flow path directly without dead angle or the detention area 'so the water can be from the flow capacitor module ( 1〇〇) easily flows out. In addition, the electrode (1〇4) must be regenerated frequently because the electrode will quickly saturate after adsorbing ions. However, one of the technicians facing electrode regeneration is cross-contamination, and the pollutants mainly from the capacitors in the flow capacitor module (1〇〇) are especially in the IL Power Module (1QQ). This phenomenon most often occurs when the flow path is long and shipped back. In a flow capacitor module (10), any of the two electrodes facing each other, the sarso and the negative electrodes, constitute a capacitor. When the domain water passes through the flow capacitor module (1〇〇), the cations in the water will be adsorbed to the surface of the positive electrode, and the anions will be adsorbed to the surface of the negative electrode. The above-mentioned capacitive ion absorption function is just a crane for storing electrical energy in an electrochemical capacitor. In the regeneration of the electrode (104), the electrode (1〇4) is connected to a load by two wires (10), 14〇) (for example, a capacitor that has not been stored yet) to break the touch, and the negative cut The residual energy of the flow capacitor thief set (100) can be stored for subsequent use. This fashion needs to use a unicorn to go to Touchezi to wash away from the circulating capacitor module (10). The flow capacitor module (100) prevents the mixed liquid and the desorbed ions from being completely discharged, thereby reducing the possibility of contamination and contamination. Z, _ It should be noted that it is important to reduce the red color, and therefore, the present invention makes it possible to turn off (10) the external electric field between the _β 冰 ice_electrode (10). Because the money is not a bribe, the four cakes can be smashed, so that they can be torn apart. Ploughing, the test also has a secret double electrode (1〇4) grades that flow out of wealth. This external current ^ travel "shunt current" can generate | ^ mouth heat at the edge of the polarity electrode (104), so that these edges are the hot spot of the circulating capacitor module (1 (8)), and the electricity of the secret recording industry The rate of the level ^ Jun margin Wei may also lead to gamma, solid amount, wonderful wire ion ^. 4 Next, Month ##第2图'The invention of the ice-invented method is based on the embodiment of the law, and the method of correcting the replacement of the current-2012-month correction-non-dashing version of the bipolar 1±electrode (104) Embedded in a sealing member (200), the itbt sealing member (200) includes a plurality of radially aligned strips (205) and edge sealing elements (203) surrounding the strips. The stripe (205) and the edge sealing element (203) can be simultaneously formed in a single injection molding process. The stripe (205) and the edge sealing element (203) may be composed of an insulating material, including an EPDM, an epoxy modified organolithium resin, an ethylene vinyl acetate copolymer (EVA), nylon, and iron. Teflon. After the double-tree raw electrode (1〇4) is embedded in the sealing member (2〇〇), the bipolar ϋ electrode (104) is a self-sustaining member (sdi^sustainedconponent), thus, as shown in FIG. The flow capacitor module (100) will be easier to install. In other words, when the moon sealing member (200) is inserted into the bipolar electrode (104), the spacer (1〇6) can be omitted. Therefore, the stripe (205) of the member (200) can be sealed and The degree of the edge sealing member (203) is increased, for example, the outline (2〇5) edge sealing member (203) thief 0.6 to 1 metric scale. Therefore, the Mir member (2〇〇) can provide a gap between the two bipolar electrodes (104), such as a fixed gap of 1 gong (wrist), which determines the voltage distribution of the circulating capacitor module (100). The key. In detail, since the bipolar electrodes (104) in the flow capacitor module (1〇〇) form a series configuration, any voltage applied between the pair of terminal electrodes (1〇2'11〇) is all double Extreme bungee (104) sharing. Ploughing, shun < voltage service net self-decoration, or the highest bipolar electrode (104) will become the lowest point in the flow capacitor module (100). The ploughing and fixed electrode gap enables the circulating electric grid module (1〇〇) to have a uniform bipolar electrode (104) resistivity, which is favorable for uniform voltage distribution. Another factor affecting the resistivity of the bipolar electrode (104) is the body conductivity of the bipolar 1± electrode (104). The value depends on the bipolar electrode (104) magic tear (eg, the secret ion medium and the metal matrix). ) depending on. Although each sturdy bipolar electrode (104) has a _ voltage, the bipolar electrode (104) in the circulatory capacitor module (1) has a single operating current. When the DC voltage is applied to the flow capacitor module (10), the fiber current can be used as an indicator of the ion surface rate of the electrode surface. When the column current is high, the ion adsorption rate is high, and the output of the nuclear operation is also high. Although the capacitive deionization operation is based on a constant voltage of #度' and electrode gap. In the entanglement parameter, the conductivity of the electrode is optimized in the south of the bipolar electrode (10), for example, 0.001 Siano^on or above. In the case of the embodiment, 'If you want to break the fiber _ tree every hour, then the capacitor module (10)) 1376355 2012 (monthly correction replacement page. Non-dash version - · must be the electrode area of the material) The ability to flow. The capacitor module (10) is a series of bipolar electrodes (104). For example, if there is a peach chick (1Q2; 11G), there is a pair of chicks. The electrode (104) consists of a green-through capacitor module (10), and the toe-flow capacitor module (10) has a function: The target voltage wire-bipolar H-electrode (104) is supplied to 饰v〇c, and the total view is made at 40VDC. Tillage, can also be green = a flow capacitor module (1〇〇) called to form a nine system, Kamakura talk feA amount 4l7jc 〇 as shown in Figure 3 is another embodiment of the invention. As shown in Figure 3, the system consists of two single-break systems. The system is hidden by two insulating capacitors (311) and two capacitors. It is obvious that A fluid capacitor module (1〇〇) in the body. At the same time, the surface capacitor modules (10) of the two single bodies;) are both thieves and can be mixed with their _ pass capacitors (groups, 102, 110). To simplify the description, in Fig. 3, the electrical connection is stored by the - lead (10). Wei continued with reference to Figure 3, the two units of the two flow capacitor modules (1 (8)) are placed in a plastic casing (10)) and fixed to a top cover (3〇5) and a bottom end cover (10) between. The Hukou (3G1) and the water outlet (3〇2) are recorded on the top cover ((10) and the bottom cover (10) respectively. ^ Emphasize that the ^_ flow capacitor module in the Lin example (10)) The double-tree bioelectrode (10) in the middle of the double-tree bioelectrode ((10)). In addition, the flow capacitor module (10) and the outer casing (10) are also sized to meet capacity requirements. The insulating interface panel (311) can be used to make a hole in the tree, and the other side of the tree is connected to the capacitor module (10). In this way, the water can be ^^^ with the capacitor module (10)). In order to control the scale voltage to a low level, for example, under the sinking, all the flow capacitor modules (the system is charged by the bird. In the buckle system, the total operating current is required for each circulating capacitor module ((10)). If the current capacitor module (10) is in a slender shape, the total current will also be large. However, the commercial power supply with a large current (for example, higher than 50 Α) is not expensive. Therefore, for the shaft wire, the super electric actuator can be used to amplify the output power '俾 to have a wire-type full-flow capacitor module (10)) Charging 12 1376355 2012 month correction replacement page · Non-dash version of the power demand. On the right, compared to modern power supplies that use digital electronic devices, the power supply with supercapacitors is less complex, and the power supply capability is higher. Therefore, using supercapacitors is not only cost-effective but also very reliable. In the prior art, the electrode age of the flow capacitor module (100) is processed; the subsequent regeneration operation generally takes several minutes to several hours, and the size and processing of the flow capacitor module (100) are viewed. The amount of water depends. However, whether or not the flow capacitor module (100) is effectively regenerated is very important for the production of the capacitor deionization process and the commercial feasibility of the slave capacitor deionization technology. Since the electrode of the circulating capacitor module (1〇〇) may contain live Ji carbon 'so the 'electrode ^ regenerative is a re-surgical surface> ί 徐 徐 其 其 娜 娜 娜 纤 纤 纤 纤 纤 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; The water edge, this natural face to Europe, makes activated carbon the most commonly used filter material when dealing with many different water bodies. However, the activity is not easy to regenerate. At present, there are four kinds of carbon regeneration U methods, the secret solvent spring secret, the lining paper shortage, the steam activity and the W production method. In W, the invention _ red capacitor deionization technology is a kind of peach county that is not fine-grained and can be effective for lion energy. It is obvious that 'the four methods of Zhao's four-dimensional method are the capacitors module (100). ) The regeneration of the electrodes. ¥—A flow capacitor module (100) is equivalent to a fully charged supercapacitor when it reaches saturation. It is known that because the circulating capacitor module (100) and the supercapacitor both store the electrical energy when they are charged, the electric charge accumulated by the ions adsorbed on the surface of the electrode is the stored electric energy. In addition, the flow capacitor module (10) can be used to discharge the storage battery _ _ a load, Lin has a face to automatically touch the surface of the electrode. According to the discharge principle described above, the electrode of the flow capacitor module (100) is regenerated by "recovering electric energy". If the flow capacitor module (100) is to be regenerated, the first flow of the capacitor module and the flow must be turned off. Secondly, the eluent is continuously passed through the flow capacitor module (1〇〇), and the capacitor module is passed. (8)) The terminal switch money is connected to a load (for example, a power domain capacitor that has not been stored) to facilitate the discharge capacitor module (100) to release the stored energy'. The stored voltage is released by the leveling capacitor. This is better than the battery. Therefore, once the charging potential is stopped, the port-through capacitor module (10) will release the power faster. It can be used to measure the sand, and the flow capacitor module (the residual electric power that can be recovered in Qingzhong is the original green lintong t 容 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ /month correction replacement page - most of the residual energy of the non-dashed capacitor array is transferred to the load at the initial stage of the power, after which some of the power is returned to the capacitor array and part of the energy is returned to the supercapacitor. Until the flow capacitor||module (1〇〇) and the supercapacitor reach a flat impurity state, as long as the residual voltage of the circulating capacitor module (1〇〇) turns to zero, the residual electrode that has been cut off from the β is always a capacitor. On the surface, it becomes the illusion of illusion. Therefore, the present invention rapidly transfers the recovered electrical energy to other electrical energy storage devices, and uses another low-level capacitor and a circulating capacitor 100 group (100) to cut off the power exchange. 'To further remove the continuation of the surface of the flow capacitor electrode." In the "regeneration" or "electrical energy exchange" test of the electrode (10) of the flow capacitor H module (100), the power supply is in the off state and the flow capacitor The polarity of the electrodes of the module (100) will alternate with a predetermined amount. Therefore, the parallel pass capacitor module (100) and the super capacitor will charge the wheel. When the circulating capacitor 1 § array becomes negative, the residual energy of the circulating capacitor module (10) will also become negative. In this way, the super-electric valley device J word is charged by the circulating capacitor module (100). This pole, the alternating current can promote the balance of the flow capacitor group (100) and the super-child container quickly, in the process, the residue In the flow capacitor module 〇 00 :) electricity; ^ 1 has ^ ^ ion ^ shape thief discharge, and thus the wire through the capacitor electrode regeneration. As described above, the current-carrying capacitor module (100) can be charged in parallel, that is, the same-voltage is used to pass through the capacitor (ie, the flow capacitor module). In addition, for the regeneration of the electrodes of the flow capacitor module (100), the flow capacitor module (10) can be discharged in series and the voltage of the lion is increased to increase the discharge rate. Therefore, the 'supercapacitor must be installed in a high-voltage module to reflect the voltage value of the electrical tear-off of all the 通电L-powered grid modules (100). If the unit operating voltage of the combat capacitor is 2.5 V, then the "in-cell series" technology shown in U.S. Patent No. 6,762 is displayed in a high-power leg group. So - come, the super capacitor thief can have a voltage of at least 3QV for the voltage slave. Through the type, the flow capacitor module (100) will be able to be quickly regenerated, and the yarn flow capacitor module (100) will be charged in the regenerative ship and the capacitor can be used as a power source. ® ' shows a schematic diagram of an automated sub-aqueous water treatment system incorporating a Bipolar FTC of the present invention. For ease of explanation, this embodiment will be described in terms of treating seawater. As shown in Figure 4, five bipolar gas-through capacitor modules in series # are listed in a water pipe (402, 404, 406, 14 1376355, 2012 revision replacement page, non-dash version 4〇8, 410) Jiacheng pick up. _The storage finger (4)q) can pass through the pipeline (411, 4(2) and one fruit (4) 〇) to pump the light flow capacitor module (10)), and the fiber touches the circulation capacitor module (4) 〇). When the system is connected to a circulating capacitor module (4〇2, Lai, tear, ship, 41〇), it is treated again and again to remove salt (ie deionization). After processing, it is collected in another storage tank (47G) via a line (413). The ploughing, still available on-line sensor (not shown in Figure 4) to determine whether the collected water has reached the total dissolved solids, the wire is subjected to further deionization. Continued #4*第4图' The electrical_frames of each flow capacitor module (4〇2, 4〇4, 4〇6, 408, 410) are sealed in a casing, and each flow capacitor module (10), 404, 406, 408, 410) are each configured with two guides connected to their respective scales. Each pair of wires is connected to the power supply management group (42 〇) through an electron microscope (Α·b α_2, α·3, Α·4, Α-5) to be charged and discharged. The power supply (4) can supply a voltage (for example, .40 V) to the power supply manifold (42〇) via the cable (c) to be five bipolar total capacitor modules (402, 404, 406, D, 41). Parallel charging. Each of the flow-through capacitor modules is connected to the power supply (43G) via the power supply tube ^_^ (42〇), and the discharge capacitor can be separated from the trace. Therefore, when the system c goes down through the flow capacitor modules to find the stacked electrodes, the amount of solids in the balance will also be less. When the circulating capacitor electrode is saturated by the adsorption of ions, electrode regeneration is required as t. The 43⁄43⁄4⁄4 regeneration method first stops the water supply to the flow capacitor array via the line (412) and simultaneously interrupts the charging voltage supplied from the power source (43〇) to the flow capacitor electrode. Then, the residual energy of the capacitor electrode is discharged to an ultracapacitor group (44 〇), such as a rated operating voltage of 15 volts and a 4 〇F ultracapacitor bank, and thereby charging the ultracapacitor bank. The supercapacitor group is connected to the power supply unit (42〇) via a cable (Rl, R-2). In order to accelerate the release of residual electrical energy, the five circulating capacitors are discharged in series, and the residual electrical energy is also an indicator of the amount of residual ions on the electrodes of the circulating capacitor. In addition, in order to cope with the high voltage and high capacitance required for charging and discharging the capacitor module (1〇〇), the ultracapacitor group can be formed in series, parallel, or simultaneously in series/parallel mode, and the present invention does not limit. In addition, all capacitor deionization operations, such as "removal of water ions" and "regeneration capacitor modules", are transmitted through a programmable (PLC) age. Next, the process of the capacitor module of the present invention will be described in the following embodiments. 15 1376355 2012 $5 month correction replacement page · Non-dash version example 1 This example uses the 4th Figure 1 of the flow capacitor module (10), with a pair of terminal electrodes (1〇2, 110) and 20 stacked on the stage. Through capacitor electrode (10)), in which each capacitor electrode (104> sentence is - diameter about 54 mm suppression. Scale, this example is from the secret wear capacitor module (_ to suspect from the silk, in the slave 2 Miscellaneous. Flow capacitance m group (100) cut _ Jing (10), 11G) are composed of non-recorded steel plate coated with activated carbon's direct compensation and flow capacitor electrode (1〇4) diameter phase... Taodian The gifts (1〇2, (10)) are respectively on the metal rods with a diameter of 2 mm, wherein the metal rods can clamp the bipolar turns (104) in the flow capacitor module (10). 〇 2, 11 〇), can also be connected to an electric paste. The double-tree bioelectrode (104) can be formed by a carbon cloth having an active complementation of Wei a. The chelating element (200) and the bipolar electrode (104) are arranged in a staggered stack so that a fixed gap of about 1 mm can be formed between the bipolar electrodes (1〇4). The flow capacitor module (10) is placed in a plastic case and covered with a W-hole W-shaped cover as a level-of-water outlet. The hole used by the metal rod for the domain (that is, the flow capacitor module (10)) protrudes from the shell. A locking crane can secure the rod to the appropriate depth in the outer casing (3〇〇) and uniformly pressurize the bipolar I-electrode (104). Next, 150 ml of the original total; the solid amount is 15Q from ^^, and is sent to the flow capacitor module (100) in _^^5〇 ml. When the tap water contacts the first end electrode, a 35 V DC The voltage is between the voltage scales and thus an electric field is formed between the two electrodes (1〇4), thereby removing ions, that is, ion noodles; and the polarity electrode (104) technology. In the deionization ^^, 搔 (the value of the 乍 current is 0·5A, and the operating voltage remains unchanged. The secret volume of the thorn from the spine is 8 〇. This is a statement The tender results show the following advantages: 1. The maximum efficiency of the electrode is achieved, and the water leakage phenomenon is not observed. Therefore, the treated water is not contaminated by the leakage of water. 2) Due to the flow capacitor (1〇〇) The bipolar electrodes (1〇4) are connected in series, therefore, the applied voltage is divided equally, for example, in addition, the total reduction is reduced, and no hydrolysis occurs during the treatment; however, at 1376355 2012 Wei Wanyue correction replacement page· The water after the non-dashing version is still 'maintained at ambient temperature, which also implies that there is no ohmic heating phenomenon. 3. The bipolar f·sheng electrode (104) is connected to the power supply after the skin, and this design pierces the surface. Capacitor deionization technology for total dissolved solids in ice making.
接著’本實例係使用一包括五個流通電容器模組（100)之系統進行水處理，其中 各流通電容器模組（100)均包括宜射丄所用流通電容器模組α〇〇)之構造。在本實例 中’流通電谷器模組（100)係串聯^列以淡^^^水。流通電容器模組（1QQ)雖係以串 聯方式供海水流通過，但卻為並聯充電，充電電壓約為35 v〇c 〇將一公升經趣街慮後 讀;雜固體量約35,000 ppm’以細讀50毫升之級送〜麵電容器模組 (100) ’且僅通過通電容器模組（1〇〇) 一次。在充電期間，工作電流之記錄值為3A， 而處理一次後之水中總溶解固體量經量測後發現已降至^ooppm 〇 在本實例中’流通電容器模組（100)之再生作業係使用一包括三個超級電容器之 超級電容器組。每一個超級電容器之規格均為30 Vx20 F，其串聯後形成一規格為卯 VX6.7F之^級電容器組’並作為五個流通電容器模組（1〇〇)再生過程中之電能儲存裝 置。由於本實施例之流通電容器模組（1〇〇)的尺寸小，且僅有少量離子被吸附，故超Next, the present example uses a system including five flow capacitor modules (100) for water treatment, wherein each of the flow capacitor modules (100) includes a configuration of a flow capacitor module α〇〇). In this example, the flow-through grid module (100) is connected in series to light water. The flow capacitor module (1QQ) is used for serial flow of seawater, but it is charged in parallel. The charging voltage is about 35 v〇c. One liter will be read after the interesting street; the amount of impurities is about 35,000 ppm. Carefully read the 50 ml class to the face capacitor module (100) ' and pass only the pass capacitor module (1〇〇) once. During charging, the recorded value of the operating current is 3A, and the total dissolved solids in the water after treatment is measured and found to have dropped to ^ooppm. In this example, the regenerative operation of the 'flow capacitor module (100) is used. An ultracapacitor bank consisting of three supercapacitors. Each supercapacitor has a specification of 30 Vx20 F, which in series forms a capacitor bank of size 卯 VX6.7F and acts as an electrical energy storage device during the regeneration of five flow capacitor modules (1〇〇). Since the size of the flow capacitor module (1〇〇) of the embodiment is small, and only a small amount of ions are adsorbed, the super
級電容器組足可匹配五個流通電容器模組（1〇〇)殘餘電位之電壓總和。表1分 在執行與不執行「電能交換」之情況下，五個流通電容器模組（1〇〇)之再生成效。 __處理方式 目標值（ppm) 1 电月 用水量 所用時間 -_f洗+電能交換 100 2餅 8 __僅水*洗 C 100 12対 2小時 17 1 狀极總撕固體量之背景讀數。 如表1所示，「電能交換」技術可為流通電容器模組（1〇〇)之再生提供明顯^， 1376355 2012年/月修正替換頁-非劃線版 · 使模組再纽率獻贿以溶劑親時之再域率，而再^斯用之寶貴資源(即淡水） 則遠少於Μ以溶劑赤先時之用水量。翻攻強調，本^明之^通電容器模組（1〇〇)於 不需使用學物或電力。 - 架構，本發明可^20雜内以之⑼平方公^之電極^^去除2^毫克 之鹽’鱗成口趙率^#^|解方妙0.062毫克。因此，本發明至少於財下歹撥 點： ’、 電谷去離子技織供-種可有效使用能源、產出量大、财需使用化學物々^理 法^、要月t*發揮"idt電谷器電極（1〇4 )之最大使用效率，再配合流通電容器電極（1⑽） 離子技術實可用於處理大量工業用水。 本發明有效提高流通電容器之雙樹生電極(104)之使用效率，而此雙極性電極⑽）· 亦可輕易組裝至流通電容器模組（100)中，故可有效^也降低生產成本^ 以上有關本發明之說明雖係嫩明之一特定實施例為參照對象，但熟習本發明所 屬技術領域之一般技藝人士當可針對上述實施例進行修改而不脫離本_之精_。@ 此’本發明之^圍並非由以上之詳細說明加以界定，而係由後附之申請專利範圍加以界 定。 【圖式簡單說明】 圖1係-根縣發明-實施例之電容去離子系統找意圖’其中該電容去離子系統 挪-流通電容器模組，而該流通電容器模蝴雖概個並列之電極。 … · 圖2係一根據本發明一實施例之流通電容器模組之電極示意圖。 3係一柜據本^明一實施例之電容去離子系統^意圖其中該電容去離子系、 包兩個安裝在一外殼内且彼此串聯之流通電容器模組。 ’、統 圖4顯示一極流通電容器之自動化電容去離子式水處理系統。 【主要元件符號說明】 流通電容器模組⑽） 末端電極對（102、11〇) 18 1376355 2012年/月修正替換頁-非劃線版 電極（104) 間隔件（106) 導線（120、140、330) 邊緣密封元件（203) 條紋（205) 夕險（300) 頂端蓋（305) 底端蓋（307) 絕緣介面板（311) 流通電容器模組（402、404、406、408、410) 管路（4U、412、413) 電源管組（420) 電源（430) 超級電容器組（440) 泵（450) 儲梢（460、470) (A-l 'A-2>A-3'A4'A-5'C'R-1 'R-2) 19The stage capacitor bank is sufficient to match the sum of the voltages of the residual potentials of the five circulating capacitor modules (1〇〇). Table 1 shows the regenerative effect of five circulating capacitor modules (1〇〇) with and without “electrical exchange”. __Processing method Target value (ppm) 1 Electricity month Water consumption Time used -_f wash + power exchange 100 2 cake 8 __ water only * wash C 100 12 対 2 hours 17 1 Background reading of the total amount of solids torn. As shown in Table 1, the "Electric Energy Exchange" technology can provide significant relief for the regeneration of the circulating capacitor module (1〇〇). 1376355 2012/Month Amendment Replacement Page - Non-dash version · Make the module renew bribe With the solvent re-time rate, the valuable resources (ie fresh water) used by the solvent are much less than the water consumption when the solvent is red. The retweet emphasizes that the ^^ capacitor module (1〇〇) does not require the use of school or electricity. - Architecture, the invention can be used in the ^20 miscellaneous (9) square ^ ^ electrode ^ ^ remove 2 ^ mg of salt 'scale into mouth Zhao rate ^ # ^ | solution Fang Miao 0.062 mg. Therefore, the present invention at least the money transfer point: ', electric valley deionization technology for the supply of energy can be used effectively, the output is large, the need to use chemicals, the chemical method ^, the month t * play " The maximum efficiency of the idt electric grid electrode (1〇4), combined with the flow capacitor electrode (1(10)) ion technology can be used to process large quantities of industrial water. The invention effectively improves the use efficiency of the double-tree electrode (104) of the flow capacitor, and the bipolar electrode (10)) can be easily assembled into the flow capacitor module (100), so that the production cost can be effectively reduced. The present invention has been described with reference to a particular embodiment of the present invention, and those skilled in the art to which the present invention pertains may be modified to the above-described embodiments without departing from the scope of the invention. The present invention is not defined by the above detailed description, but is defined by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic diagram of a capacitor deionization system of the invention of the invention - wherein the capacitor deionization system moves the capacitor module, and the flow capacitor is a parallel electrode. 2 is a schematic view of an electrode of a flow capacitor module in accordance with an embodiment of the present invention. 3 is a capacitor deionization system according to an embodiment of the invention. The capacitor deionization system is intended to be a capacitor module in which a capacitor is mounted in a housing and connected in series with each other. Figure 4 shows an automated capacitive deionized water treatment system for one-pole flow capacitors. [Description of main component symbols] Flow capacitor module (10)) End electrode pair (102, 11〇) 18 1376355 2012/Month correction replacement page - Non-dash electrode (104) Spacer (106) Wire (120, 140, 330) Edge Sealing Element (203) Stripe (205) Sunshine (300) Top Cover (305) Bottom Cover (307) Insulation Panel (311) Flow Capacitor Module (402, 404, 406, 408, 410) Road (4U, 412, 413) Power Supply Pack (420) Power Supply (430) Supercapacitor Bank (440) Pump (450) Storage Tip (460, 470) (Al 'A-2> A-3'A4'A- 5'C'R-1 'R-2) 19